1237650 玖、發明說明(1) 【發明所屬之技術領域】 一種以添加陶瓷粉末'增韌劑之纖維強化熱可塑性疒 合材料製作方法，主要的強化材為碳纖維或是破璃 ， 是克維拉纖维（含量5 0%〜70%)，主要的基材= 隆（PA)或是聚丙烯（pp)熱可塑性樹脂（含量 ，〜2 7%)，主要的添加物可為二氧化矽（s丨〇〇 是二氧化鈦（T i 〇2)奈米級陶錄末(含量不超過^ )，增韌劑可為液態橡膠（含量2%〜3%)或 1 甲酸乙酯（PU)塑膠（含量2%〜3幻，其中^= 陶莞粉末可以提高該複合材料的抗壓強度與剛性， 橡膠與聚氨基甲酸乙s旨（PU)塑糊可明加該複合材 =的勒性與彈性，適用於要求料輕、高抗麼強度 七、成型快、耐腐韻的產品，例如··自行車曲柄組、腳踏 板丄汽車保險桿、保險桿加驗、車身外殼，聽、頭盎 2全鞋贿、防護面罩、職板、高爾夫顧，同時本 複5材料可回收再生，符合環保性。 【先前技術】 魏L，纖轉倾可雜複合㈣，祕絲全勒或工 的鞋頭，在國内與曰本均有人提出專利申請並核准專 利〇 轉=内專利.公告編號第3 4 5 4 9 0號r工作鞋之安 =、鞋底製作方法」發明專利案，依據申請專利範圍 内容得知：主要係在製作工作鞋之安全鞋頭及鞋 ，時成型所需之材料、模具設備及_，其中係以三明治 ^的方式，_-難化玻雜纖軸含強化熱塑性樹 ill續’人頁（發明說明頁不敷使闱時，請註記纖甩續頁） 1237650 發明說明（2) 腊或是強傾維布（_域維、_)内含強麟 =型材料做為中心層， 曰字戚型材料加熱至軟化之後再放入模具中高壓成型。 曰本專利：特許出願公開番號特開平丄丄〜5 6 4 χ 0全轨用輕量先芯」發明專利案，依據訂正後之申請 ，利範圍第1項之内各得知.裝在安全鞋上保護穿著者承 受外部荷重的鞋頭這部分，由纖維強化熱可塑性 所形成，符合在；IS T81GW歧安全鞋㈣通 作用S種規格所規定的性能，而且每一種的重量在4 5 ^ 以下，經由J I S T 8101鞋頭單體的壓迫試驗1 1 〇 〇 k g f負荷時的鞋頭底面和拱形後端的最大變形部份 的間隙在2 5mm以上，安全鞋用輕量鞋頭於鞋頭的肉厚 匀佈上，在與鞋頭往上突出的部分的肉厚相比的話，從鞋 頭上突部分往内部的最高部分一路移過去的肩部肉厚是較 厚的，前述纖維強化熱可塑性複合材料是單層的，而且該 複合材料的強化纖維是無方向性地分散著，前述纖維強化 熱可塑性複合材料的強化纖維的平均纖維長度在i 〇mm 〜5Omm的乾圍，前述纖維強化熱可塑性複合材料的強 化纖維的體積含有率為40%〜6〇%的範圍，前述纖維 強化熱可塑性複合材料的強化纖維是玻璃纖維，前述纖維 強化熱可塑性複合材料的熱可塑性是耐龍6、聚丙烯（p P)或是聚丙烯（PP)的聚合物或是含有變性體系樹脂 等這些事項為特徵的安全鞋用輕量鞋頭。 ί發明内容】 【發明所欲解決之技術問題】 0續類（發明說明頁不敷使用時，請註言趨使周願） 1237650 發明說明（3) 本心月所欲解決之技術問題係在於：雖然目前國内盘 c日本_維強化熱可塑性複合材料，都能符合CN、 ULf9以及JiSTSl〇i的綱安全鞋的 二所規定的性能’即鞋頭單體的盧追試 , 〇k g f負荷時的鞋頭底面和拱形後端的最大變 形部份的間隙在2 5mm以上，但是依據上述國内與曰本 件專利内容’實際使用纖維強化熱可塑性複合材料，所 製作出來的安全鞋頭，經過多次樣品測驗，可以證明使用 纖維強化射雛複合㈣製成的安全_，其抗|強产 ΪΪΪΪ不夠，無法承受較大的荷4以及撞擊，為其“ 且尚待克服解決的問題與缺失。 # ^鑑於此，本發明人於是積極投入研究開發與創新改 =精神，終於完成之本發明，係在提供—種以添加陶竟 粉末、增韌劑之纖維強化熱可塑性複合材料製作方法。 【發明解決問題之技術手段】 本發贿關狀技射段餘於：製作時先將纖維 皿加熱後，3/叉在加入〜4%添加物的熱可塑性 樹脂中，該添加物包含奈米級陶瓷粉末與增韌劑，該太半 級陶瓷粉末可為二氧鮮（S i 〇2)或是二氧化^H 〇2)，增韌劑可為液態橡膠或是聚氨基甲酸乙酯（PU) 塑膠再將上述以添加陶竟粉末、增勤劑之纖維強化熱可 塑性複合材料，作為熱壓成型特定產品的素材。 【發明對照先前技術之功效】 八本發明對照先前技術之功效係在於：上述以添加陶瓷 粉末、增韌劑之纖維強化熱可塑性複合材料，製作時是先 Θ續次頁（發明說明頁不敷使用時，請註記並使用續頁） 1237650 發明說明（4.) 將纖維束含浸於反應完成之熱可塑性樹脂槽中，這中間有 添加可以提高物性之奈米級陶瓷粉末，如：二氧化矽（S i〇2)或一氧化鈦（T i〇2)，故可提高該複合材料的 抗壓強度與剛性，和增韌劑，如：液態橡膠或聚氨基甲酸 乙酯（P U) —般稱之為耐隆變性體（s u p e r Ny 1 ο η )，故可增加該複合材料的軔性與彈性，由於熱可 塑性樹脂中含有結合媒介物（C〇upie agent )’所以可以增加強度的需求，特性比一般國内或是曰本 目如單純所使用的纖維強化熱可塑性複合材料，抗盧強度 與韌性高出許多，依據本發明之方法，以添加陶瓷粉末、 增韌劑之纖維強化熱可塑性複合材料所製作出來的安全鞋 鞋頭，經過多次樣品測驗，確實可以提高產品的抗壓強度 與韌性，可以承受較大的荷重及撞擊。 【具體實施例】 為使專精熟悉此項技藝之人仕業者易於深入瞭解本發 明的製作方法以及所能達成的功能效益，兹列舉一具體實 施例，並配合圖式詳細介紹說明如下： 一種以添加陶瓷粉末、增韌劑之纖維強化熱可塑性複 合材料製作方法，敬請參閱苐一圖所示：係本^明素材之 製造流程示意圖。主要的製造流程係包括： 一、 先將絲狀或是線狀纖維(10)收編集結成纖維束(1丨）。 二、 上述纖維束（11)經過高溫加熱烤箱（20)在攝氏二百度 的高溫加熱。 三、 將高溫加熱後的纖維束(11)含浸在添加有奈米級陶瓷 粉末與增韌劑的熱可塑性樹脂反應槽(30)中，使得纖 0續次頁（發明說明頁不敷使用時’請註記並使用續頁） 1237650 發明說明（5) 維束（11)與這些含有添加物的熱可塑性樹腊結合。 四、 再由冷卻箱(40)冷卻至室溫。 五、 由切刀輪(50)裁切成2 0mm*2 0mm以上的條狀 或片狀。 六、 選擇將纖維呈無方向性排列（纖維長度限制在2 m〜4 0 mm)或是有方向性排列。 七、 由加壓模具（60)加壓成片狀素材（7〇)。