TWI290149B - Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof - Google Patents

Abstract

The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an alpha-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the alpha-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

Description

Eliminate

1290149 [Field of the invention] The present invention relates to a polar group-containing olefin copolymer, a process for producing the same, a thermoplastic resin composition containing the copolymer, and use thereof. More particularly, the present invention relates to a polar group-containing olefin copolymer having excellent adhesion properties to metal or a polar resin and excellent flexibility, a method for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and Its use. [Background of the Invention] Polyolefins generally have advantages such as excellent moldability, heat resistance, mechanical properties, hygienic quality, moisture permeability resistance, and appearance of molded articles, and are therefore widely used in extrusion moldings and blow molding. Molded articles and injection molded articles. However, since polyolefin does not contain a polar group in the molecule, compatibility with a polar resin such as nylon and EVOit is low, and adhesion between a polar resin and a metal is also low. Therefore, it is very difficult to blend or laminate polyolefins with these materials. Further, the molded article of polyolefin has a problem of poor hydrophilicity on the surface and poor antistatic property. To solve such problems, a method of grafting a polar group-containing monomer onto a polyolefin by radical polymerization has been widely used to enhance its affinity for a polar substance. Engineering plastics (e.g., nylon) have excellent heat resistance and strength and are therefore used for electronic/electrical parts, which generally have low impact resistance and are therefore sometimes blended with an olefin copolymer to improve impact resistance. However, polyolefins do not contain a polar group in the molecule and have low compatibility with a polar resin. Therefore, a method of grafting a polar monomer onto a polyolefin has been widely used to improve compatibility with a polar resin. This paper scale applies to China National Standard (CNS) A4 specifications (2) 0 X 297 public meals) 312991 (please read the notes on the back and fill in this page) --------tr--------- Μ, 1 A7 1290149 V. Inventive Note (2 However, in this method, intermolecular cross-linking of polyolefin and molecular chain cleavage occur during grafting reaction, so the viscosity of the graft polymer and the polar resin is difficult to match. In the case where satisfactory compatibility is not obtained. Further, the foreign matter (the foreign matter attached to the lip of the mold) generated by the gel component or the molecular chain breakage generated by the intermolecular crosslinking may cause molding. The appearance of the product is poor. Japanese Patent Laid-Open Publication Nos. 259012/1989, 51510/1990, 51511/1990 and 177403/1991 describe a method of copolymerizing a Q-olefin and a polar group-containing monomer using a butene catalyst or a v-catalyst. According to this method, intermolecular crosslinking and molecular chain cleavage are less likely to occur, but under the use of these polymerization catalysts, the resulting copolymer has a non-uniform molecular structure [e.g., a broad molecular weight distribution or a high inversion content]. Because the polar group is copolymerized The orientation between the interface of the substance and the polar substance may not be satisfactory, and the adhesion and compatibility with the polar substance may be insufficient. When used as a composition, the adhesion and compatibility are not exhibited unless the macromanganese graft copolymer is added. In order to enhance the hydrophilic and antistatic properties of the surface, a method of molding the mixture by adding a small amount of a low molecular weight surfactant to the polyolefin is used. However, in this method, the added surfactant overflows the surface. After molding, the surface of the film sometimes has a problem of whitening. The surfactant that has overflowed the surface flows down with the water droplets adhering thereto, and thus the problem that the effect of the surfactant cannot be sustained may occur. The present inventors addressed the above problems. As a result of the research, it was found that the copolymer having the specific structure of the genomic structure and the composition containing the copolymer have excellent compatibility with the polar resin, and the adhesion to the polar resin and the metal is excellent, and the paper size is also Applicable to China National Standard (CNS) A4 Specifications (2) G χ 297 ED) _ (Please read the phonetic on the back? Please fill out this page again} -------- Order ------ Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing A7 1290149 V. Invention description (3) The copolymer and the graded product have excellent surface hydrophilicity In addition, the present inventors have found that the copolymer and composition can be advantageously used in various applications. Preparation of an olefin polymer (e.g., ethylene homopolymer, ethylene/α-olefin copolymer, propylene homopolymerization) Method or propylene-olefin copolymer), which has heretofore been known to be included in the presence of a catalyst (composed of a solid titanium catalyst component containing magnesium, an electron donor and an electron donor, and an organic compound), or a vanadium catalyst. A method of polymerizing an olefin in the presence of (a composition of a vanadium compound and an organic compound). In the copolymerization of polar monomers using these catalysts, there is a problem that the molecular weight distribution or the composition distribution is wide and the polymerization activity is low. As disclosed in Japanese Patent Laid-Open Publication Nos. 259012/1989, 51510/1990, 51511/1990, and 177403/1991, the use of a Qiele catalyst to copolymerize an olefin and a polar group-containing monomer to prepare a 'polar group-containing poly group. In the case of a hydrocarbon, polymerization is carried out only at a low temperature. Therefore, this method is known to have a problem of low activity. It is generally known that an olefin is polymerized in the presence of a transition metal compound such as an aromatic cycloolefin metal catalyst composed of an aromatic ring olefin and an organic oxyalkylene compound. Using an aromatic cycloolefin metal catalyst, a high activity high molecular weight olefin polymer is obtained, and the resulting olefin polymer has a narrow molecular weight distribution and a narrow composition distribution. As a method of producing a polar group-containing polyolefin, a method of using an aromatic cycloolefin metal catalyst is also known. For example, as Macromolecules, 28, 5351 (1995),

Macrom〇lecules, 29, 5255 (1966), and p〇lymer 叫,

Japan, 49(2), 215 (2000), it is known in the literature to use a ligand having an uncrosslinked cyclopentyl group, a crosslinked or uncrosslinked double germination group, or a vinyl paper. The scale applies to China National Standard (CNS) A4 specification (210 X 297 public) 312991 ------------·丨| (Please read the note on the back and fill out this page) - Line _ Economy Ministry of Intellectual Property Bureau employee consumption cooperative printing 3 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 4 1290149 Λ7 __ Β7 V. Description of invention (4) Cross-linked unsubstituted thiol/diyl aromatic cycloolefin metal compound The polymerization of the OH group-containing olefin is carried out. As described in Macromolecules, 31, 2019 (1998) and Macromolecules, 32, 14 (1999), it is known in the literature to use ligands with uncrosslinked cyclopentadienyl groups, crosslinked or uncrosslinked diterpenes. The unsubstituted fluorenyl/cyclopentadienyl aromatic cycloolefin metal compound of the base or the cross-linking is subjected to polymerization of a rare hydrocarbon having a polar group of NR 2 (R · alkyl). Such as Science, 287, 460 (2000), OCOP2000 at Oslo, and

As described in Books of Abstracts (C.W. Chien), a method of using an organometallic compound other than an aromatic cycloolefin metal compound is known in the literature. However, these methods have the disadvantage of extremely low polymerization activity. For this reason, the polar group is protected by a protecting group. A method of protection is described, for example, in Macromolecules, 31, 2019 (1998), J Am Chem. Soc., 114, 9679 (1992) and P〇lymer preprints, Japan, 49(2), 209 (2000). However, in the above method, the introduced reaction needs to be removed after the reaction, and thus the operation is troublesome. In this case, the inventors have found that it is not necessary to use a radical polymerization reaction or a Ziegler polymerization catalyst, and a transition metal catalyst in which a cyclopentadienyl group or other specific ligand has been introduced exists Next, a olefin and a monomer having a polar group of 1± are copolymerized to prepare a polar group-containing thin smoke polymer. Based on this finding, the present invention has been completed. The method of selective _1,._ base at one end of the poly-chain chain or inside the main chain and one end of the main chain is still unknown. Under this circumstance, the inventor of the inventor Zhang's Zhang scale stabbed Zhongguan Jiaxian: NS) A4 specifications (2ϋ7 public meal 312991 -------------------- --------- Line (please read the notes on the back and fill out this page) CH2—CH- (1) -CH2—CH- Printed by the Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative...(2) 5 1290149 A7 B7 V. DESCRIPTION OF THE INVENTION (5 A method of selectively introducing a polar group only at one end of a polymer chain or inside a main chain and at one end of a main chain) Thus, the present invention has been completed. [Object of the Invention] Providing a polar group-containing olefin copolymer having excellent compatibility with a metal or a polar resin and having excellent compatibility therewith, a method for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and use thereof. SUMMARY OF THE INVENTION A first specific example of the polar group-containing olefin copolymer according to the present invention includes a constituent unit represented by the following formula (1), a constituent unit represented by the following formula (2), and a constituent unit represented by the following formula (3) , which has a molecular weight distribution (Mw/Mn) of not more than 3 and is measured according to the 13c_NMR spectrum of the copolymer The intensity ratio of Τα 召α α+Τα y5(Ta /5/(Τύ: α+Τα石) with not more than 1.0: •CH2—CH_ (R4)r—(χ)ρ ·· · (3 Wherein R 1 and R 2 may be the same or different and each is a hydrogen atom or a linear or branched aliphatic hydrocarbon group having 1 to 18 carbon atoms, · R 3 is a hydrocarbon group; and R 4 is a hetero atom or a hetero atom-containing group; Is 〇 or ι; χ is a polar group selected from the group consisting of an alcoholic hydroxyl group, a phenolphthalein hydroxyl 'carboxylic acid group, a carboxylate group 'anhydride group, an amine 'amine' group, an epoxy group, and a thiol group; p is 1 to An integer of 3; and when p is 2 or 3, 'each X may be the same or different. In this case, if r is 〇, then the X玎 paper size applies to the Chinese National Standard (CNS) A4 specification (2) G χ _ 297 public meal )------------ 312991 ---------------- 丨定---------Line fAW. C Jing read the back of the Note: Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau, Consumer Cooperatives, Printing 1290149 Α7 ------------Β7 V. Inventions (6) Combine the same or different atoms of R3, and if When r is 1, then X can be bonded to the same or different atoms of R4. In the present invention, R3 in the constituent unit represented by the formula (3) is preferably a hydrocarbon group having u or more carbon atoms. In the present invention, X in the constituent unit represented by the formula (3) is preferably a polar group selected from the group consisting of an enzyme type carboxyl group, a carboxylate group, an acid anhydride group, an amine group, a decylamino group, an epoxy group, and an anthracenyl group. In the present invention, it is preferred that R1 in the constituent unit represented by the formula (1) and R2 in the constituent unit represented by the formula (2) each have 2 or more carbon atoms, preferably 2 to 18 carbon atoms. The hydrocarbon group, and the copolymer has a crystallinity of not less than 10% as measured by a χ-ray diffraction method. In the present invention, it is preferred that Ri in the constituent unit represented by the formula (1) and R2 in the unconstituted unit of the formula (2) each have 2 or more carbon atoms, preferably 2 to 18 carbon atoms. The hydrocarbon group, and the copolymer preferably have a crystallinity of less than 1% by mass measured by a 乂-ray diffraction method. A second specific example of the polar group-containing olefin copolymer according to the present invention is a constituent unit including the following formula (1) and a constituent unit represented by the following formula (4), and a constituent unit represented by the formula (5), if necessary. a branched chain copolymer having a molecular weight distribution (Mw/Mn) of not more than 3 and having a value of not more than "the Τα _ ^ α + Τα stone / (Τα α + Τα 测定 根据 according to the 13C_NMR spectrum of the copolymer) )) Intensity ratio: ------------- - (Please read the notes on the back and fill out this page) Order - • Line -

6 312991 1290149

Description of the invention (7 • CH2—CH- • CH2-CH-

Wq-4R6)r4- I 0~2)n • · (1) ...(4) _CH2 一CH— f (R6L—(W)n ··· (5) Printed by the Ministry of Economic Affairs’ Intellectual Property Office Staff Consumer Cooperative R1 is a hydrogen atom or a star right 1 w and a linear or branched chain hydrocarbon group having 1 to 18 carbon atoms; R 5 is a hydrocarbon group; and R 6 is a group, a horse atom or a hetero atom-containing group; ::〇 or 1,z is a polymer sheet m obtained by any method using anionic polymerization, ring-opening polymerization or shrinkage. The base of the ring or the ring-gas soil 'P is an integer 1 of 3 to 0. '1 or 2, and p + q^3; when p or 3, each -〇_z may be the same or different. In this case, if "is 〇, then _〇彳 may be bonded to the same or different atom of R5. , if 4 b then _ 〇彳 can be combined with the same or different atoms of R6; when q is 2, each W can be the same or different, in this case, if ^ is 〇, then % can be combined with it Different atoms, and if r is 1, then w can bind to the same or different atoms of r6; in the case of (4) and ... is 〇, then W and OZ can combine the same or different atoms of ^R5, and if p then W and _〇彳 can be combined with the same or the same as R6 Different atoms; m is 0 or 1; η is an integer from 1 to 3, and when n is 2 or 3, each w may be the same or different, in which case, if m is 〇, W may be bonded to R5 The same or different atoms, and if 111 is i, W can be bonded to the same or different atoms of R6. / In this month, preferably, in formula (4), r is 〇 and z is an anionic poly-i system. The piece of paper obtained. The paper ruler money ^ 312991 · ^--------^---------Μ— , (Please read the notes on the back and fill out this page) 7 ^290149

DESCRIPTION OF THE INVENTION (In the present invention, ^^κ y , preferably in the formula (4), z is a polymer fragment obtained by ring-opening polymerization or shrinkage t. The third of the polar olefin copolymer Specific examples include a composition unit shown in the following formula (6), and a composition of the formula (3), which has a molecular weight distribution 不η of not more than 3, and The intensity ratio of Try « Ρ to Τ α α + Τ α 召 (Τ α / / (Τ α α + Τ α 召)) measured by the spectrum of the copolymer: _ch2-ch~ _CH2 a CH-

I

(R4)r-(x)D

OOr, R8—(Y)r (Please read the back of the page and then fill out this page) • (1) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing, ...(3) ...(6) R1 is a hydrogen atom or has! a linear or branched aliphatic cigarette group of up to 18 carbon atoms, R3 is a hydrocarbon group; R4 is a hetero atom or a hetero atom-containing group; is a direct bond or an aliphatic hydrocarbon group having one or more carbon atoms, · r8 Is a hydrogen atom, a direct bond or an aliphatic hydrocarbon group having one or more carbon atoms; γ is a polar group containing ruthenium and/or N, m and η are each an integer of 〇 to 2, and m + n is not 0; s is 0 or l; r is 〇 or ι; χ is selected from the group consisting of an alcohol type thiol group, a fluorenyl type light group, a carboxylic acid group, a carboxylate group, an acid anhydride group, an amine group, a decyl group, an epoxy group, and an anthracene. a polar group; Ρ is an integer from 1 to 3; when ρ is 2 or 3, each X may be the same or different, in which case, if r is 0, X may be bonded to the same or different atom of R3, And if r is 1, X can be bonded to the same or different atoms of R4. The first specific actual paper size of the polar olefin-containing copolymer according to the present invention is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 8 312991 s---------- · 149 149149 A7 B7 V. INSTRUCTIONS (9) Examples are included in the following composition: (A) compounds selected from Group 3 of the Periodic Table (including lanthanides and actinides) to Group 10 transition metals, and (Β) At least one compound selected from the group consisting of: (Β-1) organoaluminum oxy-compound, (Μ reacts with compound (4) to form an ion pair compound, and (Β-3) organoaluminum compound in the presence of a catalyst At least one olefin of a cardinal having 2 to 20 milnation carbon atoms and at least one of a polar group-containing monomer represented by the following formula (7) and a polar group-containing monomer represented by the following formula (8) Copolymerization of polar monomers: ch2=ch (R4)r~(X)p ·· (7) (Please read the notes on the back and fill out this page) Order - · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative Wherein R3 is a hydrocarbon group; R4 is a hetero atom or a hetero atom-containing group; 1 is ruthenium or 1; and X is selected from the group consisting of an alcoholic hydroxyl group and a phenolic hydroxyl group. a polar group of a carboxylic acid group, a carboxylate group, an acid anhydride group, an amine group, a decylamino group, an epoxy group, and an anthracenyl group; 1) an integer of 丨 to 3; when p is 2 or 3, each oxime may be the same Or different, in this case, if r is 0, X can be bonded to the same or different atoms of R3, and if r is 1, then X can be bonded to the same or different atoms of R4; turtle-(Y)n ... (8) - Line · Table paper scale applies to China National Standard (CNS) A4 specification (2ΐ〇Γ^7 mm) ----- 312991 A7

V. Description of invention (10) 1290149

Wherein R is a direct bond or an aliphatic hydrocarbon group having 1 or more carbon atoms; r8 is a halogen atom, a direct bond or an aliphatic hydrocarbon group having 1 or more carbon atoms; and Y is a polar group having 0 and/or N ;m and η are each an integer from 〇 to 2, and m+η is not 〇; s is 〇 or 1. In the first specific example of the method for producing a polar olefin-containing copolymer according to the present invention, it is preferred that the transition metal compound (A) is represented by the following formulas (11), (12), (13), (14), (15). And (16) as shown in any one of the above, and the polar group-containing monomer is a polar group-containing monomer wherein X is -OH or an amine group in the formula (7): (2) wherein M1 is a transition metal atom of Group 4 of the periodic table, R25, R26, R27 and R28 which may be the same or different and each of which is a hydrogen atom, a nitrogen-containing group, a phosphorus-containing group, a hydrocarbon group having 1 to 20 carbon atoms, and 1 to 20 a halogenated hydrocarbon group of a carbon atom, an oxygen-containing group, a sulfur-containing group, a thiol group or an i atom; a group represented by R25, R26, R27 and R28, a group adjacent to each other may be bonded to the group The carbon atoms are bonded together to form a ring; X1 and X2 may be the same or different and each is a hydrocarbon group having 1 to 20 carbon atoms, a halogenated group having 1 to 20 carbon atoms, an oxygen-containing group, a sulfur-containing group, and a a hydrogen atom or a halogen atom; and Y1 is a divalent hydrocarbon group having 1 to 20 carbon atoms, a divalent hydrocarbon group having 1 to 20 carbon atoms, a divalent group containing ruthenium, and a ruthenium containing group Divalent base, tin containing one, Jaki, -0_, _CO_, _S-, -SO-, -S02_, _Ge_, scale applicable to China National Standard (CNS) A4 specification (210 x 297 public f) ~ ""~ — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — Property Bureau employee consumption cooperative printed 1290149

5. Description of the invention (11 -Sn-, NRn-, _P(R21)...p(〇)(R21), _BR21 or read 21 (each R may be the same or different and is a hydrocarbon group having 1 to 2 carbon atoms, a nitrogen compound having a hydrogenated hydrocarbon group of 1 to 2 carbon atoms, a hydrogen atom, a halogen atom or one or two hydrocarbon groups having 1 to 20 carbon atoms bonded to a nitrogen atom;

··· (12) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing system w is a transition metal atom selected from Group 4 of the periodic table; cp is a 7-bonded pentadienyl group derived from m] or its derivative Zl is a ligand containing an oxygen atom, a sulfur atom, a boron atom or a group 14 element of the periodic table; γ1 is a ligand containing an atom selected from a nitrogen atom, a phosphorus atom, an oxygen atom and a sulfur atom; X1 may be the same or different and is a hydrogen atom, a _ atom, a hydrocarbon group having 2 or less carbon atoms and having 1 or more double bonds, and a silyl group having 2 or less ruthenium atoms. a germyl group containing 2 or less germanium atoms or a boronyl group containing 2 or less boron atoms;

In the formula I, Μ1 is a transition metal atom selected from Group 4 of the periodic table; Ru to r14 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210x^f^y ...(13) 11 312991 ------ --------------- Order --------- Line i^w. (Please read the notes on the back and fill out this page)

V. Description of invention (12) 1290149

Rl7 to R20 and R4i may be the same or different and each is a group having from 1 to 4 carbon atoms, a halogenated hydrocarbon group having from 1 to 40 carbon atoms, an oxygen-containing group, a sulfur-containing group, a thiol group, a halogen atom Or a hydrogen atom; R11, R12, r13, R14, r17,

Among the groups represented by Rl8, R19, RM and R41, a group which is adjacent to each other may be bonded to a carbon atom bonded to the groups to form a ring (R11, R13, R14, Rl7, Rl8, Rl9, Where R2G and r41 are all hydrogen atoms and R12 or R13 is a third butyl group, except for the case where R", R12, Rl3, Rl4, R, R, R19, R2() and R41 are a hydrogen atom) And a halogenated hydrocarbon group having an alkyl group having 1 to 20 carbon atoms and having 1 to 20 carbon atoms, an oxy group, a sulfur-containing group, a thiol group, a hydrogen atom or an i atom; Y1 is a divalent hydrocarbon group having 1 to 20 carbon atoms, a divalent halogenated hydrocarbon group having 1 to 20 carbon atoms, a divalent group containing ruthenium, a divalent group containing ruthenium, a divalent group containing tin, _〇 _, _c〇_, _s_, _s〇_, -so2-, -Ge_, _Sn_, _NR21_, _P(R21)_, _p(〇)(R2", _br2i_ or -AlR2i- (each R2! may be the same or different And a hydrocarbon group having from 2 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, a hydrogen atom, a halogen atom or one or two hydrocarbon groups having 1 to 20 carbon atoms combined with a nitrogen atom Compound residues); •··(14) 312991 --------^---------^ (Please read the notes on the back and fill out this page) Consumer Cooperatives print X" .X1 R41 R42,

Wherein Μ is a transition metal atom selected from Group 4 of the periodic table. ru'r] ^Paper £iiiT_Household Standard (CNS) A4 Specification (2)0 X 2-^17 ',, 12 A7 1290149 _________Β7__ V. Description of Invention ( Π ) (Please read the phonetic transcription on the back side and then fill out this page.) R41 and R42 may be the same or different and each is a hydrocarbon group having from 1 to 40 carbon atoms, a toothed hydrocarbon group having from 1 to 40 carbon atoms, and oxygen. a group, a sulfur-containing group, a rock-containing group, a halogen atom or a hydrogen atom; and a group represented by R11, R12, R41 and R42, which are partially adjacent to each other, may be bonded to a carbon atom bonded to the group Binding to form a ring; X1 and X2 may be the same or different and each is a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, an oxygen-containing group, a sulfur-containing group, a thiol group, a hydrogen atom or a halogen atom; and γ1 is a divalent hydrocarbon group having 1 to 20 carbon atoms (when all of RU, R12, R41 and r42 are hydrogen atoms, Y1 is not an ethyl group), and has 1 to 20 carbon atoms. Valence hydrocarbyl group, divalent group containing ruthenium, divalent group containing ruthenium, divalent group containing tin, 0, -CO-, -S-, -SO-, -S02·, -Ge-, -Sn - -NR21-, -P(R21)_, -P(0)(R21)·, -BR21- or _A1R21- (each R21 may be the same or different and is a hydrocarbon group having 1 to 20 carbon atoms, having 1 to a halogenated hydrocarbon group of 20 carbon atoms, a hydrogen atom, a halogen atom or a nitrogen compound residue formed by combining one or two radicals having 1 to 20 carbon atoms with a nitrogen atom;

In the printed version of the Intellectual Property Office of the Ministry of Economic Affairs, M1 is a transition metal atom selected from Group 4 of the periodic table; r4i and R42 are the same or different and each is a hydrocarbon group having 1 to 40 carbon atoms, having 1 奚40 The halogenated hydrocarbon group of carbon atoms, oxygen-containing, sulfur-containing, sulfhydryl-containing, halogen-based papers are applicable to China National Standard (CNS) A4 specification (210x 297 mm). 13 312991 Printed by the Intellectual Property Office of the Ministry of Economic Affairs 1290149 A7 _________B7 V. Description of the invention (Η) Atom or a hydrogen atom; a group of R and R42, a group adjacent to each other may be bonded to a carbon atom bonded to the group to form a ring; X2 may be the same or different and each is a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 2 carbon atoms, an oxygen-containing group, a sulfur-containing group, a mercapto group, a halogen atom or a halogen atom; a divalent hydrocarbon group having 1 to 20 carbon atoms, a divalent halogenated hydrocarbon group having 1 to 20 carbon atoms, a divalent group containing ruthenium, a divalent group containing ruthenium, a divalent group containing tin, _〇_, -CO-, _SO-, -S02-, _Ge-, _Sn_, -NR21_, _p(R2i)_ _p(〇)(R2i)_, _BR2i_ or -AIR21- (each R21 may be the same or different and is a hydrocarbon group having from i to 20 carbon atoms, a halogenated hydrocarbon group having from 1 to 20 carbon atoms, a hydrogen atom, a halogen atom or a nitrogen compound residue formed by combining one or two hydrocarbon groups having 1 to 20 carbon atoms with a nitrogen atom);

(16) wherein M1 is a transition metal atom selected from Group 4 of the periodic table; rii, ri2, R15 to R2G, and R42 may be the same or different and each is a hydrocarbon group having 1 to 4 carbon atoms, a halogenated hydrocarbon group of 1 to 40 carbon atoms, an oxygen-containing group, a sulfur-containing group, a thiol group, a halogen atom or a hydrogen atom; a group represented by R11, R12, R15, R16, R17, R19, R20 and R42 The partially adjacent groups 玎 are bonded together with the carbon atoms bonded to the groups to form a ring; X1 and X2 are the same or different and each is a hydrocarbon group having 1 to 20 carbon atoms, and has a size of 1 ^^. China National Standard (CNS) A4 specification U10 X 297 mm) -------------------- Order --------- (Please read the back Precautions Fill in this page) 14 312991 A7 1290149 ^------B7____ V. Description of the invention (I5) Halogenated hydrocarbon group to 20 carbon atoms, oxygen-containing, sulfur-containing group, thiol group, hydrogen atom or a halogen atom; and Y1 is a divalent hydrocarbon group having 1 to 20 carbon atoms (when R11, R12, R15, R16, R17, r18, R19, R2 0 and r42 are all hydrogen atoms, Y1 is not stretched Ethyl) with 1 to 2 carbons Divalent halogenated hydrocarbyl group, divalent group containing ruthenium, divalent group containing ruthenium, dibasic group containing tin, _0-, -CO_, -S, -SO-, _s〇2_, -Ge-, -Sn·, _NR21-, _P(R21)-, _P(〇)(R21)-, _BR2l_ or _a1R21- (each R2i may be the same or different and is a hydrocarbon group having 1 to 20 carbon atoms, having i to 2 A halogenated hydrocarbon group of a carbon atom, a hydrogen atom, a halogen atom or a nitrogen compound residue formed by combining one or two hydrocarbon groups having 1 to 2 carbon atoms with a nitrogen atom). In the first specific example of the method for producing a polar olefin-containing copolymer according to the present invention, it is preferred that the transition metal compound (A) is represented by the following formulas (u), (12), (13), (14), (15) And (16) as shown in any one of the above, and the polar group-containing monomer is in the above formula (7), and X is ->^"11'' (11, and 11, which may be the same or different and are a hydrogen atom Or an alkyl group-containing polar group-containing monomer. A second specific example of the method for producing a polar group-containing olefin copolymer according to the present invention includes the following composition: (A) a compound selected from Group 3 (including lanthanides and actinides) of the periodic table to a transition metal of Group 1 And (B) at least one compound selected from the group consisting of: (B-1) an organoaluminum oxy compound, (B-2) reacting with the compound (A) to form an ion pair compound, and (B-3) an organoaluminum In the presence of the catalyst of the compound, the paper size of the α-olefin selected from 2 to 20 carbon atoms is applied to the China National Standard (CNS) A4 specification (210 X 297 public meals) '· 312991 ---· I --------------- Line (please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 15 1290149 Five invention description 16 to ^, an alpha An olefin and a polar group selected from the group consisting of a polar group-containing monomer represented by the above formula (7), a less than one fluorene-based precursor, and a macromonomer represented by the following formula (9) The base monomer is copolymerized:

CH2=CH (W)q-fRe)r4-〇~?)p . . . (9) :·, 4 ^基' R6 is a hetero atom or a hetero atom-containing group; r is 〇 to become an anionic polymerization , ring-opening polymerization and polycondensation of any of the polymer fragments obtained by the method; W is a trans group or an epoxy group; p is an integer q of 1 is °, 1 or 2, and P + qg3; when p is 2 Or 3 B, each 〇Z may be the same or different. In this case, if 『〇, then _〇_z. 6 is the same or different atom of R, and if r is i, then -0_z can be bonded to the same or different atom of R; when 9 is 2, each W can be the same or different from the shape of '匮! 〇 ' Then ~ can be combined with the same or different atoms of r5, and if r is 1, W can be combined with the same or different atoms of ...; in the case of P-ι and q ^ l, if 1 is 〇, then % and _〇彳 may each be bonded to the same or different atoms of R5, and if 1 is i, then w and 彳 may each be bonded to the same or different atoms of R6. A third specific example of the method for producing a branched-chain polar group-containing olefin copolymer according to the present invention is included in the following composition: Consumer Co., Ltd. (A) is selected from Group 3 of the periodic table (including lanthanides and actinides) to a compound of the first steroid transition metal, and (B) at least one compound selected from the group consisting of: (B-1) an organoaluminum oxy-compound, the paper size is applicable to the Chinese National Standard (CNS) A4 specification (2I 〇 x 297 Love)· 16 (Please read the back of the 涑 涑 顼 # Fill in the tribute] 312991

5. Description of the invention (17 (10) 1290149 (B-2) reacts with the compound (A) to form an ion pair compound, and (B-3) an organoaluminum compound in the presence of a catalyst, such that it has a choice of from 2 to 20 Copolymerization of at least one olefin of the α-olefin of a carbon atom, a polar group-containing monomer represented by the following formula (10), and optionally a polar group-containing monomer represented by the above formula (8):

CH2=CH (R6)m~(W)n wherein R5 is a hydrocarbon group; R6 is a hetero atom or a hetero atom-containing group; m is hydrazine or l, w is a hydroxyl group or an epoxy group; 1! is 1 to 3 An integer; and when η is 2 or 3, 'W' may be the same or different. In this case, if m is 〇, W may be bonded to the same or different atom of r5, and if m is 1, then w may be Binding to the same or different atoms of R6; then performing any of the following steps (i) and (ii): (0 using anionic polymerization, ring opening polymerization or polycondensation to copolymerize the polar group-containing monomer The w portion forms a z moiety; (ii) reacts the W portion of the copolymerized polar group-containing monomer with a terminal functional group of a polymer obtained by anionic polymerization, ring opening polymerization or polycondensation. The thermoplastic resin composition contains a polar group-containing anthracene hydrocarbon copolymer. The binder resin according to the present invention includes a polar group-containing dilute hydrocarbon copolymer or a thermoplastic resin composition. The compatibilizing agent according to the present invention includes a polar group 312991 --------^--------- (Please read the notes on the back and fill out this page) Ministry of Commerce, Intellectual Property Bureau, Staff and Consumer Cooperatives, Printing 17 1290149 A7 B7 V. Invention Description (is Ministry of Economic Affairs Intellectual Property Officer X Consumer Cooperative Printed Base Olefin Copolymer or Thermoplastic Resin Composition. The resin modifier according to the present invention includes A polar group-containing olefin copolymer or a thermoplastic resin composition. The filler dispersant according to the present invention comprises a polar group-containing olefin copolymer or a thermoplastic resin composition. The dispersion according to the present invention comprises a polar group-containing olefin copolymer or thermoplastic. The film or sheet according to the present invention includes a polar group-containing olefin copolymer or a thermoplastic resin composition. [Detailed Description of the Invention] Hereinafter, the polar group-containing olefin copolymer according to the present invention will be described in detail. The method of the copolymer, the thermoplastic resin composition containing the copolymer, and the use thereof. The polar group-containing stimulating hydrocarbon copolymer The first specific example of the polar group-containing olefin copolymer of the present invention includes the composition represented by the following formula (1) Unit (hereinafter also referred to as "composition unit (1)", as shown in the following formula (2) The constituent unit (hereinafter also referred to as "composition unit (2)" and the constituent unit shown in the following formula (3) (hereinafter also referred to as "composition unit (3)". _CH2-CH- "CHo-CH&quot ; _CH2—CH" (R4)r one ---------------. I------ order --------- line ΙΛΨ. (Please read the back first Note: Please fill out this page again. (1) (2) (X)p (3) In the above formula, R1 and R2 may be the same or different and each is a hydrogen atom or has a straight 1 to 18 carbon atoms. A chain or branched chain aliphatic hydrocarbon group. This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 public reorganization 18 312991 A7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 19 1290149 5, invention description (l9 eight with 1 to 18 carbon atoms straight Examples of the chain or branched aliphatic hydrocarbon group include mercapto, ethyl, n-propyl, isopropyl, 2-methylpropyl, n-butyl, isobutyl, t-butyl, t-butyl, u-di Methyl propyl, 22 dimethyl propyl, pentyl, neopentyl, n-hexyl, ethyl small methyl propyl, a diethyl propyl, 2-ethylhexyl, octyl, decyl and More preferably, it is a hydrocarbon group having 1 to 10 carbon atoms, particularly 1 to 6 carbon atoms. R3 is a hydrocarbon group such as a saturated or unsaturated aliphatic hydrocarbon group, an alicyclic hydrocarbon group or an aromatic group. A saturated or unsaturated group of ketones is, for example, a straight or branched chain hydrocarbon group having 1 to 2 carbon atoms. Examples thereof include methyl group, ethyl propyl group, methyl group ethyl group, and butyl group. Base, methyl propyl group, pentyl group, hexyl group, heptyl group, octyl group, hydrazine group, hydrazine group, tenth methyl group Methyl, tetradecylmethyl, hexadecanomethyl, hexadecylmethyl, heptylmethyl, octadecylmethyl, hexadecylmethyl and hexamethyl. The hydrocarbon group preferably has a alicyclic structure as a part of its structure and a group having 3 to (four) carbon atoms, and examples thereof include a cyclopropyl-extended cyclopentyl group, a cyclohexylene group and a cyclooctyl group. The aromatic hydrocarbon group is preferably a moiety having an aromatic ring as its structure and a group having 6 to 20 carbon atoms, and examples thereof include _ph, ·4 ratio _/, _ Ph-(CH2)2-. -Ph-(CH2 ) 3- ^ -Ph-(CH2)6- . .Ph.(CH ' _ Ph_(CH2)"-, -Ph_(CH2)12- and -PMCH2)i4·. 2 1〇 When r is 1 and When R4 is combined with R3, the valence of R3 is 2. The _ and 11 valences are P+1. Tian. 'The paper scale is timely at home i^s." A4 specification (2) Q χ 312991 ------- ------Aw--------Book---------Line (please read the notes on the back and fill out this page) 1290149 V. Invention Description (20 R4 is a hetero atom Or a hetero atom-containing base ring. The hetero atom is, for example, an oxygen atom, nitrogen is an oxygen atom or a nitrogen atom. ', or a sulfur atom, preferably the hetero atom-containing group is For example, an atom-containing group, examples of which include ... b.) ', a child, a nitrogen atom or sulfur 0C (=0) 0 -, · 0 (=0) ΝΗ _, _NH :, 'c ('0-, - The aliphatic, alicyclic or aromatic hydrocarbon groups of the base ring, and the amines, -S-, and, in particular, the monomers which are exemplified by these structures may be mentioned below. The carbon atom to which the hetero atom or the hetero atom is bonded is preferably bonded to R, and examples of such structures include -R3_〇_R_X, _R3_eb (7)X, and R3-C(, 0-rx, - R3_0C(=0)_R_X, _R3_c(=〇) bribes and _R-SRX (R is methyl, phenyl or cyclohexyl). When the R4 contains a carbon atom, the number of carbon atoms forming R4 is preferably in the range of i to 20', more preferably 1 to 10, particularly preferably i to 5. r is 0 or 1. When r is 〇, X is bonded to any one of the carbon atoms forming R3. When r is 1, then X is bonded to any one of the carbon atoms forming R4. X is a polarity selected from the group consisting of an alcoholic hydroxyl group, a phenolic hydroxyl group, a carboxylic acid group, an acid vine group, an acid anhydride group, an amine group (primary, secondary and tertiary amine groups), a guanamine group, a ring gas group and a sulfhydryl group. Base 0 When X is an alcoholic hydroxyl group, the polar group-containing olefin copolymer has excellent coatability, surface hydrophilicity (anti-fog property), antistatic property, polar tree resin (amine ester resin, ring) Oxygen resin, etc.) Adhesiveness, filler dispersibility, paper size applicable to China National Standard (CNS) A4 specification (210 X 297 public ' 20 312991

(Please read the notes on the back and fill out this page) ----tr-------------------------------- - 21 1290149

Properties, gas barrier properties (in the case of high content), water absorption (in the case of high alcoholic hydroxyl groups), dispersibility in water, and oil resistance (in the case of high alcoholic hydroxyl groups). When X is a phenolic hydroxyl group, the polar group-containing olefin copolymer has excellent adhesion to a polar resin (aromatic polymer, phenol resin, etc.), and a polar resin (aromatic polymer, phenol type) Compatibility of resin, etc.). When X is a slow group, the polar group-containing olefin copolymer has excellent adhesion to metals, dispersibility in water (particularly in the case of metal salts), color dispersion, filler dispersibility, and oil resistance. (in the case of high carboxyl groups). When X is a carboxylate group, the polar group-containing olefin copolymer has excellent adhesion to a polar resin (nylon, EVOH, etc.), compatibility with a polar resin (nylon, EVOH, etc.), and surface hydrophilicity. Sex. When X is an epoxy group, the polar group-containing olefin copolymer has excellent adhesion to metals, adhesion to polar resins (polyester, epoxy resin, nylon, EVOH, urea resin, etc.), Compatibility of polar resin (polyester, epoxy resin, nylon, EVOH, urea resin, etc.), colorant dispersibility, and f coating property. Part | When X is an acid anhydride group, the polar group-containing olefin copolymer has excellent adhesion to metals, adhesion to polar resins (nylon, EVOH, polyester, etc.), and polar resin (nylon) Compatibility of EVOH, polyester, etc., dispersibility of I colorant, dispersibility of filler, and dispersibility in water (especially in the case of metal salts). 1 I When the X is an amine group, the polar group-containing olefin copolymer is excellent. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 public) ------- 312991

1290149 V. INSTRUCTIONS (22) Adhesiveness, coating property, antifogging property (in the case of ammonium salt) and ion exchange property of polar resin (epoxy resin, polyketone, polyurethane, etc.) (in the case of ammonium salt) ), surface hydrophilicity (especially in the case of ammonium salts), antistatic properties (especially in the case of ammonium salts), colorant dispersibility and filler dispersibility (especially in the case of money salts). When X is a guanamine group, the polar group-containing olefin copolymer has excellent adhesion to polyamine and compatibility with polyamine. When X is a fluorenyl group, the polar group-containing olefin copolymer has excellent adhesion to a transition metal of the periodic table (for example, Fe, Cu, Co, Ni, Cd, and Ζη), to polyamine and polyester. Compatibility and adhesion to polyamines and polyesters. ρ is an integer from 1 to 3, and when ρ is 2 or 3, each X may be the same or different. When ρ is 2 or 3 and 1« is 〇, X may be bonded to the same or different atoms of the inverse 3, and when ρ is 2 or 3 and r is 1, X may be bonded to the same or different atom of & . In the polar group-containing olefin copolymer of the present invention, the constituent unit (1), the constituent unit (2) and the constituent unit (3) are usually in a random combination. The composition of the copolymer in the polar group-containing olefin copolymer of the present invention, the sum of the constituent unit (1) and the constituent unit (2) and the molar ratio between the constituent units (3) ((1) + (2): (3)) usually at 99·99·····1 to 〇.〇1:99,99, preferably 99·95:〇〇5 to 1〇:9〇, more preferably 99.9:0.1 to 30 Within the range of 70. The molar ratio (〇) between the constituent unit (1) and the constituent unit (2): (2)) is usually 99.99··0·01 to 〇·01··99·99, preferably 99:1 to 1 : 99, more preferably 9 inches: 1〇 to 10:90. This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 Order---------Line (please read the note on the back and fill in this page) Ministry of Economic Affairs Intellectual Property Office staff Consumer Cooperatives Printed 22 A7 1290149 V. INSTRUCTIONS (23) The polar olefin-containing copolymer of the present invention may contain two or more constituent units (1), and may contain two or more constituent units (2), And may contain two or more constituent units (3). The copolymerizable component of the present invention The polar group-containing olefin copolymer of the present invention may contain the constituent unit (1) and the composition within the limits of the object of the present invention. The unit (2) and the constituent unit other than the constituent unit (3). Examples of the constituent unit which may be contained include a cyclic olefin derived from a polar group-containing monomer represented by the formula (8), a non-conjugated polyene, and a hydroxyl group-containing Ethylenically unsaturated compounds, amine-containing unsaturated compounds, epoxy-containing dilute unsaturated compounds, aromatic vinyl compounds, unsaturated carboxylic acids and derivatives thereof, vinyl ester compounds, and vinyl chloride The constituent unit. When these are included When the unit is formed, the amount thereof is not more than 3 Torr/❶, preferably not more than 20% by mole, more preferably not more than 1 所有, based on all the constituent units constituting the polar-containing dilute hydrocarbon copolymer. Molar/〇. Properties of the copolymer The weight average molecular weight (Mw) of the polar group-containing olefin copolymer of the present invention is usually from 500 to 2,000,000, preferably from 800 to 1,500,000, more preferably from 1 to 1 The molecular weight distribution (Mw/Mn) within the range of 300,000 is usually not more than 3, preferably not more than 2.8, more preferably not more than 2.7. When the molecular weight distribution (Mw/Mn) is not more than 3, the polarity is included. The olefin copolymer's polar group has excellent interposition between the copolymer and the polar material interface' and has excellent adhesion to polar materials and excellent compatibility--t- --------^ (Please read the notes on the back and fill out this page) Printed by the Intellectual Property Office of the Ministry of Economic Affairs

23 312991 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 1290149 A7 _______ B7 V. Invention description (24)

Mw and Mw/Mn were determined from GPC (gel permeation chromatography) in n-chlorobenze > granules at 140 °C. In the i3 NMR spectrum of the polar olefin-containing copolymer, the intensity ratio of Τα0 to T α α+Τα cold (Τα /5/(Τα α+Τα)) is not more than 1.0, preferably not more than 0.8, more Good is no more than 〇.5. When the intensity ratio (Τα召/(Τα α+Τα泠)) is not more than 1.0, the polar group-containing olefin copolymer has a polar group which is excellent in the position between the copolymer and the polar substance interface. In the 13C-NMR spectrum, Τα α and Τα /? are each a peak intensity of CH 2 derived from a constituent unit derived from an α-olefin having 4 or more carbon atoms, as shown below, which means Two kinds of CH2 with different relative positions of carbon

R R R R

i Λ λ i I _ L a c a c c a c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c Method determination. The 13C_NMR spectrum of the polar olefin-containing copolymer can be measured, for example, using a Japan Electron Optics Laboratory JEOL-GX270 NMR measuring device. This measurement uses a hexachlorobutadiene/d6-benzene (2/1, volume ratio) mixed solution with a sample concentration of 5% by weight, at 67.8 MHz, 25 ° C and d6-benzene (128 ppm). Under conditions, and according to Lindemann Adams (Analysis Chemistry 43, -------------------- order --------- line ^9. (Please first Read the notes on the back and fill out this page.) This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 24 312991 1290149

5. The description of the invention (25 ρ·1245 (1971)) and JC Randall (Review Macromolecuiar Chemistry Physics, C29, 201 (1989)), analyze the measured "C-NMR spectrum to determine τ α卢 / ( Τ α α +Τ α call) intensity ratio. The examples of the polar group-containing olefin copolymer according to the first embodiment of the present invention comprise the following polar group-containing olefin copolymers (1) to (VI). Polar group-containing olefin copolymer m Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed in polar group-containing olefin copolymer (I) and R2 in formula (2) are each hydrogen atom or methyl group in polar group-containing The preferred combination of the element (2) and the constituent unit (3) in the olefin copolymer (I) is a constituent unit of the unit (1) and a constituent unit selected from the group consisting of the examples of the unit (3) The combination. Examples of such combined cardiac details include 1仏, 1-B, 1_C, 1-D, 1-E, 1_F, 1_G,] w Ί τ “Η, Μ, 1 -J, L卜 L, 1·Μ, 2-Α, 2-Β, 2-C, 2-D, 2-Ε, 2 F ο η . Dongbu 2-G, 2-Η, 2-1, 2-J, 2-Κ, 2-L And the combination of 2-Μ, etc. The above combination is where R1 and R2 are in phase with each other, and the constituent unit (1) contains the constituent unit (2). In the above combination example, the number represents a table, and is early ( 1) In the example, the English alphabet represents an example of the constituent unit (3). Preferably, R1 and R and R2 in the formula (1) are identical to each other. The constituent unit (1), the constituent list is, for example, selected from the group shown in Table 1. CPlease read the notes on the back and then fill out this page.). Line - Paper size (4) _ Family Standard (CNS) A4 Regulation 25 312991 1290149 A7 B7 V. Invention Description (26) Table 1 Ministry of Economic Affairs Intellectual Property Bureau Employee consumption cooperative printing number component (1) Numbering unit (3) 1 -CH2—CH— Η A —CH2—CH— HO—C—C—CH2 h2 h2 2 —CH〇CH—I ch3 B — CH2-CH-HO-C, CH2 transport CH2 h2 C-ch2-ch- HO-g, CH2 transport CH 2 D —CH 2 —CH— HO—C—^ CH 2 )fCH 2 h 2 E —CH〇—CH—I HO—CHCH2 圬ch2 h2 F ——CH 2 —CH — I HOOC—C—C_CH2 h2 h2 G—CH 2 CH— I HOOC-C-< CH2 )2 CH2 H —CH2—CH— HOOC-C-(CH2)^CH2 h2 I —CH2—CH— I HOOC — J —01⁄2—CH— |:ch^ch2 洧Ch2 h2c This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) «·! (Please read the note on the back and fill out this page) -丨线· 26 312991 1290149 A7 B7 V. Description of invention (27)

K / C, 9h2 - CH2 - CH - \ CH-r ϋ Η I g - C = c - C - C - CH2 > y H2 H2 H2 〇 / c ^ ch2 — ch2-ch- — CH2—CH -H 〇乂J)-〇-pCH2)^H2 The polar group-containing olefin copolymer (j) according to the present invention has excellent adhesion, compatibility and lubricity to polar substances such as metals and polar resins. The polar group-containing olefin copolymer qn is in the polar group-containing olefin copolymer (II), and R1 in the formula (1) and R2 in the formula (2) are different from each other. In the polar group-containing olefin copolymer (II), a preferred combination of the composition "| _ called early 7 〇 (1), composition early element (2), and constituent unit (3) is, for example, g from Table 2 The group shown -------------Φ (please read the notes on the back and fill out this page) Order---------Line of Economics Department Intellectual Property Bureau Staff Consumer Cooperatives The constituent unit of the example of the unit (1) and the constituent unit (2) is selected from the combination of the constituent units of the example of the constituent unit (3) shown in Table 2. The detailed examples of the search, and the combination include 1- A, 1-B, 1_C, 1-D, 1-E, Ι-p, • G, 1_H, 1- 1- J, 1-K, lL, 1-M, 2·Α, 2-B, 2 · (:, 2- G, 2-H, 2-1, 2-J, 2·Κ, 2-L,

2-E, 2-F _A, 3_B, 3_C 3-D, 3_E, 3-F, 3-G, 3_H, 3_I, 3-J, 3 p W, 3_L, 3-M 4-A, 4-B , 4-C, 4-D, 4-E, 4_F, 4_G, "Tt4_H,, 4-j, 4-K, 4-L, 4-M, 5-A, 5-B, 5-C, 5 ·Ε), < ^ , 5_f, 5-G This paper scale applies to China National Standard (CNS) A4 specification (210x 297 mm) 27 312991 A7 1290149 B7 V. Invention description (28) 5_H, 5-1, 5_J , 5-K, 5-L, 5-M, 6-A, 6-B, 6-C, 6-D, 6-E, 6_F, 6-G, 6_H, 6_I, 6-J, 6-K , 6-L, 6_M, 7-A, 7-B, 7-C, 7-D, 7-E, 7_F, 7-G, 7_H, 7_I, 7_J, 7_K, 7-L and 7-M . In the above combination example, the numbers represent the examples of the constituent units (1) and (2), and the English letters represent examples of the constituent unit (3). (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Office, Staff and Consumer Cooperatives Printed This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 28 312991 1290149 Λ7 B7 V. Invention Description (29) Table 2 Printed by the Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative

Numbering unit (1), (2) Numbering unit (3) 1 - CH2 - CH - CH2 - CH - IIH CH3 A - CH2 - CH - : HO - C - C - CH2 h2 h2 2 - CH2 - CH 1-CH2-CH-H H3C-CH2 B-CH2-CH-I HO-C-(CH2)jCH2 h2 3 —CH2-CH—CH2-CH—H H3C—CC-CH2 H2 C—CH2—CH— I HO-C-( CH2^CH2 « 4 —CH2-CH—CH2 — CH— H H3C—8—CH2 ch3 D —CH 2 —CH— I HO—CHCH^CHa h2 5 —CH 2 —CH — — CH2—CH—H H3C-< CHz^CH2 E —CH2—CH a \ HO-C-( CHz^CHa 6 -ch2-〒h- -ch2-ch--ch2-ch- H CH3 H3C-CH2 F CH2-GH-HOOC-CC-CH2 h2 h2 7 -CH2-〒 H--CH2-〒 H-CH3 H3C-CH2 G-CH2-CH-I HOOC-CHCH2)jCH2 h2 H-CH2-GH--HOOC —g-<CH2)5CH2 * I —ch2-ch— I HOOC—C—(CH2^〇CH2 h2 J—CH2—CH—by ch2 HjC (please read the back note before filling this page) -------- Line - This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 29 312991 1290149 A7 ________B7 V. Description of invention (3 〇 ) κ 卜 Η — 2 —CH 2 —CH · Η Η I Ά-C a C=C_C—C—CH2 η2 Η2 Η2

L /c^ch2 •CH2 -CH· mouth rsVH2 Μ ——CH2—CH—CHg^CHg Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs, preferably the polar group-containing olefin copolymer (II) does not contain the previously mentioned And other copolymerization components are formed only by the constituent unit (1), the constituent unit (2), and the constituent unit (3). Particularly when X is an alcoholic hydroxyl group, a phenolic hydroxyl group or an amine group, the polar group-containing olefin copolymer is particularly preferably formed only of the constituent unit (1), the constituent unit (2) and the constituent unit (3). The polar group-containing olefin copolymer (II) according to the present invention has excellent adhesion, compatibility and properties to polar substances such as metals and polar resins. The polar group-containing olefin copolymer am in the polar group-containing olefin copolymer (III), and R3 in the formula (3) is a hydrocarbon group having 11 or more carbon atoms. In the polar group-containing olefin copolymer (III), a preferred combination of the constituent unit (2) and the constituent unit (3) is, for example, a constituent unit selected from the group consisting of the constituent unit (1) and the constituent unit (2). Fish, wall △ is not a combination of the constituent units of the constituent unit (3) shown in Table 3. Detailed examples of such groups, ugly σ include 1-A, 1-B, 1-C, 2-A, 2_B, 2-C, 3 δ, ______A, 3_B, and ------- -------------Set---------Line (please read the notes on the back and fill out this page) This paper scale applies to China National Standard (CNS) A4 specification ( 210 x 297 mm) 312991 30

, 5_A, 5_B, 5-C, 6-A, 6-B, 6_C, 7-A, 8, 8-B, 8-C, 9-A, 9-B, 9-C, 10-A, 10- B 1290149 '—~ ----§1 V. Description of invention)

4_A, 4-B, 4-C 7_B ' 7_C, 8-A and i〇-c combinations & Table 3 'Composition unit (1) and (2) column only shows one component unit, Department of thinking R1 And R2 are identical to each other; and the constituent units (1) and (2) display three constituent sheets 70, which means that two constituent units (1) or constituent units are included in the above combination examples, and the numbers represent constituent units (1) With the example of (2), the letter of the letter represents an example of the constituent unit (3).

If n mlm p 1_1 -n I nnn Sip < I mMmme an I ϋ I . (Please read the notes on the back and fill out this page) Line _ Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperative Printed Paper Size Applicable to China Standard (CNS) A4 specification (2]0 X 297 public) 31 312991 1290149

V. Description of invention (32 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperatives Printed Table 3 No. 1 __Composed units (1>, (2) Numbered components (3) One CH2 One CH—1 Η A —CH2 One CH— 1 HO—g^CH2^CH2 2 —--- 3 4 —GH2—CH—CH3 —--- B —CH 2 —CH—1 HOOC-C^CHa^CHg One"CH:-〒 Η ~· h3c—ch2 〜·~-— c 〇V 〇/C,?H2 —CH2-CH—〇\c^CH-(-C—C=C-^CH2 CH2—CH—One CH2—CH— 1 H ch3 5 ～--- 6 —CH 2 —CH— —CH 2 —CH— 1 1 H h3c—ch2 —CH 9 9 ——CH 2 —CH— I 1 H H3C« —CH 2 ^ — H 2 h 2 7 —CH 2 —CH — —CH厂 CH— ! u IH h3c,8-ch2 ch3 8 ~CH2-CH— —CH _ch— 1 1 H H3C-( CH2)jCH2 9 ~CH2-〒H − —ch2-〒h--ch2- ch-H ch3 h3c-ch2 10 —CH2—9H—one CH2—CH— 1 1 CH3 h3c—ch2 --------^———----^ (Please read the notes on the back and fill in This page)

32 312991 1290149

--------^-------- (Please read the notes on the back and fill out this page) 33 312991 . Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Clothing 1290149 Λ7 B7 Five , invention description 〇 4 ) Table 4 numbering unit (1) numbering unit (3) 1 a ch2-ch - Η A - CH2 - CH - 9, IH ^ / CHiCH2) 5CH2 2 - CH2-CH - ch3 B 〇 々c ^ c»2 —ch2-ch~ V^CH-C—c=c—CC—CHo 〇" h2 h2 h2 3 a CH2-CH I h3c-ch2 C % 〇/ 严 2 —CH^CH — ^CH-fc-CC^CH, 4 CH2—CH—CH2-CH—H CH3 D —CH 2 —CH~ H〇V_y °~h^ CH2^h2 5 —CH 2 —CH — —CH—CH— IIH H3C-CH2 * 6 -CH2—CH—CH2—CH—H H3C—CC—CH2 h2 h2 7 —CHo—CH— —CH 2 —CH— I h ! H H3C—8—0H2 ch3 8 —CH——CH —CH2-CH—H H3C—<CH2)jCH2 ------—- CHCH]——CH:—CH—--H CH3 H3C-CH2 10—CH2-CH—CH2-— CH—CH3 H3C-CH2 The polar group-containing dilute hydrocarbon copolymer (IV) according to the present invention has excellent adhesion and phase to polar substances such as metals and polar resins. Capacitance. ———————————^-------- (Please read the notes on the back and fill out this page) Line • This paper scale applies to China National Standard (CNS) A4 specification (2) 〇χ 297 mm) 34 312991 1290149 A7 B7 V. INSTRUCTIONS (36) Table 5 Ministry of Economic Affairs Intellectual Property Office Employees Consumption Cooperatives Printing Numbering Unit (1) Numbering Unit (3) 1 a ch2-ch- I H3C-CH2 A —CH2 CH·"— HO—CC-CH2 h2 h2 2 —*CH2—CH—H3C-U-CH2 ch3 B —CH2—CH~* HO—C-iCH2)jCH2 h2 C —ch2-ch— HO-Ci CH2 eCH2 h2 D —CH 2 —CH— I HO—G—(CH 2 ) fCH 2 h 2 E —CHg —CH— HO — g—(CH from CH 2 F —CH 2 —CH— · I hooc-cc-ch 2 H 2 H 2 G — CH〇一CH— I HOOC-g-<CH2)jCH2 Η—ch2-ch— I HOOC-Ci CH2^CH2 I —CH2_CH—I HOOC-Ci CH2^fH2 h2 J —CH2—CH— |^CHiCH2) 5CH2 H2C This paper size is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) -------------Φ (Please read the notes on the back and fill out this page) ·11111 Line - 36 312991 1290149 A7 _B7__ V. Description of invention (38) Composition of examples Combination of units. Detailed examples of such combinations include 1_A, 1-B, 1-C, 1-D, 1-E, 1-F, 1-G ' 1-H, 1-1, 1-J, 1-K, 1- L, 1-M ' 2-A, 2-B, 2_C, 2-D, 2-E, 2-F, 2_G, 2-Η, 2- 1 , 2-J, 2-Κ, 2- L and 2-Μ combinations. The above combination is one in which R1 and R2 are identical to each other, and the constituent unit (1) contains the constituent unit (2). In the above combination example, the numbers represent examples of the constituent unit (1). The English letter represents an example of the constituent unit (3). • ^1 ϋ nn _1 nnn I n .^1 nn ϋ n ϋ n J·*a in ϋ ϋ n 兮 兮 (Please read the notes on the back and fill out this page) Line · Ministry of Economic Affairs Intellectual Property Bureau staff consumption Cooperative printed paper size is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 38 312991 1290149 A7 B7 V. Description of invention (39) Table 6 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing numbering unit (1) Numbering unit (3) 1—ch2-ch—H3C—C—C—CH2 h2 h2 A—CH2—CH—I HO—C—C—0H2 h2 h2 2 —CH2—CH~· I h3c- < ch2^ch2 B - CH2 - CH - HO-Ci CH2) 2CH2 C - CH2 - CH - I ho_c - < ch2%ch2 h2 D - ch2-ch - HO - C - (CH2) 7CH2 h2 E CH2-CH-HO-C-(CH2)gCH2F-CH2-CH-*I HOOC-C-C-CH2 h2 h2 G-CH2-CH-I HOOC-C-< 〇Η2)2〇Η2 H CH2-CH-I HOOC-Ci CH2)gCH2 I-CH2-〒 H- HOOC~C-{ CH2^〇CH2 h2 J —CH;j—CH—H ?>Η^〇Η2)5〇Η2 paper The scale applies to the Chinese National Standard (CNS) A4 specification 210 x 297 mm) --------- -------- order line (please read the back of the precautions to fill out this page) 39 312991 A7, invention is described in (40

1290149 A second specific example of the polar olefin-containing copolymer of the present invention comprises a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (4) (also referred to as "composition unit 4"), and optionally A branched chain type polar group-containing olefin copolymer of a constituent unit represented by the following formula (5) (also referred to as '"composition unit 5"). ------------------^---------^. (Please read the phonetic on the back first? Then fill out this page) • CH2—CH_ • CH2 —CH, _ch2——Printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative...(1) η Wq-HR6)r +〇~Ζ)ρ • · (4) —(W)n • (5) Equation (1) The constituent unit is the same as the aforementioned constituent unit (丨). In the formulae (4) and (5), R5 is a hydrocarbon group such as a saturated or unsaturated hydrocarbon group, an alicyclic hydrocarbon group or an aromatic hydrocarbon group, and examples of the hydrocarbon group include the same groups as described above for R3 of the formula (3). Zhang Jiqian Qian Shijiao standard (cns) A4 miscellaneous (2) G X 297 public --------- 40 312991 1290149 five, invention description (41), in the formula (4) 'when r is J and R6 combined At R5, the valence of R5 is 2. When field r is 〇 and p seven or q% are each bound to R5, the valence of r5 is p + q+1. In formula (5), when m is! When r6 is combined with R5, the valence of R5 is 2. When m is 〇 and ^ is fixed to R5, the valence of R5 is n + and R5 in the formula (4) and R5 in the formula (5) may be the same or different, but are preferably identical to each other. In the formulae (4) and (5), r6 is a hetero atom or a hetero atom-containing group, and examples of the hetero atom or the hetero atom-containing group include the same atom or group as described above in the formula (3). . In the formula (4), the hetero atom in R or the carbon atom bonded to the hetero atom is preferably a ring, and examples of such structures include _&5_〇_&_〇_2, _ Ruler 5_ c(=o)-r-〇-Z, nc 〇 〇)〇冬〇m〇c(=〇)〇_nz, -R -C(=0)NH-R_0-Z and -R5-S_R _〇-Z (R is methyl, phenyl or cyclene). The above examples are those in the formula (4) where t is t and 4 is the same, and the other cases are also the same. The hetero atom of R6 or the carbon atom bonded to the hetero atom in the formula (5) printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs is preferably bonded to R5. Examples of such structures include _r5_〇_r_w... RS_ C(=0)-RW, -R5-C(=〇)〇冬w, -R5七c(=〇)〇_Rw ' -R5- C卜0)NH_R-W and _R5_S_R_W(R is extension Methyl stretch phenyl or cyclohexyl). The above example is in the formula (5) where 11 is i, and other cases are also the same. When R6 in the formulas (4) and (5) contains a carbon atom, the number of carbon atoms forming R0 is preferably from 1 to 20, more preferably from i to ,, and particularly from i to 5.

