TW588213B - Photographic or photothermographic imaging element and method of image formation - Google Patents

Abstract

This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of structure 1, substituents are as defined in the application. A photographic or photothermographic imaging element comprising an imaging layer having associated therewith a compound of structure 1, wherein: PUG is a photographically useful group, LINK 1 and LINK 2 are linking groups; TIME is a timing group; l is 0 or 1; m is 0, 1, or 2; n is 0 or 1; Y is C, N, O or S, X is an electron-withdrawing group; W is hydrogen, halogen, or a substituted or unsubstituted alkyl, cycloalkyl, aryl or heterocyclic group, or W can combine with T or R12 to form a ring, w is 0 to 3 when Y is C, w is 0-2 when Y is N, and w is 0-1 when Y is O or S, when w is 2, the two W groups can combine to form a ring, and when w is 3, two W groups can combine to form a ring or three W groups can combine to form a bicyclic substituent; R12 is hydrogen, or a substituted or unsubstituted alkyl, cycloalkyl, aryl or heterocyclic group or R12 can combine with T to form a ring; T is a substituted or unsubstituted alkyl cycloalkyl, aryl or six-membered heterocyclic group, t is 0, 1, or 2, with the proviso that if X is a sulfono group and a and l are each l and m and n are each 0, then t is 1 or 2; and if t is 2 the two T groups can combine to form a ring; X is divalent, a is 1 or 2, and b is 1; and wherein LINK 1 and LINK 2 is independently of structure II, wherein X represents carbon or sulfur; Y represents oxygen, sulfur or N-R1, where R1 is substituted or unsubstituted alkyl or substituted or unsubstituted aryl; p is 1 or 2; Z represents carbon, oxygen or sulfur; r is 0 or 1; with the proviso that when X is carbon, both p and r are 1, when X is sulfur. Y is oxygen, p is 2 and r is 0; # denotes the bond to PUG (for LINK 1) or TIME (for LINK 2): $ denotes the bond to TIME (for LINK 1) or T(t) substituted carbon (for LINK 2).

Description

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Α7 ‘Explanation of the Invention (1) The present invention relates to a device containing a warp blocking agent, such as a developer. The development of photographic techniques for compounds used for photographing has long been attempted to eliminate the ancient photographic sensibility of the camera. Every day, the photosensitivity of the simple camera = by supplying the product suitable for hand-held photos, only m, "Meet this need.-Once exposed, the latent image that appeared on the film after the film was produced. These elements have historically been made from the film that exposed the camera. Silly &gt; It is used to form an image and is processed by processing with a sodium developer solution. The color film needs to be cooled with an amine or p-phenylenediamine developer. The reducing agent is typically developed. The developer money is subsequently exposed to photographic film elements (reactive related matter) during processing. Isolation of the developer from the film element is necessary, because the developer is directly incorporated into the photosensitive photographic element, which often causes teeth. Silver emulsion desensitization and undesired haze. Therefore, considerable efforts have been made to try to produce effective <developer by blocking, which can enter the silver emulsion element without adverse desensitization or haze effect, and in the development status Deblocking, so the developer does not participate in the imaging (staining or forming silver metal) reaction at all. US Patent No. 3,342,599 issued to Reeves discloses the use of Schiff base developer precursors. Research revealed (Resea_

In DiSClOsure (129 (1975) pp. 27-30), Schleigh and Faul describe the fourth-order blocking of color developers and the ethylamino group of p-phenylenediamine Blocked. (All research references referenced here are by Kenneth Mason Publications, Ltd. (Dudley Annex, 12a North Street, Answorth, 4-paper scale) Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ------------ ^ w- ------ Order --------- (please first Read the notes on the back and fill in this page) · 588213 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (2) (Emsworth), published by Hampshire P010 7DQ, UK 〇) Then , US Patent No. 4,157,915 issued to Hamaoka et al. And US Patent No. 4,060,418 issued to Waxman and Mourning are described for color diffusion Preparation and use of blocked p-phenylenediamine in the transferred image receiving film. All these studies have failed in practical product applications due to one or more of the following problems: desensitization by photosensitizing silver; unacceptable slow deblocking of power; by blocking the developer's instability, producing haze and / Or reduced maximum density (Dmax) after storage, and the lack of a simple release developer blocking method. Recent developments in blocking and conversion chemistry have resulted in well-performed blocked p-phenylenediamine. In particular, U.S. Patent No. 5,019,492 describes a compound having a "dot-keto-fluorine" type blocking group (strictly speaking, a keto-fluorenyl-type blocking group). The use of /? _ Ketoester blocking chemistry has made it possible to incorporate p-phenylenediamine di into a system that becomes active only when development is needed. Ketofluorenyl groups are released from the film layer by blocking the developer, where they are incorporated from a basic developing solution containing a nucleophile, such as hydroxylamine. Resistance == _ Development_ In human photographic elements, it is typical to use the agent <colloid gelatin to disperse and walk. This good liquid dispersion uses this right; ^ ^ t "Wanfa preparation 'where the developer precursor is dissolved in a high vapor pressure organic lotion (such as acetylene r-^ ^, · @ 日) In some cases, And low vapour pressure organic price! (Such as dibutyl phthalate gelatin solution emulsified. Milky n n water-based surfactants and ceremonialization, often finished by colloidal grinding, to evaporate or this paper scale "China National Standard -5- X 297 public love ----------- order --------- ^^ wii. ^ Wi (Please read the precautions on the back before filling in this (Page) 588213 A7

Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. It is washed with water to remove the organic solvents that are under vapor pressure. Therefore, the family name is known; u For this reason, the need for an imaging element and Fang Nuxiang is simple and convenient. Fang Liushi, Gan Duluo Bu / the only way for consumers to develop a photo development device, especially photography and light: the element 'is included in the form Stable until the development ==> &gt; — start the processing by heating the element and / or applying a solution such as an acid solution to the element 'can be quickly and easily 2 ::::: no need There are amphiphiles. This-developer chemistry phase-first, quick-processing film, which can be processed simply and efficiently in a low-cost photo processing shop. Similarly, it is necessary to incorporate other useful compounds into the photographic element, so that they remain stable until X is added, and are then quickly released. Such photographic compounds include coupling agents, dyes and dye precursors, electron transfer agents, and the like, as discussed more fully below. The present invention relates to a blocking compound that, when thermally activated, is decomposed by a U2 removal mechanism, and releases a base that can be used for photography. In a preferred embodiment, the photographic base is a developer. In a specific embodiment, the thermal activation preferably occurs at a temperature between about 100 * 16 (rc). In another specific embodiment, the thermal activation is preferably in the presence of acid, water or water at about 20 and 10 (Temperature between TC occurs. The present invention is more about *-a photosensitive photographic element comprising a support and a compound having a blocking compound, which when thermally activated, the blocking compound is deactivated by 1, 2 The mechanism is decomposed and released, which can be used for photography. The present invention relates to an imaging method further comprising the steps of: thermally developing a full-image-exposed photographic element having a blocked compound; Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) —--------------- Order --------- (Please read the Please fill in this page again for attention) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives 213 V. Description of the invention (4 compounds are decomposed and released into a developed image by the u removal mechanism, scan the developed image; Phase (Kicheng first Lei Shao Shaozhu Lord, you take the image and develop the image from the child development image M, / 1 will The first—electronic record is digitized to form a digital storage =: / the whole digital image is formed to form a second electronic image table, which is stored and transferred to print or display the second t-sub image table. This, Mingguanguan ^ _Single-use photography with a photosensitive photographic element ^ 'The edge element includes a support and a compound with a blocking compound. When activated, the compound is decomposed by a desorption mechanism, and the release can be used for Zhao Xiangzhi ... The present invention relates to an imaging method further comprising the steps of: exposing the entire image of a photosensitive photographic element having a support and a blocking compound, in a single-use camera with a heater When thermally activated, the blocking compound is decomposed by the i, 2 removal mechanism to release a substrate that can be used for photography and heat-treats the exposure element in the camera. In a more preferred embodiment, the photographic element includes a Structural developer related layers:

, W (w) Among them: PUG is a kind that can be used for photography; This paper size is applicable to China National Standard (CNS) A4 (210 X 297 public love) ^ ^ ------ order ------ --- (Please read the notes on the back before filling out this page) 588213 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (5) LINK 1 and LINK 2 are key bases; TIME is the time base ; 1 is 0 or 1; m is 0, 1 or 2; η is 0 or 1; Υ is C, N, 0 or S; X is substituted or unsubstituted aryl or electron-withdrawing group; W is hydrogen Halogen or substituted or unsubstituted alkyl (preferably containing 1 to 6 carbon atoms), cycloalkyl (preferably containing 4 to 6 carbon atoms), aryl (such as phenyl or fluorenyl) Or heterocyclic group, or W can combine with τ or R12 to form a ring, w is 0 to 3 when γ is c, w is 0-2 when Y is N, and w is 0 when Y is 0 or S , When w is 2, the two W groups can be combined to form a ring, when w is 3, the two w groups can be combined to form a ring, or the three W groups can be boxed to form an aryl or bicyclic substituent;

Ru is hydrogen 'or a substituted or unsubstituted alkyl, cycloalkyl, aryl or heterocyclic group, or R12 can combine with T to form a ring; T is a substituted or unsubstituted alkyl, cycloalkyl , Aryl or six-membered heterocyclic group, t is 0, 1 or 2, with the limitation that if X is cyano and n is 0 'each t is 1 or 2; if X is a gauge group and a and 1 are each 1, and claw and η are each 0, 1J t is 1 or 2; and if t is 2, the two τ groups can combine to form a ring; when X is monovalent, &amp; is 1, and when x is &Amp; is 1 or 2 when bivalent; and b is 0 when X is monovalent, and 1) is i when X is bivalent. Each alkyl group preferably contains 1 to 6 carbon atoms, each cycloalkyl group preferably contains 4 to 6 carbon atoms, and each aryl group is preferably a phenyl group or a naphthyl group. --- * -------- · ------ Order --------- line (please read the precautions on the back before filling this page) -8-588213 Ministry of Economic Affairs Printed by A7 B7 of the Consumer Cooperative of the Property Bureau V. Description of the Invention (6) In a preferred embodiment of the present invention, LINK 1 and LINK 2 belong to Structure II:

⑺P II $ A /

r (z) r II where X represents 7F carbon or sulfur; Y represents oxygen, sulfur or N-Ri, where I is a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; p is 1 or 2; Z represents carbon, oxygen, or sulfur; r is 0 or 1; the restriction is when X is carbon,? And r are both 1, when X is sulfur, γ is oxygen, p is 2 and Γ is 0; # indicates bonding to PUG (about LINK 1) or TIME (about LINK 2); $ means bonding to TIME ( About LINK 1) or T⑴ substituted carbon (about LINK 2). Figure 1 shows in block form an apparatus for processing and viewing the images obtained by scanning the elements of the invention. Fig. 2 shows a block diagram showing the processing of the image-bearing signal and the winter electron signal derived from scanning the developed color element according to the present invention. In the structure, for example, the PUG can be a photographic dye or a photographic reagent. The photographic reagent here is further related to the components in the photographic element when it is released --------------- Order --------- (Please read the precautions on the back first (Fill in this page again.) -9-588213 The Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed A7 Invention Description (7) Response. Such groups that can be used for photography include, coupling agents, polymer coupling agents, and other forms of coupling agents: see: sexual bleaching inhibitors / whitening accelerators, bleach inhibitors, and inhibitor release and: Dye ^, developer (such as competitive color developer, color developer's precursor, and Nanhua silver developer), silver ion fixative migration agent, dentine silver solvent, Nanhua silver complex, reduced ketone, Shadow: agent, pre-processing and post-processing processing image stabilizer, hard = v, tincture, misting agent, ultraviolet radiation absorber, nucleating agent, chemical and photosensitizer or desensitizer, interface activity Agents, and their precursors and other additives known to be used in photographic materials. PUGs can be present in blocked compounds as complete species or precursors. For example, 'the completed development inhibitor may be bonded to a blocking group, or the development inhibitor may be attached to a timing base, which is released at a specific time and location in the photographic material. For example, PUG can be a finished dye or compound that develops color upon release from a blocking group. In a preferred embodiment of the present invention, PUG is a developer. The developer can be a color developer, a black and white developer, or a cross-oxidized developer. It may include amine phenol, phenylenediamine, quinone, pyrazoline dione, and cultivating. The developer for explanation is described in U.S. Patent Nos. 2,193,015, 2, 108,243, 2,592,364, 3,656,950, 3,658,525, 2,751,297, 2,289,367, 2,772,282, 2,743,279, 2,753,256, and 2,304,953. The PUG base used as a developer is: -10-This paper size is applicable to the Chinese National Standard (CNS) A4 (21 × 297 mm) ^ ------ tr ------- --Line (Please read the notes on the back before filling this page)

588213 A7 B7 V. Description of the invention (8)

R23 R24 ^

VN

CH2CH2OH

I

OH where R20 is hydrogen, from the prime, alkyl or alkoxy; R21 is hydrogen or alkyl;. R22 is hydrogen, alkyl, alkoxy or butanedioxy; and R23, R24, R25, R26 and R27 is hydrogen, alkyl, light alkyl or alkylene. -11-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) —% -------------- Order --------- $ 4 ( Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 588213 5. Description of the invention (9) As mentioned above, in the preferred embodiment of the present invention, link 1 or LINK 2 genus structure π:

Ρ mnMMX $ r /) (wherein χ represents carbon or sulfur; Y represents oxo 'sulfur or N_Ri, where Ri is a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group; p is 1 or 2; Z represents carbon 'oxygen or sulfur; r is 0 or 1; restrictions are that when X is carbon, P and Γ are both 1, when χ is sulfur, γ is oxygen, and ρ is 2 and 1 * 〇; # indicates bonding to PUG (about LINK 1) or TIME (about LINK 2); $ indicates bonding to TIME (about LINK 1) or τ⑴ substituted carbon (about LINK 2). Note that the bonding group includes For example: --Sr ------ 1— ^ v · ------ Order --------- i ^ wi (Please read the notes on the back before filling this page) Ministry of Economy Printed by the Intellectual Property Bureau Staff Consumer Cooperatives 〇II -0—C- S II -C-

S II

〇 II or nc2h5 TIME is the timing base. This type of base is well-known in the art, such as (1) -12- This paper size applies the Chinese National Standard (CNS) A4 specification (210 χ 297 mm) 588213 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economy A7 B7 i. Description of the invention (i) U.S. Pat. No. 5,262,291, using aromatic nucleophilicity to substitute the reaction base; (2) Using hemicondensation cleavage base (U.S. Pat. No. 4,146,396, Japanese application Nos. 60-249148; 60-249149); (3) Using the basis of the electronic transfer reaction of the car-sharing system (U.S. Patent No. 4,040,3 2 3; 4,421,845; Japanese application 57-188035; 58-98728; 58-209736; 58-209738); and (4) the use of an intermolecular nucleophilic substitution reaction group (US Patent No. 4,248,962). The timing base is represented by chemical formulas T-1 to T-4.

