TWI252832B - Biodegradable food packaging material capable of resisting high temperature baking and method for making same - Google Patents

Biodegradable food packaging material capable of resisting high temperature baking and method for making same Download PDF

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TWI252832B
TWI252832B TW93100012A TW93100012A TWI252832B TW I252832 B TWI252832 B TW I252832B TW 93100012 A TW93100012 A TW 93100012A TW 93100012 A TW93100012 A TW 93100012A TW I252832 B TWI252832 B TW I252832B
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pulp
plant
fiber
compound
paper
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TW93100012A
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TW200523184A (en
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Chi-Yee Yeh
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Chi-Yee Yeh
Huang Shu Fen
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/90Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

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Abstract

A biodegradable food packaging material capable of resisting high temperature baking and method for making same, including: preparing auxiliary agents containing anionic compounds of aluminum silicate and natural wax emulsion; putting said mixture into a pulping machine to mix with natural fibers paper pulp and water to become a well mixed natural fibers pulp after pulverizing; and putting the well mixed natural fibers pulp into a mixing pulp tank of a pulp molding machine for storage; followed by mixing auxiliary agents containing nonionic compounds and cationic compounds with said pulp natural fibers to become a moldable pulp after pulping, wherein said cross-linking agent is made with fluorochemical service, high polymer compound, aliphatic polyamine and alkyl acryl copolymers and then stored in a pulp storage tank. The above pulps are mixed in the storage tank and then molded into containers by a paper pulp molding machine. The container is then subject to release coating and dehydration to obtain the final product of this invention.

Description

1252832 五、發明說明(1) 【發明所屬之技術領域】 本發明係關於一種環保性植物纖維食品包裝 別是關於-種可用於高溫烘烤及急陳保存 =继 維食品包裝材料之配方及其製程者。 呆丨生植物纖 【先前技術】 “綜觀一般習用的紙塑成型卫業包袈製品是以 韋衆、紙邊角料等為主要原料’經水力散浆&屬 上經真空吸附成型、直接固化成型後, =t屬核具 克力、乳膠、樹酯或塗劑(例如含EVA醋酸乙二 5 2 : 劑)來進行表面處理。而樹醋及—般之塗劑-日成二之塗 遇高溫時,表面易開始產生溶出現象,i溶 —w ’ 於食物中’被人體攝入’對人體健康將會有重 人類的威脅甚至超過保力龍餐具或塑膠餐具。“對 在其他的紙塑成型工業包裝製品技術^ 不γ法及材料予以製成宣稱具有環保或可分1252832 V. INSTRUCTION DESCRIPTION OF THE INVENTION (1) Technical Field of the Invention The present invention relates to an environmentally-friendly plant fiber food package, which is related to a high-temperature baking and rapid preservation method; Process person.丨 丨 植物 植物 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前After that, =t is a nucleus, latex, resin or paint (for example, containing EVA acetic acid Ethylene ethoxide 2 2 : agent) for surface treatment. And tree vinegar and the general paint - Nisshin 2 At high temperatures, the surface tends to start to appear dissolved, i dissolved - w 'in the food 'ingested by the human body' will have a heavy human threat to human health even more than Baoli dragon cutlery or plastic tableware. "On other paper Plastic molding industry packaging product technology ^ Not gamma method and materials are made to claim to be environmentally friendly or separable

盗,例如在先前技術中,中華民國 ^ I 具製造方法及添加劑配方,《步驟如$用植物纖維環保餐 料··分別以結桿類(如稻杆、麥杆、玉Ί集粗糠^ (如稻殼、麥殼、㈣…等)、廢渣類(玉米類 渣、旦腐渣、木屑…等)、澱粉類(玉米、’一 ,,、、 木著粉...等)等無毒性植物組織為主'\馬鈴薯粉、 粗糠原料送經洗務池,及以水柱靜厂。13、洗條:將 糠原料上的泥土等雜質。c、離:Λ粗糠原料,沖刷掉粗 負 離〜乾無:將上述洗蘇後的Pirates, for example, in the prior art, the Republic of China ^ I has manufacturing methods and additive formulas, "steps such as $ use of plant fiber environmentally friendly meal · · respectively with knots (such as rice straw, straw, jade collection rough 糠 ^ (such as rice husks, wheat husks, (four), etc.), waste slag (corn slag, dad slag, wood chips, etc.), starch (corn, 'one,,,, wood powder, etc.) and other non-toxic Sex plant organizations are mainly '\ potato powder, rough raw materials are sent to the washing pool, and the water column is quiet. 13. Washing strips: impurities such as dirt on the raw materials. c, away: rough raw materials, washed away Rough and negative ~ dry no: after the above washing

