TWI281361B - Organic electro-luminescent device with protecting layer - Google Patents
Organic electro-luminescent device with protecting layer Download PDFInfo
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1281361 五、發明說明(1) 5 - 1發明領域: 本發明係關於一種有機電冷光元件(OEL; Organic Electro-Luminescent Device),特別是有關於一種具有 反應活性的保護層之有機電冷光(0EL)元件結構。 5 - 2發明背景: 一般而言, 件,例如,有機 Diode; 0LED) 之間插入一有機 子從陰電極注人 電洞將會在有機 線。此類電冷光 形成有機層之有 因此,對於各種 元件與儀器設備 電冷光(Electro-Luminescent; EL)元 發光二極體(Organic Light Emitting 或是相類似.的構造係為在一對陰陽電極 層(Laminated organic layers) ° 當電 且電洞從陽電極注入至有機層時,電子與 層中互相結合,導致電冷光元件放射出光 元件具有咼亮度與高對比的特性,而且由 ,材質所放射的光線具有多色彩的優點。 貧訊工業而言,電冷光元件可應用於顯示 之發射光源組件上。 〇 迄今,有機電冷夹; 有機電冷光元件在完ώ =件仍存在某些缺陷未予以克服。 特性(亦即發光強产)合1封裝後,在使用初期,其發光 導致此發光性質劣=的=隨著時間呈現巨幅劣化的現象。 ' M t因係由於有機電冷光元件内部殘1281361 V. INSTRUCTION DESCRIPTION (1) 5 - 1 Field of the Invention: The present invention relates to an organic electro-luminescence device (OEL), and more particularly to an organic electro-cooled light (0EL) having a reactive protective layer. ) Component structure. 5 - 2 invention background: In general, a piece, for example, an organic Diode; 0LED) inserts an organic sub-injection from the cathode electrode. The hole will be in the organic line. Such electro-cold light forms an organic layer. Therefore, for various components and instruments, Electro-Luminescent (EL) light-emitting diodes (Organic Light Emitting or similar) are constructed in a pair of yin and yang electrode layers. (Laminated organic layers) ° When electricity and holes are injected from the anode electrode to the organic layer, the electrons and the layers are combined with each other, causing the light-emitting elements to emit light having high brightness and high contrast characteristics, and the material is radiated. Light has the advantage of multi-color. In the poor industry, electric luminescence components can be applied to the display of the emission light source components. 〇 So far, organic electric cold clamps; organic luminescence components are finished ώ = some defects still exist Overcome. Characteristics (that is, luminescence strong) After 1 package, in the initial stage of use, its luminescence causes the luminescence property to be inferior = = a large deterioration phenomenon with time. ' M t due to the internal structure of the organic luminescence element Residual
1281361 五、發明說明(2) 留的水氣及元件外部侵入的水氣所造成。有機電冷光元件 -内的有機薄膜因水氣的吸附而產生潮解,而金屬電極則因 水氣及氧氣的侵入產生氧化作用而劣化。另一方面,當施 加外部電壓於有機電冷光元件的電極上以驅動有機電冷光 元件發光一段時間後,有機電冷光元件會產生熱。如此一 來,更加快劣化的速度,因而造成有機電冷光元件上的暗 點(D a r k s ρ 〇 t)。隨著氧化及潮解作用的進行,暗點會 持續地擴大,甚至危及整個發光元件。 如上所述,必須有效地降低有機電冷光元件之内部殘 $ 留的水氣及元件外部侵入的水氣以防止暗點的產生。現今 採用的方式係在有機電冷光元件外側配置一内含有吸水劑 之封蓋架構(h e r m e t i c s e a 1),以達到長期穩定與提高壽 命的目的,而封蓋的材質通常使用金屬或是玻璃。參考第 一圖所示,傳統之有機電冷光裝置100包含:一基板110, 且基板11 0下方連接一有機電冷光元件1 2 0 ; —封蓋1 3 0, 封蓋架構1 3 0之底部具有一吸水劑1 4 0,其中,封蓋1 3 0具 有一蓋緣1 5 0,蓋緣1 5 0係藉由一粘著劑1 6 0與基板11 0相連 ❸ 然而,上述之封蓋結構仍有一些問題存在。由於此結 構中必須挪出相當的空間以置放吸水劑,因此,封蓋結構 與有機電冷光元件之間存在一定的空間,此空隙中仍包含 了含有水氣與氧氣之空氣。