TWI239351B - Particles for supporting surfactant and process for preparing the same - Google Patents

Abstract

The present invention relates to particles for supporting a surfactant and a process for preparing the same. Further, the present invention relates to high-density detergent particles using the particles for supporting a surfactant, and a process for preparing the same. According to the present invention, there can be obtained particles for supporting a surfactant which are excellent in the supporting ability (supporting capacity/supporting strength) for the liquid surfactant composition, and particles for supporting a surfactant which are excellent in the absorption properties (supporting rate) for the liquid surfactant composition, by spray-drying a preparation liquid obtainable by a process comprising the steps of preparing a first preparation liquid comprising a solution or slurry comprising a water-soluble polymer and a water-soluble salt; and subjecting the first preparation liquid to a treatment of increasing a number of water-soluble salt particles, thereby preparing a second preparation liquid having an increased number of water-soluble salt particles, as compared to the number of water-soluble salt particles which are present in the first preparation liquid. Further, since the liquid surfactant composition is supported by the particles for supporting a surfactant, detergent particles which are excellent in detergent performance, quality and the like can be efficiently obtained.

Description

1239351 A7 Five Invention Description (1 B7

I

Technical Field The present invention relates to a surfactant-supporting particle group and a method for producing the same. The present invention relates to a high-density particle group using the surfactant-supporting particle group and a method for producing the same. [Background Art] One of the methods of personal cleansing agents includes a method of making a liquid interface active and holding it on a surface active agent-bearing particle group. In this manufacturing method, a high altitude handle for the liquid surfactant can be obtained from the granule group for the carrier of the agent, that is, a carrier obtainable from the granule group for the carrier of the surfactant ^ can be carried A large amount of &lt; liquid surfactant (supporting capacity), and two factors that can be strongly held inside the particle without the liquid surfactant once absorbed, mixing force. The loading capacity is blended with the required cleaning performance, and after I * biocide, the "liquid surfactant 2" is inhibited due to the supporting force 2 'to prevent the powder from being washed with reduced fluidity, agglomeration and liquid interfacial agent. It is important to migrate on the container and its surface. From the viewpoint of productivity, the characteristics of fast-absorbing liquid surfactant (supporting speed) can also be obtained from the surfactant-supporting particle group. J The structure that can be obtained in the surfactant-supporting particle group with a load-carrying capacity ^ A sufficient pore volume inside the particles can increase the load-carrying capacity, so as to have a (fine-pore size and high load-bearing capacity) Hope. With such a structure, by using fine particles, the particles are in contact with each other and maintain sufficient space on one side, which can be obtained as particles for supporting surfactants. The source of the fine particles is water solubility in the detergent composition Salts. For example, for cleaning,-.. <Representative water-soluble salts, NkCO3 can be used. NkCOs are used in pulp 4-, and, the scale of the scale is applicable to China's national standard (cns) a4 specifications ⑵ G χ 297 Dong) I measure the amount of living

---------------- (Please read the note on the back? Matters before filling out this page)

I 1239351 5. In the description of the invention (2), the monohydrate of NaAO3 and sodium acid sulfate, which is a double salt with sodium sulfate, form fine needle-like crystals, which are used in the surface-active secondary support particles. Inner Shao may form a base for effective support sites. As a technique for achieving this, it is disclosed in JP-A 6 2 _ 丨 12697 that crystal growth from an organic substance having at least 3 carboxyl groups in the molecule = an effective amount of the whole agent, which is mixed in the pulp before sodium carbonate. Sodium carbonate hydrate and / or sodium carbonate are formed in the slurry by adjusting crystal growth, and then the slurry is spray-dried to obtain a dry powder with high adsorption capacity (Λ particle group for surfactant loading) Method. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs However, the supporting capacity of the surfactant-containing particles obtained by this method is not sufficient. For this reason, the amount of finely divided sodium sulfate carbonate dispersed in the slurry before spray drying may be insufficient, and the amount of sodium carbonate carbonate in the particles obtained by spray drying may be insufficient. Fine needle-shaped crystallized carbonic acid sulfate steel is an effective base for improving the carrying capacity. In this technology, due to the dissolved sodium sulfate, sodium carbonate sulfate is generated on the surface and near the surface of granular sodium carbonate, which is mostly solid. And the aggregate with large particle size exists. Therefore, there is less sodium carbonate in the form of fine needle-like crystals in the slurry. Sodium carbonate in the form of fine needle-like crystals can be obtained. After spray-drying, it also becomes agglomerated with a large particle size in the particles. The volume and pore diameter are large, and the sufficient load carrying capacity cannot be expressed. Also, as a crystal growth regulator, a particularly effective polymer polyacrylate (polymer) is formed as a film on the particle surface, and as a detergent composition, if a polymer having an effective amount or more is blended, is the obtained particle sufficient? Use the ability to carry capacity. In this bulletin, the amount of polymer in the granules is about 丨 ~ 2 -5- This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) 1239351 V. Description of the invention (Consumer Cooperative of Employees of Intellectual Property Bureau, Ministry of Economic Affairs) When printing less than% by weight, also consider Qian Qian +, Twist of the Presence, Γπ: r ~ ..., large (supporting capacity, water-soluble polymer <blending amount, do not add some Limitation of the degree: The soluble polymer is the surface of the particles after drying with a dry mold to form a surface containing: two guests who are different from others, and they are lowered to the surface. The degree of reduction is reduced. Therefore, the supporting speed is reduced. = Γ: It is also supported on the surfactant-supporting particle group. The two-purpose particles = ^ hunting causes the surfactant to be supported on the surfactant-supporting pair. Recognize the effective production of clear particle groups, and further improve the ::: = r invention of the liquid surfactant composition of particle groups. Therefore, the subject of the present invention is to provide a liquid surfactant composition which is superior_ Supporting energy (supporting capacity / supporting force) of the surfactant-supporting particles ς group Θ Method for producing surfactant-supporting particle group, the liquid surfactant composition I is a surfactant-supporting particle group having excellent absorption characteristics (supporting speed), and cleaning using the surfactant-supporting particle group Agent particle group η attack π detergent particle group detergent composition and method for producing detergent particle group using the surfactant-supported, particle group. In view of the object of the present invention and other objects, the following description should be applicable. That is, the gist of the present invention is related to π] containing a step of preparing a preparation solution containing an aqueous polymer and a water-soluble salt, and a step of supporting the surfactant in the step of spray-drying the preparation solution obtained from the preparation step. The method for preparing the particle group, the preparation steps of the aforementioned preparation solution include ± Note-page order-6- this paper size shipping standard (0 × 297 cm) 1239351

Description of the invention (Azalea preparation is the first preparation made by containing a water-soluble polymer and water-solubility, and the Liangxi cattle formula is combined or prepared from a pulp table &lt; step and (b) the aforementioned first salt is prepared: particles The process of increasing the number of preparations is the same as that existing in the second: "Preparation: The number of particles * is larger, the number of particles is larger, the second method is to prepare particles for the surfactant-supporting particle group, [Mr polymer and water-soluble salt preparation spray drying station :: particle group for surfactant loading, by mercury porosimeter fineness: cloth read diameter is less than u micrometer, via hole G1 ~ 3G micrometer The pore volume is more than 3 liters / gram or more, and it is a group of particles for supporting surfactants having a particle strength of 15 to 100 MPa., [3] A surfactant containing a water-soluble polymer and a water-soluble salt Holding granules, at least a part of the particles constituting the particle group have a middle / portion inside, and the surface of the particles is open, and has the interfacial activity of particles (submerged particles) in the shape (submerged holes) communicating with the internal hollow portion. The particle group for the carrier, the agent [4] includes the particles contained in the agent according to the method described in [1] above. 100% by weight of the interfacial active particle-supporting particle group or the surfactant-supporting particle group described in the above [2], and the bulk density of the step of mixing 10-100 parts by weight of the surfactant composition is 500-1000 The production method of grams per liter of detergent particles is based on the system of printing of consumer cooperatives by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs [5]. The surfactant particle-supporting particle group of 1,000 parts by weight, and the detergent agent particle group of 10-100 parts by weight of the dense 500-1000 g / L detergent group, [6] containing The detergent composition of the detergent particle group described in [5]. Brief description of the figure The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 5. Description of the invention (5 of the interface of the figure) Appearance of active particle group 1 Figure 2 is the SEM photo of the JT trapped particles / sections of the particles and the cut surface in Table 7. Figure 3 shows the figure of the trapped image. ^ 'The particles seen from the surface Figure 4 is the dotted line shown in Figure 3.

Ground-cutting of the sunken particles:, :: ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, (,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, ~ ,,,,,,,,,,,,,,,,,,,,,, and, and to, and from the Sides 1 · Definition of term = granules for supporting bright surface active agents refers to granules obtained by spray-drying a preparation liquid containing na == salts for supporting a booking composition, and its aggregate is called interfacial activity The agent-supporting,, and q / liquid particles are particles containing 2% of the surfactant / cleaning agent particles, which are formed by the liquid-phase surfactant composition and the surfactant-supporting particles. Group means its aggregate. The detergent composition means each and every alpha detergent particle group, as desired, in addition to the detergent particle group, plus / 4, plus m detergent ingredients (such as detergent particles, fluorescent dyes, enzymes :, Perfume, defoamer, bleach, bleach activator, etc.). In this specification, the preparation liquid is sometimes referred to as "first preparation liquid" and "second preparation liquid" The first preparation liquid is obtained by treating the first preparation liquid. The water-soluble salt particles present in the i-th equipment liquid mean undissolved matter and precipitates derived from water-soluble salts. Undissolved matter means that it is added to the raw material in the first preparation liquid, which is a water-soluble salt that exists as a solid that is difficult to dissolve in the liquid phase. The precipitate means P is a water-soluble salt generated from the liquid phase of the first I preparation liquid. Kind of solid. -8-V. Description of the invention () From 夂 / ♦ sex salts "means that the water-soluble salt itself or its double salt or erroneous salt = water / hydrated salt has a solubility of 0.55 water per gram. Those who use the knife amount v to 1000. The water-soluble polymer is an organic polymer having a solubility in water of 2 5 :: 0.5 g / 100 g or more, and a molecular weight of not less than noodles. Water-insoluble substances are less soluble in second-generation water. 5 g, 100 (solid. The liquid surfactant composition is a composition containing a surfactant that is liquid or pasty when supported on the surfactant-supporting particle group. 2. Interface activity The support of the agent-supporting particle group can improve the surfactant-supporting particle group (hereinafter also referred to as the support particle) to the south. As a required characteristic, the particle has a Xu Xi inside. A visually active surfactant composition (hereinafter also referred to as a liquid composition) (space (supporting part)), that is, a large pore volume inside a particle, and a large supporting capacity for a liquid compound, and The small pore size inside the particles has a strong holding force for the liquid group &amp; material, and also supports the granules, and has a high holding speed for the liquid composition for effectively utilizing the supporting part inside the particles and It is necessary to have particle strength when mixing and manufacturing detergent particles for carrying a liquid composition, etc. In addition, the preparation liquid containing the water-soluble polymer and the water pure silk is dried, and the obtained particles for supporting the surfactant are dried. Group, it can improve the particle strength while improving the loading speed The method is reviewed. It is now possible to make the volume of the two pores inside the granules obtained by spray-drying the preparation liquid larger by increasing the number of particles of the water-soluble salts present in the spray-drying preparation liquid, and Make the pores inside the particles smaller and at the same time suppress the particles 1239351 A7 V. Invention Description (7 B7) The wisdom of the employees ’cooperatives printed on the surface of the printed film has formed an unprecedented brand-new fact. Large particles of rr salts, By increasing the number, fine particles are dispersed and exist. In addition, the fine particles are present in the inside of the spray-dried two drops of the liquid droplets of the preparation liquid. Thus, they exist in a dispersed state; = :; the = Soluble particles, dry in the mouth mist == The knife stays loose, which helps to form the supporting part. Also, P, the water-soluble salts in the preparation liquid, by increasing the number and drying it. The granules are used for the liquid composition of ___ = = charm. In addition, it was found that the fine water-soluble salt preparation liquid-phase liquid-phase water-soluble salt spray-dried water-soluble salt ':: ： The seed of precipitation The role of the situation. The finely identical salt and / or, two ;: containing a solid phase with the water-soluble salt dissolved in the preparation solution: η / or the salt of a solid, etc., to make a salt; to disperse: = =, The water-soluble knife falling in the liquid phase of the preparation liquid dares to spray the fine seeds of the seed crystals as the core polymer's crystal growth adjustment effect. More effective use. The load obtained by this manufacturing method becomes more effective, the diameter becomes smaller, the load of the liquid-liquid composition is smaller, the particle strength is also higher, and the load support is superior to the above interface. Group of active agent-carrying particles: manufacturing scaly detergents containing osmates and Jingxin: one: sometimes effective, in the manufacture of uncleansing agents that are difficult to achieve load-bearing,

Sheet crystal hole is also issued% This paper size is applicable to China National Standard (CNS) A4

A technique that has a particularly high effect. The internal structure of the surfactant-supporting particle group of the present invention can be confirmed as a pore volume distribution of the supporting-particle group using a mercury porosimeter. The distribution of the pore volume near the pore diameter inside the carrier particles measured with a mercury porosimeter (for example, "Shimadzu Bosai Saisai (Water T-inch Cut" 9320 "manufactured by Shimadzu Corporation) Hereafter referred to as the pore volume distribution), the larger the pore volume 4 is, the larger the carrying capacity of the liquid composition is, and the smaller the pore size is, the capillary phenomenon can maintain the ability of the liquid composition once absorbed (Supporting force) becomes higher. Therefore, the larger the pore volume and the smaller the pore diameter, the higher the holding capacity of the surfactant I, the larger the amount of the liquid composition can be supported, and the exudation of the liquid composition can be suppressed at the same time. Therefore, the particle diameter of the pore volume distribution (the obtained pore volume distribution has the largest pore volume in the obtained pore volume distribution) of the particles of the surfactant-supporting particles of the present invention suitable for supporting the liquid composition is 15 micrometers or less, 1.3 micrometers or less, u micrometers or less, 10 micrometers or less is preferable, 0.9 micrometers or less is preferable, and 0.8 micrometers or less is preferable. Also, the present invention relates to the surfactant-supporting particle group. Pore volume 'pore size 〇1〜 A pore volume of 3.0 microns is more than 0.3 ml / g, a pore volume of 0.01 to 2.5 microns is preferably more than 0.3 ml / g, and a pore volume of 0.01 to 2.0 microns is 0.33 ml / g. More preferably, the pore size is more than 0.01 g, and a pore volume of 0.01 to 1.5 μm is more preferable, and the pore volume is 0.01 to 1.0 μm, and the pore volume is more than 0 3 mL / g. The range of each pore diameter, the pore volume thereof is more preferably 035 ml / g or more, and 0.4 liters / g is more preferable. The particle strength of the surfactant-supporting particle group of the present invention is self-added -11-this paper Standards apply to China National Standard (CNS) A4 (210 X 297 mm)

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1239351

The liquid surfactant composition is habit-resistant. ^ When it is first formed in the gadolinium particle group, it prevents the particles constituting the particle group I from collapsing and reduces the carrying capacity. <Viewpoint, horse 5 ~ 200 MPa, preferably 10 ~ 150 MPa , Better] s 1ηΛ ^ ^ MPa, which is also preferably 20 to 8 c MPa, particularly preferably 25 to 60 MPa. Also, the strength of particles can be described in the method described in the physical property measurement method described later. Determination. The surfactant-supporting particle group of the present invention has the above-mentioned preferred pore volume distribution and better particle strength. As a preferred physical property, the pore volume distribution (with a mold diameter of less than L5 microns and a pore volume of qgi ~ 3 ′ microns with a pore volume of 0.3 ml / g or more 'and a particle strength of 15 to 100 watts. Better The physical and physical properties are that the pore size distribution is 1.1 micrometers or less, the pore volume is 0.1 to 2.0 micrometers, the volume of the pores is 3 ml / g or more, and the particle strength is 20 to 80 MPa. 3. Water soluble in the preparation solution The method of increasing the number of particles of the alkaline salts in the mouth (a) the step of preparing the first preparation solution made of a solution containing a water-soluble polymer and a water-soluble salt; and (b) the above-mentioned preparation solution The process of increasing the number of particles of water-soluble salts to prepare and compare the number of particles in the first preparation liquid and the number of particles of the i-salts to the second preparation liquid In the preparation liquid preparation step, the treatment of increasing the number of particles of water-soluble salts was reviewed, and the following methods (i) to (3) were found. The method of increasing the number of particles of water-soluble salts in the examples (1) to (3) below is referred to as a second preparation solution. (1) The water-soluble salts dissolved in the first preparation solution are precipitated. (2) The water-soluble salt particles in the first preparation solution are wet-pulverized. 12- This paper size is applicable to China National Standard (CNS) A4 (21 × 297 mm)

1239351 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 10 ------ V. Description of the invention () (3) In the condition that it is substantially insoluble in the presence of the first preparation liquid, it will interact with the first preparation liquid Microparticles of the same or different water-soluble salts in the water-soluble salts are added to the first preparation solution. Furthermore, a combination of two or more of the methods (1) to (3) above is a preferred form of the present invention. In addition, as a result of reviewing a method for precipitating a water-soluble salt dissolved in the first preparation solution described in (1), the following method was found. (1 -1) A fine crystal precipitation agent is added to a 1st preparation liquid. (1-2) The first preparation is concentrated. (1. 3) The temperature of the first preparation liquid is adjusted to reduce the amount of water-soluble salts dissolved in the first preparation liquid. Furthermore, by combining two or more of the methods (1_1) to (1-3), precipitation of water-based cereal salts is a preferred form of the present invention. In addition, as a method for confirming that the number of particles of water-soluble salts in the second preparation liquid is larger than that of the first preparation liquid, for example, the following in-line granular droplet monitoring system (rTSUB-TECM1 manufactured by LASENTEC) can be used. 〇〇 "). The confirmation method is shown below. Weigh 1000 grams of preparation solution in a stainless steel beaker of i liter, and adjust it in a thermostatic bath at the same temperature as that of the preparation solution, and stir at a speed of 200 1 &lt; / min with 3 pieces of 2 × 4 cm thrusters. Wings spin and stir. The in-line granular monitor system (tsub_tec M100) made by LASENTEC was immersed in an angle of 45π relative to the liquid level of the standing preparation solution, and the person was installed at a position 3 cm below the liquid level. As a result, the particles hit the surface of the window during the stirring. The software used is ". This is f〇r

-13-

1239351 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (Servicing Mver5.4Build58b "(manufactured by LAS Ec). The focus position is set to the position from the surface of the window to the inside. G2 mm is the focus. Measurement The period (-time of the measurement) was 14.5 seconds. The average (moving average) 足 was measured with i0. The count at the time of measurement at 5 minutes (number / second) was measured. The i-th preparation liquid and the second preparation liquid were measured. The above measurements compare the number of counts obtained. That is, the P preparation solution has more counts than the "preparation solution, so in the second preparation solution, it can be confirmed that the number of water-soluble salt particles is larger than that of the preparation solution." This increase in the number of counts can be directly confirmed when the second preparation liquid is prepared from the i-th preparation liquid by using the above-mentioned in-line granular particle monitoring system. Here, the particles with the water-soluble salts present in the first preparation liquid For the comparison of the number of particles, the number of particles of the water-soluble salts that are increased in the number of particles of the water-soluble salts present in the first preparation liquid cannot be limited. For example, the second preparation liquid obtained by the above method and丨 The difference in the number of counts of the preparation solution is preferably 500 or more per second, and more preferably 1,000 or more per second. Moreover, the water-soluble salt is not only present in the second preparation liquid in the above method. The number of sub-types is increased by a treatment that also increases the amount of water-soluble salts that are insoluble in the second preparation solution (that is, the aforementioned (1) or the aforementioned (3) or a combination of (1) to (3) Treatment of more than 2 methods) Increased water-soluble salts that are insoluble in the second preparation liquid (ie, precipitates from water-soluble salts and / or added to the first preparation of microparticles that are intended to be water-soluble salts) The amount is preferably 3% by weight or more relative to the amount of water-soluble salts dissolved in the first preparation solution before the method is performed. Since the inside of the particles after spray-drying forms a more effective supporting site, The view that the load can be improved is more preferably 5% by weight or more and 8% by weight or more. — — — — — — — — — III Γ III ^ 11111-- (Please read the precautions on the back before filling this page) -14-

121239351 V. Description of the invention (Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs: ΐ2% or more is the best. On the one hand, from the viewpoint of the rationality of the second preparation solution obtained by spray drying, the method ^ The amount of water-soluble salts in the liquid phase: :: 30-30% / 0 is even better, 25% by weight is the best. The water-soluble salts that make insoluble in the preparation solution, the water-soluble salts The amount α (%), two 'two :: rate = rate =. In the liquid ... sex: the first kind of ::; τ: etc. can be as water soluble as the preparation solution, the solubility of water-soluble salts can be as follows Calculate., Prepare the liquid decompression material, measure the water concentration ρ (%) in the New Zealand, measure by the far infrared heat and measure the water content (made by Shimadzu Corporation), etc. In addition, :: Water in the liquid 'grain salt The concentration s (%) can be obtained by ion chromatography, etc. The preparation solution (water is Q (%), and the water-soluble salt content rate of the preparation solution, τ (/.) ', Can be obtained by the following formula. Water-soluble salts, dissolution rate u (%). Degradation rate (%) = (100 xsx Q) / (p XT) ⑴ However, the calculated dissolution rate exceeds 100 % At 100 ° / .. The undissolved rate v (%) can be obtained by the following formula.

Order 15- The standard of this paper standard (CNS) A4 (210 x 297 mm) 1239351

V. Description of the invention (13 ΟΙ)

Undissolved rate (%) = 100-U The content of water-soluble salts in the first preparation solution is T1 (%), the dissolved rate is Ul (%), and the undissolved rate is V1 (%). The content of water-soluble salts in the second preparation liquid is T2 (%), and the undissolved ratio is V2 (%), so it is insoluble before: the increase amount a (%) of water-soluble salts in the second preparation liquid, The following formula can be obtained.

