TWI222473B - Stretchable high density fabric - Google Patents
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- TWI222473B TWI222473B TW89115026A TW89115026A TWI222473B TW I222473 B TWI222473 B TW I222473B TW 89115026 A TW89115026 A TW 89115026A TW 89115026 A TW89115026 A TW 89115026A TW I222473 B TWI222473 B TW I222473B
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1222473 A7 B7 五、發明說明(1 ) 技術領域 本發明係有關以柔軟的手感,具有良好的伸縮性及耐 水性之高密度織物。 背景技術 長久以來,對已採用聚醯胺系纖維或聚酯系纖維之高 密度織物施加撥水加工等,已賦與耐水性之織物係爲人所 知的,被廣泛的利用於鴨絨外套用禦寒衣料,或防風布, 茄克衫、外衣、兩衣用等運動衣料或外衣等。 然而,一般的高密度織物幾乎是無伸長率,故運動時 身體之動作會受阻礙,感覺壓迫,又未能自由的動作而感 覺不舒服。又因係高密度織物,手感較硬,再者藉由爲賦 與耐水性等而作的撥水加工或樹脂加工會增加織物之硬度 ,故對運動或身體之動作會有硬度增大,自由的動作受阻 礙,織物相互間在接觸時之摩擦音變大,並不舒服。 爲解決此等問題點,在日本特開平1 1 — 8 1 1 4 1 號公報內,揭示有於織物之緯紗及/或經紗採用聚對苯二 甲酸丙二醇酯纖維,於該織物上施加樹脂加工之柔軟手感 的高密度織物。又於日本特開平11一200174號公 報內,揭示有將經紗之覆蓋率及緯紗之覆蓋率之比,定義 成覆蓋率之和,彈性恢復率在9 0%以上的聚對苯二甲酸 丙二醇酯纖維構成的柔軟的手感之高密度織物。 然而,此等公報所揭示的技術,係藉由以柔軟的聚對 苯二甲酸丙二醇酯纖維形成織物,手感或織物相互間之摩 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) I----· I I • > (請先閱讀背面之注意事項再Φ本頁) 訂· •線. 經濟部智慧財產局員工消费合作社印製 -4 - 1222473 A7 B7 五、發明說明(2 ) 擦音雖經予改善,惟收縮性仍不足,故妨礙身體之動作的 問題點仍未予解決。 又,·於日本特開平9 一 1 70 1 75號公報內,提出 採用單紗纖度0 . 5丹尼以下的圓斷面之極細的多條長纖 絲,以經紗、緯紗之布面覆蓋係數之和在2 2 0 0以上的 防風性及耐水性經予提高的織物。然而,此種高密度織物 雖可得良好的耐水性,然而因伸縮性不足,會妨礙身體之 動作。 另一方面,於日本特開平11一256413號公報 內提出採用聚對苯二甲酸丙二醇酯纖維於織物之緯紗,藉 由定義出緯紗之捲縮指數,在緯紗方向有伸縮性、表面平 滑性優越、縫絲針跡之防止滑脫性能及降低壓迫感方面優 越的襯料。 然而,在該襯料雖然緯方向之伸縮性被賦與著,但未 能獲得良好的耐水性。 發明之揭示 經濟部智慧財產局員工消費合作社印製 -------B----.——裝· II <請先"閲讀背面之注意事項再4|^4頁) --線- 本發明係以提供柔軟的手感,兼具良好的伸縮性及耐 水性之高密度織物爲目的。 且本發明所謂的耐水性,係指能耐水壓之性能(耐水 壓性)。 本發明人等爲解決上述課題,經精心檢討的結果,採 用聚對苯二甲酸丙二醇酯纖維,以特定的布面覆蓋係數構 成織物,對該織物施以特殊的處理,藉由將纖維之捲縮率 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公爱) -5- 1222473 A7 -—- _ B7 五、發明說明(3 ) 、織物之伸縮率,纖維塡充度等設成特定範圍,發現可達 成本發明之目的,以至完成本發明。 亦即·,本發明係如下述般。 1 ·以布面覆蓋係數爲1800〜2540,於緯向 或經向上具有伸縮率5〜2 0 %之伸縮性,且具有至少伸 縮性之方向的纖維爲聚對苯二甲酸丙二醇酯纖維所構成的 爲特徵之具伸縮性高密度織物。 2·以表示具有伸縮性之方向之纖維之捲縮指數的 CI値(下述)爲〇 · 〇〇5〜0 · 013,表示纖維塡 充度之DS値(下述)爲〇 · 5〜1 · 0爲特徵之上述記 載的具伸縮性高密度織物。 C I = CR/CFv DS (g/cm3) = Ws/Vs =Ws CVxCFs/(CFs+CFv)] 經濟部智慧財產局員工消费合作社印製 -------^----,---裝--- •(請先时讀背面之注意事項再頁) •線· (惟,C R爲具伸縮性之方向的纖維之捲縮率,C F v爲 與具伸縮性的方向之纖維正交的纖維之布面覆蓋係數, W s爲每1 m2織物之具伸縮性的方向之纖維之表觀體積( cm3) ,V爲每lm2織物之表觀體積(cm3) ,CFs 爲具伸縮性的方向之纖維之布面覆蓋係數,) 3 .以具伸縮性的方向之纖維爲由具有扁平度2〜6 之扁平單紗截面之聚對苯二甲酸丙二醇酯纖維所構成的爲 特徵之上述1或2記載的具伸縮性高密度織物。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -6 - 1222473 A7 B7 五、發明說明(4 ) i — — — — — —— — — — — · ^ · I I (請先试讀背面之注意事項再頁) 4 ·以對織物寬度在決定寬度1 〇〜4 0%之狀態下 對織物進行1 5 0〜2 0 0°C之乾熱處理,使緯紗出現捲 縮後’進行精線、染色加工、軋光機加工爲特徵之上述1 〜3項之任一項之具伸縮性高密度織物之製造方法。 1施發明而採的最佳形態 本發明之高密度織物’係以具伸縮性的方向之纖維爲 聚對苯二甲酸丙二醇酯纖維所構成的。 線- 在本發明,聚對苯二甲酸丙二醇酯纖維係指以對苯二 甲酸丙二醇酯單位爲主要的重複單位之聚酯纖維,對苯二 甲酸丙二醇酯單位爲約5 0莫耳%以上,宜爲7 0莫耳% 以上,較宜爲8 0莫耳%以上,更宜爲9 0莫耳%以上者 。因此,至於第三成分,包含另外的酸成分及/或二醇成 分之合計量爲約5 0莫耳%以下,宜爲3 0莫耳%以下, 較宜爲2 0莫耳%以下,更宜爲1 0莫耳%以下的範圍所 含有的聚對苯二甲酸丙二醇酯。 經濟部智慧財產局員工消费合作社印製 聚對苯二甲酸丙二醇酯係在觸媒之存在下,以適當的 反應條件使對苯二甲酸或其功能性衍生物,與三亞甲二醇 或其衍生性衍生物結合而予合成。在此合成過程,添加適 當的一種或二種以上的第三成分並作爲共聚合聚酯亦可。 又將聚對苯二甲酸丙二醇酯與聚對苯二甲酸乙二酯等的聚 對苯二甲酸丙二醇酯以外的聚酯摻混,予以複合抽絲(鞘 芯、邊靠邊等)亦可。 至於添加的第三成分,可舉出:脂環族二羧酸(草酸 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1222473 A7 ____ B7 經濟部智慧財產局員工消费合作社印製 五、發明說明(5 、己二酸等)、脂環族二羧酸(環己烷二羧酸等)、芳香 族二羧酸(間苯二甲酸、磺基間苯二甲酸鈉等)、脂肪族 二醇)乙二醇1 ,2 —丁二醇、四亞甲二醇等)、脂環族 二醇(環己烷二甲醇等)。含有芳香族之脂肪族二醇(1 ,4 一雙(沒一羥乙氧基)苯等)、聚醚二醇(聚乙二醇 、聚丙二醇等)、脂肪族氧基羧酸(w —氧基己酸等)、 芳香族氧基羧酸(對-氧基安息香酸等)等。 又具有一個或三個以上的酯形成性官能基之化合物( 安息香酸等或丙三醇等)亦係聚合體在實質上線狀的範圍 內可使用。 再者’亦可含有二氧化鈦等消光劑、磷酸等安定劑、 羥基二苯甲酮衍生物等紫外線吸收劑、滑石粉等結晶化核 劑、超微粉二氧化矽(Aerosil )等容易潤滑劑、受阻酚衍 生物等抗氧化劑、耐燃劑、抗靜電劑、顏料、螢光增白劑 、紅外線吸收劑、消泡劑等。 本發明所用的聚對苯二甲酸丙二醇酯纖維,係例如以 1 5 0 0 m /分鐘之捲取速度製得未拉伸絲後,由約2〜 3 · 5倍拉撚的方法,直接連結抽絲-拉撚步驟之抽絲拉 伸(spin draw )法,捲取速度在5 0 0 Om /分鐘以上的 高速抽絲(spin take up )法等方法而得。 又,纖維之形態係可爲多條長纖絲、紡織絲,亦可爲 長度方向上呈均勻者或直徑較細者,惟以多條長纖絲較宜 。再者,至於多條長纖紗之形態,可採用多條長纖原紗( 含有極細紗)、鬆撚紗〜強撚紗、混纖紗、假撚紗(含有 請 先· 閱 讀 背 面 之 注 意 事 項 再 f 裝 訂 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -8- 1222473 經濟部智慧財產局員工消费合作社印製 Α7 Β7 五、發明說明(6 ) P〇Y之拉伸假撚紗)、液體噴射加工紗等,惟在爲使較 提高耐水性之點,宜爲多條長纖原紗,在使伸縮性、柔軟 手感較提高的點,以假撚紗爲宜。 聚對苯二甲酸丙二醇酯纖維之纖度,在製成織物之情 形爲得足夠的強度,宜爲3 3 d t e X以上,爲避免織物 變成較厚且粗硬,宜爲在1 6 7 d t e X以下。較宜的纖 度爲5 6〜1 1 1 d t e X。又單紗纖度在爲抑制抽絲時 之斷紗,提高抽絲之安定性,宜爲0 · 1 d t e X以上, 爲保持織物之耐水性,抑制成爲粗硬的手感,宜爲5 · 6 dt ex以下。較宜的單紗纖度爲0 · 56〜3 · 3 d t e X 〇 聚對苯二甲酸丙二醇酯纖維之截面形狀,雖可爲圓型 、三角型、L型、T型、Y型、W型、八葉型、扁平型、 狗骨頭型等多.邊形型、多片葉型、中空型或不定型者,惟 在使更進一步提升織物之伸縮性、耐水性、觸感之柔軟度 上,若單紗爲扁平截面即較佳。藉由採用扁平截面紗,則 在織物之中扁平的單紗會重疊並予塡充,有助於耐水性之 提高。兩者,扁平截面紗係具有顯著的抗折柔軟性,故在 織物中對與扁平截面紗正交的紗容易屈曲,由該扁平截面 紗之屈曲引起的捲縮之伸長率係可予有效的利用,使織物 之伸縮性增大,同時成爲柔軟的手感之織物。 在此所謂的扁平截面,係指單紗之截面作成W型.、I 型、V型、Μ型、狗骨頭型、橢圓型、波浪型、糖葫蘆串 型的扁平形狀截面。形成單紗之凹凸部相互重疊且予塡充 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --------------裝--- * % • <請先IKrtt背面之注意事項再ίίφΦ頁) •線· -9 - 1222473 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明(7 ) 的疊磚塊形態之W型等,在提高耐水性之點係較宜的。 再者,扁平截面紗之扁平度在爲得伸縮性、耐水性、 柔軟的手感,以2以上爲宜,在抽絲之穩定性之點宜爲6 以下。在此所謂的扁平度,係指描繪與單紗之截面外切的 長方形,此長方形之長邊L爲短邊Η所除的値。 且本發明所用的聚對苯二甲酸丙二醇酯纖維,在不損 及本發明之目的的範圍內(例如6 0重量%以下),以交 絡混纖(與高收縮紗間之異收縮混纖紗等),交撚、複合 假撚(伸長率差假撚等)、二喂紗空氣噴射加工等的手段 混用其他的纖維亦可。混用的纖維亦可爲任何種纖維、混 用聚酯系纖維、聚醯胺系纖維、聚丙烯腈系纖維、聚乙烯 基纖維、聚丙烯系纖維、聚胺酯系纖維等合成纖維爲宜。 於本發明,有以聚對苯二甲酸丙二醇酯纖維構成經紗 及/或緯紗之必要,惟即使與其他纖維交織時亦可。交織 的纖維係可使用聚酯系纖維、聚醯胺系纖維、聚丙烯腈系 纖維、聚丙烯系纖維、聚胺酯系纖維等的合成纖維等。又 ,織物組織,係以平織物最適,惟亦可爲緞紋織物、花紋 織物、多重織物。 交織的方法爲以僅於經紗或緯紗內採用聚對苯二甲酸 丙二醇酯纖維之方法,以聚對苯二甲酸丙二醇酯纖維及其 他纖維將經紗或緯紗以一根交互或二根交互等般湊齊並混 用的方法等可予交織。 本發明之具伸縮性高密度織物,係含有聚對苯二甲酸 丙二醇酯纖維3 5重量%以上爲宜,較宜爲4 0重量%以 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 請 先 閱· 讀 背 面 之 注1222473 A7 B7 V. Description of the Invention (1) Technical Field The present invention relates to a high-density fabric that has good stretchability and water resistance with a soft feel. BACKGROUND ART For a long time, water-repellent processing has been applied to high-density fabrics using polyamide fibers or polyester fibers, and water-resistant fabrics have been known, and they are widely used in duck down jackets. Winter clothing, or windproof cloth, jackets, outerwear, sportswear and other sports clothing or outerwear. However, ordinary high-density fabrics have almost no elongation. Therefore, the movement of the body will be hindered during exercise, and they will feel oppressed, but they will not be able to move freely and feel uncomfortable. Because it is a high-density fabric, it feels harder. Furthermore, water repellency or resin processing to impart water resistance will increase the hardness of the fabric, so it will increase hardness and freedom of movement or body movements. The movements of the fabrics are hindered, and the frictional sound of the fabrics in contact with each other becomes large and uncomfortable. In order to solve these problems, Japanese Unexamined Patent Publication No. 1 1 — 8 1 1 4 1 discloses that weft and / or warp yarns of fabrics use polytrimethylene terephthalate fibers, and resin processing is applied to the fabrics. High-density fabric with soft feel. In Japanese Patent Application Laid-Open No. 11-200174, a poly (trimethylene terephthalate) having a ratio of the coverage of warp yarns and the coverage of weft yarns defined as the sum of the coverage ratios and an elastic recovery rate of more than 90% is disclosed. High-density fabric with soft texture made of fibers. However, the techniques disclosed in these publications are based on the formation of fabrics with soft poly (trimethylene terephthalate) fibers. The feel of the fabric or the friction between the fabrics is based on the Chinese National Standard (CNS) A4 specification (210 X 297). (Mm) I ---- · II • > (Please read the notes on the back before Φ this page) Order · • Line. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-4-2222473 A7 B7 V. Invention Explanation (2) Although the fricative has been improved, the contraction is still insufficient, so the problems that hinder the movement of the body have not been resolved. Also, in Japanese Patent Application Laid-Open No. 9-1 70 1 75, it is proposed to use a plurality of filaments with a fine cross-section of a single yarn fineness of 0.5 denier or less, and use a warp and a weft covering factor. A fabric with improved wind resistance and water resistance when the sum is above 2 2000. However, although such a high-density fabric can obtain good water resistance, it has insufficient elasticity, which hinders the movement of the body. On the other hand, in Japanese Patent Application Laid-Open No. 11-256413, it is proposed to use polytrimethylene terephthalate fibers in the weft of the fabric. By defining the weft index of the weft, it has elasticity in the weft direction and excellent surface smoothness. 4. Excellent lining for preventing slipping performance and reducing pressure feeling of stitches. However, although the stretchability in the weft direction is imparted to this lining, good water resistance cannot be obtained. Disclosure of the invention Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ------- B ----.