1233371 修正 ___________________________案號 92112073+ 五、發明說明（1) 發明所屬之技術領域 、本發明係提供一種臭氧去除裝置，尤指一種具有一 液體擾動裝置且可快速地去除液體中之臭氧的臭氧去除 裝置。 先前技術 臭氧（ozone，03)與水反應之後會產生含有高氧化力 與高氫化力的氫氧基物質之臭氧水溶液（οζομ-ο: ο n t a i n i n g w a t e r ) ’ 因此能 夠瞬間 分解水 中的雜 菌與污 垢’故具有消毒、脫臭、降解農藥與分解自來水中過量 的含氣化合物等功效，又因為其殺菌速度優於氣，且適 用於紫外線照射不到的地方，因此臭氧水的應用範圍相 當廣泛，例如在半導體或液晶顯示器（LCD)等產業中的清 洗衣私’或疋與我們日常生活息息相關的方面，可運用 在洗澡水中、蔬果、衣服的洗淨，或是家庭器具的殺菌 等。 δ月參考表一’表一為臭氧濃度、空氣污染指標值 (pollutant standards index，PSI)與對人體健康之影 響的比較表。如表一所示，基本上安全的使用臭氧可= 完全地保證人體健康不受危害，國際臭氧協會、 (International Ozone Institute, I〇I)標準規定合办 氣濃度中含有 〇 · 1 p p m以下濃度之臭氧時，對人體有兴 1233371 (_______________________________魅_J2112073______________________________芏——3 _0___________ 魅_________________ i五、發明說明（2)1233371 Amendment ___________________________ Case No. 92112073+ V. Description of the Invention (1) The technical field to which the invention belongs, the present invention provides an ozone removal device, especially an ozone having a liquid disturbance device and capable of quickly removing ozone in the liquid Remove the device. In the prior art, ozone (ozone, 03) reacts with water to produce an aqueous ozone solution (οζομ-ο: ο ntainingwater) containing highly oxidizing and highly hydrogenating hydroxyl-containing substances. 'So it can instantly decompose the bacteria and dirt in the water' Therefore, it has the effects of disinfection, deodorization, degradation of pesticides and decomposition of excessive gas-containing compounds in tap water. Because its sterilization speed is better than gas, and it is suitable for places not exposed to ultraviolet rays, the application range of ozone water is quite wide, such as In the semiconductor or liquid crystal display (LCD) and other industries, such as washing clothes, or related to our daily life, can be used in bath water, washing fruits and vegetables, clothes, or disinfection of household appliances. δ Monthly Reference Table 1 'Table 1 is a comparison table of ozone concentration, polluting standards index (PSI), and impact on human health. As shown in Table 1, the basically safe use of ozone can completely guarantee that human health is not harmed. The International Ozone Institute (IOI) standards stipulate that the concentration of the co-gas should contain a concentration below 0.1 ppm. When it is ozone, it has an interest in the human body 1233371 (_______________________________ Charm_J2112073______________________________ 芏 ——3 _0___________ Charm_________________ i. Description of the invention (2)
I 且無任何副作用，此外，臭氧與有害物質進行分解之 後，能夠自動還原成氧氣，因此不會造成二次公害。然 而，臭氧在分解後會產生氧化氫、氳氧離子氧及臭氧等 自由基，並可同時形成過氧化氫及氧分子，這些自由基 容易使人體致癌，且其難聞之氣味亦讓人難以忍受，在 現代日益注重環保的時代，必需要對這些臭氧排放物加 以特殊地處理。 習知由工廠或家庭中的臭氧水產生裝置所產生之臭 氧水，在使用過後通常沒有經過特殊地處理就直接排放 至外界。一般而言，臭氧在大氣中（常溫）之半衰期為四 十分鐘，且會隨溫度不同而有所改變，而臭氧在水中之 半衰期為二十分鐘，且當水中的PH值高時分解速度變 快，PH值低時較緩慢，因此使用過後的臭氧水通常需要 經過數十公尺的管路，使得臭氧水自然還原成氧氣後， 才能排放至外界，否則其氣味會對人體與環境造成影 響。然而由於空間的限制，大部分的臭氧水都在還沒有 完全還原成氧氣的狀態時就被排放至大氣中，而使得空 氣中的臭氧含量過高。 因此，台灣專利第3 048 8 7號即揭露一種將臭氧自氣 體與液體中移除的濾材及方法，其主要利用包含有聚芳 醚或聚苯乙烯的濾材來吸附臭氧，然而這種吸附臭氧的 方式，必須要定期更換濾材，不但麻煩且大幅增加成 本0 1233371 ______________案號 92112073______________±_____J___0________ 五、發明說明（3) 可臭 ，之 置中 裝體 除液 去除 氧去 臭地 種速 一快 供且 提費 於浪 在的 的間 目空 要路 主管 之放 明排 容發少 内 本減 明效。 發有氧 其體時 ，氣要 置與需 裝體不 除液且 去加， 氧增氧 臭以臭 種體的 一液中 供動體 提擾液 於來除 在用去 的，地 目置速 一裝快 另動以 之擾，。 明體積材 發液面耗 本一觸換 有接更 具的常 本發明之最佳實施例係揭露了 一種臭氧去除裝置， 該臭氧去除裝置係設置於一液體管路之一輸入端與一輸 出端之間，用以去除於該液體管路内之一液體中的臭 氧。該臭氧去除裝置包含有一殼體，以及至少一液體擾 動裝置，設置於該殼體内，且該殼體包含有一用以連接 該輸入端部分之該液體管路的液體入口，一用以連接該 輸出端部分之該液體管路的液體出口，至少一用以通入 一氣體至該殼體之該液體内的進氣口，以及至少一用以 排放該氣體至該殼體外的排氣口。其中，當該液體管路 中之該液體自該液體入口流入該殼體時’該液體擾動裝 置與通入該液體内之該氣體係用以擾動該液體，以使該 液體中的臭氧伴隨該氣體經由該排氣口被排放至該殼體 之外，而擾動後之該液體則經由該液體出口流至該液體 1233371 ___________________案號 92112073_________________^________^________0__________________魅_______________________________— 丨五、發明說明（4) i管路之該輸出端。