1242413 玖 5 10 、發明說明： 【發明所屬之技術領域】 本發明是有關於-種蔬果農藥清洗與保 其装置’特別是指-種能利用臭氧之強氧化力與超！:皮: _擊力相配合，而將蔬果表面農藥有效洗除的：果曲 藥清洗與保鮮處理方法及其裝置。 L辰 【先前技術】 隨著農業栽培技術之不斷進步，蔬果的生長週期越來 越短’然而，由於環境污染日漸嚴重（例如，以豬翼尿廢 水施肥而造成農作物污染），致使蔬果所受到病蟲害更與： :增：因& ’絕大部分的蔬果必須連續施用農藥多次，始 能成熟上市。而長期且過度使用農藥，不僅對環境造成嚴 重衝擊’歹曼留於蔬果上的農藥，更嚴重危害食用者 健康。 由於殘留農藥對於食用者健康之殘害影響層面相當廣 ’輕則噁心、腹瀉，精神不振，重則全身抽搐、心力衰竭 ’甚至死亡。另外，殘留農藥會蓄積於人體内，當農業累 積超過一定量後，會干擾内分泌系統且引發疾病，例如，··、 不孕症、消化系統功能紊敗、癌症、心血管疾病、導致胎 20 兒畸形，或帕金森症等。 因此，現代人對於農藥殘留對人體健康之威脅與影響 更疋尚度警覺與重視，並積極尋求能有效洗淨蔬果殘留農 藥之方法。目前，廣為用以清除蔬果中殘留農藥的方法有 下列五種： 1242413 ι·清水浸泡洗滌法： 一般先用水沖洗掉蔬果（例如··菠菜、小白菜）之 表面污物，然後浸泡於清水中，浸泡時間需超過十分鐘 並反覆清洗浸泡二〜二次。 5 2·驗水浸泡清洗法： 大部分的有機填農藥能於鹼性環境下迅速分解，先 於五百毫升清水中加入食用鹼約五〜十克，配置成鹼水溶 液’再將初步沖洗後的蔬果置放入鹼水溶液中，於浸泡 、’、勺五十为j里後用清水沖洗’如此重複洗務三次左右。 10 3·加熱烹飪法： 氨基甲酸酯類農藥於高溫環境下會加速分解，先用 清水將蔬果（例如：芹菜、青椒）表面污物洗除，放入 彿水中約二〜五分鐘撈出，然後用清水沖洗一〜二遍後， 再進行烹煮。 15 4·清洗去皮法： 以銳器（去皮削刀）消除蔬果（例如：黃瓜、柿子）表 皮，只食用肉質部分，則較為安全。 5·儲存保管法： 農藥於空氣中會緩慢分解為對人體無害的物質，所 20 以對於易保存、保存期限長，且不易腐爛的蔬果（例如 :冬瓜、南瓜），存放十〜十五天以上，即能減少農藥殘 留量。因此，不要立即食用新採摘且為削皮的蔬果。 然而’以上述、/η水浸泡洗丨條法與驗水浸泡清洗法來況 ’皆會產生含有農藥之清洗廢水，清洗廢水通常是未經處 1242413 理而逕自排放，無形之中勢必會對環境造成污染與衝擊。 再者，上述五種方法僅適用於個人居家之小量蔬果的人工 洗滌，加上人為因素之不確定性，實難保農藥能確實有效 去除，相對農藥去除成效不彰。況且，對於餐廳等大量鋅 果的α洗需求，若採以同樣人工洗滌模式，不旦農藥去除 成效不佳，且顯得相當耗時而不便。 【發明内容】 10 15 旦#因此，本發明之目的，是在於提供一種適用於清洗大 ®蔬果，制超音波之氣穴衝擊力作肖肖臭氧之強氧化力 配合多重洗淨作業，得以將殘留於蔬果上之農藥有效去 除且確保蔬果鮮度的蔬果農藥清洗與保鮮處理方法及其裝 置。 八衣 ........丨^^〆工々/左，巴 一水體前處理步驟，以及一多重洗淨保鮮步驟。該水體 ，理步驟’是以高級淨水程序處理水體，而得清洗水。 多重洗淨保鮮步驟’將該清洗水導送人多數洗淨槽體中 利用:超音波震i單元於清洗水中產生氣穴現象，並配 —臭氧供應單元將臭氧導溶人清洗水中，將蔬果放置入 中-洗淨槽體中時，殘留於蔬果表面上的農藥會受氣穴 擊力作用而迅速分離自蔬果表面，且被臭氧迅速氧化分 ;同時’透過-水質情測單元判斷清洗水之水質變化， 控制蔬果移送至另一洗淨槽體内之時機，繼而讓蔬果進 反覆浸泡洗務的多重洗淨作t，確保蔬果呈完全潔淨狀 20 1242413 本發明之蔬果清淨裝置，用 + 、、 5義疏果表面殘留農藥於 /月洗水中洗淨，亚包含多數 夕 依序排列的洗淨槽體、一與該 夕數洗淨槽體連結的臭氧供應單 卞/u 接觸式地設置於該 2槽體處的超音波震i單元，以及-水質偵測單元。、該 2洗淨㈣㈣Μ有清洗水’以供蔬果能依序移送入 其中。該臭氧供應單元能將呈跑s &丄 ^具強减力特性之臭氧引溶入 洗净槽體内之清洗水中，藉以迅速 、总抑 疋刀解辰樂。該超音波震 盛早元是讓洗淨槽體内之清洗水巾產生 10 15 穴衝擊力讓農藥自蔬果表面分離。該水質偵測單元是用以 監控該多數洗淨槽體内之清洗水的水f變化 的洗程。 彳工刺^果 本發明之功效是利用—超音波震盘單元於清洗水中產 生氣穴現象，並配合-臭氧供應單元將臭氧導溶人清洗水 中’蔬果表面殘留農藥會受氣穴衝擊力作用而迅速分離自 蔬果表面，且被臭氧迅速氧化分解。同時，透過對於清洗 水之水質㈣，能控制蔬果移送至下—洗程的時機，二 行多重洗淨作業。藉以有效地提昇蔬果表面殘留農藥之产 除效率。 π 【實施方式】 有關本發明之前述及其他技術内容、特點與功效，在 以下配合參考圖式之數較佳實施例的詳細說明中，將可、、主 楚的明白。 m 參閱圖1與目2，本發明之蔬果農藥清洗與料處理方 法的一第一較佳實施例，是適用於清洗大量蔬果14(例如· 20 1242413 餐廳所而的龐大疏果量），並包含一水體前處理步驟u、一 ^重洗淨保,，、羊步驟〗2，以及一廢水回收再生步驟13。 I先，於該水體前處理步驟11中，是利用高級淨水裎 序處理水體，並冷卻至水溫約為5〜2(TC。其中，水體是經 5 由一逆滲透處理機進行逆滲透處理，故預處理後所得的清 洗水10即為R0水。由於逆滲透處理程序是屬習見淨水處 理技術，故其相關處理機制恕於此不再詳述。 处 接著於.亥夕重洗淨保鮮步驟J 2中，是先將清洗水10 導送入三依序排列的洗淨槽體2中。再利用一超音波震盪· 10 +兀3於該三洗淨槽體2中之清洗水1G内產生氣穴現象， 並配合-臭氧供應單元4將適量的臭氧導溶入該三洗淨槽. 體2中之清洗水1〇内。一切就緒後，將待清洗的蔬果μ 放置入排序為第一的洗淨槽體2中時，此時，殘留於 14表面上的農藥會受氣穴衝擊力作用而迅速自蔬果㈣面 刀離且被具強氧化分解能力的臭氧予以迅速氧化分解。 另，面，於清洗過程中，於有效去除殘留農藥之際，利 :臭氧所具有之強殺菌作用，並配合所使用的清洗水10水· 勺為5 2〇C以達到維持蔬果M營養成分的低溫保鮮 效用。 20 其中，該臭氧供應單元4具有三臭氧機41，以及三分 別與該Ϊ臭氧機41連結並分別設置於該三洗淨槽體2底部 、輸氣g 42每輸氣官42是設置於距離所相對應洗淨槽 體2底^約5〜10公分處，藉以將所相對應臭氧機41產製 之臭氧順暢地導溶人清洗水中。而臭氧機41產製臭氧 1242413 的原理機制’主要是利用高壓放電產生之能量，將氧㈣撞 擊成具有強氧化能力的臭氧（〇3)。本實施例中，將清洗水 1〇中之臭氧漢度控制在約1G〜25ppm，利用臭氧之強氧化力 ’能將殘留於蔬果14表面或溶於所相對應洗淨槽體2内之 5 清洗水1G中的農藥氧化分解成二氧化碳、水、氧或其他無 毋性的簡單化合物，其反應機制如下： 辰薬+ 〇 3 ^ C0 2 + Η 2〇 +其他無毒性的化合物 而該超音波震i單元3具有三分別設置於該三洗淨槽 體2底面的超音波震盡機31。每一超音波震盡機31是以石 10 彡料震動源，產生既定頻率的超音波，超音波能量會傳 、月洗水10巾並產纟氣穴現象（cavi），利用此氣穴 現象對於蔬果14表面所產生的衝擊❹力得以將蔬果14 表面的殘留農藥予以震盈移除而溶入所相對應洗淨槽體2 内之清洗水1 〇中。 15 同時，透過-水質偵測單元5監控清洗水10之水質變 化，作為水質判斷之依據，藉以控制蔬果之洗程（即更換 至下一洗淨槽體2之時機），或是更換清洗水1()之時機。 X艮貝偵測單兀5具有三分別設置於該三洗淨槽體2内的 偵測計51，本實施例中，情測計51是為電位價測計，用以 2〇 分別監控讀取位於該三洗淨槽體2内之清洗水10的氧化還 原電位變化。首先’分別將該三制計51妓顯現出三盤 告值’當隨清洗時間增長，蔬果所處之清洗水iq的氧化還 原電位已達所相對應偵測計51設定的警告值，且不穩定地 持t“匕打，表不清洗水1〇的水質差不具足夠氧化分解 5 10 15 20 1242413 -法負荷持續溶入之農藥。此時，則須將尚未洗淨 =果14移送至下—排序的洗淨㈣2内，以進行下-波 辈^同時更換該洗淨槽體2内之清洗水ig。如此重複作 業，讓蔬果持續進行多重洗淨作業。 而於排序最後的洗淨_ 2中進行洗淨過程時，直至 :主水之氧化還原電位未達所相對應偵測計51設定之 =值，且不隨清洗時間增長而變動時，表示已無農藥持 〜谷t該清洗水1G中，其中的臭氧亦不再祕，也就是說 此日^殘留於蔬果14表面的農藥已幾乎被有效分解去除着 ，確保蔬果14呈完全潔淨狀態。 最後，於該廢水回收再生步驟13 +，將該多重洗淨保 鮮12步驟中該三洗淨槽體2所排放出的清洗後廢水，予以 回收至-廢水回收處理單元6中進行廢污水處理而得可 再利用之回收水。 一般來，，視回收水循環再利用之用途，而考量該廢 水回收處理單元6所運用之處理機制對於回收水之水質要 求影響。以較低階的回收水再利用來說，例如：農業灌溉錢 用水、生活雜用水等，該廢水回收處理單元6可利用化學 混凝與沉澱過濾等處理相配合；以高階的回收水再利用來 說，例如：工業用水（冷卻水、鍋爐水）、飲用水、自來水等 ，該廢水回收處理單元6則可運用薄膜過濾（電透析、逆 渗透、超過渡等)、離子交換、吸附等處理單元。由於上： 化學混凝、薄膜過渡…等皆屬於習見水質處理技術，恕於此 不再詳述。而本實施例中，該廢水回收處理單- q、 平7L 6是為一 10 5 ι〇 15 2〇 1242413 w/透處理機，所得之回收 洗水10用途而循環再利用。 “用以供作清 由於Φ含軎/ p t 關領域研究°，= 力於農業藥物去除與水質處理等相 ’藉由本發明之菸|曲〜 貝才“驗，热庸置疑地 到下列纽：果^清洗與崎處財法，確實能達 I有效提昇蔬果14表面殘留農藥之去除效率.1242413 玖 5 10. Description of the invention: [Technical field to which the invention belongs] The present invention relates to a device for cleaning, protecting, and protecting vegetables, fruits, and pesticides, and particularly to a device capable of utilizing ozone's strong oxidizing power and super! : Skin: _The combination of the impact force and the effective removal of pesticides on the surface of vegetables and fruits: fruit koji medicine cleaning and fresh-keeping treatment method and device. L Chen [Previous technology] With the continuous advancement of agricultural cultivation technology, the growth cycle of vegetables and fruits is getting shorter and shorter. However, due to the increasingly serious environmental pollution (for example, the pollution of crops caused by the application of pig wing urine wastewater), the fruits and vegetables have suffered Pests and diseases are more related to:: Zeng: Because & 'Most vegetables and fruits must be continuously applied pesticides many times before they can be marketed maturely. The long-term and excessive use of pesticides not only has a severe impact on the environment, but the pesticides left on vegetables and fruits also endanger the health of consumers. Due to the wide range of harmful effects of residual pesticides on the health of consumers, ‘from nausea, diarrhea, and depression, and from whole body convulsions, heart failure’, and even death. In addition, residual pesticides will accumulate in the human body. When the agricultural accumulation exceeds a certain amount, it will interfere with the endocrine system and cause diseases, such as, infertility, digestive dysfunction, cancer, cardiovascular disease, and cause fetal 20 Child deformity, or Parkinson's disease. Therefore, modern people are more vigilant and aware of the threats and impacts of pesticide residues on human health, and are actively seeking ways to effectively clean up pesticides from fruits and vegetables. At present, the following five methods are widely used to remove pesticide residues in vegetables and fruits: 1242413 ι · water soaking and washing method: Generally, the surface dirt of vegetables and fruits (such as spinach and pakchoi) is rinsed with water and then soaked in water Medium, soak time should be more than ten minutes, and repeatedly wash and soak two to two times. 5 2 · Water test immersion cleaning method: Most organic filling pesticides can be quickly decomposed in alkaline environment. First, add about five to ten grams of edible alkali in 500 ml of water, and configure it into an alkaline aqueous solution. Put the fruits and vegetables into an alkaline aqueous solution, and then rinse them with water after soaking, ', spoon, fifty miles, and so on, and repeat the washing process about three times. 10 3 · Heat cooking method: Carbamate pesticides will accelerate decomposition under high temperature environment. First, use water to wash the dirt on the surface of vegetables and fruits (such as celery and green pepper) and put them in the buddha water for about two to five minutes and remove them. Rinse once or twice with water before cooking. 15 4 · Cleaning and peeling method: It is safer to remove the skin of vegetables and fruits (such as cucumbers and persimmons) with sharps (peeling and cutting), and only eat the meaty parts. 5 · Storage and storage method: Pesticides will slowly decompose into harmless substances in the air, so for fruits and vegetables (such as winter melon and pumpkin) that are easy to preserve, have a long shelf life, and are not easy to rot, store for ten to fifteen days The above can reduce the amount of pesticide residues. Therefore, do not eat freshly picked and peeled fruits and vegetables immediately. However, 'the above-mentioned, / η water immersion washing method and test water immersion washing method' will all produce pesticide-containing cleaning wastewater, and the cleaning wastewater is usually self-discharged without treatment of 1242413. The environment causes pollution and impact. In addition, the above five methods are only suitable for the manual washing of small quantities of fruits and vegetables in an individual's home. In addition to the uncertainty of human factors, it is difficult to ensure that pesticides can be effectively removed, and the effectiveness of pesticide removal is poor. Moreover, for the alpha washing needs of a large number of zinc fruits such as restaurants, if the same manual washing mode is adopted, the effectiveness of pesticide removal is not good, and it is quite time-consuming and inconvenient. [Summary of the Invention] 10 15 旦 # Therefore, the purpose of the present invention is to provide a kind of ultrasonic wave cavitation force which is suitable for cleaning large ® fruits and vegetables, and the strong oxidizing power of ozone and multiple cleaning operations, so that the residual Vegetable and fruit pesticide cleaning and fresh-keeping processing method and device for effectively removing pesticide on vegetables and fruits and ensuring freshness of vegetables and fruits. Ba Yi ........ 