TWI237874B - Method of forming bit-line contact - Google Patents

Method of forming bit-line contact Download PDF

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Publication number
TWI237874B
TWI237874B TW91136690A TW91136690A TWI237874B TW I237874 B TWI237874 B TW I237874B TW 91136690 A TW91136690 A TW 91136690A TW 91136690 A TW91136690 A TW 91136690A TW I237874 B TWI237874 B TW I237874B
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Taiwan
Prior art keywords
layer
bit line
forming
metal layer
patent application
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TW91136690A
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Chinese (zh)
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TW200411840A (en
Inventor
Kuo-Chien Wu
Yi-Nan Chen
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Nanya Technology Corp
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Publication of TWI237874B publication Critical patent/TWI237874B/en

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Abstract

A kind of method for forming bit line contact is provided in the present invention. At first, a semiconductor substrate is provided. On the semiconductor substrate, a transistor is provided, and the transistor has a gate and a source/drain region. Then, a dielectric layer, which has a contact-window exposing the surface of the source/drain region, is formed on the semiconductor substrate. A conductive plug is formed on the contact window, and then a metal layer is formed on the conductive plug surface. After that, an annealing process is conducted onto the metal layer to have reaction between the surfaces of the first metal layer and the conductive layer contact, so as to form a reaction layer. The first metal layer, which is not reacted, is removed; and a bit line is formed on the conductive plug that has reaction layer on its surface.

Description

1237874 五、發明說明(l) 發明所屬之技術領域 本發明係有關於一種接觸窗的形成方法,特別係有關 於一種形成位元線接觸的方法。 先前技術 近年來,在半導體電路的設計上,電容器的地位曰趨 重要,且已經成為一無可替換之電路元件。例如目前廣泛 使用電容器之動態隨機存取記憶體(DRAM : dynamic random access memory)、震蘯器(〇3(^11&1:〇1〇、時間延 遲電路(time delay circuitry)、類比/數位或數位/類比 轉換器(AD/DA converter)及許多其他應用電路。因此, 種堆 S 式電谷(STC : stacked capacitor cell)或溝槽 式電容(trenched capacitor cell)在緊密的記憶裝置中 被發展出來,其利用矽晶圓中存取裝置之上方空間或基底 下方來形成電容電極板,此種結構之優點在於具有低的軟 錯記率(SER : soft error rate),且可結合具高介電常數 (high dielectric constant)之絕緣層;同時,記憶單元 與位元線間需以接觸窗來連接。 請參考第la圖,首先,提供一半導體基底1〇1,半導 體基底101具有一週邊線路層1〇2。於半導體基底1〇ι上依 序形成一閘極介電層103、一導電層1〇4、一硬罩幕層1〇5 及一圖案化光阻層1 0 6,圖案化光阻層丨〇 6的位置即為後續 形成閘極之位置。其中,半導體基底1〇1例如是矽基底; 週邊線路層1 0 2例如是離子摻雜區;閘極介電層丨〇 3例如是 11 11237874 V. Description of the Invention (l) Field of the Invention The present invention relates to a method for forming a contact window, and more particularly to a method for forming a bit line contact. Prior art In recent years, in the design of semiconductor circuits, the status of capacitors has become increasingly important and has become an irreplaceable circuit element. For example, dynamic random access memory (DRAM: dynamic random access memory), oscillator (〇3 (^ 11 & 1: 〇1〇), time delay circuitry, analog / digital or Digital / analog converters (AD / DA converters) and many other application circuits. Therefore, stacked S-type capacitor valleys (STC) or trenched capacitor cells have been developed in compact memory devices. Out, it uses the space above the access device in the silicon wafer or the substrate to form the capacitor electrode plate. This structure has the advantage of having a low soft error rate (SER: soft error rate) and can be combined with a high dielectric An insulating layer with a high dielectric constant; at the same time, the memory cell and the bit line need to be connected by a contact window. Please refer to FIG. 1a. First, a semiconductor substrate 101 is provided, and the semiconductor substrate 101 has a peripheral circuit. Layer 102. A gate dielectric layer 103, a conductive layer 104, a hard mask layer 105, and a patterned photoresist layer 106 are sequentially formed on the semiconductor substrate 100m. Huaguang The position of the layer 丨 〇6 is the position where the gate is subsequently formed. The semiconductor substrate 101 is, for example, a silicon substrate; the peripheral circuit layer 102 is, for example, an ion-doped region; and the gate dielectric layer is, for example, 11 1

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II 0548-9072TWF(N1) ; 91145 ; Claire.ptd 第5頁 1237874 五、發明說明(2) 閘極氧化層;導電層1 0 4例如是摻雜多晶矽層或摻曰 石夕層;硬罩幕層1〇5例如是氮化石夕層,用以保護導電ϋ 不會在後續製程中被破壞。 θ 明荼考第1 b圖’接著’以圖案化光阻層i 〇 6為敍刻 幕依序非等向性蝕刻硬罩幕層105、導電層1〇4及閘極介带 層103,以在半導體基底101上形成閘極介電層丨: 層l〇4a及硬罩幕層丨05a,導電層1〇4a及硬罩幕層1〇5&即: 以作為閘極之用;然後,將圖案化光阻層丨〇6去除。其 中’非等向性蝕刻的方法為反應性離子蝕刻(Reactiv^II 0548-9072TWF (N1); 91145; Claire.ptd Page 5 1237874 V. Description of the invention (2) Gate oxide layer; conductive layer 104 is, for example, doped polycrystalline silicon layer or doped stone layer; hard mask The layer 105 is, for example, a nitride nitride layer, which is used to protect the conductive hafnium from being destroyed in subsequent processes. Figure 1b of the θ Mingtu test "continue" using the patterned photoresist layer i 〇6 as the narrative sequence to sequentially etch the hard mask layer 105, the conductive layer 104 and the gate dielectric layer 103, To form a gate dielectric layer on the semiconductor substrate 101: a layer 104a and a hard mask layer 05a, a conductive layer 104a and a hard mask layer 105, that is, to serve as a gate; and To remove the patterned photoresist layer. Among them, the method of anisotropic etching is reactive ion etching (Reactiv ^