再者,傳統有機電冷光元件之1281361 V. INSTRUCTIONS (2) caused by moisture and water intrusion from the outside of the component. Organic electric luminescence element - The organic film inside is deliquescent due to the adsorption of moisture, and the metal electrode is degraded by the oxidation of moisture and oxygen. On the other hand, when an external voltage is applied to the electrodes of the organic electroluminescent element to drive the organic electroluminescent element to emit light for a while, the organic electroluminescent element generates heat. In this way, the speed of deterioration is accelerated, thereby causing dark spots (D a r k s ρ 〇 t) on the organic electric luminescence element. As oxidation and deliquescence progress, the dark spots continue to expand, even jeopardizing the entire illuminating element. As described above, it is necessary to effectively reduce the moisture remaining in the internal residual portion of the organic electric luminescence element and the moisture intruded outside the element to prevent generation of dark spots. Nowadays, a cover structure (h e r m e t i c s e a 1) containing a water absorbing agent is disposed outside the organic electroluminescent element to achieve long-term stability and life improvement, and the material of the cover is usually metal or glass. Referring to the first figure, the conventional organic electro-optic device 100 includes: a substrate 110, and an organic electric cooling element 1 2 0 is connected under the substrate 11 0; a cover 1 3 0, a bottom of the cover structure 1 3 0 There is a water absorbing agent 140, wherein the cover 130 has a cover edge 150, and the cover edge 150 is connected to the substrate 11 by an adhesive 160. However, the cover is as described above. There are still some problems with the structure. Since a considerable amount of space must be removed in the structure for the water absorbing agent, there is a space between the capping structure and the organic electroluminescent element, and the air containing oxygen and oxygen is still contained in the gap. Furthermore, the conventional organic electric luminescence element
第7頁 1281361 五、發明說明(3) 封裝結構所使用的粘著劑亦具有透水性(約為〇 · 2% )。 因此,隨著使用時間的增加’含有水氣與氧氣之外部空氣 仍會經由粘著劑而滲透至封裝結構内部之空隙中。另一方 面,有機電冷光元件1 2 0的電子傳導狀態在理想狀況下應 僅止於有機電冷光元件1 2 0内部各層之間,然而,實際上 卻會經由陰極層逸漏部分電子而導致漏電流的問題。針對 此點,傳統的方式係在有機電冷光元件1 2 0的最上層結構 上添加一無機鈍化層(passivati〇n Layers)以防止上述 之問題然而’由於無機層材質之硬度較高,經過沉積製Page 7 1281361 V. INSTRUCTIONS (3) The adhesive used in the package structure also has water permeability (about 〇 · 2%). Therefore, as the use time increases, the outside air containing moisture and oxygen still penetrates into the voids inside the package structure via the adhesive. On the other hand, the electron conduction state of the organic electroluminescent element 120 should ideally only terminate between the layers inside the organic electroluminescent element 120, however, actually, some electrons are leaked through the cathode layer. Leakage current problem. In this regard, the conventional method is to add an inorganic passivation layer on the uppermost structure of the organic electroluminescent element 120 to prevent the above problem. However, due to the high hardness of the inorganic layer material, deposition is performed. system
程後,有機電冷光元件i 2 〇之有機層及其陰極間的薄膜接 合^面將因應力的作用而部分分離,使得接觸面劣化,進 而導致,子注^的效率變差,進一步造成發光元件之發光 特t的劣化。鑒於上述之種種原因,我們更需要一種新的 有機電冷光元件之結構,以便於提昇有機電冷光元件之發 光特性與使用期限。 5 - 3發明目的及概述:After the process, the film bonding surface between the organic layer of the organic electroluminescent element i 2 and the cathode thereof is partially separated by the action of stress, so that the contact surface is deteriorated, thereby causing the efficiency of the sub-injection to be deteriorated, further causing the light emission. The deterioration of the light-emitting characteristics of the element. In view of the above various reasons, we need a new structure of an organic electric luminescence element to improve the illuminating characteristics and service life of the organic luminescence element. 5 - 3 Purpose and overview of the invention:
,立-於上述之發明背景中,傳統有機電冷光元件之結構 罐2所產生的諸多缺點,本發明提供一具有反應活性的保 $ S之有機電冷光元件的結構可用以克服傳統結構上的問In the above-mentioned background of the invention, the conventional organic electroluminescent element has many disadvantages caused by the structural can 2, and the present invention provides a structure of a reactive organic electrocooling element which can be used to overcome the conventional structure. ask
第8頁 1281361 五、發明說明(4) 本發明主要的目 |構。本發明能藉由一 元件之結構應力的問 各薄膜間接合介面不 |具有反應活性的保護 法,藉此可更有效地 封蓋與有機電冷光元 能增加有機電冷光元 。所以,本發明的方 方法能適用於光電及 的係在提彳卩一 有機介電層的〗!機電冷*元件的結 題,藉此可避降低有機電冷光 佳之問題。此外,::冷光元件内部 層的形成以取代傳统:f :藉由- f接保護有機電冷光元件,且 件之間娇六—„ 且r減少 ]所存在的空隙。因此,本於明 件的使用壽命以及降低製 x 法歆釣μ A 叹降低ι知的複雜性 丰3 ί付合經濟上的效益。據此,本 + ¥體7L件之技術中。 為了達到以上所 機電冷光元件之結構 少包含 :一基 與基板之一表 -與基 1結於有 -形成 係為一 ;一黏 著劑將 光元件 板相連 機層之 於有機 底蓋與 著劑, 其蓋緣 密封於 板;一 面相連 結之陽 上的陰 介電層 一蓋緣 黏著劑 連結於 其中。 層 述之目的 。本發明 有機電冷 結,其中 極、一與 才虽、一形 上的保護 所組成以 係位於蓋 基板上之 ,本發明 之有機電 光元件, ,有機電 陽極相連 成於陰極 盆 容納有機 緣上,且 預定連接 揭不了 * 冷光元件 有機電冷 冷光元件 結之有機 上的有機 狀封蓋, 電冷光元 盆狀封蓋 處,並將 種新的有 的結構至 光元件係 至少包含 層、一連 介電層與 盆狀封蓋 件於其中 可It由黏 有機電冷Page 8 1281361 V. INSTRUCTIONS (4) The main purpose of the present invention. The present invention can provide a reactive protection method by the structural stress of a component, whereby the organic electrocooling element can be more efficiently encapsulated and organically cooled. Therefore, the method of the present invention can be applied to the electro-optical system of the organic dielectric layer. The problem of electromechanical cold* components can avoid the problem of good organic cooling. In addition, the formation of the inner layer of the luminescent element replaces the conventional: f: the organic electrocooling element is protected by the -f connection, and the gap between the pieces is 6% and r is reduced. Therefore, the present invention The service life and the reduction of the x method of fishing μ A 降低 降低 ι ι ι ι ι ι 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 The structure comprises: one of the base and one of the substrate - the base 1 is formed - the one is formed; an adhesive connects the optical component plate to the organic bottom cover and the agent, and the cover edge is sealed to the plate; An insulating layer on the side of the anode is connected to the capping adhesive. The purpose of the layering is the organic electrocooling junction of the present invention, wherein the pole, the one and the other are formed by the protection of the shape. On the cover substrate, the organic electro-optical element of the present invention, the organic electro-anode is connected to the cathode pot to accommodate the organic edge, and the predetermined connection is not removed. * The organic-like organic cover of the cold-light element organic electric cold-cooling element is Closure element at the cold basin, and the kinds of the new structure to the optical element comprises at least a layer with a line, a series of dielectric layers and the closure member to a tub in which a sticky organic It Cold
