TWI277961B - Optical storage medium, optical recording method and optical recording apparatus - Google Patents

Optical storage medium, optical recording method and optical recording apparatus Download PDF

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Publication number
TWI277961B
TWI277961B TW94100164A TW94100164A TWI277961B TW I277961 B TWI277961 B TW I277961B TW 94100164 A TW94100164 A TW 94100164A TW 94100164 A TW94100164 A TW 94100164A TW I277961 B TWI277961 B TW I277961B
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Taiwan
Prior art keywords
recording
power
reflectance
optical recording
recording medium
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TW94100164A
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Chinese (zh)
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TW200525532A (en
Inventor
Kenichi Shimomai
Kazuo Yonehara
Ikuo Matsumoto
Kenji Tokui
Hiroshi Tabata
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Victor Company Of Japan
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Priority claimed from JP2004370807A external-priority patent/JP2005243213A/en
Priority claimed from JP2004379539A external-priority patent/JP2005243217A/en
Application filed by Victor Company Of Japan filed Critical Victor Company Of Japan
Publication of TW200525532A publication Critical patent/TW200525532A/en
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Publication of TWI277961B publication Critical patent/TWI277961B/en

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Abstract

The invention relates to an optical storage medium, optical recording method and optical recording apparatus. That is, the invention provides an optical recording medium by which satisfactory recording characteristics are obtained even if recording speed is accelerated and overwrite recording characteristics for once or a plurality of times are excellently maintained. A phase transition type optical recording medium A is provided with a substrate 1 and a recording layer 3 having a track for recording information. Materials constituting the recording layer are initialized at a crystallized state so that an amplitude value of a difference signal (tracking detection signal) between both receiving signals obtained by receiving reflection light when the recording layer is irradiated with laser light at an off track state while rotating the optical recording medium by a group of first and second light receiving elements arranged opposite to the track becomes smaller than a saturation value of the amplitude value.