41 312991 1290149 V. INSTRUCTIONS (R6 in formula (4) and R6 in formula (5) may be the same or different, but preferably are the same as each other. --- (Please read the notes on the back and fill in On the page), in the formula (4), '1» is 〇 or 1. When 犷 is, it is bonded to any carbon atom forming R5. At that time, the -〇_Z system is combined with any one forming R6. In the formula (5), m is hydrazine or 1q. When 111 is fluorene, w is bonded to any one of the carbon atoms forming R5. When t is i, w is bonded to any one of the carbon atoms forming R6. In the formula (4), Z is a polymer fragment obtained by any one of anionic polymerization, ring-opening polymerization or polycondensation. I up--- Examples of the poly-α fragment include utilization from a methyl group Fractions obtained by anionic polymerization of one or more monomers of methyl acrylate, acetonyl methacrylate 0, propionic acid butyl vinegar, propylene sulphate and propionate; use internal vinegar, internal vinegar, argon a fragment obtained by ring-opening polymerization of an alkane, an indoleamine, a cyclic ether, an oxazoline or an oxirane propane; and A fragment obtained by using a monomer, a polyholeic acid and a polyamine, or a monomer such as a ruthenium acid = citric acid. Examples of a very large monomer used for forming a polymer fragment by polymerization include (meth) acrylate Classes, such as monovalent alcohols and acrylic acid or methyl, monoesters, in particular, methyl acrylate, methyl methacrylate ethyl acrylate, propyl methacrylate, butyl acrylate, A Mercaptohexyl ester, lauryl acrylate, stearyl methacrylate, acrylic acid, 1,1,1,3,3,3-hexafluoroisopropyl, methacrylic acid 111,3,33^ — ^ Ester, 2,2,2-trifluoroethyl acrylate, methacrylic acid 2,2 2-=* & isopropyl paper size applicable to China S 豕 standard (CNS) A4 specification (210 χ 297 public y -- -- 酉曰, 312991 42 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed 43 1290149 a7 "^_--_- V. Invention Description (μ) Acrylic 111,111,211,211-heptadecafluorodecyl acrylate, acrylate Propyl ester, allyl methacrylate, cyclohexyl methacrylate, glycidyl acrylate, glycidyl methacrylate, tetrahydrofurfuryl acrylate, Benzene enoate and pentyl-phenylhexyl methacrylate; terminal esters of divalent alcohol protected by ether linkage with acrylic acid or methacrylic acid, such as 2-methoxyethyl acrylate or methyl propyl acrylate Acid 2-methoxyethyl ester, 2-phenoxyethyl 2-enoate, 2-dicyclopentenyloxyethyl acrylate, 1-methoxy-2-propyl methacrylate, 3-methoxy acrylate Propyl propyl ester, 4-ethoxybutyl methacrylate, 6-methoxy hexamethyl acrylate 'methoxy bisethylene glycol acrylate, phenoxy dipropylene glycol methacrylate, ethoxy methacrylate Tripropylene glycol ester, ethoxylated polyethylene glycol acrylate and methoxypolypropylene glycol methacrylate; polyvalent ester of divalent or polyvalent alcohol with acrylic acid or methacrylic acid, such as ethylene glycol diacrylate , ethylene glycol dimethacrylate, propylene glycol diacrylate, propylene glycol dimethacrylate, 1,3-propanediol dimethacrylate, 1,4-butanediol diacrylate, 1,6-hexane Alcohol dimethacrylate, neopentyl glycol diacrylate, neopentyl glycol dimethacrylate, diethylene glycol Diacrylate, dipropylene glycol dimethacrylate, triethylene glycol dimethacrylate, tripropylene glycol diacrylate, polyethylene glycol diacrylate, polypropylene glycol diacrylate, polypropylene glycol dimethacrylate, Triacrylate, trimethacrylate, pentaerythritol tetramethacrylate, dipentaerythritol hexaacrylate, trimethylolpropane triacrylate, poly(ethylene oxide) triol triacrylate, poly(epoxy) Propane-based triol triacrylate and poly(propylene oxide) triol trimethacrylate; This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 ------ --^---------Line (please read the notes on the back and fill out this page) 1290149 A7 B7 V. Inventions (44) (Please read the notes on the back and fill out this page) Ester-bonded alcohols with esters of acrylic acid or methacrylic acid such as 2-phenyldecyloxyethyl acrylate, 2-benzylideneoxyethyl methacrylate, 2-ethenyloxy acrylate Ethyl ester, 5-tetrahydrofuranyloxycarbonyl Amyl ester, 5-tetrahydrofuryloxycarbonyl pentyl methacrylate and 2,2,6,6·tetramethyl-4-oxyheptane-1,7-- vinegar diacrylate with cyclic acetal linkage Esters of alcohols with acrylic acid or methyl acrylate, such as 2-tert-butyl-1,3-dioxycyclopentane-2'-ester of methacrylate and 2-tert-butyl acrylate -5-Ethyl-5-ethenyloxymethyl-1,3-oxocyclohexane-2'(2)-ester; Ester of oxysuccinimide with acrylic acid or methacrylic acid For example, N-oxysuccinimide acrylate and N-oxysuccinimide methacrylate; esters of alcohols having a second amine group and acrylic acid or methacrylic acid, such as 2-dimethyl acrylate Aminoethyl vinegar and 2-ethylpropylaminoethyl methacrylate; and esters of cyano alcohol with acrylic acid or methacrylic acid, such as 2-cyanoethyl acrylate and 2-cyanopropyl methacrylate ester. Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumer Cooperatives. Examples of (meth)acrylonitriles include acrylonitrile and methacrylonitrile. The acrylamides include acrylamide, N-monosubstituted or N,N-disubstituted acrylamides, for example, propylene with an amine; N-monosubstituted acrylamides, such as N-methyl propylene oxime Amine, ethyl acrylamide, N-propyl acrylamide, N-butyl acrylamide, N-octyl acrylamide, N-phenyl propylamine, N-glycidyl propylene The amine and paper scales are applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). 44 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Consumer Cooperative Printed 45 V. Invention Description (45 N, N'-Extension B Bis-acrylamide; N,N-disubstituted monoacrylamides, such as N,N-dimethyl decylamine, N_ethyl-N-methacrylamide, N,N-diethyl Acrylamide, N,N-di-n-propylpropenylamine, hydrazine, hydrazine dioctyl acrylamide, N,N-diphenylpropenylamine, N-ethyl-N-glycidyl propylene Indoleamine, N,N-diglycidylpropylamine, N-methyl-N-(4-glycidyloxybutyl)propylamine, N-methyl-N-(5-glycidol Alkyl pentyl) acrylamide, N-methyl-N-(6-shrink Glyceryloxyhexyl) acrylamide, N-propylene decyl pyrrolidine, methyl N-propenyl-L-glycolate, N-propenyl hydrazinopyridine, N-propenyl morpholine and 1-propene And N,N'-disubstituted bis acrylamides, such as N, N'-diethyl-N, N, ethyl bis decylamine, N, N'-dimethyl -N,N'-extended bis acrylamide and bis(N,N'Methyl)bis acrylamide. Examples of vinyl pyridines include vinyl- or isopropenyl-substituted pyridines, such as 2- Vinyl pyridine, 2-isopropenyl pyridine and 4-vinyl fluorene bite. Examples of N-substituted maleidinide include: N-aliphatic-substituted maleimide, such as methyl horse An imine and N-ethyl maleimide; and an N-aromatic-substituted maleimide such as phenylmaleimide and N-(4-methylphenyl) Maleic imine. Examples of vinyl 13⁄4 include: methyl vinyl ketone, isopropenyl methyl ketone, ethyl vinyl ketone, ethyl isopropenyl ketone, butyl vinyl ketone, and phenyl vinyl Brewing 1. This paper scale applies to national standards of +7 countries CNS) A4 size (21G X 297 public re -) 312991-------- --------- ^ ^ (Please read the notes on the back of this page and then fill in) 1290149

, invention description (46 Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed 46 examples of styrene derivatives include: p-methoxy dibutoxy phenyl benzene and p-cyano phenylethylene. For the first thing, tr body Examples include epoxides, for example, epoxidized butyl/epoxy bromide, propylene bromide, 1,2-epoxybutadiene, 2,3-epoxybiphenyl bromide, oxidized cyclohexene Epoxy chloropropene, epoxy propylene: soil, water glyceryl ether, allyl glycidyl ether and phenyl dimethyl sulphate. Among them, ethylene oxide, propylene oxide, 1,2- Butylene oxide oxystyrene is preferred. The more preferred ones are propylene propylene oxide and oxirane. The most preferred one is propylene oxide. In these polymer fragments, (meth) acrylates are used. The anionic polyfluorene effect and the ring-opening polymerization using ethylene oxide or propylene oxide are preferred. The molecular weight of the polymer fragment is not particularly limited, and for example, its weight average molecular weight is 200 to 1, 〇〇 〇<〇〇〇, preferably in the range of 5〇〇 to 1〇〇〇〇〇. When S 2 is ^^oxyethane or polyoxypropylene, the Polar-based olefin copolymers have excellent coating properties, surface hydrophilicity (anti-fog property), antistatic properties, adhesion to polar resins (amine ester resins, epoxy resins, etc.), compatibility with polar resins Properties, hygroscopicity, water absorption (in the case of high content of cerium), dispersibility in water and oil resistance (in the case of high content Ζ). When Ζ is ΡΜΜΑ, the polar group-containing olefin copolymer has excellent properties. Surface hardness, adhesion to metal, color material dispersibility, filler dispersibility, oil resistance (in the case of high content), adhesion to polar resins (acrylic resin, nylon, EVOH, etc.), and phase to polar resin Capacitive. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 312991 II Order --------- (Please read the back note and fill out this page)

V. Inventive Note h) 1290149 When z is polyacrylonitrile or polyacrylamide, the polar group-containing dilute smoke copolymer has excellent surface hardness, surface hydrophilicity (anti-fog property), antistatic property, and coating. Covering, adhesion to metals, adhesion to polar resins (polyacrylonitrile, polyacrylamide, polyamide, polyester, etc.), compatibility with polar resins, dispersibility in water, biological phase Capacitive, stimulating, hygroscopic and water absorbing. When Z is polyethyl methacrylate or polybutyl acrylate, the polar group-containing copolymer has excellent adhesion to metals and adhesion to polar resins (acrylic resin, nylon, EVOH, etc.) 'Compatibility and oil resistance to polar resins. When Z is a polyamine (a ring-opening polymer containing an internal guanamine), the polar group-containing olefin copolymer has excellent adhesion to a polar resin (polyamide, etc.) and a phase to a polar resin. Capacitive, gas barrier and oil resistance. When Z is a polyester (a ring-opening polymer containing an indoleamine), the polar group-containing olefin copolymer has excellent adhesion to a polar resin (polyester or the like), compatibility with a polar resin, and Gas barrier. In the formula (4), p is an integer of 1 to 3. When P is 2 or 3, each of -0-Z may be the same or different. When p is 2 or 3 and r is 〇, it may be bonded to the same or different atoms of R5; when p is 2 or 3 and 1 is 1, _ Ο-Z may be bonded to the same or different atoms of R6. In the formulae (4) and (5), W is a hydroxyl group or an epoxy group. Although W in the formulas (4) and (5) may be the same or different, they are preferably the same as each other. In formula (4), q is 〇, 1 or 2. When q is 2, each w can be the same 'this paper scale applies to China National Standard (CNS) A4 specification (21〇x 297 public ------ - 312991 蝎—订------- ίPlease read the phonetic transcription on the back first? Then fill out this page} Line· Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperative Printed 47 1290149 V. Invention Description (48 or different. When When q is 2 and !* is 0, W can be bonded to the same or different atoms of Rs; when q is 2 and !* is 1, W can be bound to the phase of R6 or different atoms. 'On P - 1 and q In the case of -1, when r is 〇, W and _〇_2 can each be bonded to the same or different atoms of R5; when Γ is 1, the arms and _〇_2 can each be combined with the same or different R6. Atom, and P+q$ 3 is defined in equation (5), n is an integer from 1 to 3. When !! is 2 or 3, each W may be the same or different. When 11 is 2 or 3 and m is When 〇, w may be bonded to the same or different atoms of R5; when η is 2 or 3 and m is 1, w may be the same or different atom of R6. In the present invention, the polar olefin-containing copolymer In two specific examples, the constituent unit (1), the composition sheet (4), and optionally, the constituent unit (5) is generally a random combination. The composition of the linear base polymer in the second specific example of the polar olefin-containing copolymer of the present invention, the constituent unit (1) and The molar ratio ((1): (4) + (5)) between the sum of the constituent unit (4) and the constituent unit (5) is usually 99.99:0.01 to 0.01:99·99, preferably 99·95· ·0·05 to 10:90, more preferably in the range of 99·9··0·1 to 30:70. The molar ratio between the constituent unit (4) and the constituent unit (5) ((4)·· (5)) is usually in the range of 10G:0 to 0.01:99.99, preferably 100:0 to 1:99, more preferably 1〇〇.〇 to 10:90. The polar olefin-containing copolymer of the present invention The second specific example may contain two or more constituent units (1), may contain two or more constituent units (4), and the paper scale applies the Chinese National Standard (CNS) A4 specification (21〇X 297) Public catering) 48 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Office Employees Consumption Cooperative Printed 49 V. INSTRUCTIONS (49) Two or more constituent units (5) may be contained. In the present invention, the constituent units (1) , component unit (4) and group A preferred combination of the unit (5) is, for example, a constituent unit selected from the examples of the constituent unit (1) shown in Table 7, selected from the constituent unit (4) - R5-(R6)r-〇-part shown in Table 7. Examples of the constituent units of the examples and the Z portion, and the combination of the constituent units selected from the examples of the constituent units (5) shown in Table 7. Detailed examples of such combinations include: 1-A-Zl-a, lA-Z2-a, lA-Z3-a, lA-Z4-a, lA-Z5-a, l-A_Z6-a, 1-A- Z7_a, 1-B-Zl-b, lB-Z2-b, l-B_Z3_b, 1-B-Z4-b, lB-Z5-b, lB-Z6-b, lB-Z7-b, lC-Zl- c, lC-Z2-C, 1-C-Z3-C, 1-C-Z4-C, 1-C-Z5-C, 1-C-Z6-C, 1-C-Z7-c, 2- A-Zl-a, 2-A-Z2-a, 2-A-Z3-a, 2-A-Z4-a, 2-A-Z5-a, 2 bribe A-Z6-a, 2-A- Z7-a, 2-B-Zl-b, 2-B-Z2-b, 2-B-Z3-b, 2_B_Z4_b, 2_B_Z5-b, 2_B-Z6-b, 2_B_Z7_b, 2_C_Zl-c, 2_C-Z2 -C, 2-C-Z3-C, 2-C-Z4-C, 2-C-Z5-C, 2-C-Z6-C, 2-C Sun Z7-c, 3-A-Zl-a , 3-A-Z2-a, 3-A-Z3-a, 3-A-Z4-a, 3-A-Z5-a, 3-A-Z6-a, 3-A-Z7-a, 3 -B-Zl-b, 3-B-Z2-b, 3-B-Z3-b, 3_B_Z4_b, 3_B_Z5_b, 3-B_Z6-b'3_B_Z7_b, 3_C-Zl_c, 3-C_Z2_c, 3_C_Z3_c, 3_C_Z4_c, 3_C_Z5_c, 3_C_Z6_c , 3-C-Z7-c, 4-A-Zl-a, 4-A-Z2-a, 4-A-Z3-a, 4-A-Z4-a, 4-A-Z5-a, 4 -A-Z6-a, 4-A-Z7-a, 4-B-Zl-b, 4-B-Z2-b, 4-B-Z3-b, 4_B_Z4_b, 4_B_Z5_b, 4_B_Z6_b, 4_B_Z7-b, 4_C_Zl_c 4) The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 312 ) ) ) 312 312 ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ ϋ % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % % ( ( ( ( ( ( ( ( B7 V. INSTRUCTIONS (50) C-Z2-C, 4-C-Z3-C, 4-C-Z4-C, 4-C-Z5-C, 4-C-Z6-C, 4-C- Z7-C, 5-A-Zl-a, 5-A-Z2-a, 5-A-Z3-a, 5-A-Z4-a, 5-A-Z5-a, 5-A-Z6- a, 5-A-Z7-a, 5-B-Zl-b, 5-B-Z2-b, 5-B-Z3-b, 5-B-Z4-b, 5-B-Z5-b, 5-B-Z6-b, 5-B-Z7-b, 5-C-Zl-c, 5-C-Z2-c, 5-C-Z3-C, 5-C-Z4-C, 5- C-Z5-C, 5-C-Z6-C, 5-C-Z7-c, 6_A-Zl_a, 6-A_Z2-a, 6-A-Z3-a, 6-A-Z4_a, 6-A- Z5_a, 6-A-Z6-a, 6-A-Z7-a, 6-B-Zl-b, 6-B-Z2-b, 6-B-Z3-b, 6-B-Z4-b, 6-B-Z5-b, 6-B-Z6-b, 6-B-Z7-b, 6-C-Zl-c, 6-C-Z2-c, 6-C-Z3-C, 6- C-Z4-C, 6-C-Z5-C, 6-C-Z6-C, 6-C-Z7-c, 7-A-Zl-a, 7-A-Z2-a, 7-A- Z3-a, 7-A-Z4-a, 7-A-Z5-a, 7-A-Z6-a, 7-A-Z7-a, 7-B-Zl-b, 7-B-Z2- b, 7-B-Z3-b, 7-B-Z4-b, 7-B-Z5-b, 7-B-Z6-b, 7-B-Z7-b, 7-C-Zl-c, 7-C-Z2-C, 7-C-Z3-C, 7-C-Z4-C, 7-C-Z5-C, 7-C-Z6-C, 7-C-Z7-c, 8- A-Zl-a, 8-A-Z2-a, 8-A-Z3 -a, 8-A-Z4-a, 8-A-Z5-a, 8-A-Z6-a, 8-A-Z7-a, 8-B-Zl-b, 8-B-Z2-b , 8-B-Z3-b, 8-B-Z4-b, 8-B-Z5-b, 8-B-Z6-b, 8-B-Z7-b, 8-C-Zl-c, 8 -C-Z2-c, 8-C-Z3-C, 8-C-Z4-C, 8-C-Z5-C, 8-C-Z6-C, 8-C-Z7-c, 9-A -Zl-a, 9-A-Z2-a, 9-A-Z3-a, 9-A-Z4-a, 9-A-Z5-a, 9-A-Z6-a, 9-A-Z7 -a, 9-B-Zl-b, 9-B-Z2-b, 9-B-Z3-b, the paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 312991 --- -----Order---------Line"ml (Please read the note on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 50 Ministry of Economic Affairs Intellectual Property Bureau staff consumption Co-operative printing 51 1290149 V. Invention description (Μ) 9-B-Z4-b, 9_B_Z5-b, 9_B_Z6_b, 9_B_Z7-b, 9_C_Zl_c, 9-C-Z2-c, 9-C-Z3-C, 9- A combination of C-Z4-C, 9-C-Z5-C, 9-C-Z6-C and 9·C-Z7-C. In the above combination examples, the numbers represent examples of constituent units (1); A, B and C represent examples of constituent units (4) - R5 - (R6) r - 〇 - portions; Z1 to Z7 represent constituent units (4) Examples of the Z moiety; and a, b, and c represent examples of the constituent unit (5) _R5-(R6)m-Wn- moiety. Table 7 Numbering unit <1) Component unit (4) Component unit (5> No. Z No. 1 - CH Guang CH - I Η A 雠 (αν, -α» (r=0) Z1 i Ethylene oxide a (m=0) 2 —CH 2 —CH—— ch3 B —(ctyj-o- (r =0) zz Polypropylene oxide b -((»ye-〇H (m=0) 3 —CHa-CH — H^C-CHz C ~((»y4CH(0H)CiV〇- (r=0) Z3 polymethyl methacrylate c -(CHP^COIOCHj-OH (m=0) ♦4 a CH2—CH— —CH2—CH—H CHs Z4 Pblyacrylo nitrile 5 —CH 2eCH—CHa—CH—H H3C-CH2 Z5 Pblyacryiamide 6—CH2-CH—CH2-CH—IIH H3C-C_C—CH2 h2 h2 ZB Pblye- caprolactone 7 CH2-CH-CH2-CH-H H3C-<CH2^CH2 Z7 Polye- caprolactam 8-CHi-CH-CH G-CH-II CH3 HaC-CH^ Θ-CH2-CH--CHj-CH-- CH2-CH-H CH3 H3C-CH2 Other copolymerizable component The branched chain polar group-containing olefin copolymer of the present invention may contain a constituent unit (1) and a constituent unit (4) within the limits of the object of the present invention. And constituent units other than the constituent unit (5). A cyclic olefin derived from a polar group-containing monomer represented by the above formula (10), a non-copolyolefin, a hydroxyl group-containing olefin. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). ) 312991 --------^-------- (Please read the notes on the back and then fill out this page) . Line - 1290149

Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumers Co., Ltd. Printed 52 Unsaturated compounds, amine-containing ethylenically unsaturated compounds Epoxy-containing ethylenically unsaturated compounds, aromatic vinyl compounds, unsaturated carboxylic acids: potted derivatives, The ethyl acetate compound and the constituent unit of the ethylene-based gas are lean acid and, when these constituent units are contained, the amount thereof is composed of the polar group-containing olefin material (4) (4) & unit is 'not more than 3G mol%' Preferably, it is not more than 20% by mole, more preferably not more than 1% by mole. Properties of Copolymer 第二 The second embodiment of the present invention contains a polar olefin copolymer having a weight average molecular weight (Mw) of usually 500 to 2 Torr, preferably M 〇〇 to 1,500,000, more preferably The molecular weight distribution (Mw/Mn) in the range of 5 〇〇〇〇〇 to 13 通常 is usually not more than 3, preferably not more than 2 8, more preferably not more than 2.5. § When the distribution (Mw/Mn) is not more than 3, the polar group-containing dilute copolymer has a polar group which is excellent in the position between the copolymer and the polar substance interface and is excellent for polar substances. Adhesion and excellent compatibility. In the 3C-NMR spectrum of the polar olefin-containing copolymer, the intensity ratio (Τα万/(Τα α +Τα)) of Ding 〇 召 α α α + Τα is not more than 1·〇, preferably Not more than 0.8, more preferably not more than 〇.5. When the intensity ratio (Τα召/(Τα α+Τα)) is not more than 1·〇, the polar group-containing olefin copolymer has a polar group which is excellent in the position between the copolymer and the polar substance interface. The second specific example of the polar olefin-containing copolymer of the present invention has excellent adhesion and compatibility with metals and polar substances (for example, polar resins), and the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X). 297 mm) 312991 -------- order --------- (please read the notes on the back and fill out this page again) 1290149

Surface hydrophilicity, coatability, printabllity, antifogging property, antistatic property, oil resistance, biocompatibility, dispersibility in water, dispersibility in a solvent, colorant dispersibility, filler Dispersibility, transparency, mobility and mouldability. The third specific example of the polar group-containing olefin copolymer of the present invention includes the following formula (the constituent unit represented by D and the constituent unit represented by the following formula (6) (also referred to as "composition unit 6")' and the following formula ( 3) The constituent units shown: -CH2 - CH2 - CH - • · · (1) (R4)r—(X)p (3)

The constituent unit represented by the formula (1) is the same as the above-mentioned constituent unit (1), and the constituent unit represented by the formula (3) is the same as the above-mentioned constituent unit (3). In the third embodiment of the polar group-containing olefin copolymer of the present invention, the constituent unit represented by the formula is preferably a constituent unit represented by the following formula (3). CH2—CH—^^^1 nii I nn MM§ · i .^1 Hi ·_1 ϋ I n 1··· · ϋ Bn 11 n ϋ ϋ·« ·1 I i (Please read the notes on the back first) Fill in this page again) Printed by the Consumer Intellectual Property Office of the Ministry of Economic Affairs (X, (3' (3'), R3, which is a hydrocarbon group, preferably a nicotine with i to 2 carbon atoms' is better. Is a hydrocarbon group having 3 to 20 carbon atoms. P is an integer of 1 to 3, preferably 1. X is a polar group containing ruthenium and/or N, preferably _〇R, _C〇〇R, -NR2 , epoxy group, T2, ^ (R is hydrogen or a hydrocarbon group),

CRO This paper scale is used in Chinese National Standard (CNS) A4 specification (21〇><297 mm) 53 312991 A7 1290149 V. Description of invention (54) _OH, -COOH or 2 0 (3') The composition of the single rabbit 7 is, for example, a constituent unit derived from a polar group-containing monomer represented by the following formula (7). In the formula (4), R is a direct bond or an aliphatic smo-group having i or more carbon atoms, preferably a direct bond or a hydrocarbon group having 1 to 1 carbon atom. R is a hydrogen atom, a direct bond or an aliphatic smoky group having i or more carbon atoms' is preferably a direct bond or a hydrocarbon group having 1 to 1 碳 of carbon atoms. Y is a group having 0 and/or a polar group, and preferred examples of such a polar group include the same groups as described above for X'. m^n is each an integer of 0 to 2, and m+n is not 〇§ 〇 or the constituent unit of the formula (6) is, for example, derived from a polar group-containing monomer represented by the formula (8) Component unit. In the third specific example of the polar group-containing olefin copolymer of the present invention, the monoketone (1), the constituent unit and the constituent unit (6) are usually in a random combination. Composition of the copolymer In the third specific example of the polar group-containing olefin copolymer of the present invention, the molar ratio between the constituent unit (1) and the total of the constituent unit (3) and the constituent unit (6) ((1): ( 3) + (6)) is usually in the range of 99.99:0.01 to 〇·〇ΐ: 99·99, preferably 99.95:0.05 to 10:90, more preferably 99.9:0.1 to 30:70. The molar ratio ((3): (6)) between the constituent unit (3) and the constituent unit (6) is usually from 0:100 to 99.99:0.01, preferably from 〇〇:1〇〇 to 99:1, more preferably It is within the range of 〇·1〇〇 to 90:10. The third specific example of the polar olefin-containing copolymer of the present invention may contain two paper scales applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) ----- 312991 —------- ---------^---------^ (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed 54 1290149 A7 Ministry of Economics Intellectual Property Bureau employee consumption cooperative printing -------______ __ V. Invention description (55) ^- or more components (1), may contain two or more constituent units (3), may contain Two or more constituent units (6). ^ Other copolymerizable component The polar group-containing olefin copolymer of the present invention may contain constituent units other than the constituent unit (1), the constituent unit (3), and the constituent unit ^ within the limits of the object of the present invention. Examples of constituent units which may be contained include a cyclic olefin derived from a polar group-containing monomer represented by the above formula (8) or (?), a non-copolyolefin, a hydroxyl group-containing ethylenically unsaturated compound, and an amine-containing compound. A constituent unit of an ethylenically unsaturated compound, an epoxy group-containing ethylenically unsaturated compound, an aromatic vinyl compound, an unsaturated carboxylic acid and a derivative thereof, a vinyl ester compound, and a vinyl chloride. When these constituent units are contained, the amount thereof is not more than 3 〇 mol%, preferably not more than 20 mol%, more preferably not more than mol, based on all the constituent units constituting the polar olefin-containing copolymer. 0/〇. Properties of the copolymer The third embodiment of the polar group-containing olefin copolymer of the present invention has a weight average molecular weight (Mw) of usually from 500 to 2,000,000, preferably from 1 to 1,500,000, more preferably from 5,000 to 1,300,000, and the molecular weight thereof. The distribution (Mw/Mn) is usually not more than 3, preferably not more than 2.8, more preferably not more than 2.5. When the molecular weight distribution (Mw/Mn) is not more than 3, the polar group-containing olefin copolymer has a polar group which is excellent in the position between the copolymer and the polar substance interface, and has excellent adhesion to polar substances. Excellent compatibility with 0 Γ Read the phonetic on the back first? Please fill out this page again} 4 =0 -------^------- Line This paper size applies to China National Standard (CNS) A4 specification (2) 0 X 297 mm) 55 312991 1290149

Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumer Cooperative of 56. In the 3C-NMR spectrum of the a-polar olefin copolymer, the intensity ratio of Τα to τ α α+Τα (Τα ^/(Tq: α+Τα召) )) is not more than 1 〇, preferably not more than 0.8, more preferably not more than 〇5. When the intensity ratio (Τ α / / (τ α α + Τ α cold)) is not more than 1.0, the polar group-containing olefin copolymer has a polar group which is excellent in the position between the copolymer and the polar substance interface. The third specific example of the polar group-containing olefin copolymer of the present invention has excellent adhesion, compatibility and flexibility to metals and polar substances such as polar resins. BACKGROUND OF THE INVENTION A first specific example of a method for producing a polar olefin-containing copolymer according to the present invention is included in the following composition: (Α) selected from Group 3 of the periodic table (including lanthanides and actinides) to a compound of a transition metal of Group 1 and (Β) selected from at least one of the following compounds: (Β-1) an organoaluminum oxy-compound, (Β-2) reacts with a compound (Α) to form an ion pair compound ( Hereinafter, sometimes referred to as "ionized ionic compound"), and (Β-3) an olefin polymerization catalyst of an organic compound, at least one α selected from an α-olefin having 2 to 20 carbon atoms The olefin and the polar group-containing monomer selected from the above formula are copolymerized with at least one polar group-containing monomer of the polar group-containing monomer represented by the above formula (8). The polar group-containing monomer represented by the above formula (7) is used as the polar paper of the present invention. The Chinese National Standard (CNS) A4 specification (210 X 297 mm) 312991 . --------^ --------1 . (Please read the notes on the back and fill out this page) 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Print 57 V. Invention Description 7 Basic Units The first specific example of the aforementioned polar group-containing olefin copolymer. When the polar group-containing monomer represented by the above formula (8) and, if necessary, the polar group-containing monomer represented by the above formula (7) are used as the polar group-containing monomer of the present invention, the aforementioned polar group-containing olefin is obtained. A third specific example of the copolymer. The components forming the olefin polymerization catalyst used in the present invention are first explained below. (A) Transition metal compound The transition metal compound (A) used in the present invention is a compound selected from the transition metals of Group 3 (including lanthanides and actinides) to Group 10 of the periodic table. Examples of transition metals selected from Group 3 of the periodic table (including lanthanides and actinides) to Group 1 include ruthenium, titanium, zirconium, hafnium, vanadium, niobium, niobium, palladium, ruthenium, cobalt, rhodium, iridium, Chromium, molybdenum, tungsten, manganese, bismuth, iron and antimony. Among them, preferred are ruthenium, titanium, zirconium, niobium, vanadium, sharp, knob, handle, nickel and cobalt. The best ones are titanium, tantalum and niobium. In the transition metal compound (A) of the present invention, in addition to the Qilenenata catalyst and the aromatic cycloolefin metal catalyst, a known organometallic composite is also used. Examples of the transition metal compound (A) which are preferably used are any compounds which are not in the following formulas (11) to (16). The transition metal compound represented by the formula (11) is explained below. X1 X2

312991 --------^--------- (Please read the notes on the back and then fill out this page) ...(11) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 58 1290149 Α7 ____Β7 5. Description of the Invention In the above formula, M1 is a transition metal atom of Group 3 (including lanthanides and actinides) of the periodic table to Group 1 , preferably a transition metal atom of Group 4 of the periodic table. In other words, it is zirconium, titanium or hafnium, and zirconium is preferred. R25, R26, R27 and R28 may be the same or different and each is a hydrogen atom, a nitrogen-containing group, a phosphorus-containing group, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated nicotine group having 1 to 2 carbon atoms, and a gas A group, a sulfur-containing group, a fragment-containing group or a _ atom. Examples of the nitrogen-containing group include an amine group; a primary amine group; an aroma group such as a methylamino group, a dimethylamino group, a diethylamino group, a dipropylamino group, a dibutylamino group, and a dihexylhexylamine group; Amine or arylalkylamine groups such as anilino, diphenylamino, xylylamino, dinaphthylamino and methylanilino. Examples of the disc-containing group include a phosphine base such as a dimethylphosphonium group and a diphenylphosphonium group. Examples of the hydrocarbon group having 1 to 20 carbon atoms include an alkyl group, a cycloalkyl group, an alkenyl group, an aralkyl group, and an aryl group. In particular, alkyl groups which may be mentioned, such as methyl, ethyl, propyl, butyl, hexyl, octyl, decyl, dodecyl and decyl; ring-based groups such as cyclopentyl , cyclohexyl, pro-alkyl and adamantyl; alkenyl, such as ethenyl, propenyl and cyclohexenyl; arylalkyl, such as benzyl, phenylethyl and phenylpropyl; and aryl For example, phenyl, tolyl, dimethylphenyl, tridecylphenyl, ethylphenyl, propylphenyl, biphenyl, naphthyl, methylnaphthyl, anthryl and phenanthryl. Examples of the halogenated hydrocarbon group having 1 to 20 carbon atoms include a group in which the above hydrocarbon group having 1 to 20 carbon atoms is substituted with _. Examples of the oxygen-containing group include a hydroxyl group; an alkoxy group such as a methoxy group, an ethoxy group, a propoxy group, and a butoxy group; an aryloxy group such as a phenoxy group, a methylphenoxy group, and a suitable size of the paper. Home Standard (CNL) A4 Specifications (2) Q χ 297 Meals "------ 312991 ----------^7--------- (Please read the notes on the back first. Fill in this page) 1290149

Printed by the Intellectual Property Office of the Ministry of Economic Affairs, the Consumers' Cooperatives 59 phenoxy and naphthyloxy; and aryl alkoxy groups, such as stupidyl methoxy Hanbenyl ethoxy. Examples of the sulfur-containing group include a group in which the oxygen is replaced by sulfur in the above oxygen-containing group, such as a methyl (tetra) salt, a trifluoromethane salt, a phenyl ore salt, and a benzyl acid salt. Toluene salt, trimethyl benzoate, diisobutyl benzoate, p-benzene benzene (tetra) salt and pentafluoro phenyl salt; and sub: acid group 'such as methyl sulphate, phenyl ia Money salt benzyl sulfite, phthalic acid salt, trimethyl benzyl sulfoxide and five gas benzene sulfinate. The solid ruthenium containing Shishiji contains a single-substituted substituted stone, such as methyl oxalate and phenyl group; hydrocarbon substituted (tetra) group, for example: methyl sulphate and monophenyl fluorenyl a dihydrocarbyl substituted decyl group, such as trimethyldecyl, triethyldecyl, tripropyldecyl, tricyclohexyldecyl, triphenyldecyl, dimethylphenyldecyl, methyl a phenyl fluorenyl group, a trimethylphenyl decyl group, and a trinaphthyl fluorenyl group; a hydrocarbon-substituted decyl alkyl decyl ether, such as dimethyl decyl ether; a hydrazine-substituted alkyl group, such as a trimethyl decyl alkyl group; And an anthracene substituted aryl group such as trimethyldecylphenyl. Examples of the halogen atom include a fluorine atom, a gas atom, a bromine atom, and an iodine atom. Among the bases represented by R25, R26, R27 and R28, a group which is adjacent to each other may be bonded to a carbon atom bonded to the groups to form a ring. R25, R26, R27 and R28 are each shown in two positions. For example, r25 and R25 may be the same group or different groups. Among the groups represented by R25 to R28, the groups having the same sign are a preferred combination of the groups which form a ring. The adjacent Chinese R25, R26, R27 and R28 are combined with these groups. The paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991 --------^-- ------ (Please read the notes on the back and fill out this page) - Line · Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 60 1290149

V. Examples of the ring formed by the carbon atoms of the invention (6〇) include fused rings such as a benzene ring, a naphthalene ring, an anthracene ring and an anthracene ring; and the hydrogen atoms of the rings are alkyl groups (for example, methyl 'B a group substituted with a propyl group, a propyl group and a butyl group. Wherein 'the preferred one is a hydrocarbon group or a halogen atom having from 1 to 2 carbon atoms, and particularly preferably a hydrocarbon group having 1 to 4 carbon atoms such as a jujube group, an ethyl group, a propyl group or a butyl group, and a hydrocarbon group. The hydrogen atom on the benzene ring formed by bonding or formed by the combination of a hydrocarbon group is alkyl (for example, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl or tert-butyl) Substituting group. X1 and X2 may be the same or different and each is the same as the above-mentioned R25, R26, R27 and R28, a hydrocarbon group having 1 to 2 carbon atoms, a toothed hydrocarbon group having 1 to 2 carbon atoms, an oxy group, Sulfur-containing, sulfhydryl, hydrogen or quiescent atoms. Among them, preferred are a halogen atom, a hydrocarbon group having from 1 to 2 carbon atoms, or a sulfonate group. Y1 is a divalent hydrocarbon group having 1 to 20 carbon atoms, a divalent halogenated hydrocarbon group having 1 to 2 atomic slave atoms, a divalent group containing a sulphate, a divalent group containing ruthenium, a divalent group containing tin, -0-, -CO--S-, -SO-, -S02-, -Sn-, -NR21-, -P(R21)_, _p(〇)(R2i)·, _BR2i_ or _A1R21 ( Each of r21 may be the same or different and is a hydrocarbon group having 1 to 2 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, an argon atom or a halogen atom). Examples of the divalent hydrocarbon group having 1 to 20 carbon atoms include an alkylene group such as a methyl group, a dimethylmethyl group, a 12-ethyl group, a dimethyl group, a 2-ethyl group, and 1, 3-propyl, 1,4-tert-butyl, ι, 2-cyclohexylene and L4-cyclohexylene; and arylalkylene, such as diphenylmethyl and diphenyl 4,2_ Ethyl. This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------------------- Order --------- Line (please read the note on the back and then fill out this page) A7 1290149 B7 V. INSTRUCTION DESCRIPTION (61) Examples of the divalent i-alkyl group having 1 to 20 carbon atoms include the above two having 1 to 20 carbon atoms A group in which a valent hydrocarbon group is dentated, such as a chlorine methyl group. Examples of the ruthenium-containing divalent group include an alkylalkylene group such as a sulfonium group, a methyl decyl group, a dimethyl decyl group, a diethyl decyl group, a di(n-propyl) group > Anthracenyl, di(isopropyl)-extension, bis(cyclohexyl)alkylene, methylphenylalkylene, diphenylalkylene, bis(p-tolyl)alkylene and di p-Chlorophenyl)alkylene; alkaryl extended; 6th alkyl; arylalkylene; alkyl dialkyl, such as tetramethyl-1,2-dihydrodecyl and tetraphenyl-1 , 2 - 二伸石夕烧基; aryl aryl dithiazide; and aryl dialkylene. Examples of the divalent group containing ruthenium include a group in which the ruthenium containing ruthenium is replaced by ruthenium. Examples of the divalent group containing tin include a group in which the above fluorene-containing divalent group is replaced by tin. R21 is the same as the above-mentioned R25, R26, R27 and R28, a hydrocarbon group having 1 to 20 carbon atoms, a toothed hydrocarbon group having 1 to 20 carbon atoms or a halogen atom, or one or two having 1 to 20 carbon atoms. A nitrogen compound residue formed by combining a hydrocarbon group of an atom with a nitrogen atom. Among them, particularly preferred Y1 is a substituted alkylene group such as dimethylalkylene, diphenylalkylene or methylphenylalkylene. Examples of the transition metal compound represented by the formula (11) include ethylidene-bis(indenyl)dimethylzirconium, diethylammonium di-(indenyl)fluorene, and the paper size is applicable to the Chinese National Standard (CNS). A4 size (210 x 297 mm) 312991 -------- order --------- line (please read the note on the back? Please fill out this page again) Ministry of Economic Affairs Intellectual Property Office staff Printed by Consumer Cooperatives 61 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed 62 1290149 a7 B7 V. Description of Invention (62 ) Bis(trifluoromethanesulfonic acid) Ethyl-bis(indenyl)anthracene, bis(methanesulfonic acid) Ethyl ethyl bis(indenyl)zirconium, bis(p-toluenesulfonic acid)-extended ethyl-bis(indenyl)zirconium, bis(p-benzenesulfonic acid)-extended ethyl-bis(indenyl)anthracene, two Gasification-extension ethyl-bis(4,5,6,7-tetrahydroindenyl)zirconium, di-vaporized isopropylidene-bis(cyclopentadienyl) zirconium, di-vaporized isopropylidene Bis(cyclopentadienyl)(methylcyclopentadienyl) hammer, di-gasified dimethyl-desmethyl-bis(cyclopentadienyl)zirconium, di-gasified dimethyl-decyl-alkyl (methylcyclopentadienyl)zirconium Dimethylated dimethylalkylene-bis(dimethylcyclopentadienyl)zirconium, di-gasified dimethyl anthracenyl-bis(trimethylcyclopentadienyl), two gasification Dimethyl decyl-bis(indenyl)zirconium, bis(trifluoromethanesulfonic acid) dimethyl hydrazinoalkyl-bis(indenyl)zirconium, di-vaporized dimethyl-decyl-alkyl (4, 5,6,7-tetraarsenyl)zirconium, dimethyldimethylene-bis(cyclopentadienyl)(fluorenyl)zirconium, di-hydrogenated diphenylalkylene-bis(fluorenyl) Zirconium, dimethylated methylphenyl thiophenanthene-bis(nodal), di-vaporized-dimethyl hydrazine-bis(2,3,5-trimethylcyclopentane) Alkenyl), di-vaporized-dimethyl hydrazino-bis(2,4, octatrimethylcyclopentadienyl) zirconium, di-vaporized-dimethylalkylene _Bis(2-methyl_4_t-butylcyclopentadienyl) fluorene, isopropylidene-(cyclopentadienyl) (diyl) dysfunction, reduction of scale for Zhongguanjia Standard (CNS) A4 specification (2) Q x 297 public meal "312991 -------------------- order --------- line (please read the back first) Precautions Fill in this page) 1290149 A7 B7 V. Inventions (64) ^ /X1

Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, R35 〇3β R38 (11a) In the above formula, Μ1 is the transition metal atom of Group 4 of the periodic table. In other words, it is wrong, titanium or tantalum. good. Each of R31 may be the same or different and is a hydrocarbon group having 1 to 6 carbon atoms. Examples of such hydrocarbyl groups include alkyl groups such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, t-butyl, n-pentyl, neopentyl, An n-hexyl group and a cyclohexyl group; and an alkenyl group such as a vinyl group and a propylene group. Among them, preferred are those having a carbon atom-based primary carbon atom bonded to a fluorenyl group, more preferably an alkyl group having 1 to 4 carbon atoms, most preferably a methyl group and an ethyl group. R32, R34, R35 and R36 may be the same or different and each is a hydrogen atom, a halogen atom or a hydrocarbon group having 1 to 6 carbon atoms which is the same as the above-mentioned R31. Each of R33 may be the same or different and is a hydrogen atom or an aryl group having 6 to 16 carbon atoms. Examples of such aryl groups include phenyl, α-naphthyl, s-naphthyl, anthracenyl, phenanthryl, keyl, phenylenyl, phenalenyl, tetrahydronaphthyl, indanyl and Biphenyl. Among them, a phenyl group, a naphthyl group, an anthracenyl group, These aryl groups may be substituted by the following substituents: a halogen atom such as fluorine, gas, bromine and argon; for example, an alkyl group such as a methyl group, a hydrocarbon base paper having 1 to 20 carbon atoms, and a Chinese national standard (CNS) A4 size (210 X 297 male jade) 312991 ti-------^ (Please read the note on the back and fill out this page) 64 1290149

V. INSTRUCTIONS (65) Ethyl, propyl, butyl, hexyl, cyclohexyl, octyl, decyl, dodecyl, eicosyl, ortho-alkyl and adamantyl; alkenyl groups such as ethylene Alkyl, propylene and cyclohexenyl; aralkyl, such as benzyl, phenylethyl and phenylpropyl; and aryl, such as phenyl, tolyl, dimethylphenyl, trimethylbenzene , ethyl phenyl, propyl phenyl, biphenyl, or _naphthyl, methylnaphthyl, anthracenyl, nonyl, phenylfylphenyl, fluorenyl, hydroxy, enchantyl, decene Anthracenyl, tetrahydronaphthyl, indanyl and biphenyl, and organodecyl, such as trimethyldecyl, triethyldecyl and triphenyl sulfhydryl. X1 and X2 may be the same or different and have the same meaning as χΐ and X2 in the formula (11). Among the above atoms and groups, a halogen atom or a hydrocarbon group having from i to 20 carbon atoms is preferred. Y1 has the same meaning as Y1 in the formula (11). Preferred among the above groups are a divalent group containing ruthenium, a divalent group containing ruthenium, a divalent alkylene group or a divalent borane group containing boron, more preferably a divalent group containing ruthenium or The divalent alkylene group, and particularly preferably, is an alkylalkylene group, an alkylarylalkylene group, an arylalkylene group, an alkylalkylene group or an arylalkylene group. Examples of the transition metal compound represented by the formula (11 a) include a racemic-dimethyl dimethyl sulfonyl-bis[1-(2-methyl-4-phenylindenyl) stilbene, a gasification Racemic-dimethylmethyl decyl-bis[1-(2-methyl-4-(α-naphthyl)) benzyl, dichloro-cyclohexane-dimethyl-alkyl [1-(2-methyl-4-(dot-naphthyl)) fluorenyl zirconium, this paper scale applies to China National Standard (CNS) A4 specification (2) G x 297 public meals) 312991 ---------- ---蝎 (Please read the note on the back and fill out this page) Order---------Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed 65 65 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 66 1290149 A7 B7 V. INSTRUCTIONS (66) Dichloro-dimethyl-decyl-bis[1-(2-methyl-4-(1-indolyl)indenyl)]zirconium dichloride Chlorinated chloro-dimethyl decyl-bis[1-(2-methyl-4-(2-indenyl) fluorenyl)] zirconium, dichloro-cyclo-dimethyl decyl _bis[1-(2-methyl-4-(9-fluorenyl)fluorenyl)]zirconium, dichloro-dichloro-demethyl-bis[1-(2-methyl-4) -(9-; phenanthrene) fluorenyl)] wrong, dichlorinated _Dimethyl decyl-bis[1-(2-methyl-4-(p-fluorophenyl) fluorenyl)]zirconium, dichloro-cyclohexyl-dimethyl-decyl-bis[1] -(2-methyl-4-(pentafluorophenyl)indenyl)]zirconium, dichloro-dimethyl-decyl-di-[1-(2-methyl-4-(p-chloro) Phenyl) fluorenyl)]zirconium, dichloro-dichloro-dimethyl hydrazino-bis[1-(2-methyl-4-(m-chlorophenyl)indenyl)]zirconium, dichlorinated Racemic-dimethylmethyl decyl-bis[1-(2-methyl-4-(o-phenyl)indolyl]]zirconium, dichloro-cyclo-dimethyl-decyl-di-di [1-(2-methyl-4-(o-, p-diphenyl)phenylindenyl)]zirconium, di-emulsified racemic-dimethyl-alkylene-bis[1-(2- Methyl-4-(p-hydroxyphenyl) fluorenyl)]zirconium, di-vaporized-dimethyl decyl-bis[1-(2-methyl-4-(p-tolyl) fluorenyl >]Zirconium, this paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 312991 -------------------- Order---- -----Line (please read the notes on the back and fill in this page) 1290149

Illustrated by the Ministry of Economic Affairs (67 Ministry of Economic Affairs, Intellectual Property Office, Staff and Consumers Co., Ltd., printing of two gasification racemic - dimethyl decyl-di-[]-based] zirconium, di-vaporized-dimethyl decyl- Bis[(indenyl)]zirconium, di-vaporized dimethyl-denidinyl-bis[methylphenyl]-1-indenyl]zirconium, di-vaporized-dimethyl decane Base-bis[yl]fluorenyl)]molecular, di-vaporized-dimethyl dimethyl sulfonyl-bis[phenyl]indenyl) hydrazine, di-cyclohexane-dimethyl decane Base-bis[phenyl]indenyl]zirconium, di-vaporized-dimethyl hydrazinoalkyl-bis[indenyl]zirconium, a gasified racemic-dimethylexene Bis[indenyl]], dichlorocyclohexane-dimethylalkylene-bis[indenylalkylphenyl)indenyl zirconium, dichloro-cyclohexyl-decyl-di-[矽 矽 矽 矽 ) ) ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] ] Tolyl)methyl-o-tolyl) 1·(2-methyl-4-(o-, o-, 1·(2-methyl-4-(p-ethylbenzene 1·(2-A) 4-(p-Isopropyl (2-methyl-4-(p-phenyl)-(2-methyl-biphenyl) 1-(2-methyl-4-(m-phenyl) 1 -(2-methyl-4-(p-trimethyl b (2-methyl-4-(m-trimethyl-1-(2-phenyl-4-phenylphenyl))] 1-(2-methyl Base-4-phenyl benzyl)] -------------------- order ·------- line mu (please read the notes on the back first) Fill in this page again. This paper size applies to China National Standard (CNS) A4 specification (10) X 297) 67 312991 A7

V. INSTRUCTIONS (68) Dimethylation of racemic _bis-(isopropyl) hydrazinoalkyl-biguanide _(2-methyl-4-ylphenyl) hydrazine, dichlorocyclohexane Di-(n-butyl)alkylene-bis-methylphenyl aryl)], dichlorocyclohexanedicyclohexylalkylene-bis[1_(2_methyl_4_phenylindole)基)]鍅, 1290149 Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, Printing Dimethylation, Racemic, Methylphenyl, Terpene-Shuang[1_(2-methylphenylindenyl)]zirconium, Dichlorination Cyclo-diphenylalkylene _bis[1-(2-methyl-4-phenylindenyl)] zirconium, di-vaporized dioxo-p-tolyl-alkyl-bis[ip- Methyl-4-phenylindenyl]]zirconium, dichloro-di(p-chlorophenyl)alkylene-bis[1(2-methyl-4-phenylindenyl)]zirconium, Racemic-dimethyl-bis-methyl-phenyl-4-phenylindenyl]zirconium dichloride, di-vaporized _extended ethyl-bismethyl-4-phenylindenyl )] zirconium, dichloro-dichloro-decanemethyl-4_phenylindenyl)] zirconium, dichlorocyclohexyl-dimethyltin-alkyl-di-tl-(2 -methyl-4-phenylindenyl)] wrong, dibrominated Cyclo-dimethyl hydrazinyl-bis[1-(2-methyl-4-phenylindenyl)], dimethylcyclod-dimethyl hydrazino-bis[1-(2 -Methyl-4-phenylindenyl)] False, this paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) ---------I------- ---Book·------- (Please read the notes on the back and fill out this page) 68 312991 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed Swordswear 1290149 Λ7 B7 V. Inventions (69) A Base gasification racemic-dimethylmethyl decyl-bis[1-(2-methyl-4-phenylindenyl)]zirconium, chlorinated S02Me racemic-dimethylmethyl sulfonyl-double [ 1-(2-methyl-4-phenylindenyl)]zirconium, chlorinated 0S02Me racemic-dimethylalkylene-bis[1-(2-methyl-4-phenylindenyl)] Zirconium, dichloro-dimethyl decyl-bis[1-(2-ethyl-4-phenylindenyl)], dichlorocyclohexane-dimethylalkylene- Bis[1-(2-ethyl_4-α-naphthyl)fluorenyl]zirconium, dichloro-dimethyl-decyl-di-[1-(2-ethyl-4-石- Naphthyl) fluorenyl] zirconium, di-vaporized-dimethyl hydrazine-bis[1-(2-ethyl-4-(2-) Zirconium-naphthyl)fluorenyl)zirconium, dichloro-dimethyl-dealkyl-bis[1-(2-ethyl-4-(5-fluorenyl)fluorenyl)]zirconium, Di-vaporized-dimethyl hydrazinoalkyl-bis[1-(2-ethyl-4-(9-fluorenyl) fluorenyl)]zirconium, di-vaporized-dimethyl decane Base-bis[1-(2-ethyl-4-(9-phenanthryl)fluorenyl) 1 zirconium, dichloro-dimethyl-decyl-di-[1_(2_ethyl-4) -(o-methylphenyl)indenyl)]zirconium, dichloro-dimethyl-dealkyl-bis[1-(2-ethyl-4-(m-methylphenyl)fluorenyl) ]鍅, ---------------------Book ---------* . (Please read the notes on the back and fill out this page) Paper The scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 69 312991 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 70 1290149 Λ7 B7 V. Description of Invention (70) Dichloro-dimethyl-dimethyl矽-alkyl-bis[1-(2-ethyl-4-(p-methylphenyl)indenyl)]zirconium, dichloro-dichloro-cycloalkyl-bis[1-(2- Ethyl-4-(2,3-dimethylphenyl)indenyl]zirconium, dichloro-dimethyl-decyl-dialkyl- Bis[1-(2-ethyl-4-(2,4-dimethylphenyl)indenyl)], dichlorocyclohexane-dimethylalkylene-bis[1-(2- Ethyl 4-(2,5-dimethylphenyl)indenyl)], dichlorocyclohexane-dimethylalkylene-bis[1-(2-ethyl-4-(2) ,4,6-trimethylphenyl)indenyl)]zirconium, dichloro-dichloro-cycloalkyl-bis[1-(2-ethyl-4-(o-chlorophenyl)) Base)] zirconium, dichloro-dichloro-dimethyl decyl-bis[1-(2-ethyl-4-(m-chlorophenyl) fluorenyl)]zirconium, di-vaporization- Dimethyl decyl-bis[1-(2-ethyl-4-(p-phenylphenyl)fluorenyl)]zirconium, dichloro-dichloro-dimethyl hydrazine-bis[1-( 2-Ethyl-4-(2,3-dichlorophenyl)indenyl]]zirconium, dichloro-dimethyl-decyl-di-[1-(2-ethyl-4-() 2,6-Dichlorophenyl)indenyl)]zirconium, dichloro-dichloro-demethyl-bis[1-(2-ethyl-4-(3,5-dichlorophenyl)茚))] zirconium, dichloro-dichloro-dimethyl-decyl-bis[1-(2-ethyl-4-(2-bromophenyl)indenyl)]zirconium, suitable for this paper scale China National Standard (CNS) A4 specification (210 x 297 mm) 31299 1 --------------------Book·-------*5^ (Please read the notes on the back and fill out this page) 1290149 Α7 __ Β7 V. Inventive Note (71) Di-cyclohexane-dimethyl hydrazino-bis[1-(2-ethyl-2-(3-bromophenyl) germination)], (Read first Note on the back side of this page) Divaporation-dimethyl dimethyl sulfonyl-bis[M2_ethyl-4-(4-bromophenyl) benzyl)] • Dimethyl decyl-bis[1-(2-ethyl-4-(4-biphenyl)] aryl, di-cyclohexane, dimethyl hydrazide-double [1-(2-ethyl-4-(4-trimethyldecylphenyl)indenyl)]zirconium, di-cyclohexane-dimethyl sulphate-bis[1- (2- N-propyl-4-phenylindenyl)], dichlorocyclohexane-dimethylexene-bis[1-(2-n-propyl-4-(α-naphthyl)anthracene Base)] zirconium, dichlorocyclohexane-dimethylalkylene-bis[1-(2-n-propyl-4-(indenyl-naphthyl)fluorenyl)]zirconium, digassing racemization - dimethyl thiophene sulphate-bis [1-(2-n-propyl-4-(5-hazardyl) germination)] wrong, Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperatives, printed clothing Di-cyclohexane-dimethyl hydrazino-bis[1-(2-n-propyl-4-(9-fluorenyl)fluorenyl)]zirconium, oxidized racemic dimethyl Calcinyl-bis[1-(2-n-propyl-4-(9-phenanthryl)-indenyl)]-, di-vaporized-dimethyl-alkylene-bis[1-(2-iso-) Propyl-4-phenyl-enyl)]zirconium, di-vaporized-dimethyl succinyl-bis[1-(2-isopropyl-4-(α-naphthyl)) )] wrong, this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 71 312991 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 72 1290149 Λ7 B7 V. Invention description (72) Dichlorination Cyclo-dimethyl hydrazinoalkyl-bis[1-(2-isopropyl-4~(d-naphthyl)fluorenyl)]zirconium, di-vaporized-dimethyl hydrazine-double [ 1-(2-isopropyl-4-(8-methyl-9-caiyl)indolyl)] s, dichlorocyclohexane-dimethylalkylene-bis[1-(2-iso) Propyl-4-(5-fluorenyl)fluorenyl)]zirconium, dichlorinated dimethyl hydrazinyl-bis[1-(2-isopropyl-4-(9-fluorenyl) fluorene Base)] zirconium, dichloro-dichloro-demethyl-bis[1-(2-isopropyl-4-(9-phenanthryl) ) fluorenyl)] zirconium, dichloro-dichloro-cycloalkyl-bis[1-(2-t-butyl-4-phenylindenyl)]zirconium, dichlorocyclohexane Dimethyl anthracene-bis[1_(2_t-butyl-4-(α-naphthyl)indenyl)], dichloro-cyclo-dimethyl-decyl-bis[1- (2-t-Butylnaphthyl)fluorenyl)]zirconium, dichloro-dimethylcyclo-decyl-bis[1_(2_2-butyl-4-(2-methyl-1) -Caiji)]] zirconium, dichloro-dichloro-demethyl-bis[1-(2-t-butyl-4-(5-fluorenyl)fluorenyl)]zirconium, Racemic dimethyl sulphate-bis[1-(2-t-butyl-4-(9-fluorenyl) fluorenyl)] zirconium, dichloro-dichloro-dimethyl Dialkyl-bis[1-(2-t-butyl-4-(9-phenanthryl)indenyl]zirconium, this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------------------- Order --------- line (please read the notes on the back and fill out this page) A7 1290149 ---- ---- -B7 V. INSTRUCTIONS (73) " -- Di-cyclohexane dimethyl thiocarbazide-biguanide-(2-n-pentyl _4_phenylindenyl zirconium , Racemic-dimethyl dimethyl sulfonyl-bis[1-(2-n-pentyl-4-(α-naphthyl)fluorenyl)]zirconium, dichlorocyclohexane-dimethyl extension矽alkyl-bis[1β(2-n-butylphenyl)), dioxin-cyclo-dimethyl hydrazine-bis-(2-n-butyl-4-(α-naphthalene) (茚))] zirconium, di-vaporized racemic dimethyl dimethyl hydrazine _ bis [1β (2-n-butyl-4- -4- phenanphthyl) fluorenyl)] zirconium, dichlorination Cyclo-dimethyl hydrazine-bis [1β(2-n-butyl-4-(2-methyl-1-naphthalenyl) fluorenyl)] fluorene, dichlorocyclohexane-dimethyl extension矽alkyl-biguanide-^-n-butyl-"^-hazardyl))], hammer, two gasification racemic - dimethyl hydrazine _ bis [1-(2-n-butyl- 4-(9-fluorenyl) fluorenyl)]zirconium, di-vaporized-dimethyl decyl-bis[1_(2-n-butyl-4-(9-phenanthryl) germination)]鍅, chlorocyclohexane-dimethyl decyl-bis[1-(2-isobutyl-4-phenylindenyl)]zirconium, dichloro-cyclodimethylene alkyl _bis[1-(2-isobutyl-4-(α-naphthyl))) hydrazine, oxidized racemic - dimethyl succinyl-di-[1-(2-iso-butyl) Base -4- (dot-naphthyl) fluorenyl)]鍅, -------------------- order --------- line ^9. (Read first Precautions on the back side Fill in this page) Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperatives Printed on this paper scale applicable +3⁄43⁄4 (CNS) A4 size (10) X 297 Μ ) 73 312991 A7 1290149 B7 V. Description of invention (75 ) Dichloro Oxidized-diphenylalkylene-bis[1-(2-ethyl-4-phenylindenyl)]zirconium, di-vaporized-diphenylalkylene-bis[1-(2 -ethyl-4-(α-naphthyl)fluorenyl)]zirconium, di-vaporized-diphenylalkylene-bis[1-(2-ethyl-4-(9-fluorenyl) fluorene Base)] zirconium, dichlorocyclohexane-diphenylalkylene-bis[1-(2-ethyl-4-(9-phenanthryl)fluorenyl)] hydrazine, an emulsified racemic-diphenyl Stretching base-bis[1·(2-ethyl·4-(4-diphenyl)fluorenyl)]indole, dichlorocyclohexane-methyl _bis-(2-ethyl- 4-phenylindenyl)zirconium, di-vaporized-extended methyl-bis[1_(2-ethyl-4-(α-naphthyl)indenyl)] oxime, dichlorocyclohexane -extended ethyl-bis[1-(2-ethyl-4-phenylindenyl)]zirconium, di-vaporized-extended ethyl-bis[1-(2-ethyl-4) -(α-naphthyl)fluorenyl)] zirconium, di-vaporized-extended ethyl-bis[1-(2-n-propyl-4-[(α-naphthyl)fluorenyl)] zirconium, two gas Racemic-dimethyl decyl-diethyl-phenylphenyl fluorenyl y zirconium, a gasified racemic-dimethyl decyl-bis[1(2-ethyl_4_(α _) Naphthyl)fluorenyl)] and a gasified racemic-dimethylalkylalkyl-biguanidine 2_n-yl_4_phenylindenyl)] Record 0 ----------- -曦(Please read the notes on the back and fill out this page) Order---------Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative

75 312991

Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumers Co., Ltd. 76 1290149 A7 _-_________ B7 V. INSTRUCTIONS (76) Compounds in which zirconium is replaced by titanium or hafnium may also be used. In the present invention, a racemic body of a transition metal compound represented by the formula (11a) is usually used as a catalyst component, but an R type or a plastic may also be used. The transition metal compound of the formula (118) can be produced according to the specification and examples of European Patent No. 0,320,762, which is described in 011111 & 1 of Organometallic Chem., 288, pp. 63-67 (1985). The transition metal compound represented by the formula (lib) is illustrated below. (11b) In the above formula, 'Μ1 is a transition metal atom of Group 4 of the periodic table, in particular, titanium, zirconium or hafnium, and zirconium is preferred. R37 and R38 may be the same or different and each is a hydrogen atom or a nitrogen-containing group, a phosphorus-containing group, a hydrocarbon group having from 1 to 20 carbon atoms, and having the same meaning as R25, R26, R27 and R28 in the above formula (11). A halogenated hydrocarbon group to 20 carbon atoms, an oxygen-containing group, a sulfur-containing group, a thiol group or an i atom. R37 is preferably a hydrocarbon group having 1 to 20 carbon atoms, particularly preferably a hydrocarbon group having from 2 to 3 carbon atoms, such as a methyl group, an ethyl group or a propyl group. R38 is preferably a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, particularly preferably a hydrogen atom or a hydrocarbon group having 1 to 3 carbon atoms such as a methyl group, an ethyl group or a propyl group. R39 and R4〇 may be the same or different and each is a hydrocarbon group having 1 to 20 carbon atoms. Examples of such hydrocarbyl groups include straight-chain or branched-chain alkyl groups, such as a smirk, this paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 312991 ------------ -曦(Please read the notes on the back and fill out this page) Order---------Line· 1290149 A7 B7 Such as raw spine alkyl and diamond just five, invention description (77 ^ base, n-propyl , isopropyl, n-butyl, isobutyl, t-butyl t-butyl, n-pentyl, neopentyl, n-hexyl, hexyl, octyl, decyl, dodecyl and eicosane And a cycloalkyl group, the soil base R39 is preferably a secondary or tertiary alkyl group. X1 and X2 may be the same or different and have the same meanings as in the formula (11) and X2. γ1 has the formula (11) The same meaning of Y1 in the formula. Examples of the transition metal compound represented by the formula (1 lb) include di-vaporized cyclo-dimethylmethyl decyl-bis[1-(2,7-dimethyl_4_B) Keine base)] cone, dioxin-cyclo-dimethyl hydrazino-bis[1-(2,7-dimethyl-4-n-propyl)] -Dimethyl decyl-bis[1_(2,7-dimethyl-4-isopropenyl)]zirconium, two Racemic-dimethyl extended thiol-bis[1-(2,7-dimethyl-4-n-butylfluorenyl)], dichlorocyclohexane-dimethylalkylene _bis[1-(2,7-dimethyl-4-t-butylfluorenyl)]zirconium, dichloro-dimethyl-decyl-di-[1-(2,7-di) Methyl-4·tert-butylfluorenyl)]molecular, dichloro-dichloro-dimethyl-decyl-bis[1-(2,7-dimethyl-4-n-pentyl) ] wrong, two gasification racemic-dimethylexene-based bis-[1-(2,7-dimethyl-4-positive paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 PCT) 312991 -------------------- Order --------- line (please read the notes on the back and fill out this page) Intellectual Property Bureau Staff Consumer Cooperative Printed 77 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Clothes 78 1290149 A7 B7 V. Inventive Note (78) 茚 茚)] Zirconium, dichlorocyclohexane-dimethyl decane Base-bis[1_(2,7-dimethyl-4-cyclohexylfluorenyl)]zirconium, dichloro-dimethyl-decyl-di-[1-(2,7-dimethyl) -4-methylcyclohexylfluorenyl)]zirconium, dichlorocyclohexane-dimethyl extension矽alkyl-bis[1-(2,7-dimethyl-4-phenylethylfluorenyl)]zirconium, dichloro-dimethyl-decyl-di-[1-(2,7- Dimethyl-4-phenyldichloromethylindenyl]]zirconium, dichloro-dimethyl-demethyl-bis[1-(2,7-dimethyl-4-chloromethyl) Sulfhydryl)] zirconium, dichlorocyclohexane-dimethyl sulfonyl-bis[1-(2,7-dimethyl-4-trimethyldecyl-f-yl)]zirconium, dichloro Racemic-dimethyl decyl-bis[1-(2,7-dimethyl-4-trimethyldecaneoxymethylindenyl)]zirconium, dichlorocyclohexane-diethyl extension矽alkyl-bis[1-(2,7-dimethyl-4-isopropylindolyl)]zirconium, dichloro-di(isopropyl)alkylene-bis[1-(2) ,7-Dimethyl-4-isopropylindenyl)]zirconium, dichloro-di(n-butyl)alkylene-bis[1-(2,7-dimethyl-4-) Isopropyl fluorenyl)] zirconium, dichloro-di(cyclohexyl) decyl-bis[1-(2,7-dimethyl-4-isopropylindolyl)]zirconium, Chlorinated racemic-methylphenyl decyl-di-[1-(2,7-dimethyl-4-isophthalate paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 3129 91 -------------------- Order --------- line (please read the note on the back and then fill out this page) 1290149 A7 B7 V. Description of the invention (79) propyl fluorenyl)] zirconium, di-vaporized-methylphenyl decyl-bis[1-(2,7-didecyl-4-th-butylfluorenyl)] Zirconium, dichloro-diphenyl-dealkyl-bis[1-(2,7-dimethyl-4-tert-butylfluorenyl)], dichloro-diphenyl-diphenyl矽-alkyl-biguanide-(2,7-dimethyl-4-isopropylindenyl)]zirconium, dichloro-diphenyl-decyl-di-[1-(2,7-dimethyl) Base_4_ethyl group)]zirconium, di-vaporized-di(p-tolyl)-extended alkyl-bis[1-(2,7-dimethyl-4- 4-isopropyl)错, 二 gasification racemic-bis(p-phenylene) hydrazinoalkyl-biguanide-(2,7-dimethyl-4-isopropylindenyl)]zirconium, dibromination racemization -Dimethyl decyl-bis[1-(2-methyl-4-isopropyl-7-ethylindenyl)]zirconium, di-vaporized-dimethyl decyl-bifluorene -(2,3,7-trimethyl-4-ethylindenyl)]zirconium, di-vaporized-dimethyl succinyl-bis[trimethyl-n-propyl fluorenyl)] Zirconium, Gasification racemic-dimethylmethyl decyl-bis[1-(2,3,7-trimethyl-4-isopropylindenyl)]zirconium, dichlorocyclohexanedimethyl extension矽-alkyl-bis[1-(2,3,7-trimethyl-4-n-butylfluorenyl)]zirconium, dichloro-dichloro-cycloalkyl-bis[1-(2, 3,7-Trimethyl-4-sheet paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 312991 -------------t (please read the back first) Note: Please fill out this page) Order---------Line· Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Clothing 79 1290149 A7 B7 V. Invention Description (80) Dibutylsulfonyl)] Zirconium , chlorocyclohexane-dimethyl decyl-bis[1-(2,3,7-trimethyl-4-tert-butylfluorenyl)]zirconium, dichlorocyclohexane-di Methyl decyl-bis[1-(2,3,7-trimethyl-4-n-pentyl fluorenyl)], dichloro-cyclohexyl-dialkyl-bis[1- (2,3,7-trimethyl-4-n-hexylfluorenyl)]zirconium, dichloro-dimethyl-demethyl-bis[1-(2,3,7-trimethyl- 4-cyclohexylfluorenyl)]zirconium, dichloro-dichloro-demethyl-bis[1-(2,3,7-trimethyl-4-methylcyclo) (茚))] zirconium, dichloro-dichloro-dimethyl-decyl-bis[1-(2,3,7-trimethyl-4-trimethyldecylmethylmethyl)]zirconium , Cyclohexane-dimethyl hydrazinoalkyl-bis[1-(2,3,7-trimethyl_4-trimethyldecaneoxymethylindenyl)]zirconium, dichlorocyclohexane -Dimethyl decyl-bis[1-(2,3,7-trimethyl-4-phenylethylindenyl)]zirconium, di-cyclohexane-dimethyl decyl-di- [1-(2,3,7-trimethyl-4-phenyldichloromethylindenyl)]zirconium, dichloro-dichloro-cycloalkyl-bis[1-(2,3 ,7-trimethyl-4-methylmethylindenyl)]zirconium, dichloro-diethyl-diethyl-decyl-bis[1-(2,3,7-trimethyl, 4-isopropyl)茚 ))]]zirconium, dichlorocyclohexane-di(isopropyl)alkylene-bis[1-(2,3,7-trimethyl-4- --------- ----蠊(Please read the notes on the back and fill out this page) Order---------Line· Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed and Teared Paper Size Applicable to Chinese National Standards (CNS ) A4 size (210 x 297 mm) 80 312991 1290149 Λ7 B7 V. Description of invention (81) Isopropyl fluorenyl)] Zirconium, dichlorination Spinal-di(n-butyl)alkylene-bis[1-(2,3,7-trimethyl-4-isopropylindenyl)]zirconium, dichlorocyclohexane-di(cyclohexyl) Ethylene alkyl bis[1-(2,3,7-trimethyl-4-isopropylindenyl)]zirconium, dichlorocyclo-methylphenyl hydrazinoalkyl-bis[1-(2 ,3,7-trimethyl-4-isopropylindenyl)]zirconium, dichloro-cyclo-methylphenyl decyl-bis[1-(2,3,7-trimethyl-4) - tert-butyl fluorenyl)] zirconium, dichloro-diphenyl-dealkyl-bis[1-(2,3,7-trimethyl-4-t-butylindenyl)]zirconium dichloride , chlorocyclohexane-diphenylalkylene-bis[1-(2,3,7-trimethyl-4-isopropylindenyl)]zirconium, dichloro-diphenyl-diphenyl extension矽alkyl-bis[1-(2,3,7-trimethyl-4-ethylindenyl)]zirconium, dichloro-di(p-tolyl)-dialkyl-bis[1-( 2,3,7-trimethyl-4-isopropylindenyl)]zirconium, dichloro-di(p-chlorophenyl)alkylene-bis[1-(2,3,7- Trimethyl-4-isopropylidene)], dimethyl, dimethyl-cyclohexyl-bis[1-(2-methyl-4-isopropyl-7-methylhydrazine) Base)] zirconium, methyl chloride racemic-dimethyl extension矽-alkyl-bis[1-(2-methyl-4-isopropyl-7-methylindenyl)]zirconium, bis(methanesulfonic acid) racemic-dimethylalkylene-bis[1- (2-methyl-4-isopropyl paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 ------------ Stuffing (please read the back note first) Matters to fill out this page) Order---------Line· Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed 81 Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed 1290149 A7 ----- B7 V. Invention Description (82) benzyl-7-methyl aryl)), bis(p-phenylsulfinic acid) racemic dimethyl dimethyl hydrazine-bis [1-(2-methyl-4-isopropyl) Methyl fluorenyl)]zirconium, di-vaporized-dimethyl hydrazinoalkyl-bis[p(2-methyl-3-methyl-4-isopropyl-7-methyl primyl) ] zirconium, di-vaporized-dimethyl hydrazinoalkyl-bis[1-(2-methyl-4,6-di-isopropyl-7-methyl yl)] zirconium, two gasification Racemic-dimethylmethylalkylene-bi-gas]-ethyl-4-isopropyl-7-methylindenyl]]zirconium, di-vaporized-dimethyl decyl-diphenyl Zirconium, 4-isopropyl-7-methylindenyl)]zirconium Racemic dimethyl dimethyl sulfonyl-bis-xylylene]-methyl fluorenyl]] zirconium, di-cyclohexane, exoethyl-bis- 1^-(2 4,7-trimethyldecyl) Zirconium and two gasification racemic · isopropyl isopropyl - bismuth b ^ seven plants trimethyl sulfhydryl zirconium. Compounds in which zirconium is replaced by titanium or hafnium may also be used. Among the above compounds, a compound having a branched alkyl group (e.g., an isopropyl group, a second butyl group or a tert-butyl group) at the position 4 is particularly preferred. In the present invention, a racemic body of a transition metal compound represented by the formula (llb) is usually used as a catalyst component, but an r-type or a type may also be used. The transition metal compound represented by the formula (lib) can be synthesized as a germination derivative by a known method, for example, the method described in Japanese Patent Laid-Open Publication No. 2683〇7/1992. -------------------- Order --------- line (please read the note on the back and then fill out this page) Then 'Description (12 The transition metal compounds shown are below.

82 312991 1290149 V. INSTRUCTIONS (83 x12 (12) In the above formula, Μ* is selected from the group of atoms, preferably 潠白, s#, transition metals of Groups 3 to 10, 卞1, Table 4 The transition metal atom of the family is more preferably ruthenium, titanium or ruthenium, especially good 鍅. More preferably

Cp is a cycloalkenyl group or a derivative thereof which is in the form of a M1 form 忐y f. ', child|atom, boron atom or the I# group of the periodic table, body, for example, -Si(R')·, -c(R')-, _Si(R222)Si(R2;): • C(R 2)C(R, )...c(r222)c(r222)c , 妒, -like addition...). or ·Ge(R222)_. C(R)-Y1 is a nitrogen-containing atom, a phosphorus atom, an oxygen atom or, for example, -n(R, _, _0_, _S4_p(r23)_. The body Z1 and Y1 may together form an anthracene ring. / is a hydrogen atom, a base, an aryl group, an yl group, a dentate base or a toothed aryl group having 20 non-hydrogen atoms, or a combination of such bases. π is a hospital base having one carbon atom and has a carbon atom a 2-group or an aralkyl group having 7 to 10 carbon atoms, or may form a fused ring having up to 30 non-hydrogen atoms together with one or more R22. X1 may be the same or different and hydrogen Atom, _ atom, a hydrocarbon group having 20 or less carbon atoms and having 1 or more double bonds, a decyl group containing 2 or less ruthenium atoms, a ruthenium group having 20 or less ruthenium atoms Or contains a boron atom of 20 or less boron atoms. This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm 83 order line 312991 A7 1290149 5. Invention description (84) Type (12) Examples of the transition metal compound shown include a gasified (t-butyl decylamine) (tetramethyl 5 - cyclopentadienyl) hydrazine, 2 - ethane-based, di-chlorinated (p. Butyl decylamine) (tetramethyl-hydrazine 5 · cyclopentadienyl) 4,2-ethanediyl titanium, di-gasified (methyl decylamine) (tetramethyl 5-cyclopentadienyl) Alkanediyl, di(methylamine) (tetramethyl-5-cyclopentadienyl)-12-ethanediyltitanium, dichloro(ethylamine) (tetramethyl-5_ Cyclopentadienyl) methyl titanium, one gasified (t-butyl decylamine) dimethyl (tetramethyl I cyclopentadienyl) titanium alkane, monochlorinated (second butyl sulphamine) Dimethyl (tetramethyl-indole I cyclopentadienyl) azacene zirconium, mono(benzylammonium) dimethyl (tetramethyl Icyclopentadienyl) decane oxime and I Methyl (phenylphosphonium) dimethyl (tetramethyl- 々 L cyclopentadienyl) decane Next, the transition metal compound represented by the formula (13) is illustrated below. r12 ^R41 ... (13) This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 χ 29f^" 84 312991 --------------- (please read the notes on the back and fill out this page) Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumption Cooperative, Printing Zirconium

Y1 R20 R14

1290149 A7 B7 V. Description of the invention (in) In the above formula, 'M1 is a transition metal atom selected from Groups 3 to 10 of the periodic table' is preferably a transition metal atom selected from Group 4 of the periodic table, more preferably Wrong, titanium or bismuth, especially good. RU to Rl4, Rl7 to R20 and R41 may be the same or different and each is a ketone group having 1 to 40 carbon atoms, a halogenated hydrocarbon group having 1 to 4 carbon atoms, an oxygen-containing group, a sulfur-containing group, and a thiol group. , _ atom or hydrogen atom; Ru, R!2, R13, R1

Among the groups represented by R, R19, R20 and R41, a group which is partially adjacent to each other may be bonded to a carbon atom bonded to the groups.

R

Looping (R11, R12, R 13

R 14 R17, Rl8, R19, R20 and R41 All 丨丨丨丨--------€ (Please read the notes on the back and fill in this page) The group is a hydrogen atom and Rl2 or R !3 is a third butyl group, except for the case where the other R11, R12, Rl3, Rl4, Rl7, r18, r19, r2Q and r41 are hydrogen atoms). Examples of the hydrocarbon group having 1 to 40 carbon atoms are an alkyl group having 1 to 20 carbon atoms such as a methyl group, an ethyl group, a propyl group, a butyl group, a hexyl group, a cyclohexyl group, an octyl group, a decyl group, a dodecyl group. And an eicosyl group; an aryl group having 6 to 20 carbon atoms such as a phenyl group, an α or a cold naphthyl group, a biphenyl group, a fluorenyl group and a phenanthryl group; an arylalkyl group having 7 to 40 carbon atoms, for example Benzyl, phenethyl, phenylpropyl, phenanthrylmethyl, phenanthrylethyl and phenanthrylpropyl; arylalkenyl having 8 to 40 carbon atoms such as vinyl phenanthryl; having 7 to 40 The alkylaryl group of a carbon atom is, for example, methylphenanthryl, ethylphenanthryl and propylphenanthrenyl; and a dilute radical having 2 to 10 carbon atoms such as an ethylidene group, a propenyl group and a cyclohexenyl group. This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 Order---------Line·Ministry of Finance and Welfare Bureau Staff Expenses Cooperation Society Printed 85

V. INSTRUCTIONS INSTRUCTIONS (86 Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperatives, Printed, 86 1290149 Examples of halogenated hydrocarbon groups having 1 to 40 carbon atoms include the above-mentioned groups in which a hydrocarbon group having 1 to 40 carbon atoms is substituted by a self-fertilization. Examples of the oxy group, the sulfur-containing group, the thiol group and the self-atomic group include the same groups and atoms as those of the above-mentioned formula (11), R25, R26, RW and R28. X1 and X2 may be the same or different and have a formula ( 11) The meaning of the middle oxime and X2. Υ1 has the same meaning as Υ1 in the formula (11). Examples of the transition metal compound represented by the formula (13) include isopropyl-(cyclopentadienyl) dichloride. (diyl) zirconium, dimethyl dialkyl decyl-(3-tert-butylcyclopentadienyl) zirconium, di-vaporized isopropyl-(3-tert-butylcyclopentane Dienyl)(diyl)zirconium, di-vaporized isopropyl-(cyclopentadienyl)(2,7-t-butyldiyl)zirconium, di-vaporized dimethyl-decyl-alkyl-( 2-methyl-cyclopentadienyl) (2,7-tert-butyldiyl), di-gasified dimethyl-decyl-(2-methyl-cyclopentadienyl) (fluorenyl) Zirconium, dimethyl dichloride Reductive alkyl-(cyclopentadienyl) (2,7-t-butyldiyl) zirconium, di-vaporized isopropyl-(2-methyl-cyclopentadienyl) (2,7- Third butyl group) zirconium, an emulsified isopropyl-(2-methyl-cyclopentadienyl) (3,6-tert-butylfluorenyl) zirconium, dimethylated dimethyl decane The base-(2-methyl-cyclopentadienyl) (3,6-t-butyl-decyl) cone and the paper scale apply to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991 —- -----------------Book------Line (please read the notes on the back and fill in this page)

/ R41

1290149 V. INSTRUCTION INSTRUCTION (87) A ratification of a base of 丄4〃, τ &_(裱pentadienyl)(fluorenyl)zirconium. It is also possible to use a compound which is displaced by titanium or ruthenium in the upper oxime of the oxime. Next, a transition metal compound of the formula n - 八^4) will be described below. (14) In the above formula, the M1 is selected from the periodic table. The transition metal atom of Group 3 to Group 10 is preferably a transition metal atom selected from Group 4 of the periodic table, more preferably zirconium, titanium or hafnium, and particularly preferably zirconium. *, R, R, R41 and R42 may be the same or different and each has a hydrocarbon group of 1 to 40 denier atoms, and has! A halogenated hydrocarbon group, an oxygen-containing group, a sulfur-containing group, a thiol group, a _ atom or a hydrogen atom to 4 carbon atoms. Examples of the hydrocarbon group having 1 to 40 carbon atoms include the same groups as defined above for R11 to R", Rl7 to r20 and r41 in the formula (13). Examples of the oxygen-containing, sulfur-containing group, thiol group-containing, and halogen atom include the same groups and atoms as defined above for R25, R26, R" and R28 in the formula (11). The groups represented by R11, R12, R41 and R42 In the group, a group which is adjacent to each other may be bonded to a carbon atom bonded to the group to form a ring. X1 and X2 may be the same or different and have the same meaning as χ1 and χ2 in the formula (11). It has the same meaning as Υ1 in formula (11), but when all Rn, Ri2, I R41 and R42 are hydrogen atoms, γΐ is not ethyl. ^ Paper scale applies to China National Standard (CNS) A4 (210 X 297) PCT '--- 312991 --------------- line (please read the phonetic on the back? Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 87

V. INSTRUCTION DESCRIPTION OF THE INVENTION (88 1290149 Example of a transition metal compound represented by the formula (14) comprises a gasified ethyl [2-methyl-4(9-phenanthryl)-1.]-group] (9-fluorenyl) zirconium , a gasification of ethyl [2-methyl_4 (9-phenanthryl)-1 - benzyl] (2,7-dimethyl-9-yl), two gasification of ethyl [2_ Methyl·4(9•phenanthryl) "-mercapto" (2,7-di-t-butyl-9-fluorenyl), monoethyl chloroacetate (2-methyl-4,5- Benzo-_1_ mentyl) (9-fluorenyl), di-gasified ethyl (2-methyl-4,5-benzo; !-mercapto) (2,7-dimethyl_9 _ 基 )), diethyl diethyl (2-indenyl 4,5-benzo-1-yl) (2,7-di-t-butyl 9-diyl) zirconium, ^ Dimethylated ethyl (2-methyl-4,5-benzoindenyl) (2J_dibromo-9-yl) di-gasified ethyl (2,6-dimethyl-4,5 -benzoyl)(2,7-di-t-butyldiyl)zirconium, di-gasified ethyl (2,6-dimethyl-4,5-benzo-i-indenyl) 2,7-dibromo-9- fluorenyl), a gasified ethyl (2-methyl-α-mercapto-1-yl) (9-yl), chloro-ethyl (2) -methyl-mercapto-1-yldimethyl _9·diyl, , ^ Diethyl diethyl (2-methyl-α-indenyl) (2,7-di-t-butyl-9-diyl), dimethyl dialkyl sulphate [ 2_Methyl_4(9_phenanthryl)4茚yl](9基基) Recording This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 public recovery 7 312991 ------- ------------- Order --------- line (please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 88 1290149 five , invention description (89) dimethyl dimethyl ketone [2 n-propyl _4 (9 phenanthrene (4) yl] (" a phenanthyl) -1 qing, 7-di 2 dimethyl chloride [2_Methyl-4(9-phenanthryl) smear] (2,7_2·Secondyl _9_fluorenyl), = chlorinated '"methyl-extension-based (2_ Methyl 4,5-benzo]-moleyl](tetra)yl) Dimethyl dimethyl diacetate (2.methyl·4,5·benzo·i•(4)) (2,7-dimethyl Base-9-diyl) zirconium, dimethyl dialkyl decyl chloride ("base _4, benzodiazepine 7-di-t-butyl _9_diyl) hammer, dichloride Methyl (tetra) fen (2_methyl-α-anisyl primate) (9_diyl) wrong, linear dichlorination Methyl decylalkyl (2-methyl oxime + germination) (2,7-dimethyl-9-fluorenyl), dimethyl dialkyl sulphate (2_methyl _α _ (2,7-di-tert-butyl-9-diyl) zirconium, diphenylalkylene dialkyl [2_methyl-4(9-phenanthryl}-1 fluorenyl) (9_fluorenyl) zirconium, diphenylalkylene dialkyl [2_methyl-4(9-phenyridinyl) (2,7•dimethyl-9-fluorenyl) cone, dichlorinated Diphenyl decylalkyl [2-methyl-4(9-phenanthryl)-1-indenyl] (2,7-di-t-butyl-9-yl) wrong, 1 paper size Gu Zhongguan Home Standard (CNS) A4 Specifications (2) G χ 297 mil) 89 312991 1290149 A7

V. Description of the invention (9〇) monophenyl-phenylene alkyl (2-methyl-4,5-benzo-1-indenyl) (9-fluorenyl) is wrong, (please read the back note first) Fill in this page again) Diphenyl dialkyl sulfonium dialkyl (2-methyl-4,5-benzo-indole) (2, octamethyl-9-yl), di-hydrogenated diphenyl decane (2_methyl_4,5-benzo-h-yl) (2,7-di-t-butyl-9-diyl) hammer, 'diphenyl dialkyl decyl (2_A) (α_苊-yl-1-yl) (9-fluorenyl) zirconium, diphenylalkylene dichloride (2-methyl-α-mercapto-1β-decyl) (2,7-dimethyl -9-9-fluorenyl), diphenylalkylene dialkyl (2-methyl-α-fluorenyl-l-fluorenyl) (2,7-di-t-butyl-9·diyl) Zirconium, methylphenyl dialkyl hydrazide [2-methyl-4(9-phenanthryl)_;!-mercapto] (9-fluorenyl) cone, methyl phenyl dichloride [2-methyl-4(9-phenanthryl)] (2,7_monomethyl-9·indenyl), Ministry of Economic Affairs, Intellectual Property Office, Staff Cooperatives, Printing, Leaving, Methylphenylphenyl [2-methyl-4(9-phenanthryl)_;!_mercapto](2,7-di-t-butyl-9-fluorenyl) Zirconium, methylphenyl dialkyl alkyl (2-methyl-4,5-benzo-indenyl) (, yl) zirconium, dimethylated methylphenyl decylalkyl (2-methyl-4) ,5-benzo-i-fluorenyl) (2,7-dimethyl-9-diyl), 2 gas methylphenyl phenoxyalkyl (2-methyl-4,5-benzopyrene Base) (2,7_di-t-butyl_9_diyl) zirconium, this paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public) 90 312991 Α7 Β7 1290149 V. Invention description φΐ Dimethylated methylphenylalkylene (2-methyl-α-indenyl) (9-fluorenyl) zirconium, methylphenyl dialkyl sulfonate (2-methyl _α _ fluorenyl hydrazine) (2,7-dimethyl-9 fluorenyl) zirconium, dimethylated methylphenylalkylene (2-methyl-α-indolyl-1-β-yl) (2,7-di- Tributyl-9-diyl)anthracene, diethylammonium diethyl [3-methyl-4(9-phenanthryl)-:ι_indenyl](9-diyl)zirconium, di-gasification [3-methyl-4(9-phenanthryl)_;!_mercapto](2,7-dimethylindenyl), di-gasified ethyl [3-methyl-4(9- Phenyl)_:u茚]] (2,7_di-t-butyl-9·diyl), chlorinated (3-methyl-4,5-benzo-1-yl) (9-diyl) zirconium, diethylammonium diethyl (3-methyl-4,5-benzo-1-indenyl) (2,7-dimethyl_9_diyl) zirconium, linear dichloroethyl (3_mercapto-4,5·benzo-1-indenyl) (2,7•II· Tributyl -9-diyl) zirconium, diethylammonium diethyl (3-methyl-α-indenyl fluorenyl) (9-diyl) zirconium, diethyl chloroacetate (3-methyl _ α 苊 茚 ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) Tributyl -9-diyl) zirconium, trimethyl chloroform, zirconium, zirconium, hydrazino, ketone, keel, keel, keel, keel , invention description (92) methyl-9-diyl), di-vaporized dimethyl-extended alkyl [3-methyl-4(9-phenanthryl)-1_indenyl] (2,7-di _ tert-butyl-9-diyl) zirconium, di-vaporized dimethyl-terminated alkyl (3-methyl-4,5-benzo-1-indenyl) zirconium, dimethyl dichloride N-alkyl (3-methyl-4,5-benzo- fluorenyl) (2,7-dimethyl-9-diyl) zirconium, dimethyl dialkyl decyl (3-methyl) -4,5-benzo-1-indenyl) (2, 182) Tert-butyl-9-diyl)zirconium, di-vaporized dimethyl-decylalkyl (3-methyl-α-mercapto-1-indenyl) (9-diyl) zirconium, dimethyl dichloride Alkyl-alkyl (3-methyl-α-hazard-1-enyl) (2,7-dimethyl-9-fluorenyl), di-gasified dimethyl-extension (3-A Base-α-hazard-1 _ germination) (2,7-di-t-butyl-9-diyl) zirconium, diphenylalkylene dialkyl [3-methyl-4 (9-phenanthrene) Base) -1_] group] (9_fluorenyl) wrong, di-vaporized diphenyl-extended alkyl [3-methyl-4(9-phenanthryl)_; u-mercapto] (2,7-dimethyl Base-9-fluorenyl), diphenyl diphenyl sulfonyl [3-methyl-4(9.phenanthryl)_1_]] (2,7_di_third butyl_9_ Zirconium, a gasified diphenyl succinyl group (3-methyl-4,5-benzo-1 fluorenyl) (, yl) zirconium, di-gasified diphenyl decyl alkyl (3-methyl Base _4,5_benzo-!-fluorenyl) (2,7_ dimethyl paper size applicable to Chinese national standard (cns) a4 specification (210 x 297 mm)" -------- --- 312991 -------------蝎 (Please read the phonetic on the back first? Matters fill out this page) Order---------Line - Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives print 92 Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives print 93 1290149 Α7 _ Β7 5, invention description (93 ) -9-fluorenyl), an emulsified diphenyl benzophenanthrene (3 -methyl-4,5-benzo-1-imyl) (2,7-di-_ tert-butyl-9 - fluorenyl) zirconium, diphenyl decyl dialkyl (3-methyl-α-anilinyl ι_ fluorenyl) (9-fluorenyl), a gasified diphenyl hydrazine (3 - A (α-Ethyl-1-enyl) (2,7-dimethyl-9-diyl), diphenylalkylene dichloride (3-methyl-α-mercapto-1) (2,7-di-di-tert-butyl-9-diyl) zirconium, an emulsified methylphenyl succinyl group [3-methyl-4(9-phenanthryl)_ι_]] 9_diyl), methyl phenyl dialkyl sulfonyl chloride [3-methyl _4 (9-phenanthryl) _i_ germination] (2, plant dimethyl-9-diyl) zirconium, two Methylphenyl hydrazinyl chloride [3-methyl·4(9.phenanthryl)_;[_mercapto](2,7-di-t-butyl-9-diyl)zirconium, dichlorination Methylphenylalkylene (3-methyl-4,5-benzo-i-) 9_diyl) zirconium, methyl phenyl dialkyl decyl (3-methyl-4,5-benzo- fluorenyl) (2,7-dimethyl-9-diyl) zirconium, two Methylphenyl decylalkyl chloride (3-methyl-4,5-benzo-; [_ gercapyl) (2,7-di-t-butyl-9-diyl) zirconium, an emulsified toluene-based extension Dreaming base (3-methyl-α-strasyl-1_enyl) (9-diyl), methic acid methylphenyl decylalkyl (3-methyl-α-mercapto-1β germination) (2,7_ two paper scales apply to China National Standard (CNS) A4 specifications (210 x 297 mm) 312991 -------------------- Order -- ------- Line "m (Please read the note on the back and fill out this page) 1290149 V. Description of the invention (94 methyl-9-diyl) wrong, dibasic thiol (iv) appearance base (four) First butyl-9-yl), = ethyl (2-methyl-4,5-benzopyrylene) (2, alkyl-9-fluorenyl) zirconium, 7 soil y dichloride Ethyl ether (2,7-dif-group 5 〇田甘二-三丁米细(^ 苯朴1婚)(2,7· 鲁丁二气化二基伸钱基(2_甲Base _4,5_benzo-3-trif-decyl-9-yl) wrong, violent) (2,7-a-bis(f-acid) dimethyl extension矽alkyl (2_methyl_4, di-tert-butyl-9.diyl) zirconium, 5 - germination) (2,7_ line

Bis(trifluorof-supply acid) dimethylexene (2-methyl-4-yl) (2,7-di-t-butyl- 9-diyl) zirconium, P 7 —dichloroformic acid Base alkyl (2,6-di-yl-4, bis(trimethyldecyl)_9-fluorenyl) zirconium, fluorenyl) (2 bis(methanesulfonic acid) dimethylalkylene (2 , 6_2' τ I _4,5-benzo-1-sweetyl) (2,7-di(trimethyldecyl)>9_diyl) zirconium, bis(difluoromethanoate) dimethyl (2,6-dimethyl sulfonyl) (2,7-di(trimethyldecyl) decyl): _4,5-benzo]- 丨2,6-di-f-alkyl-4s (2,6-di-f--4s) This paper scale is suitable for use in _ 豕 芈 (CNS) A4 specifications (2) G _ 1 · 茚 base) (2,7 94 312991 gong 1290149 5, invention description (%) di-t-butyl-9-fluorenyl) hydrazine, dimethyl dialkyl decyl (2 7_di-tributyl -9-diyl), soil, 5 _小小萌基) (2,7_dimethyl dialkyl decyl (2 7 — — germination 7. bis-tertiary butyl. 9 rhyme) 错 基 - 4, 5 ♦ methyl - stupid & : gas two base extension W (" together - two desert dichlorinated dialkyl decane (2,6-didibromo-9-diyl) zirconium, soil '_benzoxanyl) (2,7-dichlorodifluoride (2-methylbutoxy-9-) (base) error, open shouting) (2,7--- difyl dialkyl decyl alkyl (2 6 _ 2 bis - 3 -butoxy hexadyl) wrong, ., 5 benzo primate (2,7-dimethyldimethyl sulfonyl chloride (2_?-yl_45_yl-9-fluorenyl) zirconium, fluorenyl) (2,7-di-di-di-di-dialkyl) 6_didiphenylbutylidene), soil '5_benzoxyl-enyl) (2,7-dichlorodifluorenyl) ("yl-4" isopropyl-9-fluorenyl) Zirconium, ruthenium-based (2,7-di-dichloro-dimethyl ketone (2,6-:methyl- 4 bis-isopropyl-9-fluorenyl) zirconium, imprinting base) 2,7-di-diyl-dialkylene (2,2,2,2-yl), zirconium, ketone, fluorenyl (2,7-fluorene difluorenyl) 2 6_二f美本难^用用中国国家标准1基·苯苯)-1 _ 95 Order line 312991 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1290149 A7 B7 V. Invention Description (96) Section) (2,7-di-t-butyl-9-yl) wrong, dichloro Dimethyl decylalkyl (2,7-dimethyl-4,5-(2-methyl-benzo)-1-pyrene) (2,7-di(trimethylmethane)-9 -diyl), dimethyl dialkyl decyl (2,7-dimethyl-4,5-(2-methyl-benzo)-1-indenyl) (2,7-dibromo) -9-diyl) zirconium, dimethyl decyl chloride (2,7-dimethyl-4,5-(2-methyl-benzo)-1-indenyl) (2,7- Di-t-butoxy-9-diyl)zirconium, di-vaporized dimethyl-terminated alkyl (2,7-dimethyl-4,5-(2-methyl-benzo)-1-pyrene (2,7-diphenyl-9-fluorenyl)zirconium, dimethyldimethylene dichloride (2,7-dimethyl-4,5-(2-methyl-benzo)- 1-indenyl)(2,7-di-isopropyl-9-diyl)zirconium, di-vaporized dimethyl-desinyl (2,7-dimethyl-4,5-(2-methyl) -Benzyl)-1-indenyl)(2,7-dimethyl-9-diyl)zirconium, dimethyldimethylene dialkyl (2,7-dimethyl-4,5-(l -Methyl-benzo)-phenanthyl) (2,7-di-t-butyl-9-yl), dimethyl dialkyl sulfonate (2,7-dimethyl-4) , 5-(l-methyl-benzo)-didecyl) (2,7-bis(trimethyldecyl)-9-diyl)zirconium, di-methylated dimethyl Base alkyl (2,7-dimethyl-4,5-(l-methyl-benzo)-1-indenyl) (2,7-dibromo-9.diyl)zirconium, two gasification Methyl decylalkyl (2,7-dimethyl-4,5-(1-methyl-benzo)-1-indenyl) (2,7-di-t-butoxy-9-fluorenyl) Zirconium, dimethyl decyl chloride (2,7-dimethyl-4,5-(l-methyl-benzo)-1-indenyl) (2,7-diphenyl-9) - fluorenyl) zirconium, dimethyl decyl chloride (2,7-dimethyl-4,5-(1-methyl-benzo)-1- This paper scale applies to Chinese National Standard (CNS) A4 size (210 x 297 mm) i- 蔑--------book--------- line (please read the notes on the back and fill out this page) 96 312991 1290149 V. Invention Description (97) fluorenyl) (2,7-di-isopropyl-9-fluorenyl), dimethyl dialkyl decyl (2,7- - ψ^^"η V, methyl- 4,5_(1-methyl-benzo)-1-mole (), 2,7-dimethyl-9-fluorenyl), double ("acid) dimethylexene (2_A Base_4, phenyldibromo-9-diyl) zirconium, octa, bis(methicic acid) dimethyl (tetra)morphyl (2,6-dimethyl-45 benzopyrylene) (2,7-二漠-9-苐基)鍅, 双(甲Continuation of acid) dimethylexene (2_methyl_45_benzoxanthyl] _di-t-butoxy_9_diyl) zirconium, bis(methylation) dimethyl sulphate Xialing base (2,6-dimethyl-4,5-benzoxanthyl) (2,7-di-t-butoxy- 9-fluorenyl) zirconium, bis-methyl sulphate Based on the base of Shishi Xiyuan (2_methyl_4,5_benzoxanthyl) (27_diphenyl-9-diyl) cone, bis(methanesulfonic acid) dimethylexene 26-dimethyl-4,5-benzo-hydrazinyl) (2,7-diphenyl-9-yl), bis(▼) acid bis-fylylene (2_methyl_ 4,5 benzopyramine)(υ·di-isopropyl-9-diyl), bis(methyl-acid) dimethylalkylene (2,6-dimethyl-4,5_ Benzo-bromo)(2,7-di-isopropyl-9-yl) zirconium, bis(methanesulfonic acid) dimethylalkylene (2,6-dimethyl-4,5_ Benzo hydrazide) (2,7-difyl-9-diyl) cone, bis(methanesulfonic acid) dimethyl decyl (2,7-dimethyl-4,5_(2_A) (2,7-di-yl) (2,7-di(trif-decylalkyl)_9-yl), bis(f-sulfonic acid) bis-f-decylalkyl (2,7-di-f-yl) _4,5_(2_▼ base-benzene 'This paper scale - Zhongguanjia standard ((^A4 specification (10)χ297 (please read the note on the back and then fill out this page) --------Book --------- Line · 97 312991 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1290149 Λ7 Β7 5, invention description (98) and)-1-ink) (2,7-two desert-9-mercapto) wrong, bis(methanesulfonic acid) two Methyl decylalkyl (2,7-dimethyl-4,5-(2-methyl-benzo)-1 fluorenyl) (2,7-di-t-butoxy- 9-fluorenyl) Zirconium, bis(methanesulfonic acid) dimethylalkylene (2,7-dimethyl-4,5-(2). Methyl-benzo)-1 ·cobalt)(2,7-diphenyl-9-fluorenyl) cone, bis(methanesulfonic acid) dimethylalkylene (2,7-dimethyl-4) , 5-(2-methyl-benzo)-1, fluorenyl) (2,7-di-isopropyl-9-fluorenyl) zirconium, bis(methanesulfonic acid) dimethylalkylene group (2 ,7-Dimethyl-4,5-(2-methyl-benzo)-1-indenyl)(2J-dimethyl-9-diyl)zirconium, bis(methanesulfonic acid) dimethyl extension矽alkyl (2,7-dimethyl-4,5-(l-methyl-benzo)-1-indenyl) (2,7-di-t-butyl-9-fluorenyl)zirconium, double (Methanesulfonic acid) dimethylalkylene (2,7-dimethyl-4,5-(l-methyl-benzo)-1-indenyl) (2,7-di(trimethyldecane) Zirconium, bis(methanesulfonic acid) dimethylalkylene (2,7-dimethyl-4,5-(l-methyl-benzo)-1-indenyl) (2,7-dibromo-9-diyl)zirconium, bis(methicic acid) dimethyl acetal (2,7-dimethyl-4,5-(1-methyl-benzoquinone) -1-nodal) (2,7-di-t-butoxy-9-yl), bis(methanesulfonic acid) dimethylalkylene (2,7-dimethyl-4,5 -(l-methyl-benzo)-1-indenyl)(2,7-diphenyl-9-indenyl)zirconium, double (a Continuation of acid) Dimethyl decyl (2,7-dimethyl-4,5-(1-indolyl-benzo)-1·) (2,7-di-isopropyl-9)苐 ) )), bis(methanesulfonic acid) dimethyl decylalkyl (2,7-dimethyl-4,5-(l-methyl-benzoquinone)-1-pyryl) (2,7 -Dimethyl-9-diyl), dimethyl decyl chloride (2-methyl-4,5·benzo-1-indenyl) (2,7-two-division paper scale applicable China National Standard (CNS) A4 specification (210 x 297 mm) -------------------- Order --------- line (please read first Note on the back side of this page) 98 312991 1290149 V. Description of the invention (") -9-(4,5-stretching methylphenidyl)) chlorinated dimethyl hydrazine (2,6_ Dimethyl hydrazine. Benzo bromo-9-(4,5-methylphenanthrenyl)) zirconium, dimethyl chlorohydrin (2_? _4,5-benzo acetonyl) 7-di-second-butoxy-9-(4,5-methylphenanthrenyl)) cone, gasified dimethyl sylvestre (2,6 dimethyl-4,5-benzene) And small sprouts 7_-second butoxy-9-(4,5-methylphenanthrenyl)) zirconium, chlorinated dif-based exogenous group (2-f-based _4,5-benzopyrene 7-diphenyl-9-(4,5-methylphenanthrenyl) )) Zirconium, based on the basic group of 9-(4,5-methylphenanthrenyl)), di-n-based dibasic (2_methyl-4,5-benzopyrene (1)·2 -isopropyl-9-(4,5-methylphenanthrenyl)), di(n)-diyl (4)-based (2,6•dimethyl-4,5-benzo-small 7_1 -Isopropyl-9-(4,5·methylphenanthrenyl)), two = two f-groups (2,6n4,5m__(2,7_monomethyl-9_(4,5, for armor) Kifiji)) 鍅, = chlorinated two f-based stretching dream base (2, 7_ two? Base_4,5_(2^yl.benzo)b)(2,7-di(trimethyl residue)-9.(4,5-methylphenanthrenyl)), emulsified dimethyl矽alkyl (27_dif-based decyl) (2,7-dibromo-9-(4,5-methylphenylidene)), soil = dimethyl sulphate 2,7-Dimethyl_4,5_(2-methyl-phenylpyrazine) (2,7-di-t-butoxy_9_(4,5-methylphenylidene), l Two gasification base residue (2,7_H4τ *茏,7; paper scale suitable for the standard of the coffee (CNS) A4 specifications (2) G χ 297 public ρ---Tuben Kai)-1_ 2222 order line 99 312991 Description: (100): fluorenyl: (2,7-diphenyl _9_(4,5-extended f phenanthryl)) wrong, - weathered monomethyl decylalkyl (2,7 fluorenyl) ( 2 7 - 里品甘τ土 4,5 (2-methyl·phenyl opened)_1_ shirt, mono-isopropyl _9-(4,5-extension f phenanthryl)) zirconium, =7-based extension (2,7-di...yl-benzo)-1-",-mono-yl-9-(4,5-extension-f-phenanthryl)zirconium, ^:di/base-extension base (2, 7H4,5 servoylmethyl-benzo-H_ :) (,--second butyl _9-(4,5-extension)-based phenanthrenyl)), ::=2 ▼ (4)morphyl (2,7m5_ (1·methyl.benzo)] _(2,7-di(di) sulphate Ole, o-, 5-methylphenanthrenyl)), dimethyl, dimethyl (tetra), phenanthrene (2,7-dimethyl-45, thymidine, benzophenone) (2,7) -monobromo-9-(4,5-extended methylphenanthryl)) lead, two: dimethyl dimethyl benzoate (2,7-dimethyl '5-(" benzophenan)] (2,7-di-t-butoxy- 9-(4,5-extension)-based phenanthryl), dimethyl chloroformate (2,7-didecyl-45 benzyl) Benzene) + germination) (2,7-diphenyl_9_(4,5-methylphenylidene)), dimethyl dimethicone Benzo)diphenyl)(2,7-di-isopropyl-7-(4,5-methylphenanthrenyl)), dimethyldithiomethane (27 dimethyl _4,5 〇) Methylbenzo)]- fluorenyl) (2,7-dimethyl-9-(4,5-methylphenylidene)), dimethyl dialkyl sulphate (2_methyl _ 4,5_Benzyl acetonyl) (2,7_di_t-butyl-9-(4,5-methylphenylidene)), dimethyl dichloride (2_) Methyl-45_benzophenidyl) (2,7-bis(trimethyldecyl)-9-(4,5-methylphenanthrenyl))zirconium, i-dimethyldichloromethane Base (2,6-dimethyl-4,5-stupid and d•indenyl) (2 7 a paper scale for Zhongguan '豕 standard (CNS) A4 specifications (2) 7 χ _ _ _ _ 100 1J2991 Ministry of Economic Affairs Intellectual Property Bureau employees consumer cooperatives printed 1290149 A7 ____ B7 _ five, invention description ( 101) Di-tert-butyl-9-(4,5-extended f-phenanthryl)zirconium dichloride-based dialkyl-terminated alkyl group (2,6•di-f-yl-4,5-benzoindoleyl) (2, 'mono(dimethylmethylalkyl)-9-(4,5-extension)), dimethyl dialkyl (2,7-dimethyl <5 (2,7-di-t-butyl-9-(4,5-methylphenanthrenyl)) zirconium, dimethyl dialkyl sulfonate (2) ,7-Dimethyl-4,5-(2-methyl-benzoindoleyl)(2,7-bis(trimethyldecyl)_9_(4,5mmethylphenanthrenyl))zirconium, dichlorinated Dimethylmethyl (2-methyl-4,5-benzo-1β-decyl) (2,7-dibromo-9-fluorenyl), di-gasified dimethyl-methyl (2 ,6-dimethyl-4,5-benzopyridinyl 7-dibromo-9-diyl), di-gasified dimethyl-methyl (2-methyl-4,5-benzo) - mercapto) (2,7-di- 2 -butoxy-9-fluorenyl), dimethyl-methyl dichloride (2,6-dimethyl-4,5_ And Xiaomeng) (2,7-di-t-butoxy-9-diyl) zirconium, dimethyl methyl dichloride (2-methyl-4,5-benzopyrene) (2,7-diphenylfluorenyl), di-gasified dimethyl-methyl (2,6-dimethyl-4,5-benzoindenyl) (2,7-diphenyl-9) - mercapto), di-vaporized dimethyl-methyl (2-methyl-4,5-benzo-xiaoxian) (2,7-di-isopropyl-9-diyl), two gas Dimethylmethyl (2,6-dimethyl-4,5-stupidyl 7-di-isopropyl-9-diyl) zirconium, 'monomethyl-methylmethyl (2,6_Dimethyl_4,5_stupid and _1β) (2,7_ two paper scales apply to China National Standard (CNS) A4 specification (210x 297 public meals)'' ---- --- -------- Order --------- Line ^_HW. (Please read the note on the back and fill out this page) 101 312991 Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative 102 1290149 A7 __B7 V. INSTRUCTIONS (l〇2) Methyl-9-fluorenyl)zirconium, dimethylmethyl dichloride (2,7-dimethyl-4,5-(2-methyl) -benzo-3-enyl) (2,7-bis(trimethyldecyl)-9-yl)zirconium, dimethylmethyl dichloride (2,7-dimethyl-4) , 5- (2-methyl-benzo)-1-imyl) (2,7-dibromo-9-diyl)zirconium, dimethylmethyl dichloride (2,7-dimethyl-4, 5-(2-methyl-benzo)-phenanthrenyl) (2,7-di-t-butoxy-9-fluorenyl)zirconium, dimethylmethyl dichloride (2,7- Dimethyl-4,5-(2-methyl-benzo)-bromo)(2,7-diphenyl-9-fluorenyl)zirconium, di-gasified dimethyl-methyl (2, 7-Dimethyl-4,5-(2-methyl-benzo)-1-indenyl) (2,7-di-isopropyl-9-fluorenyl)zirconium, dimethylated dimethyl extension Methyl (2,7-dimethyl-4,5-(2-methyl-benzo)-1-indenyl) (2,7-dimethyl-9-fluorenyl)zirconium, dichloride Methyl stretch methyl (2,7-dimethyl-4,5-(1-methyl-benzo)-1-indenyl) (2,7-di-t-butyl-7-yl) Zirconium, di-vaporized dimethyl-methyl (2,7-dimethyl-4,5-(l-methyl-benzo)-1-indenyl) (2,7-di(trimethyldecane) Zirconium, 2-methylated dimethylmethyl (2,7-dimethyl-4,5-(l-methyl-benzo)-1-indenyl) (2, 7 - Erxi-9 -diyl) cone, dimethyl methyl dichloride (2,7-dimethyl-4,5-(l-methyl-benzo)-1-pyrene) 2,7-two-number Tributoxy-9-diyl)zirconium, dimethylmethyl dichloride (2,7·dimethyl-4,5-(l-methyl-benzo)-branches) (2 ,7·diphenyl-9-fluorenyl)zirconium, dimethylmethyl dichloride (2,7-dimethyl-4,5-(l-methyl-benzo)-1-pyrene The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 312991 -------------------- Order --------- line (Please read the notes on the back and fill out this page) 1290149

103 312991 1290149 V. Description of invention (Κ) 4 and broadly germinated) (2,7-two (three ▼ kekiji) _9_ 苐 base) wrong, I): Guang has: dilute two f base extension W (2, 6-dimethyl-dec-5-benzo-enyl) (2,7-dibromo-9-fluorenyl), diphenyl (tetra) chloride (2,7n4,5-m--second butyl _9·苐 base) lead, diphenyl decyl dialkyl (2 -筮_# f base _4,5_benzo-1-indenyl) (2,7---second butyl·9苐 ) ) ) 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Diphenyl phenyl dithioacetate (2'7-dimethyl-4,5-(2·yl-benzo)indolyl) (2,7-di-t-butyl-, fluorenyl) Zirconium, sodium diphenyl chloride (tetra) fluorenyl (2. methyl _45_benzoxanthyl) (2,7_two (two-base) dream base-9-di) wrong , methyl diphenyl phenyl decyl alkyl (2,6-dif-yl-45 benzo-hydrazino) (2,7-di-t-butyl-9-fluorenyl), two gasified Phenylphenylene alkyl (2,7-dimethyl-4,5-benzofluorenyl) (2,7-di-t-butyl-9-yl) zirconium, methylphenyl decane base (2,7-Dimethyl_4,5 gas 2_methyl_benzo> 1-indenyl) (2,7-di-t-butyl- 9-fluorenyl) zirconium Ethyl (2-methyl-7-trimethyldecyl- 4,5-benzo-1-fluorenyl) (2,7-di-t-butyl-9-fluorenyl) zirconium and dichloride Dimethylalkylene (2-methyl-7-trimethyldecyl-methyl-benzo)-1-indenyl) (2,7-di-t-butyl-9-diyl) zirconium . Compounds in which zirconium is replaced by titanium or hafnium may also be used. This paper scale applies to the Chinese National Standard (CNS;) A4 Specification Coffee x 297 Meals) 104 312991 1290149 A7 The transition metal compound shown below

V. DESCRIPTION OF THE INVENTION (10) Next, the formula (15) is described. (15) In the above formula, 'the transition metal atom selected from the group 3 to the first group of the periodic table' is preferably selected. The transition metal atom of Group 4 of the periodic table is more preferably zirconium, titanium or hafnium, and particularly preferably zirconium. R41 and R42 may be phased (5) or different and each has 1 to 4 (hydrocarbon group of a condensed carbon atom, a pendant hydrocarbon group having 1 to 40 carbon atoms, an oxy group, a sulfur-containing group, a thiol group, a ruthenium atom) Or a hydrogen atom. Examples of the hydrocarbon group having 1 to 40 carbon atoms include the same groups as described above for R" to R", Rl7 to R20 and R41 in the formula (13). Oxygen-containing, sulfur-containing group, ruthenium-containing group Examples of the group and the _ atom include the same groups and atoms as defined above for R25, R26, 尺27 and R28 in the formula (11). Among the groups represented by r4i and R42, a group adjacent to each other may be The carbon atoms bonded by the group are bonded together to form a ring. X1 and X2 may be the same or different and have the same meanings as X1 and X2 in the formula (14). Y1 has the same meaning as Y1 in the formula (11). An example of the transition metal compound shown includes exoethyl-bis(diyl)dimethylzirconium, ------------------------- ----· (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Office, Staff and Consumer Cooperatives, Printed Paper Size Applicable to China National Standard (CNS) A4 Specification (210 X 297 Meals) 105 3 12991 1290149

V. Description of invention (106)

In the above formula, M1 is selected from the group consisting of transition metal atoms selected from Group 4 of the periodic table, in particular, titanium, ruthenium or iridium, preferably a knot. RH, RB to R20, and R42 may be the same or different and each is a hydrocarbon group having 1 to 40 carbon atoms, an alkyl group having 1 to 40 carbon atoms, an oxy group, a sulfur-containing group, a thiol group, A halogen atom or a hydrogen atom. Examples of hydrocarbon groups having 1 to 40 carbon atoms include the above-mentioned related formula Ministry of Economic Affairs, Intellectual Property Office, Staff Consumption Cooperative, Printing Dimethylated Ethyl-bis(indenyl)zirconium, bis(trifluoromethanesulfonate) Zirconium (diyl) zirconium, bis(methanesulfonic acid)-extended ethyl-bis(indenyl)zirconium, di-gasified dimethyl-decylalkyl-bis(yl)-, bis(trifluoromethanesulfonic acid Dimethyl decyl alkyl _ bis (indenyl) zirconium, diphenyl decyl alkyl bis(indenyl) chloro, dimethyl methyl bis (indenyl) zirconium dichloride, two gas Dimethyl-methyl-bis(2,7-tert-butylfluorenyl)zirconium, di-vaporized dimethyl-decylalkyl-bis(2,7-tert-butylfluorenyl)zirconium, two gases Dimethyl-methyl-bis(3,6-t-butylphenyl) cone, di-vaporized dimethyl-decyl-bis(3,6-tert-butylfluorenyl)zirconium, and Emulsified N,N-diphenylamino oxy-oxo-bis(indenyl) cone. Next, the transition metal compound represented by the formula (16) will be described. \ /1 ••(16) This paper size applies to China National Standard (CNS) A4 specification (2 〗 0 X 297 mm) -------- order--------- line (please Read the notes on the back and fill out this page. 106 312991 1290149

V. INSTRUCTIONS INSTRUCTIONS W) The same group of R11 to R14, R17 to R20 and r41 are printed in the Consumer Information Agency of the Ministry of Economics and Finance. Examples of the oxygen-containing, sulfur-containing group, thiol group-containing and tooth atom include the same groups and atoms as defined above for R25, R26, R27 and r28 in the formula (11). Among the groups represented by RU, R12, R15, R", RP, RU, Rl9, 20 and R42, a group which is adjacent to each other may be combined with a carbon atom to which the groups are bonded to form a ring. X1 and X2 may be the same or different and have the same meaning as χ1 and π in the formula (u). Υ1 has the same meaning as Υ1 in the formula (11). Examples of the transition metal compound represented by the formula (16) include the aforementioned formula (11 a) or (1 lb) of the same compound exemplified as the compound. A compound in which the zirconium is replaced by titanium or ruthenium may be used. The above transition metal compound (A) may be used singly or in combination of two or more. The organoaluminum oxy-compound (B_1} used in the present invention may be a conventional aluminoxane or an organoaluminum oxy-compound which is insoluble in benzene as exemplified in Japanese Patent Laid-Open Publication No. 78687/199. Oxygen can be prepared, for example, by the following method, and is usually prepared as a solvent for a smoke solvent. (1) An organic compound (for example, a trialkyl group) is added to a compound containing adsorbed water or a salt containing water of crystallization. (for example, gasification town hydrate , copper sulphate hydrate, sulphate hydrate, nickel sulphate hydrate or chlorinated hydrates of hydrocarbons ^ _ ^ ^ ^ ^ ^ ^ ^ ^ This paper scale _1 _ siiT ^ s) A4 secret (2) ^ ^ I-day ice 107 312991 t---- (please read the note on the back and then fill out this page) — order --------- line - eliminate 108 1290149 a7 ^------ _ 5, invention description (l〇8) reaction. (2) in the medium (such as benzene, toluene, yoke or four gas blowing), so that water, ice or water vapor directly acts on organoaluminum compounds (such as trioxane) An aluminum) medium (for example, (iv), benzene or toluene) reacts with tin oxide O-methyltin oxide or dibutyltin oxide) with organoaluminum such as trialkylaluminum. The organic metal component. Furthermore, it is also possible to distill the solvent or the unreacted organic compound from the recovered solution of the oxygen 2 to dissolve the residue in the solvent. The example of the organoaluminum compound used for the preparation of the aluminoxane comprises Three-burning base, such as trimethylamine, triethylamine, tripropyl, tris, propyl, tri-n-butyl, triisobutyl, tri-butyl butyl Jiming, Sanji Jiming, Sanxinjiming and Sanming Jiming; tricycloalkyl aluminums such as tricyclohexyl aluminum and tricyclooctyl aluminum; and dialkyl-based indentations such as dimethyl chloride and chlorine Diethylaluminum bromide diethylaluminum bromide and diisobutylaluminum chloride; Tuming Erjijiming chloride 'such as deuterated diethyl ester and hydrogenated diisobutyl dialkylaluminum alkoxide, For example, f-oxidized di-f-ethylaluminum, and G-lactide, such as diethyl benzene oxide, wherein 'the preferred ones are trialkyl aluminums and tricycloalkyl aluminums. In addition, the examples of the organic compound used to prepare the oxime oxime are positive one 2x): The paper scale _ home fresh (cns) A4 --= call the 312991 ---------- ----------Book ------------ (Please read the phonetic on the back first? Please fill out this page again) 1290149

Isoprenyl aluminum. These organoaluminum compounds may be used singly or in combination of two or more. Examples of the solvent used for the preparation of the oxyalkylene include aromatic hydrocarbons such as benzene, toluene, xylene, cumene, and thyme; aliphatic hydrocarbons such as pentane, hexane, heptane, octane, decane, and ten Dioxane, hexadecane and octadecane alicyclic hydrocarbons such as cyclopentane, cyclohexane, cyclooctane and methylcyclopentane; petroleum fractions such as gasoline 'kerosene and gas oils; and these aromatics Deuterated products of aliphatic and alicyclic hydrocarbons (eg, their chlorinated or brominated products). Ethers such as diethyl ether and tetrahydrofuran can also be used. Among them, the most preferred ones are aromatic hydrocarbons. The organoaluminum oxy-compound used in the present invention is, for example, a boron-containing organoaluminum compound represented by the following formula (17): / R9

Re / R9 - 〇 - B - 0 - Al ------------ ijjl · ------- order (please read the note on the back and then fill out this page) Ministry of Economics intellectual property (17) wherein R8 is a hydrocarbon group having 1 to carbon atoms; and each R9 may be the same or different and is a hydrogen atom, a halogen atom or a hydrocarbon group having 1 to 1 carbon atom. (B-2) Ionized Separation + Antimonide The compound used in the present invention to react with a transition metal compound to form an ion pair (B-2) (hereinafter sometimes referred to as "ionized ionic compound") includes Louis. Acids, ionic compounds, borane compounds and carborane compounds, which are described in International Patent Publication Nos. 501950/1989 and 5 0203 6/1989, Japanese Patent Publication No. 179005/1991, 179006/1991, 207703/1991 And 207704/1991, and U.S. Patent No. 5,321,106. It is also possible to use heteroep〇iy compounds and homopolymerization (iSOp〇ly). This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 109 312991 line

V. INSTRUCTIONS OF THE INVENTION (110) Article 1290149 Examples of Lewis acid include a Lewis acid containing acid, an acid, and a boron-containing Lewis acid. Among them, a boron-containing Lewis acid-based Q ion compound is a salt composed of a cationic compound and an anionic compound. The anion reacts with the transition metal compound to render the transition metal compound cationic, thereby forming an ion pair and stabilizing the transition metal cation. Examples of such anions include an organoboron compound anion, an organic arsenide compound anion, and an organic compound anion. Preferred are relatively bulky and: transition metal cation stabilized. The Lewis acid containing a boron atom is, for example, a compound represented by the following formula (18): JLL · · · · · · · · · · · · · · · · · · · · · · · · · · · · · , phenyl groups which may be the same or different and each are a fluorine atom or may have a substituent (for example, a fluorine atom, a methyl group or a trifluoromethyl group). Examples of the compound represented by the formula (18) include trifluoroboron, triphenylboron, stilbene (4-fluorophenyl)boron, ginseng (3,5-difluorophenyl)boron, and stilbene (4-fluoromethylphenyl). Boron, ginseng (pentafluorophenyl) boron, ginseng (p-tolyl) boron, ginseng (o-tolyl) boron, ginseng (3,5-dimethylphenyl) boron and ginseng [3,5-di (three) Fluoromethylphenyl)]boron. Among them, the preferred one is quinone (pentafluorophenyl) boron. The ionic compound is a salt composed of a cationic compound and an anionic compound. The anion reacts with the above transition metal compound to cationize it to form an ion pair having a function of stabilizing the transition metal cation. Examples of such anions include an organoboron compound anion, an organic quinone compound anion, and an organic 18 compound anion' which are relatively large and stable to the paper size applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 metric meals) — 312991 --------BOOK--------- (Please read the note on the back? Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 110 1290149 A7 V. DESCRIPTION OF THE INVENTION (111) Transition metal cations. Cationic cations, carbon gun cations, ruthenium organometallics - s_m) cations, weaving =: °PyliUm), squamous cations and ammonium cations, and pings; bis-based cations, tri- and methylammonium cations and aromatics Cycloallenyl cation. Sub, n, n-two, among the anions of the Ministry of Economic Affairs, the Intellectual Property Bureau, the employee consumption cooperative, the anion of the boron-containing compound is an anion ionized trialkyl substituted ammonium salt. Boron triethyl (phenyl) boron tripropyl recording, tetrakis (phenyl) boron tri(n-butyl) ammonium: tetrayl) collar trimethyl record, tetra (o-tolyl) butterfly trimethyl money four Tributylammonium, tetrakis (o-butyl dimethylphenyl (tetra)tripropyl, tetra-methylphenyl) boron dibutylammonium, tetrakis (p-trifluoromethylphenyl) boron tributylammonium , tetrakis(o-tolyl)boron tri(n-butyl)ammonium and tetrakis(4-fluorophenyl)boron:aluminum)ammonium. Examples of ruthenium, osmium-dialkylanilinium salts include tetrakis(phenyl)boron ν, ν-dimethylanilinium, tetrakis(phenyl)boronium, Ν:ethylammonium and tetrakis(phenyl)boron Ν, Ν_2, 4 6_ pentamethylanilinium. Examples of the 5-dialkylammonium salt include tetrakis(pentafluorophenyl)boronium di(n-propyl)m and tetrakis(phenyl)boronium dicyclohexylammonium. Examples of the triaryl scale salt include tetrakis(phenyl)boron triphenyl scale, tetrakis(phenyl)boron tri(methylphenyl) scale, and tetrakis(phenyl)boron tris(dimethylphenyl) scale. Further used boron-containing ionic compounds are triphenylcarbene oxime (pentafluorophenyl)borate, ruthenium (pentafluorophenyl) borate, bismuth-dimethylanilinium, tetrakis(pentafluorophenyl)borate Cycloalkenyl, pentaphenylcyclopentadienyltriphenylcarbenium oxime complex This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) ---------- ---# (Please read the note on the back and fill out this page again) Order---------Line· 111 312991 1290149 V. Description of invention (112 substance, pentaphenylcyclopentadienyl N, N_diethylbenzene complex and boron compound of formula (4) or (20)··cf3 H@(〇Et2)2 ® N? Θ CF, ...(19) ...(20) - The ionic compound having a butterfly atom used in the step is the following compound (in the following ionic compound t, the anti-sub is a tri(n-butyl) group, but is not limited thereto.) An example of an anion-containing salt includes nine Bis[tri(n-butyl)ammonium borate, bis[tri(n-butyl)ammonium borate], bis[tri(n-butyl)ammonium undobauate, bis[tri(n-butyl) dodecanoate Ammonium], bis(n-butyl)ammonium ], bis[tri(n-butyl)ammonium dodecyldodecanoate, tri(n-butyl)ammonium 1-carbon decanoate, tri(n-butyl)ammonium 1-carbon borate, cadobium dodecanoic acid Tris(n-butyl)ammonium, tris(n-butyl)ammonium bromide-1-carboborate and tri(n-butyl)ammonium bromide-1-carboborate. Examples of the borane complex compound and the salt of the carborane anion include 1 paper size i suitable for wealth _ home standard ^ s) A4 size (2) Q χ 297 liters) 112 set line 312991 1290149 five, invention description (m ten boron (14), 7,8-dicarboracaborane 〇3), 2,7_two carbon eleventh marry (13), eleven argon-7,8-diindenyl-7,8_two carbon Eloborane, dodecahydrogen _] methyl-2,7-dicarbocylborane, 6-carbon decanoic acid (14) tri(n-butyl)ammonium, & carbon pentaborate (12) three (positive Butyl)ammonium, carbon undecanoic acid (13) tri(n-butyl)ammonium, 7,8-dioctadecanoic acid (12) tri(n-butyl)ammonium, 2,9•dicarbocate 12) Tris(n-butyl)ammonium, dodecahydro-8-methyl-7,2-di-n-butylammonium tris(n-butyl)ammonium, undecahydro-8-ethyl-7,9- Tris(n-butyl)ammonium octadecanoate, tris(n-butyl)ammonium 7,9-9-undecolate, eleven -8-allyl-7, Tris(n-butyl)ammonium 9-dicarbanodecanoate, tris(n-butyl)ammonium undecahydro-9-trimethyldecyl-7,8-dicarbocate, and undecahydro-4 6-Dibromo-7-carbonundecanoic acid tri(n-butyl)ammonium. Examples of the linear carborane-containing compound and the carborane-containing salt include 4-carbon nonaborane (14), 1,3-dicarbaborane (13), and 6,9-dicarba-borane (14). , eleven wind-l-phenyl-1,3-carbo-deuterium, dodecahydro-1-methyl> dicarbaborane and undecahydro-1,3-dimethyldicarbon Borane. The ionic compounds containing side atoms which can be further used are the following metal carborane salts and metal borane anions. (In the following ionic compounds, the counter ion is tri(n-butyl)ammonium, but not limited to this.) The user can be bis(noni-1,3-dicarbon 9 boroborate) cobalt (III) acid III. (n-butyl)ammonium, bis(undecyl-7,8·dicarbocate)iron (III) acid tri(n-j-yl)ammonium, bis(undecyl-7,8-dicarbon eleven) Boric acid) tris(n-butyl)ammonium citrate, bis(undecyl-7,8·dicarbocate)nicka(III) acid tri(n-butyl)ammonium, bis(undecyl-hydrogen- 7,8-dioctadecanoic acid) copper (III) acid tri(n-butyl) ammonium, this paper scale is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 113 312991 A7

