TWI242895B - Package substrate of light-emitting diode - Google Patents

Package substrate of light-emitting diode Download PDF

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TWI242895B
TWI242895B TW93122924A TW93122924A TWI242895B TW I242895 B TWI242895 B TW I242895B TW 93122924 A TW93122924 A TW 93122924A TW 93122924 A TW93122924 A TW 93122924A TW I242895 B TWI242895 B TW I242895B
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insulating
holes
item
silicon substrate
patent application
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TW93122924A
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TW200605387A (en
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Tzer-Perng Chen
Shao-You Deng
Cheng-Chang Hsieh
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United Epitaxy Co Ltd
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Abstract

A method for forming a package substrate of light-emitting diode is provided. The method includes the steps of providing a silicon substrate having a first side, a second side, and a plurality of through holes penetrating thereof; forming an insulating layer over the first side and the second side along with forming an insulating collar over the inner walls of the through holes by using plasma enhanced chemical vapor deposition (PECVD) technology; and then forming a conductive layer over the insulating layer and the insulating collar as well.

Description

1242895 九、發明說明: 【發明所屬之技術領域】 本發明關係到發光二極體之封裝,特別是關係到以矽晶片 作為封裝基板之製程技術。 【先前技術】 目前以電路板材如FR4,或是陶瓷板材如aI2〇3等來作封 裝基板已逐漸無法滿足一些會產生高熱之發光二極體元件的 要求。所以,在高耐熱性及高導熱性的考量下,改用矽晶片作 為封裝基板已成為發光二極體表面黏著封裝技術的最新發展 趨勢。 以矽晶片作為封裝基板有一缺點,就是矽本身為一半去 月且口此必須先在矽基板表面包覆一層絕緣層,使得在之後 極製作的階段,電極與電極之間不會產生漏電的現象。石夕基 上絕緣層的形成在先前技術(如中華民國專利公告號侧沒 中已有敘述,乃神基槪人—含有氧氣或聽高溫爐中使 表面形成—祕層錢化騎可。_,此技娜可在平的 對於形成规板貫細 土表面的絕緣’卻往往會有包覆不完全或結顯弱的缺陷41242895 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to the packaging of light-emitting diodes, and particularly relates to a process technology using a silicon wafer as a packaging substrate. [Previous technology] At present, circuit boards such as FR4, or ceramic boards such as aI203, etc., have gradually failed to meet the requirements of some light-emitting diode elements that generate high heat. Therefore, in consideration of high heat resistance and high thermal conductivity, switching to a silicon wafer as a package substrate has become the latest development trend of the light emitting diode surface adhesive packaging technology. One disadvantage of using a silicon wafer as a package substrate is that the silicon itself is half of the moon and the surface must first be covered with an insulating layer, so that no leakage will occur between the electrode and the electrode during the subsequent fabrication stage. . The formation of the insulating layer on Shi Xiji is described in the prior art (such as in the Republic of China Patent Bulletin No., but it is a god-like person-containing oxygen or listening to a high temperature furnace to form the surface-mysterious layer can be used.) However, this technique can be used in the insulation of flat and fine soil to form a regular plate, but it often has defects such as incomplete coating or weak knots. 4

理慈 4EPITAXY/04005TW,930401TW 1242895 乃因為貫穿孔之孔徑小深度大所產生之階梯覆蓋(StepLi Ci 4EPITAXY / 04005TW, 930401TW 1242895 is due to the step coverage due to the small depth of the through hole aperture (Step

