CN109353031A - The preparation method of battery box cover - Google Patents

The preparation method of battery box cover Download PDF

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Publication number
CN109353031A
CN109353031A CN201811374310.4A CN201811374310A CN109353031A CN 109353031 A CN109353031 A CN 109353031A CN 201811374310 A CN201811374310 A CN 201811374310A CN 109353031 A CN109353031 A CN 109353031A
Authority
CN
China
Prior art keywords
preparation
box cover
battery box
prepreg
mold core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811374310.4A
Other languages
Chinese (zh)
Inventor
吴国庆
唐昌伟
曹正宁
周金发
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Silver Jubilee New Energy Composite Material Co Ltd
Original Assignee
Suzhou Silver Jubilee New Energy Composite Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Silver Jubilee New Energy Composite Material Co Ltd filed Critical Suzhou Silver Jubilee New Energy Composite Material Co Ltd
Priority to CN201811374310.4A priority Critical patent/CN109353031A/en
Publication of CN109353031A publication Critical patent/CN109353031A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • B29C70/342Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation using isostatic pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • B29C70/345Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation using matched moulds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/712Containers; Packaging elements or accessories, Packages
    • B29L2031/7146Battery-cases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

The present invention provides a kind of preparation method of battery box cover comprising following steps: S1, providing continuous fiber reinforcement thermosetting resin prepreg and SMC sheet;S2, it is successively laid with prepreg, SMC layers and prepreg on mold core, obtains precast body;S3, mold core is placed in vaccum-pumping equipment together with precast body, carries out vacuumizing pre-compacted;S4, mold core is placed on the formpiston that preheating is completed together with the precast body of pre-compacted, and molds, solidifies;After S5, sizing to be solidified, the product by mold core together with curing molding takes out from mold, compresses product using setting tooling, is cooled down.The higher mechanical property requirements of case lid be not only able to satisfy by the battery box cover that preparation method of the invention obtains, but also have optimized that product is apparent and air-tightness.Compared with traditional case lid, the performances such as machinery, impact resistance, resistance to baked wheaten cake are improved, while invention further reduces material costs, improve production efficiency.

