TWI281361B - Organic electro-luminescent device with protecting layer - Google Patents

Organic electro-luminescent device with protecting layer Download PDF

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TWI281361B
TWI281361B TW91122565A TW91122565A TWI281361B TW I281361 B TWI281361 B TW I281361B TW 91122565 A TW91122565 A TW 91122565A TW 91122565 A TW91122565 A TW 91122565A TW I281361 B TWI281361 B TW I281361B
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Taiwan
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organic
layer
electrode
organic electroluminescent
forming
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TW91122565A
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Chinese (zh)
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Whe-Yi Chiang
Shuenn-Jiun Tang
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Univision Technology Inc
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Abstract

This invention discloses a new structure of the organic electro-luminescent (OEL) devices. The structure of the organic electro-luminescent (OEL) devices in this invention comprises: a substrate; an organic luminous device, wherein the organic luminous device is connected with a surface of the substrate, and the organic luminous device comprises a first electrode that is connected with the surface of the substrate, organic layers that are connected with the first electrode, a second electrode that is connected with the organic layers; an organic dielectric layer that is overlaid on the second electrode and a reactive protecting layer that is overlaid on the organic dielectric layer; a tub-seal cover that consists of a bottom cover and an edge, so as to contain the organic electro-luminescent (OEL) device therein; an adhesive that is located on the edge of the cover, and the edge of the cover is adhered to the predetermined region on the surface of the substrate, thereby the organic electro-luminescent (OEL) device is sealed therein.

Description

1281361 五、發明說明(1) 5 - 1發明領域: 本發明係關於一種有機電冷光元件(OEL; Organic Electro-Luminescent Device),特別是有關於一種具有 反應活性的保護層之有機電冷光(0EL)元件結構。 5 - 2發明背景: 一般而言, 件,例如,有機 Diode; 0LED) 之間插入一有機 子從陰電極注人 電洞將會在有機 線。此類電冷光 形成有機層之有 因此,對於各種 元件與儀器設備 電冷光(Electro-Luminescent; EL)元 發光二極體(Organic Light Emitting 或是相類似.的構造係為在一對陰陽電極 層(Laminated organic layers) ° 當電 且電洞從陽電極注入至有機層時,電子與 層中互相結合,導致電冷光元件放射出光 元件具有咼亮度與高對比的特性,而且由 ,材質所放射的光線具有多色彩的優點。 貧訊工業而言,電冷光元件可應用於顯示 之發射光源組件上。 〇 迄今,有機電冷夹; 有機電冷光元件在完ώ =件仍存在某些缺陷未予以克服。 特性(亦即發光強产)合1封裝後,在使用初期,其發光 導致此發光性質劣=的=隨著時間呈現巨幅劣化的現象。 ' M t因係由於有機電冷光元件内部殘1281361 V. INSTRUCTION DESCRIPTION (1) 5 - 1 Field of the Invention: The present invention relates to an organic electro-luminescence device (OEL), and more particularly to an organic electro-cooled light (0EL) having a reactive protective layer. ) Component structure. 5 - 2 invention background: In general, a piece, for example, an organic Diode; 0LED) inserts an organic sub-injection from the cathode electrode. The hole will be in the organic line. Such electro-cold light forms an organic layer. Therefore, for various components and instruments, Electro-Luminescent (EL) light-emitting diodes (Organic Light Emitting or similar) are constructed in a pair of yin and yang electrode layers. (Laminated organic layers) ° When electricity and holes are injected from the anode electrode to the organic layer, the electrons and the layers are combined with each other, causing the light-emitting elements to emit light having high brightness and high contrast characteristics, and the material is radiated. Light has the advantage of multi-color. In the poor industry, electric luminescence components can be applied to the display of the emission light source components. 〇 So far, organic electric cold clamps; organic luminescence components are finished ώ = some defects still exist Overcome. Characteristics (that is, luminescence strong) After 1 package, in the initial stage of use, its luminescence causes the luminescence property to be inferior = = a large deterioration phenomenon with time. ' M t due to the internal structure of the organic luminescence element Residual

1281361 五、發明說明(2) 留的水氣及元件外部侵入的水氣所造成。有機電冷光元件 -内的有機薄膜因水氣的吸附而產生潮解,而金屬電極則因 水氣及氧氣的侵入產生氧化作用而劣化。另一方面,當施 加外部電壓於有機電冷光元件的電極上以驅動有機電冷光 元件發光一段時間後,有機電冷光元件會產生熱。如此一 來,更加快劣化的速度,因而造成有機電冷光元件上的暗 點(D a r k s ρ 〇 t)。隨著氧化及潮解作用的進行,暗點會 持續地擴大,甚至危及整個發光元件。 如上所述,必須有效地降低有機電冷光元件之内部殘 $ 留的水氣及元件外部侵入的水氣以防止暗點的產生。現今 採用的方式係在有機電冷光元件外側配置一内含有吸水劑 之封蓋架構(h e r m e t i c s e a 1),以達到長期穩定與提高壽 命的目的,而封蓋的材質通常使用金屬或是玻璃。參考第 一圖所示,傳統之有機電冷光裝置100包含:一基板110, 且基板11 0下方連接一有機電冷光元件1 2 0 ; —封蓋1 3 0, 封蓋架構1 3 0之底部具有一吸水劑1 4 0,其中,封蓋1 3 0具 有一蓋緣1 5 0,蓋緣1 5 0係藉由一粘著劑1 6 0與基板11 0相連 ❸ 然而,上述之封蓋結構仍有一些問題存在。由於此結 構中必須挪出相當的空間以置放吸水劑,因此,封蓋結構 與有機電冷光元件之間存在一定的空間,此空隙中仍包含 了含有水氣與氧氣之空氣。再者,傳統有機電冷光元件之1281361 V. INSTRUCTIONS (2) caused by moisture and water intrusion from the outside of the component. Organic electric luminescence element - The organic film inside is deliquescent due to the adsorption of moisture, and the metal electrode is degraded by the oxidation of moisture and oxygen. On the other hand, when an external voltage is applied to the electrodes of the organic electroluminescent element to drive the organic electroluminescent element to emit light for a while, the organic electroluminescent element generates heat. In this way, the speed of deterioration is accelerated, thereby causing dark spots (D a r k s ρ 〇 t) on the organic electric luminescence element. As oxidation and deliquescence progress, the dark spots continue to expand, even jeopardizing the entire illuminating element. As described above, it is necessary to effectively reduce the moisture remaining in the internal residual portion of the organic electric luminescence element and the moisture intruded outside the element to prevent generation of dark spots. Nowadays, a cover structure (h e r m e t i c s e a 1) containing a water absorbing agent is disposed outside the organic electroluminescent element to achieve long-term stability and life improvement, and the material of the cover is usually metal or glass. Referring to the first figure, the conventional organic electro-optic device 100 includes: a substrate 110, and an organic electric cooling element 1 2 0 is connected under the substrate 11 0; a cover 1 3 0, a bottom of the cover structure 1 3 0 There is a water absorbing agent 140, wherein the cover 130 has a cover edge 150, and the cover edge 150 is connected to the substrate 11 by an adhesive 160. However, the cover is as described above. There are still some problems with the structure. Since a considerable amount of space must be removed in the structure for the water absorbing agent, there is a space between the capping structure and the organic electroluminescent element, and the air containing oxygen and oxygen is still contained in the gap. Furthermore, the conventional organic electric luminescence element

