1269820 坎、發明說明： 【發明所屬之技術領域】 、，本發明係有關一種織物及纖維製品，具備安全、而且 _ f欠久f生防触、抗菌、抗霉效果，可分解淨化有害物質， 2可發生負離子之織物及以其纖維製品為材料之纖維 表品° 【先前技術】 自攸過去’具有防蟲、抗菌、抗霉效果之， ==!用者有，例如將特定有效成分在製造原料纖二 去之纖維製品，或在染色工序時附著此等有效成分 衣口口 〇 已開發利用有’在合成樹脂薄膜間夹抗菌性金屬 =層狀構造物所成疊層紗或疊層物之纖維製品（例如曰 本特開2 0 01 — 49541赛直:ί丨丨八& 八扭號翻公報，國際公開01/98567號 公報、國際公開01/83880號公報）。 更有利用可產生電位差之多赵厶M ^ ^ „ 夕數金屬，夾於合成樹脂薄 ^ 农战童層鈔或豐層物之纖維製品 者。（例如日本特開2003-328237號專利公報）。 ^是’據說負離子有使人舒暢之效果，乃有利用可發 負離子之木厌或電石之粉碎微粉末附著•混入•塗布 之纖維製品’亦見有開發而利用去 7恢b 土、 才J用者〇(例如，日本特開2000 一73254號公報）。 可是此等纖維製品卻有下列問題存在。 利用疊層紗或疊層物之纖維製品，對細菌•病毒•及 1269820 震：等—部分霉雖有效，但是對活存力強之黑·霉•紅 X成霉等則無法期待完全控制其增殖嘴•跳蚤•昆蟲 待。避放果或大型菌類·浮遊生物之增殖控制亦無法期 又，於產生電位差之包含多數金屬《疊層紗或疊層 體，需蒸鍍多數金屬而有製造成本高之問題。 山、再者利用木厌或電石（tourmalin)之纖維製品，木 j包石寻因易受洗濯等外部刺激而脱落，有無法長 持其效能之問題。 + 、何況，併具防蟲•抗菌•抗霉效果與S生負離子能力 之纖維製品，至今未見開發。 維制月之目的為解決上述諸問題，提供—種織物及纖 、’、製品’具防蟲·抗菌·抗霉效果，同時可發生負離子， ，解淨化有害物質或振動等刺激亦不致減低此 等機能’並不損使用者之觸摸感•美觀•機能實感等 物及利用忒織物為一部分材料之纖維製品。 【發明内容】 本發明有關之第1織物，具有：第丨疊層紗，係在合 成樹脂薄膜之一面蒸鍍金屬㉟，將蒸鑛同-金屬層之雙方 合成樹脂薄膜互相間之金屬層向内面互相粘合製造^成 夾層狀構造物，再將夾層狀構造物切割成紗狀所形成1及 第2疊層紗，係與構成第丨疊層紗之金屬層有電位差之金 屬，蒸鍍於合成樹脂薄膜之一面，將蒸鍍有該金屬層之雙 方合成樹脂薄膜互相間之金屬層向内面互相粘合製造成 1269820 夾層狀構物再切割夾層狀構造物成紗狀所形成，將此 等作為原紗之一部分。 又，本發明有關之第2織物，係第J疊層紗與第2 疊層紗，互相交差配置者。 又，本發明有關之第3織物，具有··第i疊層物，係 在合成樹脂薄膜之-面蒸鍵金屬層，蒸鍍同—金屬層之雙 方合成樹脂薄膜互相間之金屬層向内面互相粘合製造形 ，夾層狀構造物，再將夹層狀構造物粉碎所形成；及第2 豐層物’係與構成第i疊層紗之金屬層有電位差之金屬， 蒸鍍=合成樹脂薄膜之一面，將蒸鍍有金屬層之雙方合成 樹脂薄膜互相間之金屬層向内面互相枯合製造成夹層狀 構造物，再將此夹層狀構造物粉碎形成，而將此等附著於 織物者。 再者，本發明有關之纖維製品，係使用上述織物作為 材料之一部分者。 一如此，本發明有關之織物及纖維製品，係由於含有不 同種類金屬之疊層紗或疊層物間產生電位差，即所謂電池 之作用，流經微弱電流而產生防蟲•抗菌•抗霉•負離子 發生作用。 又，因金屬層受合成樹脂薄膜之保護，及露出面受摩 $，反覆洗濯以疊層紗及疊層物為構成要素之織物及纖維 衣口口，或使用漂白劑，亦不致減低防蟲•殺菌•抗霉效果 ^負離子發生效果，亦不致因金屬層黑化而使疊層紗、疊 層物及以此等為構成要素之織物及纖維製品之外觀劣化。 1269820 【實施方式】 以下參照圖面說明本發明之實施方式。 立第1圖為本發明有關織物之一之先染織物（織物A ) 之部分放大圖。如圖所示，織物A係將第丨疊層紗、第$ 疊層紗、紗3，依第1疊層紗i/紗3/第2疊^紗2/紗 3/第1疊層紗1/紗3/第2疊層紗2…、之順序成一定 排列之平紋織物。再者，第i疊層紗i與第2疊層紗2 之間隔為約丄〜加咖，但是，為期待效果與成本之關係， 以約2〜15mm為佳。 …第2圖為第1疊層紗！或第2疊層紗2之放大圖，此 等豐層紗係由下述工序製造。再者，以下就疊層紗1之情 形，明之，但是除後述之金屬層不同之外，疊層紗丨與第 2璺層紗2之製造工序均相同，因此第2疊層紗2之製造 工序除不同部分省則略其說明。 百先，在合成樹脂薄膜la，由真空蒸鍍法或離子蒸 鐘法將金屬蒸鑛上成金屬層lb。其次，將蒸鍵有金屬 層lb之雙方合成樹脂薄膜la互相之金屬層^向内面用 粘合劑粘合，製造成由合成薄膜la夾住金屬層lb之夾層 狀構造物。最後將夾層狀構造物向縱向切割即完成疊層紗 1。再者，疊層紗之寬度，考慮到經濟性及對皮膚之感覺， 約100〜500 # m為宜，但是考慮到織物之質量感、切割工 序之易否等，以150〜250 //m為佳。 在此’合成樹脂薄膜la為聚酯、聚醯胺、聚烯烴等 所製成之薄膜，其厚度為約4〜5〇^m，就製品之柔軟度 1269820 而言則約6〜12g m為宜。 鐵、=構成金屬層1b及2b之金屬，可考慮銘、鎮、錫、 之金：》銀、金等金屬，只要在金屬層1b與第2疊層紗 於=2b間能產生電位差’則各種金屬均可使用。至 與金屬層2b之組合，例如有紹與錫、綱、 揚與銀、鐵與銅、鋁與金等。 聚丙^枯合劑可考慮聚氨醋系枯合劑、聚醋系枯合劑、 =合劑等’但是考慮織物之安全性，則低甲搭性 聚I系為宜。再者，疊層紗卜2可視織物 全屬Ϊ 财久性而使用在合成樹脂薄膜之一面設 屬膜，另一面為塗布合成樹脂者。 為本發明有關之_法製不織布（織物約之 二係在由纖維4所成之不織布表面'混 豐Γ6與枯合劑網印成點狀者。再者，於 圖Γ印上之各點’係僅含疊層物5或疊層物6中之 二ST疊層物5與疊層物6之雙方亦可。又，網 Ρ 4物之形狀’除點狀之外，線 上網印整面亦可。 忒在不織布 又，纖維4為天然纖維哎八， 聚乙烯酵_聚心 樹脂等’將此等樹脂經物 】知湖曰、酯系 脂有相溶性之既知發泡=、::用，或混合與上述樹 性等機能。 胃σ路出而提高抗菌性，抗霉 1269820 第4圖為疊層物5與疊層物6之類型圖構造，如圖所 示疊層物5與疊層物6，分別由合成樹脂薄膜“及6&、 將金屬層5b與6b夾住構成夾層狀構造。 如此豐層物5與疊層物6，如同疊層紗丨之方法，製 造夾層狀構造物，在縱橫雙方向切割、粉碎來製造。/再者， 疊層物5與疊層物6之切割尺寸為—邊為^.卜^㈣之 略方形為宜。再者，構成合成樹脂薄膜5&與6&，及金屬 層5b與6b之材料種類及其厚度等，可如同構成疊層紗i 及疊層紗2者。 於如此所構成之織物A及織物B，經過此等製品所含 水分及生活環境及汗之水分、廚歧賴、澡堂、洗濯等 人為給予之水分’在疊層紗丄與疊層紗2之間、或疊層物 5與疊層物6之間產生電位差，由該電位差之微弱電流產 生上述機能•效果。又，因金屬層lb、2b、此、叻，之 側面路出於外面，難免氧化•氯化，但是與鄰接之纖維互 相摩擦，該氧化部分易脱落，既使不脱落亦不易見到。又， 金屬層lb、2b、5b、6b，之侧面以外部分，係由合成樹 脂缚膜la、2a、5a或6a所保護，因此不氧化•氣化。因 =’一再洗濯或使用漂白劑，抗g效果•抗霉效果及負離 子發生效果亦不致減低。 其夂，製造本發明之織物，並進行各種試驗 細說明。 (1 )疊層紗之製造 在厚度12" mm之聚g旨薄膜（東麗製）以真空蒸鑛法 10 1269820 蒸鍍50nm之金屬層。其次，由聚酯系粘合劑將蒸鍍有相 同金屬層之雙方聚酯薄膜使金屬層向内面互相粘合，製造 成夾層狀構造物。最後切割夾層狀構造物向縱向為寬度 150//m，製造第1疊層紗。