1293316 九、發明說明： 【發明所屬之技術領域】 本發明是有關於一種多機能高分子及其纖維之製造方 法，且特別是有關於一種多機能炭粉高分子及其纖維之製 造方法。 【先前技術】 、Ik著社會發展與人民生活水準的提昇，人們對於機能 性織物有了較高的要求。-般市面上之機能性織物係於織 物中添加功能性粒子或直接以具有機能性的纖維編織而 成二例如利用活性炭粒子用以除臭、移除雜質或吸附毒性 物貝。然而，活性炭纖維所製造之機能性織物僅侷限於移 除臭味或吸附雜質，無法進一步提供其他機能。因此，近 年來開始使用竹炭作為機能性粒子，以提高機能性織物之 機能。 竹炭係採用四年生以上之天然竹材經由高溫燒製而得 到的。由於竹炭的結構緻密、孔隙多與比表面積高之特性， 再力上八έ有豆®的天然礦物質，因而能製造出高機能性 且天然的機能性織物。此外，更利用竹炭優異之吸附能力、 调濕性、抗@性、遠紅外線以及負離子等機能，將竹炭加 入紡織品中，以提高織物之複合功能。 然=，先前製造機能性纖維之方法，多半是將機能性 粒子與同分子原料混合後，接著進行押出製程，最後再進 行後續之紡絲過程。但是，此製造方法之問題處在於高分 子基材中之機能性粒子分散不均勻，故往往需要添加各種 1293316 型困難等問題，更使得製造成本:=力高°,不易或纖維成 彳必要提供-種新的機能性纖維之製造方法 以解決上述之問題。 表绝方法，BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a multi-functional polymer and a fiber thereof, and more particularly to a method for producing a multi-functional carbon powder polymer and a fiber thereof. [Prior Art], Ik has a higher level of social development and people's living standards, people have higher requirements for functional fabrics. The functional fabrics on the market are either added with functional particles in the fabric or directly woven with functional fibers to deodorize, remove impurities or adsorb toxic shells, for example, using activated carbon particles. However, the functional fabric made of activated carbon fiber is limited to removing odor or adsorbing impurities, and cannot provide further functions. Therefore, in recent years, bamboo charcoal has been used as a functional particle to improve the function of functional fabrics. The bamboo charcoal is obtained by firing a natural bamboo of four or more years at a high temperature. Due to its compact structure, high porosity and high specific surface area, bamboo charcoal is able to produce high-performance and natural functional fabrics by applying the natural minerals of Gossip. In addition, bamboo charcoal is added to textiles to improve the composite function of the fabric by utilizing the excellent adsorption capacity, humidity control property, anti-@ property, far infrared ray and negative ion function of bamboo charcoal. However, the previous method of manufacturing functional fibers mostly involves mixing the functional particles with the same molecular material, followed by an extrusion process, and finally a subsequent spinning process. However, the problem of this manufacturing method lies in the uneven dispersion of functional particles in the polymer substrate, so it is often necessary to add various problems such as difficulty in the type 1293316, and the manufacturing cost is: = high force °, not easy or fiber is necessary to provide A new method of manufacturing functional fibers to solve the above problems. Absolute method,
【發明内容】 之製發：的目的就是在提供一種多機能高分子母粒 /用以增加高分子樹脂之本身物性，使其於後 績之加工纺織過程中’仍可維持良好之纖維物性。 本發明的另-目的是在提供一種多機能高分子纖維之 製造方m提高機紐炭粉於高分子母粒巾之分散性。 本發明的又一目的是在提供一種多機能高分子纖維的 製造方法，以提高纖維之抗菌性、除臭性、遠紅外線特性 以及其織物之财水洗性。SUMMARY OF THE INVENTION The purpose of the invention is to provide a multi-functional polymer masterbatch / to increase the physical properties of the polymer resin, so that it can maintain good fiber properties during the processing of the textile process. Another object of the present invention is to improve the dispersibility of the machine carbon powder in the polymer masterbatch by providing a multi-functional polymer fiber. Still another object of the present invention is to provide a method for producing a multi-functional polymer fiber to improve the antibacterial property, deodorant property, far-infrared property of the fiber, and the water-washing property of the fabric.
