TWI281281B - Manufacturing method of energy storing device with ultra high electrical energy storage - Google Patents

Abstract

The present invention relates to a manufacturing method of energy storing device. The energy storing device has a plurality of electrodes. The method includes steps of printing a pressure sensitive adhesive on a surface of the electrode in accordance with a pattern having a gasket and a plurality of spacer dots of a screen; stacking the electrodes with patterns, in which the opposite surfaces of the stacked electrodes are all printed with patterns; next sequentially immersing the electrodes in an electrolyte while stacking the electrodes; ventilating micro-quantity air left in the pores of the electrodes immersed in the electrolyte; and pressing the stacked electrodes immersed in the electrolyte.

Description

1281281 IX. Description of the Invention: [Technical Field] The present invention relates to a method of manufacturing an energy storage device, and more particularly to a method for manufacturing an energy storage device for ultra-high energy storage energy. ^ [Prior Art] A battery is a power supply device that directly converts a form of energy into electrical energy without an intermediate mechanical conversion process. A capacitor is an electronic component that stores a charge. In general, batteries are high in stored energy but low in output power, while • Capacitors are low in stored energy but high in output power. Therefore, the battery is regarded as an "energy storage device" for electric energy, and the capacitor is a "power storage device", which is used for different purposes. With the advent of 3C (computers, communications and consumer electronics), versatile, efficient, short and thin electronic products are readily available in life, such as laptops, mobile phones, and walkmans. In order to meet the requirements for portable and long-term use of electronic products, adequate portable energy supply is a key issue. A new energy storage device, a U1 tracapaci tor, was born. Conventional capacitors are produced by the separation of insulating materials or dielectrics between two conductors. Capacitance is produced by separating the charge on the surface of the conductor. The “Electrochemical Double Layer” (referred to as £01^) used in the ultracapacitor energy storage device has no separate material to establish the dielectric layer. The charging and energy storage occurs in the interface of the electric double layer. The ultra-capacitance can achieve higher energy density (Energy Density) than the traditional capacitor technology, and the ultra-high power density (Power 326\patent specification (supplement)\94·12\TF944531 5 1281281, the supercapacitor can release a hundred times the battery Ultra-capacitor can store more than a thousand times of electricity

Density). Compared to the power of a conventional battery; compared to conventional capacitors,

ΤΙ is an energy storage device that uses the Faraday charge transfer gasification 逖 original reaction to store energy. The flat principle structure and the charge double layer capacitor (the supercapacitor is different from metal nitride or oxide (specially “τ 、, '. Material, the material RuGx) as the electrode y, the inch is the metal nitrogen, the oxide electrode is powered by the electrons, and the original reaction produces the electron flow, and the water is used, and the water is used. The storage and release energy of the inlet and outlet electrodes: (0 Η the storage capacity is higher than the simple charge double-layer structure - the number = more energy can be temporarily stored; in addition, the electricity used by the virtual capacitor; the metal is metal nitrogen, oxidation (especially a sulphur compound), its conductive material..." 双层 Double-layer supercapacitor with activated carbon as the electrode material τ 八 ^ is poor (non-conductor), so the internal resistance of bismuth oxide is nternal Resistanee) Activated carbon supercapacitors are several orders of magnitude, and have a very strong pulse charge and discharge capability' greatly improving the effect of instantaneous power supply. From the above two points, the virtual capacitor has large charge and discharge current, high power, good efficiency and high energy storage; Double layer Capacitor can be charged and discharged with a small current volume and low energy storage density. It is only suitable for medium-charged and discharged power. The structure and its manufacturing method are as shown in the figure. The method of coating, printing, spraying, etc. of the case of the Chinese patent publication No. 501324 of the super-capacitive energy storage device of the conventional application is applied in the first and the 32nd patent specification (supplement)\94_]2\TF944531 6 1281281 Plastic wall, and then the first - Thunder isolation sheet, to avoid filling the electrolyte in the rubber wall of the positive and the j, and placing a winning wall to short circuit by ultrasonic or heating. The disadvantages of the two face to face, the first: must In the first: people ^ joint. This method has the following two isolation between the positive and negative electrode pads placed spacers, with the ultra-capacitor internal resistance " touch the road, so greatly increase

