TWI285414B - Non-volatile memory and manufacturing method and operating method thereof - Google Patents

Non-volatile memory and manufacturing method and operating method thereof Download PDF

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Publication number
TWI285414B
TWI285414B TW094136825A TW94136825A TWI285414B TW I285414 B TWI285414 B TW I285414B TW 094136825 A TW094136825 A TW 094136825A TW 94136825 A TW94136825 A TW 94136825A TW I285414 B TWI285414 B TW I285414B
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Taiwan
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voltage
memory cell
memory
substrate
volatile memory
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TW094136825A
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Chinese (zh)
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TW200717722A (en
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Yung-Chung Lee
Shi-Shien Chen
Hann-Ping Hwang
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Powerchip Semiconductor Corp
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Priority to TW094136825A priority Critical patent/TWI285414B/en
Priority to US11/307,804 priority patent/US20070090453A1/en
Publication of TW200717722A publication Critical patent/TW200717722A/en
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Publication of TWI285414B publication Critical patent/TWI285414B/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/788Field effect transistors with field effect produced by an insulated gate with floating gate
    • H01L29/7881Programmable transistors with only two possible levels of programmation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/792Field effect transistors with field effect produced by an insulated gate with charge trapping gate insulator, e.g. MNOS-memory transistors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/792Field effect transistors with field effect produced by an insulated gate with charge trapping gate insulator, e.g. MNOS-memory transistors
    • H01L29/7926Vertical transistors, i.e. transistors having source and drain not in the same horizontal plane
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B41/00Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
    • H10B41/20Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by three-dimensional arrangements, e.g. with cells on different height levels
    • H10B41/23Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels
    • H10B41/27Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels the channels comprising vertical portions, e.g. U-shaped channels
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B43/00EEPROM devices comprising charge-trapping gate insulators
    • H10B43/30EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B69/00Erasable-and-programmable ROM [EPROM] devices not provided for in groups H10B41/00 - H10B63/00, e.g. ultraviolet erasable-and-programmable ROM [UVEPROM] devices

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Non-Volatile Memory (AREA)
  • Semiconductor Memories (AREA)

Abstract

A non-volatile memory unit includes a substrate, a conductive layer, a charge storage layer, a first doped regions, two second doped regions, a first bit line and a second bit line. Wherein, there is a trench in the substrate, the conductive layer is disposed in the substrate and filled the trench. The charge storage layer is disposed between the conductive layer and the substrate. The first doped region is disposed in the substrate below the trench, and the second doped regions are disposed in the substrate on the two sides of the trench respectively. Plural control gates are located above the select gates and aligned in parallel and extend in a second direction. The first bit line and the second bit line are disposed on the substrate and electrically connected to the two second doped regions respectively and parallel to each other.

Description

非禪發性記憶體中的可Non-Zenary memory

九、發明說明: 【發明所屬之技術領域】 本發明是有關於一種半導體元件及其製造方法與操作 方法,且特別是有關於一種非揮發性記憶體及其製造 與操作方法。 【先前技術】 ----— w ^ 一 j τ土少、Ρ δ貝δ匕恩體」 有可進行多次資料之存入、讀取、抹除等動作,且存入: 資料在斷電後也不會消失之優點,所以已成為個人電腦3 電子設備所廣泛採用的一種記憶體元件。 典型的可電抹除且可程式唯讀記憶體係以摻雜的多Ε 矽製作浮置閘極(Floating Gate)與控制閘極(c〇ntr Gate)。當記憶體進行程式化(Pr〇gram)時,注入浮置閘極# 電子會均勻分布於整個多晶矽浮置閘極層之中。然而,$ 多晶石夕浮置陳層下方的穿眺化層有缺陷存在時,就^ 易造成元件的漏電流,影響元件的可靠度。 3 “ ’為了解決可電抹除可奴唯讀記憶體元件漏臂 =置二Γ料的一種方法是採用一電荷儲存細」 ^曰^置間極’此電荷儲存層之材質例如是氮化石夕。^ 電荷儲存層上下通常各有—層氧化石夕,而形成一 (Sta^cked^^ /、有此堆®式閘極結構之EEPROM il 夕鼠化矽/氧化矽/矽(SONOS)記憶體。杏施加 ” 4:於此tl件之控制間極與源/汲極區上以進行程式化 5 ⑧ 1285411摩 99twf.doc/g 時’通道區中接近祕區之處會產生熱電子而注人電荷儲 存層中。由於氮切具有敵電子的雜,@此,注 荷儲存層之中的電子並不會均勻分布於整個電荷儲存層之 中,而是集巾於電荷儲存層的局部區域上。由於注入電 儲存層的電子僅射於局部_域,因此,·穿隨氧化 層中缺陷的敏感度較小’元件漏電流的現象較不易發生。 然而,堆疊式閘極位於基底表面上的平面型SONos 記憶體具有無法同時進行程式化/讀取的問題,同樣的問題 也發生在Micro Technology公司於美國專利號腦,853578 中所提出的垂直結構的SONOS記憶體中。 【發明内容】 立有鑑於此,本發明的目的就是在提供一種非揮發性記 憶體單元’可同時對—記憶體單元巾的二個記憶胞進行程 式化/讀取/抹除操作。 本發明的另一目的就是在提供一種非揮發性記憶體陣 歹J,具有自對準的字元線、源極線及汲極區。 本發明的又一目的是提供一種非揮發性記憶體陣列 製造方法,可以簡化製程。 、本發明的再一目的是提供一種非揮發性記憶體的操作 方法,能夠更容易地對記憶體單元進行操作。 本發明提供一種非揮發性記憶體單元,包括一基底、 i導體層 層電何儲存層、一個第一摻雜區、二個第 二摻雜區、、-條第—導線及—條第二導線。其中,基底中 /、有個溝渠,而導體層配置於溝渠中,並於該溝渠方向 12854 層配置於導體層與基底之間。第—換雜區, 底中。、二=一:而二第二接雜區分別配置於溝渠兩側的基 別電性連ΐ於第二導線,平行配置於基底上’分 係以與,層;:交二:二,且第—導線與第二導線 記憶ΞϊίΓ月的—較佳實施例所述,在上述之非揮發性 分別用叫接j包括錄個導錢塞,配置於基底上, 另—側的第第二摻雜區與第—導線,及溝渠 禾一穋雜區與第二導線。 記憶體單佳實施例所述’在上述之非揮發性 ,$體層的材質例如是摻雜多晶石夕。 記憶體trt較佳實施例所述,在上述之非揮發性 中,電荷儲存層的材質包括氮化矽。 記怜體;本t明的一較佳實施例所述,在上述之非揮發性 層g早疋中,更包括一層第一介電層,配置於電荷儲; 記憶體單本t明的祕貫闕所述,在上叙非揮發性 第—介電層的材質包括氧切。 記憶體ΐ本Γ的—較佳實施例所述,在上述之非揮發性 層^早7L中’更包括—層第二介電層,配置於電荷儲存 記憶::本Γ月的一較佳實施例所述’在上述之非揮發性 ^早疋中’第二介電層的材f包括氧切。 々照本發_-較佳實關所述,在上述之非揮發性 12854 ^^99twf.doc/g 記憶體單元中’這些導電插塞之材質包括多晶石夕。 依照本發明的-較佳實施例所述,在上述之 性 記憶體單元中,這些第-導線及這些第二導線的材質包括 金屣鎢。 个放•一 工%,愿體陣列,包括一基底、 多數個記憶胞行及多數個隔離結構。其中,基底且[Technical Field] The present invention relates to a semiconductor device, a method of fabricating the same, and a method of operating the same, and more particularly to a nonvolatile memory and a method of fabricating and operating the same. [Prior Art] ----- w ^ a j τ soil less, δ δ δ 匕 匕 」 ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” It will not disappear after the power, so it has become a memory component widely used in personal computer 3 electronic equipment. A typical electrically erasable and programmable read-only memory system uses a doped multi-turn 矽 to create a floating gate and a control gate (c〇ntr Gate). When the memory is programmed (Pr〇gram), the injected floating gate # electrons are evenly distributed throughout the polysilicon floating gate layer. However, when there is a defect in the penetrating layer under the polycrystalline slab floating layer, it is easy to cause leakage current of the component and affect the reliability of the component. 3 “'In order to solve the problem that the eraser can read the memory device, the drain arm=set the second material is to use a charge storage fine.” ^曰^ Placement pole' The material of the charge storage layer is, for example, nitride. Xi. ^ The charge storage layer usually has a layer of oxidized oxide on the upper and lower sides to form a (Sta^cked^^ /, EEPROM il 矽 矽 矽 / 矽 矽 / 矽 (SONOS) memory with this stack of gate structure Apricot application" 4: On the control pole and source/drain region of this tl piece for stylization 5 8 1285411, 99twf.doc/g, when the channel area is close to the secret zone, hot electrons will be generated. In the human charge storage layer, since the nitrogen cut has a hostile electron, @ this, the electrons in the charge storage layer are not evenly distributed throughout the charge storage layer, but are collected in a local area of the charge storage layer. Since the electrons injected into the electrical storage layer only hit the local _ domain, the sensitivity of the defects in the oxide layer is small. The leakage current of the component is less likely to occur. However, the stacked gate is located on the surface of the substrate. The planar SONOs memory has the problem that it cannot be programmed/read at the same time, and the same problem also occurs in the vertical structure SONOS memory proposed by Micro Technology in U.S. Patent No. 8,535,78. In view of this, this The purpose of the present invention is to provide a non-volatile memory unit that can simultaneously program/read/erase two memory cells of a memory unit. Another object of the present invention is to provide a non-volatile The memory matrix J has self-aligned word lines, source lines and drain regions. It is still another object of the present invention to provide a method for fabricating a non-volatile memory array, which can simplify the process. A further object is to provide a method for operating a non-volatile memory, which can operate the memory unit more easily. The present invention provides a non-volatile memory unit comprising a substrate, an i-conductor layer, an electrical storage layer, a first doped region, two second doped regions, a strip first wire and a second wire. wherein the substrate has a trench, and the conductor layer is disposed in the trench and is in the trench The direction 12854 layer is disposed between the conductor layer and the substrate. The first-changing region, the bottom portion, the second=one: and the second second impurity region are respectively disposed on the two sides of the trench and electrically connected to the second wire Parallel configuration On the substrate, the sub-system is connected to the layer, and the second and second wires are stored in the preferred embodiment. a money plug, disposed on the substrate, the second doped region and the first wire on the other side, and the trench and the doped region and the second wire. The memory is described in the preferred embodiment as described above. The material of the bulk layer is, for example, doped polycrystalline stone. Memory trt is described in the preferred embodiment. In the above non-volatile, the material of the charge storage layer includes tantalum nitride. In a preferred embodiment, the non-volatile layer g is further provided with a first dielectric layer disposed in the charge storage; The material of the non-volatile first-dielectric layer includes oxygen cutting. In the preferred embodiment of the memory, in the non-volatile layer 7L, the second dielectric layer is further included in the charge storage memory: a preferred one of the present month The material f of the second dielectric layer in the above-mentioned non-volatile first embodiment includes oxygen cutting. According to the present invention, in the above non-volatile 12854 ^^99 twf.doc/g memory unit, the materials of these conductive plugs include polycrystalline stone. According to a preferred embodiment of the present invention, in the above memory unit, the material of the first wire and the second wires comprises gold-tungsten tungsten. A unit of work, a body array, including a base, a majority of memory cells and a number of isolation structures. Among them, the substrate