根據本發明之上述目的，提出一種多機能高分子纖維 之製造方法。依照本發明之一較佳實施例，係先製備具有 多機旎炭粉之懸浮液。再於聚合槽中加入樹脂單體與多機 能炭粉，並進行樹脂單體與多機能炭粉之聚合反應，以形 成多機能高分子。接著，切割此多機能高分子，以形成多 機能高分子母粒。 然後，加入樹脂母粒於多機能高分子母粒中，並授拌 均勻。接著，以熔融紡絲製程讓樹脂母粒與多機能高分子 母粒形成多機能高分子纖維。隨後，進行加工紡絲製程， 使多機能高分子纖維加工為加工紗，以提高多機能高分子 6 ^93316 將加工、紗 纖維之穩度度。最後’再利用傳統之纺織製程， 編織成多機能高分子織物。 因此，本發明能製造出具較高的抗菌性、高除臭率遍 ::工外線特性之多機能高分子纖維。此外，由於本發明： ，係利用聚合反應，使機能性炭粉與樹脂單體聚合而形 多機能高分子。此方法不僅能改善機能性炭粉分散不均 :問題，更能提高樹脂本身之物性，以減少材料成本的浪 費。 口且由本發明之方法所製備的多機能纖維於後段加工製 &中’仍可維持良好的纖維物性，進而提高纖維產率。除 之外本發明之方法更可提高織物之耐水洗性。 、 【實施方式】 本發明提供一種多機能高分子纖維之製造方法，係結 合兩分子聚合製程與熔融紡絲的技術而成。 首先I備多機能炭粉懸浮液。在本發明之一較佳實施 例中’將分散劑與潤濕劑溶於溶劑中，接著進行攪拌直至 ά均勻。再將多機能炭粉加入混合液中並進行高速擾 摔。隨後進行研磨製程以形成多機能炭粉的懸浮液。 其中，上述之多機能炭粉較佳為竹炭粉、木炭粉、備 長厌叙/舌性厌粉、椰子殼炭粉、均*殼炭粉或海藻炭粉， 且其係以溫度約為300°C到1500°C燒製原料之後粉碎而 成。而懸浮液中的多機能炭粉之重量百分比較佳範圍為 5_5〇% °上述研磨後之多機能炭粉懸浮液中之多機能炭粉的 平均粒徑較佳為小於〇·5 μιη，且90%之粉末粒徑為小於 7 1293316 Ιμηι。此外，上述之溶劑較佳為水、苯類、醇類、醛類或酚 類。 上述之分散劑之成分較佳為聚萘磺酸、甲醛及甲基酚 納鹽類共聚物、馬來酐二異丁烯類共聚物、聚萘甲醛磺酸 鈉鹽類、磺酸羧酸酯類、磺酸鹽類、脂肪酸類、聚丙烯酸 酯類、聚丙烯酸鹽類、聚醚類、聚羧酸類、聚氨基甲酸酯 類、I碎氧烧類共聚物或績酸鹽類共聚物之任意組合。由 上述較佳成份所組成之分散劑較佳為高分子量分散劑、低 分子量分散劑、陰離子型分散劑、陽離子型分散劑或非離 子型分散劑。在本發明中之一較佳實施例，分散劑係採用 由余泰貿易公司所提供，型號分別為Galoryl PT2(H、Galoryl PT245L - Galoryl DT50 - Galoryl TD21 > Galoryl DT23 > Galoryl MT 830ML、Galoryl TD164L 之分散劑。或是由 TEGO公司所提供，型號分別為Dispers 610、Dispers 630、 Dispers 650、Dispers 651、Dispers 652、Dispers 700、Dispers 710、Dispers 740W、Dispers 745、Dispers 750、Dispers 752W、Dispers 760W 之分散劑。 濕潤劑之成分較佳為聚萘磺酸、甲醛及甲基酚納鹽類 共聚物、馬來酐二異丁烯類共聚物、聚萘甲醛磺酸鈉鹽類、 磺酸羧酸酯類、磺酸鹽類、脂肪酸類、聚丙烯酸酯類、聚 丙烯酸鹽類、聚醚類、聚羧酸類、聚氨基甲酸酯類、聚矽 氧烷類兵聚物或磺酸鹽類共聚物之任意組合。在本發明之 一較佳實施例中，上述之濕潤劑係採由TEGO公司所提供， 型號分別為 WET500、WET5(H、WET502、WET245、WET270 之濕潤劑。或是，由余泰貿易公司所提供，型號分別為 8 1293316According to the above object of the present invention, a method for producing a multi-functional polymer fiber is proposed. According to a preferred embodiment of the invention, a suspension having a multi-machine carbon powder is prepared. Further, a resin monomer and a multi-functional carbon powder are added to the polymerization tank, and a polymerization reaction between the resin monomer and the multi-functional carbon powder is carried out to form a multi-functional polymer. Next, the multi-functional polymer is cut to form a multi-functional polymer master batch. Then, the resin master batch is added to the multi-functional polymer masterbatch, and the mixture is uniformly mixed. Next, the resin master batch and the multi-functional polymer master batch are formed into a multi-functional polymer fiber by a melt spinning process. Subsequently, the processing and spinning process is carried out to process the multi-functional polymer fiber into a processed yarn to improve the stability of the multi-functional polymer 6 ^93316 processing and yarn fiber. Finally, the traditional textile process is used to weave into a multi-functional polymer fabric. Therefore, the present invention can produce a multi-functional polymer fiber having high antibacterial property and high deodorization rate. Further, according to the present invention, a functional multi-functional polymer is