I28l361 ------------ 五、發明說明(5) 5 ~ 4發明的詳細說明: 構 本發明在此所探討的方向為一稽 為了能徹底地瞭解本發明,將在 '電 > 光凡件之結 盡的牛_々曰士 /土处姓 、 下列的描述中提出詳 的步驟或疋70件結構。顯然地,本 於车道祕- /4·、4+益4* ^月的施<丁並未限疋 導體几件之技藝者所熟習的特殊細 所周知的製程步驟或是元件姓構卄 μ ., 叶、、,口稱並未描述於细笳φ,以僻 免造成本發明不必要之限制。太八_ k ^ 鲈汁1 Μ人 制本發明的較佳實施例會詳細 描逑如下,然而除了這必詳 、< ,, 一平"、田彳田逃之外,本發明還可以廣 泛地施行在其他的實施例中,& 、 i p; ^ ^ ^ ^ ^ 儿本發明的範圍不受限定, 乂之後的專利範圍為準。 ^考第二圖所示’在本發明之第一實施例中,首先提 供基板2 0 0,其+,基板2〇〇至少包含一透明材質,例如 f璃板連、”。於基板2 0 0之-表面上的有機發光元件 210’有機發光元件21〇的結構至少包含:一第一電極層 ϋ’例如.:—ITQ層’第—電極層220係連結於基板2 0 0之 一表面上;一有機層23〇,有機層23〇係連結於第一電極層 2電極層24°,第二電極層240係連結於有機 曰右嬙呙ΜπΓ ^生成(C〇nf〇rmati〇n)於第一電極層2 2 0蹦 、有機層23 0與第二带和^ 250,例如,一聚:::上40的四周表面上之有機介電層 件謂封於其Π:機介電層25°可將有機發光元 $ @ MO# P芸认+其與外界絕緣;一保護層2 6 0,保 §又層覆盍於有機介電層250上以形成有機電冷光元件I28l361 ------------ V. Description of the invention (5) Detailed description of the invention of 5~4: The direction of the invention discussed herein is a syllabus in order to thoroughly understand the present invention, 'Electricity' _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Obviously, this is a well-known process step or component surname that is familiar to the craftsmen of the conductors of the conductors - 4, 4, 4, and 4 months. μ , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , The present invention can be described in detail below, but in addition to this must, <,, a flat " In other embodiments, &ip; ^ ^ ^ ^ ^ The scope of the present invention is not limited, and the scope of the following patents will prevail. ^In the first embodiment of the present invention, in the first embodiment of the present invention, first, a substrate 200 is provided, and +, the substrate 2A includes at least one transparent material, such as a glass plate, "on the substrate 2 0. The structure of the organic light-emitting element 210' on the surface of the organic light-emitting element 210' includes at least: a first electrode layer ϋ', for example: -ITQ layer, the first electrode layer 220 is connected to one surface of the substrate 200 An organic layer 23〇, the organic layer 23 is connected to the first electrode layer 2 electrode layer 24°, and the second electrode layer 240 is coupled to the organic layer 曰π嫱呙Μ ^ generation (C〇nf〇rmati〇n) The organic dielectric layer on the peripheral surface of the first electrode layer 2 2 0 蹦, the organic layer 23 0 and the second strip and 250, for example, a poly::: 40 is encapsulated in the Π: machine dielectric The layer 25° can illuminate the organic light-emitting element $@MO# P+ and is insulated from the outside; a protective layer 260, which is further layered on the organic dielectric layer 250 to form an organic electric luminescent element
苐10頁 1281361 五、發明說明(6) ^-- -- ,其中,保濩層2 6 0至少包含一具有反應活性之材質,以 吸收外界之水氣、^氣或是揮發性有機溶劑等物質,且具 有反應活性之材質更包含-功函數小於4之元素,例如, ?金私入IA)或鹼土族(j IA); 一盆狀封蓋27〇,盆狀封 ΐ 係猎由一 Ϊ蓋與蓋緣所組成之凹槽結構,且盆狀封 f 可藉由黏著劑將其蓋緣連結於基板2 0 0上之預定連接 處,其中,盆狀封蓋m之材質至少包含金屬或是玻璃。 供一 ί:ΐ f ^所*,在本發明之第二實施例中,首先提 ^ 一 # & ΐ =女〇 ’例如,破璃板。一連結於透明基板3 0 0 至人:一 μ機發光兀件3 1 0,有機發光元件3 1 0的結構 明二=^以一弟#一電極層32〇,第一電極層320係連結於透 ,板3 0 0之一表面上,且第一電極層32〇至少包含一〖το A中一:Γ〇,有機層3 3 0係連結於第-電極32°上, 電子傳ίΪ 至少,含-電洞傳導層、-發光層與- 4 : I ^ 340, ^ , r。-共形生成於第-^ 極層340的四周+ + π β0與弟一電 可將有機發光元;31。密封:有機介電層350 電層3_材質至少包含= ,有機介 :ΐ :。—盆狀封蓋3 6 0 ’盆狀封蓋3 6 0係為藉I?之底有蓋機斑 -緣所組成之凹槽結構’且盆狀封蓋36〇可藉由由一黏底著盖劑、苐 10 pages 1281361 V. Description of the invention (6) ^-- -- , wherein the protective layer 210 contains at least one reactive material to absorb external moisture, gas or volatile organic solvents. The material, and the reactive material, further contains an element with a work function less than 4, for example, gold IA or alkaline earth (j IA); a potted cover 27 〇, potted seal a groove structure formed by the lid and the lid edge, and the basin seal f can be joined to the predetermined joint on the substrate 