Ion Etching,RIE)或電聚蝕刻(plasma以吡“㈧。 請參考第卜圖’於半導體基底1〇1及上述元件之表面 上順應性形成-絕緣層(未顯示),並對絕緣層進行 性蝕刻以在閘極之侧壁形成一間隙壁1〇7。直中,隙辟3 107例如是氮切層;非等向性㈣的方法例如是丄應ς 離子蝕刻(Reactive I〇n Etchlng,RIE)或電漿蝕刻〜 (plasma etching) 〇 請參考第Id圖,依序於形成有上述元件 101上形成一介電層1〇δ及一圖荦化弁ν體土底 u未化尤阻層109,圖幸仆本 阻層109具有-開nl1G,露出部分介 ⑽ 面,且開口 U0之位置即為後續形成位元 表 置。其中,介電層1 08例如是氧化声,牲θ苟固义位 氧化層。 疋爾特別是石夕酸四乙酿 請參考第1^圖’以圖案化光阻層1〇9為钱刻罩幕對介 電層2 0 8進仃非等向性蝕刻,以形成一開口丨1 ^ ,開口 mIon Etching (RIE) or electro-polymer etching (plasma to pyrene). Please refer to Figure B 'for conformal formation of the semiconductor substrate 101 and the surface of the above-mentioned components-an insulating layer (not shown), and perform an insulating layer An isotropic etching is performed to form a gap wall 107 on the side wall of the gate. In the middle, the gap 3 107 is, for example, a nitrogen-cut layer; the method of anisotropic chirping is, for example, reactive ion etching (Reactive Ion Etchlng). (RIE) or plasma etching ~ (Please refer to the Id diagram, in order to form a dielectric layer 10δ and a picture of the above-mentioned element 101 in order to form a dielectric layer) Resistive layer 109, the resist layer 109 has -open nl1G, a part of the interface is exposed, and the position of the opening U0 is the subsequent formation of the bit surface. Among them, the dielectric layer 108 is, for example, oxidized sound, and The solid oxide layer is solidified. Please refer to Fig. 1 ^, especially tetroxidonic acid, and use the patterned photoresist layer 109 as the mask to etch the dielectric layer 2 0. Etching to form an opening 丨 1 ^, opening m

〇548-9072T1VF(N1) - 91145 ; Claire.ptd 第6頁 1237874 五、發明說明(3) 即為後續會形成之位元線接 ⑽去除。其巾,非等向性:二、然後,將圖案化光阻層 u τ r 餘刻的方法例如是反應性離子 蝕刻(Reactive I〇n Etchir^, etching)。 g R 1 E )或電漿钱刻(P 1 asma 請參考第1 f圖,於形成右 -導電層(未顯示),導電居备二11之介電層108上形成 電層進行剩步驟至露;;4:;:口111。接著,對導 lilt. 既定距離;其中,導電#112 、而約為300至400〇A之 声。利用多m ΐ ΐ 是多晶石夕層或蟲晶石夕 ^ ⑴用夕日日矽層或磊晶石夕®所犯丄、 ^ t 較穩定之品質,較不會有漏^、、ώ彦t之位兀線接觸窗具有 慢。 θ ¥漏電板產生,但是傳遞速率會較 ^考弟1§圖,於介電層108之表面 光=層113,圖案化光阻層113具有—開口⑴=化 位置位於對應週邊線路層1G2之介電層㈣的表面上 在後續步驟中形成作為週邊金屬導線之 接觸窗。 曰ιυζ的 一明芩考第1 h圖,以圖案化光阻層1 1 3為蝕刻罩幕對介 電層1 08進行非等向性蝕刻,以形成露出週邊線路層1 〇2之 孔洞11 5 ;然後,將圖案化光阻層丨丨3去除。 請參考第li圖,接著,於介電層1〇8上形成_圖案化 光阻層11 6,圖案化光阻層丨丨6覆蓋於對應週邊線路區之介 電層10 8表面上,並露出對應於包含閘極等元件之記憶胞 區之介電層108之表面。〇548-9072T1VF (N1)-91145; Claire.ptd Page 6 1237874 V. Description of the invention (3) This is the removal of the bit line that will be formed later. The towel is anisotropic. Second, the patterning photoresist layer u τ r is etched, for example, reactive ion etching (Reactive Ion Etchir ^, etching). g R 1 E) or plasma money engraving (P 1 asma, please refer to Figure 1 f, forming an electrical layer on the right-conductive layer (not shown) and the conductive layer 108 of the dielectric layer 108).露 ;; 4:;: 口 111. Then, the distance to the guide lilt. A predetermined distance; among them, the conductive # 112, and the sound of about 300 to 400 〇A. The use of multi-m ΐ ΐ is a polycrystalline layer or worm crystal Shi Xi ^ ⑴Using the sun and silicon layer or epitaxial stone Xi ® made 丄, the quality is more stable, and there is no leakage ^ ,, and the contact line of the wood wire contact window has a slower. Θ ¥ 电 电 板Generated, but the transmission rate will be higher than that in the figure of §1. On the surface of the dielectric layer 108 = layer 113, the patterned photoresist layer 113 has-opening ⑴ = the position of the dielectric layer 对应 corresponding to the dielectric layer 1G2 of the peripheral circuit layer. On the surface, a contact window is formed as a peripheral metal wire in a subsequent step. Fig. 1 h of the image of ιυζ, using the patterned photoresist layer 1 1 3 as an etching mask to perform anisotropic dielectric layer 1 08 Etch to form a hole 11 5 that exposes the peripheral circuit layer 102; then, remove the patterned photoresist layer 丨 丨 3. Please refer to FIG. A patterned photoresist layer 116 is formed on the layer 108. The patterned photoresist layer 丨 6 covers the surface of the dielectric layer 108 corresponding to the peripheral circuit area, and exposes the memory cells corresponding to the elements including the gate electrode. Surface of the dielectric layer 108 of the region.

〇548-9072TWF(Nl) ; 91145 ; Claire.ptd〇548-9072TWF (Nl); 91145; Claire.ptd

、月ί考第1 j圖’接著’以圖案化光阻層1 1 6為|虫刻罩 幕’對露出表面之對應於包含閘極等元件之記憶包區之介 五、發明說明(4) 電$ 108進行非等向性蝕刻至形成一具有1 0 0 0至40 0 0 A之 既定殊度之凹槽;其中,具有既定深度之凹槽即為後續形 成4元線之位置。然後’利用化學氣相沉積法(c h e m i c a 1 vapor dep0Sitl0n,CVD)於半導體基底1〇i及孔洞115之表 面上順應性形成一厚度相當薄之阻障層1 1 7,並對阻障層 1 1 7進行回火程序。其中,阻障層丨1 7例如是氮化鈦(τ丨n ) 層。 请茶考第lk圖,於介電層1〇8之表面上形成一鎢金屬 層(未^不)’鎢(W)金屬層會填滿凹槽及孔洞1 1 5 ;然後, 對鎢金屬層進行回蝕刻步驟至露出介電層丨〇8之表面為 111 =此^來,僅剩下凹槽及孔洞11 5中之鎢金屬層11 8a 即為位元Ϊ且形成阻障層117a;位於凹槽之鎢金屬層118a 兀線,西位於孔洞115之鎢金屬 8b 導線之接觸窗。 门n & m 錄且Ξ ί鎢金屬層之阻值低’所以使用鎢金屬層作為之導 的需长父ί傳遞速率’符合週邊線路需要較快傳遞速率 鶴金屬層的過^呈電層108之上’因此在形成 @夕& I, 會有氟離子進入多晶矽層而使多曰矽 層之結構出現孔隙119,如第}1圖所示。 使…夕 發明内容Figure 1j of the monthly test “Next” with the patterned photoresist layer 1 1 6 as the worm mask ”on the exposed surface corresponding to the memory package area containing the gate and other components V. Description of the invention (4 ) Electrically anisotropically etched at $ 108 to form a groove having a predetermined degree of 100 to 400 A; wherein a groove having a predetermined depth is a position for subsequent formation of a quaternary line. Then, a chemical vapor deposition method (chemica 1 vapor dep0Sitl0n, CVD) is used to conform to the surface of the semiconductor substrate 10i and the hole 115 to form a relatively thin barrier layer 1 1 7, and the barrier layer 1 1 7 Perform the tempering procedure. The barrier layer 17 is, for example, a titanium nitride (τ 丨 n) layer. Please refer to the lk chart of the tea. A tungsten metal layer (not ^ not) is formed on the surface of the dielectric layer 108. The tungsten (W) metal layer will fill the grooves and holes 1 1 5; The layer is subjected to an etch-back step until the surface of the dielectric layer 丨 〇8 is 111 = this ^, and only the tungsten metal layer 11 8a in the grooves and holes 115 is the bit Ϊ and a barrier layer 117a is formed; The contact line of the tungsten metal layer 118a in the groove and the tungsten metal 8b wire in the hole 115 west. The gate n & m records that the resistance value of the tungsten metal layer is low, so the long-term transmission rate is required to use the tungsten metal layer as a guide, which is in line with the peripheral circuit that requires a faster transmission rate. Above 108 ', therefore, at the formation of @ 夕 & I, there will be fluorine ions entering the polycrystalline silicon layer and the pores of the structure of the silicon layer will have pores 119, as shown in Figure 1). To make