Coverage)不良現象。此將導致貫穿孔内壁的半導體矽裸露出 來,而與之後要形成的導電層接觸,產生短路與漏電的現象。 所以,要利用矽基板作發光二極體封裝,必須先改善矽基板貫 穿孔内壁的絕緣問題。 【發明内容】 本發明係針對上述問題提出一種發光二極體之封裝基板 的形成方法,包含提供一矽基板,該矽基板具有一第一面、一 第二面及複數個貫穿孔;藉由電裝加強幻b學氣相沉積 (PECVD)技術形成一絕緣層覆蓋該第一面及該第二面,並同 時形成一絕緣頸環(Insulating co丨|ar)覆蓋該複數個貫穿孔的内 壁;然後形成一導電層覆蓋該絕緣層及該絕緣頸環。 【實施方式】 圖1係本發明之第一及第二實施例的製造流程圖。圖 到圖2⑹則分別顯示圖]中每一步驟之矽基板的剖面圖。 本發明之第一實施例,如圖2(a)所示,提供一厚度約為1〇〇 的石夕基板210 (如步驟11)。石夕基板210具有一第Coverage). This will cause the semiconductor silicon on the inner wall of the through hole to be exposed, and contact the conductive layer to be formed later, resulting in short circuits and leakage. Therefore, if a silicon substrate is used as a light-emitting diode package, the insulation of the inner wall of the through-hole of the silicon substrate must be improved first. [Summary of the Invention] The present invention is directed to a method for forming a packaging substrate for a light emitting diode, which includes providing a silicon substrate having a first surface, a second surface, and a plurality of through holes; Denso's enhanced PECVD technology forms an insulating layer covering the first and second faces, and simultaneously forms an insulating neck ring (Insulating co 丨 ar) covering the inner walls of the plurality of through holes. And then forming a conductive layer covering the insulating layer and the insulating neck ring. [Embodiment] FIG. 1 is a manufacturing flowchart of the first and second embodiments of the present invention. Figures 2 through 2 show sectional views of the silicon substrate at each step in the figure]. According to the first embodiment of the present invention, as shown in FIG. 2 (a), a stone evening substrate 210 with a thickness of about 100 is provided (step 11). Shixi substrate 210 has a first

理慈 4EPITAXY/〇4〇〇5Tvv,93〇4〇1TW 1242895 -面212及-第二面214。接著’如圖綱所示,以乾式钱刻 (R旧)、濕式化學侧或是雷射貫孔的方式在矽基板21〇表面上 形成複數個貫穿孔220,其孔徑大小約在2〇/m〜8〇//m之間 (如步驟13)。 然後參考圖2⑹,利用電聚加強式化學氣相沉積(pECVD) 技術,使矽基板210之第一面212及第二面214包覆一絕緣層 230,並同時在貫穿孔220的内壁形成一絕緣頸環24〇(如步驟 15)。必須注意的是此步驟中使用PECVD技術有別於習知技 術,其主要的優點在於沉積絕緣層230及絕緣頸環24〇的同 時,也利用電漿來濺擊絕緣層230及絕緣頸環240上的表面分 子,使他們的分布更均勻、結構更加密實,因此得以完全覆蓋 在貫穿孔220的内壁以形成良好的絕緣。電漿濺擊的效果與貫 穿孔220的外觀比值(aSpect Rati〇n)有關。在此實施例中,絕 緣頸環240的較佳厚度約是在2〇〇〇A到5000A之間,矽基板 210之厚度在約100#m到5〇〇#m之間,及貫穿孔220之孔徑 大小在20//m到80//m之間時,可有較佳效果。 現在說明本發明的第二實施例,其中前兩個步驟(即步驟 11及步驟13)與第一實施例相同。在複數個貫穿孔220形成之Li Ci 4EPITAXY / 04005Tvv, 9304001TW 1242895-face 212 and-second face 214. Next, as shown in the outline, a plurality of through holes 220 are formed on the surface of the silicon substrate 21 by means of dry money engraving (R), wet chemical side or laser through holes, and the size of the holes is about 2 / m ~ 80 // m (as in step 13). Then referring to FIG. 2 (a), the first surface 212 and the second surface 214 of the silicon substrate 210 are covered with an insulating layer 230 by using electro-enhanced chemical vapor deposition (pECVD) technology, and at the same time, an inner wall of the through hole 220 is formed. Insulating neck ring 24o (as in step 15). It must be noted that the use of PECVD technology in this step is different from the conventional technology. Its main advantage is that at the same time as the insulation layer 230 and the insulation neck ring 24 are deposited, the plasma is also used to splash the insulation layer 230 and the insulation neck ring 240. The upper surface molecules make their distribution more uniform and the structure more dense, so they can completely cover the inner wall of the through hole 220 to form a good insulation. The effect of the plasma splash is related to the appearance ratio (aSpect Ratn) of the through hole 220. In this embodiment, the preferred thickness of the insulating neck ring 240 is between 2000A and 5000A, the thickness of the silicon substrate 210 is between 100 # m and 500 # m, and the through hole 220 When the pore size is between 20 // m and 80 // m, a better effect can be obtained. A second embodiment of the present invention will now be described, in which the first two steps (i.e., step 11 and step 13) are the same as the first embodiment. Formed in the plurality of through holes 220