丨 ^^ 〆 工 々 / 左, 巴 A pre-treatment step of water body, and a multiple washing and fresh-keeping step. In the water body, the treatment step is to treat the water body with an advanced water purification program to obtain washing water. Multiple washing and fresh-keeping steps' This washing water is sent to most washing tanks for use: Ultrasonic vibration i unit generates cavitation in the washing water, and it is equipped with an ozone supply unit to dissolve ozone into people's washing water and transfer fruits and vegetables. When placed in the medium-cleaning tank, pesticides remaining on the surface of vegetables and fruits will be quickly separated from the surface of vegetables and fruits by the impact of air pockets, and will be quickly oxidized by ozone; meanwhile, the 'through-water quality measuring unit' will judge the washing water. Water quality changes, control the timing of vegetables and fruits being transferred to another washing tank, and then let the vegetables and fruits enter the multiple washing operations of repeated soaking and washing to ensure that the fruits and vegetables are completely clean. 20 1242413 The vegetable and fruit cleaning device of the present invention uses +, 5. Pesticide residues on the surface of the fruit are washed in the washing water per month, and the washing tank contains most of the washing tanks arranged in sequence, and the ozone supply unit connected to the washing tanks on the eve is set in a contact manner. Ultrasonic vibration i unit at the 2 tank body, and -water quality detection unit. 2. The 2 washings have washing water 'for vegetables and fruits to be transferred into them in sequence. The ozone supply unit can dissolve ozone with strong deceleration characteristics into the washing water in the washing tank, so as to quickly and totally suppress the solution of Chenle. The ultrasonic shock Sheng Zaoyuan caused the washing water towel in the washing tank to generate 10 15 holes impact force to separate the pesticide from the surface of vegetables and fruits. The water quality detection unit is used to monitor the washing process of the water f of the washing water in the majority of the washing tanks.彳 工 刺 ^ 果 The effect of the present invention is to use the ultrasonic vibration disk unit to generate cavitation in the washing water, and cooperate with the -ozone supply unit to dissolve ozone in the washing water. The pesticide residue on the surface of vegetables and fruits will be affected by the cavitation impact. Quickly separated from the surface of vegetables and fruits, and quickly oxidized and decomposed by ozone. At the same time, the quality of the washing water can be used to control the timing of the vegetables and fruits being transferred to the bottom-washing process. This can effectively improve the production efficiency of pesticide residues on the surface of vegetables and fruits. [Embodiment] The foregoing and other technical contents, features, and effects of the present invention will be clearly understood in the following detailed description of preferred embodiments with reference to the drawings. m Referring to Figures 1 and 2, a first preferred embodiment of the method for cleaning and processing vegetables, fruits, and pesticides according to the present invention is suitable for cleaning a large number of fruits and vegetables 14 (for example, a large amount of fruits and vegetables at 20 1242413 restaurants), and It comprises a water body pre-treatment step u, a heavy washing protection step, a sheep step 2 and a waste water recovery and regeneration step 13. First, in the water body pretreatment step 11, the water body is sequentially treated with advanced water purification and cooled to a water temperature of about 5 to 2 (TC. Among them, the water body is subjected to reverse osmosis by a reverse osmosis processor through 5). Treatment, so the pre-treatment washing water 10 is R0 water. Since the reverse osmosis treatment program is a conventional water purification technology, its related treatment mechanism will not be described in detail here. In the clean freshness step J2, the washing water 10 is first introduced into the three washing tanks 2 arranged in sequence. Then, an ultrasonic vibration is used to wash 10 + 3 in the three washing tanks 2. Air cavitation occurs in the water 1G, and cooperates with the -ozone supply unit 4 to dissolve an appropriate amount of ozone into the three washing tanks. The washing water 10 in the body 2. When everything is ready, place the fruits and vegetables to be cleaned μ into When the cleaning