---- Installation II < Please read the precautions on the back before going to 4 | ^ 4 pages)- -Thread- The present invention aims to provide a high-density fabric with a soft feel and good stretchability and water resistance. In addition, the water resistance in the present invention refers to a property capable of withstanding water pressure (water pressure resistance). In order to solve the above-mentioned problems, the inventors have carefully examined the results, using poly (trimethylene terephthalate) fibers, forming a fabric with a specific cloth coverage factor, and applying special treatment to the fabric, Shrinkage This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 public love) -5- 1222473 A7 ------ _ B7 V. Description of the invention (3), the expansion and contraction of fabrics, fiber recharge, etc. In a specific range, it is found that the purpose of the invention can be achieved, and the invention is completed. That is, the present invention is as follows. 1 · The fabric covering factor is 1800 ~ 2540, the elasticity in the zonal or warp direction is 5 ~ 20%, and the fiber with the direction of at least elasticity is made of poly (trimethylene terephthalate) fiber. Is characterized by a stretchable high-density fabric. 2. The CI 値 (described below) showing the shrinkage index of the fiber with the direction of elasticity is 0. 005 ~ 0. 013, and the DS 下述 (described below) showing the fiber's fullness is 0.5 ~ 1 · 0 is the elastic high-density fabric described above. CI = CR / CFv DS (g / cm3) = Ws / Vs = Ws CVxCFs / (CFs + CFv)] Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ------- ^ ----,- -Packing --- • (Please read the precautions on the back first and then the page) • Threads (However, CR is the shrinkage rate of the fiber with the stretchable direction, and CF v is the positive direction of the fiber with the stretchable direction. Coverage factor of the intersecting fibers, W s is the apparent volume of the fiber in the direction of elasticity per cm2 of fabric (cm3), V is the apparent volume of the fabric per cm2 of fabric (cm3), CFs is elasticity The covering factor of the cloth in the direction of the fiber, 3.) The above-mentioned feature is that the fiber in the stretchable direction is a polytrimethylene terephthalate fiber having a flat single yarn cross section with a flatness of 2 to 6. The elastic high-density fabric according to 1 or 2. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -6-1222473 A7 B7 V. Description of the invention (4) i — — — — — — — — — — — ^ · II (Please Try to read the precautions on the back side first) 4) Perform a dry heat treatment on the fabric at 150 ° ~ 2 0 ° C in a state where the width of the fabric is determined to be 10% to 40%, so that the weft yarn is crimped 'A method for producing a stretchable high-density fabric according to any one of the above 1 to 3, which is characterized by performing fine thread, dyeing, and calendering. The best form adopted by the invention 1 The high-density fabric 'of the present invention is composed of a fiber having a stretchable direction as a polytrimethylene terephthalate fiber. Thread-In the present invention, the polytrimethylene terephthalate fiber refers to a polyester fiber whose main repeating unit is the trimethylene terephthalate unit. The trimethylene terephthalate unit is about 50 mole% or more. It is preferably more than 70 mole%, more preferably more than 80 mole%, and more preferably more than 90 mole%. Therefore, as for the third component, the total amount including the additional acid component and / or diol component is about 50 mol% or less, preferably 30 mol% or less, more preferably 20 mol% or less, more The polytrimethylene terephthalate is preferably contained in a range of 10 mol% or less. The polytrimethylene terephthalate printed by the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is to make terephthalic acid or its functional derivative with trimethylene glycol or its derivative under appropriate reaction conditions in the presence of a catalyst. Sex derivatives combined to be synthesized. In this synthesis process, it is also possible to add one or two or more kinds of appropriate third components and use them as copolymerized polyester. Polytetramethylene terephthalate may be blended with polyesters other than polytrimethylene terephthalate such as polyethylene terephthalate to form a composite yarn (sheath core, side-to-side, etc.). As for the third component to be added, alicyclic dicarboxylic acid (the size of oxalic acid paper is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 1222473 A7 ____ B7 Employee Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs Printed 5. Description of the invention (5, adipic acid, etc.), alicyclic dicarboxylic acids (cyclohexanedicarboxylic acid, etc.), aromatic dicarboxylic acids (isophthalic acid, sodium sulfoisophthalate, etc.) , Aliphatic diols) ethylene glycol 1,2-butanediol, tetramethylene glycol, etc.), alicyclic diols (cyclohexanedimethanol, etc.). Contains aromatic aliphatic diols (1,4-bis (per-hydroxyethoxy) benzene, etc.), polyether diols (polyethylene glycol, polypropylene glycol, etc.), aliphatic oxycarboxylic acids (w — Oxyhexanoic acid, etc.), aromatic oxycarboxylic acids (p-oxybenzoic acid, etc.), etc. Compounds having one or three or more ester-forming functional groups (such as benzoic acid or glycerol) are also polymers that can be used within a substantially linear range. Furthermore, it may contain matting agents such as titanium dioxide, stabilizers such as phosphoric acid, ultraviolet absorbers such as hydroxybenzophenone derivatives, crystallization nucleating agents such as talc, and easy lubricants such as ultra-fine powder silicon dioxide (Aerosil). Antioxidants, flame retardants, antistatic agents, pigments, fluorescent brighteners, infrared absorbers, defoamers, etc. The poly (trimethylene terephthalate) fiber used in the present invention is, for example, directly untwisted at a winding speed of 1 500 m / min, and then twisted by about 2 to 3.5 times. It is obtained by the spin draw method of the spinning-drawing step, and the high-speed spin take up method with a winding speed of more than 500 Om / min. In addition, the morphology of the fiber may be a plurality of filaments, woven filaments, or those having a uniform length or a smaller diameter in the length direction, but a plurality of filaments is more suitable. In addition, as for the form of multiple long-fiber yarns, multiple long-fiber raw yarns (including ultra-fine yarns), loose-twisted yarns ~ strong-twisted yarns, mixed-fiber yarns, and false-twisted yarns (including please read the note on the back first) Matters f bound This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -8- 1222473 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Α7 Β7 V. Description of invention (6) P0Y Stretch false twisted yarn), liquid jet processing yarn, etc., but in order to improve the water resistance, a long filament fiber yarn should be used. At the point of improving the flexibility and soft feel, false twisted yarn is used as should. The fineness of the polytrimethylene terephthalate fiber is sufficient strength when it is made into a fabric. It should be more than 3 3 dte X. To prevent the fabric from becoming thick and stiff, it should be less than 1 6 7 dte X. . The preferred fineness is 5 6 to 1 1 d t e X. The single yarn fineness should be 0 · 1 dte X or more in order to suppress yarn breakage during spinning and improve the stability of spinning. To maintain the water resistance of the fabric and suppress the rough feel, it should be 5 · 6 dt. ex or less. The preferred single yarn fineness is 0 · 56 ~ 3 · 3 dte X 〇 The cross-sectional shape of the polytrimethylene terephthalate fiber can be round, triangular, L, T, Y, W, There are many types, such as eight-leaf type, flat type, and dog-bone type. Those with edge shape, multi-leaf shape, hollow type, or indefinite shape can improve the stretchability, water resistance, and softness of touch of the fabric. It is preferable if the single yarn has a flat cross section. By adopting a flat cross-section yarn, flat single yarns in the fabric are overlapped and filled, which contributes to improvement of water resistance. In both cases, flat cross section yarns have significant bending resistance, so it is easy to buckle yarns orthogonal to flat cross section yarns in fabrics, and the elongation of crimps caused by the buckling of the flat cross section yarns is effective. By using it, the stretchability of the fabric is increased, and at the same time, it becomes a soft-feel fabric. The so-called flat cross-section here refers to the flat cross-section of a single yarn made of W-shaped, I-shaped, V-shaped, M-shaped, dog-bone-shaped, oval-shaped, wave-shaped, and sugar-cucurbit string-shaped. Concave and convex portions forming single yarns overlap each other and are pre-filled. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). -------------- Package --- * % • < Please refer to the note on the back of IKrtt first, then ίφΦ) • Thread · -9-1222473 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy It is more suitable to improve water resistance. In addition, the flatness of the flat cross section yarn is preferably 2 or more in order to obtain stretchability, water resistance, and soft feel, and it is preferable that the spinning stability is 6 or less. The so-called flatness here refers to a rectangle drawn outside the cross-section of a single yarn, and the long side L of this rectangle is divided by the short side Η. In addition, the polytrimethylene terephthalate fiber used in the present invention is interlaced and mixed with fiber (different shrinkage mixed fiber yarn with high shrinkage yarn) within a range that does not impair the purpose of the invention (for example, 60% by weight or less). Etc.), cross-twisting, composite false twisting (elongation difference false twisting, etc.), two-feed yarn air jet processing and other methods can be mixed with other fibers. The mixed fibers may be any type of fibers, polyester fibers, polyamide fibers, polyacrylonitrile fibers, polyethylene fibers, polypropylene fibers, polyurethane fibers, and other synthetic fibers. In the present invention, it is necessary to constitute warp yarns and / or weft yarns with polytrimethylene terephthalate fibers, but it may be interwoven with other fibers. As the interwoven fibers, synthetic fibers such as polyester fibers, polyamide fibers, polyacrylonitrile fibers, polypropylene fibers, and polyurethane fibers can be used. Moreover, the fabric structure is most suitable for plain fabrics, but it can also be satin fabrics, pattern fabrics, and multiple fabrics. The method of interweaving is to use polytrimethylene terephthalate fibers only in the warp or weft yarns, and use polytrimethylene terephthalate fibers and other fibers to combine the warp or weft yarns with one or two interactions. Intermixing methods and the like may be interlaced. The stretchable high-density fabric of the present invention preferably contains more than 35% by weight of polytrimethylene terephthalate fibers, and more preferably 40% by weight. The Chinese National Standard (CNS) A4 specification (210 X 297 mm) Please read · Read the note on the back
II
I裝 頁I 訂 -10 - 1222473 Α7 _ Β7 五、發明說明(8 ) 上,更宜爲5 0重量%以上。藉由聚對苯二甲酸丙二醇酯 纖維之混合率在3 5重量%以上,可作成伸縮性、耐水性 、手感良好者。 本發明之具伸縮性高密度織物,爲得良好的伸縮性、 耐水性及手感,有布面覆蓋係數1 8 0 0以上,2 5 4 0 以下之必要,較宜爲1 9 0 0〜2 3 3 0。 於本發明之高密度織物,織物之布面覆蓋係數,係以 作成較一般的高密度織物之織物布面覆蓋係數低1 0 %以 上者爲宜。其理由係一般的高密度織物係爲使耐水性提高 極力減少紗間之間隙的方向,由織物之階段織成高密度, 進行加工,惟在本發明,先將織物密度設成若千低密度, 利用高收縮處理該織物並對寬度或長度方向進行追加,施 加使相鄰的織紗相互間之間隙的特殊處理,作成高密度織 物所致。... 在此所謂布面覆蓋係數,係以織物之經紗或緯紗在並 排成每2 · 5 C m ( 1英吋)時之根數作爲各自的紗密度 時,係以下式予以給與。 經濟部智慧財產局員工消費合作社印製 --------------裝--- '* •(請先W讀背面之注意事項再頁) •線· 布面覆蓋係數=(經紗之布面覆蓋係數)+ (緯紗之 布面覆蓋係數) =(經紗密度)X (經紗之d t e X )1 / 2 + (緯紗密度)x (緯紗之d t e x ) 1 / 2 布面覆蓋係數在未滿1 8 Ο 0時’較難獲得足夠的耐 水性,若超過2 5 4 0時則較難獲得良好的伸縮性,手感 亦變成粗又硬。且經紗之布面覆蓋係數及緯紗之布面覆蓋 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -11 1222473 A7 —__ B7 五、發明說明(9 ) 係數之比,亦即(經紗之布面覆蓋係數)/(緯紗 覆蓋係數)爲0 · 7〜1 · 7,惟在使耐水性及伸 時成立之點係較宜的。 又,維持加工織物之耐水性,且於織物表面上 生皺紋、褶紋或織紋錯亂等下賦與伸縮性之點,以 布面覆蓋係數在1 6 0 0〜2 3 0 0爲宜。 本發明之高密度織物之特徵,係採用聚對苯二 二醇酯纖維之方向的伸縮率爲5〜2 0%,宜爲7 %。伸縮率未滿5%時,運動時的身體之動作受阻 覺壓迫,未能自由的動作,並不舒服,若超過2 0 則雖然可得足夠的伸長率,但是纖維之屈曲變成過 成纖維表面之粗糙感、厚度之增大、耐水性之降低 並不合適。 且,在此所謂的伸縮率,係採用katotex (股) (LES—FB1 ,在4·9N/cm之應力下伸 之布面 縮性同 由不發 織物之 甲酸丙 〜1 7 礙,感 %時, 大,生 等,故 製造的 長時之 請 先 閱· 讀 背 面 之 注I page I order -10-1222473 Α7 _ Β7 5. In the description of the invention (8), it is more preferably 50% by weight or more. When the mixing ratio of the polytrimethylene terephthalate fiber is 35 weight% or more, it can be made into a material having good stretchability, water resistance, and hand feeling. The stretchable high-density fabric of the present invention has a cloth covering factor of 1 800 or more and 2 5 4 0 or less in order to obtain good stretchability, water resistance, and hand feel, and is preferably 19 0 0 to 2 3 3 0. In the high-density fabric of the present invention, the cover factor of the fabric is preferably one which is 10% or less lower than that of the general high-density fabric. The reason is that general high-density fabrics are oriented in order to improve water resistance and reduce the gap between yarns as much as possible. The fabric is woven into high-density at the stage of the fabric for processing. The high shrinkage treatment of the fabric is performed, and the width or length direction is added, and a special treatment is applied to make the gap between adjacent weaving yarns to make a high-density fabric. ... The so-called cloth cover factor here refers to the number of warp or weft yarns in the fabric side by side each 2 · 5 C m (1 inch) as the respective yarn densities, given by the following formula . Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -------------- install --- '* • (please read the precautions on the back first, and then the page) = (Cover factor of warp yarn cloth) + (cover factor of weft yarn cloth) = (density of warp yarn) X (dte X of warp yarn) 1/2 + (density of weft yarn) x (dtex of weft yarn) 1/2 cloth cover When the coefficient is less than 1 8 0 0, it is difficult to obtain sufficient water resistance, and if it is more than 2 5 4 0, it is difficult to obtain good stretchability, and the feel becomes rough and hard. And the cloth coverage factor of warp and cloth coverage of weft is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -11 1222473 A7 —__ B7 V. Description of the invention (9) The ratio of the coefficient, That is, the (coverage coefficient of the warp yarn) / (coverage coefficient of the weft yarn) is 0 · 7 ~ 1 · 7, but the point that is established when the water resistance and elongation are made is more suitable. In addition, to maintain the water resistance of the processed fabric and to impart elasticity on the surface of the fabric, such as wrinkles, creases, or texture weaves, it is preferable that the cloth surface coverage factor is 16 0 to 2 3 0. The high-density fabric of the present invention is characterized by a stretch ratio of 5 to 20% in the direction of the polyterephthalate fiber, preferably 7%. When the stretch rate is less than 5%, the body's movements during exercise are oppressed by hindrance, and it is not comfortable to move freely. If it exceeds 20, sufficient elongation can be obtained, but the flexion of the fiber becomes too fibrous. Roughness, increased thickness, and reduced water resistance are not suitable. In addition, the so-called expansion and contraction ratio is the use of katotex (strand) (LES-FB1). The shrinkage of the cloth under the stress of 4 · 9N / cm is the same as that caused by non-fabric formic acid. , Big, raw, etc., please read the long-term manufacturing first · read the note on the back
I 裝 頁 訂 伸長率(% )。 經濟部智慧財產局員工消費合作社印製 在本發明,至於賦與伸縮特性之方法,在織物之織造 階段,藉由與聚對苯二甲酸丙二醇酯纖維正交的織紗生成 的聚對苯二甲酸丙二醇酯纖維之微細的屈曲(捲縮),藉 由熱水處理濕熱處理、乾熱處理等的高收縮處理使增大, 由於該捲縮賦與伸縮性者。亦即,該捲縮係藉由增大織物 之織物密度及加工密度間之密度差而得者,將密度已事先 粗略設計的織物藉由經方向或緯方向上高收縮處理予以高 密度化,使於紗本身的收縮以外引起組織之收縮,使顯現 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -12- 1222473 A7 B7 五、發明說明(10) 出對正交的織紗之屈曲(捲縮),且予增大而得者。 --------------裝--- «· (請先♦閲讀背面之注意事項再6本頁) 聚對苯二甲酸丙二醇酯纖維,係與向來的聚酯系纖維 之代表例的聚對苯二甲酸乙二酯纖維或聚對苯二甲酸丁二 酯纖維相比,纖維之楊氏係數較小,故具有非常的折曲柔 軟的特徵,此折曲柔軟度即成爲使組織引起收縮的大要因 。以採用此非常折曲柔軟的聚對苯二甲酸丙二醇酯纖維, 可製造出緯紗對經紗,或經紗對緯紗可充分屈曲的織物, 若實施再使其屈曲形態增大的熱處理加工時,則可得於緯 紗或經紗上附上曲屈曲引起的捲縮之形態的織物,由該捲 縮之伸縮可顯現出較高的伸長率。 此高收縮處理,係爲得足夠的伸縮性,對織物密度設 定成加工密度增大10%以上爲宜。又,織物之皺紋或較 大的織紋錯亂會發生,爲防止品位降低,高收縮處理係對 織物之織物密度設定至加工密度之增大在4 0 %以下爲宜 •線· 〇 經濟部智慧財產局員工消費合作社印製 至於高收縮處理之方法,例如於緯方向上爲賦與伸縮 性,粗略設計經紗密度,將至少於緯紗上採用聚對苯二甲 酸丙二醇酯纖維之織物,在經方向上以拉伸狀態下於精練 前或精練後利用熱處理予以決定寬幅並進行高收縮處理, 賦與伸縮性。 又爲於經方向上賦與伸縮性,例如將至少於經紗上採 用聚對苯二甲酸丙二醇酯纖維之織物,在緯方向上以拉伸 狀態下於精練前或精練後利用熱處理予以追加織物之長度 方向並進行高收縮處理。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -13· 1222473 A7 ____B7 五、發明說明(11 ) --------·!----裝·. (請先M·讀背面之注意事項再填 至於高收縮處理之熱處理條件,在乾熱條件之情形, 採用把持布邊之拉幅機,不把持布邊之輸送帶方式之網狀 物處理…轉鼓處理等裝置進行,惟爲得所期待的伸縮性, 以使用於經方向、緯方向上可控制尺度之針板拉幅機(Pin tenter )方式之乾熱處理機爲宜。又熱處理溫度,爲進行 達成期待的伸縮性而採的足夠的收縮處理,以在1 5 0°C 以上爲宜,爲避免強度降低且手感變成又粗又硬,以在 2 0 0 °C以下爲宜。 --線- 又,在熱水處理之情形,以採用揉搓效果較大的液流 染色機等的裝置爲宜,處理溫度在由進行爲達成所期待的 伸縮性而用的足夠的收縮處理之點以在9 0 °C以上,不需 特殊的裝置且無生產性上問題之點以在1 4 0 °C以下爲宜 。且熱水處理之情形,若直接熱水處理織物或精練後的織 物時,則絲、組織之急劇的高收縮化會發生較大的鈹紋或 褶紋等,在熱水處理前,以事先在1 5 0 °C以下進行較輕 的乾熱預固定較宜。 經濟部智慧財產局員工消費合作社印製 至於爲賦與伸縮性而採之較佳的高收縮處理方法,由 生產性、外觀品位、性能等方面,將於緯紗上採用聚對苯 二甲酸丙二醇酯纖維之織物,利用針板拉幅機型乾熱處理 機,對織物寬幅,以決定寬幅1 0〜4 0 %的狀態下進行 1 5 0〜2 0 0 °C之乾熱處理,使顯現出緯紗捲縮後,進 行精練、染色加工處理爲宜。藉由採用此方法’於緯紗上 採用聚對苯二甲酸丙二醇酯纖維之長纖原紗之情形’亦使 組織大量收縮,可大量顯現出緯紗之捲縮。又於緯紗上採 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -14- 1222473 A7 B7 五、發明說明(14) 之厚度(cm),乘上Ιπί之面積(lOOOOcrri)予 以算出。 表示具有伸縮性之方向的纖維之纖維塡充度之D s値 未滿0 . 5時,伸縮性會變大,惟耐水性變成稍低者,若 超過1 . 0時,耐水性雖然良好,但是卻未能足夠獲得伸 縮性,有手感降低的傾向。爲使D S値設成較宜的範圍, 若將織物之布面覆蓋係數、織物之組織之收縮程度(捲縮 程度),在加工步驟的壓延機條件(壓力、溫度)設成最 適化即可。 在本發明,係高密度織物,同時由歸因於聚對苯二甲 酸丙二醇酯纖維所具的楊氏係數之柔軟度之捲縮賦與效果 ,及適度的布面覆蓋係數,適度的纖維塡充度,具備著所 期待的伸縮性及耐水性,可得柔軟且穿用舒適性優越的織 物。 又,在本發明,藉由對所得的高密度織物進行撥水劑 處理或堵塞網眼加工等的防水加工,能保持前述性能,同 時可得撥水性、耐水性良好的防水性織物。已施加此種加 工之織物,係朝兩衣或運動用防風物等穿用舒適性優越者 ,又防絨毛性(防止禦寒衣料內所塡充的絨毛材料由基材 表面抽出的性能)優越,且兼備良好的通氣性,故用作鴨 絨外套用禦寒衣料之穿用舒適性優越者。 在此所謂穿用舒適性,係對運動時的身體之動作隨著 織物,而身體之動作不受阻礙,無壓迫感,可輕鬆的自由 動作之狀態,及未感覺出織物之堅硬性、織物相互間之摩 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ----!!·*·1 I <請先閱讀背面之注意事項再頁) 訂· --線· 經濟部智慧財產局貝工消费合作社印製 -17- 1222473 A7 B7 經濟部智慧財產局貝工消费合作社印製 五、發明說明(15) 擦音等舒適的穿用感覺。 本發明所得的織物之防水加工方法,係可採用矽系、 氟系、蠟系、鉻鹽系、伸乙基脲系、羥甲基醯胺系、吡陡 鐵鹽系、金屬巷類等,雖非爲特予限定者,惟砂系、氟系 在撥水效果,耐久性方面係優越的,故較合適的。