formed by polymerizing a functional carbon powder and a resin monomer by a polymerization reaction. This method not only improves the uneven dispersion of functional carbon powder: the problem, but also improves the physical properties of the resin itself, thereby reducing the cost of material costs. The multi-functional fibers prepared by the method of the present invention can maintain good fiber properties in the post-processing process, thereby improving the fiber yield. In addition to the method of the present invention, the water wash resistance of the fabric is further improved. [Embodiment] The present invention provides a method for producing a multi-functional polymer fiber, which is a combination of a two-molecule polymerization process and a melt spinning process. First, I prepared a multi-functional carbon powder suspension. In a preferred embodiment of the invention, the dispersing agent and the wetting agent are dissolved in a solvent, followed by stirring until the hydrazine is homogeneous. The multi-functional carbon powder is then added to the mixture and subjected to high-speed spoiling. A grinding process is then carried out to form a suspension of multi-functional carbon powder. Wherein, the plurality of functional carbon powders are preferably bamboo charcoal powder, charcoal powder, long-term disgusting/tongue powder, coconut shell charcoal powder, carbon shell powder or seaweed charcoal powder, and the temperature is about 300°. C to 1500 ° C after firing raw materials and pulverized. The weight percentage of the multi-functional carbon powder in the suspension is preferably in the range of 5_5〇%. The average particle size of the multi-functional carbon powder in the multi-functional carbon powder suspension after the grinding is preferably less than 〇·5 μιη, and 90% of the powder has a particle size of less than 7 1293316 Ιμηι. Further, the above solvent is preferably water, benzene, alcohol, aldehyde or phenol. The components of the above dispersing agent are preferably polynaphthalenesulfonic acid, formaldehyde and methylphenol sodium salt copolymers, maleic anhydride diisobutylene copolymers, polynaphthalene formaldehyde sulfonate sodium salts, sulfonic acid carboxylates, Any combination of sulfonates, fatty acids, polyacrylates, polyacrylates, polyethers, polycarboxylic acids, polyurethanes, acetonide copolymers or acid salt copolymers. The dispersing agent composed of the above preferred components is preferably a high molecular weight dispersing agent, a low molecular weight dispersing agent, an anionic dispersing agent, a cationic dispersing agent or a nonionic dispersing agent. In a preferred embodiment of the invention, the dispersant is supplied by Yutai Trading Co., Ltd., model number is Galloryl PT2 (H, Galoryl PT245L - Galoryl DT50 - Galoryl TD21 > Galoryl DT23 > Galoryl MT 830ML, Galoryl Dispersant for TD164L. Or supplied by TEGO, models are Dispers 610, Dispers 630, Dispers 650, Dispers 651, Dispers 652, Dispers 700, Dispers 710, Dispers 740W, Dispers 745, Dispers 750, Dispers 752W, Dispers 760W dispersant. The composition of the humectant is preferably polynaphthalenesulfonic acid, formaldehyde and methylphenol sodium salt copolymer, maleic anhydride diisobutylene copolymer, polynaphthalene formaldehyde sulfonate sodium salt, sulfonic acid carboxylic acid Esters, sulfonates, fatty acids, polyacrylates, polyacrylates, polyethers, polycarboxylic acids, polyurethanes, polyoxyalkylenes or sulfonate copolymers In any preferred embodiment of the invention, the humectant is supplied by TEGO, and the humectants are WET500, WET5 (H, WET502, WET245, WET270, respectively). Yes, provided by Yutai Trading Company, model number is 8 1293316