第6頁 1252832 五、發明說明(2) 粗糠原料經乾燥處理。d、粉碎:將上述 粉碎形成粉料。e、混料:將86%粉碎 二乾的粗糠予以 2%的添加劑及12%的水,均勻混合成。糠即粉料’與 包含90%的特殊食用膠、4· 5%的硫酸鹽、=添加劑配方 及1°/❶的被膜劑,該特殊食用膠是28%的 /° 1。硬貝酸, 2U的蛋白膠混合而成,其枯度控制在25二〇2:的該果膠、 ΐ是Γ%二Ϊ ”用膠、8%的氣化鈣與12%的明礬混?製膜 成。f、杈壓成型:將上述混料予以熱壓成型。烘 ^外線殺@ :脫模後,將成品送經第—道烘乾和紫^殺 滅,而該粗糠係可經脫色處理,使成品可喷塗花色圖案, 再經第二道供乾和紫外殺菌。h、品管與包裝:該成品經 過品管檢驗後,即可包裝上市。 又例如在先前技術中,中華民國專利公告編號第 2 = 30 08號專利中,揭露了一種生物可分解性物質之包裝容 器的製法,其步驟包括以液態或超臨界流體自動物結締組 織移除脂肪而製得一種結締組織蛋白質,作成一混合物, 包含2〜4 0%重量比之結締組織蛋白質,6〇〜90%重量比之澱 粉質穀物或植物物質,〇〜5 %重量比之食鹽,〇〜1 〇 %重量比 之糖,和任意地食物調色劑,其重量百分比為相對於總固 態含量,將此混合物於1 8 0至2 0 0度之溫度下1 0秒至2分鐘 及2.07MPa ( 300psi)至5.86 MPa ( 850psi)壓力下擠 壓’於擠壓過程中加入約1 〇%重量比之水以形成可塑形加 工物質,並將此擠壓物質以注模法塑成該物品。Page 6 1252832 V. INSTRUCTIONS (2) Rough raw materials are dried. d. pulverization: The above was pulverized to form a powder. e. Mixing: 86% crushed and dried 2% of the crude and 2% of the additive and 12% of water are uniformly mixed. That is, the powder 'and contains 90% of special edible gum, 4.5% of sulfate, = additive formula and 1 ° / 被 of the coating agent, the special edible gum is 28% / ° 1 . Hard shell acid, 2U protein glue mixed, its dryness is controlled at 25:2: the pectin, ΐ is Ϊ% Ϊ" with glue, 8% calcium carbonate and 12% alum mixed? Forming film into. f, rolling forming: the above mixture is hot pressed. Bake ^ outside line kill @: After demoulding, the finished product is sent to the first pass drying and purple ^ kill, and the rough system can be After decolorization treatment, the finished product can be sprayed with a floral pattern, and then subjected to a second supply for drying and ultraviolet sterilization. h, quality control and packaging: after the finished product is inspected by quality control, it can be packaged and marketed. For example, in the prior art, In the Patent No. 2 = 30 08 of the Republic of China Patent Publication No. 2 = 30 08, a method for preparing a packaging container for a biodegradable substance is disclosed, which comprises the steps of removing fat from a connective tissue of a liquid or supercritical fluid to produce a connective tissue. Protein, as a mixture, comprising 2 to 40% by weight of connective tissue protein, 6〇~90% by weight of starchy cereal or plant matter, 〇~5 % by weight of salt, 〇~1 〇% by weight Sugar, and optionally food toner, the weight percentage is relative to Solid content, the mixture is extruded at a temperature of 180 to 200 °C for 10 seconds to 2 minutes and 2.07 MPa (300 psi) to 5.86 MPa (850 psi). Add about 1 于 during the extrusion process. % by weight of water to form a moldable processing material, and the extruded material is injection molded into the article.