數個溝渠’這些溝渠為平行排列,並往列的方向延;申。^ 數個隔離結構,配置於基底中,用以隔離這些記憶胞行。 5數=憶胞行,由多數個記憶體單元所組成,各記憶體 條字元線、一層電荷儲存層、-個第-摻雜區、 、曾ΐ ΐ、Γ第三摻雜區、—條第—導線、一條第二 條第三導線。其中’字元線配置於這些溝渠'之-, ί層配=!中^連接列的這些記憶體單元。電荷儲 的i渠下方二第一摻雜區配置於所對應 用。一第二摻雜區及:列的Ϊ些記憶體單元所共Several ditches' These ditches are arranged in parallel and are oriented in the direction of the column; ^ Several isolation structures are placed in the substrate to isolate these memory cells. 5 number = memory cell, composed of a plurality of memory cells, each memory bar word line, a layer of charge storage layer, a first doped region, a Zeng ΐ ΐ, a third doped region, Article - wire, a second wire. Among them, the 'word line is arranged in these trenches', and the ί layer is matched with the !! The first first doped regions under the charge reservoir are disposed for the corresponding ones. a second doped region and a plurality of memory cells of the column

雜區係交錯排列,分彳’第二摻雜區與第三摻 線及第二導綠」別配置於溝渠兩側的基底中。第-導 別電性連接於當=配置於基底上,沿行的方向延伸,分 置於基底上,區與第三摻雜區之一。第三導線配 元所包含之第一=連接弟一摻雜區。其中,同-行記憶單 之二個記怜^穆雜區及第三摻雜區係交錯排列,且相鄰 一。〜體早μ共用這些第二掺雜區或第三摻雜區之 w本發明的—較佳實施例所述’在上述之非揮發性 12854 r499twfdoc/g 。己隐體陣列中’更包括多數個導電插塞,配置於基底上, :。用:)連接第—摻雜區與這些第_導線,及第三摻雜區 /、攻些第二導線及這些第—摻雜與這些第三導線。 二依…、本毛明的較佳實施例所述,在上述之非揮發性 zfe體陣列中’⑨些崎結構包括淺溝渠隔離·結構。 依知、本發明的-較佳實施例所述,在上述 =體陣列中,更包括多數個第一介電層,分別二 些電何儲存層與溝渠表面之間。 依照本發明的一較佳實施例所述,在上述之非揮發性 ^憶?陣列中,更包括多數個第二介電層,分別配置二這 些電荷儲存層與該字元線之間。 、 本發明提出-種非揮發性記憶體的製造方法 二:ί底排:基底中形成多數個隔離結構,而這些隔離結 構為千饤排列,亚往-第一方向延伸。接著,祕 =固溝渠’這些溝渠平行排列’並在―第二;向上延 :其广ί—方向與弟―方向相交。紐’於這些溝竿下方 底個i 一摻雜區,而於這些溝渠兩側的基 底中幵7成夕數個弟二摻_及多數個第 方向上這些第二摻雜區與這些第三;=:弟: 下來’於這些溝渠内之基底表面形成多數接 而於基底上形成填滿這些溝準的多固电何儲存層, 基底上形成多數條第-導線及多數條第=。之後’於 連接於這些第二摻雜區與這些第三線’分別電性 線及這些第二導線為平行排列,並往第—方==弟一導 1285411辟99twfdoc/g 依照本發明的-較佳實施例所述,在上述之非揮 記憶體的製造方法巾,更包括於基底上形成多數個導^插 塞,分別用以連接這些第二摻雜區與這些第一導線,及、; 些第二糝雜區與這些第二導線。 s 依照本發明的-較佳實施例所述,在上述之非揮發性 記憶體的製造方法中,形成這些第—摻雜區、這些第二換 雜區及這些第三摻雜區的方法包括離子植入法。 ^ 依照本發明的一較佳實施例所述,在上述之非揮發性 記憶體的製造方法中,更包括於各電荷儲存層下方與^底 之間形成一層第一介電層。 、土一 依照本發明的一較佳實施例所述,在上述之非揮發性 記憶體的製造方法中,更包括於各電荷儲存層上方盥^开 線之間形成一層第二介電層。 依照本發明的一較佳實施例所述,在上述之非揮發性 記憶體的製造方法中,形成這些字元線的方法,首先^基 底上形成一層導體材料層,並填滿這些溝渠。然後,移& 形成於這些溝渠以外的導體材料層。 依照本發明的一較佳實施例所述,在上述之非揮發性 記憶體的製造方法中,移除形成於這些溝渠以外的導^材 料層的方法包括化學機械研磨法。 本發明提出一種非揮發性記憶體的操作方法,適用於 排列成行/列的一記憶胞陣列,記憶胞陣列由多數個記憶體 單元所組成,各記憶體單元包括一條字元線,配置於一基 底之一個溝渠中,並延伸於溝渠中,且連接同一列的這些 12854 沖_〇 吻 記憶體單元、一屙雷丼紗— -個第-_/儲存層’配置於字元線與基底之間、 為同-列‘記==溝! 二第二 分別電性連接第二摻雜向延伸, 體單亓妓田一加〜A 雜£,且相鄰二個記憶 體單元"7 A彳H雜11或第三摻雜區,而每—個記憶 體早兀包含位於各字元線兩側的—第—記憶胞第二2 憶胞,非揮紐記龍㈣作料紐: ° -導化知作日年’於選定之第一記憶胞所對應的第 :導、^加=一電壓’於選定之第一記憶胞的第一推雜區 施口弟一電壓’於選定之第一記憶胞的字元線施加第三電 壓,其中第-電壓大於第二電壓,以程式化第一記憶胞之 上位元,第三電壓大於記憶單元之臨界電壓;以及 ”於選定之第-記憶胞所對應的第—導線施加第二電 壓,於遥疋之第一^己憶胞的第一摻雜區施加第一電壓,於 遥疋之弟一 §己丨思胞的字元線施加第三電壓,以程式化第一 記憶胞之一下位元。 依照本發明的一較佳實施例所述,在上述之非揮發性 記憶體的操作方法中,包括: 在進行程式化操作時,於選定之第二記憶胞所對應的 第二導線施加第七電壓,於選定之第二記憶胞的第_^雜 區施加第八電壓,於選定之第二記憶胞的字元線施加第九 電壓,其中第七電壓大於第八電壓,以程式化第二記憶胞 11 1285414 ’99twf.doc/g 之一上位元,苐九電壓大於記憶單元之臨界電壓;以及 β於選定之第二記憶胞所對應的第二導線施加第八電 壓,於選定之第二記憶胞的第一摻雜區施加第七電壓,於 選疋之第二S己憶胞的字元線施加第九電壓,以程式化第二 記憶胞之一下位元。 依照本發明的一較佳實施例所述,在上述之非揮發性 記憶體的操作方法中,包括: 在讀取第二記憶胞之上位元時,於選定之第二記憶胞 =的第二導線施加_壓’於選定之第二記憶胞的 c施加第十1壓,於選定之第二記憶胞的字元 線如加弟十二電壓,其中第十電壓小於第十—電壓,第十 —電壓大於第二記憶胞未程式化前之臨界帝 記憶胞程式化後之臨界電壓;以及 ,; 一 在5貝取弟一自己憶胞之下位元味 •應的第二導線施加第十_電[’〜定之第二記憶胞 的第-摻雜區施加第十電壓,於選定,第二記;胞 線施加第十二電壓。 、疋之第一 S己憶胞的子元 依照本發明的一較佳實施例 記憶體的操作方法中,包括:斤述,在上述之非揮發性 在讀取第一記憶胞之上位元 所對應的第-導線施加第四厂於選定之第一記憶胞 第-摻雜區施加第五電壓,、於選定之第—記憶胞的 施加第六電壓,其中第四電壓、=第—記憶胞的字元線 於第—記憶胞未程式化叙五電壓,第六電壓大 电峻,小於第一記憶胞程The miscellaneous regions are staggered, and the bifurcations 'second doped regions and the third doped lines and the second green guides' are disposed in the bases on both sides of the ditch. The first-conductor is electrically connected to the substrate, is disposed on the substrate, extends in the direction of the row, and is disposed on the substrate, one of the region and the third doped region. The first wire included in the third wire element is connected to the first doped region. Among them, the two memorandum and the third doped regions of the same-line memory list are staggered and adjacent one. The second doping region or the third doping region is shared by the preferred embodiment of the present invention as described above in the non-volatile 12854 r499twfdoc/g. The 'hidden body array' further includes a plurality of conductive plugs disposed on the substrate, . And: connecting the first doped region and the first thyristor, and the third doped region /, attacking the second wires and the first doping and the third wires. According to a preferred embodiment of the present invention, in the above non-volatile zfe body array, the '9-small structure includes a shallow trench isolation structure. According to the preferred embodiment of the present invention, in the above-mentioned body array, a plurality of first dielectric layers are further included, and between the two electrical storage layers and the surface of the trench. According to a preferred embodiment of the present invention, in the non-volatile memory array, a plurality of second dielectric layers are further disposed between the two charge storage layers and the word line. The invention proposes a method for manufacturing a non-volatile memory. Second: 底 bottom row: a plurality of isolation structures are formed in the substrate, and the isolation structures are arranged in a thousand ridges and extend in a sub-first direction. Then, the secret = solid trenches - these trenches are arranged in parallel 'and in the second; the upward extension: its wide-direction intersects with the younger direction. New's underneath these gullies, the bottom of the i-doped region, and the bases on both sides of the trenches are 幵 成 个 个 个 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及; = : Brother : Down 'to form a majority of the surface of the substrate in these trenches to form a multi-solid storage layer filled with these trenches on the substrate, forming a plurality of first-wires and a plurality of strips on the substrate. After that, the electrical lines connecting the second doped regions and the third lines respectively and the second wires are arranged in parallel, and the third side is replaced by the first side == 弟一导1285411 99twfdoc/g according to the present invention. In a preferred embodiment, the method for manufacturing a non-volatile memory device further includes forming a plurality of conductive plugs on the substrate for respectively connecting the second doped regions and the first conductive lines, and; These second doping regions are associated with these second wires. In accordance with a preferred embodiment of the present invention, in the method of fabricating the non-volatile memory described above, the method of forming the first doped regions, the second doped regions, and the third doped regions includes Ion implantation. According to a preferred embodiment of the present invention, in the method of fabricating the non-volatile memory, a first dielectric layer is formed between the underlying charge storage layer and the bottom. According to a preferred embodiment of the present invention, in the method for fabricating the non-volatile memory, a second dielectric layer is formed between the openings of the charge storage layers. In accordance with a preferred embodiment of the present invention, in the method of fabricating the non-volatile memory, the method of forming the word lines first forms a layer of conductive material on the substrate and fills the trenches. Then, move & layers of conductor material formed outside of these trenches. According to a preferred embodiment of the present invention, in the above method of manufacturing a non-volatile memory, a method of removing a layer of a conductive material formed outside the trenches includes a chemical mechanical polishing method. The invention provides a method for operating a non-volatile memory, which is suitable for a memory cell array arranged in rows/columns. The memory cell array is composed of a plurality of memory cells, each memory cell comprising a word line, arranged in a a ditch in the base and extending in the ditch, and the 12854 〇 〇 记忆 memory unit, a 屙 Thunder — - _ _ / storage layer connected to the same column are arranged in the word line and the base Between, the same-column's == ditch! The second and second respectively electrically connected to the second doping extension, the body single 亓妓田一加~A miscellaneous, and the adjacent two memory cells "7 A彳H hetero 11 or the third doped region, and each memory contains the second memory cell of the first memory cell located on both sides of each character line, and the non-winged dragon (four) is the material: ° - The guide is known as the first year of the selected first memory cell: guide, ^ plus = a voltage 'in the first miscellaneous region of the selected first memory cell Shikoudi a voltage' in the selected A memory cell is applied with a third voltage, wherein the first voltage is greater than the second voltage to program the first Above the cell, the third voltage is greater than the threshold voltage of the memory cell; and "the second voltage is applied to the first wire corresponding to the selected first memory cell, and the first doping of the first memory cell of the remote cell The first voltage is applied to the region, and a third voltage is applied to the word line of the remote cell to program the lower bit of the first memory cell. According to a preferred embodiment of the present invention, In the above method for operating a non-volatile memory, the method includes: applying a seventh voltage to a second wire corresponding to the selected second memory cell during the stylizing operation, in the _th of the selected second memory cell Applying an eighth voltage to the inter-cell, applying a ninth voltage to the word line of the selected second memory cell, wherein the seventh voltage is greater than the eighth voltage to program the second memory cell 11 1285414 '99twf.doc/g The upper voltage, the voltage of the ninth voltage is greater than the threshold voltage of the memory unit; and β applies an eighth voltage to the second wire corresponding to the selected second memory cell, and applies the seventh voltage to the first doped region of the selected second memory cell In the second S remembrance of the election The ninth voltage is applied to the word line of the cell to program the lower bit of the second memory cell. According to a preferred embodiment of the present invention, in the method for operating the non-volatile memory, the method includes: When reading the upper cell of the second memory cell, the second wire applied to the second memory cell of the selected second memory cell applies a tenth voltage to the selected second memory cell, and the selected second memory cell The word line is the voltage of the brother 12, wherein the tenth voltage is less than the tenth voltage, and the tenth voltage is greater than the threshold voltage of the critical memory cell before the second memory cell is not programmed; and; 5 取 弟 一 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 自己 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二 第二Apply the twelfth voltage. In the method of operating a memory according to a preferred embodiment of the present invention, the method includes: in the above non-volatile reading of the first memory cell Corresponding first-wire application fourth plant applies a fifth voltage to the selected first memory cell first-doped region, and applies a sixth voltage to the selected first memory cell, wherein the fourth voltage, = first memory cell The word line is not programmed to describe the voltage, and the sixth voltage is greater than the first memory cell.