Sulf〇Xyi 8〇、Galoryl TR16、BP、OD40 之濕潤劑。 然後，開始製備多機能高分子母粒。將樹脂單體與上 述之多機能炭粉懸浮液或是經由多機能炭粉懸浮液乾燥處 理後之多機能炭粉同時置入聚合槽内，並進行聚合反應， 以得到多機能高分子。隨後，進行切粒製程，將多機能高 分子切粒成多機能高分子母粒。 其中’上述之樹脂單體之材料較佳為己内醯胺、己二 胺、2-甲基戊二胺、2-甲基己二胺、3·曱基己二胺、2,5-二 ϋ 甲基己二胺、2,2-二甲基戊二胺、5 -曱基壬二胺、十二烧二 胺、2,2,4-三甲基己二胺、2,4,4·三甲基己二胺、2,2,7,7_四 曱基辛二胺、間-二甲苯二胺、對-二甲苯二胺、二胺基二環 • 己基甲烷乙二酸、丙二酸、丁二酸、戊二酸、己二酸、對 笨一甲酸、間苯二甲酸、鄰苯二甲酸、乙二醇、苯二甲酸 雙羥丙酯、笨二甲酸雙羥乙酯、對苯二甲酸二甲酯、1，3-丙二醇或上述樹脂單體之任意組合。 接著’進行炼融紡絲製程以製作多機能高分子纖維。 _ I上述之夕機能高分子母粒與-般的楦f脂母粒以-定比例 心二之後’進行乾燥製程。再利用熔融紡絲機進行熔融紡 絲製j到多機能高分子、纖維。由於此時所製成之多 :此：刀子纖維容易變形，因而無法直接編織成織物，故 需：行加：製程，將多機能高分子纖維加熱延伸而形成加 工I ·』t提阿多機能高分子纖維之穩定度。最後，再利用 織仏製程如針織或梭織等技術將加工紗編織成一多機能 高分子織物。 、下將刀別針對本發明之兩較佳實施例做一詳細說 9 1293316 明，且兩較佳實施例為使用兩種不同的樹脂單體。本發明 較佳實施例之兩不同樹脂單體並不用以限定本發明之範 圍。 實施例一 在本發明之一較佳實施例中，係以竹炭粉作為多機能 炭粉。且使用余泰貿易公司所提供之分散劑以及德國TEGO 公司所提供之潤濕劑作為較佳實施例，分散劑與潤濕劑之 型號分別為Galoryl PT245L與TEGO WET500。首先製備竹 炭粉的懸浮液。將分散劑與潤濕劑溶於水中，接著進行攪 拌直至混合均勻。再將竹炭粉加入混合液中並進行高速攪 拌。隨後進行研磨製程以形成竹炭粉的懸浮液。然後進行 乾燥處理，可獲得平均粒徑為小於0.5 μιη，且90%之粉末 粒徑為小於1 μηι之微細竹炭粉，其中，竹炭粉的懸浮液在 研磨製程前之溶劑、竹炭粉、分散劑、潤濕劑之重量比例 較佳為 58 : 30 : 10.5 : 1.5。 將樹脂單體對苯二甲酸與乙二醇充分攪拌混合，並將 此樹脂單體之混合液置入聚合槽内，以進行後續之酯化聚 合反應。接著，再以260°C之較佳溫度進行酯化聚合反應， 然後將上述已製備完成之微細竹炭粉置入聚合槽中，並使 其與樹脂單體進行聚合反應，以得到竹炭聚酯。隨後，進 行切粒製程，將聚合反應所得之竹炭聚酯置於切粒機中切 粒，即可得到竹炭聚酯母粒。 然後，將竹炭聚酯母粒與一般的聚酯母粒以一定比例 混合，並以乾燥空氣將其乾燥至含水率較佳低於50 ppm。 1293316 隨後，開始進行熔融紡絲製程。利用一般的熔融紡絲機， 且以較佳速度為2500〜5000 m/min，較佳溫度為280°C的條 件下，紡絲製成纖維細度為130 /根數為48之竹炭聚酯長 纖維，亦可表示成130 dtex/48f的竹炭聚酯長纖維。 隨後，進行一加工製程。利用高速短加熱假撚機，並 於較佳溫度為400°C且較佳速度為600 m/min的條件下，將 竹炭聚酯長纖維加熱延伸，使其長度較佳延伸1.65倍，且 形成75 dtex/48f之加工紗。其中，上述之加工紗強度較佳 為3.5 cN/dtex，伸縮長度較佳為25%。 實施例二 在本發明之另一較佳實施例中，係以竹炭粉作為多機 能炭粉。且使用余泰貿易公司所提供之分散劑以及德國 TEGO公司所提供之潤濕劑作為較佳實施例，分散劑與潤濕 劑之型號分別為Galoryl PT245L與TEGO WET500。首先製 備竹炭粉的懸浮液。將分散劑與潤濕劑溶於水中，接著進 行攪拌直至混合均勻。再將竹炭粉加入混合液中並進行高 速攪拌。隨後進行研磨製程以形成竹炭粉的懸浮液。其中， 竹炭粉懸浮液在研磨製程前之介質、竹炭粉、分散劑、潤 濕劑之重量比例較佳為58 ·· 30 : 10.5 : 1.5。 在此較佳實施例中，係以己内醯胺作為樹脂單體。將 己内醯胺與上述之懸浮液均勻混合後，將此混合物置入一 聚合槽内。接著，進行一聚合反應，用以使樹脂單體己内 醯胺與懸浮液中的竹炭粉聚合成一竹炭聚醯胺樹酯。於聚 合反應後，即可進行切粒製程來得到竹炭聚醯胺母粒。其 11 1293316 中，上述之竹炭聚醯胺母粒的相對黏度大約為2.3〜3.3。 隨後，將竹炭聚醯胺母粒與一般的聚醯胺粒以一定比 例混合，並且在較佳溫度為90°C以下的乾燥空氣中乾燥至 含水率低於600 ppm。然後，進行熔融紡絲過程。在較佳溫 度為260 °C且較佳紡絲速度為4000 m/min的溶融紡絲機 中，製成96 dtex/24f的竹炭聚酯長纖維。再以較佳溫度為 400°C且較佳車速為600 m/min之高速短加熱假撚機，將多 機能聚酯長纖維加熱延伸，使其之長度較佳延伸1.2倍，且 形成75 dtex/24f之加工紗。其中，上述之加工紗強度較佳 為4·5 cN/dtex，伸縮長度較佳為25%。 抗菌試驗 將上述所的之加工紗進行紡織，形成一多機能織布 後，進行抗菌試驗。本發明係使用實施例二所得之織布來 進行抗菌試驗，所得之結果列於表一中。 表一多機能織布抗菌試驗 試驗項目 一般織布 多機能織布 金黃色葡萄球菌 (AATCC 6538P) 抑菌值 0.12 2.52 上述結果係依據日本纖維製品新機能評價協議會 (Japanese Association for the Functional Evaluation of Textiles; JAFET)之抗菌標準來進行試驗。依照JAFET之抗 12 1293316 菌標準，當抑菌值（Bacteriostatic value)大於2.2表示測試樣 本有抑菌效果。由表一可知，由本發明較佳實施例的方法 所製備而成之多機能織布，具有優秀的抑菌能力。 外線試驗 將上述所的之加工紗進行紡織，形成一多機能織布 後，進行遠紅外線試驗。本發明係使用實施例二所得之織 布來進行遠紅外線試驗，所得之結果列於表二中。 試驗項目 一般織布 多機能織布 照射後室内溫度fc ) 23.9 24.3 照射後樣品溫度（°c ) 25.0 39.8 溫差rc) + 1.1 + 15.5 本發明之遠紅外線測試項目係以遠紅外線升溫值測試 為主所抓用的測試儀器為Therm〇visi〇n且以W之 素燈照射多機能織布，照射距離為綱啦，照射時間為 min。