Nu

E where:

Nu is a nucleophilic group; E is an electrophilic group including one or more talk- or heteroaromatic rings, including an electron-deficient carbon atom; LINK 3 is a bonding group, which lacks electrons in the nucleophilic position of Nu and in E 1 to 5 carbon atoms are provided in a direct channel between carbon atoms; and c is 0 or 1. Such timing bases include, for example:

This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Fill in this page) 588213 A7 B7 V. Description of the invention (1

And N

No. CH3 These timings are based on a more complete description in U.S. Patent No. 5,262,291, where V represents an oxygen atom, sulfur atom T-2 or the radicals R15, R13 and Rm each represent a hydrogen atom or a substituent; Ri5 represents a substituent; Represents 1 or 2. Typical examples of Rn * RM, when they represent substituents, and R includes

Rie

R! R ------- ## !! —IT -------- (Please read the notes on the back first and then fill out this page] Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs ^ 16NCO R17

Rl7 where R! 6 represents an aliphatic or aromatic hydrocarbon residue, or a heterocyclic group; Rl7 represents a hydrogen atom, an aliphatic or aromatic hydrocarbon residue, or a heterocyclic group, and each of / 7Ri4 and Xin 5 can represent a divalent Group, in which any two are combined with each other to form a ring structure. Specific examples of the base represented by the chemical formula (T-2) are as described below. -14- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 588213 A7 B7 5. Description of the invention (12) -OCH. ·

-SCH-I so2ch3

with

Nul—LINK4—E1- T-3 ---------- #-MW ---- &quot; --- Order --------- * · (Please read the note on the back first Please fill in this page for further information.) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, where Nu 1 represents a nucleophilic group, and oxygen or sulfur atoms can be examples of nucleophilic species; E1 represents an electrophilic group, which is a nucleophilic attack by Nil 1 LINK 4 represents a linking group that enables Nul and E1 to have a three-dimensional arrangement, so intermolecular nucleophilic substitution reactions can occur. Specific examples of the base represented by the chemical formula (T-3) are described below. -15 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 588213 A7 B7 V. Description of the invention (13) • 0

, ch2nco-C3H7 (i)

CO2C4H9 -O o

ΟII -oc

N—CO—— o oII II -OC 《CH2) 2 ^ C-

NC0—— CH (CH3 &gt; 2 CH (CH3) 2

V Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (k13) x (ftl4) y where V, R13, R14, and d are all the same as in chemical formula (T-2). In addition, R13 and R14 may be joined together to form a benzene ring or heterocyclic ring, or V may be joined to R13 or R14 to form a benzene or heterocyclic ring. 21 and Yi 2 each independent table-16 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) --------------------- Order --- ------ (Please read the notes on the back before filling this page) 588213 A7 B7 V. Description of the invention (14) shows carbon or nitrogen atom, X and y each represent 0 or 1 timing base (T-4 The specific examples are as follows

-0. CH

CHu—N

NHCOCH Η 3

co2h

-0 CHr CH〇 N

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

n &quot;, CN

— * --------------- —Order --------- (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standards (CNS ) A4 specification (210 X 297 mm) 588213 A7 B7 V. Description of invention (15)

0 Μ

ch5

ch5 ο ο

ch2

Η, ch2—

ΚΙ -CH

Ν〆 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Ο CHr

c11h23 Particularly preferred compounds that can be used in photography are blocked developers of structure III: -18-— · ^ ----------- i ^ w— —I—Order -------- -i ^ wi (Please read the notes on the back before filling out this page) This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 588213 A7 B7

W (w) V. Description of the invention (16 where: Z is, 0H or NR2R3 'where Han 2 and independently is hydrogen or substituted or unsubstituted alkyl, or &amp; and connected to form a ring; Rs '&amp;' &amp; and Rs are independently hydrogen, halogen, hydroxy, amine, alkoxy, carbonylamido, sulfoamido, sulfoamido, or alkyl, or &amp; capable of interacting with I or R6 Link, or R0 and / or can be linked to the heart or the heart to form a ring; T is a substituted or unsubstituted alkyl, cycloalkyl, aryl or six-membered heterocyclic group, t is 0, 1 or 2 The restriction is that if χ is cyano and m * n is 0, belit is 1 or 2, if X is sulfone and &amp; and 丨 are each 丨, and m * n are each t or 1 or 2 And if t is 2, two T groups can be combined to form a ring;

Rn is hydrogen 'or a substituted or unsubstituted alkyl, cycloalkyl, aryl or heterocyclic group, or R12 can combine with T or W to form a ring; X is a substituted or unsubstituted aryl or Electron radical; Y is C, N, 0 or S; a is 1 when X is monovalent, a is 1 or 2 when X is divalent; b is 0 when X is monovalent, and X is two when X is monovalent When valence, b is 1; W is hydrogen, halogen, or substituted or unsubstituted alkyl, cyclofluorenyl, aryl or heterocyclic group, or W can combine with T to form a ring, when y is (: When w is 0 to 3, when Y is N, w is 0-2, when Y is 0 or S, w is 0-1, when ... 19 This paper size applies Chinese National Standard (CNS) A4 (210 X 297) Mm) —U ---------------- Order --------- (Please read the notes on the back before filling out this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperative 588213 A7 B7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the Invention (17) At 2 o'clock, two W bases can be combined to form a ring. When ~ 3, two w bases can be combined. Instead, a ring is formed, or three w groups can be combined to form an aryl or bicyclic substituent. The heterocyclic group for the compounds of structures I and III is preferably a 5- or 6-membered heterocyclic ring containing one or more heteroatoms such as N, 0, S or Se. Such groups include, for example, substituted or Unsubstituted benzimidazolyl, benzopazolyl, benzophenylenyl, benzopyranyl, sulfanyl, pyridoxyl, isomerinyl, isothiazolyl, isoxazolyl , Oxazolyl, mepyridyl, purinyl, piperanyl 'report 17 wells' p ratio base, IT ratio base, p-blocyl, methyl p quelinyl, junwalinyl , P Chalyn, 4 喏 基 ， 基, 4 基 基 基, 违 唾 唾 唾 基, 违 唆 唆 '' '' thio and 三 U 基 坐. When the reference material in this application is a special department "This means that the moiety itself may be unsubstituted or substituted with one or more substituents (up to the maximum number possible). For example," alkyl "means a substituted or unsubstituted alkyl And "Aryl J represents a substituted or unsubstituted benzene (with up to 5 substituents) or higher carbon aromatic systems. Tong Wei 'unless specifically noted' can be used here on molecules The substituents include any group, whether substituted or unsubstituted, which will not destroy the properties required for photographic use. Examples of the substituents on any of the groups can include known substituents, such as: , Fluoro, bromo, iodo; alkoxy, especially "lower carbon alkyl" (ie, having 1 to 6 carbon atoms), for example, methoxy, ethoxy; substituted or unsubstituted Alkyl, especially lower carbon (eg, methyl, trifluoromethyl); thioalkyl (eg, methylthio or ethylthio) ', especially those having 1 to 6 carbon atoms; Substituted and unsubstituted aryl groups, especially those having 6 to 20 carbon atoms (such as phenyl); and substituted or unsubstituted heteroaryl groups, especially those containing 1 to 3 optional N, 〇 or s 5-5 or 6-20 of heteroatoms This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ^ --------------- ^- ------- (Please read the notes on the back before filling in this page) 588213 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs

-21-V. Description of the invention (1S) fluorene (for example, pyridyl, sephenyl, furyl, pyrrolyl); acid or acid salt groups as described below; and others known in the art. Alkenyl group j may more specifically include Γ lower-carbon alkyl groups (ie, having an atom), such as methyl, ethyl, and the like. In addition, with regard to any alkyl or alkynyl group, it is inferred that these can be branched, unbranched, or cyclic. The following are representative examples of compounds that can be used for photography in the present invention:

, N, D-2 D-3 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) —Bu --------- ^ w &gt; ------ Order- -------- (Please read the notes on the back before filling this page) 588213 A7 B7 V. Description of the invention (19 4 D-

N D- D-

--- ^ --------- ^ w-- ------ Order -------- ^^^ 1. ^ w— (Please read the notes on the back before filling in this Page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

ο

N 22 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 588213 A7

(Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) i ^ w. ------- Order ------ --- ^^ 1 588213 A7 B7 V. Description of the invention (21 D-12

D-13 Ο

D-14

〇 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs D-15 0H, person ', N 0

-24- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 〇II, s, —.--------------- Order ----- ---- i 丨 · (Please read the notes on the back before filling in this page) 588213 A7 B7 V. Description of the invention (22) ο D-

ο

C // o \\

N D-

D-

ο --------- 1 ------- tr ----------- (Please read the precautions on the back before filling out this page) Staff Consumption of Intellectual Property Bureau, Ministry of Economic Affairs Cooperative printed D-

N 25 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 588213 A7 B7 V. Description of the invention (23) Ο Ο W //, s. D-20 N 0

also

0 D-21 N 0

A (Please read the notes on the back before filling out this page) D-22 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs D-23 N 0

Ν Ο

-26- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) S \ ^ 0ο

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N〇2

H, person ~ N〇2

ο ο \\ // (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

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-28- ---------------- Order- ------ I. ^ W (Please read the notes on the back before filling this page) This paper size is applicable to China Standard (CNS) A4 specification (210 X 297 mm) 588213 A7 B7 V. Description of invention (26) D-33 D-34

cf3

CN, Ν, D-35

w ο

Ύ

CN cTo D-36

Cl N〇2 -----------— I—Order · -------- i ^ w. (Please read the notes on the back before filling out this page) Intellectual Property Bureau, Ministry of Economic Affairs Printed by employee consumer cooperative D-37 D-38

O n 〇 〇 Ϋ) 〇〇 T H //.

o

H /? Proceedings, O -29- This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) 588213 5. Description of the invention (27) D-39

〇 h, nA

Jii S-s〆 II II 〇 person

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The blocked developer is preferably incorporated into one.娣 Blocking and smashing, seven 禋 次 夕 种 显 # 兀 件 的 之 ^^ The amount of developer used in Jiulang, Shizhuang a, 00 ^ 5 ,, .. v "focuses on the addition of each layer The dosage is preferably from shoulder to 5 g / million, more preferably from 1-2 g / m2 to 2 g / m2. These can be taken up • Pigmented or non-colored layers. The pj-broken developer can be included in the process of processing and separating τ ^ ^ ^ 1 ^ a ^ σ from contact with the photographic element during processing. After the full image of the developing element is exposed, the developer is blocked during the developing element washing process, by heating the developing element during the developing element washing process, and / or developing The π member is activated by contact with a separation element such as a laminated sheet. This laminated sheet may contain additional processing chemicals as required, as disclosed in Chapters χ and XX of the Research Reveal, September 1996, No. 389, Item 38957 (refer to the following as "Research Reveal I" )). The chapters referenced here are those for research revealing, unless otherwise specified. Such chemicals include, for example, sulfites, hydroxylamines, isohydroxy acids, and the like, anti-mist agents such as alkali metal south compounds, nitrogen-containing heterocyclic compounds, and the like, such as chelating agents for organic acids , And other additives, such as buffering agents, sulfonated polyphenylenesulfonium, coloring reducing agents, biological acids, silver removal agents, stabilizers and the like. Blocked compounds can be used in any form of photographic system. A typical color negative film structure used in the practice of the present invention is ordered by the following components SCN-i --------- # · (Please read the precautions on the back before filling this page) 30- This paper size applies China National Standard (CNS) A4 Specification (210 X 297 mm) 588213 The Intellectual Property Bureau of the Ministry of Economic Affairs's Consumer Cooperative publishes the invention description (28):