理慈 4EPITAXY/04005TW,930401TW / 1242895 後(即步驟13之後),將矽基板210送入含有一反應氣體之高溫 爐中,此反應氣體可為氧氣、氛氣、氨氣、水氣或一定比例之 上述氣體之混合氣體,使石夕基板210之第一面212及第二面214 包覆一含氧化物或氮化物之絕緣層230 (如步驟17)。必須注意 到的是,步驟17執行時也會同時在貫穿孔220之内壁形成一絕 緣頸環240,但是,此絕緣頸環240並不能完全包覆貫穿孔22〇 之内壁故將導致之後漏電的產生。所以,在石夕基板21〇送入高 溫爐反應之後’必需以電漿加強式化學氣相沉積(pECVD)技 術處理該絕緣頸環240,使該絕緣頸環24〇均勻分佈在該複數 個貫穿孔220的内壁上,以避免該内壁露出(如步驟19)。第二 實施例中,PECVD處理步驟可僅針對容易產生漏電缺陷的絕 緣頸環240實施,與第一實施例比較係能節省PECVD的操作 時間’除此以外’所採用石夕基板210的厚度、貫穿孔22Q之孔 徑大小、及絕緣頸環240的厚度等較佳條件均與第一實施例相 似0 接下來的步驟,第一實施例與第二實施例皆同。參考圖2(d) 及步驟12,形成一導電層250覆蓋絕緣層230及絕緣頸環 240,此導電層250可為任何金屬材料,而且除了覆蓋絕緣層 230及絕緣頸環240外,也可進一步地將複數個貫穿孔22〇填Li Ci 4EPITAXY / 04005TW, 930401TW / 1242895 (that is, after step 13), the silicon substrate 210 is sent into a high temperature furnace containing a reaction gas, which may be oxygen, atmosphere, ammonia, water or a certain proportion The mixed gas of the aforementioned gases covers the first surface 212 and the second surface 214 of the Shixi substrate 210 with an insulating layer 230 containing an oxide or a nitride (step 17). It must be noted that an insulating neck ring 240 is also formed on the inner wall of the through-hole 220 at the same time when step 17 is performed. However, this insulating neck ring 240 cannot completely cover the inner wall of the through-hole 22 and will cause subsequent leakage. produce. Therefore, after the Shixi substrate 21 is sent to the high-temperature furnace for reaction, the insulating neck ring 240 must be treated with plasma enhanced chemical vapor deposition (pECVD) technology so that the insulating neck ring 24 is evenly distributed in the plurality of through holes. The inner wall of the hole 220 to prevent the inner wall from being exposed (as in step 19). In the second embodiment, the PECVD processing step may be performed only on the insulating neck ring 240 that is prone to leakage defects. Compared with the first embodiment, it can save the operating time of the PECVD 'other than that'. The preferred conditions such as the hole size of the through hole 22Q and the thickness of the insulating neck ring 240 are similar to those of the first embodiment. In the next steps, the first embodiment and the second embodiment are the same. Referring to FIG. 2 (d) and step 12, a conductive layer 250 is formed to cover the insulating layer 230 and the insulating neck ring 240. The conductive layer 250 may be any metal material, and besides covering the insulating layer 230 and the insulating neck ring 240, Further filling a plurality of through holes 22