五、發明說明(3) 【發明内容】 本發明所欲解決之技術問題 裝材:二有許多有關於可分解或環保型之包 -土製作技術,但仍存了許多缺點。 製作過程解包裝材料或餐具產品的 物分解性物質,即可保所使用的原料是易於生 是會造成環境品質的問^、:襄:百:之百分解,當然 製作的植物纖維環伴餐爭^ ^1,—般以習用技術所 都會造成消費者:κη式繼續,,種種的缺失 裝材料或餐具產品的推廣❶且礙了娘保型或可分解包 因此,如果能針對上述植物纖 明出一種可承受較高烘烤溫度及备;東保# ^之缺失而發 料及其製· ’則對;產業界實iC: 另;;者而言,亦提供-高穩定性、高品質g感: 緣此,本發明之主要目的即是 性植物纖維食品包裝材料,二種可烘烤之環保 本發明製成食品容器所包裝之丄:j供;般消費者構買以 烤箱以攝氏200度的高溫供 / 使用微波爐或 容器烤之後並不變形或=心 本發明之另一目的是提供一種可供 /烤之%保性植物纖 五、發明說明(4) 維食品包裝材料 成食品容器所包 績保存食物,gj 之環境下保存, 之虞。 特別疋提供一般消費者購買以本發明製 ,之食物時,可以使用急速冷凍的方式繼 為該本發明製成食品容器在攝氏零下35度 而且該食品容器不會發生變形或表面破裂 本發明之另 目的是提供 維食品包農材料,^二&风饮一種可烘烤之環保性植物纖 器的表面烤處理之本發明製成之食品容 本發明之沾黏現象。 維食品包裝材料之製程疋本之環保性植物纖 比重及經過特定的製程、以及^^製釦中,以特有的配方 驟,以製作出適人用於古、w 特殊添加比例的助劑等步 纖維食品包裝同溫供烤及急滚保存之環保性植物 本發明解決問題之技術手段 本發明為解決習知技術之 環保型植物纖維食品包裝材 a碭所採用之技術手段係在 準的配方比重及在製程中< 添加獨有的製程技術,其精 術手段。 助劑的步驟等都是關鍵之技 在本發明之可耐高溫烘烤 材料之配方包括5 〇〜8 〇重量百八 物纖維食品包裝環保性 1. 5〜9重量百分比的天然蠟類^比的活性矽酸鋁化合物及 的植物纖維紙漿原料及99〇重^匕,結合與100重量百分比 植物纖維紙漿漿料。例如芒θ里百分比的水份混合成均勻 右疋以該植物纖維紙襞原料為之 1252832V. OBJECTS OF THE INVENTION (3) [Draft] The technical problem to be solved by the present invention is as follows: There are many kinds of materials for the decomposing or environment-friendly packaging, but there are still many disadvantages. In the production process, the decomposable substances of the packaging materials or tableware products can be used to ensure that the raw materials used are easy to produce and cause environmental quality. ^: 襄: Hundreds: 100% decomposition, of course, plant fiber ring accompaniment Competing ^ ^1, generally with the use of conventional technology will cause consumers: κη continues, the promotion of various missing materials or tableware products, and hinders the mother-protected or decomposable package, therefore, if the above-mentioned plant fiber can be targeted Explain that it can withstand higher baking temperatures and prepare; Dongbao # ^ is missing and the material and its system are 'right; industry real iC: another;; also, provide - high stability, high quality g Sense: Therefore, the main purpose of the present invention is the sexual plant fiber food packaging material, two kinds of bakeable environmental protection, the package of the food container of the invention is packaged: j; the average consumer buys the oven to 200 degrees Celsius High temperature supply / use of microwave oven or container after baking is not deformed or = heart Another object of the present invention is to provide a usable / roasted % of the plant fiber 5, invention description (4) dimension food packaging material into a food container Preserved food Save gj under the environment at risk. In particular, when a general consumer purchases a food made in accordance with the present invention, it can be rapidly frozen to continue the food container of the present invention at a temperature of minus 35 degrees Celsius and the food container does not undergo deformation or surface cracking. Another object is to provide a foodstuff material of the present invention, and a surface-baked treatment of a bakeable environmentally-friendly plant fiber. The process of the food packaging materials, the environmentally-friendly plant fiber specific gravity, and the specific process, and the ^^ buckle, with a special formula to produce suitable additives for the ancient, w special addition ratio, etc. The invention relates to a technical method for solving the problem in the invention. The technical means adopted by the prior art for solving the environmentally-friendly plant fiber food packaging material of the prior art is based on the standard formula. Specific gravity and in the process < Add unique process technology, its fine technique. The process of the auxiliaries is the key technology. The formulation of the high temperature resistant baking material of the present invention comprises 5 〇 8 8 〇 百 物 物 纤维 食品 食品 食品 食品 食品 食品 食品 食品 1 1 1 1 1 1 1 1 1 天然 天然 天然 天然The active aluminum citrate compound and the vegetable fiber pulp raw material and the 99 〇 weight 结合, combined with 100 weight percent of the vegetable fiber pulp slurry. For example, the percentage of water in the θ θ is mixed into a uniform right 疋 疋 12 12 12 1252832

五、發明說明(5) 百分比為100,則該該活性矽酸鋁化 ”5。,,而天然蠛類乳化劑之重 :之”百, =纖維紙聚原料為之重量百分比糊時比= 重ΐ百分比恰為990。 則水伤之 再另外製備之配方包括〇. 75〜5. 4 樹脂、0.9〜7.2重量百分比的聚酷及高分里子百聚刀人比的氟素糸 〇· 15〜0· 54重量百分比的聚胺系樹脂 Α ς Θ 克力系Μ月曰。在紙塑成型機儲漿槽中儲存由t 兩組配方組成本發明之混合漿料。 甲儲存由上述 材料ίϊΓ月ί::;溫Ξ烤之植物纖維食品包裝環保性 劑的活性矽酸:化二芬製備含陰離子性化合物配方之助 化合植物纖維紙漿原料及水份# f入政漿機中 料後置入紙塑成型機紙浆聚 該儲漿槽中儲存。在該儲漿槽中由脂也置入 ;成:由紙塑成型機製成容器,再經離形塗饰匕即 本發明對照先前技術之功效 維食相較於習用的植物纖 任何塑膠=4==發明的製程中不需添加 衣保規靶,如無污染、無公害、安全衛V. Description of the invention (5) When the percentage is 100, the active bismuth citrate is “5.”, and the weight of the natural hydrazine emulsifier: “100, = fiber paper concentrating material is the weight percentage of the paste ratio= The percentage of repetition is exactly 990. Then the preparation of the water injury is further prepared by 〇. 75~5. 4 resin, 0.9~7.2% by weight of the poly and high scores of the chlorinated knives than the fluorinated 糸〇·15~0·54% by weight Polyamine resin Α Θ Θ 克力系Μ月曰. The mixed slurry of the present invention is composed of two sets of formulations in a paper forming machine storage tank. A storage of the above materials ϊΓ ί ί::; warm Ξ 之 之 植物 植物 植物 纤维 纤维 纤维 植物 植物 植物 植物 植物 植物 植物 植物 植物 植物 植物 植物 植物 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备 制备After the material is placed in the pulper, the paper is placed in the pulping machine and stored in the slurry tank. In the slurry tank, the grease is also placed; into: a container made of a paper-plastic molding machine, and then subjected to the off-line coating, that is, the present invention compares the efficacy of the prior art with the conventional plant fiber. 4==Invented process does not need to add clothing protection target, such as pollution-free, pollution-free, safety