1237650 发明 Description of the invention (1) [Technical field to which the invention belongs] A method for manufacturing a fiber-reinforced thermoplastic composite material by adding ceramic powder 'toughening agent, the main reinforcing material is carbon fiber or glass break, which is Kevlar Fiber (content 50% ~ 70%), the main base material = thermoplastic (PA) or polypropylene (pp) thermoplastic resin (content, ~ 2 7%), the main additive can be silicon dioxide ( s 丨 〇〇 is titanium dioxide (T i 〇2) nano-grade ceramics (content not more than ^), the toughening agent can be liquid rubber (content 2% ~ 3%) or 1 formate (PU) plastic ( The content is 2% ~ 3 magic, of which ^ = Tao Wan powder can improve the compressive strength and rigidity of the composite material, rubber and polyurethane s purpose (PU) plastic paste can clearly add the elasticity and elasticity of the composite material = ， It is suitable for products that require light weight, high resistance, strength, fast forming, and corrosion resistance, such as bicycle cranks, pedals, car bumpers, bumper inspection, body shells, listening, head 2 Full shoe bribes, protective face masks, professional boards, golf clubs, and materials can be recycled and recycled in accordance with environmental protection [Previous Technology] Wei L, fiber-turning hybrid hybrid ㈣, mysterious silk full toe or industrial toe, both domestic and Japanese have filed patent applications and approved patents 0 turn = internal patent. Announcement No. 3 4 5 4 9 No. 0 work shoes safety =, sole manufacturing method "invention patent case, according to the scope of the patent application: it is mainly related to the production of safety shoes toe shoes and shoes, the materials and molds required for molding Equipment and _, which is in the manner of sandwich ^, _-hardened glass fiber fiber shaft containing reinforced thermoplastic tree ill Continued 'man page (when the invention description page is insufficient, please note the fiber to continue the page) 1237650 Invention description ( 2) Wax or strong tilting cloth (_domain dimension, _) contains strong Lin = type material as the center layer, said character Qi type material is heated to soften and then put into the mold under high pressure molding. This patent: license The invention patent case of "Kaihei Hei 丄 丄 ~ 5 6 4 χ 0" for the full track is published. According to the revised application, each of them can be found within the scope of item 1. Installed on safety shoes to protect and wear. The part of the toe that bears external loads is shaped by fiber-reinforced thermoplastics It meets the performance stipulated in the IS T81GW safety safety shoe lasting action S specifications, and the weight of each is below 4 5 ^, after the compression test of the JIST 8101 sole toe load of 1 100 kgf The clearance between the bottom of the toe and the largest deformed part of the arched rear end is more than 25mm. For safety shoes, use a light toe on the toe of the toe, and compare it with the thickness of the toe protruding part. The thickness of the shoulder is thicker as it moves from the upper part of the toe to the highest part of the interior. The fiber-reinforced thermoplastic composite material is a single layer, and the reinforcing fibers of the composite material are scattered non-directionally. The average fiber length of the reinforcing fibers of the fiber-reinforced thermoplastic composite material is a dry circumference of 10 mm to 50 mm, and the volume content of the reinforcing fibers of the fiber-reinforced