Description

1277961 (1) 九、發明說明 【發明所屬之技術領域】 本發明係關於一種藉由光(例如雷射光)之照 行資訊之記錄、消除、再生之光記錄媒體、光記錄 光記錄裝置。特別是本發明係關於一種在光碟、光 之可重寫之相變化型記錄媒體,在以高線速度(高 來進行光記錄時,得到良好之重寫特性之光記錄媒 記錄方法及光記錄裝置。 【先前技術】 所謂相變化型光記錄媒體係例如近年來之CD -DVD — RW或DVD — RAM,能夠重寫資訊之媒體。 在其中,DVD — RW或DVD — RAM係主要使用在例 資訊之大資訊量者之記錄、重寫。在相變化型光 體,除了良好之記錄特性以外,也要求良好之重寫1 相變化型光記錄媒體係在具有記錄•再生或消 各個功率之雷射光所照射之面成爲底面之基板上至 地層積介電質層、記錄層、介電質層和反射層之構 錄層係在藉由濺鍍法等而進行成膜後,即刻成爲低 之非結晶質狀態。因此,在製品出貨時,爲了成爲 率之結晶化狀態,因此,進行雷射光照射等而進 化。 向來之可重寫之相變化型光記錄媒體之記錄方 如以下。藉由在前面敘述所構成之相變化型光記錄 射而進 方法及 卡片等 倍速) 體、光 -RW、 即使是 如影像 記錄媒 宇性。 除用之 少依序 造。記 反射率 高反射 行啓始 法係正 媒體, -5- (2) (2)1277961 在記錄時,以記錄功率之雷射光’來施加(照射)記錄脈 衝至記錄層,熔融及急冷記錄層’而形成非結晶之記錄標 記。該記錄標記之反射率係低於結晶狀態之記錄層之反射 率,因此,可以使得該記錄標記呈光學地成爲記錄資訊而 進行讀取。在消除該記錄標記之狀態下,可以藉由照射功 率(消除功率)小於記錄功率之雷射光,藉由使得記錄層 成爲結晶化溫度以上之溫度,由非結晶狀態開始成爲結晶 狀態,而消除記錄標記,進行重寫。 在日本專利第 2962052號公報(專利文獻1 ),提 議:以記錄密度之提升和重複記錄特性之提升來作爲目的 而規定未記錄部之反射率和記錄部之反射率之啓始化方 法;但是,並無關於相對於高線速度記錄之光記錄媒體之 啓始化方法之記載。此外,本發明人係確認:僅在專利文 獻1所記載之條件,使得在對於近年來之高記錄密度媒體 之高速度記錄之重寫特性(特別是第1次重寫之特性)變 得不充分。 在曰本特開2003 — 1 62 82 1號公報(專利文獻2 ),提 議:以在高線速度記錄之良好之抖動特性或重寫特性來作 爲目的而規定藉由直流雷射之最適當消除功率所得到之最 大消除率和在小於這個之消除功率之消除率間之差値之光 記錄媒體。此外,在日本特開2003 - 228 84 1號公報(專 利文獻3 ),提議:以使用在標記形成時之消除功率和標 記間反射率之變化關係來作爲根本並且規定最適當消除功 率之記錄方法及光記錄媒體。但是,本發明人係確認:僅 -6 - (3) 1277961 在專利文獻3所提議之條件,無法得到在高線速度記錄、 具體地說DVD之4倍速(線速度:14m/ s )以上之充分 之重寫特性(特別是第1次重寫之特性)。 【專利文獻1】日本專利第2 9 6 2 0 5 2號公報 【專利文獻2】日本特開2003 — 162821號公報 【專利文獻3】日本特開2003—228841號公報 Φ 【發明內容】 • 〔發明所欲解決之課題〕 , 正如前面敘述,在習知之光記錄媒體及光記錄方法, 有所謂在進行1次重寫時之抖動呈大幅度地惡化並且在重 寫超過數百次時而抖動特性呈惡化之問題發生,不容易充 分地確保在高線速度記錄之重寫特性。 因此’本發明係爲了解決前述問題而創作的,其目的 係提供一種即使是記錄速度成爲高速度化(例如DVD之4 • 倍速(線速度·· 14m/ s )以上之高記錄線速度)也可以得 到良好之記錄特性並且還能夠良好地維持1次或複數次之 重寫記錄特性之光記錄媒體、光記錄方法及光記錄裝置。 ‘ 〔用以解決課題之手段〕 •爲了解決前述課題,因此,本發明係提供一種以下之 (a)〜(h)之光記錄方法、光記錄裝置及光記錄媒體。 (a ):—種光記錄媒體,其特徵爲:在相變化型光 記錄媒體(A ),具備:基板(1 );以及,具有用以記錄 (4) 1277961 資訊之軌道之記錄層(3 );此外,構成前述記錄層之材 料係以旋轉前述光記錄媒體同時接受在前述記錄層以偏離 軌道狀態來照射雷射光時之反射光所得到之追蹤檢測訊號 之振幅値(SO )小於其飽和値(S 1 )之結晶化狀態,來進 行啓始化。 (b ) : (a)所記載之光記錄媒體,其特徵爲:前述 追蹤檢測訊號係藉由在對於前述軌道呈對向配置之第1及 Φ 第2受光元件群(341a〜341d)接受前述反射光而得到之 • 受光訊號之兩者之差異訊號。 ^ ( c ) : ( a )或(b )所記載之光記錄媒體,其特徵 爲:前述振幅値除以前述飽和値之値係大於 0.6、小於 1.0。 (d ):—種光記錄媒體,其特徵爲:在相變化型光 記錄媒體(A ),具備:基板(1 );以及,用以記錄資訊 之記錄層(3 );此外,前述記錄層係使得在一次也並無 φ 記錄前述記錄層之資訊之未記錄部來施加具有既定之直流 消除功率之光後而照射再生光之所得到之前述未記錄部之 反射率,成爲前述既定之直流消除功率,在由功率0開始 依序地增大時,呈現以既定之曲線來進行變化之特性;前 述既定之曲線係具有:反射率槪略成爲一定之直線部;接 續於該直線部之反射率增大之第1曲線部;以及,反射率 減少之第2曲線部;此外,在成爲前述直線部和第1曲線 部間之境界之彎曲點(Q 1 )之反射率R0、成爲前述第1 曲線部和第2曲線部間之境界之波峰點(Q2 )之反射率 (5) 1277961 R1時,呈現成立下列公式(1 )之特性:〇· 〇3 $ (( RO ) / R0 ) $ 0.1 5 …(1 )。 (e ) : ( d )所記載之光記錄媒體,其特徵爲: 前述記錄層之材料係以在1個軌道內之反射率槪略成 定之結晶化狀態,來進行啓始化。 (f ):一種光記錄方法,其特徵爲:在相變化 記錄媒體(A )之記錄層(3 )將記錄資訊予以記錄之 錄方法,前述光記錄媒體係使得前述記錄層,在一次 無記錄前述記錄層之資訊之未記錄部來施加具有既定 流消除功率之光後而照射再生光之所得到之前述未記 之反射率,成爲前述既定之直流消除功率,在由功率 始依序地增大時,呈現以既定之曲線來進行變化之特 前述既定之曲線係具有:反射率槪略成爲一定之直線 接續於該直線部之反射率增大之第1曲線部;以及, 率減少之第2曲線部;此外,在成爲前述直線部和第 線部間之境界之彎曲點(Q 1 )之反射率R0、成爲前迸 曲線部和第2曲線部間之境界之波峰點(Q2 )之反 R1時,呈現成立下列公式(1 )之特性:〇·〇3 S (( R〇 ) / RO ) S 0.15…(1 ):前述光記錄方法係包含 變前述記錄資訊而生成調變資料之調變步驟;根據前 變資料而生成要求之標記長度之標記長度生成步驟 及’根據前述標記長度,而生成由形成在從消除 (Pe )開始上升並且介於大於前述消除功率之記錄 (Pw )和小於前述消除功率之基底功率(Pb )間之記 R1 - 構成 爲一 型光 光記 也並 之直 錄部 〇開 性; 部; 反射 1曲 ;第1 射率 R1 - ••調 述調 :以 功率 功率 錄脈 (6) (6)1277961 衝(Tt()p、Tmp)以及由前述基底功率開始上升至前述消除 功率之消除脈衝(Tel)所構成之記錄脈衝圖案’對於前述 記錄層,來配合於前述記錄脈衝圖案,照射記錄光,而記 錄顯示前述記錄資訊之記錄標記之記錄步驟;此外,前述 記錄步驟係當令在前述記錄脈衝圖案之前述消除功率爲Pe 而前述彎曲點之消除功率爲p1時,使用下列公式(2 )成 立之消除功率Pe:0.5SPe/PlS1.0 …(2)。 (g ) —種光記錄裝置,其特徵爲:在相變化型光記 錄媒體(A )之記錄層(3 )將記錄資訊予以記錄之光記錄 裝置,前述光記錄媒體係使得前述記錄層,在一次也並無 記錄前述記錄層之資訊之未記錄部來施加具有既定之直流 消除功率之光後而照射再生光之所得到之前述未記錄部之 反射率,成爲前述既定之直流消除功率,在由功率〇開始 依序地增大時,呈現以既定之曲線來進行變化之特性;前 述既定之曲線係具有:反射率槪略成爲一定之直線部;接 續於該直線部之反射率增大之第1曲線部;以及,反射率 減少之第2曲線部;此外,在成爲前述直線部和第1曲線 部間之境界之彎曲點(Q1 )之反射率R〇、成爲前述第1 曲線部和第2曲線部間之境界之波峰點(Q2 )之反射率 R1時,呈現成立下列公式(1 )之特性:〇.〇3$((111-RO ) / R0 ) ^0.15…(1 );前述光記錄裝置係包含:調 變前述記錄資訊而生成調變資料之編碼器(42 );根據前 述調變資料而生成要求之標記長度之標記長度生成部 (41);以及,根據前述標記長度’而生成由形成在從消 -10- (7) 1277961 除功率(Pe )開始上升並且介於大於前述消除功率之記錄 功率(Pw)和小於前述消除功率之基底功率(Pb)間之曰己 錄脈衝(Tt〇P、Tmp)以及由前述基底功率開始上升至前述 消除功率之消除脈衝(T e i )所構成之記錄脈衝圖案,對於 前述記錄層’來配合於前述記錄脈衝圖案’照射記錄光’ 而記錄顯示前述記錄資訊之記錄標記之記錄部(400 ); 此外,前述記錄部係當令在前述記錄脈衝圖案之則述消除 φ 功率爲Pe而前述彎曲點之消除功率爲P 1時,使用下列公 • 式(2)成立之消除功率 Pe: 0.5SPe/PlS1.0… . (2) ° (h ) : (g)所記載之光記錄裝置’其特徵爲:具 備:儲存顯示前述消除功率Pe之辨識資訊之儲存部 (451);前述記錄部係使用根據儲存於前述儲存部之前 述辨識資訊所造成之消除功率。 βι 〔發明之效果〕 即使是記錄速度成爲高速度化’也可以得到良好之記 錄特性,並且,即使是進行1次或複數次之重寫,也能夠 良好地維持記錄特性。 【實施方式】 〔發明之最佳實施形態〕 第1圖係顯示用以製造相變化型光記錄媒體之製造設 備3 00或者是藉由製造設備3 00所進行之製造•啓始化製 -11 - (8) (8)1277961 程之圖。在製造裝置1 00 (製造製程),製造相變化型光 記錄媒體,在啓始化裝置200 (啓始化製程)’對於相變 化型光記錄媒體來進行啓始化。經過啓始化製程之相變化^ 型光記錄媒體係出貨成爲光記錄媒體A。 作爲相變化型光記錄媒體係列舉DVD - RW等之相變 化型光碟、光卡片等之能夠對於資訊重複地進行重寫之媒 體。此外,在以下之說明,作爲相變化型光記錄媒體之某 一實施形態係使用相變化型光碟(光記錄媒體 A ),但 是,即使是就具有相同於這個以外之光卡片等之同樣構造 之相變化型光記錄媒體而言,不用說當然也可以適用本發 明。 《光記錄媒體之構造》 第2圖係顯示成爲本發明之某一實施形態之光記錄媒 體A之擴大剖面圖。光記錄媒體A、作爲其基本構造係在 記錄•再生或消除用雷射光所入射之入射面la成爲底面 之基板1上,依序地層積第1保護層2、記錄層3、第2 保護層4、反射層5、第3保護層6。 作爲基板1之材料係可以使用各種透明之合成樹脂、 透明玻璃等。爲了避免塵埃之附著或基板1之損傷等之影 響,因此,使用透明基板丨,藉著集光之雷射光而由基板 1之入射面1 a側開始,在記錄層3來記錄資訊。作爲此種 基板1之材料係列舉例如玻璃、聚碳酸酯、聚甲基•甲基 丙烯酸酯、聚烯烴樹脂、環氧樹脂、聚醯亞胺樹脂等。特 -12- (9) 1277961 別是由光學之複折射及吸濕性變小、成形變得容易來看的 話,則最好是聚碳酸酯樹脂。 基板1之厚度係並無特別限定,但是,在考慮和DVD 間之相容性時,則最好是0.01mm〜〇.6mm,即使是在其 中,也最佳理想是〇.6mm ( DVD之全厚度係1.2mm )。這 個係由於如果基板1之厚度未滿0.0 1 m m的話,則即使是 在藉著由基板1之入射面1 a側開始聚焦之雷射光而進行 φ 記錄之狀態下,也容易受到灰塵之影響之緣故。此外,如 , 果在光記錄媒體之全厚度不具有限制的話,則可以在實用 上,成爲 〇·〇 1 mm〜5 mm之範圍內。如果是 5 mm以上的 話,則不容易使得接物透鏡之開口數變大,照射雷射光之 點尺寸變大,因此’不容易提筒記錄密度之緣故。 基板1係可以是撓性的,也可以是剛性的。撓性基板 1係使用在帶狀、薄片狀、卡片狀之光記錄媒體。剛性基 板1係使用在卡片狀或碟片狀之光記錄媒體。 • 第1保護層2及第2保護層4係發揮在記錄時因爲熱 而使得基板1、記錄層3等發生變形來惡化記錄特性等之 由於熱來保護基板1、記錄層3之效果’或者是發揮由於 光學之干涉效果而改善再生時之訊號明亮度之效果。 第1保護層2及第2保護層4係最好是分別對於記錄 •再生或消除用之雷射光成爲透明而使得折射率n位處在 1.9 S η $ 2.3之範圔。此外,由熱特性之方面來看的話, 則第1保護層2及第2保護層4之材料係最好是S i 〇2、 SiO、ZnO、Ti〇2、Ta2〇5、Nb2〇5、Zr〇2、MgO 寺之氧化 — -13- (10) 1277961 物、ZnS、In2S3、TaS4 等之硫化物、SiC、TaC、WC,TiC 等之碳化物之單體及混合物。即使是在其中,ZnS和Si02 之混合膜係即使是由於記錄、消除之重複也不容易引起記 錄感度、C / N、消除率等之惡化,因此,變得特別理想。 此外,第1保護層2及第2保護層4係可以皆不成爲 相同之材料、組成,也可以由異種之材料所構成。 第1保護層2之厚度係大約5nm〜5 00nm之範圍。此 外,因爲不容易由基板1或記錄層3來剝離、不容易發生 破裂等之缺陷,因此,第1保護層2之厚度係最好是 20nm〜300nm之範圍。在更加薄於20nm時,不容易確保 碟片之光學特性,在更加厚於3 00nm時,變差於生產性。 此外,更加理想是3 0 n m〜8 0 n m之範圍。 由於C / N、消除率等之記錄特性良好、能夠穩定地 進行許多次之重寫,因此,第2保護層4之厚度係最好是 5nm〜40nm之範圍。在更加薄於5nm時,不容易進行記 錄層3之熱確保,因此,上升最適當記錄功率,在更加厚 於40nm時,導致重寫特性之惡化。更加理想是 8nm〜 2 0 n m之範圍。 記錄層 3 係 Ag— In - Sb— Te 合金或 Ge— In— Sb - Te 合金、或者是在Ge— In— Sb— Te合金至少包含1種Ag或 Si、A1、Ti、Bi、Ga之其中任何一種之合金層。此外,記1277961 (1) Description of the Invention [Technical Field] The present invention relates to an optical recording medium for recording, erasing, and reproducing information of light (e.g., laser light), and an optical recording optical recording apparatus. In particular, the present invention relates to an optical recording medium recording method and optical recording which are excellent in rewriting characteristics when optical recording is performed at a high linear velocity (high-speed) in a rewritable phase change recording medium for optical discs and light. [Prior Art] A phase change type optical recording medium is, for example, a CD-DVD-RW or a DVD-RAM in recent years, which is capable of rewriting information media. Among them, a DVD-RW or a DVD-RAM system is mainly used in an example. Recording and rewriting of information-intensive information. In addition to good recording characteristics, phase-change light bodies also require good rewriting. One-phase change optical recording media is capable of recording, reproducing, or eliminating power. The recording layer on the substrate from which the surface irradiated by the laser light is formed on the bottom surface to the ground dielectric layer, the recording layer, the dielectric layer and the reflective layer is formed immediately after being formed by sputtering or the like. Therefore, in order to achieve a crystallization state at the time of product shipment, laser light irradiation or the like has evolved. The recording of a rewritable phase change optical recording medium has been conventionally recorded. As follows. With the above described configuration of the phase change type optical recording method and an exit and into a card speed, etc.), a light -RW, even if the image recording medium of buildings. In addition to using less order. Recording reflectance high reflection line initiation method positive media, -5- (2) (2)1277961 At the time of recording, the recording pulse is applied (irradiated) to the recording layer by the laser light of the recording power, and the recording layer is melted and quenched. An amorphous recording mark is formed. The reflectance of the recording mark is lower than the reflectance of the recording layer in the crystalline state, so that the recording mark can be optically recorded as information to be read. In a state where the recording mark is eliminated, laser light having an irradiation power (elimination power) smaller than the recording power can be used, and the recording layer becomes a crystalline state by a temperature higher than the crystallization temperature, thereby eliminating the recording. Mark and rewrite. Japanese Patent No. 2962052 (Patent Document 1) proposes an initializing method for specifying the reflectance of an unrecorded portion and the reflectance of a recording portion for the purpose of improving the recording density and improving the repeat recording characteristics; There is no record of the initiation method of the optical recording medium recorded with respect to the high line speed. In addition, the inventors of the present invention have confirmed that the rewriting characteristics (especially the characteristics of the first rewriting) of the high-speed recording of the high recording density medium in recent years are not made only by the conditions described in Patent Document 1. full. In Japanese Patent Laid-Open Publication No. 2003-62 62 No. 1 (Patent Document 2), it is proposed to specify the most appropriate elimination by DC laser for the purpose of recording good jitter characteristics or rewriting characteristics at high line speeds. An optical recording medium having a maximum cancellation rate obtained by power and a difference between the elimination rates of powers less than this. In addition, Japanese Laid-Open Patent Publication No. 2003-228 84 (Patent Document 3) proposes a recording method that uses the change relationship between the cancellation power at the time of mark formation and the reflectance between marks as a fundamental and specifies the most appropriate power cancellation. And optical recording media. However, the present inventors have confirmed that only -6 - (3) 1277961 is not able to obtain a high linear velocity recording, specifically a 4x speed (linear velocity: 14 m/s) of a DVD, under the conditions proposed in Patent Document 3. Full rewrite features (especially the characteristics of the first rewrite). [Patent Document 1] Japanese Patent Laid-Open Publication No. JP-A No. 2003-228841 (Patent Document 3) JP-A-2003-228841. The problem to be solved by the invention] As described above, in the conventional optical recording medium and optical recording method, there is a so-called jitter that is greatly deteriorated when performing one rewriting and is shaken when rewriting more than several hundred times. The problem of deterioration of characteristics occurs, and it is not easy to sufficiently ensure the rewriting characteristics at high line speed recording. Therefore, the present invention has been made to solve the above problems, and an object thereof is to provide a high recording speed which is high in speed (for example, a recording speed of 4/double speed (linear speed··14 m/s) or higher). An optical recording medium, an optical recording method, and an optical recording apparatus which are excellent in recording characteristics and which can satisfactorily maintain one or more times of rewriting recording characteristics. 「 [Means for Solving the Problems] In order to solve the above problems, the present invention provides the following optical recording methods (a) to (h), an optical recording apparatus, and an optical recording medium. (a): an optical recording medium characterized by: a phase change type optical recording medium (A) comprising: a substrate (1); and a recording layer having a track for recording (4) 1277961 information (3) Further, the material constituting the recording layer is such that the amplitude 値(SO) of the tracking detection signal obtained by rotating the optical recording medium while receiving the reflected light when the recording layer is irradiated with the off-track state to emit the laser light is smaller than the saturation thereof. The crystallization state of 値(S 1 ) is initiated. (b) The optical recording medium according to (a), wherein the tracking detection signal is received by the first and Φ second light receiving element groups (341a to 341d) disposed opposite to the track. The difference between the two signals received by the reflected light. (c) The optical recording medium according to (a) or (b), wherein the amplitude 値 divided by the saturation enthalpy is greater than 0.6 and less than 1.0. (d): an optical recording medium characterized by: a phase change optical recording medium (A) comprising: a substrate (1); and a recording layer (3) for recording information; and further, the recording layer The reflectance of the unrecorded portion obtained by applying the light having a predetermined DC canceling power to the unrecorded portion which does not have the information of the recording layer at a time, and which is irradiated with the reproducing light, is the predetermined DC. Eliminating the power, when sequentially increasing from the power 0, exhibiting a characteristic that changes with a predetermined curve; the predetermined curve has a linear portion in which the reflectance is slightly constant; and the reflection subsequent to the straight portion a first curved portion having an increased rate; and a second curved portion having a reduced reflectance; and a reflectance R0 at a bending point (Q 1 ) which is a boundary between the straight portion and the first curved portion 1 The reflectance of the peak point (Q2) of the boundary between the curve part and the second curve part (5) 1277961 R1, the characteristic of the following formula (1) is established: 〇· 〇3 $ (( RO ) / R0 ) $ 0.1 5 ... (1 ). (e) The optical recording medium according to (d), wherein the material of the recording layer is initialized in a crystallized state in which the reflectance in one track is slightly determined. (f): an optical recording method characterized by recording a recording information in a recording layer (3) of a phase change recording medium (A), wherein the optical recording medium causes the recording layer to be recorded at one time The unrecorded portion of the information of the recording layer is applied to the unrecorded reflectance obtained by irradiating the reconstructed light with light having a predetermined stream canceling power, and becomes the predetermined DC canceling power, which is sequentially increased from the power. When the time is large, the predetermined curve is changed according to a predetermined curve: the first curve portion in which the reflectance is a constant straight line and the reflectance of the straight portion is increased; and the rate is decreased. In addition, the reflectance R0 of the bending point (Q 1 ) which is the boundary between the straight line portion and the line portion is the peak point (Q2) of the boundary between the front curve portion and the second curve portion. When R1 is reversed, the following formula (1) is established: 〇·〇3 S (( R〇) / RO ) S 0.15 (1 ): The optical recording method described above includes changing the aforementioned recording information to generate modulated data. Modulation step; root Generating a mark length generation step of the required mark length according to the prior variable data and generating a record (Pw) formed at a rise from the elimination (Pe) and greater than the aforementioned cancellation power and less than the aforementioned elimination according to the aforementioned mark length The power between the base power (Pb) of the power R1 - is composed of a type of light and light, and the direct recording part is split; the part; the reflection 1 curve; the 1st rate R1 - •• the modulation: the power Recording pulse (6) (6) 1279961 rushing (Tt()p, Tmp) and a recording pulse pattern formed by the cancellation of the aforementioned substrate power to the aforementioned cancellation power (Tel) for the recording layer The recording pulse pattern is irradiated with recording light, and a recording step of recording the recording mark indicating the recording information is recorded; and the recording step is performed when the erasing power of the recording pulse pattern is Pe and the erasing power of the bending point is p1 The elimination power Pe: 0.5SPe/PlS1.0 (2) is established using the following formula (2). (g) an optical recording apparatus characterized in that an optical recording apparatus records recording information on a recording layer (3) of a phase change optical recording medium (A), wherein the optical recording medium causes the recording layer to The unrecorded portion that records the information of the recording layer at a time does not reflect the reflectance of the unrecorded portion obtained by irradiating the reconstructed light with a predetermined DC canceling power, and becomes the predetermined DC canceling power. When the power 〇 is sequentially increased, the characteristic is changed by a predetermined curve; the predetermined curve has a linear portion in which the reflectance is slightly constant; and the reflectance subsequent to the linear portion is increased. a first curved portion; and a second curved portion having a reduced reflectance; and a reflectance R〇 at a bending point (Q1) which is a boundary between the straight portion and the first curved portion, and the first curved portion and When the reflectance R1 of the peak point (Q2) of the boundary between the second curved portions, the characteristic of the following formula (1) is established: 〇.〇3$((111-RO) / R0 ) ^0.15...(1); The aforementioned optical recording device package An encoder (42) for generating the modulated data by modulating the record information; generating a mark length generating portion (41) of the required mark length based on the modulated data; and generating the mark length based on the mark length From -10- (7) 1277961, the power (Pe) starts to rise and is greater than the recording power (Pw) greater than the aforementioned cancellation power and the base power (Pb) less than the aforementioned cancellation power (Tt〇P) And Tmp) and a recording pulse pattern formed by the cancellation of the aforementioned power to the cancellation power (T ei ), and recording and displaying the recording for the recording layer 'incorporating the recording pulse pattern 'irradiated recording light' The recording unit of the information recording mark (400); wherein the recording unit is configured to eliminate the φ power of Pe in the recording pulse pattern and the power of the bending point is P 1 , the following public formula (2) is used. (2) ° (h): (g) The optical recording device described in the present invention is characterized in that: the display includes the display of the aforementioned cancellation power Pe. The identification information storage unit (451); the system using the recording section stored in said storage unit before the identification information resulting from the elimination of power. ι 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果 效果[Embodiment] [Best Embodiment of the Invention] Fig. 1 shows a manufacturing apparatus 3 for manufacturing a phase change optical recording medium or a manufacturing apparatus by manufacturing equipment 00. - (8) (8)1277961 The map of Cheng. In the manufacturing apparatus 100 (manufacturing process), a phase change type optical recording medium is manufactured, and the start-up apparatus 200 (initiation process) is initialized to the phase change type optical recording medium. The phase change optical recording medium that has undergone the initialization process is shipped as the optical recording medium A. As the phase change type optical recording medium, a medium which can repeatedly rewrite information such as a phase change type optical disc such as a DVD-RW or a light card can be used. In the following description, a phase change type optical disc (optical recording medium A) is used as an embodiment of the phase change optical recording medium. However, even if it has the same configuration as the optical card or the like other than this, It is needless to say that the phase change type optical recording medium can also be applied to the present invention. <<Structure of Optical Recording Medium>> Fig. 2 is an enlarged cross-sectional view showing an optical recording medium A according to an embodiment of the present invention. The optical recording medium A, as a basic structure thereof, sequentially stacks the first protective layer 2, the recording layer 3, and the second protective layer on the substrate 1 on which the incident surface 1a on which the laser light is incident on the recording/reproducing or eliminating laser light is bottomed. 4. The reflective layer 5 and the third protective layer 6. As the material of the substrate 1, various transparent synthetic resins, transparent glass, or the like can be used. In order to avoid the influence of adhesion of dust or damage of the substrate 1, etc., the transparent substrate 丨 is used to record information on the recording layer 3 from the incident surface 1 a side of the substrate 1 by the collected laser light. Examples of the material of the substrate 1 include glass, polycarbonate, polymethyl methacrylate, polyolefin resin, epoxy resin, and polyimide resin. Special -12- (9) 1277961 It is preferably a polycarbonate resin because the optical birefringence and hygroscopicity are small and the molding becomes easy. The thickness of the substrate 1 is not particularly limited. However, when considering compatibility with a DVD, it is preferably 0.01 mm to 〇6 mm, and even in it, it is preferably 〇.6 mm (DVD) The full thickness is 1.2mm). In this case, if the thickness of the substrate 1 is less than 0.01 mm, it is easily affected by dust even in the state where φ recording is performed by laser light that is focused by the incident surface 1a side of the substrate 1. reason. Further, if it is not limited to the full thickness of the optical recording medium, it can be practically in the range of 1 mm to 5 mm. If it is 5 mm or more, it is not easy to increase the number of openings of the lens of the receiving lens, and the size of the spot for irradiating the laser light becomes large, so that it is not easy to pick up the recording density. The substrate 1 may be flexible or rigid. The flexible substrate 1 is used in an optical recording medium having a strip shape, a sheet shape, or a card shape. The rigid substrate 1 is used in a card-shaped or disc-shaped optical recording medium. The first protective layer 2 and the second protective layer 4 exhibit the effect of protecting the substrate 1 and the recording layer 3 due to heat due to deformation of the substrate 1 and the recording layer 3 due to heat during recording. It is an effect of improving the brightness of the signal during reproduction due to the interference effect of the optical. Preferably, the first protective layer 2 and the second protective layer 4 are transparent to the laser light for recording/reproducing or eliminating, respectively, such that the refractive index n is at 1.9 S η $ 2.3. Further, in terms of thermal characteristics, the material of the first protective layer 2 and the second protective layer 4 is preferably S i 〇 2, SiO, ZnO, Ti 〇 2, Ta 2 〇 5, Nb 2 〇 5, Zr〇2, oxidation of MgO Temple—13- (10) 1277961, sulfides of ZnS, In2S3, TaS4, etc., and monomers and mixtures of carbides such as SiC, TaC, WC, TiC, etc. Even in this case, the mixed film of ZnS and SiO 2 is particularly difficult to cause deterioration in recording sensitivity, C / N, elimination rate, and the like even if it is repeated due to recording or elimination. Further, the first protective layer 2 and the second protective layer 4 may not be the same material or composition, and may be composed of a different material. The thickness of the first protective layer 2 is in the range of about 5 nm to 500 nm. Further, since the substrate 1 or the recording layer 3 is not easily peeled off, and defects such as cracking are unlikely to occur, the thickness of the first protective layer 2 is preferably in the range of 20 nm to 300 nm. When it is thinner than 20 nm, it is not easy to ensure the optical characteristics of the disc, and when it is thicker than 300 nm, it is deteriorated in productivity. Further, it is more desirable to be in the range of 3 0 n m to 8 0 n m. Since the recording characteristics such as C / N and the elimination rate are good and the rewriting can be performed many times stably, the thickness of the second protective layer 4 is preferably in the range of 5 nm to 40 nm. When the thickness is thinner than 5 nm, the heat of the recording layer 3 is not easily secured. Therefore, the optimum recording power is increased, and when the thickness is more than 40 nm, the overwrite characteristics are deteriorated. More preferably, it is in the range of 8 nm to 2 0 n m. The recording layer 3 is an Ag—In—Sb—Te alloy or a Ge—In—Sb—Te alloy, or the Ge—In—Sb—Te alloy contains at least one of Ag or Si, A1, Ti, Bi, and Ga. Any alloy layer. In addition, remember

錄層3之層厚係最好是10nm〜25 nm。在層厚度更加薄於 1 Onm時,降低結晶化速度,高速度記錄特性變差,在更 加厚於2 5 n m之際,在記錄時,需要大的雷射功率。 -14- (11) 1277961 可以設置接合於記錄層3之單面或兩面之界面層。作 爲界面層之材料係重要地不包含硫物質。在使用包含硫物 質之材料來作爲界面層時,由於重寫之重複而使得包含於 界面層之硫來擴散至記錄層3中,惡化記錄特性,因此, 變得不理想。此外,由所謂消除特性不良好之方面來看的 話,則也變得不理想。 作爲界面層之材料係最好是包含氮化物、氧化物、碳 化物中之至少1種之材料,具體地說,最好是包含氮化 鍺、氮化矽、氮化鋁、氧化鋁、氧化锆、氧化組、氧化 鉻、碳化矽、碳中之至少1種之材料。此外,可以在這些 材料,含有氧、氮、氫等。前述氮化物、氧化物、碳化物 係可以不是化學計量組成,也可以是氮、氧、碳呈過剩或 不足。會有由於這個而不容易剝離界面層來提高保存耐久 性等之提高界面層特性等之狀態發生。 作爲反射層5之材料係列舉:具有光反射性之A1、 Au、Ag等之金屬、以這些金屬作爲主成分而包含1種以 上之金屬或者是由半導體所構成之添加元素之合金、以及 在這些金屬混合Al、Si等之金屬氮化物、金屬氧化物、 金屬硫屬化物等之金屬化合物者等。 即使是在其中,由於能夠使得光反射性變高並且熱傳 導度變高,因此,最好是A卜Au、Ag等之金屬和以這些 :$:屬作爲主成分之合金。作爲合金之例子係一般是在A1 混合 Si、Mg、Cu、Pd、Ti、Cr、Hf、Ta、Nb、Mn、Zr 等 之至少1種元素者、或者是在Au或Ag混合Cr、Ag、The layer thickness of the recording layer 3 is preferably 10 nm to 25 nm. When the layer thickness is thinner than 1 Onm, the crystallization speed is lowered, and the high-speed recording characteristics are deteriorated. When the thickness is further increased to 2 5 n m, a large laser power is required at the time of recording. -14- (11) 1277961 An interface layer bonded to one side or both sides of the recording layer 3 may be provided. The material used as the interface layer is importantly free of sulfur species. When a material containing a sulfur substance is used as the interface layer, sulfur contained in the interface layer is diffused into the recording layer 3 due to repetition of overwriting, and the recording characteristics are deteriorated, so that it is not preferable. In addition, it is also unsatisfactory in terms of the so-called elimination characteristics. The material of the interface layer is preferably a material containing at least one of a nitride, an oxide, and a carbide. Specifically, it preferably contains tantalum nitride, tantalum nitride, aluminum nitride, aluminum oxide, and oxidation. A material of at least one of zirconium, an oxidation group, chromium oxide, tantalum carbide, and carbon. Further, these materials may contain oxygen, nitrogen, hydrogen, and the like. The nitride, the oxide, and the carbide may not be a stoichiometric composition, and may be excessive or insufficient in nitrogen, oxygen, or carbon. There is a state in which the interface layer is not easily peeled off to improve the durability of the storage layer, etc., and the state of the interface layer is improved. The material of the reflective layer 5 is a metal having a light-reflective A1, Au, Ag, or the like, an alloy containing one or more kinds of metals as a main component or an additive element composed of a semiconductor, and These metals are mixed with a metal compound such as a metal nitride such as Al or Si, a metal oxide or a metal chalcogenide. Even in this case, since light reflectivity can be made high and heat conductivity is high, it is preferable to use a metal such as A, Au, or Ag, and an alloy containing these :$: genus as a main component. As an example of the alloy, generally, at least one element such as Si, Mg, Cu, Pd, Ti, Cr, Hf, Ta, Nb, Mn, Zr, or the like is mixed in A1, or Cr, Ag is mixed in Au or Ag.