Description

The preparation method of battery box cover
Technical field
The present invention relates to a kind of power battery technology field more particularly to a kind of preparation methods of battery box cover.
Background technique
Along with the continuous development of New-energy electric vehicle, the course continuation mileage of the energy density of battery and electric car is always It is an important factor for restricting its Rapid Popularization.Therefore, the lightweight of power battery and body of a motor car is similarly subjected to wide in industry General concern.And the important component as power battery pack, battery case are equally continuing to develop update on material and technique.
Currently, the metallics battery case such as existing stainless steel and light aluminum alloy, equally exists many deficiencies, the most Significant such as fire resistance rating is low, poor corrosion resistance, weight weighting, on-insulated.Therefore, in view of the above-mentioned problems, it is necessary to propose Further solution.
Summary of the invention
The present invention is intended to provide a kind of preparation method of battery box cover and preparation method thereof, is existed in the prior art with overcoming Deficiency.
In order to solve the above technical problems, the technical scheme is that
A kind of preparation method of battery box cover comprising following steps:
S1, continuous fiber reinforcement thermosetting resin prepreg and SMC sheet are provided;
S2, it is successively laid with prepreg, SMC layers and prepreg on mold core, obtains precast body;
S3, mold core is placed in vaccum-pumping equipment together with precast body, carries out vacuumizing pre-compacted;
S4, mold core is placed on the formpiston that preheating is completed together with the precast body of pre-compacted, and molds, solidifies;
After S5, sizing to be solidified, the product by mold core together with curing molding takes out from mold, is compressed using setting tooling Product is cooled down.
Fiber in the improvement of preparation method as battery box cover of the invention, prepreg and SMC sheet is selected from glass One or more of fiber, carbon fiber, basalt fibre, aramid fiber.
In the improvement of preparation method as battery box cover of the invention, the prepreg and SMC sheet, the quality of fiber Content is 40%~75%.
The improvement of preparation method as battery box cover of the invention, the surface density of the prepreg be 150gsm~ 800gsm, the SMC sheet with a thickness of 1~5mm.
The improvement of preparation method as battery box cover of the invention, the continuous fiber reinforcement thermosetting resin prepreg In, the thermosetting resin is selected from epoxy resin, cyanate ester resin, bimaleimide resin, benzoxazine resin, phenolic aldehyde tree One of rouge, epoxy vingl ester resin, unsaturated polyester resin.
The improvement of preparation method as battery box cover of the invention, the step S1 further include: to SMC sheet according to step The laying of rapid S2 requires to be cut.
The improvement of preparation method as battery box cover of the invention, the material of the film core are selected from the material of the mold core Selected from one of aluminum, steel, glass fibre, carbon fiber, basalt fibre, aramid fiber reinforced composite material.
The improvement of preparation method as battery box cover of the invention in the step S3, when vacuumizing pre-compacted, is taken out true The empty time is 20~180s, 0.075~0.1MPa of vacuum degree.
The improvement of preparation method as battery box cover of the invention, in the step S4, the preheating temperature of formpiston is 110 DEG C~160 DEG C.
The improvement of preparation method as battery box cover of the invention, in the step S4, when molding, molding pressure is 0.6~15MPa, clamp time are 3~90min.
Compared with prior art, the beneficial effects of the present invention are: the battery box cover obtained by preparation method of the invention both The higher mechanical property requirements of case lid are able to satisfy, while optimizing that product is apparent and air-tightness again.Compared with traditional case lid, machine The performances such as tool, impact resistance, resistance to baked wheaten cake are improved, while invention further reduces material costs, improve production effect Rate.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, shall fall within the protection scope of the present invention.
Technical program of the present invention lies in provide a kind of preparation method of battery box cover comprising following steps:
S1, continuous fiber reinforcement thermosetting resin prepreg and SMC sheet are provided, and to SMC sheet according to step S2's Laying requires to be cut.
Wherein, the continuous fiber reinforcement thermosetting resin prepreg is a textile material, and the SMC is sheet molding compound (Sheet Molding Compound).It is fine that fiber in prepreg and SMC sheet is selected from glass fibre, carbon fiber, basalt One or more of dimension, aramid fiber.In the prepreg and SMC sheet, the mass content of fiber is 40%~75%.Institute State prepreg surface density be 150gsm~800gsm, the SMC sheet with a thickness of 1~5mm.
In addition, the enhancing thermosetting resin is selected from asphalt mixtures modified by epoxy resin in the continuous fiber reinforcement thermosetting resin prepreg Rouge, cyanate ester resin, bimaleimide resin, benzoxazine resin, phenolic resin, epoxy vingl ester resin, unsaturation are poly- One of ester resin.
S2, it is successively laid with prepreg, SMC layers and prepreg on mold core, obtains precast body.
Wherein, the material of the mold core is selected from aluminum, steel, glass fibre, carbon fiber, basalt fibre, aramid fiber One of composite material quality.
S3, mold core is placed in vaccum-pumping equipment together with precast body, carries out vacuumizing pre-compacted.
Wherein, when vacuumizing pre-compacted, the pumpdown time is 20~180s, 0.075~0.1MPa of vacuum degree.
S4, mold core is placed on the formpiston that preheating is completed together with the precast body of pre-compacted, and molds, solidifies.
Wherein, the preheating temperature of formpiston is 110 DEG C~160 DEG C.When molding, molding pressure is 0.6~15MPa, when molding Between be 3~90min.
After S5, sizing to be solidified, the product by mold core together with curing molding takes out from mold, is compressed using setting tooling Product is cooled down.
Technical solution of the present invention is illustrated below with reference to a specific embodiment:
Selection fabric surface density is 200gsm, and the alkali-free glass fiber fabric of resin content 35% enhances fast-curing epoxy resin The epoxy group SMC sheet that base prepreg and resin content are 50%, with a thickness of 2mm.It is cut according to structure and Lay up design State prepreg and SMC sheet, wherein two layers of Woven glass cloth prepreg, 1 layer of SMC sheet, and be located at two layers Woven glass cloth prepreg it Between.
When laying, one layer of above-mentioned Woven glass cloth prepreg is first spread on aluminum mold core, makes prepreg and mold core good fit, The second layer is coated with SMC sheet, and last third layer is above-mentioned Woven glass cloth prepreg.The mold core for being covered with precast body is transferred to vacuum In equipment, 50s is vacuumized under 0.085MPa vacuum pressure.Yin, yang mould on press is preheated to 150 DEG C.Precompressed will be had After reality on the mold core fast transfer to formpiston of precast body, and molding is quickly completed, molding pressure 2MPa, time 5min.It opens Mold core with cured shaped article is removed from the molds using manipulator, is pressed rapidly using profiling fixture, make to produce by mould Product are cooling, are formed.
For the battery box cover that above-described embodiment obtains, carried out by performance of one comparative example of setting to above-mentioned battery box cover Verifying:
It is wanted it can be seen that being both able to satisfy the higher mechanical performance of case lid by the battery box cover that preparation method of the invention obtains It asks, while optimizing that product is apparent and air-tightness again.Compared with traditional case lid, the performances such as machinery, impact resistance, resistance to baked wheaten cake are obtained It improves, while invention further reduces material costs, improve production efficiency.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (10)