ResIstatc(e)nt;r:?eS1StanCe " 1 It is difficult to escape and lose, and the air trapped in the pores of the charging hole will also cause the capacitor to fail. In addition, it takes time and labor to run out of the program. , _ : Place the spacer to make the alignment difficult during manufacturing, especially (10) one: mass production; the spacers are placed in mutual interference, it is difficult to it: the valley is easy to float on the electrolyte, and the solution with the glue wall makes this Supercapacitor...::: Disadvantages: This is a charge storage unit (Ce(1) stack is limited to only one second, Republic of China Patent Notice No. 283273, m9 Patent No. US 5,384,685, etc. Printed by means of printing, etc., printed on the heart = Jielu dry accumulator knot, I on the imitation of the small dog (micr〇pr〇t = pattern for electrode isolation; another dielectric layer is placed around the electrode sheet (Dlelectric gasket ), and insert the combined body into the two plug sleeves, and then remove this: the block and the gap between the benefits become accessible space to facilitate the electricity ^. This practice has the following two shortcomings One: the cost of making and placing the seam sleeve & labor, In addition, it is difficult to match, in addition to low yield, mass production is more difficult. The second shortcoming is that the dry process depends on the pre-release block (C Shen 326 _ patent specification (supplement) \ 94 -12 VTF94453〗 Ί 1281281 to open the hole, and then after the vacuum is taken, the porous electrode material 2; =, in such a way, it is difficult to seal the product." § Fill the gap after the acid filling Putting two: M, especially after a long time of temperature variation and filling of the package, the reliability of the seal is very difficult to maintain. [Summary] = These problems are more prominent in the current trend of product downsizing: Problem 'The purpose of the present invention is to provide a method for manufacturing an ultra-high::...health energy device, which is automatically aligned and printed - ::π成' eliminates the cumbersomeness of placing spacers and dielectric plug sleeves. The steps of the work and the elimination of the above-mentioned multi-program alignment problems, in addition to greatly reducing the source of processing steps and variations, can also make automated mass production into a crescent can promote 3C electronic products to light and thin The extent of the present invention by single-time printing Copy the mask and the pattern of the Spacer dot to the electrode plate in exactly the same way. Because of the one, the printing, the alignment problem, the area of the frame rubber and the support point can be reduced. That is, the available area of the electrode can be increased to the maximum. The present invention utilizes the stacking and pressing technique under the surface of the π, which eliminates the trouble of filling the electrolyte and the problem of incomplete filling. The invention provides a method for manufacturing an energy storage device, which is formed by stacking a plurality of electrode sheets, and the method for manufacturing the energy storage device comprises the following steps: First, a pressure sensitive adhesive (pressureSensitive)

Adhesive) is printed on one surface of one of the electrode sheets according to a screen seal and a pattern of support points; then, the pattern is printed on the pattern 326\patent specification (supplement)\94_12\TF944531 1281281: Some of the electrodes stacked on the electrode sheets have patterns, and secondly, in the stack 4, the surface of the tenth surface is printed and the two-package pole pieces are simultaneously inserted into the electrolyte; then, the air is discharged. Immersion in the electrolyte ί::: sheet; traces of air remaining in the pores of the sheet; and, the electrode sheets that have been stacked in the sheet. & Port / Reentrant Electrolyte [Embodiment] A preferred embodiment of the present invention will be described with reference to 1. The energy storage device 31 of the annual ultra-N energy storage energy is formed by the integral sealing 5 of the surface material device of the electrode coated with the active material, or the surface energy device of the present invention. In the middle, Nie six women went to the next morning to print 2, + messed up. There are several double-sided or single-sided printed patterns on the moon. The surface of the film 1 and 2 has a number of prints and a frame of knees. . The energy storage device 31 of the present invention can be combined only by the upper surface pattern electrode sheet 1 of the watch, or one or more double-sided or single-sided Ρ pattern pen pieces can be inserted into the upper and lower two-electrode sheets 1 2 to ★ and people 6 ^ 1, 2 have a certain distance between each other; /,: " " in each piece of electrode W & ^ ^ and between each of the electrode sheets 1, 2 filled with electricity %, The energy storage device 31 is as follows: First, a pressure sensitive adhesive is prepared, and a certain proportion of the main agent (styrene-ethylene) styrene butene (SE/bs) elastomer copolymer is added and added. Maleic Anhydride, a tackifier and various solvents are poured into a stirred tank while mixing and heating until dissolved into a homogeneous phase to prepare the pressure sensitive adhesive. Next, the pattern is printed on the surface of the electrode sheet 2, which can be a screen 326\patent specification (supplement)\94^2VrF94453i 1281281 P screen printing, steel printing (stenc (1), one pad printing (" Stamp), - dispensing (Dlspensing), - coating (-g), a glue (PaSt 1) or - exposure imaging (Photol i thography) and other methods, the frame glue 4 and support points 5 and other patterns printed To the electrode sheet 2. As shown in the second figure, the screen (or steel plate) of the printing screen of the present invention, the screen or steel plate 7 is formed with a pattern of the printing frame glue 4 and the support point 5. 6. 帛 为本 为本 为本 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印