I without any side effects. In addition, after the decomposition of ozone and harmful substances, it can be automatically reduced to oxygen, so it will not cause secondary pollution. However, after the decomposition of ozone, free radicals such as hydrogen oxide, tritium ion oxygen, and ozone can be generated, and hydrogen peroxide and oxygen molecules can be formed at the same time. These free radicals easily cause human cancer, and their unpleasant odor is difficult Tolerate, in an age where modern environmental protection is increasingly important, these ozone emissions must be treated specially. It is known that ozone water produced by ozone water generating devices in factories or households is usually directly discharged to the outside without special treatment after use. Generally speaking, the half-life of ozone in the atmosphere (normal temperature) is forty minutes, and will change with temperature. The half-life of ozone in water is twenty minutes, and the decomposition rate changes when the pH value of water is high. Fast, slow when PH value is low, so after use, the ozone water usually needs to go through tens of meters of pipeline, so that the ozone water can be naturally reduced to oxygen before it can be discharged to the outside, otherwise its odor will affect the human body and the environment. . However, due to space constraints, most of the ozone water is discharged to the atmosphere before it is completely reduced to oxygen, which makes the ozone content in the air too high. Therefore, Taiwan Patent No. 3 048 8 7 discloses a filter material and method for removing ozone from gas and liquid. It mainly uses a filter material containing polyarylether or polystyrene to adsorb ozone. However, this kind of adsorption ozone In this way, the filter medium must be replaced regularly, which is not only troublesome and greatly increases the cost. Contributions and fees to the lingering directors of the stern and empty roads of the director's open-mindedness and curtailment will reduce the cost and reduce the effect. When aerobic body is generated, the gas should be placed with the body to be removed without adding liquid, and oxygen should be added to the body to remove the liquid from the odorous body. Quickly disturbed by one install. The liquid surface of the bulk material consumes more than one touch. The preferred embodiment of the present invention discloses an ozone removal device. The ozone removal device is disposed at one input end and one output end of a liquid pipeline. Between the ends for removing ozone in a liquid in the liquid pipeline. The ozone removal device includes a casing and at least one liquid disturbance device disposed in the casing, and the casing includes a liquid inlet for connecting the liquid pipeline of the input end part, and a connection for the The liquid outlet of the liquid pipe at the output end portion has at least one air inlet for passing a gas into the liquid in the casing, and at least one air outlet for exhausting the gas to the outside of the casing. Wherein, when the liquid in the liquid pipeline flows into the casing from the liquid inlet, the liquid disturbance device and the gas system passing into the liquid are used to disturb the liquid, so that the ozone in the liquid accompanies the liquid. The gas is discharged out of the casing through the exhaust port, and the liquid after the disturbance flows to the liquid through the liquid outlet. 1233371 ___________________Case No. 92112073 _________________ ^ ________ ^ ________ 0__________________Character___________________ (4) The output end of i pipeline.