1. a kind of preparation method of battery box cover, which is characterized in that the preparation method of the battery box cover includes the following steps:
S1, continuous fiber reinforcement thermosetting resin prepreg and SMC are provided;
S2, it is successively laid with prepreg, SMC layers and prepreg on mold core, obtains precast body;
S3, mold core is placed in vaccum-pumping equipment together with precast body, carries out vacuumizing pre-compacted;
S4, mold core is placed on the formpiston that preheating is completed together with the precast body of pre-compacted, and molds, solidifies;
After S5, sizing to be solidified, the product by mold core together with curing molding takes out from mold, is compressed and is produced using setting tooling Product are cooled down.
2. the preparation method of battery box cover according to claim 1, which is characterized in that the fibre in prepreg and SMC sheet Dimension is selected from one or more of glass fibre, carbon fiber, basalt fibre, aramid fiber.
3. the preparation method of battery box cover according to claim 2, which is characterized in that in the prepreg and SMC sheet, The mass content of fiber is 40%~75%.
4. the preparation method of battery box cover according to claim 2, which is characterized in that the surface density of the prepreg is 150gsm~800gsm, the SMC sheet with a thickness of 1~5mm.
5. the preparation method of battery box cover according to claim 2, which is characterized in that the continuous fiber reinforcement thermosetting property In resin prepreg material, the enhancing thermosetting resin is selected from epoxy resin, cyanate ester resin, bimaleimide resin, benzo One of oxazines resin, phenolic resin, epoxy vingl ester resin, unsaturated polyester resin.
6. the preparation method of battery box cover according to claim 1, which is characterized in that the step S1 further include: to SMC Sheet material requires to be cut according to the laying of step S2.
7. the preparation method of battery box cover according to claim 1, which is characterized in that the material of the mold core is selected from aluminium One of matter, steel, glass fibre, carbon fiber, basalt fibre, aramid fiber reinforced composite material.
8. the preparation method of battery box cover according to claim 1, which is characterized in that in the step S3, vacuumize pre- When compacting, the pumpdown time is 20~180s, 0.075~0.1MPa of vacuum degree.
9. the preparation method of battery box cover according to claim 1, which is characterized in that in the step S4, formpiston it is pre- Hot temperature is 110 DEG C~160 DEG C.
10. the preparation method of battery box cover according to claim 1, which is characterized in that in the step S4, when molding, Molding pressure is 0.6~15MPa, and clamp time is 3~90min.
CN201811374310.4A 2018-11-19 2018-11-19 The preparation method of battery box cover Pending CN109353031A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109910330A (en) * 2019-03-20 2019-06-21 上海创轲新材料科技有限公司 A kind of manufacturing method with good apparent SMC composite material element
CN110181833A (en) * 2019-05-29 2019-08-30 郝鹏翔 A kind of lightweight prepreg battery case and preparation method thereof
CN111730876A (en) * 2020-07-10 2020-10-02 苏州银禧新能源复合材料有限公司 Forming process of upper cover of composite battery box
CN112157927A (en) * 2020-09-08 2021-01-01 江苏澳盛复合材料科技有限公司 Forming process of thermosetting material in LDS process and product thereof
CN112454941A (en) * 2020-10-09 2021-03-09 许剑海 Manufacturing process of composite material battery box
CN112895519A (en) * 2021-01-20 2021-06-04 中机精密成形产业技术研究院(安徽)股份有限公司 Forming process of upper box body of composite power battery
CN113306176A (en) * 2021-05-19 2021-08-27 重庆理工大学 Microchannel thermoplastic composite material and preparation method thereof
CN113715363A (en) * 2021-09-10 2021-11-30 安徽伯拉复合材料有限公司 Rapid forming process for upper cover of composite material battery box
CN113844118A (en) * 2020-06-26 2021-12-28 汉达精密电子(昆山)有限公司 Thermosetting light composite material and preparation method thereof
CN113968050A (en) * 2020-07-24 2022-01-25 汉达精密电子(昆山)有限公司 Thermosetting light composite material and preparation method thereof