The suction source interface 9 pairs Ray y Q * 丄 L „ 17 generates suction on the pole piece 3 to fix it to the suction rule: ', and a positioning ejector pin 10 is used for positioning the electrode piece 3. The screen plate 7 is placed on the electrode sheet 3, and the soil is used to have m 〇^ and there is a gap between them. The pressure-sensitive moon is 8 placed on the screen plate 7 and the mountain wn 13 is on the net... 'Scraper mechanism 12 Move the squeegee blade 1 ύ y over the screen plate 7, and the 0u 6 of unu is scraped into the screen plate 7 by u, scraping the surface of the pattern 6 to form the frame 4 And the height of the pattern 6 of the second coat and the support point 5 is the net 5 version of the temple 7\=. The gap between the frame and the gazelle is also, and between the plate 7 and the electrode plate 3 >, and, in,, the printed frame glue 4 is the same height as the printed branch of the f, and the support point of the πI π I clothing is 5, and the height printed by it is 10"m in the brother's picture, except for the top one = pole piece 1 σ rm ° piece 1 and the last piece of electric Ϊ printing the early face frame glue 4 and the support point 5, the basin is on both sides of the bungee piece 2 or Single-sided printing on the frame glue 4 and branch:,,::, between, to print two The middle electrode piece: the pattern. If,, four, and w / r printed on one side of the picture 妳赍 #, 妳赍 326 \ patent specification (repair identification 2VrF94453! - (5 (M5CrC) volatilized part Solvent, and make Qian Sheng ^ 1281281 to be attractive, to benefit another 5 r's... Printed with the pattern. Print the frame glue 4 and the support point off I, the pole piece, and then pass the normal temperature or high temperature (9) Printed pressure sensitive adhesive 150 C) In the middle of the evaporation process, the electrodes of each piece...only:=min, the factory agent is excellent-the inter-species electrode sheet will have the following strength::=The medium force of the early surface is weak. ^ The white printed pattern between the electrode sheets is followed by 'printing the electrode sheet with the pattern = six in the "" stack electrode sheet!, 2^^^4) or heating (such as the label (5) method will sometimes be used to shorten the trace amount of two Air 3. Dissipate out. Measure the amount of air 3. The procedure of the independent C-stage of the above-mentioned dissipative micro-pile electrode sheet 2 is first paved. In the guide groove 22, the electrode sheet = the early bungee of the film The number of sheets required for the sheet 1 to be laid on the sheet is facing upwards. The sheet is connected to the guide groove (the middle sheet is electrically replaced with the surface sheet 2). (for example, all upwards)), early, the stack, the single-sided electrode sheet 1 of the time stamp is taken on the guide sample r'甫, and the patterned side faces down. These:: The purple piece is in the electrolyte. The stack of & 丄 uz is suitable for 70% of the solution, which is called the subsurface stacking. = The four figures are the ultrasonic waves of the invention (or the side view, for example, the above-mentioned printed figure 82). The structure of the pole piece 2 is dip in the word + after the 兀 ' ' ' will be printed in the various ultrasonic waves can be penetrated ^) liquid = glass tank 17 (or its mouth first electrode sheet 1, 2 Placed in the broken 326\patent specification (supplement)\94-12\TF94453l 1281281 埚盛札17 towel one of the shelves 19 'and then placed the glass tank 17 in the agricultural pure water 18 - ultrasonic shock Then, the trace air 30 remaining in the pore structure of the electrode sheet is dissipated by means of vacuum, (e.g., reference numeral 14) or heating (e.g., numeral 15). After the residual amount of air remaining in the pore structure of the electrode sheet is dissipated, the electrode sheet can be pressed, as shown in the sixth figure, which is shown in the side view of the pressing mechanism when the device is not pressurized. The present invention can also simultaneously perform a program and a procedure for dissipating a trace amount of air, as shown in the fifth figure, which is a side view of the structure of the guide groove containing the ultrasonic wave, ς =,: energy devices, in the second