0548-9072TWF(Nl); 91145; Claire.ptd 第8頁 1237874 五、發明說明(5) 有龜於此’本發明 觸的方法,主要是藉由多晶矽方、、提供一種形成位兀緩趣 層所共同組成之位元線接 ^ f化鈦金屬層及鈦金屬 並保有穩定之品質。妾觸® ^化加記憶胞區之傳遞迷率 根據上述目的,本發 法包括下列步驟:提;1 = ”位元線接觸的方 有一電晶體,電晶體罝右一问、土氐半^體基底上具 基底上形成-介電層,;=—::及極區,·於半導體 屬層與導電層接觸 f至屬層進仃回火步驟以在第一金 之第一金屬層去除;^面反應形成一反應層,並將未反應 成一位元線。 於表面具有反應層之導電插塞上形 根據上述目白勺 方法,包括下列步靜本^月再提供—種形成位元線接觸的 有一週邊線路層,^车^供一半導體基底,半導體基底具 體具有一閘極及〜 v體基底上形成有—電晶體,電晶 層,介電層具有〜汲極區;於半導體基底上形成—介電 面,且第-開口即::開口,第一開口露出源沒極區之表 口依序形成-多曰曰:後績形成之位元線接觸窗;於第一開 行-回火步驟,以ff —第一金屬層;對第-金屬層進 形成一石夕化金屬;I . f I屬層貞多晶石夕層接觸之表面上 形成-第二開口 ^除未反應之第—金屬層;於介電層 觸窗;於介電層上#丄 、仏成之週邊線路層接 %成-圖案化光阻層,圖案化光阻層覆0548-9072TWF (Nl); 91145; Claire.ptd Page 8 1237874 V. Description of the invention (5) There is a turtle here. The method of the present invention is mainly by using polycrystalline silicon to provide a bit of fun The combined bit line is connected to the titanium metal layer and the titanium metal and maintains stable quality.妾 Touch® 化 Transfer rate of memory plus memory cell area According to the above purpose, this method includes the following steps: mention; 1 = ”the bit line is in contact with a transistor, the transistor is right, the soil is half a ^ A -dielectric layer is formed on the substrate on the body substrate; =-:: and the polar region, the semiconductor metal layer is in contact with the conductive layer f to the metal layer, and then a tempering step is performed to remove the first metal layer of the first gold ^ Plane reaction to form a reaction layer, and will not react into a bit line. Forming a conductive plug with a reaction layer on the surface According to the above method, including the following steps, this month and then provide a kind of bit line There is a peripheral circuit layer in contact with the semiconductor substrate. The semiconductor substrate has a gate and a bulk body. A transistor, a transistor layer, and a dielectric layer have a drain region. The semiconductor substrate is formed on the semiconductor substrate. On the formation-the dielectric surface, and the first opening is: the opening, the first opening exposing the surface of the source electrode region is formed in sequence-more said: the bit line contact window formed after the performance; -Tempering step with ff-first metal layer; shape the first-metal layer A petrified metal; I. f I is a layer formed on the contact surface of the polycrystalline polycrystalline layer-the second opening ^ except for the unreacted first-the metal layer; touch the window on the dielectric layer; on the dielectric layer # 丄And the surrounding circuit layers are connected to each other-patterned photoresist layer, patterned photoresist layer

0548-9072TWF(Nl) ; 91145 ; Claire.ptd0548-9072TWF (Nl); 91145; Claire.ptd

B 第9頁 1237874 五、發明說明(6) 蓋住週邊線路層接觸窗;以圖案化光阻層為蝕刻罩幕,蝕 刻介電層至一既定深度,並去除圖案化光阻層;於半導體 基底、矽化金屬層及週邊金屬接觸窗之表面上順應性形成 一阻障層;於阻障層上形成一第二金屬層,且第二金屬層 填滿週邊金屬接觸窗及第一開口;及平坦化第二金屬層, 直至露出介電層表面為止。 根據上述目的,本發明更提供一種形成位元線接觸的 方法,包括下列步驟:提供一半導體基底,半導體基底具 有一週邊線路層,且半導體基底上形成有一電晶體,電晶 體具有一閘極及一源汲極區;於半導體基底上依序形成一 介電層及一第一圖案化光阻層,第一圖案化光阻層具有一 第一開口,第一開口之位置為後續形成位元線接觸窗之位 置;以第一圖案化光阻層為蝕刻罩幕,對介電層進行非等 向性蝕刻步驟以形成一第二開口 ,第二開口露出源汲極區 之表面,且第二開口即為後續形成之位元線接觸窗;去除 第一圖案化光阻層;於半導體基底上形成一多晶矽層,且 多晶矽層填滿第二開口;對多晶矽層進行回蝕刻步驟至露 出介電層之表面,且第二開口之多晶矽層具有一第一既定 深度;於介電層及多晶矽層之表面上順應性形成一鈦金屬 層;對鈦金屬層進行一回火步驟,以在鈦金屬層與多晶石夕 層接觸之表面上形成一矽化鈦金屬層;去除未反應之鈦金 屬層,留下多晶石夕層表面之石夕化鈦金屬層;於介電層上形 成一第二圖案化光阻層,第二圖案化光阻層具有一第三開 口,第三開口之位置為後續形成週邊線路層之接觸窗之位B Page 9 12378874 V. Description of the invention (6) Covering the contact windows of the peripheral circuit layer; using the patterned photoresist layer as an etching mask, etching the dielectric layer to a predetermined depth, and removing the patterned photoresist layer; A barrier layer is conformably formed on the surface of the substrate, the silicided metal layer, and the surrounding metal contact window; a second metal layer is formed on the barrier layer, and the second metal layer fills the surrounding metal contact window and the first opening; and The second metal layer is planarized until the surface of the dielectric layer is exposed. According to the above object, the present invention further provides a method for forming a bit line contact, including the following steps: providing a semiconductor substrate, the semiconductor substrate having a peripheral circuit layer, and a transistor formed on the semiconductor substrate, the transistor having a gate and A source drain region; a dielectric layer and a first patterned photoresist layer are sequentially formed on a semiconductor substrate, the first patterned photoresist layer has a first opening, and a position of the first opening is a subsequent formation bit The position of the line contact window; using the first patterned photoresist layer as an etching mask, performing an anisotropic etching step on the dielectric layer to form a second opening, the second opening exposing the surface of the source drain region, and the first The two openings are subsequent bit line contact windows; the first patterned photoresist layer is removed; a polycrystalline silicon layer is formed on the semiconductor substrate, and the polycrystalline silicon layer fills the second opening; the polycrystalline silicon layer is etched back to the exposed substrate The surface of the electrical layer, and the polycrystalline silicon layer with the second opening has a first predetermined depth; a titanium metal layer is conformably formed on the surfaces of the dielectric layer and the polycrystalline silicon layer; The layer is subjected to a tempering step to form a titanium silicide layer on the surface where the titanium metal layer is in contact with the polycrystalline silicon layer; the unreacted titanium metal layer is removed, leaving titanium polysilicon on the surface of the polycrystalline silicon layer A metal layer; a second patterned photoresist layer is formed on the dielectric layer, the second patterned photoresist layer has a third opening, and the position of the third opening is the position of the contact window for the subsequent formation of the peripheral circuit layer