以蒸鍍錫代替鋁而同樣製造第 2疊層紗。 (2) 織物之製造 其_人，以4 0支綿紗在1英寸間1 〇 〇支之均等間隔整 經作為自動織機之經紗。於是第丨疊層紗、4()支綿紗、 第2疊層紗在i英寸間共50支，使第i疊層紗與第2疊 層紗之間隔為4mm，按第1疊層紗、4〇支綿紗，第2疊層 紗、40支綿紗、第1疊層紗、…之順序作為緯紗製造平 紋織物（貫施例1 )。再者，此時之疊層紗係使用聚酯纖 、、隹2 0旦尼爾之紗2股左右逆向2 0 〇回/ m所撼成。 (3) 抗囷性試驗 再者，實施例1依JISL027103號洗濯10次，（洗衣 劑使用JAFET標準洗衣劑）後，由搖燒瓶（shake_flask) 法進行抗菌性試驗。但是，試驗菌種則使用肺炎桿菌。其 結果有效減菌率為84· 6%，註明有優異抗菌性。 又貝方也例1依JIS L 0 2 710 3號洗濯1 〇次，（洗衣劑 使用JAFET標準洗衣劑）後，依jis [1902定量試驗（統 一試驗方法）進行抗菌性試驗。其結果，生菌活性値為 2· 0，確認有優異抗菌防臭機能。試驗菌株使用黃色葡萄 球菌（Staphyl〇coccus aureus ATCC 6538P)。但是，金 屬層為铭之豐層紗、或金屬層為錫之疊層紗之任一單獨者 1269820 均不產生抗菌性為周知之事實。 通常方法所製造之織物並不具備如此機能，因此此等 機能可認為是由於在⑴所製造之叠層紗者。又，構成 綿紗與聚賴維，構成疊層紗之合成薄膜、龜、錫等本體 雖全無抗g性，但是併用含有此2種金叙疊層紗卻可出 現抗菌性。因此，上述抗菌作用，可認為係由於抗菌試驗 所給予水分之存在而在疊層紗間作成導電狀態，以致所含 有金屬間之電位差’即有電池之作用，流過微弱電流之關 係。 (4) 疊層物之製造 除金屬層為銀之外，將如同⑴之方法所製造之夾 層狀構造物粉碎為〇· 15瞻0.15丽，製造含銀之第 層物及含鋁之第2疊層物。 (5) 印花織物之製造 於聚醋100%之纺枯型不織布，對不織布、枯合劑、 疊層物之總共重量，與將第1疊層物與第2疊層物4倍發 泡之枯合劑混合而製造混合物，將此混合物由網版印刷印 成點狀製造印花織物（實施例2)β此織物含第丨•第2 疊層物各佔織物整體重量比之25%。》，於聚醋職 之紡粘型不織布，製造第丨疊層物與粘合劑混合之第i 此合物，另，製造第2疊層物與粘合劑混合之第2混人 於是，由網版印刷印成，第i混合物所成之點列，與:第2 混合物所成之點列互相交差之印花織物（實施例3)。此 織物亦包含第1 ·帛2疊層物各佔整體重量2·5%。 12 1269820 再者，於聚酯100%之紡粘型不織布，製造僅混合第 1疊層物為4倍發泡之粘合劑之混合物，將此混合物網版 印刷成點狀之印花織物（比較例1)。此織物含有第1疊 層物佔整體重量之3%。 (6)抗霉性試驗 於（5)所製造之實施例2、實施例3及比較例1，依 J IS Z2911纖維試驗之試驗·濕式法，進行抗霉試驗。 試驗菌株採用 Aspergillis niger ATCC 6275， Penicillium citrinum ATCC 98489, Chaetoraium globosum ATCC 6205，Myrothecium verrucaria ATCC 9095 ，之 4 菌株之混合胞子懸濁液，以28°C± 2。(：培養14曰。 其結果’於比較例1經過14日後長霉，但是，於實 施例2及實施例3經過14日後認不出長霉之現象。 鋁及合成樹脂薄膜本體及粘合劑並無抗菌性•抗霉 性為一般科學常識，但是含抗菌性·抗霉性之銀之疊層物 量減少，則抗菌性•抗霉性會減低至為明顯。雖然如此， 於實施例2及實施例3,抗菌性•抗霉性卻明顯提高。此 係銀之抗菌性•抗霉性，加上構成疊層物之2種金屬間之 電位差所致’即所明電池之作用，流經電流之關係。 再者，本發明不受上述實施方式或實施例之限制，在 申請專利範圍之技術範圍内可有各種變更。 首先，於上述實施方式，未特別提及織物A&B之用 途’事實上在：内衣、貼身衣、襪子、各種襯衫、肚圍、 睡衣等衣類，床單、被單、毛毯、枕頭套等寢具，袜布、 13 1269820 天花板材、地板材等 毛巾等日用品，地毯、窗簾、壁紙 住宅器材等均可使用。 布，其他亦可為：平針織、斜㈣私分衬双不及不織 所製造之蜞物\ /、、，，八物、緞子織、紗羅織等 斤二之織物’或由、_機、拉舍爾編機、米蘭尼斯經編 ^、、福機、圓形針織機等所製造之編織物，進而由 梅雅(Carl Mayer)法等所製造之編織物亦可。 4再者，疊層紗除可單獨使用之外，亦可作為择紗材 料，或以疊層紗為芯而外皮紗為天妙 + 1欠、/々大然纖維或合成纖維之包 心，A core yarn)。又’疊層物如上述實施例由粘合劑貼 於織物之外，亦可在合成樹脂薄膜5a或5b外邊設較此人 成樹脂薄膜融點低之合成樹脂粘合層，再以熱烫壓溶解二 枯合層而貼合。又，構成金屬層之金屬種類亦可使用不同 之3種類以上之疊層紗或疊層物作為織物或纖維製品之 構成要素。 產JI上之利用可能十斗 士本發明有關之織物及纖維製品，係具備多數種由合成 树脂薄膜夾住金屬層所成之疊層紗及疊層物為構成構 件。而構成此等疊層紗及疊層物之金屬層，係由能產生電 位差之不同種類之金屬所成。 因此’含有不同種類金屬之疊層紗或疊層物間產生電 位差’即發生電池作用流經微弱電流，而有防蟲·抗菌· 抗霉·發生負離子及由電氣分解產生有害物質之分解· 無害化作用等。 _ 14 1269820 又，金屬層受合成樹脂薄膜之保護，及露出面受摩 擦，將疊層紗及疊層物為構成構件之織物及纖維製品經一 再洗濯或使用漂白劑，其防蟲、抗菌、抗霉效果或負離子 之發生也不減低，或金屬層免於黑化，而以疊層紗、疊層 物及以此等為構成構件之織物之纖維製品外觀不致受損。 15 1269820 【圖式簡單說明】 苐1圖 第2圖 第3圖 第4圖 =月：關之織物之部分放大圖 紗構成層紗之構成圖，(a)為第1之叠層 :!2，)為第2疊層紗之構成圖 I 關之其他織物之部分放大圖 :第=示織物之構成構件之疊層物之構成 物之構成圖1之$層物構成圖，⑻為第Η層 【符號說明】 A、Β 織物 2 第2疊層紗 5、6 豐層物 5b、6b金屬層 第1疊層紗 纖維 合成樹 月曰薄骐1269820 坎, invention description: [Technical field to which the invention belongs], the present invention relates to a fabric and a fiber product, which is safe, and has a long-lasting anti-touch, antibacterial, anti-mildew effect, and can decompose and purify harmful substances. 