The tank 22 is placed in the electrolyte tray I containing the electrolyte 23, and is stacked one by one in the guiding groove with the electrolyte 23, without the support frame s = placed in the fourth figure _ device 2. Then, the amount of trace air remaining in the electroporation structure is dissipated by the completion (such as the label (4) or the heating (such as the standard tiger 15). The trace air remaining in the pore structure of the dissipative electrode 2 Stacking of the electrode sheets 1, 2 · ^ also became the second two-order = the electrolyte containing the electrolyte 23 holds the tray 21 - placed in a 乂 2 = 5 set): the top, the pole ... Pie 2. No,, 曰, )) Apply repeated force (such as the number (4) in the sixth picture, when pressing the electrode piece, set the appropriate pressure 326\patent specification (supplement)\9'] 2\TF944531 12 1281281 It is transferred to the upper platen 25 to press the branch and the strong and the strong. The effect of increasing the pressing effect is 4, in order to shorten the dusting. The hoist can also be used for heating (such as the number 26) (room temperature ~ 100 The pressure-sensitive adhesive between the two pieces of the electrode piece 2 is connected. This 4, the framed glue 4 after the pressing and the support point _ cover and the limited shape are stored here @W叩二+, electrolyte package 'The situation of the 4th mountain, this I set early, such as the seventh picture is the storage of the invention

The side view of the Si's second-most mechanism is shown in the side view. The junction of the finished product of this device is stored in the first embodiment of the present invention. The energy storage device of the present invention is uniformly divided into D; ?,片卜2_,. Gan from the "one next electrode sheet 1 printed single-sided support point 5, the rest of the middle sheet of the electrode sheet early support" "point 5, and the support point surface and the lower surface are printed support The cloth needs to do two things: = position 妳 ^ When the anti-depression protection core piece 2 is also printed on only one side, the two methods are in the middle of each piece of electricity must be in the same direction - for example (all upwards). : 'Printed pattern - face type, triangular column type, multi-angle # point can be cylindrical type, square support point straight diagonal line length), for type II two. 5~2mm diameter, for Ruo Zhai It is used and enlarged, not subject to the above teeth '.,, and the size of 5 is also 〇. 5~5 points / cm ^ 2, the more commonly used is ^ Similarly, the frame glue 4 (such as the first - thousand square centimeters. 2 On the surrounding surface, except for the second f, the hook is distributed on the electrode sheet], except for the upper electrode piece and the lowermost electrode 326\patent specification (supplement)\9 this] 2vpF9445y]3 1281 281 pieces of 1 single-sided frame glue 4, the face is printed with a frame wins 4; the other = the middle electrode piece 2 is the same as the bottom of the electrode piece 2, the first method is the electrode piece 2 in the middle There is also a printed pattern on the side that must be hit in the heap, 〇.3~5.-, more commonly used. The glue 4 wire diameter is the square money public ϋΐΓ! Guard wire diameter. Especially large (such as the electrode month centimeters below The size of the electrode sheet is not limited to this. The square frame of the invention described in the present invention; 俨 styrene-butyl sulphide ... into the Γ styrene-ethylene and