且,前 述撥水劑內,視必要時,添加交聯劑,觸媒,樹脂等亦可 。依此撥水劑之加工法係可利用模壓浸漬絞液,輕觸給液 輕輪等方法予以加工。 又,堵塞網眼加工係藉由噴佈加工該撥水劑處理加工 後之織物,使該織物面成爲平滑,且減少纖維間隙,使耐 水性較提高,同時使手感較柔軟化的效果。 至於此模壓加工法,係於二對輥輪、皮帶、平板等之 間在常溫或高溫下加壓並進行加工,惟由加工性、堵塞網 眼效果、手感之方面等,一側爲金屬性之加熱輥輪,另一 方面爲金屬製、樹脂製等硬質之低溫輥輪,或橡膠、毛毡 等中硬質的低溫輥輪而成的一般壓延機加工機爲宜。 至於模壓條件,在加熱輥輪方面宜爲1 2 0〜2 0 0 °C,較宜爲140〜180 °C,在低溫輥輪方面宜爲 1 2 0°C。加熱輥輪未滿1 2 0°C時,堵塞網眼效果較薄 弱,未能獲得足夠的耐水性,又若超過2 0 0 °C時,則有 變成手感堅硬的紙狀之傾向。另一方面,低溫輥輪若超過 1 2 0 °C時,則有成爲手感堅硬的紙狀之傾向。又,至於 壓力,宜爲線壓9 80〜3 9 20N/cm。線壓力未滿 9 8 ΟΝ/cm時,堵塞網眼效果較小未能獲得足夠的耐 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ---------------裝--- - V • <請先閱讀背面之注意事項再頁) 訂: 線- -18- 1222473I Binding Elongation (%). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs on the present invention, as for the method for imparting elastic properties, in the weaving stage of the fabric, polyterephthalic acid generated by a weaving yarn orthogonal to the polytrimethylene terephthalate fiber The fine buckling (crimping) of the propylene glycol fiber is increased by a high shrinkage treatment such as hot water treatment, wet heat treatment, and dry heat treatment. This shrinkage imparts elasticity. That is, the crimping is obtained by increasing the density difference between the fabric density and the processing density of the fabric, and the fabric whose density has been roughly designed in advance is increased in density by high shrinkage treatment in the warp or weft direction. The shrinkage of the tissue caused by the shrinkage of the yarn itself, and the appearance of this paper are applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) -12- 1222473 A7 B7 V. Description of the invention (10) Orthogonal The warp (crimping) of the weaving yarn is increased and the winner is obtained. -------------- Packing --- «· (Please read the precautions on the back first and then 6 pages) Polytrimethylene terephthalate fiber Compared with polyethylene terephthalate fiber or polybutylene terephthalate fiber, which is a representative example of the fiber, the Young's coefficient of the fiber is smaller, so it has a very flexible and flexible characteristic. That is a major factor that causes tissue to shrink. By using this very flexible and flexible poly (trimethylene terephthalate) fiber, weft-to-warp yarns or warp-to-weft yarns can be fully flexed. If heat treatment is performed to increase the buckling shape, A weft or warp yarn is attached to a fabric in the form of a crimp caused by bending and buckling, and a high elongation can be exhibited by the contraction of the crimp. This high shrinkage treatment is to obtain sufficient stretchability, and it is appropriate to set the fabric density to increase the processing density by more than 10%. In addition, wrinkles or large weaves of the fabric may occur. In order to prevent the grade from falling, it is advisable to set the fabric density of the fabric to an increase in processing density of 40% or less. • Line · 〇Ministry of Economy Printed by the Consumer Cooperative of the Property Bureau for high shrinkage treatment methods, for example, to give elasticity in the weft direction, roughly design the warp yarn density, and use at least the weft yarn with a polytrimethylene terephthalate fiber fabric in the warp direction In the stretched state, the width is determined by heat treatment before or after refining, and a high shrinkage treatment is performed to give stretchability. In order to impart elasticity in the warp direction, for example, at least the fabric using polytrimethylene terephthalate fibers in the warp yarns is stretched in the weft direction before or after refining by heat treatment to add fabric. Longitudinal direction and high shrinkage treatment. This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) -13 · 1222473 A7 ____B7 V. Description of the invention (11) -------- ·! ---- packing ... ( Please read the precautions on the back of the M. Then fill in the heat treatment conditions for high shrinkage treatment. In the case of dry heat conditions, use a tenter that holds the cloth edge, and handle the mesh without a cloth belt. Drum processing and other equipment are performed, but in order to obtain the expected stretchability, a dry heat treatment machine using a pin tenter method that can control the dimensions in the warp and weft directions is suitable. The heat treatment temperature is It is advisable to perform sufficient shrinkage treatment to achieve the desired stretchability at 150 ° C or higher, and to prevent the strength from decreasing and the texture to become thick and hard, it is preferable to be below 200 ° C.- -In the case of hot water treatment, it is advisable to use a device such as a liquid flow dyeing machine with a large kneading effect. The treatment temperature is at a point where sufficient shrinkage treatment is performed to achieve the desired stretchability. Above 90 ° C, no special equipment is required and there is no productivity problem It is preferably below 140 ° C. In the case of hot water treatment, if the fabric or scoured fabric is directly treated with hot water, the sharp high shrinkage of silk and tissue will cause large beryllium patterns or folds. Before hot water treatment, it is better to pre-fix with lighter dry heat below 150 ° C. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, it is better to give flexibility. The high shrinkage treatment method, from the aspects of productivity, appearance quality, performance, etc., will use polytrimethylene terephthalate fiber fabrics on the weft yarns, using a pin plate tenter type dry heat treatment machine, It is decided to perform a dry heat treatment at 150 to 2 0 ° C in a state of a wide width of 10 to 40%, so that it is possible to perform scouring and dyeing processing after the weft yarn appears to be crimped. By using this method, The use of long-fiber raw yarn of polytrimethylene terephthalate fiber on the weft yarns also caused a large amount of shrinkage of the tissue, which can show a large number of weft yarn shrinkages. The paper size adopted on the weft yarns is subject to Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) -1 4- 1222473 A7 B7 V. Description of the invention (14) The thickness (cm) is calculated by multiplying the area of Ιπί (1000crri). The fiber sufficiency of the fiber with the direction of stretchability, D s 値, is less than 0. At 5 o'clock, the stretchability will increase, but the water resistance will be slightly lower. If it exceeds 1.0, although the water resistance is good, the stretchability will not be sufficiently obtained, and the texture will tend to decrease. The more suitable range can be set by optimizing the covering factor of the fabric and the degree of shrinkage (crimping degree) of the structure of the fabric. In the present invention, it is a high-density fabric, and at the same time, it has a curling effect and a softness attributed to the Young's coefficient due to the poly (trimethylene terephthalate) fiber, and a moderate cloth cover factor, and a moderate fiber. Sufficient, with the expected stretchability and water resistance, it is possible to obtain a fabric that is soft and excellent in wearing comfort. Further, in the present invention, the water-repellent treatment such as water-repellent treatment or clogging of the obtained high-density fabric is carried out to maintain the aforementioned properties, and at the same time, a water-repellent fabric having good water repellency and water resistance can be obtained. The fabric to which this process has been applied is superior in wearing comfort such as two coats or sports windshields, and also has a low fuzz resistance (the ability to prevent the fluff material filled in the cold clothing material from being drawn from the surface of the substrate). And it also has good air permeability, so it is used as a warm comforter for duck down jackets. The so-called wearing comfort here refers to the movement of the body with the fabric during exercise, and the movement of the body is not obstructed, there is no sense of pressure, the state of being able to move freely easily, and the stiffness of the fabric and the fabric are not felt. The paper size of each other applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ---- !! · * · 1 I < Please read the precautions on the back before you order) Order ·- Printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -17- 1222473 A7 B7 Printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (15) Comfortable wearing feeling such as fricative. The waterproof processing method of the fabric obtained by the present invention can adopt silicon-based, fluorine-based, wax-based, chromium-based, ethylurea-based, methylolamine-based, pyridinium-based, metal lanes, etc. Although not specifically limited, sand-based and fluorine-based are more suitable in terms of water repellency and durability. Moreover, in the water-repellent agent mentioned above, if necessary, a cross-linking agent, a catalyst, a resin, etc. may be added. The