1296514 (1) 九、發明說明 秦 【發明所屬之技術領域】 本發明,係有關在沖水馬桶等之使用水的場所’爲了 去除髒污而使用,且於使用後可丟棄於水中的水解性之清 • 掃用品。 【先前技術】 # 於以下之專利文獻1,揭示有關於使用在清掃沖水馬 桶之用後即棄型廁所掃除刷頭的發明。 該廁所清掃刷頭,是使用由其爲木質紙漿之短纖維以 及CMC等之黏劑所形成的紙,於該紙形成複數個切口, 並且將該紙捲成刷頭狀。上述廁所清掃刷頭,被固定於紙 製之手持部的前端部。在使用上述廁所清掃刷頭擦拭便器 後,將廁所清掃刷頭連同手持部丟棄於沖水馬桶之中,使 其在水中分解。又,也記載有爲了調整紙溶解之時間,而 • 於刷頭表面施有蠟處理。 〔專利文獻1〕日本特開昭62- 1 8 683 3號公報 【發明內容】 〔發明所欲解決之技術問題〕 於專利文獻1之專利說明書,其主旨記載有清掃便器 之時間爲從1 〇秒至2 0秒左右之短時間內,故構成廁所清 掃刷頭之紙,須能在溶解於水之前完成清掃。 但是,藉由用水溶性之CMC把木質紙漿固定的紙所 -4- (2) 1296514 形成之廁所清掃刷頭,在便器之清掃中,由於一碰觸到水 即變膨潤而強度極端降低,故難以擦掉附著於便器之髒污 。又於刷頭施有蠟處理者,由於蠟成分會抑制紙的分解, 故刷頭在淨化槽內等直至分解的時間需要很長。 又,把切有切口的紙捲起來而形成之廁所清掃刷頭, 由於剛性較低,故難以用該刷頭擦拭便器等,無法有效除 去附著於便器等之髒污。 本發明爲解決上述以往之課題者,其目的爲提供一種 可有效拭取附著於沖水馬桶之便器等的髒污之水解性清掃 用品。 又本發明,其目的爲提供一種在擦拭便器等時之強度 很高,可有效發揮去除髒污之效果,而且於使用後可在較 短的時間內在水中分散的水解性之清掃用品。 〔解決問題之技術手段〕 本發明,係針對於可在水中分散的水解性之清掃用品 ,其特徵爲: 具備有其藉由水可分散之纖維被壓縮而成的纖維壓縮 體。 使用於本發明的水解性之清掃用品的纖維壓縮體,由 於其剛性很高,故藉由把該纖維壓縮體於便器等之被清掃 部上用力擦拭,可有效除去被清掃部之髒污。又,纖維壓 縮體,爲藉由水可分散的纖維之集合體,故承接大量之水 時,纖維會在水中支離分散。 -5 - (3) (3)1296514 又,構成纖維壓縮體之纖維,爲使用氫鍵結合、藉由 水溶性接著劑之接著、纖維交織中之至少1個手段而接合 〇 又本發明,爲設置有以可裝卸自如之方式保持上述纖 維壓縮體之握桿者。 在用握桿保持住清掃用品之保持部’用清掃部進丫了擦 拭清掃後,藉由把清掃用品從握桿卸下並丟棄於沖水馬桶 內等,手不用碰觸使用後之清掃用品,便可簡單丟棄。由 於被丟棄於水中的僅爲清掃用品,故該清掃用品可在水中 短時間內被分解。 本發明,例如其纖維壓縮體,一部分爲壓縮部而其他 之部分爲非壓縮部,壓縮部是被保持於握桿地使用。 於該構成,由於可藉由非壓縮部清掃便器等之被清掃 部,故擋接於被清掃部之觸感很柔軟,藉由非壓縮部可有 效清掃較寬之範圍。而且由於保持部之側爲壓縮部,故整 體之剛性很高,於清掃中不會有變軟垮掉的情形,清掃時 的觸感會變得良好。 本發明,爲形成有將水解性薄片搓捻而成的繩體,複 數條繩體被壓縮,形成有上述纖維壓縮體者。 例如,複數條上述繩體被捲起來後被壓縮,而形成有 上述纖維壓縮體。 若使用將複數條繩體予以壓縮而成之纖維壓縮體時, 於清掃中被水弄溼時,各個繩體會各自分離,由於每個繩 體都會貢獻其去除髒污之力,故可有效清掃較寬之範圍。 -6 - (4) 1296514 或是,本發明,爲其上述纖維壓縮體,是纖維被積層 並被壓縮成薄片狀或塊狀者。 此時,以搓捻水解性薄片而成之繩體,以與上述薄片 狀或是塊狀之纖維壓縮體倂用爲理想。 • 於該構成,可使用薄片狀或塊狀的纖維壓縮體,除去 . 頑固附著於便器等之髒污,繩體柔軟變形可發揮除去較寬 之範圍的髒污之效果。 • 例如,形成繩體之上述水解性薄片,爲其纖維長度在 2 0mm以下之纖維所交織而成的纖維交織不織布。 若用纖維交織不織布形成繩體時,可提高繩體之表面 強度,於清掃時會變得不易破損。 理想爲,上述繩體,是使用其纖維長度在20mm以下 之纖維所交織而成的纖維交織不織布,以及由纖維素系纖 維所形成之水解紙所構成。 若把纖維交織不織布及水解紙一同搓捻形成繩體時, • 藉由水解紙之纖維的氫鍵結合力,易於維持於乾燥時之搓 捻後的形狀。又,碰到水而於紙產生鬆弛時,可藉由不織 布之纖維交織保持強度。 又本發明,亦可爲其上述薄片狀或塊狀之纖維壓縮體 ,是被水解性之外裝薄片包住者。 於該構成,藉由水解性之外裝薄片,被清掃部被擦拭 而被去除髒污,不過設置有作爲芯材之纖維壓縮體,故可 抑制被水弄溼時清掃用品軟化或垮掉。 此時,上述外裝薄片,以其爲纖維長度在2 0mm以下 -7- (5) 1296514 之纖維所交織而成的纖維交織不織布較理 例如,上述纖維交織不織布,爲由紙 長度在20mm以下之其他的纖維所構成者 〔發明之效果〕 譬 本發明的水解性之清掃用品,因使用 縮體,故擦拭便器等時,不會破損變形, 。而且於使用後若丟棄於水中時,纖維會 散,易於在較短時間內水解。 【實施方式】 第1圖爲顯示本發明的水解性之清掃 桿上的狀態之立體圖,第2圖乃至第4圖 1圖所示之被保持於握桿上的第1實施形 掃用品之製程的立體圖,第5圖乃至第] 解性之清掃用品的另一實施形態之立體匱 )(B ) ( C )爲依構造別顯示構成繩體 〇 第4圖本爲顯示發明之第1實施形態 用品1。該清掃用品1,具備有保持側端彳 端部3。 第1圖所示之握桿1 2 0,爲於合成樹 的前端部一體形成有支持部1 22,並設ί 122相向之合成樹脂製的壓押部123。支彳 想。 漿纖維及其纖維 爲。 強度高之纖維壓 可有效去除髒污 從壓縮狀態變鬆 用品被保持於握 ,爲依序顯示第 態之水解性的清 ί 4圖,爲顯示水 1,第15圖(A 之搓繩的說明圖 的水解性之清掃 部2以及清掃側 脂製之柄部1 2 1 置有與該支持部 if部122的支持 -8- (6) 1296514 面爲平坦面,壓押部123之與支持部122相向的內面爲平 坦面,壓押部1 2 3爲與支持部1 22平行相向。於壓押部 123 —體形成有控制桿124,該控制桿124,在被形成於 柄部121的托架121a處,夾介軸125以可轉動自如之方 式被支撐著。於上述控制桿1 24之上部以可轉動自如之方 式連接有操作金屬線126。 於上述軸125設置有扭簧(圖示省略),藉由該扭簧 ,控制桿1 24以軸1 25爲支點被朝向逆時針方向彈推,壓 押部1 23被朝向接近支持部1 22之方向彈推。於柄部1 2 1 之上部設置有操控部,於該操控部設置有操作控制桿。上 述操作金屬線1 26爲較粗的金屬線,其上端連接有上述操 作控制桿。若將操作控制桿朝上拉,則控制桿1 24會回動 而壓押部1 23會從支持部1 22離開。此時,若將清掃用品 1之保持側端部2放入於支持部1 22與壓押部1 23之間, 再放開操作控制桿,則藉由上述扭簧的彈推之力,清掃用 品1之保持側端部2會被夾於支持部1 2 2與壓押部1 2 3之 間。 藉由清掃用品1在被保持於握桿1 2 0的狀態下,用清 掃用品1之清掃側端部3擦拭便器等之被清掃部,可去除 附著於便器等之表面的髒污。此時亦可用積留於便器內的 水弄溼清掃部1來進行擦拭。清掃作業結束後,藉由將上 述操作控制桿提起,解除由壓押部1 23所產生之按壓力, 而手不用碰觸清掃用品1,便可將該清掃用品1丟棄於便 器內。 -9 - (7) 1296514 第4圖所示之清掃用品1,爲使用被集成束之由可分 散於水的纖維所形成之複數條繩體4被壓縮而成的纖維壓 縮體1 1所構成。根據第2圖乃至第4圖說明清掃用品1 之製造方法。 如第2圖(A )所示,將1條繩體4或複數條繩體4 成捲筒狀體1 〇。此時如第2圖(B)所示般,在設定了中 心線〇與半徑R垂直相交的假想圓HC後,沿著其半徑方 向朝向相對於上述半徑R爲逆時針的方向僅傾斜0 1之繞 捲方向α,繞捲繩體複數圈。其後,沿著該半徑方向朝向 相對於上述半徑R爲順時針的方向僅傾斜0 2之繞捲方向 冷,繞捲複數圈。藉由重覆朝向α方向之複數圈繞捲以及 朝向/3方向之複數圈繞捲,可製得第2圖(Α)所示之筒 狀體1 〇。構成該筒狀體1 〇之繩體是以相互交叉之狀態被 繞捲。 將第2圖(A)所示之筒狀體1 〇藉由燙壓機,朝直 徑方向給予壓扁的力F予以壓縮而製得纖維壓縮體1 i。 此時之壓力爲2000〜6000kPa左右,例如爲3920kPa(40 kgf/cm2 )。壓縮時間爲1〜5秒左右。此時之加壓爲在常 溫下進行。或亦可加熱加壓。壓縮後之纖維壓縮體11, 藉由構成繩體4之纖維的機械性集合力及氫鍵結合力維持 壓縮狀態。爲了藉由氫鍵結合力使纖維結合,作爲構成繩 體4之纖維’以使用在纖維表面具備有氫氧基的天然纖維 或是再生纖維素纖維爲理想。又,爲了提高氫鍵結合力, 亦可用噴霧器等給予筒狀體10水分後再加熱壓縮。又, -10- (8) 1296514 亦可藉聚乙烯醇(PVA )或聚丙烯酸(paa )或羧甲基纖 維素(CMC )等之水溶性黏劑使繩體4彼此間接著來提高 乾燥強度。 第3圖所示之纖維壓縮體n,由於是將筒狀體1 〇朝 向直徑方向壓扁壓縮,故於兩端部,露出有繩體4被壓扁 狀態的環部4a。可將第3圖所示之纖維壓縮體π直接作 爲水解性之清掃用品使用,不過於該實施形態,爲把纖維 壓縮體1 1在繞捲之中心線〇的位置上切斷成1 /2的大小 ’製造了 2個第4圖所示之清掃用品丨。第4圖所示之清 掃用品1,於保持側端部2之處出現有複數條繩體4之切 斷端面4 b,於清掃側端部3處出現有複數個於被壓扁狀 態的上述環部4a。 上述繩體4爲將水解性薄片如第1 5圖(A )所示般 朝向一方向搓捻,而高密度地構成者。水解性薄片爲由纖 維長度在2 0 m m以下的纖維所構成,在沖水馬桶內或淨化 槽內承接大量之水時,纖維彼此間可在短時間內支離分散 者。水解性薄片,爲僅將紙漿纖維予以抄紙而纖維間藉由 氫鍵結合力而接合者,或紙漿纖維及嫘縈纖維一同被抄紙 而纖維間藉由氫鍵結合力而接合的水解紙。或,亦可使用 藉由聚乙烯醇(PVA )或聚丙烯酸(PAA )或羧甲基纖維 素(CMC )等之水溶性黏劑接著纖維彼此之水解紙。 在將此等水解紙搓捻後之狀態下,藉由氫鍵結合力可 維持繩體4之形態,或是在將水解紙搓捻後,給予上述水 溶性黏劑,可維持繩體4之形態。 -11 - (9) 1296514 又’亦可使用對紙漿纖維施以耐水處理,使親水度稍 微降低’並將該紙漿纖維藉由水溶性黏劑予以接合的水解 性薄片。由該水解性薄片所形成之繩體4,於清掃時即使 被水弄溼,也易於保持繩子之形態。 第1 5圖(A ) ( B ) ( C),爲依構造別顯示用以形 成上述繩體4之搓繩4A、4B、4C之更理想之例。使用於 清掃用品1的繩體4,爲由搓繩4 A、4 B、4 C之任1種所 構成。或作爲清掃用品1之繩體4,亦可組合2種類以上 的搓繩4A、4B、4C來使用。 第1 5圖(A )所示之搓繩4 A,爲將特定寬幅(例如 寬幅尺寸爲2 0〜1 0 0 m m )之帶狀的水解性薄片8朝向一 方向撚捻加工而搓成者。 爲了保持搓繩4A之濕潤時的強度,水解性薄片8, 爲水解性之纖維交織不織布。水解性之纖維交織不織布, 可藉由將纖維長度在2 0 m m以下之纖維積層於網狀等之多 孔板的輸送帶上,並藉由噴射水流處理,使纖維間交織而 形成。 上述纖維交織不織布,例如爲由纖維長度在2 0 m m以 下且藉由噴射水流可交織的纖維,以及紙漿纖維所構成。 若由紙漿纖維,以及纖維長度在2 Omm以下之其他的纖維 不織布所構成時’藉由噴射水流處理,上述其他纖維會交 織,並且紙漿纖維彼此間以及紙漿纖維與上述其他的纖維 間會產生氫鍵結合。該纖維交織不織布,藉由紙漿纖維之 氫鍵結合力可維持乾燥時之高強度且可維持搓捻形狀。又 -12- (10) 1296514 於濕潤時,藉由上述其他的纖維彼此間之交織力可維持較 高之表面強度。由於當被丟棄於水中而承受大量之水時, 會藉由紙漿纖維之分離而造成繩體搓捻之鬆散,上述其他 的纖維之交織也易於變鬆散,故纖維彼此間可在較短時間 內分散。 作爲纖維長度在20mm以下且藉由噴射水流處理而可 交織的其他之纖維者,以生物分解性之纖維爲理想,並以 使用黏膠嫘縈、溶劑紡絲嫘縈、複纖嫘縈、銅氨嫘縈、藻 酸嫘縈等之再生纖維素纖維爲理想。作爲纖維長度在 2 0mm以下且藉由噴射水流處理會交織之其他的纖維,亦 可使用聚對苯二甲酸乙酯(PET )纖維、尼龍纖維、聚丙 烯(PP )纖維等之合成樹脂纖維。 又,作爲再加於紙漿纖維上,或代替紙漿纖維者,亦 可使其含有麻、綿等之天然纖維,或甘蔗渣、香蕉、鳳梨 、竹子及其他之天然纖維。 再者,把其爲水溶性樹脂之聚乙烯醇(PVA )纖維, 或是水溶性或水膨潤性之羧甲基纖維素(CMC )作爲黏劑 予以加入,可提高乾燥時的強度,且亦可易於維持搓捻形 狀。或是,可使用把纖維長度在3〜7mm左右之嫘縈予以 精煉,於表面剝離而形成其纖維長度在1 mm以下之多數 微纖維的原纖維化嫘縈,亦可使用把纖維長度在20mm以 下的纖維及該原纖維化嫘縈予以濕式抄紙,其後施以噴射 水流處理之纖維交織不織布。該不織布,其纖維長度在 2 0mm以下的纖維會交織,並且藉由原纖維化嫘縈之氫鍵 -13- (11) 1296514 結合力’纖維被堅固地固定著,故可提高在乾燥狀態及濕 潤狀態下的強度,特別是乾燥時之強度很高,故易於維持 被用力搓捻而成之繩子的形狀。 形成搓繩4A之纖維交織不織布,以含有10質量%以 上的紙漿纖維等之天然纖維,再含有1 0質量%以上之如 嫘縈纖維等般經過噴射水流處理便可交織之纖維長度在 2 0mm以下的其他纖維爲理想。藉由含有〗〇質量%以上的 天然纖維,可加強用力搓捻而構成搓繩時之氫鍵結合力, 又藉由含有1 〇質量%以上之交織的纖維,可提高濕潤時 之強度。 由纖維交織不織布所形成的水解性薄片8,其基重以 在30g/m2以上120g/m2以下爲理想,薄片厚度以在〇.lmm 以上0.5mm以下爲理想。 於第1 5圖(A ),是使用1片之其爲纖維交織不織 布的水解性薄片8來形成搓繩4A,不過亦可重疊複數片 該水解性薄片8來形成搓繩。使用於第4圖所示之清掃用 品1的各個繩體4是作成粗的,雖爲了提高清掃時之強度 ,只要增大1片之水解性薄片8的基重及厚度即可,但1 片之水解性薄片8之基重及厚度若增加過大,則於撚捻製 程會變得不易搓捻,因此,於此場合,若使用複數片水解 性薄片8形成搓繩4A,可將搓繩作成粗且剛性高者,而 且在承接大量之水而搓捨狀態變鬆散時,易於被分離成各 個之水解性薄片8再水解。 第15圖(B)所示之搓繩4B,爲將其爲纖維交織不 •14- (12) 1296514 織布的上述水解性薄片8,與水解紙9予以重疊,再將水 解性薄片8及水解紙9 一同搓捻而形成。水解紙9,爲將 紙漿纖維等之天然纖維予以抄紙,或將紙漿纖維等之天然 纖維’及螺縈纖維等之再生纖維素纖維予以抄紙而藉由纖 維彼此間之氨鍵結合力來發揮其強度者。 右將水解性薄片8及水解紙9重疊並一同搓捨時,由 於其爲纖維交織不織布的水解性薄片8之強度很高,故可 用力且確實地搓捻。於搓捻後,藉由構成水解紙9的纖維 之氫鍵結合力以及纖維間之機械性結合力,可維持於乾燥 時搓捻之形狀。因此,密度高之搓繩4 B易於加工,並可 維持該形狀。若用高密度搓繩4B,形成第4圖所示之清 掃用品1的繩體4時,即使於含有少量水分之狀態,剛性 高之繩體4也可刮取附著於便器等之表面的髒污。又,若 被丟棄於沖水馬桶內等而承接大量的水時,構成水解紙9 之纖維會變鬆散,其搓捻狀態也開始鬆散,藉此會造成水 解性薄片8之鬆散。 若將水解性薄片8及水解紙9予以組合搓捻,則於搓 繩4 B之表面可形成多數之凹凸,可提高去除髒污之效果 。又,搓繩4B,爲使用複數片之水解性薄片8及水解紙9 之至少一方而構成。 第15圖(B )所示之搓繩4B,其水解紙9被著色成 藍色或紅色等白色以外的顏色。其爲纖維交織不織布的水 解性薄片8是由白色纖維所形成。藉由把水解性薄片8及 水解紙9予以重疊搓捻,著色部及白色部交互換位而顏色 •15- (13) 1296514 交錯,外觀會變得較好看。 加工第1 5圖(B )所示之搓繩4 B時,代替上述水解 紙9可使用氣流成型不織布。氣流成型不織布,是把紙漿 纖維藉由氣流成型法予以積層而形成纖維織網,並使用 PVA等之水溶性黏劑將纖維間接著者。該氣流成型不織布 ,其纖維密度爲〇.〇4〜0.700g/cm3左右之低密度而厚度爲 0.3〜5mm左右之高膨鬆度。又可於短時間內在水中分解 。由於該氣流成型不織布具備有緩衝性,故藉由將氣流成 型不織布及其爲纖維交織不織布的水解性薄片8 —同撚捻 加工,可製得具彈性之搓繩。 第15圖(C )所示之搓繩4C,爲搓捻1片水解紙9 ,或複數片水解紙9,或上述氣流成型不織布,或將水解 紙9及氣流成型不織布予以重疊搓捻來形成芯部,並於該 芯部之周圍,一面繞捲其爲纖維交織不織布的水解性薄片 8再一面搓捻者。該搓繩4C ’其芯部會發揮強力之氫鍵結 合力而維持撚捻狀態,爲高密度者。於芯部之周圍,由於 繞捲有濕潤強度高之水解性薄片8,故可提高繩體4之表 面強度,於濕潤狀態下進行擦拭時易於維持繩體4之形狀 。又若承接大量的水時’構成芯部之水解紙9或是氣流成 型不織布會分解,藉此造成水解性薄片8之搓捻狀態鬆散 ,會變得可於短時間內水解。 上述搓繩4A、4B、4C之搓捻次數’爲形成搓繩之薄 片每長2 5 cm以4〜3 0次爲理想。比上述次數少,則密度 會變太低,不能承受進行擦拭作業時之摩擦力’會易於破 -16- (14) 1296514 損。又若超過上述次數,則於搓捻作業中薄片負荷過重, 有斷掉之虞。又搓繩4A、4B'4C之粗度以1〜10mm爲 理想。只要於該範圍內,則用繩體4擦拭時之觸感會很好 ,而丟棄於沖水馬桶等之時,於排水管內不會阻塞,易於 丟棄。 該清掃用品1,爲於使用時其保持側端部2,被保持 於第1圖所示之握桿120之支持部122與壓押部123間地 使用。清掃用品1,爲由纖維壓縮體1 1所形成,於乾燥 時繩體4不會分離。使清掃用品1保持於握桿1 20後,清 掃用品1即使被水弄溼,但此時清掃用品1被支持部1 22 及壓押部1 23夾住,故清掃中於保持側端部2處繩體4不 會分離。第4圖所示之清掃用品1,相對於中心線〇處之 斷面,繩體4爲傾斜延伸,由於繩體4彼此爲在交叉之狀 態下被壓縮,故整體之剛性變高,可將清掃側端部3用力 擦拭於便器等之被清掃部,可藉由清掃側端部3除去被清 掃部之髒污。 於清掃用品1之清掃側端部3處,存在有多數之繩體 4的環部4 a,由於在清掃側端部3處沒有出現繩體4之切 斷端面4b,故清掃側端部3即使被水弄溼,亦可防止繩 體4變得過於鬆弛。於擦拭便器等之被清掃部時,若給予 其較多之水,則其壓縮狀態會被緩和,環部4 a相互獨立 在被清掃部上來回摩擦,藉由各個環部4a,可清掃較寬 範圍之被清掃部。 由於第2圖所示之筒狀體1 0爲繞捲較長之繩體4而 -17- (15) 1296514 形成,故於形成筒狀體1 〇之製程,繩體4之搓捻不易產 生鬆動。又由於在形成筒狀體1 0後予以壓縮作成纖維壓 縮體1 1,故作爲清掃用品在流通保管之期間,可防止繩 體4之搓捻變鬆弛。由於將第3圖所示之纖維壓縮體1 1 對半切而形成各個清掃用品1,故於該清掃用品1,繩體 4被切斷成複數個單位。各個繩體4之單位的長度,爲從 清掃用品1之保持側端部2至清掃側端部3之長度的2倍 左右。因此,若於使用後被丟棄於沖水馬桶內,則藉由大 量之水其壓縮狀態會變鬆驰,再者,各個繩體4之單位會 變得易於分散。而分散後之各個繩體4會水解。 從清掃用品1之保持側端部2至清掃側端部3之長度 尺寸,爲20〜100mm左右,不過並非被限定於此。 分散成各個單位的繩體4之水解時間,爲在把1條繩 體4之長度作成120mm,並根據JIS P 45 0 1 (廁所衛生紙 散開難易度測試)來測量時,以在7 0 0秒以下爲理想,較 佳爲在6 〇 0秒以下。又更佳爲在3 0 0秒以下。上述測量, 爲在300毫公升容量之燒杯內,倒入300毫公升之水溫爲 2 0 ± 5 C的離子交換水,將繩體4投入離子交換水內後,在 水中以600rpm之回轉數使回轉子回轉,將繩體與離子交 換水一同攪拌後,測量繩體之形態消散甚至不殘留薄片狀 之形態’直至分散成原構成纖維之時間者。 第5圖(A ) ( B )爲顯示本發明之第2實施形態的 水解性之清掃用品2 2的製造方法之立體圖。