Increasing amount of water-soluble salts insoluble in the second preparation solution a (%) = 100 X (T2 X V2-T1 X V1) / (T1 X ui) (III) The first preparation liquid of the alkaline salt type is followed by a treatment for increasing the number of water-soluble salt particles present in the first preparation liquid, and the water-soluble salts existing in the second preparation liquid are increased by this treatment. The finer the particles, the smaller the pore diameter of the supporting particle group obtained by spray drying, and the greater the effect of improving the supporting capacity. From its point of view, the average particle diameter of the particles of the water-soluble salts present in the second preparation liquid increased by this treatment is preferably 40 μm or less, more preferably 35 μm or less, and more preferably 30 μm or less. Among them, 20 μm or less is preferable, 15 μm or less is more preferable, and 10 μm or less is most preferable. This average particle diameter is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, which is the particle size distribution of the particles in the second preparation liquid measured by the following measurement method, minus the degree of the particles in the first preparation liquid Distribution, the average particle size obtained. The particle size distribution of the particles in the 1st or 2nd preparation liquid, using the in-line granular particle droplet monitor system (LASENTEC Corporation 16 paper size measurement applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1239351 A7 V. Description of the invention (14 B7

The water-soluble salts in the preparation solution ("TSUB-TECM100") produced by the staff of S Bureau can be found in the homogeneous branch measured in "TSUB-TEC M100" described in this manual, which is beyond the particle size distribution using this point. It is measured when the fish front ζ /, and the test ridge are measured for 5 minutes. In addition, the intermediate code (grain =;: =, the same method of measuring f is used to average the particle diameter. Also, the existence of the same as the flat :: contains the same valley as the water-falling salts dissolved in the preparation solution :: and = : To become a liquid phase soluble in the preparation solution: and = seed crystals during precipitation during the re-drying process are preferred ~ particles of the wind-like to soluble salts' in the spray-drying process 2: water-solubility of the heart water phase Eucalyptus at the time of salt precipitation. * The liquid in i preparation: ^ seed crystal in ^ as the core, the water precipitated during the mouth mist drying process :: a fine needle for regulating the formation of polymer crystals: precipitation, in order to improve On the supporting part inside the particle, fine crystals can be effectively precipitated out of the inside of the supporting particle obtained by the mist drying, so that the field hole control is smaller, and the strength and the particle relative to the liquid composition can be improved: The strong point is that the particles of the water-soluble salt of the seed crystal are fine and most are preferred. 4. The absorption of the liquid surfactant composition by trapped pores is promoted as a group of particles for supporting the surfactant. Conditions for showing high load-carrying energy ^ There must be many liquid-like interfaces in the particles The entire composition (supporting part) of the sex agent composition is "simultaneously" used in the production of powder detergents, and the fast-absorbing liquid f-surfactant composition is particularly important for improving productivity. As mentioned above, it will contain general water-soluble polymers. And water-soluble salts

-17- This paper size is applicable to Chinese National Standard (CNS) A4 specifications (trip X 297 Gongai 1239351 A7 V. Description of the invention (15 B7 Consumption of intelligent staff of the Ministry of Economics ::: lacquer) is mainly due to evaporation of water It is carried out from the sprayed droplet surface and water, and the water-soluble components dissolved in the preparation solution are moved, and the particles obtained after the mist-drying are dried, and become a coating film composed of a surface spherical η type and a water-soluble polymer. Covering 2Γ: The coating formed on the surface of the particles becomes the main reason for the liquid interface activity, and the absorption or delay of absorption within the particles. The two groups of liquid surfactant compositions, the formation of =界 Interference = 干燥 Dry: granules' available-generally spherical or by spraying droplets: from the surface to the inner aggregate, from the surface-like surfactant combination of the spray-dried granules by needles, etc. Open the holes and find that the liquid spray dries and sprays, that is, by writing into the interior, "Er Shao has a hollow part, and the surface of the particles is open, and the shape of the liquid: the surface and the surface are sunk) No holes), and found that the particle group for carrying: Surfactant granules with excellent holding speed Γ 2 :, more Γ: advanced manufacturing :: particles for holding holes (clogged particles ^, ；; when the spraying process is dry, the surface of the particles is sunk) Prepare the heart into a range 'and adjust the inclusion conditions of the sunken particles in the adjustment system, which can obviously make the spray-dried particles Mingxin sunken particles more detailed. Basically, relative to the particles, there are fe / and holes (holes) to J. ) Existence. This traps the hole and makes the liquid interface active

%

I -18- This paper standard is applicable to China's (quot; (cns) A4 regulation1239351 A7 B7, invention description (16) The absorption of sexant composition, which fully expresses: 'Due to the interference of droplets, etc., in 1 particle Moderate :::; Several trapped holes. There may be multiple trapped holes. 5 Description of the trapped particles: :: Invention: The particle group for carrying "has a particle surface opening, and its shape (sunk hole)" The "particle (sinking particle)" is a particle having an appearance as shown in the figure η, and has a break as shown in Fig. 2: pores: It is preferable that the sinking particle contained in the supporting particle group of the present invention is = Size. It is equivalent to the diameter of the circle of the particles. As shown in Figure 3, with ^ hole = opening as the center, use a microscope to take pictures of the particles. Use the projection area (si) of the particles measured from the wide particle image. The formula (π) can be equivalent to the diameter of the circle of the particle = 2 X (SI / tt (IV). Also, the diameter of the circle that is considerably reduced (sinks the hole) is used as the opening 郅 as shown in Fig. 3. The projected area of the particle is measured in the same way. The projected area (S2) of the particle can be obtained by formula (V). I! (Please read the back first Matters of Note Pou # &lt;? Complete this page) k.

--TTi ^ ------- The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the diameter (V) equivalent to the circle of the hole and is used as the microscope for the above-mentioned foot measurement. For example, a digital microscope VH_6300 manufactured by KeyenCE and Hitachi (company) made s_40000 shape electric field 19- U39351 A7

1239351 A7 V. Description of the invention (18 B7 More than 70% printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, more preferably 80% printed, it is best to hope.。 上 '100% or less, in the present invention as the aforementioned The sinking has the size of the above-mentioned sinking holes (constituting particles, for example, *, spherical particles without sinking holes, etc., :::: ;; = 裂 之 粒 = 广 31, and more :: again, In the content ratio of the sunken particles of the present invention, the following mesh sizes are: Mi Yi: 卩: Guang_The prescribed mesh is f Wei 0 micro Zhu, 710 micron, 500 micron, 355 micron, 25 micron, 180 micron, and 125 micron | &lt; 9 ^^ | ^ Φ ^, τ ^ ^ ^ Without the 9 slave masters and wares, they will carry the granules for the women's clothing on the Vitapu machine (mouth-evening 7 7u-&gt;) (heik〇 fine SHO system, Light tap: 156 times / minute, rotation: 2900 times ^), 100g <capture 1 () of vibration; after sieving, the weight of the pan and the 4 particle groups of each sieve are calculated to calculate the weight frequency of each particle size (T1 Weight% ... 'T1G weight%). Secondly, from the sieving samples of each particle size, more than two particles are called by machine, and (a), and the investigation of each particle size is equivalent to the aforementioned trapped particles. The number of particles (VI a, ..., a Vl〇). In addition, the content ratio (VI / ϋΐ, ... · V 1 0 / U 1 0) of the above-mentioned sinking particles of each particle size is the total content multiplied by the aforementioned weight frequency as the content ratio of no particles. 6. Composition of the particle group for supporting the surfactant The particle group for supporting according to the present invention is mainly composed of a water-soluble polymer and a water-soluble salt. Water-soluble polymers and water-soluble salts, for liquid interfaces -21 This paper size applies the Chinese national standard 疋 4 specifications (210 X 297 mm) h

It is important that the printed material group of the consumer co-operative group of the Intellectual Property Bureau of the Ministry of Economic Affairs carry the printed material and form a trap hole. In addition, water-soluble polymers have the effect of imparting strength to particles. ~ As a water-soluble polymer, a polymer selected from cellulose derivatives such as a carboxylic acid polymer, carboxymethyl cellulose, etc., and polyamino acid version of polyglyoxylate, polyaspartate, etc. can be exemplified. More than one kind of substance, soluble starch, saccharides, etc., among them, the acidification of the polymer based on the miniaturization of water-soluble salts, and the cleaning power, specifically, the blocking of the role of metal ions, since the clothing will The effect of dispersing solid particles in the washing tank and preventing the particles from re-adhering is more preferable. Among the carboxylic acid-based polymers, acrylic acid alone polymers and their salts (Na, κ, NH4, etc.), acrylic maleic acid copolymers and their salts, κ, nh4, etc. are particularly preferred. The weight-average molecular weight of these water-soluble polymers is preferably from 10,000 to 300,000, more preferably from 20,000 to 100,000, and even more preferably from 20,000 to 80,000, of which from 5,000 to 50,000 is particularly preferred. As a molecular weight measurement method, it is from 6,000 to 20,000, and is converted to a standard material: AMERICAN STANDARDS CORP. 2. Eluent: 0.2 moles per liter of phosphate buffer solution / Ch3CN: 9/1 (volume ratio ) 3. Tubing: PWXL + G4000PWXL + G2500PWXL (Cambodia (East Y) (company))

4 · Detector: RI 5. Sample concentration: 5 mg / ml 6. Injection volume: 0 ″ ml-22- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) —- ----------- (Please read the precautions on the back # 'Fill this page first') 1239351 A7 Five invention description (20 B7 7 · Measurement temperature: 40 ° C 8 · Flow rate: 1 · 〇 亳 liter In addition to the polymers, core polymers such as polyamino sulfonate, bamboo cellulose and polyaspartate can also be used as metal ion blocking energy, dispersing energy, and pollution prevention energy. For this and other things, we can use polyvinylpyrrole to call propylene, as the content of the particles for carrying the dimerized water T polymer is better, 6 to 26% by weight. Jia Er is the second high: ~ 22% by weight is the best. Within this range, the strength of the particles becomes a water-soluble salt, which can be I and its heart &amp; lean, carbon bismuth group, sulfuric acid group, hydrogen carbonate ... : Belongs to ΐ :: = salt ^ metal chloride (eg, magnesium) chloride, bromide, iodine, printed by the Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs

Order: Two: daggers and selenium compounds. In addition, double salts containing these (for example, Buck and Tebu Mbu) and sesquicarbonate steel can also be mentioned. Among these, 'carbonate, sulfate and sulfite are preferred. Carbonate is better in the washing liquid as a test agent that shows a suitable Indian buffer. Solid salts such as sulfate: sulfite have high dissociation degree. It is suitable to improve the washing liquid (ionic strength, sebum oil cooling). Washing etc. Also, the sulfite has -23- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 Public Love '1239351 A7

22 1239351 V. Description of the invention (preferably 1: 0 to 1: 1. Also, the cleaning performance when the surfactant group-containing particle group detergent composition is self-contained is different: degree "is made μ (carbon slave Sodium and / or sodium sulfate): (water-soluble polymer) The preferred weight ratio is 19: 1 ~ 1: 1, more preferably 15: 1 ~ 15: 1, even more preferably ι〇ι ~ 2: 1 It is preferably 8: 1 to 2.5: 1. As the water-soluble salts, low-molecular-weight water-soluble organic bismuth salts can also be used, such as citrate, fumaric acid, and the like. From the point of self-cleaning power, there can be mentioned methylimine diacetate, imine diacetate, ethylenediamine disuccinate, taurine diacetate, and hydroxyethylimine diacetate. Acetate, alanine diacetate, hydroxyimino disuccinate, methylglycine diacetate, glutamate diacetate, asparagine diacetate, and serine diacetate are preferred. The content of water-soluble salts in the supporting particle group is preferably 20 to 90% by weight, more preferably 30 to 80% by weight, and most preferably 40 to 70% by weight. , Then carrying particles The particle strength becomes very high, and the solubility of the detergent particle group is also good. Also, the particle group for supporting the surfactant of the present invention may contain a water-insoluble substance. As the water-insoluble substance, crystalline aluminum silicon may be used Clay compounds such as acid salts, amorphous silicates, silicon dioxide, hydrated silicic acid compounds, Bharat (August ^ 4b) bentonite, etc., because the liquid surfactant composition helps to support Reasons for maintaining and not promoting the occurrence of undissolved residues are preferably crystalline aluminosilicate and amorphous aluminosilicate. The average particle size of the aluminosilicate is preferably 0.1 to 10 microns, more preferably 05. ~ 5 microns. -25- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

1239351 A7 B7 23 V. Description of the invention () As a crystalline aluminosilicate, a type A zeolite is suitable (for example, the trade name: "Duoyou Aid Cleaner (Bu 3 Dagger, Xiao Xi" 1); Dongsuo (company ), Trade name: "synthetic zeolite"; Japanese company's cleaning aid (dagger 'Shixi'); company name, "VALFORIOO"; PQ CHEMICALS (Thailand) company, trade name: "ZEOBILDER"; ZEOBUILDER company , Trade name: "VEGOBOND A"; OMAN CHEMICAL INDUSTRIES company, trade name: "Zeolite"; THAI SILICATE CHEMICAL company), better in terms of metal ion blocking energy and economy. Here, the type A zeolite uses JIS The oil absorption capacity of the K 5101 method is preferably 40 ~ 50 ml / 100 g. Other types include P type (such as the product name Γ Doucil A24 "and" ZSE 064 "; manufactured by Crosfild; oil absorption capacity is 60 to 150 ml / 100g) and type X (for example, trade name: "WessaithXD"; manufactured by Degussa; oil absorption capacity 80 ~ 100ml / 100g). The mixed zeolite described in International Publication No. 9842622 can also be cited as a suitable crystalline aluminosilicic acid Salt and metal It can also be used as a water-insoluble substance, such as amorphous aluminosilicate and amorphous silicon dioxide with high oil absorption energy but low oil absorption energy. For example, Japanese Unexamined Patent Publication No. 62-191417 can be used at the bottom right of page 2. Line 19 to 5 of the upper left column, line 17 (especially the initial temperature range of 15 to 60 ° C is preferred), Japanese Patent Application Laid-Open No. 62-191419, page 2, lower right column, line 20 to page 5, bottom left Amorphous aluminosilicate as described in line 11 (especially oil absorption of 170 ml / 100 g) and JP-A-9-132794, column 17, line 46 to 18, line 38 , Japanese Patent Application Laid-open No. 7-10526, column 3, line 3 to 5th column, 9th column, Japanese Patent Application Laid-open No. 6-227811, column 2, line 15 to column 5, line 2, Japanese Patent Application Laid-open No. 8-119622 Non--26 described in column 2 line 18 to column 3 line 4 7- This paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) ^ — — κ ----- -¾ Pack (please read the precautions on the back before filling this page) Order i * ------ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1233351 A7 B7 V. Invention Description (24 Intellectual Property Bureau of the Ministry of Economic Affairs Staff consumption Fei Cooperative Co., Ltd. prints crystalline aluminosilicate (oil absorption 285ml / 100g). For example, you can use "Special Fragmentation (Bu Xi Shi Yi / 1 /) NR" (manufactured by Tokuyama Soda (V — Xi) (company) : Oil absorption capacity of 210 ~ 270ml / 100g), "Flora (? Kouichijin 4b "(same company: 400 ~ 600ml / 100g oil absorption capacity)," TIXOLEX25 "(manufactured by Hanfo Chemical Co., Ltd .: 220 ~ 270ml / 100g oil absorption capacity)," Siro Pure "( Inch 4 mouth 1 £ 7 7) (Fuji Debisong (Yu, 4 dagger, yy) (company): oil absorption carrier 240 ~ 280 ml / 100 g) and so on. In particular, as an oil-absorbing carrier, those described in Japanese Unexamined Patent Publication No. 6-179899, column 12, line 12 to column 13, line 1 and column 17 to line 34 to column 19, line 17 are suitable. The water-insoluble substance may be composed of a single or plural components. The content of the supporting particles in the case of a water-insoluble substance is preferably 8 to 49% by weight, more preferably 16 to 45% by weight, and 24 to 40% by weight 0 / 〇. A group of surfactant holding particles with superior particle strength and solubility. In particular, as the supporting particle group of the present invention, the content of the water-soluble polymer is 2 to 30% by weight, the content of the water-soluble salts is 2 to 9 g% by weight, and the content of the soluble substance is 8 to 49% by weight. Those are better. As other ingredients, it is possible to mix the surfactant 弟 ^ 2 preparation solution containing surfactants in the group of carrier traitors and the group of crickets, and spray-dry to manufacture the group of particles for holding. In the step, since the surface of the obtained particles for carrying Ai Ai has a tendency to form a film, as a result, the absorption rate of the particles for the carrier κ and the group of particles to be used for the liquid surfactant composition is absorbed. It is not only to reduce fatigue, ^ _ direction, the formation of trapped holes is suppressed. Therefore, from this point of view, it is better to have a smaller loading content, and it is better to make the interface = in the weight (the surfactant is not present, the surfactant is better. From the nature of the load also-t 丨 丨丨 Order ----- I --- (Please read the Zhuyin on the back? Matters # 'Fill in this page)

27- This paper size applies the Chinese National Standard (CNS) A4 Hu ^ Γ (__ 21 () x 297 ^ y V. Description of the invention (5). = Noodles = The content in the particle group for carrying is better. ~ 3 If the weight is not included, it is particularly preferably G to 1% by weight. Among them, substantially SIS; an example of a biocide is the same as the carrier-supported particles (the surfactant-like surfactant composition described later). === Group :: In the case of particle strength of high-loading particle group, amorphous ageing. When water-insoluble substances such as aluminum silicon bismuth salt are prepared, the supporting particle group is co-produced over time. The material for the second system of the carrier is an agglomerate that is difficult to fall into water. Therefore, the salt of this hair is also soluble in the first substance, and it is better not to contain it. In addition, the crystalline broken acid sample is not mixed with humans. It becomes amorphous, so it is the same as the amorphous crushed acid salt. "Second = the preparation solution is:... :: The second obtained after spray drying without the use of osmic acid :: spray mixing c: Preparation of liquid acid :: =,! Liquid acid salt ... contained in the second system, more preferably 5% by weight or less, == salt salt, and substantially free of 10% by weight or less. It is preferably 2% by weight or less, preferably 'Auxiliary ingredients such as pigments in the particles for carrying. The subsidy is equal to 10% of the weight of the ingredients, dyes, and yeast. "Bottom is better, more preferably 5fold = the next grain is used, below. Particularly preferred is 2% by weight 7. Preparation method of surfactant-supporting particle group The surfactant-supporting particle group of the present invention can be printed by printing the A7 containing the following steps: 1239351 B7 V. Description of the invention ((a) and step (b) The second preparation liquid obtained by spray drying is ready. Ash step (a): Preparation of water-soluble polymers and water-soluble salts or pulp Step 1 of the first preparation solution, &amp; &amp; Step (b): The treatment of increasing the number of water-soluble salt particles in the preparation solution mentioned above, stomach preparation and water solubility existing in the first preparation solution Comparison of the number of particles of the salt type, the second step of preparing the liquid when the number of particles is increased, and the step of drying the preparation liquid prepared by the method containing the steps (a) and (b), may The second preparation liquid is directly dried, as required, for example, to improve the rationality of the preparation liquid It is also possible to provide drying after the steps of dilution and defoaming. For the drying method, all drying methods can be used, such as freeze-drying, drying under reduced pressure, etc., and it can be used to increase the number of particles in the preparation solution. From the viewpoint that the water-soluble salt particles can effectively carry the liquid composition, it is better to dry the preparation liquid instantly. Therefore, the particularly preferred drying method is the spray drying method. The spray drying tower can flow to the flow tower, and The flow tower is used in any form, but from the point of productivity, the flow tower is preferred. As a heat source of the spray drying tower, a pulsating shock wave dryer using a pulsating burner can also be exemplified as one of the preferred drying devices. In the pulsating shock wave dryer ', because the droplets of the preparation liquid for drying are dried in the high-temperature combustion gas accompanying the shock wave, the drying speed of the droplets becomes faster. As an example of a pulse shock wave dryer, there is a wave control (six small mouth y) (manufactured by Osaka Fuji Industry Co., Ltd.). For the better style of step (b), as mentioned above, it can be divided into -29- This paper size applies Chinese National Standard (CNS) A4 (210 X 297 cm)

1239351 A7

IIIII 4 I23935l A7 V. Description of the invention (28 B7 Printed by the Consumers 'Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs = two effective f-bearing sites, as the precipitation-'. Sodium carbonate and / or sodium sulfate is preferred. Fine Crystallized swords, gold a swords and horses are hunting materials added to the first preparation liquid to precipitate the effects of this precipitation, 17 (Λ from water-falling salts. Micro-fine crystal precipitation agent is a water-soluble substance In this case, the step before the addition indicates that for the case where the first preparation solution contains a water agent at 夭: 27 / preparable salt 1 ^. In this case, the temperature at which the fine crystals precipitate out of the water dissolving agent is its dissolution strength. Compared with water-soluble salts 3 or solution: the strength of dissolution is greater. The so-called dissolution strength means that the soluble shoe crystal precipitates #j. The water solubility of the first preparation liquid = 2 can be selected in various ways. It can be used as a fine crystal precipitation agent The force can be obtained in the following manner. For example, when a water-soluble substance c :; V and ° / Γ capacity: a saturated solution of salts a and water-soluble salts b, dissolve nine complex salts and In the case of the precipitation of substances from b, such as salt, H is more soluble than b The degree is large, 4 is a fine crystal precipitation agent. One is, for example, added in the order of sodium sulfate, sodium carbonate, and sodium chloride, and a saturated solution of sulfur and sodium carbonate is a fine needle of sodium carbonate and norbark ait sulfate. Crystals are precipitated without agglutination. This known shape, chlorine, is better than sulfur-containing fine crystal precipitation agent. The top carriage also uses the fine crystal precipitation agent to precipitate the fine crystals in the preparation solution. For the second The size of the crystals precipitated in the preparation solution can be measured using the aforementioned in-line granular droplet monitoring system ("tsuB-Te manufactured by LASENTEC. J) -31-This paper size applies to the Chinese National Standard (CNS) A4 specification (21〇 X 297 public love)

ίί-¾ Pack ----- I order ------- Bu 4 &gt; First read back vg 胄 夂 stomach ^ 1239351 A7