2 fabrics that can generate negative ions and fiber products made of fiber products. [Prior Art] Since the past, 'has insect, antibacterial, anti-mildew effect, ==! users have, for example, specific active ingredients in The production of a fiber product of the raw material fiber, or the attachment of such an active ingredient to the mouth of the dyeing process, has been developed and utilized as a laminated yarn or laminate formed by sandwiching an antibacterial metal = layered structure between synthetic resin films. Fiber products (for example, 曰本特开2 0 01 — 49541 赛直: 丨丨 丨丨 八 & 八 号 翻 , , 国际 国际 , , 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 It is also possible to use a material that can produce a potential difference, such as the 夕 金属 metal, which is sandwiched between a synthetic resin thin film and a fiber-reinforced product of a farmer's layer or a layered material. (For example, Japanese Patent Laid-Open Publication No. 2003-328237) ^ is 'It is said that negative ions have the effect of making people comfortable, but there are smashed micro-powders that can be used to produce negative ions or pulverized micro-powders of calcium carbide. ·Incorporated and coated fiber products' also have been developed and used to restore soil. J user 〇 (for example, Japanese Patent Laid-Open Publication No. 2000-73254). However, these fiber products have the following problems. Using a fiber product of a laminated yarn or a laminate, against bacteria, viruses, and 1269820: - Although some molds are effective, they cannot expect to completely control their proliferation mouths, fleas, insects, etc., and the proliferation control of large-scale fungi and plankton cannot be controlled by lively strong black mold, red mold, red mold, etc. In addition, in the production of potential differences, most of the metal "laminate yarns or laminates, need to vaporize most of the metal and have high manufacturing costs. Mountain, and then use wood products or tourmalin fiber products, wood j Stone The cause of the problem is easy to fall off due to external stimuli such as washing, and there is a problem that it is impossible to maintain its performance. + Moreover, the fiber products with anti-insect, antibacterial, anti-mildew effect and S-negative ion ability have not been developed yet. The purpose is to solve the above problems, to provide a kind of fabric and fiber, ', product' with anti-insect, antibacterial and anti-mildew effects, and at the same time can generate negative ions, and to eliminate the stimulation of harmful substances or vibrations, etc. The first fabric according to the present invention has a first-layer woven fabric, which is a synthetic resin, which does not impair the user's touch, aesthetics, functional reality, and the like. The metal 35 is vapor-deposited on one side of the film, and the metal layer between the synthetic resin films of the vapor-mineral and the metal layers is bonded to the inner surface to form a sandwich structure, and the sandwich structure is cut into a yarn shape. 1 and the second laminated yarn is a metal having a potential difference from a metal layer constituting the second laminated yarn, and is vapor-deposited on one surface of the synthetic resin film, and the both sides of the metal layer are vapor-deposited. The metal film between the resin films is bonded to each other inwardly to form a 1269820 sandwich structure, and the sandwich structure is formed into a yarn shape, and these are used as a part of the original yarn. Further, the second fabric according to the present invention, The third woven fabric and the second woven fabric are arranged to intersect with each