TWI247436B - White light-emitting device - Google Patents

White light-emitting device Download PDF

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Publication number
TWI247436B
TWI247436B TW93111734A TW93111734A TWI247436B TW I247436 B TWI247436 B TW I247436B TW 93111734 A TW93111734 A TW 93111734A TW 93111734 A TW93111734 A TW 93111734A TW I247436 B TWI247436 B TW I247436B
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Taiwan
Prior art keywords
light
blue
red
mixed
phosphor
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TW93111734A
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Chinese (zh)
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TW200536140A (en
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Kuen-Juei Li
Tz-Chi Jeng
Rung-Bin Jeng
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Kuen-Juei Li
Tz-Chi Jeng
Rung-Bin Jeng
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Abstract

This invention relates to a white light-emitting device, which comprises a plurality of blue-light LEDs, a plurality of red-light LEDs, and a phosphor. The blue-light LED emits blue light. The red-light LED emits red light. The phosphor is formed by mixing a green-yellow phosphor and a blue phosphor and may absorb the blue light, such that it is excited to emit a first mixed light with different wavelength from that of the blue light. The red lights emitted by the first mixed light and the red LED are further mixed to emit the second mixed light so as to achieve the main goal of obtaining the second mixed light with good color rendering and color saturation.

Description

螢光體 的藍光 波長的 發出的 合光」 再一目 色螢光 光L E 黃光、 紅光L 「繁一 一·— 再一目 紅光混 為其主 的即在 體、藍 D發出 藍光及 EDS 混合光 的,即 提供一種 色螢光體 的藍光去 紅光等波 出的紅光 」者為其 在k供一The combined light of the blue light wavelength of the phosphor" Another color of the fluorescent light LE yellow light, red light L "Traditional one - another red light mixed with its main, that is, in the body, blue D emits blue light and EDS Mixed light, that is, a blue light that provides a color fluorescent body to red light, etc.