第10頁 五、發明說明(6) 生等,當然本發明的製成品皆係可以回 的物成a,如若本發明的製成品才皮當成 》成非食品級 時也不會產生有毒物質、水解時不會,,理,在燃燒 會造成一次π染問題,使用過後能有效運用=木、丟棄不 料混合使用,而且更具有攝氏2〇〇度可 炎理進而與肥 性,使得宜力破、κ — %1里的耐敎胜 r王仗伃今态在經過尚溫之後不會分解 J τ热特 質。 刀解不利人身健康的物 【實施方式】 參閱第-圖所示’其係顯示本發 物纖維食品包裝材料之製程,而第二 十=烤之植 實現第一圖所示製程所製備配合之系統示意圖本毛明為了 茲同時參閱第一圖及第二圖所示,對^ 術及配方作-詳細說明如後。本發明之可耐; 物纖維食品包裝材料之配方主要是包括含陰離子/、' (Anionic)性化合物配方之助劑丨、含 化合物與陽離子性(Cationic)化合物配方之 纖維紙漿原料3及水份4等依本發明製造方法組成之混人 料6,再藉由紙塑成型機9a製成本發明之可洪烤之環^性 植物纖維食品包裝材料之容器者。 ’、 該含陰離子性化合物配方之助劑丨係包括活性矽酸鋁 化合物(Inorganic Aluminum SiHcate)la、天然蠟類乳 化劑(Natural wax emuisi〇n) lb。其中該含非離子性化合 物與陽離子性化合物配方之助劑2係包括氟素系樹脂 口 1252832 五、發明說明(7) (Fluorochemical series)2a、聚酯及高分子聚合物 2b(High polymer compound)、聚胺系樹脂(Aliphatic polyamine)2c、改良壓克力系樹脂(Alkyl acryl copo1ymers) 2d ° 若該該植物纖維紙漿原料3之重量為1,則該水份4之 重量為9 9。其中該含陰離子性化合物配方之助劑1的活性 矽酸鋁化合物1 a相對於該植物纖維紙漿原料3之重量百分 比為5 0〜8 0。該含陰離子性化合物配方之助劑1的天然蝶類 乳化劑1 b相對於該植物纖維紙漿原料3之重量百分比為 1 · 5 〜9 〇 而該含非離子性化合物與陽離子性化合物配方之助劑 2之氟素系樹脂2 a相對於該植物纖維紙漿原料3之重量百分 比為0· 75〜5· 4。該含非離子性化合物與陽離子性化合物配 方之助劑2之聚酯及高分子聚合物2 b相對於該植物纖維紙 漿原料3之重量百分比為〇· 9〜7· 2。該含非離子性化合物與 陽離子性化合物配方之助劑2的聚胺系樹脂2c相對於該植、 物纖維紙漿原料3之重量百分比為〇.15〜〇54。該含非離子 性化合物與陽離子性化合物配方之助劑2的改良壓克力系 樹脂2d相對於該植物纖維紙漿原料之重量百分比 ” 0· 75〜9。 .、、、 本發明之可烘烤之環保型植物纖維食品包裝材料之配 方所選用之植物纖維紙漿原料3係以某幾種植物纖维為主 要原料所混合製成者,該植物纖維之植物纖維紙漿係〜、包 有蘆葦漿、甘蔗漿、草漿、麥桿漿、竹漿、木漿等。 第12頁 1252832 五、發明說明(8) 方中,該活n:j同'皿烘烤之植物纖維食品包裝材料之配 無機片狀= 合;係是-種陰離子性疏水性之Page 10 V. Description of the Invention (6) Health, etc. Of course, the finished product of the present invention is a recyclable material, and if the finished product of the present invention is made into a non-food grade, no toxic substances are produced. It will not be hydrolyzed, and it will cause a π dyeing problem in the combustion. After use, it can be effectively used = wood, discarded and mixed, and it has 2 degrees Celsius, which can be irritated and fat, which makes it easy to break. κ — %1 is resistant to 敎 r 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃 仗伃Knife to solve unfavorable personal health [Embodiment] Refer to the figure - Figure shows the process of the fiber food packaging material of the hair, and the twentieth = roast plant to achieve the preparation of the process shown in the first figure System Schematic This document is intended to refer to both the first and second figures. The formulation of the fiber-containing food packaging material of the present invention mainly comprises an anion/, an Anionic compound-containing auxiliary agent, a fiber pulp raw material containing a compound and a Cationic compound formula, and a moisture component. 4, etc., according to the manufacturing method of the present invention, the mixed material 6 is further prepared by the paper forming machine 9a as a container for the bungable ring-shaped plant fiber food packaging material of the present invention. The auxiliaries containing the anionic compound formulation include an active aluminum silicate compound (Inorganic Aluminum SiHcate) la, and a natural wax emulsifier (Natural wax emuisi 〇n) lb. The auxiliary agent 2 containing the nonionic compound and the cationic compound formulation includes a fluorine-based resin port 1252832. 5. Inventive description (7) (Fluorochemical series) 2a, polyester and high polymer compound 2b (High polymer compound) Aliphatic polyamine 2c, Alkyl acryl copo1ymers 2d ° If the weight of the plant fiber pulp raw material 3 is 1, the weight of the moisture 4 is 9 9 . The weight ratio of the active aluminum silicate compound 1 a of the auxiliary compound 1 containing the anionic compound formulation to the vegetable fiber pulp raw material 3 is from 50 to 80. The weight ratio of the natural butterfly emulsifier 1 b of the anionic compound-containing auxiliary 1 to the vegetable fiber pulp raw material 3 is 1 · 5 to 9 〇 and the nonionic compound and the cationic compound formula are assisted The weight percentage of the fluorocarbon resin 2 a of the agent 2 to the vegetable fiber pulp raw material 3 is 0·75 to 5·4. The weight percentage of the polyester and polymer 2b of the auxiliary 2 containing the nonionic compound and the cationic compound to the vegetable fiber pulp raw material 3 is 〇·9 to 7.2. The weight percentage of the polyamine resin 2c of the auxiliary 2 containing the nonionic compound and the cationic compound formulation to the plant fiber pulp raw material 3 is 〇.15 to 〇54. The weight percentage of the modified acrylic resin 2d containing the auxiliary compound 2 of the nonionic compound and the cationic compound formula relative to the vegetable fiber pulp raw material is “················ The plant fiber pulp raw material selected for the formulation of the environmentally-friendly plant fiber food packaging material is made by mixing some plant fibers as the main raw material, and the plant fiber pulp of the plant fiber is ~, coated with reed pulp, Sugar cane pulp, straw pulp, wheat straw pulp, bamboo pulp, wood pulp, etc. Page 12 1252832 V. Invention description (8) Fangzhong, the living n:j with the 'baked plant fiber food packaging materials with inorganic Flaky = combined; is an anionic hydrophobic