, /, bearing 5 elastomers, adding maleic anhydride and other 鼗k I materials, in order to increase the adhesion of all the hydrophilic groups of the 卜 〜 一 一 一 一 一 一 一 一 一 一 一 一 一 一 一Appropriate amount = Tacky materiai and more than one type of cold backing] 'S week made of pressure sensitive adhesive 8 (one to 斛, ten, today e 胗 1 as the younger brother - not shown). Then apply the pressure sensitive adhesive 8 (10) method to the screen 4 on the screen and the support point 5 to the second electrode = to the electrode sheet, and then through the higher temperature state of the -Li gate to wave (four) printed pattern feeling _8 Contains the inside. The printed frame glue 4 盥 support point 5 円 Hong Tian 4 ^ 之 knife / name, force /, fork protection 2 5 pattern because the material is pressure sensitive adhesive, there is no viscous or sticky state Very low, not sticky to each other's system, it will not cause work troubles due to stickiness: ' 隹 and [5 days, by pressure or simultaneous heating (room temperature ~ 1 〇〇. 〇) P can The electrode sheets are fused to each other by a pattern of pressure sensitive adhesives 8 between the two sheets, and the electrolyte sheets are separated from each other while the electrolyte is coated. In addition, the pressure sensitive adhesive 8 needs to be combined with The electrolyte is contacted for a long time and passes through the process of line current and temperature rise and fall, and it will not react or deteriorate. The energy storage device 31 of the present invention directly uses the liquid 326\patent 5 (there is a supplement) in the immersion electrolyte program. ) \9句2\丁刚4 14 1281281 Stacked under the surface, into the electrolyte chamber: = electrolyte, the air in the process 30 will not entrain the vacuum or the heating side 4 2 after the reverse entry, first ultrasonic, pumping - The air 30 is dissipated ^ to the trace amount remaining in the pore structure of the electrode sheet b 2 • The electrolyte plate 21 is simultaneously used for super-wave pumping::: liquid. In Yi:; Pole piece I, 2, the pore junction is left blank;:;: The thermal program uses the liquid liquid system as the water-soluble electrolyte and the organic electrolysis water ===^ The electrolyte solution is various acids, the test Acid, mainly due to _ ^ / liquid. Acidic aqueous solution often uses sulfur. Period .0M, especially two V: ^ degree is the highest. Temple 疋 3~5M, mainly because of the concentration of sulfuric acid in the concentration of conductive Shi Maoming super Another energy storage device for energy storage is formed by an array of a plurality of electrodes, which is another storage slab of the invention. For example, the figure of the ninth garment is an exploded view of the vestibular limb assembly structure. Canfield W, in the upper and lower single-sided printed pattern electrode master 101, can be added to a number of double-sided or single-sided printing month iu, the surface of (8), (10) printed with several supports Point 1G5 piece and ^ electrode mother piece is made up of a plurality of frame glues J 04. The present invention /, and the periphery is printed with only the upper Dinggong p, the first of the energy storage device body 1 〇 6 may also be on; : The H-printed pattern electrode master 101 is combined, or the electrode master wafer m of the multi-month tapered pattern is inserted in the electrode master (10) of the early or late printed pattern. In the case of the shell yoke, the printing method of the electrode mother board and the H卩 brush material used (ie, the sense of Jing and the contents described in the second and third figures: make: = 15 3 2 patent 5 with the book (Supplement)\94-12 \TP9445 31 I28l28l::y / The difference is that the pattern of the screen is - the pattern of the H|7 system, the n-pole piece (as shown in the figure - as shown in the figure); :, a number of electric-electrode pieces are held on the mother's eve. The pattern of each body of the turtle pole piece is the same as that of the electrode of the first figure> {the pattern of the support point of the pad; the electrode (2) The width of the mask on the electrode sheet is required to be cut on the electrode sheet, and the electric 1 is slightly larger than the width of the sealant on the electrode of the electrode of the first figure. The power of the cutting _ the wide sound of the frame glue on the pole piece of Antu.

The process of stacking: In the example, the electrode mother board is immersed in the electrolyte one by one and: the second step of the second layer "# trace of residual trace air in the mother board = the same content is described] the electrode mother of this embodiment The stacking of the board is shown in the side view of the 15th mechanism when the hard-to-apply device is not filled with the ink in the invention. The inner electrode is the second phase, and the inner electrode is followed by the second phase R as described in the seventh figure. Composite energy storage of electrode master film