第5頁 域】 一種白光發光裝置,特指一種可得演 供釋出。 置’其典型之範例如·· 業股份有限公司所申請之台灣專利公 號「發光裝置及顯示裝置」專利案, 光源之藍光半導體,籍發射出之藍光 產生不同波長的白光顯現,由於僅具 未被激發的藍光混合,故其演色性 不純。 種白光發光裝置 及藍色螢光體彼 去激發該螢光體 「弟一混合光」,該 合,可得演色性及色彩飽和度 要目的。 1247436 案號 93111734 五、發明說明(1) 【發明所屬之技術領 本發明係在提供 色性佳的第二混合光 【先前技術】 按習知之發光裝 曰本日亞化學工 告號第383508 該案僅利用單一藍色 以激發黃色螢光層, 單一波長的光與部份 差,即;白色光失真 【發明内容】 本發明在提供_ 體是由綠黃色 光L E D發出 綠黃色與藍色 與紅光L E D 佳的「第二混 •本發明的 螢光體由綠黃 合而成,由藍 體被激發出綠 第一混合光與 彩飽和度佳的 本發明的 修正 特指一種藉著螢光 此混合而成,再由藍 使螢光體被激發出 第一混合光」 白光發光裝置,藉著 及紅色螢光體彼此混 激發螢光體,使螢光 長的第一混合光,該 混合可得演色性及色 再一目的。 !247436 ΛΜ 93111734五、發明說明(2) ,發光元件增加設置一 弟一混合光混合,可得 光為其再一目的。 本發明為達上述目 如圖一、二所述係 發明在提供一種白光發 LED1Q ,可發出藍 曰 修正 .至少一 螢光體 彼此混合而 (Aluminate .藍色螢 其致活物為 該螢光 俾可吸收藍 1 5波長不 L E D 2 0 9 0者; 其中螢 發出的綠黃 m之.間(如 藍色螢 定波長介於 該二種 8 0° 個以上的紅 5 0是由綠 成;其中該 )材料構成: 光體5 3由 銪(Eu); 體5 0係被 光1 5,使 同的弟一混 所發出的紅 光體5 0中 光 5 2 1, 圖三所示) 光體5 3被 4 5 0 〜5 綠黃色L E D,其所發出綠黃光與 演色性及色彩飽和度佳的第二混合 的,茲配合圖式詳述如後: 為本發明一較佳可行的實施例,本 光裝置,至少包含一個以上的藍光光1 5 ; 光LED20可發出紅光25 ; 黃色螢光體5 2及藍色螢光體5 3 綠黃色螢光體5 2由鋁酸鹽系 其致活物為鈽(Ce); 紹酸鹽系(A 1 um i nate )材料構成, 覆接於藍光LED 1 〇的上表面, 螢光體5 〇被激發出一種與藍光 合光8 〇,第一混合光8 紅光 光2 5再相混合釋出第二混合光 的綠黃色螢光體5 2被藍光1 5激 其選定波長介於5 0 〇〜r β η 藍光1 5激發出的藍光5 0 0 n m之間; 的光波長組合,以形成第 1其選 混合光Page 5 Field] A white light-emitting device, specifically one that can be released for release. The patent case of the Taiwan Patent No. "Light-emitting device and display device" applied for by the company, the blue light semiconductor of the light source, which emits white light of different wavelengths due to the emitted blue light, Unexcited blue light is mixed, so its color rendering is impure. The white light emitting device and the blue phosphor respectively excite the phosphor "different light", which can achieve the purpose of color rendering and color saturation. 1247436 Case No. 93111734 V. Invention Description (1) [Technical Field of the Invention] The present invention provides a second mixed light with good color properties [Prior Art] According to the conventional light-emitting device, the Japanese Chemical Engineering No. 383508 Only a single blue color is used to excite the yellow fluorescent layer, and a single wavelength of light is partially different, that is, white light distortion. [Invention] The present invention provides a green yellow and blue and red color by a green-yellow light LED. Light LED is good. "Second mixing. The phosphor of the present invention is composed of green and yellow. The blue body is excited by the green first mixed light and the saturation of the color is excellent. The mixture is mixed with blue, and the phosphor is excited to emit the first mixed light. The white light emitting device mixes the phosphor with the red phosphor to make the fluorescent first long mixed light. Color rendering and color can be obtained for another purpose. !247436 ΛΜ 93111734 V. Inventive Note (2), the light-emitting element is added to set up a younger-mixed light mixing, which can be used for another purpose. The present invention provides a white light emitting LED1Q which can emit blue ray correction. The at least one phosphor is mixed with each other (Aluminate) is a fluorescent material.俾 absorbable blue 1 5 wavelength is not LED 2 0 9 0; where the green and yellow of the firefly m. (such as the blue fluorescence wavelength between the two more than 80 ° red 50 is from green The material composition is: the light body 5 3 is made of eucalyptus (Eu); the body 50 is lighted by 5 5, so that the same younger brother is mixed with the red light body 5 0 light 5 2 1, as shown in FIG. The light body 5 3 is 4 5 0 〜 5 green yellow LED, and the green yellow light emitted by it is mixed with the second color mixing and color saturation. In a possible embodiment, the light device comprises at least one or more blue light light 15; the light LED 20 emits red light 25; the yellow phosphor 5 2 and the blue phosphor 5 3 green yellow phosphor 5 2 are made of aluminum The acid salt is composed of cerium (Ce); a salt of a salt (A 1 um i nate ) material, which is coated on the upper surface of the blue LED 1 ,, and the phosphor 5 is A green-yellow phosphor 5 that is combined with the blue light and condensed with the blue light, the first mixed light 8 and the red light 2 5 are mixed to release the second mixed light, and the selected wavelength is between 50 〇. ~r β η blue light 1 5 is excited by blue light between 500 nm; the wavelength of light is combined to form the first selected mixed light