1296514 (1) Inventive description Qin [Technical field to which the invention pertains] The present invention relates to the use of water in a flush toilet or the like, in order to remove dirt, and can be discarded in water after use. Qing • Sweeping supplies. [Prior Art] # In the following Patent Document 1, an invention relating to the use of a disposable toilet brush after the flushing of the flushing bucket is disclosed. The toilet head is a paper formed by using a short fiber of wood pulp and an adhesive such as CMC, and a plurality of slits are formed in the paper, and the paper is wound into a brush head shape. The toilet cleaning brush head is fixed to the front end portion of the hand-held portion of the paper. After wiping the toilet using the above-described toilet cleaning brush head, the toilet cleaning brush head and the hand-held portion are discarded in the flush toilet to be decomposed in the water. Further, it is described that in order to adjust the time during which the paper is dissolved, • wax treatment is applied to the surface of the brush head. [Patent Document 1] Japanese Laid-Open Patent Publication No. SHO-62-108 No. 683 No. PCT Publication No. Sho. In the short time of about 20 seconds, the paper that constitutes the toilet cleaning brush must be cleaned before it dissolves in water. However, the toilet cleaning brush head formed by the paper-fixed paper -4-(2) 1296514 with water-soluble CMC, in the cleaning of the toilet, is extremely swollen as soon as it touches the water, and the strength is extremely lowered. It is difficult to wipe off the dirt attached to the toilet. Further, when the wax is applied to the brush head, since the wax component suppresses the decomposition of the paper, it takes a long time for the brush head to be in the purification tank until the decomposition takes place. Further, since the toilet cleaning head formed by winding the cut paper is low in rigidity, it is difficult to wipe the toilet with the brush head or the like, and it is not possible to effectively remove dirt adhering to the toilet or the like. The present invention has been made to solve the above problems, and an object of the invention is to provide a hydrolyzable cleaning article which can effectively wipe the dirt attached to a toilet of a flush toilet or the like. Further, an object of the present invention is to provide a hydrolyzable cleaning article which is high in strength when wiping a toilet or the like, can effectively exhibit the effect of removing dirt, and can be dispersed in water in a short period of time after use. [Means for Solving the Problems] The present invention relates to a hydrolyzable cleaning article which can be dispersed in water, and is characterized in that it has a fiber compression body in which fibers which are dispersible by water are compressed. Since the fiber-compressed body of the water-disinfecting cleaning material of the present invention has high rigidity, it is possible to effectively remove the dirt of the cleaning portion by wiping the fiber-compressed body to the cleaning portion of the toilet or the like. Further, since the fiber compact is a collection of fibers dispersible by water, the fibers are dispersed and dispersed in the water when a large amount of water is taken. -5 - (3) (3) 1296514 Further, the fibers constituting the fiber-compressed body are joined by at least one of hydrogen bonding, followed by water-soluble adhesive, and fiber interlacing, and the present invention is A gripper that holds the above-mentioned fiber compression body in a detachable manner is provided. After the cleaning portion of the cleaning article is held by the grip bar, the cleaning device is wiped and cleaned, and the cleaning article is removed from the grip bar and discarded in the flush toilet, so that the hand does not need to touch the cleaning product after use. , you can simply discard. Since it is only a cleaning article that is discarded in the water, the cleaning article can be decomposed in a short time in the water. In the present invention, for example, a fiber compression body is partially a compression portion and the other portion is an uncompressed portion, and the compression portion is used by being held by the grip. According to this configuration, since the cleaning portion such as the toilet can be cleaned by the non-compressing portion, the touch feeling in the portion to be cleaned is soft, and the non-compressed portion can effectively clean the wide range. Further, since the side of the holding portion is a compression portion, the rigidity of the whole body is high, and it does not become soft and collapse during cleaning, and the touch feeling during cleaning becomes good. In the present invention, in order to form a rope body in which a hydrolyzable sheet is formed, a plurality of rope bodies are compressed to form the fiber compression body. For example, a plurality of the above-mentioned rope bodies are wound up and compressed, and the above-mentioned fiber compression body is formed. When a fiber compression body obtained by compressing a plurality of rope bodies is used, when the water is wetted during the cleaning, the respective rope bodies are separated, and each rope body contributes to the force of removing the dirt, so that it can be effectively cleaned. A wider range. -6 - (4) 1296514 Alternatively, in the above-mentioned fiber compression body, the fiber is laminated and compressed into a sheet shape or a block shape. In this case, it is preferable that the rope body made of the hydrolyzable sheet is used in combination with the above-mentioned sheet-like or block-shaped fiber compression body. • In this configuration, a sheet-like or block-shaped fibrous compression body can be used to remove the stains that remain stubbornly attached to the toilet, and the cords are softly deformed to exhibit the effect of removing dirt in a wide range. • For example, the hydrolyzable sheet forming the rope body is a fiber interwoven nonwoven fabric obtained by interlacing fibers having a fiber length of 20 mm or less. When the cord is formed by the fiber interlaced nonwoven fabric, the surface strength of the cord body can be increased, and it becomes less likely to be damaged during cleaning. Preferably, the rope body is composed of a fiber interwoven nonwoven fabric obtained by interlacing fibers having a fiber length of 20 mm or less, and a hydrolyzed paper formed of cellulose fibers. When the fiber interlaced nonwoven fabric and the hydrolyzed paper are twisted together to form a rope body, • the hydrogen bond strength of the fibers of the hydrolyzed paper is easily maintained in the shape after drying. Further, when water is encountered and the paper is slackened, the strength can be maintained by interlacing the fibers of the non-woven fabric. Further, in the present invention, it may be a sheet-like or block-shaped fibrous compression body which is surrounded by a hydrolyzable outer sheet. In this configuration, the surface to be cleaned by the hydrolyzable outer sheet is wiped and removed, and the fibrous compressed body as the core material is provided. Therefore, it is possible to prevent the cleaning article from being softened or collapsed when wetted by water. In this case, the outer sheet is a fiber interwoven nonwoven fabric obtained by interlacing fibers having a fiber length of 20 mm or less and 7-(5) 1296514. For example, the fiber interlaced non-woven fabric has a paper length of 20 mm or less. Manufacture of other fibers [Effects of the Invention] The hydrolyzable cleaning article of the present invention does not break and deform when the toilet is wiped by using a shrinkage. Moreover, if it is discarded in water after use, the fibers will be scattered and it is easy to hydrolyze in a short time. [Embodiment] Fig. 1 is a perspective view showing a state of a hydrolyzable cleaning rod of the present invention, and a process of the first embodiment of the cleaning article held on the grip bar shown in Fig. 2 to Fig. 4; FIG. 5 is a perspective view showing another embodiment of the cleaning article of the present invention. (B) (C) showing the structure of the rope according to the structure. FIG. 4 is the first embodiment of the invention. Supplies 1. The cleaning article 1 is provided with a holding side end end portion 3. The grip 1 120 shown in Fig. 1 has a support portion 1 22 integrally formed at the front end portion of the synthetic tree, and a pressing portion 123 made of synthetic resin facing the 126. Support, think. Pulp fiber and its fiber are. The high-strength fiber pressure can effectively remove the dirt. The compressed material is kept in the grip from the compressed state, and the hydrolyzable state of the first state is displayed in order to display the water 1, Fig. 15 (the reins of A) In the explanation, the hydrolyzable cleaning portion 2 and the cleaning-side grease shank portion 1 2 1 are provided with the support -8-(6) 1296514 surface of the support portion if portion 122 as a flat surface, and the nip portion 123 is supported. The inner surface of the portion 122 facing the flat surface is a flat surface, and the pressing portion 1 2 3 is parallel to the supporting portion 1 22 . The pressing portion 123 is integrally formed with a control rod 124 formed on the handle portion 121 . The carrier shaft 125 is rotatably supported at the bracket 121a. The operating wire 126 is rotatably connected to the upper portion of the control lever 1 24. The shaft 125 is provided with a torsion spring ( The illustration is omitted, and by the torsion spring, the lever 1 24 is pushed in the counterclockwise direction with the shaft 1 25 as a fulcrum, and the pressing portion 1 23 is pushed toward the support portion 1 22 in the direction of the support portion 1 22 . The upper part of 2 1 is provided with a control part, and an operation lever is arranged in the control part. The above operation wire 1 26 is a thick metal wire, and the above operation lever is connected to the upper end. If the operation lever is pulled upward, the lever 1 24 will be reversed and the pressing portion 1 23 will be separated from the support portion 1 22 . When the holding side end portion 2 of the cleaning article 1 is placed between the support portion 1 22 and the pressing portion 1 23, and the operation lever is released, the cleaning article 1 is swept by the force of the torsion spring. The holding side end portion 2 is sandwiched between the support portion 1 22 and the pressing portion 1 2 3. By the cleaning article 1 being held by the grip 1 120, the cleaning side of the cleaning article 1 is used. The end portion 3 wipes the portion to be cleaned such as a toilet, and the dirt adhering to the surface of the toilet or the like can be removed. In this case, the cleaning unit 1 can be wetted by the water accumulated in the toilet to wipe the cleaning unit 1 after the cleaning operation is completed. Lifting the above operation lever releases the pressing force generated by the pressing portion 1 23, and the cleaning article 1 can be discarded in the toilet without touching the cleaning article 1. -9 - (7) 1296514 4 The cleaning article 1 shown in the figure is a plurality