The support s can be reflective or transparent, which is often preferred. When reflective, the support is white and can take the form of a conventional support recently used in any color indene element. When the support is transparent, it can be colored or stained, and can take the form of a traditional support recently used in color negative elements-for example, a colorless or stained transparent film support. Details of the support structure are well known in the art. Examples of useful supports are polyacetal) films, polystyrene films, poly (ethyl terephthalate) films, poly (ethoxylate) films, polycarbonate films, and related resin materials , And paper, cloth, glass, metal, and other supports that withstand the intended processing environment. The element can contain additional layers, such as a filter layer, an inner layer, a cover layer ' sublayer ' anti-blooming layer and the like. Transparent and reflective support structure, including sublayers that increase viscosity, are revealed in the research reveal, Chapter XV. 〇-31-Private paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm)- -^ ---------------- tr --------- f Please read the notes on the back before filling out this page} 588213 Employees ’Consumption of Intellectual Property, Ministry of Economic Affairs Printed by the cooperative A7 V. Description of the invention (29) The photographic element of the present invention may also usefully include the magnetic green material disclosed in the research of η in 1992, Item 34390, or the transparent magnetic recording layer 'as in transparent A layer containing magnetic particles on the bottom surface of the support, such as US Patent No. 4,279,945 and US Patent No. 4,302,523. Each of the blue 'green and red recording layer units BU, GU, and RU is formed of one or more hydrophilic colloid layers, and contains the less one radiation-sensitive commercial silver emulsion and a coupling agent, including at least one dye imaging coupling agent. The preferred green and red recording layer units are subdivided into at least two recording layer units to provide increased recording latitude and reduced image granularity. In the simplest expected structure, the 'layer units or layer units' consist of a single hydrophilic colloidal layer containing an emulsion and a coupling agent. When a coupling agent present in a layer unit or a layered unit is coated with a hydrophilic colloid layer other than the emulsion-containing layer, the coupling agent-containing hydrophilic gum layer is positioned to accept the oxidized color from the emulsion during development Developer. The coupling agent-containing layer is often a hydrophilic colloid layer next to the emulsion-containing layer. In order to ensure excellent image sharpness and help the manufacture and use of the camera, all the photosensitive layers are preferably positioned on the common surface of the support. When in the form of a reel, the element will be wound on the shaft, so when unwound in the camera, the exposed light strikes all the light-sensitive layers before impacting the support that drives these layers. In addition, in order to ensure excellent sharpness of the image exposed on the element, the total thickness of the upper layer unit of the support should be controlled. Generally, the total thickness of the photosensitive layer, inner layer and protective layer on the exposed surface of the support should be less than 35 microns. Any convenient option in the conventional radiation-sensitive silver emulsion can be incorporated into the layer unit and used to provide the spectral absorption of the present invention. Most commonly used, Bu-32 This paper size applies to China National Standard (CNS) A4 (210 X 297 public love)-^^ 1 ------ ^ ------- I i ^ w (Please read the precautions on the back before filling out this page) 588213 A7 B7 V. Description of the invention (30) Dagger <High bromide emulsion. To achieve higher processing speeds, highly gaseous emulsions can be used. Light shot of light-sensitive silver gasification, desertification to Qi: stinky, silver 'silver iodide chloride' silver chlorobromide, gasification of silver, gasification, and 'odorous silver chloride particles are covered. The particles It can be regular or irregular /. The column is like a flat plate). The flat plate particles occupy at least = (preferably at least 70%, most preferably at least 9.%) in the raised area of the whole particle. It is particularly beneficial to improve the degree <Speed. After careful consideration, flat plate-like particles need two main parallel planes, and the ratio of their equal circle diameter (ECD) to their thickness is at least 2. More specifically, compared to: <Flat plate-like particle emulsions have flat plate-like particles The aspect ratio is at least 5 ^, preferably greater than 8. The preferred average flat plate-like particle thickness is less than 0.3 μK, preferably less than 0.2 micron.) In particular, the average flat plate-like particle thickness is less than the order, 〇.〇 7 micron ultra-thin flat plate-like particle emulsion. The particles preferably form a surface latent image: so when the surface developer in the form of the color negative film of the present invention is processed, a negative image is produced. Traditional radiation-sensitive silverized silver emulsion It is revealed by the researches exemplified above. I. Liye granules and preparation thereof. Photosensitivity, which can take any form, as described in the Chemical Photosensitivity section. There are compounds used as chemical photosensitizers, such as' including active gelatin, sulfur, selenium, tellurium, gold printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, Ship, palladium 'indium, starved, chain' phosphorus, or a combination thereof. Chemical photosensitivity is usually carried out at a pAg of 5 to 10, a pH of 4 to 8, and a temperature of 30 to paper. Photosensitivity and photosensitive dyes' which can It takes any form and is described in chapter ν · Light 'Photosensitivity and Desensitization. Dyes can be added at any time (for example, before and after chemical photosensitivity) before emulsion coating on photographic elements, or at the same time, by adding silver particles and hydrophilic colloids. Emulsion. For example, “Dyestuff can be dissolved in water or alcohol -33- This paper size is applicable to Zhongguanjia Standard (CNS) A4 specification (210 X 297 public f 588213) Printed by A7, Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs 2. Description of the invention (31) It is added as a liquid or as a dispersion of solid particles. The emulsion layer typically also includes one or more anti-hazing agents or stabilizers, which can adopt any traditional form Formula, as described in Section VII European Anti-Misting Agents and Stabilizers. 'The dentine silver particles used in the present invention can be prepared according to methods known in the art, as revealed by the research exemplified above, and James (James) as described in the Theory of the Photographic process. These include, for example, ammonia-based emulsions, neutral or acidic emulsions, and those known in the art. These methods are usually included in protection In the presence of colloidal colloids, the bis-soluble silver salt is mixed with the water-falling halide salt, and the temperature 'pAg, pH 値, etc. are controlled to appropriate 期间 during the formation of silver ions by precipitation. During the particle precipitation, one can be incorporated Or one or more supplements (particle occlusion other than silver and halide) to adjust the particle properties. For example, there can be any research in the emulsion of the present invention revealing chapter T • emulsion particles ^ its preparation, subchapter G · particle adjustment conditions and adjustments, various disclosed in paragraphs (3), (4) and (5) Traditional supplements. In addition, it more specifically includes supplementing the particles with a transition metal hexacoordination complex containing one or more organic ligands, as described in U.S. Patent No. 5,36,712,712 by Wom (01m) et al. Like. More explicitly includes a centrally-oriented stereolattice of an additive-enhanced particle that can increase the imaging speed by forming a shallow electron trap (hereinafter also referred to as SET), as discussed in Research Publication No. 36736 published in November 1994 Like. SET supplements are effective at any position within the particle. Usually when the set supplement is 50% of the blended particles, better results are obtained based on silver. The best SET SET particle area ranges from all silver forming particles to 85% silver formers. SET can be incorporated into the container at the same time or during the continuous precipitation of particles ... ------- Order --------- {Please read the precautions on the back before filling this page) • 34- Ministry of Economic Affairs Wisdom Printed by the Consumer Affairs Cooperative of the Property Bureau 588213 V. Description of the invention (32 Zhongtong 4 Φ Cheng SET supplements are mixed at a concentration of at least 1 × 10 · 7 mol per mol silver to its' combination limit, typically up to About 5 x 10 · 4 moles per mole of silver. SET supplements are known to reduce mutual damage. In particular, it is advantageous to use steel six coordination complexes or Ir + 4 complexes as set supplements. Indium supplements (non-SET supplements) that effectively provide shallow electron drunk can also be blended in the particles of the silver particle emulsion to reduce mutual damage. In order to effectively improve mutual properties, indium can be present in any of the particle structures. Position. The best position in the particle structure where the steel supplement produces mutual improvement is the field formed after the first 6.0 seconds and before the last 1% of the precipitated silver (preferably at the last 3/0). Within the granule area. Supplements can be mixed at the same time or blended during continuous pellet precipitation In the container. Mutually improved non-SET Ir supplements are usually blended at their lowest effective concentrations. The comparison of the hydrazone and phase components can be performed by using nitrosyl or thionitrosyl-containing ligands (NZ supplements). 6) Coordination complexes enhance the particles, as disclosed in U.S. Patent No. 7,933,272 by McDougall (= DUgle). Contrast enhanced additives can be incorporated into the particle structure at any suitable location. Medium. However, if the NZ supplement is present on the particle surface, it can reduce the sensitivity of the particle I. Therefore, the Nz supplement is preferably located in the particle, so it precipitates all precipitated silver by forming iodized silver particles. At least ι% (preferably at least 3%) and separated from the particle surface. \ 2 The better contrast of the supplement is to increase the concentration in the range of 10-11 to 10-8 Moore per mole of silver, A particularly preferred concentration range is from 7 to ^ 8 Moore range per mole of silver tincture. Although various SET, non-SET Ir and NZ supplements are _ generally better concentration range: · ------- order --- ------ 丨 · (Please read the notes on the back before filling out this page) -35 588213 A7 Printed by the Bureau ’s Consumer Cooperatives. 5. Description of the Invention (34) Any useful K-sensitive silver, such as _Silver, can be used in the components used in this: Ming, preferably less than 10 grams per square meter. Silver. Silver I is preferably less than 7 g / m², and the amount of silver is even lower than 5 g / m². The silver amount of the improved element optics is lower, so it can be used to produce sharper images. These lower amounts of silver are more important in enabling the component to develop and remove silver quickly. Conversely, to achieve exposure latitude of at least 2.7 lOgE, on the one hand, maintaining a sufficiently low granularity position for the image to be enlarged requires per square meter Support a surface area of at least 1.5 grams of silver coated silver coating. BU contains at least one yellow dye imaging coupler, υ contains at least one magenta dye imaging coupler, and RU contains at least one cyan dye imaging coupler. A suitable combination of any conventional dye imaging coupler can be used. The conventional dye imaging coupling agent is disclosed by the above-exemplified research. I, X dye imaging agent and adjusting agent &apos; Photographic elements may further include other image-adjusting compounds, such as "development inhibitor-release" compounds (DIR). There are more dirs for the elements of the present invention, known in the art, and examples are in U.S. Patent Nos. 3,137,578; 3 ^ 48,022 3,148,062; 3,227,554; 3,384,657; 3,379,529; 3,615,506 3,617,291; 3,620,746; 3,701,783; 3,733,455 4,095; 049, 459, 126; 049 4,149,886; 4,150,228; 4,211,562 4,248,962; 4,259,437; 4,362,878; 4,409,323; 4,477,563 4,783,012; 4,962,018; 4,500,634; 4,579,816; 4,607,004 4,618,571; papers, 4,746,049, 959; 4,746,602; 959, 4,746,601; China National Standard (CNS) A4 Specification (210 X 297 mm) ------ Order --------- (Please read the notes on the back before filling this page) 588213 Intellectual Property Bureau of the Ministry of Economic Affairs Printed by employees' consumer cooperatives A7 B7 V. Invention Description (35) 4,946,767; 4,948,716; 4,952,485; 4,956,269; 4,959,299; 4,966,835; 4,985,336, and Patent Bulletin German Patent No. GB 1,560,240; GB 2,007,662; GB 2,032,914; GB 2,099 167; first DE 2,842,063; DE 2,937,127; DE 3,636,824; DE No. 3,644,416, as well as the following European Patent Publication No. 272,573; 335,319; 336,411; 346,899; 362,870; 365,252; 365,346; 373,382; 376,212; 377,463; 378,236; 384,670; 396,486; 401,612 ; Described in No. 401, 613. DIR compounds are also disclosed in "Developer-Inhibitor-Release (DIR) Couplers for Color Photography", CR Barr, JR Thirtle, and P.W. Vittum '' Photographic Science And Photographic Science and Engineering, Vol. 13, p. 174 (1969). It is common practice to apply one, two, or three historical JMLc liquid layers in a single dye imaging layer unit. When two or more emulsion layers are coated in a single layer unit, they are typically selected to distinguish between photosensitivity. When a higher-sensitivity emulsion is coated on a lower-sensitivity emulsion, a faster speed is obtained than when the two emulsion systems are mixed. When the lower-sensitivity emulsion is coated on the higher-sensitivity emulsion, the obtained pair is higher than when the two emulsion systems are mixed. Preferably, the most sensitive emulsion is located closest to the source of exposure radiation, and the lowest emulsion is located closest to the support. One or more layer units of the present invention are preferably subdivided into at least two, more preferably three or more sub-unit layers. It is preferable that all the photosensitive silver halide emulsions in the color recording unit have spectral sensitivity in the same visible spectrum region. In this specific embodiment, when the silver halide emulsion mixed in the unit has -38- this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --------- --------- tr --------- ^^ 丨 # (Please read the notes on the back before filling out this page) 588213 Printed by A7, Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Description of the invention (36) In the spectral absorption of the present invention, it is expected that there will be less 4 differences in spectral absorption between them. In a still better embodiment, the sensitivity of the slower-toothed silver emulsion is explicitly adjusted to account for the light-shielding effect of the faster silver halide emulsion in the layer units above it, so as to change from low to high with exposure The photometric green material provides a uniform spectral response across the entire image. Therefore, in slower emulsions with subdivided layer units, it may be desirable to have a higher proportion of peak light absorption spectrum photosensitizing dyes to illustrate the masking and relaxation of the peaks of photosensitivity in the lower layer. The inner layers IL1 and IL2 have a hydrophilic layer with reduced color pollution as their main function-that is, to prevent the oxidized developer from moving to the adjacent recording layer unit before reacting with the color coupling agent. The inner layer is somewhat simple and effective by increasing the length of the diffusion path that the oxidized developer must travel. In order to improve the efficiency of the inner layer to intercept the oxidized developer, the traditional practice is to mix the oxidized developer. Anti-staining agents (oxidized developer digesters) can be revealed from research. • Dye-forming agents and modifiers, D. Hue modifiers / stabilizers, those selected in paragraph ⑺. When one or more of the GU and RU silver emulsions are high bromide emulsions, and therefore have a significant negative sensitivity to blue light, it is preferable to mix a yellow filter in ili, such as Carey Lea silver Or yellow rinse solution can decolorize the dye. Appropriate yellow filter dyes can be selected from the researcher, section νιπ. Absorbing and Scattering Materials, B. Absorbing Materials. In the element of the case invention, the 'violet-red staining filter material lacks IL2 and ru. The anti-blooming layer unit AHU typically contains a rinsing liquid that can remove or decolorize a light absorbing material, such as a pigment and a dye or a combination thereof. Suitable materials can be selected from those disclosed in Research Disclosure I, Section VIII. Absorbent Materials. ^ Hu -39- This paper size is applicable to China National Standard (CNS) A4 (21〇X 297 mm) (Please read the precautions on the back before filling this page) ------- Order ---- ----- 588213 A7