0548-9072TWF(N1) ; 91145 ; Claire.ptd 第10頁 案化光 邊線路 成一第 路層接 層至一 基底、 成一阻 滿週邊 露出介 明之上 特舉一 阻層為钱刻 層接觸窗; 二圖案化光 觸窗;以第 第二既定深 石夕化鈦金屬 障層;於阻 金屬接觸窗 電層表面為 述和其他目 較佳實施例0548-9072TWF (N1); 91145; Claire.ptd p.10 The light edge circuit is converted into a first layer to a substrate, and a barrier layer is filled on the periphery to expose the surface. A resistive layer is a engraved layer contact window; Two patterned light touch windows; the second predetermined deep stone titaniumized metal barrier layer; the surface of the electrical barrier layer of the metal contact window is described and other preferred embodiments

罩幕,非 去除第二 阻層,第 三圖案化 度;去除 層及週邊 障層上形 及第二開 止。 的、特徵 ,並配合 1237874 ------ 五 '發明說明(7) 置;以第二圖 層以形成一週 於介電層上形 覆蓋住週邊線 幕’钱刻介電 層;於半導體 面上順應性形 且鶴金屬層填 金屬層,直至 為使本發 顯易懂,下文 細說明如下: 等向性蝕刻介電 圖案化光阻層; 二圖案化光阻層 光阻層為蝕刻罩 第三圖案化光阻 金屬接觸窗之表 成一鎢金屬層, 口;及平坦化鎢 、和優點能更明 所附圖式,作詳 實施方式: 元線圖’第2a—21圖係顯示本發明之形成位 兀線接觸的方法之示意圖。 〜取1π 請參考第2a圖,首先,拇^ 體基底m具有-週邊二ϋ —+導體基㈣1 ’半導 序形成-閘極介電層m、—導電層2Q4、—硬 及一圖案化光阻層2 0 6,圖宰化来卩且μ ^ηβ & & φ 曰 ,、T 牛^體基底2 0 1例如是矽美麻· 如是離子摻雜區;閘極介電層2〇“如是 電層204例如是摻雜多晶石夕層或摻… 夕層,硬罩幕層2G5例如是氮切層,用以保護導電層—Mask, non-removing the second barrier layer, the third patterning degree; removing the layer and the surrounding barrier layer and forming the second stop. And features, and cooperate with 1237874 ------ Five 'invention description (7); use a second layer to form a circle on the dielectric layer to cover the surrounding wire curtain' money engraved dielectric layer; on the semiconductor surface The conformable shape is filled with a metal layer of the crane metal layer until the present invention is easy to understand, the following is explained in detail as follows: isotropic etching dielectric patterned photoresist layer; two patterned photoresist layer photoresist layer is an etching cover The surface of the third patterned photoresistive metal contact window is made of a tungsten metal layer, a mouth; and flattened tungsten, and the advantages can be more clearly shown in the drawings, for detailed implementation: Figure 2a-21 of the element line diagram Schematic diagram of the invention's method of forming a wire contact. ~ Take 1π Please refer to Figure 2a. First, the body substrate m has -peripheral ϋ-+ conductor base ㈣1 'semiconductor sequence formation-gate dielectric layer m,-conductive layer 2Q4,-hard and a patterning The photoresist layer 2 0 6 is shown in FIG. 2 and μ ^ η β & & φ, the T ^ body substrate 2 0 1 is, for example, sisami. If it is an ion-doped region, the gate dielectric layer 2 2 "If the electrical layer 204 is, for example, a doped polycrystalline layer or a doped layer, the hard mask layer 2G5 is, for example, a nitrogen-cut layer to protect the conductive layer—

1237874 五、發明說明(8) ' 不會在後續製程中被破壞。 請參考第2 b圖,接著,以圖案化光阻層2 〇 6為蝕刻罩 幕依序非等向性蝕刻硬罩幕層2 〇 5、導電層2 0 4及閘極介電 層203 ’以在半導體基底201上形成閘極介電層203a、導電 層2 0 4a及硬罩幕層2〇5a,導電層2 0 4a及硬罩幕層2 0 5a即用 以作為閘極之用;然後,將圖案化光阻層2 q 6去除。其 中,非等向性飯刻的方法為反應性離子蝕刻(Reactive Ion EtcMng,RIE)或電聚蝕刻(Plasma etching)。 請參考第2c圖,於半導體基底2〇1及上述元件之表面 上順應性形成-絕緣層(未顯示),並對絕緣層進行非等向 性蝕刻以在閘極之側壁形成一間隙壁2〇7。其中,間 2 0 7例如是氮化矽層;非等向抖蝕 土 M . . ,lirp + . τ井寺向14蝕刻的方法例如是反應性 每隹子餘刻(Reactive Ion Ei~phinrr ητ^、 ,, ,, Mehlng,HE)或電漿蝕刻 (plasma etching)。 请參考弟2d圖,依序於开彡#古 一 2〇1上形成-介電層m及二圖==件之半導體基底 阻層2 0 9具有一開口 2 1 0,開口 ? 曰2 0 9,圖案化光 面,且開口210之位置即為德婷2出°卩分介電層208之表 置。其中,介電層2 0 8例如e气 凡線接觸®之位 氧化層。 疋乳化層,特別是矽酸四乙酯 為飯刻罩幕對介 口211 ,開口211 將圖案化光阻層 如是反應性離子 洧爹亏乐ze圑,以圖案 以形 電層20 8進行非等向性蝕刻,; 即為後續會形成之位元線接觸胃 2 0 9去除。其中,非等向性蝕刻白(1237874 V. Description of Invention (8) 'Will not be destroyed in subsequent processes. Please refer to FIG. 2b, and then, using the patterned photoresist layer 2 0 6 as the etching mask, the hard mask 2 5, the conductive layer 204, and the gate dielectric layer 203 are sequentially anisotropically etched. The gate dielectric layer 203a, the conductive layer 204a, and the hard mask layer 205a are formed on the semiconductor substrate 201, and the conductive layer 204a and the hard mask layer 205a are used as gates; Then, the patterned photoresist layer 2 q 6 is removed. Among them, the method of anisotropic rice etching is Reactive Ion EtcMng (RIE) or Plasma etching. Please refer to FIG. 2c, conformally forming an insulating layer (not shown) on the surface of the semiconductor substrate 201 and the above-mentioned components, and anisotropically etch the insulating layer to form a gap 2 on the side wall of the gate 〇7. Among them, the interval 207 is, for example, a silicon nitride layer; the non-isotropic tremor etched soil M.., Lirp +. Τ Jingsi direction 14 is etched, for example, by reactive reactive ions (Reactive Ion Ei ~ phinrr ητ ^ , ,, ,, Mehlng (HE) or plasma etching. Please refer to the figure 2d, and sequentially form a dielectric layer m and a two-layer semiconductor substrate on the opening 彡 # 古 一 〇2. The resist layer 2 0 9 has an opening 2 1 0, opening? That is, 2 0, a smooth surface is patterned, and the position of the opening 210 is the position of the dielectric layer 208 of Deting 2 °. Among them, the dielectric layer 208 is an in-situ oxide layer such as e-Gas Line Contact®.疋 Emulsified layer, especially tetraethyl silicate is the interface 211 of the mask cover. The opening 211 will be a patterned photoresist layer such as reactive ions. Isotropic etching, that is, the subsequent formation of bit line contact with the stomach 209 is removed. Among them, anisotropic etching white (