2000 by an adhesive, wherein the material of the pot cover m comprises at least metal Or glass. For a second embodiment of the present invention, first, a # & ΐ = 〇 ', for example, a glass plate. A structure is connected to the transparent substrate 300 to the human: a micro-light-emitting device 3 1 0, and the structure of the organic light-emitting element 3 1 0 is a second electrode, and the first electrode layer 320 is connected. On the surface of one of the plates 300, and the first electrode layer 32〇 contains at least one of ττ A: Γ〇, the organic layer 333 is connected to the first electrode 32°, and the electrons are at least 电子, containing - hole conducting layer, - luminescent layer with - 4 : I ^ 340, ^ , r. - Conformal generation on the periphery of the -th electrode layer 340 + + π β0 and the second electron can be an organic light-emitting element; Seal: organic dielectric layer 350 electrical layer 3_ material contains at least =, organic media: ΐ:. - Basin-shaped cover 3 6 0 'The basin-shaped cover 306 is a groove structure composed of a plaque-edge of the bottom of the I? and the basin-shaped cover 36 can be made by a sticky bottom Covering agent,
1281361 一 - - 五、發明說明(7) ’例如’一 UV聚合膠,將其蓋緣連結於透明基板3 〇 〇上之 預定連接處,其中,盆狀封蓋3 6 0之材質至少包含金屬或 是玻璃。一吸水劑37 0,吸水劑3 7 0係容納於盆狀封蓋360 之底蓋上,其中,吸水劑3 7 0至少包含一磷氧化物,例如 ,P205( phosohorus pentoxide) 〇 參考第四A圖至第四C圖所示,在本發明之第三實施例1281361 一 - - 5. Description of the invention (7) 'For example, a UV polymer adhesive, the cover edge is joined to a predetermined joint on the transparent substrate 3, wherein the material of the basin cover 360 is at least metal Or glass. A water absorbing agent 370, the water absorbing agent 307 is contained on the bottom cover of the basin cover 360, wherein the water absorbing agent 370 includes at least a phosphorus oxide, for example, P205 (phosohorus pentoxide) 〇 reference fourth A 3 to C, in the third embodiment of the present invention
中’首先提供一玻璃基板400。然後,一第一電極層410A 形成於玻璃基板4 0 0上,其中,第一電極層4 1 〇 A至少包含 一透明電極層,例如,I T0層。接著,形成且定義複數個 光阻層4 2 0於第一電極層4 1 0 A上。其次,藉由複數個光阻 層4 2 0當成複數個姓刻罩幕進行一餘刻製程,以便於钱刻 第一電極層410A直到玻璃基板40 0為止,並定義出複數個 第一電極區4 1 0 B。在去除複數個光阻層4 2 0之後,形成且 覆蓋一有機層43 0於複數個第一電極區410 B與玻璃基板400 上。隨後’形成一第二電極層4 4 0,例如,一金屬電極層 ,於有機層430上以當成一陰極層,其中,每一個第一 ^ 極區410B與其上連接之有機層43〇與第二電極層44〇可定義 為一個有機發光元件45 0。接著,共形生成一有機介電層 4 6^於第二電極層44 〇的表面上,其中,有機介電層46〇的 材夤至少包含一具有分子量約低於丨〇 〇 〇之有機化合物或是 聚合物’且有機介電層4 6 〇的形成方法至少包含一物理氣 相沉積法(Physical Vapor Deposition; PVD)。隨後, 共形生成一保護層470於有機介電層46 0的表面上以形成複First, a glass substrate 400 is provided. Then, a first electrode layer 410A is formed on the glass substrate 400, wherein the first electrode layer 4 1 〇 A includes at least one transparent electrode layer, for example, an ITO layer. Next, a plurality of photoresist layers 410 are formed and defined on the first electrode layer 4 1 0 A. Secondly, a plurality of photoresist layers are used as a mask to perform a process of engraving, so as to engrave the first electrode layer 410A until the glass substrate 40 0, and define a plurality of first electrode regions. 