tank 2 is sorted as the first, at this time, the pesticide remaining on the surface of 14 will be quickly cut off from the surface of the vegetable and fruit by the impact of cavitation, and quickly oxidized and decomposed by ozone with strong oxidative decomposition ability. In addition, during the cleaning process, it is beneficial to effectively remove residual pesticides. : The strong bactericidal effect of ozone, combined with the used washing water 10 water · spoon is 5 2 ° C to achieve the low-temperature preservation effect of maintaining the nutritional content of fruits and vegetables M. 20 Among which, the ozone supply unit 4 has a three ozone machine 41 , And three are respectively connected to the tritium ozone machine 41 and are respectively arranged at the bottom of the three washing tanks 2 and each of the gas transmission g 42 is disposed at a distance from the bottom of the corresponding washing tank 2 ^ about 5 ~ 10 centimeter office, so that the ozone produced by the corresponding ozone machine 41 can be smoothly dissolved in people's cleaning water. The principle and mechanism of ozone machine 41 produced ozone 1242413 'is mainly the use of energy generated by high-voltage discharge, the impact of oxygen radon into Ozone (〇3) with strong oxidizing capacity. In this embodiment, the ozone degree of ozone in the washing water 10 is controlled to about 1G ~ 25ppm, and the strong oxidizing power of ozone can be used to remain on the surface of vegetables and fruits 14 or dissolve it. Correspondingly, the pesticide in 5G washing water in the washing tank 2 is oxidized and decomposed into carbon dioxide, water, oxygen or other simple compounds. The reaction mechanism is as follows: chen 薬 + 〇3 ^ C0 2 + Η 2 〇 + Other non-toxic compounds The ultrasonic vibrating unit i has three ultrasonic vibrating machines 31 respectively disposed on the bottom surface of the three washing tanks 2. Each ultrasonic vibrating machine 31 uses a stone 10 as a vibration source to generate ultrasonic waves of a predetermined frequency. Ultrasonic energy will be transmitted, 10 towels will be washed in the moon, and the cavitation phenomenon (cavi) will be generated. Using this cavitation phenomenon, the impact force on the surface of vegetables and fruits 14 can be used to remove the residual pesticides on the surface of vegetables and fruits 14 And dissolved in the corresponding washing water 10 in the washing tank 2. 15 At the same time, the water quality change of the washing water 10 is monitored by the -water quality detection unit 5 as a basis for water quality judgment to control the washing process of vegetables and fruits ( That is, the time to change to the next washing tank 2), or the time to change the washing water 1 (). The Xgenbei detection unit 5 has three detection meters 51 respectively disposed in the three washing tanks 2. In this embodiment, the emotional measurement meter 51 is a potentiometer, which is used to monitor and read the readings separately. The change of the oxidation-reduction potential of the washing water 10 in the three washing tanks 2 is taken. First of all, 'the prostitutes of the three systems 51 show three discreet values'. As the cleaning time increases, the redox potential of the washing water iq where the fruits and vegetables are located has reached the warning value set by the corresponding detector 51, and Stable holding “t” dagger, showing that the water quality of the washing water is not good enough to oxidize and decompose 5 10 15 20 1242413-the pesticide that is continuously dissolved in the load. At this time, you must transfer the unwashed = fruit 14 to the next —Sequence of washing ㈣2 to perform the next-wave generation ^ At the same time, the washing water ig in the washing tank 2 is replaced at the same time. Repeat this operation so that the fruits and vegetables continue to perform multiple washing operations. When the cleaning process is performed in 2 until the oxidation-reduction potential of the main water does not reach the value set by the corresponding detector 51 and does not change with the increase of the cleaning time, it means that there is no pesticide holding ~ In water 1G, the ozone in it is no longer secret, that is to say, the pesticides remaining on the surface of vegetables and fruits 14 have been effectively decomposed and removed on this day to ensure that the vegetables and fruits 14 are completely clean. Finally, in the wastewater recovery and regeneration step 13 +, The multiple washing and fresh keeping 12 steps In this step, the washed wastewater discharged from the