1237874 五、發明說明(9) ' -- 蝕刻(ReacUve Ion Etchlng,RIE)或電漿蝕刻(piasma etching) ° 、口月蒼考S 2 f圖’於形成有開口 2 i丄之介電層2 Q 8上形成 一導電層(未顯不),導電層會填滿開口 2丨】。接著,對導 電層進订回蝕刻步驟至露出介電層2〇8的表面為止,並且 開口 2 1 1中之$電層2 1 2會距離開口 2 i }頂端一既定距離, ,為3 0 0至40 0 0 A。其中,導電層212例如*多晶石夕層或蟲 曰曰矽^ L利用多晶矽層或磊晶矽層所形成之位元線接觸窗 具有較穩定之品質,較不會有漏電流產生,但是傳遞速率 會較慢。 請參考第2",於介電層2〇8及導電層212之表面上順 心陡心成鈦(T 1)金屬層2 1 3,並在攝氏5 0 0至8 0 0度之溫、 ^ L對鈦金屬層213進行回火步驟,以在鈦金屬層213與導 “曰2接觸之表面上形成一矽化鈦(TiSi )金屬層213a, 片〇 也俊、、、貝之步驟中保護導電層2 1 2不被 氟荨氣體侵I虫。然後,將去& Λ ' 时未反應之鈦金屬層2 1 3去除,如 第2h圖所示。 δ青餐考弟2 i圖,於介雪恩U .^ , , L ^ 電層2 0 8及矽化鈦金屬層21 3a之 1面上形成一圖木化光阻層214 ,圖案化光阻層214具有一 開口 21 5,開口 21 5的位罢a 士人此广 . ’ 置位於對應週邊線路層2 0 2之介電 層208的表面上,用以λ你錶电 在後 ',、貝步驟中幵> 成作為週邊金屬導 線之週邊線路層2 0 2的接觸窗。 々n 蜀等 請參考第2 j圖,以圖宏於亦 雷# I A & 案光層214為蝕刻罩幕對介 曰 仃 ' 蝕刻,以形成週邊線路層2 0 2之孔洞1237874 V. Description of the invention (9) '-Etchlng (ReacUve Ion Etchlng, RIE) or plasma etching (Piasma Etching) °, Shuangfangkou S 2 f picture' on the dielectric layer 2 with the opening 2 i 丄A conductive layer (not shown) is formed on Q 8 and the conductive layer will fill the opening 2 丨]. Next, the conductive layer is etched back until the surface of the dielectric layer 208 is exposed, and the $ electrical layer 2 1 2 in the opening 2 1 1 is a predetermined distance from the top of the opening 2 i, which is 3 0 0 to 40 0 0 A. Among them, the conductive layer 212, such as a polycrystalline silicon layer or a silicon layer, is a bit line contact window formed by using a polycrystalline silicon layer or an epitaxial silicon layer, which has relatively stable quality, and has no leakage current, but The transfer rate will be slower. Please refer to No. 2 ", on the surface of the dielectric layer 208 and the conductive layer 212, a titanium (T 1) metal layer 2 1 3 is formed concentrically and at a temperature of 500 to 800 ° C, ^ Tempering the titanium metal layer 213 to form a titanium silicide (TiSi) metal layer 213a on the surface of the titanium metal layer 213 that is in contact with the conductor 2 to protect the conduction during the step The layer 2 1 2 is not invaded by the fluorine gas. Then, the unreacted titanium metal layer 2 1 3 when removing & Λ 'is removed, as shown in Fig. 2h. Jie Xueen U. ^,, L ^ Electrical layer 208 and titanium silicide layer 21 3a are formed on one side of a photo-wooden photoresist layer 214, and the patterned photoresist layer 214 has an opening 21 5 and an opening 21 5th place. The scholars are widely used. 'It is located on the surface of the dielectric layer 208 corresponding to the peripheral circuit layer 2 0 2 to be used as a peripheral metal.' The contact window of the peripheral circuit layer 2 0 2 of the wire. Please refer to Figure 2j for details such as Hong Yuyi Lei # IA & Case light layer 214 is used as an etching mask for etching. Peripheral lines Hole 202 of the