理慈 4EPITAXY/04005TW,930401TW 1242895 円=12可藉蒸鍍、驗或電鍍的方式來進行。接著,如 ⑹所示,利用一般微影製程或利用雷射_-YAG)切割來 圖案化導電層250以形成符合需要的電極252及254(如步驟 14) ’如此即完成-發光二極體封裝用之基板。 圖2(f)及圖2(g)說明以本發明所製作之基板來封裝發光二 極體晶粒的實例。圖2_示傳統打線方式的封裝,其中· 代表發光二極體晶粒,27G代表金屬線,咖代表封膠;圖卻) 則顯示另一種覆晶法之封裝。 以上實施例之詳述,係希望能更加清楚描述本發明之特徵 與精神,而上述所揭露的實施例並非對本發明之範疇的限制。 相反地’上述的說明以及各種改變及均等性的安排皆為本發明 所欲文到保護的範疇。因此,本發明所申請之專利範圍的範疇 應此根據上述的說明作最寬廣的解釋,並涵蓋所有可能均等的 改變以及具均等性的安排。 【圖式簡單說明】 圖1:本發明之第一與第二實施例的製造流程圖。 圖2(a)到圖2(e):分別顯示圖1之製造流程圖中每一步驟之Lici 4EPITAXY / 04005TW, 930401TW 1242895 円 = 12 can be carried out by evaporation, inspection or electroplating. Next, as shown in Figure ,, the conductive layer 250 is patterned using a general lithography process or using laser-YAG) cutting to form electrodes 252 and 254 that meet requirements (as in step 14). 'This completes the light-emitting diode Substrate for packaging. Fig. 2 (f) and Fig. 2 (g) illustrate an example of encapsulating a light-emitting diode die with a substrate produced by the present invention. Figure 2_ shows the traditional packaging method of wiring, where · represents the light-emitting diode die, 27G represents the metal wire, and coffee represents the sealant; the figure) shows another kind of flip chip packaging. The foregoing embodiments are described in detail in order to more clearly describe the features and spirit of the present invention, and the embodiments disclosed above are not a limitation on the scope of the present invention. On the contrary, the above description, as well as various changes and arrangements of equality, are within the purview of the present invention to the protection. Therefore, the scope of the patent scope of the present invention should be interpreted in the broadest sense according to the above description, and cover all possible equal changes and arrangements with equality. [Brief Description of the Drawings] Figure 1: Manufacturing flowcharts of the first and second embodiments of the present invention. Figures 2 (a) to 2 (e): show each step in the manufacturing flowchart of Figure 1 separately

理慈 4EPITAXY/04005TW,930401TW 9 1242895 石夕基板的剖面圖。 圖2(f):以本發明所製作之基板來封裝發光二極體晶粒之—每 例(傳統打線法)。 ^ 圖2(g)·以本發明所製作之基板來封裝發光二極體晶粒之另— 貫例(覆晶法)。 【主要元件符號說明】 11提供一矽基板 13於矽基板上形成複數個貫穿孔 15以PECVD技術形成一絕緣層及一絕緣頸環 17將矽基板送入高溫爐以形成一絕緣層及一絕緣頸環 19以PECVD技術處理該絕緣頸環,使該絕緣頸環均勻 分佈在該複數個貫穿孔的内壁上 12形成一導電層覆蓋絕緣層及絕緣頸環或進一步填滿該 複數個貫穿孔 14圖案化導電層以形成符合需求的電極 210 矽基板 212第一面214 第二面 220 貫穿孔 230 絕緣層 240 絕緣頸環 理慈 4EPITAXY/04005TW ,930401TW 10 1242895 250 導電層 252 電極 254 電極 260 發光二極體晶粒 270 金屬線 280 封膠Li Ci 4EPITAXY / 04005TW, 930401TW 9 1242895 Sectional view of Shi Xi substrate. Fig. 2 (f): The substrate produced by the present invention is used to package light emitting diode grains—each example (conventional wire bonding method). ^ Fig. 2 (g) · Another example of encapsulating light-emitting diode die with the substrate produced by the present invention (Flip-Chip Method). [Description of main component symbols] 11 Provide a silicon substrate 13 Form a plurality of through holes in the silicon substrate 15 Use PECVD technology to form an insulating layer and an insulating neck ring 17 Feed the silicon substrate into a high temperature furnace to form an insulating layer and an insulation The neck ring 19 processes the insulating neck ring by PECVD technology, so that the insulating neck ring is evenly distributed on the inner wall of the plurality of through holes 12 to form a conductive layer covering the insulating layer and the insulating neck ring or to further fill the plurality of through holes 14 Pattern the conductive layer to form electrodes 210 silicon substrate 212 first surface 214 second surface 220 through hole 230 insulation layer 240 insulation neck ring 4EPITAXY / 04005TW, 930401TW 10 1242895 250 conductive layer 252 electrode 254 electrode 260 light emitting two Polar body grain 270 Metal wire 280 Sealant