of rope bodies 4 formed by fibers which are dispersed in water by an integrated bundle. The reduced fiber compact 11 is formed. The method of manufacturing the cleaning article 1 will be described with reference to Fig. 2 to Fig. 4. As shown in Fig. 2(A), one rope body 4 or a plurality of rope bodies 4 are provided. The rolled cylindrical body 1 is 〇. At this time, as shown in Fig. 2(B), after the virtual circle HC perpendicularly intersecting the center line 〇 and the radius R is set, the radial direction is oriented along the radial direction with respect to the radius R. The counterclockwise direction is only inclined by the winding direction α of 0 1 and is wound around the winding body a plurality of turns. Thereafter, it is cooled along the radial direction in a direction clockwise with respect to the radius R, and is only inclined by 0 2 in the winding direction. Winding multiple turns. The cylindrical body 1 第 shown in Fig. 2 (Α) can be obtained by repeating the winding of the plurality of turns in the α direction and the winding of the plurality of turns in the /3 direction. The rope bodies constituting the cylindrical body 1 are wound in a state of being intersected with each other. The tubular body 1 shown in Fig. 2(A) is compressed by a pressing force in the direction of the diameter by a pressing machine to obtain a fiber-compressed body 1 i. The pressure at this time is about 2000 to 6000 kPa, for example, 3920 kPa (40 kgf/cm2). The compression time is about 1 to 5 seconds. The pressurization at this time is carried out at normal temperature. Or it can be heated and pressurized. The compressed fiber compact 11 maintains a compressed state by the mechanical collective force and hydrogen bonding force of the fibers constituting the string 4. In order to bond the fibers by the hydrogen bonding force, it is preferable to use the natural fibers or regenerated cellulose fibers having the hydroxyl group on the surface of the fibers as the fibers constituting the rope 4. Further, in order to increase the hydrogen bonding force, the tubular body 10 may be supplied with water by a spray or the like, and then heated and compressed. Further, -10-(8) 1296514 may also use a water-soluble adhesive such as polyvinyl alcohol (PVA) or polyacrylic acid (paa) or carboxymethyl cellulose (CMC) to cause the rope bodies 4 to follow each other to improve the drying strength. . In the fiber compression body n shown in Fig. 3, since the cylindrical body 1 is crushed and compressed in the radial direction, the ring portion 4a in which the rope body 4 is crushed is exposed at both end portions. The fiber compact π shown in Fig. 3 can be directly used as a hydrolyzable cleaning article. However, in this embodiment, the fiber compact 11 is cut at a position of 1 / 2 at the center line of the winding. The size of the 'made two cleaning supplies 第 shown in Figure 4. In the cleaning article 1 shown in Fig. 4, a plurality of cut end faces 4b of the plurality of rope bodies 4 are present at the holding side end portion 2, and a plurality of the above-mentioned flat state at the cleaning side end portion 3 are present. Ring portion 4a. In the above-mentioned rope body 4, the hydrolyzable sheet is formed in a high-density manner as shown in Fig. 15(A). The hydrolyzable sheet is composed of fibers having a fiber length of 20 mm or less. When a large amount of water is taken in a flush toilet or a purification tank, the fibers can be separated from each other in a short time. The hydrolyzable sheet is a hydrolyzed paper in which only the pulp fibers are paper-bonded and the fibers are joined by hydrogen bonding force, or the pulp fibers and the ray fibers are paper-bonded together, and the fibers are joined by hydrogen bonding force. Alternatively, a water-soluble adhesive such as polyvinyl alcohol (PVA) or polyacrylic acid (PAA) or carboxymethyl cellulose (CMC) may be used, followed by hydrolysis of the fibers to each other. The state of the rope body 4 can be maintained by the hydrogen bonding force in the state of the hydrolyzed paper, or the water-soluble adhesive can be imparted after the paper is hydrolyzed, and the rope body 4 can be maintained. form. -11 - (9) 1296514 Further, a hydrolyzable sheet in which the pulp fibers are subjected to water-resistant treatment to slightly lower the hydrophilicity and the pulp fibers are joined by a water-soluble adhesive may be used. The rope body 4 formed of the water-decomposable sheet is easy to maintain the shape of the rope even if it is wetted by water during cleaning. Fig. 15(a)(B)(C) shows a more preferable example of the reins 4A, 4B, and 4C for forming the above-mentioned rope body 4 according to the structure. The cord body 4 used in the cleaning article 1 is composed of any one of the reins 4A, 4B, and 4C. Alternatively, as the cord body 4 of the cleaning article 1, two or more types of reins 4A, 4B, and 4C may be used in combination. The reins 4A shown in Fig. 15(A) are processed in a direction in which a strip-shaped hydrolyzable sheet 8 having a specific width (for example, a width of 20 to 100 mm) is processed in one direction. Adult. In order to maintain the strength when the reins 4A is wet, the hydrolyzable sheet 8 is a hydrolyzable fiber interlaced nonwoven fabric. The hydrolyzable fiber interlaced non-woven fabric can be formed by laminating fibers having a fiber length of 20 mm or less on a conveyor belt of a mesh or the like, and interlacing the fibers by a jet stream treatment. The above-mentioned fiber interlaced nonwoven fabric is, for example, composed of fibers having a fiber length of less than 20 m and being interlacable by a jet of water, and pulp fibers. When pulp fibers and other fiber nonwoven fabrics having a fiber length of 2 Omm or less are formed, the other fibers are interlaced by the jet stream, and hydrogen is generated between the pulp fibers and between the pulp fibers and the other fibers. Key combination. The fiber is interwoven with a non-woven fabric, and the hydrogen bonding force of the pulp fibers maintains the high strength at the time of drying and maintains the shape of the crucible. Further -12-(10) 1296514 When wet, the higher surface strength can be maintained by the interlacing force of the other fibers described above. Since the rope body is loosened by the separation of the pulp fibers when it is discarded in the water, the interlacing of the other fibers is liable to become loose, so that the fibers can be separated from each other in a short time. dispersion. As other fibers which have a fiber length of 20 mm or less and can be interlaced by a jet stream treatment, it is preferable to use a biodegradable fiber, and to use a viscose crucible, a solvent spinning crucible, a fibril, and a copper. Regenerated cellulose fibers such as ammonia amide and strontium alginate are preferred. As the other fibers having a fiber length of 20 mm or less and interlaced by a jet stream treatment, synthetic resin fibers such as polyethylene terephthalate (PET) fibers, nylon fibers, and polypropylene (PP) fibers may be used. Further, as the resin fiber to be added to or substituted for the pulp fiber, natural fibers such as hemp and cotton, or bagasse, banana, pineapple, bamboo, and other natural fibers may be contained. Furthermore, polyvinyl alcohol (PVA) fiber which is a water-soluble resin, or water-soluble or water-swellable carboxymethyl cellulose (CMC) is added as an adhesive to improve the strength during drying, and The shape of the crucible can be easily maintained. Alternatively, it can be refined by using a crucible having a fiber length of about 3 to 7 mm, and the surface is peeled off to form a fibrillation crucible of a plurality of microfibers having a fiber length of 1 mm or less, and the fiber length can be 20 mm. The following fibers and the fibrillated ruthenium were subjected to wet papermaking, and then subjected to a fiber interlaced nonwoven fabric treated by a jet stream. In the non-woven fabric, fibers having a fiber length of 20 mm or less are interlaced, and the fibers are firmly fixed by the fibrillation hydrogen bond-13-(11) 1296514, so that the drying state can be improved. The strength in the wet state, particularly the strength during drying, is high, so it is easy to maintain the shape of the rope which is hardened by force. The fiber-interwoven non-woven fabric of the reins 4A is made of a natural fiber containing 10% by mass or more of pulp fibers, and further containing 10% by mass or more of a fiber such as yttrium fiber, which can be interlaced by a jet stream to have a length of 20 mm. The following other fibers are ideal. When the natural fiber is contained in an amount of 5% by mass or more, the hydrogen bonding force at the time of forming the reel can be enhanced, and the strength at the time of wetting can be improved by containing the interlaced fiber of 1% by mass or more. The water-decomposable sheet 8 formed of the fiber-entangled nonwoven fabric preferably has a basis weight of 30 g/m2 or more and 120 g/m2 or less, and preferably has a sheet thickness of not more than 0.1 mm and not more than 0.5 mm. In the fifth aspect (A), the one piece of the hydrolyzable sheet 8 which is a fiber interwoven nonwoven fabric is used to form the reel 4A, but the plurality of sheets of the hydrolyzable sheet 8 may be stacked to form a rein. Each of the rope bodies 4 used in the cleaning article 1 shown in Fig. 4 is made thick, and the base weight and thickness of one sheet of the water-decomposable sheet 8 may be increased in order to increase the strength during cleaning. When the basis weight and the thickness of the water-decomposable sheet 8 are excessively increased, the crucible process becomes difficult to form. Therefore, in this case, if a plurality of hydrolyzable sheets 8 are used to form the reins 4A, the reins can be made. It is thick and rigid, and when it is subjected to a large