/〇N -15- (12) 1277961/〇N -15- (12) 1277961

Cu、Pd、Pt、Ni、Nd、In、Ca等之至少 1種元素者等。 但是,在考慮高線速度記錄之狀態下,由記錄特性之方面 來看的話,則最好是以熱傳導係數特別高之Ag來作爲主 成分之金屬或合金。 但是,在反射層5使用純銀或銀合金之狀態下’抑制 AgS化合物之生成,因此,接合於反射層5之層係最好是 使用不含有S之材料。 φ 反射層5之厚度係由於形成反射層5之材料之熱傳導 - 係數之大小而發生變化,但是,最好是50nm〜300nm。如 果反射層5之厚度成爲5 Onm以上的話,則反射層5係並 無呈光學地發生變化,對於反射率之値不造成影響,但 是,在增加反射層5之厚度時,對於冷卻速度之影響變 大。此外,形成超過30 Onm之厚度者係在製造上,需要時 間。因此,藉由使用高度之熱傳導係數之材料而儘可能地 控制反射層5之層厚度至最適當範圍。 φ 在此,在第2保護層4使用ZnS和Si02之化合物而 在反射層5使用Ag或Ag合金之狀態下,最好是在第2 保護層4和反射層5之間,插入擴散防止層(並未圖 示)。這個係因爲抑制由於第2保護層4中之S和反射層 5中之Ag間之化學反應所生成之AgS化合物而造成之反 射率之降低之緣故。 作爲擴散防止層之材料係相同於前述界面層,呈重要 地不包含硫物質之材料,具體之材料係相同於界面層之材 料。 -16- (13) 1277961 《光記錄媒體之製造方法》 接著,就製造裝置100之光記錄媒體之製造方法而進 行敘述。 作爲將第1保護層2、記錄層3、第2保護層4、反射 層5等層積於基板1上之方法係列舉在習知之真空中之薄 膜形成法。例如真空蒸鍍法(電阻加熱型或電子束型)、 % 離子植入法、濺鍍法(直流或交流濺鍍、反應性濺鍍), , 特別是組成、層厚度之控制變得容易,因此,最好是灘鍍 • 法。 此外,最好是使用在真空槽內同時地對於複數個基板 1來進行成膜之間歇法或者是使用每一片地處理基板1之 扇葉式成膜裝置。所形成之第1保護層2、記錄層3、第2 保護層4、反射層5等之層厚度之控制係藉由控制濺鍍電 源之投入功率和時間、或者是以水晶振動型膜厚計來監視 φ 堆積狀態,而容易地進行層厚之控制。 此外,第1保護層2、記錄層3、第2保護層4、反射 層5等之形成係可以進行於固定基板1之狀態或者是移 動、旋轉之狀態之任何一種。由於具有良好之層厚度之面 &gt; 內之均一性,因此,最好是自轉基板1,更加理想是還組 , 合公轉。在配合於需要而進行基板1之冷卻時,可以減少 基板1之彎曲量。 此外,可以在不顯著地損害本發明之效果之範圍內, 在形成反射層5等之後,配合於需要,設置由於已經形成 -17- (14) (14)1277961 之各層之變形防止等而使用ZnS、Si02等之介電質層或紫 外線硬化樹脂等之樹脂保護層,來作爲第3保護層6。 然後,可以同樣還準備1片之形成各層之基板1,藉 由接著劑等而貼合2片之基板1,成爲兩面之光記錄媒 體。 接著,光記錄媒體A係經過啓始化裝置200之啓始化 製程,成爲光記錄媒體A而進行出貨。啓始化係在記錄層 3照射雷射光、氣閃光燈等之光,進行加熱,使得記錄層 3之構成材料來進行結晶化。由於再生雜訊變少,因此, 最好是藉由雷射光所造成之啓始化。 在第3圖,顯示光記錄媒體A之俯視圖。光記錄媒體 A係具有中心孔5 1及其外圍之夾緊區域5 2。在夾緊區域 52之外圍,在同心圓上,設置資訊區域(導入區域)53, 並且,其外圍區域係成爲用以記錄影像資訊或聲音資訊等 之實際資料之記錄區域5 4。在此,導入區域5 3係可以是 ROM狀態或RAM狀態之任何一種。除此之外,也有藉由 在用以得到追蹤訊號之雷射導引溝槽來形成高頻擺動或孔 洞而儲存成爲再生專用之記錄資訊之方法。 《光記錄媒體之記錄方法》 在第4圖,顯示在光記錄媒體A記錄資訊時之所使用 之記錄脈衝圖案。根據記錄脈衝圖案而以3個値(記錄功 率Pw、消除功率Pe、基底功率Pb )之雷射強度,來調變 雷射光,對應於記錄訊號之標記長度而增減脈衝數’將要 -18- (15) 1277961 求之標記長度之記錄標記來形成在記錄層3。雷射強度係 記錄功率Pw變得最大,依照消除功率pe、基底功率Pb 之順序而變小。 記錄脈衝圖案係正如第4圖所示,由消除功率P e開 始上升而最初在記錄層3以記錄功率Pw來施加雷射光之 前頭脈衝Tt()p、成爲接續於前頭脈衝Tt()p之脈衝而交互地 施加記錄功率Pw和基底功率Pb之多重脈衝Tmp、以及由 基底功率Pb開始上升雷射光而位處於施加消除功率pe之 終端之消除脈衝Tu所構成。前頭脈衝Tt()p和多重脈衝 Tmp係成爲用以對於記錄層3來形成記錄標記之記錄脈 衝。此外,也有並非多重脈衝Tmp而僅藉由前頭脈衝Tt()p 來形成記錄脈衝之狀態發生。 例如在DVD — RW,標記長度係有3T、4T、5T、6T、 7T、8T、9T、10T、1 IT、14T之10種類。在標記長度成 爲nT之狀態下,多重脈衝Tmp之數目係一般成爲(n — 1)或(η - 2)。在第 4圖’顯不(η— 2)之狀態。在 此,所謂Τ係單位時脈,在DVD — RW,在DVD之1倍速 時(記錄線速度:3.5m/ s ),成爲lT=38.2ns,在DVD 之4倍速時(記錄線速度:14 · 0m / s ),成爲1T二 9.6 n s 〇 此外,隨著近年來之高速度化記錄而使得單位時脈Τ 變短成爲數ns位級,因此’可以考慮雷射脈衝之上升· 下降之響應限度而使用第5圖所示之以2T作爲基準之記 錄脈衝圖案。在第5圖,顯示:用以形成記錄脈衝A具有 -19- (16) 1277961 3T之標記長度、記錄脈衝B具有Π T之標記長度及記錄 脈衝C具有1 4 Τ之標記長度之記錄標記之記錄脈衝圖案° 《光記錄裝置》 在第6圖,顯示成爲用以將具有要求之記錄脈衝圖案 之雷射光照射在光記錄媒體Α之本發明之某一實施形態之 光記錄裝置。 首先,轉軸馬達3 1係旋轉光記錄媒體A。控制旋轉 控制部3 2而使得轉軸馬達3 1之旋轉數成爲對應於目的之 記錄速度之記錄線速度。此外,具備使用在光記錄媒體A 之記錄•再生或消除之半導體雷射(LD ) 3 3或者是對於 LD33之雷射光來進行集光照射之接物透鏡(並未圖示) 以及4分割受光元件(並未圖示)之光學頭34係可自由 移動地設置在光記錄媒體A之半徑方向。 此外,作爲使用在本實施形態之光記錄裝置之記錄用 光源係最好是正如雷射光、頻閃光之高強度光源。即使是 在其中,也由於光源能夠小型化、消耗電力變小、容易進 行調變,因此,最好是半導體雷射光。 光學頭34之4分割受光元件341係在光記錄媒體 A,接受由LD33所照射之雷射光之反射光。4分割受光元 件341係根據受光之光而生成推挽訊號,輸出至擺動檢測 部3 6。此外,4分割受光元件3 4 1係根據受光之光而將聚 焦錯誤訊號及追蹤錯誤訊號來輸出至驅動控制器44。此 外,成爲4分割受光元件34 1之合成訊號之再生訊號係輸 -20- (17) (17)1277961 出至反射率檢測部46。 驅動控制器44係根據供應之聚焦錯誤訊號及追蹤錯 誤訊號而控制致動器控制部3 5。致動器控制部3 5係控制 光學頭3 4對於光記錄媒體A之聚焦及追蹤。反射率檢測 部46係根據供應之再生訊號而檢測反射率,將檢測結果 來輸出至系統控制器45。 擺動檢測部3 6係具備可程式化帶通濾波器(BPF ) 3 6 1,將檢測之擺動訊號輸出至位址解調電路3 7。位址解 調電路3 7係由檢測之擺動訊號來解調位址而進行輸出。 輸入解調之位址之記錄時脈生成部3 8係具有PLL合成器 電路3 8 1,生成記錄通道時脈而輸出至記錄脈衝生成部3 9 及脈衝數控制部40。 記錄時脈生成部3 8係藉由驅動控制器44而進行控 制。驅動控制器44係也控制著旋轉控制部3 2、致動器控 制部3 5、擺動檢測部3 6、位址解調電路3 7及系統控制器 45 ° 驅動控制器44係將由擺動檢測部3 6所供應之擺動訊 號,來輸出至記錄時脈生成部3 8。此外,將由位址解調電 路37所供應之位址資訊,來輸出至系統控制器45。 系統控制器45係具有記憶體45 1,控制著EFM +編 碼器42、標記長度計數器41、脈衝數控制部40及LD驅 動器部43。EFM +編碼器42係對於輸入之記錄資訊來進 行8 - 1 6調變,成爲調變資料,輸出至記錄脈衝生成部3 9 及標記長度計數器4 1。標記長度計數器4 1係啓動成爲根 -21 - (18) 1277961 據調變資料而計數既定之標記長度之標記長度生成部,將 其計數値輸出至記錄脈衝生成部3 9及脈衝數控制部40。 脈衝數控制部40係控制記錄脈衝生成部3 9而根據供應之 計數値和記錄通道時脈,來使得記錄脈衝成爲既定之脈 衝。 記錄脈衝生成部3 9係具備前頭脈衝控制訊號生成部 3 9t、多重脈衝控制訊號生成部3 9m和消除脈衝控制訊號 φ 生成部39c。分別使得前頭脈衝控制訊號生成部39t生成 - 前頭脈衝控制訊號,多重脈衝控制訊號生成部3 9m生成多 ^ 重脈衝控制訊號,消除脈衝控制訊號生成部39c生成消除 脈衝控制訊號。各個控制訊號係供應至LD驅動器部43, 開關部4 3 1係藉由根據供應記錄功率Pw之驅動電流源 4 3 1 w、消除功率P e之驅動電流源4 3 1 e和基底功率P b之 驅動電流源43 1 b之控制訊號而進行開關,來生成記錄脈 衝圖案。 • Pw驅動電流源43 1 w、Pe驅動電流源43 le及Pb驅動 電流源43 1 b係根據記憶於系統控制器45之記憶體45 1之 記錄功率Pw、消除功率Pe及基底功率Pb而供應電流至 光學頭3 4。這些之3個値係用以使得光記錄媒體A之記 錄特性變得良好之最適當値,顯示該最適當値之辨識資訊 係也可以預先儲存在記憶體4 5 1,或者是藉由更新而進行 儲存,或者是利用反射率檢測部4 6而進行求出及儲存。 此外’記憶體4 5 1係例如R Ο M ( R e a d Ο η 1 y M e m 〇 r y (唯讀 g己憶體))或可 g己錄之 RAM (Random Access Memory -22- (19) 1277961 (隨機存取記憶體))。 但是,本實施形態之光記錄裝置係用以能夠對應於光 記錄媒體之高線速度(高倍速)化而設定由複數個記錄線 速度中之所選擇之記錄線速度。系統控制器45係在輸入 用以選擇記錄線速度(倍速模式)之指示訊號時’相同於 前面敘述,根據記億於記憶體45 1之指示之記錄線速度之 辨識資訊而控制 Pw驅動電流源43 1 w、Pe驅動電流源 4 3 1 e及P b驅動電流源4 3 1 b。在記憶體4 5 1,正如前面敘 述,儲存複數個記錄線速度之辨識資訊。 生成之記錄脈衝圖案係輸入至光學頭34。光學頭34 係藉由進行控制,來使得LD 3 3輸出要求之記錄脈衝圖案 及功率比ε ( Pw/ Pe)之LD發光波形,而將記錄資訊來 記錄於光記錄媒體A。 記錄脈衝生成部3 9和LD驅動器部43及光學頭3 4係 根據藉由標記長度計數器4 1所生成之標記長度,而生成 由形成在從消除功率P e開始上升並且介於大於消除功率 Pe之記錄功率Pw和小於消除功率Pe之基底功率Pb間之 記錄脈衝以及由基底功率Pb開始上升至消除功率Pe之消 除脈衝所構成之記錄脈衝圖案,對於記錄層3,由LD3 3 開始,來配合於記錄脈衝圖案,照射記錄光,成爲將顯示 記錄資訊之記錄標記予以記錄之記錄部400而進行動作。 《啓始化功率之檢討》 本發明人係推測:在啓始化裝置200,在對於光記錄 -23- (20) (20)1277961 媒體來進行啓始化時之啓始化用雷射之功率(啓始化功 率)是否對於光記錄媒體A之記錄及重寫特性來造成影 響;根據下列之實施例1〜實施例3及比較例1、比較例2 而發現··其推論變得正確,具有記錄及重寫特性變得最佳 之啓始化功率。 在本實施形態,以在偏離軌道狀態之差異訊號(追蹤 檢測訊號)之振幅’來檢討光§3錄媒體A之啓始化狀態。 此外,所謂偏離軌道狀態係指將再生用之雷射光照射於光 記錄媒體A而使得藉由該雷射光所造成之點光不追蹤於軌 道之狀態(所謂不施加追蹤之狀態)。 正如第7圖所示,4分割受光元件3 4 1係由受光元件 341 a〜341d所構成。由受光元件341a、341b所構成之第 1受光元件群和由341c、341d所構成之第2受光元件群係 進行配置而對於軌道呈對向(也就是在半徑方向)。照射 至光記錄媒體A之點光係反射於光記錄媒體A,藉由受光 元件341a〜341d而進行受光。在藉由受光元件 341a、 3 4 1 b、3 4 1 c、3 4 1 d進行受光所輸出之受光訊號(電流値) 分別成爲la、lb、Ic、Id之狀態下,差異訊號振幅係可以 藉由下列之公式(1 )而進行定義。在公式(1 ) ,AC係 顯示公式之右邊成爲交流。 差異訊號之振幅=丨(Ia+Ib) -(Ic+Id)| AC··· (1) 通常在旋轉光記錄媒體A同時再生資訊時,LD3 3係 在呈螺旋狀(或直線狀)地形成於光記錄媒體A之基板1 之軌道(溝槽)上,照射具有再生功率Pr之雷射光,在 -24- (21) 1277961 軌道追蹤集光該雷射光之點光。將該狀態稱爲對準軌道狀 態。接著,在點光以對準軌道狀態來追蹤於溝槽或接端面 中心之際,回復至4分割受光元件3 4 1之回復光量(I a + lb )和(Ic + Id )呈相等而使得差異訊號(追蹤檢測訊 號)之値係成爲〇,無法得到振幅。也就是說,4分割受 光元件之輸出係成爲一定。* 但是,在旋轉光記錄媒體A同時在再生資訊時無法追 φ 蹤來自LD33之點光於軌道而成爲將光學頭34固定於一定 . 位置之狀態(偏離軌道狀態)之情況下,在4分割受光元 _ 件之回復光量,產生差異,差異訊號(追蹤檢測訊號)之 振幅輸出係顯示第8圖之週期變動。第8圖係藉由示波器 而觀測在偏離軌道狀態下之差異訊號。該變動係在光記錄 媒體A,呈螺旋狀地刻劃溝槽,因此,溝槽相對於點光之 位置係發生由於按照光記錄媒體A之旋轉而呈週期性地產 生變化。 φ 第9圖係顯示偏離軌道狀態相對於啓始化時之照射在 光記錄媒體之直流雷射之雷射功率(啓始化功率)之差異 訊號振幅。在對於既定之光記錄媒體而依序地增大照射之 啓始化功率時,差異訊號振幅係成爲描劃圖示之曲線之特 性。在該曲線,存在即使是增大啓始化功率也不增大差異 訊號振幅之飽和點S 1。成爲第9圖所示之特性者係由於 藉由啓始化功率之強度(大小)來構成記錄層3之材料之 結晶構造發生變化之緣故。此外,也由於差異訊號振幅是 否成爲飽和點S 1而使得記錄層3之結晶構造呈不同。 -25- (22) (22)1277961 此外,在差異訊號振幅不達到至飽和點S 1之啓始化 功率P0,啓始化之狀態之光記錄媒體A之差異訊號振幅 成爲SO,在該狀態之記錄層3照射具有大於P0之功率之 直流雷射之狀態下,差異訊號振幅係隨著第9圖之曲線而 增大。認爲這個係由於藉著再度照射直流雷射而提高記錄 層3之結晶化程度之緣故。 由於藉著本發明人所造成之實驗•硏究之結果而判 明:在差異訊號振幅不達到至飽和點S 1之啓始化功率 P0,在啓始化之光記錄媒體A而藉由最適當條件來進行記 錄之狀態下,1次(初次)記錄後(DOWO ·· Direct Over Write (直接重寫))之抖動變得良好,此外,即使是在 進行1次重寫後之(DO W1 )抖動及重複進行重寫後之抖 動,也得到良好之特性。 另一方面,判明:在差異訊號振幅達到至飽和點S 1 之啓始化功率P 1以上而對於光記錄媒體A來進行啓始化 之狀態下,DO W0之抖動變得良好,但是,DO W1之抖動 變得非常差,無法得到良好之重寫特性。 在此敘述之所謂重寫係單束重寫,係指藉由1次之雷 射掃描而消除以前形成之記錄標記,形成新的記錄標記。 接著,DO W0係指對於啓始化之光記錄媒體A之未記錄部 來形成記錄標記之初次記錄,D0W1係指還形成記錄標記 至這裡之第1次重寫。此外,定義抖動賦予至錯誤率之不 良影響變少之1%以下之値來成爲良好,將由DOWO開始 涵蓋至DOW 1 000 (由初次記錄開始至重寫千次爲止)而 -26- (23) (23)1277961 穩定地得到10%以下之抖動者,定義成爲良好之DOW抖 動特性。 但是,即使是在對於光記錄媒體A來進行啓始化時之 所施加之啓始化功率成爲未知之狀態下,正如以下,也可 以判別:光記錄媒體A是否以達到至差異訊號振幅之飽和 點S 1之啓始化功率P 1以上之啓始化功率來進行啓始化或 者是以成爲不滿足於飽和點S 1之啓始化功率P0來進行啓 始化。首先,就啓始化之光記錄媒體A而言,測定偏離軌 道狀態之差異訊號振幅。接著,可以在光記錄媒體A,施 加使得測定所得到之差異訊號振幅超過企圖得到之啓始化 功率之啓始化功率直流雷射,測定偏離軌道狀態之差異訊 號振幅,來比較兩者之差異訊號振幅。 本實施形態,其特徵爲:在進行啓始化後之偏離軌道 狀態之差異訊號振幅,小於其飽和値S 1。其實現手段之 適當之某一例子係使得使用在啓始化時之雷射光之啓始化 功率,變小成爲不達到至作爲飽和値S 1之啓始化功率P 1 之程度。 在以下之各個實施例及各個比較例,使用搭載波長 658 nm之雷射二極體、ΝΑ=0·60之光學透鏡之脈衝科技 公司製之光碟驅動測試器(DDU 1 000 )而進行記錄(1光 束•重寫)及再生。 記錄線速度係14m/ s (相當於DVD - RW規格之4倍 速),記錄訊號係使用8 — 1 6 ( EFM + )調變隨機圖案而 進行記錄再生評價。單位時脈T係9.6ns ( DVD之4倍At least one element such as Cu, Pd, Pt, Ni, Nd, In, Ca, or the like. However, in the state in which high-speed recording is considered, it is preferable to use a metal or alloy having Ag having a particularly high thermal conductivity as a main component in terms of recording characteristics. However, in the state where the reflective layer 5 is made of pure silver or a silver alloy, the formation of the AgS compound is suppressed. Therefore, it is preferable to use a material which does not contain S in the layer bonded to the reflective layer 5. The thickness of the φ reflective layer 5 varies depending on the heat conduction coefficient of the material forming the reflective layer 5, but is preferably 50 nm to 300 nm. If the thickness of the reflective layer 5 is 5 Onm or more, the reflective layer 5 does not change optically, and does not affect the reflectance. However, when the thickness of the reflective layer 5 is increased, the influence on the cooling rate is exerted. Become bigger. In addition, it is necessary to form a thickness of more than 30 Onm in manufacturing. Therefore, the layer thickness of the reflective layer 5 is controlled as much as possible to the most appropriate range by using a material having a high thermal conductivity. φ Here, in the state where the compound of ZnS and SiO 2 is used for the second protective layer 4 and the Ag or Ag alloy is used for the reflective layer 5, it is preferable to insert a diffusion preventing layer between the second protective layer 4 and the reflective layer 5. (not shown). This is because the reflection rate due to the AgS compound formed by the chemical reaction between S in the second protective layer 4 and Ag in the reflective layer 5 is suppressed. The material as the diffusion preventing layer is the same as the above-mentioned interface layer, and is a material which does not substantially contain a sulfur substance, and the specific material is the same as the material of the interface layer. -16- (13) 1277961 "Manufacturing Method of Optical Recording Medium" Next, a method of manufacturing the optical recording medium of the manufacturing apparatus 100 will be described. The method of laminating the first protective layer 2, the recording layer 3, the second protective layer 4, the reflective layer 5, and the like on the substrate 1 is a film forming method in a conventional vacuum. For example, vacuum evaporation (resistance heating or electron beam type), % ion implantation, sputtering (DC or AC sputtering, reactive sputtering), especially the composition and layer thickness control becomes easy. Therefore, it is best to apply the beach plating method. Further, it is preferable to use a batch method of forming a film for a plurality of substrates 1 simultaneously in a vacuum chamber or a blade type film forming apparatus for processing the substrate 1 for each sheet. The layer thickness of the first protective layer 2, the recording layer 3, the second protective layer 4, and the reflective layer 5 formed is controlled by controlling the input power and time of the sputtering power source, or by using a crystal vibration type film thickness meter. To monitor the φ accumulation state, it is easy to control the layer thickness. Further, the formation of the first protective layer 2, the recording layer 3, the second protective layer 4, the reflective layer 5, and the like may be performed in a state in which the substrate 1 is fixed or in a state of being moved or rotated. Since the surface having a good layer thickness &gt; is uniform, it is preferable to rotate the substrate 1, and it is more preferable to further group and revolve. When the substrate 1 is cooled as needed, the amount of bending of the substrate 1 can be reduced. Further, in the range in which the effect of the present invention is not significantly impaired, after the formation of the reflective layer 5 or the like, it is possible to provide a deformation prevention or the like due to the formation of each layer of -17-(14)(14)1277961. A dielectric protective layer such as ZnS or SiO 2 or a resin protective layer such as an ultraviolet curable resin is used as the third protective layer 6. Then, one substrate 1 on which each layer is formed can be prepared in the same manner, and two substrates 1 are bonded together by an adhesive or the like to form optical recording media on both sides. Then, the optical recording medium A is initialized by the initialization device 200, and becomes the optical recording medium A to be shipped. In the recording layer 3, light such as laser light or gas flash lamp is irradiated and heated to crystallize the constituent material of the recording layer 3. Since the amount of regenerative noise is small, it is preferable to initiate by laser light. In Fig. 3, a plan view of the optical recording medium A is shown. The optical recording medium A has a center hole 5 1 and a clamping region 52 of its periphery. On the periphery of the clamp area 52, on the concentric circle, an information area (import area) 53 is provided, and the peripheral area thereof is a recording area 54 for recording actual information such as image information or sound information. Here, the lead-in area 533 may be any one of a ROM state or a RAM state. In addition to this, there is also a method of storing recording information dedicated to reproduction by forming a high-frequency wobble or hole in a laser guiding groove for obtaining a tracking signal. <<Recording Method of Optical Recording Medium>> In Fig. 4, the recording pulse pattern used when recording information on the optical recording medium A is displayed. The laser light is modulated by the laser intensity of three 値 (recording power Pw, cancellation power Pe, base power Pb) according to the recording pulse pattern, and the number of pulses is increased or decreased corresponding to the mark length of the recording signal. (15) 1277961 The recording mark of the mark length is formed on the recording layer 3. The laser intensity is such that the recording power Pw becomes maximum, and becomes smaller in the order of the cancel power pe and the base power Pb. The recording pulse pattern is as shown in FIG. 4, and the head pulse Tt()p is caused by the erasing power P e and is initially applied to the recording layer 3 at the recording power Pw before the head light Tt()p, which is connected to the head pulse Tt()p. The multiple pulses Tmp of the recording power Pw and the substrate power Pb are alternately applied by pulse, and the canceling pulse Tu at the terminal of the applied cancellation power pe is started by rising the laser light from the base power Pb. The leading pulse Tt()p and the multi-pulse Tmp are used as recording pulses for forming recording marks for the recording layer 3. Further, there is also a state in which the recording pulse is formed by the front pulse Tt()p instead of the multiple pulse Tmp. For example, in DVD-RW, the mark length is 10 types of 3T, 4T, 5T, 6T, 7T, 8T, 9T, 10T, 1 IT, and 14T. In the state where the mark length is nT, the number of the multiple pulses Tmp is generally (n - 1) or (η - 2). In the state of Fig. 4, the state of (η - 2) is shown. Here, the unit time of the Τ system is in DVD-RW, at 1x speed of DVD (recording line speed: 3.5m/s), it becomes lT=38.2ns, and at 4x speed of DVD (recording line speed: 14 · 0m / s ), which becomes 1T and 9.6 ns. In addition, with the recent high-speed recording, the unit clock Τ becomes shorter and becomes several ns. Therefore, the response of the rise and fall of the laser pulse can be considered. The recording pulse pattern based on 2T as shown in Fig. 5 is used as a limit. In Fig. 5, there is shown a recording mark for forming a recording pulse A having a mark length of -19-(16) 1277961 3T, a recording pulse B having a mark length of Π T, and a recording pulse C having a mark length of 14 Τ. Recording pulse pattern ° "Optical recording device" In Fig. 6, an optical recording device according to an embodiment of the present invention for irradiating laser light having a desired recording pulse pattern on an optical recording medium is shown. First, the spindle motor 3 1 rotates the optical recording medium A. The rotation control unit 32 is controlled so that the number