理慈 4EPITAXY/04005TW,930401TW 11Li Ci 4EPITAXY / 04005TW, 930401TW 11

Claims (1)

1242895 十、申請專利範圍·· 1·種發光一極體之封裝基板的形成方法,包含: 提供一矽基板,該矽基板具有一第一面、一第二面及複數 個貫穿孔’該複數個貫穿孔係貫穿該矽基板; 藉由電漿加強式化學氣相沉積(PECVD)技術形成一絕緣層 覆蓋該第一面及該第二面,及形成一絕緣頸環(hsu|ating collar)覆蓋該複數個貫穿孔的内壁;以及 形成一導電層覆蓋該絕緣層及該絕緣頸環。 2_如申請專利範圍第1項所述之方法,該矽基板的厚度約在 100"m 到 500//m 之間。 3·如申請專利範圍第1項所述之方法,該貫穿孔的孔徑大小 約在20/ym到80//m之間。 4·如申請專利範圍第1項所述之方法,該絕緣頸環的厚度約 在2000A到5000A之間。 5·如申請專利範圍第1項所述之方法,其中該導電層進一步 包含填滿該複數個貫穿孔。 理慈 4EPITAXY/04005TW,930401TW 12 1242895 6· —種發光二極體之封裝基板的形成方法,包含: 長:供一石夕基板’該石夕基板具有一第一面、一第二面及複數 個貫穿孔; 將該矽基板經過含有一反應氣體之一高溫爐,以形成一絕 緣層覆蓋該第一面及該第二面,及形成一絕緣頸環 (insulating collar)覆蓋該複數個貫穿孔的内壁; 以電漿加強式化學氣相沉積(PECVD)技術處理該絕緣頸 環,使該絕緣頸環均勻分佈在該複數個貫穿孔的内壁上, 以避免該内壁露出;以及 形成一導電層覆蓋該絕緣層及該絕緣頸環。 7·如申請專利範圍第6項所述之方法,該矽基板的厚度約在 100//m到500川11之間。 8·如申請專利範圍第6項所述之方法,該貫穿孔的孔徑大小 約在20//m到80/ym之間。 9·如申請專利範圍第6項所述之方法,該絕緣頸環的厚度約 在2000A到5000A之間。 理慈 4EPITAXY/04005TW,930401TW 1242895 1〇.如^請專纖圍第6項所述之方法,其中該反應氣體係選 自合有氧氣、氮氣、氨氣、水氣、及上述之任何組合之群 組。 11·如申料利範圍第6項所述之方法,其中該導電層進一步 包含填滿該複數個貫穿孔。 12· 一種發光二極體之封裝基板的形成方法,包含·· 提供一矽基板,該矽基板具有一第一面、一第二面及複數 個貫穿孔,該複數個貫穿孔係貫穿該矽基板,該矽基板的 厚度約在100//m到500/ym之間,該貫穿孔的孔徑大小約 在20//m到80"m之間; 藉由電漿加強式化學氣相沉積(PECVD)技術形成一絕緣層 覆蓋該第一面及該第二面,及形成一絕緣頸環(insulating collar)覆蓋該複數個貫穿孔的内壁;以及 形成一導電層覆蓋該絕緣層及該絕緣頸環。 13·如申請專利範圍第12項所述之方法,該絕緣頸環的厚度 約在2000A到5000A之間。 理慈 4EPITAXY/04005TW,930401TW 14 1242895 14.如申請專利範圍第12項所述之方法,其中該導電層進一 步包含填滿該複數個貫穿孔。1242895 10. Scope of patent application ... 1. A method for forming a package substrate for a light emitting monopole, including: providing a silicon substrate having a first surface, a second surface, and a plurality of through holes; A through hole is formed through the silicon substrate; an insulating layer is formed to cover the first surface and the second surface by plasma enhanced chemical vapor deposition (PECVD) technology, and an insulating collar is formed. Covering the inner wall of the plurality of through holes; and forming a conductive layer covering the insulating layer and the insulating neck ring. 2_ The method described in item 1 of the scope of patent application, the thickness of the silicon substrate is between about 100 " m and 500 // m. 3. The method according to item 1 of the scope of patent application, wherein the pore size of the through hole is between about 20 / ym and 80 // m. 4. The method described in item 1 of the scope of patent application, the thickness of the insulating neck ring is between 2000A and 5000A. 5. The method according to item 1 of the patent application scope, wherein the conductive layer further comprises filling the plurality of through holes. Li Ci 4EPITAXY / 04005TW, 930401TW 12 1242895 6 · —A method for forming a package substrate for a light emitting diode, including: Long: for a Shi Xi substrate 'The