three washing tanks 2 is recycled to a wastewater recycling treatment unit 6 for waste water treatment to obtain reusable recycled water. Generally, it is considered that the recycled water is recycled and reused. Use, and consider the impact of the treatment mechanism used by the wastewater recycling treatment unit 6 on the water quality requirements of the recycled water. In terms of lower-level recycled water reuse, such as agricultural irrigation water, miscellaneous water, etc., the wastewater is recycled. The treatment unit 6 can use chemical coagulation and sedimentation filtration to cooperate; in terms of high-level recycled water reuse, such as: industrial water (cooling water, boiler water), drinking water, tap water, etc., the wastewater recovery treatment unit 6 You can use membrane filtration (electrodialysis, reverse osmosis, ultra-transition, etc.), ion exchange, adsorption and other processing units. Due to the above: chemical coagulation, membrane transition, etc. are all conventional water quality treatment technologies, and will not be described in detail here. In this embodiment, the waste water treatment sheet-q, flat 7L 6 is a 10 5 ι〇15 2〇1242413 w / permeability treatment machine, the obtained recovered washing water is used for 10 Recycling. "Used for research in the field of Φ 軎 / pt related to clear °, = for the removal of agricultural drugs and water quality treatment, etc. 'By the smoke of the present invention | Qu ~ Bei Cai" Examination, hot doubt From ground to the following buttons: Fruit ^ cleaning and shochu method can indeed achieve I effectively improve the removal efficiency of pesticide residues on the surface of vegetables and fruits 14.
農華利=音波震靈作用能有效去除蔬果14表面的殘留 以’问時配合溶於清洗水！ W 氧化分Μ你田 Τ炙吴虱此對農樂產生強痛 :: Γπ能有效去除蔬果14表面難清除與難分 二=，同時，於洗淨過程中配合對於清洗水 測，進-步輔料認蔬果14表面殘留農藥確實 古除，因而相對能明顯提昇整體之農藥去除效率 問題效改善-般農藥清除法等對於農藥去除效率不彰等 2·對於蔬果14的保鮮成效佳： 於超音波震盈作用與臭氧的強氧化分解能力，能有效β =蔬果Η表面的殘留農藥，加上臭氧之殺菌保鮮特性 —洗水1 〇之低溫特性，同時能達到蔬果i 4的良好保鮮 成效，有效改善-般農藥清除法於控制不當（例如：於利 1加熱烹㈣時’加熱時間過長）時，容易影響蔬果鮮度 寻問題。 3·適用於大量絲Η之清洗作業，能有效節省人力： 由前所述，於超音波震㈣用與臭氧的強氧化分解能 11 1242413 力，月匕有效去除蔬果14表面的殘留農藥，同時配合對於 清洗水i 〇之水質變化谓測，不旦能控制蔬果i 4之多㈣ 洗程，且能確知蔬果14表面殘留農藥確實已有效去除Γ 5 10 15 20 相當適用於清洗大量蔬果14，並有效節省人力成本 效改善:般農藥清除法之耗時與作業繁複，而不利於大量 蔬果之 洗作業等問題。 4·清洗後廢水能回收再利用，確保環境零污染： 再者’由於農藥能被臭氧有效分 ’解：無毒的簡單化 合物’所產生的清洗後廢水不會對環境造成太大的不良 影響’再“收集並處理成特定用途的时水得以達 再利用之效，有效改善-般農藥清洗法所 有農藥的清洗廢水，直接排放而對環境造成污染 等問遞。 ㈣圖1與圖3 ’為本發明之蔬果農藥清洗與保鮮處理 一第二較佳實施例，其中’與該第一較佳實施例不 於該水體前處理步驟11中，水體是經由-電解 水機處理’而得分別呈電解驗性水（pH約為9〜u)與電解 酉^生水（PH約為2.5〜5)特性的二股清洗水10，並分別導 达入排序刀別為第—與第二的洗淨槽體2巾。另外，水體 經由一逆滲透處理機處理，而成R〇水特㈣清洗水1〇並 導送入排序為楚— > ”、、弟二的洗淨槽體2内。而由於電解水機之電 解水原理即為_ 与一奴水於電解時所產生的氧化還原反應機制 ’故.、相關處理機制恕於此不再詳述。 接著於忒多重洗淨保鮮步驟12中，是先將蔬果14置 12 1242413 放入承裝有電解驗性水特性之清洗水lG的洗淨槽 藉由清洗水10之驗性特性，能夠分解部分農藥（例 碟農藥），同時，能增強農藥分子與蔬果14表 有 性相斥力，有助於農藥自蔬果丨 有效電 盪作用配人下，* & 专除而於超音波震 下辰樂即能更有效地自蔬果U表面移除，加 上臭氧對於曲農藥之強氧化分解力，相較於該第-較佳實施 例，整體之農藥去除效率能更加提昇。 貝 ίο 15 20Nonghuali = sonic shock effect can effectively remove the residue on the surface of vegetables and fruits 14 W oxidizing fractions M and T can cause strong pain to Nong Le: :: Γπ can effectively remove the surface of vegetables and fruits 14 which are difficult to remove and difficult to divide into two =. At the same time, in the process of washing, cooperate with the measurement of washing water. The auxiliary material recognizes that the pesticide residue on the surface of vegetables and fruits 14 is indeed eliminated, so it can significantly improve the overall pesticide removal efficiency. The general pesticide removal method is not effective for pesticide removal. 2. The freshness preservation effect of vegetables and fruits 14 is good. Seismic action and strong oxidative decomposition of ozone can effectively β = residual pesticides on the surface of vegetables and fruits, coupled with the sterilization and freshness characteristics of ozone-low temperature characteristics of washing water 10, and can achieve the good freshness and effectiveness of fruits and vegetables i 4 and effective Improvement-General pesticide removal methods are not properly controlled (for example, when the heating time of Yuli 1 is too long), it can easily affect the freshness of vegetables and fruits. 3. It is suitable for the cleaning of a large number of silkworms, which can effectively save manpower: As mentioned above, it can use the strong oxidative decomposition energy of ozone for ultrasonic shocks 11 1242413, and the moon dagger can effectively remove residual pesticides on the surface of vegetables and fruits 14 at the same time. As for the change of the water quality of the washing water i 〇, Bhutan can control the washing process of fruits and vegetables i 4, and it can be confirmed that the pesticide residues on the surface of fruits and vegetables 14 have indeed effectively removed Γ 5 10 15 20 It is quite suitable for washing a large number of fruits and vegetables 14 and Effectively save manpower and improve cost-effectiveness: The time-consuming and complicated operation of the general pesticide removal method is not conducive to the washing of a large number of vegetables and fruits. 