thermoplastic composite material is in the range of 40% to 60%. The reinforcing fiber of the fiber-reinforced thermoplastic composite material is glass fiber, and the thermoplasticity of the fiber-reinforced thermoplastic composite material is resistant to dragon 6, polypropylene (PP) or polypropylene (PP). Or a compound containing these modified resins matters system characterized by toe lightweight safety shoes. [Abstract] [Technical problem to be solved by the invention] 0 Continued (When the description page of the invention is not enough, please make a note to make a wish) 1237650 Description of the invention (3) The technical problem that the heart wants to solve is ： Although the current domestic plate c Japan_dimensionally reinforced thermoplastic composite materials can meet the performance requirements of CN, ULf9 and JiSTS10i's Gang safety shoes', that is, the retrospective test of the sole of the toe, the load at 0kgf The gap between the bottom surface of the toe cap and the maximum deformation of the arched rear end is more than 25 mm, but according to the above-mentioned domestic and Japanese patent content 'Actual use of fiber-reinforced thermoplastic composite materials, the safety toe cap produced has undergone many times Sample tests can prove the safety of using fiber-reinforced shooter composite crickets, which are not resistant to high-yield crickets, can not withstand large loads and impacts, and are "problems and shortcomings that need to be resolved. # ^ In view of this, the present inventors have actively invested in research and development and innovative reform = spirit, and finally completed the present invention, which is to provide-a kind of fiber reinforcement with ceramic powder, toughening agent Method for making plastic composite material. [Technical means for solving the problem of the invention] The brigade-like technical shots are left over: after the fiber dish is heated first, 3 / fork is added in the thermoplastic resin with ~ 4% additives, The additive comprises nano-grade ceramic powder and a toughening agent. The half-stage ceramic powder may be dioxane (S i 〇2) or dioxide ^ H 〇2), and the toughening agent may be liquid rubber or Polyurethane (PU) plastic uses the above-mentioned fiber-reinforced thermoplastic composite material added with ceramic powder and time-increasing agent as the material for hot-press molding of specific products. [Effects of the invention compared with the prior art] Eight comparisons of the invention The function of the prior art is that the fiber-reinforced thermoplastic composite material with the addition of ceramic powder and toughening agent mentioned above is made before Θ (the description page of the invention is insufficient, please note and use the continuation page) 1237650 Invention Explanation (4.) The fiber bundle is impregnated in the thermoplastic resin tank after the reaction is completed. There is a nano-grade ceramic powder which can improve the physical properties, such as: silicon dioxide (SiO 2) or titanium oxide ( T i〇2), so it can improve the compressive strength