TWI267395B - Multifunctional active plant flame retarding fire extinguishing agents - Google Patents

Multifunctional active plant flame retarding fire extinguishing agents Download PDF

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TWI267395B
TWI267395B TW93138867A TW93138867A TWI267395B TW I267395 B TWI267395 B TW I267395B TW 93138867 A TW93138867 A TW 93138867A TW 93138867 A TW93138867 A TW 93138867A TW I267395 B TWI267395 B TW I267395B
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fire extinguishing
extinguishing agent
grass
flame retardant
plant
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TW93138867A
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TW200618838A (en
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Bang-Dung Liou
Yu-Jian Chiou
Jin-Shing Tsai
Shu-Huei Wen
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Bang-Dung Liou
Yu-Jian Chiou
Jin-Shing Tsai
Shu-Huei Wen
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Abstract

This invention concerns a multifunctional active plant flame retarding fire extinguishing agents, which is especially useful in extinguishing fire caused by water soluble inflammable substance (such as alcohol, ether, ketone, and ester), A type substance (such as wood, cotton, and paper), B type substance (such as crude oil, petroleum, and cooking oil), and inflammable organic solvent. The flame retarding fire extinguishing agent of the present invention enables to produce an omentum which is formed with the solid substance to emulsify and change the state of inflammable liquid for rapid flame retarding and fire extinguishing purpose. The product is non-toxic, tasteless, and non-pollutant, which is an environmental friendly ideal fire extinguishing product.

Description

1267395 九、發明說明: 【毛明所屬之技術領域】 本發明「多功能植物活性阻燃滅火劑」,尤指一種 以植物為原料的活性阻燃滅火劑,其利用阻燃滅火液中 可產生出固態物質所形成的網膜,配合對易燃液體的 乳化親和改性作用,即可達到迅速阻燃滅火之作用者。 【先前技術】 當乙醇或乙醚等水溶性易燃液體發生火災後,以往 之滅火方法,例如以蛋白泡沫滅火劑滅火時,由於空氣 泡珠遇到水溶性易燃液體容易被水溶性液體所吸收,導 致空氣泡沫破滅,以致於不能滅火,這是衆所周知的。 後來,爲了解決撲滅水溶性易燃液體之火災,採用 在蛋白泡沫液中加入有機酸形成鹽類,使泡沫的抗溶能 力得到提高,起到滅火的作用。 隨著科技發展到七零年代,一位叫奇薩的美國人, 成功的在水成膜泡泳滅火劑的基礎上添加了高分子化 合物。製成了既能滅極性溶液(如··醇,醚等)又能滅 油火的滅火劑,國際上通稱AFFF〜AR。由於高分子化合 物的存在’在液體表面上能形成一層柔細的高分子膜’ 該膜遇到水溶性易燃液體則可脫水形成凝膠停留在燃 料表面上,產生防止其上面泡沫破壞的作用,進而達到 有效滅火的目的。 對於現有滅火劑之技術來說,仍有下述不足之處: 一是由於水溶性易燃液體蒸汽壓較大而蒸汽穿透力強 1267395 ’滅火時必須採用較大的泡沫供給強度,否則不能滅火 。二是在較大供給強度下雖然具備了抗溶、鎮火的能力 ’針對較大火災,由於泡沫與水溶性易燃液體在滅火過 程中發生的必然衝擊,泡沫中自然要夾帶水溶性液體, 導致泡沫破壞率增大,致使滅火效果大大降低,甚至不 能滅火。基於上述情況,不得不設置泡沫緩衝設備來滿 足滅火的需要,很顯然的,增加花費是小事,更重要的 是受到局限性所限制,最後往往仍會使滅火失敗。三是 抗熱性能低,例如:油品燃燒後放出大量的輻射熱。對 於輕質油品來說,由於其揮發性大,吸收熱氣化量多, 油品溫度較低,而重質油品,由於其揮發性小,吸收熱 氣化量少,故油品加熱快、溫度高。又如:煤油、原油 其燃燒時的油品溫度可高達30(rc以上,以現有滅火技 術來說,其泡沫含水率一般都大於9〇%,當含水泡沫與 其接觸後,會立即被加熱氣化,極難滅火。目此只有將 油…皿度降至攝氏i47°c以下時才有可能推進泡珠滅火 。,對成膜滅火劑的成難來說,當在油品溫度小於8〇 夸所産生的水膜依賴它的堅韌性,能起到不同程度 的滅火作用。當然溫度大於2〇〇。。時,水膜自然因受埶 破壞,消失,同時失去它的滅火作用,特別是大型火^ °四是因爲含有氣表面活性劑對大氣臭氧層的破壞。嚴 重危害和影響到人類的生態環境,而且當前國内外-部 分企業將被減産、停産,最後被淘汰。 /明人有鑑於此,遂特以研創成本案,期能藉本案 提出俾改進現有缺點,期使滅火劑之效能得以漆致 1267395 完善、理想與實用。 【發明内容】 本發明「多功能植物活性阻燃滅火劑」,其主要目 的在於··提供一種由植物為原料所製成的滅火劑,其利 用阻燃滅火液中,可產生出固態物質所形成的網膜,'配 合對易燃液體的乳化親和改性作用,俾達到迅速阻燃滅 火之作用。 / 本案另一目的在於··該種「多功能植物活性阻燃滅 火劑」,可廣泛的應用在撲滅··水溶性易燃物質(例如 •醇、醚、酮、酯等)造成的火災、A類物質(例如·· 木、棉、紙等)和B類物質(例如:原油、汽油、烹調 油專)以及易燃性有機溶劑所引起的各式火災。 本案再一目的為:設計一種新式滅火劑,該産品無 毒、無味且無公害,以達到符合環保之目的。 【實施方式】 茲謹就本發明「多功能植物活性阻燃滅火劑」之結 構組成,及其所產生之功效,配合圖式,舉一本案之較 佳實施例詳細說明如下: 本案「多功能植物活性阻燃滅火劑」,包括有下述 製作流程與方法: 如圖一,取材自雜草木灰(10),經適當挑選(12) 後’予以粉碎(14),形成純草木灰(丨5),按比例投入 (1 6);另配合水(11),按比例投入(i 3),按浸取工藝制 1267395 備(1 7),經由過濾(18),除渣(1 9 ),取得草木灰水(1)。 該草木灰水(1)具體的製造工藝可以是: 配方一: 1 ·配比:雜草木灰5% 、水95% 。 2·製備工藝:將選好的雜草木灰用粉碎機粉碎後稱 畺至次取容器中,加入定量的水(自來水 )’攪拌3 0分鐘,經靜止5〜7小時後再攪 拌3 0分鐘’再靜止2 5〜3 0小時後濾出固 • 體物,集其清液待用。 如圖二,將草木灰水(丨),按比例投入(22),配合 植物曬乾(20),經切碎(21 ),按比例投入(23);混合後 經18°C〜30°C浸取1〇〜12小時(24),再經8(rc〜85t保 持2小時(25),經93t;〜97t保持2小時(26),隨後降 溫至40°C以下過濾(27),料渣回收(28),曬乾(29), 氧化處理(30),得出雜草木灰(3),另得出植物草木灰 水⑷。 修 植物草木灰水(4)可以由下述配方達成: 配方二、植物草木灰水的製備工藝A: 1. 配比:草木灰水80% 、青蒿5% 、粘榆樹皮糗、 豬牙皂角果皮6%、側柏樹皮⑽及紅松樹皮2%。 2. 製備工藝: (a).將選好的植物,用切碎機切成2〜IGnrn大小 的塊。 ⑻·將定量的草木灰水置入浸取容器中。 (c)·將(a)加人⑻中,在18~3〇t條件下浸泡 1267395 10〜12小時,放出植物草木灰液體備用。 (d) ·將(c)中留下的固體物置入反應鍋(加熱 式)中,升溫至80〜85°C軟化處理1〜2小時。 (e) ·將(c)中液體加入(d)中,再升溫至80〜85 c提取60分鐘,繼續升溫至95 土 2°C提取 120分鐘,然後降溫至<4〇t:濾除固體物集 其清液備用。