I | 由於本發明之含有臭氧的液體會先經過該液體擾動 裝置再流入該殼體中’且由該進氣口通入氣體’以大幅 地增加流入該殼體内之液體與通入該殼體之氣體的接觸 面積，使得液體中的臭氧得以快速地經由該排氣口排放 至外界，以減少該液體管路之空間使用。 實施方式 請參考圖一，圖一為本發明之臭氧去除裝置1 〇之剖 面示意圖。如圖一所示，本發明之臭氧去除裝置1 0主要 包含有一殼體12，設置於一液體管路14之一輸入端16與 一輸出端1 8之間，且殼體1 2包含有一液體入口 2 0與一液 體出口 2 2，用以分別連接液體管路1 4之輸入端1 6部分與 輸出端18部分，至少一進氣口（gas inlet)24，用以適入 一氣體至殼體12之液體内，至少一排氣口（gas outlet) 2 6，用以排放氣體至殼體1 2外，以及至少一液體擾動裝 置2 8，設置於殼體1 2内，用以擾動流入液體擾動裝置2 8 之液體。 在本發明之最佳實施例中，臭氧去除裝置1 0是裝設 於一臭氧水產生設備（未顯示於圖一中）之後端，用來當 作臭氧水棑放時的終端處理，且臭氧水產生設備是設於 一 LCD之玻璃基板的清洗製程中，用以產生具有高濃度的I | Because the ozone-containing liquid of the present invention passes through the liquid disturbance device and then flows into the casing 'and the gas is passed through the air inlet' to greatly increase the liquid flowing into the casing and the casing The contact area of the gas in the body allows the ozone in the liquid to be quickly discharged to the outside through the exhaust port, thereby reducing the space usage of the liquid pipeline. Embodiment Please refer to FIG. 1. FIG. 1 is a schematic cross-sectional view of an ozone removing device 10 according to the present invention. As shown in FIG. 1, the ozone removing device 10 of the present invention mainly includes a casing 12 disposed between an input end 16 and an output end 18 of a liquid pipeline 14, and the casing 12 includes a liquid The inlet 20 and a liquid outlet 22 are used to connect the input end 16 and the output end 18 of the liquid pipeline 14 respectively, and at least one gas inlet 24 is used to fit a gas to the shell. Inside the liquid of the body 12, at least one gas outlet 2 6 is used to discharge gas to the outside of the housing 12, and at least one liquid disturbance device 28 is provided in the housing 12 to disturb the inflow. The liquid disturbs the liquid of the device 2 8. In a preferred embodiment of the present invention, the ozone removing device 10 is installed at the rear end of an ozone water generating device (not shown in FIG. 1), and is used as a terminal treatment when the ozone water is released, and the ozone The water generating equipment is set in the cleaning process of the glass substrate of an LCD, and is used to produce high-concentration
第8頁 1233371 _______________________________案號 92112073_______________生A_____S __________________________ 五、發明說明（5) 臭氧水來清洗玻璃基板。當使用完畢且含有高濃度臭氧 的臭氧水3 0流至液體管路1 4中後，臭氧水3 0會自液體入 口 2 0流入臭氧去除裝置10内之液體擾動裝置28中，之後 經由液體擾動裝置2 8擾動後的臭氧水會流入殼體1 2中， 此時，臭氧去除裝置1 0會持續地經由進氣口 2 4通入氣體 至殼體12内的臭氧水32中，使得通入臭氧水32内之氣體 與臭氧水3 2相作用而擾動臭氧水3 2，以增加臭氧水3 2以 及通入殼體1 2内之氣體的接觸面積，使得臭氧水3 2中的 臭氧加速地排出，並伴隨氣體經由排氣口 2 6被排放至殼 體1 2外，而擾動後之含有低濃度臭氧的臭氧水3 4則經由 液體出口 2 2流至液體管路1 4之輸出端1 8，再排放至外 界，以避免危害人體健康與空氣品質。 值得注意的是，本發明之液體擾動裝置2 8可以為一 蓮蓬頭裝置、一攪拌裝置，甚或是一超音波震盪裝置， 以快速地擾動流入液體擾動裝置2 8内的臭氧水3 0，使得 臭氧水3 0中的臭氧可以快速地被排放出來，並加速臭氧 還原成氧氣的速度。而通入臭氧水3 2中的氣體也可以利 用各種方式，例如：臭氧去除裝置1 0可另包含有一氣泡 產生器（未顯示於圖一中），而該氣泡產生器係用來將氣 體以大量微氣泡的方式通入至臭氧水3 2中，或者是，將 進氣口 2 4連接於一氣體加壓裝置（未顯示於圖一中），利 用高壓方式將氣體通入至臭氧水3 2中，以擾動臭氧水3 2 並增加氣體與臭氧水3 2的接觸面積。此外，排氣口 2 6可 以直接與外界環境相連接，使得殼體1 2内之臭氧水3 2與 1233371 广________________________________案號92112073__________免—_^ 日_________________________魅____________________________________ |五、發明說明（6) |外界空氣相接觸，以增加臭氧水3 2與空氣的接觸面積， |又排氣口 2 6亦可以連接於一抽氣裝置（未顯示於圖一 中），以加速臭氧的排放。