0548-9072TWF(Nl) ; 91145 i Claire.ptd 第13頁 1237874 五、發明說明(10) 一 " --Γ 2 1 6,然後,將圖案化光阻層2丨4去除。接著,於介電層 208上形成一圖案化光阻層217,圖案化光阻層217覆蓋於 對應週邊線路區之介電層2〇8表面上,並露出對應於包含 閘極等元件之記憶包區之介電層2〇8之表面。 明參考第2 k圖’接著,以圖案化光阻層2 1 7為钱刻罩 幕’對露出表面之對應於包含閘極等元件之記憶包區之介 電層2 0 8進行非等向性蝕刻至形成一具有} 〇 〇 〇至4 〇 〇 〇 a之 既定深度之凹槽;其中,具有既定深度之凹槽即為後續形 成位元線之位置。然後,利用化學氣相沉積法(chemical vapor deposit ion,CVD)於半導體基底201、矽化鈦金屬 層2 1 3a及孔洞2 1 6之表面上順應性形成一厚度相當薄之阻 障層218,並對阻障層218進行回火程序。其中,阻障層 2 1 8例如是氮化鈦(T i N )層。 曰 請參考第21圖,於介電層208之表面上形成一鎢金屬 層(未顯示)’鎢(W)金屬層會填滿凹槽及孔洞2 1 6 ;然後, 對鎢金屬層進行回蝕刻步驟至露出介電層2 〇 8之表面為 止,如此一來,僅剩下凹槽及孔洞2丨6中之鎢金屬層2 1 9 a 及219b,並且形成阻障層218& ;位於凹槽之鎢金屬層〖lb 即為位元線,而位於孔洞216之鎢金屬層219b為週 導線之接觸窗。 w 因為鎢金屬層之阻值低,所以使用鎢金屬層作為之 線具有較佳之傳遞速率,符合週邊線路需要較快傳遞速 的需求,然而,因為鎢金屬層219a、219b主要是以i化被 (WF6)作為反應氣體來沉積於介電層2〇8之上,因此在形成0548-9072TWF (Nl); 91145 i Claire.ptd page 13 1237874 V. Description of the invention (10) A " --Γ 2 1 6 Then, the patterned photoresist layer 2 丨 4 is removed. Next, a patterned photoresist layer 217 is formed on the dielectric layer 208. The patterned photoresist layer 217 covers the surface of the dielectric layer 208 corresponding to the peripheral circuit area, and exposes the memory corresponding to the components including the gate electrode and the like. The surface of the dielectric layer 208 of the cladding region. Referring to Figure 2k, 'the next step is to use a patterned photoresist layer 2 1 7 as a engraved mask' to perform an anisotropy on the exposed surface of the dielectric layer 2 0 corresponding to the memory envelope containing the gate and other components. The etching is performed to form a groove having a predetermined depth of 0.001 to 4,000a; wherein a groove having a predetermined depth is a position where a bit line is subsequently formed. Then, a chemical vapor deposition (CVD) method is used to conformally form a relatively thin barrier layer 218 on the surface of the semiconductor substrate 201, the titanium silicide layer 2 1 3a, and the hole 2 1 6, and The barrier layer 218 is subjected to a tempering procedure. The barrier layer 2 1 8 is, for example, a titanium nitride (T i N) layer. Please refer to FIG. 21, a tungsten metal layer (not shown) is formed on the surface of the dielectric layer 208. The tungsten (W) metal layer will fill the grooves and holes 2 1 6; then, the tungsten metal layer is returned. The etching step is until the surface of the dielectric layer 208 is exposed. In this way, only the tungsten metal layers 2 1 9 a and 219 b in the grooves and holes 2 丨 6 are left, and a barrier layer 218 & The tungsten metal layer [lb] of the groove is a bit line, and the tungsten metal layer 219b located in the hole 216 is a contact window of the peripheral wire. w Because the tungsten metal layer has a low resistance value, using the tungsten metal layer as the wire has a better transmission rate, which meets the needs of peripheral circuits for faster transmission speeds. However, because the tungsten metal layers 219a and 219b are mainly made of silicon (WF6) is deposited on the dielectric layer 208 as a reactive gas.

0548-9072TWF(N1) ; 91145 ; Claire.ptd 第14頁 1237874 五、發明說明(11) —--0548-9072TWF (N1); 91145; Claire.ptd page 14 1237874 V. Description of invention (11) ---

鶴金屬層的過程中常會有氟離子進入多晶矽層而使多晶矽 層之結構出現孔隙。本發明於gI 間形成之矽化鈦金屬層2 i 3 a可有效阻鎢全:二 之位元線接觸窗中,避免位元;晶摩形= 時,…金屬層2⑽具;= f構被破壞;同 鶴金屬層219a與導請12之广/界:間阻值之用處,使 由導電層212 1化鈦B金屬層= 低,同時可藉 而成之位元線接觸窗爽福斗捕fa及鎢金屬層21 9a所組合 之穩定的品質。 ’ ^速率並保有位元線接觸窗 雖然本發明p — 限定本發明,任何熟::::揭::土 :然;並非用以 視後附之申請專利;者:;本發明之保護“:In the process of the crane metal layer, fluorine ions often enter the polycrystalline silicon layer and cause the structure of the polycrystalline silicon layer to show pores. The titanium silicide metal layer 2 i 3 a formed between gI according to the present invention can effectively block all tungsten: two bit line contact windows to avoid bits; crystal friction shape = , ... metal layer 2 harness; = f structure Destruction; the wide / boundary of Tonghe metal layer 219a and guide 12: the usefulness of the inter-resistance value, so that the conductive layer 212, titanium B metal layer = low, and the bit line contact window that can be borrowed at the same time is a blessing. Stable quality combined with fa and tungsten metal layer 21 9a. '^ Rate and retain the bit line contact window Although the present invention p-defines the invention, any familiar ::::::: soil: Ran; not for the purpose of seeing the attached patent; or :; protection of the invention " :

0548-9072TWF(N1) ; 91145 ; Claire •Ptd 第15頁 1237874 圖式簡早說明 第1 a- 1 1圖係顯示習知之形成位元線接觸的方法之示 意圖。 第2 a — 2 1圖係顯示本發明之形成位元線接觸白勺方法之 示意圖。 符號說明: 1 0 1、2 01〜半導體基底; 1 0 2、2 0 2〜週邊線路層; 1 0 3、1 0 3 a、2 0 3、2 0 3 a〜閘極介電層; 104 、 104a、 112 、 204 、 204a 、 212〜導電層; 105、105a、2 0 5、2 0 5a〜硬罩幕層; 1 0 6、1 0 9、11 3、1 1 6〜圖案化光阻層; 1 0 7、2 0 7〜間隙壁; 108、2 08〜介電層; 110 、 111 、 114 、 115〜開口; 117、117a、218、218a〜阻障層; 118a、118b、219a、219b 〜鎢金屬層; 1 1 9〜孔隙; 206、209、214、217〜圖案化光阻層; 2 1 0、2 11、2 1 5、2 1 6 〜開口; 213〜鈦金屬層; 2 1 3 a〜石夕化鈦金屬層。0548-9072TWF (N1); 91145; Claire • Ptd Page 15 1237874 Brief description of the drawings Page 1 a-1 1 1 shows the conventional method of forming the bit line contact. Figures 2a to 21 are schematic views showing the method for forming a bit line contact according to the present invention. Explanation of symbols: 1 0 1, 2 01 ~ semiconductor substrate; 1 0 2, 2 0 2 ~ peripheral circuit layer; 1 0 3, 1 0 3 a, 2 0 3, 2 0 3 a ~ gate dielectric layer; 104 , 104a, 112, 204, 204a, 212 ~ conductive layer; 105, 105a, 2 0 5, 2 5a ~ hard cover curtain layer; 1 06, 1 0 9, 11 3, 1 1 6 ~ patterned photoresist Layers; 1 07, 2 07 ~ spacer wall; 108, 2 08 ~ dielectric layer; 110, 111, 114, 115 ~ opening; 117, 117a, 218, 218a ~ barrier layer; 118a, 118b, 219a, 219b ~ tungsten metal layer; 1 1 9 ~ porosity; 206, 209, 214, 217 ~ patterned photoresist layer; 2 1 0, 2 11, 2 1 5, 2 1 6 ~ openings; 213 ~ titanium metal layer; 2 1 3 a ~ Shi Xihua titanium metal layer.