and rigidity of the composite material, and toughening agents, such as: liquid rubber or polyurethane (PU)-commonly known as resistance to denaturation (super Ny 1 ο η), so the flexibility and elasticity of the composite material can be increased. Since the thermoplastic resin contains a bonding agent (Coupie agent) ', the demand for strength can be increased, and the characteristics are as simple as those in China or Japan. The fiber-reinforced thermoplastic composite material used has much higher strength and toughness. According to the method of the present invention, the toe of a safety shoe made of fiber-reinforced thermoplastic composite material with ceramic powder and toughening agent is added. Multiple sample tests can indeed improve the compressive strength and toughness of the product, and it can withstand large loads and impacts. [Embodiment] In order to make those who are familiar with this technology easily understand the production method of the present invention and the functional benefits that can be achieved, a specific embodiment will be enumerated, and it will be described in detail in conjunction with the drawings as follows: The manufacturing method of fiber-reinforced thermoplastic composite materials with ceramic powder and toughening agent, please refer to the figure below: it is a schematic diagram of the manufacturing process of this material. The main manufacturing process includes: 1. First, the filament or thread-like fibers (10) are collected and assembled into a fiber bundle (1 丨). 2. The fiber bundle (11) is heated in a high temperature heating oven (20) at a high temperature of two degrees Celsius. 3. The fiber bundle (11) heated at a high temperature is impregnated in a thermoplastic resin reaction tank (30) added with nano-grade ceramic powder and a toughening agent, so that the fiber is continued on the next page (when the description page of the invention is insufficient) 'Please note and use the continuation sheet) 1237650 Invention description (5) The dimensional bundle (11) is combined with these thermoplastic waxes containing additives. 4. Cool to room temperature from the cooling box (40). Fifth, cut by the cutter wheel (50) into a strip or sheet of more than 20mm * 2 0mm. 6. Choose to arrange the fibers in a non-directional arrangement (the fiber length is limited to 2 m ~ 40 mm) or in a directional arrangement. 7. Pressing into a sheet material (70) by a pressing mold (60).
上述添加物之奈米級陶瓷粉末，可為含量在1%以内 的二氧化梦（S i 〇2)或二氧化鈦（τ丨〇2)，所謂夺米 級係指粉末大小為J 〇的負9次方米(m)，平均分佈在該 複合材料内，作為提高該複合材料的抗壓強度與剛性之用 ，上述添加物之增韌劑，可為含量在2%〜3%的液態橡 膠或是含量在2%〜3%的聚氨基^酸乙酯（pu)^膠 ，作為增加該複合材料的韌性與彈性之用。 v 藉由上述各元件組成之本發明，係在提供一種以添加 陶瓷粉末、增韌劑之纖維強化熱可塑性複合材料製作方法 ，敬請參閱第二圖所示：係本發明產品之製造 。