processing method based on this water-repellent agent can be processed by moulding impregnated wrinkle liquid, lightly tapping the liquid wheel, etc. In addition, the clogging mesh processing is an effect of processing the woven fabric processed by the water-repellent agent by spraying to smooth the surface of the woven fabric, reduce fiber gaps, improve water resistance, and soften the feel. As for this molding method, it is pressurized and processed at room temperature or high temperature between two pairs of rollers, belts, flat plates, etc., but it is metallic on one side in terms of processability, clogging effect, and feel. On the other hand, it is suitable to use a general calendering machine made of a hard low-temperature roller such as metal or resin, or a medium-hard hard roller such as rubber or felt. As for the molding conditions, it is preferably 120 to 200 ° C in terms of heating rollers, more preferably 140 to 180 ° C, and 120 ° C in terms of low temperature rollers. When the heating roller is less than 120 ° C, the effect of clogging the mesh is weak, and sufficient water resistance is not obtained. When it exceeds 200 ° C, it tends to become hard and paper-like. On the other hand, when the low-temperature roller exceeds 120 ° C, it tends to become paper-like with a hard feel. As for the pressure, the linear pressure is preferably 9 80 to 3 9 20 N / cm. When the line pressure is less than 9 8 ΝΝ / cm, the effect of clogging the mesh is small, and sufficient resistance is not obtained. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -------- ------- install ----V • < Please read the precautions on the back first and then the page) Order: Thread- -18-1222473
五、發明說明(16) 經濟部智慧財產局員工消费合作社印製 水性’又若超過3 9 2 ON/cm時,則有變成手感堅硬 的紙狀之傾向。 又,在本發明,藉由塗布或層合樹脂於所得的高密度 織物或防水性織物上’加上前述性能,可得具有高耐水性 、透濕性之透濕防水性織物,可得在嚴苛的環境下之運動 衣料等用途之穿用舒適性優越者。 爲得此透濕防水性織物而採的加工方法,係可採用聚 月女醋系聚合物、聚丙錄酸酯系聚合物、聚酿胺系聚合物、 聚酯系聚合物、聚氯乙烯系聚合物、聚氟碳系聚合物等, 惟由手感方面以採用聚胺酯系聚合物爲宜。至於被膜構造 亦可使用微多孔質被膜,無孔質被膜之任一者。 無孔質被膜係於上述聚合物由使用具有一 S〇3H、 —S〇3M(M表示鹼金屬或一 NH4)、一 COOM、一 C〇〇H、 一NH2、 一 CN、 一 〇H、 一 NHCONH2 等親水基之聚合物即可。將此種含有親水基之聚合物利用 乾式凝固方式使形成被膜時,由此親水性可得透濕性且因 係無孔質被膜可得高耐水性之織物。 又爲使形成微多孔質被膜作爲聚合物被膜,以於聚合 物內添加發泡劑使於凝固後發泡的方法,於聚合物內添加 微粒子並於凝固後溶解萃取微粒子之方法,及以已溶解聚 合物之聚合物溶液形成被膜後,萃取溶劑(以水等取代) 使形成微多孔質被膜之濕式凝固方法等,惟由膜,微多孔 之均勻性、安定性等方面,以濕式凝固方法爲宜。 樹脂之塗布方法,並未予特別限定,惟一般採用浮刀 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) <請先閱讀背面之注意事項再β本頁) -裝 il· -線- -19- 1222473V. Description of the invention (16) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs When the water-based value exceeds 3 92 2 ON / cm, it tends to become hard and paper-like. Furthermore, in the present invention, by coating or laminating a resin on the obtained high-density fabric or waterproof fabric, the aforementioned properties are added to obtain a moisture-permeable and waterproof fabric having high water resistance and moisture permeability. Excellent wearing comfort for sports clothing and other applications in harsh environments. The processing method adopted to obtain this moisture-permeable and waterproof fabric can be poly-vinyl vinegar-based polymer, polyacrylic acid ester-based polymer, polyamine-based polymer, polyester-based polymer, and polyvinyl chloride-based. Polymers, polyfluorocarbon-based polymers, and the like are preferably polyurethane-based polymers in terms of feel. As for the film structure, either a microporous film or a non-porous film can be used. The non-porous coating is based on the above-mentioned polymer by using a polymer having a SO3H, -SO3M (M represents an alkali metal or a NH4), a COOM, a COH, a NH2, a CN, a 0H, A polymer of hydrophilic group such as NHCONH2 is sufficient. When such a polymer containing a hydrophilic group is formed into a film by a dry coagulation method, a hydrophilic fabric can obtain moisture permeability and a non-porous film can obtain a highly water-resistant fabric. In order to form a microporous film as a polymer film, a method of adding a foaming agent to the polymer to cause foaming after solidification, a method of adding fine particles to the polymer, and dissolving and extracting the fine particles after solidification, and After the polymer solution that dissolves the polymer is formed into a membrane, the solvent is extracted (replaced with water, etc.) to form a microporous membrane by a wet coagulation method. However, the membrane, microporous uniformity, stability, etc. A coagulation method is suitable. The coating method of the resin is not particularly limited, but the size of the paper is generally applied to the Chinese national standard (CNS) A4 specification (210 X 297 mm) < Please read the precautions on the back before β page)- Loading il · -line- -19- 1222473
五、發明說明(17) ---— — — — — — — — I!裝 i — 梦 . (請先閲讀背面之注意事項再I本頁) 利塗器、刀片輥輪上頭塗佈器、反轉輥輪塗布器輥輪刮刀 塗布器、凹版輥輪塗布器、輕觸給液輥輪塗布器、夾子輥 輪塗布器等可予塗佈。 又樹脂之層合方法,例如採用前述樹脂之薄膜(膜) ’事先與已塗布於織物之接著劑貼合並予加熱接著的方法 〇 使織物及薄膜接著而用的接著劑,可使用聚胺酯系聚 合物,聚丙烯酸酯系聚合物、聚醯胺系聚合物、聚酯系聚 合物、聚氯乙烯系聚合物、聚醋酸乙烯酯系聚合物等,惟 宜爲聚胺酯系聚合物、聚醯胺系聚合物、聚酯系聚合物即 可〇 接著劑之塗布方法,並未予特別限定者,惟一般採用 浮刀刮塗器、刀片輥輪上頭塗佈器、反轉輥輪塗布器、輥 輪利刀塗布器、凹版輥輪塗布器、輕觸給液輥輪塗布器、 夾子輥輪塗布器等可塗佈於織物全面的全面接著法,或點 狀或線狀的部分塗布的部分接著法等可適宜使用。 經濟部智慧財產局員工消费合作社印製 且前述塗布、層合之膜厚,由手感之面宜爲5〜20 //m,膜厚未滿5 //m時,較難有均勻的膜厚,且未能獲 得足夠的耐水性之情形。又,若超過2 0 // m時,則膜厚 過大且有手感變硬的傾向。 如上述,本發明之織物,係高密度織物,藉由同時歸 因於聚對苯二甲酸丙二醇酯纖維所具約低楊氏係數之柔軟 度引起的捲縮之賦與效果,與適度的布面覆蓋係數、適度 的纖維塡充度,具備良好的伸縮性及耐水性,柔軟且穿用 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -20· 1222473 Α7 _____Β7 經濟部智慧財產局員工消費合作社印製 五、發明說明(18) 舒適性優越的織物。 以下利用實施例再具體的說明本發明,惟本發明並非 受此等所限定者。 且,織物特性之測定方法,評估方法係如下述,測定 及評估結果示於表1。 (1)伸縮率(%) 採用Katotex (股)製造的KES - FBI ,將20 cmx2〇cm之織物在拉伸速度〇 · 2mm/s e c伸 長於織物之具有伸長性的方向上,在4·9N/cm之應 力下將已伸長的長度設爲A ( cm)時,依下式求得的伸 長率(%)設爲伸縮率(%)。 伸長率(%)=(A/20)X100 (2 )手感 將織物之柔軟感依官能檢查,以◎:非常良好,〇: 良好,△約略低劣,X :非常低劣之4階段予以評估。 (3 )摩擦音 將行走1 0分鐘時之織物相互間之摩擦音,利用官會g 檢查,以◎:摩擦音少且良好,〇:稍有摩擦音,但良好 ,△:摩擦音稍大而低劣,X :摩擦音大且非常低劣的四 階段予以評估。 (4)通氣度(c c/crri/s e c) 依J I S L 1 0 9 6 ( A )法予以測定。 (5 )防絨毛性 Γ---:------ 請t閱讀背面之注意事項再頁) ί 言 Γ 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) • 21 - 經濟部智慧財產局員工消费合作社印製 1222473 A7 —_ B7 五、發明說明(19) 將1 7 cmx 1 7 cm之試料疊合二片,以1 cm之 縫邊縫成3邊,於其中插入鴨絨1 2 g後,對殘有的另一 邊予以縫合,製成小型棉被。將此小型棉被放入2 0 c m X 2 0 cm之聚乙烯袋內,密閉至不使空氣進入,於 I C I起毛球測試器(peeling tester )之箱盒內放入小型 棉被及下述所示的規定球,以下述條件令箱盒旋轉後,測 定已貫穿試料之鴨絨的根數。 球:(大)軟式棒球 61mm0x2個 (小)高爾夫球 4 2 η η 0 X 2個 (6 )耐水壓(k P a ) 依J I S L 1 Ο 9 2 ( A法)予以測定。 〔製造例〕 已使用於實施例,比較例的聚對苯二甲酸丙二醇酯纖 維係依下述方式予以製造。 採用7? s p/c = 0 · 8之聚對苯二甲酸丙二醇酯, 以抽絲溫度2 6 5 °C,抽絲速度1 2 0 0 m /分鐘而得未 拉伸絲,其次以熱輥輪溫度6 0 °C,熱板溫度1 4 0 °C, 拉伸倍率3倍,拉伸速度8 0 Om/分鐘拉撚,而得5 6 d t e X 3 6條長纖之圓型截面的拉伸紗。拉伸紗之強 度,伸長率各爲2 · 8cN/d t ex,46%。 同法而得56d t ex 30條長纖之W型截面(扁 平度3 )之拉伸絲。 且7? s p/c係於9 0°C溶解聚合物於鄰一氯酚內或 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --------:111!1·裝 i — (請t閱讀背面之注意事項再) 訂· -線* •22 1222473 A7V. Description of the invention (17) ----- — — — — — — — I! Install i — Dream. (Please read the notes on the back before I page) Sharp applicator, blade applicator , Reverse roll coater Roller blade coater, gravure roll coater, light-feed liquid roll coater, clip roll coater, etc. can be applied. As a method for laminating resins, for example, the aforementioned film (film) of the resin is used. “A method of pasting together with an adhesive that has been applied to fabrics and pre-heating them together. 〇 Adhesives used to bond fabrics and films can be polymerized with polyurethane. Materials, polyacrylate-based polymers, polyamide-based polymers, polyester-based polymers, polyvinyl chloride-based polymers, polyvinyl acetate-based polymers, etc., but preferably polyurethane-based polymers, polyamide-based polymers Polymers and polyester polymers can be used. The method of coating the adhesive is not particularly limited, but generally a floating knife blade coater, a blade roll top coater, a reverse roll coater, and a roll are generally used. Knife applicator, gravure roller applicator, light-feeding roller applicator, clip roller applicator, etc. can be applied to the entire surface of the fabric in a comprehensive way, or spot or linear part of the part can be applied. The method can be suitably used. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and the film thickness of the aforementioned coating and lamination should be 5 ~ 20 // m from the feel surface. When the film thickness is less than 5 // m, it is difficult to have a uniform film thickness. And fail to obtain sufficient water resistance. When it exceeds 2 0 // m, the film thickness becomes too large and the texture tends to become hard. As described above, the fabric of the present invention is a high-density fabric, and the effect of curling due to the softness of the low Young's coefficient of polytrimethylene terephthalate fiber is at the same time. Surface coverage factor, moderate fiber filling, good elasticity and water resistance, soft and wearable This paper is compliant with China National Standard (CNS) A4 (210 X 297 mm) -20 · 1222473 Α7 _____ Β7 Economy Printed by the Consumer Cooperatives of the Ministry of Intellectual Property Bureau V. Invention Description (18) Fabrics with superior comfort. Hereinafter, the present invention will be described in more detail using examples, but the present invention is not limited thereto. The measurement method and evaluation method of the fabric properties are as follows. Table 1 shows the measurement and evaluation results. (1) Stretch ratio (%) KES-FBI made by Katotex (strand) was used to stretch a 20 cmx20 cm fabric at a tensile speed of 0.2 mm / sec in the direction of the fabric's elongation at 4 · 9N When the stretched length is set to A (cm) under a stress of / cm, the elongation (%) obtained by the following formula is set to the expansion and contraction (%). Elongation (%) = (A / 20) X100 (2) Feelings The softness of the fabric was checked by function, and ◎: Very good, :: Good, △ was slightly inferior, and X: Very inferior was evaluated in 4 stages. (3) The friction sound will be the friction sound between the fabrics when walking for 10 minutes. Check with the official meeting g to indicate that ◎: the friction sound is small and good, 〇: there is a slight friction sound, but good, △: the friction sound is slightly large and inferior, X: Four stages with high fricative sounds were evaluated. (4) Ventilation (c c / crri / s e c) was measured according to the method of J I S L 1 0 9 (A). (5) Anti-fluff properties Γ ---: ------ Please read the notes on the back page again) ί Γ This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) • 21-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1222473 A7 —_ B7 V. Description of the invention (19) Laminate a sample of 17 cm x 17 cm in two pieces and sew 3 sides with a 1 cm seam. After inserting 12 g of duck down, the remaining side was sutured to make a small quilt. Put this small quilt in a polyethylene bag of 20 cm x 20 cm and keep it tightly closed to prevent air from entering. Put a small quilt in the box of the ICI fluffing tester and the following The prescribed ball shown below was used to rotate the box under the following conditions, and then the number of duck feathers passing through the sample was measured. Ball: (large) soft baseball 61mm0x2 (small) golf balls 4 2 η η 0 X 2 (6) Water pressure resistance (k P a) Measured in accordance with J I S L 1 0 9 2 (A method). [Production Example] Polytrimethylene terephthalate fibers used in Examples and Comparative Examples were produced in the following manner. Using 7? Sp / c = 0 · 8 polytrimethylene terephthalate, undrawn yarn was obtained at a drawing temperature of 2 65 ° C and a drawing speed of 12 0 0 m / min, followed by a heat roller The wheel temperature is 60 ° C, the hot plate temperature is 140 ° C, the draw ratio is 3 times, and the draw speed is 80 Om / min. Twisting is performed to obtain 5 6 dte X 3 6 filaments with a round cross-section. Stretch yarn. Tensile yarn strength and elongation were each 2 · 8cN / d t ex, 46%. In the same way, 56 d ex 30 filaments with W-shaped cross section (flatness 3) were obtained. And 7? Sp / c is dissolved at 90 ° C in o-chlorophenol or the paper size applies Chinese National Standard (CNS) A4 (210 X 297 mm) --------: 111! 1 · install i — (Please read the precautions on the back again) Order · -line * • 22 1222473 A7
五、發明說明(20) 1 g/d L之濃度’將所得的溶液移入奧斯特華德黏度管 內並在3 5 °C測定,依下式算出。 ---------.---I!裝--- (請先M讀背面之注意事項再填頁) 7?sp/c =〔(丁/TO) - l〕/c 式內,T爲試料溶液之落下時間(秒),τ 〇爲溶劑 之落下時間(秒),c爲溶液濃度(g / d L )。 〔實施例1〕 線- 以56dt ex 36條長纖之圓型截面之聚對苯二 甲酸丙二醇酯纖維爲經紗、緯紗,而得各自的編織密度爲 120條/2·54cm, 120條/2·54cm之平 織之織物。採用針板拉幅機型之乾熱處理機,以經方向爲 拉伸狀態下以決定寬幅率20%,在200 °C,對該織物 進行3 0秒鐘之熱處理。 經濟部智慧財產局員工消費合作社印製 此時之決定寬幅率(% )係以〔{(織物寬度)一( 決定寬幅時之設定寬度)}/ (織物寬度)〕X100予 以算出。 其次,以連續精線機洗除糊料,在1 2 0 °C進行循環 器染色並乾燥後,以下述條件進行撥水加工、軋光加工。 所得的織物,係有伸縮性、柔軟且耐水性亦良好的織 物。 (撥水加工條件) 浸漬於Asahiguard L S - 3 1 7 (旭玻璃(股)製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -23- 1222473 A7 B7 五、發明說明(27) 產業上之可利用# 本發明之織物,因係經予賦與伸縮性及耐水性者,手 感柔軟,由織物相互間之接觸引起的摩擦音可予降低、耐 絨毛性良好的高密度織物。因此較合適使用於防風衣料、 茄克衫、雨衣、鴨絨外套等禦寒衣料,又運動衣料或外衣 衣料等,顯示出良好的穿用舒適性。 ----— 11*1— — !·裝 i I •(請ib閱讀背面之注意事項再ϋΐφφ頁) 1:0- ί線· 經濟部智慧財產局員工消费合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -30-V. Description of the invention (20) Concentration of 1 g / d L ′ The obtained solution was transferred into an Osterwalder viscosity tube and measured at 35 ° C, and calculated according to the following formula. ---------.--- I! Equipment --- (please read the precautions on the back before filling in the page) 7? Sp / c = 〔(丁 / TO)-l〕 / c Here, T is the falling time (seconds) of the sample solution, τ 0 is the falling time (seconds) of the solvent, and c is the solution concentration (g / d L). [Example 1] Thread-Polyethylene terephthalate fibers with a circular cross section of 56 dt ex 36 long fibers were used as warp and weft yarns to obtain respective knitting densities of 120 / 2.54cm and 120/2 · 54cm plain woven fabric. A dry heat treatment machine using a pin-plate tentering model was used to heat-treat the fabric for 30 seconds at a temperature of 200 ° C with a width ratio of 20% determined in the stretched state in the warp direction. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The determined width ratio (%) at this time is calculated by [{(fabric width) one (set width when deciding on width)} / (fabric width)] X100. Next, the paste was washed with a continuous fine thread machine, circulated with dye at 120 ° C and dried, and then water-repellent and calendered under the following conditions. The obtained woven fabric was a woven fabric which was stretchable, soft, and good in water resistance. (Water-repellent processing conditions) Immersion in Asahiguard LS-3 1 7 (The paper standard of Asahi Glass (stock) applies to Chinese National Standard (CNS) A4 (210 X 297 mm) -23- 1222473 A7 B7 V. Description of the invention ( 27) Available in the industry # The fabric of the present invention is a high-density fabric with a good softness and a soft touch due to its elasticity and water resistance. The frictional sound caused by the contact between the fabrics can be reduced. Therefore, it is more suitable for use in windproof clothing, jackets, raincoats, duck down jackets and other winter clothing, and sports clothing or outer clothing, etc., which shows good wearing comfort. ----— 11 * 1— —! · Outfit i I • (Please read the precautions on the back page, ϋΐφφ page) 1: 0- ί Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs This paper is printed in accordance with China National Standard (CNS) A4 (210 X 297 mm) ) -30-
申請曰期 89 年 7 月 27曰 案 號 89115026 A4 C4 類 1>吓 (以上各欄由本局填註)Application date July 27, 89 Case No. 89115026 A4 C4 Class 1 > Scared (The above columns are filled by this Office)
姓 名 國 籍 雄彦之 秀郁滿 永森本 池福山 (1)(2)(3) (1)曰本 (2)曰本 (3) 日本Surname First Name Nationality Takahiko Hideaki Mannaka Eimoto Hon Ichifukuyama (1) (2) (3) (1) Japanese (2) Japanese (3) Japan
裝 發明 創作 人 住、居所 姓名 (名稱) (1)日本國京都府京都市伏見區葭島金井戶町一七 一二克斯摩伏見一一〇號 0 日本國大阪府高槻市奧天神町三一二一七 (3)日本國石川縣金澤市新保本一丁目一三五一番 地花神別墅I一〇二號室 (1)旭化成股份有限公司 旭化成株式会社 訂 線 人 請 t-_^_ 經濟部智慧时產均㈣工消費合作社印製 國 籍 住、居所 (事務所) 代表人 姓名 (1)曰本 (1)日本國大阪府大阪市北區堂島浜一丁目二番六 m (1)山本一元 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 1222473 經濟部智慧財產局員工消費合作社印製 B7 91. ?. 26'五、發明説明()2 用聚對苯二甲酸丙二醇酯纖維之假撚紗時,亦抑制假撚紗 之過度捲縮顯現引起的摺紋之發生,可使顯現出由組織之 收縮引起的良好的緯紗捲縮。且利用上述的處理方法,使 伸縮性之管理亦成爲容易。 又,於本發明,精練係爲去除附著於織製後的織物上 的抽絲油或經紗糊劑等而用的步驟,至於此精練所用的處 理液,以含有水或界面活性劑與鹼之水溶液爲宜。進行該 精練之方法,並未予特別限定者,惟在織物之精練方面以 採用一般常用的平幅皂洗機型連續精練機、液流型染色機 、液中鬆垂型連續精練機、繩狀染色機、軟式精練機等在 1 0 0 °c以下處理爲宜。 進行熱處理及精練後,進行一般的加工步驟之染色、 加工等步驟。爲將手感作成較柔軟時,在染色前進行鹼減 量加工亦可。 於本發明,表示具有伸縮性之方向的纖維之捲縮指數 之c I値,爲得足夠的伸縮性,必須在0 · 0 0 5以上, 爲抑制織物表面成爲粗糙且手感粗澀、摩擦音較大者,必 須設在0 . 0 1 3以下。 捲縮指數係將具有伸縮性之方向的纖維之捲縮率( C R )爲與該纖維正交的纖維之布面覆蓋係數(C F v ) 所除而算出的値。捲縮率之測定方法爲於織物(加工織物 )之具有伸縮性之方向上註上2 0 c m之標記後,分解織 物並取出的具有伸縮性之方向的纖維上施加〇 · 〇 9 g / d t e X之負載,測定該時之記號間之長度L ( c m ), 本紙張尺度適用中國國家標準(CNS ) A4規格(21〇X297公釐) (請先閲讀背面之注意事項再填寫本頁) -15- 1222473 經濟部智慧財產局員工消費合作社印製 A7 B7 9L 7. 2g______ 五、發明説明(0 依下式算出的値。 捲縮率(%)二{ (L — 20)/20 jxl〇〇 再者,在本發明,以表示具有使捲縮顯現的具有伸縮 性之方向之纖維的纖維塡充度之D S値必須爲0 · 5〜 1 · 0。若將捲縮指數設成前述範圍內時,則可得良好的 伸縮性,惟爲使伸縮性及耐水性之兩者成爲優越者,使纖 維塡充度成爲重要。表示該纖維塡充度之D S値,係將每 1 ηΐ織物之具有伸縮性的方向之纖維之質量W s ( g )爲 每1 m2織物之具有伸縮性的方向之纖維之表觀體積V s ( c m 3 )所除而算出的値,意指具有伸縮性之方向之具有捲 縮之纖維的織物中的表觀密度(塡充度)者。此際,V s (c m 3 )係將每1 c m2織物之表觀體積設成V ( c m 3 ) 具有伸縮性之方向之纖維之布面覆蓋係數設爲C F s ,與 具有伸縮性之方向之纖維正交的纖維之布面覆蓋係數設爲 C F v時,依下式算出者。 Vs-{VxCFs/(CFs+CFv) } 且,每1. c rri織物之具有伸縮性之方向的纖維之質量 W s ( g ),係將1 〇 c m見方的織物分解,測定出具有 伸縮性之方向的纖維之質量並予算出,又,織物之表觀體 積V ( c m 3 )係對以〇 . 5 g / c m2之負載所測定的織物 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁) -16- 1222473 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(会1 ·) 6重量%,Sumitex resin M-3 (住友化學(股)製造) 0 . 0 3重量%,異丙醇3重量%之配合之水分散液後’ 用橡膠輥輪絞液,在1 6 0 °C進行1分鐘熱處理。 (壓延機加工條件) 上輥輪·· 1 4 0 °C之金屬輥輪、下輥輪:8 0 °C之樹 脂製輥輪、線壓2 4 5 0 N/ c m進行。 〔比較例5〕 以5 6 d t e X 3 6條長纖之圓型截面之聚對苯二 甲酸乙二醇酯纖維爲經紗、緯紗,而得各自的編織密度爲 1 9 〇條/ 2 · 5 4 c m,1 4 0 條/ 2 . 5 4 c m 之平 織之織物。對該織物進行鬆弛精練,以1 3 0 °C進行循環 器染色並乾燥後,與實施例1進行相同的撥水加工、乳光 機加工(惟金屬輥輪溫度1 8 0 °C )。 所得的織物,係無伸縮性,手感粗硬的織物。 〔比較例6〕 以5 6 d t e X 3 6條長纖之圓型截面之聚對苯二 甲酸丙二醇酯纖維爲經紗、緯紗,而得各自的編織密度爲 1 9 0 條/ 2 . 5 4 c m,1 4 0 條/ 2 . 5 4 c m 之平 織之織物。對該織物進行鬆弛精練,以1 3 0 °C進行循環 器染色並乾燥後,與比較例5進行相同的條件進行撥水加 工、壓延機加工。 所得的織物,係無伸縮性、手感粗硬的織物。 