V. Description of invention (U4) 1290149 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing clothing 114 bis (undecyl dicarbocate) gold (ΠΙ) acid tri(n-butyl) ammonium, bis (nonahydro-7 , 8-dimethyl-7,8-dioctadecanoic acid) tri(n-butyl)ammonium iron, bis(9虱8,8-dimethyl-7,8-dicarbon ten Monoacid) chromium (Η!) acid tri(n-butyl)ammonium, bis(tribromotetrahydro-7,8-dicarbocate)cobalt(ΠΙ) acid tri(n-butyl)ammonium, double ( Dodecahydrododecaborate)cobalt(III) acid tri(n-butyl)m, bis(tudecandecylborate)nickel(III) acid tri(n-butyl)ammonium, bis(undecyl-hydrogen- 7-carbon undecanoic acid) chromium (III) acid ginseng [tri(n-butyl) money], bis(undecyl-7-carbonundecanoic acid) cerium (IV) acid bis[tri(n-butyl) money ], bis(undecyl-7-carbonundecanoic acid)cobalt(III) acid bis[tri(n-butyl)ammonium] and bis(undecin-7_carbonundecanoic acid)nickel (IV) acid double [three (n-butyl) money]. Further examples of the ionic compound containing a boron atom include the following compounds such as ruthenium [(2,3,5,6-tetrafluoro-4-triisopropylcarbazide)phenyl]boronic acid triphenylcarbene gun, ruthenium [(2,3,5,6-tetraki-4-diisopropyl chopping group) phenyl] column acid-dimethylbenzyl ammonium, hydrazine [(2,3,5,6-tetrafluoro-4) -Dimethyl-t-butyldecyl)phenyl]boronic acid tris- carbene gun, 肆[(2,3,5,6-tetrafluoro-4-dimethyl-t-butyldecyl) Phenyl] bismuth borate, bismuth-dimethylanilinium, bis(octafluorophenyl)phenyl triphenyl carbene bismuth, bis(octafluoroexetylene) bismuth borate, bismuth dimethyl benzyl ammonium , This paper scale applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 312991 --------^---------^ ^9. (Please read the back of the note first) Please fill in this page again) A7 1290149 ___B7 "~------------- V. Description of invention (115) Bis(octafluoro-1,1,r)boronol (biboronol) III Phenyl carbene gun and bis(octafluorospiro)difluoroboranol N,N-dimethylanilinium. The heteropoly compound consists of one or more atoms selected from the group consisting of cerium, lanthanum, titanium, lanthanum, god or tin and one selected from the group consisting of hunger, bismuth, molybdenum and tungsten. Examples of such compounds include phosphonium, bismuth vanadate, arsenic vanadate, phosphonic acid, citric acid, tartaric acid, molybdenum acid, titanium molybdate, lanthanum molybdate, arsenic molybdate, tin molybdate , taurine, barbituric acid, tungstic acid, phosphomolybdic acid, phosphotungstic acid, strontium tungstate, strontium tungstate, strontium molybdenum, acid, uranium, acid Salts of such acids, in particular, such as salts of such acids with metals of Group 1 or 2 of the Periodic Table, such as lithium, sodium, potassium, rubidium, cesium, cesium, magnesium, calcium, strontium and barium, and their acids Organic salts such as triphenylethyl salt. The plasmad ionic compound may be used singly or in combination of two or more. (B-3) Organoaluminum compound The organoaluminum compound (B_3) used in the present invention can be represented by the following formula (21):

RanAlX3.n (21) wherein Ra is a hydrocarbon group having 1 to 12 carbon atoms, hydrazine is a halogen atom or a hydrogen atom, and η is 1 to 3. In the above formula (21), V is a hydrocarbon group having from 1 to 12 carbon atoms, for example, an alkyl group, a cycloalkyl group or an aryl group. Examples thereof include methyl, ethyl, n-propyl, isopropyl, isobutyl, pentyl, hexyl, octyl, cyclopentyl, cyclohexyl, phenyl and tolyl groups. Examples of organic compounds include tri-sodium bases such as tri-y-aluminum, triethylaluminum, triisopropylaluminum, and this paper scale applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm)~ *- 312991 --------------------- Order -------- line "till (please read the notes on the back and fill out this page) Intellectual Property Bureau employees consumption cooperatives prints the remaining clothes 115 ethyl aluminum chloride 1290149 five, invention description (116) triisobutyl aluminum, trioctyl aluminum and tris-2-ethylhexyl aluminum; women's base 'such as isopren Dialkylene; 〃二院基(四)化' such as dimethyl chloride, gasified diethyl, emulsified monoisopropylaluminum, diisobutylaluminum chloride and dimethylaluminum bromide;乙明倍半_化, such as sesqui-halogenated methyl ester, sesquichloride ethyl, isopropyl sesquichloride, sesquichloride and sesquiterpene ethyl aluminum; A bidentate such as di-aluminum f-aluminum di-aluminum isopropylaluminum and ethylaluminum dibromide; and a ruthenium hydride such as diethyl hydride and diisopropylaluminum hydride. The organoaluminum compound (B-3) can also be represented by the following formula (22):

RanAlY3.n (22) where Ra is as described above, and γ is a —ORb group, a _〇SiRc3 group, a _〇AlRd2*, a —NRe2 group, a —SiRf3 group or a —N(Rg)A1Rh2 group, and n is 1 To 2, Rb, RC, R and Rh are each methyl, ethyl, isopropyl, isobutylcyclohexyl and benzene

Further, Re is hydrogen, methyl, ethyl, isopropyl, phenyl and trimethyl, and R and Rg are each a methyl group and an ethyl group. Examples of the organoaluminum compound include a compound represented by the formula (i) RanAl(〇Rb)sn such as dimethylaluminum methoxide, diethylaluminum ethoxide and diisobutylaluminum oxylate; (η)RanAl (OSiRc3) ) compounds represented by 3_n such as (C2H5)2Ai (〇si (CH3)3), (iso-C4Hg)2Al (OSi(CH3)3) and (iso-C4H0), Al (Osi) This paper scale applies to Chinese national standards (CNS) A4 size (210 x 297 mm) 312991 t------ Order---------Line _ (Please read the note on the back and fill out this page) Employees' Consumption Cooperatives Printed 116 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed 1290149 A7 --- ____ V. Inventions (117 ) (C2H5) 3); (iii) Compounds of the formula RanAl(OAlRd2)3_n (C2H5)2A1(〇al(C2H5)2) and (iso-C4H9)2A1(0A1(iso-C4H9)2); (iv) a compound of the formula RanAl(NRe2)3_n such as (CH3)2A1(n ( C2h5)2), (c2h5)2ai(nh(ch3)), (ch3)2ai(nh(c2h5)), (C2H5)2Al[N(Si(CH3)3)2] and (iso-C4H9)2Al[ N(Si(CH3)3)2]; and (v) a compound of the formula RanAl(SiRf3)3-n, for example, (iso(CH3)3). In the present invention, among them, an organic compound represented by Ra3Al, RanAl(〇Rb)3 n and R nAl(OAlR ι)3_η is preferable, and a compound of the formula wherein n is an isothermal group and η = 2 is particularly preferable. The organoaluminum compound may be used in combination of two or more. The olefin polymerization catalyst used in the present invention comprises a transition metal compound and at least one compound selected from the group consisting of an organoaluminum oxy-compound (Β-1), an ionized ionic compound (Β-2), and an organoaluminum compound (Β-3). For example, in the case where the transition metal compound (Α) contains a cyclopentadienyl skeleton ligand, the catalyst includes the compound (Α) and an organoaluminum oxy compound (Β_1} and/or an ionized ionic compound (Β) -2), and if desired, an organoaluminum compound (Β_3). The olefin polymerization catalyst used in the present invention may be a solid catalyst, wherein the transition metal compound (Α) and an organoaluminum oxy-compound (Β_1}, ionized At least one component of the ionic compound (Β-2) and the organoaluminum compound (Β-3) is supported on the particulate carrier, or is prepared by prepolymerization, including a particulate carrier, a transition metal compound (Α), and an organoaluminum. Oxygen compounds (B_iK or ionized ionic compounds (B-2)), olefin polymers, and, if necessary, organic paper scales applicable to China National Standard (CNS) A4 specifications (2) 297 297 metric meals) 312991 --- -----^---------^ ^9. (Please read the notes on the back and fill out this page) 117 Ministry of Economic Affairs Intellectual Property Bureau Consumer Cooperative Printed 118 1290149 A7 ___B7_ V. Invention Description (118) Pretreatment of aluminum compound (B-3) The catalyst carrier used in the solid catalyst and the prepolymerization catalyst is inorganic or organic in the form of particles or particulate solids (having a particle diameter of 10 to 300 // m, preferably 20 to 200 " m) Preferred examples of the inorganic carrier are porous oxides, inorganic chlorides, clays, clay minerals, and ion-exchange layered compounds. Examples of porous oxides include SiO 2 , Al 2 〇 3 , MgO, ZrO, TiO 2 , and B 2 〇 3. CaO, ZnO, BaO, Th02, and mixtures containing such oxides, for example

Si02-Mg0, SiO 2 -Al 203, SiO 2 -Ti 〇 2, SiO 2 -V 205, SiO 2 -Cr 203 and SiO 2 -Ti02-Mg0. Among them, preferred are compounds containing si02 and/or Al2〇3 as main components. The inorganic oxide may contain a small amount of carbonate, sulfate, nitrate and oxide components, such as Na2C03, K2C03, CaC03, MgC03, Na2S04, A12(S04)3, BaS04, KN03, Mg(N03)2, Al(N〇 3) 3, Na20, K20 and Li20 〇 particulate carrier properties vary depending on the type and process, but preferably have a specific surface area of 50 to 1,000 m2 / g, preferably 1 to 700 m2 / g, and Pore volume of 0.3 to 2.5 cm3/g. If necessary, the particulate carrier may be calcined at 100 to 15000 ° C., preferably 150 to 7 Torr (TC). Further, the particulate carrier is, for example, a particle size of 1 to 3 Å. a particulate or particulate solid organic compound of m. Examples of such organic compounds include the use of an olefin having 2 to 14 carbon atoms such as ethylene, propylene-1-butene or 4-methyl-1-pentene as a main component. The (co)polymer or the use of vinylcyclohexane or styrene as the main component (to) a total of 312991 -------------------- --------- Line 1^· (Please read the notes on the back and fill out this page)

V. Description of the invention (119) 1290149. Examples of the inorganic vapor used in the present invention include MgCl2, MgBr2, MnC2 and MnBh. These inorganic chlorides may be used as such or may be used after being pulverized by, for example, a ball mill or a vibrating mill. The inorganic gasification material may also be used in the form of fine particles obtained by dissolving an inorganic chloride in a solvent (e.g., an alcohol) and then precipitating it with a precipitating agent. Clay is usually composed mainly of clay minerals. The ion exchange layered compound is a compound having a crystal structure in which planes formed by ionic bonding or the like are laminated in parallel with each other with weak bond strength, and ions contained therein are exchangeable. Most clay minerals are ion exchange layered compounds. The clay, clay rattan and ion exchange layered compound used in the present invention are not limited to naturally occurring but include a synth. Examples of such clays, clay minerals, and ion exchange layered compounds include clays, clay minerals, and ion exchange layered compounds having, for example, hexagonal closest packing type, yttrium type, CdCl2 type, and Cdl2 type crystal structure. Specific examples of clay and clay minerals include clay, bentonite, organic carbon clay, frog clay, gibbsite, stellite, pyrophyllite, mica montmorillonite, vermiculite, chlorite, sloping Stone, kaolin, pearl clay, dickite and halloysite. Specific examples of the ion exchange layered compound include crystalline salts of polyvalent metals, such as a_Zr (HAS〇4>2.H2〇, a-Zr(HP04)2 > a -Zr(KP04)2 · 3H2〇. a -Ti(HP〇4)2 . a ^ Ti(HAs04)2 · H20 ^ a -Sn(HP04)2 · H2〇^ γ -Zr(HP04)2 r -Ti(HP〇4)2 and r _Ti (NH4P04)2 · H2〇. Clay, clay minerals and ionic parent-formed compoundes preferably have a benefit of 312991 -------------i ------- ------Line (please read the note on the back of the note and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative print 119 1290149

When the pores having a radius of not less than 2 〇A are measured by the mercury infiltration method, the pore volume is not less than ο ce/$; and particularly preferably the pore volume having 0 to 5 cc/g. The pore volume is measured using a mercury porosimeter using a mercury infiltration method for pores having a radius of 20 to 3 x 1 〇 4A. When a pore having a measured radius of not less than 20 A is used, and a compound having a pore volume of less than 0 j cc / g is used as a carrier, there is a tendency that it is difficult to obtain high polymerization activity. Preferably, the clay and clay minerals are also chemically treated. Any surface treatment can be used, for example, to remove impurities attached to the surface and to affect the crystal structure of the clay. Examples of such chemical treatments include acid treatment, inspection treatment, salt treatment, and organic matter treatment. The acid treatment not only helps to remove impurities from the surface, but also dissolves the cations (e.g., A and Fe) present in the crystal structure to increase the surface area. Alkali treatment destroys the crystalline structure of the clay and changes the structure of the clay. Alkali treatment and organic material treatment can produce, for example, an ionic composition, a molecular composition, or an organic derivative, while changing the surface area or the distance between the layers. The ion exchange layered compound may be a layered compound in which the exchangeable ions between the layers have been exchanged with other large and bulky ions by ion exchange properties to increase the distance between the layers. The bulking ions act like pillars to support the layered structure, often referred to as the "pillar." The introduction of other substances between the layers of the layered compound and the layer is called "inclusion reaction". Examples of the foreign compound to be contained include cationic inorganic compounds such as Tici4 and ZrCl4; metal oxide oxides such as Ti(OR)4, Zr(〇R)4, p〇(qr)3, and the paper scale are applicable to the Chinese national standard. (CNS) A4 size (210 χ 297 mm) 312991 I-------t (please read the phonetic note on the back? Please fill out this page again) — order --------- line · economy Ministry of Intellectual Property Bureau employee consumption cooperative printing 120 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 121 1290149 Δ7 ----- Β7____ V. Description of invention (m) B(〇R)3 (R is a hydrocarbon group, etc.); Metal hydroxide ions such as [A1i3〇4(〇H)24]7+, [Zr4(〇H)14]2+ and [Fe30(0C0CH3)6r. The above compounds may be used singly or in combination of two or more. The inclusion reaction of the compounds may be in the presence of a polymer obtained by hydrolysis of a metal alkoxide such as Si(〇R)4, Al(〇R)3, and Ge(OR)4 (R is a hydrocarbon group, etc.) or It is carried out in the presence of a colloidal inorganic compound such as Si〇2. Examples of the support include an oxide which is obtained by dehydration using a metal hydroxide ion intercalation reaction between the above layers. The above clay, clay mineral and ion exchange layered compound may be used as such or may be used after ball milling, sieving, and the like. In addition, they can also be used after water adsorption or heat dehydration treatment. The clay, the clay mineral, and the ion exchange layered compound may be used singly or in combination of two or more. Among the above, clay and clay minerals are preferred, and montmorillonite, vermiculite, hectorite, mica and synthetic mica are preferred. The olefin polymerization catalyst used in the present invention may contain the following organic hydrazine compound (c) and/or the following dicalcium zinc compound (D). (C) Organic ruthenium compound The organic ruthenium compound (C) used as needed is represented by the following formula (22): R'R^'SiH (22) where R1, ^ with R3 may be the same or different and each is a hydrogen atom, a carbon atom-based alkyl group (such as methyl, ethyl, propyl, isopropyl, butyl isobutyl or tert-butyl), with 6 to Aryl group of 12 carbon atoms (for example, laughing at 312991 --------^---------^ ^9. (Please read the notes on the back and fill out this page) Property Bureau Staff Consumer Cooperatives Printed 122 1290149 Λ7 B7 V. Inventive Note (122) or tolyl), alkaryl having 7 to 20 carbon atoms (eg ethylphenyl or ethyltolyl), with 7 to An aryl group of 20 carbon atoms (for example, phenylethyl or benzyl), an alkoxy group having 1 to 4 carbon atoms (for example, methoxy, ethoxy, propoxy or butoxy), a gasified alkyl group having 3 to 6 carbon atoms (for example, 3,3,3-trifluoropropyl), a dialkylamino group having an alkyl group having 1 to 4 carbon atoms (for example, dimethylamino group) ), or containing 1 to 10 oxime-oxygen units and R63Si0(SiR620)n-(R6 is methyl, phenyl, 3,3,3-trifluoropropyl, methoxy or ethoxy, η The diorganopolyoxyalkylene chain is represented by an integer from 0 to 9. Wherein 'preferably a hydrogen atom, a methyl group, an ethyl group, an isopropyl group, an isobutyl group, a 3,3,3-trifluoropropyl group, a dimethylamino group or a R63Si〇(siR62〇)n- Group. Preferred examples of the organic ruthenium compound represented by the formula (22) include phenyl decane, diphenyl sulphur, phenylmethyl sinter, pentamethyl oxime, methyl sulphur, and dimethyl Decane. The above organoindole compounds may be used singly or in combination of two or more. (D) Dialkyl zinc compound The dialkyl compound (D) used as needed is represented by the following formula (23):

ZnR4R5 (23) wherein R4 and R5 may be the same or different and each is an alkyl group having 1 to 2 carbon atoms, such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, Tributyl, hexyl, octyl, decyl, decyl, dodecyl or eicosyl. Wherein ' is preferably an alkyl group having 1 to 12 carbon atoms, more preferably an alkyl group having 1 to 6 carbon atoms. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public) 312991 -------------------- Order --------- Line (please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 123 1290149 Λ7 _ _ Β7 V. Invention Description (I23) Formula II (23) Preferred examples include diethyl zinc, diisobutyl zinc, and di-n-decyl zinc. Among them, diethyl zinc is particularly preferred. The above-mentioned dialkyl compound (D) may be used singly or in combination of two or more. Each of the organic compound (C) and the dialkyl compound (d) may be combined with hydrogen and used as a chain transfer agent. When the organic hydrazine compound (C) is used as a chain transfer agent, an olefin compound having a terminal decyl group is obtained. Examples of the α-fluorene hydrocarbon having 2 to 20 carbon atoms include ethylene, propylene, 1-butene, 2-butene, 1-pentene, 3-methyl-1-butene, [_hexene, 4_Methyl-1-pentene, 3-methyl-1-pentene, 3-ethyl-1-pentene, 4,4,-dimethyl-1-pentyl, 4-methyl-1- Rust, 4,4-dimethyl-1-hexene, 4-ethyl-1-hexene, 3-ethyl-1-hexene, 1-octyl, 1-indole, 1-dodecene , ι_tetradecene, 1-hexadecene, 1-octadecene and 1-tine. Among them, α-olefins selected from the group consisting of ethylene, propylene, butene, 4-methyl-1-pentene, 1-hexene and i-octene are preferred. Next, the polar group-containing monomer represented by the formula (7) will be described in detail below.

CH2=CH

Wherein R3, R4, r, X and p have the same meanings of r3, R4, r, X and P in the formula (3), respectively. Examples of the polar group-containing monomer include: a compound of the formula (7) wherein X is an alcoholic hydroxyl group, in particular, an ω-alkenyl alcohol, for example, the paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991 -·ϋ ^1 .1 ϋ l^i ϋ ϋ n .1 ·ϋ ϋ ·ϋ 1 ϋ ·1-1 nn ϋ 1^ 11 ·*1· ϋ IH ϋ n I ι (please Read the precautions on the back and fill out this page.) 1290149 Λ7 Β7 5. Inventive Note (124) Allyl alcohol, 4-penten-1-ol, 5-hexen-1-ol, 6-hepten-1-ol , 7-octen-1-ol, 8-decen-1-ol, 9-nonen-1-ol, (Please read the back of the note before you fill out this page) 10-undecen-1-ol And 11-dodecen-1-ol; alcohols having a linear hydrocarbon group, such as 5-hexacene-2-frying, 6-hepta-2-ol, 7-octane-2-drunk, 8-inch Dilute _2-fresh, 9-decene-2-ol, 10-undecen-2-ol, 6-hepten-3-ol, 7-octene-3-ol, 8-anthracene-3 Alcohol, 9-indole-3-ol, 10-11-dish-3-ol, 11-dip-1,3-ol, 7-octyl-4-solution, 8-decyl-4-solution, 9 - 癸--4-drunk, 10-undecen-4-ol, 8-decene-5-ol, 9-nonene-5-ol and 10-undecene-5 - an alcohol; an alcohol having a branched hydrocarbon group, such as 2-ethyl-5-hexan-1-ol, 3-methyl-6-heptac-1-ol, 3-methyl-7-octene- 1-alcohol, 4-methyl-8-nonen-1-ol, 3·ethyl-9-fluoren-1-ol, 2-methyl-1 0-undec-2-ol, 2, 2-Dimethyl-7-octyl-1-ol, 3-ethyl-2-methyl-8-indole-1-ol, 2,2,3-trimethyl-9-nonene-1 -Alcohol and 2,3,3,4-tetramethyl-10-undecene-2·ol; Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing diols such as 9-pinene-1,2-two Alcohol, 10-undecene-1,2-diol and 11-decadiene-1,2-diol; and triols such as 10-undecene-1,2,3-triol; A compound of the formula (7) wherein X is a carboxylic acid group, in particular an ω-alkenyl carboxylic acid such as 3-butenoic acid, 5-hexanoic acid, 6-glycidic acid, 7-octanoic acid, 8-壬 dilute acid, the paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 124 312991 1290149 Α7 Β7 V. Description of invention (125) 9-decenoic acid, 10-undecenoic acid and 11- Decadienoic acid; (Please read the notes on the back and fill out this page) Alkenyl carboxylic acids with linear hydrocarbon groups, for example 2-methyl-5-hexenoic acid, 2-methyl-6-heptenoic acid, 2-methyl-7-octenoic acid, 2-methyl-8-decenoic acid, 2-methyl-9 -decenoic acid, 2-methyl-10-undecenoic acid, 2-methyl-11-dodecenoic acid, 2-ethyl-5-hexenoic acid, 2-ethyl-6-heptenoic acid , 2-ethyl-7-octenoic acid, 2-ethyl-8-decenoic acid, 2-ethyl-9-decenoic acid, 2-ethyl-10-undecenoic acid, 2-propyl -5-hexenoic acid, 2-propyl-6-heptanoic acid, 2-propyl-7-octenoic acid, 2-propyl-8-decenoic acid, 2-propyl-9-decenoic acid , 2-propyl-10-undecenoic acid, 2-butyl-5-hexanoic acid, 2-butyl-6-heptenoic acid, 2-butyl-7-octenoic acid, 2-butyl -8-decenoic acid, 2-butyl-9-decenoic acid and 2-butyl-10-undecenoic acid; and alkenyl carboxylic acids having a branched hydrocarbon group, such as 2-isopropyl-5- Hexenoic acid, 2-isopropyl-6-heptenoic acid, 2-isopropyl-7-octenoic acid, 2-isopropyl-8-decenoic acid, 2-isopropyl-9-decene Acid, 2-isopropyl-10-undecenoic acid, 2-isobutyl-5-hexenoic acid, 2-tert-butyl-6-heptenoic acid, 2-isopropyl-3-methyl -7 - Diacid, 2-methyl-3-isopropyl-8-indole acid, Ministry of Economic Affairs, Intellectual Property Office staff consumption Co-produced 3-isobutyl-3-methyl-9-decenoic acid, 2,2-dimethyl-10-undecenoic acid and 2,3,3-trimethyl-11-twelve a dilute acid; a compound of the formula (7) wherein X is a carboxylate group, in particular an ω-smelt carboxylate such as methyl 3-butenoate, methyl 5-hexenoate, 6-g Methyl enoate, methyl 7-octenoate, methyl 8-decenoate, methyl 9-decenoate, methyl ketone 10-11, methyl 11-dodecanoate, 5-hexyl Ethyl citrate, this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 125 312991 A7 1290149 B7_ V. Description of invention (l26) 6-Heptenoic acid ethyl ester, 7-octenoic acid B Ester, ethyl 8-decenoate, ethyl 9-decenoate, ethyl 10-undecanoate, ethyl 11-dodecanoate, isopropyl 5-hexenoate, 6-heptenoic acid Isopropyl ester, isopropyl 7-octenoate, isopropyl 8-decenoate, isopropyl 9-decenoate, isopropyl 10-undecenoate, isopropyl 11-dodecenoate , butyl 5-hexenoate, butyl 6-heptenoate, butyl 7-octenoate, butyl 8-decenoate, butyl 9-decenoate, butyl 10-decanoate, 11-dodecenoic acid butyl ester, 5-hexenoic acid pentane Ester, 6-heptenoic acid amyl ester, 7-octenoic acid amyl ester, 8-decenoic acid amyl ester, 9-decenoic acid amyl ester, 10-undecenoic acid amyl ester and 11-dodecenoic acid pentane Ester; an alkenyl carboxylate having a linear hydrocarbon group, such as methyl 2-methyl-5-hexenoate, methyl 2-methyl-6-glyoxylate, 2-methyl-7-octene Ethyl acetate, methyl 2-methyl-8-decenoate, butyl 2-methyl-9-decenoate, ethyl 2-methyl-10-undecenoate, 2-ethyl·5 - butyl hexenoate, ethyl 2-ethyl-6-heptenoate, isopropyl 2-ethyl-7-octenoate, ethyl 2-ethyl-8-decenoate, 2-B Methyl-9-decenoate, ethyl 2-ethyl-1〇-undecenoate, methyl 2-propyl-5-hexenoate, methyl 2-propyl-6-heptenoate , 2-propyl-7-octenoate ethyl ester, 2-propyl-9-decenoic acid methyl ester, 2-propyl-10-undecenoate ethyl ester, 2-butyl-7-octene Methyl ester, methyl 2-butyl-8-decenoate, methyl 2-butyl-9-decenoate and methyl 2-butyl-10-undecenoate; and having a branched hydrocarbon group Alkenyl carboxylates such as butyl 2-isopropyl-5-hexenoate, ethyl 2-isopropyl-6-heptenoate, methyl 2-isopropyl-7-octenoate, 2-isopropyl-8-oxime Methyl ester, this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 11 II —--------^--------- (Please read the back Note: Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 126 312991 A7 1290149 ~~--~ ____ V. Invention description (127) ~ 2-isopropyl-9-decenoic acid vinegar, 2 _Isopropyl_1〇-undecenoic acid A, 2·isobutyl-5-hexenoic acid methyl ester, 2-tert-butylheptenoic acid methyl ester, 2-isopropyl-3-methyl- 7-succinic acid ethyl vinegar and 3-isobutyl-3-methyl-9-indole propyl ester; a compound of the formula (7) wherein X is an acid anhydride group, for example, (2,7-octadienyl) The succinic anhydride, pentapropenylsuccinyl anhydride, and the oxime of the above formula are compounds in which the carboxylic acid group is replaced by a carboxylic anhydride group in the carboxylic acid group, wherein the compound of the formula (7) wherein X is an amine group, Omega-alkenylamines, such as allylamine, % hexenylamine, 6-heptenylamine, 7-octenylamine, 8-decenylamine, 9-nonenylamine, 1 〇_undeamine 11-dodecenylamine; alkenylamines having a linear hydrocarbon group, such as 2-methyl-5-hexenylamine, 2-methyl-6-heptenylamine, 2_ Methyl-7-octylamine, 2-methyl-8-nonenylamine, 2-methyl-9-nonenylamine, methyl 4 〇_undeamine, 2-methyl-11-twelve Enamine, 2-ethyl-5-hexenamine, 2-ethyl-6-heptenylamine, 2-ethyl-7-octeneamine, 2-ethyl-8-nonenylamine, 2_B Base_9_癸 diluted amine, 2-ethyl-10-undecenylamine, 2-propyl-5-hexenylamine, 2-propyl-6-heptenylamine, 2-propyl-7-octyl Enamine, octapropyl-8-decenylamine, propyl decenylamine, 2-propyl-10-undecenylamine, 2-butyl 5-hexenylamine, butyl-6-heptylamine, 2-butyl-7-octeneamine, 2-butyl-8-decenylamine, butyldecenylamine, and 2-butyl-10-undecenylamine; alkenylamines having a branched hydrocarbon group, For example, 2-isopropyl-5-hexenylamine, 2-isopropyl-6-heptenylamine, 2-isopropyl-7-octeneamine, 2-isopropyl-8-nonenylene, - -------IIIII * — — — — — — — ^ --------- IAW. (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumer Cooperatives The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 mm). 127 312991 A7 1290149 ___Β7__15, invention description (128 2-isopropyl-9-decenylamine, 2-isopropyl-10-undenylamine, 2-isobutyl-5-hexylamine, 2-tert-butyl-6-heptenylamine , 2-isopropyl-3-methyl-7-octenylamine, 2-methyl-3-isopropyl-8-nonenylamine 3-isobutyl-3-methyl-9-nonenylamine , 2,2-dimethyl-10-undecenylamine and 2,3,3-trimethyl-11-dodecenylamine; N-alkyl- 6J-lead amines, such as N-methyl -5-hexenylamine, N-methyl-6-heptylamine, N-methyl-7-octylamine N-methyl-8-nonenylamine, N-methyl-9-nonenylamine, N-methyl-10_undecenylamine, N-methyl-11-dodecylamine, N-ethyl-5-hexylamine, N-ethyl-6-heptamine, N-ethyl -7-octeneamine N-ethyl-8-decylamine, N-ethyl-9-oxime amine, N-ethyl_10_undecamide and N-ethyl-11-twelve Amine; N-alkylenylamines having a linear hydrocarbon group, such as N-methyl-6-hepten-2-amine, N-ethyl-7-octyl, 2-amine, N-methyl- 8-decene-2_amine, N-ethyl-9-nonenylamine, N-methyl·1〇-undecene-2-amine, N_ethyl_8_nonene_3_amine, N-methyl-9-pinene-3-amine, N-ethyl-1 (K eleven-3-amine, printed by the Intellectual Property Office of the Ministry of Economic Affairs, Ν-B -8-indole-4-amine, hydrazine-methyl-9-quinone _4_amine and hydrazine-ethyl_10_undec-4-amine; fluorene-alkylene having a branched hydrocarbon group Base amines, such as Ν-methyl-2-methyl-5-hexenamine, decylethylmethylglycolide,

Ν-Methyl-2_methyl_7-octeneamine, Ν-ethyl | methyl s IT decene, enamine N-ethyl-2-methyl-9-nonenylamine, N-A Base-2-methyl·1〇_ + N-methyl-2·ethyl-7-octylamine, N-ethylethyl_9_癸 This paper scale applies to China National Standard (CNS) A4 specification ( 21Ό X 297 公爱1 312991 128 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1290149 Λ7 Β7 V. Description of Invention (129) N-Methyl-2-ethyl-10-undecenamine; N,N-II Alkyl-omega-alkenylamines such as hydrazine, hydrazine-dimethyl-5-hexenamine, hydrazine, hydrazine-dimethyl-6-heptenylamine, hydrazine, hydrazine-dimethyl-7-octyl Enamine, hydrazine, hydrazine-dimethyl-8-nonenylamine, hydrazine, hydrazine-dimethyl-9-nonenylamine, hydrazine, hydrazine-dimethyl-10 undecenylamine, hydrazine, hydrazine- Dimethyl-11-dodecanamine, hydrazine, hydrazine-diethyl-5-hexenamine, hydrazine, hydrazine diethylamine-heptenylamine, hydrazine, hydrazine-diethyl-7-octyl Enamine, hydrazine, hydrazine diethyl 8-deceneamine, hydrazine, hydrazine-diethyl-9-oxime amine, hydrazine, hydrazine-diethyl-10-undecenamine and hydrazine, hydrazine- Diethyl-11-dodecenylamine; fluorene-dialkylenylamines having a linear hydrocarbon group, such as hydrazine, hydrazine-dimethyl-6-g -2-amine 'Ν, Ν-diethyl-7-octene-2.amine, hydrazine, hydrazine-dimethyl-8-oxime-diamine- ', Ν·diethyl_9_癸Dilute-2_amine, hydrazine, hydrazine-dimethyl-10-undecen-2-amine, hydrazine, hydrazine-diethyl _8_nonene _3_amine, hydrazine, hydrazine dimethylene-9 -decene-3-amine, hydrazine, hydrazine-diethyl-10-undecene-3.amine, hydrazine, hydrazine-diethyl-8-nonene _4-amine, hydrazine, hydrazine-dimethyl -9-nonene-4-amine and hydrazine, hydrazine-diethyl-10-undecen-4-amine; and fluorene having a branched hydrocarbon group, fluorenyl-dialkylenylamines such as hydrazine, hydrazine -Dimethyl-2.methyl-5-hexenamine, hydrazine, hydrazine-diethyl-2-methyl-6-heptenylamine, hydrazine, hydrazine-dimethyl-2.methyl-7- Octenamine, hydrazine, hydrazine-diethyl-2-methyl-8-indole amine, hydrazine, hydrazine-diethyl-2-methyl-9-oxime amine, hydrazine, hydrazine-dimethyl- 2-methyl-10-undeceneamine, hydrazine, hydrazine-dimethyl-2·ethyl-7-octeneamine, this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) ---------------------Book ---------w_w— (Please read the notes on the back and fill out this page) 129 312991 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1290149 Λ7 Β7 V. (130) N,N-diethyl-2-ethyl-9-nonenylamine and N,N-dimethyl-2-ethyl-10-undecenamine; wherein X is decylamine a compound of the formula (7), in particular an ω-alkenylamine, such as allylamine, 5-hexenylamine, 6-hepteneamine, 7-octeneamine, 8-decene Indoleamine, 9-nonenylamine, 10-undecenylamine and 11-dodecenylamine; alkenylamines having a linear hydrocarbon group, such as 6-heptene-2-decylamine, 7- Octene-2-decylamine, 8-decene-2-guanamine, 9-nonene-2-decylamine, 10-undecene-2-decylamine, 8-decene-3-nonylamine, 9 -decene-3-decylamine, 10-undecene-3-decylamine, 11-dodecene-3.decylamine, 8-decene-4-nonylamine, 9-anthracene-4-bristamine , 1 0-unde-4-indoleamine, 11-dodeca-4-amine, 9-decene-5-decylamine and 10-undecene-5-decylamine; oxime-alkyl group- Omega-alkenylamines, for example, Ν-methyl-5-hexene decylamine, hydrazine methyl-6-heptene decylamine, hydrazine-methyl-7-octene decylamine, hydrazine-methyl- 8-decene decylamine, hydrazine-methyl-9-decene decylamine, hydrazine-methyl-10·undecene decylamine, hydrazine-methyl-11-dodecenylamine, hydrazine-ethyl- 5-hexene decylamine, hydrazine-ethyl-6-heptyl amide , Ν-ethyl-7-octylamine, hydrazine·ethyl-8-decene decylamine, hydrazine-ethyl-9-decene decylamine, hydrazine-ethyl-10-undecene amide Ν-ethyl-11-dodecenylamine; hydrazine, hydrazine-dialkyl-ω-alkenylamine, such as hydrazine, hydrazine-dimethyl-5-hexene decylamine, hydrazine, hydrazine-II Methyl-6-heptene decylamine, hydrazine, hydrazine-dimethyl-7-octene decylamine, hydrazine, hydrazine-dimethyl-8-nonene amide, hydrazine, hydrazine-dimethyl-9 Terpene amide, hydrazine, hydrazine-dimethyl-10-undecene amide, ------------#------- -定------- --Line (please read the notes on the back and fill out this page) This paper size applies to China National Standard (CNS) A4 specification (210 x 297 mm) 130 312991 A7 1290149 B7 V. Invention description (13i) N,N - dimethyl-11-dodecenylamine, N,N-diethyl-5-hexenylamine, N,N-diethyl-6-hepteneamine, hydrazine, hydrazine diethyl -7-octene decylamine, hydrazine, hydrazine-diethyl-8-decene decylamine, hydrazine, hydrazine-diethyl-9-decene decylamine, hydrazine, hydrazine -diethyl-10 - eleven Thin amines and hydrazine, hydrazine-diethyl-11-tide thin amine, alkenyl amides having branched hydrocarbon groups, such as 2-methyl-5-hexamethylene 2-methyl-6-heptylamine, 2·methyl-7-octeneamine, 2-methyl-8-noneneamine, 2-methyl-9-noneneamine, 2- Methyl_10_undeceneamine, 2-ethyl-5-hexamethyleneamine, 2-ethyl-6-heptylamine, 2-ethyl-7-octeneamine, 2-B -8-decene decylamine, 2-ethyl-9-nonenyl decylamine, 2-ethyl-10-undecene decylamine, 2·ethyl-11-dodecenylamine, 2, C 5-Benzene decylamine, 2-propyl-6-heptene decylamine, 2-propyl-7-octene decylamine, 2-propyl-8-nonene decylamine, 2-propyl- 9-decene decylamine, 2-propyl-10-undecenamide, 2-propyl-11-dodecenylamine, 2-butyl-5-hexene decylamine, 2-butyl- 6-heptene decylamine, 2-butyl-7-octene decylamine, 2-butyl-8-nonene decylamine, 2-butyl-9-nonenyl decylamine and 2-butyl-10- Undecyl decylamine; fluorene having a branched hydrocarbon group, fluorenyl-dialkylalkenylamines such as hydrazine, hydrazine-dimethyl-2-methyl-5-hexene decylamine, hydrazine, hydrazine Ethyl-2-methyl_6_heptanylamine, hydrazine, hydrazine-dimethyl-2-methyl-7-octene decylamine, hydrazine, hydrazine-diethyl-2-methyl-8-壬 Thin amine, this paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 312991 ---------------------Order---------Line (Please read the notes on the back and fill out this page. ) Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed clothing 131

V. INSTRUCTIONS (132) Indoleamine and 1290149 N,N-diethyl-2-methyl-9-nonene decylamine, N,N-diethyl-2-methyl-10_undecene Amine, N,N-dimethyl-2-ethyl-7-octene decylamine, N,N-diethyl-2-ethyl-9-decene decylamine and N,N-dimethyl- 2-ethyl-1-indole-1-endecylamine; alkenyl diamines such as 6-heptene ", 2 - diamine, 7-octene 1, 2 - diamine, decene _152_diamine, 9-anthracene-1,3-difunctional amine, 10_ten-lean-M-di-handling amine and 11-dodecene-1,3-diamine; alkenyl triterpenoid Amines such as hydrazine 丨 2 3 10-H ene-1,2,3-trienamine; and compounds of the formula (7) wherein X is an epoxy group, in detail, a dilute epoxide, For example, 5_hexyl ring: compound, 6-heptene epoxide, 7-octane epoxide, 8-9-thin epoxide, 10_deca- epoxide, and oxime 11 ·12 Ethene epoxide; and — — — — — — — — — — — — 1111111 « — — — — — — I — (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office Staff Cooperatives Printed with Branched smoky group of ω-alkenyl epoxide hexene epoxide, 2-methyl-6-heptene epoxide, such as 2-methyl-5-oxide, 2-methyl-8 a terpene epoxide, 2-methyl and 2-methyl-10-undecene epoxide; and a compound of the formula (7) wherein X is a fluorenyl group, for example, -CH2_CH2-〇-Ph_SH 〇 contains a polar group Other examples of monomers include the following formulas. The paper scale applies to the Chinese National Standard (CNS) A4 specification (21〇X 297 public I methyl-7-octene ring based _9_nonene epoxide shown The combination of 132 312991 A7 1290149 _B7_ V. Description of invention (133) printed by the Intellectual Property Office of the Ministry of Economic Affairs

-------------4 (Please read the notes on the back and fill out this page) Order---------Line · This paper scale applies to China National Standard (CNS) A4 Specification (210 297 297 mm) 133 312991 1290149 V. Description of invention (134 ) A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing

OH -------------------- Order --------- line (please read the notes on the back and fill out this page) This paper size applies to China National Standard (CNS) A4 Specification (210 x 297 mm) 134 312991 1290149 A7 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed

-------------€ (Please read the phonetic on the back? Please fill out this page again) This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm). ------- Line - 135 312991 1290149 Λ7 _B7 V. Description of invention (1%) Printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative

-1------------------^---------_ (Please read the notes on the back and fill out this page)

Η This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 136 312991 1290149 A7 B7 V. Description of invention (m

-------------# (Please read the notes on the back and fill out this page.) The Ministry of Economic Affairs, Intellectual Property Office, and the Consumer Cooperatives can also print n-decyl-1-ol and ruthenium. -1-acidified acid group, 1,2-epoxy-fluorenyl group, (6-hexen-1-yl)succinic acid J6 anhydride, n-undecyl-1-ol, n-dodecyl-1-destroy acid, n-Dodecyl-1-pentaethoxy, 4-hexylphenylene, 4-hexyloxy-phenylsulfonium, n-decyl-1-hydrazinyl, n-decyl-1-amine And n-decyl-1-N-methylamino group. In the preparation method of the polar group-containing olefin copolymer according to the first embodiment of the present invention, the polar group-containing monomer represented by the formula (7) may be a lower type gate, and the polar group monomer:壬--1- ethoxylate---------line ηφ------ ch2=ch(i)b where R3', Ρ and X' have the formula (3') The meaning of R2. The paper scale is based on the Chinese National Standard (CNS) A4 specification (210 X 297 mm), P and X, the same 312991 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 138 1290149 Α7 Β7 5, invention description (138) Examples of the polar group-containing monomer in which X' is -OR include: ω-alkoxy·α-olefins such as 3-methoxy-1-propene, 5-methoxy-1-pentene, 6-methoxy-1-hexene, 7-methoxy-1-heptene, 8-methoxy-1-octene, 9-methoxy-1-decene, 10τmethoxy-1 -decene, 11-methoxy-1-undecene, 5-ethoxy-1-pentene, 6-ethoxy-1-hexene, 7-ethoxy-1-heptene, 8 -ethoxy-1-octene, 9-ethoxy_1_oxime, 10-ethoxy-1-decene, 11-ethoxy-1-undecene, 5-propoxy- 1-pentene, 6-propoxy-1-hexene, 7-propoxy-1-heptene, 8-propoxy-1-octene, 9-propoxy-1-decene, 10 -propoxydecene, 11-propoxy-1-undecene, 5-butoxy-1-pentene, 6-butoxy-1-hexene, 7-butoxy-1-heptane Alkene, 8-butoxy-1-octene, 9-butoxy-1-decene, 10-butoxy-1 - fluorene and 11-butoxy-1-undecene; Ethers having a branched chain hydrocarbon group, such as 7-methoxy-7-methyl-1-heptene, 8-methoxy-8-methyl-1-octene, 9-methoxy-8- 1-decene, 10-methoxy-9-methyl-1-decene, 11·methoxy-7-ethyl-1-undepine, 7-ethoxy-6-methyl -1-heptane, 8-ethoxy-6-ethyl-1-octyl, 9-ethoxy-7-ethyl-1-anthracene, 10-ethoxy-ethyl-1-anthracene Alkene, 11-ethoxy-8-propyl-1-undecene, 6-propoxy-6-methyl-1-hexene, 7-propoxy-7-methyl-1_heptene , 8-propanyl-8,8-dimethyl-1 -octyl, 9-propoxy-9-methyl-1 -indole, 10-propoxy-9,9-dimethyl- 1-decene, 11-propoxy-10-methyl-1-undecene,-5-butoxy-5-ethyl-1-pentene, 6-butoxy-6,6-di Methyl-1-hexene, 7·butoxy-6-methyl-1-heptene, 8-butoxy-6-ethyl-1-octene, 9-butoxy-9-methyl -1-decene, this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 I IW aw I IW μ··· ί I r · t ·ϋ n ·ϋ n ϋ — Hi 1 *1 in I ϋ ·ϋ ϋ— I · (Please read the notes on the back and fill out this page) 1290149 A7 Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, Printed B7_ V. Inventions (139) 1〇-Butoxy-8,8-dimethyl-1-decene and 11-butoxy-8,9-diethyl Alkoxy-1-decene; a di-oxyl-α-olefin such as 9,10-dimethoxy-1-dodecene and 1〇,11-dimethoxy-1-undecene; And a tris-oxygen-α-olefin such as 9,10,11-trimethoxy-1-undecene. Examples of the polar group-containing monomer in which X' is -COOR in the formula (7,) include: ω-alkenyl carboxylate such as methyl 5-hexenoate, methyl 6-heptenoate, 7-octyl Dilute methyl ester, methyl 8-decenoate, methyl 9-decenoate, methyl 10-undecenoate, methyl 11-dodecenoate, ethyl 5-hexenoate, 6-g Ethyl enoate, ethyl 7-octenoate, ethyl 8-decenoate, ethyl 9-decenoate, ethyl 10-decenoate, ethyl 11-dodecenoate, 5-hexyl Isopropyl enoate, isopropyl 6-heptenoate, isopropyl 7-octenoate, isopropyl 8-decenoate, isopropyl 9-decenoate, isopropyl 10-undecenoate Ester, isopropyl 11-dodecenoate, butyl 5-hexenoate, butyl 6-heptenoate, butyl 7-octenoate, butyl 8-decanoate, 9-decenoic acid Ester, butyl 10-undecenoate, butyl 11-dodecenoate, amyl 5-hexenoate, amyl 6-heptenoate, amyl 7-octenoate, 8-decenoic acid Esters, amyl 9-decenoate, amyl 10-undecenoate and amyl dodecenoate; dilute carboxylic acid esters having a linear hydrocarbon group, such as 2-methyl-5-hexene Methyl ester, methyl 2-methyl-6-heptenoate, 2-methyl-7-octyl Ethyl enoate, methyl 2-methyl-8-decenoate, butyl 2-methyl-9-decenoate, ethyl 2-methyl-10-undecenoate, (please read the back first) Note: Please fill in this page) t Order---------Line - This paper scale applies to China National Standard (CNS) A4 specification (2]0 X 297 mm) 139 312991 A7 1290149 B7_ V. Invention Description (14〇) 2-ethyl-5-hexenoic acid butyl ester, 2-ethyl-6-heptenoic acid ethyl ester, 2-ethyl-7-octenoic acid isopropyl ester, 2-ethyl- Ethyl 8-decenoate, methyl 2-ethyl-9-decenoate, ethyl 2-ethyl-10-undecanoate, methyl 2-propyl-5-hexanoate, 2- Methyl propyl-6-heptenoate, ethyl 2-propyl-7-octenoate, methyl 2-propyl-9-decenoate, ethyl 2-propyl-10-undecenoate , methyl 2-butyl-7-octenoate, methyl 2-butyl-8-decenoate, methyl 2-butyl-9-decanoate and 2-butyl-10-undecene a methyl ester; and an alkenyl carboxylate having a branched hydrocarbon group, such as butyl 2-isopropyl-5-hexenoate, ethyl 2-isopropyl-6-heptenoate, 2-isopropyl Methyl -7-octenoate, methyl 2-isopropyl-8-decenoate, butyl 2-isopropyl-9-decenoate, 2-isopropyl-10- Methyl undecylenate, methyl 2-isobutyl-5-hexenoate, methyl 2_t-butyl-6-heptenoate, 2-isopropyl-3-methyl-7-octyl Ethyl acetate and 3-isobutyl-3-methyl-9-indole propylene vinegar. Examples of the polar group-containing monomer in which X' is -CRO in the formula (7,) include: an alkenyl ketone having a linear hydrocarbon group, for example, 5-hexacene-2-indole, 6-heptacene-2-indole, 7 - 奇稀-2 -陋' 8 - 壬_2_陋, 9-nonen-2-one, 10-undecene-2-one, 11-dodecen-2-one, 6-heptene 3-keto, 7-octen-3-one, 8-decen-3-one, 9-nonen-3-one, 10-undecen-3-one, 11-dodecene-3- Ketone, 7-octene-4-one, 8-decen-4-one, 9-anthrene-4-one, 10-undec-4-one, 11-dide-4-one, 9 - Terpene-5-one, 10-undecene-5-one and 11-dip-5-anthracene, this paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 312991 --- -----------------Book---------Line (please read the notes on the back and then fill in this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative System 140 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 141 1290149 Α7 Β7 V. Description of Invention (141) Alkenyl ketone with branched hydrocarbon group, such as 3-methyl-6-heptacene-2-indole, 3-methyl Base-7-octyl-2-indole, 3-methyl-8-indole-2 -嗣, 3-methyl-9-indole-2 -嗣, 3-B -10-undecene-2·one, 3-methyl-11-dodecene-2·one, 2-methyl-7-octyl _3-net, 2•methyl-8-壬-- 3 -嗣, 2 -methyl-9 -oxime-3 _嗣, 2 -methyl-1 0 -10* 稀-3 -嗣, 3 -methyl-7 - octyl-4-嗣, 3 - Ethyl-8-indole-4 -indole, 3-ethyl-9-indole-4 -indole, 3-ethyl·1 0 -10*, dilute-4 -嗣, 3-ethyl-11-ten Dien-4-one, 3-ethyl-9-indole-5-one, 3-ethyl-10 • ten* dilute-5-ah and 3-ethyl-11-dilute-5-嗣An alkenyldione such as 8-decene-2,4-one, 9-nonene-2,4-one and 10-undecene-2,4-one; and a divalent triterpene such as 10- Undecene-2,4,6-ketone and 11-dodecane-2,4,6-one. Examples of the polar group-containing monomer of the formula (7') wherein X' is -NR'R" (R' and R" may be the same or different and are a hydrogen atom and/or a hydrocarbon group) include: ω-sweet amines, For example, 5-hexenylamine, 6-heptenylamine, 7-octeneamine, 8-decenylamine, 9-decenylamine, 10-undecenylamine, and 11-dodecenylamine; having a linear hydrocarbon group Alkenylamines such as 2-methyl-5-hexenylamine, 2-methyl-6-heptenylamine, 2-methyl-7-octeneamine, 2-methyl-8-nonenylamine, 2-methyl-9-decenylamine, 2-methyl-10-undecenylamine, 2-methyl-11-dodecylamine, 2-ethyl-5-hexylamine, 2-ethyl -6-heptylamine, 2-ethyl-7-octylamine, 2-ethyl-8-oxime amine, 2-ethyl-9-oxime amine, this paper scale applies to Chinese National Standard (CNS) A4 size (210 x 297 mm) 312991 --------------------- Order --------- Line ^M_w. (Please read the back first Note: Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 142 1290149 Α7 Β7 V. Invention Description (142) 2·Ethyl-10-undenylamine, 2-propyl-5-hexene Amine, 2-propyl-6-heptamine, 2-propyl-7-octeneamine, 2-propyl-8-nonenylamine 2-propyl-9-nonenylamine, 2-propyl-10-undecenylamine, 2-butyl 5-hexenylamine, 2-butyl-6-heptylamine, 2-butyl-7 - octeneamine, 2-butyl-8-nonenylamine, 2-butyl-9-nonenylamine, and 2-butyl-10-undecenylamine; and alkenylamines having a branched chain hydrocarbon group, For example, 2-isopropyl-5-hexylamine, 2-isopropyl-6-heptylamine, 2-isopropyl-7-octeneamine, 2-isopropyl-8-nonenylamine, 2 -isopropyl-9-oxime amine, 2-isopropyl-10-undecamine, 2-isobutyl-5-hexenamine, 2-tert-butyl-6-heptylamine, 2 -isopropyl-3-methyl-7-octylamine, 2-methyl-3-isopropyl-8-oxime amine, 3·isobutyl-3-methyl-9-decenylamine, 2,2-dimethyl-10-undecenylamine and 2,3,3-trimethyl-11-dodecenylamine. N-alkyl-ω-alkenylamines such as Ν-methyl-5·hexenylamine, Ν-methyl-6-heptenylamine, Ν-methyl-7-octeneamine, hydrazine can also be used. -Methyl-8-decenylamine, Ν-methyl-9·decenylamine, Ν-methyl-10-undecenamine, Ν-methyl-11-dodecenylamine, Ν-ethyl- 5-hexenylamine, hydrazine-ethyl-6-heptenylamine, hydrazine-ethyl-7-octeneamine, hydrazine-ethyl-8-decylamine, hydrazine-ethyl-9-nonenylamine, Ν-ethyl-10-undecenylamine and fluorenyl-ethyl-11-dodecenylamine; fluorene-alkylenylamines having a linear hydrocarbon group, such as hydrazine-methyl-6-glycol-2 -amine, hydrazine-ethyl-7-octyl-2-amine, hydrazine-methyl-8-nonen-2-amine, hydrazine-ethyl-9-nonen-2-amine, methyl-10- Undecen-2-amine, Ν-ethyl-8-nonene-3-amine, this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------- ------------Book --------- line (please read the note on the back and fill out this page) 1290149 Λ7 Β7 5, invention description (143) N-曱基-9-oxime-3 -amine, N-ethyl-10-undec-3-amine, N-ethyl-8·indole-4-amine, N-methyl-9-oxime-4 -amine and N-ethyl· 10-unde-4-amine, having a branched chain N-alkyl alkenylamines such as N-methyl-2-methyl-5-hexenamine, N-ethyl-2-methyl-6-heptenylamine, N-methyl-2 _Methyl-7-octylamine, N-ethyl-2-methyl-8-oxime amine, N-ethyl-2-methyl-9-nonenylamine, N-methyl-2-methyl Alkyl-10-undecenamine, N-methyl-2-ethyl-7-octeneamine, N-ethyl-2-ethyl-9-nonenylamine and N-methyl-2-ethyl -10-11 diluted amine; N,N-dialkyl-diluted amines such as N,N-dimethyl-5-hexenamine, N,N-dimethyl-6-heptenylamine , N,N-Dimethyl-7-octeneamine, N,N-dimethyl-8-nonenylamine, N,N-dimethyl-9-nonenylamine, N,N-dimethyl -10-undenylamine, N,N-dimethyl-11 • dodecenylamine, N,N-diethyl-5-hexenamine, N,N-diethyl-6-heptenylamine , N,N-diethyl-7-octeneamine, N,N-diethyl-8-nonenylamine, N,N-diethyl-9-nonenylamine, N,N-diethyl -10-undenylamine and hydrazine, hydrazine·diethyl-11-dodecenylamine; fluorene-dialkylenylamines having a linear hydrocarbon group, such as hydrazine, hydrazine-dimethyl-6 _heptene-2_amine, hydrazine, hydrazine_diethyl-7-octene-2-amine, hydrazine, hydrazine-dimethyl-8-nonene-2.amine, hydrazine Ν-Diethyl-9-nonen-2-amine, hydrazine, hydrazine-dimethyl-10-undecen-2-amine, hydrazine, hydrazine-diethyl-8-nonene-3-amine, Ν,Ν_dimethyl-9-nonene-3-amine, hydrazine, hydrazine-diethyl-10-undecen-3-amine, hydrazine, hydrazine-diethyl-8-decene-4- Amine, hydrazine, hydrazine-dimethyl-9·nonene-4-amine and hydrazine, hydrazine-diethyl-10-unde-4-amine; and the paper size applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 312991 ------------- Rust (please read the notes on the back and fill out this page) Order---------Line · Ministry of Economics Property Bureau Staff Consumer Cooperatives Printed 143 A7 1290149 ___ B7 _ V. Illustrative (I44) N,N-dialkylenylamines with branched hydrocarbon groups such as N,N-dimethyl-2-methyl -5-Hexenylamine, N,N-.monoethyl-2-methyl-6-heptamine N,N-dimethyl-2-methyl-7-octeneamine, N,N-di Ethyl-2-methyl-8-decenylamine, N,N-diethyl-2-methyl-9-nonenylamine, N,N-dimethyl-2-methyl-10-11 Enamine, N,N-dimethyl-2-ethyl-7-octeneamine, hydrazine, hydrazine-diethyl-2-ethyl-9-decenylamine and hydrazine, hydrazine-dimethyl-2 -ethyl-10-undeceneamine. Examples of the polar group-containing monomer of the formula (7,) wherein X' is -CONR2 (R is a halogen atom or a hydrocarbon group) include: ω - dilute amines such as 5-hexene-enamine, 6-heptene Amine, 7-octene decylamine, stilbene decylamine, 9-nonenyl decylamine, 10-undecenylamine and 11-dodecenylamine; alkenyl amides having a linear hydrocarbon group, for example 6-heptene-2-decylamine, 7-octene-2-decylamine, 8-decene-2-decylamine, 9-decene-2-indoleamine, 10-undecene-2-decylamine , 8-indole-3-amine, 9-decene-3-decylamine, 10-undecene-3-decylamine, 11-dodecylamine, 8-decene-4-nonylamine, 9-decene-4-decylamine, 10-undecene-4-nonylamine, 11·dode-4-amine, 9-decene-5-decylamine and 1〇_undecene_5醯 醯 ;; Ν-alkyl-ω-alkenyl amides, such as Ν-methyl _5-hexamethyleneamine, Ν-methyl _6 • heptylamine, Ν-methyl-7-xin Enoxaamine, Ν-methyl _8_nonene amide, this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 I n ··1 ϋ ·ϋ I- i^in ϋ · n ϋ ϋ I ϋ ϋ Hi I I ϋ ϋ ϋ I ϋ —ϋ n I *^^^1 rtt Read the notes on the back and fill in Page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 144 A7 1290149 B7_ V. Description of Invention (l45) Ν·Methyl-9-decylamine, N-methyl-10-undeceneamine, Ν- Methyl-11-dodecenylamine, Ν-ethyl-5-hexene decylamine, hydrazine-ethyl-6-heptene decylamine, hydrazine-ethyl-7-octene decylamine, hydrazine-B -8-decene decylamine, hydrazine-ethyl-9-decene decylamine, hydrazine-ethyl-10-undecene amide and hydrazine-ethyl-11-dodecenylamine; hydrazine, hydrazine Dialkyl-ω-alkenylamines such as hydrazine, hydrazine-dimethyl-5-hexene decylamine, hydrazine, hydrazine-dimethyl-6-heptylamine, hydrazine, hydrazine-dimethyl -7-octene decylamine, hydrazine, hydrazine-dimethyl -8-oxime amide, hydrazine, hydrazine-dimethyl-9-nonene amide, hydrazine, hydrazine-dimethyl-10-10 Monodecylamine, hydrazine, hydrazine-dimethyl-11-dodecene decylamine, hydrazine, hydrazine-diethyl-5-hexene decylamine, hydrazine, hydrazine-diethyl-6-heptene decylamine , hydrazine, hydrazine-diethyl-7-octene decylamine, hydrazine, hydrazine-diethyl _8_nonene decylamine, hydrazine, hydrazine-diethyl-9 decyl decylamine, hydrazine, hydrazine- Diethyl-10-undeceneamine and hydrazine, hydrazine-diethyl-11-dodecenylamine; alkenyl amides having branched hydrocarbon groups For example, 2-methyl-5-hexenylamine, 2-methyl-6-hepteneamine, 2-methyl-7-octylamine, 2-methyl-8-noneneamine, 2 -methyl-9-decene decylamine, 2-methyl-10-undecene decylamine, 2-ethyl-5-hexene decylamine, 2-ethyl-6-heptene decylamine, 2- Ethyl-7-octene decylamine, 2-ethyl-8-nonene decylamine, 2-ethyl-9-nonene decylamine, 2-ethyl-10-undecene decylamine, 2-B Base-11-dodecene decylamine, 2-propyl-5-hexyl decylamine, 2-propyl-6-heptene decylamine, 2-propyl-7-octene decylamine, 2-propyl -8-decene decylamine, 2-propyl-9-indole amide, this paper scale applies to China National Standard (CNS) A4 specification (2 〗 0 X 297 mm) 312991 -------- ^---------^ (Please read the notes on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 145 1290149 A7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 146 B7 Five , invention description (l46) 2-propyl-10-undecenamide, 2-propyl-11-dodecenylamine, 2-butyl-5-hexenylamine, 2-butyl-6 -heptene decylamine, 2-butyl-7-octene decylamine, 2-butyl-8-nonene decylamine, 2-butyl-9-nonene amide 2-butyl-10-undecenylamine; N,N-dialkylalkenylamines having a branched hydrocarbon group, such as N,N-dimethyl-2-methyl-5-hexene醯Amine, N,N-diethyl-2-methyl-6-heptene decylamine, N,N-dimethyl-2-methyl-7-octene decylamine, N,N-diethyl- 2-methyl-8-decene decylamine, N,N-diethyl-2-methyl-9-nonene decylamine, N,N-diethyl-2-methyl-10-undecene Indoleamine, N,N-dimethyl-2-ethyl-7-octene decylamine, N,N-diethyl-2-ethyl-9-decene decylamine and N,N-dimethyl -2·ethyl_10_H--eneamine; alkenyldiamines such as 6·heptene-1,2-diamine, 7-octene-1,2-diamine, 8-壬Alkene-1,2-diamine, 9-decene-1,3-dioxylamine, 10-undecene-1,3-didecylamine and 11-dodecene-1,3-dioxamide And alkenyl tridecylamines such as 9-decene-1,2,3-tridecylamine and 1〇-undecene-1,2,3-tridecylamine. An example of a polar group-containing monomer of the formula (7,) wherein X is _OCOR (R is a hydrocarbon group) is a carboxylic acid ω-alkenyl group such as formic acid-5-hexenyl group or formic acid-6-heptenyl group. ,-7-octenyl formate, this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 I Η» I BMM a···· ΜΜ Μ·· II · ϋ «ϋ I nn ( an TJ ·ϋ ϋ ·ϋ (Please read the note on the back and fill out this page) Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 147 1290149 A7 B7 V. Invention Description "47) Formic acid-8-pinene Base, formic acid-9-nonenyl, formic acid-10-undenyl, formic acid-11-dodecenyl, acetate 5-hexenyl, acetate-6-heptenyl, acetate-7-octene Base, -8-decenyl acetate, 9-nonenyl acetate, 10-undecenyl acetate, 11-dodecenyl acetate, hexenyl propionate, 6-heptenyl propionate , 7-octenyl propionate, _8-decenyl propionate, -9-mercaptopropionic acid, propionic acid-10-undecyl, propionic acid-II-undecyl, butyric acid -5-hexenyl, butyric acid-6-heptenyl, butyric acid-7-octenyl, butyric acid-8-nonenyl, butyric acid-9-nonenyl, butyl Acid-10-undecyl, butyrate-11-dodecenyl; and carboxylic acid ω-alkenyl having a branched hydrocarbon group, such as formic acid-2-methyl-5-hexenyl, formic acid-2_ Methyl-6-heptenyl, formic acid-3-ethyl-7-octenyl, formic acid-2-methyl-8-nonenyl, formic acid-3-ethyl-9-nonenyl, formic acid- 2-methyl-10-undecenyl, formic acid 2-methyl-11-dodecenyl, acetic acid-2-methyl-5-hexenyl, acetic acid-2-methyl-6-heptene Base, 3-ethyl-7-octyl acetate, 2-methyl-8-nonenyl acetate, 3-ethyl-9-fluorene acetate, acetic acid-2-methyl-10- 11. Alkenyl, ethyl acetate-11-dodecyl, propionate-2-methyl-5-hexenyl, propionic acid-2-methyl-6-heptenyl, propionic acid-2- Methyl-7-octenyl, propionate-2-methyl-8-decenyl, propionate-2-mercapto-9-nonenyl, propionate-2-methyl-10-undecene Base, propionate-2-methyl-11-dodecenyl, butyric acid-2-methyl-5-hexenyl, butyric acid-2-methyl-6-heptenyl, butyric acid-2- Methyl-7-octenyl, butyrate-3-methyl-8-nonenyl, butyric acid-3-methyl-9-indole, butyrene-4-methyl-10-undecene And butyric acid-3-methyl-11-dodecenyl. The paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------- order --------- line - (please read the notes on the back and fill in Page 7 A7 1290149 B7_ V. INSTRUCTION DESCRIPTION (M8) Examples of polar group-containing monomers in which X' is -CN in formula (7,) include: ω-smelry nitriles such as 5-hexenenitrile, 6- Glycidonitrile, 7-octenenitrile, 8-decenenitrile, 9-decenenitrile, 10-undecenenitrile and 11-dodecenenitrile; alkenyl nitriles having a linear hydrocarbon group, such as 2-A 5--5-hexane, 2-methyl-6-heptacene, 2-methyl-7-octylsulfonium, 2-methyl-8-decenenitrile, 2-methyl-9-decene Nitrile, 2-methyl-10-undecenitrile, 2-methyl-11-dodecenenitrile, 2-ethyl-5-hexenenitrile, 2-ethyl-6-heptenenitrile, 2- Ethyl-7-octene diet, 2-ethyl-8-indole, 2-ethyl-9-anthraquinone, 2-ethyl-10-undecenitrile, 2-propyl-5- Hexenenitrile, 2-propyl-6-heptenenitrile, 2-propyl-7.octenenitrile, 2-propyl-8-nonenenitrile, 2-propyl-9-decenenitrile, 2- Propyl-10-undecenitrile, 2-butyl-5-hexenenitrile, 2-butyl-6-heptenenitrile, 2-butyl-7-octylsulfonium, 2-butyl-8-壬 臆2-butyl-9·anthraquinone and 2-butyl-10-indolene, an alkenyl nitrile having a branched hydrocarbon group, such as 2-isopropyl-5-hexenenitrile, 2-isopropyl -6-heptonitrile, 2-isopropyl-7-octenenitrile, 2-isopropyl-8-decenenitrile, 2-isopropyl-9-nonenenitrile, 2-isopropyl- 10-undecenenitrile, 2-isobutyl-5-hexenenitrile, 2-tert-butyl-6-heptenenitrile, 2-isopropyl-3-methyl-7-octyl diet, 2 -methyl-3-isopropyl-8-indole, 3-isobutyl-3-methyl-9-decenenitrile, 2,2-dimethyl-10-undecenitrile and 2, 3,3-trimethyl-11•dodecenenitrile; mercapto dinitrile, such as 10-11-dilute-1,2-diindole and 11-dilute-1,2-·-indole, and The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------------------- Order --------- line (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Office, Staff and Consumers Co., Ltd. Printed 148 A7 B7 1290149 V. Description of Invention (l49) Alkenyl trinitrile, for example, 10-11 diluted-1,2, 3 - three. Examples of the polar group-containing monomer in which X' is -OH in the formula (7,) include: ω-smelt alcohols such as 4-penten-1-ol, 5-hexen-1-ol, 6-g En-1-ol, 7·octene-1-ol, 8-decen-1-ol, 9-nonen-1-ol, 10, undecen-1-ol and 11-decadiene-1 - an alcohol; an alcohol having a linear hydrocarbon group, such as 5-hexen-2-ol, 6-hepten-2-indole, 7-octene-2-ol, 8-decyl-2-ol, 9- Terpene-2-ol, 10-undecen-2-ol, 6-hepten-3-ol, 7-octene-3-ol, 8-decen-3-ol, 9-decene-3 - alcohol, 10-undecen-3-ol, 11-dodecen-3-ol, 7-octene-4-ol, 8-decene-4-ol, 9-fluoren-4-ol, 10-undecen-4-ol, 8-decene-5-ol, 9-nonene-5-ol and 10-undecene-5-alcohol; alcohols having a branched chain hydrocarbon group, for example 2_B 5--5-hexen-1-ol, 3-methyl-6-hepten-1-ol, 3-methyl-7-octene-1-ol, 4-methyl-8-nonene-1 _ alcohol, 3-ethyl-9-nonen-1-ol, 2-methyl-10-undecen-2-ol, 2,2-dimethyl-7-octene-1 -ol, 3 -ethyl-2-methyl-8-nonen-1-ol, 2,2,3-trimethyl-9-nonen-1-ol and 2,3,3,4-tetramethyl-10 _ undecen-2-ol; glycols such as 9- Alkene-1,2_diol, 10-undecene-1,2-diol and 11-dodecene-1,2-diol; and this paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------------------- Order --------- line (please read the notes on the back and fill out this page) Economy Ministry of Intellectual Property Bureau employee consumption cooperative printed 149 1290149 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed A7 B7 V. Description of invention (15〇) Triols, such as 10 -11-dilute-1,2,3-triol . Examples of the polar group-containing monomer in which X' is -CHO in the formula (7,) include: ω-mercaptoacids such as 5-hexenal, 6-heptenal, 7-octenal, 8-decene Aldehyde, 9-nonenal, 10-epean acid, and 11.12 acid; alkenyl aldehydes having a linear hydrocarbon group, such as 2-methyl-5-hexenal, 2-methyl-6 _heptenal, 2-methyl-7-octenal, 2-methyl-8-nonenal, 2-methyl-9-nonenal, 2-methyl-10-undecenal, 2-methyl-11-dodecenal, 2-ethyl-5-hexenal, 2-ethyl-6-heptenal, 2-ethyl-7-octenal, 2-ethyl- 8-furfural, 2-hexyl-9-nonenal, 2-ethyl·10·undecenal, 2-propyl-5-hexenal, 2-propyl-6-heptenal , 2-propyl-7-octanoic acid, 2-propyl-8-indole acid, 2-propyl-9-indole acid, 2-propyl-10-undecanoic acid, 2-butyl -5-Hard, 2-butyl-6-heptone, 2-butyl-7-octanoic acid, 2-butyl-8-indole acid, 2-butyl-9-indole acid And 2-butyl-10-undecenal; alkenyl aldehydes having a branched hydrocarbon group, such as 2-isopropyl-5-hexenal, 2-isopropyl-6-heptenal, 2- Isopropyl-7-octenal, 2-isopropyl-8 -nonenal, 2-isopropyl-9-nonenal, 2-isopropyl-10-undenal, 2-isobutyl-5-hexenal, 2-tert-butyl-6 -heptenal, 2-isopropyl-3-methyl-7-octenal, 2-methyl-3-isopropyl-8-nonenal, 3-isobutyl-3-methyl- 9-nonenal, 2,2-dimethyl-10-undecenal and 2,2,3-trimethyl-11-dodecenal. Examples of the polar group-containing monomer in which X' is -COOH in the formula (7,) include: The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 150 312991 -------- Order ---------line (please read the note on the back and fill in this page) A7 B7 1290149 V. Description of invention ((5) ω-alkenyl carboxylic acids, such as acrylic acid, 5-hexenoic acid , 6-heptenoic acid, 7-octenoic acid, 8·decenoic acid, 9-fluorene acid, 10-undecenoic acid and 11-dodecenoic acid; alkenyl tremologies having a linear hydrocarbon group, for example 2-methyl-5-hexenoic acid, 2-methyl-6-heptenoic acid, 2-methyl-7-octanoic acid, 2-methyl-8-decenoic acid, 2-methyl-9 _decenoic acid, 2-methyl-10-undecenoic acid, 2-methyl-11-dodecenoic acid, 2-ethyl-5-hexenoic acid, 2-ethyl-6-heptenoic acid , 2-ethyl-7-octenoic acid, 2-ethyl·8-decenoic acid, 2·ethyl·9·decenoic acid, 2-ethyl-10-undecanoic acid, 2-propyl -5-hexamic acid, 2-propyl-6-glycidic acid, 2-propyl-7-octenoic acid, 2-propyl-8-decenoic acid, 2-propyl-9-decenoic acid , 2-propyl-10·undecic acid, 2-butyl-5-hexanoic acid, 2-butyl-6-glyoxylic acid, 2·butyl-7-octyl Alkenoic acid, 2-butyl-8-decenoic acid, 2-butyl-9-decenoic acid and 2·butyl-10-undecic acid; alkenyl carboxylic acids having a branched bond hydrocarbon group, for example 2- Isopropyl-5-hexanoic acid, 2-isopropyl-6-heptanoic acid, 2-isopropyl-7-octenoic acid, 2-isopropyl-8-decanoic acid, 2·isopropyl 9-decenoic acid, 2-isopropyl-ίο-undecenoic acid, 2-isobutyl-5-hexanoic acid, 2-tert-butyl-6-glyoxylic acid, 2-isopropyl 3-methyl-7-octenoic acid, 2-methyl-3-isopropyl-8-decenoic acid, 3-isobutyl-3-methyl-9-decenoic acid, 2,2 - dimethyl-10-undecenoic acid and 2,2,3-trimethyl-11-dodecenoic acid. Examples of the polar group-containing monomer wherein X is an oxy group in the formula (7) include: ω- Alkenyl epoxides, such as 5-hexene epoxide, 6-heptene epoxide, 7-octene epoxide, this paper scale applies to the Chinese National Standard (CNS) A4 specification (2) G X 297 public ) — ------- 312991 t (Please read the notes on the back and fill out this page) Order---------Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed Clothing 151 1290149 A7