4 1 0 B. After removing the plurality of photoresist layers 420, an organic layer 430 is formed over the plurality of first electrode regions 410B and the glass substrate 400. Subsequently, a second electrode layer 410 is formed, for example, a metal electrode layer on the organic layer 430 to form a cathode layer, wherein each of the first electrode regions 410B is connected to the organic layer 43 and the first The two electrode layer 44A can be defined as one organic light emitting element 45 0 . Next, an organic dielectric layer is formed on the surface of the second electrode layer 44 ,, wherein the material of the organic dielectric layer 46 夤 comprises at least one organic compound having a molecular weight of less than about 丨〇〇〇 The method of forming the polymer and the organic dielectric layer 4 6 至少 includes at least one physical vapor deposition (PVD). Subsequently, a protective layer 470 is formed on the surface of the organic dielectric layer 46 0 to form a complex
第12頁 1281361 五、發明說明(8) 數個有機電冷光元件,其中,保護層4 7 0的形成方法至少 包含一物理氣相沉積法(PVD),而保護層47〇的材質至少 包含一具有功函數小於4之固態化合物的反應活性材料, 例如,鹼金族(ϊ A)氧化物或鹼土族(丨丨A)氧化物。最 後,藉由黏著劑將一盆狀封蓋4 8 0之蓋緣連結於基板4 〇 〇上 之預定連接處,以密封複數個有機發光元件45 0及其上之 有機介電層46 0與保護層47 0 (亦即複數個有機電冷光元件 ^於盆狀封蓋4、8〇内部,其中,盆狀封蓋48〇係為藉由一底 盍與蓋緣所組成之凹槽結構,且盆狀封蓋4 8 〇之材質至少 包含金屬或是玻璃。 如上所 機介電層的 藉此可避免 佳之問題。 層的形成以 保護有機電 間所存在的 使用壽命以 方法能夠符 及半導體元 例中 光元 各薄 由一 的方 封蓋 能增 複雜 此, 述,在 形成以 有機電 此外, 取代傳 冷光元 空隙。 及減少 合經濟 件之技 本發明 降低有 冷光元 本發明 、统貼附 件,且 因此, 其製造 上的效 術中。 μ ^ 機電冷 件内部 也能藉 吸水劑 可減少 本發明 過程的 益。據 件之内 膜之間 具有反 法,藉 與有機 加有機 性。所 本方法 明能藉 部結構 的接合 應活性 此可更 電冷光 電冷光 以,本 能適用 由一有 應力, 介面不 之保護 有效地 元件之 元件的 發明的 於光電 元件的結構上,也 ’本發明藉由保護 當然,本發明可能用在有機電冷 可能用在任何發光元件的結構上。而Page 12 1281361 V. Description of the Invention (8) A plurality of organic electroluminescent elements, wherein the formation method of the protective layer 470 includes at least one physical vapor deposition (PVD), and the material of the protective layer 47 至少 includes at least one A reactive material having a solid compound having a work function of less than 4, for example, an alkali gold (ϊ A) oxide or an alkaline earth (丨丨A) oxide. Finally, a cover edge of a pot-shaped cover 4805 is bonded to a predetermined joint on the substrate 4 by an adhesive to seal the plurality of organic light-emitting elements 45 0 and the organic dielectric layer 46 0 thereon. The protective layer 47 0 (that is, a plurality of organic electric luminescence elements) are inside the basin-shaped cover 4, 8 ,, wherein the basin-shaped cover 48 is a groove structure composed of a bottom rim and a cover edge. And the material of the pot-shaped cover 4 8 至少 at least contains metal or glass. The above dielectric layer can avoid the problem of good. The formation of the layer to protect the service life of the organic electricity can be used to meet the semiconductor In the elementary case, the thin elements of the thin elements can be complicated by the one-side cover. In the above, the formation of the organic electricity, in addition to replacing the cold-transisting optical element gaps, and the reduction of the economical components, the invention reduces the cold-light element of the invention. Attachment, and therefore, in the manufacture of the effect. μ ^ Electro-hydraulic cold parts can also reduce the benefits of the process of the invention by means of water absorbing agent. The inner membrane of the piece has an anti-method between the film, and organic and organic. The method The bonding of the structure of the energy structure can be more electrically cooled, and the instinct is applied to the structure of the photovoltaic element by the invention of a component having a stress and an interface that does not protect the effective component. Protection Of course, the invention may be used in organic electrocooling which may be used in the construction of any illuminating element.