amount of water and the state of the shed is loose, it is easily separated into individual hydrolyzable sheets 8 and hydrolyzed. The reel 4B shown in Fig. 15(B) is a hydrolyzable sheet 8 which is woven with a fiber interlaced without 14-(12) 1296514, and is superposed on the hydrolyzed paper 9, and the hydrolyzable sheet 8 and The hydrolyzed paper 9 is formed together. The hydrolyzed paper 9 is obtained by paper-making a natural fiber such as pulp fibers, or by reproducing a natural fiber such as pulp fibers and a regenerated cellulose fiber such as snail fibers, and by utilizing the ammonia bond strength between the fibers. Intensity. When the hydrolyzable sheet 8 and the hydrolyzed paper 9 are superposed on each other and are stacked together, the hydrolyzable sheet 8 which is a fiber interwoven nonwoven fabric has a high strength, so that it can be forcefully and surely rubbed. After the crucible, the shape of the crucible during drying can be maintained by the hydrogen bonding force of the fibers constituting the hydrolyzed paper 9 and the mechanical bonding force between the fibers. Therefore, the high density reins 4 B are easy to process and can maintain the shape. When the cord body 4 of the cleaning article 1 shown in Fig. 4 is formed by using the high-density reel 4B, the cord body 4 having a high rigidity can scrape the dirt adhering to the surface of the toilet or the like even in a state containing a small amount of water. Sewage. Further, when a large amount of water is taken in the flush toilet or the like, the fibers constituting the hydrolyzed paper 9 become loose, and the crepe state is also loosened, whereby the hydrolyzable sheet 8 is loosened. When the hydrolyzable sheet 8 and the hydrolyzed paper 9 are combined, a large number of irregularities can be formed on the surface of the crepe 4B, and the effect of removing dirt can be improved. Further, the reins 4B are configured to use at least one of the hydrolyzable sheet 8 and the hydrolyzed paper 9 of a plurality of sheets. In the reins 4B shown in Fig. 15(B), the hydrolyzed paper 9 is colored in a color other than white such as blue or red. The hydrolyzable sheet 8 which is a fiber interwoven nonwoven fabric is formed of white fibers. By superimposing the hydrolyzable sheet 8 and the hydrolyzed paper 9, the colored portion and the white portion are alternately transposed, and the color • 15-(13) 1296514 is interlaced, and the appearance becomes better. When the reins 4B shown in Fig. 15(B) is processed, a non-woven fabric can be formed by using an air flow instead of the above-mentioned hydrolyzed paper 9. The air-laid non-woven fabric is formed by laminating pulp fibers by a gas flow molding method to form a fiber-woven net, and indirectly infiltrates the fibers using a water-soluble adhesive such as PVA. The air-laid non-woven fabric has a fiber density of a low density of about 〜4 to 0.700 g/cm3 and a high bulk of about 0.3 to 5 mm. It can be decomposed in water in a short time. Since the air-laid nonwoven fabric is cushioned, it is possible to obtain an elastic reel by processing the air-laid nonwoven fabric and the hydrolyzable sheet 8 which is a fiber-woven interwoven fabric. The reins 4C shown in Fig. 15(C) are a sheet of hydrolyzed paper 9 or a plurality of hydrolyzed papers 9, or the above-mentioned air-laid non-woven fabric, or the hydrolyzed paper 9 and the air-laid non-woven fabric are superposed to form a crucible. The core portion is wound around the core portion, and the hydrolyzable sheet 8 which is a fiber interwoven nonwoven fabric is wound around one another. The reins 4C' have a strong hydrogen bonding force and maintain a sturdy state, which is a high density. Since the hydrolyzable sheet 8 having a high wet strength is wound around the core, the surface strength of the cord body 4 can be improved, and the shape of the cord body 4 can be easily maintained when wiping in a wet state. Further, when a large amount of water is taken up, the hydrolyzed paper 9 constituting the core or the air-laid non-woven fabric is decomposed, whereby the hydrolyzable sheet 8 is loosened and becomes hydrolyzed in a short time. It is preferable that the number of twists of the above-mentioned reins 4A, 4B, and 4C is 4 to 30 times per length of the sheet forming the reins. If the number is less than the above, the density will become too low, and the frictional force when the wiping operation cannot be carried out will be easily broken. -16- (14) 1296514 Loss. If the number of times exceeds the above-mentioned number of times, the sheet load is too heavy during the operation, and there is a break. Further, the thickness of the reins 4A and 4B'4C is preferably 1 to 10 mm. When it is within this range, the touch feeling when rubbed with the cord body 4 is good, and when it is discarded in a flush toilet or the like, it does not block in the drain pipe and is easily discarded. The cleaning article 1 is held between the support portion 122 of the grip 120 shown in Fig. 1 and the pressing portion 123 when the holding side end portion 2 is used. The cleaning article 1 is formed of a fibrous compression body 1 1 and does not separate the rope body 4 when dried. After the cleaning article 1 is held by the grip 1 20, the cleaning article 1 is wetted by water, but at this time, the cleaning article 1 is sandwiched by the support portion 1 22 and the pressing portion 1 23, so that the cleaning is performed on the holding side end portion 2 The rope body 4 does not separate. In the cleaning article 1 shown in Fig. 4, the rope body 4 extends obliquely with respect to the cross section of the center line, and since the rope bodies 4 are compressed in a state of being crossed, the overall rigidity becomes high, and the rigidity can be increased. The cleaning side end portion 3 is wiped by force on the cleaning portion such as the toilet, and the cleaning portion can be removed by the cleaning side end portion 3. At the cleaning side end portion 3 of the cleaning article 1, there is a ring portion 4a of a plurality of rope bodies 4, and since the cutting end surface 4b of the rope body 4 does not appear at the cleaning side end portion 3, the cleaning side end portion 3 is provided. Even if it is wetted by water, the rope body 4 can be prevented from becoming too slack. When the cleaning portion of the toilet or the like is wiped, if a large amount of water is given, the compressed state is relaxed, and the ring portions 4a are rubbed back and forth independently of the cleaning portion, and the respective ring portions 4a can be cleaned. A wide range of parts are being cleaned. Since the cylindrical body 10 shown in Fig. 2 is formed by winding the long rope body 4 and -17-(15) 1296514, the process of forming the cylindrical body 1 , is not easy to occur after the rope body 4 is formed. Loose. Further, since the tubular body 10 is compressed and then formed into the fiber compression body 1 1, it is possible to prevent the rope 4 from becoming slack during the storage and storage of the cleaning article. Since the fiber compact 1 1 shown in Fig. 3 is cut in half to form each cleaning article 1, the string 4 is cut into a plurality of units in the cleaning article 1. The length of each unit of the cord body 4 is about twice the length from the holding side end portion 2 of the cleaning article 1 to the cleaning side end portion 3. Therefore, if it is discarded in the flush toilet after use, the compressed state will be relaxed by a large amount of water, and the units of the respective rope bodies 4 will be easily dispersed. The dispersed ropes 4 are hydrolyzed. The length from the holding side end portion 2 of the cleaning article 1 to the cleaning side end portion 3 is about 20 to 100 mm, but is not limited thereto. The hydrolysis time of the rope body 4 dispersed into each unit is 120 mm in the length of one rope body 4, and is measured in accordance with JIS P 45 0 1 (toilet toilet paper spread difficulty test) at 700 seconds. The following is ideal, preferably below 6 〇 0 seconds. More preferably, it is below 300 seconds. The above measurement is to pour 300 milliliters of ion exchange water with a water temperature of 20 ± 5 C in a beaker of 300 milliliters capacity, and put the rope 4 into the ion exchange water, and then rotate the water at 600 rpm in water. After the rotor is rotated, the rope body is stirred together with the ion-exchanged water, and the shape of the rope body is measured to dissipate or even remain in the form of a sheet-like shape until it is dispersed into the original constituent fibers. Fig. 5(A) and Fig. 5(B) are perspective views showing a method of manufacturing the hydrolyzable cleaning article 2 2 according to the second embodiment of the present invention.