other. The third woven fabric according to the present invention has an i-th laminate, which is a surface-vapor-bonded metal layer of a synthetic resin film. The two layers of the synthetic resin film of the same metal layer are bonded to each other to form an in-line surface, and the sandwich structure is formed by pulverizing the sandwich structure; and the second layer layer is formed and structured. The metal layer of the i-th laminated yarn has a potential difference metal, vapor deposition = one side of the synthetic resin film, and the metal layer between the synthetic resin films on which the metal layer is vapor-deposited is inwardly merged with each other to form a sandwich structure. Then, the sandwich structure is pulverized, and these are attached to the fabric. Further, in the fiber product according to the present invention, the above fabric is used as a part of the material. In this way, the fabric and the fiber product according to the present invention are caused by a potential difference between the laminated yarns or laminates containing different kinds of metals, that is, the function of a so-called battery, and the weak current is generated to generate insect proof, antibacterial, and anti-mildew. Negative ions occur. In addition, since the metal layer is protected by the synthetic resin film, and the exposed surface is subjected to a rubbing cost of $, the fabric and the fiber clothing mouth are laminated with the laminated yarn and the laminate as a constituent element, or a bleaching agent is used, and the insect pest is not reduced. • Sterilization and anti-mildew effect • Negative ion generation effect, and the appearance of the woven fabric, the laminate, and the woven fabric and the fiber product which are constituent elements are not deteriorated due to the blackening of the metal layer. 1269820 [Embodiment] Hereinafter, embodiments of the present invention will be described with reference to the drawings. Figure 1 is a partially enlarged view of a first dyed fabric (fabric A) of one of the fabrics of the present invention. As shown in the figure, the fabric A is a first-layer laminated yarn, a first-stacked yarn, and a yarn 3, according to the first laminated yarn i/yarn 3/second stack yarn 2/yarn 3/first laminated yarn. 1/Yarn 3/2nd laminated yarn 2... The plain weave fabric in a certain order. Further, the interval between the i-th laminated yarn i and the second laminated yarn 2 is about 丄 to ga, but the relationship between the desired effect and the cost is preferably about 2 to 15 mm. ... Figure 2 shows the first laminated yarn! Or an enlarged view of the second laminated yarn 2, which is produced by the following steps. In the following, in the case of the laminated yarn 1, the manufacturing process of the second laminated yarn 2 is the same as the manufacturing process of the second layered yarn 2 except for the metal layer described later. The process is omitted except for the different parts of the province. First, in the synthetic resin film la, the metal is steamed into a metal layer lb by a vacuum evaporation method or an ion-vapor method. Then, the metal layer of the synthetic resin film la of the metal layer 1b is bonded to the inner surface by an adhesive to form a sandwich structure