Z如弟十-图 is a side view of the structure of the finished product of the energy storage device of the present invention. The composite energy storage device body 106 is subjected to a cutting process after the pressing, as shown in the twelfth figure, the cutting energy storage device is cut by the cutter according to the present invention. The schematic diagram and the tenth three-third diagram show the schematic diagram of the composite energy storage device matrix i 0 6 - the device body 108. The composite energy storage device precursor 106 having the array-arranged electrode sheets is cut by a cutter 107 to form a single energy storage device body 1〇8 of each predetermined pattern, and the composite energy storage device mother body 1〇6 is before being cut. The width of the sealant to be cut is equal to or slightly twice the width of the sealant that is not to be cut, and the sealant after cutting may be slightly lost. 16 326\Patent Specification (Repair)\94-12\TF944531 1281281 The visibility, but does not affect the size of the single energy storage device body 丨〇8. The manufacture of the energy storage device of the present embodiment can be accomplished by the above various private sequences. The invention can be applied to a bipolar (B丨po丨ar) stack: in a multi-chamber stacking structure, a double-sided coated active coffin is shared adjacent to two electrolyte chambers: a pole piece to divide the two chambers . The stacked energy storage device is charged, and each of the middle gate electrodes is induced by the two end sheets, and the positive and negative electrodes are naturally formed on both sides thereof, and such push, that is, the number of stacked layers can be increased without an upper limit, Different stacking * g numbers reach any desired voltage (one to hundreds of volts). The advantages of .= Ming are in the process of automatic alignment, printing the complete isolation of the spacer and the dielectric plug sleeve, and eliminating the problem of alignment between the above multi-programs, in addition to the end source of Automated mass production and manufacturing becomes possible, and the pen products can be promoted to the sound of light and short, and the privateness of the smuggling. The present invention uses a single tracing, and the same as the frame glue and the punctuation point The figure is on the board. Because of the one-------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- The present invention simultaneously utilizes the deburring and the filling of the whisker and the filling with the electrolyte, V: 2:::: preferred specific examples and exemplary drawings, if ι should not be regarded as a system Restricted. 孰 戈 戈 戈 戈 戈 戈 戈 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及Exploded view of the structure of the dingyi; Π 326\patent specification (supplement)\94·]2\TF94453] 1281281 The second picture is The screen of the printing screen (or steel plate) of Ming Xi p; the second drawing of the invention is the side view of the printing mechanism of the invention; the screen (or steel plate) of the pattern of the electrode plate is shown in the figure Ultrasonic (or heating or vacuuming) tank junction storage "Shift = Minghe ultrasonic, heating or vacuuming mechanism, etc. Stacked storage:: Side view of the guiding groove of the Shi set; FIG. 7 is a side view of the pressing mechanism when the energy storage device of the present invention is not pressurized. The seventh view of the pressing mechanism after the adding force of the energy storage device of the present invention is a side view of the energy storage device of the present invention. Side view of the structure; Figure 9 shows the decomposition of the overall package structure of the other energy storage device of the present invention, and is a side view of the pressing mechanism of another energy storage device without pressure; τI& A side view of the structure of the finished product of the energy storage device of the present invention; = 12 is a schematic view of the energy storage device cut by the cutter according to the present invention; and a Le 13 diagram of the present invention cuts the mother of the composite energy storage device into A schematic diagram of a single storage device body. [Main component symbol description] 1 Pole piece 2 Electrode piece 3 Electrode sheet specification Patent 5 scription (supplement) \94-12\TF944531 18 1281281 4 Plastic frame 5 Support point 6 pattern. 7 Screen version 8 Pressure sensitive glue 9 Suction source interface 10 Positioning thimble * 11 suction fixture • 12 scraper mechanism 13 to blade 14 vacuum 15 heating 16 electrolyte 17 glass tank 18 pure water ^ 19 support frame 20 ultrasonic oscillator 21 electrolyte tray 22 guide groove - 23 electrolyte 24 pressure 25 upper plate 26 heating 27 lower plate

326\Patent Specification (Repair)\94-12\TF944531 19 1281281 30 Air 31 Energy Storage Device 101 Electrode Master 102 Electrode Master 104 Frame Glue 105 Support Point 106 Composite Energy Storage Device Parent 1 0 7 Cutter 108 Single Storage Device body

326\Patent specification (supplement)\94-12\TF944531 20

Claims (1)