實際應用在產品時之主要的製造流程係、包括：程不意圖 、備料，即先將上述片狀素材⑽，依照產品的形狀、 大小裁切成長方形、正方形、梯形尊形狀及大小， 時根據^品的體積及實作經驗，秤量出片狀素材⑽The nano-grade ceramic powder of the above-mentioned additives can be a dream dioxide (S i 〇2) or titanium dioxide (τ 丨 〇2) with a content of less than 1%. The so-called rice-meter grade means that the powder size is minus 9 The cubic meters (m) are evenly distributed in the composite material. To improve the compressive strength and rigidity of the composite material, the toughening agent of the above-mentioned additives can be liquid rubber or 2% ~ 3% liquid rubber or Polyurethane (PU) gum with a content of 2% to 3% is used to increase the toughness and elasticity of the composite material. v The present invention composed of the above elements is to provide a method for manufacturing a fiber-reinforced thermoplastic composite material by adding ceramic powder and a toughening agent. Please refer to the second figure: manufacturing of the product of the present invention. The main manufacturing process when it is actually applied to a product includes: the process is not intended, and the material is prepared, that is, the above sheet material is first cut into rectangular, square, trapezoidal shapes and sizes according to the shape and size of the product. ^ The volume and practical experience of the product, weighing out the sheet material⑽
的總重量 二' 將準備好的片狀素材(70)高溫加熱軟化。 下模具加壓加熱成型 三、將軟化的片狀素材（70)，由上、 為成品 本發明以添加陶餘末、增_之纖_化熱可塑性 13續次頁（發明說明頁不敷使用時，請註記並使用續頁） x 1237650 發明說明（6 ): 複合材料，就目·前所知，可以適用於製作自行車曲柄组（ 如=二圖所示）、自行車腳踏板（如第四圖所示）、汽車保 險桿（―如第五圖所示）、汽車保險桿加強板（如第六圖所 二）、:飞車車身外殼（如第七圖所示）、盾牌（如第八圖所 = )、，（如第九圖所示）、安全鞋鞋頭（如第十圖所示 _、防護面罩（如第十—圖所示）、划雪板（如第十二圖所 爾夫球頭（如第十三圖所示）料求質量輕、抗 壓強度鬲、韌性高、成型快、耐腐蝕的產品。 一敬睛配合參閲第十圖所示··係本發明製作成安全鞋鞋 =品示意圖。上述安全鞋鞋頭⑽，先在片狀素材(7 i覆一層克維拉纖維編織布或是玻璃纖維編織布(卯）， 再=熱加壓成型為產品，使安全鞋鞋頭⑽)外面與内面棋 形前緣⑻)處包财—層克綠雜編财歧玻璃維 編織布，，作為安全鞋鞋頭⑽在荷重或是撞擊變形時 ，有夕了這一層克維拉纖維編織布或是玻璃纖 〇)包覆住拱形前緣⑽，可以避免碎屑崩裂飛 屑傷人的安全顧慮。 敬請配合參卿十二圖·:係本發贿作成划雪板 之產品不意圖。上述划雪板⑴係由木板⑵、複料 (3)、木板(2)、複合材料⑶、木板⑵夹層共同點合黏固 而成，並於第一層木板(2)上對應於雙腳踩踏的地方， 空援埋設置兩塊複合材料(3)，減少划雪板(〇 匕 增加正常的使用壽命。 、 綜合上述所陳之本發明係在提供一種以添加陶曼粉 、增新劑之纖維強化熱可塑性複合材料製作方法， 發明人實際製做完成以及反覆操作測試之後，證實的確可 0獻頁(翻說明頁不雖用時，請註記並使用動 1237650 發明說明（7) 本:1:!期的功能效益’同時又為目前坊間尚益 已經符合發明專利「實雜」與「進步性」之成立要ί:，、、 爰依專利法之規定向鈞局提出發明專利之申請。 【圖式簡單說明】 第一圖 第二圖 第三圖 第四圖 第五圖 第六圖 第七圖 第八圖 第九圖 第十圖 第十一圖 第十二圖 第十三圖 係本發明素材之製造流程示意圖。 係本發明產品之製造流程示意圖。 係本發明製作成自行車曲柄組之產品示意圖。 係本發明製作成自行車腳踏板之產品示意圖。 係本發明製作成汽車保險桿之產品示意圖。 係本發明製作成汽車保險桿加強板之產品示意圖 係本發明製作成汽車車身外殼之產品示意圖。 係本發明製作成盾牌之產品示意圖。 係本發明製作成頭盔之產品示意圖。 係本發明製作成安全鞋鞋頭之產品示意圖。 係本發明製作成防護面罩之產品示意圖。 係本發明製作成划雪板之產品示意圖。 係本發明製作成高爾夫球頭之產品示意圖。The total weight II 'softens the prepared sheet material (70) by heating at high temperature. The lower mold is pressurized and heated to form. 3. The softened sheet material (70) is made from the top and the finished product. The present invention is added with ceramic residue and fiber. (Please note and use the continuation sheet) x 1237650 Invention description (6): Composite materials, as far as we know before, can be used to make bicycle crank sets (as shown in the second figure), bicycle pedals (as (Shown in Figure 4), car bumper (-as shown in Figure 5), car bumper reinforcement plate (as shown in Figure 6) (2): speeding car shell (as shown in Figure 7), shield (such as Figure 8 =), (as shown in Figure 9), safety shoes toe caps (as shown in Figure 10_), protective masks (as shown in Figure 10-Figure), snowboarding (as shown in Figure 12) Tusolf ball heads (as shown in Figure 13) are expected to have light weight, high compressive strength, high toughness, fast