由表二可知，由本發明較佳實施例的方法所製備 之多機能織布，其遠紅外線吸收率遠高於一般 外線吸收率，使其溫度可比室溫高15度以上。 心 除臭試驗^ 將上述所的之加工紗進行纺織，形成一多機能織布 13 1293316 後，進行除臭試驗。本發明係使用實施例二所得之織布來 進行除臭試驗，所得之結果列於表三中。 表三多機能織布之除臭試驗 試 驗項目 空白 多機能織布 Ohr NH3初始濃度 100 100 24hr nh3殘留濃度 68 41 nh3除臭率 - 40 上述結果係依據曰本纖維製品新機能評價協議會 JAFET之除臭性能評估試驗法來進行試驗。本發明之除臭 試驗係將體積為3 L且初始濃度為100 ppm的氨氣（NH3)， 置入於體積為5 L的Tedlar袋之中進行氨氣的除臭性能測 試。置入10x10 cm2之多機能織布，且於24小時之後量測 袋中之氨氣殘留濃度。接著，即可計算多機能織布之除臭 率。由表三可知，由本發明較佳實施例的方法所製備而成 之多機能織布，其除臭率約為40%，除臭效果相當不錯。 由上述之分析結果可知，由本發明較佳實施例的方法 所製備而成之多機能高分子纖維及其織物，皆具有較佳之 抗菌效果、高除臭率以及遠紅外線之吸收效能。且本發明 之方法係利用高分子聚合之方式，讓機能性粉粒與樹脂單 體一起進行聚合反應，以形成多機能高分子。本發明之方 法不僅能改善先前技術中分散不均之問題，更能提高樹脂 本身之物性，以減少材料成本的浪費。 1293316 因此，本於明 盤藏中，法所製備的多機能纖維於後段加工 "維持良好的纖維物性，進而提高纖維產率。 _ M Lk方法更可提高織物之财水洗性。 本發明已以—較佳實施例揭露如上，然其並非用 以限定本發明，任何熟習此技藝者，在不脫離本發明之精 神和範圍内，當可作各種之更動與潤飾，因此本發明之保 護範圍當視後附之申請專利範圍所界定者為準。 15Wetting agent for Sulf〇Xyi 8〇, Galoryl TR16, BP, OD40. Then, preparation of a multi-functional polymer masterbatch is started. The resin monomer and the multi-functional carbon powder suspension or the multi-functional carbon powder dried by the multi-functional carbon powder suspension are simultaneously placed in a polymerization tank, and polymerization is carried out to obtain a multi-functional polymer. Subsequently, a pelletizing process is carried out to pellet the multi-functional high molecular weight into a multi-functional polymer masterbatch. Wherein the material of the above resin monomer is preferably caprolactam, hexamethylenediamine, 2-methylpentanediamine, 2-methylhexamethylenediamine, 3,mercaptohexanediamine, 2,5-di ϋ Methyl hexanediamine, 2,2-dimethylpentanediamine, 5-nonyl stilbene diamine, dodecapine diamine, 2,2,4-trimethylhexanediamine, 2,4,4 · Trimethylhexamethylenediamine, 2,2,7,7-tetradecyloctanediamine, m-xylylenediamine, p-xylenediamine, diaminobicyclohexylmethane ethanedioic acid, C Diacid, succinic acid, glutaric acid, adipic acid, p-monoformic acid, isophthalic acid, phthalic acid, ethylene glycol, bishydroxypropyl phthalate, dihydroxyethyl benzoate Dimethyl terephthalate, 1,3-propanediol or any combination of the above resin monomers. Then, the smelting spinning process is carried out to produce a multi-functional polymer fiber. _ I The above-mentioned functional polymer masterbatch and the general 楦f lipid masterbatch are subjected to a drying process after a predetermined ratio of two. Further, the melt spinning machine is used to melt-spin the yarn into a multi-functional polymer or fiber. Because of the many things made at this time: this: the knives are easily deformed, so they cannot be directly woven into fabrics. Therefore, it is necessary to add: the process, and heat-extend the multi-functional polymer fibers to form a process I · 』t Tiado function The stability of polymer fibers. Finally, the woven fabric process, such as knitting or woven, is used to weave the processed yarn into a multi-functional polymer fabric. The lower knives are described in detail with respect to the two preferred embodiments of the present invention 9 1293316, and the two preferred embodiments use two different resin monomers. The two different resin monomers of the preferred embodiment of the invention are not intended to limit the scope of the invention. Embodiment 1 In a preferred embodiment