Li ίϊ製程中添加此劑,在製程中不僅可缩短脫 水及乾燥時間,更可以估士找 丨至〗难姐脫 性。 更τ ^使本發明之製成品具有耐高溫的特 方中本=ί可耐高溫供烤之植物纖維食品包裝材料之配 ,内;f撥水助劑。使用該天然蠛類乳化劑lb的;I;製 面強度。 且了鈥问该製成紙品之張力與表 本”之可耐高溫烘烤之植物纖維食品包 ’該亂素系樹脂2a是一種非離子性化合物之 用之撥水助劑及撥油助劑。 表、、、氏内添 本發明之可耐高溫烘烤之植物纖維食品包裴 方中’該聚S旨及高分子聚合物2b是由陽離子八 子聚合物所形成的中性上膠劑。 σ物同分 本發明之可耐高溫烘烤之植物纖維食品包粗 方中,該聚胺系樹脂2c是一種陽離子性固定劑,=之配 添用撥水助劑合併使用之助劑,能增進撥水劑边内 配合度,並能提高其撥水效果。 ”工版劑的 本發明之可耐高溫烘烤之植物纖 方中’該改良壓克力系樹脂2d是一種陽離;性^ =料之配 之撥水助劑。 、、’氏内添用 1252832 五、發明說明(9) 本發明之可耐高溫烘烤之植物纖維食品包裝材料之製 造方法,所使用的離型塗佈配方8為離型劑心、架橋劑讣 及稀釋水8c組成者。其中該離型劑“相對於該離型劑仏盥 該稀釋水8c總重量之重量百分比為1〇〜1〇〇,而該稀釋水心 相對於讜離型劑8 a與該稀釋水8 c總重量之重量百分比為 9=。例如當離型劑8a相對於該離型_與該稀釋水8^總 I之重量百分比為10,則該稀釋水8c相對於該離型劑心 =稀釋水化總重量之重量百分比細,絲型购 2離型雜與該稀釋她總重量之重量百分比為1〇〇, 旦“稀釋水8c相對於該離型劑8&與該稀釋水8c總重量之 1百分比為0。 旦再者該架橋劑8b的添加比例係相對於該離型劑8a之 分比為5。例如若離型劑8a之重量百分比為以 劑作為離型塗佈的硬= 橋劑係一種聚合起始 t述配方中之助劑,如果是自市面上取得 ===用合物及陽離子性化合物等: 份作為稀製造麻說明書記載添加適當的水 翏閱第 材料之製程及物纖維食品包. 程所製備配合之系、見f-圖所示: 含陰離子性化合物配方之助#11 (步驟1G1),再5^=備Adding this agent to the Li ϊ ϊ process not only shortens the dehydration and drying time in the process, but also can be used to find the 难 姐 姐 。 。. More τ ^ makes the finished product of the present invention have high temperature resistance, and can be used for the distribution of plant fiber food packaging materials; Using the natural terpenoid emulsifier lb; I; face strength. And the question of the tension and the form of the finished paper product, the high-temperature-baked plant fiber food package, the chaotic resin 2a is a water-repellent aid for the non-ionic compound and the oil-assisting aid. The present invention is a high-temperature-baked plant fiber food package containing the present invention. The poly-polymer and the high-molecular polymer 2b are neutral sizing agents formed from a cationic octapolymer. In the crude fiber of the plant fiber food package which can withstand high temperature baking according to the present invention, the polyamine resin 2c is a cationic fixing agent, and the additive used in combination with the water-repellent auxiliary agent can be improved. The degree of blending of the water-repellent agent can improve the water-repellent effect. "The method of the present invention can be used in the high-temperature baking of the plant fiber." The modified acrylic resin 2d is a kind of cation; = the water-dispensing aid of the material. ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,讣 and the composition of the dilution water 8c. Wherein the release agent "relative to the release agent 仏盥 the weight percentage of the total weight of the dilution water 8c is 1〇~1〇〇, and the dilution water core is relative to the release agent 8a and the dilution water 8c The weight percentage of the total weight is 9 = For example, when the weight percentage of the release agent 8a relative to the release type and the dilution water 8 is 10, the dilution water 8c is relative to the release agent core = dilution water The weight percentage of the total weight is fine, and the weight percentage of the silk type 2 and the total weight of the diluted one is 1 〇〇, and "the dilution water 8c is relative to the release agent 8 & and the total weight of the dilution water 8c 1 percentage is 0. Further, the addition ratio of the bridging agent 8b is 5 in proportion to the releasing agent 8a. For example, if the weight percentage of the release agent 8a is a auxiliaries in the formulation of the polymerization start-up formula of the hard-coated agent which is used as a release coating, if it is obtained from the market, === the compound and the cationicity Compounds, etc.: As a method for the preparation of a suitable water-based material, the product and the fiber package are prepared as a method for the preparation of a suitable material. See f-picture: Formulation with anionic compound #11 ( Step 1G1), then 5^=