Also known as "fine fine micro-knob" ^ mountain line intragranular granule droplets;: / Precipitation effect, can be seen by adding ^ the number of particles over time = can be seen by adding the precipitation agent :::: in sodium carbonate With the preparation solution of sodium sulfate, the fine crystal precipitation agent &lt; tolerance method can be exemplified. ,, And diarrhea methods to prepare a saturated solution containing sodium sulfate and sodium carbonate. 400 g of sodium sulfate (99% purity) was added to 1500 g of ion-exchanged water adjusted at the preparation temperature of the first preparation solution, and the solution was stirred for 20 minutes in a constant temperature bath at the preparation temperature of the i preparation solution to dissolve. 400 g of sodium carbonate (heavy ash (〒, y / ash), manufactured by Chuo Glass Co., Ltd.) was added, and the mixture was stirred for 30 minutes to prepare a suspension. The supernatant solution was recovered after the suspension was left to stand or filtered. Suspension method to prepare a saturated solution of sodium sulfate / sodium carbonate, and the first preparation temperature here refers to any temperature in the range of 30 ~ 8 (rc.) In a 1 liter stainless steel beaker Weigh 1000 grams of the sodium sulphate / sodium carbonate saturated solution prepared in the above method, in a constant temperature bath that becomes the preparation temperature of the pulp, etc., at a speed of 200 rpm, stir the wings with 3 propellers of 2x4 cm. Stir. In the same way as above, start the measurement in the LASENTEC in-line granule monitoring system. Add 100 grams of the test sample within 30 seconds, and continue to stir and measure for 60 minutes. After 60 minutes The average particle size (the cumulative length of the number of particles is 50% of the code (mouth length)), fine crystals of sodium carbonate and / or sodium sulfate below 40 microns, such as sodium carbonate and its hydrates, Analysis of at least one of sodium sulfate and hydrates, double salts of sodium carbonate and sodium sulfate情 情 32- This paper size is applicable to Chinese National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling this page) _ 装 tTi · ------- Ministry of Economy Wisdom Printed by the Consumer Property Cooperative of the Property Bureau Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1239351

V. Description of the invention (30 ^ mm product rides on the micro-junction of ㈣ and / or sodium weird and the 'precipitated fine crystals' average particle diameter is better to be bright rice, more preferably to less than 1 meter, most preferably to less than 1G microns Also, the precipitation is analyzed and identified by X-ray diffraction, elemental analysis, etc. As the fine crystal precipitation agent 'can be exemplified as sodium, mai = or soil metal vapors, deserts, moths, emulsions: ★ Also '(salts. In addition, ethanol, methanol', acetone, etc. are compatible with water / capacitors and (anhydrous) zeolite, etc. That is, the 'fine crystal precipitation agent' uses the micro crystal precipitation agent μ to dissolve and hydrate, etc., to deprive the first preparation liquid for dissolving the water-soluble salt = two, and the horse has a solution for making the water-soluble salts from the i-th preparation liquid. The base of the effect of phase precipitation. The viewpoint of 2 degree of solution is better 'bromide and broken compound, and the stability of self-cleaning agent particle 2 is preferably chloride, and because of the cleaning performance ::: alkali Metal salts are preferred. Among them, from the economic point of view, sodium chloride is used as a fine crystal precipitation agent at the interface. Dongli in the active agent-carrying particle group "cleanliness from the viewpoint that the precipitation effect of fine crystals is fully exhibited," and that the washing performance can be maintained for 5 substances, preferably 0.2 to 35% by weight,- 3. Better by weight% i ~ 25% by weight is even better, of which 2 ~ 2qinmajia, 4 ~ 15% by weight is particularly good. Also, the solubility of the water-soluble fine crystal precipitation agent in the second preparation solution is the second 1 more solution was dissolved in the solution part of the preparation solution, so that the second preparation solution cap produced more precipitates. For the particles of the carrier particles obtained after spray drying, 33 Guan Tzu Xian (CNS) A4

1239351 A7 V. Description of the invention (B7 The second form (bearing part, so that the structure has a better structure, high life is good. The fine crystal precipitation agent is better to 80 weight. / To t) ~ solution rate, It is preferably 75% by weight or more, external weight% :::: and more preferably 85% by weight or more, of which it is preferably completely dissolved.-Medium is also preferably "% by weight or more, and the best is: ?? precipitation The dissolution rate of the agent in the second preparation liquid can be combined with a bulletin-type moisture meter (island chapter II decompression test data, infrared heating production ... Made by the company) to determine the water concentration in the filtrate. The moisture content of the preparation liquid of the fine crystal precipitation agent di 屮 二 Μ 罘 2 in the filtrate is Q (%), and the content of the fine junction preparation liquid is used as the formula to calculate the fineness: the dissolution rate in the precipitate state °, but the calculated dissolution A ten-mesh shape with a rate of more than 100% has a resolution of 100%. Concentrate (Please read the precautions on the back before filling this page}

Dissolution rate (%) = (100 XSXQ) / (PX Τ) (VI) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, so that the first preparation solution contains sodium carbonate and sodium sulfate together. After the addition of sodium carbonate, it is better from the viewpoint of improving the carrying capacity of the particles. The water content of the second preparation liquid is preferably from 30 to 70% by weight, more preferably from 35 to 70%, from the viewpoint of effectively reducing the effect of the fine crystal precipitation agent from the non-degraded solution of the non-fine crystal water-soluble component. 65% by weight, preferably 40 to 60% by weight. In addition, the temperature of the preparation liquid, in terms of the amount of the water-soluble salts dissolved and the liquid-sending property, is preferably 30 to 80 °, and more preferably it is installed there. Order --------- 34- 1239351

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 3 5 ~ 75 ° C. As a specific example of the production method of this mode, for example, all or almost all of the water is initially added to the mixing tank, preferably after the water temperature reaches about a set temperature, and then other components are added for the i-th preparation liquid. As a preferred order of addition, a liquid component, sodium sulfate, sodium carbonate, and the like are added first. Further, a small amount of auxiliary components such as water-insoluble substances such as zeolite and dyes may be added. In a state where the solution of the first preparation liquid is partially saturated, a fine crystal precipitation agent is added, or in a state where the solution is partially unsaturated, it is added in an amount exceeding the amount necessary to make the solution partially saturated by adding the fine crystal precipitation agent '. The water-insoluble substance may be added before the fine crystal precipitation agent is added, and then added, and may be added before and after the division. Finally, in order to obtain a homogeneous second preparation solution, after adding all the ingredients to the preparation solution, it is preferably mixed for more than 10 minutes, more preferably more than 30 minutes. 7-1-2. Precipitation by Concentration of the First Preparation Solution As a result of reviewing the aforementioned method of precipitating water-soluble salts, it was found that a method of precipitating by concentrating the preparation solution was found. That is, by performing the operation of concentrating the water-soluble salts in a dissolved state in the presence of the water-soluble polymer to cause precipitation, most of the second preparation liquid can be finely crystallized. The concentration of the preparation solution of this style is further detailed. A method for obtaining a thickened slurry that is analyzed by a part of the water-soluble salts falling in the first preparation liquid by concentrating the first preparation liquid containing a water-soluble polymer and a water-soluble salt is described. First, the first preparation solution before concentration may be prepared by a known method, and the water-soluble polymer and water-soluble salt may be mixed in any order. In addition, in the case of mixing water-insoluble substances, it can also be blended before the first preparation solution is concentrated, concentrated -35- This paper size applies Chinese National Standard (CNS) A4 X 297 mm 1 ^ —.— &gt;- ----- (Please read the notes on the back first and fill in this t 1239351

Post blending is also possible. In addition, the concentration operation can also be performed by the second preparation solution of the crystallizing agent printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. ] If the mixing of the fine junction 2 with the undissolved water in the m-th stock solution before concentration is reduced, the loading particles obtained after spray drying are high. Therefore, the 'water-soluble salts' ratio is 1 before the concentration, and is preferably 5. ~ 10. % By weight, more preferably 9 to 90% by weight *%. The material rate is less than 100%. In the case of a very good horse, 4 hours, ri / 100, using the two ST machines described below to pulverize the first preparation solution to refine the undissolved matter is also a preferred form. The wet pulverization of the i-th preparation liquid can also be performed on the concentrated slurry. The dissolution rate of water-falling salts was measured by the method described above. Secondly, by concentrating the ith preparation liquid, water-soluble salts dissolved in the ^ preparation liquid can be precipitated. The degree of concentration can be measured by reducing the amount of water in the preparation solution. The amount of water reduction in the first preparation liquid is not particularly limited, and the amount of the water-soluble salts to be precipitated can be determined within a preferable range. The amount of water in the first preparation liquid is not particularly limited. As the concentration device, any type of concentration device may be used as long as it is generally used. For example, there are natural circulation type evaporation tanks that boil and rise liquid in the heating tube inside the evaporation tank, drop down the concentrated liquid collection tube collected in the center, and use circulating pumps to circulate liquid at high speed in the evaporation tank and heat Between the tanks, the evaporation tank can be used to evaporate the water, and the outer side is forced to circulate the evaporation tank, and the liquid thick self-contained heating tank is poured into the wall to form a uniform liquid film. Cans, these can be used alone or in multiple utility. There is also a flush-type evaporation device that evaporates moisture by ejecting the liquid heated above the boiling point in a decompression evaporation tank -36-This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) -III Γ (Please read the note on the back? Matters # | Fill in this page) Order i .-------

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1239351 V. Description of Invention (34) Effective. The first preparation liquid used in this mode produces water-soluble salts &lt; crystals by concentrating, so that scale can easily adhere to the concentration device. Therefore, a thickening device having a function of removing scale deposits and a thickening device which is difficult to use are more preferable. As the former device, there are devices that include: = agitating blades for extracting scale in a two-film flow-down evaporation tank, such as Waipu Chain (7 4 y (made by Kobelco Pantec (eight. &Gt; made by the company)). As the latter device, there is a Ross-evaporable fasting which has a plate-shaped heating element inside the evaporation tank, and the liquid is concentrated on the surface of the heating element under reduced pressure (the mouth is only 7 workers A). —) (Manufactured by Sumitomo Heavy Industries, Ltd.). 7-1-3 · Through the adjustment of the temperature of the i-th preparation solution to reduce the amount of dissolution, the result of reviewing the aforementioned method of precipitating water-soluble salts was found to make the water-soluble Method for changing the temperature of the first preparation liquid when the amount of dissolved salts is reduced. That is, the temperature is adjusted to reduce the amount of water-soluble salts dissolved in the first preparation solution. Precipitation of water-soluble salts in the state can cause most of the fine crystals to be precipitated in the preparation solution. For the precipitation in this style by adjusting the temperature of the preparation solution to reduce the solubility, it is more detailed. Containing water-soluble polymers and water-soluble Salt The first preparation liquid is prepared by changing the temperature of the first preparation liquid to reduce the dissolved amount of the water-soluble salts, so as to obtain a method of analyzing the second preparation liquid which is a part of the dissolved water-soluble salts. The first preparation solution before the temperature change operation can be prepared by a known method. In the case of mixing with water-insoluble substances, the first preparation solution -37-This paper size applies Chinese National Standard (CNS) A4 specifications. 297 public ^^ _i 丨 h ------- ^ install ------- (Please read the precautions on the back before filling this page) Order -------

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs &lt; Blended before the temperature change operation is also possible, and mixed into the factory after the temperature change operation is possible. In addition, water-soluble polymerization in the second preparation solution after the Yanhai operation = two parts is also possible. The crystal size of the water-soluble salts which can be analyzed by it is: can be saved. In addition, the temperature change operation may be performed on 1 in the same manner as the concentration operation. m The less the coarse particles of the undissolved water-soluble salts in the preparation solution before the temperature change operation, the smaller the particle size of the surfactant-supporting particles obtained: the higher the supporting energy. Therefore, the solubility of the water-soluble salts in the second liquid before the temperature change operation is preferably 50 to 100% by weight, more preferably "~ 丨% by weight, and particularly preferably 90 to 100% by weight. When the dissolution rate is less than 100% by weight, a wet pulverizer or the like described below is used to pulverize the first preparation liquid to make the undecomposed product finer. Wet pulverization of the preparation liquid is effective for temperature changes. The second preparation solution after the operation may be performed. In addition, the dissolution rate of the water-soluble salts is measured according to the method described above. Next, a part of the dissolved water-soluble salts is analyzed by changing the temperature of the first preparation solution. As a method for changing the temperature of the first preparation liquid, an apparatus having an external jacket layer and an internal coil can be used when preparing the first preparation liquid. The method of using such heating / cooling is used. The temperature of the preparation liquid is preferably set to increase the solubility of the water-soluble salts contained in the preparation liquid, and the optimum temperature is determined by the type and amount of the water-soluble salts to be blended. Temperature of preparation liquid, setting As a result, the solubility of the water-soluble salts in the preparation solution is low, but the type and amount of the water-soluble salts to be blended have to be selected for heating / cooling. As a raw material for cleaning agents, 38 paper standards are applicable to China National Standard (CNS) A4 Specification (210 X 297 Male 1) ~ Install i II. (Please read the precautions on the back first and fill in this page) tTi ------- 4 1239351 A7

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Description of the Invention (In the case of the first preparation of polycarboxylate and sodium sulfate produced by the printed consumer cooperative of employees of the Intellectual Property Bureau of the Ministry of Economic Affairs, it is formed into a buckyate derived from a double salt of sodium carbonate. Coarse particles formed on the surface where most of sodium carbonate is added. Barcette's existence of such large and coarse particles will almost help the formation of the supporting part of the supporting particle group by using wet The type pulverization effectively utilizes the miniaturization to form the supporting part of the supporting particle group, and the supporting capacity of the particle group can be improved. In addition, if the advantages of mixing sodium carbonate in the first preparation solution are stated, a dry pulverizer is used. When sodium carbonate is finely pulverized and mixed with the preparation solution, undissolved matter is hydrated and aggregated to form large coarse particles. When sodium carbonate is mixed with the i-th preparation solution and wet-pulverized, the agglomeration can be suppressed. Coarse granules are formed. The conditions of the wet pulverization are not limited to the pulverizing device used in the concentration of the water-soluble salts in the first preparation liquid. For the pulverizing device that can be used in this mode, only one Any of the known wet-type pulverizers can be used. As commonly used pulverizers, there are devices in the form of fine powder of a pulverizing medium, and (ii) devices in the form of finely pulverizing the gap between the pulverizing knife and the stator. i) The medium in the vertical cylindrical container is agitated with a stirring blade or a stirring plate, and the processing liquid is supplied from the lower part of the container, and is pulverized by the shear force generated by the difference in the flow velocity of the medium. The device that discharges the processing liquid from the upper part of the container. As a continuous type of such a device, there are a sander (made by Isuzu Machinery Manufacturing Co., Ltd., a general-purpose grinder (made by Mitsui Miike Co., Ltd.), and a return type Across micronizer (7x7 γ 彳 gan ') (Hosokawa Micron (shown V force 7 $ Xikou &gt;) (manufactured by)). As a horizontal type with the same structure, there is a Deno mill ( Evening, 4 SW) (manufactured by WAB). -40- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)-· III hi III · 11111111 · (Please read the note on the back first? Matter # | Fill in this page)

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1233351 V. Description of the invention (38) In addition, it is made of a cylindrical roll machine and a ring-shaped sleeve containing it. Liquid, diamond fine mill (Mitsubishi Heavy Industries (manufactured by the company), small ball mill (manufactured by Kobelco Pantec (manufactured)) for pulverization by the high-speed rotating force of the medium. The condition is (ii). It consists of a roller machine and a holder. When the treatment liquid passes through this gap, it is crushed by repeatedly applying shearing force to pulverize the colloid mill (made by Kobelco Pantec (company)), and the crushing structure (Bu U: / Yu Xiao) (Mitsui Miike Chemical Machinery Co., Ltd.), with the same pulverizing mechanism, a roller mill and a Golo mill with vermiculite (Xi, Kouichi $ A) ((Company) Gero Mechanical Engineering (/口 一 工 ： / 、 ：; 2 7 9 V, 、)), super-quality colloid machine (only-〆 一 YJ 口 彳 〆) (Zhengxing Industry (Company)), Kolandum mill (α Yu Y Xi ,, A $ A) (made by Kobelco Pantec (company)). In addition, there are turbines and stators Shear coarse pulverization, a homogeneous mill with a 2nd roll mill and fine pulverization of the holder (Shenren 5 74 y $ Sm) (manufactured by Special Machinery & Chemical Industry Co., Ltd.) In addition, it has both emulsification and dispersion and uniform mixing The wet emulsification and dispersing machine with micronization function, through the special shape of the high-speed rotating rotor and the fixed stator, and the strong impact of the liquid megahertz unit can be obtained with the high-pressure sentence pulp machine parallel dispersion effect of the strange Bitter Dragon (Feng Shi β Bukou &gt;) (made by Pacific Engineering Co., Ltd.) 7-3 · Addition of fine particles to the preparation liquid This pattern is prepared in step (a) from a water-soluble polymer and a water-soluble salt. The first preparation solution formed from the solution or slurry is added to the first preparation solution under the condition that step (b) is substantially insoluble in the presence of the first preparation solution. Style, "essentially insoluble in the first system -41-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling out this page) ---- ---- ^ --------- 1239351 A7 B7 Intellectual Property of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperatives 39-&quot; 1.- V. Description of the Invention () In the presence of the stock solution "means that the solution of the first preparation solution is partially saturated in the shape of a ridge, and the added particles do not dissolve. When the solution part is unsaturated, it means that by the addition of fine particles, it will be dissolved until it is saturated, and it will not be dissolved after reaching saturation. The particles of the water-soluble salts are water-soluble with the remaining residue of the first preparation solution. Alkali salts are essentially the same salts and / or salts that are the same as the water-soluble salts that are initially precipitated and / or salts that have the lowest dissolution strength in the second preparation liquid. In addition, fine particles of water-soluble salts are added. The aforementioned first preparation liquid may be prepared by a known method, and the water-soluble polymer and water-soluble salt may be blended in any order. In the case of blending a water-insoluble substance, the microparticles may be blended before the first preparation solution is added, and thereafter, the microparticles may be blended. As the fine particles of the water-soluble salts, fine particles having substantially the same composition as those of the water-soluble salts initially precipitated from the first preparation liquid are preferred. "The microparticles having substantially the same composition as the water-soluble salts originally precipitated from the first preparation liquid" refer to the case where the particles of the water-soluble salts are not present in the first preparation liquid before the microparticles are added, and when the microparticles are added In the previous i-th preparation solution, a substance that is precipitated when the water is evaporated and / or a substance that is precipitated when the temperature is changed is substantially the same composition of fine particles. As a method for producing the fine particles, a commercially available substance may be finely pulverized, but fine crystallization is more preferable in the presence of a water-soluble polymer. Specifically, a substance having the same composition as the fine particles is dissolved in water together with a water-soluble polymer, and is crystallized by spray drying or the like. Ball mills, impact mills, and roll mills include USV mills (made by Ube Industries, Ltd.) and MRS mills (Mitsubishi Heavy Industries (Company)) -42- (Please read the precautions on the back first # ^ Fill in this page }; €

-ϋ LI ^ a · 1 it I This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) 1239351 Printed by A7 B7 -j · 4〇A of the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives, Invention Description ()), SH mill (IHI), etc. As ball mills, there are dynamic mills (made by Mitsui & Miike Chemical Machinery Co., Ltd.), vibration mills (made by Chuo Chemical Machinery Co., Ltd.), etc. The pulverizer includes an atomizer (7 y Y Gan, 1), a pulverizer (Yashi Shi &lt; Yu 4 Gan, 1) (any one is made of powder (company)). When the average particle size of the fine particles is small, the effect of improving the support of the particles of the surfactant-supporting particles obtained by spray drying in the subsequent step becomes large. From this point of view, the average particle diameter of the fine particles is preferably 40 micrometers or less, more preferably 35 micrometers or less, and even more preferably 30 micrometers or less. Among them, 25 micrometers or less is preferable, and 20 micrometers or less is more preferable. It is even more preferably 15 micrometers or less, and even more preferably 10 micrometers or less. The average particle diameter was measured by the following method. 1,000 grams of ethanol was weighed in a 1-liter stainless steel beaker, and the stirring wings with 3 propeller blades of 2 x 4 cm were rotated and stirred in a constant temperature bath at 20 ° C at a speed of 200 rpm. Next, the above-mentioned fine particles were put into 20 g. In the aforementioned LASENTEC in-line granular monitoring system (TSUB-TEC M100), the particle size distribution at the time of measurement at 10 minutes was measured in the same manner. In addition, the average particle size is defined as the median code (the particle size when the cumulative number of particles is 50%). Also related to step (b) above, the treatment for increasing the number of particles of water-soluble salts is preferably selected from (1) adding a fine crystal precipitation agent to the i-th preparation liquid, and (2) concentrating the first Preparation liquid, (3) adjusting the temperature of the first preparation liquid to reduce the amount of soluble salts, (4) wet pulverizing the particles of the water soluble salts in the first preparation liquid, and (5) substantially In the presence of &lt; insoluble in the first preparation liquid, fine particles of water-falling salts which are the same as or different from the water-soluble salts in the first preparation liquid are preferably added to one or more of the first preparation liquid. According to the above-mentioned step and step (b), a second preparation liquid can be obtained. -43- This paper size applies Chinese National Standard (CNS) A4 regulations ^ 1〇x 297 public love) | installed ----- (Please read the precautions on the back first ^ fill out this page) f Order ----- -1239351