第5圖(A)所示之纖維壓縮體21,爲把第2圖(A -18- (16) 1296514 )所示之筒狀體10藉由沿著中心線〇之方向的力Fv予 以壓縮成形者。該壓縮時之條件,爲與形成第3圖所示之 纖維壓縮體1 1之時相同。 可直接將第5圖(A)所示之纖維壓縮體21保持於 握桿120作爲清掃用品使用。不過,第5圖(B )所示之 清掃用品22,是將第5圖(A )所示之纖維壓縮體21切 斷而形成。此時,可將第5圖(A)所示之纖維壓縮體21 予以2等分,亦可切成3等分,以中心線0爲中心,把 角度在1 20度的範圍者作成各個之清掃用品22。或亦可 切成4等分,以中心線〇爲中心,把角度在90度的範圍 者作成各個之清掃用品22。 該清掃用品22,其出現有繩體4之切斷端面4b的部 分被作爲保持側端部23使用,大致沿著圓周形出現的繩 體4之環部4c的部分被作爲清掃側端部24使用。 該清掃用品22,由於亦如第2圖(A )所示般被作成 繞捲繩體4而成的筒狀體1 0,再經過如第5圖(A )所示 般之將筒狀體1 〇予以壓縮的製程而被形成,故於製造過 程中繩體4之搓捻不易鬆弛,又於流通或保管時,繩體4 之搓捻也不易鬆弛。第5圖(B )所示之清掃用品22,由 於其繩體4被切斷成尺寸較短之複數個單位,故將其沖水 馬桶沖走等而承接大量之水時,會分離爲各個之繩體4, 各個繩體4之搓捻再變鬆散而纖維於水中分散。 第6圖爲顯示本發明之第3實施形態的水解性之清掃 用品3 1的立體圖。 -19- (17) 1296514 該清掃用品3 1,爲把特定長度之上述繩體4於該長 度尺寸之中點處轉折使其對折,並使折曲部4 d朝向一方 向再將複數條之繩體4排齊成束,將該束繩體4予以壓縮 而成者。此時之壓縮條件,爲與製造第3圖所示之纖維壓 縮體1 1及第5圖(A )所示之纖維壓縮體21時之條件相 同。 第6圖所示之清掃用品3 1,其將繩體4之切斷端面 4g排齊之側爲保持側端部32,其將折曲部4d排齊之側爲 清掃側端部3 3。於含有上述保持側端部3 2的特定長度範 圍內之成束的繩體4予以壓縮形成有壓縮部34’含有清 掃側端部3 3的特定長度之範圍,成爲繩體4沒有被壓縮 之非壓縮部3 5。上述壓縮部3 4被作爲保持部,而被夾於 第1圖所示之握桿120的之支持部122與壓押部123之間 利用。 於壓縮部3 4處,由於各個繩體4被壓縮固定’故於 保管時或運搬時等,乾燥狀態之清掃用品3 1不會四散分 解,可隨時維持其形狀。由於壓縮部3 4被支持部1 22及 押構件1 23保持著,故於使用時碰到水,壓縮部34之壓 縮即使變鬆弛,亦可維持清掃用品3 1之形態。於清掃側 端部3 3,由於各個繩體4之折曲部4d爲自由狀態,故藉 由該折曲部4d之獨立自由動作,可有效清掃被清掃部之 較寬的範圍。 若於使用後丟棄於沖水馬桶內而承接大量之水時,清 掃用品3 1會被分離爲各個之繩體4,繩體4之搓捻變更 - 20- (18) 1296514 鬆弛時,纖維會分散再被分解。 又,於第6圖之清掃用品3 1,亦可壓縮其整體作成 壓縮部。又,於第4圖所示之清掃用品1及第5圖(B ) 所示之清掃用品2 2,亦可將含有保持側端部2、2 3的特 定長度之區域作成壓縮部,而將清掃側端部3、24作成非 壓縮部。 又,於上述各實施形態,亦可把清掃用品之保持側端 部之特定範圍,用水解紙或水溶性薄膜予以包捲形成保持 部。 第7圖乃至第9圖所示之實施形態的水解性之清掃用 品,具備有具特定體積之塊狀的纖維壓縮體40。該纖維 壓縮體40,爲將纖維長度在20mm以下之可在水中分散 的纖維之集合體予以壓縮而高密度化者。作爲構成纖維壓 縮體40之纖維者,是使用紙漿纖維等之天然纖維或嫘縈 纖維等之再生纖維素纖維。若壓縮此等纖維時,藉由被壓 縮之纖維間的機械性結合力及氫鍵結合力,可維持於乾燥 時之塊狀。或是,亦可用水溶性接著劑將纖維之間固定。 此時,亦可使其含有PET纖維、PP纖維、PE纖維、尼龍 纖維等之合成樹脂纖維。理想爲,纖維壓縮體40僅由生 物分解性纖維所形成。 例如纖維壓縮體40,爲僅用紙漿纖維成形爲塊狀者 。該製法,爲使紙漿纖維分散於水中,作成可形成圓筒形 等者,並於底部形成有用以去除水分之多孔部的凹狀模型 內,灌入紙漿纖維,脫水並加熱使其乾燥者。或,爲於上 -21 - (19) 1296514 述模型內或其他形狀之加壓用的押壓模型內,供給紙漿纖 維,脫水後或是一面脫水一面用燙壓機加壓壓縮,使其乾 燥者。 或是’亦可爲把由紙漿纖維及增黏劑以及水溶性之接 著劑所混合而成之泥狀的原料,用螺旋式擠壓機予以擠壓 ’其後脫水並加熱使其乾燥者。於該擠壓成形,會形成圓 柱狀之纖維壓縮體。又於具備有特定形狀之模腔的成形模 型內’藉由螺旋式擠壓機把泥狀之原料予以擠壓並射出成 形’可製得任意之立體形狀的纖維壓縮體。 將纖維壓縮體40用燙壓機加壓時,該加壓條件爲與 第3圖所示之纖維壓縮體11相同。 各個之纖維壓縮體40,由於爲使用纖維長度在20mm 以下之纖維,較佳爲使用紙漿纖維等而形成,故丟棄於沖 水馬桶內等時,纖維可在較短時間內支解分散。因此纖維 壓縮體之大小可對應清掃用品之形狀任意設定。不過,爲 了纖維壓縮體40在水中可於短時間內分解,各個之纖維 壓縮體40在含有本身重量之3 0 0%的水分時,纖維壓縮體 4 〇之體積以可膨潤2倍以上爲理想。又1片纖維壓縮體 40的水解時間(測量方法如前述般),以在700秒以下 爲理想,再以600秒以下爲更理想,最佳爲3 00秒以下。 又,纖維壓縮體40的質量以在20g以下爲理想。2〇g,相 當於廁所紙9 m的份量,爲於一般之沖水馬桶,不易產生 排水管阻塞之範圍。 再者,若將纖維壓縮體以形成圓筒狀’亦即沿著中心 -22- (20) 1296514 線形成有貫通孔的形狀之方式,於塊體內形成中空部,則 被丟棄於沖水馬桶內時可提早分解。 又,使塊狀之纖維壓縮體4 0的內部,含有洗淨劑、 硏磨劑、抗菌劑、香料等,則於使用該纖維壓縮體40之 際,可提高洗淨效果。 於第7圖乃至第9圖所示之清掃用品,使用了上述纖 維壓縮體40及繩體4。繩體4,爲由第1 5圖(A〉 ( B ) (C )所示之搓繩4A、4B、4C之任1種所構成,或是組 合2種以上而構成。繩體4爲不壓縮上述搓繩地使用。不 過,於第7圖乃至第9圖之實施形態,作爲繩體4,亦可 使用壓縮搓繩而作成纖維壓縮體者。 第7圖所示之第4實施形態的水解性之清掃用品41 ,爲於圓柱形的塊狀之纖維壓縮體4 0的周圍配置有被切 成特定尺寸的複數條上述繩體4,於基部,各別之繩體4 爲由水溶性接著劑所接著於纖維壓縮體40的周面。再者 ,於基部,在繩體4之外周捲有由水解性之薄片所形成的 保持材4 4,並藉由水溶性接著劑接著一起。 捲有上述保持材44的部分爲保持部42,比其更前端 之部分爲清掃部43。保持該清掃用品4 1的握桿,並非第 1圖所示之支持部122及壓押部123之平面狀,支持部 122及壓押部123的相互相向之面爲圓筒狀,上述保持部 42是被圓筒形之支持部122及壓押部123夾住。清掃用 品4 1之保持部42,直至被保持於握桿,只要能發揮可保 持圓筒形狀左右之強度即可。於被保持於握桿後,即使因 -23- (21) 1296514 水而保持材44之保持力變弱,亦可藉由上述支持部122 及壓押部1 2 3保持清掃用品4 1,故於清掃中,不會有清 掃用品4變形之情形。 於使用後被丟棄於水中時,首先於具有保持材44的 保持部42之處開始變形,纖維壓縮體40及繩體4於水中 分離。其後被分離之纖維壓縮體4 0及繩體4個別水解。 在被丟棄於水中之極短的時間內,纖維壓縮體4 0及繩體 4會相互分離,並被沖水馬桶之洗淨水沖走,故不易於排 水管內產生阻塞。 於清掃部43,纖維壓縮體40位於中心處,而其周圍 位有繩體4,繩體4之切斷端面4e被朝向清掃部43之前 端。若將纖維壓縮體40在便器等之被清掃部上用力擦拭 ,則即使因水分造成纖維壓縮體4 0膨脹,亦可維持塊體 形狀,再者吸收了水分之纖維壓縮體40會變軟,可發揮 緩衝性。因此可有效除去附著於被清掃部上之髒污,又擋 接於被清掃部之觸感也變柔軟。又,位於纖維壓縮體40 之周圍的繩體4會朝向周圍擴散,可寬範圍地清掃到被清 掃部之各個角落。 第8圖所示之第5實施形態的水解性之清掃用品5 1 ,於清掃部53處,在纖維壓縮體40的周圍位於繩體4, 不過該繩體4被折曲,而該折曲部4 f爲被朝向清掃部5 3 之前端。於又保持部5 2,於纖維壓縮體4 0之周圍藉由水 溶性接著劑接著有繩體4之基部,於周圍捲有保持材44 並接著一起。繩體4,其折曲部4 f被朝向清掃部5 3之前 -24- (22) 1296514 端部,如第7圖般,由於繩體4之切斷端面4e沒有 清掃部之前端部,故折曲部4f即使吸收了水,繩體 搓檢狀態也不易鬆驰。保持該清掃用品5 1之握桿, 第1圖所示之支持部122及壓押部123之平面狀,支 1 22及壓押部1 23的相互相向之面爲圓筒狀,上述保 52是被圓筒形之支持部122及壓押部123夾住。 第9圖所示之第6實施形態的水解性之清掃用口F ’爲藉由複數條繩體4形成環部4h,並把繩體4之 端面49排齊。於保持部62處,繩體4彼此間藉水溶 著劑接著被,再於外側捲有保持材44並由水溶性接 所接著。於各別繩體4的內部被插入有圓柱狀或是圓 的水解性之纖維壓縮體4 0,纖維壓縮體4 0與各別之 4爲由水溶性接著劑所接著固定。 該清掃用品6 1,將繩體4之環部4h按壓於被清 上清掃時,由於纖維壓縮體4 0會作爲芯材來支撐, 繩體4之環部4h強力按壓於被清掃部上,可去除髒 又,若纖維壓縮體40 —吸收水分會膨脹而成爲彈性 故環部4h會以適度壓力於被清掃部上來回摩擦。 第1 〇圖爲顯示本發明之第7實施形態的水解性 掃用品71的立體圖。 設置於該清掃用品7 1的纖維壓縮體70,爲由上 出成形法等所形成者,是於具備有相向之斜面70a、 的三角柱部分之上部,一體形成有特定寬幅尺寸的保 7〇b。於各別之斜面70a、70a,以水溶性接著劑接著 朝向 4之 並非 持部 持部 h 61 切斷 性接 著劑 筒狀 繩體 掃部 故將 污。 am 體, 之清 述射 70a 持部 有複 -25- (23) 1296514 數條繩體4。繩體4,其切斷端面4g被朝向上排齊,折曲 部4f被排齊於下側。折曲部4f爲比纖維壓縮體70之底 面7 0 c更突出於下側,折曲部4 f相互爲自由狀態。 該清掃用品71 ’其保持部70b,是被第1圖所不之握 桿120的支持部122及壓押部123夾住保持。藉由將纖維 壓縮體70之底面70c按壓於便器等之被清掃部擦拭,可 除去清掃部之髒污,又,由於繩體4之折曲部4 f與被清 掃部接處時會擴開,故可清掃到較寬範圍,連角落也不放 過。 第1 1圖(A )爲顯示本發明之第8實施形態的水解 性之清掃用品8 1的立體圖,第1 1圖(B )爲說明上述清 掃用品8 1之基本構造的展開立體圖。 該水解性之清掃用品8 1,具備有保持部82及清掃部 83。清掃用品81,具備有至少1個清掃用單體88。於圖 之實施形態,重疊有2個清掃用單體8 8,清掃用單體8 8 之上部彼此由水溶性接著劑所接著,再將清掃用單體8 8 用水解紙等之保持材84予以覆蓋,該保持材84爲藉水溶 性接著劑被接著於各清掃用單體8 8。於又清掃部8 3,清 掃用單體8 8相互爲可自由動作。 第11圖(B)爲將上述清掃用單體88之構造予以展 開顯示。清掃用單體8 8,爲於水解性之外裝薄片8 5處收 納有纖維壓縮體8 6者。外裝薄片8 5,其與形成第1 5圖 (A )所示之搓繩4 A的水解性薄片8爲相同者,是纖維 交織不織布。構成外裝薄片8 5之纖維交織不織布的構成 -26- (24) 1296514 或纖維之成份等之理想範圍,爲與上述水解性薄片8相同 〇 纖維壓縮體8 6爲薄片狀(板狀),其複數片被重疊 並被收納於外裝薄片8 5內。纖維壓縮體8 6爲把纖維長度 在20mm以下之藉水可分散的纖維予以積層並壓縮者。纖 維爲紙漿纖維等之天然纖維或嫘縈纖維等之再生纖維素纖 維。纖維壓縮體8 6在被壓縮之狀態下,藉由纖維素系纖 維之氫鍵結合力,以及藉由壓縮產生之纖維間的機械性結 合力,可維持薄片形狀。又,亦可將纖維間藉水溶性接著 劑接合。此時,亦可含有PET纖維、PP纖維、PE纖維、 尼龍纖維等之合成樹脂纖維。不過,纖維壓縮體86以僅 由生物分解性纖維形成爲理想。 例如,纖維壓縮體8 6爲僅由紙漿纖維所形成。壓縮 時之壓力爲與第3圖所示之纖維壓縮體11以及第5圖( A)所示之纖維壓縮體21相同,壓縮時間爲1〜5秒左右 。該壓縮在常溫下進行,不過亦可加熱又壓縮。再者,亦 可藉由在以噴霧器等給予水分後之狀態下加熱壓縮,可更 強化纖維間之氫鍵結合力。 纖維壓縮體8 6,由於爲使用纖維長度在2 0 m m以下 之纖維,更佳爲使用紙漿纖維等而形成,故丟棄於沖水馬 桶內等時,纖維會在較短時間內被支解分散。因此纖維壓 縮體86之大小可對應清掃用品之形狀任意設定。不過, 爲了纖維壓縮體8 6在水中可於短時間內分解,各個之纖 維壓縮體8 6在含有本身重量之3 0 0 %的水分時,纖維壓縮 -27- (25) 1296514 體8 6之體積以可膨潤2倍以上爲理想。又1片纖維壓縮 體8 6的水解時間(測量方法如前述般),以在7 0 0秒以 下爲理想,再以600秒以下爲更理想,最佳爲3 00秒以下 。又,使用於1個清掃用品8 1之纖維壓縮體8 6的質量之 合計以在2 0 g以下爲理想。2 0 g,相當於廁所紙9m的份 量,爲於一般之沖水馬桶,不易產生排水管阻塞之範圍。 又於纖維壓縮體8 6,亦可使其含有洗淨劑、硏磨劑 、抗菌劑、香料等。 如第1 1圖(B )所示,於展開之長方形的外裝薄片 85之上,重疊配置有複數片纖維壓縮體86,將外裝薄片 8 5在假想線L之部分折曲。然後,以不夾住纖維壓縮體 8 6之方式,將外裝薄片8 5之長邊側的側緣部8 5 a彼此藉 水溶性接著劑接著。再將短邊側之端緣部8 5 b彼此藉水溶 性接著劑接著。亦可代替藉由水溶性接著劑之接著,或與 藉由水溶性接著劑之接著倂用,將上述側緣部8 5 a彼此與 端緣部8 5 b彼此予以重疊加壓,或加熱且加壓,藉由外裝 薄片85之氫鍵結合力及機械性結合力接合。第丨〗圖(a )所示之清掃用品8 1,爲使其在將外裝薄片8 5於假想線 L之處折曲而形成的曲折部8 5 c朝向下方的狀態下,於含 有端緣部8 5 b之特定寬幅的範圍內,清掃用單體8 8彼此 由水溶性接著劑所接著,保持材84再被接著固定上。 清掃用品8 1,其保持部82,爲於第1圖所示之握桿 120的支持部122與壓押部123之間被夾住保持。若用清 掃用品8 1之清掃部83在便器等之被清掃部來回摩擦,則 -28- (26) 1296514 可藉由外裝薄片85去除髒污。由於清掃部83之側面爲平 坦面,故藉由使該清掃部8 3之側面於被清掃部上來回摩 擦,可進行較寬面積之清掃。由於外裝薄片8 5爲由纖維 交織不織布所形成,故擦拭被清掃部時外裝薄片8 5不易 - 產生破損。於清掃中若給予其水分,由於外裝薄片85內 ^ 之纖維壓縮體86會膨脹,且呈現彈性,故可藉由外裝薄 片85以適度壓力擦拭被清掃部。 φ 由於保持材84爲將紙漿纖維予以抄紙之水解紙,或 是將紙漿纖維予以抄紙後藉水溶性接著劑而纖維被接合之 水解紙等,故於使用後若將清掃用品81丟棄於水中則藉 由保持材84產生之保持力會立刻解除,則清掃用單品88 會互相獨立。再者,於水中,外裝薄片8 5的側緣部8 5 a 彼此間之接著及端緣部8 5b彼此間之接著會解除,外裝薄 片85及纖維壓縮體86會分離,外裝薄片85及纖維壓縮 體86會獨立並被分解成各別之纖維。 # 於第1 2圖乃至第1 4圖所示之實施形態,清掃部,爲 由薄片狀之纖維壓縮體90以及繩體4所構成。 薄片狀之纖維壓縮體90,爲與第1 1圖所示之纖維壓 縮體86同樣地,是纖維長度在20mm以下的纖維被積層 壓縮而被作成薄片狀者,理想爲僅由紙漿纖維所形成。該 薄片狀之纖維壓縮體90,比起第15圖(B )等所示之水 解紙9 (基重爲10〜30g/m2左右),其纖維基重大得多, 纖維壓縮體90之基重爲500〜1 000g/m2左右。由於薄片 狀之纖維壓縮體90,其基重較大,密度也高且剛性很高The fiber compression body 21 shown in Fig. 5(A) is a compression of the cylindrical body 10 shown in Fig. 2 (A-18-(16) 1296514) by a force Fv in the direction of the center line 〇. Former. The conditions at the time of this compression are the same as those at the time of forming the fiber-compressed body 1 shown in Fig. 3. The fiber compression body 21 shown in Fig. 5(A) can be directly held by the grip 120 as a cleaning article. However, the cleaning article 22 shown in Fig. 5(B) is formed by cutting the fiber compression body 21 shown in Fig. 5(A). In this case, the fiber-compressed body 21 shown in Fig. 5(A) can be equally divided into two, or can be cut into three equal parts, and the angle of the range of 1 to 20 degrees can be made centered on the center line 0. Cleaning supplies 22. Alternatively, it may be cut into 4 equal parts, and the center line 〇 is centered, and the angle of the 90 degree range is made into each of the cleaning supplies 22. In the cleaning article 22, a portion in which the cut end surface 4b of the cord body 4 appears is used as the holding side end portion 23, and a portion of the loop portion 4c of the cord body 4 which appears substantially along the circumference is used as the sweep side end portion 24. use. The cleaning article 22 is also formed into a cylindrical body 10 formed by winding the rope body 4 as shown in Fig. 2(A), and then the cylindrical body is as shown in Fig. 5(A). 1 〇 The process of compression is formed, so that the enthalpy of the rope body 4 is not easily slack during the manufacturing process, and the enthalpy of the rope body 4 is not easily slackened during circulation or storage. In the cleaning article 22 shown in Fig. 5(B), since the rope body 4 is cut into a plurality of units having a short size, when the flush toilet is washed away and a large amount of water is taken, it is separated into individual parts. The rope body 4, the enthalpy of each rope body 4 becomes loose again and the fibers are dispersed in the water. Fig. 6 is a perspective view showing a water-disinfecting cleaning article 3 1 according to a third embodiment of the present invention. -19- (17) 1296514 The cleaning article 31 is such that the above-mentioned rope body 4 of a certain length is folded at a midpoint of the length dimension to be folded in half, and the bending portion 4 d is oriented in one direction and then a plurality of The rope bodies 4 are arranged in a bundle, and the bundle body 4 is compressed. The compression conditions at this time are the same as those in the case of producing the fiber compression body 1 1 shown in Fig. 3 and the fiber compression body 21 shown in Fig. 5 (A). In the cleaning article 3 1 shown in Fig. 6, the side on which the cut end faces 4g of the rope body 4 are aligned is the holding side end portion 32, and the side on which the bent portion 4d is aligned is the cleaning side end portion 33. The bundle 4 in a specific length range including the above-described holding-side end portion 32 is compressed to form a range in which the compressed portion 34' includes a specific length of the cleaning-side end portion 3 3, so that the rope body 4 is not compressed. Uncompressed portion 35. The compression portion 34 is used as a holding portion, and is used between the support portion 122 of the grip 120 shown in Fig. 1 and the pressing portion 123. In the compression unit 34, since the respective rope bodies 4 are compressed and fixed, the cleaning articles 31 in the dry state are not dispersed, and the shape can be maintained at any time during storage or transportation. Since the compression portion 34 is held by the support portion 1 22 and the holding member 1 23, water is caught during use, and even if the compression of the compression portion 34 is relaxed, the shape of the cleaning article 3 1 can be maintained. In the cleaning side end portion 3 3, since the bent portion 4d of each of the rope bodies 4 is in a free state, the widened range of the portion to be cleaned can be effectively cleaned by the independent operation of the bent portion 4d. If it is discarded in the flush toilet after use and receives a large amount of water, the cleaning supplies 31 will be separated into individual ropes 4. After the rope