1281281 X. The scope of application for patents: 1 · The most prolific pile of energy storage devices, ^ / , the energy storage device is composed of a plurality of energy storage devices, including the following steps: Some of the electrodes==the sizing and the tangential point of the electrode sheets, the stacked ruthenium surfaces of the electrode sheets are printed with a pattern; in the liquid while stacking the electrode sheets; The pole pieces are immersed in the electrolysis and immersed in the electrolyte to immerse the + trace air; and the remaining fins in the pores of the pole piece are immersed in the electrode sheets which have been stacked in the electrolyte. 2. The manufacturing method of the energy storage device, the pole piece stack A is made into a mystery. The clothing is made up of several electric wires: it is suitable, and an electrode mother piece is formed: The manufacturing method includes the following steps: The pressure sensitive adhesive is printed on the surface of the electrode master according to the pattern of the screen. The eclipse and the plurality of branch points are printed on the surface of the stack. The stacked < 3 surfaces of the electrode master are printed with a pattern; while the electrode master is stacked, the liquid will be filled; The current patent specification (supplement) in which the upper mother sheet is immersed in the pores of the mother electrode sheet which is immersed in the electrolytic solution to be immersed in the electrolyte is immersed in the electrolyte electrode from the 12VTF944531 factory and becomes a 21 electrode. 1281281 The energy storage device precursor; and the mother body for cutting the composite energy storage device is 3. The storage body of the patent application scope. Further, the main agent, a tackifier and a solvent are added: the method is prepared, and the pressure sensitive adhesive is prepared. The M W is uniformly mixed, and as in the health of the third item of the patent application, the main agent is a stupid ethylene-ethylene and X-coating method, and a maleic anhydride is added. Elastomer polymerization of enebutene 5. In the case of energy storage through the first or second aspect of the patent application, the manufacturing method of 赍, W々r 吨, /, hanging / phoenix or 50~1 50 The high temperature of 0c volatilizes one of the solvents in the printed enamel. Muhui I lost the printed pattern 6. As in the patent application range i, the early A, shell < abbreviated manufacturing method, 1, to the temperature to l ° ° C heating to press immersion The electrode sheets or the electrode master sheets which have been J4 stacked in the electrolyte. Further, in the method of manufacturing the energy storage device of the first or second aspect of the pile 7 in the pile 7 , the === or the opposite of the surface of the electrode master stacked on the surface, and on the surface of the crucible The distribution of the support points is bilaterally symmetric, vertically symmetrical, and positively antisymmetric. 1^ The manufacturing method of the energy storage device according to the first or second aspect of the patent scope of the patent, the column opening/supporting point is a cylindrical shape, a square column shape, a triangular column shape, a multi-angle main=ten pre-column shape, a hill shape and a hemisphere In the shape, etc., the 1 t of the support points is 〇·4~4.0_, and the distribution density of the support points is 0.5~5 points/cm 2 . 9. For the manufacturing method of the energy storage device of the δth item of the patent application, the patent specification is adopted (repair money mTF94453i 1281281, ~2·〇_, the support points: the diameter of the four support points is preferably The density of 〇 is 1 to 4 points/cm 2 . 10 · If the scope of the patent application is ,, the wire diameter of the seal is the manufacturer of the energy storage device of 〇· item. In the storage: h, the wire diameter of the seal is preferably: the manufacturing method of the garment, η 〇, , ^ J 0 mm 〇 12. If the patent application scope i method ', the sealant And the manufacturing method of the energy storage device of the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ' ^ Acid aqueous solution, the concentration of which is widely used in the energy storage device of claim 14 of the patent application, the infiltration of the sulfuric acid aqueous solution is preferably 3 heat 5. (10) - 16 · If the patent application scope is the seventh], Ben Gan Manufacturers of energy storage devices of 1 or 2 of the division, 2 - screen printing, - steel printing, - pad printing, a little glue , the glue is turned and the exposure is exposed to the towel - the feeling; the screen glue and the pattern of the points are printed on the surface of the electrode plate or the electrode master Π· 如 Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ Μ A small amount of air remaining in the pores. 326\Patent specification (supplement)\94-12\TF94453l 23 1281281 1 8. The method of manufacturing an energy storage device according to the second aspect of the patent application, wherein the cutter is cut, One of the laser cutting, plasma cutting, wire cutting, and punching processes cuts the composite energy storage device precursor. 326\Patent specification (supplement)\94-12\TF944531 24