在本發明之最佳實施例中，經 由進氣口 2 4通入殼體1 2内之氣體係為空氣，且經由排氣 口 2 6排放至殼體1 2外之氣體係包含有空氣與臭氧，且排 出的臭氧濃度約小於0 . 1 p P m。 簡言之，本發明之臭氧去除裝置主要利用液體擾動 裝置來擾動臭氧水，並通入氣體以增加臭氧水與氣體之 接觸面積，以加速臭氧水中的臭氧之排放，並使得臭氧 能夠快速的還原為氧氣，且排放至外界之臭氧濃度很 低，完全不會危害人體健康與環境，因此本發明之臭氧 去除裝置不但可以減少液體管路空間的浪·費與其製造成 本，亦使得廢水中的臭氧含量與排放至外界中的廢氣能 夠符合環境安全的標準，且不需要時常更換耗材，成本 低廉且方便使用。 以上所述僅為本發明之較佳實施例，凡依本發明申 請專利範圍所作之均等變化與修飾，皆應屬本發明專利 之涵蓋範圍。Page 8 1233371 _______________________________ Case number 92112073_______________ Health A_____S __________________________ V. Description of the invention (5) Ozone water to clean glass substrates. When the ozone water 30 with high concentration of ozone has been used and flows into the liquid pipeline 14, the ozone water 30 will flow from the liquid inlet 20 into the liquid disturbance device 28 in the ozone removal device 10, and then be disturbed by the liquid The ozone water perturbed by the device 28 will flow into the casing 12, and at this time, the ozone removal device 10 will continuously pass gas through the air inlet 24 to the ozone water 32 in the casing 12, so that the The gas in the ozone water 32 interacts with the ozone water 32 to disturb the ozone water 32, so as to increase the contact area of the ozone water 32 and the gas flowing into the housing 12, so that the ozone in the ozone water 32 is accelerated. It is discharged, and the gas is discharged to the outside of the casing 12 through the exhaust port 26, and the ozone water 3 4 containing the low concentration ozone after the disturbance flows to the output end 1 of the liquid pipeline 1 through the liquid outlet 2 2 8. Re-emission to the outside to avoid harming human health and air quality. It is worth noting that the liquid disturbance device 28 of the present invention may be a shower head device, a stirring device, or even an ultrasonic vibration device to quickly disturb the ozone water 30 flowing into the liquid disturbance device 28 to make the ozone The ozone in water 30 can be quickly discharged and accelerate the reduction of ozone to oxygen. The gas in the ozone water 32 can also be used in various ways. For example, the ozone removal device 10 may further include a bubble generator (not shown in FIG. 1), and the bubble generator is used to transfer the gas to A large number of micro-bubbles are introduced into the ozone water 3 2, or the air inlet 24 is connected to a gas pressurizing device (not shown in FIG. 1), and the gas is introduced into the ozone water 3 by high pressure. 2 to disturb the ozone water 3 2 and increase the contact area of the gas with the ozone water 32. In addition, the exhaust port 2 6 can be directly connected to the external environment, so that the ozone water 3 2 and 1233371 in the casing 12 can be ________________________________ Case No. 92112073 __________ exempt — _ _ day _________________________ charm ____________________________________ | Description of the invention (6) | The outside air contacts to increase the contact area of the ozone water 3 2 with the air, and the exhaust port 2 6 can also be connected to an extraction device (not shown in Figure 1) to accelerate the ozone Emissions. In the preferred embodiment of the present invention, the