of rotations of the spindle motor 3 1 becomes the recording linear velocity corresponding to the recording speed of the object. Further, there is a semiconductor lens (LD) 3 3 which is used for recording, reproduction, or erasing of the optical recording medium A, or a lens (not shown) for collecting light by laser light of the LD 33, and a 4-segment light receiving unit. The optical head 34 of the element (not shown) is movably disposed in the radial direction of the optical recording medium A. Further, it is preferable that the recording light source used in the optical recording apparatus of the present embodiment is a high-intensity light source such as laser light or stroboscopic light. Even in this case, it is preferable that the light source can be miniaturized, power consumption is small, and it is easy to perform modulation. Therefore, semiconductor laser light is preferable. The four-divided light-receiving element 341 of the optical head 34 is attached to the optical recording medium A, and receives the reflected light of the laser light irradiated by the LD 33. The four-divided light-receiving element 341 generates a push-pull signal based on the received light, and outputs it to the wobble detecting unit 36. Further, the four-divided light-receiving element 314 outputs a focus error signal and a tracking error signal to the drive controller 44 based on the received light. Further, the reproduced signal of the composite signal of the four-divided light receiving element 34 1 is outputted to -20-(17)(17)1277961 to the reflectance detecting unit 46. The drive controller 44 controls the actuator control unit 35 based on the supplied focus error signal and the tracking error signal. The actuator control unit 5 controls the focusing and tracking of the optical recording medium A by the optical head 34. The reflectance detecting unit 46 detects the reflectance based on the supplied reproduced signal, and outputs the detection result to the system controller 45. The wobble detecting unit 36 includes a programmable band pass filter (BPF) 361, and outputs the detected wobble signal to the address demodulating circuit 37. The address demodulation circuit 37 is outputted by demodulating the address by the detected wobble signal. The recording clock generation unit 38 that inputs the demodulated address has a PLL synthesizer circuit 381, generates a recording channel clock, and outputs it to the recording pulse generating unit 39 and the pulse number control unit 40. The recording clock generation unit 38 is controlled by the drive controller 44. The drive controller 44 also controls the rotation control unit 3, the actuator control unit 35, the swing detection unit 36, the address demodulation circuit 37, and the system controller 45. The drive controller 44 is controlled by the swing detection unit. The supplied swing signal is output to the recording clock generation unit 38. Further, the address information supplied from the address demodulation circuit 37 is output to the system controller 45. The system controller 45 has a memory 45, and controls the EFM + encoder 42, the mark length counter 41, the pulse number control unit 40, and the LD drive unit 43. The EFM + encoder 42 performs 8 - 16 modulation on the input recording information, and becomes modulated data, and outputs it to the recording pulse generating unit 3 9 and the mark length counter 4 1 . The mark length counter 4 1 is activated as the root - 21 - (18) 1277961. The mark length generating unit that counts the predetermined mark length based on the modulated data, and outputs the count 値 to the recording pulse generating unit 39 and the pulse number control unit 40. . The pulse number control unit 40 controls the recording pulse generating unit 39 to cause the recording pulse to be a predetermined pulse based on the supplied count 値 and the recording channel clock. The recording pulse generating unit 39 includes a front pulse control signal generating unit 39t, a multiple pulse control signal generating unit 39m, and a cancel pulse control signal φ generating unit 39c. The front pulse control signal generating unit 39t generates a front pulse control signal, and the multiple pulse control signal generating unit 39m generates a multi-comp. pulse control signal, and the cancel pulse control signal generating unit 39c generates a cancel pulse control signal. Each of the control signals is supplied to the LD driver unit 43, and the switch unit 433 is driven by the drive current source 4 3 1 w according to the supply recording power Pw, the drive current source 4 3 1 e of the cancellation power P e , and the base power P b . The control signal of the current source 43 1 b is driven to switch to generate a recording pulse pattern. • Pw drive current source 43 1 w, Pe drive current source 43 le and Pb drive current source 43 1 b are supplied according to recording power Pw, cancellation power Pe and base power Pb of memory 45 1 stored in system controller 45. Current is supplied to the optical head 34. These three lines are used to make the recording characteristics of the optical recording medium A the most appropriate, and the most appropriate identification information can be stored in the memory 451 in advance or by updating. The storage is performed or determined and stored by the reflectance detecting unit 46. In addition, 'memory 4 5 1 is for example R Ο M ( R ead Ο η 1 y M em 〇 ry) or RAM can be recorded (Random Access Memory -22- (19) 1277961 (random access memory)). However, the optical recording apparatus of the present embodiment is configured to be capable of setting a recording linear velocity selected from a plurality of recording linear velocities in accordance with the high linear velocity (high speed) of the optical recording medium. The system controller 45 controls the Pw drive current source according to the identification information of the recording line speed indicated by the memory 45 1 when the input signal for selecting the recording line speed (double speed mode) is input. 43 1 w, Pe drive current source 4 3 1 e and P b drive current source 4 3 1 b. In the memory 4 5 1, as described above, the identification information of a plurality of recording line speeds is stored. The generated recording pulse pattern is input to the optical head 34. The optical head 34 controls the LD 3 3 to output the desired recording pulse pattern and the LD luminescence waveform of the power ratio ε (Pw/P), and records the recorded information on the optical recording medium A. The recording pulse generating unit 39, the LD driver unit 43, and the optical head 34 are generated based on the mark length generated by the mark length counter 41, and are generated to be raised from the cancel power P e and greater than the cancel power Pe. The recording pulse between the recording power Pw and the substrate power Pb which is smaller than the cancellation power Pe and the erasing pulse which is raised from the substrate power Pb to the cancellation power Pe, for the recording layer 3, is started by the LD3 3 In the recording pulse pattern, the recording light is irradiated, and the recording unit 400 that records the recording mark of the recording information is operated. <<Initialization of Initialization Power>> The inventors presume that in the initiation device 200, the initiation laser is used for initializing the optical recording -23-(20) (20)1277961 medium. Whether the power (initialization power) affects the recording and rewriting characteristics of the optical recording medium A; it is found from the following Examples 1 to 3 and Comparative Example 1 and Comparative Example 2 that the inference is correct , with the initialization power that the recording and rewriting characteristics become optimal. In the present embodiment, the initial state of the optical recording medium A is reviewed by the amplitude of the difference signal (tracking detection signal) in the off-track state. Further, the off-track state refers to a state in which the laser light for reproduction is irradiated onto the optical recording medium A so that the spot light caused by the laser light does not follow the track (a state in which no tracking is applied). As shown in Fig. 7, the four-divided light-receiving element 341 is composed of light-receiving elements 341a to 341d. The first light receiving element group composed of the light receiving elements 341a and 341b and the second light receiving element group including the 341c and 341d are arranged to face each other in the track (that is, in the radial direction). The spot light that has been irradiated onto the optical recording medium A is reflected on the optical recording medium A, and is received by the light receiving elements 341a to 341d. In the state where the light receiving signals (current 値) output by the light receiving elements 341a, 3 4 1 b, 3 4 1 c, and 3 4 1 d are respectively la, lb, Ic, and Id, the difference signal amplitude can be It is defined by the following formula (1). In equation (1), the AC system displays the right side of the formula to become an exchange. Amplitude of the difference signal = 丨 (Ia + Ib) - (Ic + Id) | AC · (1) When the information is reproduced simultaneously on the rotating optical recording medium A, the LD3 3 is spirally (or linearly) The track (groove) formed on the substrate 1 of the optical recording medium A is irradiated with laser light having a reproducing power Pr, and the spot light of the laser light is collected and tracked at -24-(21) 1277961 orbit. This state is referred to as an aligned orbital state. Then, when the spot light is tracked at the center of the groove or the end face in the aligned track state, the amount of return light (I a + lb ) and (Ic + Id ) returned to the four-divided light receiving element 341 are equal. The difference between the difference signal (tracking detection signal) becomes 〇 and the amplitude cannot be obtained. In other words, the output of the four-divided light-receiving element is constant. * However, when the optical recording medium A is rotated while the information is being reproduced, the point light from the LD 33 cannot be traced to the track, and the optical head 34 is fixed in a fixed position (off-track state). The difference in the amount of light recovered by the optical element is different, and the amplitude output of the difference signal (tracking detection signal) shows the periodic variation of Fig. 8. Figure 8 shows the difference signal in the off-track state by the oscilloscope. This variation is based on the optical recording medium A, and the groove is spirally scribed. Therefore, the position of the groove with respect to the spot light is periodically changed by the rotation of the optical recording medium A. φ Fig. 9 shows the difference in signal amplitude between the off-orbit state and the laser power (initialized power) of the direct current laser irradiated on the optical recording medium at the time of initiation. When the initializing power of the illumination is sequentially increased for a predetermined optical recording medium, the difference signal amplitude becomes a characteristic of the curve of the drawing. In this curve, there is a saturation point S 1 which does not increase the amplitude of the difference signal even if the initializing power is increased. The characteristic shown in Fig. 9 is due to the change in the crystal structure of the material constituting the recording layer 3 by the intensity (size) of the initializing power. Further, the crystal structure of the recording layer 3 is also different because the difference signal amplitude becomes the saturation point S1. -25- (22) (22)1277961 Further, in the case where the difference signal amplitude does not reach the initializing power P0 to the saturation point S1, the difference signal amplitude of the optical recording medium A in the initialized state becomes SO, in which state In the state where the recording layer 3 illuminates a direct current laser having a power greater than P0, the difference signal amplitude increases with the curve of FIG. This is considered to be because the degree of crystallization of the recording layer 3 is increased by re-illuminating the direct current laser. As a result of the experiment and study by the inventors, it was found that the initializing power P0 of the difference signal amplitude does not reach the saturation point S1, and the optical recording medium A is initialized by the most appropriate In the state of recording, the jitter of the DOWO·· Direct Over Write is good after one (first) recording, and even after one rewriting (DO W1 ) Dithering and repeated re-shaping jitter also yield good characteristics. On the other hand, it has been found that the DO W0 jitter becomes good in the state where the difference signal amplitude reaches the initializing power P 1 of the saturation point S 1 and is started for the optical recording medium A, but the DO is good. The jitter of W1 becomes very poor, and good rewrite characteristics cannot be obtained. The so-called rewriting of the single-beam rewriting described herein means that the previously formed recording marks are eliminated by one-time laser scanning to form a new recording mark. Next, DO W0 means that the first recording of the recording mark is formed for the unrecorded portion of the optical recording medium A which is initialized, and D0W1 is the first rewriting in which the recording mark is formed. In addition, it is good to define the jitter that is less than 1% of the adverse effect of the error rate, and it will be covered by DOWO to DOW 1 000 (from the first recording to the rewriting 1000 times) and -26- (23) (23) 1279761 Stable to obtain jitter below 10%, defined as good DOW jitter characteristics. However, even in the state where the initializing power applied when the optical recording medium A is initialized is unknown, as described below, it can be discriminated whether or not the optical recording medium A is saturated with the difference signal amplitude. The initializing power of the starting power P 1 or more at the point S 1 is initialized or initialized with the initializing power P0 which is not satisfied with the saturation point S 1 . First, with respect to the initiated optical recording medium A, the difference signal amplitude of the off-track state is measured. Then, in the optical recording medium A, an initialized power DC laser such that the measured difference signal amplitude exceeds the originally obtained initial power can be applied, and the difference signal amplitude of the off-track state can be measured to compare the difference between the two. Signal amplitude. The present embodiment is characterized in that the difference signal amplitude of the off-track state after the initiation is smaller than the saturation 値S 1 . An example of a suitable implementation means that the initial power of the laser light at the time of initiation is reduced to such an extent that it does not reach the initial power P 1 which is the saturation 値S 1 . In each of the following examples and comparative examples, recording was performed using a disc drive tester (DDU 1 000) manufactured by Pulse Technology Co., Ltd., which is equipped with a laser diode of 658 nm and an optical lens of ΝΑ=0.60. 1 beam • rewrite) and regeneration. The recording linear velocity is 14 m/s (equivalent to 4 times the DVD-RW specification), and the recording signal is evaluated by using a 8 - 16 (EFM + ) modulation random pattern for recording and reproduction. Unit clock T system 9.6ns (4 times the DVD)

