1247798 九、發明說明： 【發明所屬之技術領域】 本發明係關於一種硬質表面用清潔劑組合物，更詳細的 係關於一種於精密零件、冶工具類、金屬、玻璃、陶竟器、 塑料等之硬質構件表面（以下，亦稱為硬f表面）上存在之污 垢成分之除去性以及沖洗性較好，且安全性較高之清潔劑 口物X係、關於一種使用該清潔劑組合物清潔硬質表 面之方法。 ' 【先前技術】 先前，精密零件或組裝加工步驟中所使用之冶工具、零 件等硬質構件表面存在之油脂、機械油、切削油、潤滑油二 液晶、松香系躐等有機物作為主體之污垢成分之除去中， 使用有三氯乙烷、四氯乙烯等之氣系溶劑，三氯氟乙烷等 之氟氣碳化物系溶劑，於正矽酸鈉或苛性鈉中添加有界面 活性劑或助洗劑之驗性清潔劑’低沸點碳氫系溶劑等。但 是，氯系以及氟氣碳化物系溶劑於安全性、毒性、作業環 境以及環境污染等方面存在問題，又，於精密零件等使用 驗性清潔劑之情形’若殘存於被清結斗匆表面則有對塑料 零件等產生不良影響之憂慮，於電機、電子零件巾對電^ 特性有極壞影響之憂慮。 ” 為解決該問題，例如揭示有包含烷基甘油醚與十八烷及/ 或水之清潔劑組合物（日本特開平6_346〇92號公報），含有特 疋烷基聚糠苷之清潔劑組合物（日本特開平8_319497號公 報）’包含烷基糖苷、烷基聚甘油醚之清潔劑組合物（日本特 93358.doc I247798 開平3-m496號公報）等。但是，無法肯定該等清潔劑組合 物均於冲洗性或J1業用清潔劑所要求之反覆清潔性等方面 具有充分滿足的效果。 、主又，作為使用該等清潔劑組合物之清潔方法，首先作為 ^冰步mi潔劑原液或水稀釋之清潔劑液清潔，之 後作為冲洗步驟用水沖洗，之後，經過乾燥步驟係一般 清潔方法。 再者，最近存在精密零件之加工精度提高，凹凸非常多 且凹部間隙亦非常狹窄，生產性進—步提高故清潔步驟汽 費時間亦更加短縮化之傾向。 尤其是關於液晶污垢之除去，伴隨液晶顯示面板之薄聖 液曰曰7L件之間隙間隔變得更狹窄，間隙間存在之液晶 的清潔變得更困難。對於㈣液晶污垢，使用如上述之先 2清_組合物之情料，即使對存在於表面之液晶之 ’月：性良好，存在於間隙間之液晶之清潔性亦不充分。 2此#月望一種精密零件或組裝加工步驟中所使用之冶 々件等之硬I構件表面存在之各種油脂污垢（尤其是 ㈣密零件之㈣間隙、凹部附著之污垢）之溶解性、除去 /·生車又好，且沖洗亦不需要時間之清潔劑。 另一=面，金屬、玻璃、陶究器、塑料等之硬質構件之 表面之清料，過去即較廣泛地使用驗性 性清潔劑之領域中，A蔣古生, 更用驗 、主” ^ ψ為如同清春性，杈多的是自室溫升高 進行清潔。例如，連續清潔製鐵料中之鋼板 ’1之情形時，其清潔設備通常為連續清潔卷為卷狀之鋼 93358.doc 1247798 板（鋼帶）之構造，以30_1100m/分鐘左右之速度操作，鋼板 之清潔時間為最多數秒之極短時間。因此，鋼板用清潔劑， 一般為了以短時間去除鋼板表面附著之油分，清潔劑溫度 通常為60-80°C。但是，自經濟性方面考慮欲尋求一種即使 降低清潔溫度亦可維持高溫時之清潔性之清潔劑。 作為如上述之硬質表面用清潔劑組合物，揭示有含有聚 甘油醚型非離子界面活性劑及鹼性試劑之鹼性清潔劑組合 物（日本特開平5_194999號公報），含有甘油醚、萜系烴、界 面活性劑、鹼性試劑之鹼性清潔劑組合物（日本特開平 1 1 -256200號公報）等。但是，該等清潔劑組合物於低溫（5〇它 以下）且短時間清潔條件下之反覆清潔性、低泡性等方面並 不充分。 【發明内容】 即’本發明之要旨係關於 [1] 一種硬質表面用清潔劑組合物，其含有烷基糖苷、甘 油鱗、烯系烴及/或鏈烷系烴以及水， [2] —種清潔硬質表面之方法，係使用上述π]之清潔劑組 合物。 【實施方式】 本务明係關於一種硬質表面用清潔劑組合物以及使用該 /月潔劑組合物清潔硬質表面之$〉去，該清潔齊！組合物對於 硬質表面上之各種污垢可共通使用，且具有較好之溶解 性、除去性，尤其是可較大改善至今成為速率決定之沖洗 ^生且無環境污染之危險，安全性較高。 93358.doc 1247798 1貝表面用清潔劑組合物（以下，簡稱為清潔劑 組合物）較大特徵在於含有烧基糖普、甘油醚、浠系烴及/ 或鏈烧系烴以及水’且併用相關成分。 特別疋本务明之較大特徵在於藉由組合烧基糖普與甘 油趟，使本來不溶於水Μ系烴及/或鏈烧系烴於高含水域 中亦可分散。 因此’即使高含水率亦可溶解除去硬質表面上存在之油 性污垢，不僅可較大降低清潔劑成本，且與先前之清潔劑 相比，不需考慮點火性進行嚴密之水分管理，故而操作變 為容易。 又’先剛之含有煙之水系清潔劑，因附著於被清潔物之 清潔成分被帶入沖洗槽而產生白濁，◎被清潔物洗掉清 潔成分時之沖洗時之負荷較大，但本發明之清潔劑組合 物’因於高含水域亦可穩定地分散烴，故即使稀釋亦均— 透明，故可大幅度降低清潔後之沖洗步驟的負荷。 再者，發現可清潔液晶元件之間隙間存在之液晶，尤其 是對於清潔困難之間隙間較狹窄之液晶元件内存在之液晶 污垢亦具清潔的效果。X ’先前之清潔劑，為洗掉元件間 隙内殘留之清潔成分，沖洗時之負荷較大，但藉由使用本 發明之清潔劑組合物，沖洗變得格外容易。 再者，本發明如後述，藉由烷基糖苷與甘油醚之特定比 率下與鹼性試劑組合，與烷基糖苷單獨相比不僅可降低表 面張力，提高對油垢之浸透·溶解力，且可維持烷基糖苷之 乳化力、沖洗容易性。 93358.doc 1247798 藉此，本發明之清潔劑組合物，可以極短時間低溫下有 效除去油分，於尋求反覆清潔性或低泡性之工業用清潔 劑，尤其是以非常短時間要求脫脂性之鋼板等之鋼板用清 潔劑領域為有用。 另，本發明之清潔劑組合物於低溫下亦具有充分之硬質 表面之π 4性能，於高於50。〇之高溫下亦具有優於先前所 不之衆所周知之清潔劑的性能。 另本务明中’硬質表面係被清潔物之精密零件、冶工 ^類、金屬、玻璃、陶竞器、塑料等之硬質構件表面，本 :明之清潔劑組合物係以該硬質表面上附著之液晶、油成 分、造渣（焊接時產生之餘）等各種㈣作為清潔對象者。 本發明中使用之烷基糖苷以下述一般式（1)表示： Rl(OR2)XGy (1) [式中，Rl表示直鏈或分歧鏈之碳數8-18之烷基、烯基、或 、一 土苯基r表不奴數2_4之伸烧基，G表示來自具有碳數 之還原糖之殘基，χ(平均值）表示〇_5，〆平均值）表示 1 -5] 〇 式中，較好是0-2，更好是〇。γ較好是丨_15，更好是 ^1·4。R1之碳數，自清潔性方面考慮，較好是9_16，更好 疋10 14。另’ X以及y藉由質子（1H)NMR求得。 為^基糖苦，只要滿足上述—般式⑴即可，並無特別 限制二例如自獲得較高清潔性方面考慮，較好是癸基糖芽、 十一蚝基糖苷、肉豆蔻基糖苷等。 作為燒基糖苦之含量，於清潔劑組合物中較好是0·01. 93358.doc 1247798 董量％ 其中，清潔精密零侔w r± ^ 牛口工具類之硬質表面時，自獲 诗h兩沖洗性方面考A r目焱 重量。/。，更好是K50重Ί 糖普之含量，較好是_ 重里❻/。，尤其好的是2_4〇重量 好的是5-30重量％。 里里/。，特別 清潔金屬、破璃、廟签 θ “ ㈣盗、塑料等之硬質表面時，較好 是併用烷基糖苷及鹼性气制 平又灯 性方面考岸，作為;^：=°時’自獲得較高沖洗 号慮作為&基料之含量，較好纽gi_2g重量％， =。.02-10重量％，尤其好的是〇〇3_5重量％，特別好的 疋0.04-3重量％ 〇 、作，本發明中使用之甘油喊，自不降低清潔性且於使用 :度範圍内維持均一透明之製品性狀方面考慮，可列舉出 碳數4-12之直鏈或分歧鏈之絲或縣，例如較好是且有^ 或2個，特別是具有i個選自例如正丁基、異丁基、正己基、 異己基、正庚基、正辛基、2_乙基己I、正壬基、正癸基 等具有碳數4_12之烧基者，尤其是碳數5_1()，進而碳數5_8 之烷基者。再者作為本發明中使用之甘油醚，甘油基為2個 以上’較好是2·3個甘油基以關連接之單院基二甘油喊或 單院基聚甘㈣均可。尤其是自於液晶污垢清潔性較好方 面考慮，較好是單烷基甘油醚、單烷基二甘油醚。該等甘 /由醚可單獨或混合2種以上使用。本發明中，因使用相關甘 油鱗’而可穩定有機溶劑與水之分散性，故有可獲得污垢 更嚴重之強油性污垢及/或液晶污垢之清潔性之優點。 尤其好的甘油醚係2-乙基己基甘油醚。 93358.doc -11 - .1247798 作為甘油醚之含量，於清潔劑組合物中，較好是〇〇2_肋 重量％。 其中，清潔精密零件以及冶工具類之硬質表面時，自穩 疋烴與水之分散，兼具較高清潔性與沖洗性方面考慮，作 〇為甘油醚之含量，較好是〇·2_8〇重量％，更好是〇·5_5〇重量 °/〇，尤其好的是1-30重量％，特別好的是卜2〇重量％。 清潔金屬、玻璃、陶竟器、塑料等之硬質表面時，較好 是併用驗性試劑。該情形時，自提高對於油污垢之浸透性 方面考慮，作為甘油醚之含量，較好是〇〇2_4〇重量％，更 =是〇.〇3_2〇重量％，尤其好的是G.G5_1G重量％，特別。好的 疋0.1-5重量％。 本發明之清潔劑組合物中，燒基糖糾油ϋ之重量比較 好是 0.25-10。 其中’清潔精密零件以及冶工具類之硬質表面時，自抑 制f潔時之起泡性方面考慮，炫基糖苦/甘油趟之重量比較 好疋10以下，又自穩定分散煙與水方面考慮，較好是丄以 上。因此，院基糖糾油峻之重量比較好是M0,更好是 3-8，尤其好的是3_6。 /青潔金屬、玻璃、陶究器、塑料等之硬質表面時，較好 疋併驗性試劑。該情形時，貌基㈣/甘㈣之重量比， 自兼具次透性與沖洗性方面 洗性方®考慮’較好是4以下，自維持沖 冼性方面考慮較好是〇·25以卜m , 曰 。因此，该烷基糖苷/甘油醚 之重篁比較好是〇·25_4 ,更 f疋〇·3-3，尤其好的是〇·4-ΐ。 本舍明中使用之烴係稀煙系煙及/或鏈燒系烴。 93358.doc -12- .1247798 作為烯烴系烴以及鏈烷系烴較好的是碳數ι〇， :二之化合物，例如可列舉出：癸院、十二烧、+四；: 十二、i八烷、癸烯、十二碳烯、十四碳烯、十六碳烯' 八碳料直鏈或分歧鏈之飽和或不飽和烴系溶劑；環癸 =環十二碳烯等環狀化合物等之脂環式烴系溶劑等。該 ，較好是碳數1(M8，較好是⑽4之直鏈或分歧鏈之飽 和或不飽和烴’更好的是烯系烴。 、二可早獨或混合2種以上使用。 本I明巾，除上述烯烴系烴以及鍵烧系烴以外，亦 可使用壬基苯、十-烷其贫 烷基本專烷基苯，甲基萘、二甲基萘 奈化合物等之芳香族烴系溶劑。 本發明之清潔劑組合物φ Λ aa w、且σ物中，作為該等烴之含量較好是 0.005-80 重量 ％。 π其：，清潔精密零件以及冶工具類之硬質表面時，自獲 于車乂…月潔性方面考慮，上述烴之含量較好是〇 . 1，重量 % ’尤其好的是0.5-50重量％，白基θ、丄ν、也主 自兼具油分清潔性與沖洗性 方面考慮，較好是1_2〇番吾〇/，®丨，《 疋丄川重里/〇，更好是4_2〇重量〇/〇， 的是5_20重量。/。。 〃 f 清潔金屬、玻璃、陶_亮器、塑料等之硬質表面時，較好 是併用鹼性試劑。該情形時，作為烯烴系烴以及鏈烷系烴 之含量’自提高對於油污垢之浸透性，且抑制起泡性方面 考慮，較好是0.005，重量％’更好是〇〇ι·8重量％，尤1 好的是0.02-5重量％。 八 作為本發明中使用之水 並無特別限制 可列舉出··離 93358.doc -13- .1247798 子交換水、純水、去離子水等。 作為水之含量，於、、主 盆中、主兔 、4劑組合物中較好是5 - 9 9.8重量％。 二量==件以及冶工具類之硬質表面時 慮：是== ㈣重量。/。，特別好1是1G·95重量％’尤其好的是 重量％。 、 力疋50·90重量％，特別好的是60-90 >月潔金屬、玻m器、塑料等之硬f表面時，較好 是併用驗性試劑。該情形時，作為水之含量，自降低使用 時之排水負荷且濃縮化清潔液方面考慮，較好是5.99.8重量 % ’尤其好的是10-99.5重量％。 本赉明中，作為烧基糖苷、甘油醚、埽烴系烴及/或 ㈣系烴之較好組合，可列舉出：烧基㈣為癸基糖普以 及十二烷基糖苷，甘油醚為2_乙基己基甘油醚以及己基甘 /由驗’烯煙系烴及/或鏈烷系烴為分別選自癸烯、十二碳 稀、十四碳烯、癸烷、十二烷以及十四烷者。 又’本發明之清潔劑組合物，自獲得更高清潔性方面考 慮，較好是含有鹼性試劑。 作為本發明中使用之鹼性試劑，若為水溶性鹼性試劑則 可使用任一種。至於具體例，可列舉出··氫氧化鈉、氫氧 化鉀等鹼金屬之氫氧化物，正矽酸鈉、偏矽酸鈉、倍半矽 酸鈉（例如，一號矽酸鈉、二號矽酸鈉、三號矽酸鈉）等之矽 酸鹽，磷酸二氳鈉、磷酸氫二鈉、磷酸三鈉、焦磷酸鈉、 三聚磷酸鈉、六偏磷酸鈉等之磷酸鹽，碳酸二鈉、碳酸氫 93358.doc -14- .1247798 納、碳酸二細 山 卜 —’甲、奴酸氫鉀等之碳酸鹽，硼酸納等之硼酸鹽 等。可組合二錄, 一裡Λ上水溶性鹼性試劑使用。該等鹼性試劑 車乂好氧化納、氫氧化卸、正石夕酸納、偏石夕酸納。 作：：潔劑組合物中鹼性試劑之含量，自維持較高清潔 /辰鲕q潔液方面考慮，較好是〇•卜5〇重量％，更好是 0.1-10重晉〇/ 々朴 0 u y、好的是0·2-8重量％，特別好的是0.5-5 重量％。 使用驗性试劑時’尤其是連續清潔附著於鋼板（鋼帶）表面 之堡延油之情形時，較好是併用螯合劑及/或水溶性高分子 缓酸。 太本电明之清潔劑組合物，可藉由併用整合劑進一步提高 :潔(·生肊’至於所使用之螯合劑’可列舉出：帛萄糖酸、 =庚糖^等之搭糖酸類，乙二胺四乙酸等之胺基缓酸類， 榑檬酸、蘋果酸等之經基叛酸類，胺基三亞甲基膦酸、經 基乙叉二膦酸等之鱗酸類，以及該等之驗金屬鹽、低級胺 鹽、銨鹽、燒醇録鹽等，尤其好的是葡萄糖酸納、葡庚糖 酸鈉、乙二胺四乙酸鈉、檸檬酸鈉、羥基乙又二膦酸鈉。 本發明之清潔劑組合物中螯合劑之含量，自清潔性以及 經濟性方面考慮較好是0.01_15重量％，尤其好的是0 05_10 重量％。 本發明之清潔劑組合物，可藉由添加水溶性高分子缓 酸，進-步提高保存穩定性或清潔性能。至於本發明中使 用之水溶性高分子M，可列舉出以—般式⑺表示之化合 物。 93358.doc 15 1247798 [化1] 广Γ —Π π — ? V R3 m C'— 〇 —-- ,1 1 COOM」 [式中，rLr6為相同或不同且表示氫原子 (2) 碳數1-5之烷 基、碳數1-5之燒氧基、c〇〇M、i〇H，M表示氮原子、驗 金屬、碳數1-4之烷基胺、i碳數卜6之烷醇胺，❿以及· 別表示括號内之構成單位之莫耳數，m/n(莫耳比）為 0/10-10/1]。 作為一般式（2)之兩末端之基團，並無特別限制，可列舉 出：氫原子、OH、碳數！·5之烷基、碳數丨_5之烷氧基或 S〇3M(M與上述相同）等，兩末端之基團相同或不同均可。m 亦可為0。又，以一般式（2)表示之化合物之重量平均分子量 (Mw)為 1，000-100,000，較好是 3,000_5〇,〇〇〇，尤其好的是 5,000-20,000。聚合形態可為嵌段或無規。 至於以一般式（2)表示之水溶性高分子羧酸之具體例，可 列舉出··丙稀酸均聚物、丙烯酸-馬來酸共聚合體、c^經基 丙稀酸均聚物、C5烯烴-馬來酸共聚合體、異丁烯-馬來酸共 聚合體等，以及該等之鹼金屬鹽或胺鹽等。較好是丙稀酸 均聚物、丙烯酸-馬來酸共聚合體，亦可組合使用2種以上 之水溶性高分子羧酸類。 本發明之清潔劑組合物中之水溶性高分子羧酸之含量， 自水的軟水化性能、清潔性以及低COD(chemical oxygen demand，化學需乳I)方面考慮’較好是0.05-1重量％，尤 93358.doc -16- 1247798 =好的是〇·⑷重量％。藉由使其為q量％以上， =業用水等硬度較高之水之情形時，賴子或鎂離子與 作為污垢混入之脂肪酸蓉 、 潔不良之效果者。㈣成水不溶性鹽，而可有抑制清 又本杳明之清潔劑組合物中為降低清潔液之黏度 制清潔時之起泡性，淮而 攸 進而’降低清潔之後沖洗時[以下稱 預備沖洗]之排水負荷，較好是加人二賴。至於H ^列舉出：乙二醇單燒基（碳數M2㈣、二乙二醇單 數M聊、三乙二醇單燒基（碳數Μ训、乙二醇苯甲^ 一乙一知本甲醚、乙二醇苯醚、丙二醇或二丙二醇之單烷 基（礙數1_12)鍵，二燒二醇（碳數2_12)之單院基（碳數卜^) 醚，其中較好是乙二醇單己基趟、乙二醇單2-乙基己基縫、 -乙一知早丁基謎、二乙二醇單己基趟、二乙二醇單2·乙 基己基醚、三乙二醇罩丁装 ^ 咚早丁基醚、二丙二醇單丁基醚、二乙 一醇二曱基醚、二乙二醇二丁基醚’自進行曰本專利第 2W報巾揭示之降低沖洗液之排水負荷之清潔方 法（以下’稱為油水分離法）方面考慮，尤其好較二乙二醇 単己基醚、二乙二醇單2_乙基己基喊、二丙二醇單丁基鍵、 二乙二醇二丁基醚。 又併用驗性試劑之情料，自提高清錢之浸透性且抑 制清潔液之起泡性方面考慮，尤其好的是乙二醇單2_乙基 己基醚、二乙二醇單2-乙基己基醚。 該等二醇醚可單獨或混合2種以上使用。 作為二醇趟之含量，於清潔劑組合物令較好是〇 〇1-4〇重 93358.doc -17- 1247798 量％。 其中，清潔精密零件以及冶工具_ # /、賴吋，作為二醇人 量，自清潔劑之曇點為賊以上’於高溫下清潔 ： 油水分離法方面考慮，較好是0.01_40重量％，更^ 重量％，尤其好的是0卜25重量％， 0 荷別好的是0.5_20會 %，最好是0.5-15重量。/。。 清潔金屬、玻璃、陶曼器、塑料等之硬質表面時 是併用驗性試劑。