1267395 IX. Description of the invention: [Technical field to which Maoming belongs] The "multifunctional plant active flame retardant fire extinguishing agent" of the present invention, especially a plant-based active flame retardant fire extinguishing agent, which can be produced by using a fire retardant fire extinguishing liquid The net film formed by the solid material can be combined with the emulsified affinity modification of the flammable liquid to achieve the role of rapid flame retardant fire extinguishing. [Prior Art] When a water-soluble flammable liquid such as ethanol or ether is fired, the conventional fire-extinguishing method, such as a protein foam fire extinguishing agent, is easily absorbed by the water-soluble liquid when the air bubbles encounter a water-soluble flammable liquid. It is well known that the air bubbles are so broken that they cannot be extinguished. Later, in order to solve the fire that extinguished the water-soluble flammable liquid, the organic acid was added to the protein foam to form a salt, which improved the solvent resistance of the foam and played a role in extinguishing the fire. As technology developed into the 1970s, an American named Chisa successfully added a polymer compound to the water-filming foaming agent. It is made into a fire extinguishing agent which can extinguish the polar solution (such as alcohol, ether, etc.) and can extinguish the oil fire. It is commonly known as AFFF~AR in the world. Due to the presence of the polymer compound, a soft polymer film can be formed on the surface of the liquid. The film can be dehydrated to form a gel on the surface of the fuel, thereby preventing the foam from being destroyed. In order to achieve the purpose of effective fire fighting. For the existing fire extinguishing agent technology, the following deficiencies still exist: First, due to the high vapor pressure of the water-soluble flammable liquid and the high steam penetration force of 1267935 'When the fire is extinguished, a large foam supply intensity must be used, otherwise it cannot Extinguishing. Second, although it has the ability to resist dissolution and fire at a large supply intensity. For large fires, due to the inevitable impact of foam and water-soluble flammable liquids during the fire extinguishing process, the foam naturally contains entrained water-soluble liquids. The rate of foam damage increases, resulting in greatly reduced fire-extinguishing effects, even failing to extinguish the fire. Based on the above situation, foam buffer equipment has to be set to meet the fire-fighting needs. Obviously, increasing the cost is a trivial matter, and more importantly, it is limited by limitations, and in the end, the fire-fighting will often fail. Third, the heat resistance is low, for example, a large amount of radiant heat is released after the oil is burned. For light oils, because of its high volatility, the amount of heat absorbed by the gas is high, and the temperature of the oil is low. However, because of its low volatility and low absorption of heat, the oil is heated quickly. High temperature. Another example: kerosene, crude oil when burning, the oil temperature can be as high as 30 (rc or more, in the existing fire-fighting technology, the foam moisture content is generally greater than 9〇%, when the aqueous foam is in contact with it, it will be heated immediately It is extremely difficult to extinguish the fire. It is only possible to promote the foaming of the fire when the oil is lowered to below the temperature of i47 ° C. For the difficulty of forming a fire extinguishing agent, when the temperature of the oil is less than 8〇 The water film produced by the boast relies on its toughness and can exert different degrees of fire extinguishing. Of course, the temperature is greater than 2 〇〇. When the water film is naturally destroyed by the cockroach, it disappears and loses its fire extinguishing effect, especially The large fire ^ ° four is because of the destruction of the atmospheric ozone layer by the inclusion of gaseous surfactants. It seriously harms and affects