12 12854 li^twf.doc/g 式化後之臨界電壓;以及 在讀取第-記憶胞之下位元時,於選定之第一記㈣ Γ〜 導線施加第五電壓’於選定之第-記憶胞的 加第四電壓,於選定之第—記憶_字元線 施加第/、笔堡。 依照本發明的一較佳實施例所述,在上述之非揮發性 :己憶=操作方法中,包括在進行抹除操作時,於基丄施 曜,於選定之記憶體單元的字元線施加二第12 12854 li^twf.doc/g The threshold voltage after characterization; and when reading the bit below the first-memory cell, the fifth voltage is applied to the selected first (four) Γ~ wire to the selected first-memory The fourth voltage is applied to the cell, and the /th pen is applied to the selected first-memory_word line. According to a preferred embodiment of the present invention, in the above non-volatile: memory=operation method, including the word line in the selected memory unit when performing the erase operation Apply two

^四電堡’其中第十三電壓大於第十四電壓,以利用F_N 牙隧效應進行抹除。 =於本發_非機性記賴結構,因為具有分離的 二=3同時對同—個記憶體單元中的二個記憶胞進行 私式化/項取/抹除操作。 洛白二卜2發明之非揮發性記憶體的製造方法,可以形 、準的字兀線、源極線及汲極區,能有效地簡化製程。 另方面,本發明之非揮發性記憶體的操作方法,可 求在分離的位元線上施加電壓’能夠更容易地對 吕己fe體早70進行操作。 為讓本發明之上述和其他目的、特徵和優點能更明顯 紐,下文特舉實關,並配合所關式,作詳細說明如、 下0 【實施方式】 性記〜f 1D所緣示為依照本發明一實施例之非揮發 性°己匕體的製造流程立體圖。 13 12 8 3 4 l· 499twf.d〇c/g 12 8 3 4 l· 499twf.d〇c/g^四电堡' where the thirteenth voltage is greater than the fourteenth voltage to be erased by the F_N tunneling effect. = In the present invention, the non-mechanical record structure, because there are separate two = 3, at the same time, the two memory cells in the same memory cell are privateized/elected/erased. The manufacturing method of the non-volatile memory of the invention of Luo Bai Er Bu 2 can form a standard word line, a source line and a drain area, which can effectively simplify the process. On the other hand, the method of operating the non-volatile memory of the present invention allows the voltage to be applied to the separated bit lines to more easily operate the L. In order to make the above and other objects, features and advantages of the present invention more obvious, the following is a detailed description, and in conjunction with the closed type, the detailed description is as follows, and the following is a description of the present invention. A perspective view of a manufacturing process for a non-volatile hexanide according to an embodiment of the present invention. 13 12 8 3 4 l· 499twf.d〇c/g 12 8 3 4 l· 499twf.d〇c/g

=,請參照圖1A,提供一基底議,基底刚例如 疋石土 & ’於基底刚中形成多數個隔離結構102。隔離 結構102例如是淺溝渠隔離結構,材質例如是氧 些隔離結構H)2為平行排列,並往—χ_γ平財χ的方向 延伸’X的方向例如是記憶體陣列中行的方向,γ的方向 例如是記憶體陣列中列的方向。隔離結構1G2㈣成方法 例如是S於基底HK)上依序形成錄化層(树示)、硬罩 幕層(未繪示)及圖案化之罩幕層(未緣示),然後以圖案化之 =幕層為罩幕’對硬罩幕層及墊氧化層進行—個乾餘刻製 私Ik後,移除圖案化之罩幕層。接著,以圖案化之塾氧 化層及硬罩幕層為罩幕’移除部份基底刚,以形成多數 個溝渠(未繪示)。之後,與基底⑽上形成—隔離材料層 亚填滿這些溝渠,再以硬罩幕層為研磨終止層,進行一個 化學機械研磨製程,以移除部份隔離材料層而形成隔離結 構102。繼之,移除墊氧化層及硬罩幕層。 接著,於基底100中形成一井區1〇4,例如是p型井 區。P型井區的形成方法例如是以硼為摻質,進行一個離 子植入製程而形成之。此外,在形成井區104之後,更可 以進行一個回火製程,以修復在進行離子植入時,對基底 100所造成的晶格缺陷。 然後’請參照圖1B ’於基底1〇〇中形成溝渠,這 些溝渠106為平行排列,並在γ的方向上延伸。溝罕1 〇6 的形成方法例如是先在基底100上形成圖案化之罩幕廣 (未繪示),再以圖案化之罩幕層為罩幕,對基底100進行 14 128541^799twf.d〇c/g 一個製程’隨後移除圖案化之罩幕層而形成之。 為^所進^基底100進行一個推雜製程,例如是_ 丁的離子植入製程,以於溝渠106 τ方之基底 成摻雜區110。換雜區應fr 基底100中形 區。 》雜£ 108及払雜區11〇例如是n型摻雜 號(如圖m中的料F :Λ方向編號,可分為第 中二π 1及110_3)及第2η號(如圖1ΒReferring to Figure 1A, a substrate is provided in which a substrate, such as ochre, ', forms a plurality of isolation structures 102 in the substrate. The isolation structure 102 is, for example, a shallow trench isolation structure, and the material is, for example, an oxygen isolation structure H) 2 is arranged in parallel, and the direction of the 'X direction of the χ γ 平 χ 例如 例如 is, for example, the direction of the row in the memory array, the direction of γ For example, the direction of the columns in the memory array. The isolation structure 1G2 (4) is formed by sequentially forming a recording layer (tree), a hard mask layer (not shown), and a patterned mask layer (not shown) on the substrate HK), and then patterning = The curtain layer is the mask "to the hard mask layer and the pad oxide layer - after a dry moment to make the private Ik, remove the patterned mask layer. Next, a portion of the substrate is removed by using the patterned ruthenium oxide layer and the hard mask layer as a mask to form a plurality of trenches (not shown). Thereafter, a spacer layer is formed on the substrate (10) to fill the trenches, and the hard mask layer is used as a polishing stop layer, and a chemical mechanical polishing process is performed to remove a portion of the spacer material layer to form the isolation structure 102. Following this, the pad oxide layer and the hard mask layer are removed. Next, a well region 1〇4 is formed in the substrate 100, such as a p-type well region. The formation method of the P-type well region is formed, for example, by using boron as a dopant to perform an ion implantation process. In addition, after forming the well region 104, a tempering process can be performed to repair the lattice defects caused to the substrate 100 during ion implantation. Then, please refer to Fig. 1B' to form trenches in the substrate 1〇〇, which are arranged in parallel and extend in the direction of γ. For example, the method of forming the gully 1 〇 6 is to form a patterned mask on the substrate 100 (not shown), and then use the patterned mask layer as a mask to perform 14 128541 ^ 799 twf. 〇c/g A process 'subsequently removes the patterned mask layer to form. A doping process is performed for the substrate 100, for example, an ion implantation process for forming a doped region 110 on the substrate of the trench 106. The swap area should be fr the base area of the base 100. 》# 108 and the noisy area 11〇 are, for example, n-type doping numbers (such as material F in the m: Λ direction number, can be divided into the second two π 1 and 110_3) and the second η (Figure 1Β

、多:、區110·2),η為大於等於1的整數。 成、|ίϊ ’請參照圖1C,於溝渠106内之基底100表面形 112’例如是由介電層U2a、電荷儲存層112b 戽:其Π。所組成。複合層112的形成方法,例如是依 &上形成介電層U2a、電荷儲存層112b及介 ^"私層112a的材質例如是氧化矽,形成方法 :如是化學氣相沈積法或熱氧化法。電荷儲存層㈣的材 貝例士疋氮化秒或摻雜多晶秒,形成方法例如是化學氣相More than: area 110·2), η is an integer greater than or equal to 1. Referring to FIG. 1C, the surface shape 112' of the substrate 100 in the trench 106 is, for example, a dielectric layer U2a and a charge storage layer 112b. Composed of. The method for forming the composite layer 112 is, for example, a material for forming the dielectric layer U2a, the charge storage layer 112b, and the dielectric layer 112a, such as yttrium oxide, by a method such as chemical vapor deposition or thermal oxidation. law. The material of the charge storage layer (4) is a nitriding second or a doped polycrystalline second, and the formation method is, for example, a chemical vapor phase.