4 · Wastewater can be recycled and reused after cleaning to ensure zero pollution to the environment: Furthermore, 'because pesticides can be effectively separated by ozone' solution: non-toxic simple compounds ', the generated wastewater after cleaning will not cause much adverse impact on the environment' Re-collection and treatment of water for specific uses can achieve the effect of reuse, effectively improve the general pesticide cleaning method for all pesticide cleaning wastewater, which is directly discharged and causes pollution to the environment. ㈣Figure 1 and Figure 3 A second preferred embodiment of the vegetable and fruit pesticide cleaning and fresh-keeping treatment of the present invention, wherein 'the first preferred embodiment is not in the water body pre-treatment step 11 and the water body is treated by-an electrolyzed water machine', respectively Two cleaning waters 10 with the characteristics of electrolyzed test water (pH about 9 ~ u) and electrolytic water (pH about 2.5 ~ 5), and lead to the first- and second-cleaning sorting knives, respectively. Tank 2 towels. In addition, the water body was processed by a reverse osmosis treatment machine to form RO water special cleaning water 10 and was introduced into the cleaning tank body 2 sorted by Chu- > And because the principle of water electrolysis of the water electrolyzer is the redox reaction mechanism generated by _ and a slave water during electrolysis, so the relevant processing mechanism will not be described in detail here. Next, in step 12 of multiple washing and freshness preservation, first place the fruits and vegetables 14 12 1242413 into the washing tank containing the washing water 1G of the electrolyzed test water characteristics. With the test characteristics of the wash water 10, it can decompose the part Pesticides (such as dish pesticides), at the same time, it can strengthen the sexual repulsion between pesticide molecules and fruits and vegetables, and help pesticides to self-vegetate. Effective oscillating effects are suitable for people. * &Amp; Except for the ultrasonic shock Chenle That is, it can be more effectively removed from the surface of vegetables and fruits U, and the strong oxidative and degrading power of ozone on koji pesticides, compared with the first preferred embodiment, the overall pesticide removal efficiency can be further improved. Shell ίο 15 20
I +同時配合該水質_單Μ對清洗水U)水質監控，者 :果Η料人承裝有電解酸性水特性之清洗水Μ的下: 2槽體2中時，於超音波震盪作用與臭氧氧化作用下， ；:有效分解去除蔬果14表面農藥之際，藉由清洗水10之 :=性’更能與臭氧相配合而達到雙重的蔬果14殺菌保 、果14依序經由排序為第—、二之洗淨槽體2等洗 而導送入最後的洗淨槽體2内時，同樣地，直至清 《氧化還原電位未達所相對應之警告值，且不隨清 "間增長而變動’蔬果14即已呈完全潔淨狀態。 r —閱圖2為本發明疏果清淨裝置的一較佳實施例，用 水^ I 14表面殘留農藥於清洗水10中洗淨，而該清洗 壯疋為R〇水且水溫是維持在約丨5〜20。(：。該蔬果清 '置包3〕用以承裝清洗水1〇且呈 狀的洗淨槽 …超曰波辰覆單兀3、一臭氧供應單it 4、-水質债 、’單元5，以及一廢水回收處理單元6。 4超音波震盈單元3具有三能產生超音波的超音波震 13 ίο 15 20 1242413 盪機31，是分別接觸式設置於該三洗淨槽體2底面處。每 一超音波震盪機31所產生之超音波能量會傳遞至清洗水ι〇 中亚產生氣穴現象（cavitati〇n)，利用此氣穴現象對於蔬果 14表面所產生的衝擊作用力，得以將蔬果14表面的殘^專 藥予以震盪移除。 辰 該臭氧供應單元4具有三能產製臭氧的臭氧機4ι，以 及—刀別與該二臭氧機41連結並分別設置於該三洗淨槽體 2底部内的輸氣管42。每-輸氣管42是設置於距離所相^ 應洗淨槽體2底部約5〜1G公分處，藉以將所相對應臭氧機 41產製之臭氧順暢地導溶人清洗水1()巾。將純引溶入先 淨槽體2内之清洗水1G中，洲臭氧之強氧化力即能迅. 速將朗於蔬果14表面或溶於清洗水1G巾的農藥予以氧 热尽買偵测單元 三洗=體2内部’用以監控該三洗淨槽體2内：清洗: 化本:控制蔬果14的洗程順序’或是更換清洗水 分別監控讀取位於該三洗淨貞槽]體=^^^ 原電位變化。當蔬果所處之清洗二 的氧化還 …曰拟“ /月/先水10的氧化還原電位已達 ，則51設定的警告值，且不穩定地持續變化時 内：Ϊ淨之蔬果14移送至下-排序的洗淨槽趙2 "。!仃下一波洗程，同時更換該洗淨槽體2内之清洗 幻=重複作業，讓蔬果持續進行多重洗淨作業/ 、口收處理早π 6是與該三洗淨槽體2相連通， 14 ίο 15 20 1242413 王X回收自洗淨槽體2排放出之清洗後廢水，並進一步處 理成能供利用的回收水。本實施例中，該廢水回收處理單 是-逆滲透處理機，故回收之清洗廢水經由處理後， 即能成RO水以供循環再利用。 於進行蔬果14清洗作業時’蔬果14於置放入洗淨槽 ]中後Μ用超曰波辰盪作用能有效去除蔬果14表面的 1 留農藥，配合溶於清洗水1G中之臭氧能對農藥產生強氧 曲=解作Lx有效去除蔬果14表面難清除與難分解的 辰桌’加上臭氧之殺g保鮮特性與清洗水之低溫特性， 5 t此對疏果14產生良好的保鮮成效。同時偵測計$丄 2所相對應洗淨槽體2内之清洗水10進行氧化還原電位 、田'月洗水10内之農藥量增高，臭氧量逐漸消耗，導 κ 10之氧化還原電位達該警告值時，則需將蔬果14 移送往下-排序之洗淨㈣2巾持續清洗（或是進行清洗 水10更換），以達到進行多重洗淨作業之目的。直至，於 最後之洗淨槽體2的洗淨與浸泡洗務過程中，所相對則貞 :汁5”斤測得的清洗水1〇氧化還原電位已穩定而不變動 日守’表不殘留於蔬果14表面的農藥已幾乎被有效分解去除 。错以進-步輔助確認蔬果14表面殘留農藥確實已有效去 除’而呈完全潔淨狀態’同時’相對能彰顯出整體 去除效率。 辰采 另一方面，自洗淨槽體2排放出的清洗後廢水則统一 於該廢水回收處理單元6中收集處理，處理後產生的回收 水則此供以再利用，能達到水資源回收再利用與環境保護 15 5 10 15 20 1242413 之效 因此，藉由該超音波震盪單元3方 相配合，讓農藥於超音波震逢作用氧供應單元4 用下，能有效自蔬果14表面清陝一、虱強虱化力分解作 鮮度；同時於該水質_單元^除能有效維持蔬果14 蔬果〗4洗程，以進行多重洗％。