the human ecological environment, and at present, some domestic and foreign enterprises will be reduced, stopped production, and finally eliminated. In view of this, 遂 special research and development cost case, the period can be proposed in this case to improve the existing shortcomings, so that the effectiveness of the fire extinguishing agent can be improved to 1,267,395. Perfect, ideal and practical. The main purpose of the active flame retardant fire extinguishing agent is to provide a fire extinguishing agent made of plants as raw materials, which can use the flame retardant fire extinguishing liquid to produce a net film formed by solid substances, 'cooperating against flammable materials Emulsifying affinity modification of liquid, 俾 achieves the role of rapid flame retardant fire extinguishing. / Another purpose of this case is · · This kind of "multifunctional plant active flame retardant fire extinguishing agent" can be widely used in extinguishing · · water soluble and flammable Fires caused by substances (eg alcohols, ethers, ketones, esters, etc.), Class A substances (eg wood, cotton, paper, etc.) and Class B substances (eg crude oil, gasoline, cooking oil) and flammability Various fires caused by organic solvents. Another purpose of this case is to design a new type of fire extinguishing agent, which is non-toxic, odorless and pollution-free, in order to achieve environmental protection. [Embodiment] The structural composition of the active flame-retardant fire extinguishing agent, and the effect it produces, together with the drawings, a preferred embodiment of the present invention is described in detail as follows: "Multifunctional plant active flame retardant fire extinguishing agent" The following production processes and methods are included: As shown in Figure 1, the material is obtained from weed ash (10), and after appropriate selection (12), it is pulverized (14) to form pure ash (丨5), which is proportionally invested (1 6 In addition, with water (11), proportionally input (i 3), according to the leaching process, 1267930 (1 7), through the filtration (18), the slag (1 9 ), the grass ash water (1) is obtained. The specific manufacturing process of grass ash water (1) can be: Formulation 1: 1 · Matching ratio: 5% of weed wood ash and 95% of water 2. Preparation process: The selected weed wood ash is crushed by a pulverizer and weighed to the secondary container. Adding a certain amount of water (tap water) 'stirring for 30 minutes, stirring for 5 to 7 hours, then stirring for 30 minutes' and then standing still for 5 to 30 hours, filtering out the solid matter and collecting the supernatant for use. . As shown in Figure 2, the grass gray water (丨), proportionally input (22), with the plants dried (20), chopped (21), proportionally input (23); after mixing, after 18 ° C ~ 30 ° C Dip 1 〇~12 hours (24), then 8 (rc~85t for 2 hours (25), after 93t; ~97t for 2 hours (26), then cool down to below 40 °C (27), Residue recovery (28), drying (29), oxidation treatment (30), weed wood ash (3), and plant grass ash water (4). Planting plant ash water (4) can be achieved by the following formula: Preparation process of plant grass and grey water A: 1. Proportion: 80% of grass gray water, 5% of Artemisia annua L., bark of sticky bark, 6% of bark saponin, arborvitae bark (10) and red pine bark 2%. Process: (a). Select the selected plants and cut them into 2~IGnrn-sized pieces with a chopper. (8)·Place the quantitative amount of plant ash water into the leaching container. (c)·Add (a) to (8) Under the condition of 18~3〇t, soak 1667739 for 10~12 hours, and release the plant ash liquid for use. (d) · Put the solid material left in (c) into the reaction pot (heating type) and heat up to 80~85 °C The treatment is carried out for 1 to 2 hours. (e) The liquid in (c) is added to (d), and the temperature is raised to 80 to 85 c. The extraction is continued for 60 minutes, and the temperature is further raised to 95 °C at 2 ° C for 120 minutes, and then the temperature is lowered to <; 4〇t: Filter out the solids and collect the supernatant for use.