V. Description of the invention (Preparation method for printing and sunken granules by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economics) The present invention I prepares the particle group for carrying by at least one part of the particles constituting the particle group. Granules with a hollow part inside, and the surface of the granules is 7, and there are particles (submerged holes) in the shape communicating with the medium, preferably, from the surface of the granules carrying the surfactant to the inside, fine Needle design hole. It's a more efficient method for manufacturing the sunk particles of the present invention. It can make the interface activity of the second air preparation liquid mainly containing water-soluble polymer and water-soluble salts obtained by the method described in item i. The content of the agent is ˜2% by weight, and the water content of the second preparation liquid adjusted to increase the number of water-soluble salt particles is in the range of 35 to 65% by weight, and a method for spray-drying the preparation liquid. This month, the surfactant and water content of the second preparation liquid were adjusted in the aforementioned range, respectively, and the solid number of the water-soluble salt particles in the second preparation liquid was increased, that is, by making the water-soluble salt The presence of the class in an undissolved state allows The effect of significantly increasing the content rate of the sunken particles in the mist-dried particle group. The content of the second preparation liquid <surfactant increases from the content of the sunk particles in the particle group obtained by spray-drying the preparation liquid. From the viewpoint of the ratio, it is 0 to 2% by weight, preferably 1% by weight, and more preferably 0% by weight. The water content of the second preparation liquid is preferably 35 to 65% by weight. Moreover, the moisture content is' From the viewpoint of increasing the holding capacity of the supporting particle group and sufficiently opening the sunken hole, it is preferably 35% by weight or more, preferably ％% by weight or more, more preferably 3 to 9% by weight, and more preferably 4丨 Weight% or more, especially good * 3% by weight or more and 45% by weight or more. In addition, the moisture content is self-suppressed due to the drop temperature • 44-This paper size is applicable to China National Standard (CNS) A4 (210 X 297) (Public love) π Please read the law on the back to read this article. ^ 装 装 —if '421239351 V. Description of the invention (The point of view of the printed mi-crack by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is 65% by weight or less. Preferably 62.5% by weight or less, more preferably 60% by weight or less Below, 55% by weight. Ran is better 57.5%. The following, the best two: the content of other components of the preparation liquid, water-dropping polymer car parent is 1 ~ 20% by weight, more preferably 3 ~ 15% by weight. %, More preferably 5 to 10% by weight of water = class is better 7 to 59% by weight, better &quot; ~ 45% by weight ". Still more. In addition, in the case of water-containing insoluble substances, 3 to 32% by weight is preferred, It is more preferably 7 to 25% by weight, and more preferably 8% by weight. The preparation liquid with this composition can be delivered with _ as long as it may be non-hardening: Yes. Also, the method and order of addition of each component can be appropriately changed according to circumstances. In addition, in the second preparation liquid, part of the water-soluble salts is present in an undissolved state. In the present invention, as a part of the preparation liquid exists in an unconverted state, it is useful The undissolved amount of the water-soluble salt in the particle group, which is trapped / re-porous and can be lifted to the liquid surfactant composition, is preferably from 5 to 15% by weight of the second preparation liquid. "Better" is "% by weight", still more preferably 2 to 9% by weight, and most preferably 3 to 7% by weight. In addition, the average particle diameter of the particles of the above-mentioned undissolved water-soluble salts (hereinafter, also referred to as undissolved substances) is 80 μm or less, more preferably 60 μm or less, and even more preferably 40 μm or less, It is preferably less than 20 meters. Ma You, as a method for making undissolved substances exist in the second preparation liquid, for example, the amount of water-soluble salts and the amount of water may be adjusted in the aforementioned garden, and the preparation liquid may be adjusted by considering the amount of dissolved salts Temperature and other means. : -45- 'The paper size applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) with micro-water 43 1239351 5. Description of the invention (As a means to make the particle size of the undissolved material small, do not dissolve in the first The existence of the preparation solution can be substantially added to the first preparation solution, the second system :: == salt particles are small, and the temperature of the first preparation solution is changed to dissolve the material and so on. The crystal is changed to make the eighth solution amount of the water in the first preparation liquid, and the fine crystal precipitation agent is mixed in the first! The preparation liquid is dissolved ::: crystals, and the microcrystals are precipitated, and the previous means are used. For the determination of the undissolved amount of water-soluble salts, centrifugation to recover the clarified solution, that is, the solution part of the second preparation solution. Weigh the solution a (g) with 2 = precision balance, and dry it for 4 hours in a dryer. After cooling for 15 minutes, the supernatant was weighed with a precision balance = Gangg). Here, b / (a_b) x l0. Calculate the solubility of the supernatant ^ c (/ 〇). Also, analyze the dry residue The inherent rate d (%) of the water-soluble salts in the part. The water content e (%) of the second preparation liquid and the water solubility of the second preparation 2 Class content rate f (0/0), calculate the amount (%) of water-soluble salts by the following formula. ○ For the measurement of the average particle size of the undissolved water-soluble salts, use the aforementioned in-line granule droplet monitoring. Measurement by a system ("TSUB-TEC M100" manufactured by LASENteC). The second preparation liquid is obtained by using a known method to obtain the first preparation liquid, and then performing the aforementioned treatment for increasing the number of water-soluble salt particles in the preparation liquid. May -46- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

One outfit • I ^ I-| (Please read the ‘Near Notes’ and fill out this order --------

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1233351 A7 V. Description of the invention (obtained from the spray drying process, as a good method, you can control the appropriate particle group to trap the particles. The control range is 1 difference. The composition of the group is different at the optimal moisture content of the preparation liquid. ~ The control of drying conditions and control of the second part is to make the spray-dried droplets fast, that is, the temperature of the spray-dried droplets is preferably above 85. ^ Haoma 90C or more, more preferably more than valence. But the thermal decomposition Hm wind temperature of self-contained components is preferably below t, more preferably ⑽. Below, more preferably 325 C or less, of which 30 〇π or less. 9. Physical properties of the particle group for the surfactant support, the bulk density of the particle group for the support is to ensure the liquid surfactant, and the content is <supported in the valley> viewpoint and the support is ensured From the viewpoint of liquid interface activity and subsequent bulk density, it is better to have a side weight per liter, more preferably gram to gram per liter, more preferably 400 to 700 gram per liter, and particularly preferably 400 to gram per liter. , ', Since the use of a carrier liquid-containing surfactant composition in the carrier particle group <Dusting property and solubility when the detergent composition of the detergent particle group is formed <viewpoint 'The average particle diameter of the supporting particle group is preferably ㈣ to 6 ⑼, more preferably 160 to 500 ，, and 18 to 18 400 micrometers is better. Interfacial activity = the preferred liquid surfactant composition of the particle group for the carrier of the agent. The viewpoint is 0.35 l / g or more, more preferably 0.40 ml / g or more, particularly preferably 0.45 ml / g or more, and most preferably 50 ml / g or more. Speed, speed and efficiency 47- This paper size applies the Zhongguanjia standard (CNS) A4 specification ⑵Q χ Norwegian public hair) (Please read the precautions on the back before filling this page) IH 1 ^ 1 · Economy Printed by the Ministry of Intellectual Property Bureau's Consumer Cooperatives 1239351

Description of the invention: (from the viewpoint of improving the productivity by collecting liquid surfactant composition, preferably 2 ml / g or more, more preferably 0.3 ml / g or more, more preferably 0 4 ml / g or more, and 0 for supporting particles The moisture content of the group measured by the infrared moisture meter is preferably from the supporting capacity of the liquid surfactant composition of the particle group, preferably &quot;% by weight or less, more preferably 10% by weight or less% by weight. The degree of looseness, average particle size, supporting grain content, supporting speed, and moisture content of the liquid surfactant composition can be measured by methods described in the physical property measurement method described later. 10 · Detergent particle group Composition and physical properties The cleaning agent particle group of the present invention is a surfactant composition supported on the supporting particle group. In the surfactant composition, an anionic surfactant and a nonionic surfactant can be used alone, It is better to mix the two. Especially when using a nonionic surfactant with a melting point below 30% (combined with a melting point that increases the melting point of the surfactant 45 ~ 10 (rc, molecular weight) ^ Thousands to 30,000 water A non-ionic organic compound (hereinafter referred to as a melting point enhancer) or an aqueous solution thereof is preferred. Examples of the melting point improver that can be used in the present invention include polyethylene glycol, polypropylene glycol, and polyoxyethylene alkane. Ethers, protonic non-ionic surfactants, etc. In addition, amphoteric surfactants and cationic surfactants can be used in combination according to the purpose. In addition, anionic surfactants such as alkylbenzene sulfonates can be used in combination with 5 ~ 25% by weight is incorporated into the detergent particle group, which can improve the dispersion of the detergent particle group in low temperature water. -48- This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297mm f)

46 1239351 V. Description of the invention (as a horse surfactant composition, for example, one or more species selected from anionic surfactants, nonionic surfactants, cationic surfactants, and amphoteric surfactants can be used. As anionic The surfactant may be exemplified by benzoyl benzoate, alkynyl or alkenyl ether sulfate, chain alkyl sulfonate, sulfonic acid fatty acid salt, or esters thereof, alkyl or alkenyl ether carboxylate, and amine. Acid-based surfactants, N. amino acid-based surfactants, etc. In particular, straight chain alkyl benzoate salts of the number 1 () to 14 and pit groups of the number 1 () to 18 may be mentioned. Sulfate or alkyl ether sulfate is preferably used as an amine such as an alkali metal such as sodium or potassium, monoethanolamine, or diethanolamine as a pair of ions. In addition, in order to obtain a defoaming effect, a fatty acid salt may be used in combination. A fatty acid is preferred Number of C 1 2 ~ 1 8 0 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. As non-ionic surfactants, polyoxyethylfluorenyl or alkyd acid, polyoxyethylenephosphonyl phenyl ether , Polyoxyethyl # polyoxypropyl fluorenyl or alkenyl ether, represented by the trademark Pronick Polyoxyethylene polyoxypropylene glycol, polyoxyethylene alkylamines, high-carbon fatty acid alkanolamines, alkylglucosamines, alkylglucosamines, alkylated oxygens, etc. Among them, those with higher hydrophilicity and It is better to form liquid crystal with low or no liquid crystal when mixed with water, especially polyoxyalkylene alkyl or alkenyl ether. It is better (: several ⑺ ~; ^, preferably 12 ~ 14, The average additional mole number is 5 to 30, preferably 7 to 30, more preferably 9 to 30, and more preferably U to 30. The alcohol core ethylene oxide (the following EO) add-on, the other (^ 数 卜 ^ 之) Alcohol of e〇 and propylene oxide (P0) are preferred. As an additional sequence, p 0 is added after EO, £ 0 is added after p 0, or EO and P 0 are added with the base. It can be used. As a particularly good addition sequence, after adding EO, the block is added with P0, and then the block is added with the general formula -49- M's scale. Applicable to China National Standard (CNS) A4 specification ( (210 X 297 mm) 1239351 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. H. V. Invention Description ()

R-0- (E0) x_ (P0) Y_ (E0) z-H

[Wherein R represents a hydrocarbon group, preferably an alkyl group or an alkenyl group, E0 represents an ethylene oxide group, P0 represents a propylene oxide group, and X, γ, and Z each represent an average additional mole number. ] Among them, the relationship of the optimal average additional mole number is χ &gt; 〇, z &gt; 〇, X + Y + Z = 6 to 14, X + Z = 5 to 12, and Y = 1 to 4 〇 as the cationic interface Examples of the active agent include grade 4 ammonium salts such as alkyltrimethylammonium salts. As the amphoteric surfactant, a carbonyl betaine type and a sulfo betaine type can be exemplified. The blending amount of the anionic surfactant is preferably 0 to 300 parts by weight, more preferably 20 to 200 parts by weight relative to 100 parts by weight of the nonionic surfactant, and particularly preferably 30 to 180 parts by weight. The blending amount of the melting point of the nonionic surfactant is preferably 1 to 100 parts by weight, more preferably 5 to 5 parts per 10 parts by weight of the nonionic surfactant. Parts by weight. Within this range, the temperature of the composition above the pour point of the composition is 10 Pa · s or less, preferably 5 Pa · s or less, and particularly preferably 2 Pa · s or less And at a temperature lower than the pour point of the composition, and lower than the melting point of the non-ionic I * surfactant, the composition has a hardness of 10 kPa or more, preferably 30 kPa or more, and particularly preferably 50. The temperature range above kPa is due to the processing of the composition and the cleaning agent particle group at the time of manufacturing -50-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----- ^- -^ — — — — — — — — — — (Please read the note on the back # (Fill this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Also, it is suitable to prevent the bleeding of nonionic surfactants during storage of the detergent particle group. The physical properties of the surfactant composition can be measured by the following method. The pour point can be measured by the method of JIS K 2269. The melting point uses FP800 Shamo (inch 17 The system "Meitra (Fu Bu)-FP81" (Mettler Instnimente AG), measured at a heating rate of 0.2 ° C / min. Viscosity is measured using a B-type viscometer ("DVM-B type" manufactured by TOKYO KEIKI Corporation) ）, Lotta (Yi Yi Yi Yi) No. 3, 60 rpm to determine the measurement conditions. In addition, under the conditions of the measurement 値 more than 2 Pa · s can not be measured, Lota No. 3,1 Measured at 2 revolutions per minute. The hardness is determined by using a galvanometer ("nrm_ 3002D", manufactured by Fudo Industries, Ltd.) and a circular joint (No. 3, 8 with a diameter of 8 mm and a base area of 0,5 cm 2). 0), the joint enters the inside of the surfactant composition at an entry speed of 20 mm / min. The load when the joint is divided by the joint of the circular joint. The amount of the surfactant composition, self-cleaning and solubility The viewpoint 'is preferably a range of 10 to 100 parts by weight, more preferably a range of 20 to 80 parts by weight, and a range of 30 to 60 parts by weight with respect to 100 parts by weight of the supporting particle group. It is particularly preferred that the added amount of the so-called surfactant composition is not included even if the surfactant is added to the preparation solution. The amount of the surfactant added. When the surfactant composition is mixed with the supporting particle group, it is preferred that even if a powder material other than the particle group is added, the added amount is preferably relative to the particle group. 100 parts by weight, 0 ~ 150 parts by weight. As a powder raw material, for example, aluminosilicate, s KS-6 (Cricket (Xijin) -51-book, paper ^ face grid ⑽ x 29 Han ---- ^-— — — h- — — — 11111111-(Please read the notes on the back before filling in this page) I239351 V. Description of the invention (49) 7 &gt; Bu) Company) and other crystallinity Silicate. In addition, the external components in the detergent particle group may be contained in the carrier = surfactant composition, water-soluble salts, and water-insoluble substances :: ： 《》 Contains the crystalline dicamba acid described later; etc. In addition, using water-insoluble materials and using raw materials that can be used as adhesives, the cleaning agent and powder agglomerate layer are covered during the production of the cleaning thread group, and there may be a case where only the appearance A * is used to pass the child component. Recognized in this case: === Shape of the particle group :: Organic solvent extracted from the detergent particle group can be confirmed :::: group. Also, the type of the binder substance of each constituent unit of the extracted organic solvent detergent particles is suitable for the type of substance ::: Shows that the group shape of the surfactant-supporting particles will be reduced and weighed by solvent extraction. Clear „particles 5 grams, ㈣ 财 bath plus 5 / 〇 00 00 liters reflux operation η, time and time 'side was washed thoroughly with hot ethanol-tender to filter the ethanol insolubles with suction filtration, will be separated under pressure: ethanol After drying the insoluble matter for 24 hours, it was carefully recovered so as not to destroy the structure of the non-soluble fraction. After doing this several times, the insoluble ethanol was obtained. The standard sieve of JISZ 8801 was used to make the obtained ethanol insoluble. After shaking for 10 minutes, measure the weight on each sieve, and observe and analyze the particles classified on the mesh sieve. The obtained particle group is to confirm whether it is the supporting particle group of the present invention and the ethanol insoluble added in the next step. ___ -52- This paper size applies Chinese National Standard (CNS) A4 (21〇χ 297 mm) 1239351 A7 B7 V. Description of the invention (50 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 醢 = Alcohol is not cold It is confirmed that the second particle added to the supporting particle group in the subsequent step is not ::: ^ 'The average particle diameter of the particle group due to the effect of the particle size distribution due to the added portion in the subsequent step is removed. Or eight, and &amp; perform separate solvent insolubilization operations, remove the surfactant composition and the composition added in the next step, the shape of the particle group. &Lt; Sheng Dao Temple <, you can confirm the basis for the use The preferred physical properties of the cleaning agent particle group of the present invention are as follows. The bulk density is preferably 500 to 500 g / L, more preferably 650 to 850 g / L. The average particle diameter is preferably 150 to 500 μm. , More preferably 180-400 microns. 11 · Method for preparing detergent particle group / getting clean _ particle group is pure ^ Contains ㈣ ㈣ Requirement may also include step (H). Buyi, step (I) 1 The liquid or paste of the surfactant composition: the surfactant-supporting particles obtained by the method of the present invention are mixed; step (i: the mixture obtained in step i) and the surface is covered with the surface-covering agent powder On the surface of the cleaning agent particle group, step (11) also includes pulverization at the same time. Circumstances. ~ But step &lt; Step (I) &gt; As a method for supporting the surfactant composition on the supporting particle group, for example, a method using a batch type and a continuous type mixer can be used to mix the surfactant composition. Here, with the shape of the intergranular group, as a method to install people in the mixer, it is preferable to first carry 53- This paper size applies the Chinese National Standard (CNS) A4 specification (21〇χ 297 mm ---- -^ ---------. (Please read the precautions on the t side first ^^ Fill in this page) 51 1239351 V. Description of the invention (2 ^ After the machine, add the surfactant composition Hold the particle group and the surfactant composition into the mixer ... 2 After the particle group is partially installed in the mixer, place the remaining particles and the surfactant composition in small amounts. Among the active agent compositions: in practical temperature range, such as 50 ~ 90 C, if it is also solid or pasty, it will be dispersed or dissolved in advance in a non-ionic non-ionic interface with low viscosity. Agent = aqueous surfactant solution or water to prepare a blend of surfactant compositions. The shoes or water drops can be added to the carrier in the form of the mixed solution or aqueous solution, and the pellet group can be used. According to this method, it is also possible to easily add the surfactant composition in a solid or pasty state to the supporting particle group. The mixing ratio of the low viscosity surfactant composition or water and solid or pasty surfactant composition is as long as the obtained mixed solution or aqueous solution has a sprayable viscosity range. A method of putting a surfactant or a surfactant or a surfactant-like composition in water in a mixed state, and adding an acid precursor of the surfactant, such as an anionic surfactant, in a viscous surfactant or in water The acid precursor can also be neutralized with a test agent (such as the aqueous solution printed by the employee ’s cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the Chlorine Oxide Steel to print an aqueous solution of water and aquatic hydroxide solution) to prepare a mixed solution of surfactant composition. In addition, at this step, before the addition of the surfactant composition, at the same time as the addition of the surfactant composition, at the same time as the addition of the surfactant composition or after the addition of the surfactant composition, an anionic property is added. Surfactant acid precursors are also possible. To add anionic surfactant, interface 54- This paper size is applicable to China National Standard (CNS) A4 (210 x 297 mm 7 1239351)

V. Description of the Invention (52) Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs printed the high blending of active agents and the carrying capacity of the particle group, which can control and inhibit the rotor interface activity of the Qing sub-group. It is possible to improve the physical properties and quality of the exuding fluid. Examples of the acid precursor of the anionic surfactant that can be used in the present invention include alkylbenzenesulfonic acid, alkyl or alkenyl ether sulfuric acid, alkyl or feminine sulfuric acid, α-alkenesulfonic acid, α_sulfonic acid, and the like. Acidified fatty acids, alkyl or alkenyl ether carboxylic acids, fatty acids, and the like. The fatty acid is added after the surfactant is added, which is particularly preferable from the viewpoint of improving the fluidity of the detergent particle group. The amount of the acid precursor of the anionic surfactant is preferably from 5 to 30 parts by weight, more preferably from 1 to M parts by weight, and still more preferably from 1 to 10, based on 100 parts by weight of the supporting particle group. Parts by weight, particularly preferably parts by weight. In addition, the amount of osmic acid precursor used is not included in the amount of the surfactant composition of the present invention. The method of adding an acidic precursor of the anionic surfactant is preferably sprayed for those who are liquid at normal temperature, and those that are solid at normal temperature 'as powder, or sprayed after melting. However, in the case of powder addition, it is preferable to raise the temperature of the detergent particle group in the mixer to a temperature at which the powder melts. As a preferable mixing device, the following may be specifically mentioned. In the case of performing a back-fraction equation, it is preferable to use one of (1) to (3). (1) Henschel (~ y シ 工 士) mixer (Mitsui Miike Chemical Machinery Co., Ltd.), high-speed mixer (Shenjiang Industry (Moses)), vertical manufacturing machine (Company) )), Thunder drop (b X ^ ^) mixer (Matsusaka Giken (manufactured by the company)), Procchia (7-port X X 7) mixer (manufactured by Pacific Machinery Co., Ltd.), kaihei ^ _ 296064 and Japanese Patent Application Publication No. 10_296065, the mixed skirt-55- sheet size is applicable to China National Standard (CNS) A4 (210 X 297 mm) !!!!!.% T ------ --Order! (Please read the notes on the back before filling out this page) ♦ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1239351

V. Description of the invention (㈤) Eighth grade (2) Li fine (J shown v) mixer (made by He Machinery Industry (Company)), knife batch kneader (made by Satake Chemical Machinery Industry (Company)), Libo Control (Y seeking j company) manufactured by Ogawara Manufacturing Co., Ltd., etc., ⑺NO Tower (^ Xi) mixing table (made by Hosokawa Micron (❺ 力 ... 口, Xiang company)), sv mixer (Kami ,, Gompantik (company)制) and so on. Among the above-mentioned mixers, a preferable one is a thunder-drop mixer, a Procchia mixer, JP-A-King ... Mixing clothes described in the Japanese Patent Publication No. 10-296065, etc., because the steps described below can be performed ( II) It is better to use the same device and simplify the equipment. Among them, the mixing devices described in Japanese Patent Application Laid-Open No. 10-296064 and Japanese Patent Application Laid-Open No. 10-2960665 can adjust the humidity and temperature of the mixture by aeration, since the particles of the surfactant-supporting particles can be suppressed. Collapse, so it's better. In addition, without giving a strong shearing force, a mixing device such as a Nuota mixer, an SV mixer, and a back-and-forth mixer capable of mixing powder and liquid can suppress the disintegration of the particle group for surfactant loading. Also better. Further, the continuous type device of the above mixer may be used to mix the supporting particle group with the surfactant composition. In addition, as a continuous type device of a mixer other than the above, there is a Fu Lei Ji Shuo (7b 丰 y) hybrid type ((company)