8_decene epoxide, 9-decene epoxide, 10-undecene epoxide and η-dodecane epoxide; and decene% emulsion and alkenyl epoxy having branched hydrocarbon group Compounds such as 2-methyl-5-hexene epoxide, 2-methyl-6-hepte epoxide, 2-methyl-7-octyl epoxide, 2-methyl-8-decene Epoxide, 2-methylanthracene epoxide and 2-methyl-1-indene epoxide. • OOr (8) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing system, where R7, R8, γ, m, n and s have the same meanings of r7, r8, Y, 111, 11 and 8 in formula (6), respectively. In the above formula (8), R7 and R8 are preferably a direct bond or a hydrocarbon group having 1 to 10 carbon atoms, and Y is preferably _〇R, -C〇〇R, _CR〇, _NR2, epoxy group, l, "°| (R is an argon atom or a hydrocarbon group), -C^N, -OH, _c〇〇H or NH2. Examples of the polar group-containing monomer represented by the formula (8) wherein Y is -OR (R is a hydrogen atom or a hydrocarbon group) include: a bicyclic monoether such as the paper size applicable to the Chinese National Standard (CNS) A4 specification (210 X 297) ) 152 312991 -------------------- Order ---------. (Please read the notes on the back and fill out this page) 1290149 Α7 Β7 V. Invention description (153) or σ CH2OCH3

(X ch2och3

CH 3 ch2ch2och3 or ch2ch2ch2och3

(CH2) 4och3

( CH2) 5och3 CH2) 6OCH3

Ir(T ch2)7och3 —------------------ Order --------- Line 11^. (Please read the notes on the back and fill in this Page) Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumption Cooperative, Printed Clothes

This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 153 312991 1290149 A7 B7 V. Description of invention (154)

(Xor (X

Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing

(X ΙΑ, och3 , ch2ch2ch3 CK ^^ch2ch3 ^ch2och3 , ch2ch2ch3 ^^^ch2ch2och3 xCH2CH2OCH3 , ch2ch3 广介 / CH2CH2OCH3 ^ch2ch2ch2och3 , ch3 •och2ch3 ^CH2CH2CH〇0CHq 〇C3 ^OCHoCHoCHo or och2ch2ch2och3 ^ch2ogh〇gh3 〇r ch2och2ch2ch3 ^ ^s^-CH2〇CH2CH2CH2CH3 Bicyclic diethers such as this paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 154 312991 dtr---------#·· (Read first Note on the back page of this page) 1290149 A7 B7 Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperatives, Printing 5, Inventions (155)

Ch2och3

OCH 3 ch2ch2ch2och3 ch2och3

aCH2CH2OCH3 ch2ch2och3 CH2OCH3 tetracyclic monoethers such as

OCH 3 OCHq

-------------------- Order --------- Line WV. (Please read the note on the back and fill out this page)

This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 155 312991 1290149 A7 _B7 V. Description of invention (156), and tetracyclic diethers such as

------------- (Please read the note on the back and fill out this page) Y is a polar group represented by formula (8) of -COOR (R is a hydrogen atom or a hydrocarbon group) Examples of monomers include: Bicyclic carboxylic acid esters such as order---------Line · Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed clothing paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 156 312991 A7 1290149 B7 V. Description of invention (157)

-------------螓(Please read the notes on the back and fill out this page) Order---------Line - Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed^ \^cooch3 〇C3 This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 157 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (158)

CH2COOCH3 h2ch3ch2ch2cooch3 ch3ch2ch2cooch3:h2ch2ch3

Or COOCH2CH2CH2CH3 bicyclic dicarboxylates such as this paper scale applicable to China National Standard (CNS) A4 specification (210x 297 mm) 158 312991 in na·^—i_^i ·_1 1 HI in n- · · 1 flu In — ϋ I ·_ϋ 1* _1 n Hi 1>- n ϋ·. I (Please read the notes on the back and fill out this page) 1290149 Α7 Β7 V. Invention description (I59)

H2cooch3 COOCH3 ^\^^COOCti2CH3(κ ^VsNs^CH2CH2COOGH3 _ch2ch2cooch3 ί ΤΓ

(Please read the notes on the back and fill out this page.) Tetracyclic monocarboxylates such as

OOCH 3

Cooch3 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperatives print leftovers

Ch2cooch3

This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 159 312991 A7 B7

(Please read the precautions on the back and fill out this page) 1290149 V. INSTRUCTIONS (160) Tetracyclic dicarboxylates such as

OOCH -cooch3 3

And anhydrides such as

An example of a polar group-containing monomer represented by formula (8) in which 160 Y is -CRO (R is a hydrocarbon group) is contained in the Intellectual Property Office of the Ministry of Economic Affairs. The bicyclic ketones such as this paper scale are applicable to the Chinese National Standard (CNS). ) A4 size (210 x 297 mm) 312991 1290149 Λ7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (161)

€OCH3

Ch2coch3

Ch2goch3

CH 3

(X Ο" ch2) 6coch3 ch2)8coch3

(CH2)7COCH3

(X CH2) 9coch3 ------------------------ Order---------Line (Please read the notes on the back and fill out this page)

Coch2ch3

CH 3

COGH3 ch2ch3 This paper size applies to China National Standard (CNS) A4 specification (210 x 297 mm) 161 312991 1290149 Λ7 Β7 V. Invention description (162)

orH3 (Please read the notes on the back and fill out this page) t Order---------Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing

Or, or cy ch2ch2coch3 ch2ch3 ch2ch2ch2coch3

3

Ch2ch3 ch2ch2coch3 ch3 ch2ch2coch3 ch2ch2ch3 :h2ch2ch2coch3 :h2ch3 coch2ch2ch3 coch3ch2ch2ch3 ch2coch2ch2ch3 bicyclodiketones For example, this paper size is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) ch2coch2ch3 ch2coch2ch2ch2ch3 162 312991 1290149 A7 B7 V. Description of invention ((6)

Ch2coch3 COCH3 CH2CH2CH2COCH3 ch2coch3

^^^ch2ch2coch3 _ch2ch2coch3

,ch2coch3 ch2coch3 ch2)4coch3 coch2ch3 h2ch2coch3 ch2coch3 tetracyclic ketones such as

Coch3 COCH,

COCH 3

Ch2coch3 n ϋ ϋ ϋ · ϋ .1 ϋ ( ι ϋ n ϋ r · ϋ ϋ ϋ ϋ ϋ n TJ II mmmew tmmm I ϋ n I / €^1 < 言^ (Please read the notes on the back and fill in this Page) ch2ch3

This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 163 312991 A7

1290149 B7 V. Description of invention (164), and tetracyclic diketones such as

Examples of the polar group-containing monomer represented by the formula (8) wherein Y is -NR2 (R is a hydrogen atom or a hydrocarbon group) include: a bicyclic amine such as ---------------- ---Order---------Line (please read the note on the back and fill in this page again) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed on the paper size applicable to China National Standard (CNS) A4 size (210x 297 mm) 164 312991 1290149 A7 B7 V. Description of invention (165)

〇r〇r(T 〇r CH2N(CH3)2

CX CH2N(CH3)i

CH 3 CH2CH2N(CH3)2 CH2)4N(CH3)2 cror CH2CH3CH2N (CH3) 2 (CH2)5N(CH3)2

(CH2)7N(CH3)2

(ch2)8n(ch3)2

, (ch2)9n(ch3)2 --------------------Book --------- Line "11^· (Please read the back first Note: Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed This paper scale applies China National Standard (CNS) A4 specification (210 X 297 mm) 165 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumption Cooperative Printing 5, invention instructions (166)

•N(CH3)2 ch2nhch3 H2N(CH2CH3)2 CH 3

Ch2nhch2ch3 bicyclic diamines such as - ch2n(ch3)2 ‘CH2N(CH3)2 ch2nhch3 -CH2N(CH3)2 -ch2ch2n (ch3) 2 , ch2ch2n(ch3)2

Tetracyclic amines such as

Ή2ν (CH2CH3) 2

CH2N(CH2CH3)2 CH2)3N(CH2CH3)2 ch3) 2nhch3 (Please read the notes on the back and fill out this page)

CH2N(CH3)2 n(ch3)2 ^xw^ch2nhch3(X, ^ch2nhch3 aCH2CH2N(CH3)2 c -CH2N(CH3)2 This paper scale is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 166 312991 1290149 Λ7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printing V. Inventions (167)

N(CH3)2

N(CH3)2

N(CH3)2 ch2ch3 ch2n (CH3) 2

CH2N(CH3)2

CH2N {CH3) 2 ch2ch3 and tetracyclic diamines such as

-CNR2 N(CH3)2 ^^/华3)2 N(CH3)2 \ch2n(ch3)2 CH2N(CH3)2 CH2CH2NH2 CH2N(CH3)2 \ch2n(ch3)2 Y is II (R is a hydrogen atom Or an example of a polar group-containing monomolecular group represented by the formula (8): a bicyclic guanamine such as the paper size applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 167 312991 --- -----------------Book---------Line (please read the note on the back and then fill out this page) 1290149 A7 B7 V. Invention Description ) ^^^οονη2 ^^n^ch2conh2 (F 〇j

Ch2conh2

CH 3 or cr or or h2ch2conh2 ch2)4conh2 ch2) 6conh2 CH2)8CONH2 (T(X π cr h2ch2ch2conh2 CH2)5CONH2 ch2)7conh2 ch2)9conh2 (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office The employee consumption cooperative printed this paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 168 312991 1290149 A7 B7 V. Invention description (I69) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed clothing

CH2CON(CH2CH3)2 CH2CHCON(CH3)2 -------------------- Order---------Line (please read the notes on the back first) Fill in this page)

Ch2conhch3

€H2C (CH3) 2ch3conh2

CH 3

CH2CONHCH2CH3

CH 3 bicyclic diamines such as this paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 169 312991 1290149 Α7 Β7 V. Description of invention (mouth)

Ch2conh2

CONH 2 aCH2CH2CH2NH2

CH2CONH2 CH2CH2CONH2 CH2CH2CONH2

CH2)4CONH2 CONH

CH2CH2CONH2 ch2conh2 2 (Please read the note on the back and fill out this page) Tetracyclic guanamines such as

This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 170 312991

1290149 A7 _B7 V. INSTRUCTIONS (171) Tetracyclic diamines such as

Examples of the polar group-containing monomer represented by the formula (S) wherein Y is °| (R is a hydrogen atom or a hydrocarbon group) include: a bicyclic ester such as ------------ «---- ----1T--------- ί (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Bureau, Employees, Consumer Cooperatives, Printed Paper Scale, Applicable to China National Standard (CNS) A4 Specifications (210 X 297 mm) 171 312991 1290149 Λ7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (172)

(Τ

€H2OCOCH3

CH 3

(Please read the notes on the back and fill out this page) ch2) 6ococh3 <ch2) 8ococh3 cr

^ococh2ch3 cc

OCOCH3 €H2CH3 This paper size is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) CH2) 7ococh3 (ch2)9ococh3

OCOCH 3 ch2ch2ch3 172 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description ((7)

(X〇rc

CH2) 3OCOH

QTc〇H

OCOCH2CH2CH3

Ch2ococh2ch3

, ch2ococh2ch2ch2ch3 bicyclic diesters such as

Ococh2ch2ch2ch3 or ,ch2ococh2ch2ch3 --------------------Book --------- Line IJI. (Please read the notes on the back and fill out this page) This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 173 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (174)

Ch2ococh3

OCOCH

Ch2ococh3 ch2ococh3 3

Tetracyclic esters such as

Coch3

Coch3 ch2ch3 :h2ococh3 ch3 h2ch2ococh3

COCH 3

H2ococh3

CHoCH, ch2ch2ococh3 -------------------- Order ---------^9. (Please read the notes on the back and fill out this page) The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 174 312991 A7 1290149 B7 V. Inventions (175), and tetracyclic diesters such as

Examples of the polar group-containing monomer represented by the formula (8) wherein Y is -C three N include: a bicyclic nitrile such as ------------------- ------- Line (please read the notes on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed This paper scale applies to China National Standard (CNS) A4 specification (210x 297 mm) 175 312991 1290149 Λ7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printing V. Inventions (176)

QT or h2ch2cn

iT or(X ch2) 8cn

Ch2cn

H2cn

CH 3

( CH2 ) 7cn or CH2)9cn (Please read the notes on the back and fill out this page) oc or ch3 \ch2ch3

CN ch2ch2ch3 This paper scale is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 176 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing acupuncture clothing 5. Invention description (177)

Ch2cn ch2ch3 ch2ch2cn ch3 ch2ch2cn h2ch2ch3 ch2ch2ch2cn ch2ch3

(Please read the notes on the back and fill out this page)

a σ' CH3CH(CN)CH3

H(CN)CH2CH3 CH2C (CH3) 2ch2cn Bicyclic dinitrile For example, this paper scale is applicable to China National Standard (CNS) A4 specification (210x 297 mm) 177 312991 1290149 A7 B7 V. Description of invention (claw)

aCH2CH2CN ch2ch2cn

(Please read the notes on the back and fill out this page.) Tetracyclines such as

CH2CH3

This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 178 312991 A7 1290149 B7 V. Description of invention (179) Tetracyclic diterpenoids such as

Examples of the polar group-containing monomer represented by the formula (8) wherein Y is -OH include: bicyclic alcohols, for example (please read the back of the note first and then fill in this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed this paper The scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 179 312991 1290149 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed B7

(Please read the note on the back and fill out this page.) The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 mm). 180 312991 1290149 A7 B7 V. Description of the invention ((8)

(X

Ch2oh ch2ch3 ch2ch2oh ch3 ch2ch2oh ch2ch2ch3 ch2ch2ch2oh ch2ch3 CH(OH)CH3 cx ch2oh ch2ch2ch3

Or CH (OH) CH2CH3 〇r H2CH(OH)CH3

CH(OH)CH 3 ch3

CH (OH) CH2CH3

CH2C(CH3) 2ch2oh —------------------- Order---------Line (please read the notes on the back and fill in this page) Double Ring Glycols such as the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperatives, printed paper scales, applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) 181 312991 1290149 A7 B7 V. Description of invention ((8))

(X ch2oh ch2oh

0C (X

0H

CH2) 4OH

OH

CH2CH20H ch2oh (please read the notes on the back and fill out this page) Tetracyclines such as

Printed by the Consumers’ Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs and

Ch2oh

Tetracyclic diols such as this paper scale apply to China National Standard (CNS) A4 specifications (2) 297 297 mil. 182 312991 1290149 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description ((8))

Examples of the polar group-containing monomer represented by the formula (8) wherein Y is -COOH include: a bicyclic monocarboxylic acid such as

------------麴--------π---------Line 丨· (Please read the notes on the back and fill out this page) Applicable to China National Standard (CNS) A4 specification (2〗 297 297 mm) 183 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (w

COOH

CH

(T 3 ch2cooh h2ch3 ch2ch2cooh ch3 ch2ch2cooh ch2ch2ch3 ch2ch2ch2cooh ch2ch3 H (COOH) CH2CH3

CH(COOH)CH3

CH 3

:H2CH2COOH

Ch2ch3 ch2gh2ch2cooh or (please read the notes on the back and fill out this page) or

H2C(CH3)2CH2COOH bicyclic dicarboxylic acids such as

CH 3 CH(COOH)CH〇

This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 184 312991 1290149 Λ7 B7 V. Description of invention ((8))

(X

Ch2cooh ^ XVs^CH2C00H ch2cooh s^/^COOH ch2ch2ch2cooh if , ch2cooh k JL , COOH CHoCHoCOOH if ^Sv^ch2ch2cooh , CH2CH2COOH , JL 'CH, COOH (please read the note on the back and fill out this page) Tetracyclic carboxylic acids E.g

00H

00H Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing and

H2COOH

H2cooh ch2ch3 H2€H2COOH ch2ch3 Tetracyclic dicarboxylic acid such as this paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 185 312991 A7 1290149 B7 V. Invention description (186)

Examples of the polar group-containing monomer represented by the formula (8) in which Y is -CHO include: Bicyclic aldehydes (for example, please read the back of the note and fill in the page) The Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, printed this paper. The scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 186 312991 A7 1290149 B7 V. Description of invention (187) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative prints

---------------------- Order.-------- Line · (Please read the notes on the back and fill in this page) Paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 187 312991 1290149 Λ7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 5, invention description (m) _ch2cho ch2ch3 ch2ch2cho ch3 cc

(X

Ch2cho ch2ch2ch3 ch2ch2cho ch2ch3

Or ch2ch2ch2cho ch2ch3 ch(cho)ch2ch3

(X H(CHO)CH3 CH2CH{CH0)CH3 (Please read the notes on the back and fill out this page)

CH(CHO)CH3

CH 3

Ch(cho)ch2ch3

CH 3 CH2C (CH3) 2ch2cho Cyclodialdehydes such as this paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 188 312991 1290149 Λ7 B7 Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed clothing five, invention Description ((10))

Ch2cho ch2cho

0C (X (X

CHO CH2) 4cho

CHO CH2CH2CHO ch2cho tetracyclic aldehydes such as

CH〇CH ch2cho -------------------- order --------- line "1^^- (please read the notes on the back first) Fill in this page) and

3 CH2CH2CHO

Tetracyclic dialdehydes such as this paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 189 312991 1290149 A7 B7 V. Description of invention (l9〇)

Examples of the polar group-containing monomer represented by the formula (8) wherein Y is -NH2 include a bicyclic monoamine such as #· 1 ϋ amMmw ai n. Hi eBia 1 ^ n ·· ί§ ϋ I—I—I - (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Office, Staff and Consumer Cooperatives Printed on this paper scale Applicable to China National Standard (CNS) A4 Specification (210 x 297 mm) 190 312991 1290149 Λ7 B7 V. Description of the invention (191)

/V^ch2nh2 QT 〇c -------------------- Order --------- line (please read the notes on the back and fill out this page Printed by the Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative

(T σ

H2ch2nh2 (CH2) 4nh2 (CH2)8NH2

(X CJ (X QT gh2ch2gh2nh2 ac;: ac NHo ch2ch3 ac ch2ch2ch3 This paper scale applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 191 312991 1290149 A7 B7 V. Invention description (192) Ministry of Economics intellectual property Bureau employee consumption cooperative printing

Bicyclic diamines (for example, please read the notes on the back and fill out this page) This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 192 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumption Cooperative Printed five, invention description (193)

^>s^CH2NH2 (X ^ch2nh2 or ch2nh2 NH,

Tetracyclic monoamines such as

ϋ 1 n ϋ n —.1 I l ϋ ·ϋ n · ·ϋ ·ϋ ϋ n n I— I I I_1_1 n 1_1 -i-i -m 1 (Please read the back note and fill out this page)

Ch2ch2nh2

This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 193 312991 1290149 A7 V. Description of the invention (I94) and tetracyclic diamines such as fine 2

Ch2nh2

-------------%.! (Please read the phonetic transcription on the back? Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives printed in the present invention 'may also be polyene Inviting, α·olefins and polar JI 共聚 copolymerization. Examples of polyenes are olefins having an aliphatic ring or a monomeric group, such as terpene or cycloheptene ' 2 -methyl-1, 4, 5 , 8_ dimethyl & τ 1 戍 、, styrene and vinyl ring appearance; chain or ring dilute, such as butyl isodecadiene, Μ hexadiene, dicyclopentadiene, 5 _ Ethyl-2-prosthetic, 7-methyl-indene dioctyl, chain or cyclic tri-contained, for example, 61 〇 _ dimethyl]" undecane triene and 5,9-dimethyl hydrazine , 8 decane trisap; and chain or ring tetra, ene, such as 6,10,14-trimethyl-1,5,9513-pentadecanedetene and 5,9,13 = methyl_1,4 , 8, 12-tetradecenetetraene in the first method according to the present invention, in the presence of the aforementioned olefin polymerization catalyst and under the polymerization conditions described below, selected from at least the above-mentioned a-olefin having 2 to 20 carbon atoms An alkenyl group-containing monomer represented by the formula (7) and/or a monopolar group-containing monopolymer represented by the formula (8). The paper in the formula (7) is X and 式 and the paper size in the formula (8) is applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 194 312991 s.--------- Line · 1290149

V. Description of Invention (195) When the Employees' Consumer Cooperative of the Ministry of Economic Affairs printed the 195 monomer of -OH, it is preferred to use the transition metal compound (A) represented by any one of the formulas (1) to (16). More preferably, the transition metal compound (A) represented by any one of the formulae (n) to (15) is used. When the polar group-containing monomer is in the formula (7), χ is -NR R (R and R may be the same or different from each other, a nitrogen atom and an alkyl group) and Y in the formula (8) is -NR2 (R) When it is a monomer of hydrogen or an alkyl group, it is preferred to use the transition metal compound (a) represented by any one of the formulae (U) to (16), and it is more preferred to use the formula (11), (12), ( 14) The transition metal compound (A) represented by any one of (15) and (16). In the method for producing a polar group-containing copolymer according to the first embodiment of the present invention, a polar group type and a reaction condition can be utilized. Alternatively, the polar group is selectively introduced into the terminal or main chain of the polymer chain. Further, the characteristics of the polar group-containing polymer can be varied by using two or more olefins during polymerization. The metal compound (A) and/or the polar group-containing monomer is first contacted with the organoaluminum compound, so that the deactivation of the catalyst is as low as possible due to the functional group-containing monomer. When the compound is contacted, there is a method of contacting the compound before it is added to the polymerization system, and another method is to The two components are successively added to the polymerization system, and either method can be used. When the transition metal compound is brought into contact with the organoaluminum compound, there is a method of contacting it before adding it to the polymerization system, and another method is to combine the two components. Addition to the polymerization system, either method can be used. In the polymerization reaction, the amount of the transition metal compound (A) is 1 liter of polymerization volume, and in terms of transition metal atoms, usually about GO QQ 05 to 〇1 This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------------------- Order --------- Line (please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 196 1290149 A7 __B7 V. Invention Description (196) mm ο 1 ' It is preferably about 0.0001 to 〇.〇5 mmol The amount of the organic oxy compound (B-1), based on the 1 m〇i transition metal atom, is such that the amount of the atom is usually about i to 1 〇〇〇〇 mol, preferably 10 to 5,000 mol. The amount of ionized ionic compound (B-2), based on 1 mol of transition metal atom The amount of the atom is usually from about 0 to 500 mol, preferably from 1 to 100 mol. The amount of the organic compound (B_3) is, based on 1 m〇1 of the transition metal atom, the amount of the aluminum atom is usually From about 1 to 500 m〇l, preferably from about 20 to 200 mol ° When an organoaluminum oxy-compound (B-1) and an organoaluminum compound (Β·3) are used in combination, an organoaluminum oxy-compound (B- 1) In the case of 1 m〇1 aluminum atom, the amount of the organic compound (B_3) is usually about 200 mol, preferably about 0 to 100 mol, when necessary. When the ionized ionic compound (B-2) and the organoaluminum compound (B-3) are used in combination, an organoaluminum compound is required as needed, based on 1 mol of the boron atom in the ionized ionic compound (B-2) The amount of B-3) is usually from about 0 to 1000 mol, preferably from about 〇 to 500 mol. When the organic hydrazine compound (C) is used, it is used in an amount of from 1 to 10,000 mol, preferably from 1 to 5 mol%, based on 1 m〇i of the transition metal atom. When a dicalcium-based zinc compound is used ( When D) is 1 m〇i transition metal atom, the amount of the compound is 1 to 10000 mol, preferably 1 〇 to 5000 mol ° when SL is used, '1 mol of olefin used in the polymerization reaction and basic polarity The paper scale applies to the Chinese National Standard (CNS) A4 specification (21〇X 297 metric tons) 312991 ------------€--------Set-------- -Line· (Please read the note on the back and fill in this page) 1290149 Α7 ___ Β7 V. Invention description (197) Total amount of monomers 'Hydrogen is 1〇-5 to 1 m〇, preferably 1〇 _4 to 1〇-1 mol ° The ratio between the polar group-containing monomer and the transition metal atom is not particularly limited, but the molar ratio of the polar group-containing/transition metal atom is usually from 1/100 to 10,000. /1, preferably 1/10 to 5000/1, in the park. The copolymerization of an olefin with a polar group-containing monomer can be carried out by any one of a liquid phase polymerization method (e.g., suspension polymerization or solution polymerization), a gas phase polymerization method, and a high pressure method. In the liquid phase polymerization, an inert hydrocarbon medium is used, examples of which include aliphatic hydrocarbons such as propane, butane, pentane, hexane, heptane, octane, decane, eleven and kerosene; alicyclic hydrocarbons For example, cyclopentane, cyclohexane and methylcyclopentane; aromatic hydrocarbons such as benzene, toluene and xylene; and self-generated hydrocarbons such as diethylene bromide, gas benzene and diqi methane. The olefin itself can be used as a solvent. These solvents can be used in combination. When the suspension polymerization is carried out, the polymerization temperature is usually in the range of -50 to 10 ° C, which is in the range of 0 to 90 ° C; in the case of solution polymerization, the polymerization temperature is usually 0 to 300 ° C, preferably 2 Torr. To the range of 25 (rC; when performing gas phase polymerization), the polymerization temperature is usually from 0 to 12 (rc, preferably from 2 Torr to 1 Torr (in the range of rc). When the high pressure method is carried out, the party temperature is usually 5 聚会. It is preferably in the range of 100 to 500 ° C. The polymerization pressure is usually in the range of normal pressure to ι 〇〇 kg / cm ', preferably from atmospheric pressure to 5 〇 kg / cm 2 . In the case of the method, the polymerization pressure is usually in the range of 1 Torr to 1 〇〇〇〇 kg/cm 2 , preferably 5 Å to 5,000 kg/cm 2 . The polymerization reaction can be carried out in a batch type, a semi-continuous mode and Any one of the continuous methods can be carried out. In addition, the polymerization reaction can be used in the absence of the Chinese National Standard (CNS) A4 specification (21〇χ 297 mm) 312991 --------- ----€ (Please read the notes on the back and fill out this page) Order---------Line· Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative print 197

5. Description of the invention (m 1290149 is carried out in two or more steps under the same reaction conditions. The molecular weight of the obtained polar olefin-containing copolymer can be controlled by controlling the amount of the gas generator compound or the dicalcium-based zinc compound or changing the polymerization pressure. The method for producing a polar group-containing copolymer according to the first embodiment of the present invention comprises the following composition: (A) a transition metal compound, and (B) at least one compound selected from the group consisting of: (B-1) organoaluminum oxide a base compound, (Β·2) reacts with the compound (A) to form an ion pair compound, and (Β-3) an organoaluminum compound in the presence of a catalyst to make a dilute smoke having 2 to 20 carbon atoms The polar group-containing monomer represented by the formula (7") and/or (8') is copolymerized. CH2=CH_R3'X"p (7") wherein R3 is a hydrocarbon group having 2 or more carbon atoms, X " is -qkqor, ' _C(0)NR2, -0C(0)R (R is a hydrogen atom or a hydrocarbon group), an epoxy group, -CEN or _NH2, and p is a positive integer of 1 to 3. Formula (7) The polar group-containing monomer is, for example, a group other than _〇H and _NR2 among the polar group-containing monomers represented by the above formula (7').

·· (8M This paper scale applies Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------- order --------- line (please read the back of the note first) Matters to fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employees consumption cooperatives printed 198

1290149 V. INSTRUCTION DESCRIPTION (1") wherein R7 is a direct bond or an aliphatic hydrocarbon group having one or more carbon atoms, and R8 is a hydrogen atom, a direct bond or an aliphatic hydrocarbon group having one or more carbon atoms, γ, Is _0R, -COOR, -CRO, -C(0)NR2, -〇c(〇)R (R is a halogen atom or a hydrocarbon group), an epoxy group, -c Ξ N or -NH2, and m and n are each An integer from 0 to 2 'm+n is not 〇, and s is 0 or 1. The polar group-containing monomer represented by the formula (8') is, for example, a group other than _〇H and -NR2 in the polar group-containing monomer represented by the above formula (8). These polar group-containing monomers may be used singly or in combination of two or more. The polymerization conditions were the same as used above. Next, a process for producing a polar group-containing olefin copolymer according to a second embodiment of the present invention will be explained below. The process for the polar-containing dilute hydrocarbon copolymer according to the second embodiment of the present invention is included in the composition comprising the following composition: (A) selected from Group 3 of the periodic table (including lanthanides and fishing elements) to the first! The compound of the steroid transition metal is preferably a transition metal compound represented by any one of the above formulas (11) to (15), and (B) at least one compound selected from the group consisting of: (B-1) organoaluminum The oxy compound, (B-2) is reacted with the compound (A) to form an ion pair compound, and (B-3) is an organic olefin polymerization catalyst in the presence of an olefin polymerization catalyst, and is selected from α having 2 to 20 carbon atoms. At least one α-olefin of an olefin, a macromonomer represented by the following formula (9), and a polar group-containing monomer selected from the above formula (7) and a polar group-containing monomer represented by the above formula (8) At least one polar group-containing monomer is copolymerized. This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 public meals) 312991 -------------------- Order --------- Line ^9 (Please read the note on the back and fill out this page) Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative 199

1290149 Λ7 _B7_ V. Description of invention (200) ch2=ch (W^-fR^r-fO-Zjp (9) where R5, R6, Z, W, p, q, and r have the formula (4) The same meanings of R5, R6, 2, B, 9, 9 and 1*. When the polar group-containing monomer represented by the formula (7) is used as the polar group-containing monomer of the present invention, the aforementioned invention is obtained. Two specific examples of the polar group-containing olefin copolymer. The macromonomer represented by the formula (9) contains the following macromonomers: -------------------- Order-- -------Line« (Please read the notes on the back and fill out this page)

This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm). 200 312991 1290149 A7 V. Description of the invention (2〇1

Printed by the Ministry of Economic Affairs, the Intellectual Property Bureau, and the Consumer Cooperatives. The macromonomer can be prepared, for example, by using a polar monomer (described below). In particular, the macromonomer can be utilized by anionic polymerization, ring opening polymerization or polycondensation, similar to method (i) below, to include The polar group of the polar group monomer is used to prepare a polymer segment. The copolymerization reaction of the α-olefin having 2 to 20 carbon atoms with the macromonomer represented by the formula (9) is carried out by using the «-olefin having 2 to 20 carbon atoms and the formula (1) shown in the following method (1) The same olefinic polymerization catalyst used for the copolymerization reaction of a polar group-containing monomer, copolymerization of an α-olefin having 2 to 20 carbon atoms in the following method (1) with a polar group-containing monomer represented by the formula (1〇) It is carried out under the same conditions as used. In the preparation method of the polar group-containing copolymer according to the second embodiment of the present invention, the at least one paper size of the α-olefin having the above 2 to 20 carbon atoms is turned over (CNS) A4 secret (10); Public *- 201 312991 ------------.----------- (Please read the notes on the back and fill out this page) 1290149 V. Invention description (2 〇2) an olefin, the macrotype represented by the formula (9), which comprises at least one polar-containing precursor of the polar-containing monomer represented by the formula (8) represented by the formula () In the presence of the above-mentioned smoky polymerization catalyst, the polymerization is carried out under the same conditions as in the preparation of the polar olefin-containing copolymer according to the first and the shale: the polar-containing dilute-smoke copolymer according to the third embodiment of the present invention The physical system is comprised of the following composition: (A) a compound selected from Group 3 of the Periodic Table (including lanthanides and actinides) to a transition metal of the ι〇 group, and (B) at least one compound selected from the group consisting of · (B-1) organoaluminum oxy-compound, (B-2) reacts with compound (A) to form an ion pair compound, and (B-3) organoaluminum compound line In the presence of a medium, at least one olefin selected from the group consisting of olefins having 2 to 20 carbon atoms, a polar group-containing monomer represented by the following formula (10) (hereinafter also referred to as "polar group-containing monomer (10)", And, if necessary, the polar group-containing monomer represented by the above formula (8) is subjected to copolymerization reaction: Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, printed ch9=ch (R6)m-(W>n • (10) Wherein R5, R6, m, w and η have the same meanings of R5, R6, m, w and η in the formula (5); respectively, and then any one of the following steps (1) and (ii) is carried out to prepare a branched chain type Polar group-containing olefin copolymer·· This paper scale is applicable to China National Standard (CNS) A4 specification (210 x 297 mm). 202 312991 1290149 V. Description of invention (2〇3) (1) Using anionic polymerization, ring-opening polymerization or By polycondensation, the w portion of the copolymerized polar group-containing monomer (1〇) is formed into a z moiety; (8) the % portion of the copolymerized polar group-containing monomer (1()) is used in combination with the benefit == Polymer produced by polycondensation: The method (1) is described in detail below. In the method (1), the system will have 2 to 2 carbon atoms. The olefin oxime contains a polar group monomer (10), and optionally contains a polar group represented by the formula (8); copolymerizes ' to prepare a functional group-containing olefin copolymer, and then uses an anion polymerization, ring-opening polymerization or Polycondensation, from the copolymerization of the polar group contained in the W portion of the manganese monomer, to form a polymer segment (Ζ). If the constituent unit from the functionally-containing dilute hydrocarbon copolymer [the constituent unit is self-contained with polarity The polar group contained in any one of the monomers (10)]w forms a polymer segment, and the constituent unit becomes a constituent unit (4) from a constituent unit of the functional group-containing dilute smoke copolymer [the constituent unit is derived from The monomer of the polar group (1G)] any of the W groups does not form a polymer segment, and this constituent unit becomes a constituent unit (7). Examples of the hydrocarbon having 2 to 20 carbon atoms, such as ethylene, propylene, 1-butene, butene, terpene, 3-methylbutene, i.hexene, and 4-methyl· Pentylene, 3·methyl-pentene, 3-ethyl + pentane, 4,4, dimethyl 1:1 pentene, 4-methyl hexene, 4,4 dimethyl dimethyl Alkene, 4 ethyl 2 hexaploid, 3-ethyl-1-hexene, octene, 1-decene, "- twelve rare, four rare, h sixteen, forty eight rare, twenty rare. Among them, it is better to choose Dilute, Alkene, Budden and the paper scale for the Zhongguanjia Standard (CNS) A4 specification (2) Q χ 297 public £^---卞埽 203 line 312991 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative Printed 204 1290149 A7 B7 5. At least two alpha-anthracene hydrocarbons of the invention description (2〇4). Examples of the polar group-containing monomer (10) include: a compound of the formula (10) wherein W is a hydroxyl group, in detail an ω-alkenyl alcohol such as 4-penten-1-ol, 5_hex En-1-ol, 6-hepten-1-ol, 7-octene-1-ol, 8-decen-1-ol, 9-nonen-1-ol, 10-undecene-1- Alcohol and 11 - dodeca-1 -alcohol, alcohols having a linear hydrocarbon group, such as 5-hexen-2-ol, 6-hepten-2-ol, 7-octene-2-ol, 8- Terpene-2-ol, 9-nonene-2-ol, 10-undecen-2-ol, 6-hepten-3-ol, 7-octene-3-ol, 8-decene-3 - alcohol, 9-nonen-3-ol, 10-undecene-3-ol, 11-dodecen-3-ol, 7-octene-4-ol, 8-decen-4-ol, 9-decen-4-ol, 10-undecen-4-ol, 8-decene-5-ol, 9-nonene-5-ol and 10·undecene-5-ol; having a branched chain Hydrocarbyl alcohols such as 2·ethyl-5-hexen-1-ol, 3-methyl-6-hepten-1-ol, 3-methyl-7-octene-1-ol, 4- Methyl-8-nonen-1-ol, 3-ethyl-9-nonen-1-ol, 2-methyl-10-undecen-2-ol, 2,2-dimethyl-7 Octen-1-ol, 3-ethyl-2-methyl-8-nonen-1-ol, 2,2,3-trimethyl-9-nonen-1-ol and 2,3, 3,4-tetramethyl-10- a olefin-2-ol; a diol such as 9-decene-1,2-diol, 10-undecene-1,2-diol and 11-decadiene-1,2·diol; And the paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 312991 -^1 ϋ ϋ ϋ ϋ ϋ i^i ϋ 1— n · 1 I ϋ ·1· n ϋ ϋ TJ ϋ n · ϋ I words (please read the notes on the back and fill out this page) Line - 29〇i49 A7 5; ^---- Triols, such as 10-undecene-u, % triol; a compound represented by the formula (10) which is an epoxy group, in detail, a 6 ω alkenyl epoxide such as a 5-hexene epoxide, a 9 olefin oxide, a 7-octene epoxide, 8_decene epoxide, terpene % oxide, 1 fluorene-undecene epoxide and lK dodecene epoxide; and fluorenyl-alkenyl epoxides having a branched hydrocarbon group, such as armor 5--5-hexene epoxide, 2-methyl-6-heptene epoxide, methyl octene epoxide, 2-methyl-8-nonene epoxide, methyl _9_ Terpene epoxide and methyl-1〇-undecene epoxide. Furthermore, examples of the polar group-containing monomer (10) also include the following compounds------------------------------------------------------------------------- Ministry of Intellectual Property Bureau employees consumption cooperatives printed this paper scale applicable to China National Standard (CNS) A4 specifications (2) 297 297 mm) 205 312991 1290149 Λ7 _B7_ V. Invention description (2〇6) Ministry of Economic Affairs Intellectual Property Bureau employees Printed by consumer cooperatives

OH -------------------- Order --------- Line ^_^w. (Please read the notes on the back and fill out this page) This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm). 206 312991 A7 1290149 _B7 V. Invention description (2〇7) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative prints

OH (Please read the note on the back and fill out this page) This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 207 312991 1290149 Α7

Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing

The copolymerization of an α-olefin having 2 to 20 carbon atoms with a polar group-containing monomer (1〇) and, if necessary, a polar group-containing monomer represented by the formula (8) is contained in the following composition: (Α) a compound selected from Group 3 of the periodic table (including lanthanides and actinides) to a transition metal of Group 1 and (Β) selected from at least one of the following compounds (·-1) organic An aluminum oxy compound, (Β_2) reacts with a compound (Α) to form an ion pair compound, and (Β-3) an organic olefin compound in the presence of the aforementioned olefin polymerization catalyst, and in accordance with the first embodiment Applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------- order --------- line ^9 (please read the phonetic on the back? Page 208 208 1290149 V. INSTRUCTION OF THE INVENTION (2〇9) The same is carried out under the same polymerization conditions for the preparation of the polar olefin copolymer. Then, it is obtained from the above by anionic polymerization, ring-opening polymerization or polycondensation. The functional olefin copolymer is copolymerized with the W portion of the polar group-containing monomer (10) to form a (Z) moiety. When the (z) moiety is prepared by copolymerization of the W moiety of the polar group-containing monomer (10) by anionic polymerization, ring-opening polymerization or polycondensation, for example, a polar group-containing olefin copolymer and a proton extracting agent are used. Anionic polymerization of a polar monomer in the presence of a (pr〇t〇n abstracting agent) or in the presence of a polar-containing terpene hydrocarbon copolymer, a proton extracting agent, and an active hydrazine compound. Examples of polar monomers include the aforementioned constituent units. Examples listed in (4), such as (meth)acrylic acid vinegar, (sub)acrylonitrile, acrylamide, ethylene pyridine, N-substituted maleimide, vinyl residue And a styrene derivative. Among the polar monomers, a compound having one or more ethylenically unsaturated bonds in one molecule and having a T or a plurality of ethylenically unsaturated bonds in the molecule itself gives a highly crosslinked polymer in the polymerization of the compound itself; When the compound is copolymerized with a polar group-containing ethylenically unsaturated monomer having only one ethylenically unsaturated bond, the polar group-containing ethylenically unsaturated monomer having only one sparingly unsaturated bond produced The main chain of the polymer may be cross-linked to each other. Among the above polar monomers, it is preferred to treat the mono-alcohol with a monoester of acrylic acid or methacrylic acid, and the terminal is terminated by an ether bond. Junction-protected glycols and propylene

^ or y acrylic acid monoester, two open red A x 297 mm) 财关绪鬲 alcohol and acrylic or f-based 209 order line 312991 !29〇ΐ49

, invention description (210) Ministry of Economic Affairs, Intellectual Property Bureau, Consumer Cooperatives, printing all of the hydroxyl groups of acrylic acid esterified polyester, acrylonitrile, methacrylonitrile, disubstituted monoacrylamide, vinyl or isoprene Substituted pyridinium N-aromatic substituted maleic imides and vinyl ketones. More preferred are monohydric glycerides of monohydric alcohols and acrylic acid or methacrylic acid, diols whose oxime terminal is protected by ether linkage, and mono-t, di- or higher alcohols and acrylic or methyl groups of acrylic acid or methacrylic acid. All of the hydroxyl groups of acrylic acid are deuterated polyesters, acrylonitrile, methacrylonitrile and N,N-disubstituted monoacrylamide. Examples of the polar monomer include examples of the aforementioned constituent unit (4), for example, per oxide. These polar monomers may be used singly or in combination of two or more. When two or more polar monomers are used in combination, it is preferred to use a combination of the above polar monomers other than the epoxide (the monomers are sometimes referred to as "ethylenically unsaturated monomers" and epoxides. In the copolymerization reaction using a plurality of polar monomers, a plurality of ethylenically unsaturated monomers, a single dilute unsaturated monomer and a plurality of epoxides, a plurality of ethylenically unsaturated monomers and a single epoxide, or a plurality of uses are used. The ethylenically unsaturated monomer and the plurality of epoxides can be used; when the components are added to the polymerization reactor, a simultaneous addition method, a sequential addition method, or a repeated sequential addition method can be employed. And co-polymerization, to obtain a polymer fragment composed of a copolymer having a relatively high degree of randomness, depending on the difference in reactivity of the compounds used. If the two are each successively copolymerized , obtained from the inclusion of two or more blocks of the inset from the 1 /. The scorpion copolymer red into the paper size applies to the Chinese National Standard (CNS) A4 specifications (210 X 297 public factory

312991 旷 (Please read the note on the back and fill out this page) Order --------- Line · 1290149

V. Description of invention (m) 211 pieces of material printed by the Consumers' Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs. If these successive t 重复 are repeated, a polymer fragment composed of a complex copolymer is obtained. The most important 'preferably for the second time to use the ethylenically unsaturated monomer and epoxide to prepare a polymer composed of a plurality of monomer-opening gentlemen, from & π flattened block copolymer Fragment 0 In this case, it is more preferred that the ring is made of propylene oxide or ethylene oxide, and the epoxide is more preferably propylene oxide. The active hydrogen compound is, for example, an active hydrogen compound having an active hydrogen on a carbon atom, an active ruthenium compound having an active oxime on an oxygen atom, an active hydrogen compound having an active hydrogen on a nitrogen atom, or having an activity on a sulfur atom. Hydrogen active hydrogen compound. Examples of active hydrogen compounds having active hydrogen on a carbon atom include hydrogen cyanide, monocarboxylic acid esters such as ethyl acetate, cyclohexyl propionate, isopropyl butyrate, methyl isobutyrate, isobutyric acid. Third butyl ester, hexyl hexanoate, butyl laurate, methyl stearate, ethyl oleate, methyl phenylacetate, methyl cyclohexanecarboxylate, 1,2-bis(2-propyl Carboxyoxy)ethane and hydrazine, propyl-propylcarbonyloxy)propane, polyphenolic acid vinegars such as dimethyl acrylate, dimethyl methylmalonate, diethyl succinate, Butyl 2,3-dimethylsuccinate, methyl adipate, ethyl suberate, methyl butane tetracarboxylate, 1,2-bis(2-methoxycarbonylethoxy)ethane, 1,2-bis(2-ethoxycarbonylpropoxy)ethane, i,2-bis(2-ethoxycarbonylpropenyl)ethane and N,N,N,,N,-肆(2- Butyroxycarbonylpropyl) ethyl enediamine; ketocarboxylic esters such as ethyl acetate, cyclopentyl acetate, methyl mercaptoacetate, ethyl 2-cyclohexylcarbonyl Butyl benzylidene acetate; nitriles such as acetonitrile, 2-cyanopropane, malononitrile, Methylmalononitrile, 1,3-dicyanopropane and adiponitrile; and ketones, such as C-paper standards applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 ----- ---1---------$ (Please read the note on the back and fill out this page) 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed V. Invention Description (212 Ketone, Methyl Ethyl-, di-isopropyl ketone, dicyclohexyl ketone, depleted 7 Benzene _ and isopropyl phenyl ketone. Examples of active hydrazine compounds having active hydrogen on an oxygen atom include human water; Methanol, ethanol, n-propanol, propanol, n-butanol, dibutanol, tert-butanol, isoamyl alcohol, third pentanol, n-octanol, lauryl alcohol, cetyl alcohol, cyclopentanol, Cyclohexanol, allyl alcohol, crotyl alcohol, methyl vinyl methanol 'benzyl alcohol, 1-phenylethanol, trisyl methanol, cinnamol, perfluoro-tert-butanol, α-hydroxyisopropylbenzene Base, transcyclohexylphenyl _, isopropyl isopropyl naphthyl ketone and methyl isobutyric acid; polyols, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, 1, 3_ Glycol, 1,3, butanediol, 1,4-butanediol, 1,6-hexanediol, iota, 4_cyclohexanediol, trishydroxypropylpropane, glycerin, diglycerin, pentaerythritol and Pentaerythritol; and aromatic warp-based compounds, such as age, meth, dimethyl, 2-naphthyl, 2,6-di-b-naphthalene, and biguanide. Examples of active hydrogen compounds having active hydrogen on a nitrogen atom Containing aliphatic or aromatic primary amines such as methylamine, ethylamine, n-propylamine, isopropylamine, n-butylamine, isobutylamine, second butylamine, tert-butylamine, cyclohexylamine, benzylamine, / 3-phenylethylamine, aniline, o-toluidine, m-toluidine and p-toluidine; aliphatic or aromatic secondary amines such as dimethylamine, methylethylamine, diethylamine, di-n-propylamine, B N-butylamine, methyl second butylamine, diamylamine, dicyclohexylamine, N-methylaniline and diphenylamine; polyamines having primary or secondary amine groups, such as ethylidene diamine , bis(2-aminoethyl)amine, hexyldiamine, 4,4'-diaminodiphenylethane, tris(2-aminoethyl)amine, dinonylethylidene, N, N'-diethylethylidene diamine and two 2_Methylaminoethylamine; Saturated--------^---------Line (Please read the notes on the back and fill out this page) This paper scale applies to Chinese national standards. (CNS) A4 size (210 X 297 mm) 212 312991 1290149

V. Description of the Invention "Class", poly(vinyl-) and poly(styrene derivative), polyacetate, polyamine polylactide and polymu Among the above active antimony compounds, cyanide is preferred. Hydrogen, monocarboxylic acid esters, 7 retinoids, water, monohydric alcohols, polyhydric alcohols, monothiols, polymers having active hydrogen at the terminal and/or main chain, such as poly(extension oxygen) Class), poly((meth)acrylic acid (iv)), poly((meth)acrylonitrile), poly(propionamide), poly(vinyl π-bite), poly(仏substituted) The proton extracts, the poly(styrene derivatives), and the poly(styrene derivatives), and copolymers thereof. The proton extracts may be used singly or in combination of two or more. i a less polar single system in the presence of a proton extracting agent and a reactive nitrogen compound, or in the presence of a proton extracting agent, an anionic polymerization reaction. In this method, ring-opening polymerization can be carried out. The following method is a method using a proton extracting agent , or a method of extracting protons from an active hydrogen compound to obtain an anion: (1) using alkali gold a method of hydroxide or alkali metal carbonate; () a method of using a metal test, a metal hydride test, a metal guanamine or a metal alkyl group; (3) a method using a zinc compound; (4) using a hydrogen hydroxide And (5) a method using a phosphazenium salt. The phosphazene gun compound can be prepared by the method described in Ep 〇 7916 〇〇, p. i2_i3 or the like. The method of the w part of the base monomer (1〇) is not limited, as long as at least the proton extract bungee (four) coffee (CNS) ATiiT^7^j7 ', 214 order line 312991 Ministry of Economic Affairs Intellectual Property Bureau staff consumption Co-operative printing 215 1290149 A7 __ B7 V. Description of invention (offence) Sexual monomers can be effectively contacted, and any batch method and methods including intermittent or continuous feeding of polar monomers can be used. The polar monomer is carried out in a molten state, or may be carried out in a liquid phase using a suitable solvent. The liquid phase may be a homogeneous phase or a suspended phase. Examples of the solvent used include aliphatic or alicyclic hydrocarbons such as n-hexane and n-glycol. And Cyclohexane; aromatic hydrocarbons such as benzene, toluene and xylene; aromatic compounds such as chlorobenzene and dichlorobenzene; ethers such as diethyl ether, phenyl ether, tetrapyran, tetrahydropyran, 1, 4-dioxane, ethylene glycol dimethyl ether and diethylene glycol diethyl ether; and aprotic polar solvents such as dimethylformamide, dimethyl sulfoxide, cyclopentadiene and N, N'-di The amount of the proton extracting agent is not particularly limited, but the amount is usually in the range of 1χ1〇_6 to 1x101 mol, preferably in the range of ΐχΐ4 to 3x10-1 m〇i. Usually, it is in the range of -50 to 250 ° C, preferably -20 to 15 Torr, depending on the type and amount of proton extracting agent and polar monomer used. The polymerization pressure is usually not more than 3 〇Mpa (absolute pressure, the unit is MPa), preferably 〇〇1 to 15 MPa, more preferably 〇·1 to 1.0 MPa'. The type and polarity of the polar monomer to be used vary depending on the reaction temperature and the reaction temperature. The polymerization time is usually not more than 50 hours, preferably from 1 to 24 hours, depending on the type and amount of the proton extracting agent and the polar monomer, and the reaction temperature. Next, the method (ii) is detailed below. In the method (ii), the α-olefin having 2 to 20 carbon atoms and the polar group-containing monomer (10) and, if necessary, the polar group-containing monomer represented by the formula (8) Applicable to China National Standard (CNS) A4 Specifications (2) Q 297 297 public re------ 312991 -------------------- Order ------ Line WV. (Please read the notes on the back and fill out this page) 1290149 A7