of the present invention, bamboo charcoal powder is used as a multi-functional carbon powder. Further, as a preferred embodiment, a dispersant provided by Yutai Trading Co., Ltd. and a wetting agent provided by TEGO, Germany are used. The types of dispersant and wetting agent are Galoryl PT245L and TEGO WET500, respectively. First, a suspension of bamboo charcoal powder is prepared. The dispersing agent and the wetting agent are dissolved in water, followed by stirring until homogeneously mixed. The bamboo charcoal powder is then added to the mixture and stirred at high speed. A grinding process is then carried out to form a suspension of bamboo charcoal powder. Then, drying treatment is performed to obtain a fine bamboo charcoal powder having an average particle diameter of less than 0.5 μm and 90% of the powder particle diameter of less than 1 μηι, wherein the suspension of the bamboo charcoal powder is a solvent, a bamboo charcoal powder, and a dispersing agent before the grinding process. The weight ratio of the wetting agent is preferably 58 : 30 : 10.5 : 1.5. The resin monomer terephthalic acid and ethylene glycol are thoroughly stirred and mixed, and a mixture of the resin monomers is placed in a polymerization tank for subsequent esterification polymerization. Next, esterification polymerization is carried out at a preferred temperature of 260 ° C, and then the prepared fine bamboo charcoal powder is placed in a polymerization tank and polymerized with a resin monomer to obtain a bamboo charcoal polyester. Subsequently, the dicing process is carried out, and the bamboo charcoal polyester obtained by the polymerization reaction is placed in a pelletizer to be granulated to obtain a bamboo charcoal polyester masterbatch. Then, the bamboo charcoal polyester masterbatch is mixed with a general polyester masterbatch in a certain ratio and dried in a dry air to a moisture content of preferably less than 50 ppm. 1293316 Subsequently, the melt spinning process was started. Using a general melt spinning machine, and spinning at a preferred speed of 2500 to 5000 m/min, preferably at a temperature of 280 ° C, a bamboo charcoal polyester having a fiber fineness of 130 / 48 is prepared. Long fiber, can also be expressed as 130 dtex / 48f bamboo charcoal polyester long fiber. Subsequently, a processing process is performed. The bamboo charcoal polyester long fiber is heated and extended by a high-speed short heating false twisting machine at a preferred temperature of 400 ° C and a preferred speed of 600 m / min, so that the length is preferably extended by 1.65 times and formed. 75 dtex/48f processed yarn. Among them, the above-mentioned processed yarn has a strength of preferably 3.5 cN/dtex, and the stretchable length is preferably 25%. Embodiment 2 In another preferred embodiment of the present invention, bamboo charcoal powder is used as a multi-functional carbon powder. Further, as a preferred embodiment, a dispersant provided by Yutai Trading Co., Ltd. and a wetting agent provided by TEGO, Germany are used. The types of dispersant and wetting agent are Galoryl PT245L and TEGO WET500, respectively. First, a suspension of bamboo charcoal powder is prepared. Dispersant and wetting agent are dissolved