0548-9072TWF(Nl) ; 91145 ; Claire.ptd 第16頁0548-9072TWF (Nl); 91145; Claire.ptd page 16

Claims (1)

1237874 六、申請專利範圍 1 · 一種形成位元線接觸的方法,包括下列步驟: 提供一半導體基底,該半導體基底上具有一電晶體, 該電晶體具有一閘極及一源沒極區; 於該半導體基底上形成一介電層,該介電層具有一接 觸窗,該接觸窗露出該源汲極區表面; 依序於該接觸窗形成一導電插塞; 於該導電插塞表面形成一金屬層; 對該金屬層進行回火步驟以在該第一金屬層與該導電 層接觸之表面反應形成一反應層,並將未反應之該第一金 屬層去除;及 於表面具有該反應層之該導電插塞上形成一位元線。 2. 如申請專利範圍第1項所述之形成位元線接觸的方 法,其中該介電層為氧化層。 3. 如申請專利範圍第2項所述之形成位元線接觸的方 法,其中該氧化層為矽酸四乙酯氧化層。 4. 如申請專利範圍第1項所述之形成位元線接觸的方 法,其中該導電插塞為多晶矽層或磊晶矽層。 5. 如申請專利範圍第1項所述之形成位元線接觸的方 法,其中該金屬層為鈦金屬層。 6. 如申請專利範圍第1項所述之形成位元線接觸的方 法,其中該反應層為石夕化鈦金屬層。 7. 如申請專利範圍第1項所述之形成位元線接觸的方 法,其中該位元線為鎢金屬層。 8. —種形成位元線接觸的方法,包括下列步驟:1237874 VI. Application Patent Scope 1. A method for forming a bit line contact, including the following steps: providing a semiconductor substrate having a transistor on the semiconductor substrate, the transistor having a gate and a source / anion region; A dielectric layer is formed on the semiconductor substrate, and the dielectric layer has a contact window, which exposes the surface of the source-drain region; a conductive plug is sequentially formed on the contact window; and a conductive plug is formed on the conductive plug surface. A metal layer; performing a tempering step on the metal layer to form a reaction layer on a surface where the first metal layer is in contact with the conductive layer, and removing the unreacted first metal layer; and having the reaction layer on the surface A bit line is formed on the conductive plug. 2. The method for forming a bit line contact as described in item 1 of the patent application scope, wherein the dielectric layer is an oxide layer. 3. The method for forming a bit line contact as described in item 2 of the patent application scope, wherein the oxide layer is a tetraethyl silicate oxide layer. 4. The method for forming a bit line contact as described in item 1 of the patent application scope, wherein the conductive plug is a polycrystalline silicon layer or an epitaxial silicon layer. 5. The method for forming a bit line contact as described in item 1 of the patent application scope, wherein the metal layer is a titanium metal layer. 6. The method for forming a bit line contact as described in item 1 of the scope of patent application, wherein the reaction layer is a titanium metal layer. 7. The method of forming a bit line contact as described in item 1 of the scope of the patent application, wherein the bit line is a tungsten metal layer. 8. A method of forming bit line contacts, including the following steps: 0548-9072TWF(Nl) ; 91145 ; Claire.ptd 第17頁 1237874 六、申請專利範圍 提供一半導體基底’該半導體基底具有一週邊線路 層,且該半導體基底上形成有一電晶體,該電晶體具有一 閘極及一源汲極區; 於該半導體基底上形成一介電層,該介電層具有一第 一開口 ,該第一開口露出該源汲極區之表面,且該第一開 口即為後續形成之該位元線接觸窗; 於該第一開口依序形成一多晶矽層及一第一金屬層; 對該第一金屬層進行一回火步驟,以在第一金屬層與 該多晶石夕層接觸之表面上形成一石夕化金屬層; 去除未反應之該第一金屬層; 於該介電層形成一第二開口 ,該第二開口即為後續形 成之週邊線路層接觸窗; 於該介電層上形成一圖案化光阻層,該圖案化光阻層 覆蓋住該週邊線路層接觸窗; 以該圖案化光阻層為#刻罩幕,#刻該介電層至一既 定深度,並去除該圖案化光阻層; 於該半導體基底、該矽化金屬層及該週邊金屬接觸窗 之表面上順應性形成一阻障層; 於該阻障層上形成一第二金屬層,且該第二金屬層填 滿該週邊金屬接觸窗及該第一開口;及 平坦化該第二金屬層,直至露出該介電層表面為止。 9.如申請專利範圍第8項所述之形成位元線接觸的方 法,其中該週邊線路層為離子摻雜區。 1 0.如申請專利範圍第8項所述之形成位元線接觸的方0548-9072TWF (Nl); 91145; Claire.ptd Page 17 1237874 6. The scope of the patent application provides a semiconductor substrate 'the semiconductor substrate has a peripheral circuit layer, and a transistor is formed on the semiconductor substrate, and the transistor has a A gate and a source drain region; forming a dielectric layer on the semiconductor substrate, the dielectric layer having a first opening, the first opening exposing a surface of the source drain region, and the first opening being The bit line contact window formed subsequently; a polycrystalline silicon layer and a first metal layer are sequentially formed on the first opening; and a tempering step is performed on the first metal layer so that the first metal layer and the polycrystalline silicon A petrified metal layer is formed on the surface in contact with the petrified layer; the unreacted first metal layer is removed; a second opening is formed in the dielectric layer, and the second opening is a contact window of the peripheral circuit layer to be formed subsequently; A patterned photoresist layer is formed on the dielectric layer, and the patterned photoresist layer covers the contact window of the peripheral circuit layer. The patterned photoresist layer is #etched the screen, and #etched the dielectric layer to a Given depth, Removing the patterned photoresist layer; compliantly forming a barrier layer on the surface of the semiconductor substrate, the silicided metal layer and the peripheral metal contact window; forming a second metal layer on the barrier layer, and the first metal layer Two metal layers fill the peripheral metal contact window and the first opening; and planarize the second metal layer until the surface of the dielectric layer is exposed. 9. The method for forming a bit line contact as described in item 8 of the scope of the patent application, wherein the peripheral circuit layer is an ion-doped region. 10. The method of forming a bit line contact as described in item 8 of the scope of patent application 0548-9072TWF(Nl) ; 91145 ; Claire.ptd 第18頁 1237874 六、申請專利範圍 法,其中該介電層為氧化層。 1 1.如申請專利範圍第8項所述之形成位元線接觸的方 法,其中該氧化層為矽酸四乙酯氧化層。 1 2.如申請專利範圍第8項所述之形成位元線接觸的方 法,其中該第一金屬層為鈦金屬層。 1 3.如申請專利範圍第8項所述之形成位元線接觸的方 法,其中該石夕化金屬層為$夕化鈦金屬層。 1 4.如申請專利範圍第8項所述之形成位元線接觸的方 法,其中該阻障層為鈦/氮化鈦層。 1 5.如申請專利範圍第8項所述之形成位元線接觸的方 法,其中該第二金屬層為鐫金屬層。 1 6. —種形成位元線接觸的方法,包括下列步驟: 提供一半導體基底,該半導體基底具有一週邊線路 層,且該半導體基底上形成有一電晶體,該電晶體具有一 閘極及一源汲極區; 於該半導體基底上依序形成一介電層及一第一圖案化 光阻層,該第一圖案化光阻層具有一第一開口 ,該第一開 口之位置為後續形成該位元線接觸窗之位置; 以該第一圖案化光阻層為餘刻罩幕,對該介電層進行 非等向性蝕刻步驟以形成一第二開口 ,該第二開口露出該 源汲極區之表面,且該第二開口即為後續形成之該位元線 接觸窗; 去除該第一圖案化光阻層; 於該半導體基底上形成一多晶矽層,且該多晶矽層填0548-9072TWF (Nl); 91145; Claire.ptd Page 18 1237874 6. Patent application method, where the dielectric layer is an oxide layer. 