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. A common alternative location for invention description (37) is between the support s and the green layer closest to the coating of the support. The surface covering layer SOC is a hydrophilic colloid layer, which is used to physically protect the color negative element during the processing process. Each Soc also provides a convenient location for admixtures that are most effective at or near the surface of the color negative element. In some examples, the surface cover layer is divided into a surface layer and an inner layer, the latter serving as a spacer within the surface layer and adjacent recording layer units. In another common variation, the addenda are located between the surface layer and the inner layer, the latter containing addenda that are compatible with adjacent recording layer units. Most typically this SOC contains additives such as coating auxiliaries, plasticizers and lubricants, anti-static agents and matting agents, as described in research reveals, Chapter IX • Coating Physical Properties Adjustment Additives. The soc covers the emulsion layer and preferably additionally contains an ultraviolet absorber, as described in Research Rev. J, chapter v · uv dyes / optical brighteners / luminescing agents, paragraph (1). Instead of the layer unit sequence of the element SCN-1, alternative layer unit sequences can be used and are particularly attractive for some emulsion options. Use of noble gas emulsions and / or thin (&lt; 0.2 micron average particle thickness) flat plate-like particle emulsions can ensure all possible alternate positions of BU, GU, and RU positions, providing less negative blue to record the risk of blue light pollution Because these emulsions exhibit tiny innate sensitivity in the visible spectrum. For the same reason, it is not necessary to incorporate a blue light absorber in the inner layer. When the speed of the emulsion layer in the dye imaging layer unit is different, the traditional practice is to limit the dye imaging coupling agent blended in the higher speed layer to less than the stoichiometric amount, based on silver. The function of the highest speed emulsion layer is to produce characteristic curve -40- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------------ -Order --------- 丨 · (Please read the notes on the back before filling out this page) 588213 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 —1__ ' ) The line is just south of the lowest-density shao-the exposure area that is lower than the door shake sensitivity of the remaining emulsion layer in the layer unit. In this way, adding the highest sensitivity speed emulsion layer with increased particle size to the resulting dye image recording is minimized without sacrificing development speed. In the above discussion, the blue, green, and red recording layers are described as yellow-purple and cyan-containing image color couplers, as is the traditional practice of color negative elements for printing. The present invention can be suitably applied to the conventional color negative film structure exemplified. The reverse color film structure will take a similar form, except that the color modification coupling agent will be completely absent; in a typical form, the development inhibitor release type coupling agent will also not exist. In a preferred embodiment, the color negative element is limited to scanning to produce three individual electronic color greens. Therefore, the positive tone produced by dyes is not important. It is absolutely necessary that the stained image produced only in each layer unit is different from that produced in each remaining layer unit. To provide this discrimination, each layer unit is expected to contain one or more selected dye imaging coupling agents to produce imaging dyes with absorption half-peak bandwidths in different spectral regions. Blue, green, or red records whether the green layer unit forms a yellow, magenta, or cyan dye with an absorption half-peak bandwidth in the blue, green, or red region of the spectrum, as insignificant as traditionally used in color negative elements intended for printing The absorption half-peak bandwidth in the spectrum, or in any other suitable region of the spectrum, ranges from near-ultraviolet (300-400 nm) to visible and near-infrared (70CM200 nm), as long as the absorption of the image dye in the layer unit The half-peak bandwidth extends beyond the substantially non-coextensive wavelength range. "Substantially non-co-extending wavelength range" means that each image dye exhibits an absorption half-peak bandwidth that extends beyond at least 25 (preferably 50) nanometer spectral region, and this region is not another -41-This paper scale applies Chinese National Standard (CNS ) A4 size (210 X 297 Gongchu) (Please read the notes on the back before filling out this page} Write this page ------ tr --------- 588213 A7 B7 V. Description of the invention (39) The absorption half-peak bandwidth of the image dye is occupied. Ideally, the image dyes exhibit mutually exclusive absorption half-peak bandwidths. (Please read the precautions on the back before filling this page.) When the layer sheet contains two or more different speeds In the emulsion layer, by forming a dyed image in each emulsion layer of the layer unit, the absorption half-peak bandwidth is located in different spectral regions, and the image granularity of the image to be observed and reconstructed from the electronic record is reduced below the layer. Dyeing images of other emulsion layers in the unit. This technique is particularly suitable for elements in which the layer unit is subdivided into sub-units of different speeds. This allows each layer unit to generate multiple electronic records, which is equivalent to the same spectral sensitivity. Different dyeing images formed by the emulsion layer. The digital record formed by scanning the dyeing images formed by the highest-speed emulsion layer is used to modify the dyed image to observe the portion just above the lowest density. At higher spectral luminosity, the second and the visual The required third electronic record green can be formed by scanning the spectrally differentiated stained images formed by the remaining emulsion layer. These digital records contain lower noise (lower granularity) and can be measured on the threshold spectrum of the slower emulsion layer Reconstruct the image to be observed over the exposure range. This technique for reducing the granularity is disclosed in more detail by Sutton in US Patent No. 5,314,794. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the layers of the color negative element of the present invention The contrast coefficient of the characteristic curve of the dyed image produced by the unit is lower than 1.5, which helps to obtain an exposure latitude of at least 2.7 log E. The minimum acceptable exposure latitude of a multi-color photographic element is to allow correct interpretation of what has occurred in photographic applications. The most extreme white (such as a bridal gown) and the most extreme black (such as a groom's tuxedo). Exposure latitude 2.6 l og E is able to accommodate typical bride and groom wedding scenes. Exposure latitude is at least 301 g. E is better because it allows photographers to choose a fairly margin of error for exposure. Even larger exposure latitude is particularly preferred because Achieved with large exposure error -42- This paper size 剌 τ National Standard (CNS) A4 size x 297 public ^ 7 A7 B7 Printed by the Ministry of Smart Financial Staff Consumer Cooperatives V. Description of the invention (4〇) = True image weight At the time when the expected negative value of the color negative element of the used film to the print film is abnormally low, the number of color negative films that are often lost due to the loss of the printed scene can be scanned to generate a digital dye image. The contrast can be adjusted by adjusting Electronic signal information. When scanning an element of the invention using a reverse + first beam, the beam moves through the layer unit twice. This: Effectively doubles the density by the density ⑽) (there is-to-times. So 'includes a low contrast factor like 1G or even G6 and an exposure latitude of about 5.01 gE or higher It is feasible. Contrast coefficient of about 0.55 is preferred. Contrast coefficient of between about 〇4 and 〇5 is particularly preferred. Without the use of a color coupling agent, it can produce any dyed image traditionally mixed in multi-color development. Compounds are incorporated in the blue, green, and red recording layers. Dye images can be selectively destroyed, formed, and physically removed as a result of exposure. For example, silver dye bleach processing is well known and commercially available. The above series is used to form dye images by selectively destroying the mixed image dyes. The silver dye bleaching method is revealed by research], Chapter χ Dyeing Image Forming Agents and Regulators, A. Silver Dye Bleaching Instructions. Pre-imaging dyes can It is also well known that it is mixed in blue, green and red recording layer units. The selected dye is initially fixed, but it can be released as it enters the redox reaction with the oxidized developer. The dye chromophore in the moving part. These compounds are commercially referred to as redox dye release agents (RDR). By washing away the released mobile dye, the retained dyed image can be scanned. The released mobile can also be released. The dye is transferred to the receiver, where the receiver is fixed in the mordant layer. After that, the film receiver can be scanned. Initially, the receiver is a complete part of the color negative element. When -43-This paper standard applies to China Standard (CNS) A4 specification (21G X 297 public love — 588213 A7 B7 V. Description of the invention (41) When scanning with a receiver that maintains a complete part of the component, the receiver typically contains a kind of transparent support 'load dyeing' The image mordant layer is just below the support body, and the white reflective layer is just below the mordant layer. The receiver support can be reflective when the receiver is peeled from the color film element to help scan the dyed image. When the dye is expected to be observed It is the most common choice when imaging, or it is transparent, which allows transmission to scan the stained image. RDR and their mixed dye image transfer systems were established in 1976 1 January research reveals that it is described in Volume ι51, Item 15162. It is also understood that the stained image can be provided by a compound that was initially movable but was given immobility during full-image development. Using this form of developing dye; image transfer The systems have long been used in previously disclosed dye image transfer systems. These and other image transfer systems that are compatible with the practice of the present invention were disclosed in the December 1978 Research Reveal 'Volume 176, Item 17743, XXIII · Image Transfer System Many color negative elements have been suggested for regulating scanning, as described in Research Reveal I, Chapter XIV. Scanning Help Features. These systems are included in the practice of the present invention to the extent that the color negative elements are structurally compatible as described above. It is expected that the developing element of the present invention can be used with non-conventional photosensitive designs. For example, instead of using a developing layer that is sensitive to the red, green, and blue regions of the spectrum, the photosensitive material may have a white photosensitive layer to record the luminous density of the scene, and a two-sensitive color layer to record the chromaticity of the scene. After development, the resulting image can be scanned and digitally reprocessed to reconstruct the full color of the original scene, as described in US Patent No. 5,962,205. The developing element can also include a pan-sensitizeci milk with a color separation exposure -44- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Fill in this page again)

^ 9 ------- tr --------- L Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 588213 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 V. Description of the Invention (42) Liquid . In this embodiment, the .1 φ ^ ^ developer causes a kind of staining. „丄 丄 The moon dagger is enough to fully restore the original scenery, Yi Cai. In this element, the image is scarce and you can see the quality of the developed silver, a combination of one or more traditional conjugates. ^ Bi ^ ^ + especially the resorcinol coupling agent, especially through the appropriate filter in order, at two o'clock: from the discontinuous mirror element (often referred to as "color ㈣ development element can also be A black-and-white developing material, which includes: a fully photosensitive auto-silver emulsion and an agent of the present invention. In this embodiment, the image can be formed by developing the density of the developed silver followed by processing, or by producing The coupling agent of the dye that drives the neutral image tone ratio produces 0. When the traditional yellow, magenta or cyan image dye is formed to analyze the recorded scenes for exposure, following the chemical development of traditional exposure color photographic materials, the components are red, green and blue. The response of the recording unit can be accurately discriminated by detecting its density. The optical density method is a transmission light measurement of a fake, which uses a selected colored filter to separate the full image response of the RGB dye imaging unit into a correlation (Independent channel. The status MEMS mirror is often used to judge the response of the color negative element expected for photon printing, and the inverse color film expected to be used for direct transmission observation is to use the Status A filter In complete densitometry, unwanted side and tail absorption in imperfect images cause a small amount of channel mixing, of which, for example, the full response part of the magenta channel can come from the yellow or cyan image dye records in the mid-color characteristic curve or two Non-sharp ridge absorption. This kind of epigenetic can be ignored when measuring the spectral sensitivity of the film. -45- This paper standard meets 1P National Standard (CNS) A4 specification (21〇X 297 public love) (Please read first Note on the back, please fill out this page) I. ------- tr --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 213 5. Invention Description (43)

phenomenon. By properly processing the complete density response, these undesired &lt; non-spike density distributions can be fully corrected to provide analytical density, where the given color # 己 录 &lt; response is independent of the spectral distribution of other image dyes. Analytical Density Measurements are Extracted from the SPSE of Photographic Science and Engineering, W. Thomas, Author, John Wiley and Sang, New York '1973 , Chapter 15.3, Color Optical Density Analysis, ρρ · 840-848. The moon dagger can reduce the noise of the shirt. By scanning the exposed and processed color negatives, a convertible electronic record of the image totem is obtained, and then the adjusted electron 1 is converted into an observable form to obtain an image. . Image sharpness and color appearance can be improved by designing the layer contrast coefficient ratio within a narrow range. On the one hand, it avoids or minimizes other performance disadvantages. Among them, the green color system is used to transform the color image to be observed. The electronic form cannot separate the image noise from the rest of the image information. Whether it is printed during printing or by changing the electronic image to record green, the electronic image record with low noise can be adjusted as if it has a low contrast coefficient. The proportional color negative element provides the same, but with a general curve shape and sharpness characteristics that can not be achieved by known printing technology. Therefore, it is possible to reconstruct an image from an electronic image derived from such a color negative element, which is superior to those similarly derived from a conventional color negative element constructed for optical printing applications. When the contrast coefficient ratio of each of the red, green and blue recording units is lower than 12, the excellent developing characteristics of the element are obtained. In a better specific implementation, the ratios of the contrast coefficients of the red, green, and blue photosensitive color rendering units are each low; 1.15. In an even better specific embodiment, the red, green and blue sensations -46- κ paper size is applicable to China National Standard (CNS) A4 specifications (21 × 297 mm)

— — — — — — Ti! _% (Please read the notes on the back before filling out this page) 588213 A7 B7 V. Description of the invention (M) The ratio of the contrast coefficient of each light-colored unit is less than 110. In a preferred embodiment, each of the red, green and blue photosensitive color-forming units exhibits a contrast ratio of less than 1.10. In all cases, it is preferred that the individual color units exhibit a contrast coefficient ratio of less than 1.15, more preferably that they exhibit a contrast coefficient ratio of less than 110, and even better that their main present contrast coefficient ratio is less than 1 ·. The contrast coefficients of the layer units need not be equal. These low-contrast coefficient ratios are indicators of low-private inner-parent interactions between layer units. They are also known as inter-layer image effects, and are used to explain the improved quality of images after scanning and electronic transformation. Visually unfavorable images resulting from chemical parent interactions between layer units do not need to be electronically suppressed during image transformation actives. Interactions are often difficult if they cannot be properly suppressed using known electronic image transformation designs. Elements with excellent sensitivity are best used in the practice of this invention. The element should have a sensitivity of at least ISO 50, preferably have a sensitivity of at least ISO 100, and more preferably have a sensitivity of at least ISO 200. This includes components with a sensitivity of ISO 3200 or higher. The speed or sensitivity of a color negative photographic element is inversely related to the exposure required to obtain a specific density higher than the haze after processing. The photographic speed of a color negative element having a contrast coefficient of approximately 0.65 in each color record is clearly defined by the American National Standards Institute (ANSI) as the ANSI standard digital PH 2.27-1981 (IS0 (ASA Speed )), Especially in the green film and the lowest-sensitivity color recording unit in the color film, the average degree of exposure required to produce a density higher than the minimum density of 0.15 is evenly related. This definition conforms to the ISO film speed evaluation. For the purpose of this application, if the color unit contrast coefficient is different from 0.65, the ASA or ISO speed will be -47- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back first (Fill in this page again)-! S Order --------- * ^^ 1 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 588213