,積法。’丨電層112c的材質例如是氧化石夕,形成方法例如 疋化學氣相沈積法。 繼之,於基底100上形成填滿溝渠1〇6的字元線114, 字元線114的材質例如是摻雜多晶石夕,形成方法例如是先 以臨場摻雜的方式,_化學氣相沈積法於基底 100上形 成一層摻雜多晶矽材料層(未繪示),並填滿溝渠1〇6。然 後’移除溝渠106以外的換雜多晶石夕材料層。溝渠1〇6以 外之摻雜多晶㈣料層的移除方法,例如是以基底1〇〇為 研磨終止層’利用化學機械研磨法進行移除溝渠1〇6以外 12854 m99twfd〇c/g 的摻^多晶石夕封料層及複合層112。 接著,請參照圖1D於基底1〇〇上形成 位元線m。位元線m電性連接么及 1H)(如圖m中的摻雜區购及u位=摻雜區 連接於第2η號的摻雜區⑽㈣ 性 ^位元線场118騎彳剩,, 伸。其中’位元線116及位元線118與摻::向延 接的方式’例如是透過導電插塞12G使第2η 1 性連 :圖m中的摻雜區i _及】10_3)與位元== 連接,以及透過導電插塞120使第2 圖ω中的摻雜區购)與位元線118電性連=110(如 此外,可在形成上述形成位元線118、位元 前緩先形成一層介電層(未1會示)覆蓋於基 底觸上,而位兀線118、位元線120及導電插塞, the accumulation method. The material of the tantalum layer 112c is, for example, an oxidized stone, and a forming method is, for example, a rhodium chemical vapor deposition method. Then, a word line 114 filling the trench 1〇6 is formed on the substrate 100. The material of the word line 114 is, for example, doped polycrystalline stone, and the forming method is, for example, first, in the presence of field doping, _chemical gas. The phase deposition method forms a layer of doped polysilicon material (not shown) on the substrate 100 and fills the trenches 1〇6. Then, the layer of the modified polycrystalline stone material other than the trench 106 is removed. The method for removing the doped poly (tetra) layer other than the trench 1 〇 6 is, for example, using the substrate 1 〇〇 as the polishing stop layer 'by chemical mechanical polishing to remove 12854 m99 twfd 〇c/g other than the trench 1 〇 6 The polycrystalline stone sealing layer and the composite layer 112 are doped. Next, a bit line m is formed on the substrate 1A with reference to FIG. 1D. The bit line m is electrically connected and 1H) (as shown in Figure m, the doped region is purchased and the u-bit = doped region is connected to the doped region of the second n-th (10). (4) The bit line field 118 is left over, Wherein the 'bit line 116 and the bit line 118 and the doping: the way of the extension' are, for example, the second η 1 connection through the conductive plug 12G: the doped regions i _ and _ 10_3 in the graph m) Connecting with the bit ==, and electrically connecting the doped region in the second figure ω through the conductive plug 120 to the bit line 118 is electrically connected = 1010 (so that the above-described formed bit line 118 can be formed, Forming a dielectric layer (not shown) over the substrate, and placing the germanium line 118, the bit line 120, and the conductive plug

如是:成於此介電層中。位元線118、位元線120的材J 例如是金屬鶴,而導電插塞122的材質例如是多晶石夕。貝 在另-個實施例中,位元線118、位元線12g 插塞122的形成方法例如是先形成導電插S 122,再形2 位7G線118及位元線120。導電插塞122的形成方法例如 是先於基底100上形成一圖案化之罩幕層,再以圖案化 罩幕層為罩幕,對覆蓋於基底上的介電層進行一個乾 製程,以定義出導電插塞開口(未綠示)。隨後,移除圖案 化之罩幕層。然後’進行沈積製程形成—層導體材料層夫 繪示)填滿導電插塞開口,再進行一個回餘刻製程而形曰成導 16 1285411碑99twf doc/g 電插塞122。位元線118、位元線12〇的形成方法,例如是 先依序形成另-層導體材料層(請示)及圖案化之罩幕層 (未繪不)於介電層上,再以圖案化之罩幕層為罩幕,對此 導體材料層進行-個乾_製程而形成之。隨後,移 案化之罩幕層。 μ 、在上述之非揮發性記憶體的製造方法中,可形成自對 準^播雜108、字元線114及位元線116、118,能有效 地簡化製造流程,進而加快生產的速度。在匕外,所形成的 非揮發性記憶體具有垂直的記憶胞結構,為單一記憶胞二 位元儲存的非揮發性記憶體。 以下’將說明本發明的非揮發性記憶體結構。 圖2所繪示為依照本發明一實施例之非揮發性記憶體 的立體圖。 請參照圖2,本發明所提出的非揮發性記憶體陣列包 括一基底100、隔離結構102及記憶胞行122。其中,基底 100中已形成一井區104 ,且具有溝渠106,這些溝渠106 為平行排列,並往Υ的方向延伸。井區1〇4例如是Ρ型井 區。 隔離結構102例如是配置於基底1〇〇中,用以隔離這 些記憶胞行122。隔離結構1〇2例如是淺溝渠隔離結構, 材質例如是氧化石夕。 記憶胞行122例如是由多數個記憶體單元124所組 成,各記憶體單元124包括字元線114、複合層U2、摻雜 區(源極線)1〇8、摻雜區(汲極區)ιι〇、位元線116及位元線 17 1285411伞 9twf.d〇c/g 118。字元線114例如是配置於基底loo中,填滿所對應的 溝渠106,並延伸於溝渠1〇6中,連接同一列的記憶體單 元124。子元線Π4的材質例如是例如是換雜多晶石夕。 複合層112例如是配置於字元線114與基底1〇〇之 間。複合層112,例如是由介電層112a、電荷儲存層U2b 及介電層112c所組成,介電層112a及介電層n2c的材質 例如是氧化矽,而電荷儲存層112b的材質例如是氮化矽或 摻雜多晶石夕。 摻雜區(源極線)1〇8例如是配置於所對應的溝渠1〇6 下方的基底1〇〇中,且為同一列的記憶體單元124所共用。 摻雜區108例如是N型摻雜區。 摻雜區(汲極區)11〇例如是分別配置於溝渠1〇6兩側 的基底,中,在同—記憶胞行122中,沿χ的方向編號, 可分為第2η·1號(如圖2中的掺雜區11(M及11〇_3)及第 2n號(如圖2中的摻雜區11〇_2),n為大於等於i的整數, 且相鄰二個記憶體單幻24共用—個摻雜區UG。換雜區 110例如是N型摻雜區。 位元線116及位元線118例如是配置於基底1〇〇上, 沿X的方向延伸M立元線116電性連接於第2n_i號的推 ,區no(例如是摻雜區11(M及11〇_3)。位元線ιΐ8電性 連接於第2η號的摻雜區⑽(例如是摻雜區ug_2)。位元 線116及位元線118的材質例如是如金屬鎢。 此外’非揮發性記憶體陣列中更可包括導電插塞 2〇。導電插塞120 §己置於基底1〇〇上,用以連接第w 1285416库 9twf.doc/g ΓΐΠ雜贫區例如是換雜區ii(M及u〇_3)與位元線 2n唬的摻雜區110(例如是摻雜區1102)與位元 線118。導電插塞12〇的材質例如是多晶矽。If yes: into this dielectric layer. The material J of the bit line 118 and the bit line 120 is, for example, a metal crane, and the material of the conductive plug 122 is, for example, polycrystalline. In another embodiment, the bit line 118 and the bit line 12g are formed by, for example, forming a conductive plug S 122 and then forming a 2-bit 7G line 118 and a bit line 120. The conductive plug 122 is formed by, for example, forming a patterned mask layer on the substrate 100, and then using a patterned mask layer as a mask to perform a dry process on the dielectric layer covering the substrate to define Conductive plug opening (not shown in green). Subsequently, the patterned mask layer is removed. Then, the deposition process is formed to form a layer of conductive material, and the conductive plug opening is filled, and then a back-cut process is performed to form a conductive plug 12212. The method for forming the bit line 118 and the bit line 12A is, for example, sequentially forming another layer of a conductor material layer (indicated) and a patterned mask layer (not shown) on the dielectric layer, and then patterning The mask layer is a mask, and the conductor material layer is formed by a dry-process. Subsequently, the mask layer was moved. μ In the above-described method for manufacturing a non-volatile memory, the self-alignment 108, the word line 114, and the bit lines 116 and 118 can be formed, which can effectively simplify the manufacturing process and speed up the production. Outside of the sputum, the non-volatile memory formed has a vertical memory cell structure and is a non-volatile memory stored in a single memory cell. The following describes the non-volatile memory structure of the present invention. 2 is a perspective view of a non-volatile memory in accordance with an embodiment of the present invention. Referring to FIG. 2, the non-volatile memory array of the present invention includes a substrate 100, an isolation structure 102, and a memory cell line 122. A well region 104 has been formed in the substrate 100 and has trenches 106 which are arranged in parallel and extend in the direction of the crucible. The well area 1〇4 is, for example, a 井-type well area. The isolation structure 102 is, for example, disposed in the substrate 1 to isolate the memory cell lines 122. The isolation structure 1〇2 is, for example, a shallow trench isolation structure, and the material is, for example, oxidized oxide. The memory cell row 122 is composed, for example, of a plurality of memory cells 124, each of which includes a word line 114, a composite layer U2, a doped region (source line) 1〇8, and a doped region (bungee region). ) ιι〇, bit line 116 and bit line 17 1285411 umbrella 9twf.d〇c/g 118. The word line 114 is disposed, for example, in the base loo, fills the corresponding trench 106, and extends in the trench 1〇6 to connect the memory cells 124 of the same column. The material of the sub-line Π 4 is, for example, a mixed polycrystalline spine. The composite layer 112 is disposed, for example, between the word line 114 and the substrate 1〇〇. The composite layer 112 is composed of, for example, a dielectric layer 112a, a charge storage layer U2b, and a dielectric layer 112c. The material of the dielectric layer 112a and the dielectric layer n2c is, for example, yttrium oxide, and the material of the charge storage layer 112b is, for example, nitrogen. Pupation or doping of polycrystalline stone. The doped regions (source lines) 1〇8 are, for example, disposed in the substrate 1〇〇 below the corresponding trenches 1〇6, and are shared by the memory cells 124 of the same column. The doped region 108 is, for example, an N-type doped region. The doped regions (drain regions) 11 〇 are, for example, substrates disposed on both sides of the trenches 1〇6, and are numbered in the same-memory cell row 122 along the direction of the ,, and can be divided into the second η·1 ( As shown in FIG. 2, the doping regions 11 (M and 11 〇 _3) and the second n (such as the doping region 11 〇 2 in FIG. 2), n is an integer greater than or equal to i, and adjacent two memories The body phantom 24 shares a doped region UG. The pad region 110 is, for example, an N-type doped region. The bit line 116 and the bit line 118 are, for example, disposed on the substrate 1 and extend in the direction of X. The line 116 is electrically connected to the push of the 2n_i, and the area no is, for example, the doped region 11 (M and 11〇_3). The bit line ι 8 is electrically connected to the doped region (10) of the 2nd n (for example, The doping region ug_2). The material of the bit line 116 and the bit line 118 is, for example, metal tungsten. Further, the non-volatile memory array may further include a conductive plug 2〇. The conductive plug 120 is placed on the substrate. 1〇〇, used to connect the w 1285416 library 9twf.doc / g doped poor region, such as the doping region ii (M and u 〇 _3) and the bit line 2n 唬 doped region 110 (for example, doping Miscellaneous region 1102) and bit line 118. Example of material of conductive plug 12〇 Such as polycrystalline germanium.