12474361247436

案 5虎 93111734 £、發明說明(3) 依據别述所述主要縣微,4同 心土受符倣,如圖八所示,其中蒂 5 0材料中,:增加一紅色勞光體5工俾與原有的綠‘色 螢光體5 2及監色發光體5 q相、、0人 ^ ^ 踅尤餸D J相混合成;該紅色螢光體 5 1被藍光1 5激發出的紅光5丄丄,其選定波長介於 585〜700nm之間。 依據W述所述主要特徵,其中可增設一綠黃色L E D 30 ’可發出綠黃光35,其選定的波長介於500〜 5 8 5 n m之間(如圖八所示)。 依據前述所述主要特徵(如圖三所示),其中光源為 藍光15,其選定的發光波長介於4〇〇〜48〇1^以之 間,光源為紅光2 5其選定的光波長介於5 8 5〜7 8 〇 n m間。 依據前述所述主要特徵,其中螢光體5 〇中之綠黃 色、藍色及紅色榮光體5 2、5 3、5 1 ,可由下列材料 來選擇單一或組合使用: (1).鋁酸鹽系;(2)·矽酸鹽系;(3).磷酸鹽系;(4). 硼酸鹽系;(5 )·硫化物系。 【實施方式】 ⑴.如圖-所示’藍光LED10及紅光led2〇被裝 置::;射蓋6 〇中,其中藍光L E D 1 0的上表面 , 體5 〇覆接,另外再藉透明勝6 5封裝於 反射盖60的凹槽6",俾以將藍光LED1(^ .= ”20封裝。針對藍光Ledi〇及紅光l E D 2 0施以電極;如圖二所示,冑光l e D工〇合Case 5 Tiger 93111734 £, invention description (3) According to the description of the main county micro, 4 concentric soil is imitation, as shown in Figure 8, in which the 550 material,: add a red light body 5 work Mixed with the original green 'color phosphor 5 2 and the color illuminator 5 q phase, 0 person ^ ^ 踅 餸 DJ; the red phosphor 5 1 is excited by the blue light 15 5丄丄, the selected wavelength is between 585~700nm. According to the main features described in the above, a greenish yellow L E D 30 ' can be added to emit green yellow light 35 with a selected wavelength between 500 and 5 8 5 n m (as shown in FIG. 8). According to the foregoing main features (as shown in FIG. 3), wherein the light source is blue light 15 and the selected light emitting wavelength is between 4 〇〇 and 48 〇 1 ^, and the light source is red light 2 5 and the selected light wavelength is selected. Between 5 8 5~7 8 〇nm. According to the main features mentioned above, the green yellow, blue and red glomeriums 5 2, 5 3, 5 1 in the phosphor 5 can be selected from the following materials in combination or in combination: (1). Aluminate (2)·Citrate system; (3). Phosphate system; (4). Borate system; (5) Sulfide system. [Embodiment] (1). As shown in the figure - 'Blue LED10 and red LED2' are installed::; Cap 6 ,, where the upper surface of the blue LED 10, the body 5 〇, and then transparent 6 5 is packaged in the recess 6" of the reflective cover 60, to encapsulate the blue LED1 (^.= ”20. The electrodes are applied to the blue light Ledi〇 and the red light l ED 2 0; as shown in Fig. 2, the light is D work combination