Shi Xi substrate has a first side, a second side and a plurality of Through-holes; passing the silicon substrate through a high-temperature furnace containing a reactive gas to form an insulating layer covering the first and second faces, and forming an insulating collar covering the plurality of through-holes Inner wall; treating the insulating neck ring with plasma enhanced chemical vapor deposition (PECVD) technology so that the insulating neck ring is evenly distributed on the inner wall of the plurality of through holes to prevent the inner wall from being exposed; and forming a conductive layer covering The insulating layer and the insulating neck ring. 7. The method as described in item 6 of the scope of patent application, the thickness of the silicon substrate is between about 100 / m to about 500 m. 8. The method as described in item 6 of the scope of the patent application, wherein the pore size of the through hole is between about 20 // m and 80 / ym. 9. The method according to item 6 of the scope of patent application, the thickness of the insulating neck ring is between 2000A and 5000A. Li Ci 4EPITAXY / 04005TW, 930401TW 1242895 1 10. The method described in item 6 of the special fiber, wherein the reaction gas system is selected from the group consisting of oxygen, nitrogen, ammonia, water, and any combination thereof Group. 11. The method according to item 6 of the claim range, wherein the conductive layer further includes filling the plurality of through holes. 12. A method for forming a packaging substrate for a light emitting diode, comprising: providing a silicon substrate, the silicon substrate having a first surface, a second surface, and a plurality of through-holes, the plurality of through-holes passing through the silicon Substrate, the thickness of the silicon substrate is between 100 // m and 500 / ym, and the aperture size of the through hole is between 20 // m and 80 "m; by plasma enhanced chemical vapor deposition ( PECVD) technology forms an insulating layer covering the first surface and the second surface, and forms an insulating collar covering the inner walls of the plurality of through holes; and forming a conductive layer covering the insulating layer and the insulating neck ring. 13. The method according to item 12 of the scope of patent application, the thickness of the insulating neck ring is between 2000A and 5000A. Li Ci 4EPITAXY / 04005TW, 930401TW 14 1242895 14. The method described in item 12 of the scope of patent application, wherein the conductive layer further includes filling the plurality of through holes. 理慈 4EPITAXY/04005TW,930401TW 15Lici 4EPITAXY / 04005TW, 930401TW 15
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