第7頁 1281361 五、發明說明(3) 封裝結構所使用的粘著劑亦具有透水性(約為〇 · 2% )。 因此,隨著使用時間的增加’含有水氣與氧氣之外部空氣 仍會經由粘著劑而滲透至封裝結構内部之空隙中。另一方 面,有機電冷光元件1 2 0的電子傳導狀態在理想狀況下應 僅止於有機電冷光元件1 2 0内部各層之間,然而,實際上 卻會經由陰極層逸漏部分電子而導致漏電流的問題。針對 此點,傳統的方式係在有機電冷光元件1 2 0的最上層結構 上添加一無機鈍化層(passivati〇n Layers)以防止上述 之問題然而’由於無機層材質之硬度較高,經過沉積製Page 7 1281361 V. INSTRUCTIONS (3) The adhesive used in the package structure also has water permeability (about 〇 · 2%). Therefore, as the use time increases, the outside air containing moisture and oxygen still penetrates into the voids inside the package structure via the adhesive. On the other hand, the electron conduction state of the organic electroluminescent element 120 should ideally only terminate between the layers inside the organic electroluminescent element 120, however, actually, some electrons are leaked through the cathode layer. Leakage current problem. In this regard, the conventional method is to add an inorganic passivation layer on the uppermost structure of the organic electroluminescent element 120 to prevent the above problem. However, due to the high hardness of the inorganic layer material, deposition is performed. system

程後,有機電冷光元件i 2 〇之有機層及其陰極間的薄膜接 合^面將因應力的作用而部分分離,使得接觸面劣化,進 而導致,子注^的效率變差,進一步造成發光元件之發光 特t的劣化。鑒於上述之種種原因,我們更需要一種新的 有機電冷光元件之結構,以便於提昇有機電冷光元件之發 光特性與使用期限。 5 - 3發明目的及概述:After the process, the film bonding surface between the organic layer of the organic electroluminescent element i 2 and the cathode thereof is partially separated by the action of stress, so that the contact surface is deteriorated, thereby causing the efficiency of the sub-injection to be deteriorated, further causing the light emission. The deterioration of the light-emitting characteristics of the element. In view of the above various reasons, we need a new structure of an organic electric luminescence element to improve the illuminating characteristics and service life of the organic luminescence element. 5 - 3 Purpose and overview of the invention:

,立-於上述之發明背景中,傳統有機電冷光元件之結構 罐2所產生的諸多缺點,本發明提供一具有反應活性的保 $ S之有機電冷光元件的結構可用以克服傳統結構上的問In the above-mentioned background of the invention, the conventional organic electroluminescent element has many disadvantages caused by the structural can 2, and the present invention provides a structure of a reactive organic electrocooling element which can be used to overcome the conventional structure. ask

第8頁 1281361 五、發明說明(4) 本發明主要的目 |構。本發明能藉由一 元件之結構應力的問 各薄膜間接合介面不 |具有反應活性的保護 法,藉此可更有效地 封蓋與有機電冷光元 能增加有機電冷光元 。所以,本發明的方 方法能適用於光電及 的係在提彳卩一 有機介電層的〗!機電冷*元件的結 題,藉此可避降低有機電冷光 佳之問題。此外,::冷光元件内部 層的形成以取代傳统:f :藉由- f接保護有機電冷光元件,且 件之間娇六—„ 且r減少 ]所存在的空隙。因此,本於明 件的使用壽命以及降低製 x 法歆釣μ A 叹降低ι知的複雜性 丰3 ί付合經濟上的效益。據此,本 + ¥體7L件之技術中。 為了達到以上所 機電冷光元件之結構 少包含 :一基 與基板之一表 -與基 1結於有 -形成 係為一 ;一黏 著劑將 光元件 板相連 機層之 於有機 底蓋與 著劑, 其蓋緣 密封於 板;一 面相連 結之陽 上的陰 介電層 一蓋緣 黏著劑 連結於 其中。 層 述之目的 。本發明 有機電冷 結,其中 極、一與 才虽、一形 上的保護 所組成以 係位於蓋 基板上之 ,本發明 之有機電 光元件, ,有機電 陽極相連 成於陰極 盆 容納有機 緣上,且 預定連接 揭不了 * 冷光元件 有機電冷 冷光元件 結之有機 上的有機 狀封蓋, 電冷光元 盆狀封蓋 處,並將 種新的有 的結構至 光元件係 至少包含 層、一連 介電層與 盆狀封蓋 件於其中 可It由黏 有機電冷Page 8 1281361 V. INSTRUCTIONS (4) The main purpose of the present invention. The present invention can provide a reactive protection method by the structural stress of a component, whereby the organic electrocooling element can be more efficiently encapsulated and organically cooled. Therefore, the method of the present invention can be applied to the electro-optical system of the organic dielectric layer. The problem of electromechanical cold* components can avoid the problem of good organic cooling. In addition, the formation of the inner layer of the luminescent element replaces the conventional: f: the organic electrocooling element is protected by the -f connection, and the gap between the pieces is 6% and r is reduced. Therefore, the present invention The service life and the reduction of the x method of fishing μ A 降低 降低 ι ι ι ι ι ι 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 The structure comprises: one of the base and one of the substrate - the base 1 is formed - the one is formed; an adhesive connects the optical component plate to the organic bottom cover and the agent, and the cover edge is sealed to the plate; An insulating layer on the side of the anode is connected to the capping adhesive. The purpose of the layering is the organic electrocooling junction of the present invention, wherein the pole, the one and the other are formed by the protection of the shape. On the cover substrate, the organic electro-optical element of the present invention, the organic electro-anode is connected to the cathode pot to accommodate the organic edge, and the predetermined connection is not removed. * The organic-like organic cover of the cold-light element organic electric cold-cooling element is Closure element at the cold basin, and the kinds of the new structure to the optical element comprises at least a layer with a line, a series of dielectric layers and the closure member to a tub in which a sticky organic It Cold