1252832 五、發明說明(10) 3離子性化合物配方之助劑i置入散漿機槽7内,與植物纖 ^紙漿原料3加水份4混合授拌成均勻植物纖維紙m聚料5 步驟102)。該攪拌的適當時間係為1〇〜4()分鐘。 ^步驟103中H配方製備含非離子性化合物 /、1¼離子性化合物配方之助劑2。 在步驟1〇4中,係將步驟1〇3之助劑2與步驟(1〇2)之均 ^者植物、纖維紙漿漿料5置入儲聚槽9内混合授拌成混合聚料 ,步驟1〇5中’係將該混合衆料6藉由紙塑成型機9“ ί::ί ΐ ΐ f處理,以完成本發明之可耐高溫烘烤之植 切纖維食品包裝材料者。 f步驟106中,係將步驟105的製成品,在離型塗佈裝 钸處I,使用配方槽C製備好的離型塗佈配方8進行離型塗 理的再^步驟1〇7乾燥處理裝置11的乾燥處理,該乾燥處 的工作溫度攝氏120度,乾燥處理的時間約需15秒。 再經步驟108中將步驟1〇7的製成品包裝者。 本發明之可耐高溫烘烤之植物纖維食品包裝材料之配 化I铷ί含陰離子性化合物、非離子性化合物及陽離子性 同二# ^之助劑、添加劑,不但採用對人體健康無害者, 準。' 口以通過FDA美國食品藥物管理局之嚴格的檢驗標 高㈤、fat祕上所述本發明之較佳實施例可知,本發明之可耐 服、、之植物纖維食品包裴材料之配方及製程確能達到 12528321252832 V. INSTRUCTIONS (10) The auxiliary agent i of the ionic compound formulation is placed in the slurry tank 7 and mixed with the vegetable fiber pulp raw material 3 plus water 4 to form a uniform plant fiber paper m-polymer 5 steps 102). The appropriate time for the agitation is 1 〇 to 4 () minutes. ^ Formulation H in Step 103 to prepare Auxiliary 2 containing a nonionic compound /, 11⁄4 ionic compound formulation. In the step 1〇4, the auxiliary agent 2 of the step 1〇3 and the plant of the step (1〇2) and the fiber pulp slurry 5 are placed in the storage tank 9 and mixed to form a mixed aggregate. In the step 1〇5, the mixed mass material 6 is processed by the paper-forming machine 9 “ ί:: ΐ ΐ ΐ f to complete the high-temperature-resistant baking-cut fiber food packaging material of the present invention. In step 106, the finished product of step 105 is subjected to the release coating formulation 8 prepared by using the formulation tank C at the release coating assembly I, and the step 1〇7 drying treatment device is further processed. Drying treatment of 11 , the working temperature of the drying place is 120 degrees Celsius, and the drying treatment time is about 15 seconds. Then, the finished product of step 1〇7 is packaged in step 108. The high temperature baking plant of the present invention Formulation of fiber food packaging materials I铷 Anionic compounds, nonionic compounds and cationic cations and additives are not only harmful to human health, but also FDA-based foods. The strict inspection elevation of the Authority (5), the preferred embodiment of the invention described above is known. The formulation and process of the plant fiber food packaging material of the present invention can reach 1252832

五、發明說明(11) 預期的效果,業已符合於專利之要件。 由以上之實施例說明可知,本發明確具高度的產業利 用價值。惟以上之實施例說明,僅為本發明之較佳實施例 說明’凡精於此項技術者當可依據本發明之上述實施例說 明而作其他種種之改良及變化。然而這些依據本發明實施 例所作的種種改良及變化,當仍屬於本發明之發明精神及 以下所界定之專利範圍内。V. INSTRUCTIONS (11) The expected effect has been met with the requirements of the patent. As can be seen from the above embodiments, the present invention has a high industrial value. However, the above embodiments are merely illustrative of the preferred embodiments of the present invention. Those skilled in the art will be able to make various other modifications and changes in accordance with the embodiments of the present invention. However, various modifications and changes made in accordance with the embodiments of the present invention are still within the scope of the inventive concept and the scope of the invention as defined below.