molding, and corrosion resistance. The invention is a schematic diagram of safety shoes and shoes. The toe cap of the safety shoes is first covered with a sheet of Kevlar fiber (7 i). Woven cloth or glass fiber woven cloth (卯), and then = hot press molding into products, so that the safety shoes toe ⑽) outside and inside chess-shaped leading edge 包) to cover the wealth-layer green mixed miscellaneous wealth Woven cloth, used as a safety shoe toe ⑽ under load or impact deformation, this layer of Kevlar fiber woven cloth or glass fiber) to cover the arched leading edge ⑽, can avoid debris flying Fouling safety concerns. Please cooperate with the twelfth figure of the Senate: This is a bribery product that is not intended to be a snowboarding product. The above-mentioned snowboard rafter is made of wood rafter, composite (3), wooden board (2), composite material ⑶, and wood veneer sandwich, and it is fixed on the first layer of wooden board (2). Where the foot is stepped on, two pieces of composite material (3) are installed in the air to reduce the snowboarding (0) to increase the normal service life. The present invention, based on the above, is to provide a method for adding Taoman powder and adding new materials. The fiber-reinforced thermoplastic composite material manufacturing method of the agent, after the inventor's actual production and repeated operation tests, it is confirmed that it can be donated 0 pages (when the description page is not used, please note and use the 1237650 invention description (7) this : 1: The functional benefits of the period! At the same time, it is also necessary for the current establishment of the invention patent to meet the establishment of the invention patent "real miscellaneous" and "progressiveness". [Simplified description of the drawings] The first figure, the second figure, the third figure, the fourth figure, the fifth figure, the sixth figure, the seventh figure, the eighth figure, the ninth figure, the eleventh figure, the twelfth figure, and the thirteenth figure. It is a schematic diagram of the manufacturing process of the material of the present invention. Schematic diagram of the manufacturing process of the product. Schematic diagram of the product made by the invention into a bicycle crank set. Schematic diagram of the product made by the invention into a bicycle pedal. Schematic diagram of the product made by the invention into a car bumper. The product schematic diagram of the rod reinforcing plate is a schematic diagram of a product made into a car body shell by the present invention. It is a schematic diagram of a product made into a shield by the present invention. It is a schematic diagram of a product made by the present invention into a helmet. It is a schematic diagram of a product made by the present invention into a safety shoe toe. Schematic diagram of a product made into a protective face mask by the present invention. Schematic diagram of a product made into a snowboard according to the present invention. Schematic diagram of a product made into a golf head according to the present invention.