之里控下，能自動地控制 藥去除效率，有助於大量蔬果’施有效提昇整體的農 農藥清洗法之農藥去除效率L 14 f洗作業，明顯改善-般 且過程繁複耗時而不利於:旦=14鮮度難以保持， 裝置，利用超音波清洗與保鮮處理方法及其 配合該水質❹I單元5之㈣與臭氧之強氧化力， 將殘留於蔬果14上之㈣…平作業桓式， ^ 〇 n . A 辰樂有效去除，且有效維持蔬果14 . b^,J^14 旦月顯k幵整體的農藥去除效率，相當適用於清洗大 里疏果14，故確實能達到本發明之目的。 ^ 、所述者，僅為本發明之較佳實施例而已，當不鲁 一、此限定本發明貫施之範圍，即大凡依本發明申請專利 fe圍及1明况明書内容所作之簡單的等效變化與修飾，皆 應仍屬本發明專利涵蓋之範圍内。 【圖式簡單說明】 圖1疋一流程圖，說明本發明蔬果農藥清洗與保鮮處 理方法之-第-較佳實施例； 圖2疋一農置示意圖，說明本發明蔬果清淨裝置之一 16 1242413 較佳實施例；以及 圖3是一流程圖，說明本發明蔬果農藥清洗與保鮮處 理方法之一第二較佳實施例。 17 1242413 【圖式之主要元件代表符號說明】 11 水體前處理步驟 12 多重洗淨保鮮步驟 13 廢水回收再生步驟 10 清洗水 2 洗淨槽體 3 超音波震盪單元 31 超音波震盪機 4 臭氧供應單元 41 臭氧機 42 輸氣管 5 水質偵測單元 51 偵測計 6 廢水回收處理單元 18I + at the same time with the water quality _ single MU on the cleaning water U) water quality monitoring, the following: the person carrying the washing water with the characteristics of the electrolytic acid water: 2 tanks 2 in the ultrasonic vibration effect and Under the effect of ozone oxidation,: When effectively decomposing and removing pesticides on the surface of vegetables and fruits 14, by cleaning the water 10: = sex can better cooperate with ozone to achieve a double protection of vegetables and fruits 14 sterilization, and fruits 14 are ranked first in order. — When the second cleaning tank 2 is washed and guided into the final cleaning tank 2, the same, until the "redox potential does not reach the corresponding warning value, and does not follow the cleaning" Growth and change 'The fruits and vegetables 14 are now completely clean. r—See FIG. 2 for a preferred embodiment of the fruit thinning and purifying device according to the present invention. The residual pesticide on the surface of the water is used to clean the washing water 10 in the cleaning water 10, and the cleaning strength is Ro water and the water temperature is maintained at about丨 5 ~ 20. (: The vegetable and fruit clear 'Set Package 3] is used to hold washing water 10 and a washing tank in the shape of ... Super Bossian Cover Unit 3, an ozone supply unit it 4,-Water Quality Debt,' Unit 5 And a waste water recovery and treatment unit 6. 4 The ultrasonic vibration unit 3 has three ultrasonic vibrations capable of generating ultrasonic waves 13 15 15 1242413 Oscillator 31, which are respectively disposed in contact with the bottom surface of the three washing tank body 2 The ultrasonic energy generated by each ultrasonic oscillator 31 will be transferred to the washing water, and the cavitation phenomenon (cavitation) will be generated in the central Asia. Using this cavitation phenomenon, the impact force on the surface of the vegetables and fruits 14 can be obtained. The residual medicine on the surface of vegetables and fruits 14 is removed by shaking. The ozone supply unit 4 has an ozone generator 4m capable of producing ozone, and-a knife is connected to the two ozone machines 41 and is separately installed in the three washings. The gas pipe 42 in the bottom of the tank 2. Each gas pipe 42 is installed at a distance of 5 to 1 G centimeters from the bottom of the corresponding tank 2 to clean the ozone produced by the corresponding ozone machine 41 smoothly. Dissolve the person in the washing water 1 () towel. Dissolve the pure water into the washing water 1G in the cleaning tank 2 The strong oxidizing power of ozone can quickly. The pesticides on the surface of vegetables and fruits 14 or 1G towels dissolved in washing water are heated with oxygen. Buy the detection unit three washings = inside the body 2 to monitor the three washing tanks. In the body 2: cleaning: chemical: control the washing sequence of the fruits and vegetables 14 or change the washing water to monitor and read the three washing chase tanks] body = ^^^ original potential changes. When the fruits and vegetables are in the cleaning second The oxidation also ... said "/ month / Xianshui 10 has reached the redox potential, then the warning value set by 51, and it is constantly changing steadily: the clean fruits and vegetables 14 are transferred to the bottom-sorted washing tank Zhao 2 "! 仃 In the next wave of washing, replace the cleaning in the washing tank 2 at the same time = repeated operation, let the vegetables and fruits continue to perform multiple washing operations /, and the mouth is closed as early as 6 and the three washing The clean tank 2 is connected, 14 ίο 15 20 1242413 King X recovers the washed wastewater discharged from the clean tank 2 and further processes it into recyclable water that can be used. In this embodiment, the wastewater recycling treatment unit is -Reverse osmosis treatment machine, so the recovered washing wastewater can be converted into RO water for recycling and reuse after treatment. During the cleaning operation of vegetables and