in water, followed by stirring until homogeneous. The bamboo charcoal powder is then added to the mixture and stirred at high speed. A grinding process is then carried out to form a suspension of bamboo charcoal powder. Among them, the weight ratio of the bamboo charcoal powder suspension before the grinding process, the bamboo charcoal powder, the dispersing agent and the wetting agent is preferably 58 ·· 30 : 10.5 : 1.5. In the preferred embodiment, caprolactam is used as the resin monomer. After the caprolactam was uniformly mixed with the above suspension, the mixture was placed in a polymerization tank. Next, a polymerization reaction is carried out to polymerize the resin monomer caprolactam and the bamboo charcoal powder in the suspension into a bamboo charcoal polyamide resin. After the polymerization reaction, a pelletizing process can be carried out to obtain a bamboo charcoal polyamide precursor. In 11 1293316, the above-mentioned bamboo charcoal polyamide precursor has a relative viscosity of about 2.3 to 3.3. Subsequently, the bamboo charcoal polyamide precursor is mixed with the usual polyamide particles in a certain ratio and dried in a dry air preferably at a temperature of 90 ° C or lower to a moisture content of less than 600 ppm. Then, a melt spinning process is performed. A 96 dtex/24f bamboo charcoal polyester long fiber was produced in a melt spinning machine having a preferred temperature of 260 ° C and a preferred spinning speed of 4000 m/min. Then, with a high-speed short heating false twisting machine with a preferred temperature of 400 ° C and a preferred speed of 600 m / min, the multi-functional polyester long fiber is heated and extended to extend the length of the multi-function polyester by 1.2 times and form a 75 dtex. /24f processed yarn. Among them, the above-mentioned processed yarn has a strength of preferably 4·5 cN/dtex, and the stretchable length is preferably 25%. Antibacterial test The above-mentioned processed yarn was woven to form a multi-functional woven fabric, and an antibacterial test was carried out. In the present invention, the woven fabric obtained in Example 2 was used for the antibacterial test, and the results obtained are shown in Table 1. Table 1 Multi-functional woven fabric antibacterial test test project General woven multi-functional woven fabric Staphylococcus aureus (AATCC 6538P) Antibacterial value 0.12 2.52 The above results are based on the Japanese Association for the Functional Evaluation of Japanese The antibacterial standard of Textiles; JAFET) was tested. According to JAFET's anti- 12 1293316 bacteria standard, when the Bacteriostatic value is greater than 2.2, the test sample has a bacteriostatic effect. As can be seen from Table 1, the multi-functional woven fabric prepared by the method of the preferred embodiment of the present invention has excellent bacteriostatic ability. External line test The above-mentioned processed yarn was woven to form a multi-functional woven fabric, and subjected to a far-infrared test. In the present invention, the woven fabric obtained in Example 2 was used for the far-infrared ray test, and the results obtained are shown in Table 2. Test item General weaving multi-functional woven fabric after