I28l361 ------------ 五、發明說明(5) 5 ~ 4發明的詳細說明: 構 本發明在此所探討的方向為一稽 為了能徹底地瞭解本發明,將在 '電 > 光凡件之結 盡的牛_々曰士 /土处姓 、 下列的描述中提出詳 的步驟或疋70件結構。顯然地,本 於车道祕- /4·、4+益4* ^月的施<丁並未限疋 導體几件之技藝者所熟習的特殊細 所周知的製程步驟或是元件姓構卄 μ ., 叶、、,口稱並未描述於细笳φ,以僻 免造成本發明不必要之限制。太八_ k ^ 鲈汁1 Μ人 制本發明的較佳實施例會詳細 描逑如下,然而除了這必詳 、< ,, 一平"、田彳田逃之外,本發明還可以廣 泛地施行在其他的實施例中,& 、 i p; ^ ^ ^ ^ ^ 儿本發明的範圍不受限定, 乂之後的專利範圍為準。 ^考第二圖所示’在本發明之第一實施例中,首先提 供基板2 0 0,其+,基板2〇〇至少包含一透明材質,例如 f璃板連、”。於基板2 0 0之-表面上的有機發光元件 210’有機發光元件21〇的結構至少包含:一第一電極層 ϋ’例如.:—ITQ層’第—電極層220係連結於基板2 0 0之 一表面上;一有機層23〇,有機層23〇係連結於第一電極層 2電極層24°,第二電極層240係連結於有機 曰右嬙呙ΜπΓ ^生成(C〇nf〇rmati〇n)於第一電極層2 2 0蹦 、有機層23 0與第二带和^ 250,例如,一聚:::上40的四周表面上之有機介電層 件謂封於其Π:機介電層25°可將有機發光元 $ @ MO# P芸认+其與外界絕緣;一保護層2 6 0,保 §又層覆盍於有機介電層250上以形成有機電冷光元件I28l361 ------------ V. Description of the invention (5) Detailed description of the invention of 5~4: The direction of the invention discussed herein is a syllabus in order to thoroughly understand the present invention, 'Electricity' _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Obviously, this is a well-known process step or component surname that is familiar to the craftsmen of the conductors of the conductors - 4, 4, 4, and 4 months. μ , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , The present invention can be described in detail below, but in addition to this must, <,, a flat " In other embodiments, &ip; ^ ^ ^ ^ ^ The scope of the present invention is not limited, and the scope of the following patents will prevail. ^In the first embodiment of the present invention, in the first embodiment of the present invention, first, a substrate 200 is provided, and +, the substrate 2A includes at least one transparent material, such as a glass plate, "on the substrate 2 0. The structure of the organic light-emitting element 210' on the surface of the organic light-emitting element 210' includes at least: a first electrode layer ϋ', for example: -ITQ layer, the first electrode layer 220 is connected to one surface of the substrate 200 An organic layer 23〇, the organic layer 23 is connected to the first electrode layer 2 electrode layer 24°, and the second electrode layer 240 is coupled to the organic layer 曰π嫱呙Μ ^ generation (C〇nf〇rmati〇n) The organic dielectric layer on the peripheral surface of the first electrode layer 2 2 0 蹦, the organic layer 23 0 and the second strip and 250, for example, a poly::: 40 is encapsulated in the Π: machine dielectric The layer 25° can illuminate the organic light-emitting element $@MO# P+ and is insulated from the outside; a protective layer 260, which is further layered on the organic dielectric layer 250 to form an organic electric luminescent element

苐10頁 1281361 五、發明說明(6) ^-- -- ,其中,保濩層2 6 0至少包含一具有反應活性之材質,以 吸收外界之水氣、^氣或是揮發性有機溶劑等物質,且具 有反應活性之材質更包含-功函數小於4之元素,例如, ?金私入IA)或鹼土族(j IA); 一盆狀封蓋27〇,盆狀封 ΐ 係猎由一 Ϊ蓋與蓋緣所組成之凹槽結構,且盆狀封 f 可藉由黏著劑將其蓋緣連結於基板2 0 0上之預定連接 處,其中,盆狀封蓋m之材質至少包含金屬或是玻璃。 供一 ί:ΐ f ^所*,在本發明之第二實施例中,首先提 ^ 一 # & ΐ =女〇 ’例如,破璃板。一連結於透明基板3 0 0 至人:一 μ機發光兀件3 1 0,有機發光元件3 1 0的結構 明二=^以一弟#一電極層32〇,第一電極層320係連結於透 ,板3 0 0之一表面上,且第一電極層32〇至少包含一〖το A中一:Γ〇,有機層3 3 0係連結於第-電極32°上, 電子傳ίΪ 至少,含-電洞傳導層、-發光層與- 4 : I ^ 340, ^ , r。-共形生成於第-^ 極層340的四周+ + π β0與弟一電 可將有機發光元;31。密封:有機介電層350 電層3_材質至少包含= ,有機介 :ΐ :。—盆狀封蓋3 6 0 ’盆狀封蓋3 6 0係為藉I?之底有蓋機斑 -緣所組成之凹槽結構’且盆狀封蓋36〇可藉由由一黏底著盖劑、苐 10 pages 1281361 V. Description of the invention (6) ^-- -- , wherein the protective layer 210 contains at least one reactive material to absorb external moisture, gas or volatile organic solvents. The material, and the reactive material, further contains an element with a work function less than 4, for example, gold IA or alkaline earth (j IA); a potted cover 27 〇, potted seal a groove structure formed by the lid and the lid edge, and the basin seal f can be joined to the predetermined joint on the substrate 2000 by an adhesive, wherein the material of the pot cover m comprises at least metal Or glass. For a second embodiment of the present invention, first, a # & ΐ = 〇 ', for example, a glass plate. A structure is connected to the transparent substrate 300 to the human: a micro-light-emitting device 3 1 0, and the structure of the organic light-emitting element 3 1 0 is a second electrode, and the first electrode layer 320 is connected. On the surface of one of the plates 300, and the first electrode layer 32〇 contains at least one of ττ A: Γ〇, the organic layer 333 is connected to the first electrode 32°, and the electrons are at least 电子, containing - hole conducting layer, - luminescent layer with - 4 : I ^ 340, ^ , r. - Conformal generation on the periphery of the -th electrode layer 340 + + π β0 and the second electron can be an organic light-emitting element; Seal: organic dielectric layer 350 electrical layer 3_ material contains at least =, organic media: ΐ:. - Basin-shaped cover 3 6 0 'The basin-shaped cover 306 is a groove structure composed of a plaque-edge of the bottom of the I? and the basin-shaped cover 36 can be made by a sticky bottom Covering agent,

1281361 一 - - 五、發明說明(7) ’例如’一 UV聚合膠,將其蓋緣連結於透明基板3 〇 〇上之 預定連接處,其中,盆狀封蓋3 6 0之材質至少包含金屬或 是玻璃。一吸水劑37 0,吸水劑3 7 0係容納於盆狀封蓋360 之底蓋上,其中,吸水劑3 7 0至少包含一磷氧化物,例如 ,P205( phosohorus pentoxide) 〇 參考第四A圖至第四C圖所示,在本發明之第三實施例1281361 一 - - 5. Description of the invention (7) 'For example, a UV polymer adhesive, the cover edge is joined to a predetermined joint on the transparent substrate 3, wherein the material of the basin cover 360 is at least metal Or glass. A water absorbing agent 370, the water absorbing agent 307 is contained on the bottom cover of the basin cover 360, wherein the water absorbing agent 370 includes at least a phosphorus oxide, for example, P205 (phosohorus pentoxide) 〇 reference fourth A 3 to C, in the third embodiment of the present invention

中’首先提供一玻璃基板400。然後,一第一電極層410A 形成於玻璃基板4 0 0上,其中,第一電極層4 1 〇 A至少包含 一透明電極層,例如,I T0層。接著,形成且定義複數個 光阻層4 2 0於第一電極層4 1 0 A上。其次,藉由複數個光阻 層4 2 0當成複數個姓刻罩幕進行一餘刻製程,以便於钱刻 第一電極層410A直到玻璃基板40 0為止,並定義出複數個 第一電極區4 1 0 B。在去除複數個光阻層4 2 0之後,形成且 覆蓋一有機層43 0於複數個第一電極區410 B與玻璃基板400 上。隨後’形成一第二電極層4 4 0,例如,一金屬電極層 ,於有機層430上以當成一陰極層,其中,每一個第一 ^ 極區410B與其上連接之有機層43〇與第二電極層44〇可定義 為一個有機發光元件45 0。接著,共形生成一有機介電層 4 6^於第二電極層44 〇的表面上,其中,有機介電層46〇的 材夤至少包含一具有分子量約低於丨〇 〇 〇之有機化合物或是 聚合物’且有機介電層4 6 〇的形成方法至少包含一物理氣 相沉積法(Physical Vapor Deposition; PVD)。隨後, 共形生成一保護層470於有機介電層46 0的表面上以形成複First, a glass substrate 400 is provided. Then, a first electrode layer 410A is formed on the glass substrate 400, wherein the first electrode layer 4 1 〇 A includes at least one transparent electrode layer, for example, an ITO layer. Next, a plurality of photoresist layers 410 are formed and defined on the first electrode layer 4 1 0 A. Secondly, a plurality of photoresist layers are used as a mask to perform a process of engraving, so as to engrave the first electrode layer 410A until the glass substrate 40 0, and define a plurality of first electrode regions. 4 1 0 B. After removing the plurality of photoresist layers 420, an organic layer 430 is formed over the plurality of first electrode regions 410B and the glass substrate 400. Subsequently, a second electrode layer 410 is formed, for example, a metal electrode layer on the organic layer 430 to form a cathode layer, wherein each of the first electrode regions 410B is connected to the organic layer 43 and the first The two electrode layer 44A can be defined as one organic light emitting element 45 0 . Next, an organic dielectric layer is formed on the surface of the second electrode layer 44 ,, wherein the material of the organic dielectric layer 46 夤 comprises at least one organic compound having a molecular weight of less than about 丨〇〇〇 The method of forming the polymer and the organic dielectric layer 4 6 至少 includes at least one physical vapor deposition (PVD). Subsequently, a protective layer 470 is formed on the surface of the organic dielectric layer 46 0 to form a complex