該情形時，作為二醇趟之含量 對於油污垢之浸透性且抑制起泡性方面考慮，: 0.02-40重量％，更好是〇 〇3_2〇重量％ 疋 兀具好的是0.04-10 重篁％，特別好的是0·04_5重量0/〇。 又，本發明之清潔劑組合物，亦可根據需要添加抑 f劑分離用之可溶化劑，或使清潔劑之外觀為白色懸浮狀 悲之漿化劑製造成為濃縮清潔劑組合物之形離。 至於本發明中使用之可溶化劑 合1了列舉出··脂肪酸及其 皿、以及硫酸烧酯及其鹽，且體。 ^ n ^ 、凰，、體為•妷數6_18之烯基琥珀 酉文及其鹽、己酸、庚酸、辛酸、癸 卞夂六®夂、月桂酸、丁酸、戊 酉文、異丁酸、2-乙基己酸及其鹽。 至於本發明中使用之漿化劑，可列舉出：上述水溶性高 分子缓酸、或蔡二甲酸、萘二石黃酸或鄰苯二甲酸及該等之 驗金屬鹽或胺鹽。 又，本發明之清潔劑組合物中， 丌了添加抑制清潔步驟 產生氣泡之消泡劑，例如，聚石夕羞古 卞^氧 阿級醇、高級脂肪 酉夂及其鹽、普朗尼克型共聚 m “拉尼克型共聚物、聚乙 93358.doc 1247798 二醇、聚丙二醇等。 、、辰縮巧β Y]之形恶提供本發明之清潔劑組合物之情形 、/、、、且成並無特別限制，自獲得較好之製品穩定性以及 配管輸_方面考慮’甘油醚較好是W猶量％，更好是 〇·5:5重量％ ’燒基㈣較好是GI2G重量％，更好是0.5-5 重’婦經系煙及/或鏈燒系煙較好是0.05-20重量。/。，更 子= 0·1 5重里％，二醇醚較好是〇,卜重量％，更好是巧 里％驗劑較好是卜⑼重量％，更好是15_45重量％， 。可心化诏或水化劑較好是〇 〇5·4〇重量％，更好是重量 又3有螯合劑之情形時較好是〇·卜20重量％，更好是 〇重里％潔劑組合物穩定則可不使用可溶化劑或 漿化劑。 本發明之清潔麻合物中，於不損壞本發明之效果範圍 内’可根據需要適宜併用於通常清潔劑組合物中使用之豆 他界面活性劑、、防腐劑、防銹劑、聚彻之、細 有構成之本發明之清潔劑組合物，可藉由根據常 ==成分以及任意成分等製造。例如，授拌並混合 炉二：：、上述甘油醚 '上述烯烴系烴及/或鏈烷系 :丫”根據需要混合其他任意成分，最後 添加水，即可製造。 取1交 又，本發明之清潔劑組合物，較好是作 於清潔時財等水性介質稀_❹。 本發明之清潔劑組合物，可適用於清潔精密零件、冶工 玻离陶“、塑料等之硬質材料之表面的 93358.doc -19- 1247798 來斤周知之清潔方法。例如，藉由使用以本發明之清潔劑 組合物之原液或水稀釋之液進行清潔步驟，繼而經過沖洗 步驟、乾燥步驟，進行被清潔物之清潔。因此，本發明 關於使用上述清潔劑組合物清潔硬f表面之方法。x '、 清潔步驟、沖洗步驟之物理力並無特別限制，例如，时 獨或組合浸潰法、超聲波清潔法、浸潰搖動法、法早 電解/月潔、手拭法等各種衆所周知之清潔方法進行清 溫度等清潔條件亦可為通常進行之衆所周 例。 較好是自常溫至90。〇以下m 料例如 80t以下。 C以下，考慮到水分之蒸發尤其好的是 本‘明之清潔劑組合物，於低溫下清潔金 陶瓷器、塑料等時為有尤 、、玻璃、 “潔，即浸潰清潔、喷霧 鋼板之連 中可發揮其效果。 “ ’月潔、電解清潔等 本毛明之清潔劑組合物亦可 負荷之油水分離法的清潔。 _冲洗液之排水 其中’本發明之清潔劑組合物，於 工步驟中所使用之冶在“牛及其組裝加 貝之/月春中具有+、甘丄2 本發明中之精密零件係指例如電子2 1 果。 機零件、樹脂^零件、光學零件等 ^零件、電 此處所謂之電子零件，例如 體封裝、印刷佈線基板、IC導線、陶=面板、半導 材料、水晶振子。至於金屬零件，例士是板等之半導體 動機器中使用之軸承、 彳如可列舉出：精密驅 電子亞或電瓶之深昼容器或罐等之 93358.doc -20. 1247798 塑性加工品。至於電機 發動機〜之… 列舉出：電刷、轉子、 出之電動機零件。至於樹脂加工品，例如可列舉 學^丰⑴ 使用之精密m旨加卫零件。至於光 予零件，例如可列舉出··攝 之透鏡。 爾心機眼鏡、先學機器中使用 上中組裝加工步驟中所使用之冶工具類係指，將如 等件例之精密零件進行製造、加工、組裝、濁飾 2驟中使用之冶具、工具，此外亦指操作該等精密 零件之各種機器、其零件等。 ^明之清潔劑組合物’尤其是對於上述中之液晶面板 :中存在之泄漏液晶污垢、半導體封裝、印刷佈線基 殘存之造逢、石夕錠切削後附著於表面之加工油、金屬 )件之塑性加工時附著於表面之加卫油發揮較高清潔性， 仁成為本發明之清潔對象之精密零件類以及冶工具類並非 『於”亥等之例者，若為附著有組裝加工步驟中之各種加 工油、液晶或造逢等之後步驟之有害物質，或降低製品之 =性的各種油形污染物質之具有一定形狀的個體表面之精 密零件類以及冶卫具類，則可適用本發明之清潔劑組合物。 典再者’該等污染物質為例如油脂、機械油、切削油、潤 月’由松香系造渣、液晶、石油瀝青等之主要為有機油分 垢時，本發明之清潔劑組合物尤其有效，對於於其中 此入有金屬粉、無機物粉、水分等之污垢亦具有較高清潔 性。 實施例 93358.doc -21 - 1247798 以下，藉由貫施例進一步揭示本發明之態樣。該實施例 僅僅係本發明之示例，並無任何限定意義。 <試驗基板之製作> 將於液晶元件（間隙間距離5 μχη)之間隙内密封TFT(薄膜 電晶體）液晶，於室溫下靜置30分鐘者作為試驗基板。 實施例1 - 6、比較例1 - 3 以表1所不組成之方式，添加混合各成分，分別調製實施 例1-6以及比較例1-3之清潔劑組合物。於該調製之糾它之清 潔劑組合物中，10分鐘超聲波清潔（39 kHz、200 W)試驗基 板，之後，於4槽之各純水槽（4(rc)中進行3分鐘沖洗後，於 90C之熱風乾餘機中進行30分鐘乾燥，觀察樣品。 [液晶清潔性評估方法] 以偏光顯微鏡（倍率25倍）觀察清潔後殘留於液晶元件之 間隙内之液晶，以及沖洗時未充分排出之液晶與清潔劑組 合物之混合物，評估液晶面板之清潔性。 液晶清潔性評估表示為自觀察之間隙之全面積減去液晶 以及液晶與清潔劑之混合物殘留部分之全面積之面積，除 以觀察之間隙之全面積的值。又，評估基準如以下規定。 [液晶清潔性評估基準] ◎ : 90%以上 〇：80-未達90% △ : 40-未達 80% X :未達40% (反覆清潔性） 93358.doc -22- 1247798 為評估清潔液之反覆清潔性，調查液晶飽和溶解濃度。 保持於40°C之清潔劑組合物20 g中添加TFT液晶〇_〇2 g，於 40 C下保持3分鐘。於該狀態下確認溶液狀態，若為透明則 判斷已溶解’重複同一操作。重複該操作，自清潔液開始 出現白濁之液晶量減去〇·〇丨g之量算出飽和溶解濃度，定義 為液晶飽和溶解濃度。 例如’假疋加入TFT液晶〇·24 g時開始出現白濁，則液晶 飽和溶解濃度以（0.24-0.01)/(20+0.24-0.0l)x 1〇〇算出。使用 相關液晶飽和溶解濃度，基於下述評估基準評估反覆清潔 性。 〆、 [反覆清潔性評估基準] ◎ : 2%以上 〇：1%以上·未達2% △ : 0.5%以上·未達ι〇/0 x :未達0.5 % (沖洗水評估） 為評估沖洗水之液狀態，調製各清潔液之5重量％水溶液 作為預備沖洗液’又調製各清潔液找5重量％水溶液作為 沖洗液，觀察60<t下該等預#沖洗液以及沖洗液之狀態， 評估沖洗水。 (沖洗性評估） 1·於清潔液（60。〇之1〇重量％水溶液中⑽g)浸潰18張玻 璃面板（35X48 mm) 10分鐘。 •之後ffi20移提升面板，於加入有6〇。〇純水湖g 93358.doc -23- 1247798 之第1沖洗槽中浸潰（2分鐘）。 3.同樣地提升面板，於加入有6〇t純水5〇〇g之第2沖洗槽 中浸潰（2分鐘）。 4·繼而於保持為70艽之純水的萃取槽（超聲波槽）中，為萃 取蜮存於面板表面之清潔劑成分，以超聲波（38 κΗζ，4⑻w) 進行10分鐘沖洗。 5·然後藉由TOC(全有機碳計）測定各沖洗槽（第i、第幻之 冲洗水以纟超聲波槽之萃#水之有機物濃度，減下式算 出第1沖洗槽之油分除去率。 式·第1沖洗槽之油分除去率（％)=(第1沖洗槽之有機物重 里）/(第1沖洗槽之有機物重量+第2沖洗槽之有機物重量+超 聲波槽之有機物重量）X 100 對於第1沖洗槽之油分除去率如以下之方式評估。 ◎ •第1沖洗槽之油分除去率為9〇%以上 〇·第1沖洗槽之油分除去率為7〇%以上_未達90〇/〇 △ •第1沖洗槽之油分除去率為5〇以上_未達70〇/〇 X:第1沖洗槽之油分除去率為未達50% 93358.doc -24- 1247798 [表i] 實 實 實 實 實 實 比 比 比 施 施 施 施 施 施 較 較 較 例 例 例 例 例 例 例 例 例 1 2 3 4 5 6 1 2 3 烷基糖苷υ (平均碳數 21.4 16 10.7 16 - 20 - 25 - 11.3) 烷基糖苷2) (平均碳數 - - - - 12 - 40 - - 清 潔 10.2) 2-乙基己基 5.3 4 2.7 4 3 5 10 劑 甘油醚 戊基甘油喊 - - - - - - - 25 40 組 合 烷基糠苷/ 口 物 甘油醚之重 4 4 4 6 4 4 - - 一 N 量比 重 ce-嫦烴 13.3 10 6.6 10 5 15 • 5 王 量 (C12) 二乙二醇單 〇 % 己基醚 0 三乙二醇單 2 丁基醚 水 60 70 80 70 80 50 60 50 40 聚氧化乙烯 油醚 - 5 (HLB = 13.0) 液晶清潔性 ◎ ◎ ◎ ◎ ◎ ◎ X X Δ ll 士 反覆清潔性 ◎ ◎ ◎ ◎ ◎ ◎ X X 〇 特 .kJ- 預備沖洗液 透 透 透 透 白 透 透 白 之狀態 明 明 明 明 濁 明 明 濁 5干 /J- 沖洗液之狀 g 日 透 透 透 透 透 透 透 白 1石 態 明 明 明 明 明 明 明 濁 沖洗性評估 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 Δ 1)一般式（1)中 χ=〇、y=l.3 2)—般式（1)中 χ=0、y=1.3 表1之實施例1 -5中，因預備沖洗水、沖洗水均透明，沖 洗性評估亦較高，液晶溶解性亦較高，故判斷清潔後之間 隙中，無液晶以及液晶與清潔劑組合物之混合物，具有較 93358.doc -25- 1247798 高液晶清潔性。又實施例6中顯示為可實施油水分離法之清 潔劑組合物，雖然預備沖洗水白濁，但沖洗水透明，故可 充分沖洗清潔成分。 對此可知，比較例1及2雖然沖洗水為逸明，但因不含烴 故無液晶溶解性，液晶清潔性較低。因此以同樣之清潔液 反覆清潔之工業用清潔劑中，該等清潔液不具有充分之性 能。又，可知比較例3雖然含有烴，具有液晶溶解性，但沖 洗性較差，其結果液晶清潔性降低。 實施例7-10以及比較例4-7 · 如表2所示之組成，添加混合各成分，分別調製實施例 7-10以及比較例4-7之清潔劑組合物（殘量為去離子水），藉 由下述方法進行鋼板清潔試驗，評估鋼板之清潔性、起泡 ， 性以及消泡性。結果示於表2。 _ <鋼板清潔試驗> (1) 被清潔鋼板 將被清潔鋼板全部冷軋為厚〇·5 mm之附著油分量350 ❿ mg/m2之鋼板切斷為縱50 mm>^f25 mm之大小進行製作。 (2) 疑似劣化清潔液之調製 於清潔劑組合物中以1 ·〇重量％之方式於清潔劑組合物中 · 添加自附著堆積於壓延機之鐵渣以己烷萃取獲得之鐵渣萃 取油，充分攪拌調製疑似劣化清潔液。 (3) 清潔以及沖洗方法 於清潔劑組合物（無污垢之清潔液）以及疑似劣化清潔液 中’分別自設置之縱1〇〇 mmx橫50 mm大小之電極板1對（電 93358.doc -26- 1247798 極板間距離20 mm)間以等距離且於中心浸潰被清潔鋼板i 秒，之後以電流密度10 A/dm2將鋼板電位自負至正切換一 次，分別以每0.5秒通電流進行電解清潔。之後繼續自噴嘴 1〇 cm之位置進行水喷淋洗滌（水溫2〇。〇，水壓〇2 Mpa》秒 鐘，溫風乾燥。另，試驗清潔液之溫度為4〇t：。 (4) 鋼板清潔性之評估（殘存附著油分量測定方法） 關於無污垢清潔液以及疑似劣化清潔液，分別使用鋼板 附著油分量測定裝置「麵A_⑴」（(株）堀場製作所製造） 測定清潔以及沖洗後之鋼板附著油分量，5張之平均作為測 定值、，以下述基準評估鋼板之清潔性。另，使用疑似劣化 清潔液之評估係假定於清潔槽中蓄積有附著於鋼板表面之 油分之情形的反覆清潔性之清潔性評估。作為清潔性之評 估基準，若敎後之殘存附著油分量未達45mg/m2則合格。 (5) 起泡性評估 起泡性評估如以下之方式進行。 於25 mm驗管中填充清潔液1QmI，保持液溫為靴。之 後，以手振蘯試驗管10次，剛靜置後之清潔液與泡高之她 體積作為初期泡高加崎估。又，將詞。⑽持該試驗管; 分鐘後之同樣的清潔液與泡高之體積作為靜置^鐘後之 泡高。作為起泡性評估之基準，若初期泡高（初期起泡性） 為：：1以下，且靜置1分鐘後之泡高(消泡性)為11㈤以下 則合格。 1 93358.doc -27- 1247798 實 施 例 7 實 施 例 8 實 施 例 9 清潔劑組合物{ 重量%} 烷基糖苷υ(平 碳數 11.3) 2-乙基己基甘 油醚 烷基糖苷/甘油 醚之重量比 j烯烴(C12) 乙二醇2-乙基 _己基醚 五¥"檬烯 氫氧化鈉 水 0.3 0.4 0.3 實 施 例 10 0.15 比 較 例 4 比 較 例 5 0.6 0.5 0.1 2 96.5 0.5 0.4 0.2 0.8 0.1 2 96.2 0.75 0.10.2 0.75 0.05 0.1 2 96.25 0 比 較 例 6 0.40.60.66 比 較 例 7 0.4 0.50.8 2 96.75 特性評估 鋼板清潔性 (mg/m2) (無污垢清潔 液） 鋼板清潔性 (mg/m2) (疑似劣化清潔 液） 初期起泡性 —(mL) 消泡性(1分鐘 後)(mL) 97 11.3 15.6 13 12 12 15 83 2 "^97" 220 2 9634" 0.1 962 10 14.2 20 14 15 11 35 150 260 12 18.7 11 10 23 23 13 25 20 10 21 131247798 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD The present invention relates to a hard surface cleaning composition, and more particularly to a precision part, a metallurgical tool, a metal, a glass, a ceramics, a plastic, etc. The removal of the dirt component on the surface of the hard member (hereinafter, also referred to as the hard f surface) and the rinsing property of the cleaning agent having a high safety and high safety, and the cleaning of the detergent composition using a cleaning agent composition The method of hard surfaces. [Prior Art] Previously, the grease, mechanical oil, cutting oil, lubricating oil, liquid crystal, rosin and other organic substances on the surface of hard parts such as metal tools and parts used in precision parts or assembly processing were used as the main body dirt components. For the removal, a gas solvent such as trichloroethane or tetrachloroethylene or a fluorine gas carbide solvent such as trichlorofluoroethane is used, and a surfactant or a builder is added to sodium orthosilicate or caustic soda. Initiative cleaner for the agent 'low boiling point hydrocarbon solvent, etc. However, chlorine-based and fluorine-carbon carbide-based solvents have problems in terms of safety, toxicity, working environment, and environmental pollution, and in the case of use of an in-progressive cleaning agent for precision parts, if they remain on