gas system that is introduced into the housing 12 through the air inlet 24 is air, and the gas system that is discharged to the outside of the housing 12 through the air outlet 26 includes air and Ozone, and the emitted ozone concentration is less than about 0.1 p P m. In short, the ozone removal device of the present invention mainly uses a liquid perturbation device to perturb the ozone water, and introduces gas to increase the contact area between the ozone water and the gas, so as to accelerate the emission of ozone in the ozone water and enable the ozone to be quickly reduced. It is oxygen, and the ozone concentration discharged to the outside is very low, which will not endanger human health and the environment. Therefore, the ozone removing device of the present invention can not only reduce the waves and expenses of the liquid pipeline space and its manufacturing cost, but also make the ozone in the wastewater. The content and exhaust gas discharged to the outside world can meet the environmental safety standards, and it is not necessary to replace consumables from time to time, which is low cost and convenient to use. The above description is only a preferred embodiment of the present invention, and any equivalent changes and modifications made in accordance with the scope of the patent application of the present invention shall fall within the scope of the patent of the present invention.
第10頁 1233371 ______________________________案號 92112073______________________________壬___________η_________a________________修正— 圖式簡單說明 圖式之簡單說明 圖一為本發明之臭氧去除裝置之剖面示意圖。 圖式之符號說明 10 臭 氧 去 除 裝 置 12 殼 體 14 液 體 管 路 16 液 體 管 路 之 輸入端 18 液 體 管 路 之 輸出端 20 殼 體 之 液 體 入口 22 殼 體 之 液 體 出口 24 進 氣 口 26 排 氣 π 28 液 體 擾 動 裝 置 30 高 濃 度 臭 氧 水 32 殼 體 内 的 臭 氧水 34 低 濃 度 臭 氧 水 1233371 臭氧濃度、空氣污染指標值與對人體健康之影響的比較表 臭氧濃度 (ppm) 空氣污染指標值 (PSI) 對人體健康之影響 0. 06 50 無影響 0. 12 100 普通 0· 3 250 刺激眼睛，對人體不良 0· 5 400 減低肺功能，對人體極不良 1. 0 > 500 咳嗷、疲勞、呼吸阻力增加， 對人體有害 10. 0 > 500 肺水腫、急性細支氣管炎、 脈搏微弱，對人體極有害 表一Page 10 1233371 ______________________________ Case No. 92112073______________________________ Ren ___________ η _________ a________________ Amendment-Simple Description of the Drawings Simple Description of the Drawings Figure 1 is a schematic cross-sectional view of the ozone removal device of the present invention. Explanation of symbols in the drawing 10 Ozone removal device 12 Housing 14 Liquid pipeline 16 Liquid pipeline input terminal 18 Liquid pipeline output terminal 20 Liquid inlet of the housing 22 Liquid outlet of the housing 24 Air inlet 26 Exhaust π 28 Liquid perturbation device 30 High-concentration ozone water 32 Ozone water in the case 34 Low-concentration ozone water 1233371 Comparison of ozone concentration, air pollution index values, and effects on human health Ozone concentration (ppm) Air pollution index value (PSI) Impact on human health 0. 06 50 No effect 0. 12 100 Normal 0 · 3 250 Stimulate eyes, bad for human body · 5 400 Reduce lung function, extremely bad for human body 1. 0 > 500 Cough, fatigue, breathing Increased resistance, harmful to humans 10. 0 > 500 Pulmonary edema, acute bronchiolitis, weak pulse, extremely harmful to humans Table 1