發出波長介於400〜48〇ηΓΤ1ί^γ τ , κ 曰 ____i m的藍光15;螢光 1247436 • 案號93111734_年月 曰 修正_ 五、發明說明(4) 體5 0係由綠黃色螢光體5 2及藍色螢光體5 3二者 混合而成,其中綠黃色螢光體5 2吸收了一部份的藍 光1 5而被激發出波長介於5 0 0〜5 8 5 n m之間 的綠黃光5 2 1 ,藍色螢光體5 3吸收了一部份的藍 光15 ,而被激發出波長介於450〜500nm之 間的藍光5 3 1 ,被激發出的綠黃光5 2 1與藍光5 3 1等二種不同波長的混合以形成第一混合光8 0供 .釋出。紅光LED20發出波長介於585〜780 n m之間的紅光2 5 ,該紅光2 5與第一混合光8 0 再混合可得第二混合光9 0者。 如圖三所示係指光源為藍光1 5及紅光2 5及被激發 出的綠黃光5 2 1 、藍光5 3 1各自獨立且未混合前 的波形曲線圖,該圖可知二光源的藍光1 5、紅光2 5與被動發光的綠黃光5 2 1及藍光5 3 1等四者均 具有特定的「波長」及「發光強度」。 第四圖所不’係為藍光1 5、紅光2 5與綠黃光5 2 .1及藍光5 3 1混合後的曲線圖,該第二混合光9 0 被混合形成,其綜合波長平均值介於4 0 0〜7 0 0 n m之間,請再參閱圖四係第二混合光9 0與假想線 所示的太陽光光譜9 5 (即自然光)做比較,可知第 二混合光9 0與太陽光光譜9 5在介於4 0 0〜6 8 0 n m之可見光區域的演色性極高,因此本案所達成 的第二混合光9 0其色彩(如白光)的演色性更接近 於自然光,而屬於色彩的飽和度佳。 (2).螢光體5 0基本上是由綠黃色螢光體5 2及藍色螢光Blue light with a wavelength of 400~48〇ηΓΤ1ί^γ τ , κ 曰____i m is emitted; fluorescent 1247436 • Case number 93111734_年月曰 _ _ V. Invention description (4) Body 5 0 is composed of green yellow firefly The light body 5 2 and the blue phosphor 5 3 are mixed, wherein the green yellow phosphor 52 absorbs a part of the blue light 15 and is excited to have a wavelength of 5 0 0 5 5 5 5 nm. Between the green yellow light 5 2 1 , the blue phosphor 5 3 absorbs a part of the blue light 15 and is excited by the blue light 5 3 1 having a wavelength between 450 and 500 nm, and the green yellow is excited. The mixing of light 5 2 1 and two different wavelengths of blue light 5 3 1 to form first mixed light 80 is released. The red LED 20 emits red light 2 5 having a wavelength between 585 and 780 nm, and the red light 2 5 is mixed with the first mixed light 80 to obtain a second mixed light 90. As shown in Figure 3, the light source is a blue light wave and a red light light 5 and the excited green light yellow light 5 2 1 and blue light 5 3 1 are independent and unmixed waveforms. Blu-ray 1 5, red light 2 5 and passively-emitting green yellow light 5 2 1 and blue light 5 3 1 have specific "wavelength" and "luminous intensity". The fourth figure is not a mixture of blue light 1 5, red light 2 5 and green yellow light 5 2 .1 and blue light 5 3 1 , and the second mixed light 90 is mixed to form an integrated wavelength average. The value is between 4 0 0 and 7 0 0 nm. Please refer to Figure 4 for the second mixed light 90 to compare with the solar spectrum 9 5 (ie natural light) shown by the imaginary line. 0 and the solar spectrum 9.5 are extremely high in color rendering in the visible region between 4 0 0 and 600 nm, so the second mixed light 90 achieved in this case is closer to the color rendering of the color (such as white light). Natural light, and the saturation of color is good. (2). The phosphor 50 is basically composed of green-yellow phosphor 5 2 and blue fluorescent light.

1247436 _案號 93111734 五、發明說明(5) 年 月 日1247436 _ Case number 93111734 V. Invention description (5) Year Month Day