在上述非揮發性記憶體陣列中,每—個記憶體單元 可分為位於各字元線114_的—個第_記憶胞叫 =一個第二記憶胞m_2。第—記憶胞124]與第二記憶胞 M-2共用一條字元線114、一個摻雜區1〇8與一個複合層 :12 ’而相鄰二個第一記憶胞124]共用一個第μ號的 杉雜區ιιο(例如是掺雜區11(M或11〇_3),而相鄰二個第 二記憶胞124-2共用一個第2n號的第二摻雜區丨丨〇(例如是 摻雜區ιι〇2)。亦即,將摻雜區110連接到位元線116的 記憶胞定義為第一記憶胞^44,將摻雜區11〇連接到位 元線116的記憶胞定義為第二記憶胞124-2。 在上述的非揮發性記憶體結構具有垂直的記憶胞結 構’為單一記憶胞二位元的非揮發性記憶體結構。此外, 非揮發性記憶體結構的同一記憶胞行122中,因為具有分 離的位元線116及位元線118,可同時對同一個記憶體單 元中的二個記憶胞進行程式化/讀取/抹除操作。 圖3所繪示為依照本發明一實施例之非揮發性記憶體 的電路圖。 請參照圖3,本發明所提出的非揮發性記憶體陣行包 括字元線WL1〜WL4、源極線SL1〜SL4、位元線BL1〜BL8 及記憶體單元Mil〜M44。記憶體單元Mil〜M44以陣列的 方式排列,Ml 1 〜M14、M21 〜M24、M31 〜M34、M31 〜M34、 12 8 5 41蜂9twfcloc/g 各組成一心):¾胞行,Mil〜M41、M12〜M42、M13〜M43、 M14〜M44各組成一記憶胞列。每一記憶體單元的結構如 上述圖2所示,例如是具有閘極、源極區、二汲極區及電 荷儲存層。 其中,字元線WL1〜WL4沿著一 χ_γ平面中γ的方 向延伸’ Υ的方向例如是記憶體陣列中列的方向,X的方 向例如是記憶體陣列中行的方向,字元線WL1〜WL4分別 用以連接同一記憶胞列的記憶體單元之閘極。舉例來說, 字元線WL1用以連接Mil〜M41之閘極,依此類推,字元 線WL2、WL3、WL4分別用以連接M12〜M42、M13〜M43、 M14〜M44之閘極。 源極線SL1〜SL4沿著Y的方向延伸,源極線SL1〜SL4 分別用以連接同一記憶胞列的記憶體單元之源極區。舉例 來說’源極線SL1用以連接Mil〜M41之源極區,依此類 推’源極線SL2、SL3、SL4用以連接M12〜M42、M13〜M43、 M14〜M44之源極區。 位元線BL1〜BL8以二條位元線為一組,如位元線bli 及BL2為一組’沿著X的方向進行延伸。在同一記憶胞行 中,將汲極區沿行的方向編號,可分為第2η-1號及第2n 號,η為大於等於1的整數。在位元線bli及BL2所組成 的位元線組中,位元線BL1連接Ml 1〜M14所組成之記憶 胞行中第2n-l號的汲極區,位元線BL2連接記憶胞行中 第2n號的汲極區。依此類推,位元線bl3及BL4為一位 元線組、位元線BL5及BL6為一位元線組、位元線BL7 20 12854 l^^twf.doc/g =中為第一=組。這些位元線組分別連接撕^ d灯中弟2η·1 #b的汲極區及第%號的沒極區。 f下來,將以圖3中的記憶體單元Mu及體為例, 、=本發明之鱗發性記龍的操作方法。由於在操作方 法:源極線及位几線的定義會因為所要操作的位元是上 元:有所不同,所以在以下說明中,將源極線 su〜SL4通稱為導線SL1〜SL4,位元線bli〜bl 導線BU〜BL8,以便免造成混淆。 轉马 圖= 〜圖7所繪示為本發明—實施例之程式化操作的示 思^圖8〜圖11崎示為本發明—實施例之讀取操作的 圖12崎示為本發明-實施例之抹除操作的示意 ,圖4〜圖10的非揮發性記憶體結構已在圖2及圖3中 评述,於此不再贅述。 ~ 先’請麥照圖4 ’對選定的記憶體單元Mil的第-A之上位元進行程式化操作時,於所對應的導線 第一電壓’例如是5伏特,於選定之第-記憶 月^的導線SL1施加-第二電壓,例如是Q伏特,於選定 的字讀wu施加—第三電壓,例如是 # %壓大於第二電壓,崎式化選定的第 =¼胞^上位心第三電壓大於第—記憶胞A之臨界 =°2同日1’可,基底_上及其它綠選定的記憶體單 請參照圖5,對選定之記憶體單元簡的第二記憶胞 21 12854 Μ99—,8 β之上位元進行程式化操作時,於所對應的導線BL2施加 一第七電壓,例如是5伏特,於選定之第二記憶胞b的導 線SL1施加一第八電壓,例如是〇伏特,於選定之第二記 憶胞B的字元線WL1施加一第九電壓,例如是12伏特, 其中第七電壓大於第八電壓,以程式化選定的第二記憶胞 B之上位元,第九電壓大於第一記憶胞a之臨界電壓。同 日才’可在基底1〇〇上及其它未被選定的記憶體單元M12之 子元線WL2、導線BL1及導線SL2上施加一個〇伏特的 電壓。 ^請參照圖6,同時對選定之記憶體單元Mil的第一記 憶胞A及第二記憶胞B之上位元進行程式化操作時,於所 對應的導線BL1及BL2施加一第十五電壓,例如是5伏 特胃’於選定之記憶體單元Mil的導線SL1施加一第十六 電壓,例如是0伏特,於選定之記憶體單元Mn的字元線 WL1施加一第十七電壓,例如是12伏特,其巾第十五電 壓大於第十六電壓,以程式化選定的第—記憶胞A及第二 e己k、胞B。同時,可在基底⑽上及其它未被敎的記憶 體單元M12之字元線WL2及導線su上施加一個〇伏特 的電壓。 請夢照@ 7 ’ J5]時對選定之記憶體單元MU的第一記 憶胞A及第二記憶胞β之下位元進行程式化操作時,於所 對應的導線BL1及BL2施加一第十六電壓,例如是〇伏 特:於選定之記憶體單元M11的導線su施加一第十五 電壓’例如是5伏特’於選定之記憶體單元Mn的字元線 22 12854 WU施加—第十七電壓,例如是12伏特,以程式化選定 的第-疏胞A及第二記憶胞B之下位元。同時,可在基 底1〇〇上及其它諸敎的記憶料元Mi2 ^ WL2及導線SL2上施加—㈣伏特的電壓。之子兀線 請參照圖8,對選定的# ,陰辨留_In the above non-volatile memory array, each memory cell can be divided into a first _ memory cell located at each word line 114_ = a second memory cell m_2. The first memory cell 124 shares a word line 114, a doped region 1〇8 and a composite layer with the second memory cell M-2: 12' and the adjacent two first memory cells 124 share a μμ No. 1 of the dolo area (for example, doped region 11 (M or 11 〇 _3), and two adjacent second memory cells 124-2 share a second doped region 第 of the 2nd (for example) Is a doped region ιι〇2). That is, the memory cell connecting the doped region 110 to the bit line 116 is defined as a first memory cell 44, and the memory cell connecting the doped region 11A to the bit line 116 is defined as The second memory cell 124-2. The non-volatile memory structure described above has a vertical memory cell structure' as a non-volatile memory structure of a single memory cell. In addition, the same memory of the non-volatile memory structure In the cell row 122, since there are separated bit lines 116 and bit lines 118, two memory cells in the same memory cell can be simultaneously programmed/read/erase. Figure 3 is A circuit diagram of a non-volatile memory according to an embodiment of the present invention. Referring to FIG. 3, the non-volatile memory proposed by the present invention The array includes word lines WL1 to WL4, source lines SL1 to SL4, bit lines BL1 to BL8, and memory cells Mil to M44. The memory cells Mil to M44 are arranged in an array, M1 1 to M14, M21 〜 M24, M31 ~ M34, M31 ~ M34, 12 8 5 41 bees 9twfcloc / g each component one heart): 3⁄4 cell line, Mil~M41, M12~M42, M13~M43, M14~M44 each constitute a memory cell. The structure of each memory cell is as shown in Fig. 2 above, for example, having a gate, a source region, a dipole region, and a charge storage layer. The direction in which the word lines WL1 WL WL4 extend along the direction of γ in a χ γ plane is, for example, the direction of the columns in the memory array, and the direction of X is, for example, the direction of the rows in the memory array, and the word lines WL1 WL WL4 The gates of the memory cells used to connect the same memory cell column. For example, the word line WL1 is used to connect the gates of Mil to M41, and so on, the word lines WL2, WL3, and WL4 are used to connect the gates of M12 to M42, M13 to M43, and M14 to M44, respectively. The source lines SL1 to SL4 extend in the Y direction, and the source lines SL1 to SL4 are respectively connected to the source regions of the memory cells of the same memory cell. For example, the source line SL1 is used to connect the source regions of Mil to M41, and the source lines SL2, SL3, and SL4 are connected to connect the source regions of M12 to M42, M13 to M43, and M14 to M44. The bit lines BL1 to BL8 are grouped by two bit lines, and the bit lines bli and BL2 are a group 'extending in the direction of X. In the same memory cell row, the drain regions are numbered in the direction of the row, and can be divided into 2n-1 and 2n, and η is an integer greater than or equal to 1. In the bit line group formed by the bit lines bli and BL2, the bit line BL1 is connected to the second n-1th bungee region in the memory cell line composed of M1 1 to M14, and the bit line BL2 is connected to the memory cell line. The bungee area of No. 2n. And so on, the bit lines bl3 and BL4 are one bit line group, the bit lines BL5 and BL6 are one bit line group, and the bit line BL7 20 12854 l^^twf.doc/g = medium first = group. These bit line groups are respectively connected to the bungee region of the 2nd·1 #b of the tearing lamp and the non-polar zone of the %th. f down, taking the memory unit Mu and the body in Fig. 3 as an example, = the operation method of the scaly dragon of the present invention. Since the operation method: the definition of the source line and the bit line will be different because the bit to be operated is the upper element: in the following description, the source lines su to SL4 are collectively referred to as the wires SL1 to SL4. Line bli~bl wire BU~BL8 to avoid confusion. FIG. 7 is a schematic view of a stylized operation of the present invention. FIG. 8 to FIG. 11 are diagrams showing a read operation of the present invention. FIG. The non-volatile memory structure of FIG. 4 to FIG. 10 has been reviewed in FIG. 2 and FIG. 3, and the details are not described herein again. ~ First 'Please Mai Zhao Figure 4' When the stylized operation of the upper-A bit of the selected memory cell Mil is performed, the first voltage of the corresponding wire is, for example, 5 volts, in the selected first-memory month. The wire SL1 is applied - the second voltage, for example Q volts, is applied to the selected word wu - the third voltage, for example, the # % voltage is greater than the second voltage, and the selected first =1 ^ ^ ^ ^ The three voltages are greater than the critical value of the first memory cell A = °2 on the same day 1', the base_upper and other green selected memory banks please refer to Figure 5, the second memory cell of the selected memory cell is simple 21 12854 Μ99- When the bit above 8β is programmed, a seventh voltage is applied to the corresponding wire BL2, for example, 5 volts, and an eighth voltage is applied to the wire SL1 of the selected second memory cell b, for example, volts. Applying a ninth voltage to the word line WL1 of the selected second memory cell B, for example, 12 volts, wherein the seventh voltage is greater than the eighth voltage to program the selected second memory cell B above the bit, ninth The voltage is greater than the threshold voltage of the first memory cell a. On the same day, a voltage of 〇V can be applied to the sub-line WL2, the line BL1 and the line SL2 of the other unselected memory cells M12. Referring to FIG. 6, when the first memory cell A and the second memory cell B of the selected memory cell Mil are programmed, a fifteenth voltage is applied to the corresponding wires BL1 and BL2. For example, a 5 volt stomach applies a sixteenth voltage to the wire SL1 of the selected memory cell Mil, for example, 0 volts, and a seventeenth voltage is applied to the word line WL1 of the selected memory cell Mn, for example, 12 Volt, the fifteenth voltage of the towel is greater than the sixteenth voltage, to program the selected first memory cell A and the second e k, cell B. At the same time, a voltage of 〇V can be applied to the substrate (10) and other word lines WL2 and wires su of the uncharged memory cell M12. Please perform a stylized operation on the corresponding memory cells BL1 and BL2 of the selected memory cell MU when programming the @7' J5] The voltage, for example, volts: a fifteenth voltage 'for example, 5 volts' is applied to the wire su of the selected memory cell M11, and the word line 22 12854 WU of the selected memory cell Mn is applied - the seventeenth voltage, For example, 12 volts to programmatically select the selected first-small cell A and the second memory cell B. At the same time, a voltage of - (four) volts can be applied to the memory cell Mi2^WL2 and the wire SL2 on the substrate 1 and other cells. The son of the line, please refer to Figure 8, for the selected #, 阴辨留_