第16頁 1252832 圖式簡單說明 【圖式簡單說明】 第一圖所示,其係顯示本發明可耐高溫烘烤之植物纖維食 品包裝材料之製程。 第二圖係顯示本發明為了實現第一圖所示製程所製備配合 之系統示意圖。 圖式各元件符號之說明: 1 含陰離子性化合物配方之助劑 1 a 活性矽酸鋁化合物 1 b天然蠟類乳化劑 2 含非離子性化合物與陽離子性化合物配方之助劑 2a 氟素系樹脂 2b聚酯及高分子聚合物 2c 聚胺系樹脂 2d改良壓克力系樹脂 3 植物纖維紙漿原料 4 水份 5 均勻植物纖維紙漿漿料 6 混合漿料 7 散漿機槽 8 離型塗佈配方 8a離型劑 8b架橋劑 8c稀釋水Page 16 1252832 Brief description of the drawings [Simplified description of the drawings] The first figure shows the process of the plant fiber food packaging material which can withstand high temperature baking according to the present invention. The second figure shows a schematic diagram of the system for the preparation of the process of the invention shown in the first figure. Description of the symbols of each component: 1 Auxiliary compound formulation additive 1 a Active aluminum citrate compound 1 b Natural wax emulsifier 2 Auxiliary 2a fluorocarbon resin containing nonionic compound and cationic compound formula 2b polyester and polymer 2c polyamine resin 2d modified acrylic resin 3 plant fiber pulp raw material 4 moisture 5 uniform plant fiber pulp slurry 6 mixed slurry 7 slurry machine tank 8 release coating formula 8a release agent 8b bridging agent 8c dilution water

第17頁 1252832Page 17 1252832

第18頁Page 18

Claims (1)