in which the metal layer 1b is sandwiched by the synthetic film la. Finally, the laminated structure 1 is completed by cutting the sandwich structure in the longitudinal direction. Furthermore, the width of the laminated yarn, in consideration of economy and feeling to the skin, is preferably about 100 to 500 #m, but considering the quality of the fabric, the ease of the cutting process, etc., 150 to 250 //m It is better. Here, the synthetic resin film la is a film made of polyester, polyamide, polyolefin or the like, and has a thickness of about 4 to 5 〇 ^ m, and about 6 to 12 g for the softness of the product 1269820. should. Iron, = metal constituting the metal layers 1b and 2b, can be considered gold, gold, gold, etc., as long as the metal layer 1b and the second laminated yarn can produce a potential difference between =2b' Various metals can be used. To the combination with the metal layer 2b, there are, for example, tin, stellite, yang and silver, iron and copper, aluminum and gold, and the like. As the polyacrylic acid-drying agent, a polyurethane dry-cleaning agent, a polyester-based dry-cleaning agent, a mixture, or the like can be considered. However, in consideration of the safety of the fabric, a low-complexity poly-I system is preferred. Further, the laminated yarn 2 is a fabric which is used for one of the surface of the synthetic resin film and the other side is coated with a synthetic resin. For the purpose of the present invention, the legal non-woven fabric (the fabric is about the second surface of the non-woven fabric made of the fiber 4) is mixed with the dry agent net and printed on the dot. In addition, the points on the map printed on the map Only the two of the ST laminate 5 and the laminate 6 of the laminate 5 or the laminate 6 may be used. Further, the shape of the mesh 4 is 'in addition to the dot shape, the line is printed on the entire surface.忒 不 不 不 不 又 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维 纤维, or mixed with the above-mentioned tree sex and other functions. Stomach σ out to improve antibacterial, anti-mold 1269820 Figure 4 is the type of laminate 5 and laminate 6 structure, as shown in the stack 5 and stack The layered material 6 is composed of a synthetic resin film "and 6&, and the metal layers 5b and 6b are sandwiched to form a sandwich structure. Thus, the layered material 5 and the laminate 6 are laminated as a crepe to produce a sandwich structure. The object is cut and pulverized in both directions in the longitudinal and transverse directions. Further, the cutting size of the laminate 5 and the laminate 6 is - the edge is ^. Further, the types of materials and thicknesses of the synthetic resin films 5& and 6& and the metal layers 5b and 6b may be the same as those of the laminated yarn i and the laminated yarn 2. The fabric A thus constituted And the fabric B, through the moisture content of the products and the living environment and the moisture of the sweat, the kitchen disregard, the bathhouse, the washing and the like, the water is given by the artificially mixed yarn and the laminated yarn 2, or the laminate 5 A potential difference is generated between the laminate 6 and the weak current of the potential difference to produce the above-mentioned function and