-27- (24) l277961 速),位元長度係〇·267 // m/位元。像這樣,對於光記錄 媒體A而進行相同於DVD — ROM之同樣密度之記錄。該 狀態下之光記錄媒體A之容量係4.7 G位元組。此外,在 以對於光記錄媒體A之最適當條件而也包含鄰接之軌道來 進行1 〇次之重寫後,在其再生訊號之振幅中心,進行切 斷’測定時鐘對資料之抖動。此外,再生光之雷射功率 (再生功率)Pr係一定於〇.7mW。 此外,記錄策略係使用按照第4圖所示之D V D - RW 版本1 · 1之規定之分割脈衝系列。 (實施例1 ) 在直徑120mm、板厚〇.6mm之聚碳酸酯樹脂製之基 板1上,形成後面敘述之各層。在基板1,以軌道間距 〇 . 7 4 /z m,來形成空溝。該溝槽深度係2 5 nm,溝槽幅寬和 接端面幅寬之比値係大約40 : 60。此外,溝槽係由記錄· φ 再生或消除用雷射光之入射方向開始觀察而成爲凸狀。 首先,在排氣真空容器內至3xlO_4Pa爲止後,在2x 10_1Pa之Ar (氬)氣體氣氛中,藉由使用添加20mol%之 Si02之ZnS標靶之高頻磁控管濺鍍法,而在基板1上,形 成層厚70nm之第1保護層2。 接著,依序地藉由Ge— In - Sb — Te之4元素單一合 金標靶而層積層厚度1 6nm之記錄層3,接著,藉由相同 於第1保護層2之同樣材料而層積層厚度16nm之第2保 護層4,藉由Ag— Pd— Cu標靶而層積層厚度I20nm之反 -28- (25) 1277961 射層5。 在由真空容器內而取出基板1後,在該反射層5上, 呈旋轉地塗敷丙烯系紫外線硬化樹脂(新力化學製 SK5 110),藉由紫外線照射而進行硬化,形成膜厚3/zm 之第3保護層6。像這樣而作成未啓始化之光記錄媒體。 對於未啓始化之光記錄媒體之記錄層3,使用日立電 腦機器製POP 120來作爲啓始化裝置200,使用輻射方向 雷射光幅寬250μηα、掃描方向雷射光幅寬Ι.Ομιη之雷射, 以掃描線速度7.0m / s、傳送間距200 μιη之啓始化條件, 來進行啓始化,得到第2圖所示之光記錄媒體Α。在此, 利用啓始化裝置200而預先檢測光記錄媒體A之差異訊號 振幅之飽和點S 1。光記錄媒體A之差異訊號振幅係在照 射 2400mW之雷射功率時,達到飽和點 S1,其値係 5.2V。 作爲實施例1係準備以雷射功率200 OmW來對於未啓 始化之光記錄媒體進行啓始化之光記錄媒體A,在測定偏 離軌道狀態之差異訊號振幅S0時,成爲5.04V。因此,實 施例1之振幅比S 0 / S 1係〇 . 9 7。將各個値顯示於表1。 此外,在此所示之S0及S1之各個値係藉由光記錄媒 體或測定裝置而進行變化之値,除了振幅比S 0 / S 1以 外,其餘係並非限定於本發明。這個係也相同於其他之實 施例及比較例。 接著,在光記錄媒體A,由基板1側開始,對於記錄 層3之溝槽,來進行記錄。 -29- (26) 1277961 成爲對於光記錄媒體A之最適當記錄條件之記錄脈衝 圖案係在線速度14m / s ( DVD之4倍速),成爲TtQp = 〇·6[Τ]、Tmp= 0·5[Τ]、0·0[Τ]。此外,雷射光之雷射 強度係使用記錄功率 Pw = 1 7.0[mW]、消除功率 Pe = 5[mW]、基底功率Pb = 0.5[mW]之3個値。該最適當記錄 條件係也相同於以下之實施例2、實施例3及比較例1、 比較例2。-27- (24) l277961 speed), bit length system 〇 · 267 / m / bit. In this manner, recording of the same density as that of the DVD-ROM is performed for the optical recording medium A. The capacity of the optical recording medium A in this state is 4.7 Gbytes. Further, after rewriting the adjacent track for the most appropriate condition for the optical recording medium A, the center of the amplitude of the reproduced signal is subjected to the cutoff to measure the jitter of the clock pair data. Further, the laser power (regeneration power) Pr of the regenerated light is fixed at 〇.7 mW. In addition, the recording strategy uses a split pulse train as defined by D V D - RW version 1 · 1 shown in Fig. 4. (Example 1) Each of the layers described later was formed on a substrate 1 made of a polycarbonate resin having a diameter of 120 mm and a thickness of 66 mm. On the substrate 1, voids are formed at a track pitch of 7. 7 4 /z m. The groove depth is 25 nm, and the ratio of the groove width to the end face width is about 40:60. Further, the groove is formed in a convex shape by the recording/φ reproduction or the elimination of the incident direction of the laser light. First, in the exhaust vacuum vessel to 3x10_4Pa, in a 2 x 10_1 Pa Ar (argon) gas atmosphere, by using a high frequency magnetron sputtering method of adding 20 mol% of SiO 2 ZnS target, on the substrate On the first, a first protective layer 2 having a layer thickness of 70 nm is formed. Then, a recording layer 3 having a thickness of 16 nm is laminated by a 4-element single alloy target of Ge—In—Sb—Te, and then the layer thickness is laminated by the same material as the first protective layer 2. The second protective layer 4 of 16 nm is laminated with a reverse layer -28-(25) 1277961 shot layer 5 having a layer thickness of I20 nm by an Ag-Pd-Cu target. After the substrate 1 was taken out from the inside of the vacuum container, propylene-based ultraviolet curable resin (SK5 110 manufactured by Shin-Chem Chemical Co., Ltd.) was spin-coated on the reflective layer 5, and cured by ultraviolet irradiation to form a film thickness of 3/zm. The third protective layer 6. In this way, an optical recording medium that is not initialized is created. For the recording layer 3 of the optical recording medium which is not initialized, the POP 120 made of Hitachi Computer Equipment is used as the initialization device 200, and the laser beam width 250 μηα in the radiation direction and the laser light width Ι.Ομιη in the scanning direction are used. The initializing condition is performed at a scanning linear velocity of 7.0 m / s and a transmission pitch of 200 μm to obtain an optical recording medium 第 shown in Fig. 2. Here, the saturation point S 1 of the difference signal amplitude of the optical recording medium A is detected in advance by the initialization device 200. The difference signal amplitude of the optical recording medium A reaches the saturation point S1 when the laser power of 2400 mW is irradiated, and the 値 is 5.2 V. In the first embodiment, an optical recording medium A for starting an unactivating optical recording medium with a laser power of 200 OmW is prepared, and when the difference signal amplitude S0 of the off-track state is measured, it becomes 5.04V. Therefore, the amplitude ratio of the embodiment 1 is S 0 / S 1 〇 . 9 7 . Each 値 is shown in Table 1. Further, each of S0 and S1 shown here is changed by an optical recording medium or a measuring device, and is not limited to the present invention except for the amplitude ratio S 0 / S 1 . This system is also identical to other embodiments and comparative examples. Next, on the optical recording medium A, recording is performed on the groove of the recording layer 3 from the side of the substrate 1. -29- (26) 1277961 The recording pulse pattern which becomes the most suitable recording condition for the optical recording medium A is the line speed of 14 m / s (4 times the speed of the DVD), and becomes TtQp = 〇·6 [Τ], Tmp = 0·5. [Τ], 0·0[Τ]. Further, the laser intensity of the laser light is three turns of the recording power Pw = 1 7.0 [mW], the cancellation power Pe = 5 [mW], and the base power Pb = 0.5 [mW]. The most appropriate recording conditions were also the same as in the following Example 2, Example 3, Comparative Example 1, and Comparative Example 2.