Throwing rake), disturbing mixer (Xiyi dagger, X Jinyagan,-) (Hosokawa Micron (company)). A. In this step, when a nonionic surfactant is used, before adding the surfactant composition, add the surfactant composition at the same time as adding the surfactant composition, or add the surfactant composition. After the product is added, a water-soluble non-ionic organic compound having a melting point of 45 to 100 ° C and a molecular weight of 1,000 to 30,000 is added to increase the melting point of this surfactant. A4 size (21 × 297 mm)

1239351

(Hereinafter referred to as a melting point increasing agent) or an aqueous solution thereof 'or it is preferably added to the surfactant composition in advance. Adding a melting point rising agent can suppress the agglomeration of detergent particle channels and the exudation of surfactants in the detergent particle group. As such a melting point increasing agent, the same ones as those exemplified for the above-mentioned cleaning agent particle group I composition can be used. The amount of the melting point rising agent I is preferably from 5 to 8 parts by weight, more preferably from 0.5 to 5 parts by weight, and most preferably 3 parts by weight, relative to 100 parts by weight of the supporting particle group. This range is preferable from the viewpoint of suppressing aggregation between detergent particles containing the detergent particle group, high-speed solubility, and suppression of exudation and agglomeration. As a method for adding a melting point rising agent, mixing with a surfactant in advance by any method, or adding a melting point rising agent after the surfactant is added, is advantageous for suppressing the exudation and agglomeration of the detergent particle group. It is more preferable that the temperature in the mixer in this step is raised above the pour point of the surfactant composition for mixing. The pour point of the surfactant composition is measured in accordance with the method specified in JIS K 2269. Here, as long as the temperature rise is lower than the pour point of the surfactant composition added to promote the support of the surfactant composition, the practicability is beyond the mud moving point to 5 A temperature higher than 0 C is preferred, and a temperature higher than the pour point is better. In addition, in this step, the acid precursor to of the anionic surfactant is added, and it is more preferable to mix the acid precursor to a temperature at which the acid precursor of the anionic surfactant can react. In order to obtain a suitable detergent particle group, the average residence time in the intermittent mixing time and the continuous mixing time is preferably 1 to 20 minutes, more preferably 2 to 1 () minutes. 0 -57- This paper size Applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the notes on the back before filling this page) H- ϋ n &quot; ---- ^ --------- Economic Printed by the Employees 'Cooperative of the Ministry of Intellectual Property Bureau 1233351 Α7 Β7 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In the case of an aqueous solution, there may be a step of drying excess water during and / or after mixing. It is also possible to add the powder before adding the surfactant composition, at the same time as it is added, or after adding the powder. Surfactants and / or powder detergents. Adding powder detergents can control the particle diameter of the detergent particle group and improve the cleaning power. Especially when the acid precursor of anionic surfactants is added, Before the addition of the acid precursor, the addition of an alkaline powder detergent is effective from the standpoint of promoting the neutralization reaction. Here, the so-called powder detergent refers to a powder detergent enhancer other than a surfactant. Specifically, it refers to zeolites, citrates and other bases that exhibit metal ion blocking energy, bases such as sodium carbonate and potassium carbonate that exhibit alkali properties, crystalline silicates and other metal ion blocking energy, Bases of any one of alkali properties, other bases that increase ionic strength, such as sodium sulfate, etc. As a crystalline dream salt, this can be described in JP 5_2 7 9 〇13 column 3 Line 17 (especially, it is preferable to burn at 500 to 1000 ° C to crystallize), Japanese Patent Application Laid-Open No. 7-89712, column 2, line 45, Japanese Patent Application Laid-open No. 60-227895 The crystalline silicate in line i 8 (especially the silicate in Table 2) in the lower right column of the page is used as a preferred powder detergent. Here, the metal silicate is tested for S〇2 / M2. (However, M represents an alkali metal) 0.5 to 32, and 1.5 to 2.6 are more suitable for use. The used amount of the cleaning aid is preferably 5 to 12 parts by weight, more preferably 1 to 6 parts by weight relative to the weight of the supporting particle group of 100 parts. The used amount of the powdered cleaning aid for the cleaning agent, Good solubility is available in Fanyuan here -58- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm)

1239351 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (In addition, after step (I), it is better to add step (II) to modify the surface of the detergent particle group. &Lt; Step (11 ) &gt; In the present invention, in order to modify the particle surface of the detergent particle group carrying the surfactant in step (I), as a form of addition, the following (1) fine powder may be added ( 2) The step (11) of the various surface covering agents for the liquid substance is performed in more than one step. The particle surface of the cleaning agent particle group of the present invention improves the fluidity and the blocking resistance of the cleaning agent particle group. Therefore, it is better to design the surface modification step. The device used in step (II), for example, is exemplified in the mixer of step (I), it is better to have both the stirring blade and the crushing blade. The surface is described below. Covering agents are explained separately. (1) As a micronized powder, the average particle size of the primary particles is preferably 10 micrometers or less, and more preferably 0.1 to 10 micrometers. The average particle diameter is within this range, and The coverage of the particle surface is improved, The viewpoint of improving the fluidity and blocking resistance of the detergent particles is suitable. The average f π of the fine powder is measured by light scattering method, such as a particle analyzer (Horiba, Ltd., or k. Measurements such as measurement. In addition, it is necessary to know that the body has a high ion exchange energy and a high test energy, and is preferably self-cleaning. As the fine powder, aluminosilicate is desired. It can be any one of k ~ 叩 and amorphous. Other than aluminosilicate, such as sodium sulfate, broken acid, silicon dioxide, clay, talc, clay 'amorphous silicon dioxide derivatives ： 2 59- | Installation ----- (Please read the note on the back? Matters before filling out this page) · 1111111 Moderate rule paper on paper centimeter 97 2 X 10 2 / V Grid gauge A4 S) N (C standard Biaojia1239351 Α7 Β7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 57 V. Description of the invention () The fine powder of silicate is also good. In addition, the interfacial activity of metal soaps and powders whose primary particles are 0.1 ~ 10 microns Agents (such as alkyl sulfates) and water-soluble organic salts can be used in the same manner. In the case of crystalline silicate, it is better to use it in combination with fine powders other than crystalline silicate for the purpose of preventing deterioration by coagulation of crystalline silicates that absorb moisture and carbon dioxide. The amount used is preferably 0.5 to 40 parts by weight, more preferably 1 to 5 parts by weight, and particularly preferably 2 to 20 parts by weight relative to 100 parts by weight of the detergent particle group. The amount of the fine powder used is Within this range, the fluidity is improved, and a good feeling of use is given to the consumer. (2) As a liquid substance, a water-soluble polymer and a fatty acid can be mentioned, and it can be added in an aqueous solution and a molten state. (2-1) Water-soluble Examples of the polymer as a water-soluble polymer include carboxymethyl cellulose, polyethylene glycol, sodium polyacrylate, a copolymer of acrylic acid and maleic acid, or a polycarboxylate of a salt thereof. The amount of the water-soluble polymer used is preferably from 5 to 10 parts by weight, more preferably from 1 to 8 parts by weight, and particularly preferably from 2 to 6 parts by weight relative to 100 parts by weight of the detergent particle group. The use amount of the water-soluble polymer is within this range, and it can show the cleaning agent particle group with good solubility, good fluidity, and agglomeration resistance. (2-2) Fatty acid Examples of the fatty acid include fatty acids of 10 to 22C. The amount of the fatty acid to be used is preferably 0.5 to 5 parts by weight and particularly preferably 0.5 to 3 parts by weight based on 100 parts by weight of the detergent particle group. In the case of solid at room temperature, -60- This paper size is applicable to China National Standard (CNS) A4 (21〇X 297 mm) ~ Packing --------- ^ -------- -· F Please read the notes on the back before filling this page) 1239351

V. Description of the invention (Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs and warmed to a temperature showing fluidity, the spray is better. 1 2 · Cleanser composition The cleaner composition of the present invention contains the above-mentioned detergent particles Group of compositions, in addition to other detergent particles, additional detergent ingredients (such as detergent particles, fluorescent dyes, enzymes, perfumes, defoamers, "whitening agents, bleach activators, etc." The content of the detergent particle group in the detergent composition, from the point of self-cleaning power, is preferably 50% by weight, more preferably 60% by weight, still more preferably 70% by weight, 80% by weight or more and 100% by weight. The content of detergent components other than the detergent particle group in the detergent composition is preferably 50% by weight or less, more preferably 40% by weight or less, 30% by weight or 20% by weight. The following are particularly preferred. 1 3 · Method for measuring physical properties The physical properties of this specification are measured by the following methods. (Bulk density): Measured by the method specified in JIS K 3362. (Average particle size): As specified in JIS Z 8801 Sieve For example, using a 9-stage screen of 2000 micron, 1400 micron, 100 micron, 710 micron, 500 micron, 355 micron, 250 micron, 180 micron, and 125 micron and installed on a Rotapo machine (HEIKO Made by SEISAKUSHO, light tap: 156 times / minute, rotation: 290 times / minute), 100 grams of sample is shaken for 10 minutes, and after sieving, the receiving dish is 125 microns, 180 microns, 25 microns, 355 microns, 500 micron, 710 micron, 1000 micron, 1400 micron, 2000 micron order, accumulatively receive m and the weight frequency on each sieve, then the initial sieve mesh with the accumulated weight frequency of 50% or more is In micrometers, and larger than no micrometers -61-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ~ Packing ----- 1 —IT- · ----- 1 —. (Please read the notes on the back before filling out this page) 1239351

Description of the invention (, when the mesh size of the sieve is micron, the cumulative frequency of weight from pan to alpha micron is r% 'and when the frequency of weight on alpha sieve is $%, according to (average particle size) = 1 〇 Α: Θ x 1 〇g β)

A θ log is cold-1 ο g a can be obtained. (Particle strength): Put 20 grams of the sample into an E cylindrical container with an inner diameter of 3 cm \ height 8 cm, and perform 30 taps (Tsutsui Rika Chemical Co., Ltd., τνρ type tapping compaction looser r Degree measuring device, tapping the condition; 3 times, 6 times, free fall from a height of 60 mm), measure the height of the sample at that time (beginning of the sample height). Thereafter, the entire upper end surface of the sample held in the trough was further pressurized at a speed of 10 mm / min in a pressure tester, and the load_displacement was calculated. The slope of the linear portion below the displacement rate of 5% or less is multiplied by the initial sample g degree 'divided by the pressure area 値 as the particle strength. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

(Supporting capacity and supporting speed of the liquid surfactant composition): Put 100 g of chips into a β-tube mixing tank with an inner diameter of 5 cm x 15 cm with a stirring wing, and stir at 350 rpm. Polyoxyethylene alkyl ether (Ci2 / Ci4 = 6/4, E02 7.7, | point = 25 ° C) was dripped at a speed of 10 ml at 300 ° C, and the change of the stirring power over time was measured. ．The stirring power becomes the highest B 62. The paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 1239351 A7 V. Description of the invention (60 B7 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 4 Polyoxyethane : Fe-based ether <The amount of the input amount divided by the weight of the particle group (g) is taken as the carrying capacity of the particle group (ml / g). In addition, the carrying speed is such that the power of disturbance is increased to the power of disturbance The process of showing the maximum 値, the change in the amount of polyoxyethyl ether at the time when the amount of change per unit time is the largest divided by the weight of the particle group (100 grams) 値 (亳 liters / gram) is expressed, this The larger the number is, the better the loading speed is, that is, the particles with better loading speed are gathered on the surface of the particles. As a result of the remaining suppression of acetamyl ether, the time for the rise of the mixing power is delayed. (Water knife) The moisture measurement of the t group is performed by the infrared moisture meter method. That is, 'weigh in a sample dish of known weight' Take 3 grams of the sample and heat the sample with infrared moisture meter (Coteb) Scientific Institute (Company) (infrared lamp for 18 minutes). After that, weigh the sample dish and dry the sample. The container and sample before and after drying (the weight of ^, divided by the weighed sample amount, multiplied by ⑽ to calculate the moisture content of the sample from the operation described in μ.) (Fine, volume distribution): surfactant loading The pore volume of the holding particle group is measured using a mercury porosimeter "SHIMADZl ^ porosimeter 9320", based on: the instruction manual is as follows. That is, 200 mg of a surfactant is supported. The particle group is placed in a measuring cell (magic maggot, and the low-pressure part (0 ~ 142 and high-pressure part (14.2 ~ 3_psia) are used to measure the mercury intrusion. The two data before and after each (average, smooth the measurement data, find G . (U micron ~ 3 micron maximum frequency diameter and pore volume. (Flowability : The flow time is 佑 ττς; γ udt M Menma according to JIS K 3362 100 milliliters of detergent powder from the hopper used to determine the density of the time required to flow out. ·, I installed ---- (Please read the back first Note for this page, please fill in this page) Order --------- Peak · -63 1239351

Description of the invention (Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (caking resistance): use two types of filter paper according to JIS P 3801 (for example, "Qualitative No. 2 Filter Paper" manufactured by Toyo Filter (Company)) to make wide X Length X Height = 1 0 cm X 6 cm X 4 cm Container with opening on top. Load 100 grams of sample in this box 'total load the acrylic resin plate and lead plate (or iron plate) on it Weight 15g + 250g. This is placed in a strange temperature-humidifier with a temperature of 30 ° C and a humidity of 80%. After 7 days, the agglomeration status is determined. The determination is made by determining the passing rate as follows. The passing rate The higher the agglomeration resistance, the better the physical properties as a detergent particle group. (Passing rate): Put the sample after the test gently on a sieve (mesh 4760 microns in accordance with JIS Z 8801), Measure the weight of the powder that passed, and determine the pass rate for the test sample. (Exudability): Use 2 types of filter paper specified by jIS P 3801 (for example, "Qualitative No. 2 Filter Paper" made by Toyo Paper Co., Ltd.), Making width X length X height = 丨 0 cm X 6 cm X 4 cm open container Use an oil-based pen ("Magic Ink M760-T1" manufactured by Uchida Yoko Co., Ltd.) on the sample filling surface of the bottom surface of the container to draw a line with a width of 0. 5 ~! 0 mm in the diagonal direction. Place the sample Fill this container, and load a total weight of 15 grams of propylene-based resin plate and lead plate (or iron plate) + 250 grams on it. Put this into a moisture-proof container and put it in a strange thermostat at 30 ° C, 7 Days later, the penetration of the oily mark was visually judged, and the exudation was judged. The judgment criteria are as follows: 5th grade: Exudation width of oily mark 2 cm or more 4th grade: Exudation width of oily mark 1 cm or more 3rd grade: Exudation width of oily mark Above 0.5 cm and 2nd grade: Exudation of oily marks can only be identified slightly -64- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -Packing --------- Order-- --- '(Please read the notes on the back before filling this page) A7 B7

^ ___ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1233351 Invention Description (62) 1 etc .: Exudation of oily marks cannot be identified 1 4 · Method for producing detergent composition The method for producing the detergent composition is not particularly limited. For example, A method of mixing the aforementioned detergent particle group and an additional detergent component. The detergent composition thus obtained contains a large amount of surfactant and a large amount of the detergent particles, so that it can exhibit a sufficient cleaning effect even in a small amount. The application of this detergent composition is not particularly limited as long as it is used for powder cleaners, and examples thereof include powder cleaners for clothing and cleaners for automatic food containers. ^ Example In this example, the following raw materials were used unless otherwise stated. Sodium sulfate: Anhydrous mirabilite (manufactured by Shikoku Kasei Co., Ltd.) Sodium sulfite: Sodium sulfite (Mitsui Chemical Co., Ltd.) Fluorescent dye: Tinopal CBS · X (Chiba-specific chemicals ^ 10W at 4S; U only) Co., Ltd.) Sodium carbonate: heavy ash (average particle size: 290 microns, manufactured by Chuo Nitra (Company)) 40% by weight sodium polyacrylate aqueous solution: weight average molecular weight Huata (manufactured by the company) Sodium chloride ·· Salt (manufactured by the Japanese salt company (manufactured by the company)) A) (Average particle size of type 4A: 3.5 microns) (manufactured by Tosho) I milk acetic acid · 俾 马 Malkian (work V KM (epoxy. Average number of moles added to the burn: 8 · 5, 垸Number of c in the base chain: 1 2 ~ 1 4, Huadu (company) -65- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) I -------- «Install -------- Order --------- (Please read the precautions on the back before filling out this page) A239351 、 Invention description (Polyethylene glycol · · K-PEG6000 (weight average Molecular weight: 8500, (Made by King (Company)) Amorphous silicate: The preparation example 2 described in JP-A-9-132794 is pulverized into an average particle size of 8 microns. Example 1 375 parts by weight of water is charged into a mixing tank, and the water temperature reaches After 3 5 t, add 127 parts by weight of sodium sulfate, 5 parts by weight of sodium sulfite, 1 part by weight of fluorescent dyes, and lose 10%. Add 12 7 parts by weight of sodium carbonate, and 7 5 parts by weight of polypropylene cotton and acid steel aqueous solution, and stir 10 minutes was used as the first preparation liquid. 24 parts by weight of sodium chloride as a fine crystal precipitation agent was added, and the mixture was stirred for 10 minutes. In addition, 266 parts by weight of zeolite was added, and 30 minutes were stirred to obtain a homogeneous second preparation solution (42 parts of slurry water). % By weight). The final temperature of this preparation solution is 40. (:. The amount of water-soluble seeder salts precipitated by adding sodium chloride is 16.3% by weight of those dissolved in the first preparation solution. In preparing the first preparation solution After adding sodium chloride i 0 minutes, samples were taken from each preparation, and the number of particles and particle size distribution were measured on TSUB-TEC M100. The number of particles in the first preparation was 778 particles / s, and the average particle size (each Number basis) is 172 microns. The number of particles in the second preparation solution after adding sodium gasification The number was 2634 pieces / s, and the average particle size was 21.2 microns. From the results of these measurements, by adding sodium chloride, the number of water-soluble salts increased by 1856, and the average particle size of the increased water-soluble salts increased. The diameter is 12.5 microns. The second preparation liquid is supplied to the spray-drying tower (downflow type) by pumps, and is sprayed at a pressure of 2 5 "from a pressure spray nozzle installed near the top of the tower. It is supplied to the spray-drying tower. The high-temperature gas is supplied from the lower part of the tower at a temperature of 200 ° C and discharged from the top of the tower at 90 ° C. The obtained surfactant-supporting particle group (please read the precautions on the back before filling this page) t * equipment ------------ Order --------- Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Employee Consumer Cooperatives-66- 1239351 A7 B7

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the Invention (64) The water content is 4% by weight. The surfactant particle supporting particle group was used to produce a detergent particle group in the following manner. The surfactant composition (polyoxyethylene alkyl ether / polyethylene glycol / sodium pyrobenzyl sulfonate / water di 42/8/42/8 (weight ratio) was 8 (rC.) The resulting interface activity 1 100 parts by weight of the agent-carrying particle group was put into a lightning drop (bY Y) mixer (made by Matsuzaka Giken Co., Ltd., with a capacity of 130 liters and a jacket), and the main shaft (stirring wing, rotation number: 60 rpm, Peripheral speed: 1.6 m / s). Also, 80 liters of warm water was poured into the jacket at 10 liters / minute. 50 parts by weight of the above-mentioned surfactant composition was put into it at a time of 2 minutes. After that, stirring was performed for 5 minutes. In addition, 6 parts by weight of the amorphous aluminosilicate was added as the minimum amount of detergent particles, and the main shaft (number of rotations: rpm, peripheral speed: 3.1 m / Seconds) and an interrupter (rotation number · 3600 rpm, peripheral speed: 28 m / s) for 1 minute, and the detergent particle group was discharged. Example 2 The interface was obtained in the same manner as in Example 1. Particle Group 2 for Active Agent Support Using the particle group 2 for surfactant support, a detergent particle group 2 was produced in the same manner as in Example 1. The amount of amorphous aluminosilicate is 4 parts by weight as the minimum amount of detergent particle group exudation. Comparative Example 1 Water was added to the bucket; before sodium salts, sodium chloride was added as a fine crystal precipitation agent, and stirred. A surfactant group-supporting particle group 3 was obtained in the same manner as in Example J except that it was completely dissolved at 10 minutes. The surfactant group-supporting particle group 3 was obtained by the same method as in Example 丨 to produce the same. Detergent particle group 3. However, the amorphous aluminosilicate is the same as in Example 1 with 6 parts by weight ___-67-This paper size applies the Chinese National Standard _Α44 ^ Nogong Dong) ------ --- ^ ---------- (Please read the precautions on the back ^ Fill this page first) Explode ^ 39351 V. Description of the invention (65 Printed by Tiandi to the employee consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs During the stirring in the machine, the surfactant-supporting particle group 3 continued to support the surfactant composition into an agglomerated state, and the physical properties were deteriorated to a beneficial method. "", Example 3 As a fine crystal precipitation agent, sodium bromide ( Except for Otsuka Chemical Co., Ltd., the same procedure as in Example i To obtain the surfactant-supporting particle group 4. With the addition of sodium bromide, the amount of the water-soluble inorganic salt that precipitates out, 2: 27% by weight of the “4 solution in the first preparation solution. Use the obtained The interfacial activity only supported the particle group 4 and the detergent particle group 4 was produced in the same manner as in Example j. The amorphous aluminosilicate was used in an amount of 7 parts by weight, and the permeability of the detergent particle group was the lowest i. Comparative Example 2 As a fine crystal precipitation agent, sodium bromide (manufactured by Otsuka Chemical Co., Ltd.) was used, and in the same manner as in Example 1, granules for supporting surfactants were obtained. 5. The obtained surfactants were used for supporting Using the particle group $, a detergent particle group 5 was produced in the same manner as in Example 1. However, the example 3 of the amorphous manganese acid was also used to give the weight of 7 parts by weight to the mixer, and the ::: holding particle group 5 was continuously loaded with the surfactant composition to form a collective grudge. Deteriorated so that it cannot be measured. As shown in Table 2, the composition and physical properties of the surfactant group-containing particle group 5 are shown in Table 2. Examples of the present invention The effect of the fine crystal precipitation agent a. The particle size of the water-soluble salts precipitated in the pulp is fine. It is also necessary to remove more crystal precipitating agent, which can make the number of crystals (water-soluble salts. Therefore, the surfactant of the present invention supports -68-^ 纸 码 _ 巾 关 家 鲜 (C'NS ) A4 size (210 X 297 ¾ ^ (Please read the precautions on the back first ^ Fill in this page) Pack n -Γ H 1 凝 Condensate tr-i · ------- canister · 51 3 9 3 2 A7 B7 Description of the invention (66 particle groups (particle groups 1, 2 for "surfactant carrying", "", "", and comparative examples) can be improved in carrying, so the detergent particles of the present invention (detergent particles Yuqun 1, 2, 4) can reduce the amount of amorphous aluminosilicate. Compared with the pore volume distribution method, the diameter becomes smaller, which is a favorable pore volume distribution. Table 1 Employee Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printing example 1 Example 2 Comparative example 1 Example 3 Comparative example 2 Zeolite 44.0 42.0 44.0 44.0 Sodium carbonate 21.0 20.0 21.0 21.0 Group sulfuric acid pin 21.0 20.0 21.0 21.0 into sulfurous acid steel 0.8 0.8 0.8 0.8 Polypropionate 5.0 5.0 5.0 5.0 Fluorescent Dye 0.2 0.2 0.2 0.2 Sodium Gasified 4.0 8.0 4.0 0.0 Volume Sodium Bromide 0.0 0.0 0.0 4.0 % Moisture 4.0 4.0 4.0 4.0 Total 100.0 100.0 100.0 100.0 Fine crystal precipitation agent is added after adding 〇〇〇 concentration operation for temperature adjustment of the precipitation slurry-crushing slurry-moisture [%] 42 42 42 42 42 slurry polymerization-temperature [° C] 40 40 40 40 40 Increase in undissolved salts [%] 16.3 32.5 3.0 Average particle size [mm] 250 253 245 240 242 -69- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Loading ---- 1 (Please read the precautions on the back to fill out this page)