effect. Further, since the metal layers lb, 2b, 叻, 叻, the side surface is outside, it is inevitable to oxidize and chlorinate, but Adjacent fibers rub against each other, and the oxidized portion is apt to fall off, and is not easily seen even if it is not detached. Further, the metal layers lb, 2b, 5b, and 6b are not bonded to the side of the metal resin la, 2a, 5a or 6a is protected, so it is not oxidized and vaporized. Because of the repeated washing or use of bleach, the anti-g effect, the anti-mildew effect and the negative ion-generating effect are not reduced. Thereafter, the fabric of the present invention is produced, and various tests are carried out. Description (1) The system of laminated yarn A 50 nm metal layer was deposited by a vacuum evaporation method 10 1269820 in a film of thickness 12 " mm, and a polyester film of the same metal layer was deposited by a polyester binder. The metal layer was bonded to the inner surface to form a sandwich structure. Finally, the sandwich structure was cut to have a width of 150/m in the longitudinal direction to produce a first laminated yarn. The second stack was produced by vapor-depositing instead of aluminum. (2) The manufacture of the fabric is made by using 40 yarns at an equal interval of 1 inch and 1 inch as the warp of the automatic loom. Then the third layer of yarn, 4 () cotton The yarn and the second laminated yarn are 50 in total between i inches, and the distance between the ith laminated yarn and the second laminated yarn is 4 mm, and the first laminated yarn, the 4 twisted yarn, and the second laminated yarn are used. The order of 40 cotton yarns, first laminated yarns, ... was used as a weft yarn to produce a plain weave (Example 1). Further, the laminated yarn at this time was formed by using a polyester fiber, a yarn of 隹20 denier, and a reverse twist of 2 0 //m. (3) Resistance test Further, in Example 1, the sample was washed 10 times according to JIS L027103, (the JAFET standard detergent was used as the laundry agent), and the antibacterial property test was carried out by a shake flask method. However, the test strains use Klebsiella. The result is an effective reduction rate of 84.6%, indicating excellent antimicrobial properties. In addition, the shellfish was also subjected to an antibacterial test according to JIS L 0 2 710 No. 3 (JACKER standard laundry detergent), and then subjected to an antibacterial test according to the jis [1902 quantitative test (uniform test method). As a result, the activity of the bacteria was 0.02, and it was confirmed that the bacteria had an excellent antibacterial and deodorizing function. The test strain used Staphylococcus aureus ATCC 6538P. However, it is a well-known fact that the metal layer is a layered yarn of Ming, or a single layer of tin with a metal layer of 1269820. The fabrics produced by the usual methods do not have such a function, and therefore such functions are considered to be due to the laminated yarns produced in (1). Further, the composite film, the turtle, the tin, and the like which constitute the wavy yarn are not resistant to g, but the antibacterial property is obtained by using the two kinds of woven yarns. Therefore, the above-mentioned antibacterial action is considered to be caused by the presence