初期及重寫記錄特性係正如表1所示,初次記錄 (DOWO)抖動係6.5%,重寫1次(D0W1 )抖動係9.1 %,重寫9次(D0W9 )抖動係 7.9%,此外,在重寫 1 000次(DOWIOOO)之抖動成爲8.8%時,重寫特性係非 常穩定,記錄特性變得良好。 [表1] 雷射功率 顫動[%] S0/S1 S[V] S1[V] [mW] DOWO DOW1 DOW2 DOW9 DOW100 DOW 1000 實施例1 2000 6.5 9.1 8.3 7.9 8.2 8.8 0.97 5.04 5.20 實施例2 1800 6.4 8.6 8.4 7.8 7.9 8.0 0.78 4.06 5.20 實施例3 1600 6.7 8.9 8.4 7.8 8.3 8.6 0.63 3.28 5.20 比較例1 2400 7.2 14.3 13.0 10.8 10.5 11.0 1.00 5.20 5.20 比較例2 1400 (實施例2 ) 作爲實施例2係準備以雷射功率1 8 0 0 m W來對於未啓 始化之光記錄媒體進行啓始化之光記錄媒體A,在測定偏 -30- (27) (27)1277961 離軌道狀態之差異訊號振幅SO時,成爲4·06ν。因此,實 方也例2之振幅比S 0 / S 1係0 · 7 8。其他條件係相同於實施 例1。 初期及重寫記錄特性係正如表1所示,D Ο W 0抖動係 6.4%,DOW1抖動係8.6%,D0W9抖動係7·8%,此外, 在D Ο W 1 0 0 0抖動成爲8 · 0 %時,重寫特性係非常穩定,記 錄特性變得良好。 (實施例3 ) 作爲實施例3係準備以雷射功率1 600mW來對於未啓 始化之光記錄媒體進行啓始化之光記錄媒體A,在測定偏 離軌道狀態之差異訊號振幅SO時,成爲3.28V。因此,實 施例3之振幅比SO/ S1係0.63。其他條件係相同於實施 例1。 初期及重寫記錄特性係正如表1所示,DO W0抖動係 6.7%,DOW1抖動係8.9%,DOW9抖動係7.8%,此外, 在DO W1 000抖動成爲8.6%時,重寫特性係非常穩定,記 錄特性變得良好。 (比較例1 ) 作爲比較例1係準備以雷射功率240 OmW來對於未啓 始化之光記錄媒體進行啓始化之光記錄媒體A °其他條件 係相同於實施例1。在測定偏離軌道狀態之差異訊號振幅 S0時,成爲5.2V。因此,比較例1之S0和S1係相等, -31 - (28) 1277961 振幅比S Ο / S 1係1. 〇。 初期及重寫記錄特性係正如表1所示,DO W〇抖動係 7.2%,DOW1 抖動係 14.3%,DOW9 抖動係 1〇,8%,此 外,在D Ο W 1 0 〇 〇抖動成爲丨丨.〇 %時,d 〇 w 1抖動係特別 差,無法得到良好之D Ο W抖動特性。 得知:像這樣,在使用振幅比S 0 / S 1成爲1 · 〇、也就 是偏離軌道狀態之差異訊號振幅達到至飽和値S 1之啓始 φ 化功率時,DO W1抖動係變差,無法得到良好之重複記錄 . 特性。相對於此,如果SO/ S 1小於1、也就是以不達到 至飽和値S 1之啓始化功率來進行啓始化的話,則得到良 好之DOW抖動特性。 (比較例2) 除了改變啓始化功率成爲1400mW以外,其餘係相同 於實施例1,製作光記錄媒體。但是,在比較例2,在記 φ 錄層3仍然成爲非結晶質之狀態下,在啓始化製程200, 無法得到結晶化狀態,無法進行啓始化。 由比較例2和實施例3而得知:如果降低啓始化功率 之輸出而使得偏離軌道狀態之差異訊號振幅成爲飽和値 , S 1以下的話,則得到良好之DOW抖動特性,在啓始化功 _ 率變得過度小時,無法進行啓始化。其限度之振幅比S0 / S1係,0.6,在低於這個時,不容易進行光記錄媒體之 啓始化。 由以上之實施例1〜實施例3及比較例1、比較例2 -32- (29) 1277961 而判明:在振幅比SO/ S1大於0.6、小於1·〇時,得到良 好之DOW抖動特性,也防止DO W1抖動之惡化。如果振 幅比S 0 / S 1成爲0.6以下的話,則不容易進行光記錄媒 體之啓始化,另一方面,在成爲1.0時,DOW1抖動係變 差,無法得到良好之重複記錄特性。 在考慮滿足藉由DVD— RW規格所決定之反射率18% 以上時,更加理想是振幅比S 0 / S 1大於〇 · 8、小於1.0。 φ 此外,本發明之特徵係特別有效於對應在高線速度 . (DVD之4倍速以上)之記錄之光記錄媒體A。 以表1之値作爲基礎而將以上之結果來顯示在第1 〇 圖。也由該圖而得知:藉由以不達到至飽和値S 1之程度 之啓始化功率來進行光記錄媒體之啓始化,而使得DO W 1 之抖動得到良好之値。 《最適當消除功率之檢討》 φ 接著,本發明人係推測消除功率P e是否對於光記錄 媒體之記錄及重寫特性,來造成影響,根據下列之實施例 4〜8及比較例3〜7而發現··其推論變得正確,具有記錄 及重寫特性變得最佳之最適當消除功率。 (實施例4) 作爲實施例4係準備以掃描線速度4.5m/ s、雷射功 率160 OmW、傳送間距220 μιη來對於未啓始化之光記錄媒 體進fr啓化之先錄媒體Α。其他條件係相同於實施例 -33- (30) 1277961 1。此外,藉由該啓始化條件而進行啓始化之光記錄媒體 A係正如第11圖所示,在1個軌道內之反射率變動變 小,反射率係槪略呈一定。 接著,在光記錄媒體A之記錄區域54,在一度也並 無記錄資訊之未記錄部,求出在由LD 3 3開始照射具有再 生功率 Pr ( 0.7m W )之再生光時之未記錄部之反射率 R0。在該未記錄部,改變消除功率Pe,同時,照射具有 φ 消除功率Pe之雷射光,在由LD33開始照射再生用之雷射 . 光而測定各個消除功率P e之未記錄部之反射率R時,在 第1 2圖,描劃藉由實線所示之反射率曲線C 1。 反射率曲線C1係可以使得消除功率Pe由OmW之起 始點開始至彎曲點Q1爲止而近似於傾斜幾乎〇之直線。 使得在彎曲點Q 1之消除功率成爲P 1。此外,由起始點 (功率0 )開始至彎曲點Q 1爲止之反射率係相等於未記 錄部之反射率R0。在反射率曲線C1經過彎曲點Q1而使 φ 得消除功率大於P 1時,反射率係隨著消除功率之增加而 依序地增大,到達至波峰點Q2。波峰點Q2之消除功率係 P2,使得此時之反射率成爲最大反射率R1 °在到達至波 峰點Q2時,即使是照射大於消除功率P2之消除功率’也 減少反射率。 使用在實施例4之光記錄媒體A之未記錄部之反射率 R0係19.5,彎曲點Q1之消除功率P1係6.5mW,最大反 射率R 1係2 1 . 1。因此,反射率比((R 1 - R 0 ) / R 0 )係 0.08。 -34- (31) (31)1277961 接著,在光記錄媒體A,由基板1側開始,對於記錄 層3之溝槽,來進行記錄。 成爲對於實施例4之光記錄媒體A之最適當記錄條件 之記錄脈衝圖案係在線速度ί 4m/ s ( DVD之4倍速)’ 成爲 Tt(3p=0.6[T]、Tmp 二 0.5[T]、Tel=〇.〇[T]。此外,雷 射光之雷射強度係使用記錄功率Pw= l7.〇[mW]、消除功 率Pe=4.6[mW]、基底功率Pb二0.5[mW]之3個値。消除 功率比(Pe/ P1 )係〇·7。將測定之値,整理及顯示於表 2 ° 初期特性及重寫記錄特性係正如表2所示,初次記錄 (DOWO)抖動係6.5%,重寫1次(DOW1)抖動係8.4 % ’重寫9次(DO W9)抖動係8.1%。此外,在大約千次 重寫(DOW1000)之抖動成爲8.8%時,即使是進行重 寫,也使得特性一直穩定,記錄特性變得良好。The initial and rewrite recording characteristics are as shown in Table 1. The initial recording (DOWO) jitter is 6.5%, the rewriting is once (D0W1), the jitter is 9.1%, and the rewriting is 9 times (D0W9) is 7.9%. In addition, When the jitter of overwriting 1000 times (DOWIOOO) becomes 8.8%, the rewriting characteristics are very stable and the recording characteristics become good. [Table 1] Laser power flutter [%] S0/S1 S[V] S1[V] [mW] DOWO DOW1 DOW2 DOW9 DOW100 DOW 1000 Example 1 2000 6.5 9.1 8.3 7.9 8.2 8.8 0.97 5.04 5.20 Example 2 1800 6.4 8.6 8.4 7.8 7.9 8.0 0.78 4.06 5.20 Example 3 1600 6.7 8.9 8.4 7.8 8.3 8.6 0.63 3.28 5.20 Comparative Example 1 2400 7.2 14.3 13.0 10.8 10.5 11.0 1.00 5.20 5.20 Comparative Example 2 1400 (Example 2) Prepared as Example 2 The laser power of the optical recording medium A for the initiation of the uninitiated optical recording medium with a laser power of 1 800 m W is measured by the difference -30-(27) (27) 1278961 At the time, it became 4·06ν. Therefore, the actual example also has an amplitude ratio S 0 / S 1 of 0 · 7 8 . Other conditions are the same as in Example 1. The initial and rewrite recording characteristics are as shown in Table 1. The D Ο W 0 jitter is 6.4%, the DOW1 jitter is 8.6%, and the D0W9 jitter is 7.8%. In addition, the jitter at D Ο W 1 0 0 becomes 8 · At 0%, the rewrite characteristics are very stable and the recording characteristics become good. (Embodiment 3) As an embodiment 3, an optical recording medium A for initializing an uninitiated optical recording medium with a laser power of 1 600 mW is prepared, and when the difference signal amplitude SO of the off-track state is measured, 3.28V. Therefore, the amplitude ratio of the third embodiment is 0.63 in the SO/S1 system. Other conditions are the same as in Example 1. The initial and rewrite recording characteristics are as shown in Table 1. The DO W0 jitter is 6.7%, the DOW1 jitter is 8.9%, and the DOW9 jitter is 7.8%. In addition, the rewrite characteristics are very stable when the DO W1 000 jitter is 8.6%. The recording characteristics become good. (Comparative Example 1) As Comparative Example 1, an optical recording medium A which was prepared by initializing an illuminating recording medium with a laser power of 240 OmW was prepared in the same manner as in Example 1. When the difference signal amplitude S0 of the off-track state is measured, it becomes 5.2V. Therefore, S0 and S1 of Comparative Example 1 are equal, and -31 - (28) 1277961 has an amplitude ratio S Ο / S 1 system 1. 〇. The initial and rewrite recording characteristics are as shown in Table 1. The DO W〇 jitter is 7.2%, the DOW1 jitter is 14.3%, and the DOW9 jitter is 1〇, 8%. In addition, the jitter at D Ο W 1 0 丨丨 becomes 丨丨When 〇%, d 〇w 1 jitter is particularly poor, and good D Ο W jitter characteristics cannot be obtained. It is known that, as in this case, when the amplitude ratio S 0 / S 1 becomes 1 · 〇, that is, the difference signal amplitude of the off-track state reaches the initial φ power of the saturation 値 S 1 , the DO W1 jitter deteriorates. Unable to get good duplicate records. Features. On the other hand, if SO/S 1 is smaller than 1, and initialization is performed without starting power to saturation 値S 1, good DOW jitter characteristics are obtained. (Comparative Example 2) An optical recording medium was produced in the same manner as in Example 1 except that the initializing power was changed to 1400 mW. However, in Comparative Example 2, in the state where the recording layer 3 is still amorphous, in the initiation process 200, the crystallization state cannot be obtained, and the initiation cannot be performed. It is known from the comparative example 2 and the third embodiment that if the output of the initializing power is lowered so that the difference signal amplitude of the off-track state becomes saturated, and below S 1 , a good DOW jitter characteristic is obtained, which is initialized. The power _ rate becomes too small to be initialized. The amplitude of the limit is greater than the S0 / S1 system, 0.6. Below this, it is not easy to initialize the optical recording medium. From the above-described Example 1 to Example 3, Comparative Example 1, and Comparative Example 2 - 32 - (29) 1277961, it was found that when the amplitude ratio SO / S1 is more than 0.6 and less than 1 · ,, good DOW jitter characteristics are obtained. It also prevents the deterioration of DO W1 jitter. When the amplitude ratio S 0 /S 1 is 0.6 or less, it is not easy to start the optical recording medium. On the other hand, when it is 1.0, the DOW1 jitter is deteriorated, and good repeat recording characteristics cannot be obtained. When it is considered that the reflectance determined by the DVD-RW specification is 18% or more, it is more preferable that the amplitude ratio S 0 / S 1 is larger than 〇 · 8 and less than 1.0. φ Further, the feature of the present invention is particularly effective for the optical recording medium A corresponding to recording at a high linear velocity (above 4 times the speed of the DVD). The above results are shown in Figure 1 on the basis of Table 1. It is also known from the figure that the start of the optical recording medium is performed by the initializing power which does not reach the saturation 値S 1 , so that the jitter of the DO W 1 is good. "Review of the most appropriate power cancellation" φ Next, the inventors have inferred whether or not the elimination power P e has an influence on the recording and rewriting characteristics of the optical recording medium, according to the following Examples 4 to 8 and Comparative Examples 3 to 7. And found that its inference has become correct, with the most appropriate power cancellation for recording and rewriting characteristics. (Embodiment 4) As Example 4, a pre-recorded medium 对于 for the uninitiated optical recording medium was prepared at a scanning linear velocity of 4.5 m/s, a laser power of 160 OmW, and a transmission pitch of 220 μm. Other conditions are the same as in the examples -33-(30) 1277961 1. Further, the optical recording medium A which is initialized by the initiation condition is as shown in Fig. 11, and the reflectance variation in one track is small, and the reflectance is slightly constant. Then, in the recording area 54 of the optical recording medium A, an unrecorded portion in which no information is recorded once, and an unrecorded portion when the reproducing light having the reproducing power Pr (0.7 m W ) is started to be irradiated by the LD 3 3 is obtained. The reflectance R0. In the unrecorded portion, the erasing power Pe is changed, and the laser light having the φ erasing power Pe is irradiated, and the reflectance R of the unrecorded portion of each of the erasing powers P e is measured by the LD 33 starting to irradiate the laser for reproduction. At the time of Fig. 12, the reflectance curve C 1 shown by the solid line is drawn. The reflectance curve C1 is such that the elimination power Pe is approximated to a straight line which is inclined almost from the start point of OmW to the bending point Q1. The cancellation power at the bending point Q 1 is made P 1 . Further, the reflectance from the start point (power 0) to the bending point Q 1 is equal to the reflectance R0 of the unrecorded portion. When the reflectance curve C1 passes through the bending point Q1 such that the φ elimination power is greater than P1, the reflectance sequentially increases as the cancellation power increases, reaching the peak point Q2. The elimination power of the peak point Q2 is P2, so that the reflectance at this time becomes the maximum reflectance R1. When the peak point Q2 is reached, even if the cancellation power is greater than the cancellation power P2, the reflectance is reduced. The reflectance R0 of the unrecorded portion of the optical recording medium A of Example 4 was 19.5, the erasing power P1 of the bending point Q1 was 6.5 mW, and the maximum reflectance R 1 was 21.1. Therefore, the reflectance ratio ((R 1 - R 0 ) / R 0 ) is 0.08. -31- (31) (31) 1279961 Next, on the optical recording medium A, recording is performed on the groove of the recording layer 3 from the side of the substrate 1. The recording pulse pattern which becomes the most suitable recording condition for the optical recording medium A of the fourth embodiment is the line speed ί 4m/s (4 times speed of the DVD)' becomes Tt (3p=0.6[T], Tmp two 0.5[T], Tel=〇.〇[T]. In addition, the laser intensity of laser light is 3 using recording power Pw=l7.〇[mW], elimination power Pe=4.6[mW], base power Pb=0.5[mW]消除 Elimination power ratio (Pe / P1) system 〇 · 7. After the measurement, finishing and display in Table 2 ° initial characteristics and rewrite record characteristics as shown in Table 2, the initial record (DOWO) jitter is 6.5% , Rewrite once (DOW1) jitter is 8.4% 'Rewrite 9 times (DO W9) jitter is 8.1%. In addition, when the jitter of about 1000 rewrites (DOW1000) becomes 8.8%, even if it is rewritten, It also makes the characteristics stable and the recording characteristics become good.

-35- (32) 1277961 [表2] 雷射功率[mW] 功率比 反射率[%] 反射率比 顫動[%] Pw Pe PI Pe/Pl R0 R1 (R1-R0)/R0 DOWO DOW1 DOW9 DOW 1000 實施例4 17.0 4.6 6.5 0.7 19.5 21.1 0.08 6.5 8.4 8.1 8.8 實施例5 17.5 6.0 7.5 0.8 21.0 21.7 0.03 6.8 8.8 7.8 8.0 實施例6 16.0 4.2 6.0 0.7 16.0 18.4 0.15 7.4 8.7 8.2 8.9 實施例7 17.0 3.0 6.5 0.5 20.0 21.6 0.08 7.2 9.2 8.8 8.8 實施例8 17.0 6.5 6.5 1.0 20.0 21.6 0.08 6.4 8.3 8.5 9.4 比較例3 17.0 4.6 21.6 22.0 0.02 7.2 16.6 8.1 9.6 比較例4 15.0 4.2 19.1 19.4 0.02 7.5 13.2 10.5 11.0 比較例5 17.0 4.6 5.0 0.9 17.5 21.0 0.20 9.8 12.8 9.2 9.8 比較例6 17.0 2.5 6.5 0.4 19.5 21.1 0.08 10.0 20.0 18.0 18.0 比較例7 17.0 7.5 6.5 1.2 19.5 21.1 0.08 7.4 8.9 9.2 12.0-35- (32) 1277961 [Table 2] Laser power [mW] Power ratio reflectance [%] Reflectance ratio jitter [%] Pw Pe PI Pe/Pl R0 R1 (R1-R0)/R0 DOWO DOW1 DOW9 DOW 1000 Example 4 17.0 4.6 6.5 0.7 19.5 21.1 0.08 6.5 8.4 8.1 8.8 Example 5 17.5 6.0 7.5 0.8 21.0 21.7 0.03 6.8 8.8 7.8 8.0 Example 6 16.0 4.2 6.0 0.7 16.0 18.4 0.15 7.4 8.7 8.2 8.9 Example 7 17.0 3.0 6.5 0.5 20.0 21.6 0.08 7.2 9.2 8.8 8.8 Example 8 17.0 6.5 6.5 1.0 20.0 21.6 0.08 6.4 8.3 8.5 9.4 Comparative Example 3 17.0 4.6 21.6 22.0 0.02 7.2 16.6 8.1 9.6 Comparative Example 4 15.0 4.2 19.1 19.4 0.02 7.5 13.2 10.5 11.0 Comparative Example 5 17.0 4.6 5.0 0.9 17.5 21.0 0.20 9.8 12.8 9.2 9.8 Comparative Example 6 17.0 2.5 6.5 0.4 19.5 21.1 0.08 10.0 20.0 18.0 18.0 Comparative Example 7 17.0 7.5 6.5 1.2 19.5 21.1 0.08 7.4 8.9 9.2 12.0