irradiation indoor temperature fc) 23.9 24.3 Post-irradiation sample temperature (°c) 25.0 39.8 Temperature difference rc) + 1.1 + 15.5 The far-infrared test project of the present invention is based on far-infrared heating value test. The test instrument used was Therm〇visi〇n and the multi-functional woven fabric was irradiated with the W-light. The irradiation distance was as follows, and the irradiation time was min. As can be seen from Table 2, the multi-functional woven fabric prepared by the method of the preferred embodiment of the present invention has a far-infrared absorption rate much higher than that of the general external absorption rate, so that the temperature can be higher than room temperature by more than 15 degrees. Heart Deodorization Test ^ The above-mentioned processed yarn is woven to form a multi-functional woven fabric 13 1293316, and then subjected to a deodorization test. In the present invention, the woven fabric obtained in Example 2 was used for the deodorization test, and the results obtained are shown in Table 3. Table 3 Deodorization test test program for multi-functional woven fabric Blank multi-functional woven fabric Ohr NH3 Initial concentration 100 100 24hr nh3 Residual concentration 68 41 nh3 Deodorization rate - 40 The above results are based on the new functional evaluation protocol of the 曰 纤维 fiber product JAFET Deodorization performance evaluation test method was used for the test. The deodorizing test of the present invention is carried out by placing ammonia gas (NH3) having a volume of 3 L and an initial concentration of 100 ppm in a Tedlar bag having a volume of 5 L for the deodorizing performance test of ammonia gas. A multi-functional woven fabric of 10 x 10 cm2 was placed, and the residual ammonia concentration in the bag was measured after 24 hours. Then, the deodorization rate of the multi-functional woven fabric can be calculated. As can be seen from Table 3, the multi-functional woven fabric prepared by the method of the preferred embodiment of the present invention has a deodorizing rate of about 40%, and the deodorizing effect is quite good. From the above analysis results, it is understood that the multi-functional polymer fibers and their fabrics prepared by the method of the preferred embodiment of the present invention have better antibacterial effects, high deodorization rate, and absorption efficiency of far infrared rays. Further, in the method of the present invention, the functional powder is polymerized together with the resin monomer by means of polymer polymerization to form a multi-functional polymer. The method of the present invention not only improves the problem of uneven dispersion in the prior art, but also improves the physical properties of the resin itself, thereby reducing waste of material costs. 1293316 Therefore, in the Ming Dynasty, the multi-functional fibers prepared by the law are processed in the latter stage to maintain good fiber properties and thus improve fiber yield. _ M Lk method can improve the fabric's water washability. The present invention has been disclosed in the above-described preferred embodiments, and is not intended to limit the invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application. 15