of moisture in the antibacterial test to make a conductive state between the laminated yarns, so that the potential difference between the metals is contained, that is, the battery acts as a battery, and the weak current flows. (4) The manufacture of the laminate, except that the metal layer is silver, the slab-like structure produced by the method of (1) is pulverized into 〇·15 0.1 0.15 丽, and the first layer containing silver and the second layer containing aluminum are produced. Laminate. (5) The printed fabric is made of 100% spun-type non-woven fabric of polyacetate, and the total weight of the non-woven fabric, the deadener, and the laminate is 4 times that of the first laminate and the second laminate. The mixture was mixed to prepare a mixture, and the mixture was printed by dot printing to produce a printed fabric (Example 2). This fabric contained 2nd and 2nd laminates each accounting for 25% by weight of the entire fabric. 》In the smear-bonded non-woven fabric of the polyacetate, the ith composition of the second layer of the laminate and the binder is produced, and the second mixture of the second laminate and the binder is prepared, Printed by screen printing, the dots formed by the i-th mixture, and the printed fabric in which the points of the second mixture are intersected with each other (Example 3). The fabric also comprises a 1·2 stack of 2% by weight of the total weight. 12 1269820 Moreover, in a 100% spunbonded nonwoven fabric of polyester, a mixture of only 4 times of foamed binder of the first laminate was prepared, and the mixture was screen printed into a dot-shaped printed fabric (Comparative) example 1). This fabric contains 3% of the total weight of the first laminate. (6) Anti-fungal test The anti-mildew test was carried out in accordance with the test of the JIS Z2911 fiber test and the wet method in Example 2, Example 3 and Comparative Example 1 produced in (5). The test strain was a mixed cell suspension of Aspergillis niger ATCC 6275, Penicillium citrinum ATCC 98489, Chaetoraium globosum ATCC 6205, Myrothecium verrucaria ATCC 9095, 4 strains at 28 °C ± 2. (: 14 cultivating. The result was "long-term mildew after 14 days in Comparative Example 1, but the phenomenon of mildew was not recognized after 14 days in Example 2 and Example 3. Aluminum and synthetic resin film body and adhesive There is no antibacterial property and anti-fungal property is common scientific knowledge, but the amount of antibacterial and anti-fungal silver laminate is reduced, and the antibacterial property and anti-fungal property are reduced to be obvious. However, in Example 2 and In Example 3, the antibacterial property and the antifungal property were remarkably improved. This is the antibacterial property and the antifungal property of silver, and the potential difference between the two metals constituting the laminate is the function of the battery, flowing through Further, the present invention is not limited to the above-described embodiments or examples, and various modifications are possible within the technical scope of the patent application. First, in the above embodiments, the use of the fabric A & B is not particularly mentioned. 