Hfrn〜 體70 的第—記憶胞Hfrn~ body 70 first memory cell

=之亡位兀進仃魏操作時,於選定之第—記憶胞A 應的導線BL1施加—第四電壓,例如伏特,於之 第一記憶胞A的導绫ST 1竑如馀τ不同、 、、疋之When the dead bit is in the Wei operation, a fourth voltage, such as volt, is applied to the selected wire BL1 of the first memory cell A, and the first memory cell A has a different guiding parameter ST 1 such as 馀τ. , 疋之之

牲,於、势 弟五電壓,例如是1伏 、疋之弟一圮憶胞A的字元線wu施加一 壓,例如是3伏特,其中第四電壓小於第五電壓,第二帝 壓大於第-記憶胞A未程式化前之臨界電壓,小於第一記 憶胞A程式化後之臨界電壓,以讀取選定的第—記情胞^ 體早兀M12之子70線饥2上施加-個〇伏特的電壓,且 於導線BL2施加一個i伏特的電壓。Sacrifice, Yu, the five voltages of the brother, for example, 1 volt, the brother of the 圮 圮 圮 圮 的 的 的 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加 施加The threshold voltage before the first memory cell A is not programmed, is less than the threshold voltage after the stylization of the first memory cell A, to read the selected first sympathetic cell body, the early M12 son 70 line hunger 2 The voltage of volts is applied and a voltage of one volt is applied to the wire BL2.

請參照目9,對選定的記憶體單元Mil的第二記憶胞 B之上位元進行讀取操作時,於選定之第二記憶胞b所對 ,的導線BL2施加一第十電壓,例如是〇伏特,於選定之 第一 δ己k、胞B的導線SL1施加一第十一電壓,例如是i伏 特胃’於選定之第二記憶胞B的字元線wu施加一第十二 電壓,例如是3伏特,其中第十電壓小於第十一電壓,第 十一電壓大於第二記憶胞B未程式化前之臨界電壓,小於 第二記憶胞B程式化後之臨界電壓,以讀取選定的第二記 憶胞B之上位元。同時,可在基底1〇〇上及其它未被選定 23 12 8 3 4 ΐ 伞9twf.d〇c/g 的記憶體單S M12之字元線WL2上施加—個Q伏特的電 壓,且於導線BL2施加一個1伏特的電壓。 請參照圖ίο,同時對選定之記憶體單元Mu的第一 記憶胞A及第二記憶胞B之上位元進行讀取操作時, 對應的導線BL1及BL2施加一第十八電壓,例如是〇伏 特,於選定之記憶體單元M11的導線su施加一第十 電壓’例如是1伏特’於選定之記憶體單元聽的字元線 WL1施加-第二十電壓,例如是3伏特,其中第十八電壓 小於第十九,以讀取選定的第—記憶胞A及第二記情 胞B之上位元。同時,可在基底1〇〇上及1 二 記憶體單元M12之字元線WL2上施加一個〇伏特的電疋壓的 請麥照圖11,同時對選定之記憶體單元Mu 記憶胞A及第二記憶胞B之下位元進行讀取操作時 對應的導線BU及BL2施加—第十九f壓,例如是j 特’於選定之記憶體單元M11的導線su施加一 ❿ 電壓’例如是1伏特,於選定之記憶體單元Mil的字元綠 WL1施加-第二十電壓,例如是3伏特,以讀取選定的第 -記憶胞A及第二記憶胞B之下位元。同時,可在Referring to item 9, when a read operation is performed on the bit cell of the second memory cell B of the selected memory cell Mil, a tenth voltage is applied to the wire BL2 of the selected second memory cell b, for example, 〇 Volt, applying an eleventh voltage to the selected first delta k, cell B wire SL1, for example, i volt stomach 'applies a twelfth voltage to the word line wu of the selected second memory cell B, for example Is 3 volts, wherein the tenth voltage is less than the eleventh voltage, and the eleventh voltage is greater than the threshold voltage before the second memory cell B is unprogrammed, and is smaller than the threshold voltage after the second memory cell B is programmed to read the selected voltage. The second memory cell B is above the bit. At the same time, a voltage of Q volts can be applied to the substrate 1 〇〇 and other word lines WL2 of the memory single S M12 of the unselected 23 12 8 3 4 ΐ umbrella 9 twf.d 〇 c / g, and Wire BL2 applies a voltage of 1 volt. Referring to the figure, when the read operation is performed on the first memory cell A and the second memory cell B of the selected memory cell Mu, the corresponding wires BL1 and BL2 are applied with an eighteenth voltage, for example, 〇 Volt, a tenth voltage 'for example, 1 volt' is applied to the wire su of the selected memory cell M11 to apply a twentieth voltage to the selected word line WL1 of the memory cell, for example, 3 volts, of which tenth The eight voltages are less than the nineteenth to read the selected first memory cell A and the second bit cell B. At the same time, a 〇 特 疋 上 上 上 上 施加 基底 基底 1 1 1 1 1 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定 选定When the bit cell under the memory cell B performs a read operation, the corresponding wires BU and BL2 are applied - the nineteenth f-voltage, for example, j-characterized by applying a voltage to the wire su of the selected memory cell M11, for example, 1 volt. The twentieth voltage, for example, 3 volts, is applied to the character green WL1 of the selected memory cell Mil to read the selected first memory cell A and the second memory cell B lower bit. At the same time, at

上及其它未被選定的記憶體單元M12之字元線ς-上施加一個0伏特的電壓。 L 士凊參照目12,對上述之非揮發性記憶體進行抹除操 日守,於基底1〇〇施加一第十三電壓,例如是12伏 定之記憶體單AMU及題的字元線術及肌2施力1 -弟十四電壓,例如是〇伏特,其中第十三電壓大於第十 24 1285411伞 9twf.d〇c/g 四電壓,以利用F-N穿隧效應對記憶體單元Mil及M12 的弟一 $己憶胞A及第二記憶胞B進行抹除。同時,可對導 線SL1、導線BL1及導線BL2進行浮接(floating),亦即不 施加任何電壓。A voltage of 0 volts is applied to the upper and other unselected memory cells M12. L 士 凊 Refer to item 12, the above non-volatile memory is erased, and a thirteenth voltage is applied to the substrate 1 ,, for example, a 12 volt memory single AMU and a word line And muscle 2 force 1 - brother fourteen voltage, for example, 〇 volt, where the thirteenth voltage is greater than the twenty-fourth 24,854,541 umbrella 9twf.d〇c / g four voltage to use FN tunneling effect on the memory unit Mil and The younger brother of M12 has recalled cell A and second memory cell B for erasure. At the same time, the wire SL1, the wire BL1, and the wire BL2 can be floated, that is, no voltage is applied.