第12頁 1281361 五、發明說明(8) 數個有機電冷光元件,其中,保護層4 7 0的形成方法至少 包含一物理氣相沉積法(PVD),而保護層47〇的材質至少 包含一具有功函數小於4之固態化合物的反應活性材料, 例如,鹼金族(ϊ A)氧化物或鹼土族(丨丨A)氧化物。最 後,藉由黏著劑將一盆狀封蓋4 8 0之蓋緣連結於基板4 〇 〇上 之預定連接處,以密封複數個有機發光元件45 0及其上之 有機介電層46 0與保護層47 0 (亦即複數個有機電冷光元件 ^於盆狀封蓋4、8〇内部,其中,盆狀封蓋48〇係為藉由一底 盍與蓋緣所組成之凹槽結構,且盆狀封蓋4 8 〇之材質至少 包含金屬或是玻璃。 如上所 機介電層的 藉此可避免 佳之問題。 層的形成以 保護有機電 間所存在的 使用壽命以 方法能夠符 及半導體元 例中 光元 各薄 由一 的方 封蓋 能增 複雜 此, 述,在 形成以 有機電 此外, 取代傳 冷光元 空隙。 及減少 合經濟 件之技 本發明 降低有 冷光元 本發明 、统貼附 件,且 因此, 其製造 上的效 術中。 μ ^ 機電冷 件内部 也能藉 吸水劑 可減少 本發明 過程的 益。據 件之内 膜之間 具有反 法,藉 與有機 加有機 性。所 本方法 明能藉 部結構 的接合 應活性 此可更 電冷光 電冷光 以,本 能適用 由一有 應力, 介面不 之保護 有效地 元件之 元件的 發明的 於光電 元件的結構上,也 ’本發明藉由保護 當然,本發明可能用在有機電冷 可能用在任何發光元件的結構上。而Page 12 1281361 V. Description of the Invention (8) A plurality of organic electroluminescent elements, wherein the formation method of the protective layer 470 includes at least one physical vapor deposition (PVD), and the material of the protective layer 47 至少 includes at least one A reactive material having a solid compound having a work function of less than 4, for example, an alkali gold (ϊ A) oxide or an alkaline earth (丨丨A) oxide. Finally, a cover edge of a pot-shaped cover 4805 is bonded to a predetermined joint on the substrate 4 by an adhesive to seal the plurality of organic light-emitting elements 45 0 and the organic dielectric layer 46 0 thereon. The protective layer 47 0 (that is, a plurality of organic electric luminescence elements) are inside the basin-shaped cover 4, 8 ,, wherein the basin-shaped cover 48 is a groove structure composed of a bottom rim and a cover edge. And the material of the pot-shaped cover 4 8 至少 at least contains metal or glass. The above dielectric layer can avoid the problem of good. The formation of the layer to protect the service life of the organic electricity can be used to meet the semiconductor In the elementary case, the thin elements of the thin elements can be complicated by the one-side cover. In the above, the formation of the organic electricity, in addition to replacing the cold-transisting optical element gaps, and the reduction of the economical components, the invention reduces the cold-light element of the invention. Attachment, and therefore, in the manufacture of the effect. μ ^ Electro-hydraulic cold parts can also reduce the benefits of the process of the invention by means of water absorbing agent. The inner membrane of the piece has an anti-method between the film, and organic and organic. The method The bonding of the structure of the energy structure can be more electrically cooled, and the instinct is applied to the structure of the photovoltaic element by the invention of a component having a stress and an interface that does not protect the effective component. Protection Of course, the invention may be used in organic electrocooling which may be used in the construction of any illuminating element.

第13頁 1281361 五、發明說明(9) 層以及有機介電層直接保護有機發光元件以提昇有機發光 元件的發光特性及其使用壽命,迄今仍未發展用在關於有 機電冷光元件之結構方面。對產業而言,本方法實為一較 佳可行之有機電冷光元件的結構。 顯然地,依照上面實施例中的描述,本發明可能有許 多的修正與差異。因此需要在其附加的權利要求項之範圍 内加以理解,除了上述詳細的描述外,本發明還可以廣泛 地在其他的實施例中施行。 上述僅為本發明之較佳實施例並非用以限定本發明之 申請專利範圍;凡其它未脫離本發明所揭示之精神下完成 的等效改變或修飾,均應包含在下述申請專利範圍内。 1281361 圖式簡單說明 第一圖為傳統的有機電冷光元件之結構剖面圖; 第二圖係為根據本發明之第一較佳實施例中,具有保 護層與有機介電層之有機電冷光元件的結構剖面圖; 第三圖係為根據本發明之第二較佳實施例中,具有有 機介電層的有機電冷光元件之結構剖面圖;與 第四A圖至第四C圖所示係為根據本發明之第三較佳實 施例中,形成具有保護層與有機介電層之有機電冷光元件 的製程剖面圖。 主要部分之代表符號:Page 13 1281361 V. INSTRUCTIONS (9) The layer and the organic dielectric layer directly protect the organic light-emitting element to enhance the light-emitting characteristics of the organic light-emitting element and its service life have not been developed so far for the structure of the electro-optical cold-light element. For the industry, this method is a better and more viable structure of organic electroluminescent elements. Obviously, many modifications and differences may be made to the invention in light of the above description. It is therefore to be understood that within the scope of the appended claims, the invention may be The above are only the preferred embodiments of the present invention and are not intended to limit the scope of the invention. All other equivalents and modifications may be made without departing from the spirit of the invention. 1281361 BRIEF DESCRIPTION OF THE DRAWINGS The first figure is a structural sectional view of a conventional organic electroluminescent element; the second figure is an organic electroluminescent element having a protective layer and an organic dielectric layer in accordance with a first preferred embodiment of the present invention; FIG. 3 is a cross-sectional view showing the structure of an organic electroluminescent element having an organic dielectric layer in accordance with a second preferred embodiment of the present invention; and FIG. 4A to FIG. In a third preferred embodiment of the present invention, a process cross-sectional view of an organic electroluminescent element having a protective layer and an organic dielectric layer is formed. Representative symbols of the main part:

100 有 機 電 冷 光 裝 置 110 基 板 120 有 機 電 冷 光 元 件 130 封 蓋 140 吸 水 劑 150 蓋 緣 160 粘 著 劑 200 基 板 210 有 機 電 冷 光 元 件 220 第 —一 電 極 層 230 有 機 層 第15頁 1281361 圖式簡單說明 240 第二電極層 2 5 0 有機介電層 2 6 0 保護層 2 70 盆狀封蓋 3 0 0 透明基板 310 有機電冷光元件 3 2 0 第一電極層 33 0 有機層 34 0 第二電極層 350 有機介電層 __ 3 6 0 盆狀封蓋 3 7 0 吸水劑 40 0 玻璃基板 410A 第一電極層 4 1 0 B 第一電極區 42 0 光阻層 4 3 0 有機層 440 第二電極層 4 5 0 有機電冷光元件 4 6 0 有機介電層 4 470 保護層 48 0 盆狀封蓋100 Organic Electric Cooling Device 110 Substrate 120 Organic Electric Cooling Element 130 Cover 140 Water Absorber 150 Cover Edge 160 Adhesive 200 Substrate 210 Organic Electric Cooling Element 220 First Electrode Layer 230 Organic Layer Page 15136361 Simple Description 240 Second electrode layer 2 5 0 organic dielectric layer 2 6 0 protective layer 2 70 basin cover 3 0 0 transparent substrate 310 organic electroluminescent element 3 2 0 first electrode layer 33 0 organic layer 34 0 second electrode layer 350 Organic dielectric layer __ 3 6 0 basin cover 3 7 0 water absorbing agent 40 0 glass substrate 410A first electrode layer 4 1 0 B first electrode region 42 0 photoresist layer 4 3 0 organic layer 440 second electrode layer 4 5 0 Organic luminescence element 4 6 0 Organic dielectric layer 4 470 Protective layer 48 0 Basin cover

第16頁Page 16

Claims (1)