(實施例5 ) # 使用將實施例4之第2保護層4之層厚度變更成爲 12nm之光記錄媒體A。R0係21.0,在彎曲點qi之消除 功率P1係7.5mW,R1係21.7,反射率比係0.〇3。 在實施例4之記錄條件中,改變記錄功率Pw成爲 17.5mW,改變消除功率pe成爲6.0mW,來進行記錄•評 _ 價。消除功率比係0.8。 初期特性及重寫記.錄特性係正如表2所示,D〇w〇抖 動係6.8%,DOW1抖動係8.8%,DOW9抖動係7 8%。 此外,在DOW 1 000之抖動成爲8·0%時,即使是進行重 -36- (33) I277961 寫’也使得特性一直穩定,使得記錄特性變得良好。 (實施例6 ) 使用將實施例4之記錄層3之層厚度變更成爲12nm 之光記錄媒體A。R0係1 6.0,在彎曲點Q 1之消除功率P 1 係6.0mW,R1係1 8.4,反射率比係0· 15。 在實施例4之記錄條件中,改變記錄功率Pw成爲 • l6.0mW,改變消除功率pe成爲4.2mW,來進行記錄•評 價。消除功率比係0.7。 正如表2所示,初期特性及重寫記錄特性係相同於實 施例4,得到良好之特性。 (實施例7 ) 使用相同於實施例4之光記錄媒體A,在實施例4之 記錄條件中,改變消除功率Pe成爲3. OmW,來進行記錄 § ·評價。在彎曲點Q 1之消除功率P 1係相同於實施例4而 成爲6.5mW,消除功率比係0.5。 正如表2所示,D0W1抖動係成爲9.2%而得到稍微 大之値,但是,相同於實施例4,得到良好之特性。 (實施例8 ) 使用相同於實施例4之光記錄媒體A,在實施例4之 記錄條件中,改變消除功率pe成爲6.5mW,來進行記錄 •評價。在彎曲點Q 1之消除功率P 1係相同於實施例4而 -37 - (34) (34)1277961 成爲6.5mW,消除功率比係1·〇。 正如表2所示,DOW1 000抖動係成爲9.4%而得到稍 微大之値,但是,相同於實施例4,得到良好之特性。 (比較例3 ) 使用實施例4之記錄層3所採用之Ge— in— Sb- Te 之4元素單一合金標靶之Sb / Te比變大之光記錄媒體 A。在作成比較例3之光記錄媒體A之反射率曲線時,並 無彎曲點Q 1及波峰點Q2,在第1 2圖,描劃藉由虛線所 示之反射率變化小之反射率曲線C2。因此,無法得到在 彎曲點Q 1之消除功率P 1,但是,使得未記錄部之反射率 R0成爲21.6,反射率曲線C2之最大値成爲最大反射率 Rl= 22.0,相同於前面敘述而算出之反射率比係〇.〇2。 藉由相同於實施例4之同樣之記錄條件而進行記錄· 評價。 初期特性及重寫記錄特性係正如表2所示,D Ο W 0及 DOW9抖動係變得良好,但是,DOW1抖動係變差,無法 得到良好之D OW抖動特性。 (比較例4 ) 使用實施例4之記錄層3所採用之Ge — In—Sb— Te 之4元素單一合金標靶之S b / T e比變小之光記錄媒體 A。反射率曲線係相同於比較例3而描劃C2,無法得到在 彎曲點Q 1之消除功率P 1,但是,使得未記錄部之反射率 -38- (35) 1277961 R0成爲19·1,反射率曲線C2之最大値成爲最大反射率 R1 = 19.4,相同於前面敘述而算出之反射率比係0.02。 在實施例4之記錄條件中,改變記錄功率Pw成爲 l5.〇mW,消除功率Pe成爲4.2mW,來進行記錄·評價。 初期特性及重寫記錄特性係正如表2所示,DO W0抖 動係變得良好,但是,DO Wl、DO W9及DOW 1 000抖動係 變差,無法得到良好之D Ο W抖動特性。(Example 5) # An optical recording medium A in which the layer thickness of the second protective layer 4 of Example 4 was changed to 12 nm was used. R0 is 21.0, which is eliminated at the bending point qi. Power P1 is 7.5 mW, R1 is 21.7, and reflectance is 0. 〇3. In the recording conditions of the fourth embodiment, the recording power Pw was changed to 17.5 mW, and the erasing power pe was changed to 6.0 mW to perform recording and evaluation. The elimination power ratio is 0.8. The initial characteristics and rewrite characteristics are shown in Table 2. The D〇w〇 jitter is 6.8%, the DOW1 jitter is 8.8%, and the DOW9 jitter is 78%. Further, when the jitter of the DOW 1 000 becomes 8·0%, even if the weight -36-(33) I277961 write ' is performed, the characteristics are always stabilized, so that the recording characteristics become good. (Example 6) An optical recording medium A in which the layer thickness of the recording layer 3 of Example 4 was changed to 12 nm was used. R0 is 1 6.0, and the power P 1 at the bending point Q 1 is 6.0 mW, R1 is 1 8.4, and the reflectance ratio is 0·15. In the recording conditions of the fourth embodiment, the recording power Pw was changed to • l6.0 mW, and the erasing power pe was changed to 4.2 mW to perform recording and evaluation. The elimination power ratio is 0.7. As shown in Table 2, the initial characteristics and the rewrite recording characteristics were the same as in Example 4, and good characteristics were obtained. (Example 7) Using the optical recording medium A of the same manner as in Example 4, in the recording conditions of Example 4, the erasing power Pe was changed to 3. OmW, and recording was performed. The cancellation power P 1 at the bending point Q 1 is the same as that of the embodiment 4 and becomes 6.5 mW, and the elimination power ratio is 0.5. As shown in Table 2, the D0W1 jitter was 9.2% and was slightly larger, but similarly to Example 4, good characteristics were obtained. (Embodiment 8) Using the optical recording medium A of the fourth embodiment, in the recording conditions of the fourth embodiment, the erasing power pe was changed to 6.5 mW to perform recording and evaluation. The cancellation power P 1 at the bending point Q 1 is the same as in the embodiment 4 and -37 - (34) (34) 1279961 becomes 6.5 mW, and the power ratio is eliminated. As shown in Table 2, the DOW1 000 jitter system was 9.4% and was slightly larger, but similarly to Example 4, good characteristics were obtained. (Comparative Example 3) An optical recording medium A having a large Sb / Te ratio of a 4-element single alloy target of Ge-in-Sb-Te used in the recording layer 3 of Example 4 was used. When the reflectance curve of the optical recording medium A of Comparative Example 3 is produced, there is no bending point Q 1 and peak point Q2, and in the second drawing, the reflectance curve C2 having a small change in reflectance indicated by a broken line is drawn. . Therefore, the cancel power P1 at the bending point Q1 cannot be obtained, but the reflectance R0 of the unrecorded portion becomes 21.6, and the maximum 値 of the reflectance curve C2 becomes the maximum reflectance R1 = 22.0, which is calculated in the same manner as described above. The reflectance ratio is 〇.〇2. Recording and evaluation were carried out by the same recording conditions as in Example 4. The initial characteristics and the rewrite recording characteristics are as shown in Table 2. The D Ο W 0 and DOW9 jitter systems are good, but the DOW1 jitter is deteriorated, and good D OW jitter characteristics cannot be obtained. (Comparative Example 4) An optical recording medium A having a small S b /T e ratio of a 4-element single alloy target of Ge-In-Sb-Te used in the recording layer 3 of Example 4 was used. The reflectance curve is the same as that of Comparative Example 3, and C2 is not obtained, and the power P 1 at the bending point Q 1 cannot be obtained, but the reflectance of the unrecorded portion is -38 - (35) 1277961 R0 becomes 19·1, and the reflection is made. The maximum 値 of the rate curve C2 becomes the maximum reflectance R1 = 19.4, and the reflectance ratio calculated in the same manner as described above is 0.02. In the recording conditions of the fourth embodiment, the recording power Pw was changed to 1.5 〇 mW, and the erasing power Pe was 4.2 mW to perform recording and evaluation. The initial characteristics and the rewrite recording characteristics are as shown in Table 2. The DO W0 jitter system is good, but the DO Wl, DO W9, and DOW 1 000 jitter systems are deteriorated, and good D Ο W jitter characteristics cannot be obtained.

I (比較例5 ) 使用以雷射功率220 OmW來對於相同於實施例4之同 樣構造之光記錄媒體進行啓始化之光記錄媒體A。以該啓 始化條件來進行啓始化之光記錄媒體A係正如第1 3圖所 示,使得在 1個軌道內之反射率之變動變大。R〇係 17.5,在彎曲點 Q1之消除功率 P1係 5.0mW,R1係 2 1.0,反射率比係〇 . 2 0。 &gt; 在以相同於實施例4之同樣之記錄條件而進行記錄· 評價時,正如表2所示,DOWO、DOW1及DOW1000抖動 係變差,無法得到良好之DOW抖動特性。此外,消除功 率比係0.9。 (比較例6) 使用相同於實施例4之光記錄媒體A,在實施例4之 記錄條件中,改變消除功率Pe成爲2.5mW,來進行記錄 •評價。在彎曲點Q 1之消除功率P 1係相同於實施例4而 -39- (36) 1277961 成爲6.5mW,消除功率比係0.4。 正如表2所示,由DOW0抖動而使得抖動! 以上,無法得到良好之DOW抖動特性。 (比較例7) 使用相同於實施例4之光記錄媒體A,在實 記錄條件中,改變消除功率Pe成爲7.5mW,來 •評價。在彎曲點Q 1之消除功率P 1係相同於實 成爲6.5mW,消除功率比係1.2。 正如表2所示,由DO W0抖動而使得DO W9 到良好之値,但是,DOW 1 000抖動係顯示10% 法得到良好之DOW抖動特性。 由以上而判明:在反射率比((R1 — R0 ) 足以下之公式(2 )時,光記錄媒體係得到良好之 動特性。 0.03 ^ (Rl— R0) / R0 ^ 0.15 …(2) 在第14圖,顯示實施例4〜實施例6及比_ 較例5之DOW抖動特性。在隨著反射率比小於 就是消除功率之增加而不增加反射率之狀態下, 動係成爲1 0 %以上,惡化記錄特性。另一方面, 比大於〇 · 1 5之狀態下,以在1個軌道中而混在 之部分和反射率小之部分之條件,來進行啓始化 無法由DOW0來得到良好之記錄及重寫特性。 在第1 5圖,顯示實施例4〜實施例6及比_ 示10% 施例4之 進行記錄 施例4而 之抖動得 以上,無 / R0 )滿 :DOW 抖 ί例3〜比 0.03 、也 D Ο W 1 抖 在反射率 反射率大 ,因此, ί例3〜比 -40- (37) (37)1277961 較例5之RF訊號相對於消除功率Pe之關係。 此外,判明:由表2而得知消除功率比(pe/ p丨)最 好是滿足以下之公式(3 )。 0.5 ^ Pe/ P 1 ^ 1.0 …(3 ) 在第1 6圖,顯示實施例4、實施例7、實施例8及比 較例6、比較例7之DOW抖動特性。在消除功率比小於 〇 · 5時,消除功率Pe變小,無法充分地消除記錄標記,医! 此,無法由DOW0來得到良好之記錄及重寫特性。另一方 面,在消除功率比大於1·〇時,DOW9以後之抖動係成爲 1 0 %以上,惡化記錄特性。 此外,判明:光記錄媒體Α之啓始化條件係也影響到 記錄及重寫特性。正如第13圖所示,以在1個軌道內之 反射率變動大之啓始化條件來進行啓始化之光記錄媒體A 係無法得到良好之記錄及重寫特性。因此,光記錄媒體A 係最好是以在1個軌道內之反射率實質不變動之最適當之 啓始化條件來進行啓始化。 不僅是在前面敘述所提到之DVD - RW等之相變化型 光記錄媒體,即使是第1 7圖所示之超高密度之相變化型 記錄媒體之構造,也可以說是具有同樣之效果。第17圖 所示之光記錄媒體B係成爲在以記錄•再生或消除用雷射 光之入射面17a作爲底面之保護層17上依序地層積第1 保護層12、記錄層13、第2保護層14、反射層1 5及基板 Π之構造。 (38) 1277961 【圖式簡單說明】 第1圖係顯示相變化型光記錄媒體之製造設備3 0 0或 者是藉由製造設備3 0 0所進行之製造•啓始化製程之圖。 第2圖係顯示本發明之光記錄媒體之某一實施形態之 擴大剖面圖。 第3圖係顯示本發明之光記錄媒體之某一實施形態之 俯視圖。 第4圖係顯示記錄脈衝圖案之第1例之圖。 第5圖係顯示記錄脈衝圖案之第2例之圖。 第6圖係顯示本發明之光記錄裝置之某一實施形態之 方塊圖。 第7圖係顯示4分割受光元件之某一實施形態之擴大 剖面圖。 第8圖係藉由示波器而觀測在偏離軌道狀態之差異訊 號振幅之圖。 第9圖係顯示和偏離軌道狀態相對於啓始化功率之差 異訊號振幅間之關係之圖。 第10圖係顯示抖動相對於DOW次數之關係之DOW 抖動特性圖。 第1 1圖係顯示光記錄媒體A之反射率變動之理想之 某一例子之圖。 第1 2圖係呈示意地顯示反射率曲線之某一例子之 圖。 第1 3圖係顯示光記錄媒體A之反射率變動之不理想 -42- (39) 1277961 之某一例子之圖。 第1 4圖係顯示實施例4〜實施例6及比較例3〜比較 例5之DOW抖動特性之圖。 第1 5圖係顯示實施例4〜實施例6及比較例3〜比較 例5之RF訊號相對於消除功率pe之關係之圖。 第16圖係顯示實施例4、實施例7、實施例8及比較 例6、比較例7之D Ο W抖動特性之圖。 第1 7圖係顯示本發明之光記錄媒體之其他實施形態 之擴大剖面圖。 $要元件符號說明】 A 光記錄媒體 B 光記錄媒體 Pi 彎曲點Q1之消除功率 Pb 基底功率 Pe 消除功率 P w 記錄功率 TC1 消除脈衝 Tmp 記錄脈衝 Tt〇p 記錄脈衝 1 基板 la 入射面 2 第1保護層 3 記錄層 -43- (40)1277961 4 5 6 11 12 13 14I (Comparative Example 5) An optical recording medium A which was initialized with the optical power of the same configuration as that of Example 4 at a laser power of 220 OmW was used. The optical recording medium A which is initialized under the priming condition is as shown in Fig. 3, so that the fluctuation of the reflectance in one track becomes large. R 〇 17.5, the power at the bending point Q1 is eliminated. P1 is 5.0mW, R1 is 2 1.0, and the reflectance is 〇. &gt; When recording and evaluation were performed under the same recording conditions as in Example 4, as shown in Table 2, the DOWO, DOW1, and DOW1000 jitters were deteriorated, and good DOW jitter characteristics could not be obtained. In addition, the elimination power ratio is 0.9. (Comparative Example 6) Using the optical recording medium A of the fourth embodiment, in the recording conditions of the fourth embodiment, the recording power was changed to 2.5 mW, and recording and evaluation were performed. The cancellation power P 1 at the bending point Q 1 is the same as in the embodiment 4 and -39-(36) 1277961 becomes 6.5 mW, and the elimination power ratio is 0.4. As shown in Table 2, jitter is caused by DOW0 jitter! Above, good DOW jitter characteristics cannot be obtained. (Comparative Example 7) Using the optical recording medium A of the same manner as in Example 4, in the actual recording conditions, the erasing power Pe was changed to 7.5 mW for evaluation. The cancellation power P 1 at the bending point Q 1 is the same as 6.5 mW, and the power ratio is 1.2. As shown in Table 2, DO W9 is good by DO W0 jitter, but the DOW 1 000 jitter shows that the 10% method gives good DOW jitter characteristics. From the above, it was found that the optical recording medium obtained good dynamic characteristics when the reflectance ratio ((R1 - R0) was sufficient (2). 0.03 ^ (Rl - R0) / R0 ^ 0.15 (2) Fig. 14 shows the DOW jitter characteristics of the embodiment 4 to the embodiment 6 and the ratio _ compared with the example 5. The dynamic system becomes 10% in a state where the reflectance ratio is smaller than the increase in the elimination power without increasing the reflectance. In the above, the recording characteristics are deteriorated. On the other hand, in the state where the ratio is larger than 〇·15, the start-up can not be obtained by DOW0 under the condition that the portion mixed in one track and the portion having a small reflectance are small. The recording and rewriting characteristics are shown in Fig. 15, and the jitters of the recording example 4 are shown in the fourth embodiment to the sixth embodiment and the ratio of 10% to the fourth embodiment, and no/R0) is full: DOW is shaken. ίExample 3~ is more than 0.03, and D Ο W 1 is shaken at a reflectance reflectance. Therefore, ί3~40-37(37) (37)1277961 is compared with the RF signal of Example 5 relative to the cancellation power Pe. . Further, it has been found that it is preferable from Table 2 that the elimination power ratio (pe/p丨) satisfies the following formula (3). 0.5 ^ Pe / P 1 ^ 1.0 (3) The DOW jitter characteristics of Example 4, Example 7, Example 8, Comparative Example 6, and Comparative Example 7 are shown in Fig. 16. When the elimination power ratio is less than 〇 · 5 , the elimination power Pe becomes small, and the recording mark cannot be sufficiently eliminated. Therefore, good recording and rewriting characteristics cannot be obtained by DOW0. On the other hand, when the cancellation power ratio is greater than 1·〇, the jitter after DOW9 becomes 10% or more, and the recording characteristics are deteriorated. In addition, it was found that the initiation conditions of the optical recording medium also affect the recording and rewriting characteristics. As shown in Fig. 13, the optical recording medium A which was initialized with the initialization condition in which the reflectance variation in one track was large was not able to obtain good recording and rewriting characteristics. Therefore, it is preferable that the optical recording medium A is initialized with an optimum starting condition in which the reflectance in one track does not substantially change. Not only the phase-change optical recording medium such as the DVD-RW mentioned above, but also the structure of the ultra-high-density phase change type recording medium shown in Fig. 7 can be said to have the same effect. . The optical recording medium B shown in Fig. 17 is formed by sequentially laminating the first protective layer 12, the recording layer 13, and the second protective layer on the protective layer 17 having the incident surface 17a for recording/reproducing or eliminating the laser light as the bottom surface. The structure of the layer 14, the reflective layer 15 and the substrate stack. (38) 1277961 [Simplified description of the drawings] Fig. 1 is a diagram showing a manufacturing apparatus of the phase change type optical recording medium 300 or a manufacturing/initiation process by the manufacturing apparatus 300. Fig. 2 is an enlarged cross-sectional view showing an embodiment of an optical recording medium of the present invention. Fig. 3 is a plan view showing an embodiment of an optical recording medium of the present invention. Fig. 4 is a view showing a first example of a recording pulse pattern. Fig. 5 is a view showing a second example of the recording pulse pattern. Fig. 6 is a block diagram showing an embodiment of the optical recording apparatus of the present invention. Fig. 7 is an enlarged cross-sectional view showing an embodiment of a four-divided light-receiving element. Figure 8 is a graph showing the amplitude of the difference signal in the off-track state by an oscilloscope. Figure 9 is a graph showing the relationship between the amplitude of the difference signal and the difference between the off-track state and the initial power. Figure 10 is a plot of DOW jitter characteristics showing the relationship of jitter to DOW times. Fig. 1 is a view showing an example of the ideal change in the reflectance of the optical recording medium A. Fig. 12 is a diagram schematically showing an example of a reflectance curve. Fig. 1 is a view showing an example of the variation of the reflectance of the optical recording medium A - 42 - (39) 1277961. Fig. 14 is a view showing the DOW jitter characteristics of Examples 4 to 6 and Comparative Examples 3 to 5. Fig. 15 is a view showing the relationship between the RF signals of Example 4 to Example 6 and Comparative Example 3 to Comparative Example 5 with respect to the cancellation power pe. Fig. 16 is a view showing the D Ο W jitter characteristics of Example 4, Example 7, Example 8, Comparative Example 6, and Comparative Example 7. Fig. 17 is an enlarged cross-sectional view showing another embodiment of the optical recording medium of the present invention. $Required symbol description] A Optical recording medium B Optical recording medium Pi Bending point Q1 Elimination power Pb Base power Pe Elimination power P w Recording power TC1 Elimination pulse Tmp Recording pulse Tt〇p Recording pulse 1 Substrate la Injecting surface 2 1 Protective layer 3 Recording layer -43- (40)1277961 4 5 6 11 12 13 14