(45) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Consumption Cooperative. 2 Before the speed is defined in a time-defined manner, "the coefficient of contrast relative to the log E (exposure) curve is linearly large or not enlarged to ㈣. The present invention also includes the use of the photographic element of the present invention as a single-use camera (or film with lens unit). These cameras are sold pre-loaded with film and the exposed film is retained The entire camera is returned to the processor in the camera. The single-use camera used in the present invention can be any person known in the art. These cameras can provide specific features known in the art, such as shutter devices, film rolling devices , Push device, waterproof frame, single or multiple lens, lens selection device, variable aperture, focal length lens, device to monitor the lighting environment, adjust the shutter exposure time or according to the lighting environment or the characteristics of the lens provided by the user. And cameras will use a ring mirror to record directly on film. These features include, but are not limited to: Provides manual or automatic slide and reset shutter simplification mechanism as described in US Patent No. 4,226,5 17 of Skarman; provided in US Patent No. 4,345,835 of Matterson et al The automatic exposure control device described; moisture-proof as described in US Pat. No. 4,766,451 of Fujimura etal; provision of internal and external parts as described in US Pat. No. 4,751,536 of Ohmura Film cassette; device for recording use environment on film as described in US Patent No. 4,780,735 by Taniguchi; provided with mounted lens camera as described in US Patent No. 4,804,987 of Arai ; Providing a film support having excellent anti-curling properties as described in US Patent No. 4,827,298 of Sasaki et al; providing a viewfinder as described in US Patent No. 4,812,863 of Omla et al;- 48- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ——— Order · 丨 丨 丨 丨 · (Please read the precautions on the back before filling this page} 5882 13 A7 B7____ V. Description of the invention (46) Provide a lens with a defined focal length and lens speed as described in US Patent No. 4,812,866 of Ushiro et al; provide the United States of America Nakayama et &amp; 1 Patent Nos. 4,831,398 and Umella &amp; 1 U.S. Patent No. 4,833,495, multiple film containers; provided with Shiba's U.S. Patent No. 4,866,469, films with improved anti-friction characteristics Provide the reeling mechanism, rotating reel, or flexible cassette described in US Patent No. 4,884,087 to Mochida; provide US Patent Nos. 4,890,130 and 5,063,400 to Takei et al A film patrone or a film cassette that can be moved in the axial direction as described in the above; an electronic flash device described in U.S. Patent No. 4,896,178 of Omra et al; and a U.S. Patent No. 4,954,857 provided by Mujida et al Said externally operable member for effective exposure; provided in Murakami U.S. Patent No. 5,049,908, a flexible sheet support having an adjusted pinion gear hole and advancing the soft Device; provided with an internal mirror as described in U.S. Patent No. 5,084,719 to Hara; and provided in European Patent Application No. 0,466,417 A for Yagi etal for use on a tight-winding reel Silver halide emulsion. The film can be mounted in a single-use camera in any manner known in the art, and it is particularly preferred to mount the film in a single-use camera so that the film is pushed into the cassette to begin exposure. The push-in box is made up of U.S. Patent No. 5,226,613 by Kataoka et al; U.S. Patent No. 5,200,777 by Zander; U.S. Patent No. 5,031,852 by Dowling; and Robertson ( (Robertson) et al, U.S. Patent No. 4,834,306. Narrow body single pusher using push-in box in this way -49- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back and fill in this page)- ------ tr --------- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 588213 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (47) The camera is used by US Patent No. 5,692,221 to Tobika et al. More broadly, the limited-size cameras that are most useful for single-use cameras are generally rectangular in shape and meet the requirements for ease of handling and mobility in, for example, a pocket, when the cameras described herein have a limited volume. The total camera volume should be less than about 45 cubic centimeters (cc), more preferably less than 380 cc, more preferably less than 300 cc, and most preferably less than 22 cc. In order to provide comfortable grip and fit in a pocket, the depth-height-length ratio of this camera will usually be about 1: 2: 4, each range is about 25%. Usually the minimum usable depth is set by the focal length of the combined lens and the size of the combined film reel and filmmaker. Cameras usually prefer a radius of curvature of most corners and edges between about 0.2 and 3 cm. The use of a push-in cassette provides a special advantage of the present invention 'in that it provides a simple scanning method for a photographic transported object on a roll, on the one hand, protecting the film from dust, scratches, and abrasion, all of which tend to degrade image quality. ′ While any known finder lens can be used in the camera of the present invention, the single-use framing lens mounted on the single-use camera of the present invention is preferably a single non-shaped plastic lens. The focal length of these lenses will be between about 10 and 100 mm, and the lens aperture will be between f / 2 and f / 32. The focal length is preferably between about 15 and 60 mm, and most preferably between about 20 and 40 mm. Regarding painting applications, the focal length is better than 25% of the exposure area of the rectangular film. The second lens aperture between f / 28 * f / 22 includes lens apertures of about f / 4 to f / 16. In the film plane lens, the MTF can be as low as 〇6 with a frequency of 20 lines per millimeter (1 pm). Although the volume includes 咼 like 0.7 or the best 0.8 or higher. Higher The lens MTF 値 allows for sharper images. In particular, it includes two types, three == ___ -50- This paper size is applicable to the Chinese national standard (〇sfS) A4 specification (210 X 297 public love) 丨 丨 丨--- ----- Order --------- 丨 · (Please read the precautions on the back before filling out this page) V. Description of the invention (48) More functional-the multi-lens arrangement of the component lens. ; == Built-in processing capability, such as heating elements. This 9;,; = The design of the image capture and display system is based on Ru Ru, the patent is described in the Wu patent, please serial number 009 / 388,573 = The disclosure of the use of the single-use camera in the practice of the present invention especially includes the use of any known technique for full-image exposure, as disclosed in Section XVI. This typically includes exposure, and Light, this exposure is typically a vivid shadow through a lens ^, although exposure can also use light emitting devices (such as Volume, crt, etc.) are exposed to stored images (such as computer storage images). Photothermographic elements also use various energy forms to expose 'including the ultraviolet and infrared regions of the electromagnetic spectrum, as well as electron beam and krypton radiation, r-rays, X · Rays, & particles, neutron radiation, and non-homogeneous (arbitrary phase) or homogeneous (in-phase) particle wavy radiant energy produced by laser. Exposure is monochromatic, monochromatic, or panchromatic Depending on the spectral sensitivity of the photographic silver halide. The elements discussed above can be used as the starting material for some or all of the following processing: image scanning produces an electronic interpretation of the captured image, which is then digitally processed for electronic operation , Store, transmit, output 'or display the image. The barrier compound of the present invention can be used in photographic elements including any or all of the above characteristics, but is expected to be used in different processing forms. These system forms will be described in detail below. Forms I: Thermal processing system (thermal green and light thermal photography), of which -51-This paper size is applicable to Chinese national standards (CNS) A4 specification (210 X 297 Gongchu) A7 V. Description of the invention (49) B7 Printing and processing by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is started by applying heat to the developing element. Form II: Low-volume system 'Where the film processing is started, but the processing is assisted by contact processing, such as the processing force, including the addition of non-solution processing, such as heat or lamination applied during the processing time. Form III: Traditional camera system , Its photo, φ, Qin, Yu; 4, by contact with the traditional '/ wash processing, the volume of such solutions is very large compared to% &gt; volume. State branch in the layer (form I · Thermally sensitive green and photothermographic systems According to one aspect of the present invention, the blocked developer is incorporated in a photo-salt thermographic π. The study reveals the photothermographic format described in 17㈣ and is available for reference. The photothermographic element may be a type A or a type B as described in the research revealing process. The type A element contains a photosensitive silver-based reactivator or developer, a activator, and a coating medium or a binder. In these systems, development occurs by reducing silver ions in inductive silver to metallic silver. The B-type system can contain all elements of the A-type system in addition to salts or complexes of organic compounds and silver ions. In these systems, this organic complex is reduced during development to produce silver metal. The organic silver salt will be referred to as a silver precursor. References describing such developing elements include, for example, U.S. Patent Nos. 3,457,057; 4,459,350; 4,264,725 and 4,741,992. The photothermographic element includes a photosensitive component which consists essentially of a photographic silver halide. In the B-type photothermographic material, the latent image silver derived from self-chemical silver is used as a catalyst for the imaging combination when processed. In these -52- this paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) ^ 9 ------- Order ---------% 1 · (Please read first Note on the back, please fill out this page again) 588213 A7 B7-------- 丨-V. Description of the Invention (50) In the system, the photo is taken in the photothermographic material. The ear silver body is in the range of 100 to 100 moles of silver halide. Type B photothermographic elements include a redox imaging conjugate containing an organic silver salt oxidant. Organic silver salt is a kind of silver salt, which is relatively singular to light, but when heated to 80 ° C or high temperature in the presence of an exposed photocatalyst (ie, photosensitive silver halide) and a reducing agent, it helps to form a silver image . Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs ------- Order: (Please read the precautions on the back before filling this page) Appropriate organic silver salts include carboxyl groups Silver salts of organic compounds. Preferable examples thereof include salts of an aliphatic polyacid and silver salts of an aromatic acid. Preferred examples of silver salts of aliphatic carboxylic acids include silver behenate, silver stearate, silver oleate, silver laurate, silver decanoate, silver myristate, silver palmitate, and maleic acid. Silver acid, silver fumarate, silver tartrate, silver furoate, silver mulberry acid, silver butyrate, and silver malate, mixtures thereof, and the like. Silver salts substituted with halogen elements or hydroxyl groups can also be effectively used. Preferable examples of the aromatic quinic acid and other compound-containing silver salts include silver benzoate, substituted silver benzoate, such as silver 3,5-dihydroxybenzoate, silver o-fluorenylbenzoate, m-formyl Silver benzoate, semi-p-methylbenzoate, silver 2,4-digas benzoate, silver acetamide, silver p-phenylbenzoate, etc., silver gallic acid, silver tannin, gj; Acid silver, silver terephthalate, silver salicylate, silver acetoacetate, silver pyromellitic acid, 3-carboxymethyl-4-methyl-4-pyrazolin 2.thione or as U.S. Patent No. 3,785,830 Analogs described in No. 3, and silver salts of aliphatic carboxylic acids as described in U.S. Patent No. 3,330,663. In particular, silver salts of compounds substituted with thiol or thioketones have a heterocyclic nucleus containing 5 or 6 ring atoms, at least one of which is nitrogen, and other ring atoms include carbon, and up to two selected from oxygen, sulfur, and nitrogen. Heteroatom. It is typically -53- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) A7 B7 V. Description of the invention (51) Good heterocyclic nuclei include triazole, &quot; sedazole, thiazoline, Pyrimazole, Pyramid Sit, Two Sit, Sit cold one (please read the notes on the back before filling this page) and Erqian. Examples of these heterocyclic compounds include the silver salt of winter soil 2,4-diazole, the silver salt of 2-mercaptopyrazole, the silver salt of 2-sulfo: 5 · amine 4 diamidine, 2_ (2 · B Ethylene glycol donkey amine) silver salt of benzopyrene 'Ί1 :: Silver salt of phenyl-2 · phenyl-4-pyrene, silver salt of succinic acid' 2-green winter and P number TT sitting phase The silver salt of t | ° '丨, 2,4-pyrtriazole derivative in U.S. Patent No. 4,123,274, such as 3-amino-5, ^^ 3_ ^ 6 ΐ: diΓ ...- sulfur Ketone silver salts, such as U.S. Patent No. 3, _ Heterocyclic nucleus-containing thiol or copper sulfide substitution: "Useful" The example is as follows: silver salt of thioacetic acid, such as S-burn, silver salt of ethano ( Wherein the calcined group has _ carbons, as described in Application No. 28221/73, a silver salt of a dithiocarboxylic acid, such as a silver salt of dithioacetic acid and a silver salt of thiamidine. Imine: Silver salt of a compound. Preferred examples of these compounds include silver salts of benzotris (3) derivatives,% printed by Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs = No. 027/69 and- As described in, for example, benzotris. Instead of silver benzotritonate, such as 5. silver benzotriwa silver salt, etc., U, 4-tri-salt silver salt, 3. amine hydrazone], 2,4_tri slave silver salt 'is a US patent No. 4,22〇, Xiezhongzhongjin ... H-tetrazole'pyrazole and silver salts of pyrimazole derivatives, and the like. It is also found that silver half I is used, in which by Mortar ginseng blends such as sodium behenate were prepared by reducing precipitation in sleeping water, and analyzed about M ″ -54- This paper size is suitable for financial standards (CNS) A4 (210 X 297) Chu 213 A7- --------- ---_ B7___ V. Description of the invention (52) ~ '~ Percentage silver, which is a preferred example. The transparent thin-film material tuned transparent coating manufactured on the transparent film lining is For this purpose, it is possible to use all-inclusive silver-tetracosamate containing no = or 5 percent free behenic acid and analyzing about 25 2 percent silver. The method of making a silver-clad dispersion is well known in the art ^ And disclosed in the research of October 1983 (23419) and U.S. Patent No. 3,985,565. The silver salt complex can also be mixed with silver ion water species aqueous solution, such as silver acid, and the complex with silver. The solution of organic ligands is prepared by mixing. The method of mixing can take any form, including the silver precipitation method. The stabilizer can be used to avoid flocculation of the silver complex particles. The stabilizer can be any known available Materials for photographic technology, such as, but not limited to, gelatin 'polyethylene glycol or polymers or monomeric surfactants. Photosensitivity_Silver particles and organic silver salts are coated, so the catalyst is approximately the same during development. It can be applied in a continuous layer, but it is preferably mixed before coating. The traditional mixing technology is revealed by the research exemplified above, page 1729, and US Patent No. 3,700,458 and published Japanese Patent Application No. 32928 / 75, 13224/74, 17216/75 and 42729/76. A reducing agent may be included in addition to the blocked developer. The reducing agent for the organic silver salt may be any material capable of reducing silver ions to metallic silver, and an organic material is preferred. Conventional photographic developers, such as sigmazolide, are useful for amines, p-phenylamine and catechins, but are better for reducing agents. The reversion agent is preferably present at a concentration between 5 and 25 percent of the photothermographic layer. Various reducing agents were revealed in the dry silver system, including ammonium fats, such as -55- This paper size is applicable to China National Standard (CNS) A4 specifications (21〇X 297 mm) --------- · %! (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by 588213 A7 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, 5. Description of the Invention (53) Amphoxime , 2-pyrimoxime oxime and p-phenoxy-amidooxime, cultivated species (for example, 'hydroxy_ 3,5-dimethoxybenzaldehyde cultivation); a combination of an aliphatic carboxylic acid aryl amidine and ascorbic acid' such as 2,2, _Bis (methyl) propanyl, phenyl, phenyl, and ascorbic acid; a combination of polyphenylene and hydroxylamine, reducing ketones, and / or cultivating, for example, from Kun and bis (ethoxyethyl) ) Hydroxyamine conjugates, piperidine hexose reducing ketone or methyl-4-methylphenyl, hydroxamic acid or phenylhydroxamic acid, p-hydroxyphenyl-isohydroxamic acid, and ortho Alanine hydroxamic acid; Teng and sulfamethoxols, such as' non-groin and 2,6-dioxo-4-phenylamine amines; &amp; _ cyano-phenylacetic acid derivatives, such as α _ Cyano Ethyl-2-methylphenylacetate, α-cyano · phenylethylacetate; bis-fluorenol, such as from 2,2, -dihydroxy-1 · dimosyl, 6,6, -dibromo -2,2'-dihydroxy-1,1'-difluorenyl, and bis (2-hydroxyfluorenyl) methane; bis-o-o-phenol and a 1,3-dihydroxybenzene derivative Conjugates (for example, '2,4-monobenzophenone or 2,4-dienylacetone); such as ^ 5-pyrazolidine of phenyl-5-pyrazolidine; Methylaminohexose reducing ketones, anhydrous monohydroaminohexose, and reducing ketones as described by water dihydro_hexahydroρbitalone_hexose reducing ketones; sulfofluorenediamine phenol reducing agents, such as 2,6 _Dichlorobenzene-sulfofluorenyl_ fluorenylamino-phenol, and p-toluenesulfanilide; 2-benzindene 4,3_dione, etc .; benzodihydropiranes, such as 2,2-bis Methyl-7-tert-butylhydroxybenzodihydropiran; 1,4-dihydropyridines, such as 2,6-dimethoxy-3,5 • diethoxycarbonyl-1,4-a Hydropyridine; bisphenols, such as bis (2-hydroxy · 3-tertiarybutyl-5-tolyl) methane; 2,2-bis (4-hydroxy-3 · fluorenyl) · propane; 4, 4 • Ethylene · bis (2-tertiarybutyl-6-cresol); and 2,2-bis ( 3,5-dimethyl-4-hydroxyphenyl) propane; ascorbic acid derivatives, for example, ascorbyl palmitate, ascorbyl stearate, and unsaturated aldehydes and ketones, such as benzyl and diacetamidine Base; Py-56- This paper size applies Chinese National Standard (CNS) A4 Regulation @ 10 X 297 Public Love) (Please read the precautions on the back before filling this page) Ρ · 11111111% ·