1 1. The method for forming a bit line contact as described in item 8 of the scope of the patent application, wherein the oxide layer is a tetraethyl silicate oxide layer. 1 2. The method for forming a bit line contact as described in item 8 of the patent application, wherein the first metal layer is a titanium metal layer. 1 3. The method for forming a bit line contact as described in item 8 of the scope of the patent application, wherein the petrified metal layer is a matted titanium metal layer. 1 4. The method for forming a bit line contact as described in item 8 of the patent application scope, wherein the barrier layer is a titanium / titanium nitride layer. 1 5. The method for forming a bit line contact as described in item 8 of the patent application scope, wherein the second metal layer is a rhenium metal layer. 16. A method for forming a bit line contact, including the following steps: providing a semiconductor substrate having a peripheral circuit layer, and a transistor formed on the semiconductor substrate, the transistor having a gate and a A source drain region; a dielectric layer and a first patterned photoresist layer are sequentially formed on the semiconductor substrate, the first patterned photoresist layer has a first opening, and a position of the first opening is formed subsequently The position of the bit line contact window; using the first patterned photoresist layer as a post-etch mask, performing an anisotropic etching step on the dielectric layer to form a second opening, the second opening exposing the source The surface of the drain region, and the second opening is the bit line contact window formed subsequently; removing the first patterned photoresist layer; forming a polycrystalline silicon layer on the semiconductor substrate, and filling the polycrystalline silicon layer 0548-9072TWF(Nl) ; 91145 ; Claire.ptd 第19頁 1237874 六、申請專利範圍 滿該第二開口; 對該多晶矽層進行回蝕刻步驟至露出該介電層之表 面,且該第二開口之該多晶矽層具有一第一既定深度; 於該介電層及該多晶石夕層之表面上順應性形成一鈦金 屬層; 對該鈦金屬層進行一回火步驟,以在該鈦金屬層與該 多晶石夕層接觸之表面上形成一石夕化鼓金屬層; 去除未反應之該鈦金屬層,留下該多晶石夕層表面之該 石夕化鈦金屬層; 於該介電層上形成一第二圖案化光阻層,該第二圖案 化光阻層具有一第三開口,該第三開口之位置為後續形成 該週邊線路層之接觸窗之位置; 以該第二圖案化光阻層為蝕刻罩幕,非等向性蝕刻該 介電層以形成一週邊線路層接觸窗; 去除該第二圖案化光阻層; 於該介電層上形成一第三圖案化光阻層,該第三圖案 化光阻層覆蓋住該週邊線路層接觸窗; 以該第三圖案化光阻層為蝕刻罩幕,蝕刻該介電層至 一第二既定深度; 去除該第三圖案化光阻層; 於該半導體基底、該矽化鈦金屬層及該週邊金屬接觸 窗之表面上順應性形成一阻障層; 於該阻障層上形成一鎢金屬層,且該鎢金屬層填滿該 週邊金屬接觸窗及該第二開口;及0548-9072TWF (Nl); 91145; Claire.ptd page 19 1237874 6. The scope of the patent application is full of the second opening; the polycrystalline silicon layer is etched back to expose the surface of the dielectric layer, and the second opening is The polycrystalline silicon layer has a first predetermined depth; a titanium metal layer is compliantly formed on the surfaces of the dielectric layer and the polycrystalline silicon layer; and a tempering step is performed on the titanium metal layer to form the titanium metal layer. A stone metal drum metal layer is formed on a surface in contact with the polycrystalline stone layer; the unreacted titanium metal layer is removed, leaving the stone metal titanium layer on the surface of the polycrystalline silicon layer; on the dielectric A second patterned photoresist layer is formed on the layer, and the second patterned photoresist layer has a third opening, and the position of the third opening is the position of the contact window of the peripheral circuit layer to be formed subsequently; The photoresist layer is an etching mask. The dielectric layer is anisotropically etched to form a peripheral circuit layer contact window. The second patterned photoresist layer is removed. A third patterned light is formed on the dielectric layer. Barrier layer, the third patterned photoresist Cover the contact window of the peripheral circuit layer; use the third patterned photoresist layer as an etching mask to etch the dielectric layer to a second predetermined depth; remove the third patterned photoresist layer; on the semiconductor substrate, A barrier layer is compliantly formed on the surface of the titanium silicide metal layer and the peripheral metal contact window; a tungsten metal layer is formed on the barrier layer, and the tungsten metal layer fills the peripheral metal contact window and the second Speak; and 0548-9072TWF(Nl) ; 91145 ; Claire.ptd 第20頁 1237874_ 六、申請專利範圍 平坦化該鐵金屬層,直至露出該介電層表面為止。 1 7.如申請專利範圍第1 6項所述之形成位元線接觸的 方法,其中該週邊線路層為離子摻雜區。 1 8.如申請專利範圍第1 6項所述之形成位元線接觸的 方法,其中該介電層為氧化層。 1 9.如申請專利範圍第1 6項所述之形成位元線接觸的 方法,其中該氧化層為矽酸四乙酯氧化層。 2 0.如申請專利範圍第1 6項所述之形成位元線接觸的 方法,其中該非等向性蝕刻步驟為反應性離子蝕刻或電漿 餘刻。 2 1.如申請專利範圍第1 6項所述之形成位元線接觸的 方法,其中該阻障層為鈦/氮化鈦層。0548-9072TWF (Nl); 91145; Claire.ptd Page 20 1237874_ VI. Scope of patent application Flatten the ferrous metal layer until the surface of the dielectric layer is exposed. 17. The method for forming a bit line contact as described in item 16 of the scope of the patent application, wherein the peripheral circuit layer is an ion-doped region. 18. The method for forming a bit line contact as described in item 16 of the scope of patent application, wherein the dielectric layer is an oxide layer. 19. The method for forming a bit line contact as described in item 16 of the scope of patent application, wherein the oxide layer is a tetraethyl silicate oxide layer. 20. The method for forming a bit line contact as described in item 16 of the scope of the patent application, wherein the anisotropic etching step is reactive ion etching or plasma etching. 2 1. The method for forming a bit line contact as described in item 16 of the scope of patent application, wherein the barrier layer is a titanium / titanium nitride layer. 0548-9072TWF(Nl) ; 91145 ; Claire.ptd 第21頁0548-9072TWF (Nl); 91145; Claire.ptd page 21
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