松發13谢_孝)正本1 1 銮號_年月日__ 六、申請專利範圍 1 · 一種有機電冷光元件的結構,該有機電冷光元件的結構 包含: 一基板; 一有機發光元件,該有機發光元件係與該基板之一表面相 連結; 一有機介電層,該有機介電層係包覆該有機發光元件以將 該有機發光元件密封於該基板上;及 一保護層,該保護層係包覆該有機介電層以將該有機介電 層密封於該基板上,該保護層包含一具有反應活性之材 2. 如申請專利範圍第1項所述之有機電冷光元件的結構, 其中上述之基板至少包含一透明材質。 3. 如申請專利範圍第2項所述之有機電冷光元件的結構, 其中上述之透明材質包含一玻璃材質。 4. 如申請專利範圍第1項所述之有機電冷光元件的結構, 其中上述之有機發光元件包含: 一第一電極,該第一電極係與該基板之該表面相連結; 一有機層,該有機層係連結於該第一電極上;與 一第二電極,該第二電極係連結於該有機層上,且該第二 電極上覆蓋該有機介電層。Songfa 13 Xie_xiao) Original 1 1 銮号_年月日日__ VI. Patent scope 1 · The structure of an organic electric luminescence element, the structure of the organic luminescence element comprises: a substrate; an organic light-emitting element, The organic light emitting device is coupled to a surface of the substrate; an organic dielectric layer covering the organic light emitting device to seal the organic light emitting device on the substrate; and a protective layer, the protective layer The protective layer is coated with the organic dielectric layer to seal the organic dielectric layer on the substrate, the protective layer comprising a reactive material. 2. The organic electroluminescent element according to claim 1 The structure, wherein the substrate comprises at least one transparent material. 3. The structure of the organic electroluminescent element according to claim 2, wherein the transparent material comprises a glass material. 4. The structure of the organic electroluminescent device of claim 1, wherein the organic light-emitting device comprises: a first electrode, the first electrode is coupled to the surface of the substrate; an organic layer, The organic layer is coupled to the first electrode; and a second electrode is coupled to the organic layer, and the second electrode covers the organic dielectric layer. 第17頁 1281361 _案號91122565_年月日_«_ 六、申請專利範圍 5.如申請專利範圍第4項所述之有機電冷光元件的結構, 其中上述之第一電極包含一透明電極。 6 ^如申請專利範圍第5項所述之有機電冷光元件的結構, 其中上述之透明電極包含一 I TO層。 7.如申請專利範圍第4項所述之有機電冷光元件的結構, 其中上述之第二電極包含一金屬層。 8 .如申請專利範圍第1項所述之有機電冷光元件的結構, ^ 其中上述之有機介電層的材質包含一聚合物。 9.如申請專利範圍第1項所述之有機電冷光元件的結構, 其中上述之有機介電層的材質包含一分子量約小於100 0之 有機化合物。 1 0 .如申請專利範圍第1項所述之有機電冷光元件的結構, 其中上述之具有反應活性之材質可與水氣、氧氣與有機溶 劑等有害該有機電冷光元件之物質反應。 11.如申請專利範圍第1項所述之有機電冷光元件的結構, 其中上述之具有反應活性之材質包含功函數約小於4之固 態化合物。。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 The structure of the organic electroluminescent element according to claim 5, wherein the transparent electrode comprises an I TO layer. 7. The structure of an organic electroluminescent device according to claim 4, wherein the second electrode comprises a metal layer. 8. The structure of the organic electroluminescent element according to claim 1, wherein the material of the organic dielectric layer comprises a polymer. 9. The structure of an organic electroluminescent device according to claim 1, wherein the material of the organic dielectric layer comprises an organic compound having a molecular weight of less than about 100. The structure of the organic electroluminescent element according to claim 1, wherein the reactive material is reactive with a substance harmful to the organic electroluminescent element such as moisture, oxygen and an organic solvent. 11. The structure of an organic electroluminescent device according to claim 1, wherein the reactive material comprises a solid compound having a work function of less than about 4. 第18頁 1281361 _案號91122565_年月曰 修正_ 六、申請專利範圍 1 2.如申請專利範圍第1項所述之有機電冷光元件的結構, 其中上述之具有反應活性之材質包含一驗金族之氧化物。 1 3.如申請專利範圍第1項所述之有機電冷光元件的結構, 其中上述之具有反應活性之材質包含一驗土族之氧化物。 1 4. 一種有機電冷光元件的結構,該有機電冷光元件的結 構包含: 一透明基板; 一有機發光元件,該有機電發光元件係與該透明基板之一 || 表面相連結; 一有機介電層,該有機介電層係覆蓋於該有機發光元件的 四周表面上,其中,該有機介電層係為一分子量約小於 1 0 0 0之有機化合物; 一具有一蓋緣與一底蓋之封蓋,該封蓋係藉由一黏著劑將 其該蓋緣連結於該透明基板之一預定連接處,其中,該預 定連接處係位於該有機發光元件所在之該透明基板的該表 面上;與 一吸水劑,該吸水劑係容納於該封蓋之該底蓋中。 1 5 .如申請專利範圍第1 4項所述之有機電冷光元件的結 構,其中上述之透明材質包含一玻璃材質。 1 6 .如申請專利範圍第1 4項所述之有機電冷光元件的結Page 18 1281361 _ Case No. 91922565_年月曰 曰 Amendment _ 6. Patent Application Range 1. 2. The structure of the organic electrocooling element described in claim 1, wherein the reactive material comprises The oxide of the gold family. The structure of the organic electroluminescent element according to claim 1, wherein the reactive material comprises an oxide of a soil test group. 1 . The structure of an organic electroluminescent device, the structure of the organic electroluminescent device comprising: a transparent substrate; an organic light emitting device, wherein the organic electroluminescent device is coupled to one surface of the transparent substrate; An electric layer covering the peripheral surface of the organic light emitting device, wherein the organic dielectric layer is an organic compound having a molecular weight of less than about 100; and a cover edge and a bottom cover a cover which is attached to a predetermined joint of the transparent substrate by an adhesive, wherein the predetermined connection is located on the surface of the transparent substrate where the organic light emitting element is located And a water absorbing agent, the water absorbing agent is accommodated in the bottom cover of the cover. The structure of the organic electroluminescent element according to claim 14, wherein the transparent material comprises a glass material. 1 6 . The knot of the organic electric luminescence element as described in claim 14 第19頁 1281361 _案號91122565_年月日_«_ 六、申請專利範圍 構,其中上述之有機發光元件包含: 一第一電極,該第一電極係與該透明基板之該表面相連 結,其中,該第一電極係為一透明電極; 一有機層,該有機層係連結於該第一電極上;與 一具有金屬層之第二電極,該第二電極係連結於該有機層 上,且該第二電極上覆蓋該有機介電層。 1 7.如申請專利範圍第1 6項所述之有機電冷光元件的結 構,其中上述之第一電極包含一 I TO層。 1 8.如申請專利範圍第1 4項所述之有機電冷光元件的結 ^ 構,其中上述之有機介電層的材質包含一聚合物。 1 9. 一種有機電冷光元件的結構,該有機電冷光元件的結 構包含: 一透明基板; 一有機發光元件,該有機發光元件係與該透明基板之一表 面相連結; 一有機介電層,該有機介電層係覆蓋於該有機發光元件的 表面上,其中,該有機介電層係為一分子量約小於1 0 0 0之 4 有機化合物; 一具有反應活性之保護層,該具有反應活性之保護層係覆 蓋於聚合物介電層的表面上,其中,該具有反應活性之保 護層具有一功函數小於4之元素;與Page 19 1281361 _ Case No. 91922565_年月日日_«_6. Patent application scope, wherein the above organic light-emitting element comprises: a first electrode, the first electrode is connected to the surface of the transparent substrate, Wherein, the first electrode is a transparent electrode; an organic layer is coupled to the first electrode; and a second electrode having a metal layer, the second electrode is coupled to the organic layer, And the second electrode covers the organic dielectric layer. The structure of the organic electroluminescent device of claim 16, wherein the first electrode comprises an I TO layer. The structure of the organic electroluminescent device of claim 14, wherein the material of the organic dielectric layer comprises a polymer. 1 . The structure of an organic electroluminescent element, the structure of the organic electroluminescent element comprising: a transparent substrate; an organic light emitting element connected to a surface of the transparent substrate; an organic dielectric layer, The organic dielectric layer covers the surface of the organic light emitting device, wherein the organic dielectric layer is an organic compound having a molecular weight of less than about 10,000; a reactive protective layer, which is reactive a protective layer covering the surface of the polymer dielectric layer, wherein the reactive protective layer has an element having a work function of less than 4; 第20頁 1281361 _案號91122565_年月日__ 六、申請專利範圍 一具有一蓋緣與一底蓋之封蓋,該封蓋係藉由一黏著劑將 其該蓋緣連結於該透明基板之一預定連接處,其中,該預 定連接處係位於該有機發光元件所在之該透明基板的該表 面上。 2 0 .如申請專利範圍第1 9項所述之有機電冷光元件的結 構,其中上述之有機發光元件包含: 一第一電極,該第一電極係與該透明基板之該表面相連 結,其中,該第一電極係為一透明電極; 一有機層,該有機層係連結於該第一電極上;與 一具有金屬層之第二電極,該第二電極係連結於該有機層 上,且該第二電極上覆蓋該有機介電層。 2 1.如申請專利範圍第2 0項所述之有機電冷光元件的結 構,其中上述之透明電極包含一 IT 0層。 2 2 .如申請專利範圍第1 9項所述之有機電冷光元件的結 構,其中上述之有機介電層的材質包含一聚合物。 2 3 .如申請專利範圍第1 9項所述之有機電冷光元件的結 構,其中上述之具有反應活性之保護層可與水氣、氧氣與 有機溶劑等有害該有機電冷光元件之物質反應。 2 4.