上述對於本發明所提出的非揮發性記憶體所進行之操 作方法,可以對一個選定之記憶體單元的一個記憶胞進行 操作,也可以同時對一個記憶體單元的二個記憶胞進行操 =。除此之外,本發明所提出的非揮發性記憶體所進行之 細作方法更可關時對多個選定之記憶體單元中選定的吃 憶胞進行操作。如此-來,可以更容㈣依照操作需求°, 對記憶體單元進行操作。 综上所述,本發明至少具有下列優點·· 1·本發明的非揮發性記憶體結構,因為具有分離的位 可同時對同_個記憶體單以的二個記憶胞 式化/讀取/抹除操作。 丁布王 •科㈣之非揮發性記憶體的製造方法The above-mentioned operation method for the non-volatile memory proposed by the present invention can operate on one memory cell of a selected memory cell, or can simultaneously operate two memory cells of one memory cell. In addition, the fine-grained method of the non-volatile memory proposed by the present invention can operate on selected memory cells of a plurality of selected memory cells. In this way, it is possible to operate (4) the memory unit according to the operation requirements. In summary, the present invention has at least the following advantages: 1. The non-volatile memory structure of the present invention, because the separated bits can simultaneously align two memory cells with the same memory. / erase operation. Dingbu Wang • Section (4) Non-volatile memory manufacturing method

的字元線、源極線及祕區,能有效]^ 而進一歩縮短生產週期。 I私 3·依照本發明之麵發性 離的位元線,可以更容易地依昭摔作=作f法,利用矣 進行操作。 mi、、、㈣4 ’對記憶體單六 限定揭在露如“ 和範圍内’當可作些許之更:賴不 25 12854 l_99twf d〇c/g 範圍s視後附之申請專利範圍所界定者為準。 【圖式簡單說明】 # 圖1A〜圖1D所繪示為依照本發明一實施例之非揮發 性記憶體的製造流程立體圖。 圖2所繪不為依照本發明一實施例之非揮發性記憶體 的立體圖。 圖3所繪示為依照本發明一實施例之非揮發性記憶體 的電路圖。 圖4〜圖7所繪示為本發明一實施例之程式化操作的示 意圖。 圖8〜圖11所繪示為本發明一實施例之讀取操作的示 意圖。 圖12所繪示為本發明一實施例之抹除操作的示意圖。 【主要元件符號說明】 100 :基底 102 :隔離結構 104 :井區 106 :溝渠 108 ·播雜區(源極線) 110、110-1、110-2、110-3 :摻雜區(汲極區) 112 :複合層 112a、112c :介電層 112b :電荷儲存層 114、WL1〜WL4 :字元線 26 128541499twfdoc/g 116、118、BLl〜BL8 ··位元線(導線) 120 :導電插塞 122 :記憶胞行 124 ··記憶體單元 124-1 :第一記憶胞 124-2 :第二記憶胞 SL1〜SL4 :源極線(導線)The word line, source line and secret area can effectively shorten the production cycle. I Private 3. According to the face line of the present invention, it is easier to use the 矣 method to perform the operation. Mi,,, (4) 4' is limited to the memory of a single six in the "such as the scope of the "and within the scope" can be made a little more: Lai not 25 12854 l_99twf d〇c / g range s as defined by the scope of the patent application BRIEF DESCRIPTION OF THE DRAWINGS [FIG. 1A to FIG. 1D are schematic perspective views showing a manufacturing process of a non-volatile memory according to an embodiment of the present invention. FIG. 2 is not a view of an embodiment of the present invention. FIG. 3 is a circuit diagram of a non-volatile memory according to an embodiment of the invention. FIG. 4 to FIG. 7 are schematic diagrams showing a stylized operation according to an embodiment of the present invention. 8 to FIG. 11 are schematic diagrams showing a read operation according to an embodiment of the present invention. FIG. 12 is a schematic diagram showing an erase operation according to an embodiment of the present invention. [Description of Main Components] 100: Substrate 102: Isolation Structure 104: well region 106: trench 108 · doping region (source line) 110, 110-1, 110-2, 110-3: doped region (drain region) 112: composite layer 112a, 112c: dielectric Layer 112b: charge storage layer 114, WL1 WLWL4: word line 26 128541499twfdoc/g 116, 118 , BL1~BL8 ··bit line (wire) 120: conductive plug 122: memory cell line 124 · memory unit 124-1: first memory cell 124-2: second memory cell SL1~SL4: source Line (wire)

Claims (1)