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JPS6270028A (en) * 1985-09-25 1987-03-31 Bridgestone Corp Joining method of laminate resin
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CN103407018A (en) * 2013-07-04 2013-11-27 京信通信技术(广州)有限公司 Antenna and antenna cover thereof as well as mould and forming process of antenna cover
CN203409926U (en) * 2013-07-04 2014-01-29 京信通信技术(广州)有限公司 Antenna, antenna housing of antenna and die for antenna housing
CN104441684A (en) * 2014-12-18 2015-03-25 中国电子科技集团公司第三十九研究所 After-treatment-free forming method of composite material tubes
CN105946247A (en) * 2016-05-12 2016-09-21 北京鸿鹄雄狮技术开发有限公司 Method and mold for preparing workpiece with complex inner cavity
CN106553357A (en) * 2016-11-09 2017-04-05 江苏恒神股份有限公司 Hollow multi-cavity abnormal shape surface composite material complex structural member integral forming technique

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JPS57125020A (en) * 1981-01-28 1982-08-04 Mitsubishi Electric Corp Molding of reinforced plastics
JPS6270028A (en) * 1985-09-25 1987-03-31 Bridgestone Corp Joining method of laminate resin
CN101567433A (en) * 2008-04-25 2009-10-28 现代自动车株式会社 Fuel cell separator and method for manufacturing same
CN103407018A (en) * 2013-07-04 2013-11-27 京信通信技术(广州)有限公司 Antenna and antenna cover thereof as well as mould and forming process of antenna cover
CN203409926U (en) * 2013-07-04 2014-01-29 京信通信技术(广州)有限公司 Antenna, antenna housing of antenna and die for antenna housing
CN104441684A (en) * 2014-12-18 2015-03-25 中国电子科技集团公司第三十九研究所 After-treatment-free forming method of composite material tubes
CN105946247A (en) * 2016-05-12 2016-09-21 北京鸿鹄雄狮技术开发有限公司 Method and mold for preparing workpiece with complex inner cavity
CN106553357A (en) * 2016-11-09 2017-04-05 江苏恒神股份有限公司 Hollow multi-cavity abnormal shape surface composite material complex structural member integral forming technique

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109910330A (en) * 2019-03-20 2019-06-21 上海创轲新材料科技有限公司 A kind of manufacturing method with good apparent SMC composite material element
CN110181833A (en) * 2019-05-29 2019-08-30 郝鹏翔 A kind of lightweight prepreg battery case and preparation method thereof
CN113844118A (en) * 2020-06-26 2021-12-28 汉达精密电子(昆山)有限公司 Thermosetting light composite material and preparation method thereof
CN111730876A (en) * 2020-07-10 2020-10-02 苏州银禧新能源复合材料有限公司 Forming process of upper cover of composite battery box
CN113968050A (en) * 2020-07-24 2022-01-25 汉达精密电子(昆山)有限公司 Thermosetting light composite material and preparation method thereof
CN112157927A (en) * 2020-09-08 2021-01-01 江苏澳盛复合材料科技有限公司 Forming process of thermosetting material in LDS process and product thereof
CN112454941A (en) * 2020-10-09 2021-03-09 许剑海 Manufacturing process of composite material battery box
CN112454941B (en) * 2020-10-09 2022-07-08 许剑海 Manufacturing process of composite material battery box
CN112895519A (en) * 2021-01-20 2021-06-04 中机精密成形产业技术研究院(安徽)股份有限公司 Forming process of upper box body of composite power battery
CN112895519B (en) * 2021-01-20 2022-12-13 中机精密成形产业技术研究院(安徽)股份有限公司 Forming process of upper box body of composite power battery
CN113306176A (en) * 2021-05-19 2021-08-27 重庆理工大学 Microchannel thermoplastic composite material and preparation method thereof
CN113715363A (en) * 2021-09-10 2021-11-30 安徽伯拉复合材料有限公司 Rapid forming process for upper cover of composite material battery box
CN113715363B (en) * 2021-09-10 2023-01-06 安徽伯拉复合材料有限公司 Rapid forming process for upper cover of composite material battery box

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Application publication date: 20190219