配方三、植物草木灰水的製備工藝B : 1 ·配比:草木灰水80% 、白沙蒿5% 、麻榆樹皮5 % 、肉皂角5% 、刺柏樹皮3°/◦及紅松樹皮2% 。 2.製備工藝:按配方二中2製備工藝製備。 配方四、植物草木灰水的製備工藝C: 1·配比:草木灰水85%、茼蒿4%、雜榆樹皮4% 、 雜皂角果皮5% 、側柏樹皮1 %及油松樹皮丨% 。 2·製備工藝:按配方二中2製備工藝製備。 如圖三所示,按比例投入植物草木灰水(4),及, 按比例投入防腐劑(5),混合後於18°c〜3〇t保持一小 時(41),經過過濾(42),分別得到料渣(43)以及植物液 (6)。 植物液(6)可透過配方五製程:植物液的製備: 1·製備工藝:將定量的配方二至入攪拌容器中,在 18〜30°C條件下,加入定量配方三攪拌1〇分鐘, 加入疋里的配方四擾掉分鐘,加入定量的丙 1267395 二醇(Propylene glycol)攪拌30分鐘,最後加 入苯耕三氮嗤(BENZOTRIAZOLE)授拌60分鐘,過 濾除渣備用。 如圖四所示,按比例投入草木灰水(1 ),配合按比 例投入防凍劑(70),於38°C〜43°C條件下投入(71),經 70°C〜75°C保持一小時(72),經過過濾(73),分別得到 料渣(75)以及複合防凍劑(7)。 配方六、複合防凍劑(7)複合製備工藝 # 1·配比:草木灰水60 % 、硫酸亞鐵(ferrous sulfate)5% 、氯化鋰(LITHIUM CHL0RIDE)18% 及氯化 鎂(MAGNESIUM CHL0RIDE)17% 。 2·製備工藝:將定量的草木灰水至入反應鍋(加熱 式)中,升溫至38〜43°C,加入定量的硫酸亞鐵保溫攪 拌30分鐘,加入定量的氯化鋰保溫攪拌5分鐘,加入 定$的氣化鎮保溫攪拌2分鐘,升溫至7 0〜7 5 °C保溫擾 拌6 0分鐘,過濾、除潰貯存。 # 如圖五所示,將植物液(6)、表面活性劑surface active agents (81 )、複合防凍劑(7),按比例投入(82) ,於60°C〜65°C保持一小時(83),再於80°C〜85T:保持 二小時(84),降溫至38。(:以下(85),經過過濾(86), 可得到料渣(87),以及,多功能植物活性阻燃滅火劑(9) 〇 配方七、多功能植物活性阻燃滅火劑合成工藝 1.配比: (a)配方五50% ; 1267395 (b) 乙二醇(Ethylene glycol)6% ; (c) 聚氧乙烯失水山梨醇單油酸酯1 8% ; (d) 脂肪醇聚氧乙烯醚CmH2m + l〇 . (CH2CH2O)nH20°/〇 ; (e) CX〜90約 0· 05% ; (f) 正十二醇1.2% ; (g) 配方六5% ;Formulation 3, preparation process of plant grass and grey water B: 1 · Matching ratio: 80% of grass gray water, 5% of Artemisia scoparia, 5% of bark bark, 5% of meat saponin, 3°/◦ of juniper bark and 2% of red pine bark . 2. Preparation process: Prepared according to the preparation process of Formulation 2 and 2. Formulation 4, preparation process of plant grass wood gray water C: 1·Material ratio: 85% of grass gray water, 4% of Artemisia argyi, 4% of bark of bark, 5% of saponin, 1% of bark of arborvitae and 1% of bark of Chinese pine. 2. Preparation process: Prepared according to the preparation process of Formulation 2 and 2. As shown in Figure 3, the plant grass ash water (4) is put into proportion, and the preservative (5) is put into proportion. After mixing, it is kept at 18 °c~3〇t for one hour (41), after filtering (42), Separate residue (43) and vegetable liquid (6) were obtained, respectively. The vegetable liquid (6) can pass the formula five process: preparation of the vegetable liquid: 1. Preparation process: the quantitative formula 2 is put into the stirring container, and the quantitative formula is added at 18 to 30 ° C for 3 minutes. After adding the recipe of the crucible, the mixture was disturbed for a minute, and a certain amount of propane 126395 diol (Propylene glycol) was added and stirred for 30 minutes. Finally, Benzene triazole (BENZOTRIAZOLE) was added for 60 minutes, and the slag was filtered for use. As shown in Figure 4, the grass ash water (1) is put into proportion, and the antifreeze (70) is added in proportion, and is put in (71) at 38 ° C to 43 ° C, and maintained at 70 ° C to 75 ° C. After hour (72), through filtration (73), the residue (75) and the composite antifreeze (7) are obtained, respectively. Formulation 6, composite antifreeze (7) composite preparation process # 1 · ratio: 60% of plant gray water, ferrous sulfate 5%, lithium chloride (LITHIUM CHL0RIDE) 18% and magnesium chloride (MAGNESIUM CHL0RIDE) 17% . 