body 4 is changed - 20- (18) 1296514 Dispersion is then broken down. Further, the cleaning article 3 1 of Fig. 6 can also be compressed to form a compression portion as a whole. Further, in the cleaning article 1 shown in Fig. 4 and the cleaning article 2 shown in Fig. 5(B), a region having a specific length of the holding-side end portions 2, 2 3 may be formed as a compression portion, and The cleaning side end portions 3, 24 are formed as non-compressed portions. Further, in each of the above embodiments, the specific portion of the holding side end portion of the cleaning article may be wrapped with a hydrolyzed paper or a water-soluble film to form a holding portion. The hydrolyzable cleaning product of the embodiment shown in Fig. 7 to Fig. 9 is provided with a block-shaped fibrous compression body 40 having a specific volume. The fiber-compressed body 40 is a compacted body of a fiber which can be dispersed in water having a fiber length of 20 mm or less and which is highly densified. As the fiber constituting the fiber compression body 40, a regenerated cellulose fiber such as a natural fiber such as pulp fiber or a ray fiber is used. When these fibers are compressed, the mechanical bonding force and the hydrogen bonding force between the compressed fibers can be maintained in a block shape during drying. Alternatively, the fibers can be fixed with a water-soluble adhesive. In this case, synthetic resin fibers such as PET fibers, PP fibers, PE fibers, and nylon fibers may be contained. It is desirable that the fiber compression body 40 is formed only of biodegradable fibers. For example, the fiber compression body 40 is formed into a block shape using only pulp fibers. In this method, in order to disperse the pulp fibers in water, a cylindrical shape or the like is formed, and a concave mold having a porous portion for removing moisture is formed in the bottom portion, and the pulp fibers are poured, dehydrated, and heated to be dried. Or, in the compression model for pressurization in the model or other shapes described in the above -21(12) 1296514, the pulp fiber is supplied, dehydrated or dehydrated while being compressed and compressed by a hot press to dry it. By. Alternatively, it may be a mud-like raw material obtained by mixing pulp fibers, a tackifier, and a water-soluble binder, which is extruded by a screw extruder, and then dehydrated and heated to dry. In this extrusion, a cylindrical fiber compact is formed. Further, in a molding mold having a cavity having a specific shape, a fibrous body of any three-dimensional shape can be produced by extruding a mud-like material by a screw extruder and projecting it into a shape. When the fiber compression body 40 is pressurized by a hot press, the pressurization conditions are the same as those of the fiber compression body 11 shown in Fig. 3. Each of the fiber-compressed bodies 40 is formed by using fibers having a fiber length of 20 mm or less, preferably pulp fibers or the like. Therefore, when discarded in a flush toilet or the like, the fibers can be dispersed and dispersed in a short period of time. Therefore, the size of the fibrous compression body can be arbitrarily set according to the shape of the cleaning article. However, in order to allow the fiber-compressed body 40 to be decomposed in water in a short time, and each of the fiber-compressed bodies 40 contains 300% by weight of its own weight, the volume of the fiber-compressed body 4 is preferably more than 2 times as long as it can be swollen. . Further, the hydrolysis time of the one fiber compressed body 40 (measuring method as described above) is preferably 700 seconds or less, more preferably 600 seconds or less, and most preferably 300 seconds or less. Further, the mass of the fiber compression body 40 is preferably 20 g or less. 2〇g, equivalent to 9 m of toilet paper, is a general flush toilet, and it is not easy to produce a range of drain pipe obstruction. Further, if the fiber compression body is formed into a cylindrical shape, that is, a shape in which a through hole is formed along a line of the center -22-(20) 1296514, a hollow portion is formed in the block body, and is discarded in the flush toilet. It can be decomposed early. Further, when the inside of the block-shaped fiber-compressed body 40 contains a detergent, a honing agent, an antibacterial agent, a fragrance, or the like, the cleaning effect can be improved when the fiber-compressed body 40 is used. In the cleaning article shown in Fig. 7 to Fig. 9, the above-mentioned fiber compression body 40 and the rope body 4 are used. The rope body 4 is composed of any one of the reins 4A, 4B, and 4C shown in Fig. 5 (A > (B) (C), or two or more types are combined. The rope body 4 is not The above-mentioned reins are used for compression. However, in the embodiment of Fig. 7 to Fig. 9, as the cord body 4, a compression reel can be used as the fiber compression body. The fourth embodiment shown in Fig. 7 The hydrolyzable cleaning article 41 is provided with a plurality of the above-mentioned rope bodies 4 cut into a specific size around the cylindrical block-shaped fibrous compression body 40, and the respective rope bodies 4 are water-soluble at the base portion. The subsequent agent is attached to the peripheral surface of the fiber-compressed body 40. Further, at the base, a holding material 44 formed of a hydrolyzable sheet is wound around the outside of the rope body 4, and is then joined together by a water-soluble adhesive. The portion where the holding member 44 is wound is the holding portion 42, and the portion closer to the holding portion is the cleaning portion 43. The holding rod of the cleaning article 4 1 is not the support portion 122 and the pressing portion 123 shown in Fig. 1 . In a planar shape, the mutually opposing faces of the support portion 122 and the pressing portion 123 are cylindrical, and the holding portion 42 is a cylindrical branch. The portion 122 and the pressing portion 123 are clamped. The holding portion 42 of the cleaning article 41 is held by the grip bar so long as it can maintain the strength of the cylindrical shape. -23- (21) 1296514 The holding force of the water retaining material 44 is weakened, and the cleaning article 4 can be held by the support portion 122 and the pressing portion 1 2 3, so that no cleaning article 4 is cleaned during cleaning. In the case of being dismantled in water after use, the deformation is first started at the holding portion 42 having the holding member 44, and the fiber compression body 40 and the rope body 4 are separated in water. The fiber compression body 4 after being separated is then removed. And the rope body 4 is separately hydrolyzed. In a very short time that is discarded in the water, the fiber compression body 40 and the rope body 4 are separated from each other and washed away by the washing water of the flush toilet, so it is not easy to drain inside the pipe. In the cleaning portion 43, the fiber compression body 40 is located at the center, and the rope body 4 is located around the wire, and the cutting end surface 4e of the rope body 4 is directed toward the front end of the cleaning portion 43. If the fiber compression body 40 is in the toilet or the like Wiped by the cleaning part, even if the fiber is compressed by moisture 40 expansion, the shape of the block can be maintained, and the fibrous compression body 40 which absorbs the water becomes soft and can be cushioned. Therefore, the dirt adhering to the cleaning portion can be effectively removed, and the dirt can be removed and cleaned. Further, the tactile sensation of the portion is also softened. Further, the cord body 4 located around the fiber compression body 40 is diffused toward the periphery, and can be swept in a wide range to the respective corners of the portion to be cleaned. The hydrolyzable cleaning article 5 1 is located at the cleaning portion 53 at the periphery of the fiber compression body 40 at the rope body 4, but the rope body 4 is bent, and the bent portion 4f is oriented toward the cleaning portion 5 3 In the holding portion 52, a holding material 44 is wound around the base of the rope body 4 around the fibrous body 40 by a water-soluble adhesive, and then held together. In the rope body 4, the bent portion 4f is directed toward the end of the cleaning portion 5-3 -24- 1296514. As shown in Fig. 7, since the cut end surface 4e of the rope body 4 has no front end portion of the cleaning portion, Even if the bent portion 4f absorbs water, the rope body inspection state is not easily relaxed. The grip of the cleaning article 51 is held, the support portion 122 and the pressing portion 123 shown in Fig. 1 are planar, and the mutually facing faces of the support 1 22 and the pressing portion 1 23 are cylindrical, and the above-mentioned 52 It is sandwiched by the cylindrical support portion 122 and the pressing portion 123. In the hydrolyzable cleaning port F' of the sixth embodiment shown in Fig. 9, the ring portion 4h is formed by a plurality of rope bodies 4, and the end faces 49 of the rope body 4 are aligned. At the holding portion 62, the rope bodies 4 are followed by a water-soluble solvent, and the holding material 44 is wound on the outside and followed by a water-soluble material. A cylindrical or round hydrolyzable fibrous compression body 40 is inserted into the interior of each of the rope bodies 4, and the fibrous compression bodies 40 and 4 are respectively fixed by a water-soluble adhesive. When the cleaning device 6-1 presses the ring portion 4h of the rope body 4 to be cleaned, the fiber compression body 40 is supported as a core material, and the ring portion 4h of the rope body 4 is strongly pressed against the portion to be cleaned. The dirt can be removed. If the fibrous compression body 40 absorbs moisture and expands to become elastic, the ring portion 4h rubs back and forth on the portion to be cleaned