the surface of the cleaned up There are concerns about adverse effects on plastic parts, etc., and the motor and electronic parts have a very bad influence on the electrical characteristics. In order to solve this problem, for example, a detergent composition containing an alkyl glyceryl ether and octadecane and/or water (Japanese Laid-Open Patent Publication No. Hei 6-346〇92), a detergent composition containing a decyl polyglycoside is disclosed. A liquid detergent composition containing an alkyl glycoside or an alkyl polyglyceryl ether (Japanese Patent No. 93358. doc I247798, Kaiping No. 3-m496), etc. However, such a cleaning agent combination cannot be confirmed. The material is sufficiently satisfactory in terms of rinsing property or the repetitive cleaning property required for the cleaning agent for J1. Mainly, as a cleaning method using the detergent composition, firstly, as a liquid solution of the ice step mi detergent Or the water-diluted detergent solution is cleaned, and then rinsed with water as a rinsing step, and then the drying step is a general cleaning method. Furthermore, the precision of precision parts has been improved recently, the unevenness is very large, and the recess gap is also very narrow, and productivity The step-by-step improvement of the cleaning step is also a tendency to shorten the steaming time. Especially regarding the removal of liquid crystal dirt, accompanied by the thin film of the liquid crystal display panel. The gap interval between the liquid helium 7L pieces becomes narrower, and the cleaning of the liquid crystal existing between the gaps becomes more difficult. For the (4) liquid crystal dirt, the use of the composition as described above, even if it exists on the surface The 'month of liquid crystal: good sex, and the cleanliness of the liquid crystal existing between the gaps is not sufficient. 2######################################################################### The solubility of the dirt (especially the (four) gap of the (four) dense parts, the dirt attached to the recess), the removal of the car, and the cleaning of the car, and the washing agent does not require time. Another = face, metal, glass, ceramics The clearing of the surface of hard components such as plastics has been widely used in the field of inspective detergents in the past. A Jiang Gusheng, more test, the main "^ is like the spring, and the more is the rise from room temperature. High cleaning. For example, in the case of continuously cleaning the steel sheet '1 in the iron-making material, the cleaning equipment is usually a continuous cleaning roll of the steel 93358.doc 1247798 plate (steel strip), which is operated at a speed of about 30_1100 m/min. The cleaning time of the steel plate is extremely short time of up to several seconds. Therefore, in the case of a cleaning agent for steel sheets, in general, in order to remove oil adhering to the surface of the steel sheet in a short time, the temperature of the cleaning agent is usually 60 to 80 °C. However, from the viewpoint of economy, it is desired to find a cleaning agent which can maintain the cleanliness at a high temperature even if the cleaning temperature is lowered. An alkaline detergent composition containing a polyglyceryl ether type nonionic surfactant and an alkaline agent is disclosed as a hard surface cleaning agent composition as described above (Japanese Laid-Open Patent Publication No. Hei 5-194999), and contains glyceryl ether and anthraquinone. An alkaline detergent composition of a hydrocarbon, a surfactant, and an alkaline agent (Japanese Unexamined Patent Publication No. Hei No. Hei No. Hei No. Hei. However, such detergent compositions are insufficient in terms of low-temperature (below 5 Å) and reversible cleaning properties, low foaming properties, and the like under short-time cleaning conditions. SUMMARY OF THE INVENTION The subject matter of the present invention relates to [1] a hard surface cleaner composition comprising an alkyl glycoside, a glycerin scale, an olefinic hydrocarbon and/or a paraffinic hydrocarbon, and water, [2]. A method of cleaning a hard surface is to use the above π] detergent composition. [Embodiment] The present invention relates to a hard surface cleaner composition and a cleansing of a hard surface using the /month detergent composition, which is clean! The composition can be used in common for various soils on a hard surface, and has good solubility and removability, and in particular, it can greatly improve the safety of the rate-determined flushing and environmental pollution, and has high safety. 93358.doc 1247798 1 cleansing agent composition (hereinafter, simply referred to as detergent composition) is characterized by containing a burntose, a glyceryl ether, a lanthanide and/or a chain-burning hydrocarbon and water and using Related ingredients. In particular, it is a major feature of the present invention that the insoluble water-based hydrocarbons and/or the chain-burning hydrocarbons can be dispersed in a high water-containing region by combining the base sugar and the glycerin. Therefore, even if the high water content can dissolve and remove the oily dirt existing on the hard surface, the cost of the cleaning agent can be greatly reduced, and the smelting property is not required to be strictly controlled compared with the previous cleaning agent, so the operation becomes changed. For the sake of ease. Moreover, the water-based detergent which contains the first smoke is white turbid due to the cleaning component attached to the object to be cleaned being brought into the rinsing tank, and ◎ the load at the time of rinsing when the cleaning component is washed away, but the load of the present invention is large. The detergent composition's can also stably disperse hydrocarbons due to high water content, so even if it is diluted, it is transparent, so that the load of the rinsing step after cleaning can be greatly reduced. Further, it has been found that the liquid crystal existing between the gaps of the liquid crystal element can be cleaned, and in particular, the liquid crystal dirt existing in the narrow liquid crystal element between the gaps where cleaning is difficult is also clean. The cleaning agent of X' prior is to wash away the residual cleaning component in the interstitial space, and the load during rinsing is large, but by using the detergent composition of the present invention, rinsing becomes particularly easy. Further, as described later, the present invention can be used in combination with an alkaline reagent at a specific ratio of an alkyl glycoside to a glyceryl ether, thereby not only lowering the surface tension but also improving the penetration and dissolving power of the oil stain, compared to the alkyl glycoside alone. Maintain the emulsifying power and ease of rinsing of alkyl glycosides. 