588213 V. Description of the invention (54) Salidin-3-one; and certain hydroindenes, fluorenediones. The organic reducing agent θ 7 d in the photothermographic element depends on the optimum concentration, such as the photothermographic element, and it is hoped that it will be compatible with the host &lt; shirt image, processing environment, specific organic silver salt and specific oxidant . The heat-sensitive 7G piece can include a conditioner, which is also known as an activator toner or a toner accelerator. Toner combinations are also useful in photothermographic elements. Examples of useful toners and toner combinations are described, for example, in Research Disclosure, June of next year, item 17029 and U.S. Patent No. 4,123,282. Examples of useful toners include, for example, dimethylformamide imine, N-hydroxybenzidine imine, N-potassium xylylenediamine imine, succinimide, N-^- 1,8-pyridine diimide, phthalocyanine, bu (2H) 'phytonone, 2-ethyl acetophthalone, salicylanilide, benzamidine, and dimethyl urea. Post-processed image stabilizers and latent image retention stabilizers are useful for photothermographic elements. Stabilizers known in any photothermography technique are useful for the photothermographic element. Illustrative examples of useful stabilizers include, for example, photolytically active stabilizers and stabilizer precursors as described in U.S. Patent No. 4,459,350. Examples of other useful stabilizers include pyrrole ethyl sulfide and blocked azolinethione stabilizer precursors and carbamate stabilizers, as described in U.S. Patent No. 3,877,940. The photothermographic element preferably contains various colloids and polymers alone or in combination with, for example, a vehicle and a binder, or in various layers. Useful materials are hydrophilic or hydrophobic. It is transparent or translucent and includes naturally occurring substances such as gelatin, gelatin derivatives, cellulose derivatives, polysaccharides such as polydextrose, acacia, etc .; and synthetic polymer materials such as water-soluble polyethylene- 57- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 public love) — — — · · · · · · · · · · · · (Please read the precautions on the back before filling this page) Economy Printed by the Consumer Cooperative of the Ministry of Intellectual Property Bureau of the Ministry of Economic Affairs 588213 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 ____ B7_____ 5. Description of the invention (S5) -based compounds, such as poly (ethylpyrrolidone) and propylammonium polymer Other useful synthetic polymeric compounds include dispersed vinyl compounds, such as in the form of latexes, especially those that increase the dimensional stability of photographic elements. Effective polymers include acrylates such as alkylpropionate and methylpropionate, propionate, water-insoluble polymers of sulfoacrylate, and those having cross-linked sites. Preferred high molecular weight materials and resins include poly (acetonitrile), cellulose acetate, butyric acid, poly (methylpropionate), poly (ethylene P to P, each ketone), and ethyl acetate. Cellulose, polystyrene, polyethylenic acid), gasified rubber, polyisobutylene, butadiene-styrene copolymer, gaseous ethylene and ethyl acetate acetate, gaseous ethylene and vinyl acetate Copolymers, poly (acetol) and polycarbonate. When the coating is made of an organic solvent, the organic soluble resin can be applied by directly mixing it with the coating formulation. When applied from an aqueous solution, any useful organic soluble material can be blended like a latex or other fine particle dispersion. The photothermographic element can contain additives known to help form a useful image. Photothermographic elements can contain development modifiers that function as speed increasing compounds, photosensitizing dyes, hardeners, antistatic agents, plasticizers and lubricants, coating additives, brighteners, absorption and filter dyes, as revealed by research No. 17743 of December Project No. 1978 and research revealed that it was described in No. 17029 of June 1978 Project. Photosensitive element layers are applied to the support by coating steps known in the photographic art, including dip coating, air knife coating, curtain coating, or extrusion coating using an addition funnel. If necessary, two or more layers may be applied simultaneously. p • 58 'This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

ϋ ϋ ϋ H -H ϋ ^ OJ · —Bi 1 · 1 I% 588213 A7 B7 V. Description of the invention (56) The photothermographic element printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs preferably includes a thermal stability Agents to help stabilize the photothermographic elements during exposure and processing. This thermal stabilizer provides the stability of a photothermographic element during storage. The preferred thermal stabilizer is 2-bromo-2-arylsulfoacetamidine, such as 2-bromo-2-p-toluenesulfonylacetamide; 2- (tribromosulfanyl) benzopyrimidine Azole; and 6-substituted-2,4-bis (trifluoromethyl) -secondary triple farming, such as 6-methyl or 6_phenyl-2,4_bis (tribromomethyl) · secondary triple p well. The full-image exposure preferably lasts for a period of time and is strong enough to produce a developable latent image in the light-sensitive thermal imaging element. The latent image produced after the whole image of the photothermographic element is exposed can be developed in various ways. The simplest is to heat the entire component to the hot processing temperature. This overall heating only includes heating the photothermographic element to about 90. Temperatures in the range of 0 to about 18 ° C, until a developed image is formed, such as in about 0.05 to about 60 seconds. It is useful to increase or decrease the temperature of the thermal processing process, and it is useful to increase or decrease the processing time. The best thermal processing temperature is in the range of about 160 ° C. Additions known in photothermography # are used to provide the exposed photothermographic elements. The desired temperature: add bulk '=, simple heating Plate 1 bucket 'light, heating barrel, microwave addition device, heating air, steam, etc. It is expected to be used for the development of photothermographic elements +-, 7 factory bucket, fan, 丄 i processors designed and used for storage &lt; Cassette or cassette design and the use of the element or the data on 11 can be used to adjust the element ,,,:,. In addition, to store soft traces. To complete the steps in these development systems, ', processing conditions Or Scanned U.S. Patent No. 09/206586 and U.S.A. * Issued 'Co-suspension U.S. Patent Nos. 6,062,746 and -59- This paper uses Chinese National Standard (CNS) A4 specifications (21G X 297) ) (Please read the notes on the back before filling (This page)%

i ^ i ϋ I n 1- ^ δ ,, i n I ϋ ϋ I%. 588213 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (57) No. 6,048,110. A device is used in which the processor can be used to write information on the component, and it can also be used to adjust the processing, scanning and image display information. This system is disclosed in European Patent No. 1,008,901, published on June 14, 2000, and US Patent Application Serial No. 09 / 333,092, issued June 5, 1999. The thermal processing is preferably performed under the pressure and humidity of the surrounding environment. Environments other than normal atmospheric pressure and humidity are useful. The photothermographic component can be located anywhere within the element, which provides the desired image. If necessary, one or more components can be in one or more pieces. For example, in some examples, it is desirable to include a percentage of reducing agent, toner, stabilizer, and / or other additives on the photothermographic image recording layer of the element. In some examples, this reduces the migration of certain add-ons in the component layer. According to an aspect of the present invention, the blocked developer is incorporated in a photothermographic element. In a thermal recording element, an image is formed by heating the cell with a full image. Such elements are described, for example, in Research Disclosure, June KM, Project No. 17029, and U.S. Patent Nos. 3, _, 254, 3,457,075, and 3,933,508. The thermal energy source and device used for development can be any full-image thermal exposure source and device known in the art of thermal recording. The thermal recording image device can be, for example, an infrared heating device, a laser, a microwave heating device or the like. Form Π: Low-volume processing: According to the viewpoint of the present day, the blocked developer is incorporated in a photographic element for low-volume processing. Low-volume processing is defined as _ -60 · Σ paper size applicable to Chinese National Standard (CNS) A4 specifications ⑵〇x 297 public love) —---- (Please read the precautions on the back before filling this page) Order- --------% Which 213 A7 V. Description of the invention (58) === The volume of the liquid is between the solutions needed to swell the photographic element c Please read the Jiang Yishi on the back before filling in this Page] 10 pieces, "" 10 times the heart (rinsing process, preferably about 0.5 to about this. The washing process can be applied as a solution, the inner layer is laminated, and the heating is the second one :: instead of the 'low volume washing processing system' It can include any of the above forms 1 = Thermal camera system. In addition, it includes any front parts in particular: for the purpose of photographic processing, the components that are not required for the formation or stability of the original soft film can be used from the following methods All film pieces are removed and contacted at any time during exposure. Form II photographic elements can accept some or all of the following treatments: (I) Apply the solution directly to the film using any device, including spray, inkjet, coating, Gravure printing, etc. (II) Immerse the film in a bag Rinse solution in the reservoir. This method can also take the form of dipping or passing the component through a small box.% · (III) Laminating the auxiliary processing element on the developing element. The lamination can provide processing chemistry, transfer Except for the purpose of using chemistry, or transferring image information from the latent image green film elements. Transferred = image can be derived from the dye 'dye precursor, or silver-containing compound that can be transferred to the auxiliary processing element in a full-image manner. IV) Appropriate heating equipment, including simple heating plates, irons, rollers, printed thermal barrels by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, microwave heating equipment, heating air, steam, etc. Heating can be in the aforementioned processing MII Before any period, after the period ^, or the entire period is completed. Heating can make the processing temperature between room temperature and 10 (TC. Fox again) 'Form III: Traditional system: -61-588213 V. Description of the invention ( 59) According to another aspect of the present invention, # ^ is used in a photographic element. The blocked developer is incorporated into a conventional photographic processing solution of the conventional photographic element according to the present invention. One, for example, in the research covenant, MaCmillan, edited by the editor τη ^, or in 1977, The Theorv nf Ph · · &amp; Mu Si &lt; lUli goes to the original 4th edition, with It is well known that any one of the photographic methods is suitable for obtaining any image L σ. The method can be progressed. In these examples, it is possible to produce a month within the processing of the brewing element. After blocking the developer to provide a signal of improvement from cm to a shorter development time, or to reduce, u, and then develop all color recording balanced development. In terms of processing and processing negative film elements, this element is a color developer (Ie, a color imaging dye that will form a color coupling agent), and then treated with an oxidizing agent and a solvent to remove silver and silver. Hao 'was first processed with a black-and-white developer (that is, a developer that does not form a color dye with a coupling compound), followed by a haze of silver halide (often chemical haze or light Haze) 'followed by treatment with a color developer. A preferred color developer is p-phenylenediamine. Especially preferred are: 4-amino-N, N-diethylaniline hydrogenate, 4-amino-3-methyl-N, N-diethylaniline hydrogenate, 4-amino-3-methyl- N-ethyl-N- (2- (methanesulfonamido) ethylaniline pyrosulfate hydrate, 4-amino-3-methyl-N-ethyl-N_ (2-hydroxyethyl) sulfuric acid Aniline, -62- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