如申請專利範圍第1 9項所述之有機電冷光元件的結Page 20 1281361 _ Case No. 91922565_年月日日__ VI. Patent Application Scope A cover having a cover edge and a bottom cover, the cover is attached to the transparent edge by an adhesive a predetermined connection of one of the substrates, wherein the predetermined connection is on the surface of the transparent substrate on which the organic light emitting element is located. The structure of the organic electroluminescent device of claim 19, wherein the organic light-emitting device comprises: a first electrode, the first electrode is coupled to the surface of the transparent substrate, wherein The first electrode is a transparent electrode; an organic layer is coupled to the first electrode; and a second electrode having a metal layer, the second electrode is coupled to the organic layer, and The second electrode covers the organic dielectric layer. 2. The structure of an organic electroluminescent device according to claim 20, wherein the transparent electrode comprises an IT 0 layer. The structure of the organic electroluminescent element according to claim 19, wherein the material of the organic dielectric layer comprises a polymer. The structure of the organic electroluminescent element according to claim 19, wherein the reactive protective layer is reactive with a substance harmful to the organic electroluminescent element such as moisture, oxygen and an organic solvent. 2 4. The junction of the organic electroluminescent element as described in claim 19 第21頁 1281361 _案號91122565_年月曰 修正_ 六、申請專利範圍 構,其中上述之具有反應活性之保護層的材質包含一鹼金 族的元素。 2 5 .如申請專利範圍第1 9項所述之有機電冷光元件的結 構,其中上述之具有反應活性之保護層的材質包含一鹼土 族的元素。 2 6. —種有機電冷光元件之結構,該有機電冷光元件的結 構包含: 一玻璃基板; 一第一電極,該第一電極係與該玻璃基板之一表面相連 結; 一有機層5該有機層係覆蓋於該第一電極上; 一第二電極,該第二電極係覆蓋於該有機層上; 一具有聚合物之有機介電層,該有機介電層係覆蓋於該第 二電極的表面上; 一具有反應活性之保護層係覆蓋於該有機介電層的表面 上,該具有反應活性之保護層可與水氣、氧氣與有機溶劑 等有害該有機電冷光元件之物質反應,其中,該具有反應 活性之保護層的材質包含功函數約小於4的固態化合物; 與 一具有一蓋緣與一底蓋之金屬封蓋,該金屬封蓋係藉由一 UV聚合膠將其該蓋緣連結於該玻璃基板之一預定連接處, 其中,該預定連接處係位於該有機電冷光元件所在之該玻Page 21 1281361 _ Case No. 91922565_年月曰 Amendment _ 6. Patent application scope, wherein the material of the reactive protective layer mentioned above contains an alkali metal element. The structure of the organic electroluminescent element according to claim 19, wherein the material of the reactive protective layer comprises an alkaline earth element. 2 6. The structure of an organic electroluminescent element, the structure of the organic electroluminescent element comprising: a glass substrate; a first electrode, the first electrode is coupled to a surface of the glass substrate; an organic layer 5 An organic layer covering the first electrode; a second electrode covering the organic layer; an organic dielectric layer having a polymer, the organic dielectric layer covering the second electrode a reactive protective layer covering the surface of the organic dielectric layer, the reactive protective layer reacting with substances such as moisture, oxygen and organic solvents that are harmful to the organic electroluminescent element, Wherein the material of the reactive protective layer comprises a solid compound having a work function of less than about 4; and a metal cap having a lid edge and a bottom cover, the metal cap is made by a UV polymer glue a cover edge is coupled to a predetermined connection of the glass substrate, wherein the predetermined connection is located at the glass where the organic electroluminescent element is located 第22頁 1281361 案號 91122565 年月曰 修正 六、申請專利範圍 璃基板的該表面上。 2 7 .如申請專利範圍第2 6項所述之有機電冷光元件的結 構,其中上述之第一電極包含一 ITO層。 2 8.如申請專利範圍第2 6項所述之有機電冷光元件的結 構,其中上述之第二電極包含一金屬層。 2 9 .如申請專利範圍第2 6項所述之有機電冷光元件的結 構,其中上述之有機介電層的材質包含一分子量約小於 1 0 0 0之有機化合物。 3 0 .如申請專利範圍第2 6項所述之有機電冷光元件的結 構,其中上述之具有反應活性之保護層的材質包含一鹼金 族的元素。 3 1.如申請專利範圍第2 6項所述之有機電冷光元件的結 構,其中上述之具有反應活性之保護層的材質包含一鹼土 族的元素。 32.—種有機電冷光元件的形成方法,該有機電冷光元件 的形成方法包含: 提供一基板; 形成一有機發光元件於該基板上;Page 22 1281361 Case No. 91122565 Year of the month Amendment VI. Patent application area on the surface of the glass substrate. The structure of the organic electroluminescent device of claim 26, wherein the first electrode comprises an ITO layer. The structure of the organic electroluminescent device of claim 26, wherein the second electrode comprises a metal layer. The structure of the organic electroluminescent device of claim 26, wherein the material of the organic dielectric layer comprises an organic compound having a molecular weight of less than about 10,000. The structure of the organic electroluminescent device of claim 26, wherein the material of the reactive protective layer comprises an alkali metal element. 3. The structure of the organic electroluminescent device according to claim 26, wherein the material of the reactive protective layer comprises an alkaline earth element. 32. A method for forming an organic electroluminescent device, the method for forming an organic electroluminescent device comprising: providing a substrate; forming an organic light emitting device on the substrate; 第23頁 1281361 _案號91122565_年月日__ 六、申請專利範圍 共形生成一有機介電層包覆該有機發光元件以將該有機發 光元件密封於該基板上;及 共形生成一保護層以包覆該有機介電層,以將該有機介電 層密封於該基板上,該保護層包含一具有反應活性之材 質。 3 3 .如申請專利範圍第3 2項所述之有機電冷光元件的形成 方法,其中上述之有機發光元件的形成方法包含: 形成一第一電極層於該基板之表面上; 形成且定義一光阻層於該第一電極上; U 藉由該光阻層當成一#刻罩幕以姓刻該第一電極層,且形 成一第一電極區; 移除該光阻層; 形成一有機層於該第一電極區上;與 形成一第二電極層於該有機層上以形成該有機發光元件。 3 4 .如申請專利範圍第3 2項所述之有機電冷光元件的形成 方法,其中上述之有機介電層的形成方法包含一物理氣相 沉積製程。 3 5 .如申請專利範圍第3 2項所述之有機電冷光元件的形成 方法,其中上述之有機介電層的材質包含一聚合物。 3 6 .如申請專利範圍第3 2項所述之有機電冷光元件的形成Page 23 1281361 _ Case No. 91922565_年月日日__ Sixth, the patent application scope conformally generates an organic dielectric layer covering the organic light emitting element to seal the organic light emitting element on the substrate; and conformal generation The protective layer covers the organic dielectric layer to seal the organic dielectric layer on the substrate, and the protective layer comprises a reactive material. The method for forming an organic electroluminescent device according to claim 3, wherein the method for forming the organic light-emitting device comprises: forming a first electrode layer on a surface of the substrate; forming and defining a a photoresist layer is disposed on the first electrode; U is formed by a photoresist layer as a mask to form the first electrode layer, and a first electrode region is formed; removing the photoresist layer; forming an organic layer Laminating on the first electrode region; and forming a second electrode layer on the organic layer to form the organic light emitting element. The method of forming an organic electroluminescent device according to claim 3, wherein the method for forming the organic dielectric layer comprises a physical vapor deposition process. The method of forming an organic electroluminescent device according to claim 3, wherein the material of the organic dielectric layer comprises a polymer. 3 6 . Formation of an organic electric luminescent element as described in claim 3 第24頁 1281361 _案號91122565_年月日 修正_ 六、申請專利範圍 方法,其中上述之有機介電層的材質包含一分子量約小於 1 0 0 0之有機化合物。 3 7.如申請專利範圍第3 2項所述之有機電冷光元件的形成 方法,其中上述之保護層的形成方法包含一物理氣相沉積 法。 3 8 .如申請專利範圍第3 2項所述之有機電冷光元件的形成 方法,其中上述該具有反應活性之材質可與水氣、氧氣與 有機溶劑等有害該有機電冷光元件之物質反應。 || 3 9 .如申請專利範圍第3 2項所述之有機電冷光元件的形成 方法,其中上述之具有反應活性之材質包含一具有功函數 小於4之元素。 4 0 .如申請專利範圍第3 2項所述之有機電冷光元件的形成 方法,其中上述之具有反應活性之材質包含一鹼土族之氧 化物。 4 1.如申請專利範圍第3 2項所述之有機電冷光元件的形成 # 方法,其中上述之具有反應活性之材質包含一鹼金族之氧 化物。 4 2. —種有機電冷光元件的形成方法,該有機電冷光元件Page 24 1281361 _ Case No. 91922565_年月日日 Amendment _ VI. Patent Application The method wherein the material of the above organic dielectric layer comprises an organic compound having a molecular weight of less than about 100. 