93358.doc 1247798 Thereby, the detergent composition of the present invention can effectively remove oil in a very short time at a low temperature, and seeks an industrial detergent which is repetitively clean or low foaming, especially in a very short time. It is useful in the field of detergents for steel sheets such as steel sheets. Further, the detergent composition of the present invention also has a sufficiently hard surface π 4 performance at a low temperature of more than 50. The high temperature also has better performance than the previously unknown detergents. In addition, the surface of the hard surface of the hard surface is a precision part, a metallurgy, a glass, a pottery machine, a plastic, etc., and the cleansing agent composition is attached to the hard surface. Various liquid crystals, oil components, slag formation (when it is produced during welding), etc. (4) are used as cleaning targets. The alkyl glycoside used in the present invention is represented by the following general formula (1): R1(OR2)XGy (1) wherein R1 represents a linear or branched chain having 8 to 18 carbon atoms, an alkenyl group, or一 苯基 r 表 一 r r r r 2 2 2 r r , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , Medium, preferably 0-2, more preferably 〇. γ is preferably 丨15, more preferably ^1·4. The carbon number of R1 is preferably 9_16, more preferably 疋10 14 in terms of self-cleaning property. The other 'X and y were obtained by proton (1H) NMR. The sugar is as long as it satisfies the above formula (1), and is not particularly limited. For example, from the viewpoint of obtaining high cleanability, it is preferably a thioglycoside, an eleventh glycoside, a myristyl glycoside, or the like. . As the content of the bitter sugar, it is preferably 0.01. 93358.doc 1247798 Dong%% of which, when cleaning the hard surface of the Niukou tool type, it is obtained from the poem h. The two flushing aspects are tested in terms of weight. /. It is better that the K50 is heavy and the content of sugar is better. It is especially good that the weight of 2_4 〇 is 5-30% by weight. Lili. , especially when cleaning metal, broken glass, temple sign θ "(4) stealing, plastic and other hard surfaces, it is better to use alkyl glycoside and alkaline gas to make the flat and light aspect of the test, as ^; = ° ° ' Since the higher rinse number is obtained as the content of the & base, it is preferably GI 2g wt%, = .02-10 wt%, particularly preferably 〇〇3_5 wt%, particularly preferably 疋0.04-3 wt%甘油 作 , , 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油 甘油The county is, for example, preferably and has 2 or 2, in particular, having i selected from, for example, n-butyl, isobutyl, n-hexyl, isohexyl, n-heptyl, n-octyl, 2-ethylhexyl, A fluorenyl group having a carbon number of 4 to 12, such as a fluorenyl group having a carbon number of 4 to 12, in particular, an alkyl group having a carbon number of 5 to 1 (and a carbon number of 5 to 8). Further, as the glyceryl ether used in the present invention, the glyceryl group is 2 The above 'better is 2·3 glyceryl groups to be connected to the single-base diglycerin shunt or single-yard polyglycan (four). Especially from the liquid crystal In view of the fact that the cleansing property of the scale is good, it is preferably a monoalkyl glyceryl ether or a monoalkyl diglyceryl ether. These may be used singly or in combination of two or more kinds. In the present invention, It can stabilize the dispersibility of the organic solvent and water, so it has the advantage of obtaining the strong oily dirt and/or the cleanliness of the liquid crystal dirt which is more serious. Especially good glyceryl ether 2-ethylhexyl glyceryl ether. 93358.doc - 11 - .1247798 The content of the glycerol ether is preferably 〇〇2_ rib% by weight in the detergent composition. Among them, when the precision surface of the precision parts and the hard surface of the tool are cleaned, the self-stabilizing hydrocarbon and water are dispersed. In view of high cleanliness and rinsing properties, the content of glycerol ether is preferably 〇·2_8〇% by weight, more preferably 5·5_5〇 weight °/〇, especially preferably 1-30. % by weight, particularly preferably 2% by weight. When cleaning hard surfaces of metals, glass, ceramics, plastics, etc., it is preferable to use an inspecting agent. In this case, self-improving the permeability to oil and dirt Consider, as the content of glyceryl ether, it is preferably 〇2_4〇% by weight, more = 〇.〇3_2〇% by weight, particularly preferably G.G5_1G% by weight, especially good 疋0.1-5% by weight. In the detergent composition of the present invention, burnt sugar The weight of the oil refining crucible is preferably 0.25-10. Among them, 'when cleaning the hard surface of the precision parts and the metallurgical tools, the weight of the daddy sugar/glycerin is better than the foaming property when suppressing the cleaning. 10 or less, and since the stable dispersion of smoke and water, it is better to be above. Therefore, the weight of the yard-based sugar correction oil is better than M0, more preferably 3-8, especially good 3_6. When a hard surface such as a metal, a glass, a ceramics or a plastic is used, it is preferable to use a reagent. In this case, the weight ratio of the appearance base (four) / Gan (four), from the side washability and rinsing properties, the washability side is considered to be 'better than 4, and the self-sustaining chargeability is preferably 〇·25 Bu m, 曰. Therefore, the weight of the alkyl glycoside/glyceryl ether is preferably 〇·25_4 , more f疋〇·3-3, and particularly preferably 〇·4-ΐ. The hydrocarbons used in the present invention are thin smoke and/or chain burned hydrocarbons. 93358.doc -12- .1247798 The olefin-based hydrocarbon and the paraffin-based hydrocarbon are preferably a carbon number 〇, and a compound of the two, for example, a brothel, a twelfth burn, a +4; Isooctane, decene, dodecene, tetradecene, hexadecene, a saturated or unsaturated hydrocarbon solvent of a straight or divalent chain of eight carbon materials; a ring of ring 癸=cyclododecene An alicyclic hydrocarbon solvent such as a compound. Preferably, the carbon number is 1 (M8, preferably a saturated or unsaturated hydrocarbon of a linear or divalent chain of (10) 4' is more preferably an olefinic hydrocarbon. The second may be used alone or in combination of two or more. In addition to the above-mentioned olefin-based hydrocarbons and key-burning hydrocarbons, an aromatic hydrocarbon system such as mercaptobenzene, deca-alkane, an alkyl group-depleted alkylbenzene, methylnaphthalene or dimethylnaphthalene compound may be used. The detergent composition of the present invention φ Λ aa w and σ is preferably contained in an amount of from 0.005 to 80% by weight as the hydrocarbon. π: When cleaning a hard surface of a precision part and a metallurgical tool, Considering the rutting degree of the rut, the above hydrocarbon content is preferably 〇. 1, wt% 'especially 0.5-50% by weight, white base θ, 丄ν, and also the main self-cleaning oil For the sake of rinsing and rinsing, it is preferably 1_2 〇番吾〇/,®丨, “疋丄川重里/〇, more preferably 4_2〇重量〇/〇, which is 5-20 weight. 。 f Clean metal When a hard surface such as glass, pottery, or plastic is used, it is preferred to use an alkaline reagent in combination. In this case, as an olefin-based hydrocarbon The content of the paraffinic hydrocarbon is preferably 0.005, and the weight % is more preferably 〇〇·8 wt%, particularly preferably 0.02-, from the viewpoint of improving the permeability to the oil stain and suppressing the foaming property. 