--------Book-------in (Please read the note on the back? Please fill out this page again) 216 312991 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 217 1290149 A7 ____B7^ Five Description of the Invention (2Π) Two or more copolymers of the polymer are formed, or may be formed of a thermoplastic resin other than the polar group-containing olefin copolymer and the polar group-containing olefin copolymer. Thermoplastic Resin The thermoplastic resin preferred for use in the present invention is selected from the group consisting of polyolefin, polyamine, polyester, polyacetal, polystyrene, acrylonitrile/butadiene/styrene copolymer (ABS), polymethyl propyl, A thermoplastic resin of a olefin ester, a polycarbonate, a polyphenylene scale, a polyvinyl chloride, a polyvinylidene ethylene, a polyvinyl acetate, an ethylene/(meth) acrylate copolymer, and a diene rubber. Examples of the polyolefins include olefin homopolymers such as polyethylene, polypropylene, poly-1-butene, polymethylpentene, and polymethylbutene; and olefin copolymers such as ethylene/α-olefin random Copolymer, ethylene/propylene/diene terpolymer, propylene/ethylene random copolymer, propylene/α-olefin random copolymer, and propylene/ethylene/α-olefin terpolymer. Among them, preferred are polyethylene, polypropylene, ethylene/a-olefin random copolymer, ethylene/propylene/diene terpolymer, propylene/ethylene random copolymer, and propylene/qj-tobacco random copolymer. . If the polysmoke is a polyolefin obtained from an olefin having 3 or more carbon atoms, the olefin may be an isotactic polymer or may be a syndiotactic polymer to prepare a poly As the catalyst for olefin, a Qierlena catalyst, an aromatic metal olefin catalyst, and a known catalyst can be used. Examples of the imine amines include aliphatic polyamines such as nylon-6, nylon-66, nylon-10, nylon-12 and nylon-46; and aromatics prepared from aromatic dicarboxylic acids and aliphatic diamines. Alanines. Among them, nylon_6 is preferred. Examples of poly S include aromatic polyesters such as polyethylene terephthalate 312991 — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — Please note the following on the back page) 1290149

The Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs printed 218 m of ethylene formate and polybutylene terephthalate; polycaprolactone; and polybutyric acid. Among them, polyethylene terephthalate is preferred. Examples of the polycondensate include polyformic acid (polyoxymethylene), polybenzazole, polypropionaldehyde, and polybutyraldehyde. Among them, polyoxymethylene is preferred. The polystyrene can be a homopolymer of stupid ethylene or can be a copolymer of styrene and acrylonitrile, methyl methacrylate, alpha methyl styrene or the like, such as acrylonitrile/styrene copolymer. As for the ABS, it is preferred to use a constituent unit derived from acrylonitrile in an amount of from 2 to 35 m〇i%, an amount of 20 to 30 mol% derived from butadiene, and the amount thereof 40 to 60 mt) 1% of ABS derived from the constituent units of styrene. As for the polymethacrylate, polymethyl methacrylate (PMMA) is preferred. Examples of the polycarbonates include bis(4-hydroxyphenyl)methane, bis-bis (light base), ethidium, 2,2-bis(4-phenylene)propane, and 2,2-di (4-Phenyl) Butane is obtained. Among them, a polycarbonate obtained by using 2,2-bis(4-hydroxyphenyl)propane is preferred. As for the polyphenylene ether, poly(2,6-dimethyl-1,4-polyphenylene ether) is preferred. The polyethylene glycol may be a homopolymer of ethylene, or may be a copolymer of ethylene and vinylidene chloride, acrylate, acrylonitrile, propylene or the like. As for polymetaethylene, the composition is composed of vinylidene chloride and ethylene, acrylonitrile, (meth) acrylate, allyl ester, unsaturated ether, styrene, etc., and the content of vinylidene chloride unit is usually not less than 85%. Copolymer. Polyvinyl acetate can be a homopolymer of vinyl acetate, or can be acetic acid. The paper size is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 ------------ ---------1---------^ (Please read the notes on the back and fill out this page) 1290149 V. Invention Description) Copolymer of Ethylene S曰 with Ethylene or Ethylene . Among them, an ethylene/vinyl acetate copolymer is preferred. As the ethylene/(meth) acrylate copolymer, an ethylene/acrylic methacrylate copolymer, an ethylene/methyl methacrylate copolymer or an ethylene/methyl methacrylate copolymer is preferred. Examples of the monoolefin rubber include conjugated polydienes such as polybutadiene, polyisoprene-type styrene-butadiene copolymer, so-called SBR (styrene/butadiene rubber). In the diene rubber, at least a part of the double bonds in the molecule can be nitrided. The above thermoplastic waxes may be used singly or in combination of two or more. Among the thermoplastic resins, polyolefin, polyester, polyamine or polystyrene is preferably used. The thermoplastic resin composition of the present invention can be blended with a thermoplastic resin by using, for example, a belt blender, a drum blender or a Henschel blender (Henschel core (4)) The thermoplastic resin composition of the present invention can also be obtained by using a melt kneading device, for example, a kneading machine such as a co-kneader, a Banbury mixer (Ban-nnxei), a Brabender machine, a single Screw or double screw extruder, horizontal scrambler such as twin screw surface replacement machine or twin screw disc type device, or vertical scrambler such as double spiral belt type weighing machine, will contain polarity The base olefin copolymer is prepared by melt-kneading with a thermoplastic resin. 3 Additives _ Μ 含 Μ Μ 含 含 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ For the composition, money ------- I · 111111. (Please read the note on the back and then fill out this page) Line 1P! 219 312991 1290149

Illustrated by the Ministry of Economic Affairs, the Intellectual Property Office of the Ministry of Economic Affairs, the Consumers' Cooperatives, printed 220 items, and within the limits of the purpose of the present invention, the addition of τ, such as inorganic fillers, organic fillers, nucleating agents, heat stabilizers, and winds (4) Fixing agents, antistatic agents, coloring agents, lubricants, flame retardants and frost-resistant agents. - Examples of inorganic fillers include vermiculite, diatomaceous earth, alumina, titanium oxide, magnesium, pumice powder, pumice gas ring , aluminum hydroxide, magnesium oxyhydroxide, basic magnesium t-acid, dolomite, calcium sulfate, calcium titanate, barium sulfate, calcium sulfite, talc, clay, mica, asbestos, fiberglass, broken glass, glass beads , calcium citrate, montmorillonite (m〇ntm〇rill〇nite), bentonite, graphite, aluminum powder and vulcanized pin. Among them, the layered compound is preferred, used in the dispersion medium and has swelling and splitting properties. Clay minerals are particularly good. Clay minerals are generally divided into a two-layer structure consisting of a tetrahedral layer of a second stone and an octahedral layer containing a Ming or town as a central metal on a tetrahedron, and a tetrahedral layer of the rare stone. Four sides The three-layer structure consisting of octahedral layers containing inscriptions or magnesium as the central metal is sandwiched between the body layers. The two-layer structure type (the former) is, for example, the kaolin group or the serpentine group; the three-layer structure type (the latter) is For example, montmorillonite (group, insect to stone group or mica group; it is grouped according to the number of cations between layers. Detailed examples of clay minerals include kaolin, dickite, pearlite, halloysite, serpentine, fiber Serpentine, pyrophyllite, montmorillonite (m〇ntmorillonite), beide stone, smectite, special stone, smectite rich montmorillonite, montmorillonite, four broken mica, with mica Muscovite, pearl mica, talc, vermiculite, phlogopite, xanth〇 phyllite and chlorite. This paper scales the fineness of the standard (CNS) A4 specification (21Q χ 312991 ------- -t---------Μ 1^. (Please read the notes on the back and fill out this page) 1290149

V. Description of the invention (221) Printing by the Ministry of Economic Affairs, the Ministry of Finance and Industry

This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 221 clay minerals that have been treated with organic matter (sometimes referred to as "organically modified clay minerals" can also be used as inorganic layered compounds. For clay minerals treated with organic matter, see Asakurashoten's “Clay Dictionary.” Among the above clay minerals, from the viewpoint of swelling properties or splitting properties, it is preferable to have a smectite group, a vermiculite group, and a mica group. Excellent smectite group. Examples of smeetite group clay minerals include montmorillonite (montm〇rill〇nite), beidellite, smectite, smectite, magnesium Montmorillonite and hectorite. In the case of natural swelling clay minerals, examples of dispersion media for swelling or splitting inorganic layer-shaped compounds are water; alcohols such as methanol, ethanol, propanol, isopropanol, and B. a diol and a diethylene glycol; a mercaptoamine; a dimethyl hydrazine and an acetone. Among them, water and an alcohol such as methanol are preferred. In the case of an organically modified clay mineral, T ^ ^ ^ a W, Aromatic hydrocarbons For example, benzene, toluene and xylene; ethers such as acetyl and tetrahydrofuran; ketones such as acetone, methyl ethyl and methyl isobutyl; aliphatic hydrocarbons such as n-pentyl, n-hexyl and n-octyl Burning; southern chemical smoke, such as chlorobenzene carbon, gas, m1, 2 · digas burn and full gas ethylene; acetic acid ethyl acetate; methacrylic acid acetaminophen dioctyl vinegar (D〇p); Methionine; dimethyl sulfoxide; ethylene glycol monomethyl _ and (iv) oil. Nucleating agent as nucleating agent' can use a variety of nucleating agents known to date without particular limitation. Examples of nucleating agents include the following aryl Family of citrate salts, benzotriene, aromatic terrorism and rosin nucleating agent 312991 --------^--------- line (please read the back note first) Fill in this page again. 5. Inventive Note (222) An example of an aromatic phosphate salt is a compound represented by the following formula (A):

In the above formula, R11 is an oxygen atom, a sulfur atom or a ketone group having i to one carbon atom; R12 and R13 are each hydrogen or a hydrocarbon group having 1 to 1 carbon atom and may be the same or different, and each R12 and Each of Rl3 or R12 may be bonded to each other to form a ring;]V [is a metal atom having a valence of 1 to 3; and n is an integer of 1 to 3. Specific examples of the compound of the above formula (Α) include 2,2'-methyl-bis(4,6-di-t-butylphenyl)phosphate, 2,2'-ethylene-double Sodium (4,6-di-t-butylphenyl)phosphate, 2,2'-methyl-bis(4,6-di-t-butylphenyl)phosphate, 2,25· Ethylene-bis(4,6·di-t-butylphenyl)phosphate lithium, 2,2,-ethylene-bis(4-isopropyl-6-t-butylphenyl)phosphoric acid Sodium ester, 2, 2, methyl-bis(4-methyl-6-t-butylphenyl) phosphate chain, 2,2,-methyl-bis(4-ethyl-6- Tributyl phenyl) lithium citrate, bis[2,2,-thiobis(4-methyl-6-t-butylphenyl)phosphoric acid], bis[2,2,-thiol double (4-ethyl-6-t-butylphenyl)phosphate] fishing, bis[2,2,-thiobis(4,6-di-t-butylphenyl)phosphate],

This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) A7 1290149 B7_ V. Invention Description Magic 3) Bis[2,2,-thiobis(4·trioctylphenyl)phosphoric acid Ester] magnesium, 2,2,-butylene-bis(4,6-dimethylphenyl)phosphate, 2,2,-butylene-bis(4,6-di-t-butylphenyl) Sodium phosphate, 2,2,-third octyl-methyl-bis(4,6-dimethylphenyl)phosphate, 2,2,-third octylmethyl-bis (4,6 -di-t-butylphenyl)phosphate sodium, bis[2,2,-methyl-bis(4,6-di-t-butylphenyl)phosphate] calcium, double [2,2 , _ methyl-bis(4,6-di-t-butylphenyl)phosphate] magnesium, bis[2,2,-methyl-bis(4,6-di-t-butylbenzene) Phosphate] 钡, 2, 2, methyl-bis(4-methyl-6-t-butylphenyl)phosphate, 2,2,-methyl-bis(4-ethyl Sodium -6-tert-butylphenyl)phosphate, sodium (4,4,-dimethyl-5,6,2-di-tert-butyl-2,2,-biphenyl)phosphate, double -[(4,4,_dimethyl_6,6,_di-t-butyl-2,2,-biphenyl)phosphate] Mom, 2, 2, _A - bis(4-m-butyl-6-t-butylphenyl) phosphate, sodium 2,2,-methyl-bis(4,6-dimethylphenyl)phosphate, 2,2 ,-sodium bis(4,6-diethylphenyl)phosphate, potassium 2,2,-ethylene-bis(4,6-di-t-butylphenyl)phosphate, Bis[2,2,-ethylidene-bis(4,6-di-t-butylphenyl)phosphate] calcium, bis[2,2,-ethylene-bis(4,6-di-) Tert-butylphenyl)phosphate] town, bis[2,2,-ethylene-bis(4,6-di-t-butylphenyl)phosphate] 钡, gin [2,2,- Methyl-bis(4,6-di-t-butylphenyl)phosphate] and ginseng [2,2,-ethylene-bis(4,6-di-t-butylphenyl) Phosphate] aluminum, and mixtures of two or more thereof. Among them, 2,2'-extended methyl-bis (4,6--di-dibutyl paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 312991 -------- Order --------line (please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 223 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 224 1290149

In the above formula, R14 represents a hydrogen peroxide or a hydrocarbon group having 1 to 1 carbon atoms; a metal horse having a valence of 1 to 3 is an atom; and η is an integer of 1 to 3. Specific examples of the compound represented by the above formula (Β) include sodium bis(4-t-butylphenyl)phosphate, sodium bis(4-methylphenyl)phosphate, and bis(4-ethylphenyl) dish. Sodium oleate, sodium bis(4-isopropylphenyl)phosphate, sodium bis(4-secondoctylphenyl)phosphate, potassium bis(4-t-butylphenyl) silicate, double (4-t-Butylphenyl) phthalic acid vinegar, bis(4-t-butylphenyl) phthalate town, bis(4-t-butylphenyl) phosphate clock, double (4- The second butyl phenyl)phosphate aluminum, and the 1 _ is preferably a bis(4_t-butylphenyl) phthalic acid vinegar: a mixture of the genus. A specific example of the substance Abbott methyl sorbitol is the combination of the paper size shown in the following formula (6)_China National Fresh (CN_S) A4 Specification (2) G χ 312991 --------^------ ---Μ (Please read the notes on the back and fill out this page) A7 1290149 V. Description of Invention (225) Alcohol^(R15)n

OH In the above formula, each Rl5 may be the same or different and represents a halogen atom or a hydrocarbon group having up to 10 carbon atoms; m and η are each an integer of 〇 to 5. Examples of the compound represented by the above formula (C) include 1,3,2,4-dibenzylidene sorbitol, 1,3-benzylidene-2,4-p-methylbenzylidene sorbose Alcohol, 1,3-benzylidene-2,4_p-ethylbenzylidene sorbitol, I3-p-f-benzylene-2,4-benzylidene sorbitol, 1, 3-p-ethylbenzylidene-2,4-brenyl sorbitol, p-methylbenzylidene-2,4_p-ethylbenzylidene sorbose-p-ethyl benzylene _2,4_p-methylbenzylidene sorbose 1,3,2,4-di(p-methylbenzylidene) sorbitol, 1,3,2,4-di(p-ethylidene) Benzyl)sorbitol, bis(p-propylphenylene) sorbitol, 1'3,2,4_(p-isopropylbenzylidene) sorbitol, 1,3,2 , 4-di(p-butylidenebenzylidene) sorbitol, I'3'2'4·one (p-butylbutyl benzylidene) sorbitol, ,,,··1 (2' , 4, bis-f-benzylidenemethyl) sorbitol, 1,3,2,4-di(p-methoxy-indolyl), sorbitol, 5 sheets, suitable for use in 312991 -- -----------------^Book---------Line· (Please read the back first Please fill out this page again) 225 1290149

1290149 V. Description of the invention Methyl-1-butene and polyalkenyl decane. Examples of the metal salt of an aromatic carboxylic acid or an aliphatic carboxylic acid include aluminum benzoate, aluminum p-butyl butyl benzoate, sodium adipate, sodium thioate and sodium pyrrolecarboxylate. Further, the polar group-containing olefin copolymer and the thermoplastic resin composition of the present invention can be produced by various molding methods such as calender extrusion molding, injection molding, blow molding, molding, and press bonding. The polar olefin-containing copolymer and the thermoplastic resin composition can be molded into a sheet or film (unstretched) by extrusion molding. Stretching extruded sheet or film (unstretched) by tentering (longitudinal-transverse stretching, transverse-longitudinal stretching), simultaneous biaxial clamping or uniaxial stretching, etc. Stretched film. Inflatable enthalpy can also be produced from the polar olefin-containing copolymer or thermoplastic resin composition of the present invention. For example, filaments can be produced by extruding a molten composition through a spinneret. Filaments can also be produced by marshal blow molding. Under the known conditions, the injection molded product can be produced by projecting the composition into various shapes by an injection molding machine known hitherto. The injection molded product obtained by using the polar olefin-containing copolymer or the thermoplastic resin composition of the present invention is not easily electrostatically charged and has excellent rigidity 'heat resistance, impact resistance, surface gloss, chemical resistance and abrasion resistance. Can be widely used in automotive interior renovation, automotive exterior renovation, electrical appliance covers, containers and so on. Under the known conditions, a blow molded product can be produced by using a blow molding machine known hitherto. This paper scale is suitable for the country of wealth (LNS) A4 specifications (2) G χ 公 gong ^) 228 order line 312991 1290149

Printed by the Intellectual Property Office of the Ministry of Economic Affairs, Employees' Consumer Cooperatives 229 V. Inventive Note (23⁄4) In the injection molding blow molding method, the polar olefin-containing copolymer or thermoplastic resin composition of the present invention is at a resin temperature of 1 〇. 〇 to 3 〇 (in rc, inject the melt mold (padsonm〇ld)* to form a melt, then load the melt into a mold of the desired shape, blow air into the melt, and make the melt mold The shape 'is thus a blow molded product. The molded product is, for example, molded. The use of the polar-containing olefin copolymer and the thermoplastic resin composition according to the present invention can be applied to various uses, for example, the following uses: (1) The film and the sheet are excellent in flexibility, transparency, adhesion, antifogging property, heat resistance and separation property of the film and sheet composed of the polar olefin-containing copolymer or the thermoplastic resin composition according to the present invention. (2) The laminate contains at least one laminate comprising a polar olefin-containing copolymer or a thermoplastic resin composition according to the present invention, for example, an agricultural film, a packaging film a shrink film, a protective film, a separation film such as a blood plasma separation or a water permeation selective vaporization film, or a selective separation film such as an ion exchange membrane, a battery separation membrane or an optical resolution membrane. (3) Polarity according to the present invention The base olefin copolymer or the thermoplastic resin composition can be used for microcapsules, PTP encapsulation, chemical bulbs, and drug delivery systems, etc. (4) Modifiers according to the present invention, the polar olefin-containing copolymer or thermoplastic Resin group paper size is appropriate for National Standard (CNS) A4 specification (210 X 297 public) ---- 312991 --------------- C Please read the notes on the back and fill in This page) . Line · Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1290149

When the product is used as a lyophilized material, it can be modified in terms of impact resistance (four), flow (four), coating properties, crystallinity, adhesion, and transparency. The polar-containing dilute-smoke copolymer or the thermoplastic resin composition according to the present invention can be used as a rubber (tetra) agent (4) to obtain a modification effect in wind resistance (four), heat resistance, adhesion, and oil resistance. Examples of the mouth rubber include crosslinked rubber such as natural rubber (nr), isoprene rubber (IR), butadiene rubber (BR), styrene/butadiene rubber (SBR), and chloropentadiene rubber ( CR), acrylonitrile/butadiene rubber (nbr), butyl rubber (IIR), ethylene/propylene rubber (EpM, EpDM), chlorosulfonated polyethylene (CSM), acrylic rubber (ACM, octopus, etc.), Epoxy chlorinated rubber (CO, ECO, etc.), anthrone rubber (q) and fluororubber (FKM, etc.); and thermoplastic rubber, such as styrene type, olefin type, amine ester type, ester type, guanamine type, And vinyl chloride rubber. The polar group-containing olefin copolymer and the thermoplastic resin composition of the present invention can be used as a lubricating oil (for example, gasoline engine oil, diesel engine oil, marine engine oil, gear oil, metal processing oil, motor oil, engine oil, spindle oil, and insulating oil) The modifiers can also be used as viscosity modifiers or freeze point inhibitors for these lubricants. When the polar olefin-containing copolymer or the thermoplastic resin composition of the present invention is used as a wax modifier, the adhesion, fluidity and hardness can be improved. Examples of waxes include mineral waxes such as montan wax, peat wax, ceresin/microcrystalline cerium and petroleum enthalpy; synthetic ceriums such as polyethylene, Fischer-Tropsch wax, chemically modified hydrocarbon waxes and substituted guanamine waxes; Vegetable wax and animal mites. This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991

--------1-------- (Please read the notes on the back and fill out this page) Line - 230 1290149 V. Description of the invention (2M) Copolymerization of the polar group-containing olefin of the present invention When the composition or the thermoplastic resin composition is used as a cement modifier, the moldability and hardness can be improved. Examples of binders include air setting cements such as lime, gypsum and magnesia cements; water setting cements such as Roman glues, natural glues, Polish glues, alumina cements and high sulfate slag binders; And special adhesives, such as acid-resistant adhesives, high temperature adhesives, water glass adhesives and dental glues. (5) Viscosity modifier, moldability improver The polar group-containing olefin copolymer and thermoplastic resin composition of the present invention can be used as an ink and a paint (for example, a book printing ink, a lithographic ink, a flexo graphic). Viscous modifiers or moldability improvers for inks, gravure inks, paints, cellulose derivative paints, synthetic resin paints, water bake paints, powdered water paints and Japanese varnishes. (6) Building materials, civil engineering materials The polar olefin-containing copolymers and thermoplastic resin compositions of the present invention are useful for construction/civil engineering resins and construction/civil engineering molded products, such as flooring, monuments, flooring, Acoustic panels, insulation panels, shock absorbing materials, decorative panels, skirting boards, asphalt modifiers, gaskets, sealing materials, roofing waves and cut-off sheets. (7) Internal or external refurbishment of the automobile, the gasoline barrel is composed of the polar-based copolymer or thermoplastic resin composition of the present invention, and the interior or exterior of the automobile is refurbished and the gasoline barrel has excellent rigidity, shock resistance and oil resistance. Sex and heat resistance. This paper size is applicable to China National Standard (CNS) A4 specification (210x297 mm). 231 Ordering line 312991 A7 1290149 V. Description of invention (233) Sealing properties. (1) Coating Substrate The solvent dispersion containing the polar olefin-containing copolymer or the thermoplastic resin composition according to the present invention has excellent dispersion stability in a solvent, and exhibits a polar state when a metal or a polar resin is bonded to a polyolefin. Good adhesion to the surname. (11) Medical or health care equipment The polar-containing olefin copolymer and thermoplastic resin composition of the present invention can be used for medical applications such as non-woven fabrics, non-woven laminates, electrets, medical tubes, medical containers, Blood transfusion bags, prefill syringes and syringes, medical equipment, artificial muscles, artificial membranes, hygienic/health foods, high temperature sterilization bags, and plastic wrap. (12) Various articles The polar-containing olefin copolymer and thermoplastic resin composition of the present invention can be used for stationerys such as desk mats, cutting mats, rulers, pen holders, pen covers, scissors handles, cutter handles, magnet pieces, pen cases, File holders, adhesives, label seals, strips and whiteboards; various daily necessities such as clothes curtains, sheets, carpets, sill mats, bathroom mats, buckets, water pipes, bags, seeders, air conditioners Filters, vent filters, cutlery, plates, cups, lunch boxes, coffee maker hoppers, frames, containers, storage boxes, hangers, ropes and laundry nets; sports equipment such as shoes, goggles, skis, racquets, Balls, tent ice mirrors, rubber fins, fishing rods, refrigerated cabinets (c〇〇ler b〇x), rest sheets) and sports nets; toys, such as building blocks and cards; containers, such as kerosene tanks Bottles for detergents and bottles for shampoos and exhibition items' such as billboards, target towers and plastic chains are applicable to Chinese national standards ((:Qing 8:4; each (21〇χ 297 公发丁) 312991 -------------------- Order --- ------ Line ^9. (Please read the notes on the back and fill out this page.) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 233 A7 1290149 - ... B7 V. Inventions (234) (13) Fillers Modifier The polar group-containing olefin copolymer and the thermoplastic resin composition of the present invention can be advantageously used as an additive to prepare a filler dispersibility improver or a filler which has improved dispersibility. (14) Compatibilizer according to the present invention The polar olefin copolymer or the thermoplastic ruthenium composition can be used as a compatibilizing agent. When the polar olefin-containing copolymer of the present invention is used, the polyolefin can be mixed with the polar group-containing thermoplastic resin at any mixing ratio. The polar olefin-containing copolymer of the invention has a polyolefin main chain and a side chain having a polar group, which, when used, can make the previously incompatible components compatible. Therefore, without using a polar olefin-containing copolymer or a thermoplastic resin In the case of the composition, the elongation at break is remarkably improved. Next, the use of the polar olefin-containing copolymer and the thermoplastic resin composition according to the present invention will be described in detail. When the polar group-containing olefin copolymer or the thermoplastic resin composition of the present invention is used as a binder resin, the oxime in the formula (3) is preferably an acid anhydride group, an epoxy group, an amine group or a hydroxyl group, and in the formula (6) The γ is preferably an epoxy group, an amine group or a hydroxyl group. If X is a trans group and R3 in the formula (3) is a linear or branched bond aliphatic hydrocarbon group having 9 or less carbon atoms, it can be obtained. An adhesive resin that achieves an excellent balance between fluidity and adhesion properties. If X is a hydroxyl group and R3 in formula (3) has u or more carbon atoms ------------ ------tr--------- (Please read the notes on the back and fill out this page.) The linear or branched aliphatic hydrocarbon group printed by the Ministry of Economic Affairs, Intellectual Property Office, and the Consumer Cooperatives. An adhesive resin having excellent adhesion properties can be obtained.

234 312991 Ministry of Economic Affairs Intellectual Property Office Employees Consumption Cooperative Printed 235 1290149 Λ7 B7 V. Inventive Note (235) The adhesive resin of the present invention comprises a polar group-containing soot copolymer or a thermoplastic resin composition, and thus for metals such as iron and Aluminum, and polar group-containing polymers, such as polyamide, polyester, polystyrene, polystyrene, propylene oxide/butadiene/styrene copolymer (ABS), polymethylpropionic acid Full or partial saponification products of vinegar, polycarbonate, polyphenylene ether, polyethylene, polyethylene ethylene, polyvinyl acetate, polyethylene glycol, ethylene/ethylene acetate copolymer, and B-baked / ( Methyl) propyl acrylate copolymer with excellent adhesion properties. Further, since the main structure is a polyolefin structure, the adhesive resin of the present invention has an extremely strong adhesive property to polyolefins, and can be used as a binder resin between polar substances or between a polar substance and a polyolefin.

When the polar group-containing olefin copolymer or the thermoplastic resin composition of the present invention is used as a compatibilizing agent, the polyolefin and the polar group-containing thermoplastic resin may be mixed at any mixing ratio. The polar olefin-containing copolymer or thermoplastic resin composition of the present invention has a polyolefin main chain and a side chain having a polar group, and therefore, the originally incompatible components can be compatible with each other. Therefore, the elongation at break is remarkably improved as compared with the case where the polar olefin-containing copolymer or the thermoplastic resin composition is not used. When used as a compatibilizing agent, X in the formula (3) is more preferably an acid anhydride group, an epoxy group, an amine group, a carboxylic acid group, a carboxylate group or a hydroxyl group, particularly preferably an acid anhydride group, an epoxy group or an amine group. Or a carboxylate group, and γ in the formula (6) is preferably an epoxy group, an amine group or a trans group. If X is a hydroxyl group and R3 in the formula (3) has 9 or fewer carbon atoms, preferably 8 or less carbon atoms, more preferably 7 or less carbon atoms, the paper size is applicable to China. National Standard (CNS) A4 Specification (210 x 297 mm) 312991 —------------------- Order---------Line WV. (Please Read the back of the note first and then fill out this page) 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing 236 V. Inventions (236), &gt; Diji', the compatibilizer can be fluid and compatible An excellent balance between sex. The right X is a radical and the R3 in the formula (3) is a radical having 11 or more carbon atoms, preferably 12 or more carbon atoms, more preferably 13 or more carbon atoms. The synergistic effect can be particularly enhanced. Resin modification 丨 When the polar olefin-containing copolymer or the thermoplastic resin composition of the present invention is used as a resin modifier, a modification effect of hydrophilicity, antistatic property, coating property, printability, and the like can be obtained. When used as a hydrophilic modifier or an antistatic modifier, X in the formula is preferably a trans group, a carboxylic acid group, a decylamino group, an amine group, an acid anhydride group or a carboxylate group. When a coating modifier or a printability modifier is used, X in the formula (3) is preferably a trans group, a carboxylic acid group, a decylamino group, an amine group, an epoxy group or an acid anhydride group, and a formula ( γ in 6) is preferably an epoxy group, an amine group or a trans group. The polar group-containing olefin copolymer or thermoplastic resin composition of the present invention is used as a coating modifier or a printability modifier, and When X is a hydroxyl group and R3 in the formula (3) is an aliphatic hydrocarbon group having 9 or less carbon atoms, preferably 8 or less carbon atoms, more preferably 7 or less carbon atoms, The modifier can provide an excellent balance between fluidity and coatability or printability; when X is a hydroxyl group and R3 in formula (3) has 11 or more carbon atoms, preferably The aliphatic hydrocarbon group of 12 or more carbon atoms, more preferably 13 or more carbon atoms, can further enhance the coating property and the printability enhancement effect. The paper scale is applicable to the Chinese national standard (CN) S) A4 size (210 X 297 mm) 312991 -nn mmmKm I ·1· ϋ Mu n ·ϋ · ϋ ·ϋ —.1 I ϋ —·1—, ·1 Βϋ ϋ a— n _ t (please Read the precautions on the back page and fill out this page. Line A7 1290149 V. Inventive Note (237) 1 Material Dispersant The polar group-containing olefin copolymer and thermoplastic resin composition of the present invention can be advantageously used as a filler dispersant to enhance The dispersibility of the filler, or used as an additive to prepare a filler having improved dispersibility. For example, when a thermoplastic resin is mixed with a filler, a filler dispersant is used. Examples of the thermoplastic resin include the aforementioned thermoplastic resin, preferably a hydrocarbon. Examples of the filler used in the present invention include fibers such as all aromatic polyamine fibers, aliphatic polyamide fibers, vinegar fibers, and cellulose fibers; organic fillers such as liquid polyesters or fine dispersions of polyamides, And the foregoing inorganic filler. The amount of the filler is not specially made, and the filler is used in an amount of from 0 to 100 parts by weight, preferably from 〇丄 to 2 parts by weight, based on the weight of the thermoplastic tree wax. Agent for packing Highly affinitive property I. Dispersibility of the filler. When using these filler dispersibility improvers, the mechanical properties (such as rigidity, hardness, heat resistance, impact resistance and elongation) of the thermoplastic resin composition containing U may have The filler dispersant can be used for a thermoplastic resin or a thermoplastic resin using a filler, preferably for a polyolefin. The rhodium-based olefin copolymer of the present invention and the ruthenium-containing plastic resin composition containing a filler dispersant can be used by any known The method, for example, the aforementioned method, is molded. The molded product obtained by the methods is applied to a wide range of applications such as household goods to industrial equipment. The molded product obtained by the t method is applicable to the Chinese country. Standard (CNS) A4 specification (210 x 297 mm) ----- < 312991 -------- order --------- line (please read the notes on the back and fill in the form) Page} Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 237 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 238 V. Invention Description (238) Example contains electrical parts 1 sub-parts Automobile parts, mechanical mechanism parts, food Fen two Film, sheet and fiber. In particular, mention can be made of office and OA equipment, such as printers, personal computer word processors, keyboards, PDAs (portable data terminals), telephones, fax machines, photocopiers, ECR (electronic cashier) Machines, electronic computers, portable films, electronic characters, cards, folders and stationery; electrical appliances, such as washing machines, refrigerators, vacuum cleaners, electronic ovens, lighting, electric toy consoles, hair buckets and foot warmers; AV device, for example 'Τλ, VTD Α“ then such as TV, VTR, camera, tape recorder, recorder, mini disk, CD player, speaker and liquid crystal display, and electrical or electronic parts and communications Such as connectors, relays, capacitor switches, printed boards, coil shafts, semiconductor sealing materials, wires, cables, transformers, deflection yokes, switchboards and clocks. ', his examples include automotive, marine or aerospace equipment and building materials, such as Seats (fillers, seat covers), belts, roof foam partitions, car awnings, handrail trims, rear package trays, carpets, mats, Plates, tire covers, mattress covers, air bags, insulation equipment, hangers, hand slings, wire covering materials, electrical insulation materials, coatings, coating materials, edging materials, flooring materials, corner walls, floor panels, Covers, plywood, * panel partitions, wallpaper, wall renovation materials, exterior finishing materials, interior finishing materials, roofing materials 'sunscreen materials, thermal insulation materials and window equipment, and supplies or sporting goods, such as clothing, Curtains, sheets, plywood, synthetic fiberboard, carpets, door mats, sheets, buckets, water pipes, containers, glasses, bags, boxes, goggles, skis, hoods and musical instruments f 〇

^^^ China national standard iBTs) A4 regulations €7iT〇X 312991 -------- order--------- line (please read the notes on the back and fill out this page) Property Bureau Staff Consumer Cooperatives Printed 239 1290149 a7 --- B7 V. INSTRUCTIONS (239) Also mentioned are bottles and beverages for shampoo and detergent bottles, seasonings (such as cooking oil and soy sauce) For example, mineral water and juice) are used in bottles, heat-resistant foods such as lunch boxes and cooking bowls, tableware such as plates and chopsticks, various food containers, packaging films, and packaging bags. Dispersion The polar olefin-containing copolymer or thermoplastic resin composition of the present invention is dispersed in water 'can be used as an aqueous resin dispersion; it is dispersed in a solvent' and can be used as a solvent dispersion. The surname of the resin in the present invention consists of water and a polar olefin-containing copolymer or a thermoplastic tree deer. The aqueous resin dispersion of the present invention may contain a modified polyolefin and/or a surfactant, as needed, within the limits of the object of the present invention. The modified polyolefin is graft-modified with a polyolefin obtained by polymerizing a polymer having 2 to 20 carbon atoms and an ethylenically unsaturated carboxylic acid compound. The viscosity average molecular weight of the polyolefin (starting polyolefin) for upgrading the polyolefin material is usually from 1,000 to 5,000 Å, preferably from 2,000 to 30,000, more preferably from 5,000 to 10,000 Å. In-plane. For excellent emulsion properties, the melt viscosity measured at 180 ° C is usually in the range of 10 to 5,000 cps, preferably 20 to 2,000 cps, more preferably 30 to 1,000 cps. The preparation of the starting polyolefin can employ a variety of hitherto known methods. For example, a method of polymerizing an olefin by using a transition metal catalyst (for example, a known aromatic ring metal catalyst) to obtain a desired molecular weight, and a method of heating a high molecular weight polyolefin by using a transition metal catalyst for degradation . This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991. I ---- n iai MMmf ί I 1§ «ϋ a—·. r · 11 II flu —.1 ϋ IJ· · flu ·1 Mmammm tmmm I ·ϋ n I i ----- f 矣 (please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office Staff Cooperatives Printed Clothing 241 1290149

5. Description of the invention ((4)) Alcohol; and styrene-type hydrocarbon compounds, such as styrene, α-methylstyrene, o-methylstyrene methyl styrene, p-methyl styrene, m-ethyl styrene, P-ethylstyrene, o-isopropylstyrene, m-isopropylstyrene and p-isopropylstyrene. The proportion of the dilute unsaturated acid compound contained in the entire graft monomer is preferably not less than 5 Å. The politic polycondensate can be produced according to a known method, for example, the method described in Japanese Patent Publication No. 22988/1977. In particular, it is heated at a temperature higher than the melting point of the starting polyolefin, and an ethylenically unsaturated carboxylic acid compound is added thereto, and a peroxide is added while stirring or subsequently to carry out graft copolymerization. reaction. The modified polyolefin has a viscosity average molecular weight of usually from 1, 〇〇〇 to 50,000, preferably from 2,000 to 20,000, more preferably 5 至 to! Oh, hey, within the scope. The amount of the ethylenically unsaturated carboxylic acid compound contained in the modified polyolefin is usually 1.0x1 〇 _3 to 0 2 m 〇 1 equivalent, preferably 5·0 χ 10'3, based on 1 〇〇g modified polyolefin. It is in the range of 15 m〇i equivalent, more preferably 〇01 to 〇1 mol equivalent. The modified polyolefin may be used singly or in combination of two or more. Examples of the surfactant include a sulfonic acid or a carboxylic acid type anionic surfactant such as an alkylnaphthalenesulfonate, a Na salt of a naphthalenesulfonate formaldehyde condensate, and a Na of a Shaffer's acid formaldehyde condensate. Salt, alkyl diphenyl ether disulfonate Na salt, lignosulfonate Ca salt, melanin resin sulfonate Na salt, special polyacrylate, gluconate, olefin/maleate copolymer, fluorene methyl fiber Na salt, metal soap (Zn, Al, Na or K salt), oleic acid paper size applicable to China National Standard (CNS) A4 specifications (210 x 297 mm) 312991 -------- order -- ------- Line (please read the note on the back and then fill out this page) 1290149 Ministry of Economic Affairs Intellectual Property Bureau Consumer Cooperative Printed A7 V. Inventions ~) A B7 Salt, Oleic Acid Na Salt, I. Bovine saponin K salt, stearic acid Na salt, tallow acid K saponin Na salt and two, age two, Example 1 - ethanol stearate amine salt; nonionic surface active such as fatty acid monoglycerol part _ , 赘 ^ Mountain 4 polysaccharides, fatty acid vinegar, sugar fatty acid, heart, stupid base: oil vinegar, polyoxyethylene _, polyoxyethylene Pearitol fatty acid part = mountain = sugar fatty acid part vinegar, polyoxy acetazone r α boring tool ® 9, polyoxyethylene glycerol fatty acid partial ester, ritual ethylene fatty amine, poly fat (hard sesame oil, polyoxyethylene Glycol polyethylene _ olefin polyoxypropylene block polymer, hydroxyethyl cellulose, sex agent /, polyvinyl pyrrolidine _ and methyl cellulose; cationic surface active (four) money, _ trimethyl pure ammonium chlorinated (d) = and amphoteric surfactants, such as dimethyl beakers and glycine. b "" anionic surfactants are more ambiguous due to the availability of hydrazine-stabilized water-based tree-knife bulk. Among them, more preferred are higher fatty acids. More preferably, it is a salt of a saturated or unsaturated higher fatty acid having 1 to 2 G carbon atoms, and a particularly good one is a metal salt thereof. # More details, a citrate, eleven Carbonic acid, lauric acid, myristic acid, palmitic acid, linoleic acid, stearic acid, arachidic acid, thujic acid, petroselinic acid, oleic acid, linoleic acid, linoleic acid, An alkali metal salt of arachidonic acid and tallow acid, etc. Surfactants may be used alone or in combination The aqueous resin dispersion of the present invention can be used, for example, to disperse a polar group-containing olefin copolymer or a thermoplastic resin composition in an aqueous dispersion medium, and optionally to modify a polyolefin or a surfactant. And various additives This paper scale applies to the Central Standards (CNS) A4 regulations "(2) 〇χ 297 public ------- salt agent 242 312991 ------------- Wei (please first Read the notes on the back and fill out this page) Order --------- Line · 1290149

Prepared by 243. In detail, the following methods (1) and (2) can be used. (1) A polar group-containing olefin copolymer or a thermoplastic resin composition is dissolved in an organic solvent such as toluene or xylene to prepare a solution having a concentration of 10 to 50% by weight. Next, the solution is added to water together with a hydrophilic solvent such as methanol, ethanol or isopropyl alcohol, and an emulsifier, and stirred by a homomixer or the like to obtain an emulsion. Then, the organic solvent and the emulsifier in the emulsion are removed by means of an evaporator or the like. (2) A polar group-containing olefin copolymer or a thermoplastic resin composition is melt-kneaded, and water is added to the melt-kneaded product. The step of kneading the tree raft and the water while the resin is still molten is simultaneously or successively performed, and if the modified polyolefin is not neutralized, the step of adding the alkaline substance is included. Among the above methods, it is preferred to use the method (2) to prepare an aqueous resin dispersion. The method (2) is explained in more detail below. First, a polar group-containing olefin copolymer or a thermoplastic resin composition is melt-kneaded. The temperature of the melt-kneading is higher than the melting of the polar-containing olefin copolymer or higher than the melting point of the highest melting point of the resin contained in the thermoplastic resin composition, preferably such that the melt viscosity is not more than 1 poise. Then, water is added to the melt kneaded material, and the resin and water are kneaded while the resin is still molten, so that the resin solid becomes dispersed particles. If a non-neutralized and/or unsaponified polyolefin is used on the right, an inert substance may be added in this step to neutralize the polyolefin. Examples of alkaline substances include substances that have a role in causing alkalis in water, such as metals, soils, ammonia, and alkalis in water. This paper scale applies to China National Standard (CNS) A4 specifications (2). 0 χ_ 297 public y--------- 312991

—m--------订---------Μ.0. Γ Read the first note on the back and fill out this page&gt; Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative print 1290149 five Description of the invention (244), such as metal oxides, hydroxides, weak acid salts or chlorides, and alkaline earth metal oxides, hydroxides, weak acid salts or tellurides; and alkoxylation of these metals Things. Detailed examples of such materials are as follows. Examples of the k alkali metal include sodium and potassium; examples of the alkaline earth metal include calcium, barium, and strontium; examples of the amine include inorganic amines such as hydroxylamine and hydrazine, methylamine, ethylamine, ethanolamine, and cyclohexylamine; alkali metals and alkaline earth metals Examples of oxides, hydroxides, and hydrides include sodium oxide, sodium peroxide, oxidative desorption, potassium persulfate, calcium oxide, cerium oxide, cerium oxide, sodium hydroxide, potassium hydroxide, calcium hydroxide, and hydroxide.锶, cesium hydroxide, sodium hydroxide 'potassium hydroxide and calcium telluride; examples of alkali metal and alkaline earth metal weak acid salts include sodium carbonate, potassium carbonate, sodium hydrogencarbonate, potassium hydrogencarbonate, calcium hydrogencarbonate, sodium acetate, Examples of acetic acid decommissioning and calcium acetate; and examples of ammonia and amine compounds include quaternary ammonium compounds such as ammonium hydroxide and tetramethylammonium oxide. The test substance may be added as such, but the step of adding 0 to the aqueous solution to form the dispersed particles and the step of neutralizing the unneutralized and/or unsaponifiable modified polyolefin may be carried out sequentially or simultaneously. The melt kneading can be carried out by any known method, but preferred examples of the melt kneading device include a kneading machine, a Banbury mixer, and a multi-screw extruder. Then, the aqueous dispersion obtained by sequentially adding water and melt-kneading to disperse the molten resin is cooled to room temperature in a natural or artificial manner. At this time, the dispersed particles are hardened to obtain a stable aqueous resin dispersion. Of course, in the preparation of the aqueous resin dispersion of the present invention, the paper scale can be combined to apply the Chinese National Standard (CNS) A4 specification (2) 0 x 297 public meals) - a 244 312991 --------^--- ------ (Please read the notes on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1290149 A7 ______B7 V. Description of Invention (245) Various side-by-side substances commonly used in aqueous resin dispersions Side material, such as stabilizers, wetting agents, foaming agents, defoamers, coagulants, gelling agents, anti-aging agents, plasticizers, fillers, colorants, aromatizers, anti-resistants And the release agent. The dispersed particles contained in the aqueous resin dispersion of the present invention obtained as above have a spherical shape, but do not necessarily need to be spherical. The average diameter of the dispersed particles is not particularly limited, but is usually from 1 to 20// The particle concentration (solid concentration) of the aqueous resin dispersion is not particularly limited, but is usually in the range of 5 to 40% by weight. The aqueous resin dispersion of the present invention is suitable. In combination with Polyolefins that are difficult to combine, such as polyethylene and polypropylene; the dispersion is used in combination with polyolefins and polyolefins or in combination with polyolefins. For other substances, for example, cloth, fiber, plastic, paper or Any material of metal. Examples of cloth or fiber include natural fibers such as cotton and hemp; inorganic fibers such as glass fibers, carbon fibers, asbestos fibers and metal fibers; regenerated fibers such as viscose enamel and cuprammonium; semi-synthetic fibers, For example, di- or tri-acetate fibers; nylon-6, nylon-66 and polyester (polyethylene terephthalate) fibers; and aromatic polyamide fibers, acrylic fibers, polyethylene fibers, Polyolefin fiber, and insoluble or poorly soluble polyvinyl alcohol fiber. Short iron is applied to the bonding by woven fabric. As for plastic, not only polyolefin but also other plastics such as polyethylene gas and ABS can be used. , polyester, polyamide, polycarbonate and epoxy resin. The plastic molded product to be combined can be in any shape, for example, the sheet wave is used by the Chinese National Standard (CNS). A4 size (210 x 297 mm) 312991 I n ϋ HI ϋ n I ϋ ϋ nn · · 1 n ϋ · 1 nn 1 I 1 n I ϋ ϋ ϋ «II · (Please read the note on the back? Fill in this page) 245

5. Description of the Invention (246 1290149 臈 or other shapes. Adhesive bonding can be applied to the surface of the adherend by applying the aqueous resin dispersion of the present invention to a surface of the adherend like a conventional aqueous dispersion type adhesive, and if necessary, heating the dispersion to The solvent dispersion of the present invention comprises an organic medium and a polar group-containing olefin copolymer or a thermoplastic resin composition dispersed therein in a solid state. An example of an organic medium which is a good solvent for polyolefin contains aromatic a hydrocarbon such as benzene, toluene and xylene, an aliphatic hydrocarbon such as hexane, heptane, cinnabar and simmer; alicyclic fumes such as cyclohexane, cyclohexene and methylcyclohexane; aliphatic Alcohols such as ethanol and isopropanol; ketone solvents such as acetone, methyl isobutyl steel and methyl ethyl _ and deuterated hydrocarbons such as triethylene glycol, dioxanol and chlorobenzene. Examples of the organic medium of the poor solvent include alcohols, ketones, ethers, vinegars, and cellosolve. In detail, methanol, ethanol, propanol, butanol, pentanol, hexanol, propylene glycol, Benzine, B scale, C-mystery, Ether, methyl ether, di-alkane, tetrahydrofuran, acetone, methyl ethyl hydrazine, methyl isobutyl ketone, pentanone, ketone, isophorone, acetophenone, anhydrous acetic acid Ethyl acetate, butyl acetate, methyl propionate, butyl formate, ethylene glycol monomethyl ether and ethylene glycol monoethyl ether. Organic shells can be used alone or in combination of two or more, from low temperature fluidity and dispersion stability From the viewpoint of the nature, it is preferred to use a mixture of a good solvent and a poor &gt; cereal. The ratio of a good solvent to a poor solvent is particularly limited. ^ 312991 -------- order---- -----Line&quot;in (Please read the note on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Printed 246 A7 1290149 V. Inventive Note (247 In the solvent dispersion of the present invention, When necessary, known additives such as colorant fillers and stabilizers may be added without damaging the object of the present invention. In the preparation of the solvent dispersion of the present invention, for example, a polar group-containing olefin copolymer is used. Or thermoplastic resin composition and organic media Mix and heat until completely dissolved. The temperature used for melting is usually in the range of 1 〇〇 to 15 〇. 钱, the solution is cooled, and the smectite-containing thin smoke copolymer or thermoplastic resin composition is precipitated. The copolymer or composition is precipitated in the range of 60 to 10 (rc), preferably the composition of the organic medium is set first, and the average cooling rate is adjusted to 1 to 2 (rc/hour, preferably 2 to ^/hour). It is also possible to dissolve the polar group-containing olefin copolymer or the thermoplastic resin composition in an organic medium composed only of a good solvent, and to add a poor solvent after the precipitation is completed, and then further precipitate. The solvent dispersion of the present invention obtained as above is used. The dispersed particles are usually spherical, but do not necessarily need to be spherical. The average diameter of the dispersed particles is not particularly limited, but is usually in the range of 1 to 20 β m, preferably 5 to 15 V m. The particle concentration (solid concentration) of the solvent dispersion is not particularly limited, but is usually in the range of 5 to 40% by weight. As a resin dispersion for metal and metal, polyolefin and polyolefin or metal and polyolefin bonding adhesive, it exhibits excellent adhesion, so it can be effectively used as a binder for PTP packaging, laminated adhesive, For coating materials or primers. The film and the skin are composed of a polar group-containing olefin copolymer or a thermoplastic resin composition. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210x 297). 312991 --------^- --------^ (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 247 1290149 A7

248 312991

5. Description of the Invention (3⁄49) 1290149 Obtained as an extruded film or sheet as described above. When stretching an unstretched film or sheet, the desired stretching ratio is usually in the range of 20 to 70 times in the case of biaxial positioning; in the case of single drawing stretching, usually in 2 to Within 10 times, depending on the thickness of the unstretched film or sheet. The thickness of the stretched sheet or sheet is preferably in the range of 5 to 200 / / m, depending on the use of the film or sheet. Next, 'the film or sheet of the invention having two or more layers of different compositions (hereinafter sometimes referred to as "laminate") is described below. The multilayer structure film or sheet according to the present invention is composed of two or different compositions. a multilayer structure film or sheet composed of a plurality of layers (at least one of which may be formed of a polar group-containing olefin copolymer); the thin enamel or sheet of the present invention is composed of two or more layers having different compositions (at least one of which may be made of a thermoplastic resin) The composition is formed into a multilayer structure thin sheet or sheet. The multilayer structure film or sheet according to the present invention is preferably also composed of (a) a layer comprising a polar olefin-containing copolymer and (b) a thermoplastic resin layer. Or preferably, it is composed of a layer of a thermoplastic resin layer and (4) a layer comprising a thermoplastic resin composition. The laminate system of the present invention comprises a multilayer structure film or sheet having two or more layers of the same composition, at least the layers. One layer may be formed of a polar group-containing olefin copolymer or a thermoplastic resin composition. The laminate preferably has the following composition: 〇) a layer comprising a polar olefin-containing copolymer, and (b) Composition of thermoplastic resin layer, this paper size is applicable to the _ family standard (CN-; Grid (2) Q χ 公 $ $) 312991 (please read the phonetic note on the back? Please fill out this page again) I: eJ·- 丨线- Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, Printed 249

1290149 or (b) a thermoplastic resin layer, and (c) a layer comprising a thermoplastic resin composition. In the film or sheet having a multilayer structure, examples of the thermoplastic resin forming the thermoplastic resin layer (b) include a resin for the aforementioned thermoplastic resin composition, such as polyolefin, polyamide, polyester, polyacetal, Polystyrene, acrylonitrile/butadiene/styrene copolymer (ABS), polycarbonate, polyphenylene ether, polyacrylate, and polyvinyl chloride. These thermoplastic resins can be used singly or in combination. The thermoplastic resin layer (b) preferably comprises a copolymer selected from the group consisting of polyolefin, polyamine, polystyrene, polyacetal, polyvinyl chloride, polystyrene, acrylonitrile/butylene/styrene (ABS). And a thermoplastic resin of at least one resin of polycarbonate, more preferably comprising a thermoplastic tree selected from the group consisting of polyolefin, ethylene/polar group-containing vinyl copolymer, polyester, polycarbonate, and polyamine. The resin is a polyester formed from a di-based compound unit - a long-lasting acid unit. Dihydroxy compounds are derived from aliphatic diterpenoids such as ethylene glycol, propylene glycol, 1,4-butanediol, neopentyl glycol and hexamethylene oxalate, alicyclic diols such as cyclohexane Methanol; an aromatic dihydroxy compound, y such as a double expectant; or derived from two or more dibasic groups selected from the compounds. The second acid-supplementing unit is derived from an aromatic dibasic acid, such as a succinic acid, a stupid-methyl and a 2,6-naphthalenedicarboxylic acid; an aliphatic dicarboxylic acid, such as an anthracene, a blister 33⁄4 Acid, hexanoic acid, azelaic acid and undecanedicarboxylic acid; alicyclic dicarboxylate hardened, such as hexachloro-dish dicarboxylic acid, or derived from two or more selected from the acid _ Sour. Juxi Palace Resin can be used in small amount of trivalent or higher polyhydroxy compounds or more than 1 paper size. It is applicable to China National Standard (CNS) A4 specification (210 X 297 public hair --- Jun, for example, three 312991

. --------^---------^. (Please read the notes on the back and fill out this page) 250 1290149 A7 B7 V. Invention Description (251 Ministry of Economic Affairs Intellectual Property Office staff The consumer cooperative prints or tricarboxylic acid, which is modified. As for the thermoplastic polyester resin, it is preferred to use polyethylene terephthalate, polybutylene terephthalate, and polyethylene isophthalate. Glycol/terephthalate copolymer, etc. As for the polycarbonate resin, any of various polycarbonic acids obtained by reacting a dihydroxyl compound with phosgene or diphenyl carbonate by a known method is used. And copolycarbonates. Examples of dihydroxy compounds include hydroquinone, resorcinol, 4,4,-di-diphenyldiphenylmethane, 4,4'-dihydroxydiphenylethane, 4,4, -di-diphenyldibutane, 4,4,-dihydroxydiphenylheptane, 4,4,-di-diphenylphenylpyrene, 4,4'-dipyridyl Base-2,2-propane (double test a), 4 4,-di-mercapto-3,3'-dimethyldiphenyl-2,2-propane, 4,4, dipyridyl-3 , 3, dibenyl diphenyl, 2, 2-propene, 4, 4, di-based di-diphenyl 2, 2-propane, 4 4 , dihydroxydiphenyl-1,1-cyclopentane, 4,4, dihydroxydiphenyl β11 cyclohexane, 4,4, dihydroxydiphenylmethylphenylmethane, 4,4, _ Ethyl phenylmethane, 4,4'-dihydroxydiphenyl-2,2,2-trichloroethane 2,2'-dihydroxydiphenyl, 2,6-dihydroxy Naphthalene, 4,4' dihydroxydiphenyl ether, 4,4'-di-trans-3,3'-di-diphenyl ether and 4,4'-di-diyl 2,5-diethyl hydrazine Phenylphenyl ether. Among the above compounds, polycarbonate having 4,4'-di-diphenyldiphenyl- 22-propane (double-prepared A) is more entangled due to excellent mechanical and transparency properties. The guanamine resin is any of various polyamines and copolymerized guanamines which are known to be obtained by ring-opening polymerization of caprolactam or polycondensation of diamines and dicarboxylic acids. Use nylon _6, this paper scale applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) Nylon--------------------- Order--- ------· (Please read the notes on the back and fill out this page) 251 312991 1290149

V. Description of invention (252 Ministry of Economic Affairs Intellectual Property Office employee consumption cooperative printed 252 -6,6 or m-xylenediamine/adipic acid condensation polymer. Examples of polyolefins include ethylene (co)polymer, propylene ( (a) a polymer butene (co)polymer, a 4-methylpentene (co)polymer, a %methyl-1-butene (co)polymer, and a hexene (co)polymer. Ethylene (co)polymer, propylene (co)polymer or 4-methylpentene (co)polymer is preferred. As for ethylene (co)polymer, ethylene/vinyl acetate copolymer or ethylene/acetic acid The vinyl ester copolymer saponified product is more preferable. In the ethylene/vinyl acetate copolymer, the ethylene content is preferably in the range of 15 to 60 mol%, preferably 25 to 50 mol%, of ethylene/vinyl acetate. The melt flow rate of the vinegar copolymer measured at 190 ° C is from 〇丨 to 500 g/10 min, preferably from ι·ι to 4〇〇g/1〇min, more preferably from 1 to 300 g/l. Within the range of 〇min, as for the saponification product of the ethylene/vinyl acetate copolymer, it is preferred to use it because the degree of saponification is not small 50%, preferably not less than 90%, an ethylene content of 15 to 60 mol%, preferably 25 to 50 mol%, obtained by saponification of an ethylene/vinyl acetate copolymer. When the ethylene content is In the above range, the saponified product is hardly decomposed by heating, is easily melt-molded, and has excellent elongation, water resistance and gas permeability. When the degree of saponification is not less than 50%, the saponified product is excellent. The laminate of the present invention may be interposed between the thermoplastic resin layer (b) and the polar olefin copolymer layer (a) or the thermoplastic resin composition layer (c), for example, An ethylene (co)polymer or a propylene polymer graft copolymerized with maleic anhydride. The film and sheet of the multilayer structure (laminate) according to the present invention can be applied to the Chinese National Standard (CNS) A4 specification using the paper scale. (210 x 297 public f) 312991 -------------------- order --------- line mp (please read the notes on the back and fill in This page) 1290149

253 312991 1290149 A7 -_B7 V. Description of Invention $54 The thickness of the olefin copolymer layer (a) or the thermoplastic resin composition layer (c) having a thickness of 0.005 to 1 mm and usually has a thickness of 0.01 to 5 mm. When the laminate of the present invention comprises, for example, a polar group-containing olefin copolymer layer (a) and a thermoplastic resin layer (b), the structure of the laminate may be a two-layer structure, that is, (a) / ( b); layer (a) a structure arranged on both sides, that is, (a) / (b) / (a); or another layer (x) (for example, a layer of a dense hydrocarbon layer), that is, a) / (b) / (x) / (b) / (a), (x) / (a) / (b) or (x) / (b) / (a). In the film or sheet of the present invention, at least one layer is a polar group-containing olefin copolymer layer (a) or a thermoplastic resin composition layer (c), which is advantageously used as a film for agriculture, packaging, shrinkage or protection or Sheet. Further, the film or sheet of the present invention can be advantageously used as a selective separation membrane (e.g., a plasma separation membrane, a water permeation selective vaporization membrane, an ion exchange membrane, a battery separation membrane, or an optical resolution membrane). The sheet or film of the present invention can be used in a variety of applications such as microcapsules, PTP encapsulation, chemical bulbs, and drug delivery systems. EFFECTS OF THE INVENTION The polar group-containing olefin copolymer or thermoplastic resin composition according to the present invention has excellent adhesion, compatibility and flexibility to polar substances such as metals and polar resins. EXAMPLES The invention is further illustrated by the following examples, which are not intended to limit the invention. In the examples, various properties were determined by the following methods. Adhesive 皙 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 312 Intellectual Property Bureau employee consumption cooperative printed 254 1290149, invention description knows)) Fuli is manufactured on a molding plate, and the aluminum sheet, polyimine film and thickness l〇〇vm with thickness 〇.lmm are sequentially stacked. At the center, a square piece of aluminum of 2〇em X cm has been hollowed out, and a 40 g sample (a polar group-containing olefin copolymer) is placed at the center (hollowed portion). Then, it is sequentially placed thereon. Stacking the polyimide film, aluminum sheet and molding plate. Place the sample embedded between the molding plates in a 19 (rc hot press, preheating for about 5 knives. Repeat the pressurization in order to remove the bubbles in the sample. (5〇kgkm2_G) and / World pressure operation several times. Then, increase the pressure to i 〇〇 kycm2_G, and heat the sample for 5 minutes under pressure. After the pressure is released, remove the mold plate from the heat press. It is moved into the compression part and kept in different molding machines of 2〇〇c, and is cooled for 5 minutes under the pressure of l〇〇kg/cm2-G. After the pressure is released, the sample is taken out. In the obtained film (containing the polar olefin copolymer film), the adhesion strength is measured using a portion having a uniform thickness of about 15 〇 to 170 克. The adhesion of A1 is strong and the tear of n will be contained. The polar olefin copolymer is sandwiched between two sheets of 2 〇χ 2 〇 (thickness: 50 cc) square aluminum sheets, and the same molding conditions as in the above-mentioned "manufacturing of the film" are layered. A film containing a polar-based dilute smoke copolymer. The obtained laminate was cut to obtain a strip having a width of 15 mm at the bonding interface, and the aluminum sheet and the polar olefin-containing copolymer film were peeled off at a peeling angle of 180, and the peel strength was measured.