^ 1 ϋ I ：: ， ϋ III ϋ I n I%-printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 588213 A7 B7 V. Description of the invention (60) 4-amino-3-α-(methanesulfonium Fluorenylamino) ethyl-N, N-diethylaniline hydride, and 4-amino-N-ethylphosphonoethyl) -m-toluidinedi-p-xylenesulfonic acid. Dye images can be produced by using dye image reducing agents, inert transition metal ion complex oxidants, such as US Patent Nos. 3,748,138, 3,826,652, 3,862,842 and 3,989,526 and Crowvis (Bissonete). Travis), as described in U.S. Patent No. 3,765,891, and / or a method of forming or amplifying a combination of peroxide oxidizing agents, such as Matejec U.S. Patent No. 3,764,490, Research Disclosure, Vol. 116, 1973 In December, No. 11,660, and the Bizonite Study revealed that Book 148, August 1976, as described in Nos. 14836, 14846 and 14847. In particular, a photographic element can be used to form a dye image by a method as described below. U.S. Pat. Nos. 3,822,129 to Dunn et al, U.S. Pat. Nos. 3,834,907 and 3,902,905 to Bisonnet, Bison Knut's U.S. Patent No. 3,847,619, Mowrey's U.S. Patent No. 3,904,413, Hirai et al's U.S. Patent No. 4,880,725, Iwano's U.S. Patent No. 4,954,425 'Mass US Patent No. 4,983,504 to Marsden et al, US Patent No. 5,246,822 to Evans et al, US Patent No. 5,324,624 to Twist, and European Patent No. to Fyson EPO 〇487 616, Tanner Shire (Ding 3111 ^ 11 丨 11) 6 〖&amp; 1 World Patent No. 0090/13059, Masden's World Patent No. WO 90/13061 'Gracie (Grimsey) et al, World Patent No. WO 91/16666, World Law No. wo91 / 17479, • 63- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back before filling this page) ------ -Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 588213 A7 V. Description of the invention (61) Masid et al, World Patent No. w〇92 / 〇1972, Tanase World Patent No. WO 92 / 〇5471, World Patent No. WO92 / 〇7299 of Hensson, World Patent No. 093 / 〇1524 and No. 093 of Drizzt / No. 11460, and German Patent No. 4,211,460 of Wingender et al. After development, it can be bleached and fixed, removed silver or silver halide, washed and dried. Once the yellow, magenta, and cyan dye image records are formed in the washed processing element of the present invention, the image information of each color record can be repaired using conventional techniques, and then a record can be produced that can see a color balanced image. For example, it is possible to continuously scan a photographic element in the spectral blue, green and red regions, or to grab blue, green and red light in a single-scanning beam which is distinguished and passed through blue, green and red mirrors to form each color Record the separated scanning beam. A simple technique is to scan the photographic element little by little along a branch parallel scan path. Take induction! !! Note the intensity of the light passing through the component at the scanning point, and the sensor will convert the light shot received into an electronic signal. This electronic badge number is most often changed through steps to form a useful image electronic record green. For example, the electronic signal can be printed by an analog digital converter (anal〇g VII), and printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). (Dot) location information is sent to the digital computer together. In another specific embodiment, the electronic signal is encoded by a colorimeter or color = information to form an electronic record, which is suitable for allowing the image to be reconstructed into a visible form, such as an image displayed on a computer monitor, television Images, printed images, etc. It is expected that many of the developing elements of the present invention will be 64- ^ paper size before the removal of the silver element from the Chinese standard (CNS) A4 (210 X 297 mm) 588213, invention description (62) (Please read first Note on the back, please fill out this page again) Scanning: The remaining dented silver produces a dense murmur coating, and it is found that the quality of the scanned image can be improved by using the diffused bright light and the ',, and = device. It is possible to use = ^ in this technique to generate diffuse lighting. The preferred system includes a reflection system, which uses a diffusion hole whose inner wall is specially designed to generate highly diffuse reflection, and a transmission system, which diffuses the specular light beam by the optical element in the first beam to diffuse the light. Such components can be glass or plastic, either incorporated into a component that produces the desired diffusion, or surface treated to promote the required diffusion. A challenge encountered when generating images from scanned and selected information is that the number of information pixels that can be used for viewing f can only be used from a fairly basic photographic film. Therefore, it is even more important to scan and develop in order to maximize the quality of the usable image information. Improving image sharpness and minimizing the impact of abnormal pixel signals (ie, noise) is a common study to improve image quality. A traditional technique that minimizes the impact of abnormal pixel signals is to decompose adjacent pixels and read more. The closer the neighboring pixels are, the more weighted they are, and the density readings of each pixel are adjusted to the weighted average. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the element of the present invention can have a density scale insert from one or more insert areas on a part of the unexposed photographic recording material for reference exposure, such as Wheeler et a丨 U.S. Patent No. 5,649,260, Koen et al. U.S. Patent No. 5,563J17, and Cosgrove et. U.S. Patent No. 5,644,647 Like. The description system of the scanning signal conversion, including the technology to improve the image recording quality to the most advanced, is U.S. Patent No. 4,553,156 by Bayer; U.S. Patent No. 4,591,923 by Urabe et al; Qi-65- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 588213 A7 B7 Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of Invention (63) (Sasaki) et al. Patent No. 4,631,578; U.S. Patent No. 4,654,722 to Alkofer; U.S. Patent No. 4,670,793 to Yamada et al; U.S. Patent Nos. 4,694,342 and 4,962,542 to Klees; U.S. Patent No. 4,805,031 by Powell; U.S. Patent No. 4,829,370 by Mayne et al; U.S. Patent No. 4,839,721 by Abdulwahab; Matsunawa et al U.S. Patent Nos. 4,841,361 and 4,937,662; U.S. Patent No. 4,891,713 to Mizukoshi et al; U.S. Patent No. 4,912,569 to Petilli; Su Lifan U.S. Patent Nos. 4,920,501 and 5,070,413 to Sullivan) et al; U.S. Patent No. 4,929,979 to Kimoto et al; U.S. Patent No. 4,972,256 to Hirosawa et al; Kaplan (Kaplan ), US Patent No. 4,977,521; Sakai, US Patent No. 4,979,027; Ng, US Patent No. 5,003,494; Katayama et al, US Patent No. 5,008,950; Chimura (Kimura) et al, U.S. Patent No. 5,065,255; Osamu et al, U.S. Patent No. 5,051,842; Lee, et al, U.S. Patent No. 5,012,333; Bowers, et al U.S. Patent No. 5,107,346; Telle U.S. Patent No. 5,105,266; MacDonald et al. U.S. Patent No. 5,105,469; and Kwon et al. U.S. Patent No. 5,081 , As revealed by No. 692. Techniques for color balance adjustment during scanning • These are disclosed by Moore et al. U.S. Patent No. 5,049,984 and Davis U.S. Patent No. 5,541,645. In most cases, the digital color green is adjusted as soon as it is obtained. The paper size is -66-this paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (This page)%

1 ϋ · 1 mmM§ 1 emmm 1 ϋ I ϋ i_i ϋ ϋ I% · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Ⅴ. Invention Description (64) ίΐ: Look at the color balance image of the two people's joy and pass through various When the output is changed, the color accuracy of the carrier number is saved on the security monitor or when it is printed as a traditional color print 5. The best technique for sweeping is by Qiao Jiani (G country = combined with Figure 8 to get the signal change technique of viewing two t.30) ^ .A. 1IL ^ （See (especially better technology for color balance image) 1 Further explanation of this art's ability to manage color digital image information is provided by = 98 Giorgini and Madden Digital Color Management㈣㈣_

Management), courtesy of Addison-Wesley. The block diagram format shows the way in which the image information using the color = of the present invention is used. The image scanner 2 is used by transmitting a full-image exposure and a color negative element i processed according to the 2 ::: phase process. V-beams are most suitable for white beams, which pass through the layer unit and pass through the filter, and then separate the image to produce a red record layer unit image brother record (R), green record green unit image record ⑹, and blue Record layer list ^ Γ t money (B). Without splitting the beam, the blue, green, and red filters and filters can intersect continuously at the :: setting. In another scanning variation, individual blue, green, and J-colored lights, 'as generated by collecting light-emitting diodes', can be directed at each pixel location. Since the element is scanned one pixel at a time using a detector row, such as a charge coupling device (CCD) row, or a linear one or two row scan is performed using a linear detector row, such as a linear CCD row, r, ^ and 3 image 70-signal sequence, which can be correlated with the spatial position data provided from the scanner. Send the signal strength and position information to the workstation 4, and the information will be converted into electronic forms R, G, and B, which can be stored in any suitable -67- 297 mm) P% ------- Order ---------% · (Please read the notes on the back before filling this page) 588213 A7 B7

Printed in storage device 5 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. In the film development industry, a common attempt is to use television film devices to convert color negative film information into film and television signals. The most common type of TV movie and movie turning device: 飞 Flying spot scanner using photomultiplier tube detector: CCD for ^ sensor. These devices change the color negative &lt; scanning light number &quot; through each pixel position to t pressure. After signal processing, the electronic | sign is inverted so that the image is positive. The signal is then amplified and adjusted and sent to a cathode ray & viewfinder to display the image or recording on a tape for storage. Although it has both analog and digital image signal conversion, it is better to send the number in digital form: for conversion, since most computers are now digital, this is my opinion: brain peripherals such as magnetic tape, magnetic disk or optical disk. The film video monitor 6, which accepts digital image information i adjusted according to its needs, is labeled R ", G", and B ", enabling viewing of the image received by the workstation 4. It does not rely on the cathode-ray tube of the film monitor, and can Replaced by liquid crystal display or other suitable electronic image viewing devices. The video monitor typically relies on the image control device 3, which can include a keyboard and cursor, so that the workstation operator can provide image conversion instructions in order to adjust the displayed video image , And any image reproduced from digital image information. Any image adjustment can be viewed because it is imported into the video display 6 and stored in the storage device 5. The adjusted image information R ,,, G &quot;, and b, m can be adjusted. Sent to output device 7 to produce a modified image. The output device can be any combination of traditional component writers, such as thermal dye transfer, inkjet, electrostatic, electronic photo binocular 'thermal dye sublimation or other forms of indene film Machine. It also includes or prints on light-sensitive photo paper. It can use the output device to control the traditional South-68-This standard is applicable to the Zhongguanjia Standard (CNS) A4 Grid (21q χ tear public Chu) _ · _ ------- Order --------- (Please read the precautions on the back before filling out this page) A7 Employee Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printing V. Description of the invention (66) Exposure of silver colored paper. Output of the modified image for viewing. The most #out medium 8, which contains broken noise (grain size), sharpness, right :: two ends: Officials use it for viewing and judging images. Film and television display 2: output medium = sharpness 'hue' color balance, and color reproduction, :: network, inter-computer network of the world's website (wodd_on Consider the image transmitted between related parties. Using the arrangement shown in Figure 1, the color negative element according to the present invention: "The image system is transformed into a digital form, transformed, and transformed into a viewable form." Niseta's Lamex No. 5,267, as described in the predicate = step. The color negative recording material according to the present invention can be used with any suitable method described in U.S. Patent No. 5,257,030. In a preferred-Ruan In the embodiment, Giorgi et al provides a method and apparatus for transferring R, C from a transmission scanner. ^ B video signal is converted to measurement, and its reference material such as film or paper recorder, thermal display, etc. generates a three-color signal of the imaging device. Measurement 値 is equivalent to appropriately reproducing a color image on the device Those who need it. For example, if the selected reference image generation device is a specific film and television display, the selected intermediate image data is measured as R, G &gt; B of the reference film and video display device, and the adjustment signal (encoding) is used for input. For film, the R, 0, and 6 load signals from the scanner will be converted to R, G ', and B' codes equivalent to those required for proper reproduction of color images on the device. A data set is generated from which The mathematical transformation that converts the R 'G and B video signals into the above-mentioned encoding is then deduced. Choose to fully simplify and cover the useful exposure range of the scaled film. Exposure 69 paper size applies Chinese National Standard (CNS) A4 specification (21 × X 297 mm) I — I — I — — — — — — ^ --- 1 — — — — — · (Please read the notes on the back before filling out this page) 588213 A7 __B7 V. Description of the invention (6?) An totem generator will generate an exposure totem and send it to the exposure device . The exposure device produces a three-color exposure on the film, producing a test image consisting of nearly 15 () color inserts. Test images can be produced using a variety of methods suitable for the application. 14 methods include: using an exposure device such as a photometer, using an output device of a color developing device, recording an image of a test object illuminated by a known light source with a known reflectance, or calculating a three-color exposure using a method known in photography value. If input films of different speeds are used, the entire red, green, and blue exposure must be adjusted appropriately for each film in order to compensate for the relative speed difference between the films. Therefore each film receives equal exposure, suitable for its red, green and blue speeds. The exposed film was chemically processed and processed. The film chemical inserts are read with a transfer scanner, which produces the r, g, and B image-bearing signals equivalent to the color inserts. The signal of the encoder and generator, the totem generates the rgb intensity adjustment signal, and sends it to the reference video display. Adjust the R ′, G ’, and B’ codes of each test color to make the color matching device, which can be equivalent to an instrument or a type j observer, instruct the film display test color to match the positive test color or negative ind t color. The conversion device converts the R, 0 and video signals of the test colors of the film into R, G, and B, corresponding to the test colors, and encodes them. The mathematical operations for converting the R, G, and B carrier signals into intermediate data can consist of a series of matrix operations and look-up tables (LUTs). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs --------, _ ·! (Please read the notes on the back before filling out this page) "Refer to Figure 2 'In the preferred embodiment of the present invention The input image number R, G and the pulse are converted into intermediate data 値, 纟 is equivalent to the following = == Rt, G, and B required for proper reproduction of color images on the device, and the output loader G, B, and G are output. Carrier signal, which is equivalent to the measured transmittance of a film. The paper size of the -70 sheet is applicable to the Chinese National Standard (CNS) A4 size X X 297 public love. 588213 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (68) The 1-dimensional look-up table LUT 1 is transformed into the corresponding density in the computer used to receive and store the film from the scanner. (2) The density from step (1) is then used by a matrix derived from the conversion device 1 conversion to generate the intermediate shadow signal. (3) Adjust the density of step (2) as needed by the derived dimensional identification table [1; 72, so that the light density of the input film is converted to the reference light density. (4) Convert the density of step (3) through the 1-dimensional look-up table LUT 3 to produce Reference the corresponding R, G, and B output devices to output the shadow-carrying signal. It is inferred that each input color typically provides an individual lookup table. In a specific embodiment, three 1-dimensional lookup tables LUT, red can be used. , Green and blue records each. In another embodiment, a multidimensional look-up table can be used like US Patent No. 4,941,039 by D'Errico. It will be expected in step 4 above The output video signal of the reference output device may be the code of the slave device, or the output video signal may need to be further adjusted to become a device-specific code. Such adjustments can be performed by additional matrix conversion or BV table conversion 'or a combination This type of conversion is done to correctly prepare the output video signal for any of the steps of transferring, storing, printing or displaying using a specific device. In a second preferred embodiment of the present invention, it is from a transfer scanner The R ′ G and B load image signals are transformed into image recall and / or storage measurement by #, which is equivalent to the measurement or description of a single reference image recording device and / or medium, in which all input media The measured value is equivalent to the three-colored tadpole, which is formed by a reference device or medium, which captures the original scene under the same environment, and enters the medium to capture 1¾ of the scene under this environment. For example, if the selected reference image recording medium ___- 71 -This paper size applies to Chinese National Standard (CNS) A4------ (Please read the precautions on the back before filling this page)