體5 3均勻混合而成,二者係依其元素成份”比例值 1的不同而有不同的致光顏色反應,綠黃色螢光體5 2的受光致顏色為綠黃光,藍色螢光體5 3的受光致 顏色為藍光,故綠黃色螢光體5 2及藍色螢光體5 3 可選擇採相同的材料元素,但二者的成份比例不同, 即會產生不同的光致顏色。本案螢光體5 〇的材料可 採用下列的一種或多種元素的組合(1).鋁酸鹽系 (Aluminate) ; (2).石夕酸鹽系(Silicates ) ; (3).石舞 酸鹽系(Phosphates) ; (4).石朋酸鹽系(Bornates); (5 ) ·硫化物系(S u 1 f i d e s)。 如圖五所示係為本案另一較佳可行的實施例,螢光_ 5 0中可增加另一紅色螢光體5 1的混合,其中該矣工 色螢光體5 1係由MgF2 · MgO · Ge02 : Μη材料構成,俾 與上述的綠黃色螢光體5 2及藍色螢光體5 3相混人 ;藉此當螢光體5 0受藍光1 5光源的激發時,乃f 被激發出紅光5 1 1、藍光5 3 1及綠黃光5 2 1 y 混合成第一混合光8 0 /,因此第一混合光8 〇 >具 備有紅光5 1 1 、藍光5 3 1及綠黃光5 2 1二者不 同波長的混合光,其中紅光5 1 1的光波長介於5 8 5〜7 OOnm之間,如圖六所示,光源為藍光丄5 、紅光2 5及綠黃光3 5各自獨立且未混合前的、皮長 區域及相對的發光強度,以及被激發的藍光5 3 ^ •長區域及相對的發光強度,第六圖可知,丄 <檀不同 的光均具有特定的油县为硌亦.強唐。The body 5 3 is uniformly mixed, and the two have different light color reactions depending on the elemental composition "proportion value 1", and the light-induced color of the green-yellow phosphor 5 2 is green yellow light, blue fluorescent light The light-receiving color of the body 53 is blue light, so the green yellow phosphor 5 2 and the blue phosphor 5 3 can be selected from the same material elements, but the composition ratios of the two components are different, that is, different photo-induced colors are generated. The material of the phosphor 5 本 in this case may be a combination of one or more of the following elements: (1). Aluminate (Aluminate); (2). Silicates (Silicates); (3). Stone dance Phosphates; (4). Bornates; (5) Sulfate (S u 1 fides). Figure 5 is another preferred embodiment of the present invention. In the fluorescent _50, a mixture of another red phosphor 5 1 may be added, wherein the 矣 color phosphor 5 1 is composed of MgF2 · MgO · Ge02 : Μη material, and the green yellow fluorescent light described above The body 5 2 and the blue phosphor 5 3 are mixed; thereby, when the phosphor 50 is excited by the blue light source, f is excited by red light 5 1 1 , blue light 5 3 1 and green yellow 5 2 1 y is mixed into the first mixed light 8 0 /, so the first mixed light 8 〇> is provided with mixed light having different wavelengths of red light 5 1 1 , blue light 5 3 1 and green yellow light 5 2 1 . The light wavelength of red light 5 1 1 is between 5 8 5 and 700 nm, as shown in FIG. 6 , the light source is blue 丄 5 , red light 2 5 and green yellow light 3 5 are independent and unmixed before the skin The long region and the relative luminous intensity, as well as the excited blue light 5 3 ^ • long region and relative luminous intensity, the sixth figure shows that the different light of the 丄 &Tan; Tan has a specific oil county for the 硌 also.