3. The method of forming an organic electroluminescent device according to claim 3, wherein the method for forming the protective layer comprises a physical vapor deposition method. The method of forming an organic electroluminescent device according to claim 3, wherein the reactive material is reactive with a substance harmful to the organic electroluminescent element such as moisture, oxygen or an organic solvent. The method of forming an organic electroluminescent device according to claim 3, wherein the reactive material comprises an element having a work function of less than 4. The method of forming an organic electroluminescent device according to claim 3, wherein the reactive material comprises an alkaline earth oxide. 4. The method of forming an organic electroluminescent device according to claim 3, wherein the reactive material comprises an alkali metal oxide. 4 2. A method of forming an organic electric luminescent element, the organic luminescent element 第25頁 1281361 案號 91122565 六、申請專利範圍 的形成方法至少包含: 提供一玻璃基板; 形成一第一電極層於該玻璃基板之一表面上; 形成且定義複數個光阻層於該第一電極層上; 藉由該複數個光阻層當成複數個蝕刻罩幕以蝕刻該第一電 極層,且形成複數個陽極於該玻璃基板上; 移除該複數個光阻層; 形成且覆蓋一有機層於該複數個陽極上; 形成且覆蓋一第二電極層於該有機層上以當成一陰極;Page 25 1281361 Case No. 91922565 6. The method for forming a patented scope includes at least: providing a glass substrate; forming a first electrode layer on a surface of the glass substrate; forming and defining a plurality of photoresist layers on the first On the electrode layer; the plurality of photoresist layers are formed as a plurality of etching masks to etch the first electrode layer, and a plurality of anodes are formed on the glass substrate; the plurality of photoresist layers are removed; and a layer is formed and covered Organic layer on the plurality of anodes; forming and covering a second electrode layer on the organic layer to form a cathode; 進行一物理氣相沉積製程以共形生成一具有聚合:之有 介電層於該複數個第二電極層上,並形成該複數個有機發 光元件;與 x 之蓋緣黏附於該 連接處係位於該 的該表面上,曰 藉由一黏著劑 預定連接處, 冷光元件所在 底盖中容納一 將一盆狀封蓋 其中,該預定 之該玻璃基板 吸水劑。 玻璃基板之一 複數個有機電 該盆狀封蓋之 ^3、·如申請專利範圍第42項所述之有機電冷光元件的形 法,其中上述之第二電極層包含一金屬層。 7 a ^如申Λ專利範圍第42項所述之有機電冷光元件的形成 方法’其中上述之有機介電層的材質包含一 小於1〇。。之有機化合物。 ㈠具有分子量約 45·如申睛專利範圍第42項所述之有機電冷光元件的形成Performing a physical vapor deposition process to conformally form a polymerized dielectric layer on the plurality of second electrode layers, and forming the plurality of organic light-emitting elements; and attaching a cover edge of the x to the joint On the surface of the surface, a predetermined connection is made by an adhesive, and a bottom cover of the cold light element is accommodated in a bottom cover, the predetermined glass substrate water absorbing agent. The method of the organic electrocooling element of claim 42, wherein the second electrode layer comprises a metal layer. 7 a ^ The method for forming an organic electroluminescent device according to claim 42 wherein the material of the above organic dielectric layer comprises less than 1 Å. . Organic compound. (1) Formation of an organic electric luminescence element having a molecular weight of about 45, as described in claim 42 of the patent application scope 第26頁 1281361 _案號91122565_年月曰 修正__ 六、申請專利範圍 方法,其中上述之盆狀封蓋的材質包含一金屬材質。 4 6 .如申請專利範圍第4 2項所述之有機電冷光元件的形成 方法,其中上述之盆狀封蓋的材質包含一玻璃材質。 4 7.如申請專利範圍第4 2項所述之有機電冷光元件的形成 方法,其中上述之黏著劑的材質包含一 UV聚合膠。 4 8.如申請專利範圍第42項所述之有機電冷光元件的形成 方法,其中上述之吸水劑包含一構氧化物。 4 9. 一種有機電冷光元件的形成方法,該有機電冷光元件 的形成方法包含: 提供一玻璃基板; 形成且覆蓋一第一電極層於該玻璃基板之一表面上; 形成且定義複數個光阻層於該第一電極層上; 藉由該複數個光阻層當成複數個蝕刻罩幕蝕刻該第一電極 層以形成複數個陽極於該玻璃基板上; 移除該複數個光阻層; 形成一有機層於該複數個陽極上; 4 形成一具有金屬層之第二電極層於該有機層上以當成一陰 極層,且形成複數個有機發光元件於該玻璃基板之該表面 上; 進行一第一物理氣相沉積製程以共形生成一分子量約小於Page 26 1281361 _ Case No. 91922565_年月曰 Amendment__ VI. Patent Application Method The above-mentioned pot-shaped cover material consists of a metal material. The method of forming an organic electroluminescent element according to claim 4, wherein the material of the above-mentioned pot-shaped cover comprises a glass material. 4. The method of forming an organic electroluminescent device according to claim 4, wherein the material of the adhesive comprises a UV polymer. 4. The method of forming an organic electroluminescent device according to claim 42, wherein the water absorbing agent comprises a constituent oxide. A method of forming an organic electroluminescent element, comprising: providing a glass substrate; forming and covering a first electrode layer on a surface of the glass substrate; forming and defining a plurality of lights The first electrode layer is etched by the plurality of photoresist layers as a plurality of etching masks to form a plurality of anodes on the glass substrate; removing the plurality of photoresist layers; Forming an organic layer on the plurality of anodes; 4 forming a second electrode layer having a metal layer on the organic layer to form a cathode layer, and forming a plurality of organic light-emitting elements on the surface of the glass substrate; a first physical vapor deposition process is formed by conformal formation with a molecular weight of less than about 第27頁Page 27 1281361 --^^案號 91122565 六、申請專利範圍 1 0 0 0之有機介電層於該第二電極層上; 進打了第二物理氣相沉積製程以共形生成一具有反應活性 之保護層於該有機介電層上,以便於與水氣、氧氣與有機 溶劑等有害該複數個有機電冷光兀件之物質反應,其中, 該具有反應活性之保護層係為一功函數約小於4之材質; 與 藉由一黏著劑將一具有金屬材質之盆狀封蓋之蓋緣黏附於 該玻璃基板之一預定連接處,其中’該預疋連接處係位於 該複數個有機發光元件所在之該玻璃基板的該表面上’且 該盆狀封蓋之底蓋的表面約與該保護層相抵觸。 5 0 ·如申請專利範圍第4 9項所述之有機電冷光元件的形成 方法,其中上述之有機介電層的材質包含一聚合物。 5 1 ·如申請專利範圍第4 9項所述之有機電冷光元件的形成 方法,其中上述之具有反應活性之保護層包含一氧化物。 5 2 ·如申請專利範圍第$ 1項戶斤述之有機電冷光元件的形成 方法,其中上述之氧化物包含一鹼金族元素。 5 3 ·如申請專利範圍第$ 1項戶斤述之有機電冷光元件的形成 方法,其中上述之氧化物包含一鹼土族元素。 5 4 ·如申請專利範圍第4 9項戶斤述之有機電冷光元件的形成1281361 --^^ Case No. 91122565 6. The organic dielectric layer of the patent application range of 100 is applied to the second electrode layer; the second physical vapor deposition process is performed to form a reactive protection by conformalization. Laminating on the organic dielectric layer to facilitate reaction with moisture, oxygen and an organic solvent, which are harmful to the plurality of organic electroluminescent elements, wherein the reactive protective layer has a work function of less than about 4 a material; and a cover edge of a metal-shaped pot-shaped cover adhered to a predetermined joint of the glass substrate by an adhesive, wherein the pre-twisted joint is located at the plurality of organic light-emitting elements The surface of the bottom surface of the glass substrate and the surface of the bottom cover of the basin-shaped cover are in contact with the protective layer. The method of forming an organic electroluminescent device according to claim 49, wherein the material of the organic dielectric layer comprises a polymer. The method of forming an organic electroluminescent device according to claim 49, wherein the reactive protective layer comprises an oxide. 5 2 . The method of forming an organic electric luminescence element according to the scope of claim 1 wherein the oxide comprises an alkali metal element. 5 3 . The method of forming an organic electroluminescent element according to claim 1 wherein the oxide comprises an alkaline earth element. 5 4 ·Formation of organic electroluminescent elements such as the 49th item of the patent application scope 1281361 案號 91122565 年月曰 修正 六、申請專利範圍 方法,其中上述之盆狀封蓋的材質包含一玻璃材質。 5 5.如申請專利範圍第49項所述之有機電冷光元件的形成 方法,其中上述之黏著劑的材質包含一 UV聚合膠。 5 6 .如申請專利範圍第4 9項所述之有機電冷光元件的形成 方法,其中上述之吸水劑包含一構氧化物。 I _ I 第29頁1281361 Case No. 91122565 Issue rev. 6. Scope of application for patents The above-mentioned pot-shaped cover material consists of a glass material. 5. The method of forming an organic electroluminescent element according to claim 49, wherein the material of the adhesive comprises a UV polymer. The method of forming an organic electroluminescent device according to claim 49, wherein the water absorbing agent comprises a constituent oxide. I _ I第29页
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