2. Preparation process: the quantitative plant ash water is put into the reaction pot (heating type), the temperature is raised to 38~43 ° C, the quantitative ferrous sulfate is added and stirred for 30 minutes, and the quantitative lithium chloride is added and stirred for 5 minutes. Add a fixed amount of gasification town and stir for 2 minutes, heat up to 70 ~ 7 5 °C, stir and mix for 60 minutes, filter, remove and store. # As shown in Figure 5, plant liquid (6), surfactant surface active agents (81), composite antifreeze (7), proportionally (82), kept at 60 ° C ~ 65 ° C for one hour ( 83), then at 80 ° C ~ 85 T: keep two hours (84), cool down to 38. (: The following (85), after filtration (86), can obtain the residue (87), and the multifunctional plant active flame retardant fire extinguishing agent (9) 〇 formula VII, multifunctional plant active flame retardant fire extinguishing agent synthesis process 1. Proportion: (a) Formulation 5 50%; 1267395 (b) Ethylene glycol 6%; (c) Polyoxyethylene sorbitan monooleate 18.8%; (d) Fatty alcohol polyoxygen Vinyl ether CmH2m + l〇. (CH2CH2O)nH20°/〇; (e) CX~90 about 0. 05%; (f) n-dodecanol 1.2%; (g) Formula 5%;

(h)損耗水1.75% 。 2·製作合成工藝:將定量的(a)至入反應釜(加熱 式)中,在18〜25°C條件下加入定量的(b)攪拌15分鐘, 鐘,升溫至60〜65°C保溫攪拌60分鐘,加入定量的(f) 保溫攪拌10分鐘,加入定量的保溫攪拌1〇分鐘,加 入疋1的(h)後繼續升溫至8〇〜π°c保溫攪拌12〇分鐘, 降溫至<38t過濾放入貯存器,待穩定,檢測合格 裝出廠。 萑(h) Loss of water 1.75%. 2. Manufacture and synthesis process: add quantitative (a) to the reaction kettle (heating type), add quantitative amount at 18~25 °C (b) stir for 15 minutes, clock, heat up to 60~65 °C Stir for 60 minutes, add a fixed amount of (f) and keep stirring for 10 minutes. Add a constant amount of heat to stir for 1 minute. Add the (h) of 疋1 and continue to increase the temperature to 8 〇 to π °c for 12 minutes, and cool to <; 38t filter into the storage, to be stable, the test is qualified to install the factory. reed

加入疋里的(c)攪拌20分鐘。加入定量的(e)擾拌i〇分 、,示上所述,本案「多功能植物活性阻燃滅火劑」, 其具體改進f知缺失,相較於習知技術明顯具有突破性 之進步優點’而具有功效之增進,且非易於達成。本案 未冒公開或揭露於國内與國外之文獻與市場上,^(c) added to the crucible for 20 minutes. Adding a quantitative (e) scrambling component, as shown above, the "multifunctional plant-reactive flame retardant agent" in this case, the specific improvement is known to be missing, which is a breakthrough improvement advantage over the prior art. 'With the improvement of efficacy, and not easy to achieve. The case has not been disclosed or disclosed in domestic and foreign literature and market, ^

規f。是以’本案符合新穎性、實用性與進U 爰依法申請專利,懇請釣局詳查 准’以勵創新。 I千日賜 節,雖藉由實施例來描述’仍可變化其形態與細 -亦不脫離本發明之精神而達成,並由熟悉此項技 11 1267395 藝 士 』了解。如述本案之較佳實施例,僅係藉本案 原理可以目 v、 、體實施之方式之一,但並不以此為限制,庳 以依後R^ 之申請專利範圍所界定為準。 【圖式簡單說明】 |^| >— · 圖一 .·…為本發明中草木灰水的製作流程。 σ —.係為本發明中雜草木灰與植物草木灰 程。 j裂作流 圖三· 孫迭 一·恭為本發明中植物液的製作流程。Regulation f. Therefore, the case is in line with the novelty, practicality and U 爰 patent application, and the fishing bureau is required to check the details to encourage innovation. I. Thousands of Days, although described by way of example, can still change its form and detail - without departing from the spirit of the present invention, and are understood by those skilled in the art 11 1267395. As described in the preferred embodiment of the present invention, only one of the methods of the present invention can be implemented, but it is not limited thereto, and is determined by the scope of the patent application of R^. [Simple description of the drawing] |^| >- · Figure 1 . . . is the production process of the grass gray water in the present invention. σ — is the weed ash and plant ash ash in the invention. j split flow Figure III · Sun Die Yi·Gong is the production process of the plant liquid in the invention.