被激發出的綠黃光5 2 1及被激發的紅光5 ] Ί盆祕 1247436 _案號93111734_年月曰 修正_ 五、發明說明(6) 如圖九所示係為本案另一較佳可行的實施例,其中螢 光層5 0係直接封裝於綠黃光L E D 3 0、紅光L E D20及藍光LED10上。本案在反射蓋60中, 特別選擇加裝了一綠黃色L E D 3 0可選定波長介於 5 0 0〜5 8 5 n m之間的綠黃光3 5做為另一光源 ,如圖八、九所示,藉此綠黃光3 5、紅光2 5及藍 光1 5等三光源一併與前述的第一混合光8 0 >混合 可得第二混合光9 0 /其波長的曲線如第七圖所示, 藉由第七圖與第四圖中的第二混合光9 0 >、9 0兩 者波形的比較,可知第七圖中的第二混合光9 0 /增 加了紅光2 5部份的波形強度以及增加了綠黃光3 5 的波形強度,因此第七圖中第二混合光9 0 >與太陽 光譜9 5 (即自然光)做比較,可知第二混合光9 0 /與太陽光譜9 5在介於40 0〜6 8 0 nm之間的 可見光區域之相似率極高,因此第二混合光9 0 —其 色彩(如白光)的演色性更接近於自然光,色彩之飽 和度更佳。Excited green yellow light 5 2 1 and excited red light 5 ] Ί 秘 secret 1247436 _ case number 93111734_ 年月曰 _ _ 5, invention description (6) Figure 9 is another comparison of this case A preferred embodiment wherein the phosphor layer 50 is directly packaged on the green yellow LED 30, the red LED D20, and the blue LED 10. In the case of the reflective cover 60, a green-yellow LED 3 0 is selected to select a green yellow light 3 5 having a wavelength between 5 0 0 and 5 8 5 nm as another light source, as shown in FIG. As shown, the three light sources such as green yellow light 3 5, red light 2 5 and blue light 15 are mixed with the first mixed light 8 0 > to obtain a curve of the second mixed light 90 / wavelength thereof. As shown in the seventh figure, by comparing the waveforms of the second mixed light 9 0 > 90 in the seventh and fourth figures, it can be seen that the second mixed light 9 0 in the seventh figure is increased by red. The intensity of the waveform of the light portion 5 and the intensity of the waveform of the green yellow light 3 5 are increased, so that the second mixed light 9 0 > in the seventh figure is compared with the solar spectrum 9 5 (ie, natural light), and the second mixed light is known. The similarity rate of 9 0 / with the solar spectrum 9 5 in the visible region between 40 0 and 600 nm is extremely high, so the color of the second mixed light 90 - its color (such as white light) is closer to natural light. The color saturation is better.

第10頁 1247436 _案號93111734_年月曰 修正_ 圖式簡單說明 【圖式簡單說明】 第一圖為本發明裝置的一斷面圖。 第二圖為本發明的演色混合的流程方塊圖。 第三圖為本發明發光L E D主動發光與螢光體被動發光的 各獨立的光波長曲線圖。 第四.圖為本發明第二混合波長的曲線圖。 第五圖為本發明螢光體增加紅色螢光體後的演色混合流程 方塊圖。 第六圖為本發明第二混合波長與太陽光(day 1 i ght )波形 比較的曲線圖。 第七圖為本發明增加了被動紅光及綠黃光源混合後第二混 合波長的曲線圖。 第八圖為本發明另一實施例的流程方塊圖。 第九圖為本發明裝置的另一實施斷面圖。 【主要元件符號說明】 藍 光L E D--- 1 0 藍 光一 一 — 1 5 紅 光L E D--- 2 0 紅 光一 — — 2 5 綠 黃色 L E D-- 3 0 螢 光體 一 — 5 0 紅 色螢 光 n--- 5 1Page 10 1247436 _ Case No. 93111734_年月曰 Correction _ Schematic description of the drawing [Simple description of the drawing] The first figure is a sectional view of the device of the present invention. The second figure is a flow block diagram of the color mixing of the present invention. The third figure is a graph of independent optical wavelengths of the luminous L E D active illumination and the fluorescent passive illumination of the present invention. Fourth, the graph is a graph of the second mixed wavelength of the present invention. The fifth figure is a block diagram of the color mixing process after the red phosphor is added to the phosphor of the present invention. The sixth graph is a graph comparing the second mixed wavelength of the present invention with the day 1 i ght waveform. The seventh figure is a graph showing the second mixed wavelength of the passive red light and the green yellow light source mixed according to the present invention. Figure 8 is a block diagram of a flow of another embodiment of the present invention. Figure 9 is a cross-sectional view showing another embodiment of the apparatus of the present invention. [Main component symbol description] Blu-ray LE D--- 1 0 Blu-ray one-one - 1 5 Red light LE D--- 2 0 Red light one - 2 5 Green yellow LE D-- 3 0 Phosphor 1 - 5 0 red fluorescent n--- 5 1

第11頁 1247436Page 11 1247436

第12頁Page 12

Claims (1)