I.:--------- (請先閲讀背面之注意事項再填寫本頁)Name (name) of the person who created the invention and residence (1) No. 1712, Kumidoto, Toshima, Fushimi-ku, Kyoto, Kyoto, Japan 0 No. 110, Fushimi-machi, Takahata-shi, Osaka Prefecture, Japan One hundred and twenty seven (3) Room I 102, New Preservation, one-chome, one-three-five, and one-five-five-year-old Villa God Kanazawa, Kanazawa, Ishikawa Prefecture, Japan Printed by the Ministry of Wisdom, Real Estate and Consumer Goods Cooperatives Nationality Residence and Residence (Office) Name of Representative (1) Japanese Version (1) Dojima-jima, Dojima, Kita-ku, Osaka-ku, Osaka Prefecture, Japan (1) Yoshimoto Yamamoto This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 1222473 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs B7 91.?. 26 'V. Description of the invention (2) Polytrimethylene terephthalate The false twisting of the fiber also suppresses the occurrence of creases caused by the excessive shrinkage of the false twisted yarn, which makes it possible to show a good weft curling caused by the shrinkage of the structure. In addition, the above-mentioned processing method makes it easy to manage scalability. Moreover, in the present invention, the scouring is a step for removing the spinning oil or warp yarn paste and the like attached to the woven fabric. As for the processing liquid used for this scouring, it contains water or a surfactant and alkali. An aqueous solution is preferred. The method for carrying out this scouring is not particularly limited, but in terms of fabric scouring, a commonly used open-type soaping machine type continuous scouring machine, liquid flow type dyeing machine, liquid sag type continuous scouring machine, rope It is better to treat the dyeing machine and soft scouring machine below 100 ° C. After the heat treatment and scouring, the dyeing and processing steps of the general processing steps are performed. In order to make the texture softer, alkali reduction processing may be performed before dyeing. In the present invention, c I 値, which indicates the shrinkage index of a fiber having a stretchable direction, must be greater than 0 · 0 0 5 in order to have sufficient stretchability. In order to prevent the surface of the fabric from becoming rough and rough, the friction sound is relatively low. The larger one must be set below 0. 1 13. The crimp index is a value calculated by dividing the crimp ratio (C R) of a fiber having a stretchable direction by the cloth coverage factor (C F v) of a fiber orthogonal to the fiber. The method of measuring the shrinkage rate is to place a 20 cm mark on the stretchable direction of the fabric (processed fabric), and then disassemble the fabric and take out the stretchable fiber in the direction of 0.9 g / dte. The load of X is to measure the length L (cm) between the marks at that time. The size of this paper applies the Chinese National Standard (CNS) A4 specification (21 × 297 mm) (Please read the precautions on the back before filling this page)- 15- 1222473 Printed by A7 B7 9L 7.2g ______ of Consumer Cooperatives of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of invention (0 値 calculated according to the following formula. Crinkling rate (%) 2 {(L — 20) / 20 jxl〇〇 In addition, in the present invention, the DS of the fiber 塡 adequacy of the fiber having the direction of elasticity which makes the shrinkage appear must be 0 · 5 ~ 1 · 0. If the shrinkage index is set within the foregoing range In this case, good stretchability can be obtained, but in order to make both the stretchability and water resistance superior, and the fiber sufficiency is important. DS 値, which represents the fiber sufficiency, is calculated per 1 ηΐ of the fabric. The mass W s (g) of the fibers in the stretchable direction is M 算出 calculated by dividing the apparent volume V s (cm 3) of fibers in a stretchable direction in a fabric, which means the apparent density in a stretchable fabric with crimped fibers (塡At this time, V s (cm 3) is set as the apparent volume of each 1 c m2 fabric is V (cm 3). The covering factor of the fabric in the direction of elasticity is CF s, and When the coverage factor of the fibers with the stretchable fibers orthogonal to the cloth is set to CF v, it is calculated according to the following formula: Vs- {VxCFs / (CFs + CFv)} And each 1. c rri fabric has stretch The mass W s (g) of the fibers in the direction of sex is to decompose a 10 cm square fabric, and the mass of the fibers in the stretchable direction is measured and calculated, and the apparent volume of the fabric V (cm 3) For the fabric measured with a load of 0.5 g / c m2, the paper size applies the Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) -16- 1222473 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (Meeting 1 ·) 6% by weight, Sumitex resin M-3 (manufactured by Sumitomo Chemical Co., Ltd.) 0.3% by weight and 3% by weight of isopropyl alcohol in a water dispersion solution, using a rubber roller wringer, at 1 60 ° C for 1 minute Heat treatment (Calenching machine processing conditions) Upper rollers · Metal rollers at 140 ° C, lower rollers: resin rollers at 80 ° C, linear pressing 2 4 5 0 N / cm. [Comparative Example 5] Using 5 6 dte X 3 6 long-fiber round-shaped polyethylene terephthalate fibers as warp and weft yarns, the respective knitting densities were 190/2 · 5 4 cm, 1 40 pieces / 2.5 4 cm plain woven fabric. This fabric was subjected to relaxation and scouring, and then dyed with a circulator at 130 ° C and dried. Then, the same water repellent processing and opalescent machining were performed as in Example 1 (but the temperature of the metal roller was 180 ° C). The obtained fabric was a fabric having no stretchability and a rough feel. [Comparative Example 6] Using 5 6 dte X 3 6 long-fiber round cross-section polytrimethylene terephthalate fibers as warp and weft yarns, the respective knitting densities were 190 / 2.5 4 cm , 140 pieces / 2.5 4 cm flat woven fabric. This fabric was subjected to relaxation and scouring, and then subjected to circulatory dyeing at 130 ° C and dried, and then subjected to water repellent processing and calendering under the same conditions as in Comparative Example 5. The obtained woven fabric was a non-stretchable woven fabric having a rough feel. I .: --------- (Please read the notes on the back before filling this page)
、1T 秦丨 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -24- 1222473 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(妇 〔實施例2、3,比較例1、7、8〕 除實施例1之經密度變更爲8 6條/ 2 · 5 4 c m ( 比較例7 )、1 〇 〇條/ 2 . 5 4 c m (實施例2 )、 1 4 8 條/ 2 · 5 4 c m (實施例 3 )、1 7 2 條/ 2 . 5 4 c m (比較例 1 )、1 9 5 條/ 2 , 5 4 c m ( 比較例8 )外,餘以與實施例1同法而得織物(緯密度相 同)。 將此等織物,均以決定寬幅率2 0 %與實施例1同法 進行熱處理,製作布面覆蓋係數不同的織物,與實施例1 同樣的進行處理、加工。 所得的織物係如下所示。本發明之範圍內的實施例2 、3之織物係具伸縮性、柔軟且耐水性亦良好,惟比較例 7之織物係耐水性低,比較例1、8之織物係伸縮性低、 再者比較例8之織物之手感亦粗硬。 〔實施例4〜6〕 使用實施例2所得的織物,除熱處理時之決定寬幅率 變化爲3 5 % (.實施例4 ) ,4 0 % (實施例5 ) ,4 5 % (實施例6 )外,餘與實施例2進行相同的處理,加工 而得織物。 所得的織物係如下述般。本發明之範圍內的實施例4 、5之織物係具有伸縮性、柔軟且耐水性亦良好。又實施 例6之織物係耐水性良好’惟織物表面稍微褶紋、有織紋 (請先閲讀背面之注意事項再填寫本頁} 本紙張尺度適用中國國家標準(CNS ) A4規格(210X29?公釐) -25- 1222473 經濟部智慧財產局員工消費合作社印製 A7 Β7 9L 7. 28五、發明説明(妇 錯亂發生,與實施例4、5之織物相比,品位上或若干低 劣者。 〔實施例7〕 以56d t ex 36條長纖之圓型截面之聚對苯二 甲酸丙二醇酯纖維之假撚紗(假撚條件如下示)爲經紗、 緯紗,而得各自的編織密度爲1 1 3條/ 2 . 5 4 c m, 1 1 3條/ 2 . 5 4 c m之平織織物。該織物與實施例1 同法進行處理、加工。 所得的織物,係具伸縮性,柔軟且耐水性亦良好的織 物。 (假撚加工條件) 假撚機:夾子皮帶(nip belt)方式假撚機,‘絲速: 3 0 0 m / m i η, DR·· 1 .020,〇F2:+4.70%,TA: 1 1 ◦度, HI : 160t:,H2: 160〇C 〔實施例8〕 於經紗採用5 6 d t e x 3 6條長纖之圓型截面之 聚對苯二甲酸丙二醇酯纖維,於緯紗採用5 6 d t e x 3 6條長纖之圓型截面之聚對苯二甲酸丙二醇酯纖維,使 手流體噴射加工紗(液體噴射加工條件示於下述),而得 各自的織物密度爲1 1 0條/ 2 . 5 4 c m,1 1 〇條/ 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) -26- 1222473 A7 9L 7. 26 Β7 五、發明説明(心 2 · 5 4 c m之平織織物。此織物與實施例1同法進行處 理、加工。 (請先閲讀背面之注意事項再填寫本頁) 所得的織物,係具伸縮性、柔軟且耐水性亦良好的織 物, (流體噴射加工條件) 加工機:空氣加工機,紗速:3 0 0 m/m i η, 空氣壓力:735kPa,超喂率:15%,、 1T Qin 丨 This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) -24-1222473 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of invention (women [Examples 2, 3, Comparative Examples 1, 7, and 8] Except for Example 1, the warp density was changed to 86 lines / 2.54cm (Comparative Example 7), 100 lines / 2.54cm (Example 2), 1 4 8 bars / 2 · 5 4 cm (Example 3), 172 bars / 2.5 4 cm (Comparative Example 1), 195 bars / 2, 5 4 cm (Comparative Example 8), and the rest The fabric of Example 1 was obtained in the same way (with the same weft density). These fabrics were all heat-treated in the same manner as in Example 1 to determine the width ratio of 20%, and fabrics with different cloth coverage factors were produced. The same treatment and processing are performed. The obtained fabric is shown below. The fabrics of Examples 2 and 3 within the scope of the present invention are stretchable, soft, and have good water resistance, but the fabric of Comparative Example 7 has low water resistance. The fabrics of Comparative Examples 1 and 8 have low stretchability, and the texture of the fabric of Comparative Example 8 is also rough. [Examples 4 to 6] The obtained fabric was the same as in Example 2 except that the determined width change during heat treatment was 35% (. Example 4), 40% (Example 5), and 45% (Example 6). The obtained fabrics are as follows. The fabrics of Examples 4 and 5 within the scope of the present invention have elasticity, softness, and good water resistance. The fabric of Example 6 is water-resistant Good, but the fabric surface is slightly wrinkled and textured (please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 specification (210X29? Mm) -25- 1222473 Ministry of Economy Wisdom Printed by the Consumer Cooperative of the Property Bureau A7 B7 9L 7. 