第13頁 1281361 五、發明說明(9) 層以及有機介電層直接保護有機發光元件以提昇有機發光 元件的發光特性及其使用壽命,迄今仍未發展用在關於有 機電冷光元件之結構方面。對產業而言,本方法實為一較 佳可行之有機電冷光元件的結構。 顯然地,依照上面實施例中的描述,本發明可能有許 多的修正與差異。因此需要在其附加的權利要求項之範圍 内加以理解,除了上述詳細的描述外,本發明還可以廣泛 地在其他的實施例中施行。 上述僅為本發明之較佳實施例並非用以限定本發明之 申請專利範圍;凡其它未脫離本發明所揭示之精神下完成 的等效改變或修飾,均應包含在下述申請專利範圍内。 1281361 圖式簡單說明 第一圖為傳統的有機電冷光元件之結構剖面圖; 第二圖係為根據本發明之第一較佳實施例中,具有保 護層與有機介電層之有機電冷光元件的結構剖面圖; 第三圖係為根據本發明之第二較佳實施例中,具有有 機介電層的有機電冷光元件之結構剖面圖;與 第四A圖至第四C圖所示係為根據本發明之第三較佳實 施例中,形成具有保護層與有機介電層之有機電冷光元件 的製程剖面圖。 主要部分之代表符號:Page 13 1281361 V. INSTRUCTIONS (9) The layer and the organic dielectric layer directly protect the organic light-emitting element to enhance the light-emitting characteristics of the organic light-emitting element and its service life have not been developed so far for the structure of the electro-optical cold-light element. For the industry, this method is a better and more viable structure of organic electroluminescent elements. Obviously, many modifications and differences may be made to the invention in light of the above description. It is therefore to be understood that within the scope of the appended claims, the invention may be The above are only the preferred embodiments of the present invention and are not intended to limit the scope of the invention. All other equivalents and modifications may be made without departing from the spirit of the invention. 1281361 BRIEF DESCRIPTION OF THE DRAWINGS The first figure is a structural sectional view of a conventional organic electroluminescent element; the second figure is an organic electroluminescent element having a protective layer and an organic dielectric layer in accordance with a first preferred embodiment of the present invention; FIG. 3 is a cross-sectional view showing the structure of an organic electroluminescent element having an organic dielectric layer in accordance with a second preferred embodiment of the present invention; and FIG. 4A to FIG. In a third preferred embodiment of the present invention, a process cross-sectional view of an organic electroluminescent element having a protective layer and an organic dielectric layer is formed. Representative symbols of the main part:
100 有 機 電 冷 光 裝 置 110 基 板 120 有 機 電 冷 光 元 件 130 封 蓋 140 吸 水 劑 150 蓋 緣 160 粘 著 劑 200 基 板 210 有 機 電 冷 光 元 件 220 第 —一 電 極 層 230 有 機 層 第15頁 1281361 圖式簡單說明 240 第二電極層 2 5 0 有機介電層 2 6 0 保護層 2 70 盆狀封蓋 3 0 0 透明基板 310 有機電冷光元件 3 2 0 第一電極層 33 0 有機層 34 0 第二電極層 350 有機介電層 __ 3 6 0 盆狀封蓋 3 7 0 吸水劑 40 0 玻璃基板 410A 第一電極層 4 1 0 B 第一電極區 42 0 光阻層 4 3 0 有機層 440 第二電極層 4 5 0 有機電冷光元件 4 6 0 有機介電層 4 470 保護層 48 0 盆狀封蓋100 Organic Electric Cooling Device 110 Substrate 120 Organic Electric Cooling Element 130 Cover 140 Water Absorber 150 Cover Edge 160 Adhesive 200 Substrate 210 Organic Electric Cooling Element 220 First Electrode Layer 230 Organic Layer Page 15136361 Simple Description 240 Second electrode layer 2 5 0 organic dielectric layer 2 6 0 protective layer 2 70 basin cover 3 0 0 transparent substrate 310 organic electroluminescent element 3 2 0 first electrode layer 33 0 organic layer 34 0 second electrode layer 350 Organic dielectric layer __ 3 6 0 basin cover 3 7 0 water absorbing agent 40 0 glass substrate 410A first electrode layer 4 1 0 B first electrode region 42 0 photoresist layer 4 3 0 organic layer 440 second electrode layer 4 5 0 Organic luminescence element 4 6 0 Organic dielectric layer 4 470 Protective layer 48 0 Basin cover
第16頁Page 16
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