5% by weight. The water used in the present invention is not particularly limited. It is exemplified by sub-exchange water, pure water, deionized water, etc. as water content, Preferably, the main pot, the main rabbit, and the four doses of the composition are 5 - 9.9.8 wt%. The amount of the second amount == and the hard surface of the metallurgical tool: Yes == (4) Weight. /., particularly good 1 1G·95% by weight 'particularly good is % by weight. 疋50·90% by weight, particularly preferably 60-90 gt; when it is hard surface of metal, glass, plastic, etc., it is preferably In this case, as the water content, from the viewpoint of reducing the drainage load at the time of use and concentrating the cleaning liquid, it is preferably 5.99.8% by weight, and particularly preferably 10 to 99.5% by weight. In the present invention, as a preferred combination of a burnt glycoside, a glyceryl ether, a terpene hydrocarbon, and/or a (tetra) hydrocarbon, the alkyl group (four) is Mercapto saccharide and dodecyl glucoside, glyceryl ether is 2-ethylhexyl glyceryl ether and hexyl ganyl / acetylene hydrocarbon and / or paraffinic hydrocarbon are selected from the group consisting of terpenes and twelve carbons And tetradecene, decane, dodecane, and tetradecane. Further, the detergent composition of the present invention preferably contains an alkaline agent from the viewpoint of obtaining higher cleanability. The alkaline reagent may be any one of water-soluble alkaline reagents. Specific examples thereof include hydroxides of alkali metals such as sodium hydroxide and potassium hydroxide, sodium ortho-sodium citrate and meta-antimony acid. Sodium citrate, sodium sesquisulfate (for example, sodium citrate No. 1 , sodium citrate No. 2, sodium citrate No. 3 ), sodium citrate, disodium hydrogen phosphate, trisodium phosphate, pyrophosphate Phosphate such as sodium, sodium tripolyphosphate or sodium hexametaphosphate, disodium carbonate, hydrogen carbonate 93358.doc -14- .1247798 sodium, carbonated bismuth bromide - 'A, carbonate of hydrogen hydride, boric acid Borate such as sodium. It can be combined with two records, one for the use of water-soluble alkaline reagents. These alkaline reagents are good for sodium oxide, hydrogen peroxide, sodium sulphate, and sodium sulphate. For the content of the alkaline agent in the detergent composition, it is better to maintain the higher cleaning/Chenqin q clean liquid. It is preferably 〇•卜5〇% by weight, more preferably 0.1-10重晋〇/々 Pu 0 uy, preferably 0. 2-8 wt%, particularly preferably 0.5-5 wt%. When an inerting agent is used, especially in the case where the oil adhered to the surface of the steel sheet (steel strip) is continuously cleaned, it is preferred to use a chelating agent and/or a water-soluble polymer to retard the acid. The cleansing agent composition of Taiben Mingming can be further improved by using an integrator together: the chelating agent used for sputum gluconic acid, heptose saccharide, etc. An amine-based acid retardant such as ethylenediaminetetraacetic acid, a sulfonic acid such as citric acid or malic acid, an amine trimethylene phosphonic acid, a bisulphate such as an ethylidene diphosphonic acid, and the like. A metal salt, a lower amine salt, an ammonium salt, a melamine salt, etc., particularly preferably sodium gluconate, sodium glucoheptonate, sodium edetate, sodium citrate, sodium hydroxydiphosphonate. The content of the chelating agent in the detergent composition of the invention is preferably from 0.01 to 15% by weight, particularly preferably from 0.05 to 10% by weight, in terms of self-cleaning property and economy. The detergent composition of the present invention can be dissolved by adding water. The polymer is acid-suppressed, and the storage stability or the cleaning performance is further improved. The water-soluble polymer M used in the present invention may, for example, be a compound represented by the general formula (7). 93358.doc 15 1247798 [Chemical Formula 1]广Γ—Π π — ? V R3 m C'— 〇—-- , 1 1 COOM” [ Wherein, rLr6 is the same or different and represents a hydrogen atom (2) an alkyl group having 1 to 5 carbon atoms, an alkoxy group having 1 to 5 carbon atoms, c〇〇M, i〇H, M represents a nitrogen atom, a metal test, The alkylamine having 1 to 4 carbon atoms, the alkanolamine of i carbon number, 6 and the other are the molar numbers of the constituent units in the parentheses, and the m/n (mol ratio) is 0/10-10/ 1] The group at both ends of the general formula (2) is not particularly limited, and examples thereof include a hydrogen atom, an OH, a carbon number of -5 alkyl groups, a carbon number of 丨5 alkoxy group or S. 〇3M (M is the same as above), etc., the groups at both ends may be the same or different. m may also be 0. Further, the weight average molecular weight (Mw) of the compound represented by the general formula (2) is 1,000- 100,000, preferably 3,000_5 〇, 〇〇〇, particularly preferably 5,000-20,000. The polymerization form may be a block or a random. As a specific example of the water-soluble polymer carboxylic acid represented by the general formula (2), Examples of the acrylic acid homopolymer, the acrylic acid-maleic acid copolymer, the c-based acrylic acid homopolymer, the C5 olefin-maleic acid copolymer, the isobutylene-maleic acid copolymer, and the like The alkali metal salts or A salt or the like is preferably an acrylic acid homopolymer or an acrylic acid-maleic acid copolymer, and two or more kinds of water-soluble polymer carboxylic acids may be used in combination. The water-soluble polymer carboxylic acid in the detergent composition of the present invention. The acid content, from the soft hydration properties of water, cleanliness and low COD (chemical oxygen demand), is preferably 0.05-1% by weight, especially 93358.doc -16-1247798 = good 〇·(4)% by weight. When it is made of q or more of q, when the water having a high hardness such as water is used, the effect of the fatty acid or the magnesium ion mixed with the fat is poor. (4) water-insoluble salts, and may be used to suppress the foaming property of the cleaning liquid in the cleaning agent composition to reduce the viscosity of the cleaning liquid, and then reduce the cleaning after cleaning [hereinafter referred to as preparatory washing] The drainage load is better than the addition of people. As for H ^, there are listed: ethylene glycol monoalkyl (carbon number M2 (four), diethylene glycol singular M, triethylene glycol monoalkyl (carbon number training, ethylene glycol benzene ^ yiyizhi methyl ether) a single-alkyl (intermediate 1-12) bond of ethylene glycol phenyl ether, propylene glycol or dipropylene glycol, and a single-base (carbon number) ether of a dialkyl diol (carbon number 2_12), preferably ethylene glycol. Monohexyl hydrazine, ethylene glycol mono 2-ethylhexyl sulphide, bis- butyl butyl mystery, diethylene glycol monohexyl hydrazine, diethylene glycol mono-2-ethylhexyl ether, triethylene glycol hood ^ 咚 early butyl ether, dipropylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol dibutyl ether 'cleaning of the drainage load of the rinse liquid disclosed in the 2W newspaper of the patent The method (hereinafter referred to as 'oil-water separation method') is particularly preferable to diethylene glycol hexyl ether, diethylene glycol mono-2-ethylhexyl sulfonate, dipropylene glycol monobutyl bond, diethylene glycol dibutyl ether. In addition, the use of the test reagent, in order to improve the permeability of the money and inhibit the foaming of the cleaning liquid, especially good ethylene glycol mono-2-ethylhexyl Diethylene glycol mono-2-ethylhexyl ether. These glycol ethers may be used singly or in combination of two or more. As the content of the diol oxime, it is preferably 〇〇1-4 〇 in the detergent composition. 