1252832 六、申請專利範圍 1 · 一種可财高溫焕快 植物纖維紙漿原料;植物纖維食品包裝材料, ίϊ離:物配方之助劑,其係與該植物 物纖置入散裝機槽内混合授拌而形 性化合物與陽離子性化合物配方之助 漿:植物纖維紙衆聚料置入一储漿槽内混合搜 H ί ί ί漿料以—紙塑成型機進行熱壓紙塑 燥處理,而得到該可耐高 : 艮品包裝材料。 品t = i利範圍第1項所述可耐高溫烘烤之植彩 ϋ ^材料,其中該植物纖維紙漿原料係以選 定之;^要原料混合部分比例之短木漿而製成 之纖維之植物纖維紙毁係包括有蘆葦漿 7皁漿、麥桿漿、竹漿等。 3. : t ΐ專利範圍第1項所述可耐高溫烘烤之植物 :=裝材料,其中該含陰離子性化合物配方之 /性矽酸鋁化合物及天然蠟類乳化劑。 4. 專利範圍第3項所述可烘烤之環保性植物 口口匕裝材料,其中該活性矽酸鋁化合物係是 包括: 纖維紙默 成均勻植 劑,其係 拌成混合 成型、離 植物纖維 7纖維食 定之植物 者,該選 、甘蔗 纖維食 )劑包括 纖維食 1252832 六 申請專利範圍 該植物纖::J::;旦該活性矽酸紹化合物相對於 蠟類乳化劑係是二種降;:::匕為50〜80 ;而該天然 然_化劑相對;= = = 劑,該天 為1. 5~9。 植物、義維紙漿原料之重量百分比 = 述可耐㈣烤之植物織维食 物配方之助劑'包:以=化合物與陽離子性化合 聚酯及高分子%人& '、’、树月曰、改良壓克力系樹脂、 刀子聚合物、及聚胺系樹脂。 6 ·如申请專利範圍第& 品包裝材料,其中兮* ^逑可耐高溫烘烤之植物纖維食 之製紙内添用之撥::劑$ m -種非離子性化合物 對於該植物纖維紙i ,油助劑,該氟素系樹脂相 原科重篁百分比為0.75〜5.4。 7 ·如申請專利範圍第5 一 品包裝材料,其中該 /可、耐向溫烘烤之植物纖維食 子性之中性紙類上;η:,子,合物係是-種陽離 該植物纖維紙漿原 μ歎酯及高分子聚合物相對於 、董$百分比為0· 9〜7· 2。 、 8·如申睛專利範圍苐$項戶、,、 品包裝材料,其中誃、所述可耐鬲溫烘烤之植物纖維食 時所添加之固定劑f誃脸樹脂係是一種陽離子性製紙 _ μ Λ胺系樹脂相對於該植物纖維紙 1252832 六、申請專利範圍 漿原料重量百分比為〇· 15〜0. 54 9·如申請專利範圍第5項所述可耐高溫烘烤之植物 ί :=料,其中改良壓克力系樹脂係是-種陽離/性 製::添用之撥水助劑’該改良壓克力 = 植物纖維紙漿原料重量百分比為〇, 75〜9。日相對於該 10. —種可耐高溫烘烤之植物纖維食品包裝材料 包括下列步驟: 表’ (:)製備植物纖維紙漿原料、含陰離子性 以及含非離子性化合物與陽離子性化合::方之之 (b)將該含陰離子性化合物配方之助劑置入散 内,與該植物纖維紙漿原料加水份 ’ θ 植物纖維紙漿漿料; 此口攪拌此合成均勻 (C )將該含非離子性化合物與陽 ^ ^ ^ ^ ^ ^ ^ :!=)所得到之植物纖維紙聚浆料; 内混合攪拌成混合漿料; 减果糟 ⑷將該混合漿料以—紙塑成型機進行熱壓紙塑成型。 11食如:Λ專二範圍第10項所述可耐高溫烘烤之植物纖维 製程’其中步驟⑷之後更包括在^ 為塑成型後之包裝材料進行離型劑塗佈之步驟。1252832 VI. Patent application scope 1 · A kind of high-temperature and fast-growing plant fiber pulp raw material; plant fiber food packaging material, ϊ ϊ: the formula of the auxiliaries, which is mixed with the plant fiber into the bulk machine tank The slurry of the compound compound and the cationic compound formula: the plant fiber paper aggregate is placed in a slurry tank, and the H ί ί pulp is processed by a paper-plastic forming machine for hot-pressing and plastic drying. The high resistance: 艮 packaging materials. Product t = i profit range The high temperature-resistant baking plant material according to item 1, wherein the plant fiber pulp raw material is selected; the fiber is made by mixing a portion of the short wood pulp with the raw material. The plant fiber paper destruction system includes reed pulp 7 soap slurry, wheat straw pulp, bamboo pulp and the like. 3. : t ΐ The high-temperature-tolerant roasted plant described in the first paragraph of the patent scope: = the loaded material, wherein the anionic compound is formulated with an aluminum citrate compound and a natural wax emulsifier. 4. The environmentally-friendly plant oral mouth-washing material according to item 3 of the patent scope, wherein the active aluminum citrate compound system comprises: a fiber paper silent uniform plant, which is mixed into a mixture and formed from a plant. The fiber 7 fiber-defining plant, the selected, sugar cane fiber food agent includes the fiber food 1252832. The patent application scope: the plant fiber::J::; the active bismuth acid compound is two kinds of wax emulsifier system 5至9。 The drop;::: 匕 is 50~80; and the natural _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Percentage of plant, Yiwei pulp raw material = 耐耐(四) roasted plant woven food formula additive 'Package: = compound and cationic compound polyester and polymer% & ', ', tree month 曰, modified acrylic resin, knife polymer, and polyamine resin. 6 ·If you apply for the patent scope & product packaging materials, 兮* ^逑 can be added to the high temperature baking plant fiber food paper:: agent $ m - a kind of non-ionic compound for the plant fiber paper i, oil auxiliaries, the percentage of the original fluorinated resin phase is 0.75~5.4. 7 ·Applicable to the 5th product packaging material of the patent scope, in which the vegetable fiber can be used for the baking of the vegetable fiber, and the η:, the child, the compound is a kind of cation away from the plant. The fiber pulp original 叹 酯 ester and high molecular polymer relative to, the percentage of Dong is 0·9~7·2. 8. If the scope of the patent application is 项$, household, and packaging materials, the fixing agent added to the vegetable fiber that can be used for baking and baking is a cationic paper. _ μ amide-based resin relative to the plant fiber paper 1252832 6. The patented range of pulp raw material weight percentage is 〇·15~0. 54 9 · The high-temperature baking-resistant plant as described in claim 5: = material, wherein the modified acrylic resin is - a kind of cation / property system:: added water auxiliaries 'the improved acryl = plant fiber pulp raw material weight percentage 〇, 75~9. The plant fiber food packaging material with respect to the high temperature baking is included in the following steps: Table ' (:) Preparation of plant fiber pulp raw material, anionic and nonionic compound and cationic compound: (b) placing the anionic compound-containing auxiliary agent into the dispersion, and adding water θ plant fiber pulp slurry to the vegetable fiber pulp raw material; the mixture is stirred and the synthesis is uniform (C) Plant fiber paper pulp obtained by ionic compound and cation ^ ^ ^ ^ ^ ^ ^ :! =); mixing and mixing into a mixed slurry; reducing fruit dough (4) the mixed slurry is carried out by a paper forming machine Hot press paper forming. 11 Foods such as: The high-temperature-baked vegetable fiber process described in Item 10 of the Λ2, wherein the step (4) further comprises the step of applying a release agent to the packaged material after molding. 1252832 六、申請專利範圍 1 2.如申請專利範圍第11項所述可耐高溫烘烤之植物纖維 食品包裝材料之製程,其更包括將該塗佈離型劑後之包 裝材料進行乾燥處理之步驟。1252832 VI. Application for Patent Range 1 2. The process of high temperature baking of plant fiber food packaging materials as described in claim 11 of the patent application, which further comprises drying the packaging material after coating the release agent. step. 第22頁Page 22
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TWI404849B (en) * 2009-09-04 2013-08-11
TWI421392B (en) * 2010-12-27 2014-01-01 Fomson Dev Entpr Co Ltd Anti-tearing protective structure manufacturing method and anti-tearing product

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US10640277B2 (en) * 2017-06-01 2020-05-05 Chef Pack, Llc Packaging for a food item
CN111501403A (en) * 2020-05-21 2020-08-07 安徽顺彤包装材料有限公司 High-temperature-resistant food packaging material and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI404849B (en) * 2009-09-04 2013-08-11
TWI421392B (en) * 2010-12-27 2014-01-01 Fomson Dev Entpr Co Ltd Anti-tearing protective structure manufacturing method and anti-tearing product

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