I Alignment of E1X's bonding strength The polar olefin-containing copolymer film is sandwiched between two 2 〇cmx2〇cm (thickness, 100/zm) square homopolyethylene terephthalate ( The paper size of pET) film is applicable to Chinese national standard (CNSM4 regulation (5)^297 public love 255 312991

V. INSTRUCTIONS (STATES) 1290149, in the same molding conditions as in the above "manufacturing of film", except that the hot pressing temperature was changed to 280 ° C and the preset temperature of the cooling molding was changed to ^^, lamination «Hai et al. PET film and film containing polar olefin copolymer. The resulting laminate was cut to obtain a strip having a width of 15 mm at 18 Å at the bonding interface. The peeling strength was measured by peeling off the PET film and the polar group-containing olefin copolymer. The measurement of Ny's adhesion is carried out by sandwiching a film containing a polar olefin copolymer between two sheets of 2 〇X 2 〇 (thickness: 100//m) square nylon 6 film, which is the same molding as the above "manufacturing of the film". Conditions, except that the hot pressing temperature was changed to 25 〇 1, and the nylon film and the polar olefin-containing copolymer film were laminated. The resulting laminate was cut to obtain a strip having a width of 15 mm at 18 Å at the bonding interface. The peeling strength was measured by peeling off the nylon 6 film and the polar group-containing olefin copolymer 剥离. The adhesion of ^_EVOH is strong. The film of a polar olefin copolymer is sandwiched between two sheets of 2〇cm X 20 cm (thickness·100 β m) square ethylene/vinyl alcohol copolymer, as above. The same molding conditions as in the "manufacture of the film", except that the hot pressing temperature was changed to 2 ° C to laminate the ethylene/vinyl alcohol copolymer film and the polar olefin-containing copolymer film. The resulting laminate was cut to obtain a strip having a width of 15 mm, which was 180 at the bonding interface. The ethylene/vinyl alcohol copolymer film and the polar olefin-containing copolymer film were peeled off at the peeling angle, and the peel strength was measured. Breaking test, tensile test ^Strong Tang 切口 cut, __ impact test is carried out according to ASTM D 256, at 23 ° C. This paper scale applies to China (CNS) A4 Regulation 4 (21〇X 297 public meals)---- 312991 --------1------ (Please read the notes on the back and fill in this Page) Line - Ministry of Economic Affairs and Intellectual Property Office Staff Cooperatives Printed 256 1290149 V. Invention Description (257 Tensile test according to ASTM D 638, in furnace, 23C, span 30mm and application rate 30mm/min Under the conditions, the @(4) sample punched out from the mold tablet is subjected to a tensile test to determine the tensile strength and the elongation at break. The drum film is printed on a mold plate, and the PET sheet is sequentially laminated and the thickness is I〇〇^m, a 20 cm x 20 em square piece of aluminum has been hollowed out at its center, and a 3 · 3 g sample (a polar group-containing olefin copolymer) is placed in the center (hollowed portion). Then, The PET sheet, the aluminum sheet and the molded plate are sequentially stacked thereon. The sample interposed between the molded plates is placed in a 2 Torr hot press and preheated for about 7 minutes. To remove the bubbles in the sample, repeat Pressurize (5〇kg/em2_G) and pressure relief operation several times. Then, increase the pressure to 1〇〇kg/cm2_G and heat the sample 2 under pressure. After the pressure is released, the mold plate is taken out from the heat press 'move it into the different molding machine where the compression part is kept at 〇°c, and then cooled under the pressure of 100 kg/cm2-G for 4 minutes. The sample was taken out. The a polar olefin copolymer film was used to evaluate the initial anti-fog property. The initial anti-fog property was evaluated in a 100 CC beaker, 70 cc of water was placed, and the upper part of the beaker was covered with a sample film. The beaker was placed in a constant temperature water bath at 50 ° C, and the water bath was placed in a thermostatic chamber at 20 ° C. After 24 hours, the degree of fogging on the inner surface of the sample was observed. Evaluation criteria: AA · Water droplets on the surface of the film Flowing, no water droplets adhered to the surface of the film. 1 Paper size scale Guanzhong fresh (CNS) A4 size (2) 0x297 public meals) 257 Order line 312991 258 1290149 V. Invention description (258 BB: large water droplets adhere to the surface of the film Part: CC: Fine water droplets adhered to almost the entire surface of the film. Frost-coated cross-section bonded 詖醅 Prepared cross-cut samples according to the transverse section bonding test described in JIS K5400. Make Cell〇tape (trade name, available from Nichiban Limited) the company Attached to the sample. Then, the cellotape is quickly pulled up at an angle of 90. It is separated from the sample. The number of transverse slices left on the coated film is calculated, which is an indicator of the adhesive properties. The montmorillonite was prepared at 70 C, and 40 g of Na-type montmorillonite was dispersed in 1000 ml of distilled water. In the obtained suspension, 2 〇g of 12-aminododecanoic acid and 2 ml of hydrochloric acid were introduced. The solution obtained in 1 〇〇mi distilled water was at 7 Torr. The crucible was stirred for 2 hours to exchange the metal ions present between the montmorillonite layer and the interlayer with the organic cation. Subsequently, the resulting precipitate was filtered, washed thoroughly with warm water, and then freeze-dried and pulverized to obtain 27 g of montmorillonite which imparts organic properties. The property evaluation test was carried out by containing 92 parts by weight of a propylene/ethylene block copolymer (ethylene content: 56 mol%, MFR: 25 g/10 min), and 5 parts by weight of the above-mentioned organic montmorillonite. And 3 parts by weight of the mixture containing the polar olefin copolymer obtained in each of the examples, each of which is added in an amount of 0.25 parts by weight, Irgan〇x 1〇1〇TM,

Irgaphos 168TM and stearic acid sulphate, the resulting resin in a nitrogen atmosphere, using this paper scale applicable to the Central Standards (CNS) A4 specifications (2) Q χ 297 no 312991 -------- order ------ --- (Please read the note on the back and fill out this page) 1290149

, invention description (259 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 259 twin-screw extruder with a diameter of 20 mm and a cylinder temperature of 200 °c melt-mixed to prepare pellets. The cylinder temperature is 200 ° C, the mold temperature is 40 ° Under the conditions of C and injection pressure of 1 〇〇〇kg/cm2, the pellets were injection molded to obtain samples for evaluation of various properties. The samples were maintained at 23 ° C for 168 hours, and then tested. FM) The injection molded sample was measured using a length of 5 inches, a width of 1/2 inch, and a thickness of ι/8 inch, and the flexural modulus was measured according to ASTM D 638. Impact strength ΠΖ) Using a 1/4 thick sample (back slit), The lz〇d impact strength was measured according to ASTM D258 at 23 °C.盏 Deformation Wen Tang (ΗΡΊΊ Use a length of 5 吋, a width of 1/4 吋 and a thickness of 1/2 射 to form a sample, and determine the heat distortion temperature according to ASTM D 648. Dispersibility in water 丞 Dispersion preparation at room temperature, 40 g of the polar olefin-containing copolymer obtained as a modified polyolefin, 4 g of maleic anhydride grafted polypropylene (propylene/ethylene: 98/2 molar ratio, maleic anhydride content: 4.0% by weight , viscosity average molecular weight: 17,000, density: 0.919 g / cm3, melting point: 136 ° C, softening point: 143 ° C, melt viscosity (180 ° C): 500 cps) and 1 2 g oleic acid surfactant Potassium was mixed. Then, the mixture was kneaded and mixed for 5 minutes with a laboratory plastic grinder (labo-plastomill) (preset temperature: 200 ° C), followed by adding 1 · 4 g 18·7 to the kneaded material. % potassium hydroxide aqueous solution, followed by remelting and kneading for 5 minutes. Next, the contents were taken out from the grinder, and the obtained viscous emulsion was dispersed on 60 paper scales for Chinese National Standard (CNS) A4 specification (210 X 297 public meals) 312991 --------^------- (Please read the notes on the back and fill out this page) Line · 1290149

V. Description of the invention (After 26 〇 〇 〇 员工 员工 员工 员工 员工 员工 印 260 260 260 260 260 260 260 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性 水性Diameter Stability Dispersion stability The aqueous resin dispersion prepared in each example was placed in a closable glass bottle and allowed to stand at room temperature. After one month, the separation between the aqueous phase and the resin phase was observed. The sealant was coated with each dispersion on an aluminum foil (5 〇〆m) by a bar coater, air-dried and then heated in an oven preset at 200 ° C for 10 seconds to obtain a coating having a uniform coating film. Foil. At a temperature of 18 (rc, pressure 1 kg/cm2), according to the method of JIS Z1707, heat-bonded coated foil and LLDPE sheet (available from Akosu Kogyo 厚度·Κ·, thickness: 300 &quot; m) for 1 second Then, cut into a sample with a width of 15 mm. At a measurement temperature of 23 °C, a 180 peel test was performed on the sample to measure the adhesive strength (tensile rate: 3 〇〇mm/min). Dispersibility in the 〇Xuan 1 label. Preparation of 遂A dispersion in 1L glass with stirrer In an autoclave, 55 g of the obtained polar olefin-containing copolymer and 495 g of toluene were placed, and heated to 130 ° C to completely dissolve the resin. Then, the solution was cooled to 85 ° C over 1 hour, followed by 4.5. During the hour, it was cooled from 85 to 4 ° C, and then cooled from 40 ° C to 30 ° C during 30 minutes to obtain a resin dispersion. G's sheet &amp; degree applies to Chinese national standard (CNS) ) A4 size (210 x 297 public) 312991 *111^--------order--------- line - (please read the phonetic on the back? Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 261 1290149

V. INSTRUCTIONS INSTRUCTIONS (261 Dispersed Pellets 4) The diameter of the dispersed particles was measured using a micro-tracking machine manufactured by H〇neywell V. Dispersion stability The solvent dispersion prepared in each example was placed in a closable glass bottle. After the temperature, it was allowed to stand. After a month, observe the separation of the solvent phase from the resin phase. The heat seal strength of ΙΔ1 was applied to each dispersion by a bar coater in a box (5 M m), air dried, and then The coated foil having a uniform coating film was obtained by heating at a temperature of 20 (rc) in an oven for 1 sec. at a temperature of 18 (rc, pressure i kg/cm 2 , according to the method of JIS Z1707, heat bonding coating _ and uDpE tablets (available from Akosu Kogyo KK, show Don · irm &quot;, , w ~ · slice · 300 &quot; m) for 1 second, then cut into a sample 15 mm wide. At a measurement temperature of 23 t, the sample Perform a 180° peel test to measure the bond strength (tensile rate: 3〇〇mm/min) ° Example 1 Place 4 〇〇ml of 癸 癸 in a 1000 ml glass polymerization reactor thoroughly purged with nitrogen Then, at a rate of 201/hr, nitrogen gas was passed at I% °c to maintain its contents for ίο minutes. Then, Tim 0 6mm〇l triisobutylate, followed by further addition of 0.48 mmol of eleven dihydrogen as shown in the following formula (drying with active oxidation). Undecene-1 _ alcohol followed by further addition of 1.100 mm0l methyl aluminum Oxygenane pass + ladder into 312991 _ n «n Hi nnm an'—1 B ϋ an .1« an I— (Please read the note on the back and fill out this page) 嗓线· 1290149

V. Description of the invention (262 nitrogen, followed by a rate of 12.5 Ι / hr? 铋 铋 λ 八 八 八 归. Finally, add 〇 · 〇〇 2 mmol dimethylated dimethyl hydrazine, ^ ^, , —methyl_4,5_(2-methyl-benz)·1-indenyl) (2,7-di-t-butyl-tertene)-zirconium with 0.500 mm〇1 methyl aluminum emulsion The alkane was contacted for 1 minute at room temperature to initiate the polymerization. After 13 hours of TC and atmospheric pressure, the polymerization was carried out for 1 hour, and then the polymerization was added. Then, H) 0 ml of isobutanol solution containing 1 ml of concentrated aqueous hydrochloric acid solution was added, followed by nitrogen at 75 t. Heat in the atmosphere. The prepared polymer solution was introduced into an excess of methanol to precipitate a polymer, followed by 8 (TC vacuum drying), and the product was dried for 12 hours. As a result, 3.73 g of a polymer was obtained. The properties of the resulting polar olefin-containing copolymer are described in Table 8. The adhesive strength of the polar olefin-containing copolymer (pair ai) was measured by the above method, and the results are summarized in Table 9. Example 2 In a 1 〇〇〇 ml puzzle glass polymerization reactor thoroughly purged with nitrogen, 400 ml of toluene was placed, and then nitrogen gas was back-twisted at 20 1 / hr, and the contents were kept at 90 ° C. minute. Next, 〇 6 mm〇i triisobutylaluminum was added, followed by further addition of 48·48 mmol of T2-31⁄4 ethoxy-9-pinene (dried with vermiculite alumina). !, 2_epoxy-9-nonene, the addition and stop of the introduction of gas into the step then followed by ethylene at a rate of 12.5 Ι / hr. Finally, add it to make 0.002 mm〇i di-n-based dialkyl-based alkyl group (27 dimethyl _4 paper size standard (CNS) A4 specification (2) Gx297 soil, order m 262 312991 A7

Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing

1290149 V. INSTRUCTIONS (263) Benzyl-benzo)-1-indenyl) (2,7-di-t-τ = gangan, ^-butylyl) wrong with 0.500 mmol methyl oxy-oxygen The toluene slurry of the eight demon minutes was contacted at room temperature to initiate the polymerization reaction at 0 〇C, under normal pressure, and the polymerization was carried out for 1 hour, and a small amount of isobutanol was added to terminate the polymerization. The service ‘people, n 莪 ,, added 1 〇〇ml of isobutyl hydrazine solution containing 1 ml of concentrated aqueous hydrochloric acid solution, followed by heating at 75 ° C in a nitrogen atmosphere. The resulting polymer solution was introduced into a large excess of methanol to precipitate the polymer' followed by vacuum drying at 8 Torr for 12 hours. As a result, 3 64 g of a polymer was obtained. The properties of the polar-containing dilute copolymers are known in Table 8. The bonding strength of the polar olefin-containing copolymer (for PEτ) was measured by the above method, and the results are shown in Table 9. Example 3 In a 1 〇〇〇ml glass polymerization reactor thoroughly purged with nitrogen, 400 ml of n-decane was placed, and then nitrogen gas was introduced at a rate of 20 Torr/hr to maintain its contents at 90 °C. Minutes. Next, 〇 6 mmol of triisobutyl yt was added, followed by further addition of 2 48 mmol of (2,7-octanedi-diyl) succinic anhydride (drying with activated alumina) of the following formula. (2,7-octanedien-1-yl) succinic acid needle Next, 1.100 mmol of methylaluminoxane was further added and nitrogen gas was stopped, followed by introduction of ethylene at a rate of 12.5 Torr/hr. Finally, add 0.002 mmol of dimethyl dithiomethane (2,7-dimethyl-4,5-(2-A--------------- -------- Line mr (Please read the note on the back and fill out this page) This paper scale applies to China National Standard (CNS) A4 specification (210x297 public) 263 312991 1290149 A7 B7 Ministry of Economic Affairs Intellectual Property Bureau Printed by the Employees' Cooperatives 264 V. INSTRUCTIONS (264) Benzyl benzo)-1-indenyl) (2,7-di-t-butyldiyl) and 〇500 mm〇1 Methyl Aluminoxy The toluene slurry was contacted for 1 minute at room temperature to initiate the polymerization. After polymerization was carried out for 1 hour at 13 CTC under normal pressure, the polymerization reaction was terminated by adding J-isobutyl thin. Next, 100 ml of an isobutanol solution containing i ml of a concentrated salt solution was added, followed by heating at 75 ° C in a nitrogen atmosphere. The resulting polymer solution was introduced into a large excess of methanol to precipitate the polymer, followed by drying at 80 t: vacuum for 12 hours. As a result, 3-18 g of a polymer was obtained. The properties of the resulting polar olefin-containing copolymer are described in Table 8. The bonding strength of the polar olefin-containing copolymer (Ny) was measured by the above method, and the results are shown in Table 9. Example 4 The copolymerization reaction of propylene and a polar group-containing monomer was carried out in the same manner as in Example 1, except that 0.00075 mm 二l second morning dimethyl decyl alkyl group (2 methyl · 4 phenanthrenyl group 1 fluorenyl group) Zirconium substituted dimethyl dialkyl decyl (2,7-dimethyl-4,5-(2-methyl-benzo)-yl) (2,7·di-t-butyldiyl)铢, using pentapropenyl succinic anhydride represented by the following formula as a monomer having a polar group, and introducing propylene-substituted ethylene, polymerization was carried out at 60 ° C for 30 minutes. 0

The properties of the polar olefin-containing copolymer obtained from pentapropylene succinic anhydride are described in the paper size g of the Chinese National Standard (cns) A4 specification (21〇χ 297 mm) 312991 ----------- ---------Book---------Line· (Please read the notes on the back and fill out this page) 1290149 A7 Printed by the Ministry of Intellectual Property, Consumer Cooperatives. 265) The bonding strength of the polar group-containing olefin copolymer (for Evqjj) was measured by the method described, and the results are shown in Table 9. Example 5 Polymerization was carried out in the same manner as in Example 4 except that pentane, 2-epoxy-t-decene was substituted for pentapropenylsuccinic acid J6 anhydride. The properties of the obtained polar olefin-containing copolymer are described in Table 8. 20% by weight of the polar olefin-containing copolymer prepared above, 80% by weight of nylon 6 (relative viscosity: 2*35 di/g), at 25 〇ΐ, melted by a twin-screw extruder with a diameter of 20 mm The mixture was kneaded to prepare a thermoplastic resin composition. The impact resistance test and the tensile test of the thermoplastic resin composition were carried out by the methods described above, and the results are shown in Table 9. Example 6 In 10% by weight of the polar olefin-containing copolymer prepared in Example 4, 30% by weight of nylon 6 (relative viscosity: 2 35 dl/g) &amp; 6 〇 by weight of propylene homopolymer (MFR (230) was added. °C, load 2.16 kg): 2·2 g/l〇min), the mixture was melt-kneaded at 250 ° C in a twin-screw extruder having a diameter of 20 mm to prepare a thermoplastic resin composition. The impact resistance test and the tensile test of the thermoplastic resin composition were carried out by the methods described above, and the results are shown in Table 9. Comparative Example 1 In a 70% by weight propylene homopolymer (MFR (23 (rc, load 2 l6 kg): 2 Jg/l 〇 min), 3 〇 weight 0 / 〇 nylon 6 (relative viscosity · 2 35 dl / g) was added. The mixture was melt-kneaded at 250 ° C in a twin-screw extruder having a diameter of 20 mm to prepare a thermoplastic resin composition. The impact resistance test and tensile test of the thermoplastic resin composition were carried out by the aforementioned method. -------,,,,, ° The paper size of the paper applies to the Chinese National Standard (CNS) A4 specification (10) x 297 public) 312991 265 ------------- 镰 (please Read the precautions on the back and fill out this page. -------------- 1290149 A7 B7 V. Description of invention (266) in Table 9. Example 7 Polarized by Example 1. The base olefin copolymer was produced by the method described above, and the thin enthalpy was produced, and the impurities were evaluated. The result was dispersed in 9. The coating example 8 was polymerized in the same manner as in Example 1, and the following formula was shown. Decyl enol replaces de-olefin "alcohol, and replaces ethylene with propylene. Printed by the Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative (5 12-trifluorocarbon The properties of the dilute hydrocarbon copolymer are described in Table 8. The coating properties of the polar group-containing olefin copolymer were evaluated by the foregoing method, and the results are shown in Table 9. Example 9 The polar group-containing olefin copolymer obtained in Example 4 was used. The filler dispersibility was evaluated by the foregoing method, and the results are summarized in Table 9. Comparative Example 2 The dispersibility of the filler was evaluated in the same manner as in Example 9, except that the polar group-containing copolymer was not used, and the results are summarized in Table 9. Example 1 0 Example of use The obtained polar olefin copolymer was prepared by the above method, and the dispersibility in water was obtained by the method of the method. The results are shown in Table 9. Example 11 - --------------------^---------^. (Please read the notes on the back and fill out this page) -nn I _

266 312991 1290149 A7 V. INSTRUCTION DESCRIPTION OF THE INVENTION (267) The reaction of ethylene with a polar group-containing monomer was carried out in the same manner as in Example 1 except that the decenoic acid represented by the following formula was substituted with a decyl alcohol. ,

The properties of the obtained polar olefin-containing copolymer obtained from undecylenic acid are shown in Table 8. The water-free dispersion was prepared by using the thus obtained polar group-containing hydrocarbon copolymer, and the dispersibility in water was evaluated by the aforementioned method. The results are summarized in Table 9. . Example 12 Using the polar group-containing olefin copolymer obtained in Example 3, a solvent dispersion was prepared by the aforementioned method, and its dispersibility in a solvent was evaluated by the aforementioned method. The results are shown in Table 9. (Please read the note on the back and then fill out this page) Order---------Line· Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed This paper scale applies China National Standard (CNS) A4 specification (210 X 297 mm) 267 312991 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1290149 A7 ___B7 V. Invention description (268) *l:^lvo°oc '##2.16kgT^#isM *2: Qin 230 oc ' 潍瀚2·16kgT^ftMM Instance 11 Instance 8 Instance 5 Instance 4 Instance 3 Instance 2 Instance 1 5C ο X Ca&gt; ch3 ο X w ΣΤ π: Composition unit (1) ! Rl C8Hi6 CiiH2? C6Hi2! C13H18 c6H10 C6Hi2 C9H18 ! 1 1 1 1 1 I 50 constituent unit (3) COOH ο a epoxy group 1 s change anhydride group 1 1 1 Γ ^ 1 phthalic anhydride group / epoxy group 0 X 99.5/0.5 99.5/0.5 -: -1 99.5/0.5 99.5/0.5 99.5/0.5 99.5,0,5 1 99.5/0.5 (1)/(3) Composition (Morby) 70,000 250,000 250,00. 250,000 70,000 72,000 100,000 ro Lu CJ1 14.6 Μ « Η» • C\ Κ) • Cn to • cn 0 • :(g/l〇) MFR μί Ν3 to 5(- 冷ro • N&gt; 鲁σ\ ro -a ω i cn Ν5 参N) ro 00 00 fO • 1 Mw/Mn ο • ο Η* ο • Ν) Ο 0.15 0 Η » » » » » » » » » » » » » » » » » ------Line (please read the precautions on the back and fill out this page) This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 268 312991 1290149 A7 B7 V. Description of invention (269 ) Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperatives Printed Table 9 Nature Item Property Value Unit Example 1 Bond Strength (for A1) 2 Kgf/15mm Example 2 Bond Strength (for PET) Matrix Cracking Kgf/15mm Example 3 Bond Strength (for Ny 6.2 Kgf/15mm Example 4 Adhesive strength (for EV0H) 6.5 Kgf/15mm Example 5 IZ 32 J/m Tensile strength 41 MPa Elongation at break 11 % Example 6 IZ 28 J/m Tensile strength 40 MPa Elongation at break 13 % Comparative Example 1 IZ 15 J/m Tensile strength 22 MPa Elongation at break 4 % Example 7 Antifogging properties observed) ΆΆ Example 8 Cross-section bonding test 100/100 Cut-month number/slice number Example 9 FM 1900 MPa IZ 55 J/m HDT 129 °C Comparative Example 2 FM 1250 MPa IZ 52 J/m HDT 115 °C Example 10 Dispersed particle diameter 0.7 Pm Dispersion stability not separated Heat seal strength of A1 2 Kgf/15mm Example 11 Dispersed particle diameter 0.6 pm Dispersion stability not separated Heat seal strength of A1 2.5 Kgf/15mm Example 12 Dispersed particle diameter 10 pm Dispersion stability is not separated iiAl ¥¥^degree 3 Kgf/15rom -------------Mm (Please read the back note first and then fill out this page) Order --------- Line - Ben The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 269 312991 1290149

V. INTRODUCTION INTRODUCTION Pan 70 Example 13 In a 2 liter stainless steel (SUS) high pressure crucible thoroughly purged with nitrogen, 120 g of butene, 880 ml of hexane (Mitsui) and 1.50 mm of 三1 triisobutyl cui were placed. Lu. The SUS autoclave was heated to 150 ° C, and 1.140 mm 〇i methyl aluminoxane was added. Then, 1.350 mmol of undecene-co-alcohol represented by the following formula (dried with activated alumina and then vacuum distilled) was further added. . While maintaining the temperature at 150 ° C, the high pressure crucible was pressurized with ethylene so that the total pressure became % kg / cm 2 - G. 0Η eleven-1 -ol was additionally injected into a 20 ml glass flask thoroughly purged with nitrogen, and nitrogen gas was injected therein to 0.00075 mmol of dimethyldimethylene dichloride (2-methyl-'benzino) (2,7-di-t-butylindenyl) is a toluene slurry which has been contacted with Q4300 mmol methyl oxane for 10 minutes at room temperature, and further injected with 000 Nml of hydrogen. During the period of 1 minute after the injection, the temperature of the autoclave was maintained at 150 ° C, and the pressure therein was maintained at a pressure just after the pressure injection of ethylene. The polymerization was then terminated by adding a small amount of isobutanol. The obtained polymer solution was introduced into a large excess of methanol to precipitate a polymer, followed by vacuum drying at 80 ° C for 12 hours. As a result, 1 〇 4 〇 g of a polymer was obtained. The polymerization activity was 83 kg/mmol. Zr · hr. The properties of the resulting polar olefin-containing copolymer are described in Table 1. The coating properties of the polar olefin-containing copolymer were evaluated by the methods described above. The results are shown in Table U. Example 14 atm 13 method to make ethylene, 1-butene and a polar group-based single paper ruler _ _ fresh 270 ordering line 312991 1290149 B7 five, invention description) body 仃 polymerization 'but the following ten - dilute acid instead of eleven small alcohol

The properties of the polar olefin-containing copolymer obtained from undecanoic acid are described in Table ι. The bonding strength of the polar group-containing olefin copolymer (for A) was measured by the method described above, and the results are shown in Table U. Example 15 In the same manner as in Example 13, the monomer of the group B, and the monomer having a polar group was subjected to the same method. The polymerization was carried out as shown in the following formula: ls2 epoxy group _9_癸 dilute undecen-1-ol and 550 Nml of hydrogen was used.

The properties of the polar olefin-containing copolymer obtained from the i,2-epoxy-9-nonene produced by the Ministry of Economic Affairs, the Ministry of Finance, and the Consumers' Co., Ltd. are described in Table 1. 20% by weight of the polar group-containing olefin copolymer prepared above, 80% by weight of nylon 6 (relative viscosity: 2.35 dl/g), and melt-kneaded at 25 (rc, a twin-screw extruder having a diameter of 20 mm) The mixture was prepared to prepare a thermoplastic resin composition. The impact resistance test and the tensile test of the thermoplastic resin composition were carried out by the methods described above, and the results are shown in Table U. Example 16 In the same manner as in Example 13, ethylene 'butene and a polar group were used. The monomer is polymerized, but the (2,7-octadienyl) succinic anhydride shown in the following formula is substituted for undecene, and the alcohol is used and 550 Nml of hydrogen is used. The paper size is applicable to the Chinese National Standard (CNS) A4 specification. (210x297 public) 271 312991 --------------------- Order --------- line · (Please read the phonetic on the back? Fill in this page)

1290149 A7 __ ______ B7 V. DESCRIPTION OF THE INVENTION (272 (2,7-octadiene); succinic anhydride The properties of the polar olefin-containing copolymer obtained are described in Table 1. 20 20% by weight as prepared above In the polar group-containing olefin copolymer, a weight % nylon 6 (relative viscosity ······························· The impact resistance test and the tensile test of the thermoplastic resin composition were carried out by the methods described above, and the results are shown in Table u. Example 17_ Polymerization of ethylene, propylene and a monomer having a polar group in the same manner as in Example 16 However, under the initial partial pressure of 3 kg/cm2, the propylene-butene-injection was replaced by propylene, and hydrogen was not added and the polymerization was carried out at 8 (TC polymerization temperature). The properties of the obtained polar olefin-containing copolymer are described in Table 1. Adding 8 重量% of nylon 6 (relative viscosity: 2 dl/g) to 20% by weight of the polar olefin-containing copolymer prepared above, and mixing the mixture with the diameter of the snail in the second generation To prepare a plastic tree deer composition. The impact resistance test and the tensile test of the thermoplastic resin composition were carried out, and the results are shown in Table 11. The paper scale standard (CNS) A4 specification (2) Q χ 29^^7 312991 -------- -------------Book-丨------- (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 272 1290149 A7

B V. INSTRUCTIONS (273) Printed by the Consumers’ Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs

畸 宣 宣 宣; X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X ο 1 1 〇tc 00 〇\ Ι-» VD gin cn \ 〇ΪΟ U% 00 00 \ Η» H* • cn \ o K) cn CO CD \ Η·1 Η» ^3 ϋΐ \ ο Ν3 cn &lt;χ&gt; 0D \ Μ Η* cn \ ο Ν Ν&gt;&lt;J\ 00 ω \ M cn \ O cn 卜 1 po r 备IS&gt; ^ \如sz Μ ω Μ Ο Ο ο ro to ooo Μ ω ο ο ο ο Μ Ο Ο ο ο an oooof ro ω to VO ΓΟ (λ) Do • ro s Ά Today 33 Ν ϋΐ ΓΟ • ΪΟ • ω Ν &gt; • κ> NJ 00 1 ο ο NJ oo (a&gt; ο ο cn ο o S --------------------^---------mu (Please read the notes on the back and fill out this page) China National Standard (CNS) A4 Specification (210 X 297 mm) 273 312991 1290149 V. Description of Invention (274) Table 11 Nature of Property Item Unit Example 13 Cross-Slice Bonding Test 100/100 Number of Slices/Slice Number Example 14 Adhesive Strength (Α1) 3.6 Kgf/15mm Example 15 ΙΖ 490 J/m Tensile strength 40 MPa Breaking extension Rate 40 % Example 16 ΙΖ 260 J/m Tensile strength 45 MPa Elongation at break 120 % Example 17 ΙΖ 265 J/m Tensile strength 46 MPa Elongation at break 122 % (Please read the notes on the back and fill out this page) Printed by the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative 274 Example 18 In a 1000 ml glass polymerization reactor thoroughly purged with nitrogen, 400 ml of n-decane was placed, and then nitrogen gas was introduced at a rate of 20 Torr/hr. 130. (: Keep the contents for 1 minute. Then, add 6 mmol of triisobutylate, followed by further addition of 0.48 mmol of δ 12-tridecenol of the formula (drying with activated alumina, then vacuum distillation) The paper size applies to the Chinese National Standard (CNS) A4 specification (210 297 297 gong a) 312991 A7 1290149 V. Description of the invention (275 of 12-tridecenol followed by further addition of 1.100 mjnol methyl aluminoxo Nitrogen gas was stopped and ethylene was introduced at a rate of 12·5 17 hj. Finally, add 2 mmol of diammonium dimethyl hydrazide (2 7 dimethyl _4 5 (2 methyl-benzo)-1 _ group) (2,7_di- The third butyl group) was combined with a 0.500 mm 〇1 methyl oxysulfide toluene slurry which had been exposed to room temperature for 10 minutes to initiate polymerization. After polymerization was carried out at 130 ° C under normal pressure for 1 hour, a small amount of isobutanol was added to terminate the polymerization. Next, 100 ml of an isobutanol solution containing 1 ml of a concentrated salt solution was added, followed by heating at 75 ° C in a nitrogen atmosphere. The resulting polymer solution was introduced into a large excess of methanol to precipitate the polymer, followed by vacuum drying for 12 hours. As a result, 3-44 g of a polymer was obtained. The properties of the resulting polar olefin-containing copolymer are described in Table 12. The coating properties of the polar olefin-containing copolymer were evaluated by the methods described above. The results are shown in Table 13. Example 2 The copolymerization of propylene and a polar group-containing monomer was carried out in the same manner as in Example 18 except that it was replaced by 0 00075 mmol of dimethylalkylene chloride (2-methyl-4-phenanthryl). Dimethyl decyl chloride (2,7-dimethyl-4,5-(2-methyl-benzo)indolyl) (2,7-di-t-butylidene) The ethylene was replaced by propylene, and polymerization was carried out at 60 ° C for 30 minutes. The properties of the resulting polar olefin-containing copolymer are described in Table 12. τ The above method is used to evaluate the frost-coated Keben paper ruler of the polar-containing dilute hydrocarbon copolymer n?iiiiy^A4 secret (2)^ x 297^---_ 312991 I / I n 11 1 n ϋ βϋ nn 0 I ·ϋ ϋ L_i n ϋ n IV a ϋ nna- n ϋ I /€^/1 I Volume mi (please read the phonetic on the back? Please fill out this page again) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 275 1290149 A7 ___ B7 Five Inventive Note (m) Quality 'The results are summarized in Table 13. Example 20 In a 2 liter stainless steel (SUS) high pressure punch thoroughly purged with nitrogen, 120 g of 1-butene, 950 ml of hexane (Mitsui) and 1.50 mmol of triisobutyl were placed. The SUS autoclave was heated to 150. (:, add 〇14〇mm〇1 methyl oxygen, then further add 1.350 mmol of the above formula to account for i2_tridecene thin (dried with vermiculite alumina, then vacuum distilled). Keep the temperature at 15 °C, and add the high pressure dad to ethylene to make the total pressure become % k/cm2-G. In addition, in a 20 ml glass flask purged with nitrogen, nitrogen is injected into it. 0.00075 mmol of dimethylated dimethyl anthracene (2-methyl-4,5-benzo--1_enyl) (2,7-di-t-butyldiyl)zirconium and 04300 mm〇l The methoxane was contacted with a toluene slurry at room temperature for 10 minutes and further injected with 600 Nml of helium. During the 1 minute period after the injection, the temperature of the autoclave was held at 150 °C, and the pressure inside it was maintained. The pressure immediately after the injection of ethylene was carried out. Then, a small amount of isobutanol was added to terminate the polymerization. The obtained polymer solution was introduced into a large excess of methanol to precipitate a polymer, followed by vacuum drying at 80 ° C. 12 hours. As a result, 10.40 g of a polymer was obtained. The polymerization activity was 83 kg / mmol · Zr · hr. The obtained polar olefin-containing copolymer The properties are described in Table 12. The coating properties of the polar group-containing olefin copolymer were evaluated by the methods described above, and the results are shown in Table 13. Example 21 The copolymerization of acetamidine and a polar group-containing monomer was carried out in the same manner as in Example 18. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 312991 -------------€ (Please read the note on the back and fill out this page) ------- Line·· Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperative Printed 276 1290149 A7 ______B7______ V. Invention Description (277) Reaction 'But the fifteen d-renoic acid substitution shown in the following formula accounts for 12_10 Trienol.

Fifteen-14-enoic acid The properties of the 3-polar olefins copolymerized are described in Table 12. The bonding strength of the polar group-containing olefin copolymer (for A1) was evaluated by the aforementioned method, and the results are shown in Table i3. Example 22 The copolymerization of propylene and a polar group-containing monomer was carried out in the same manner as in Example 19 except that the penta-alkenyl amber anhydride represented by the following formula was substituted for 5 12 -tridecanol 0 -------- ----羲(Please read the notes on the back and fill out this page)

Jade propylene succinic anhydride Printed by the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperatives The properties of the resulting polar olefin-containing copolymers are described in the table. The bonding strength of the polar group-containing olefin copolymer (for A1) was evaluated by the above method, and the results are shown in Table 13.

277 312991 1290149 A7 _B7 V. Description of invention (278) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed *1MM Department Feng 190..°雉澎2· 16kg *2M^&gt;窬丰:230..°滩澉2.16kg Η 窆Μ IV&gt;窆Ν&gt; Ο 4 室 re pn 匁r bran ω ac S j Ο ΙΟ 3: ro a Μ X κ a sc S a Ι-» 3: K&gt;IS&gt; να One potential X 1 1 1 1 1 β I η ο ο κ I § o κ I o 3: κο VO • -J ϋΐ \ Ο in VD VO cn \ ο to cn 00 00 \ Μ 4 cn \ ο cn vo VO • cn \ o Cn VD cn cn \ o 皋 (J! Μ F Τ ^ 土书ISJ /pN r K \ 44 N) Do VD oo P -'•J Μ Ο ο ο Η» Η1 Ο ο ο ο ro cn oo O o - J oooo I 办心 to 参玲办ro * Ί-* Η» • σ\ r5 cn * -Λ% yQ Η» « 〇ζ 50 Μ ίο N) 呒ϋΐ Ν3 00 ro ωω rs&gt; • &gt;〇ISD Ο • Μ 00 ο Ο ο Μ σ\ o I | 1 12 --------------------- Order --------- Line (please Read the notes on the back and fill out this page. This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 278 312991 1290149 A7 B7 , invention description (279) Table 13 Evaluation item property value unit example 18 Cross-section bonding test 100/100 Number of slices/slice number Example 19 Cross-section bonding test 100/100 Number of slices/slices · Example 20 Cross-section bonding test 100/ 100 slice number/slice number example 21 Adhesive strength (for A1) 3 Kgf/15rrim Example 22 Adhesive strength (for A1) 3.5 Kgf/15mm (please read the note on the back before filling this page) Suspect - Ministry of Economics Intellectual Property Bureau employee consumption cooperative printing 279 Example 23 In a 1000 ml glass polymerization reactor thoroughly purged with nitrogen, 400 ml of toluene was placed, and then nitrogen gas was introduced at a rate of 20 Torr/hr to maintain its contents at 60 ° C. 10 minutes. Next, 0.6 mmol of triisobutylate was added, followed by further addition of 0.48 mmol of (2,7-octadien-1-yl)succinic acid if represented by the following formula. This paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991 1290149

Printed (2,7-octadienyl-1_yl) succinic acid by the Ministry of Economic Affairs, Intellectual Property Office, and the Consumer Cooperatives. Further, add L100 mmol methyl oxane and stop the introduction of nitrogen guanidine. After 16.9 1/hr The rate is passed into propylene. Finally, the addition of 〇·〇〇75 mmol di-vaporized dimethyl-extended fluorenyl (2·methyl-4 phenanthyl d-yl) and 0.500 mmol of methyl jaloxane was contacted at room temperature. A minute of toluene slurry was added to initiate the polymerization. After polymerization was carried out for 6 minutes at 6 (rc, normal pressure), the polymerization was terminated by adding a small amount of isobutanol. Then, 100 ml of an isobutanol solution containing 1 ml of concentrated aqueous hydrochloric acid was added, followed by a nitrogen atmosphere at 75 t. The obtained polymer solution was introduced into a large excess of methanol, and the polymer was allowed to settle, followed by vacuum drying at 8 ° C for 12 hours. As a result, 175 g of a polymer was obtained. The properties of the copolymer are described in Table 4. The adhesion strength of the polar olefin-containing copolymer (for A1) was evaluated by the method described above, and the results are shown in Table 15. f Example 24 1000 ml of glass thoroughly purged with nitrogen In the polymerization reactor, 400 ml of toluene was placed, and then nitrogen gas was introduced at a rate of 20 Torr/hr, and the contents were kept at 90 ° C for 10 minutes. Then, 〇·6 mmol of triisobutylaluminum was added, followed by further addition. 0.48 mmol of 1,2-epoxy-9-decene as shown in the following formula (dried with vermiculite alumina). This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 280 312991 ------------# (Please read the notes on the back first) Complete this page) book ---------_ 1290149

Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, printed 281 epoxy-9-decene, then add UO mm〇1 methyl group to stop nitrogen, and then pass 12.5 1 / hl • 诘 λ, from ^ rate Into the ethylene. Finally, add its deficit. The dimethyl chlorohydrin group is dimethyl-5,5·(2-methanebenzo)1 germination) (2,7-di-t-butylidene) and 〇5〇. The 1 M minute toluene slurry was contacted with μmethyl(tetra) I at room temperature to initiate the polymerization reaction. The polymerization reaction was terminated by adding a small amount of isobutanol at 50 C and atmospheric pressure τ for 1 hour. Next, a 100 m]isobutanol solution containing 1 ml of a concentrated aqueous solution of hydrochloric acid was added, followed by heating at 75 t:, helium atmosphere. The resulting polymer solution was introduced into a large excess of methanol to precipitate the polymer, followed by drying under vacuum at 80 Torr for 12 hours. As a result, 3 g of a polymer was obtained. The properties of the resulting polar olefin-containing copolymer are described in Table 14. The bonding strength of the polar group-containing olefin copolymer (for A1) was evaluated by the method described above, and the results are shown in Table 15. Example 25 A copolymerization reaction of ethylene with a polar group-containing monomer was carried out in the same manner as in Example 24, except that 4-hex-5-sweetoxy-benzene was substituted for 1,2-epoxy-9- represented by the following formula. Terpene.

XX 4-Hex-5-alkenyloxy-phenol This paper scale applies to Chinese National Standard (CNs) A4 specification (210x 297 mm) 312991 --------^--------- $ m (Please read the notes on the back and fill out this page) A7 1290149 V. INSTRUCTIONS (282) The properties of the obtained polar olefin-containing copolymer are described in Table 14. The polar olefin-containing copolymer was evaluated by the method described above. PETy bond strength, the results are described in Table 15. -------------------- Order --------- line (please read the back of the note first) Fill in this page again) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Printed on this paper scale Applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) 282 312991 1290149 A7 B7 V. Invention Description (283) MM$+ ” 23°0c, 搀#2· 16kg *2m$f+: 19°oc, ^#r°16kg Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs

窆宣ro 〇ι ro N&gt; OJ X -s ?3 c bran-^s AP 00 〇σν tc K oa\ SC M ?〇〇1 1 cn ω J one phase A 锞pi X irt K〇KD VO KD VO CJi (ji CJi 参 \ \ 〇 \ \ Μ Ο o OJ Μ cn N) CJi N) 〇l S o σ\ oo tO (J1 oooooooooo PO N&gt; do s cn 00 as Ι-» o 奇5〇r5 cold Today ooo 参to cn • N) (jy • NJ U&gt; O o 〇_ 1 1-3 i W -------------------- order----- ----Line (please read the note on the back and then fill out this page) This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 283 312991 A7 B7 1290149 V. Invention description (284) 15 Evaluation Item Property Value Unit Example 23 Adhesive Strength (for A1) 3.6 Kgf/15mm Example 24 Adhesive Strength (for PET) Matrix Cracking Kgf/15mm Example 25 Adhesive Strength (for PET) 3 Kgf/15mm (Please read the back note first) Please fill out this page again) 旷Example 26 In a 1000 ml glass polymerization reactor thoroughly purged with nitrogen, put 400 ml of toluene, then at a rate of 20 Ι / hr The atmosphere was purged with nitrogen and the contents were kept at 〇 ° C for 10 minutes. Next, 〇·6 mmol of triisobutylaluminum was added, followed by further addition of 0.48 mmol of undec-1-ol of the formula. -1-Alcohol Next, further adding 1.100 mmol of methyl oxynitride and stopping the passage of nitrogen, followed by 1-butene at a rate of 12.5 Torr / hr. Finally, adding 0.0020 mmol of dimethyl dichloride The alkyl (2-methyl-4-phenanthryl-1-yl) group was contacted with 0.500 mmol of methyloxo-oxygen in a toluene slurry at room temperature for 1 minute to initiate polymerization. After the polymerization was carried out for 60 minutes under normal pressure, the polymerization was terminated by adding a small amount of isobutanol. Then, 100 ml of an isobutanol solution containing 1 ml of a concentrated aqueous hydrochloric acid solution was added, followed by heating at 75 ° C under a nitrogen atmosphere. Introduce the prepared polymer solution into the paper size. Applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 —I _1 an 一1 ·1_1 n ·ϋ I -ϋ «1_ι nf Ministry of Economics Intellectual Property Bureau staff consumption cooperatives printed 284 A7 B7 1290149 V. Invention description (285) for excess The polymer was allowed to stand in methanol and then dried under vacuum for 8 hours at rc. As a result, 0 J5 g of a polymer was obtained. The properties of the resulting polar olefin-containing copolymer are described in Table 16. The coating properties of the polar group-containing hydrocarbon copolymer were evaluated by the methods described above. The results are shown in Table 17. In the same manner as in Example 26, 1-butene was polymerized with a polar group-containing monomer, except that 1,2·epoxy-9-decene was substituted with undecen-1-ol.

1,2_Epoxy-9-oxime The properties of the resulting polar olefin-containing copolymer are described in Table 16. The adhesive strength of the polar olefin-containing copolymer (for PET) was evaluated by the aforementioned method, and the results are shown in Table 17. Example 28 In the same manner as in Example 26, 1-butene was polymerized with a polar group-containing monomer, and 1.15 mmol of undecylenic acid substituted with undecen-1-ol as shown in the following formula was used and 1.5 mmol of triiso was used. Butyl.

The properties of the resulting polar olefin-containing copolymer are described in Table 16. The bonding strength of the polar group-containing olefin copolymer (for A1) was evaluated by the above method, and the results are shown in Table 17. This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 312991 §1 n 1 ϋ I n ϋ —Bi ϋ ϋ ·ϋ ϋ · ϋ ·ϋ ϋ ·1_1 I ϋ n .1J · μ· * μη* μμ μμ μμ μμ* ι _ t Μ φ (Please read the notes on the back and fill out this page) Ministry of Economic Affairs Intellectual Property Office Staff Cooperatives Printed Farmers 285 1290149 A7 B7 0

V. INSTRUCTION DESCRIPTION (m) Example 29 In the same manner as in Example 26, butene was polymerized with a polar group-containing monomer, except that (2,7-octadienyl)-succinic anhydride represented by the following formula was substituted. Mono-1-ol. (2,7-octyl-1 -yl) acid-cracking needle The properties of the polar-containing dilute hydrocarbon copolymer are described in Table 16. The adhesion strength of the polar olefin-containing copolymer (for Ai) was evaluated by the method of the above description. The results are shown in Table 17. (Please read the notes on the back and then fill out this page) Γ % Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperative Printed on this paper scale Applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) 286 312991 1290149 A7 _B7 Five , invention description (287) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed MM Chafeng" 190.. ° holding 郐 2 · 16kg 碕 N) ΛΟ to to 00 N> 宣 N> 办 o - _ _ _ 〇 ι ι Π Μ 〇mmo (Λ tc io o VO ffi H* 00 5〇ω one more; A 1 1 1 1 r〇β 1 oow tungsten pi 1 〇rc XV£> VO cn O • MU\ ΛΟ -J tJl o • Cn \o VD «-J cn o 瘫ro cn ΛΟ SO cn O • cn κ Ϊ 2 η Μ Μ £ l·-1 〇ooo CS GO 〇ooo -j lO oooo -joooo S ro GO M w • H4 o • Ίο &lt;Γ» 〇^ s Μ ^ Ο owe 3f 今Η N) tn N) CJ ro UU) N) ro 1 S 3 〇oooo 1 IS &gt;tv 00 00 σσ\ S &gt; ---- ----------------^---------Line (please read the notes on the back and fill in this page) This paper scale applies to China National Standard (CNS) A4 size (210 X 297 mm) 287 312991 A7 1290149 V. INSTRUCTIONS) Table 17 Evaluation item property value unit Example 26 Cross-section bonding test 100/100 Number of slices/slice number Example 27 Adhesive strength 23°C (for PET) 8〇〇c Matrix fracture Example 28 Adhesive strength 23 °C ' 2.8 Kgf/15mm (for Al) 8〇〇c 2.8 Kgf/15mm Example 29 Bond strength 23°C 3.5 Kgf/15mm (for Al) 80°C 3.5 Kgf/15mm Example 30 Fully purged with nitrogen In a 300 ml glass polymerization reactor, 40 ml of 1-octene was placed, then nitrogen gas was introduced at a rate of 20 Torr/hr, and the contents were kept at 60 ° C for 1 minute. Then, 0·6 mmo1 was added. Isobutylate, followed by the further addition of 0.48 mmol of eleven-1-ol shown by the formula. Eleven-1 -ol Next, 1100 mmol of methylaluminoxane and 40 ml of 1-octene were further added. Finally, 0 002 mmol of dimethylated dimethyl anthracene (2-methyl-4-phenanthryl-1-yl) zirconium and 0.500 mmol of methylaluminoxane were added for 10 minutes at room temperature. A toluene slurry was used to initiate the polymerization. After the polymerization was carried out for 60 minutes at 20 ° C under normal pressure, the polymerization was terminated by adding a small amount of isobutanol. Next, a solution of 1 ml of a concentrated aqueous solution of hydrochloric acid in 1 ml of isobutanol was added, followed by heating at 75 ° C in a nitrogen atmosphere. The paper will be made up of the T-National Standard (CNS) A4 specification (210 χ 297 mm) 312991 -------- order --------- line _ (please Read the notes on the back and fill out this page.) Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, Print A7

1290149 Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs 289 The polymer solution was introduced into a large excess of methanol to precipitate the polymer, which was vacuum dried at 80 ° C for 12 hours. As a result, 〇 25 g of a polymer was obtained.性质 The properties of the obtained polar olefin-containing copolymer are described in Table 8. The coating of the polar olefin-containing copolymer was evaluated by the method described above. The results are shown in Table 19. Example 31 An octene was polymerized with a polar group-containing monomer in the same manner as in Example 30 except that 1,2-cyclodecyl-9-decene was substituted for undecene_丨_ as shown in the following formula.

1,2-Epoxy- 9-decene The properties of the obtained polar olefin-containing copolymer are described in Table 18. The impact resistance test and the tensile test of the polar group-containing olefin copolymer were carried out by the methods described above, and the results are shown in Table i9. Example 32 The octene was polymerized with a polar group-containing monomer in the same manner as in Example 30 except that the undecylenic acid substituted by undecylenic acid represented by the formula: 1.35 mmol was used and 1 · 5 mmol of three was used. Isobutyl.

Undecylenic acid The properties of the polar olefin-containing copolymer obtained are described in the table! 8. The impact resistance test and the tensile test of the polar olefin-containing copolymer were carried out by the above method, and the results are shown in the table! 9. This paper size is applicable to China National Standard (CNS) A4 specification (2) 0 X 297 mil.) 312991 I ϋ ml n ϋ ϋ nt nt nt * n * ϋ n ϋ ΛΜΜΚ nn nn J , · I fen ϋ ϋ ϋ 0 cPlease read the phonetic transcription on the back first? Please fill in this page again) Line·

1290149 A7 _B7 V. Inventive Note (290) Example 33 1-octene was polymerized with a polar group-containing monomer in the same manner as in Example 30 except that (2,7-octadien-1-yl group represented by the following formula) Succinic anhydride replaces undecen-1-ol. 0 (2,7-octadienyl-1-yl)succinic anhydride The properties of the obtained polar olefin-containing copolymer are described in Table 18. The impact resistance test and the tensile test of the polar group-containing olefin copolymer were carried out by the aforementioned methods, and the results are shown in Table 19. -------------------- Order --------- line (please read the notes on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Office staff Consumer Cooperatives Printed Paper Size Applicable to China National Standard (CNS) A4 Specification (210 x 297 mm) 290 312991 1290149 A7 _B7 V. Invention Description (291) Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Print *1M§f: 190. .16kg Room U) (α&gt; 宣ω to ω Η1 4 宣ω ^EL Ψ Ψ vTtn Ψ M - Phase A 〇σι X Ι-» ο o &lt;Ti XK σ\ ο \os I 1 I 1 ^ ω 鈇Λ a 缪% ooo PC tungsten pi ow X VO VO cn \ o • Ni V£&gt; VD cn O N&gt; VO VO cn o to cn VD • cn 〇« cn a bran ginseng \ ^ on η ^ Μ K&gt; 〇l ro (λ) N3 ro cn α „ 〇〇〇(3^ ΓΟ Η» 00 2 o &lt;J1 ooo Μ 〇S cold ro to ro 参 PO Ni • Ca) f P oo (Ji Ο Ο1 Ο o H* cn o • M ΪΟ 1 I io Ο o &家&gt; w鲥 (please read the notes on the back and fill out this page)

Mm I ϋ n·-Μ I l_i nn an ϋ 10 0 line - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 291 312991 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative prints 292 1290149 Λ7 Β7 V. Description of invention (292) Table 19 Example of evaluation item property value unit 30 Cross-section bonding test 100/100 Number of slices/slice number Example 31 IZ 260 J/m 1 Tensile strength 42 MPa Elongation at break 125% Example 32 IZ 505 J/m Tensile strength 35 MPa Elongation at break 42% Example 33 Adhesive strength (for A1) 2 Kgf/15 mm In the following Examples 34 to 39, the preparation of the sample and the measurement of the mechanical properties were carried out as follows. Preparation of sample The graft copolymer obtained in the example was molded at a cylinder temperature of 200 ° C and a mold temperature of 40 ° C using a 55-ton injection molding machine (IS55EPN, manufactured by Toshiba Machine Co., Ltd.). In Examples 34 to 39 below, the flexural modulus, Rockwell hardness and stray hardness, and calculation of (4)/(5) by 1H-NMR were carried out as follows. This paper scale applies to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 -------------------- Order --------- Line (please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 293 1290149 A7 B7 V. Invention Description (293) Pulling modulus using 1/8 pairs of thick samples, in the diameter The flexural modulus was determined according to ASTM C790 under conditions of 51 mm and a flexural curvature of 20 mm/min. Rockwell Hardness (HR) Rockwell hardness is determined according to ASTM D785 using a square plate of 2 mm (thickness) X 120 mm (length) X 1 30 mm (width). Pencil Hardness Using a 1/8 inch thick sample, the pencil hardness was measured in accordance with JIS K5401 at a temperature of 23 °C. Calculation by 1H-NMR (4)/(5) Device: JOEL GFX400 NMR observation tube: β Observation frequency: 400 MHz Pulse width: 45° Repeat time: 5.0 seconds number of integration times: 8000 Temperature: 115 ° C Measurement solvent: Determination of n-dioxene: 25 to 40 mg of the obtained polymer was dissolved in n-dichlorobenzene, and NMR was measured under the above conditions. Example 34 In a 1 〇〇〇 ml glass polymerization reactor thoroughly purged with nitrogen, 400 ml of toluene was placed, and then nitrogen gas was introduced at a rate of 20 Torr/hr, and the contents were kept at 90 ° C for 10 minutes. Next, add 2.0 mmol of triisobutylaluminum. This paper scale is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 312991 ------------------- --Book --------- Line _ (Please read the note on the back and fill in this page) 1290149 V. Invention description (2) 4 ) Then add further ^ 88 One of the following formulas - 1. Alcohol (drying with live cockroaches, then vacuum distillation). Undecene, :U alcohol, then, UOOmmoi f-based aluminoxane was further added and the gas was stopped. Then ethylene was introduced at a rate of 5 Torr/hr. Finally, add mmol8 mmol of di-vaporized dimethyl-terpene alkyl (27-dimethyl-4,5-(2-methylbenzo)-1-fluorenyl) (2,7-di-third) Zididyl) Zirconium and 2 〇〇mm&quot; methane-based aluminoxane were contacted with a toluene slurry at room temperature for 10 minutes to initiate polymerization. At 90. . After the polymerization was carried out for one hour under normal pressure, a small amount of isobutanol was added to terminate the polymerization. Then, add the inclusion! A solution of 1 ml of isobutanol in 1 ml of concentrated aqueous hydrochloric acid was then heated at 75 ° C under a nitrogen atmosphere. The resulting polymer solution was introduced into a large excess of methanol to precipitate the polymer, followed by vacuum drying at 8 Torr for 12 hours. As a result, 12 21 g of a polymer having an ethylene/side chain monomer molar ratio of 99.2/0.8 was obtained. The Intellectual Property Office of the Ministry of Economic Affairs is printed in a 1500 ml autoclave equipped with a thermometer tube, a pressure gauge, a stirrer and an epoxide feed tube, and filled with i2.0 g of ethylene/side chain monomer copolymer (ethylene/side). Key monomer molar ratio = 99.2/0.8), 31.0 mg of cesium hydroxide synthesized by the same method as described on page 32 of EP 0791600 [J(Dimethylamino) phosphite alkylamine] scale ([ (Me2N)3P=N]4P+〇H·), and 800 g of tetrahydronaphthalene. Next, the contents were heated to 125 ° C, and allowed to react at the same temperature for 12 hours' and intermittently fed into the 3 · 1 g ring Oxygen ethane, maintaining the pressure at 〇9 MPa (absolute pressure). Then, at the same temperature and under reduced pressure, the unreacted epoxy ethene remaining in the autoclave was distilled off. Then, the contents were cooled to room temperature. This paper scale applies to the Chinese National Standard (CNS) A4 Regulation ^ (210 X 297 public meals) --- 294 312991 1290149

, invention description (295 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 295, eight poured into 800 ml of methanol. Separated and precipitated white solid by filtration, add 20 ml of methanol to the solid in step I, then reflux for 3 minutes. The mouth material was subjected to hot filtration, and the obtained solid was dried under reduced pressure at 6 Torr to obtain W·1 g of a graft copolymer in which about 13 ethylene oxide units were graft-polymerized in terms of one hydroxy group. The properties of the obtained polar group-containing branched olefin copolymer are shown in Table 2. Further, the antifogging property of the film prepared from the polar group-containing branched olefin copolymer was evaluated by the above method, and the results are shown in Table 21. The ratio of (4) / (5) of the polymer was determined by 1H_NMR to be 1 〇〇 / 〇. Example 3 5 In a 1 〇〇〇 ml glass polymerization reactor thoroughly purged with nitrogen, 400 ml of toluene was placed, and then The contents were kept at a rate of 2 〇 1 / hr at 9 Torr for 10 minutes. Then, 1 〇 8 mm 〇 1 triisobutyl aluminum was added, and IK was further added with 0.90 mmol of undecenol (active). The alumina is dried and then vacuum distilled.) One step, add 丨1〇〇mm〇1 methyl oxymethane and stop introducing nitrogen, then pass ethylene at a rate of 1 〇〇 1 / hr. Finally add ' 0.008 mmol of dimethyl decane dichloride (2,7-monomethyl-4,5-(2-methyl-benzo)-1-indenyl)(2,7-di-t-butylindenyl)zirconium with 2.00 mm〇l The aluminoxane was contacted at room temperature for 1 minute toluene slurry to initiate polymerization. After polymerization was carried out at 90 ° C under normal pressure for 1 hour, the polymerization was terminated by adding a small amount of isobutanol. Add 1 ml of a solution of concentrated hydrochloric acid in 1 ml of isobutanol, followed by heating at 75 ° C in a nitrogen atmosphere. The obtained polymer solution was introduced into a large excess of methanol to precipitate the polymer; , then vacuum drying at 80 °C 12 paper scales apply to China National Standard (CNS) A4 specifications (210 X 297 public meals) 312991 ------------ --------- ------- Line ^9 (Please read the note on the back and then fill out this page) V1290149 Description of the invention (296 hours. As a result, 14.83 g of ethylene/side chain monomer molar ratio is 99.75 /〇·25 polymer Then, the polymerization was carried out in the same manner as in Example 34 except that 12.0 g of the above-prepared polymer and 151 g of ethylene oxide were used to obtain 11.8 g of a graft copolymer, wherein a superbase was used. About 51 ethylene oxide units are graft-polymerized. The properties of the obtained polar group-containing branched olefin copolymer are described in Table 2. Further, the above-mentioned method is used to evaluate the copolymerization of the polar group-containing branched olefin. The antifogging property of the film produced by the article' is shown in Table 21. Example 36 The procedure of Example 34 was repeated except that 5 〇 g propylene oxide was used in place of epoxidation. As a result, 1 G. 3 g of a graft copolymer was obtained in which about 10 propylene oxide units were graft-polymerized on a basis of one basis. The properties of the resulting polar group-containing branched alkene copolymer are described in Table 2A. Further, the antifogging property of the film produced by the polar group-containing branched olefin copolymer was evaluated by the above method, and the results are shown in Table 21. The polymer was measured by 1H-NMR to have a (4)/(5) ratio of 99/1. Example 37 Using the ethylene/side chain monomer polymer (ethylene/side chain monomer molar ratio = 99.75/0.25) prepared in Example 35, polymerization was carried out under intermittent feed of 3 丨g of ethylene oxide. As a result, 8 g of a graft copolymer was obtained in which about 13 ethylene oxide units were graft-polymerized in terms of one hydroxyl group. The properties of the resulting polar group-containing branched alkene copolymer are described in the table. Further, the above method is used to evaluate the application of the Chinese National Standard (CNS) A4 specification (the 21st love of the 21st) of the polar basis of the paper-based paper-&quot;~&quot;——__—— 296 312991 - -------^---------^^9 (Please read the notes on the back and fill out this page) 297 1290149 5. Description of the invention) Prevention of film made of smoke copolymer The nature of the mist is shown in Table 21. The procedure of Example 34 was repeated as an example except that in addition to the starting material, 7.75 g of isopropylidene phenyl ketone was further charged, the pressure was changed from 9 MPa to 〇2 MPa, and 5.8 g of methyl methacrylate was substituted for epoxy B. Alkane, and substituted methanol with tetrahydrofuran. As a result, 11.3 g of a graft copolymer in which about 20 methyl methacrylate units were graft-polymerized on a basis basis was obtained. The properties of the resulting polar group-containing branched alkene copolymer are described in Table 2A. Further, the mechanical properties of the polar group-containing branched olefin copolymer were evaluated by the aforementioned methods, and the results are shown in Table 21. Example 39_ 105 g of 1-octene, 895 ml of hexane (Mitsui) and 1.50 mmol of triisobutylaluminum were placed in a 2-liter stainless steel (SUS) autoclave thoroughly purged with nitrogen. The sus high pressure was heated to i50 ° C, i140 mniol methyl aluminum oxide was added followed by further addition of 1 3 50 mmol Η-en-1-ol (dried by active oxidation) and then vacuum distilled. While maintaining the temperature at 15 (rc, pressurize the high pressure crucible with ethylene to make the total pressure 3 〇kg/cm2_G. In addition, in a 20 ml glass flask thoroughly purged with nitrogen, nitrogen gas was injected therein to 0.00075 mmol. Dimethyl decyl chloride (2-methyl·4,5-benzo- fluorenyl) (2,7·di-t-butylindenyl)zirconium with 0.4300 mmol methyl oxy-oxygen The toluene slurry was contacted for 10 minutes at room temperature, and further 600 Nml of hydrogen was injected. During the period of 1 minute after the injection, the temperature of the autoclave was maintained at 150 ° C, and the pressure therein was maintained at the pressure just after the pressure injection of ethylene. Then 'add a small amount of isobutanol to terminate the polymerization. It will be prepared for this &amp; Zhang scale applicable Zhongguanjia Standard (CNS) A4 specification (2) Q χ 29 ) 312991 --------1----- --- (Please read the note on the back and then fill out this page). Line · 5,129,149,149, invention, the polymer solution of the sputum introduces a large excess of methanol, so that the polymer is swelled, then vacuum dried at 80 C 12 hour. As a result, 8 45 g of a polymer was obtained. - 8 g of this polymer was used, and the polymerization was carried out by intermittently feeding 3 Jg of ethylene oxide. As a result, 118 g of a graft copolymer was obtained in which about 13 kinds of epoxy groups were graft-polymerized by a single basis. The properties of the obtained polar group-containing branched chain hydrocarbon #polymer are summarized in Table 2〇. Further, the dispersibility of the polar group-containing branch-bonding furnace copolymer in water was evaluated by the above method, and the results are shown in Table 21.二--------^-------- (Please read the notes on the back and fill out this page). The Ministry of Economic Affairs, Intellectual Property Office, Staff and Consumers Cooperatives, Printed Paper Scale, Applicable to Chinese National Standards (CNS) A4 specification (210 x 297 public hair) 312991 298 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed 1290149 A7 __ B7 V. Invention description such as 9) H/C6H13/ {4) + (5)~^+ttcr

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3: ω KD Ca&gt; GO w 窆 (λ &gt; (Λ Ca&gt; cn CO X Ρ X Μ ω 〇 3: u&gt; 5: tc »n a bran - death A ο X Μ GO o u&gt; m M CO i o Ο VO Μ 09 00 o VO CO N Xj; -fStt A Si 1 1 1 1 1 II 0 tt H* U) 1 3: 1 o rn N) o nc 〇oo 0 a: ω to o 1 s: 1 〇in to^ 3: *0 C 1 Π: 1 η κ N) Ο 5c u&gt; ο Η» ω 1 PC 1 0 D: s 1 n: 1 J»~S. o M 0 ro 〇M LJ 1 Re MN) Η» h-* Η» Θ ® ❺ Θ Θ Θ OD \ M 〇\ 〇Cn * VD V£> • \ o CD VD U) • U1 \ o • N&gt; cn νο Ν&gt; \ Ο 00 Cn \ o ΓΟ CJi \D 馨 PO \ o 00 \ 参 + Μ 5 SMU) 〇〇oo cn OO oo -j 〇o O o σ\ cn ο ο ο -J oooo -J oooo 1 N&gt; cn to 〇&gt ;Ν&gt; CJI N&gt; σ\ N3 00 I \ oh·1 PO o • o 00 〇ο oo ! IS --------^---------^ ^9 (please read first Note on the back side of this page) This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 299 312991 Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing and printing 300 1290149 A7 B7 V. Description of invention ( 3(8) ) Table 2 1 Evaluation of project property value units Example 34 Anti-fog properties (visual observation) AA - Example 35 Anti-fog properties (visual observation) AA - Example 36 Anti-fog properties (visual observation) AA - Example 37 Anti-fog properties (visual observation) AA example 38 FM 2500 MPa Rockwell hardness 115 Pencil hardness 2H HDT 130 °C Example 39 Dispersed particle diameter 0.4 μπι Dispersion stability not separated Example 40 'Set 400 ml toluene in a 500 ml glass polymerization reactor thoroughly purged with nitrogen Then, nitrogen gas was introduced at a rate of 20 Torr/hr to maintain its contents at 75 ° C for 1 minute. Next, 〇·8000 mmo1 methyl oxy-oxygen was added, followed by further addition of 〇.1 〇〇〇 mm〇i undecene-I-alcohol (dried with smectite aluminum oxide and then vacuum distilled). Then, nitrogen gas was stopped and ethylene was introduced at a rate of 100 Torr/hr. Finally, O.OOD 8 mmol of di-vaporized isopropylidene (cyclopentadienyl) (2,7-di-tert-butylfluorenyl)zirconium was added to initiate polymerization. At 75 ° C, this paper scale applies Chinese National Standard (CNS) A4 specification (210 x 297 mm) 312991 1-1 ·ϋ ·ϋ ϋ ϋ nnn · in 1 ϋ MMmme tmtw in n TJ _ I ϋ n 1 ϋ ϋ n I (please read the notes on the back and fill out this page) 1290149 V. INSTRUCTIONS (301 After the polymerization is carried out for 15 minutes, a small amount of isobutanol is added to terminate the polymerization. The polymer obtained will be obtained. The solution was introduced into a large excess of methanol to precipitate a polymer, followed by vacuum drying at 80 ° C for 12 hours. As a result, a polymer of 9 〇g was obtained, and the polymerization activity was 4 5 kg / mm 〇 1 · · hr , and the melting point of the polymer is 129 〇〇c. Example 41 In a 500 ml glass-filled polymerization reactor thoroughly purged with nitrogen, 400 ml of toluene was placed, and then nitrogen gas was introduced at a rate of 20 Torr/hr. °C keep the grain inside for 1 minute. Then, add 〇〇〇1〇〇〇min〇l methyl aluminum oxide to burn 卩 and then add 〇1 5 mm〇l undecene-1-alcohol (in order to crush the stone) Order drying 'and then vacuum distillation. Then, stop introducing nitrogen and pass ethylene at a rate of 1 〇〇丨 / hr. At the end of the line, add 0.0160 mmol of diphenylmethyl dichloride (cyclopenta) (diyl) zirconium and 1.1000 mmol of methyl aluminoxane have been contacted at room temperature for a minute toluene slurry to initiate polymerization. The reaction is carried out at 75 ° ° C, under normal pressure for 30 minutes, and the polymerization reaction is terminated by adding a small amount of isobutanol. The obtained polymer solution is introduced into a large excess of methanol to cause the polymer to sink. Subsequently, it was vacuum dried at 80 ° C for 12 hours. As a result, 6.67 g of a polymer was obtained, and the polymerization activity was 〇·83 lcg/mmo bz · hr, and the polymer [] was 3·82 dl/g. Example 42 In a 500 Å glass polymerization reactor thoroughly purged with nitrogen, 400 ml of toluene was placed, and then nitrogen gas was introduced at a rate of 20 1 /hr, and the contents were kept at 75 ° C for 1 minute. 'Add】1000 mmo] Methyl aluminum oxide This product is suitable for medium-sized (CNS) A4 specifications (2) G Χ 297 gongs 7 301 312991 Five 1290149, invention description φ〇2 alkane, further added after pickling 2〇mm〇1 undecene (dried with vermiculite alumina and then vacuum distilled). Then, stop Nitrogen was introduced into the oxime at a rate of 〇〇 浠 最后. Finally, '0.0160 mmol of di-gasified (t-butylammonium) dimethyl (tetramethylcyclopentadienyl) decane titanium was added. The polymerization reaction was initiated by contacting 1·1000 mmol of methylaluminoxane with a toluene slurry for 1 minute at room temperature. After 75 hours of normal pressure T, the polymerization reaction was carried out for 1 hour, and a small amount of isobutanol was added to terminate the polymerization. The resulting polymer solution was introduced into a large excess of methanol to precipitate a polymer, followed by vacuum drying at rib C for 12 hours. As a result, 2 54 g of a polymer was obtained. The polymerization activity was 0.03 kg/mra〇l.Zr.hr, the polymer (1) was 3 55 _, the melting point was 129 C, and the polar group introduction ratio by 4-NMR was 0.25 mol%. Example 43 4 Torr of toluene was placed in a 500 ml glass polymerization reactor purged with nitrogen, and then nitrogen gas was introduced at 75 ° C for 10 minutes at a rate of 20 1 /hr. Next, 1 14 〇〇mm〇i methylaluminum was added, followed by further addition of 0.20 mmol of decaenol (dried with vermiculite alumina, followed by vacuum distillation). Then, nitrogen gas was stopped and ethylene was introduced at a rate of i〇〇i/hr. Finally 'added 0.0008 mmol: dimethyl decyl chloride (2_methyl---benzo+ germination from ^2-tert-butyl group) (a) then mm〇1 methyl oxy-along The polymerization reaction was started by contacting the toluene slurry at room temperature for 1 minute to initiate the polymerization reaction. After the polymerization reaction was carried out for 5 minutes under hydrazine and atmospheric pressure, the obtained polymer solution was introduced.