fruits 14, the vegetables and fruits 14 are placed in the washing tank], and the super-wave wave effect can effectively remove the 1 remaining pesticide on the surface of vegetables and fruits 14, and the ozone energy dissolved in the washing water 1G Produce strong oxygen curve for pesticides = interpret Lx to effectively remove the hard-to-remove and hard-decompose the surface of vegetables and fruits 14 ', plus the killing characteristics of ozone and the low-temperature characteristics of washing water, this will produce good freshness for sparse fruits 14 At the same time, the redox potential of the washing water 10 in the washing tank 2 corresponding to $ 丄 2 was detected, and the amount of pesticides in the Tian'yue washing water 10 increased, and the amount of ozone was gradually consumed, leading to the redox of κ 10. When the potential reaches the warning value, the fruits and vegetables 14 need to be transferred to the bottom-sequential cleaning ㈣ 2 towels for continuous cleaning (or replace with washing water 10) to achieve the purpose of multiple cleaning operations. Until, during the washing and immersion washing process of the final washing tank 2, the relative value is: the redox potential of the washing water measured by the juice 5 ”kg has stabilized and does not change. The pesticides on the surface of vegetables and fruits 14 have been almost effectively decomposed and removed. It is wrong to further confirm that the pesticide residues on the surfaces of vegetables and fruits 14 have indeed been effectively removed 'and are in a completely clean state' while at the same time relatively showing the overall removal efficiency. The cleaned wastewater discharged from the washing tank 2 is collected and treated in the wastewater recycling treatment unit 6, and the recovered water generated after the treatment is reused, which can achieve water resource recycling and environmental protection15 5 10 15 20 1242413 Therefore, with the combination of the three sides of the ultrasonic vibration unit, the pesticide can be effectively removed from the surface of vegetables and fruits 14 by the use of the ultrasonic supply unit 4 of the oxygen supply unit. It can be effectively decomposed into freshness; at the same time, the water quality unit can effectively maintain fruits and vegetables 14 fruits and vegetables 4 washing courses to perform multiple washing%. Under the control, it can automatically control the removal efficiency of the medicine, which helps a lot of The fruit application effectively improves the pesticide removal efficiency of the overall agro-pesticide cleaning method. The L 14 f washing operation is significantly improved-it is generally complicated and time-consuming and unfavorable: once the freshness is difficult to maintain, the device uses ultrasonic cleaning and fresh-keeping treatment. Method and its combination with the strong oxidizing power of the water quality unit I unit 5 and ozone to remove the residues on the fruits and vegetables 14 ... flat operation type, ^ 〇n. A Chenle effectively removes fruits and vegetables 14 b ^ J ^ 14 Once the overall pesticide removal efficiency is quite suitable for cleaning Dali Shugu 14, it can indeed achieve the purpose of the present invention. The above mentioned are only the preferred embodiments of the present invention, When it is not first, this defines the scope of the present invention, that is, any simple equivalent changes and modifications made according to the contents of the patent application of the present invention and the contents of the 1 clear statement should still fall within the scope of the patent of the present invention. [Brief description of the drawings] Fig. 1 is a flowchart illustrating the first-best embodiment of the method for cleaning and keeping fresh fruits and vegetables pesticides according to the present invention; Fig. 2 is a schematic diagram of an agricultural plant illustrating one of the fruits and vegetables cleaning device 16 12424133 is a flowchart illustrating a second preferred embodiment of the method for cleaning and keeping fresh fruits and vegetables and pesticides of the present invention. 17 1242413 [Description of the main symbols of the main elements of the drawing] 11 Steps for pretreatment of water 12 Multiple Washing and freshness step 13 Wastewater recovery and regeneration step 10 Washing water 2 Washing the tank body 3 Ultrasonic vibration unit 31 Ultrasonic vibration machine 4 Ozone supply unit 41 Ozone machine 42 Gas pipeline 5 Water quality detection unit 51 Detection meter 6 Wastewater recycling treatment Unit 18