I ti -------- 1239351 A7 B7 67 V. Description of the invention () Bulk density [g / L] 601 603 599 607 610 Particle strength [MPa] 29 34 28 32 30 Material carrying capacity [mL / g] 0.45 0.51 0.44 0.38 0.37 Maximum frequency diameter of sexual pore volume distribution [// m] 0.81 0.67 L63 0.78 1.58 0.01 ~ 3 microns [mL / g] 0.32 0.34 0.29 0.33 0.29 Table 2 Employee Consumption Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Printing Example 1 Example 2 Comparative Example 1 Example 3 Comparative Example 2 Particle group for surfactant cleaning 1 100 Particle group for surfactant cleaning 2 100 Particle group for surfactant cleaning 3 100 Group of surfactant-supporting particles 4 100 Group of surfactant-supporting particles 5 100 Surfactant 50 Sodium alkylbenzene sulfonate (21) Heavy polyoxyethylene alkyl ether (21) Amount of polyethylene glycol (4) Parts (water) (4) Number of amorphous aluminosilicates 6 4 6 7 11 Average particle size [μm] 258 264 Cannot measure 262 Cannot measure bulk density [g / l] 738 748 Cannot measure 745 Cannot measure Fluidity [sec] 6.2 6.1 Cannot be measured 6.2 Cannot be measured Of 11,515 Example 4-70- (Read Notes on the back page fill iv)

I --------- Order --------- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1239351 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (5-15 parts by weight of water is placed in a mixing tank with a decompression device and a stirrer device with a jacket to raise the temperature to 35r. In this step, 108 parts by weight of sodium carbonate are added as sodium 108 wound weight, 4 parts by weight of sodium sulfite, 40 parts by weight of 40% by weight sodium polypropionate aqueous solution, 58 parts by weight, 1 part by weight of glory dye, and 20 parts by weight of stagnant stone were stirred for 30 knives to obtain the water-soluble component completely dissolved. Preparation liquid. The final temperature of this preparation liquid was prepared to 60 ％ (moisture 55% by weight). This i-th preparation liquid was passed through a jacket while the warm water of valence was passed under a reduced pressure of _ ear, and the water was allowed to flow. Evaporate and concentrate to 45% by weight of water. The amount of water-soluble inorganic salt (average particle size: 18 microns) produced by concentration is 25% by weight of those dissolved in the first preparation solution. The concentrated preparation solution is The same method as in Example 1 was used to spray dry the spray drying tower (high temperature gas' from the lower part of the tower at a temperature of 22 〇 .. Supply and discharge at 110 ° C from the top of the tower. The moisture content of the obtained surfactant-supporting particle group 6 is 4% by weight. -1 Use the obtained surfactant-supporting particles The method of manufacturing cleanser particle group 6 is as follows. The minimum amount of amorphous acid salt that is used as the minimum amount of clean particle group is i. Example 5 The amount of water added is adjusted to prepare the water content to be concentrated to moisture. 45% by weight, to obtain the second preparation / 0 &lt; the first preparation solution ', to obtain the surfactant group-bearing particle group 7 Example 4 in the same inorganic salt (average particle size: 20 microns) as the preparation solution (The amount of the aqueous solution is 19% by weight. The amount of the particles is measured in jindeli, and the number of particles in the preparation solution before and after the concentration of the noodles is 71.-This paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 public ^ (Please read the precautions on the back ^ fill in this page) € ---------- ^ --------- 1239351 A7 V. Description of the invention (69 and particle size distribution. In addition, in the measurement, in order to improve the measurement accuracy, it is equivalent to 1 ^ 64.9 weights prepared by using other zeolite blending tanks. ), And this concentrated phase, and water (7% by weight) were measured. It is equivalent to the liquid of H 2 preparation (the slurry water fraction is 426 / s, the average particle grip (the number of liquids in 2 4f liquid) Fortunately, the size of the second preparation solution of the reduced particles was 114 microns, which is equivalent to the concentration of 6351 / s, and the average diameter is 20.0 microns. Based on the results of these measurements, the water-soluble salt was concentrated. The number of particles increased by 5925 particles / S and increased by 185 microns. "丨 The average particle size of raw salt cores is the particle group 7 for the surfactant-supporting particles obtained in the same manner, and the detergent particle group 7 is manufactured in the same manner. As the minimum amount of the detergent particle group, the input amount of the amorphous osmate was 2.5 parts by weight. Comparative Example 3 The amount of water added was adjusted to prepare a preparation solution having a water content of 45% by weight, except that the concentration in row A was carried out in the same manner as in Example 4 to obtain a surfactant-supported particle group 8. The obtained surfactant was used to support the granule group 8, and the fish-like material was used to prepare the good group 8. The minimum amount of amorphous aluminosilicate that is used as the detergent detergent particle is ^ servings. If the amorphous aluminosilicate is less than 8 parts by weight, no exudability can be obtained. ^ Comparative Example 4 The amount of water added was adjusted to prepare a preparation solution with a water content of 55% by weight, except for concentration. The same procedure as in the example was performed to obtain the interfacial activity. Grain cluster 9. The water-soluble components in the preparation solution are completely dissolved. Using the obtained surfactant-supporting particle group 9, in the same manner as in Example i, the manufacturing process was ordered and re-introduced. -72- This paper is suitable for financial purposes_ ϋ〇x 297mm70 1239351 V. Description of the invention (Detergent particle group 9. The amount of amorphous _ acid salt used as the detergent particle group is 6 parts by weight: the minimum amount of k is less than 6 parts by weight, no exudability can be obtained 1. &quot; Example 6 of salt reduction In the same manner as in Example 4, 46% by weight of water was prepared. After that, it was added to a finely reduced amount to parts by weight, and then stirred for 3. minutes to obtain a second preparation liquid (water 4). Sodium dichloride 19 is concentrated by the thick drawing operation and the addition of fine crystal precipitation agent (❶). The amount of borrowed salt is 35.7 weight of those dissolved in the first preparation solution: water-soluble inorganic. In the same method as in Example 1, the second active agent Supporting particle group 10. The supporting particle group 1G obtained at the interface is dried to obtain the particle group 10 as proposed in the embodiment. The cleaning agent particle group 10 has ten :: r 1 Preparation of the preparation solution, and then the household particles H11 with the active agent H. Surfactant-carrying particle group u, the detergent particle group U was prepared by the toilet method. Example 1 is the same as the minimum value printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The exudation property is 1 (take the lower part of your non-aluminous aluminosilicate as the weight. The composition and physical properties of the active agent-carrying particle group 6 ~ "are shown in Table 3, and the detergent particle group 6 ~ u The physical properties are shown in Table 4 .: As a result of Tables 3 to 4, because the surfactant group-carrying particle groups 8, 9 have a relatively low carrying capacity, the use of this detergent group has a good exudative detergent sheet paper. Scale Turning Towels Guan Jiaxian (CNS) A4 Specification (21Q_ x -73 1239351

V. Description of the invention In the case of the subgroup (71), it is necessary to add a lot of amorphous aluminosilicate. On the one hand, the maximum frequency path of the 6 '7 pore volume distribution of the surfactant supported by the concentration operation is I: Below micron, the freshness is higher than its carrying capacity. With this particle group, the amount of amorphous aluminosilicate can be reduced, and the detergent particle group with good exudation can be obtained. In addition, the combined use of pulp = concentration operation With the addition of fine crystal precipitation agent, the loading capacity of the surfactant-supporting particle group can be further improved. Table 3 Printing by Employee Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Example 4 Example 5 Comparative Example 3 Comparative Example 4 Implementation Example 6 Example 7 Zeolite 44.0 40.0 _ Sodium carbonate 23 0 23.0 Group sodium sulfate 23 0 23.0 _ Sodium sulfite 08 0.8 Sodium polypropionate 5 0 5.0 One fluorescent dye 0.2 0.2 One sodium chloride 00 4.0 One sodium bromide 00 0.0% Moisture 4.0 4.0 A total of 100.0 100.0 A fine crystal precipitation agent is added after adding a concentration operation of 0.000 for temperature adjustment of the precipitation slurry-crushing ^ • water [〇 / 〇] 55—45 50—45 45 55 55- ^ 45 50—45 Pulp-Temperature 60 60 60 60 60 60 -74- This paper size applies to China National Standard (CNS) A4 (210 X 297) (Centi) 1239351 A7 B7 heart 72 V. Description of the invention () Increase in undissolved salts [%] 25 19 35.7 27 Average particle size [mm] 280 265 235 210 264 258 Bulk density [g / L] 615 600 600 480 601 605 grain strength [MPa] 28 28 28 17 30 30 material carrying capacity [mL / g] 0.68 0.6 0.42 0.53 0.66 0.64 maximum frequency diameter of sexual pore volume distribution [// m] 0.82 0.96 1.8 2.2 0.55 0.54 0.01 ~ 3 micrometers [mL / g] 0.37 0.36 0.35 0.47 0.38 0.37 Table 4 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Example 4 Example 5 Comparative Example 3 Comparative Example 4 Example 6 Example 7 Surfactant-supporting particles Group 6 100 Group of surfactant-supporting particles 7 100 Group of surfactant-supporting particles 8 100 Group of surfactant-supporting particles 9 100 Group of particle-supporting groups 10 100 Interfacial activity Particle-supporting particle group 11 100 interfacial activity 50 Benzylbenzoic acid steel (21) Heavy polyoxyethylenyl ether (21) Amount of polyethylene glycol (4) Parts (water) (4) Number of amorphous aluminosilicate 1.5 2.5 8 6 0 1 Average Particle size [micron] 300 280 245 230 271 268 Bulk density [g / l] 740 740 730 660 742 743 Fluidity [sec] 6.3 6.3 6.3 6.4 6.3 6.3 Exudability 1 1 1 1 1 1 -75- (Please (Read the notes on the back first and fill in this page)

I n ϋ ϋ l · — ϋ ϋ ϋ &lt;, J &gt; ϋ ^ 1 I n -ϋ · ϋ ϋ I Μ &quot; 々ο This paper size applies to China National Standard (CNS) A4 (210 χ 297 mm) 1239351 A7 V. Description of the Invention (73 Employee Consumption Example 8) Put 407 parts by weight of water into a mixing tank with a jacket with a stirring device, and pass warm water at 40 ° C through the jacket. 132 parts by weight of sodium sulfate Add 1 part by weight of sodium sulfite, 1 part by weight of fluorescent dye, and stir off 10 minutes. Add 132 parts by weight of sodium carbonate, 72 parts by weight of 40% ❻ / ❾ sodium polyacrylate aqueous solution, and 252 parts by weight of zeolite, and stir. 15 minutes, the first preparation solution of 40 ℃ was obtained. Next, 60C of water was passed through the jacket, and stirred for 30 minutes, so that the temperature of the preparation solution was 60 ° C to obtain a second preparation solution. The temperature was increased to prepare the preparation solution. The viscosity was increased from 60 mPa · S to 1200 mpa · s, and the amount of the water-soluble inorganic salt precipitated by this operation was 8 2% by weight of those dissolved in the first preparation liquid. The second preparation liquid obtained was used to compare with the Example丨 The same method is used for spray drying. The high-temperature gas supplied to the spray drying tower is supplied from the lower part of the tower at a temperature of 2 l (rc, from the tower). At 105. (: discharged. The obtained surfactant-supporting particles and the moisture content were 4% by weight.: The obtained surfactant-supporting particle group 12 was used in the same manner as in the example] = method, preparation Detergent particles and. As a clean. Subgroup of the paintability of 1 <the minimum amount of amorphous aluminosilicate input is 6 parts Example 9 Preparation H Example t] 8 In the same order, a 40 ° C The first preparation liquid, the preparation and the tube-type heat exchanger, the temperature of the preparation liquid is raised to 70 ℃, the second preparation liquid. In this preparation liquid, confirm the water solubility :, L decanted. Fine heating operation, The viscosity of the preparation solution is from M to the first! The amount of the prepared soluble inorganic salt is 1.02% by weight of the amount of K 罘 II in the preparation solution. 5 事 T 丁丁 -4 The solution of this paper Γ degree is applicable iiii ^ s) A4 size (21. -76-

I 1239351 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 74 V. Description of the invention () Measure the number of particles and particle size distribution in the preparation solution before and after the TSUB-TEC M100 is concentrated. At the time of measurement, as in Example 4, a liquid equivalent to the first preparation liquid (slurry water content 60.1% by weight) prepared by using a separate blending tank without blended zeolite was heated to 7 (TC equivalent Liquid of the second preparation liquid. The number of particles in the liquid equivalent to the first preparation liquid was 769 particles / s, and the average particle diameter (number basis) was 170 μm. After heating, the particles were equivalent to the liquid in the second preparation liquid. The number was 8255 particles / s, and the average particle size was 280 microns. Since then, the number of particles of water-soluble salts has increased by 7486 particles / s, and the average particle size of the increased water-soluble salts has been 23.4 microns. The obtained second preparation liquid was spray-dried in the same manner as in Example 1. The high-temperature gas supplied to the spray-drying tower was supplied from the lower part of the tower at a temperature of 22 ° C, and was discharged from the top of the tower at no ° c. The obtained interface activity The moisture content of the agent-supporting particle group 2 was 4% by weight. Using the obtained surfactant-supporting particle group i 3, the detergent particle group 13 was produced in the same manner as in the Example. As the detergent particle group infiltration Amorphous aluminosilicate with a minimum input of 1 is 5 parts by weight Comparative Example 5 In the same procedure as in Example 8, 40 t of the i-th preparation liquid was prepared, and the preparation liquid was spray-dried under the same conditions as in Example 8 without increasing the temperature of the preparation liquid to obtain the active agent-supporting particle group 14. Supported with the obtained surfactant; particles = Group 1 4 and manufactured detergent particle group ^ 4 in the same manner as in Example 1. Made = Amorphous inscription with minimum amount of i The salt is 8 parts by weight. If the amorphous aluminosilicate is less than 8 parts by weight, it cannot be carcass-packed ---------- 1Γ --------- (Please read the back (Note #Fill this page) f -77-

1239351 A7 B7

Printed in Comparative Example 6 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, so that the temperature of the warm water passing through the jacket is 70 r, which is 70. . Except for the Wth stock solution, the same procedure as in Example 5 was performed to obtain a surfactant-supporting particle group. Using the obtained surfactant-supporting particle group, a detergent particle group 15 was produced in the same manner as in Example ^. The minimum amount of oxalate that was injected into the cleaning agent particle group was 1G parts by weight. Continuing blood Exudability cannot be obtained with less than 10 parts by weight of memantine1. …, Example 10 / Read Example 9 The same method was used to prepare the first preparation solution, and then the slurry was passed through a ## (heat exchanger), and the temperature of the preparation solution was raised to 7 generations, and then finely added The second crystallization solution was obtained by crystallization of the precipitating agent. Precipitation was carried out by increasing the temperature of the preparation solution (the amount of the hydrous inorganic salt is ^% of the amount of those dissolved in the ith preparation solution. The second preparation solution was obtained in accordance with the example] The same method is used for spray drying. The high-temperature gas supplied to the spray drying tower is acknowledged from the bottom of the tower at a temperature of 205 ° F and from the top of the tower is 95. (: discharged. The obtained interfacial activity _ holding particles ^ moisture is 4 weight %. Using the obtained particle group 16 for supporting the surfactant, the cleaning agent particle group 16 was manufactured in the same manner as in Example π, and the amorphous aluminum silicon having the minimum amount of the detergent particle group having an exudation property of 1 was input. The amount of the acid salt is 3 parts by weight. The composition and physical properties of the obtained surfactant-supporting particle groups 12 to 16 are shown in Table 5, and the physical properties of the detergent particle groups 12 to 16 are shown in Table 6. From Tables 5 to 6 As a result, due to the particle group η for the surfactant support, the support energy of μ is relatively low. Use this particle group as a cleaner with good exudation • 78-(Please read the note on the back first? Matter 1 ^ Fill this page) t Binding -------- This paper size applies to Chinese national standards (CNS ) A4 size (210 X 297 mm) 1239351 A7 B7 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives 76 V. Description of the invention () In the case of particle swarms, it is necessary to add many amorphous aluminosilicates. On the one hand, The maximum frequency diameter of the pore volume distribution of the surfactant-supporting particle groups 1 2 and 13 is 1.5 μm or less, and because of its high supporting energy, using this surfactant-supporting particle group, even if it is amorphous The amount of aluminosilicate is small, and detergent particles with good exudation can also be obtained. In addition, due to the thickening operation of the slurry and the addition of a fine crystal precipitation agent, the particle-holding performance of the surfactant-supporting particle group can also be obtained. Table 5. Example 8 Example 9 Comparative Example 5 Comparative Example 6 Example 10 Zeolite 44.0 40.0 Sodium carbonate 23.0 23.0 Group sodium sulfate 23.0 23.0 Sodium sulfite 0.8 0.8 Polyacrylic acid sodium 5.0 5.0 Fluorescent dye 0.2 0.2 Heavy gas Sodium chloride 0.0 4.0 Amount of brominated steel 0.0 0.0% Moisture 4.0 4.0 Total ίΟΟ.〇 100.0 After adding a fine crystal precipitation agent, add a concentration operation to adjust the temperature for precipitation. 〇〇〇〇 Pulp-pulverized pulp-Moisture [%] 45 45 45 45 45 -79- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)-installed ------------ order --------- ^^^ 1. (Please read the precautions on the back ^ Fill this page first) t 1239351 A7 B7 77 V. Description of the invention () Printed pulp for consumer cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-Temperature [° C] 40- ^ 60 40-70 40 70 40—70 Increase in undissolved salts [%] 8.2 10.2 _ 25.2 Average particle size [mm] 248 245 260 244 238 Bulk density [g / L] 608 615 598 620 614 Particle strength [MPa] 30 30 28 30 32 Object carrying capacity [mL / g] 0.47 0.49 0.42 0.38 0.55 The maximum frequency diameter of sexual pore volume distribution [// m] 1.2 1.1 1.9 1.6 0.95 0.01 ~ 3 microns [mL / g] 0.33 0.32 0.37 0.32 0.31 Table 6 Example 8 Example 9 Comparative Example 5 Comparative Example 6 Example 10 Clearing the surfactant-supporting particle group 12 100 Surfactant-carrying particle group 13 100 Agent Surfactant-carrying particle group 14 100 Set of Surfactant-carrying particle group 15 100 Forming Surfactant-carrying particle group 16 100 Surfactant 50 Alkylbenzene Sodium sulfonate (21) Heavy polyoxyethylene alkyl ether (21) Amount of polyethylene glycol (parts) (water) (4) Number of amorphous aluminosilicates 6 5 8 10 3 Average particle size [micron] 265 267 278 266 250 Bulk density [g / l] 740 752 732 745 748 Sexual fluidity [sec] 6.1 6.2 6.3 6.2 6.1 Exudation 1 1 1 1 1 -80- (Please read the precautions for Shanghai noodles first

I -----, fill in this page) tr-i · ------ 4 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1239351