93358.doc -17- 1247798 %. Among them, cleaning precision parts and metallurgical tools _ # /, Lai, as a diol person, the point of self-cleaning agent is above the thief 'cleaning at high temperature: oil and water separation method It is preferable that it is 0.01 to 40% by weight, more preferably 2% by weight, particularly preferably 0 to 25% by weight, and 0 is preferably 0.5 to 20% by weight, preferably 0.5 to 15% by weight. In the case of hard surfaces such as glass, ceramics, plastics, etc., it is used in combination with the test agent. In this case, as the content of the diol oxime for the permeability of the oil stain and the suppression of the foaming property, it is: 0.02-40% by weight, more Preferably, 〇〇3_2〇% by weight is preferably 0.04-10% by weight, particularly preferably 0·04_5 by weight 0/〇. Further, the detergent composition of the present invention may be added as needed. a solubilizing agent for separating the agent, or making the appearance of the cleaning agent white suspension The dissolving agent is used for the separation of the detergent composition. The solubilizing agent used in the present invention is exemplified by the fatty acid and its dish, and the sulfuric acid ester and its salt, and the body is ^ n ^ , phoenix, body • 6-18 alkenyl amber and its salts, caproic acid, heptanoic acid, octanoic acid, hexamethylene phthalate, lauric acid, butyric acid, pentamidine, isobutyric acid, 2-ethylhexanoic acid and The salting agent used in the present invention may, for example, be a water-soluble polymer, or a dicarboxylic acid, naphthalene diterpenic acid or phthalic acid, or a metal salt or an amine salt thereof. Further, in the detergent composition of the present invention, an antifoaming agent which suppresses the generation of bubbles by the cleaning step is added, for example, a polysulfide, an omega alcohol, a high-grade fat bismuth and a salt thereof, and Pluronic. Copolymerization m "Larnik type copolymer, polyethyl 93358.doc 1247798 diol, polypropylene glycol and the like. The case of the detergent composition of the present invention is provided without any particular limitation, and the glycerol ether is considered from the viewpoint of obtaining better product stability and piping. Preferably, W is still %, more preferably 〇·5:5 wt% 'burning base (four) is preferably GI2G wt%, more preferably 0.5-5 wt 'women's warfare and/or chain burnt smoke better. It is 0.05-20 weight. /. , more sub = 0 · 1 5 wt%, glycol ether is preferably 〇, 卜% by weight, more preferably, the % test is preferably (9) wt%, more preferably 15_45 wt%. Preferably, the hydrazine or hydrating agent is 〇〇5·4 〇% by weight, more preferably the weight is 3 chelating agent, preferably 〇·卜20% by weight, more preferably 〇重里% detergent The composition may be stable without the use of a solubilizing or slurrying agent. The cleansing hemp of the present invention can be suitably used as needed in the usual detergent composition, preservative, rust preventive, and polypyretic, without damaging the effects of the present invention. The detergent composition of the present invention having a fine structure can be produced by a component according to a constant == component and an optional component. For example, the mixing and mixing furnace 2:: the above-mentioned glyceryl ether 'the above-mentioned olefin-based hydrocarbon and/or alkane-based: 丫" may be prepared by mixing other optional components as needed, and finally adding water, thereby producing the same. The detergent composition is preferably used as an aqueous medium such as a cleansing agent. The detergent composition of the present invention can be applied to the surface of a hard material such as a clean precision part, a slab of a ceramic, or a plastic. 93358.doc -19- 1247798 To know how to clean. For example, the cleaning step is carried out by using a liquid diluted with the stock solution of the detergent composition of the present invention or water, followed by a rinsing step, a drying step, and cleaning of the object to be cleaned. Accordingly, the present invention relates to a method of cleaning a hard f surface using the above detergent composition. The physical force of the x ', the cleaning step, and the rinsing step is not particularly limited, for example, the so-called single or combined dipping method, the ultrasonic cleaning method, the dipping shaking method, the early electrolysis/month cleaning, the hand wiping method, and the like are well known. Cleaning methods Cleaning conditions such as cleaning temperature can also be a common practice. It is preferably from normal temperature to 90. 〇 The following m materials are, for example, 80t or less. Below C, it is considered that the evaporation of water is particularly good. This is a cleaning composition of the present invention. When cleaning gold ceramics, plastics, etc. at low temperatures, it is especially good, glass, "clean, that is, impregnated and clean, sprayed steel. The effect can be exerted in the middle of the process. "The cleansing agent composition of 'Mengjie, Electrolytic Cleaner, etc. can also be cleaned by the oil-water separation method of the load. _ rinse of the rinsing liquid, wherein the detergent composition of the present invention is used in the process step: "the cow and its assembly plus the shell / the spring of the month has +, gans 2, the precision parts in the invention refers to For example, electronic parts, machine parts, resin parts, optical parts, etc., electronic parts, such as body package, printed wiring board, IC wire, ceramic panel, semi-conductive material, crystal vibrator. Metal parts, such as bearings used in semiconductor moving machines such as boards, for example, 938.5.doc -20. 1247798 plastic-processed products for precision-driven electronic or battery squat containers or cans. Engines are listed as follows: For the resin-processed products, for example, the precision of the materials used in the study (1) can be used to clarify the parts. For the light-receiving parts, for example, The lens of the ergonomic glasses and the smelting tool used in the upper assembly process, the manufacturing, processing, assembly, and turbidity of the precision parts such as the case. The tools and tools used, and also the various machines, parts, etc. for operating such precision parts. ^The detergent composition of the 'specially for the liquid crystal panel mentioned above: leakage liquid crystal dirt, semiconductor package, printed wiring The refractory oil adhering to the surface during the plastic working of the processing oil and metal parts adhered to the surface after the cutting of the stone stalk and the metal slab is highly clean, and the ren is the precision part of the cleaning object of the present invention and The smelting tools are not the case of "Yu Hai", etc., if they are attached to various processing oils in the assembly process, liquid crystals, or harmful substances in the subsequent steps, or various oil-like pollutants that reduce the sex of the products. The detergent composition of the present invention can be applied