28 V. Description of the invention (women's disorder occurred, compared with the fabrics of Examples 4 and 5, it was of poor quality or some inferior ones. [Example 7] 56d t ex 36 The false-twisted yarns of the round cross-section polytrimethylene terephthalate fibers (false twisting conditions are shown below) are warp and weft yarns, and the respective weaving densities are 1 1 3 / 2.5 4 cm. 1 1 3 strips / 2.5 4 cm flat woven fabric. The fabric is the same as in Example 1. Processing and processing. The obtained fabric is a stretchy, soft and water-resistant fabric. (False twist processing conditions) False twisting machine: nip belt type false twisting machine, 'Silk speed: 3 0 0 m / mi η, DR ·· 1.020, 〇F2: + 4.70%, TA: 1 1 °, HI: 160t :, H2: 160 ° C [Example 8] 5 6 dtex 3 6 is used for warp Polyethylene terephthalate fiber with round cross section of long fiber, 5 6 dtex 3 6 polyfilament terephthalate fiber with round cross section for weft yarn, hand-jet processing yarn (liquid) The jet processing conditions are shown below), and the respective fabric densities are 110 strips / 2.54 cm, and 10 strips / This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) ( Please read the notes on the back before filling this page) -26- 1222473 A7 9L 7. 26 Β7 V. Description of the invention (Heart woven fabric of 2.5 4 cm). This fabric was treated and processed in the same manner as in Example 1. (Please read the precautions on the back before filling in this page) The obtained fabric is a stretchy, soft, and water-resistant fabric. (Fluid jet processing conditions) Processing machine: Air processing machine, Yarn speed: 3 0 0 m / mi η, air pressure: 735kPa, overfeed rate: 15%,
噴嘴:Hema Jet 丁 E — 3 1 2 K 〔比較例2、比較例9〕 採用實施例7而得的織物,連續精練8 0 °C並去除糊 劑後,進行預設定(在寬幅進行1 0 0 °C (乾熱處理), 其次在1 2 0 °C進行循環器染色。 供比較用,進行預固定下,製作直接在 1 2 0 °C 循 環器染色者,與實施例1同法進行撥水加工、軋光機加工 0 經濟部智慧財產局員工消費合作社印製 於所得的織物中,比較例2之織物雖具有伸縮性,惟 耐水性稍差。另外,比較例9之織物係在織物上發生大的 皺紋,成爲較厚底材者,耐水性亦低者。 〔比較例3、. 4〕 將與實施例1進行相同的撥水加工之織物,除於比較 例3中變更成壓延機條作爲線壓9 8 0 N/cm,金屬輥輪溫 度1 4 0 t:,於比較例4中變更成線壓3 4 3 0 N / c m 本紙張尺度適用中國國家標準(CNS ) A4規格(210Χ297公釐) -27 - 1222473 A7 B7 ?· 2孓 五、發明説明(知 ,金屬輥輪溫度1 7 〇 °c外,餘與實施例1同法進行軋光 機加工。 比較例3之織物係有耐水性較低的傾向,比較例4之 織物係手感有較低的傾向。 〔實施例9〕 於經紗採用5 6 d t e X 3 6條長纖之圓型截面之 聚對苯二甲酸丙二醇酯纖維,緯紗採用5 6 d t e X 3 0條長纖之扁平度3之W型截面之聚對苯二甲酸丙二醇 酯纖維,而得各自的編織密度1 2 0條/ 2 · 5 4 c m ’ 1 2 0條/ . 2 . 5 4 c m之平織織物。所得的織物與實施 例1同法進行處理、加工。 所得的織物係伸縮性、耐水性、手感均非常良好的織 物0 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -28 - 1222473 A7 917.26 B7 五、發明説明(妇 經濟部智慧財產局員工消費合作社印製 m 耐水壓 (kPa). 〇〇 vd cs csj oo VO o wo r—H tn VO r—< vd On — § CO oo ON OO OO oo 〇 cK OO cn 通氣度 (cc/cm2· sec) Ο) r—i 1-i CN cn t—H r—H S oo r—H 1~< <N T—< cn cs CN cn r-H ON o 寸 o t—H On οά 寸 o cn cn 耐絨毛 性(根) Ο cn o 〇 r-H H 〇 o o <N CSI 〇 o o o Ό o 寸 摩擦音 ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ 〇 ◎ 〇 ◎ X X 〇 < X 1 ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ ◎ ◎ 〇 ◎ X X 〇 <] 〇 伸縮率(%) 緯方向 oo 〇6 〇 oo crs 卜^ ON r—i vq r—H r—( t—i o r4 r—H On p Λ-< to 06 CO r—< ON I 1 寸 cs 1-( CO OO _ 靈 纖維塡充 .JSDS (g/cm3) 1-< MD s o cn O o s 〇 cn \〇 〇 wn o Ό 〇 s o (N vo On c? S i~1 卜 r—< oo to C<l !>; cn o 捲縮指數 CI 0.007 0.008 0.005 0,004 r—i o 0.011 0.011 0.008 CD 0.014 0.008 0.007 0.009 0.001 0.001 0.008 0.002 0.014 捲縮率CR (%) CSI oo 卜: CN ON WO 寸 o CO CN ON CO t—< On OO CN 〇 OO OO oo oa t—H oo H CSI to •O 厚度 (mm) CSI r—i t—< t—< m T—H cn r-H cs T—< oa Ί—< CN 1—i r—< 1-ί T—4 r—i CO r—1 w〇 o o r—i r—i 〇 cn t—H cn r—i r—< ^~i cn Csi r—H _ g 冢 t-H CO cs s 〇j cn s CN WO cs vn t—H Csl <N VO On Ό CN CSI o g oa s csi cn On r—< vo CN ON wn oo Csi csi s cs cs VO 加工密度 .經/緯 (根/2.54cm) 148/130 124/130 180/130 202/130 143/130 154/130 166/130 140/130 134/130 148/130 148/130 147/129 150/129 204/146 220/162 107/130 223/130 220/129 織物密度 經/緯 (根/2.54cm) 120/120 100/120 148/120 172/120 100/120 100/120 100/120 113/113 110/110 113/113 120/120 120/120 120/120 190/140 190/140 86/120 195/120 113/113 實施例1 實施例2 實施例3 比較例1 實施例4 實施例5 實施例6 實施例7 實施例8 比較例2 比較例3 比較例4 實施例9 比較例5 比較例6 比較例7 比較例8 比較例9 I..-------^^衣-- (請先閱讀背面之注意事項再填寫本頁) 、1Τ 本紙張尺度適用中.國國家標準(CNS ) A4規格(210X297公釐) -29-Nozzle: Hema Jet Ding E — 3 1 2 K [Comparative Example 2, Comparative Example 9] The fabric obtained in Example 7 was used for continuous scouring at 80 ° C and the paste was removed. 0 0 ° C (dry heat treatment), followed by circulator dyeing at 120 ° C. For comparison purposes, pre-fixing was performed, and those directly dyed at 120 ° C circulator were produced in the same way as in Example 1. Water-repellent processing and calendering processing 0 The employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs printed on the obtained fabrics. Although the fabric of Comparative Example 2 had elasticity, its water resistance was slightly worse. In addition, the fabric of Comparative Example 9 was in Large wrinkles occur on the fabric, and those who become thicker substrates have lower water resistance. [Comparative Examples 3, 4] The fabric subjected to the same water repellent processing as in Example 1 was changed to calendering in Comparative Example 3 The bar pressure is 9 8 0 N / cm, and the metal roller temperature is 1 4 0 t: It is changed to the line pressure 3 4 3 0 N / cm in Comparative Example 4. The paper size is applicable to Chinese National Standard (CNS) A4. (210 × 297 mm) -27-1222473 A7 B7 2 · 5. Description of the Invention (Knowledge, Gold Except for a roller temperature of 170 ° C, the calender was processed in the same manner as in Example 1. The fabric of Comparative Example 3 tended to have a lower water resistance, and the fabric of Comparative Example 4 tended to have a lower feel. [Example 9] A polytrimethylene terephthalate fiber having a round cross section of 5 6 dte X 3 6 long fibers was used for the warp yarn, and a W-shaped cross section of flatness 3 of 5 6 dte X 3 0 long fibers was used for the weft yarn. Polytrimethylene terephthalate fiber to obtain a plain weave fabric with a respective weaving density of 120/2 · 5 4 cm '1 20 /. 2.5 4 cm. The obtained fabric was the same as in Example 1. The obtained fabric is a fabric with excellent stretchability, water resistance, and hand feel. 0 (Please read the precautions on the back before filling this page.) Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Applicable to China National Standard (CNS) A4 specification (210X297 mm) -28-1222473 A7 917.26 B7 V. Description of the invention (printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Women's and Economic Affairs m) Water pressure resistance (kPa). VO o wo r—H tn VO r— < vd On — § CO o o ON OO OO oo cc OO cn Ventilation (cc / cm2 · sec) 〇) r—i 1-i CN cn t—H r—HS oo r—H 1 ~ < < NT— < cn cs CN cn rH ON o Inch ot—H On οά Inch o cn cn Fuzz resistance (root) 〇 cn o 〇rH H 〇oo < N CSI 〇ooo Ό o Inch friction sound ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 XX 〇 < X 1 ◎ ◎ ◎ ◎ ◎ ◎ 〇 ◎ ◎ ◎ ◎ ◎ XX 〇 <] 〇Expansion ratio (%) Weft direction oo 〇6 〇oo crs BU ^ ON r—i vq r—H r— (t—io r4 r—H On p Λ- < to 06 CO r— &ON; 1 inch cs 1- (CO OO _ spiritual fiber filling. JSDS (g / cm3) 1- < MD so cn O os 〇cn \ 〇〇wn o 〇 〇so (N vo On c? S i ~ 1 bu r— < oo to C < l! >; cn o Curl index CI 0.007 0.008 0.005 0,004 r— io 0.011 0.011 0.008 CD 0.014 0.008 0.007 0.009 0.001 0.001 0.008 0.002 0.014 Shrinkage ratio CR (%) CSI oo Bu: CN ON WO inch o CO CN ON CO t— &On; On OO CN 〇OO OO oa oa-H oo H CSI to • O Thickness (mm) CSI r—it— < t— < m T—H cn rH cs T— & l t; oa Ί— < CN 1—ir— < 1-ί T—4 r—i CO r—1 w〇oor—ir—i 〇cn t—H cn r—ir— < ^ ~ i cn Csi r—H _ g tsu tH CO cs s 〇j cn s CN WO cs vn t—H Csl < N VO On Ό CN CSI og oa s csi cn On r— < vo CN ON wn oo Csi csi s cs cs VO processing density. Warp / latitude (root / 2.54cm) 148/130 124/130 180/130 202/130 143/130 154/130 166/130 140/130 134/130 148/130 148/130 147/129 150/129 204/146 220/162 107/130 223/130 220/129 Fabric density warp / weft (root / 2.54cm) 120/120 100/120 148/120 172/120 100/120 100/120 100/120 113/113 110/110 113/113 120/120 120/120 120/120 190/140 190/140 86/120 195/120 113/113 Example 1 Example 2 Example 3 Comparative Example 1 Example 4 Example 5 Example 6 Example 7 Example 8 Comparative Example 2 Comparative Example 3 Comparative Example 4 Example 9 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 I ..--------- ^^ -(Please read the precautions on the back before filling this page), 1T This paper size is applicable. National National Standard (CNS) A4 specification (210X297 mm) -29-
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