V. Description of the invention (78) Example 11 1 The first preparation solution prepared in the same manner as in Comparative Example 1 was prepared in a colloid mill MZ-80 (manufactured by Kobelco Pantec (Company)) in the form of _kg / hour. Crush. '' Just before TSUB-TEC M, the number of particles and particle size distribution in the preparation solution before and after pulverization were measured. During the measurement, as in Example 4, a solution equivalent to the first preparation liquid prepared without zeolite blending in another blending tank and 800 kg / hour was used to find this crusher as equivalent. The second preparation liquid. The number of particles in the first preparation liquid &lt; solution was 778 particles / s, and the average particle size (based on the average particle size) was 172 m. The number of particles in the liquid equivalent to the second preparation liquid after pulverization was 2648 particles / s, and the average particle diameter was 24 5 m. As a result of these measurements, the number of particles by pulverizing the water-soluble salts increased by 2476 particles / §. The second preparation was pulverized and spray-dried in the same manner as in Example 丨. The high-temperature gas supplied to the spray-drying tower is supplied from the lower part of the tower at a temperature of 200, and is discharged from the top of the tower at 90 ° C. The moisture content of the obtained surfactant-supporting particle group 7 was 4%. The surfactant group-carrying particle group 17 obtained by the employee cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs was used to manufacture the detergent particle group 17 in the same manner as in Example 1. The minimum amount of amorphous aluminate which is 1 as the detergent particle group exudation is 8 parts by weight. Example 1 2 A second preparation solution prepared in the same manner as in Example 1 was used on a Cittron (Buffalo y) CD 1010 type (manufactured by Pacific Engineering Co., Ltd.) with a rotation number of 1 Wet pulverization at a flow rate of 800 kg / h under the condition of 1200 rpm. Measure the number of particles in the preparation solution before and after pulverization at TSUB-TEC M100 -81-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1239351 A7 B7 V. Description of the invention (79 Wisdom of the Ministry of Economic Affairs Printed by the Consumers' Cooperative of the Property Bureau = Degree points ^ Same as in the example &quot; It is equivalent to the number of particles in the preparation &lt; Xinzhong is 778/8, the average particle size is 172, = The number of particles is 2634 particles / 8, the average particle size (number: rate) is 21.2 microns, and the number of particles in the liquid equivalent to the second preparation solution after crushing is 5 particles / S, and the average particle size is 18.4 microns. Since then, the determination of the social fruit 'hunting was made by crushing, and the number of particles of water-soluble salts was increased by 2,041 / 8 / 8.- The second preparation liquid of the crushing was spray-dried in the same manner as in Example i. The difficulty of Linmei subgroup, the analysis results of dragons and no holes, for the circle purity of particles, 2 ~ 70% of the holes equivalent to the diameter of the circle and more than 10% of the depth of the hole has the presence of β or more ^ The particle 'contains 85%. In addition, for the 90% of the trapped particles, the "hole equivalent" of the trapped hole is required. The diameter of the circle / the diameter of the particle is equivalent to the average diameter of the circle "and 100 is 15%. Using the obtained surfactant-supporting particle group i 8, the detergent particle group 18 was produced in the same manner as in the example. As The minimum amount of the amorphous aluminosilicate charged with the detergent particle group having a permeability of 1 was 5 parts by weight. Example 1 3 A second liquid preparation of 45% by weight of water prepared in the same manner as in Example 5 was used in Colloidal mill MZ-80, wet pulverization at a flow rate of 800 kg / hr. The number and particle size distribution of particles in the preparation solution before and after pulverization were measured at TSUB-TEC M100. In addition, no blending will be performed in Example 5. The zeolite-prepared liquid is equivalent to the second preparation liquid before and after pulverization, and the measurement is performed. The number of particles in the preparation liquid before pulverization is 635 1 particles / s, and the average particle diameter (number basis) is -82. Standards apply to China National Standard (CNS) A4 specifications (210 X 297)

X 出 备 —----- ^ --------- (Please read the notes on the back first to fill in this page) ^ 1239351

8916 Water soluble 20.0 microns. The number of particles equivalent to that in the second preparation solution after pulverization was / s, and the average particle diameter was 17.0 m. From these measurements, the number of particles of pulverized A salt increased by 2565 particles / s. In the same manner as in Example 1, the pulverized second preparation liquid mist was dried. The high-temperature gas supplied to the spray-drying tower was discharged from the lower part of the tower at a temperature of 22 ° C and discharged from the top of the tower at 11 ° C. Sosi ψ ^! L. The pellet group for the surfactant-supporting granules was 9 The moisture content was 4%. Using the obtained surfactant-supporting particle group 19, the detergent particle group 19 was produced in the same manner as in the example, and the minimum amount of the detergent particle group was 1 without any input. The shaped aluminosilicate is 0.5 parts by weight. &Quot; Example 14 The second preparation liquid prepared in the same manner as in Example 9 was used in Kitpit 1 ^ 1010, and the number of rotations Under the conditions of 112 million, wet pulverization at a flow rate of lion kg / hour. Printed on the TSUB-TEC M100 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs to determine the number of particles and particle size distribution in the preparation solution before and after pulverization. The liquid equivalent to the second preparation liquid prepared in Example 9 without zeolite was pulverized and measured before and after. The number of particles in the center of the liquid preparation before the pulverization was 8255 particles / s, and the average particle size (number Benchmark) is 28.0 microns. Crushing | equivalent to the second preparation solution The number of particles was 11,831 particles / s, and the average particle size was controlled to 203 micrometers. From these measurements, the number of water-soluble salt particles that were pulverized increased by 3576 particles / s. The same method as in Example i was used. The second preparation liquid pulverized and spray-dried. The high-temperature gas supplied to the spray-drying tower is supplied from the lower part of the tower at a temperature of 220 ° C and from the top of the tower at 110. (: discharged. The obtained surfactant-supporting particle group 2 〇Moisture is 4%. 83-

811239351 A7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the Invention The minimum input amount of amorphous aluminosilicate is 35 parts by weight. The composition and contents of the obtained surfactant group particles 17 to 20 are shown in Table 7, and the detergent particle groups 17 to 20 are shown. The physical properties are shown in Table 8. From the results of Tables 7 to 8, the water-soluble salt particles in the slurry were wet-pulverized, and the number of particles could be increased to increase the holding capacity of the particles for the surfactant support. Amount of amorphous aluminosilicate. In addition, the effect of improving the support of the interface and tongue-supporting particles by wet pulverization can be increased. The more the content of the slurry, the greater the amount. ㈣ Table 7

-84 This paper size applies to China National Standard (CNS) A4 specifications (21Q χ 297 public love) i IIIII · (Please read the note on the back? Matters # Fill this page} Order-% 1239351 A7 B7 Intellectual Property Bureau, Ministry of Economic Affairs Printed by the Employee Consumption Cooperative 82 V. Description of the invention () Precipitation for temperature adjustment 〇 crowd-crush 〇 〇 〇 浆 pulp-moisture [%] 42 42 50- &gt; 45 45 pulp-temperature [° c] 40 40 60 40- ^ 70 Increase of undissolved salts [%] 16.3 19 10.2 Average particle size of particle physical properties [// m] 240 252 258 244 Bulk density [g / L] 604 605 602 610 Particle strength [MPa] 31 31 30 30 Carrying capacity [mL / g] 0.42 0.51 0.65 0.54 Maximum frequency of pore volume distribution [ym] 1.05 0.76 0.56 0.92 0.01 to 3 microns [mL / g] 0.3 0.32 0.36 0.32 Table 8 Example 11 Example 12 Example 13 Example 14 Detergent composition parts by weight Surfactant-supporting particle group 17 100 Surfactant-supporting particle group 18 100 Surfactant-supporting particle group 19 100 Surfactant-supporting particle group 20 100 Interface Active agent 50 Acid steel (21) Polyoxyethyl ether (21) Polyethylene glycol (4) (Water) (4) Amorphous aluminosilicate 8 5 0.5 3.5 Average particle size [micron] 251 267 273 256 -85 -I pack ----- (Please read the notes on the back first and fill out this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) f Order -------- -1239351 A7 B7 83 Bulk density, fluidity, exudation 5. Description of the invention ([sec]

~ 243_ 750 —Z55 6.1 — --- ^ _63 1_ 1 1 1 Ί 1 --J Example 15 In the same manner as in Example 4, a “moisture” heavy solution was prepared, and colloidal mill MZ__ was used to prepare crushing. After that, carry out the concentration of your ^ ^ pounds, &lt; Wet powder in the machine, Chen '% operation to 48% by weight of water, to get the first :. The = preparation solution is spray-dried to obtain the surfactant loading 2 = Two: Γ agent carrying particle group 21, the same as in Example 1 ^? ^ Clear _ particle group 21. For riding _ particle group infiltration ^ Horse K takes a low input of amorphous aluminosilicate is 7 Comparative Example 7 The same method as in Example 15 was used to adjust the water content of 48% by weight to prepare the first and second pulverized, concentrated, and spray-dried to obtain interfacial active particles. Supported with a surfactant Detergent particle group 22 was manufactured by using the particle group 22, in the same manner as described above. However, the "amorphous incisive acid sol" was similar to that in Example 1 5 and 7 parts by weight was added to the sand mixer in the mixer. The surfactant-supporting particle group 22 continues to support the surfactant composition into an agglomerated state, and the physical properties are deteriorated so that it cannot be measured. Example 16 In the same manner as in Example 8, a first preparation solution with a moisture content of 48% by weight was prepared. The colloidal mill MZ-80 was wet-pulverized at a flow rate of 800 kg / hour. The preparation liquid was heated to 70 ° C to obtain a second preparation liquid. Apply this 2nd 86-M scale to China National Fresh (CNS) A4 specifications (21G X 297 public love. Packing * ---- Order --------- ίPlease read the note on the back first Matters written on this page), printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy

、 Explanation of the invention (84 _ preparation liquid spray-dried to obtain W m particles for shovel warfare 23 supported by surfactants. Particle groups 23 for shovel warfare supported by surfactants, same as in Example 1) Method: The weight of the non-aqueous aluminosilicate whose cleaning agent A group of detergent particles had the lowest exudation amount was 7 parts by weight. Comparative Examples 8, 2, and Example 16 In the same method, the moisture content was adjusted to 48% by weight. The first preparation liquid ... Wet pulverization and heating operation and spray drying to obtain the surfactant group supporting particle group 24. The surfactant group supporting particle group 24 is used in the same manner as in Example 16, Detergent particle group 24 was manufactured. Amorphous crushed acid salt was blended with 7 parts by weight in the same manner as in Example 16. The surfactant group-containing particle group 24 continued to support the surfactant composition and was discharged from the thunder drop to the mixer. The physical properties of the detergent particle group 値 are greatly deteriorated. The combination and physical properties of the obtained surfactant-supporting particle group 2 丨 to 2 4 are shown in Table 9 'The physical properties of the detergent particle group 21 to 24 are shown in Table 10. From the results in Tables 9 to 10, the first preparation liquid was wet-pulverized. Concentration and temperature increase also increase the carrying capacity of the surfactant-supporting particle group. Table 9 Example 15 Comparative Example 7 Example 16 Comparative Example 8 Zeolite 4 10.0 _ 40.0 Sodium carbonate 13.0 36.0 Group sodium sulfate 36.0 13.0 into sodium sulfite 0.8 0.8 Polyacrylic acid steel — 6.0__ 6.0 -87 • Applicable to China National Standard (CNS) A4 (210 X 297 mm) 1239351 A7 B7 V. Description of invention (85) Printed by the Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Fluorescent dyes 0.2 0.2 Sodium chloride chloride 0.0 0.0 Amount of brominated steel 0.0 0.0% Moisture 4.0 4.0 Total 100.0 100.0 Fine crystal precipitation agent is added after concentration operation. Precipitation for temperature adjustment. Pulp-crushing 00 Pulp-water [% ] 51—48 48 48 48 Slurry-temperature [° C] 50 50 40—70 40 Increase in undissolved salts [%] 11.6 _ 9 average particle size in sun exposure | &gt; m] 225 205 210 198 bulk density [ g / L] 545 551 505 460 Granular particle strength [MPa] 22 16 17 12 Material carrying capacity [mL / g] 0.45 0.38 0.46 0.4 Maximum frequency distribution of pore volume distribution [# m] 1.12 1.89 1.2 1.5 0.01 ~ 3 micrometers [mL / g] 0.33 0.28 0.36 0.38 Table 1 0 Example 15 Comparative Example 7 Example 16 Comparative Example 8 Particle group for surfactant cleaning 21 21 Particle group for surfactant cleaning 22 100 Group of surfactant-supporting particles 23 100 Group of surfactant-supporting particles 24 100 Please read the back and front precautions, III day. The size of the paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1239351 A7 B7 heart 86 V. Description of the invention () into a surfactant — &quot; &quot; ~ ~ _______ —---- 50 sodium alkylbenzene sulfonate — ---------- --- A · (1) (21) Heavy polyoxyethylene alkyl ether- (21) Amount of polyethylene glycol 份 parts (water) (4) Number of amorphous aluminosilicates 7 7 7 7 Average particle size [micron ] 243 Cannot measure 231 240 Bulk density [g / l] 721 Cannot measure 702 LTV / --- 623 Unisex fluidity [sec] 6.2 Cannot measure 6.2 8.6 Exudative 1 5 1 4 _ (Please read the back Precautions and filling in this page) Example 17 In the same manner as in Example 12, a surfactant was obtained. Particle group 25. A 40% by weight aqueous solution of sodium polyacrylate was produced by the following method. Charge 80.3 kg of water 'and raise the temperature to 100 ° C. While maintaining the temperature at 100 ° C, it took 4 hours to put 190 kg (2 · mol 仟 mol) of 80% by weight propionate and 3.9 kg (48.6 mol) of 98% 2-fluorenyl alcohol aqueous solution in another 6 5.0 kg (6.3 mol) of a 30% by weight aqueous solution of persulfate soda was dripped at a certain rate to perform polymerization. After the completion of the dropwise polymerization, 21.1 kg (217.6 mol) of 35% by weight hydrogen peroxide solution was dripped for 1 hour for deodorization, and then ripened for 4 hours and cooled. At a temperature of 6 (TC, as a reducing agent, 3.3 kg (11.5 mol) of 35% by weight sodium bisulfite aqueous solution) was reacted for 1 hour. After cooling, while maintaining below 40 ° C, 48% by weight aqueous sodium hydroxide solution was added. 167 -89-This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm). · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Note on the back? Matters? Fill out this page) kg (2 moles), add concentrated water to obtain 485 kg of the target 40% by weight polymer aqueous solution. The weight average molecular weight of the polymer obtained is 1,000. 〇. Molecular weight measurement method 1 · Conversion standard material: Polyacrylic acid (AMERICAN STANDARDS CORP) 2 · Dissolution ·· 2 · mol / L phosphate buffer / CIi3CN: 9/1 (volume ratio) 3 · Column ·· PWXL + G4000PWXL + G2500PWXL (manufactured by Tosho Corporation)

4. Detector: RI 5. Sample concentration: 5 mg / ml 6. Injection volume: 0. liter liter 7. Measurement temperature: 40 ° C 8. Flow rate: 1.0 ml / min. The analysis results of the pores of the particles of the particle group for carrying are analyzed, and the diameter of the circle corresponding to the particle has 2_70 //. The pores having a diameter equivalent to a circle and a depth of 10% or more existed in the above-mentioned sunk particles and contained 90%. In addition, for the 90% of the sunken particles, the average value of [the diameter of the hole corresponding to the circle / the diameter of the circle corresponding to the particle] X 100 of the sunken hole required was 19%. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Using the obtained particle group 25 for supporting surfactants, a detergent particle group 21 was produced in the same manner as in Example i. Detergent particle group 25 'has very good fluidity, and the second degree of exudation is 1 even without adding amorphous aluminosilicate. Wang You Example 1 8 -90- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) A7 1239351 V. Description of the invention (88 B7 After being prepared in the same way as in Example 6, the concentration operation is performed To 51% by weight of water; 52%: the first preparation of the liquid agent to make 50% by weight of water, and then spray crystals to precipitate the particle group 26. Using the interface activity :: 55 particles of detergent particles produced by the same method using the surfactant Weight., 26, when the surfactant combination cleaner particle group 26 is fully self-contained, ψ ft m, ready to move, even without the addition of A-shaped aluminum silicon bismuth salt, the degree of exudation is also i.…,疋 Comparative Example 9 In the same manner as Comparative Example 1, 27. You Tian Zhang π, method 仵 Surfactant-carrying particle group 7 using all components &lt; Surfactant-carrying class γ7 Manufacture cleaner particles in the same manner : 2 groups of 7 particles 27 'to the same as in Example., Shovel to group 27. Sowing alumino-silicate aluminous; 17 similarly no addition, because the female sex agent Lin and female == and interface The active agent supporting particle group 25 is relatively low, and is continuously supported: a surfactant combination The substance 'was brought into an agglomerated state in the mixer by a lightning drop, and the physical properties were deteriorated to an unmeasured level. The composition and physical properties of the obtained surfactant-supporting particle groups 25 to 27 are shown in Table 11, and the physical properties of the detergent particle groups 25 to 27 were shown. The results are shown in Table 12. From the results of 1 1 1 2, by using the group of particles of the surfactant-supporting group, the water content of the preparation liquid can make the particle-groups of the surfactant-supporting group more efficient. The maximum pore volume distribution of the pore volume distribution of the surfactant-supporting particle groups 25 and '26 obtained by the method of the present invention is 15 micrometers or less, and its supporting capacity is large. This particle group is used even if no aluminum silicon is added. Acid salt, scary detergent particles can be obtained with good exudation, of course, can be highly blended with the interface 91 297 mm)