'In fact: underwear, underwear, socks, all kinds of shirts, belly, pajamas and other clothing, bed sheets, sheets, blankets, pillowcases and other bedding, socks, 13 1269820 ceiling materials, floor boards and other daily necessities, carpets ,curtain , wallpaper, residential equipment, etc. can be used. Cloth, other can also be: jersey, oblique (four) private lining double can not be made of non-woven fabrics / /,,,, eight things, satin weaving, gauze weaving a fabric made of woven fabrics made of, for example, _machine, raschel machine, Milanese warp knitting machine, machine, circular knitting machine, etc., and then manufactured by the Carl Mayer method. The fabric can also be used. 4 In addition, the laminated yarn can be used alone or as a yarn selection material, or the laminated yarn can be used as the core and the outer skin yarn can be used as a subtle yarn, 1 owe, / 々 然 fiber or synthetic fiber. A core yarn). Further, the laminate may be attached to the fabric by an adhesive as in the above embodiment, or a synthetic resin adhesive layer having a lower melting point than the artificial resin film may be disposed outside the synthetic resin film 5a or 5b, and then blanched. Press and dissolve the two dry layers to fit. Further, as the metal type constituting the metal layer, a laminated yarn or a laminate of three or more different types may be used as a constituent element of the woven fabric or the fiber product. The woven fabric and the fiber product according to the present invention have a plurality of laminated yarns and laminates in which a metal layer is sandwiched by a synthetic resin film as a constituent member. The metal layers constituting the laminated yarns and the laminates are made of different kinds of metals capable of generating a potential difference. Therefore, 'the potential difference generated between the laminated yarns or laminates containing different kinds of metals' means that the battery acts through a weak current, and there are insects, antibacterial, anti-mildew, negative ions, and decomposition of harmful substances by electrical decomposition. Chemical effects, etc. _ 14 1269820 Moreover, the metal layer is protected by the synthetic resin film, and the exposed surface is rubbed, and the woven fabric and the fibrous product which are the constituent members of the laminated yarn and the laminate are repeatedly washed or bleached, and the insectproof, antibacterial, and The anti-mold effect or the occurrence of negative ions is not reduced, or the metal layer is free from blackening, and the appearance of the fibrous product of the laminated yarn, the laminate, and the fabric constituting the member is not impaired. 15 1269820 [Simple description of the drawing] 苐1Fig. 2, Fig. 3, Fig. 4 = month: Part of the enlarged fabric of the closed fabric constitutes the composition of the layer yarn, (a) is the stack of the first: !2 ,) is a partial enlarged view of the other fabrics of the second laminated yarn shown in Fig. I: The composition of the laminate of the constituent members of the fabric shown in Fig. 1 is the composition of the layer of Fig. 1, and (8) is the third Layer [Description of Symbols] A, 织物 Fabric 2 Second tiered yarn 5, 6 Thickened material 5b, 6b Metal layer First laminated yarn Fiber composite tree
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