with moderate pressure. Fig. 1 is a perspective view showing a water-disinfecting cleaning article 71 according to a seventh embodiment of the present invention. The fiber compression body 70 provided in the cleaning article 7 1 is formed by an upper molding method or the like, and is formed on the upper portion of the triangular prism portion having the inclined surface 70a facing each other, and is integrally formed with a specific width. b. In the respective inclined faces 70a, 70a, the water-soluble adhesive is applied to the fourth portion instead of the holding portion h 61 to cut off the squeezing agent cylindrical body sweeping portion. The am body, the clear statement 70a holding part has a complex -25- (23) 1296514 several ropes 4. In the rope body 4, the cut end faces 4g are aligned upward, and the bent portions 4f are aligned on the lower side. The bent portion 4f protrudes from the bottom surface 70c of the fiber compression body 70 to the lower side, and the bent portion 4f is free from each other. The cleaning unit 71' has a holding portion 70b that is held by the support portion 122 and the pressing portion 123 of the grip 120 of Fig. 1 . By pressing the bottom surface 70c of the fiber compression body 70 against the cleaning portion of the toilet or the like, the dirt of the cleaning portion can be removed, and the bent portion 4f of the rope body 4 can be expanded when it is joined to the portion to be cleaned. Therefore, it can be cleaned to a wider range, and even the corners are not missed. Fig. 1(A) is a perspective view showing a water-repellent cleaning article 8 1 according to an eighth embodiment of the present invention, and Fig. 1(B) is a developed perspective view showing a basic structure of the cleaning article 81. The water-repellent cleaning article 181 is provided with a holding portion 82 and a cleaning portion 83. The cleaning article 81 is provided with at least one cleaning monomer 88. In the embodiment of the figure, two cleaning cells 8 are superposed, and the upper portions of the cleaning cells 8 8 are each followed by a water-soluble adhesive, and the cleaning monomer 8 is further provided with a holding material such as a hydrolyzed paper. In addition, the holding material 84 is adhered to each of the cleaning monomers 8 8 by a water-soluble adhesive. In the cleaning unit 83, the cleaning units 8 8 are freely movable. Fig. 11(B) shows the structure of the cleaning unit 88 described above. The cleaning monomer 8 8 is a fiber-compressed body 8 in the form of a hydrolyzable outer sheet 8 5 . The outer sheet 85 is the same as the hydrolyzable sheet 8 forming the reins 4A shown in Fig. 5(A), and is a fiber interwoven nonwoven fabric. The composition of the fiber interlaced nonwoven fabric constituting the exterior sheet 85 is -26-(24) 1296514 or the composition of the fiber or the like is the same as that of the above-mentioned hydrolyzable sheet 8, and the fiber compressed body 86 is in the form of a sheet (plate shape). The plurality of sheets are overlapped and housed in the exterior sheet 85. The fiber-compressed body 86 is a layered and water-dispersible fiber having a fiber length of 20 mm or less. The fibers are regenerated cellulose fibers such as natural fibers such as pulp fibers or rayon fibers. In the compressed state, the fiber-compressed body 86 can maintain the shape of the sheet by the hydrogen bonding force of the cellulose-based fibers and the mechanical bonding force between the fibers by compression. Further, the fibers may be joined by a water-soluble adhesive. In this case, synthetic resin fibers such as PET fibers, PP fibers, PE fibers, and nylon fibers may be contained. However, the fibrous compression body 86 is preferably formed of only biodegradable fibers. For example, the fibrous compression body 86 is formed only of pulp fibers. The pressure at the time of compression is the same as that of the fiber-compressed body 11 shown in Fig. 3 and the fiber-compressed body 21 shown in Fig. 5(A), and the compression time is about 1 to 5 seconds. The compression is carried out at room temperature, but it can also be heated and compressed. Further, the hydrogen bonding force between the fibers can be further enhanced by heating and compressing in a state where water is supplied by a sprayer or the like. The fiber-compressed body 86 is formed by using a fiber having a fiber length of 20 mm or less, more preferably pulp fiber or the like. Therefore, when it is discarded in a flushing drum or the like, the fiber is dispersed and dispersed in a short time. Therefore, the size of the fiber compression body 86 can be arbitrarily set according to the shape of the cleaning article. However, in order to decompose the fiber-compressed body 86 in water in a short time, each of the fiber-compressed bodies 86 contains 300% of its own weight of water, and the fiber is compressed by -27-(25) 1296514. The volume is ideal for swelling more than 2 times. Further, the hydrolysis time of the one fiber compressed body 86 (measuring method as described above) is preferably 700 seconds or less, more preferably 600 seconds or less, and most preferably 300 seconds or less. Further, the total mass of the fiber-compressed body 86 used in the one cleaning article 8 1 is preferably 20 g or less. 2 0 g, which is equivalent to 9m of toilet paper, is not suitable for the scope of the drainage pipe in the general flush toilet. Further, the fibrous compression body 86 may contain a detergent, a honing agent, an antibacterial agent, a fragrance, and the like. As shown in Fig. 1(B), a plurality of fiber compression bodies 86 are superposed on the unfolded rectangular outer sheet 85, and the outer sheet 85 is bent at a portion of the imaginary line L. Then, the side edge portions 85 5 a on the long sides of the exterior sheet 85 are adhered to each other by a water-soluble adhesive agent so as not to sandwich the fiber compression body 8 6 . The edge portions 8 5 b of the short sides are then joined to each other by a water-soluble adhesive. Alternatively, the side edge portions 85 a and the edge portions 8 5 b may be superposed on each other or heated by the subsequent use of the water-soluble adhesive or by the subsequent use of the water-soluble adhesive. The pressurization is joined by the hydrogen bonding force and the mechanical bonding force of the exterior sheet 85. In the state in which the meandering portion 8 5 c which is formed by bending the outer sheet 85 at the imaginary line L is directed downward, at the containing end Within the specific width of the edge portion 8 5 b , the cleaning monomers 8 8 are each followed by a water-soluble adhesive, and the holding material 84 is then fixed. The cleaning device 81 has a holding portion 82 that is sandwiched and held between the support portion 122 and the pressing portion 123 of the grip 120 shown in Fig. 1 . When the cleaning portion 83 of the cleaning article 8 1 is rubbed back and forth in the cleaning portion of the toilet or the like, the -28-(26) 1296514 can be removed by the exterior sheet 85. Since the side surface of the cleaning portion 83 is a flat surface, the cleaning of the wide area can be performed by rubbing the side surface of the cleaning portion 83 back and forth on the portion to be cleaned. Since the exterior sheet 85 is formed of a fiber interwoven nonwoven fabric, the exterior sheet 85 is less likely to be damaged when the portion to be cleaned is wiped. When the water is given during the cleaning, the fiber compressed body 86 in the outer sheet 85 expands and exhibits elasticity, so that the portion to be cleaned can be wiped with an appropriate pressure by the outer sheet 85. φ Since the holding material 84 is a hydrolyzed paper which is used to paper pulp fibers, or a hydrolyzed paper in which the pulp fibers are paper-coated and then the water-soluble adhesive is used to bond the fibers, the cleaning article 81 is discarded in the water after use. When the holding force generated by the holding member 84 is immediately released, the cleaning items 88 are independent of each other. Further, in the water, the side edge portions 85 5 a of the outer sheet 85 and the edge portions 8 5 b are released from each other, and the outer sheet 85 and the fiber compressed body 86 are separated, and the outer sheet is separated. 85 and the fibrous compression body 86 are separated and broken down into individual fibers. In the embodiment shown in Fig. 12 to Fig. 14, the cleaning portion is composed of a sheet-like fiber compression body 90 and a rope body 4. In the same manner as the fiber-compressed body 86 shown in Fig. 1, the fiber-like fibrous body 90 having a fiber length of 20 mm or less is compressed and laminated to form a sheet, and is preferably formed of only pulp fibers. . The sheet-like fibrous compression body 90 is much more fibrous than the hydrolyzed paper 9 (having a basis weight of about 10 to 30 g/m 2 ) as shown in Fig. 15 (B) or the like, and the basis weight of the fibrous compression body 90 is much larger. It is about 500~1 000g/m2. Due to the sheet-like fibrous compression body 90, the basis weight is large, the density is high, and the rigidity is high.