圖四:你炎I 圖五·/、為本I明中複合防凍劑的製作流程。 β 人為本I明多功能植物活性阻燃滅火 程。 Κ製作流 【圖號簡單說明】 1 ···草木灰水 1 〇…雜草木灰 1 1 ···水 12…挑選 籲 13…按比例投入 14…粉碎 15…純草木灰 16…按比例投入 17…按浸取工藝制備 18…過濾 19…除渣 12 1267395 2 0…植物曬乾 21…切碎 22···按比例投入 23…按比例投入 24··· 18〇C〜30〇C浸取10〜12小時 25··· 80〇C〜85〇C保持2小時 26··· 93〇C〜97〇C保持2小時 27···降溫至40〇C以下過濾 • 28···料渣回收 鲁 29…曬乾 3 ......雜草木灰 30···氧化處理 4 ......植物草木灰水 41…混合後於18°C〜30°C保持一小時 4 2…過渡 5…按比例投入防腐劑 I 6 · · ·..植物液 | 7 0….防涞劑 7…複合防涞劑 71…38°C〜43°C條件下投入 72…70°C〜75°C保持一小時 ” 7 3…過遽 75…料渣 81…表面活性劑 82…按比例投入 13 1267395 83··· 60〇C〜65〇C保持一小時 84··· 80〇C〜85〇C保持二小時 85···降溫至38〇C以下 8 6…過濾 8 7…料渣 9 ......多功能植物活性阻燃滅火劑Figure 4: Your inflammation I Figure V · /, this is the production process of composite antifreeze. β human-based I multi-functional plant active flame retardant fire extinguishing process. Κ Κ Κ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ Leaching process preparation 18... Filtration 19... Deslagging 12 1267395 2 0... Plant drying 21...Chopping 22···Proportional input 23...Proportional input 24··· 18〇C~30〇C leaching 10~ 12 hours 25··· 80〇C~85〇C for 2 hours 26··· 93〇C~97〇C for 2 hours 27··· Cooling to 40〇C or less • 28···Residue recovery 29...drying 3...weed wood ash 30···oxidation treatment 4...plant grass ash water 41...mixed and kept at 18°C~30°C for one hour 4 2...transition 5... Proportional input of preservative I 6 · · ·.. plant liquid | 7 0....Anti-mite agent 7...Composite anti-caries agent 71...38 °C ~ 43 °C, put 72...70 °C~75 °C to keep One hour" 7 3... Over 遽 75... slag 81... Surfactant 82... Proportional input 13 1267395 83··· 60〇C~65〇C for one hour 84··· 80〇C~85〇C Two hours 85···cooling to 38〇C or less 8 6 Filter 87 ... 9 ...... versatile plant bagasse active flame extinguishant

Claims (1)

1267395 十、申請專利範圍: 1 · 一種多功能植物活性阻燃滅火劑,包括: 選自由蒿類、榆類、松類、柏類和皂角果皮組成的 組植物中的植物莖、枝、根、皮製備出草木灰水; 將前述草木灰水混合植物曬乾,製備後取得植物草 木灰水; 另將草木灰水與防凍劑製備取得複合防凍劑; 將前述植物草木灰水、複合防凍劑混合表面活性 劑’製備取得該多功能植物活性阻燃滅火劑。 2.如申請專利範圍第1項之多功能植物活性阻燃滅 火劑,其中所述的蒿類,包括:青蒿、白沙蒿、茼蒿; 所述的柄類,包括·枯榆,麻榆、粉榆、黃榆、灰榆; 所述的松類,包括:油松、青松、紅松;所述的柏類, 包括:黃柏、側柏、刺柏;所述的皂角果皮,包括:鴨 皂角、豬皂角、肉皂角。 3·如申請專利範圍第1項之多功能植物活性阻燃滅 火劑,其中所述的表面活性劑爲陰離子表面活性劑和非 離子表面活性劑。 4 ·如申請專利範圍第3項之多功能植物活性阻燃滅 火劑,其中所述的陰離子表面活性劑爲脂肪醇聚氧乙烯 醚硫酸脂鈉鹽’月桂醇聚氧乙烯喊硫酸納。 5·如申請專利範圍第3項之多功能植物活性阻燃滅 火劑,其中所述的非離子表面活性劑爲脂肪醇聚氧乙烯 醚,聚氧乙烯失水山梨醇單硬脂酸酯或聚氧乙稀失水山 梨醇單油酸酯。 15 1267395 6·如申請專利範圍第1項之多功能植物活性阻燃滅 火劑’其中所述的植物草木灰水浸取液是按下述方法得 到的:將所選用植物中的莖、枝及莖枝果根的皮,曬乾, 用切碎機切成2〜1 〇毫米大小塊;然後將其與草木灰水按 (1 0〜2 0 ) · ( 9 0〜8 0 )的比例混合,在常溫下浸泡} 〇 ~】2 小時’放出草木灰水浸泡液,留下固體物,升溫至8〇〜85 °C,在次條件下軟化處理丨〜2小時,在將上述放出的草 木灰水浸泡液注回原處與軟化後的固體物混合,再升溫 80〜85°C提取1〜2小時,升溫至9〇〜95t提取卜2小時,最 後降溫至40°C以下濾除固體物,集其清夜。 7·如申請專利範圍第1項之多功能植物活性阻燃滅 火劑,其中所述的草木灰水是按下列方法得到的:將選 用的草木灰,將其與水按5~1〇% : 95〜9〇%比例混合, 在18〜30°C條件下浸泡30〜35小時後,濾除固體物;集其 清液。 8·如申請專利範圍第6項之多功能植物活性阻燃滅 火劑,其中所述的草木灰水,是8〇%草木灰水,5%青 高莖、枝’ 4%枯榆樹皮,⑽豬牙皂角果皮,3%側柏 樹皮’ 2%紅松樹皮,所述為重量的百分比。 9·如申請專利範圍第6項之多功能植物活性阻燃滅 火劑,其中所述的草木灰水浸取液,是8〇%草木灰水, 5%白沙蒿莖、枝,5%麻榆樹皮,5%肉皂角果皮,3 %刺柏樹皮’ 2%紅松樹皮,所述為重量的百分比。 1 〇·如申請專利範圍第6項之多功能植物活性阻燃 16 1267395 ~ 滅火劑,其中所述的草木灰水,是85%草木灰水,4% 茼蒿莖、枝,4%雜榆樹皮,5%雜皂角果皮,1%側柏 树皮,1 %油松樹皮,所述為重量的百分比。 11·如申請專利範圍第6項之多功能植物活性阻燃 滅火劑,其中該表面活性劑,其用量爲草木灰水的3〜5%。 12·如申請專利範圍第丨項之多功能植物活性阻燃 滅火劑,其中所述的表面活性劑,爲聚氧乙烯失水山梨 • 醇單硬酯酸酯或聚氧乙烯醚失水山梨醇單油酸酯,或脂 肪醇聚氧乙烯鱗。 1 3·如申請專利範圍第丨項之多功能植物活性阻燃 滅火劑,其中還進一步含有至少一種穩定劑。 14·如申請專利範圍第13項之多功能植物活性阻燃 滅火劑,其中所述的穩定劑包括:黃單胞細菌多糖, SATIAXANE[CX〜90]合成生物聚合膠,KELTR〇L Βτ合成生 物聚合膠,正十二醇。 • I5.如申請專利範圍第1項之多功能植物活性阻姆· 滅火劑’其中還進-步含有至少—種防腐劑。 16. 如申請專利範圍第15項之多功能植物活性阻燃 滅火劑,其中所述的防腐劑包括:酸納、_三氮 吐、硫酸亞鐵。 17. 如申請專利範圍第1項之多功能植物活性㈣ 滅火劑,其中該防束劑包括:氯化鎂、氣化鋰、乙二醇、 丙二醇。 17 1267395 18.如申請專利範圍第1項之多功能植物活性阻燃 滅火劑,其中以100%植物草木灰水浸取液中含有:苯 甲酸鈉0.8〜1.5% ,苯駢三氮唑0.5〜1.2% ,正十二醇 0· 8〜1. 5%,2〜(2J氧基乙氧基)乙醇5〜10% ,丙二醇 , 15〜30% ,所述為重量的百分比。 1 9.如申請專利範圍第1項之多功能植物活性阻燃 滅火劑,還進一步含有··氣化鎂,氯化鋰,SATIAXANE CX〜90或KELTROL.BT 。 • ❿1267395 X. Patent application scope: 1 · A multifunctional plant-based flame retardant fire extinguishing agent, including: plant stems, branches and roots in a group of plants selected from the group consisting of artemisia, acarid, pine, cypress and saponin The skin is prepared with the grass gray water; the plant mixed with the grass and gray water is dried, and the plant grass gray water is obtained after preparation; the composite antifreeze is prepared by preparing the grass gray water and the antifreeze; and the plant grass gray water and the composite antifreezing agent are mixed with the surfactant. The versatile plant active flame retardant fire extinguishing agent is prepared. 2. The multifunctional plant active flame retardant fire extinguishing agent according to claim 1, wherein the artemisia, including: Artemisia annua, Artemisia scoparia, Artemisia scoparia; said stalk, including dried stalk, paralysis, White mites, scutellaria, ash; said pines, including: Pinus tabulaeformis, Pinus koraiensis, Pinus koraiensis; said cypresses, including: cork, arborvitae, juniper; said saponin peel, including: duck Saponin, pig saponin, meat saponin. 3. The multifunctional plant active flame retardant fire extinguishing agent according to claim 1, wherein the surfactant is an anionic surfactant and a nonionic surfactant. 4. The multifunctional plant-active flame retardant fire extinguishing agent according to claim 3, wherein the anionic surfactant is a fatty alcohol polyoxyethylene ether sulfate sodium salt, a lauryl alcohol polyoxyethylene sodium sulfate. 5. The multifunctional plant active flame retardant fire extinguishing agent according to item 3 of the patent application, wherein the nonionic surfactant is a fatty alcohol polyoxyethylene ether, polyoxyethylene sorbitan monostearate or poly Oxyethylene sorbitol monooleate. 15 1267395 6·Multifunctional plant-reactive flame-retardant fire extinguishing agent as claimed in claim 1 'The plant grass ash water leaching solution described therein is obtained by the following method: stems, branches and stems of the selected plants The skin of the roots of the branches, dried, cut into 2~1 mm-size blocks with a chopper; then mix it with the ratio of (1 0~2 0 ) · ( 9 0~8 0 ) Soak at room temperature} 〇~】2 hours' release the grass ash water soaking solution, leave a solid, warm to 8 〇~85 °C, soften under conditioned conditions for ~2 hours, in the above-mentioned planting ash water soaking solution The original part is mixed with the softened solid matter, and then heated at 80 to 85 ° C for 1 to 2 hours, heated to 9 〇 to 95 t for 2 hours, and finally cooled to 40 ° C or less to filter out solid matter. Clear night. 7. The multifunctional plant active flame retardant fire extinguishing agent according to item 1 of the patent application scope, wherein the grass gray water is obtained according to the following method: the grass ash to be used is selected according to the water and 5~1%%: 95~ Mixing at a ratio of 9〇%, soaking for 30 to 35 hours at 18 to 30 ° C, filtering off the solid matter; collecting the supernatant. 8. The multifunctional plant-active flame-retardant fire extinguishing agent according to item 6 of the patent application, wherein the grass gray water is 8〇% grass gray water, 5% green stem, branch '4% dry bark, (10) pig tooth Saponin peel, 3% arborvitae bark '2% red pine bark, said as a percentage of weight. 9. The multifunctional plant active flame retardant fire extinguishing agent according to item 6 of the patent application scope, wherein the grass ash water leaching liquid is 8 〇% grass wood gray water, 5% white wormwood stem, branch, 5% palsy bark, 5% meat saponin, 3% juniper bark '2% red pine bark, said as a percentage of weight. 