to a precision part of an individual surface having a certain shape and a sifter. Further, the detergent composition of the present invention is particularly effective when the pollutants are, for example, oils and fats, mechanical oils, cutting oils, and lunar rains, which are mainly oleaginous slag, liquid crystal, petroleum pitch, and the like, which are mainly organic oil scales. It also has high cleanliness for dirt in which metal powder, inorganic powder, moisture, and the like are incorporated. EXAMPLE 93358.doc -21 - 1247798 Hereinafter, the aspect of the present invention will be further disclosed by way of examples. This embodiment is merely an example of the invention and is not intended to be limiting in any way. <Preparation of test substrate> A TFT (thin film transistor) liquid crystal was sealed in a gap between liquid crystal elements (the distance between the gaps was 5 μm), and was allowed to stand at room temperature for 30 minutes as a test substrate. Examples 1 - 6 and Comparative Examples 1 - 3 The components of Examples 1 to 6 and Comparative Examples 1 to 3 were prepared by mixing and mixing the components as shown in Table 1. In the prepared cleaning agent composition, the ultrasonic cleaning (39 kHz, 200 W) test substrate was carried out for 10 minutes, and then washed in a pure tank of 4 tanks (4 (rc) for 3 minutes, at 90 °C). The sample was dried in a hot air dryer for 30 minutes, and the sample was observed. [Liquid crystal cleaning evaluation method] The liquid crystal remaining in the gap of the liquid crystal element after cleaning and the liquid crystal which was not sufficiently discharged during the cleaning were observed with a polarizing microscope (magnification: 25 times). The cleanliness of the liquid crystal panel was evaluated by a mixture with the detergent composition. The liquid crystal cleanability evaluation is expressed by subtracting the total area of the liquid crystal and the residual portion of the mixture of the liquid crystal and the cleaning agent from the entire area of the observed gap, divided by observation. The value of the total area of the gap. In addition, the evaluation criteria are as follows: [Liquid crystal cleanliness evaluation standard] ◎ : 90% or more 80: 80 - less than 90% △ : 40 - less than 80% X : less than 40% ( Repeated cleanliness) 93358.doc -22- 1247798 To evaluate the reproducibility of the cleaning solution, investigate the saturated dissolved concentration of the liquid crystal. Add TFT liquid crystal 〇_〇2 g to 20 g of the detergent composition kept at 40 ° C. C under warranty 3 minutes. In this state, confirm the state of the solution. If it is transparent, judge that it has dissolved. 'Repeat the same operation. Repeat this operation, and calculate the saturated dissolved concentration by subtracting the amount of 液晶·〇丨g from the amount of liquid turbid liquid from the cleaning liquid. It is defined as the saturated concentration of liquid crystal. For example, if the white turbidity begins to appear when TFT liquid crystal 〇·24 g is added, the saturation concentration of liquid crystal is calculated as (0.24-0.01)/(20+0.24-0.0l)x 1〇〇. The liquid crystal saturation dissolved concentration was evaluated based on the following evaluation criteria. 〆, [Repeat cleanliness evaluation criteria] ◎ : 2% or more 〇: 1% or more · less than 2% △ : 0.5% or more · not up to ι〇 /0 x : less than 0.5% (flush water evaluation) To evaluate the state of the rinse water, prepare a 5 wt% aqueous solution of each cleaning solution as a preliminary rinse solution, and prepare a 5 wt% aqueous solution for each cleaning solution as a rinse solution. 60 <t The state of the pre-flush and the rinse solution was evaluated under t, and the rinse water was evaluated. (Evaluation of rinsing property) 1. Dip 18 glass panels (35 x 48 mm) for 10 minutes in a cleaning solution (60 〇1% by weight of an aqueous solution (10) g). • After the ffi20 moves the lifting panel, there are 6 加入 added.浸 Pure water lake g 93358.doc -23- 1247798 The first rinse tank was dipped (2 minutes). 3. Lift the panel in the same manner and immerse it in the second rinse tank containing 5〇g of pure water (2 minutes). 4. Then, in the extraction tank (ultrasonic tank) which was kept at 70 Torr of pure water, the detergent component which was deposited on the surface of the panel was extracted by ultrasonic waves (38 κ Ηζ, 4 (8) w) for 10 minutes. 5. Then, the TOC (all organic carbon meter) was used to measure the oil removal rate of the first rinse tank in each of the rinse tanks (the i-th, the phantom rinse water, the radon ultrasonic tank extract # water organic matter concentration, and the reduction formula). The oil removal rate (%) of the first rinse tank = (the organic matter weight of the first rinse tank) / (the organic matter weight of the first rinse tank + the organic weight of the second rinse tank + the organic weight of the ultrasonic tank) X 100 The oil removal rate of the first rinse tank was evaluated as follows. ◎ • The oil removal rate of the first rinse tank was 9% or more. 油 The oil removal rate of the first rinse tank was 7〇% or more _ less than 90〇/ 〇△ • The oil removal rate of the first rinse tank is 5〇 or more _ less than 70〇/〇X: the oil removal rate of the first rinse tank is less than 50%. 93358.doc -24- 1247798 [Table i]实 实 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比11.3) Alkyl glycosides 2) (average carbon number - - - - 12 - 40 - - cleaning 10.2) 2-ethylhexyl 5.3 4 2.7 4 3 5 10 glycerol ether amyl glycerol shout - - - - - - - 25 40 combined alkyl glucoside / mouth glyceryl ether weight 4 4 4 6 4 4 - - one N Specific gravity ce-hydrocarbon 13.3 10 6.6 10 5 15 • 5 King (C12) Diethylene glycol monoterpene hexyl ether 0 Triethylene glycol mono 2 butyl ether water 60 70 80 70 80 50 60 50 40 Polyoxidation Vinyl ether ether-5 (HLB = 13.0) Liquid crystal cleanliness ◎ ◎ ◎ ◎ ◎ ◎ XX Δ ll 士 清洁 清洁 ◎ ◎ ◎ ◎ ◎ ◎ XX 〇 . k k k 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备 预备State clearly and clearly turbidity and clear turbidity 5 dry / J- rinsing liquid shape g permeable transparent permeable white 1 stone state clearly clear and clear turbidity evaluation ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 Δ 1) general formula ( 1) 中χ=〇, y=l.3 2)—In the general formula (1), χ=0, y=1.3 In the first embodiment of Table 1, the flushing water and the rinse water are both transparent and flush. Evaluation is also , The solubility of the liquid crystal is higher, so the gap between the cleaning is determined, and a liquid crystal mixture without the composition of the cleaning agent, having a relatively high liquid 93358.doc -25- 1247798 cleanability. Further, in the sixth embodiment, the detergent composition which can be subjected to the oil-water separation method is shown. Although the preliminary rinse water is cloudy, the rinse water is transparent, so that the cleansing component can be sufficiently washed. On the other hand, in Comparative Examples 1 and 2, although the rinse water was illuminating, since it did not contain hydrocarbons, there was no liquid crystal solubility, and the liquid crystal cleanability was low. Therefore, in the industrial detergent which is repeatedly cleaned with the same cleaning liquid, the cleaning liquids do not have sufficient performance. Further, although