(S -29- (27) 1296514 ,故若於清掃部處,與繩體4同時配置時,易於藉剛性高 之薄片狀的纖維壓縮體90除去附著於便器等之被清掃部 的表面之髒污,再者,繩體4較可自由變形,可擦拭較寬 範圍之被清掃部。又,藉由繩體4,便器角落部之清掃會 變得較容易。 若於使用後丟棄於沖水馬桶內時,薄片狀之纖維壓縮 體90會在較短的時間內,被分解成紙漿纖維。 於第1 2圖所示之第9實施形態的水解性之清掃用品 91,在重疊有複數片(例如5〜20片左右)薄片狀之纖維 壓縮體90的狀態下,於該周圍配置複數條繩體4。於保 持部92處,纖維壓縮體90及繩體4由水溶性接著劑所接 著,由水解紙等所形成之保持材44再被繞捲於其周圍並 被接著。於清掃部93處,各個之薄片狀的纖維壓縮體90 爲相互獨立,再者,繩體4也獨立。又,繩體4之切斷端 面4e被朝向清掃部93之前端。保持該清掃用品91的握 桿,並非第1圖所示之支持部122及壓押部123之平面狀 ,支持部1 22及壓押部1 23的相互相向之面爲圓筒狀,上 述保持部92是被圓筒形之支持部122及壓押部123夾住 〇 該清掃用品9 1,若將清掃部93之前端部按壓於被清 掃部上來回摩擦時,會用到薄片狀之纖維壓縮體9 0的端 面擦拭被清掃部,再者,各個之繩體4會擴開,可清掃被 清掃部之較寬的範圍,又藉由繩體4亦可清掃便器等之角 落部。於該清掃用品91,亦可作成第8圖所示之繩體4 -30- (28) 1296514 的折曲部4f位於清掃部93之構造。 第1 3圖所示之第1 0實施形態的水解性之清掃用 1 0 1,爲重疊1片或複數片之與清掃用品1 0 1大致相同 小的水解性之薄片狀的纖維壓縮體90而使用。複數條 體4被形成環狀,環部4h,是以圍住薄片狀之纖維壓 體90的下邊90a之方式被配置。各繩體4之切斷端面 ,是以與薄片狀之纖維壓縮體90的上邊90b —致之方 組合,繩體4之切斷端面4g的附近爲被接著於薄片狀 纖維壓縮體90的兩面,再於周圍捲上保持材44並接著 起,而形成有扁平形狀之保持部102。又於清掃部103 各個之繩體4可相互獨立動作,又,薄片狀之纖維壓縮 90亦可獨立動作。 該清掃用品1 0 1,藉由使清掃部1 03對被清掃部朝 第13圖所示之Y方向來回摩擦,可把薄片狀之纖維壓 體90的下邊90a在被清掃部上用力擦拭。若再朝向與 述Y方向垂直相交的X方向來回摩擦時,可藉由各別 繩體4的環部4h清掃被清掃部。 第1 4圖所示之第1 1實施形態的水解性之清掃用 1 1 1,是重疊複數片長方形的上述水解性之薄片狀的纖 壓縮體9 0,並於其兩側面配置複數條繩體4,於薄片狀 纖維壓縮體9 0的上部及繩體4之上部被捲有保持材4 4 接著一起’而形成有扁平形狀之保持部1 1 2。於清掃 1 1 3 ’位有相互獨立之其切斷端面4e被朝向下側的複數 繩體4以及纖維壓縮體90。 品 大 繩 縮 4g 式 之 體 向 縮 上 之 品 維 之 且 部 條 -31 - (29) (29)1296514 該清掃用品 η l,亦可藉由薄片狀之纖維壓縮體9 ο 及繩體4來進行擦拭。又,位於薄片狀之纖維壓縮體90 的兩側面之繩體4,亦可爲第8圖所示之折曲部4f或第9 圖所示之環部4h被朝向下側者。 【圖式簡單說明】 第1圖爲顯示本發明之水解性的清掃用品被保持於握 桿上的狀態之立體圖。 第2圖(A ) ( B )爲顯示構成第1實施形態之水解 性的清掃用品之纖維壓縮體的製造方法之立體圖。 第3圖爲構成第1實施形態之水解性的清掃用品之纖 維壓縮體的立體圖。 第4圖爲顯示將纖維壓縮體切斷之第i實施形態的水 解性之清掃用品的立體圖。 第5圖(A )爲顯示構成第2實施形態之水解性的清 掃用品之纖維壓縮體的立體圖。(B )爲顯示將纖維壓縮 體切斷之第2實施形態的水解性之清掃用品的立體圖。 第6圖爲顯示第3實施形態之水解性的清掃用品之立 體圖。 第7圖爲顯示第4實施形態之水解性的清掃用品之立 體圖。 第8圖爲顯示第5實施形態之水解性的清掃用品之立 體圖。 第9圖爲顯示第6實施形態之水解性的清掃用品之立 •32- (30) (30)1296514 體圖。 第1 〇圖爲顯示第7實施形態之水解性的清掃用品之 立體圖。 第1 1圖(A )爲顯示第8實施形態之水解性的清掃 用品之立體圖。(B )爲將清掃用單品展開之立體圖。 第1 2圖爲顯示第9實施形態之水解性的清掃用品之 立體圖。 第1 3圖爲顯示第1 0實施形態之水解性的清掃用品之 立體圖。 第1 4圖爲顯示第1 1實施形態之水解性的清掃用品之 立體圖。 第1 5圖(A ) ( B ) ( C )爲依構造別說明用以形成 繩體之搓繩的說明圖。 【主要元件符號說明】 1 :清掃用品 2 :保持側端部 3 :清掃側端部 4 :繩體 4 A、4 B、4 C :搓繩 4a :環部 4 :切斷端面 4 c . ί哀部 4d :折曲部 -33- (31) 1296514 4e :切斷端面 4f :折曲部 4g :切斷端面 4 h · ί哀部 • 8 :水解性薄片 . 9:水解紙 1 〇 :筒狀體 • 1 1 :纖維壓縮體 2 1 :纖維壓縮體 23 :保持側端部 24清掃側端部 3 1 :清掃用品 3 2 :保持側端部 3 3 :清掃側端部 3 4 :壓縮部 • 3 5 :非壓縮部 40纖維壓縮體 4 1、5 1、6 1 :清掃用品 42、52、62 :保持部 43 、 53 、 63 :清掃部 4 4 :保持材 70 :纖維壓縮體 71 :清掃用品 7〇b :保持部 -34 (32) (32)1296514 8 1 :清掃用品 8 2 :保持部 8 3 :清掃部 84 :保持材 8 5 :水解性薄片 86 :纖維壓縮體 8 8 :清掃用單體 9 1、1 0 1、1 1 1 :清掃用品 9 2、1 0 2、1 1 2 :保持部 9 3、1 0 3、1 1 3 :清掃部 1 2 0 :握桿 122 :支持部 123 :壓押部(S -29-(27) 1296514, when it is disposed at the same time as the rope body 4 at the cleaning portion, it is easy to remove the dirt adhering to the surface of the cleaning portion such as the toilet by the sheet-like fibrous compression body 90 having a high rigidity. In addition, the rope body 4 can be freely deformed to wipe a wide range of the cleaning portion. Moreover, by the rope body 4, the cleaning of the corner portion of the toilet bowl becomes easier. If it is discarded after use, it is flushed. In the case of the toilet, the sheet-like fibrous compression body 90 is decomposed into pulp fibers in a short period of time. The hydrolyzable cleaning article 91 of the ninth embodiment shown in Fig. 2 has a plurality of overlapping sheets. In the state of the sheet-like fibrous compression body 90 (for example, about 5 to 20 pieces), a plurality of rope bodies 4 are disposed around the fiber compression body 90. The fiber compression body 90 and the rope body 4 are followed by a water-soluble adhesive agent at the holding portion 92. The holding material 44 formed of the hydrolyzed paper or the like is wound around the same and is followed. At the cleaning portion 93, the respective sheet-like fibrous compression bodies 90 are independent of each other, and the rope body 4 is also independent. Further, the cut end surface 4e of the rope body 4 is directed toward the front end of the cleaning portion 93. The grip of the cleaning article 91 is not in the planar shape of the support portion 122 and the pressing portion 123 shown in Fig. 1, and the mutually opposing faces of the support portion 1 22 and the pressing portion 1 23 are cylindrical, and the holding portion 92 is provided. The cleaning member 9 is sandwiched between the cylindrical support portion 122 and the pressing portion 123. When the front end portion of the cleaning portion 93 is pressed against the cleaning portion, the sheet-like fibrous compression body is used. The end surface of the 90 is wiped by the cleaning portion, and the rope body 4 is expanded to clean the wide range of the cleaning portion, and the corner portion of the toilet or the like can be cleaned by the rope body 4. The article 91 may have a structure in which the bent portion 4f of the cord body 4-30-(28) 1296514 shown in Fig. 8 is located in the cleaning portion 93. The hydrolyzability of the first embodiment shown in Fig. 3 is shown. For cleaning, 100 1 is used, and a sheet-like fibrous compression body 90 having a hydrolyzability which is substantially the same as that of the cleaning article 101 is superimposed on one or more sheets. The plurality of strips 4 are formed into a ring shape, and the ring portion 4h is formed. It is disposed so as to surround the lower side 90a of the sheet-like fibrous press body 90. The cut end faces of the respective rope bodies 4 are in the form of flakes. The upper side 90b of the fiber compression body 90 is combined, and the vicinity of the cut end surface 4g of the rope body 4 is attached to both sides of the sheet-like fiber compression body 90, and the holding material 44 is wound around and then lifted up. The flat portion of the holding portion 102 is formed. The respective rope bodies 4 of the cleaning portion 103 can be independently operated, and the sheet-like fiber compression 90 can also be independently operated. The cleaning material 1 0 1 is provided by the cleaning portion 1 03. The paired cleaning portion rubs back and forth in the Y direction shown in Fig. 13, and the lower side 90a of the sheet-like fibrous press body 90 can be wiped hard on the portion to be cleaned. If it is further turned back and forth in the X direction perpendicular to the Y direction. At the time of friction, the portion to be cleaned can be cleaned by the ring portion 4h of each of the rope bodies 4. In the first aspect of the present invention, the hydrolyzable cleaning 1 1 1 of the first embodiment is a plurality of rectangular hydrolyzed sheet-like fibrous compacts 90, and a plurality of strands are disposed on both sides thereof. In the body 4, a holding portion 1 1 2 having a flat shape is formed by winding a holding material 4 4 on the upper portion of the sheet-like fiber compression body 90 and the upper portion of the rope body 4. In the cleaning 1 1 3 ′ position, the plurality of rope bodies 4 and the fiber compression body 90 whose mutually cut end faces 4e are directed toward the lower side are provided. The product of the large rope is reduced by 4g, and the strip is folded upwards. -31 - (29) (29)1296514 The cleaning article η l can also be compressed by the flaky fiber 9 ο and the rope body 4 To wipe it. Further, the cord body 4 located on both side faces of the sheet-like fibrous compression body 90 may be such that the bent portion 4f shown in Fig. 8 or the loop portion 4h shown in Fig. 9 is directed downward. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a perspective view showing a state in which a hydrolyzable cleaning article of the present invention is held on a grip. Fig. 2(A) and Fig. 2(B) are perspective views showing a method of producing a fibrous compression body constituting the water-repellent cleaning article according to the first embodiment. Fig. 3 is a perspective view showing a fiber compact of the water-repellent cleaning article of the first embodiment. Fig. 4 is a perspective view showing a water-repellent cleaning article according to an i-th embodiment in which a fibrous compression body is cut. Fig. 5(A) is a perspective view showing a fiber compression body constituting the water-repellent cleaning article of the second embodiment. (B) is a perspective view showing a hydrolyzable cleaning article according to the second embodiment in which the fiber compressed body is cut. Fig. 6 is a perspective view showing the water-repellent cleaning article of the third embodiment. Fig. 7 is a perspective view showing the water-repellent cleaning article of the fourth embodiment. Fig. 8 is a perspective view showing the water-repellent cleaning article of the fifth embodiment. Fig. 9 is a view showing the body of a hydrolyzable cleaning article according to the sixth embodiment, 32-(30) (30) 1296514. Fig. 1 is a perspective view showing a water-repellent cleaning article according to a seventh embodiment. Fig. 1(A) is a perspective view showing a water-repellent cleaning article according to the eighth embodiment. (B) is a perspective view of a cleaning article. Fig. 1 is a perspective view showing the water-repellent cleaning article of the ninth embodiment. Fig. 13 is a perspective view showing the water-repellent cleaning article of the tenth embodiment. Fig. 14 is a perspective view showing the water-repellent cleaning article of the first embodiment. Fig. 15(a)(B)(C) is an explanatory view showing the reins for forming a rope body according to the structure. [Explanation of main component symbols] 1 : Cleaning supplies 2 : Holding side end portion 3 : Cleaning side end portion 4 : Rope body 4 A, 4 B, 4 C : Reins 4a : Ring portion 4 : Cutting end face 4 c . Mourning part 4d : Bending part -33- (31) 1296514 4e : Cutting end face 4f : Bending part 4g : Cutting end face 4 h · 哀 部 part • 8 : Hydrolyzable sheet. 9: Hydrolyzed paper 1 〇: tube Shape 1 1 : Fiber compression body 2 1 : Fiber compression body 23 : Holding side end portion 24 cleaning side end portion 3 1 : Cleaning article 3 2 : Holding side end portion 3 3 : Cleaning side end portion 3 4 : Compression portion • 3 5 : uncompressed portion 40 fiber compression body 4 1 , 5 1 , 6 1 : cleaning articles 42, 52, 62: holding portions 43 , 53 , 63 : cleaning portion 4 4 : holding material 70 : fiber compression body 71 : Cleaning material 7〇b: holding portion -34 (32) (32) 1296514 8 1 : cleaning material 8 2 : holding portion 8 3 : cleaning portion 84 : holding material 8 5 : hydrolyzable sheet 86 : fiber compression body 8 8 : Cleaning monomer 9 1 , 1 0 1 , 1 1 1 : cleaning supplies 9 2, 1 0 2, 1 1 2 : holding portion 9 3, 1 0 3, 1 1 3 : cleaning portion 1 2 0 : grip 122 : Support Department 123: Compression Department
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