% National Fresh (CNS) A4 specifications (210: 1239351 A7 B7 89) V. Description of invention () Active agent. Table 1 1 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Example 17 Example 18 Comparative Example 9 Zeolite 36.0 Sodium carbonate 25.0 Group sodium sulfate 23.8 Sodium sulfite 1.0 Polyacrylic acid sodium 6.0 Fluorescent dye 0.2 Sodium vaporization 4.0 Amount of sodium bromide 0.0% Moisture 4.0 Total 100.0 Fine crystal precipitating agent is added after adding 〇 Concentration operation 〇 Precipitation for temperature adjustment Pulp-crushing 〇 Pulp-moisture [%] 50 55-50 50 Pulp polymerization · temperature [° C] 50 60 50 Increase in undissolved salts [%] 11.7 24.1 _ average particle size [um] 259 253 250 bulk density [g / L] 542 548 579 Granular strength [MPa] 30 36 15 Material carrying capacity [mL / g] 0.68 0.72 0.52 -92- ~ pack ---------- order ----- ---- (Please read the notes on the back first and fill in this page) t This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1239351 A7 B7 90 V. Description of the invention () Volume distribution maximum frequency path [// m] 0.81 0.48 1.63 0.01 ~ 3 microns [mL / g] 0.43 0.45 0.5 Table 12 Example 17 Example 18 Comparative Example 9 Detergent Composition Weight Parts Surfactant Supporting Particle Group 25 100 Surfactant Supporting Particle Group 26 100 Interfacial Activity Particle group for carrier 27 27 Surfactant 50 55 50 Sodium benzoate (21) (23) (21) Polyoxyethylene alkyl ether (21) (23) (21) Polyethylene glycol (4 ) (4.5) (4) (water) (4) (4.5) (4) Amorphous aluminosilicate 0 0 5 Physical property average particle diameter [micrometer] 272 274 Cannot measure bulk density [g / l] 738 743 Cannot measure Flowability [sec] 6.2 6.1 Cannot measure exudation 1 1 5 ---------- Order ---------_ (Please read the precautions on the back to fill in this page) f Economy Example 1 printed by the Ministry of Intellectual Property Bureau's Consumer Cooperatives. 9 In a mixing tank with a stirring device and a jacket, add 650 parts by weight of water. After the water temperature reaches 3 5 ° C, add 72 parts by weight of sodium carbonate. , 194 parts by weight of sodium sulfate, 40 parts by weight of a polyacrylic acid steel aqueous solution 83 parts by weight, stir: mix 30 minutes to obtain a homogeneous aqueous solution (water 70 %, The amount of "paper present scale -93- applies the Chinese national standard (CNS) A4 size (210 X 297 mm) 1239351 A7 B7 91 V. invention is described in () in the same manner as in Example 1. The spray-drying an aqueous solution. The high-temperature gas supplied to the spray drying tower is 230 from the lower part of the tower. (: The temperature is supplied, and it is discharged from the top of the tower at 95 ° C. The moisture content of the obtained particles is 5% by weight. The atomizer EIIW-7.5 type (made by Fujitadar (Company)) is used, and the sieve mesh is 0.5 mm. 1. The dry powder is pulverized under the conditions of a grinding supply of 60 kg / hour and a rotation number of 5000 rpm to obtain a fine powder with an average particle size of 5 microns (hereinafter referred to as a fine powder). In addition, it is attached to another attachment with a stirring device. Add 462 parts of water in the mixing tank to the water temperature of 3 5 C, then add 95 parts by weight of sodium sulfate, 5 parts by weight of sodium sulfite, i parts by weight of the fluorescent dye, and stir. Add sodium carbonate 123 Parts by weight, 64 parts by weight of 40% by weight sodium polyacrylate aqueous solution was added, and stirred for 10 minutes. Fine powder was added to the first preparation solution and stirred for 10 minutes. In addition, 198 parts by weight of zeolite was added and stirred for 30 minutes to obtain the second Preparation solution (water content of 50% weight /%). The final temperature of this second preparation solution is 50 ° C. After the first preparation solution is prepared and fine powder i is added, samples are taken from each of the preparation solutions and taken at TSUB-TEC. M100 measures the number of particles and particle size distribution. The solution was completely dissolved, and almost no particle number was observed. The number of particles in the second preparation solution after the addition of the fine powder was 4,009 particles / s, and the average particle diameter was 10.5 μm. In the same manner as in Example 1 The second preparation liquid was spray-dried, and the high-temperature gas supplied to the spray-drying tower was supplied from the lower part of the tower at a temperature of 220 ° C and discharged from the top of the tower at 1 ο. The moisture content of the obtained surfactant-supporting particle group 28 was 4 % By weight. The obtained surfactant-supporting particle group 28 was used in accordance with Example i-94-This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) (Please read the back Note: Please fill in this page) f Pack ---------- Order -------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1233351 Description of Invention (Same way to make detergent particles 2 8. The minimum amount of amorphous aluminosilicate which is used as the minimum amount of detergent particle group is 1. 3 parts by weight. Comparative Example 10 The same method as in Example 10 was used except that fine particles were not added to obtain the interfacial activity. Particle-supporting particle group 2 9. Using the obtained surfactant carrier Using Particle Group 2 9 in the same manner as in Example 19, Detergent Particle Group 2 9 was manufactured. Amorphous silicate was added in the same amount as in Example i 9 to 3 parts by weight, and the surfactant composition was continuously supported. Lightning drops give the inside of the mixer an agglomerated state, and the physical properties are deteriorated so that it cannot be measured. The composition and physical properties of the obtained surfactant-supporting particle groups 28, 29 are shown in Table 13, and the physical properties of the detergent particle groups 28, 29 are shown. The results are shown in Table 14. The particle group 29 for surfactant loading of Comparative Example i 〇 without the addition of water-soluble salts of microparticles, because the particle strength is weak, the maximum frequency of the pore volume distribution is also large. In the step of the agent composition, exudation of the absorbed surfactant composition can be seen by disintegration of the particles, etc., and the physical properties of the elixirs particle group are greatly deteriorated. On the one hand, the surfactant-supporting particle group 28 has the same composition and high particle strength. Since the maximum frequency diameter of the pore volume distribution is 1.5 micrometers or less, and its supporting energy is high, using this particle group can Significantly reduces amorphous aluminosilicate. &gt; Outfit—ί C Please read the phonetic on the back first? Matters Θ fill in this page) f 1111111 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-95 · This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1239351 A7 B7 93 V. Description of the invention () Printed by the Employees ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Table 13 Example 9 Comparative Example 10 Zeolite 38.0 Sodium Carbonate 26.0 Group Sodium Sulfate 24.8 Sodium Sulfite 1.0 Polypropionate Steel 6.0 Chelating Dye 0.2 Heavy Gas Sodium 0.0 Amount Brominated Steel 0.0% Moisture 4.0 Total 100.0 Precipitation slurry after fine crystal precipitation agent is added for concentration adjustment. Precipitation and crushing. Pulping-moisture [%] 50 50 Slurry-temperature [° C] 50 50 Increase in undissolved salts [%] 23.3 Average particle size [wm] 255 269 bulk density [g / L] 510 461 particle strength [MPa] 25 12 material carrying capacity [mL / g] 0.57 0.44 maximum frequency diameter of sexual pore volume distribution [// m] 0.88 1.85 0.01 ~ 3 microns [mL / g] 0.48 0.4 -96- (Please read the notes on the back first and fill in this page) Pack — — — — — — — — — This paper size is applicable to China Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1233351 A7 B7 94 V. Description of the invention () Table 14 Example 19 Comparative Example 10 Cleaning agent surfactant loading Particle group 28 100 Composition of surfactant group particles 29 100 Surfactant 50 50 Alkyl benzoic acid steel (21) (21) Heavy polyoxyethylene alkyl ether (21) (21) Amount of polyethylene Alcohol (4) (4) Parts (water) (4) (4) Number of amorphous aluminosilicates 3 8 Average particle size [micrometer] 270 Impossible to measure bulk density [g / l] 723 Impossible to measure fluidity [ Sec] 6.3 Cannot measure exudability 1 5 Example 2 0 Put 430 parts by weight of water into the mixing tank. After the water temperature reaches 3 5 ° C, add 108 parts by weight of sodium sulfate, 5 parts by weight of sodium sulfite, and 2 parts of fluorescent dye. Weight, stir for 10 minutes. 115 parts by weight of sodium carbonate was added, 150 parts by weight of a 40% by weight aqueous sodium polyacrylate solution was added, and the mixture was stirred for 10 minutes as a first preparation solution. 40 parts by weight of sodium chloride was added as a fine crystal precipitation agent, and after stirring for 10 minutes, it was crushed in a colloid mill MZ-80 at a flow rate of 800 kg / hr by wet grinding. Thereafter, 150 parts by weight of zeolite was added, and the mixture was stirred for 30 minutes to obtain a homogeneous second preparation solution (the slurry moisture content was 52% by weight). The final temperature of this preparation was 50 ° C. By adding chlorinated-97- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) I --------- Order ---------. (Please First read the notes on the back # &lt; fill in this page) f Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1233351 A7-* ------- B7 _V. Description of the invention (95) = precipitated water-soluble inorganic The amount of salt is 17.8 weight of those who were dissolved in the first preparation solution. 1 After the preparation solution, after adding 10% of sodium gasification, and after the preparation solution is crushed, samples are taken from each preparation solution, and the number of particles and particle size distribution are measured at TSUB_TEC M100. . The number of particles in the first preparation solution was 557 particles / s, and the average particle pinch (number basis) was 125 microns. The number of particles in the preparation solution after adding the steel chloride was 3798 particles / s, and the average particle diameter was 205 microns. As a result of these measurements, the number of fine crystals added by adding sodium gaseum increased by 3,241 / 8, and the average particle size of the increased fine particles ^ 4 was 17.0 micrometers. In addition, the number of particles in the second preparation solution after pulverization was 5,438 particles / s, and the average particle size was 18.2 m. The number of particles by pulverizing the water-soluble salts was further increased by 1,640 particles / s. Mouth spray drying was performed in the same manner as in Example 12 to obtain a surfactant-supporting particle group. Using the surfactant-supporting particle group 30, the following method was used to produce a detergent particle group 30. # Make the surfactant composition (polyoxyethylammonium ether / polyethylene glycol / sodium alkylbenzenesulfonate / water = 25/5/25/5 (weight ratio) to 80. (:. Second, 100 parts by weight of the surfactant-supporting particle group of a mixer (made by Matsuzaka Technological Research Co., Ltd., with a capacity of 130 liters and a jacket) will be put into the mixer, and the wing and rotation number will be one and the peripheral speed. : 1.6 m / sec). The shaft (two drops of 0 ° 0 of warm water flows into the jacket at 10 liters / minute. 60 parts by weight of the above surfactant composition is put into it in 2 minutes, followed by 5 In addition, 20 parts by weight of crystalline silicate and zeolite were charged, and a main shaft (number of rotations: 120 rpm, peripheral speed: 3.1 m / s) and a shredder (number of rotations: 3600 rpm, peripheral speed) were charged. : 28 meters / second) for 1 minute, and the cleaning agent particle group 30 is discharged. As -98- This paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) (Please read the precautions on the back first) (Write this page) f-* equipment ---------- order --------- 4 5 invention description (96 detergent particle group exudation of 1 cut stone minimum amount of 3 Weight and. Example 2 1 里The same method as in Example 20 was used to obtain the particles for supporting the surfactant. When preparing the preparation solution, 40% by weight of sodium polyacrylic acid was dissolved in water. The obtained surfactant was used to support the particles. The detergent particle group 3m was produced in the same manner as in Example 20. &amp; The particle group 31 has a very good fluidity, even if no ㈣ == degree is 1. &gt; r Health Heart Comparative Example 1 1 Except for Example W In addition to the fine crystal precipitation agent, the interfacial-agent-supporting particle group 32 was obtained in the same manner. Using the obtained surfactant-supporting particle group 32 ', a detergent particle group 32 was produced in the same manner as in Example 2G. The exudation property of the cleaning agent particle group is compared with the minimum amount of ^ as Comparative Example 12, and the composition and physical properties of the obtained surfactant-supporting particle group 30 to 33 are shown in Table 15, and the cleaning agent particle group 3 The physical properties of ~ 3 3 are shown in Table 16. From this example, the use of the technology of the present invention increases the blending amount of the polymer, and also improves the carrying capacity of the surfactant-supporting particle group: In Comparative Example η, the surfactant-supporting particle group 33 was obtained in the same manner. When the first preparation liquid was prepared, a 40% by weight aqueous sodium polyacrylate solution was added together with water. Using the obtained surfactant-supporting particle group ", the detergent particle group 33 was produced in the same manner as in Example 2G. As The minimum amount of bleaching stone of the detergent particle group 舄 1 is 13 parts by weight. • 99- This paper size applies the Chinese National Standard (CNS) A4 specification (21〇X 297 mm) 1239351

V. Description of the invention (97 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 7 greatly reduces the amount of surface modification materials. &Amp;, During the preparation of the i-th exhibition, water-soluble polymers were added earlier than sodium carbonate. The supporting energy of the surfactant-supporting particle group is improved, but the effect is small compared with the effect of improving the supporting energy by the technology of the present invention. Table 1 5 Example 20 Example 21 Comparative Example 11 Comparative Example 12 Zeolite 30.0 30.0 30.0 30.0 Sodium carbonate 23.0 23.0 27.0 27.0 Group sodium sulfate 21.6 21.6 25.6 25.6 Sodium sulfite 1.0 1.0 1.0 1.0 Polypropionate steel 12.0 12.0 12.0 12.0 Fluorescent dye 0.4 0.4 0.4 0.4 Sodium gaseous 8.0 8.0 0.0 0.0 Amount of sodium bromide 0.0 0.0 0.0 0.0% Moisture 4.0 4.0 4.0 4.0 Total 100.0 100.0 100.0 100.0 After adding the fine crystal precipitation agent, add a precipitation slurry for concentration adjustment for temperature adjustment-crushing-slurry-moisture [%] 52 52 52 52 slurry-temperature [° C] 50 50 50 50 Increase in undissolved salts [%] 17.8 18.6 Average particle size [um] 255 248 244 243 100- Use Chinese National Standard (CNS) A4 specification (210 X 297 mm) —installed --------- (Please read the precautions on the back # &lt; fill out this page) I: ^^ · 111111 1239351 A7 B7 98 V. Description of the invention () Bulk density [g / L] 536 525 503 512 grain strength [MPa] 35 35 21 23 Material carrying capacity [mL / g] 0.62 0.68 0.52 0.54 Maximum frequency of sexual pore volume distribution Diameter m] 0.72 0.68 2.20 1.80 0.01 to 3 microns [mL / g] 0.49 0.49 0.47 0.47 Table 16 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy Example 20 Example 21 Comparative Example 11 Comparative Example 12 Surfactant loading Group of particles 30 100 Group of particles for supporting surfactants 31 100 Group of particles for supporting groups 32 100 Group of particles for supporting groups 33 100 Group of surfactants 60 60 60 60 Sodium (25) (25) (25) (25) Heavy polyoxyethylammonyl ether (25) (25) (25) (25) Amount of polyethylene glycol (5) (5) (5) (5) ) Parts (water) (5) (5) (5) (5) Number of talents 3 0 15 12 Crystalline aluminosilicate 20 20 20 20 Average particle size [micron] 263 255 261 257 Bulk density [g / l] 716 725 680 694 Sexual fluidity [sec] 6 6.1 6.5 6.4 Exudability 1 1 1 1 Example 2 2 -101-f equipment -------- (Please read the back Please fill in this page before ordering) t Order ---- This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1239351 A7 B7 V. Description of invention (of), human &amp; example 1 same Method, the surfactant-containing particle group 34 was obtained. The 40% by weight aqueous solution of sodium polyacrylate was produced by the method described in the example of JP-A-2-24283. An aqueous solution of sodium propionate with a neutralization degree of 95% and a concentration of 37.7% by weight was supplied at 3 kg / hour, an aqueous solution of sodium bisulfite with a concentration of 35.5% by weight was provided at 0.13 kg / hour, and air was supplied at 3 m3 / hour. The average temperature of the jacket was 20 c &gt; c, and the weight average molecular weight was 10,000. In addition, as for the particles constituting the obtained surfactant-supporting particle group, the results of the analysis of the sunken pores were obtained, and 2 to 70% of the diameter of the particles corresponded to the diameter of the wood corresponding to the diameter of the circle. There are more than 1 submerged particles in the pores containing 91%. In addition, the ratio of "1" and "91%" (the diameter of the circle equivalent to the diameter of the hole / the diameter of the circle equivalent to the particle) of the sunk particles was 17%. In addition, the average value of the depth of the recessed hole was 55% of the equivalent circle diameter of the particle. Table 17 shows the composition and physical properties of the obtained surfactant-supporting particle group. In addition, the absorbency of the liquid active agent composition obtained by the aforementioned method showed a value of 0.45 ml / g, and the absorbent property of the liquid surfactant composition was superior. Comparative Example 1 3 In the same manner as in Comparative Example 3, the surfactant-supporting particle group 35 was also used as a 50 wt% summer-based dry benzene hindrance acid dehydrating solution, using a new formulation of thunder ... only p / evening only) 176 &quot; Chemical King (manufactured by the company), for spray-drying preparation, water-soluble salts are completely dissolved. In addition, for the particles constituting the obtained “surfactant-carrying particle group,” the analysis results of the sunken pores are shown. The equivalent diameter of the particles is 2 to 7G%, which is equivalent to the round straight 102. This paper is applicable to China Standard (CNS) A4 specification (210 X 297 mmr, ^ — — — — — — II ^ — — — — — — — (Please read the precautions on the back # | Fill this page first) 1239351 A7 B7 V. Description of the invention (A pore with a depth of 10 / ❽ or more, there are more than 1 trapped particles, which are virtually non-existent. The composition and physical property values of the obtained particle group for surfactant support are shown in Table 7F. i 7. The liquid surfactant composition obtained by the aforementioned method &lt; the absorbency is as small as 0.10 ml / g, showing that the liquid surfactant composition is poor in absorbance. For the interface activity of Example 22 and Comparative Example 13 The particle groups 3, 3, and 5 for the agent support are supported by adding the surfactants at the ratios listed in Table 8 to obtain the detergent particle groups 34 and 35. With 80 ×: relative to Polyoxyethylene alkyl ether 丨 0 parts by weight, adding polyethylene Alcohol 丨 2% by weight, equivalent to sodium palmitate 0.7% by weight of palmitic acid (Lunak (Guashi Shiv) p_95, manufactured by King Chemical (A Division)) and equivalent to sodium phthalate 12 parts by weight of benzenebenzenesulfonic acid precursor (newly equipped with Rex GS, manufactured by Kao (Company)) and NaOH water as a neutralizer; the liquid is prepared as the aqueous surfactant group described in Table i 8 For the stone object / person, put 50 parts by weight of the above-mentioned base particle group into a thunderdrop to a mixer (made by Matsuzaka Giken Co., Ltd., with a capacity of 20 liters, with a jacket). 40,000 rpin). Then, 800 c of warm water was poured into the jacket at 10 liters / minute. The above-mentioned aqueous surfactant composition was charged at 2 minutes, and then stirred at 4 minutes: after mixing 10 parts by weight of crystalline second acid salt and 10 parts by weight of zeolite were added, and a 2 minute surface covering operation was performed to obtain detergent particle groups 3 4, 3 5. In addition, by adding 2 parts by weight of zeolite and enzyme A granular detergent composition was obtained at 1% by weight of the particulate matter. The composition and physical properties of the obtained detergent composition are shown in Table 18. Compared to the interface using Example 22 The detergent composition of the active agent-carrying particle group 34 shows satisfactory physical property values. In the case where the surfactant-supporting particle group 35 of Comparative Example 13 is used, in the above operation ----, ---- ---- Equipment (please read the precautions on the back before filling this page) — I— ^ «— — — — — — I — Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives -103-

1239351 A7 B7 101 V. Description of the invention During the period of (), the surfactant composition was continuously supported to form an agglomerated state, and the physical properties were deteriorated so that it could not be measured. Table 17 Example 22 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Comparative Example 13 Zeolite 27.4 50.0 Sodium carbonate 25.6 20.0 Group sodium sulfate 21.6 10.0 Sodium sulfite 1.0 1.5 Polypropionate 13.0 9.0 Fluorescent dye 0.4 0.5 Heavy gasification Sodium 8.0 0.0 Amount Sodium Bromide 0.0 4.0% Moisture 3.0 5.0 Total 100.0 100.0 After adding a fine crystal precipitation agent, add a precipitation slurry-pulverized slurry-water [%] for concentration adjustment for temperature adjustment 53 50 slurry-temperature [° C] 50 58 Increasing amount of undissolved salts [%] 21.5. Average particle size [um] 246 225 Bulk density [g / L] 510 620 Particle strength [MPa] 40 25 104- This paper applies Chinese national standard (CNS) A4 Specifications (210 X 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 1233351 A7 B7 102 V. Description of the invention () Particle sinking rate [%] 91 0 Average sinking pore size [%] 17 average Depth of sinking hole [%] 55 Carrying capacity [mL / g] 0.60 0.52 Absorptivity [mL / g] 0.45 0.10 Maximum frequency of pore volume distribution [// m] 0.73 1.60 0.01 to 3 microns [mL / g ] 0.4 8 0.28 Table 18 Example 2 Comparative Example 13 Detergent Surfactant Supporting Particle Group 34 50 Composition of Surfactant Supporting Particle Group 35 50 Surfactant 27 27 Sodium Tiger Benzoate (12) (12) Polyoxyethenyl ether (1〇) (10) (0.7) (0.7) Polyethylene glycol (12) (1.2) Weight (water) (3.1) (3.1) The amount of 7 'is given to 12 12 parts Crystalline aluminosilicate 10 10 Number of enzyme granules 1 1 Average particle size [micrometer] 275 Undeterminable bulk density [g / l] 745 Undeterminable fluidity [sec] 6.2 Undeterminable exudation 1 -105- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

1239351 A7 ------ _B7 heart 103 ------ V. Description of the invention () Industrial application possibilities According to the present invention, the carrying capacity of the liquid surfactant composition (bearing capacity / A group of particles for supporting surfactants with excellent holding force, and a group of particles for supporting surfactants with excellent absorption characteristics (supporting speed) of the liquid surfactant and composition. In addition, by supporting the liquid surfactant composition on the surfactant-supporting particle group, it is possible to efficiently obtain a detergent particle group having good cleaning performance and quality. Obviously, the present invention described above has a majority of equivalent gardeners. Such diversity should not be regarded as deviating from the intention and scope of the present invention. All such changes understood by the industry are included in the technical scope of the following patent applications. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -106- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

Claims (1)

1239351 A8 B8 C8 D8 Patent Application No. 089114620 Chinese Patent Application Replacement (December 1992) Patent Application Scope-1--Method for preparing surfactant-containing particles, including preparation A step of preparing a solution containing a water-soluble polymer and a water-soluble salt, and a step of spray-drying the preparation solution obtained by the preparation step, and the special step is that the preparation step of the aforementioned preparation solution includes the following steps: Of the polymer or water-soluble salt solution or the first preparation solution, and the first preparation solution is processed to increase the number of water-soluble salt particles, and is prepared and exists in the first preparation solution. Of water-soluble salts: the second step of preparing a liquid when comparing the number of particles with the largest number of particles. 2. According to the method of patent application No. θ, sodium carbonate and / or sodium sulfate in water.义 # 员》 has 3. According to the method of making the first or second item of the patent scope, the water-soluble polycharacter is selected from the group consisting of homoacrylic acid homopolymer, acrylic acid-maleic acid copolymer and their sleeping More than one. Now 4. According to the manufacturing method of item 1 of the Chinese Patent Patent Park, which includes a large amount of water-soluble categories, in order to make it soluble in the first preparation liquid 5. According to the manufacturing method of item 4 of the scope of patent application, Which makes dissolved in the first Γ;:. The method for precipitating salts is to add a fine crystalline precipitation agent in the method of item 6.1 = Qing Patent No. 5 where the fine crystalline precipitation agent is a compound of alkali metals and / or alkaline earth metals. 7 '"= Method for making the fourth item of the patent scope", wherein the means for dissolving in the "night" precipitation of water-soluble salts is to concentrate the first preparation solution. 8. According to the manufacturing method of item 4 of the patent scope of Zhongli, which is dissolved in the first paper prepared for the application of the standard 12393351 AB c D, the patent application scope, and the Wang Meng dialysis reduces the amount of soluble salts / B. The temperature of the preparation liquid 1. According to the method of the patent application scope, the number of processing methods is as large as pulverizing the first salt. Rain from ^ water> capacitive salt particles 10, according to the manufacturing method of the scope of patent application No. 1, in which the increase in the number of staircases, the number is the same as the first! Microparticles of hydrazone, Γΐ salts and / or different water-soluble salts in the preparation solution are added to the i-th preparation solution under the condition that the substance = the same salt exists. W insoluble ^ 11. According to the "Membership Law of the Patent Application Scope", the number of particles in the seedlings is increased ^. Y 'Grainy salts-called number 喟 喟 treatment, in order to carry out more than 2 kinds of 4 ~ 10 The method described in the item. "% Patent application" 12. A kind of particles for supporting surfactants, which is obtained by spray-drying a preparation liquid containing water &amp; substances and water-soluble salts through 2 holes. The maximum frequency diameter of the pore volume distribution is 1.5 micrometers or less, and the pore volume of 5 (0.01 to 3.0 micrometers is 0.33 milligrams per gram of two pores 4 * 15 to 100 MPa. Apparent particle strength 乂 13 · According to the application The surfactant-supported granules of the scope of the patent No. 12 in which the content of the water-soluble polymer is 5 to 30 wt./Q. Group 14. The interface activity according to the scope of the patent application No. ^ or 丨 3 The fainting group for the carrier, which contains another insoluble substance, in this case, essentially, crystalline crystalline salt. "^ 15. According to the application of the scope of patent application No. 12 of the surface active agent carrier with display # 君, Which is prepared by containing a water-soluble polymer and water-soluble ^ f-2 Standard (CNS) A4 specification (210X297 mm) 6. Apply for a patent solution or slurry to obtain the first preparation solution, and then perform a treatment to increase the number of particles of water-soluble salts before the hardening process. Comparison of the number of particles of water-soluble salts in the first preparation liquid == obtained by the system obtained by the step of increasing the number of the second preparation liquid. &Amp; Gewugan New 16. According to the 12th scope of the patent application The surfactant-supporting treatment in which the number of particles of water-soluble salts is increased is selected from the group consisting of the following: (1) Adding a fine crystal precipitation agent to the concentrated g-th stock solution, 3) Adjust the temperature of the first preparation solution to reduce the amount of water 2: 2) The amount of the two η solution is reduced, (4) wet-grind the water-soluble salt in the first preparation solution: the heart seed, and (5) combine with the i The particles in the preparation solution = or different water-soluble salts are obtained in essence; the solution is added under the conditions of the presence of the first preparation solution. Η Insoluble 17.—Surface-active agent-carrying and water-soluble components. Operation 4 contains cut polymer = part with a hollow part, and has a particle surface opening and part:;:; The "shape (sinking hole) particles (sinking particles) are the same. ^ The group of surfactant-supporting particles of item 17 can be obtained by using the method of any one of items 1 to 11 Particle group. Jin-Ji Zai "~ 1_ gram, the production method of the detergent particle group, the obtained interface activity: J Zaizhu = Γ &quot; any one of the methods used in the production method, fruit group, or such as The scope of the patent application is the size of this paper, such as -3 10X297 mm) 1239351, the scope of patent application 1 2 8: 100 particles of surfactant-supporting particles 20: 20, as claimed, 1: active agent composition 10 to 100 parts by weight mixing step. Steps of covering agent.丨 Add another surface 21. Two! !! Γ 500 ~ 1000 g / L of cleaning agent particle group, which is relative to the application of the method of any of the scope of 1 ~ 11 in the patent application of the method-supported particle group for interfacial activity holding or as claimed in the patent scope &quot; Any of ~ 18 items-It is made of 100 parts by weight of a surfactant-containing particle group and 10 ~ 100 parts by weight of a surfactant composition. 22. Detergent particle group according to the scope of patent application No. 21, wherein a surface covering agent is additionally added. 23. A detergent composition comprising a detergent particle group as defined in item ⑴ of the patent scope. -4-This paper size applies to China National Standard (CNS) Α4 (210X 297mm)