128541499twfdoc/g 更包括一第二介電層,配置於該電荷儲存層上方。 8·如申請專利範圍第7項所述之非揮發性記憶體單 其中苐一介電層的材質包括氧化石夕。 9·如申请專利範圍第1項所述之非揮發性記憶體單 其中該些導電插塞之材質包括金屬。 一 10.如申請專利範圍帛1項所述之非揮發性記憶體單 兀’其中忒些第-導線及該些第二導線的材質包括金屬鎢。 11·一種非揮發性記憶體陣列,包括·· 基底,忒基底中具有多數個溝渠,該些溝渠為平行 排列,並往列的方向延伸; 多數個記憶胞行,由多數個記憶體單元 記憶體單元包括: hΘ/ :字元線,配置於該麵渠之—中,並延伸於該溝 連接同一列的該些記憶體單元; -,荷儲存層,配置於該字元線與姆渠之間; -第-摻雜區i置於所對應的該溝渠下方的該基 且為同一列的該些記憶體單元所共用; *偏兮:雜區及—第三摻雜區,分別配置於該溝渠 兩側的該基底中; 第&quot;1導線及—第二導線,平行配置於該基底上, 別電性連接於該第二摻雜區及該第三 一弟二導線’配置於該基底,用 雜區;以及 絲上用从連接該第-摻 元 元 元 渠中 底中 29 128541伞twfdoc/g 多數個隔離結構,配置於該基底中,用以隔離該些記 憶胞行,其中 同一行記憶單元所包含之該些第二摻雜區及該些第三 摻雜區係交錯排列,且相鄰之二個記憶體單元係共用該第 二摻雜區或該第三摻雜區之一。 〜 12.如申請專利範圍第11項所述之非揮發性記憶體陣 列,更包括多數個導電插塞,配置於該基底上,分別用以 連該些第二摻雜區與該些第一導線,該些第三摻雜區與該 些第二導線及該些第一摻雜區與該些第三導線。 13·如申請專利範圍第11項所述之非揮發性記憶體陣 列,其中該些隔離結構包括淺溝渠隔離結構。 14·如申請專利範圍第11項所述之非揮發性記憶體陣 列,其中該些導體層的材質例如是摻雜多晶矽。 15·如申請專利範圍第11項所述之非揮發性記憶體陣 列,其中該些電荷儲存層的材質包括氮化矽。 16. 如申請專利範圍第11項所述之非揮發性記憶體陣 列,更包括多數個第一介電層,分別配置於該些電荷儲存 層與該溝渠表面之間。 17. 如申請專利範圍第16項所述之非揮發性記憶體陣 列,其中該些第一介電層的材質包括氧化矽。 18. 如申請專利範圍第11項所述之非揮發性記憶體陣 列,更包括多數個第二介電層,分別配置於該些電荷儲存 層與該字元線之間。 19. 如申請專利範圍第18項所述之非揮發性記憶體陣 12854 li4^9twfd〇c/g 列,其中該些第二介電層的材質包括氧化矽。 20·如申請專利範圍第11項所述之非揮發性記憶體陣 列’其中該些導電插塞之材質包括多晶矽。128541499twfdoc/g further includes a second dielectric layer disposed above the charge storage layer. 8. A non-volatile memory sheet as described in claim 7 wherein the material of the dielectric layer comprises oxidized stone. 9. The non-volatile memory sheet of claim 1, wherein the material of the conductive plug comprises a metal. 10. A non-volatile memory device as claimed in claim 1, wherein the material of the first and second wires comprises metal tungsten. 11. A non-volatile memory array comprising: a substrate having a plurality of trenches in the substrate, the trenches being arranged in parallel and extending in a column direction; a plurality of memory cells being memorized by a plurality of memory cells The body unit comprises: hΘ/: a word line disposed in the channel of the face channel and extending in the groove to connect the memory cells of the same column; - a storage layer disposed on the word line and the channel - the first doped region i is shared by the corresponding memory cells of the same column below the trench; * hemiplegia: hetero region and - third doped region, respectively In the substrate on both sides of the trench; the first &quot;1 wire and the second wire are arranged in parallel on the substrate, and are electrically connected to the second doped region and the third one The substrate is provided with a miscellaneous region; and a plurality of isolation structures are connected to the wire from the bottom of the first-doped elementary channel, and the plurality of isolation structures are disposed in the substrate, for isolating the memory cells. The second doping included in the same row of memory cells The regions and the third doped regions are staggered, and two adjacent memory cells share one of the second doped regions or the third doped regions. The non-volatile memory array of claim 11, further comprising a plurality of conductive plugs disposed on the substrate for connecting the second doped regions and the first a wire, the third doped region and the second wires and the first doped regions and the third wires. 13. The non-volatile memory array of claim 11, wherein the isolation structures comprise shallow trench isolation structures. 14. The non-volatile memory array of claim 11, wherein the conductor layers are made of, for example, doped polysilicon. The non-volatile memory array of claim 11, wherein the material of the charge storage layer comprises tantalum nitride. 16. The non-volatile memory array of claim 11, further comprising a plurality of first dielectric layers disposed between the charge storage layers and the trench surface. 17. The non-volatile memory array of claim 16, wherein the material of the first dielectric layer comprises yttrium oxide. 18. The non-volatile memory array of claim 11, further comprising a plurality of second dielectric layers disposed between the charge storage layers and the word lines. 19. The non-volatile memory array 12854 li4^9twfd〇c/g column of claim 18, wherein the second dielectric layer comprises yttrium oxide. 20. The non-volatile memory array of claim 11, wherein the material of the conductive plugs comprises polysilicon. 21·如申請專利範圍第11項所述之非揮發性記憶體陣 列’其中该些第一導線及該些第二導線的材質包括金屬鎢。 22·—種非揮發性記憶體的製造方法,包括: 提供一基底;21. The non-volatile memory array of claim 11, wherein the first wires and the second wires are made of metal tungsten. 22. A method of making a non-volatile memory, comprising: providing a substrate; 於6亥基底中形成多數個隔離結構,而該些隔離結構為 平行排列,並往一第一方向延伸; 於該基底中形成多數個溝渠,該些溝渠平行排列,並 在一第二方向上延伸,且該第二方向與該第一方向相交; 於該些溝渠下方之該基底中形成多數個第一摻雜區· 於該些溝渠兩側的該基底中形成多數個第二摻雜區 多數個第三摻雜區,在該第—方向上該些第二摻雜區 些第三摻雜區係交錯排列; 〃邊 於该些溝渠内之該基底表面形成多數個電荷儲存眉· 於該基底上形成填滿該些溝渠的多數條字元線;二, 於该基底上形成多數條第一導線及多數條第二導 分別電性連接於該些第二摻雜區與該些第三摻雜區',而」 些第一導線及該些第二導線為平行排列,並往該 4 延伸。 万向 23.如申請專利範圍第22項所述之非揮發性 製造方法,更包括於該基底上形成多數鱗電插塞1的 用以連接該些第二摻雜區與該些第一導線,及該此第== 31 128541^9twf.d〇c/g 雜區與該些第二導線。 24.如申請專利範圍第22項所述之 製造方法,其中形成該些第 H體的 該些第三摻雜區的方法包括離子植人法,摻雜區及 化2方m專概㈣22酬述之神發性記憶μ 些電荷儲存層的材質包括氮化石夕。 製造方ΐ 圍第22顿狀__憶體的 成-第-介電i 電荷儲存層下方與該基底之間形 製造利範圍第26項所述之非揮發性記憶體的 '八中该些第一介電層的材質包括氧化矽。 制、/古8t巾請專利範圍第22項所述之非揮發性記憶體的 ^ / ,更包括於各該電荷儲存層上方與該字元線之間 形成一第二介電層。 门 29·如巾請專利範圍第28賴述之非揮發性記憶體的 方法’其中該些第二介電層的材質包括氧化矽。 !3〇·如申請專利範圍第22項所述之非揮發性記憶體的 方法,其中形成該些字元線的方法,包括: 於該基底上形成一導體材料層,並填滿該些溝渠;以 及 、 移除形成於該些溝渠以外的該導體材料層。 掣乂31·如申請專利範圍第22項所述之非揮發性記憶體的 方法,其中移除形成於該些溝渠以外的該導體材料層 、方去包括化學機械研磨法。 32 128541伞twfdoc/g 32·—種非揮發性記憶體的操作方法,適用於排列成行 /列的一記憶胞陣列,該記憶胞陣列由多數個記憶體單元所 組成,各該記憶體單元包括一字元線,配置於一基底之一 ,渠中,並延伸於該溝渠中,且連接同—列的該些記憶體 單几、一電荷儲存層,配置於該字元線與該基底之間、一 第一摻雜區,配置於所對應的該溝渠下方的該基底中,且 為同列的该些5己丨思體單元所共用、一第二摻摻雜區及一 第三摻雜區,分別配置於該溝渠兩側的該基底中、及一第 一導線及一第二導線,配置於該基底上,沿行的方向延伸, 刀另]氣性連接於$亥弟一摻雜區及該第三摻雜區,且相鄰二 個記憶體單元共用一個第二摻雜區或該第三摻雜區,而每 一記憶體單元包含位於各該字元線兩側的一第一記憶胞與 一第二記憶胞,該非揮發性記憶體的操作方法包括: &gt; #進行程式化操作時,於選定之該第一記憶胞所對應的 ,第一導線施加一第一電壓,於選定之該第一記憶胞的該 ==摻雜區施加一第二電壓,於選定之該第一記憶胞的該 =元線施加一第三電壓,其中該第一電壓大於該第二電 ^以&amp;式化该第一記憶胞之一上位元,該第三電壓大於 該記憶單元之臨界電壓;以及 -兩!^選定之該第一記憶胞所對應的該第一導線施加該第 ΐί壓’於選定之該第—記憶胞的該第—摻雜區施加該第 私壓’於敎之該帛—記憶胞的該字元線施加該第三電 ^以心式化該第一記憶胞之一下位元。 33·如申凊專利範圍第32項所述之非揮發性記憶體的Forming a plurality of isolation structures in the 6-well substrate, wherein the isolation structures are arranged in parallel and extend in a first direction; a plurality of trenches are formed in the substrate, the trenches are arranged in parallel, and in a second direction Extending, and the second direction intersects the first direction; forming a plurality of first doped regions in the substrate under the trenches; forming a plurality of second doped regions in the substrate on both sides of the trenches a plurality of third doped regions, wherein the third doped regions are staggered in the second direction; the plurality of charge storage brows are formed on the surface of the substrate in the trenches a plurality of word lines filling the trenches are formed on the substrate; second, a plurality of first wires are formed on the substrate, and a plurality of second wires are electrically connected to the second doped regions and the The three doped regions ', and the first wires and the second wires are arranged in parallel and extend toward the four. The non-volatile manufacturing method of claim 22, further comprising forming a plurality of scale plugs 1 on the substrate for connecting the second doped regions and the first wires And the first == 31 128541^9twf.d〇c/g miscellaneous area and the second wires. [24] The method of claim 22, wherein the method of forming the third doped regions of the H-th body comprises an ion implantation method, a doping region, and a two-party m The material of the charge storage layer includes the nitrite. Manufactured by the 22nd __ memory of the dynasty-first dielectric i under the charge storage layer and the substrate between the base of the non-volatile memory of the 26th paragraph The material of the first dielectric layer includes yttrium oxide. The / / 8b towel of the non-volatile memory of the 22nd item of the patent scope is further included to form a second dielectric layer between the charge storage layer and the word line. The method of the non-volatile memory of the patent application, wherein the second dielectric layer comprises yttrium oxide. The method of claim 22, wherein the method of forming the word lines comprises: forming a layer of conductive material on the substrate and filling the trenches And removing the layer of the conductor material formed outside the trenches. The method of non-volatile memory according to claim 22, wherein the layer of the conductor material formed outside the trenches is removed to include a chemical mechanical polishing method. 32 128541 Umbrella twfdoc / g 32 - a non-volatile memory operation method, suitable for a memory cell array arranged in rows / columns, the memory cell array is composed of a plurality of memory cells, each of the memory cells including a word line disposed in one of the bases, in the channel, and extending in the trench, and connecting the memory cells of the same column to a single charge and a charge storage layer disposed on the word line and the substrate And a first doped region disposed in the corresponding underlying trench, and shared by the same 5 丨 丨 单元 unit, a second doped region, and a third doped region And a first wire and a second wire respectively disposed on the two sides of the trench, disposed on the substrate, extending in a row direction, and the gas is connected to the gas-doped doping And the third doped region, and the adjacent two memory cells share a second doped region or the third doped region, and each memory cell includes a first pixel on each side of the word line a memory cell and a second memory cell, the method of operating the non-volatile memory </ RTI> &gt;# performs a stylization operation, a first voltage is applied to the first wire corresponding to the selected first memory cell, and a first voltage is applied to the == doped region of the selected first memory cell a second voltage is applied to the = element line of the selected first memory cell, wherein the first voltage is greater than the second voltage and the upper memory of the first memory cell is The third voltage is greater than a threshold voltage of the memory cell; and the first wire corresponding to the first memory cell selected by the first memory cell applies the third voltage to the first doped region of the selected first memory cell Applying the first private voltage to the word line of the memory cell to apply the third circuit to embellish one of the first memory cells. 33. Non-volatile memory as described in claim 32 of the patent scope 33 I2854t 伞twfd〇c/g 操作方法,包括: ▲在進行程式化操作時,於選定之該第二記憶胞所對應 的該第二導線施加—第七電壓,於選定之該第二記憶胞的 該第-摻雜區施加-第^電壓,於選定之該第二記憶胞的 該字兀線施加-第九電壓,其中該第七電壓大於該第八電 f.’以!:式化該第二記憶胞之—上位元,該第九電壓大於 «亥σ己丨思早7〇之臨界電壓;以及33 I2854t Umbrella twfd〇c/g operation method, comprising: ▲ during the stylization operation, applying a seventh voltage to the second wire corresponding to the selected second memory cell, and selecting the second memory cell Applying a voltage to the first doped region, applying a voltage to the ninth voltage of the selected second memory cell, wherein the seventh voltage is greater than the eighth electrical f. The second memory cell, the upper voltage, the ninth voltage is greater than the threshold voltage of 7 σ 丨 丨 早 早 ; 7 ; =選定之該第二記憶胞所對應的該第二導線施加該第 八電壓’於選定之該第二記憶胞的該第—摻雜區施加該第 =電壓’於選定之該第二記憶胞的該字元線施加該第九電 S ’以程式化該第二記憶胞之一下位元。 34.如巾請專利_第%項所述之非揮發性記憶體的 操作方法,包括: 在讀取該第二記憶胞之該上位元時,於選定之該第二 ^1*思胞所對應的该第二導線施加—第十電壓,於選定之該 第^記憶胞的該第-#雜區施加—第十—電壓,於選定之 δ亥第一§己憶胞的該字元線施加—第十二電壓,其中該第十 電£小於3第十-電壓,該第十二電壓大於該第二記憶胞 未程式化前之臨界電壓,掃該第二記憶齡式化後之臨 界電壓;以及 在讀取該第二記憶胞之該下位元時,於選定之該第二 記憶胞所對應的該第二導線施加該第十—電壓,於選定之 該,二記憶胞的該第—摻雜區施加該第十電壓,於選定之 該第二記憶胞的該字元線施加該第十二電壓。 ⑧ 34 12854沖_均 記憶體的 35·如申請專利範圍第32項所述之非揮發性 操作方法,包括: 在項取该第一記憶胞之該上位元時,於選定之該第一 ,憶胞所對應的該第—導線施加—第四電壓,於選定之該 第一記憶胞的該第一摻雜區施加一第五電壓,於選定之該 第一記,胞的該字元線施加-第六電壓,其中該第四電壓 =於該第五電壓’該第六大於該第-記憶胞未程式化 則之以界祕,小於該第—記憶胞程式化後之臨界電壓; 在言買取該第一記憶胞之該下位元時,於選定之該第一 記憶胞所對應的該第一導線施加該第五電壓,於選定之該 第-記憶胞的該第-換雜區施加該第四電壓,於選定之該 第一圮憶胞的該字元線施加該第六電壓。 β 36·如申4專利㈣帛32項所述之非揮發性記憶體的 插作方法’包括在進行抹除操作時,於該基底施加一第十 三電壓,於選定之該記憶體單元的該字元線施加一第十四 ❿ I壓’其中遠第十二電壓大於該第十四電壓,以利用F-N 穿隧效應進行抹除。 35= the second wire corresponding to the selected second memory cell applies the eighth voltage 'the selected first voltage in the first doped region of the selected second memory cell' to the selected second memory cell The word line applies the ninth electric S' to program a lower bit of the second memory cell. 34. The method for operating a non-volatile memory according to the invention of claim 1, wherein: when reading the upper bit of the second memory cell, selecting the second ^1* Corresponding to the second wire, a tenth voltage is applied, and a tenth voltage is applied to the first-# miscellaneous region of the selected memory cell, and the word line of the selected first phase of the memory cell Applying a twelfth voltage, wherein the tenth electric charge is less than the third tenth voltage, the twelfth voltage is greater than a threshold voltage before the second memory cell is unprogrammed, and sweeping the threshold after the second memory ageing a voltage; and when reading the lower bit of the second memory cell, applying the tenth voltage to the second wire corresponding to the selected second memory cell, and selecting the second memory cell The doped region applies the tenth voltage, and the twelfth voltage is applied to the word line of the selected second memory cell. </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; The first wire corresponding to the cell is applied with a fourth voltage, and a fifth voltage is applied to the first doped region of the selected first memory cell, and the word line of the first cell is selected Applying a sixth voltage, wherein the fourth voltage = at the fifth voltage 'the sixth is greater than the first memory cell is not programmed to be a secret, less than the threshold voltage after the first memory cell is programmed; When the lower cell of the first memory cell is purchased, the fifth voltage is applied to the first wire corresponding to the selected first memory cell, and is applied to the first change region of the selected first memory cell. The fourth voltage applies the sixth voltage to the word line of the selected first memory. β 36 · The method for inserting non-volatile memory as described in claim 4 (4) 包括 32 includes applying a thirteenth voltage to the substrate during the erasing operation, and selecting the memory unit The word line is applied with a fourteenth ❿ I voltage, wherein the twelfth voltage is greater than the fourteenth voltage to be erased by the FN tunneling effect. 35
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US6853578B1 (en) * 2002-03-18 2005-02-08 Piconetics, Inc. Pulse driven single bit line SRAM cell
US6853587B2 (en) * 2002-06-21 2005-02-08 Micron Technology, Inc. Vertical NROM having a storage density of 1 bit per 1F2
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US7112490B1 (en) * 2005-07-25 2006-09-26 Freescale Semiconductor, Inc. Hot carrier injection programmable structure including discontinuous storage elements and spacer control gates in a trench
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