Comparative Example 3 contained a hydrocarbon, it had liquid crystal solubility, but the washability was inferior, and as a result, the liquid crystal cleanability was lowered. Examples 7-10 and Comparative Examples 4-7. As shown in Table 2, the components were added and mixed, and the detergent compositions of Examples 7-10 and Comparative Examples 4-7 were separately prepared (residual amount of deionized water) The steel sheet cleaning test was carried out by the following method to evaluate the cleanability, foaming, and defoaming properties of the steel sheet. The results are shown in Table 2. _ <Steel plate cleaning test> (1) The steel plate to be cleaned is cold-rolled to a thickness of 〇·5 mm, and the steel plate of 350 ❿ mg/m2 is cut to a length of 50 mm>^f25 mm. Production. (2) The suspected deterioration cleaning liquid is prepared in the detergent composition in an amount of 1% by weight to the detergent composition. The iron residue extraction oil obtained by extracting the iron residue deposited on the calender from the calender is extracted with hexane. Stir thoroughly to prepare the suspected deteriorating cleaning solution. (3) Cleaning and rinsing methods in the detergent composition (cleaning agent without dirt) and the suspected deterioration of the cleaning solution '1' of the electrode plate 1 mm1 horizontally and 50 mm horizontally (electrical 93358.doc - 26- 1247798 The distance between the plates is 20 mm) and the cleaned steel plate is dipped at the center for i seconds, then the plate potential is switched from positive to negative at a current density of 10 A/dm2, respectively, with a current of 0.5 seconds. Electrolytic cleaning. Then continue to spray from the nozzle 1 〇 cm (water temperature 2 〇. 〇, water pressure 〇 2 Mpa) seconds, warm air drying. In addition, the temperature of the test cleaning solution is 4 〇 t: (4 ) Evaluation of the cleanliness of the steel plate (measurement method of the residual oil component). For the non-soil cleaning liquid and the suspected deteriorating cleaning liquid, use the steel plate adhesion oil measuring device "face A_(1)" (manufactured by Horiba, Ltd.). The steel plate adhered to the oil component, and the average of the five sheets was used as the measured value, and the cleanliness of the steel sheet was evaluated on the basis of the following criteria. The evaluation using the suspected deterioration cleaning liquid is assumed to be the case where the oil adhered to the surface of the steel sheet is accumulated in the cleaning tank. Cleanability evaluation of repetitive cleanliness. As a basis for evaluation of cleanliness, it is acceptable if the residual residual oil content after the sputum is less than 45 mg/m2. (5) Foaming evaluation Foaming evaluation is carried out as follows. Fill the cleaning tube with 1QmI in the mm tube and keep the liquid temperature as the boot. After that, the test tube is shaken by hand 10 times, and the volume of the cleaning liquid and the bubble height immediately after standing is used as the initial bubble height. In addition, the word (10) holds the test tube; after the minute, the same volume of the cleaning solution and the bubble height is used as the bubble height after standing. As the basis for the evaluation of the foaming property, the initial bubble height (initial foaming property) ) is: 1 or less, and the bubble height (defoaming property) after standing for 1 minute is 11 (five) or less. 1 93358.doc -27- 1247798 Example 7 Example 8 Example 9 Detergent composition { Weight %} alkyl glycoside 平 (flat carbon number 11.3) 2-ethylhexyl glyceryl ether alkyl glycoside / glyceryl ether weight ratio j olefin (C12) ethylene glycol 2-ethyl hexyl ether five ¥ " limene hydrogen Sodium oxide water 0.3 0.4 0.3 Example 10 0.15 Comparative Example 4 Comparative Example 5 0.6 0.5 0.1 2 96.5 0.5 0.4 0.2 0.8 0.1 2 96.2 0.75 0.1 0.2 0.75 0.05 0.1 2 96.25 0 Comparative Example 6 0.40.60.66 Comparative Example 7 0.4 0.50. 8 2 96.75 Characteristic evaluation Steel plate cleanability (mg/m2) (no dirt cleaning liquid) Steel plate cleanability (mg/m2) (suspected deterioration cleaning liquid) Initial foaming property - (mL) Defoaming property (after 1 minute) mL) 97 11.3 15.6 13 12 12 15 83 2 "^97" 220 2 9634" 0.1 962 10 14.2 20 14 15 11 35 150 260 12 18.7 11 10 23 23 13 25 20 10 21 13
W U 一股式（1)中 x=〇、yy 3 根據表2之結果可知u鲁a /丨 札 以實知例7_10所獲得之清潔劑組合 物均比比較例4-7所獲得去相!故 一 又侍者鋼板之清潔性好，為低泡性者。 貫施例11 調製具有表3所示之稀釋 A 4-M^ 、，成之4潔劑組合物（殘量 為去離子水）後，以成為矣一 去雜；之稀釋後的濃度之方式以 去離子水稀釋δ周氣试驗法、、替 ’ W夜。關於該清潔液，盥實施例 7-10同樣進行鋼板清潔試驗， ^ 4估鋼板之清潔性、起泡性、 93358.doc -28. 1247798 消泡性。結果示於表3 基糖苷' 平均碳數 11.3) 2·乙基己基甘油醚 乙一醇2 -乙基己基鱗 ^ ^ (Mw:8000) 鋼板清潔性（mg/m2) __垢清潔液） 鋼板清潔性（mg/m2) 一劣化清潔液） 一 初期起泡性（mL) 鐘後）（mL·)According to the results of Table 2, it can be seen that the detergent compositions obtained by the actual example 7_10 are out of phase with the comparative examples 4-7 obtained by the results of Table 2! Therefore, the waiter's steel plate is clean and has low foaming properties. Example 11 Modulation has the dilution A 4-M^ shown in Table 3, and the 4 detergent composition (residual amount is deionized water), so as to become a deuterated; Dilute the δ cycle gas test method with deionized water, and replace it with 'W night. Regarding the cleaning liquid, the steel sheet cleaning test was carried out in the same manner as in Example 7-10, and the cleanability and foaming property of the steel sheet were evaluated, and the defoaming property of 93358.doc -28. 1247798 was evaluated. The results are shown in Table 3. The base glycoside 'average carbon number 11.3) 2·ethylhexyl glyceryl ether ethyl alcohol 2-ethylhexyl scale ^ ^ (Mw: 8000) steel plate cleanability (mg/m2) __scale cleaning liquid) steel plate Cleanability (mg/m2) - Deteriorated cleaning solution) - Initial foaming (mL) after the clock) (mL·)
0L- ¥烴（C12) 葡萄糖酸鈉 清潔劑 組合物 (重量％) 氫氧化鈉 水 特性 評估 D一般式（1)中 x=〇、y=l 3 一根據表3之結果可知以實施例11所獲得之清潔劑組合物 同，為於鋼板之清潔性較好，低泡性者。 1由使用本發明之硬質表面用清潔劑組合物，對於破質 ^上之各種污垢可共通使用，對於該等污垢具有較好之 解丨生=去性，且可較大改善至今成為速率決定之沖洗 ▲工且•衣=木之危險’可安全性較高地清潔精密零件、 :而奏f麵、_、塑料等之硬質構件之表 金=之== 交適合地用於例如電子零件、 件，將該精密零件製、//零件、光學零件等精密零 t使用之冶具、工農， w 、、’哀、潤飾等之各種步騾 其零件等組裝加 卜操作17亥等精密零件之各種機器、 步料所使用之冶卫具類的沖洗。 93358.doc -29-0L- ¥ hydrocarbon (C12) sodium gluconate detergent composition (% by weight) sodium hydroxide water characteristic evaluation D general formula (1) x = 〇, y = l 3 According to the results of Table 3, it can be seen that Example 11 The detergent composition obtained is the same as the cleanability of the steel sheet and the low foaming property. 1 By using the hard surface cleaning composition of the present invention, it can be used in common for all kinds of dirt on the broken material, and has good deterioration and de-saturation for the dirt, and can greatly improve the rate-determining flushing. ▲Working and clothing=Wood hazard' It is safe to clean precision parts, and the surface of hard parts such as f-face, _, plastic, etc. === Suitable for use in, for example, electronic parts, parts, This precision parts, / / parts, optical parts and other precision parts used in the production of tools, workers and peasants, w,, "sorrow, retouching, and other various steps, such as the assembly of the equipment, such as 17 Hai, and other precision parts of the machine, The rinsing of the swarf used in the step material. 93358.doc -29-