12474361247436 1 · 一種白光發光裝置,乃包含·· 至少包含一個以上的藍光led,可發出藍光; 至少一個以上的紅光L E D,可發出紅光; 螢光體是由綠黃色螢光體及藍色螢光體彼此混合而成 ’其中該綠黃色螢光體由鋁酸鹽系(Aluminate)材料 構成,其致活物為鈽(Ce); 監色读光體由鋁酸鹽系(Aluminate)材料構成,其致 活物為銪(Eu); 〃 該螢光體係被覆接於藍光L E D的上表面,俾可吸收 ,土、,使螢光體被激發出一種與藍光波長不同的第一 混t光,第一混合光與紅光L E D所發出的紅光再相 混a釋出第二混合光者; /、3读光體中的綠黃色螢光體被藍光激發出的綠黃光 + 、波長介於5 0 0〜5 8 5 n m之間; 螢光體被藍光激發出的藍光其波長介於4 5 〇〜 b 〇 0 n m之間; σ亥一種不同的顏色的光波長組合,以形成第一混合光 第1項所述之白 增加一紅色螢光 光體相混合成; 其波長介於5 8 •依據申請專利範圍 读光體材料中,可 色螢光體及藍色螢 光激發出的紅光, 間〇 光發光裝置,其中 體俾與原有的綠黃 該紅色螢光體被藍 5〜7 00nm之 依據申明專利範圍第1或2項所述之白光發光裝置1 · A white light emitting device comprising: at least one or more blue LEDs emitting blue light; at least one red LED emitting red light; the phosphor is a green yellow phosphor and blue fluorescent The light body is mixed with each other, wherein the green-yellow phosphor is composed of an aluminate (Aluminate) material, and the activator is cerium (Ce); the color-reading light reading body is composed of an aluminate (Aluminate) material. The living material is 铕 (Eu); 〃 the fluorescent system is coated on the upper surface of the blue LED, and the yttrium can absorb, earth, and the phosphor is excited to emit a first mixed light having a wavelength different from the blue light. The first mixed light is mixed with the red light emitted by the red LED to release the second mixed light; /, the green yellow light in the 3 reading body is excited by the blue light + blue, and the wavelength Between 5 0 0 and 5 8 5 nm; the blue light excited by the blue light of the phosphor has a wavelength between 4 5 〇 and b 〇 0 nm; σ hai combines light wavelengths of different colors to form The white light described in item 1 of the first mixed light is mixed with a red fluorescent light body; Between 5 8 • According to the patent application range, the red light emitted by the colorable phosphor and the blue fluorescent light, the intercalating light emitting device, wherein the body and the original green yellow are red fluorescent The white light emitting device according to the first or second aspect of the patent scope is claimed by the blue 5~7 00 nm 1247436 _案號93111734_年月日_修正 _ 六、申請專利範圍 其中可增設一綠黃色LED,可發出綠黃光,其光波 長介於5 0 0〜5 8 5 nm之間。 4 ·依據申請專利範圍第1項所述之白光發光裝置,其中 光源為藍光,其選定的發光波長介於4 0 0〜4 8 0 n m之間,光源為紅光其選定的光波長介於5 8 5〜 7 8 0 n m 間。 5 ·依據申請專利範圍第1或2項所述之白光發光裝置, 其中螢光體中之綠黃色、藍色及紅色螢光體,可由下 列材料來選擇單一或組合使用: (1).鋁酸鹽系;(2).矽酸鹽系;(3 ).磷酸鹽系;(4). 硼酸鹽系;(5 ).硫化物系。1247436 _ Case No. 93111734_年月日日_Amendment _ VI. Patent application scope A green-yellow LED can be added to emit green-yellow light with a wavelength of between 5 0 0 and 5 8 5 nm. 4. The white light emitting device according to claim 1, wherein the light source is blue light, the selected light emitting wavelength is between 4 0 0 and 48 nm, and the light source is red light, and the selected light wavelength is between 5 8 5~ 7 8 0 nm. 5. The white light emitting device according to claim 1 or 2, wherein the greenish yellow, blue and red phosphors in the phosphor are selected from the following materials in a single or combined manner: (1). Aluminum Acid salt system; (2). citrate system; (3) phosphate system; (4). borate system; (5). sulfide system. 第14頁Page 14
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