17a 3 2 第2保護層 反射層 第3保護層 基板 第1保護層 記錄層 第2保護層 反射層 保護層 入射面 轉軸馬達 旋轉控制部 33 3417a 3 2 2nd protective layer Reflective layer 3rd protective layer Substrate 1st protective layer Recording layer 2nd protective layer Reflective layer Protective layer Injecting surface Rotary axis motor Rotation control unit 33 34

3 5 36 3 7 38 3 9 39c 39m 39t 40 4 1 LD 光學頭(讀出部、記錄部) 致動器控制部 擺動檢測部 位址解調電路 記錄時脈生成部 記錄脈衝生成部(記錄部) 消除脈衝控制訊號生成部 多重脈衝控制訊號生成部 前頭脈衝控制訊號生成部 脈衝數控制部 E F Μ +編碼器(編碼器) -44- (41)12779613 5 36 3 7 38 3 9 39c 39m 39t 40 4 1 LD optical head (reading unit, recording unit) Actuator control unit wobble detection site demodulation circuit recording clock generation unit recording pulse generation unit (recording unit) Elimination pulse control signal generation unit Multiple pulse control signal generation unit Front pulse control signal generation unit Pulse number control unit EF Μ + Encoder (Encoder) -44- (41)1277961

42 標記長度計數器(標記長度生 43 LD驅動器部(記錄部) 44 驅動控制器 45 系統控制器 46 反射率檢測部 5 1 中心孔 52 夾緊區域 53 資訊區域(導入區域) 54 記錄區域 100 製造裝置(製造製程) 200 啓始化裝置(啓始化製程) 300 製造設備 34 1 4分割受光元件(第1受光元 元件群) 34 1a 受光元件 34 1b 受光元件 34 1c 受光元件 341d 受光元件 361 可程式化BPF 38 1 PLL合成器 400 記錄部(記錄脈衝生成部3 9、 43、光學頭34 ) 43 1 開關部 43 1 b P b驅動電流源 成部) 件群、第2受光 LD驅動器部 -45- (42) 1277961 43 le 4 3 1 w 45 1 P e驅動電流源 P w驅動電流源 記憶體42 Marker length counter (mark length 43 LD driver section (recording section) 44 Drive controller 45 System controller 46 Reflectance detecting section 5 1 Center hole 52 Clamping area 53 Information area (introduction area) 54 Recording area 100 Manufacturing apparatus (Manufacturing Process) 200 Initializing Device (Initialization Process) 300 Manufacturing Equipment 34 1 4 divided light receiving elements (first light receiving element group) 34 1a Light receiving element 34 1b Light receiving element 34 1c Light receiving element 341d Light receiving element 361 Programmable BPF 38 1 PLL synthesizer 400 recording unit (recording pulse generating unit 39, 43 and optical head 34) 43 1 switch unit 43 1 b P b driving current source forming unit), second light receiving LD driver unit - 45 - (42) 1277961 43 le 4 3 1 w 45 1 P e drive current source P w drive current source memory

-46-46

Claims (1)

(1) 1277961 十、申請專利範園 1. 一種光記錄媒體,其特徵爲:在相變化型光記錄媒 體,具備: 基板;以及, 具有用以記錄資訊之軌道之記錄層;此外, 構成前述記錄層之材料係以旋轉前述光記錄媒體同時 接受在前述記錄層以偏離軌道狀態來照射雷射光時之反射 光所得到之追蹤檢測訊號之振幅値,小於其飽和値之結晶 化狀態,來進行啓始化。 2·如申請專利範圍第1項所記載之光記錄媒體,其 中,前述追蹤檢測訊號係藉由在對於前述軌道呈對向配置 之第1及第2受光元件群接受前述反射光而得到之受光訊 號之兩者之差異訊號。 3·如申請專利範圍第1或2項所記載之光記錄媒體, 其中,前述振幅値除以前述飽和値之値係大於0 · 6、小於 1.0。 4·一種光記錄媒體,其特徵爲:在相變化型光記錄媒 體,具備: 基板;以及, 用以記錄資訊之記錄層;此外, 前述記錄層係使得在一次也並無記錄前述記錄層之資 訊之未記錄部來施加具有既定之直流消除功率之光後而照 射再生光之所得到之前述未記錄部之反射率,成爲前述既 定之直流消除功率,在由功率〇開始依序地增大時,呈現 -47- (2) 1277961 以既定之曲線來進行變化之特性; 前述既定之曲線係具有: 反射率槪略成爲一定之直線部; 接續於該直線部之反射率增大之第1曲線部;以及, 反射率減少之第2曲線部;此外, 在成爲前述直線部和第1曲線部間之境界之彎曲點之 反射率R0、成爲前述第丨曲線部和第2曲線部間之境界 • 之波峰點之反射率R1時,呈現成立下列公式(1 )之特 、 性: 〇·〇3 g ( ( R1 - R〇 ) / r〇 ) g 〇」5 …(1 )。 5 ·如申請專利範圍第4項所記載之光記錄媒體,其 中,構成前述記錄層之材料係以在1個軌道內之反射率槪 略成爲一定之結晶化狀態,來進行啓始化。 6 .· —種光記錄方法,其特徵爲:在相變化型光記錄媒 體之記錄層將記錄資訊予以記錄之光記錄方法,前述光記 φ 錄媒體係使得前述記錄層,在一次也並無記錄前述記錄層 之資訊之未記錄部來施加具有既定之直流消除功率之光後 而照射再生光之所得到之前述未記錄部之反射率,成爲前 述既定之直流消除功率,在由功率0開始依序地增大時, 呈現以既定之曲線來進行變化之特性; 述既定之曲線係具有: 反射率槪略成爲一定之直線部; 接續於該直線部之反射率增大之第1曲線部;以及, 反射率減少之第2曲線部;此外, -48- (3) (3)1277961 在成爲前述直線部和第1曲線部間之境界之彎曲點之 反射率R0、成爲前述第1曲線部和第2曲線部間之境界 之波峰點之反射率R1時,呈現成立下列公式(1 )之特 性: 0.03 ^ ( (R1-R0) / R0 ) €0.15 …(1) 前述光記錄方法係包含: 調變前述記錄資訊而生成調變資料之調變步驟; 根據前述調變資料而生成要求之標記長度之標記長度生成 步驟;以及, 根據前述標記長度,而生成由形成在從消除功率開始 上升並且介於大於前述消除功率之記錄功率和小於前述消 除功率之基底功率間之記錄脈衝以及由前述基底功率開始 上升至前述消除功率之消除脈衝所構成之記錄脈衝圖案, 對於前述記錄層,來配合於前述記錄脈衝圖案,照射記錄 光,而記錄顯示前述記錄資訊之記錄標記之記錄步驟;此 外, 前述記錄步驟係當令在前述記錄脈衝圖案之前述消除 功率爲Pe而前述彎曲點之消除功率爲P 1時,使用下列公 式(2 )成立之消除功率Pe : 0.5 ^ Pe/ P1 ^ 1.0 …(2 )。 7 · —種光記錄裝置,其特徵爲:在相變化型光記錄媒 體之記錄層將記錄資訊予以記錄之光記錄裝置,前述光記 錄媒體係使得前述記錄層,在一次也並無記錄前述記錄層 之資訊之未記錄部來施加具有既定之直流消除功率之光後 -49- (4) 1277961 而照射再生光之所得到之前述未記錄部之反射率,成爲前 述既定之直流消除功率,在由功率〇開始依序地增大時, 呈現以既定之曲線來進行變化之特性; 前述既定之曲線係具有: 反射率槪略成爲一定之直線部; 接續於該直線部之反射率增大之第1曲線部;以及, 反射率減少之第2曲線部;此外, φ 在成爲前述直線部和第1曲線部間之境界之彎曲點之 . 反射率R0、成爲前述第1曲線部和第2曲線部間之境界 之波峰點之反射率R1時,呈現成立下列公式(1 )之特 性: 0.03 ^ ( (Rl— R0) / R0 ) $0.15 …(1) 前述光記錄裝置係包含: 調變前述記錄資訊而生成調變資料之編碼器; 根據前述調變資料而生成要求之標記長度之標記長度 φ 生成部;以及, 根據前述標記長度,而生成由形成在從消除功率開始 上升並且介於大於前述消除功率之記錄功率和小於前述消 除功率之基底功率間之記錄脈衝以及由前述基底功率開始 上升至前述消除功率之消除脈衝所構成之記錄脈衝圖案, 對於前述記錄層,來配合於前述記錄脈衝圖案,照射記錄 光,而記錄顯示前述記錄資訊之記錄標記之記錄部;此 外, 前述記錄部係當令在前述記錄脈衝圖案之前述消除功 -50- (5) 1277961 率爲Pe而前述彎曲點之消除功率爲P1時, (2)成立之消除功率Pe : 0.5 ^ Pe/ P1 ^ 1.0 …(2 )。 8 .如申請專利範圍第7項所記載之光 中,具備:儲存顯示前述消除功率Pe之辨 部;前述記錄部係使用根據儲存於前述儲存 資訊所造成之消除功率。 使用下列公式 記錄裝置,其 識資訊之儲存 部之前述辨識(1) 1277961 X. Patent application studio 1. An optical recording medium characterized by: a phase change optical recording medium comprising: a substrate; and a recording layer having a track for recording information; The material of the recording layer is rotated by rotating the optical recording medium while receiving the amplitude of the tracking detection signal obtained by the reflected light when the recording layer is irradiated with the off-track state, and is smaller than the saturation crystallization state. Initiation. The optical recording medium according to the first aspect of the invention, wherein the tracking detection signal is received by receiving the reflected light from the first and second light receiving element groups disposed opposite to the track. The difference between the two signals. 3. The optical recording medium according to claim 1 or 2, wherein the amplitude 値 divided by the saturation enthalpy is greater than 0.6 and less than 1.0. 4. An optical recording medium, comprising: a substrate; and a recording layer for recording information; and the recording layer is such that the recording layer is not recorded at one time. The non-recording unit of the information applies the reflectance of the unrecorded portion obtained by irradiating the regenerated light after applying the light having the predetermined DC canceling power, and becomes the predetermined DC canceling power, and sequentially increases from the power 〇. In the case of -47- (2) 1277961, the characteristic is changed by a predetermined curve; the predetermined curve has: a linear portion in which the reflectance is slightly constant; and the first increase in the reflectance of the straight portion a curved portion; and a second curved portion having a reduced reflectance; and a reflectance R0 at a bending point which is a boundary between the straight portion and the first curved portion, and between the second curved portion and the second curved portion When the reflectance of the peak point of the boundary is R1, the following formula (1) is established: 〇·〇3 g (( R1 - R〇) / r〇) g 〇"5 ... (1). In the optical recording medium according to the fourth aspect of the invention, the material constituting the recording layer is initialized by a crystallized state in which the reflectance in one track is substantially constant. 6. An optical recording method characterized by: an optical recording method for recording recorded information on a recording layer of a phase change optical recording medium, wherein said optical recording φ recording medium causes said recording layer to be absent at a time The unrecorded portion that records the information of the recording layer and applies the reflectance of the unrecorded portion obtained by irradiating the reproduced light with light having a predetermined DC canceling power, and becomes the predetermined DC canceling power, starting from the power 0 When sequentially increasing, the characteristic is changed by a predetermined curve; the predetermined curve has: a linear portion in which the reflectance is slightly constant; and a first curved portion in which the reflectance of the straight portion is increased. And a second curve portion in which the reflectance is reduced; and -48-(3) (3)1277961, the reflectance R0 at a bending point which is a boundary between the straight portion and the first curved portion, becomes the first curve When the reflectance R1 of the peak point of the boundary between the portion and the second curved portion is set, the characteristic of the following formula (1) is established: 0.03 ^ ( (R1-R0) / R0 ) €0.15 (1) The optical recording method described above The method includes: a modulation step of generating the modulation data by modulating the foregoing record information; generating a mark length generation step of the required mark length according to the modulation data; and generating, according to the mark length, the generation from the cancellation power a recording pulse pattern formed by rising and between a recording power greater than the aforementioned cancellation power and a substrate power smaller than the cancellation power and a cancellation pulse rising from the base power to the cancellation power, for the recording layer a recording step of illuminating the recording light and recording the recording mark indicating the recording information; and the recording step is such that the cancellation power of the recording pulse pattern is Pe and the power of the bending point is When P 1 , the elimination power Pe is established using the following formula (2): 0.5 ^ Pe / P1 ^ 1.0 (2). An optical recording apparatus characterized in that an optical recording apparatus records recording information on a recording layer of a phase change optical recording medium, wherein the recording medium does not record the recording at a time The unrecorded portion of the information of the layer applies the reflectance of the unrecorded portion obtained by irradiating the reproduced light to -49-(4) 1277961 after the light having the predetermined DC canceling power, and becomes the predetermined DC canceling power. When the power 〇 is sequentially increased, the characteristic is changed by a predetermined curve; the predetermined curve has: a linear portion in which the reflectance is slightly constant; and the reflectance subsequent to the straight portion is increased. a first curved portion; and a second curved portion having a reduced reflectance; and φ is a bending point which is a boundary between the straight portion and the first curved portion. The reflectance R0 is the first curved portion and the second portion When the reflectance R1 of the peak point of the boundary between the curves is set, the following formula (1) is established: 0.03 ^ ( (Rl - R0) / R0 ) $0.15 (1) The above optical recording device The method includes: an encoder that modulates the record information to generate modulated data; generates a mark length φ generating portion of a required mark length according to the modulated data; and generates a power generated by the slave according to the mark length a recording pulse pattern formed by a recording pulse composed of a recording pulse having a recording power greater than the aforementioned cancellation power and a substrate power smaller than the cancellation power and a cancellation pulse rising from the substrate power to the cancellation power, for the recording layer, Cooperating with the recording pulse pattern, illuminating the recording light, and recording the recording portion of the recording mark indicating the recording information; and the recording portion is configured to cancel the above-mentioned recording pulse pattern by the -50-(5) 1277961 rate. When the cancellation power of the aforementioned bending point is P1, (2) the elimination power Pe: 0.5 ^ Pe/ P1 ^ 1.0 (2) is established. 8. The light as recited in claim 7 includes: a portion for storing and displaying the cancel power Pe; and the recording portion for canceling power based on the stored information. Use the following formula to record the device, and the aforementioned identification of the information storage section -51 --51 -
TW94100164A 2004-01-30 2005-01-04 Optical storage medium, optical recording method and optical recording apparatus TWI277961B (en)

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JP2004370807A JP2005243213A (en) 2004-01-30 2004-12-22 Optical recording medium
JP2004379539A JP2005243217A (en) 2004-01-30 2004-12-28 Optical recording medium, optical recording method and optical recorder

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