1 〇·Multifunctional plant active flame retardant 16 1267395 ~ fire extinguishing agent as claimed in item 6 of the patent application scope, wherein the grass gray water is 85% grass gray water, 4% stalk, branch, 4% chowder bark, 5 % miscellaneous stalk peel, 1% arborvitae bark, 1% pine bark, said as a percentage of weight. 11. The multifunctional plant-active flame retardant fire extinguishing agent according to item 6 of the patent application scope, wherein the surfactant is used in an amount of 3 to 5% of the grass gray water. 12. The multifunctional plant active flame retardant fire extinguishing agent according to the scope of the patent application, wherein the surfactant is polyoxyethylene dehydrated sorbitol alcohol monostearate or polyoxyethylene ether sorbitol Monooleate, or fatty alcohol polyoxyethylene scales. 1 3. The multifunctional plant active flame retardant fire extinguishing agent according to the scope of the patent application, further comprising at least one stabilizer. 14. The multifunctional plant active flame retardant fire extinguishing agent according to claim 13, wherein the stabilizer comprises: xanthophyll polysaccharide, SATIAXANE [CX~90] synthetic biopolymer gel, KELTR〇L Βτ synthetic organism Polymeric gum, n-dodecyl alcohol. • I5. A multi-functional plant active damper fire extinguishing agent as claimed in item 1 of the patent application, which further contains at least one type of preservative. 16. The multifunctional plant-active flame retardant fire extinguishing agent according to claim 15, wherein the preservative comprises: sodium sulphate, striol, ferrous sulfate. 17. The multifunctional plant active (IV) fire extinguishing agent according to claim 1, wherein the anti-crushing agent comprises: magnesium chloride, lithium gasification, ethylene glycol, propylene glycol. 17 1267395 18. The multifunctional plant active flame retardant fire extinguishing agent according to claim 1, wherein 100% plant grass wood ash water extract comprises: sodium benzoate 0.8~1.5%, benzotriazole 0.5~1.2% , n-dodecan 0. 8~1. 5%, 2~(2J oxyethoxy)ethanol 5~10%, propylene glycol, 15~30%, as a percentage by weight. 1 9. The multifunctional plant-active flame retardant fire extinguishing agent according to item 1 of the patent application further contains magnesium carbide, lithium chloride, SATIAXANE CX~90 or KELTROL.BT. • ❿ 18 1267395 七、指定代表圖: (一) 本案指定代表圖為:第(五)圖。 (二) 本代表圖之元件符號簡單說明: 6….植物液 7…複合防凍劑 81…表面活性劑 82···按比例投入 83··· 6(TC〜65〇C保持一小時 84".80°C〜85°C保持二小時 85···降溫至38〇C以下 8 6…過濾 87…料渣 9 ......多功能植物活性阻燃滅火劑 φ 八、本案若有化學式時,請揭示最能顯示發明特徵的化學式:18 1267395 VII. Designated representative map: (1) The representative representative of the case is: (5). (2) A brief description of the symbol of the representative figure: 6....plant liquid 7...composite antifreeze 81...surfactant 82···proportional input 83··· 6 (TC~65〇C for one hour 84" .80 ° C ~ 85 ° C for two hours 85 · · · cooling to 38 〇 C below 8 6 ... filter 87 ... slag 9 ... multi-functional plant active flame retardant φ VIII, if this case In the chemical formula, please reveal the chemical formula that best shows the characteristics of the invention:
TW93138867A 2004-12-15 2004-12-15 Multifunctional active plant flame retarding fire extinguishing agents TWI267395B (en)

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CN107050730A (en) * 2017-06-21 2017-08-18 宁波水星环保科技有限公司 A kind of high-efficiency environment friendly plant composite fire-retardant extinguishing chemical
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