This paper size 赖 towel Guan Jia Xian (CNS) A4 specifications (2) Qx297 public hair F 312991 --------^------ (please read the back note before filling this page) • Line · 302 1290149

For example, in the case of an excess of methanol, the polymer was precipitated in an excess of methanol, followed by vacuum drying for 8 or 2 hours at 8{rc. As a result, 3 23 g of a polymer was obtained. The polymerization activity was .kg/mmnhr, and the polymer [7?] was 937. 4 ml of toluene was placed in a 500 ml glass polymerization reactor thoroughly purged with nitrogen, and then 2 〇 1 /hr. The contents were maintained at a rate of nitrogen for 7 minutes. Then, 'i 14 甲基 methyl aluminoxane' was added, followed by further addition of 0 30 mmol 1 undecen-1-ol (dried with crushed stone and then vacuum evaporated). Then, nitrogen gas was stopped and ethylene was introduced at a rate of i〇〇i/hr. After taking it, add 〇.〇〇16 mmol of dimethyldimethylene dichloride (2_methyl 4,5-benzo-ιι) (2,7-di-t-butyl group) Zirconium and ytterbium 43 〇〇mol methyl oxoxane have been contacted with a toluene solution at room temperature for a few minutes to initiate the polymerization. After polymerization was carried out for 5 minutes at 7 rc under normal pressure, a small amount of isobutanol was added to terminate the polymerization. The obtained polymer solution was introduced into a large excess of methanol to precipitate a polymer, followed by vacuum drying at 8 (rc for 12 hours). As a result, 2.46 g of a polymer was obtained. The polymerization activity was 18.45 kg/mm. l . Zr . hr, and the polymer [??] is 7 89 dl / g. Example 45 In a 500 ml glass polymerization reactor thoroughly purged with nitrogen, 400 ml of toluene was placed, then 20 Ι / At a rate of hr, nitrogen was passed through and the contents were kept at 75 Torr for 10 minutes. Then, 0.480 mm of triethylaluminum and 0.480 mmol of undecen-1-ol were added (dried with vermiculite alumina and then vacuum distilled). The toluene solution has been pretreated at room temperature for 10 minutes, and then the further &amp; Zhang scale applies to the Chinese national standard CNSW specification (10) x 297 public meal 312991 --------t--------- ^ rtt first read the note on the back and then fill out this page) Bureau Cooperative Print 1290149

Add 1.1400 mmol of methyl aluminoxane. Then, 100 1 / κ is passed through the nitrogen gas, and ethylene is introduced at a rate of (10) Ι / hr. Finally 'adding 0.0020 mm 〇l two gasification one ψ ^ Λ ^ ^ 一 一 methyl hydrazine alkyl (2_ methyl-4,5-benzo-1β fluorenyl) (2,7_ two_third苐 ) ) 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 At 75. . After the polymerization was carried out for 2 minutes under normal pressure, the polymerization reaction was terminated by adding an amount of isobutanol. The obtained polymer was dissolved in (iv) ^ in a large excess of the alcohol, and the polymer (tetra) was then dried in a vacuum for 12 hours. As a result, 3 63 poly Μ, σ was obtained. The polymerization activity was 杳g/mm (&gt;1.Zr.hr, and the U of the polymer) was 4.97 dl/g. Example 4 6 was placed in a 5 G () ml surface polymerization reactor sufficiently purged with nitrogen. Into 400 ml of toluene, then 2 〇 1 / hr only fascinating ~ < 迷 通 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气 氮气Add G 48mmG1 de-enol (step by Shi Xi Shi oxidized dry, then vacuum steamed). After 3 minutes of scramble, add 1 to test with 〇 1 methyl oxyhydrogen, then stop introducing nitrogen. Ethylene was fed at a rate of H) 01/hr. ^ Finally 'added 0.0017mmol of dimethyl dithiomethylene (2_methyl_4,5·benzocylinyl) (2,7-di-tert-butylfluorenyl) with 0.4300 mm〇 1 Methylamine was contacted at room temperature for 1 minute toluene to initiate polymerization. After 25 minutes of polymerization under hunger and atmospheric pressure, the polymerization was terminated by adding a small amount of isobutanol. The prepared polymer solution is introduced into methanol to cause the polymer to be submerged, and then dried at 8&lt;rc vacuum. The paper scale is determined by the Chinese Jade Standard (CNS) A4 specification (2) G X N., 312991

^------! (Please read the phonetic on the back? Please fill out this page again.) Line·304 51290149, invention description (305 = 12 hours. As a result, 3 〇〇g polymer was obtained. Polymerization The activity is kg/mmol · zr · hr. ΧΜΛ1 400 ml of toluene is placed in a 500 ml glass polymerization reactor thoroughly purged with nitrogen, and then nitrogen gas is introduced at a rate of 2 〇 1 /hr to keep the contents 1 () minutes. Next, add (10) ^ triisobutylaluminum, then add 0.48 mmol of deca-ene + aldehyde (distilled with vermiculite, then vacuum distilled). After stirring for 3 minutes, add ι ΐ4 〇〇Methyloxane' Then, the nitrogen gas was stopped and the ethylene was introduced into the mixture. Finally, 0.0017 mmol of the dimethylated dimethyl(tetra)alkyl group (2_methyl-4,5-) was added. Benzopyrene (27-di-t-butyldiyl) lead and hydrazine *methyl aluminoxane have been contacted with a toluene slurry for 1 minute at room temperature to initiate polymerization. (;, under normal pressure, after 25 minutes of polymerization, a small amount of isobutanol is added to terminate the polymerization. The obtained polymer solution is introduced into a large excess In methanol, the polymer was precipitated, followed by 8 〇β (: vacuum drying for 12 hours. As a result, 45 〇g of a polymer was obtained. The polymerization activity was 63·5 kg/mm 〇 · Zr · hr 〇 Example 4 8 500 ml of the glass polymerization reactor was purged with nitrogen, 400 ml of toluene was placed, and then nitrogen gas was introduced at 75 Torr to maintain its contents for 10 minutes. Then, 〇48 was added. 〇mm〇1 triisobutylaluminum, followed by further addition of 48.48mmol deca-amine (dried with vermiculite alumina) and then dried over the air. After stirring for 3 minutes, 'add〗' 400 mm〇1 paper The scale applies to China's national standard (CNS:) A4 specification (10) X 297 public meal 312991 --------------- (please read the note on the back and then fill out this page). Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 305 1290149 A7 V. Invention Description (3〇6) Methyl decane, then stop introducing nitrogen and pass ethylene at a rate of 1〇〇1/hr. Finally, Add 0.0017 mm 〇1: dimethyl decyl chloride (2_methyl-4,5-benzo-1-phenyl) (2 7_di-t-butyl) Base) and 〇4 Curry 1 methyl oxy-oxygen has been contacted at room temperature for 10 minutes in toluene slurry to initiate polymerization. At 75 ° C, atmospheric pressure, Yi a, Gan Tian transfer polymerization 2.5 After a minute, the polymerization was terminated by adding ruthenium isobutanol. 1 The obtained polymer solution was introduced into a large excess of methanol to cause the polymer to coagulate, followed by 8 (TC vacuum drying for 12 hours). . As a result, 〇 8〇 g flat, and an ash compound were obtained. The polymerization activity was 11 · 3 kg / mm 〇 · Zr · hr 〇 Examples 49, 50, 51, 52, 53, 54, 〇 ~ 56, 57 and 58 under the same conditions as in Example 40 # I The olefin copolymer, but the alpha-olefin and the polar group-containing monomer type and amount, the type and amount of the trialkyl aluminum compound, and the polymerization temperature and the polymerization time are changed as shown in Table 22. The results are also shown in Table 22. (Please read the notes on the back and fill out this page.) 4 ·11111 Ministry of Finance, Intellectual Property Office, Staff and Consumer Cooperatives Printed This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public ' 306 312991 1290149 A7 R7 V. Description of invention (3〇7) * 1: wt^cru f 涔一: (2丨f 鲥丨4, 5—doing a half 丨 1IS&) (2,7 丨 by WT; &full; 10 miscellaneous* 2:^食: jcg/mmol-Zr · hr MAO: f 济,TEA: wDTIBA: h 驷Tig Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed U1 00 Uj (Jl σ\ U1 cn U1 cn Ui cn N3 Ui Μ s KD to Cn Κ) tn to cn ΓΟ cn cn N&gt; cn K&gt; (Jl Ν&gt; ςπ N3 Ul N) Ol 芳环灿金属★1 (μτηοΐ) a ο Curtain C4 Raspberry Recruiting Raspberry Review 100 Ν5 in to CJt &lt;Ji N3 to K) 馈 Feeding rate (mmol) Eleven-1-ol tetracyclododecene methanol tetracyclododecene methanol thick spine methylamine thick spine methanol eleventh - 1-ol allylamine propylamine 1 allyl alcohol | dilute propanol type comonomer 4^ amount (mmol} 1-» cn Μ CJI -J cn -j Μ in Μ (Jl Μ αι Η Cn Η* (jy Μ Oj Μ ΜΑ0 (m Mol) TEA TEA TEA | ! . __1 TEA TEA TEA ΤΙΒΑ TEA ΤΙΒΑ TEA L——_____________ Type ί Aluminium oo 00 00 CO 00 OO 00 σο 00 00 Dosage (mmol) s (J&gt; CJI m cn CD οι Ln ( Jn (Jl temperature; (°C) 5: 00 oo 00 00 cn 5: fO cn 105 time 1 (min) i_-_ Μ N3 Ο ω UD j-1 (Jl ω ΙΌ NJ U1 Cn N) cn η ΓΟ CTy Cn cn to o KO Cji (Jl 〇cn Revenue (g) 1_ ο α\ 00 o 00 o Cf\ N&gt; o (Jl Ln 0 01 (Jl 〇CJI Μ VX5 cn M σν 00 cn cn o h-» [ η] (dl/g) ο KD La) o cn ITM1 LO OH* 〇o (Jl U) &lt;JT c\ ο Ν) ΡΟ o OO 0J u&gt; Co-monomer (mol%) Ο 00 00 o Cn H* Ui o VD 00 H-* Ul 〇to N3 Ul Ο oo oo cn ooo Ι-» ts^ Polymerization activity.*2 ^22 Α___^--------^------ -- (Please read the notes on the back and fill out this page) • Line _ This paper scale applies to China National Standard (CNS) A4 specification (2) 〇χ 297 mm) 307 312991

1290149 V. INSTRUCTIONS (3〇8, Comparative Example 3, 500 ml of toluene was placed in a 500 ml glass-filled reactor thoroughly purged with nitrogen, and then nitrogen gas was introduced at a rate of 2 〇i/hr. 75. Keep the inner grain for 1 minute. Then, add 0480 mm 〇i sesquiethyl aluminum hexanoate, then add 〇48 mmol of undec-1-amine (dry with vermiculite alumina, then vacuum distillation) After stirring for 3 minutes, add 14 〇〇 mmol of ethyl hexachloride, then stop introducing nitrogen to ethylene at a rate of 1 (10) i / k. Finally, add 20.0017 mmol of VO (〇C2H5)Cl The polymerization was started with 0.4300 mmol times of semi-aerated ethyl aluminum in contact with a toluene slurry at room temperature for one minute. At 75 t:, under normal pressure, polymerization was carried out for 25 minutes, and a small amount of isobutanol was added to terminate the polymerization. The resulting polymer solution was introduced into a large excess of methanol in an attempt to precipitate the polymer, however, no polymer was produced. Example 59 In a 2 liter stainless steel (SUS) high pressure mark thoroughly purged with nitrogen, Place 120 g 1-butene, 88 〇ml hexane (three And i 5〇mm〇i triisobutylaluminum. The SUS autoclave was heated to 15 ° C, and l l4 〇 methyl aluminoxane was added, followed by further addition of 1 350 mmol of undecyl alcohol represented by the following formula (Dry with activated aluminum telluride, then vacuum distillation). Keep the temperature at i5 〇. (:, pressurize the high pressure with ethylene to make the total pressure become 2 9 Mpa_G (3〇kg/cm2_G). _1-Alcohol paper size applicable to China National Standard (CNS) A4 specification (2) 297 297 public meals) 312991 n I nn ϋ n I βϋ · ·ϋ ϋ I «ϋ n ϋ H I I n n ama§ Mu ϋ ϋ Met I _ (Please read the note on the back and then fill out this page) Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 308 V1290149, Invention Description (309) In addition, 2 〇ml glass flask thoroughly purged with nitrogen Injecting nitrogen into it, 〇〇0075 mm〇1 di-gasified dimethylalkylene (2_methyl-4,5-benzo]-mole) (2,7_di_tert-butyl burial) Base) wrong with 0.4300 mmol methyl oxy-oxygen has been contacted at room temperature for a minute toluene slurry, and further injected with 000 Nml of hydrogen. During the 1 minute period after injection, high The temperature of the autoclave was maintained at 15 (TC), and the pressure therein was maintained at a pressure just after the injection of ethylene under pressure. Then, a small amount of isobutanol was added to terminate the polymerization. The obtained polymer solution was introduced into the large The polymer was precipitated in excess methanol, followed by vacuum drying at 8 ° C for 12 hours. As a result, an i〇 4〇g polymer was obtained. The polymerization activity was 83 kg/mmol · Zr . hr. The properties of the polar-containing dilute-smoke copolymers are described in Table 23. Example 60 Ethylene, butene and a polar group-containing monomer were polymerized in the same manner as in Example 59 except that the undecylenic acid substituted by undecyl i...

The properties of the obtained polar olefin-containing copolymer obtained from 0H 0 undecylenic acid are described in Table 2. Example 61 Ethylene's butadiene was polymerized with a polar body in the same manner as in Example 59 except that: 1,2-epoxydecene was substituted for the alken-1-ol and 550 Nml of helium was used. , 0 paper size applies to China National Standard (CNS) A4 specifications (21〇X 297 public) 312991 --------^---------$ ίιρ (Please read the back Note: Please fill out this page) Epoxy _9-pinene 309

Description of the invention (310 0

The properties of the obtained polar olefin-containing copolymer are described in the same manner as in Example 23 of Example 23, and ethylene, butadiene and a polar group are polymerized, but the following formula (2,7-octadiene 4·) The soil is substituted with undecen-1-ol and 550 Nml of hydrogen is used. The properties of the polar olefin-containing copolymer obtained from the soil succinic anhydride (2,7-octane bismuth) are described in the table. Ethylene, propylene and a polar group-containing monomer were polymerized in the same manner as in Example 62 except that at the initial partial pressure of 3 kg/cm2, the propylene was replaced by propylene and the hydrogen was introduced without adding hydrogen at a polymerization temperature of 80 ° C. The polymerization reaction is carried out. 'The properties of the obtained polar olefin-containing copolymer are described in the table. --------^---------^. ΓQing first read the phonetic transcription on the back? Page} Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperatives Printed clothing paper scale applicable to China National Standard (CNS) A4 specifications (210 χ 297 mm 310 312991 1290149 A7 B7 V. Invention Description (Ml) Ministry of Economic Affairs Intellectual Property Bureau staff consumption Cooperative printing 窆 宣 宣 \ &lt;jj σ&gt; ΙΌ σ\ S cn VD Ο Γ 4荼 Special review curtain but A a 1» Η—^ μ—a 1~~&gt;· 1 1 , I 1 1 二杂赛Μ Special raspberry &quot;Η 莓 A ο η Ο PC as ο σ% SC ο ο &lt;Τ\ 3: μ ο m XU) X Η* 00 Book 1 ο ο ω ζ 挪 1 ο A ο XX GO Ο 00 00 00 00 00 00 ω 00 Η* \ \ \ \ \ Μ VO U1 U1 1 μ μ ω ϋ v v ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U * ω Η ο ο Μ ΡΟ ΡΟ ο ο Ο ο Ο ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; 0 0 0 0 0 0 0 办 办 办 办 办 办 办 办 办 办 办 办 办 办 办 办 办 办 办 办 办 办 办 S S S S S S S S S S S S S S To a *-* Ο ΓΟ Ν) to ΓΟ to 1 • Cn ΓΟ • ω ΓΟ • 00 !3 ο Ο ο ο Ν) Ο Οϋ • ο 〇» ο ο + ------------ --------Set---------Line (please read the note on the back and fill in this page first) This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) ) 311 312991

Claims (1)

...A,,·6, application for patent scope supplement d &quot;9^ 丄t CH2-CH— -CH2&quot;-CH- (1) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printing patent application No. 90112258 (96 years) May 14th) - a hetero group containing a polar group, including a composition unit of the formula (1), a composition unit represented by the formula (2), and a composition unit represented by the following formula (3): the copolymer has not more than The molecular weight distribution (MW·) of 3, and the intensity ratio of not more than 1〇2Τα α +Τα (Τα /3 /(Τα α +Τα /3 )) according to C-NMR spectroscopy ·, _CH2—CH R3 (R4)r— (2) wherein R1 and R2 may be the same or different and each is a hydrogen atom or a linear or branched aliphatic hydrocarbon group having from 丨 to i8 carbon atoms; and R3 is from 丨 to 2〇 carbon atoms. a hydrocarbon group, R4 is a hetero atom or a hetero atom-containing group; ^ is hydrazine or 1; X is selected from the group consisting of an alcoholic hydroxyl group, a phenolic hydroxyl group, a carboxylic acid group, a carboxylate group, an acid anhydride group, an amine group, a decylamine a polar group of a group, an epoxy group and a fluorenyl group; P is an integer of 1 to 3; and when p is 2 or 3, each X may be the same or different, and here, if If is 〇, then X Knot R3 to different atoms or the same, and if r is 1, X may be bonded to the same or different atom of R4. 2. The polar group-containing olefin copolymer according to claim 1, wherein R3 in the constituent unit represented by the formula (3) is a hydrocarbon group having π or more carbon atoms. 3. The polar olefin-containing copolymer according to claim 1, wherein X in the constituent unit represented by the formula (3) is selected from the group consisting of a phenolic hydroxyl group, a carboxylate group, an acid group, an amine group, and a decylamine. a polar group of a group, an epoxy group, and a fluorenyl group. 4. The polar olefin-containing copolymer according to claim 1, wherein R1 in the constituent unit and R2 in the constituent unit represented by the formula (2) are each (CNS) A4 size (10) X 297 PCT) ' (Please read the note on the back and fill out this page) (X)p ...(3) -§1 n -nn If n mm— ^^aJ· ϋ mmmMm a — nn ϋ n I - 312 (Revised This patent 312991 1290149 A8B8C8D8 Patent No. 90112258 (May 96; ug VIII) The patent application range is from a hydrocarbon group having 2 or more carbon atoms, and the copolymer is crystallized by a 射线-ray diffraction method. The degree of not less than 1 〇〇 / 0. The polar group-containing olefin copolymer of the first aspect of the patent application, wherein R1 in the constituent unit represented by the formula (1) and R2 in the constituent unit represented by the formula (2) It is a hydrocarbon group having 2 or more carbon atoms, and the copolymer has a crystallinity of less than 10% as measured by a 射线-ray diffraction method. 6·~ a branched chain type polar group-containing olefin copolymer, including the following formula ( 1) a composition unit shown below and a composition unit represented by the following formula (4), and a composition shown in the following formula (5): the copolymer has no The molecular weight distribution (Mw/Mn) greater than 3, and the intensity of τ cold versus τ ^ α cold (Τα /3 / (Τα α + Τα /5 )) which is not more than 丨·〇 as determined by 13C-NMR spectroscopy Ratio: (Please read the notes on the back and fill out this page) 41^ JQ^r •CHo—CH- 'CH2—CH- _ch2—ch—Wq-fR6)r *4-0—Z )n (R6) M—(W)n Printed by the Intellectual Property Manager of the Ministry of Economic Affairs...(1) (4) (5) where R1 is a hydrogen atom or a linear or branched aliphatic hydrocarbon group having 1 to 18 carbon atoms; R5 is a hydrocarbon group having up to 2 carbon atoms; R6 being a hetero atom or a hetero atom-containing group; "为〇 or 1; z is a polymer fragment obtained by any method of anionic polymerization, ring-opening polymerization or polycondensation; W is a hydroxyl group or an epoxy group; ^ is an integer of 丨 to 3, q is 〇, 1 or 2, and p+qS3; when p is 2 or 3, each-0-Z may be the same or different. In this case, if r is 〇, then 〇_z may be combined with the same or different R5. An atom, and if r is 1, then -0_z can be bound to the phase r-^i of R6 or a different atom; when q is 2, each W can be the same or different, and this scale is applicable to the towel standard (CNS). A4 size (210 297 297 mil) ~ '&quot;&quot; --------- 313 (amendment) 312991 1290149 Patent Application No. 90112258 (May 14, 2014;) In the case of patent application, if r is 0, then W can be ##, ,,,. The same or different atoms of R5, and if r is 1, W can be bonded to the same or different atoms of p6 and K; in the case of p -1 and q ^ 1, if Γ is 〇, then W -0-Z may be bonded to the same or different atoms of R5, and if the right Γ is 1, W and -0-Ζ may be bonded to the same or different atoms of R6; disc m is 〇 or 1; η is 1 to 3 An integer; and when η is 2 or 3, you may be the same or different. In this case, if m is 0, the shell &quot; may be combined with the same or different atoms of R6, and if "i, then W Binding to the same or different atoms of R7. 7····································· (4) A polymer fragment obtained by the use of the polymer according to the sixth aspect of the invention, wherein the branched chain type polar group-containing olefin in the formula (4) is a ring-opening polymerization or polycondensation. Polymer Fragment Printed by the Intellectual Property Office of the Intellectual Property Office of the Ministry of Economic Affairs. 9. A polar group-containing olefin copolymer, including the group shown by the following formula (1) a composition unit represented by the following formula (6), and a composition unit represented by the following formula (3), the copolymer having a molecular weight distribution (Mw/Mn) of not more than 3, and having a 13C-NMR spectrum as determined by root electricity Not greater than 丨· 〇 τ α 对 τ + Τα /5 (Τα 10,000 / (Τα 〇: +Τα million)) intensity ratio ···CH2 a CH— •CH2—CH· ------- -Book---------Line_! (Please read the notes on the back and fill out this page) (1) (R4) "One (X)p ... (3) This paper scale applies to the Chinese National Standard (CNS) A4 specification (21〇 x 297 mm) 314 (Revised) 312991 1290149 Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative, printed patent application scope, / R is a hydrogen atom or a linear or branched aliphatic hydrocarbon group having U 18 carbon atoms; R3 is a hydrocarbon group having 1 to 20 carbon atoms; a group of atoms or a hetero atom; r7 is a direct bond or has a plurality of anaerobic groups: a hydrogen atom, a direct bond or a ruthenium having no or more carbon atoms; Y is a polar group containing ruthenium and/or N; m and η are each an integer of 0 to 2, and m + n is not 〇; s is 〇 or 0 or 1; X is selected from -0R, one (10)R , a CR 〇, -NR 2 , an epoxy group, a C (〇 HR 2 , -0C (0) R, a N, -〇 H, -c〇〇H or an NH 2 (wherein, hydrogen or /, has 1 a polar group of up to 2 hydrocarbon atoms; p is an integer from 3 to 3; when ? is 2 or 3, each X may be the same or different, in which case 'if Γ is, then χ may be combined If the same or different atoms', and if r is 1, then χ can be bonded to the same or different atoms of R4. 1〇· A method for preparing a polar olefin-containing copolymer, including a catalyst having the following composition: (A) selected from the cycle a compound of a Group 4 transition metal, and (B) at least one compound selected from the group consisting of: (B 1 ) an organoaluminum oxy-compound selected from the group consisting of oxy-alkane or an organoaluminum oxy-compound insoluble in benzene, (B - 2) reacting with the compound (A) to form an ion pair selected from the group consisting of Lewis I, an ionic compound, a borane compound, and a carborane compound, and (B-3) an organoaluminum compound RanAlX3-n represented by the following formula Ra is a hydrocarbon group having 1 to 12 carbon atoms, X is a halogen, a sub or a hydrogen atom, and n is 1 to 3; this New Zealand standard is applicable to the Chinese National Standard (10) x 297 public 315 (Revised) 312991 (please Read the notes on the back and fill out this page) --------Book i I··· III ^ Line 1290149 A8 B8 C8 D8 Patent Application No. 90112258 (May 14, 2014) VI. Application The patent range is at least one α-olefin selected from the group consisting of 2 to 20 carbon atoms, and the polar group-containing monomer selected from the following formula (7) and the formula (8) Copolymerization of at least one polar group-containing monomer containing a polar group monomer · ch2=ch (R4)-(X)p · (7) where R3 has 1 a hydrocarbon group of up to 20 carbon atoms; V is a hetero atom or a group containing a hetero atom; r is 0 or ι; χ is selected from the group consisting of -〇R, _c〇〇R, -CRO, -NR2, epoxy, -C(0)NR2, -〇c(〇)R, -Ce N, -OH, C00H or NH2 (wherein 'R is hydrazine or a thiol group having from 1 to 2 carbon atoms); p is An integer from 1 to 3; when? When 2 or 3, each X may be the same or different. In this case, if r is 〇, X may be bonded to the same or different atom of R3, and if r is 1, X may be bonded to the same or of r4. Different atoms; 'Dm •00η (Please read the notes on the back and fill out this page.) Printed by the Consumer Intellectual Property Office of the Ministry of Economic Affairs. • (8) where R is a direct bond or an aliphatic hydrocarbon group having one or more carbon atoms; R8 is a hydrogen atom, a direct bond or an aliphatic hydrocarbon group having one or more carbon atoms; Y is a polar group having 0 and/or N; m and η are each an integer of 〇 to 2, and m + n is not 〇 ; s is 0 or 1. 11 · The method for preparing a polar-containing dilute hydrocarbon copolymer according to item 1 of the scope of the patent application, wherein the transition metal compound (A) is subjected to the following formulas (11), (12), and the paper scale is applicable to the Chinese national standard ( CNS) A4 size (210 X 297 mm) 316 (Revised) 312991 1290149 A8 Patent Application No. 90112258, C8 (May 14, 1996, application of patents (13), (14), (15) and (16), and the monomer containing the polar group For the polar group-containing monomer in which the X in the formula (7) is -〇H: The Intellectual Property Office of the Ministry of Economic Affairs, the Consumers’ Cooperatives, prints the transitional metal atom of the periodic cousin of Group 4, and R25, R26, R27 and R28 may be the same or different and each is a hydrogen atom, a nitrogen-containing group, a phosphorus-containing group, and a hydrocarbon group of 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 2 carbon atoms, an oxygen-containing group, a sulfur-containing group, a mercapto group or a halogen atom; a group represented by R25, R26, R and R 'Partially adjacent groups may be bonded together with carbon atoms bonded to the groups to form a ring; χΐ and X2 may be the same or different and each is a hydrocarbon group having 1 to 20 carbon atoms, having 1 to 2 〇 a halogenated hydrocarbon group of a carbon atom, an oxygen-containing group, a sulfur-containing group, a stone-containing group, a hydrogen atom or a halogen atom; and Υ1 is a divalent hydrocarbon group having 1 to 20 carbon atoms, and has 2 to 20 carbon atoms. a valence halogenated hydrocarbon group, a divalent group containing a sulphate, a divalent group containing ruthenium, a divalent group containing tin, -C0-, -, -S0-, -S〇2-, -Ge-, -Sn-, -NR21-, -P(R21)-, -p(〇)(R2i)-, -BR21- or - A1R21- (each R21 may be the same or different and is a hydrocarbon group having 1 to 20 carbon atoms, having 1 to 20 carbon atoms a halogenated hydrocarbon group, a hydrogen atom, a halogen atom or a nitrogen compound residue of one or two hydrocarbon groups having 1 to 20 carbon atoms bonded to a nitrogen atom); This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 x 297 mils) (Please read the notes on the back and fill out this page) 丨—! —丨···· i 317 (Revised) 312991 1290149 A8B8C8D8 Patent application No. 90112258 -y1, x12 • (12) where Μ1 is a transition metal atom selected from the group 4 of the periodic group; Cp is a cyclopentadienyl group or a derivative thereof, and Z1 is an oxygen-containing atom, a sulfur atom, a ligand or a ligand of a 14th element of the periodic table; γ is a ligand containing an atom selected from a nitrogen atom, a phosphorus atom, an oxygen atom, and a sulfur atom, and each r may be the same or different and is hydrogen. An atom, a halogen atom, a hydrocarbon group having 20 or less carbon atoms and having 1 or more double bonds, 3 having 20 or fewer germanium atoms, or 20 or more germanium atoms a decyl group (ger 1) or a borane group containing another or less boron atoms (b〇r〇nyl gr〇up); ...(13) Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperatives Printed Medium 1 is a transition metal atom selected from Group 4 of the Periodic Table; R11 to RH R to R and R41 may be the same or different and each has 1 to 4 carbon bases, a halogenated hydrocarbon group having 1 to 40 carbon atoms, an oxygen-containing sulfur group, a mercapto group, a halogen atom or a hydrogen atom; R11, R12, R13, rm R17, R18, R19 Among the groups represented by R2G and R41, partially adjacent to each other, the group may be bonded to a carbon atom bonded to the groups to form a ring (only Rn, Ri2, Rl3, R&quot;, Rl7, Ru, R&quot; , r2〇 and all groups pong -· · —丨丨丨丨丨丨丨丨丨丨丨丨线», (Please read the notes on the back and fill out this page) This paper size applies to the Chinese National Standard (CNS) A4 specification (210 χ 297 mm) 318 (Revised) 312991 1290149 ABaD $90122058 Patent Application (May 14, 1996) Printed by the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperatives. VI. The scope of application for patents is chlorine atoms and ..., the third butyl group, Except that the remaining rii core nmn R41 is a hydrogen atom); X1 and r may be the same or different and each is a hydrocarbon group having 2 carbon atoms, a hydrocarbyl group having 1 i 20 carbon atoms, an oxygen-containing group, and a sulfur-containing group. a group, a sulfhydryl group, a hydrogen atom or a _ atom; and r is a divalent hydrocarbon group having 2 to 2 carbon atoms, a divalent halogenated hydrocarbon group having 1 to 2 carbon atoms, a divalent group containing ruthenium, Divalent group containing ruthenium, divalent group containing tin, -0-, -C0-, -S-, -SO-, -S02-, -Ge-, -Sn_-nr21 I, _PU21) - ' _PC〇 ) U21) _ '-BR21 — or an A1R21 — (each R21 may be the same or different and is a ketone group having 1 to 20 carbon atoms, having 1 to 20 carbon atoms a halogenated hydrocarbon group, a hydrogen atom, a halogen atom or a nitrogen compound having one or two hydrocarbon groups having 1 to 20 carbon atoms bonded to a nitrogen atom; Wherein Μ1 is a transition metal atom selected from Group 4 of the periodic table; R11, R12, R41 and R42 may be the same or different and each is a hydrocarbon group having 1 to 40 carbon atoms, and has a toothing of 1 to 40 carbon atoms. a hydrocarbon group, an oxygen-containing group, a sulfur-containing group, a thiol group, a halogen atom or a hydrogen atom, and a group represented by R&quot;, R12, R41 and R42, and a group adjacent to each other may be bonded to the group The combined carbon atoms combine to form a ring; X1 and X2 may be the same or different and each is a hydrocarbon group having 1 to 20 carbon atoms, and a halogen having 1 to 20 carbon atoms is applicable to the Chinese National Standard (CNS) A4 specification. (210 X 297 mm) 319 (Revised) 312991 — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — Shen Qing patented hydrocarbon group, oxygen-containing, sulfur-containing group, .vA . . , s 〇 3 fluorenyl group, wind atom or halogen atom; and bismuth with 8 to 20 carbon atoms, which is a gas atom When Y1 is not a divalent hydrocarbon group of an ethyl group to 20* carbon atoms, a divalent group is cut, and the Monovalent group, tin-containing divalent group, -〇1Bei丞0-, one (3)-S-, -S0-, -S〇2 I, -Ge-, -Sn-, -NR21-, one ρπ? 2ι, n . P(R )-, -P(〇)(r21)_,, 2 -AIR - (each R21 may be the same or different and is a nicotine group having one carbon atom, having 1 to 20 carbon atoms a nitrogen compound residue formed by coupling a hydrocarbon group, a hydrogen atom, a halogen atom or - or two hydrocarbon groups having from 1 to 2 carbon atoms to a nitrogen atom; (Please read the notes on the back and fill out this page) ...(15) Order---------The Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, Printed Lieutenant is a transition metal atom selected from Group 4 of the Periodic Table; ru may be the same or different and each a ketone group having 1 to 40 carbon atoms, a halogenated hydrocarbon group having 1 to 40 carbon atoms, an oxygen-containing group, a sulfur-containing group, a thiol group, a halogen atom or a hydrogen atom; and a group represented by R41 and R42, The mutually adjacent groups may be bonded together with carbon atoms bonded to the groups to form a ring; X1 and X2 may be the same or different and each is a hydrocarbon group having 1 to 2 carbon atoms, having 1 to 20 a halogenated hydrocarbon group of a carbon atom, an oxygen-containing group, a sulfur-containing group, a fragment-containing group, a hydrogen atom or an atom; and γ ΐ is a divalent hydrocarbon group having 1 to 20 carbon atoms and having a carbon atom of 1 to 20 carbon atoms The paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 320 (Revised) 312991 1290149 Patent application for divalent i-hydrocarbon group, divalent group containing ruthenium, divalent group containing ruthenium, and tin-containing No. 90112258 (May 14, 2014) 仏基基,〇C0—s—,—s〇 1. s〇r, _Ge-, -Sn-, P(R21), p(0)(r2i)-, 21- or _A1R21 — (each r2i-NR21 eight κ corpse, -Bp- or _ Alir — (Valley gamma is the same or different and is a hydrocarbon group having from 1 to 2 carbon atoms, a toothed hydrocarbon group having from i to 20 carbon atoms, a hydrogen atom, a halogen atom or one or two having 1 to 20 carbons a nitrogen compound residue formed by the combination of a hydrocarbon group of a atom and a nitrogen atom; (Please read the precautions on the back and fill out this page.) · The Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumer Cooperative, Printed Lieutenant is a transition metal atom selected from Group 4 of the periodic table; Rll, R15 to R2°, and R42 The same or different and each are a hydrocarbon group having 1 to 4 carbon atoms, a halogenated hydrocarbon group having 1 to 40 carbon atoms, an oxygen-containing group, a sulfur-containing group, a mercapto group, a halogen atom or a hydrogen atom; R11, R12 Among the groups represented by Rn, R16, R17, R18, R19, ^° and R42, a group adjacent to each other may be bonded to a carbon atom bonded to the groups to form a ring; X1 and X2 may be the same Or different and each of which is a pyrophoric group having 1 to 20 carbon atoms, a sulfonic acid group having 1 to 20 carbon atoms, an oxygen-containing group, a sulfur-containing group, a thiol group, a hydrogen atom or a halogen atom; and γΐ Is a divalent hydrocarbon group having 1 to 20 carbon atoms (when all R&quot;, R12, Rl5, Rl6, r17, R18, R19, and R42 are hydrogen atoms, γΐ is not an ethyl group), and has 1 to 2 a divalent halogenated hydrocarbon group of 0 carbon atoms, containing; a divalent group of 5, a divalent group containing a fluorene, a divalent group containing tin, - (3)---s_-s - This paper scale applicable Chinese National Standard (CNS) A4 size (210 χ 297 mm) 321 (Revised), 3129911290149 -NR21-, -p(R21)-, -p(〇)(R21)-, or AIR- (each R may be the same or different and is a hydrocarbon group having 1 to 2 carbon atoms, having 1 to 20 carbons A halogenated hydrocarbon group of an atom, a hydrogen atom, a halogen atom or a nitrogen compound residue in which one or two hydrocarbon groups having from 2 to 2 carbon atoms are bonded to a nitrogen atom). 1 2 · The method for preparing a polar olefin-containing copolymer according to the ninth aspect of the patent application, wherein the transition metal compound (A) is represented by the following formulas (11), (12), (13), (14), As shown in any one of (15) and (16), and the polar group-containing monomer is represented by the formula (7), X is -NR, R" (R, and R, which may be the same or different and are a hydrogen atom. Or alkyl group containing polar group monomers: Yr ...(11) (Please read the notes on the back and fill out this page.) M1 is the transition metal atom of Group 4 of the periodic table in the printed version of the Intellectual Property Office of the Ministry of Economic Affairs, R25, R26, R27 and R28. The same or different and each are a hydrogen atom, a nitrogen-containing group, a phosphorus-containing group, a hydrocarbon group having 1 to 20 carbon atoms, a halogenated fe group having ～2 碳 carbon atoms, an oxy group, a sulfur-containing group, and a ruthenium-containing group a group or a halogen atom; a group represented by R25, R26, R27 and R28, a group which is adjacent to each other may be bonded to a carbon atom bonded to the group to form a ring; χ1 and χ2 may be the same or different and Each is a hydrocarbon group having 1 to 20 carbon atoms, an i-alkyl group having from ～2 石 a stone anti-atom, an oxy group, a sulfur-containing group, a thiol group, a hydrogen atom or a halogen atom, and Y1 having 1 to Divalent hydrocarbon group of 2 carbon atoms, divalent halogenated hydrocarbon group of 1 to 20 carbon atoms, divalent group containing ruthenium, this paper scale is applicable to China National Standard (CNS) A4 specification (21G X 297 mil )_ --------- 322 — (Revised) 312991 -------- Order --------- Line » [290149 A8 B8 C8 D8 Patent Application No. 90112258 (May 14, 1996) VI. The scope of application for patents contains the divalent base of bismuth, the divalent base of tin, _〇—, _C〇—, _S—, —s〇—, S〇2-, -Ge-, -Sn-, -NR21-, one P(R21)-, -P(〇)(R21)-, -BR2- or _A1R- (each ru may be the same or different and A nitrogen compound having a group of carbon atoms to a carbon atom, a halogenated hydrocarbon group having 1 to 2 carbon atoms, a hydrogen atom, a functional atom or one or two hydrocarbon groups having 1 to 2 carbon atoms bonded to a nitrogen atom base); (12) wherein M1 is a transition metal atom selected from Group 4 of the periodic table; Cp is a cyclopentadienyl group or a derivative thereof which is bonded to M1 by 7Γ; z1 is an oxygen atom, a sulfur atom or a boron atom; Or a ligand of a group 14 element of the periodic table; Y1 is a ligand containing an atom selected from a nitrogen atom, a phosphorus atom, an oxygen atom and a sulfur atom; and each X1 may be the same or different and is a hydrogen atom, a halogen atom, a hydrocarbon group having 20 or less carbon atoms and having 1 or more double bonds, a decyl group having 20 or less ruthenium atoms, a ruthenium group containing 2 Å or less of ruthenium atoms or containing 20 or more Less roasting of boron atoms; (Please read the notes on the back and fill out this page) Order --------- Line! Ministry of Economic Affairs, Intellectual Property Bureau, employee consumption cooperative, printing . . . (13) where Μ is a transition metal atom selected from Group 4 of the periodic table; rii to ri4, R&quot; to R2° and R41 may be the same or different and each have an order to 至 4 carbon paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) '' -- 323 (Revised) 312991 Β 8 C8 D8 (May 14, 1996) 1290149, the scope of patent application, ^halogenated hydrocarbon group having 1 to 4 carbon atoms, oxygen-containing, sulfur-containing group, sulfhydryl group, tooth atom or hydrogen atom; R&quot;, R' Rl3, Rl4, R17, R18, R19, η π - - * /, R not in the group, partially adjacent to each other: group:: and the carbon atoms combined with these groups - combine to form a ring (only R, R13, R14, R ", R &quot;, R' R2. When all groups of r41 are hydrogen atoms, rn Ru is a third butyl group, and the rest R11, R12, 'R2, R, ^, . . . X1 and X2 may be the same or different and each is a hydrocarbon group having from 2 to 2 carbon atoms, a oxyhydrin group having 1 to 20 carbon atoms, an oxy group, a sulfur-containing group, a thiol group, a hydrogen atom or _ An atom; and γ1 are a divalent hydrocarbon group having from 1 to 2 carbon atoms, a divalent halogenated hydrocarbon group having from j to 2 carbon atoms, a divalent group containing ruthenium, a divalent group containing ruthenium, and a tin containing Valence base, +, -C0-, one s-one, -so one, -s〇2, one Ge-, _Sn-, -nr21-, -PU21)-_p(8)u21)-, -BR21 one or one A1R21-( Each R21 can be the same Or a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having 1 to 2 carbon atoms, a hydrogen atom, a halogen atom or one or two hydrocarbon groups having 1 to 20 carbon atoms combined with a nitrogen atom Nitrogen compound residue); (14) wherein Μ1 is a transition metal atom selected from Group 4 of the periodic table; R41 and R42 may be the same or different and each is a hydrocarbon K paper having 1 to 40 carbon atoms The scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (please read the note on the back and fill out this page) ill — — — — II ^ Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Print X ( / X1 324 (amendment) 312991 1290149 six—Sn—, one 〇 21—...P (〇, -P(〇)(R21)-, -BR21- or one A1R21—(each R21 may be the same or different and have 1 to An L-group of 20 carbon atoms, a halogenated hydrocarbon group having 1 to 2 carbon atoms, a chlorine atom, a halogen atom or - or a nitrogen compound having two hydrocarbon groups having from ! to 2 carbon atoms bonded to a nitrogen atom ); ο. Patent-scoped base, a halogenated hydrocarbon group having 1 to 40 carbon atoms, an oxygen-containing group, a sulfur-containing group, a thiol group, a halogen atom or a hydrogen atom; and a group represented by Rn, R and R42 The partially adjacent groups may be bonded together with carbon atoms bonded to the groups to form a ring; X1 and X2 may be the same or different and each is a hydrocarbon group having 1 to 20 carbon atoms, having from 1 to 2 carbons. a halogenated hydrocarbon group of an atom, an oxygen-containing group, a sulfur-containing group, a thiol group, a hydrogen atom or a halogen atom; and Y is a divalent hydrocarbon group having 1 to 20 carbon atoms (when all of RU, RR and 1^ are hydrogen atoms) When γ1 is not ethylidene), has j to 20; divalent halogenated hydrocarbon group of ε anti-atom, divalent group containing ruthenium, divalent group containing ruthenium, divalent group containing tin, 〇- , -C〇-, -S_, _s〇—, —s〇2—, (15) where M1 is a transition metal atom selected from Group 4 of the periodic table; “and π may be the same or different and each have From i to 40 atomic groups of the atomic acid group, having a hydrocarbon group of 1 to 4 carbon atoms, an oxygen-containing group, a sulfur-containing compound, a sulfonium-f-group functional atom or a chlorine atom; and a group represented by R41 and R42 Youth department ® paper in the national standard (CiNb scale applicable; A4 size (21G X 297 male hair) ~ * ____________ 325 (Revised) 312 991 (please read the Notes on the back page and then fill in} 1290149 098899 ABCD Patent No. 90112258 (May 14, 2014) 6. Groups in which the patent applications are adjacent to each other may be combined with carbon atoms bonded to the groups to form a ring; X1 and X2 may be the same or Different and each are a hydrocarbon group having 1 to 2 carbon atoms, a halogenated hydrocarbon group having 1 to 20 carbon atoms, a lactam group, a sulfur-containing group, a rock-containing group, a hydrogen atom or a halogen atom; and γΐ has 1 a divalent hydrocarbon group of up to 20 carbon atoms, a divalent functional hydrocarbon group having 1 to 2 carbon atoms, a divalent group containing ruthenium, a divalent group containing ruthenium, one of 4 kinds of tin, and ~~ 〇-, _C0_, -S-, -SO-, -S〇2-, -Ge-, -Sn-, -NR21-, -P(R21)-, -P(〇)(R21)--BR21- Or -AIR21 - (each γ may be the same or different and is a hydrocarbon group having 1 to 20 carbon atoms, a halogenated hydrocarbon group having from i to 20 carbon atoms, a hydrogen atom, a halogen atom or one or two having 1 to 20 a nitrogen compound residue formed by combining a hydrocarbon group of a carbon atom with a nitrogen atom); Wherein M1 is a transition metal atom selected from Group 4 of the periodic table; R11, Ri2, R15 to R2°, may be the same or different from R42, and each is a hydrocarbon group having 1 to 40 carbon atoms, having 1 to 40 carbons a halogenated hydrocarbon group of an atom, an oxygen-containing group, a sulfur-containing group, a sulfhydryl group, a halogen atom or a hydrogen atom; and a group represented by R11, R12, R15, R16, R17, R18, R19, R2Q and R42, partially mutually The adjacent groups may be bonded together with carbon atoms bonded to the groups to form a ring; X1 and X2 may be the same or different and each is a hydrocarbon group having 1 to 20 carbon atoms, having 1 to 20 carbon atoms. Hydrocarbon-based, oxygen-containing, paper grades applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) (Please read the notes on the back and fill out this page) • I n _n nni n-^rwJ n Bi ·· ϋ mmmmm ϋ II · Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 326 (Revised) 312991 1290149 A8B8C8D8 Please in the middle of the day 4 Lee 1 Special number 8 5 05 220 The patent application scope contains sulfur-based &amp; a hydrogen atom or a halogen atom; and γ1 is a divalent hydrocarbon group having from 1 to 2 carbon atoms (when When all R&quot;, Rl2, r15, Ri6, ^, R, R, R and r42 are hydrogen atoms, γ1 is not a divalent halogenated hydrocarbon group having 1 to 20 carbon atoms and a valence of ruthenium containing ruthenium. Base, divalent group containing ruthenium, divalent group containing tin, -0-, -CO-, -S-, one, - S〇2 -, -Ge-, -Sn-...nr21-, _P(R21 )-, -p(〇)(r21)-, a BR21- or -AIR21- (each γ may be the same or different and is a hydrocarbon group having from i to 2 carbon atoms, having from ! to 2 carbon atoms) a hydrocarbon group, a hydrogen atom, a halogen atom or a nitrogen compound residue having one or two hydrocarbon groups having from 2 to 2 carbon atoms bonded to a nitrogen atom. 13) A method for preparing a polar group-containing olefin copolymer, In the presence of a catalyst having the following composition, (A) a compound selected from the transition metal of Group 4 of the periodic table, and (B) at least one compound selected from the group consisting of: (B-1) selected from aluminoxane or An organoaluminum oxy-compound which is insoluble in the organoaluminum oxy compound, (B-2) reacts with the compound (a) to form an ion pair selected from the group consisting of Lewis acid, ionic compound, borane compound and carborane compound a compound, and (B-3) an organoaluminum compound RanAlX3 represented by the formula: wherein Ra is a hydrocarbon group having 1 to 12 carbon atoms, X is a halogen atom or a hydrogen atom, and η is 1 to 3; At least one α-olefin having an α-dilute hydrocarbon having 2 to 20 carbon atoms and a polar group-containing monomer selected from the following formula (7), and a torn-off ancient planting as shown in the following formula (8) Further _' ' .....................__ 327 (Revised) 312991 (Please read the notes on the back and fill out this page) Order ------- --Line 1 Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperatives Printed on this paper scale Applicable to China National Standard (CNS) A4 Specification (210 X 297 public) 1290149 A8 Βδ C8 D8 Patent No. 90112258 (May 1st, 1996) 4. 曰, VI. The polar group-containing monomer in the patent application range is copolymerized with at least one polar group-containing monomer of the macromonomer represented by the following formula (9): CH2=CH (R4) • (x)D .. (7) wherein R3 is a hydrocarbon group having 1 to 20 carbon atoms; R4 is a hetero atom or a group containing a hetero atom; r is 0 or 1; X is -0R, -C00R, -CR0, -C(0 ) NR2, -C(0)R (R is a hydrogen atom or a hydrocarbon group) , epoxy, -Ν or -NR R" (R' and R' may be the same or different and are a hydrogen atom or an alkyl group); p is an integer from 1 to 3; when 0 is 2 or 3, each X The same or different, in this case, if r is 〇, χ can be bonded to the same or different atoms of R3, and if r is 1, X can be bonded to the same or different atom of R4; turtle-(Y) m -(Y)r (Please read the notes on the back and fill out this page) Order---------Line Economy Ministry Intellectual Property Bureau Staff Consumer Cooperative Print (8) where R7 is a direct key or An aliphatic hydrocarbon group having one or more carbon atoms; R8 is a hydrogen atom, a direct bond or an aliphatic hydrocarbon group having one or more carbon atoms; Y is -0R, -C00R, -CR0, -C(0)NR2 -C(0)R (R is a hydrogen atom or a hydrocarbon group), an epoxy group, -CEN or -NR, R" (R, and R, which may be the same or different and are a hydrogen atom or an alkyl group); 111 and 11 Each is an integer from 〇 to 2, and m+n is not 〇; s is 〇 or 1; 328 (amendment) 312991 1290149 Sixth, the scope of application for patents (W)q-fRe)r-f (9) wherein R5 is a hydrocarbon group having 1 to 20 carbon atoms; R6 is a hetero atom or a hetero atom-containing group; r is ruthenium or 1; and Z is anion polymerization, ring-opening polymerization, and polycondensation. a polymer fragment obtained by any method; W is a hydroxyl group or an epoxy group; p is an integer of 1 to 3, ^ is ^, 1 or 2, and p + q'3; when p is 2 or 3, each -0-Z may be the same or different. In this case, if r is 〇, then -0-Z may be bonded to the same or different atoms of R5, and if r is 1, then -o-z may be bonded to R6. The same or different atoms; when q is 2, each w may be the same or different. In this case, if r is 0, W may be bonded to the same or different atoms of R5, and if r is 1, W may be combined. The same or different atoms in R6; in the case of p -1 and q - 1, if r is 0, then W and _〇4 can be bonded to the same or different atoms of R5, and if r is 1, then w and -0-Z can be bonded to the same or different atoms of R6. 14. A method for preparing a branched-chain polar-containing olefin copolymer, which is included in the presence of a catalyst having the following composition: Printing by the Ministry of Economic Affairs, Intellectual Property Office, Staff Consumer Cooperative (A) a compound selected from the transition metal of Group 4 of the periodic table. And (B) at least one compound selected from the group consisting of (B-1) an organoaluminum oxy-compound selected from an aluminoxane or an organoaluminum oxy compound insoluble in benzene, (B-2) and a compound ( A) The reaction forms an ion pair selected from the group consisting of a Lewis acid, an ionic compound, a borane compound and a carborane compound, and the paper size applies to the Chinese National Standard (CNS) A4 (21〇X 297) 1290149 A8 B8 C8 D8 (May 14, 1996) "Applicant's patent garden (Β - 31) The organic compound Ε'ΑΐΧ3~η is a hydrocarbon group having 1 to 12 carbon atoms, and X is a halogen. An atom or a hydrogen atom, and at least one a-hydroquinone of 2 to 3 carbon atoms, a polar group-containing monomer represented by the following formula (10), and optionally, Copolymerization of a polar group-containing monomer of the following formula (8): ch2=ch (R6) m-(W)n to 20 hydrocarbon groups which are impeding atoms; R6 is a hetero atom or (10) wherein R5 is a group having a hetero atom; m is 0 or 1; ff is a hydroxyl group or an epoxy group n is an integer from 1 to 3; and when η is 2 or 3, each W may be the same or different, in which case 'w if m is 〇, w may be bonded to the same or different atom of R5' and if m If it is 1, then w can be combined with the same or different atoms of R6; Earn: •00n 00η (please read the note on the back and fill out this page) |!1Book.— ί线β Ministry of Economic Affairs Intellectual Property Bureau Staff Consumption Cooperative Printed garment (8) wherein R is a direct bond or an aliphatic hydrocarbon group having one or more carbon atoms; r8 is a hydrogen atom, a direct bond or an aliphatic hydrocarbon group having one or more carbon atoms; Y is -OR, -C00R, -CR0, -C(0)NR2, -C(0)R (R is a hydrogen atom or a hydrocarbon group), an epoxy group, -CeN or _NR' R" (R, and R, may be the same or The difference is a hydrogen atom or a burnt group. · 'πι and η are each an integer of 〇 to 2, and m+n is not 0; s is 0 or 1; The paper scale applies to the Chinese National Standard (CNS) A4 specification (210) X 297 mm) 330 (Revised) 312991 1290149 No. 901 Patent Application No. 22058 (May 14, 1996) /, Applying for a patent range and then performing any of the following steps (1) and (ii): using, (using anionic polymerization, ring-opening polymerization or polycondensation) / The W portion of the polar group-containing monomer copolymerized to form a z-part; the sub-co-polymerized polar group-containing monomer? The reaction is partially carried out with a poly-functional group prepared by using anion: =, ring-opening polymerization or polycondensation. The composition of the thermoplastic resin is taken as the polar group-containing olefin copolymer according to any one of the above claims. 16. The type of the binder resin is a polar group-containing olefin copolymer as claimed in any one of the above claims. A compatibilizing agent (CQmpatibiHzing kiss (4), which comprises a polar olefin-containing copolymer as claimed in any of claims 1 to 9 of the patent application. 18. A resin modifying agent, including a patent application The polar olefin-containing copolymer according to any one of the items of the item -9. A filler-dispersing agent comprising the polar-containing olefin copolymer according to any one of claims 1 to 9. A dispersion comprising a polar olefin-containing copolymer as claimed in any one of claims 9 to 9. A film comprising a polar olefin-containing copolymer according to any one of claims 197 to 9. 22. A sheet-like material comprising the polar-containing polyglycol copolymer as claimed in any one of claims 1-5. A binder resin comprising a thermoplastic resin composition as claimed in claim 15 of the patent application. , 24·- a compatibilizer' is included in the thermoplastic paper scale as claimed in Article 15 of the patent application. The Chinese National Standard (CNS) A4 Regulation (21〇X 297 public interest)'* ------ 331 (Revised) 312991 1290149 Patent Application No. 90112258 (May 14, 1996) Sixth, the scope of application for patents resin composition. 25. A resin modifier which is a plastic resin composition. For example, the heat % of the 15th item of the profit range - the type of filler dispersant, including the application of the plastic resin composition. 视 弟 弟 15 15 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎 敎The thermoplastic film of the 15th item is a plastic resin composition such as the 埶 玍 2 2 专利 第 第 第 第 第 第 。 2 2 2 2 2 2 玍 玍 玍 玍 玍 玍 玍 玍 玍 玍 玍 玍 玍 玍 玍 埶 埶 埶 埶 埶For example, apply for a resin composition. The thermoplasticity of item 15 of the scope of interest (please read the note on the back and then fill out this page) -- Line · Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative printed on this paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 PCT (Amendment) 312991