-I 1 ϋ I ϋ ϋ i ϋ ^ * δ ,, 8 ϋ n I ϋ ii ϋ I ρ 588213 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 '^^ ------ B7_____ (69) Referred to as a specific color negative film, and the selected intermediate image data is the measured RGB density of the reference film, for the input color negative film according to the present invention, the R, G * B load-bearing signal from the scanner will be Converted to ri, &amp; and B, density 値, which corresponds to the image formed by the reference color negative, which is exposed in the same environment as the color negative material according to the present invention. Exposure-Totem, choose to fully simplify and cover the useful B exposure range of the corrected film, which is generated by exposing the totem generator and transported to the exposure device. The exposure device produces a three-color exposure on the film to produce an image composed of nearly 150 color films. Test images can be generated using a variety of methods suitable for the application. These methods include: · using an exposure device such as a photometer, using an output device such as a color developing device, recording green reflected light from a known light source &lt; test object image, or calculating a three-color exposure using a method known in photography . If input films with different speeds are used, the entire red, green, and blue exposures must be adjusted properly for each film to compensate for the relative speed differences between the films. Each film thus receives equal exposure, suitable for its red, green and blue speeds. The exposed film was chemically processed and processed. The transfer film picker is called a soft chemical patch, which generates a ruler corresponding to each color patch, 0 and b image-bearing signals, and a transfer density meter, which generates ri, G, and B, density 値. The conversion device converts the signal 载 of the test color of the film into R, G, and B, and the density corresponding to the test color of the reference color negative film. In another variation, if the selected reference image is a specific color negative green medium, and the selected intermediate image is the predetermined R, g, and B intermediate rule and degree of step 2 of the reference film, then the input according to the present invention For color negative film, the R, G, and B load signals from the scanner will be converted to the equivalent of the device -72- this paper size @ @ 家 standard (CNS) A4 specifications (210 X 297 Gongchu) (please first Read the notes on the reverse side and fill out this page) m. Order: .¾ 5. Description of the invention (70) It is necessary to properly reproduce the color image on the same ring ^ ^ ^ ^ 罟 R, G and B , The middle density 値, • The work is formed by the reference cedar negative, and the phase is exposed under the negative color of the reference color. The phase of the exposure of the negative material is made according to this method. The correction of each input person film will now produce the same intermediate data as much as possible, which is equivalent to going to Shangu Tian M. You, Qi Tian Yu appropriately reproduce color 2 on the reference output device. G * B 'encoding 値, which is not * reference output device consideration: color negative film soft Formed. Uncorrected film can also be used with a similar type of film conversion device, and the result will be similar to that described. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, the conversion of RG and B carrier halls to this is a better specific implementation For example, the mathematical operation of intermediate data can be composed of-series matrix operation and Pu Weiguang. Three input colors typically provide three tables. It is expected that this type of conversion can also be implemented in other specific implementations, making it possible to combine mathematical operations or mathematical operations. The calculation steps generated by the master are complete, including, but not limited to, matrix algebra, which depends on the algebraic representation of one or more shadow-carrying signals, and the Bouvier LUT. In a specific embodiment, the matrix of step 2 is 3χ3 matrix. In a more specific embodiment, matrix 1 in step 2 is a 3 χ 丨 〇 matrix. In a preferred embodiment, the 1-dimensional LUT 3 in step 4 divides the intermediate carrier signal according to the characteristics of the color negative film. The curve is converted, thus reproducing the color fade of the normal color print image. In another preferred embodiment, the Budweiser LUT 3 in step 4 carries the video message in the middle. According to the more preferred color negative characteristic curve conversion, such as having lower image contrast. Due to the complexity of these conversions, it should be noted that from R, G and b to R ,, G 'and B, the conversion can often be changed from 3_ The dimension lUT is better completed. This type of 3_dimensional-73- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 588213 A7 V. Description of the invention (71) The LUT can be based on j. The leading development in US Patent No. 4,941,039 by Gram. 'It is expected that when the image is in electronic form, image processing and processing is not limited to the above-mentioned special features. When the image is in this form, additional image transformation can be used , Including but not limited to standard scene balance calculations (to determine the relationship between density and color balance based on the density of the areas within two or more negatives), tonal ratio conversion, to magnify the unexposed contrast coefficient of the film, and through convolution or non-sharp color Sharpening is not suitable or suitable for sharpening, red-eye reduction, and particle suppression is not suitable or suitable. In addition, the image can be manually transformed, zoomed in, cut out, combined with more images or other changes known in the art ^ Ren ~ The image is corrected, and any additional image processing and transformation occurs, ~ The image can be Electronically transmitted to remote locations or recorded locally on various output devices, including but not limited to _Silver or paper writing green device, thermal indica film machine, electronic ..., photo printer, inkjet indica film machine, display Monitors, CDs, optical and magnetic electronic signal storage devices, and other forms of storage and display devices known in the art. In another embodiment of the present invention, the illumination, chroma-sensitive, and image extraction objects and methods described in Arakawa et ai U.S. Patent No. 5,962,205 can be used. Preparation Example The synthesis of a representative trivalent compound used in the present invention has been previously described. Qiao Zhang E Yong -74- (Please read the precautions on the back before filling this page} ί ti I 72) \ Δ ♦ CHjSOjNa

3

D-16 (Please read the notes on the back before filling out this page) Printed tritium oxide ^ (L, 7.2 ml, 105 mmol), Methane sulfinic acid Sodium (9.19 g. '90 millimoles) 'valence acid sodium monohydrate (56 g) was heated in ⑽ml of 90 C water for 8 hours. The solution was cooled and extracted with 1 mL of ethyl phthalate. The extract was dried over sodium sulfate and concentrated to a solid. The yield of 1 is 6.42 grams (46 millimoles, 52%). Mix 2 (3.32 g, 24 mmol), a compound fork (4.08 g, 20 mmol), and tributyltin diacetate (0.05 ml) in 60 ml of dichloroethane. The solution was stirred at room temperature for 7 days. The crude reaction mixture was purified by chromatography on silica gel. The yield of 〇-16 is 6.15 g (18 mol, 90%), 111.?.80-82&lt;&gt; (:, ESMS: ES + m / z 343 (M + 1, 100%) 〇 Preparation D-17 -75- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 cm) I ϋ ϋ ϋ a · — 1 i · — 一 &amp;, 0 I ϋ 1 11 n · 588213 A7 ----—-— R7 V. Description of the invention (73)

Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs printed 5 coats Sodium borohydride (3.95 g, 104 mol) was added to the compound (9.11 g, 50 mmol) in methanol (15. Ml) of the suspension. Water (50 liters) was added to evaporate the methanol. The extract was extracted with ether, and the extract was dried over sodium sulfate and concentrated to an oil. The yield was 8.85 grams (48 millimoles, 96%). A solution of 5 (4.05 g, 22 mmol), i (4.08 g, 20 mmol), and 0.05 mL of tributyltin diacetate in methane (20 mL) was stirred at room temperature for 20 hours. The reaction mixture was diluted with ether (100 ml) and gradually treated with water to give the crude product, which was purified by silica gel chromatography. The yield of D-17 is 5.49 grams (14 millimoles, 71%), mp 149-151 ° C, ESMS: ES + m / z 389 (M + 1, 100%), ES-m / z 387 (M -1,350 / 〇) 〇Photographs · _ ^^ ------- tr --------- (Please read the precautions on the back before filling this page) -76- This paper size Applicable to China National Standard (CNS) A4 specification (210 x 297 public love) 588213

DESCRIPTION OF THE INVENTION (74) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, and the main worker's washing environment is as described in the example. Unless otherwise specified, dipping / being in Kodak Color Fixer (K〇dak Flexk_r Fix⑽ 如 ⑽) Tooth removal is removed. In general, deleting this step will increase the measured density by about 0.2. The following components are used in the example. The entire chemical structure table is also included. Silver Salt Dispersion SS-1: Will stir the reaction The container was filled with 431 grams of lime-treated gelatin and 6569 grams of distilled water. A solution (solution B) containing 214 grams of benzotriazole, 2150 grams of distilled water, and 79 grams of 2.5 Molar sodium hydroxide solution was prepared. The solution was added as needed 3, nitrate

Acid and sodium hydroxide to adjust the mixture in the reaction vessel to pAg 7 25, pH 8.00 〇 4 liters of 0.54 Molar silver nitrate was added to the pot at 25 cc / min, while solution B was added to maintain pAg at 7.25. This process was continued until the silver nitrate solution was consumed, at which point the mixture was concentrated by ultrafiltration. The resulting silver salt dispersion contains fine particles of benzotrillium salt. Silver salt dispersion SS-2: Fill a stirred reaction container with 43 grams of lime-treated gelatin and 6569 grams of steamed water to prepare 320 grams of 1-fluorenyl-5-¾ tetra wah, 2044 grams of distilled water, and 790 grams 2.5 mol sodium hydroxide solution (solution b). Add solution B, nitric acid and sodium hydroxide as needed to adjust the mixture in the reaction vessel to pAg 7.25, pH 8.00. Add 4 liters of 0.54 Molar silver nitrate to the pot at 250cc / min. pAg was maintained at 7.25. This process was continued until the silver nitrate solution was consumed, at which point the mixture was concentrated by ultrafiltration. The resulting silver salt dispersion contained fine 1-phenyl-5-tetratyl fine p-dense particles. -77- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) # Order --------- 丨 · (Please read the precautions on the back before filling this page) 588213 A7 _______B7__ 5. Description of the invention (75) Silver halide emulsion: The emulsions used in these examples are all silver iodide bromide flakes, which can be borrowed (please read the precautions on the back before filling this page). Known by this technology Precipitation by traditional methods. The table below ^, refined I1 'spear pen, uses its iodide content (the remainder is assumed to be bromide), its dimensions, and photosensitizing dye to obtain the sensitivity. These emulsions are all known in the art: chemically sensitive to produce the best sensitivity. Table 1 Emulsion sensitivity Iodide content (%) Diameter (micron) Thickness s (micron) Dye EY-1 yellow 1.3 0.54 0.084 SY-1 EY-2 yellow 4.1 1.25 0.137 SY-1 EY-3 yellow 2 1.23 0.125 SY-1 EY-4 Yellow 2 0.45 0.061 SY-1 EY-5 Yellow 2 0.653 0.093 SY-1 EM -1 Fuchsia 1.3 0.55 0.084 SM-1 + SM-2 EM-2 Fuchsia 4.1 1.22 0.111 SM-1 + SM- 3 EM-3 Fuchsia 2 1.23 0.125 SM-1 + SM-3 EM-4 Fuchsia 2 0.45 0.061 SM-1 + SM-3 EM-5 Fuchsia 2 0.653 0.093 SM-1 + SM-3 EC-1 Green 1.3 0.55 0.084 SC-1 EC-2 Green 4.1 1.2 0.11 SC-1 EC-3 Green 2 1.23 0.125 SC-1 + SC-2 EC-4 Green 2 0.45 0.061 SC-1 + SC-2 EC-5 Green 2 0.653 0.093 SC- 1 + SC-2 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs-78-— This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 588213 A7 _B7_ V. Description of the invention (76) Coupling agent Dispersion CDM-1: An oil-based coupling agent dispersion was prepared by a conventional method including the coupling agent M-1 and tricresyl phosphate in a weight ratio of 1: 0.5. Coupling Agent Dispersion CDM-2 ... A coupling agent dispersion was prepared by the conventional method including the coupling agent M-2 without any additional fixing solution. Coupling Agent Dispersion Liquid CDC-1 An oil-based coupling agent dispersion was prepared by a conventional method including the coupling agent C-2 and dibutyl phosphate at a weight ratio of 1: 2. Coupling agent dispersion CDC-2: An oil-based coupling agent dispersion was prepared by a conventional method including the coupling agent C-2 and phosphoric acid-dibutyl ester in a weight ratio of 1: 1. Coupling agent dispersion CDY-1: An oil-based coupling agent dispersion was prepared by a conventional method including the coupling agent Y-1 and dibutyl phosphate in a weight ratio of 1: 0.5. (Please read the precautions on the back before filling out this page) ------- Order --------- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy DC-1 H, ', person 0

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N, ^ NHS02CH3 79- This paper size applies to Chinese National Standard (CNS) A4 (210 χ 297 mm) 588213 A7 B7 V. Description of the invention (77)

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NO, 588213 A7 B7 V. Description of the invention (78) DC-6 DC-7 DC-8 0 people

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Cl-83- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 588213 A7 B7 V. Description of the invention (81) SM-2

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ΝΗ Hardener-1 -------- # § .----- —Order --------- (Please read the notes on the back before filling out this page) Intellectual Property Bureau, Ministry of Economic Affairs Employee Consumer Cooperative Printed Hardener-2 Anti-Misting Agent AF-1 φ

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-84 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 588213 A7 B7_ '' ------------- V. Description of Invention (82): All Examples 1 The coatings all contain a single photosensitive layer 'and are prepared according to the format listed in the table "with changes in the developer mixed. On a poly (ethylene terephthalate) support with a thickness of 7 mils All coatings were prepared. &Amp; The developer was ball milled in an aqueous slurry using the oxidized beads of the following chemical formula for 3 days. 0.2 g of sodium triisopropyl teatinate and 10 g of water were added per gram of developer mixed. , And 25 ml beads. After grinding, filter to remove oxidized beads. Refrigerate the slurry before use. Table 1-1: Basic format components deposit silver (from emulsion E_1) 0.54 g / m² silver ( From silver salt SS-1) 0.54 g / m 2 coupling agent M-1 (from coupling agent dispersion CDM-1) 0.54 g / m 2 Basic release agent (guanidine triacetate) 0.81 g / Salicylic acid aniline 0.86 g / m 2 1-phenyl-5-chloro tetravot 0.32 g / m 2 Lime-treated gelatin 4.31 g / m 2 The developer of 2.2 meters per square meter will expose the resulting coating through a stepped machine to a 3.04 log lux light source with 3000K filtering by daylight 5 A and Wratten 2B filters. Exposure time It is 1 second. After exposure, the coating is contacted with a heated platen for 20 seconds and heat-treated. Many strips are processed at various platen temperatures to produce the best strip processing environment. From this data, two coefficients are obtained: A. Starting temperature, TQ : -85- This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) (Please read the precautions on the back before filling this page)

I I--Order ·----- I I I Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 588213 A7

Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The maximum density (0.011) corresponding to the required temperature is 0.5. Lower temperatures indicate a more active developer, which is desirable. Β · Spike difference, Dp: Regarding the optimal platen temperature, the spike difference is equivalent to this:

Dmax-Dmin

Dp == —-———

Dmin

A higher Dp 値 indicates that the noise signal generated by the developer is increased, which is desirable. Table 1-2 shows the results of the route used in Example 1. The listed items are developers, starting temperature T. , And the relative difference, Dp. The comparative example developer is a material known in the art. Table 1-2 Coating developer T0 (° C) Dp CM-1 (control) DC-1 191 0.23 C-1-2 (control) DC-2 141 3.98 M-1 (invention) D-17 144 5.55 This table shows that the developer of the present invention, when producing an equivalent starting temperature or better than a control developer, produces a fairly improved spike difference. Example 2 The following example was performed similar to the previous example, except that the base release agent (guanidine triacetate) was removed from the coating format. All coating examples were prepared according to the format listed in Table 2-1 below, in various variations by varying the mixed developer. The developer mixed hair was the same as in Example 1. All coatings are poly 7 mil thick (terephthalene-86- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) --------- ·-·- ------ Order ------- (Please read the notes on the back before filling out this page) 588213 A7 V. Description of the invention (84)

1-benji-5-mirror with four mouths / 卞万公 and 0.32 g / m2 lime-treated gelatin 4.31 g / m2 developer Moore / m2 (please read the Please fill in this page again for attention) §

ϋ ϋ I 玍 座 &lt; 坌 layer, to exposure from the stepped machine to 3.04 log Lux light source with 3000K filtering by daylight 5 A and Leighton 2B filter. The exposure time is j seconds. After exposure, the coating was heat-treated by contacting the heated platen for 20 seconds. Many strips are processed at various platen temperatures to produce the best strip processing environment. Two photographic factors were measured in the same manner as in Example 1. The resulting coefficients are shown in Table 2_2. Order III. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Table 2-2 Coating Developer T〇 (° C) Dp C-2-1 (Control) DC-1 164 3.61 C-2-2 (Control) DC -2 170 3.20 1-2-1 (invention) D-28 140 6.49 1-2-2 (invention) D-29 164 5.40 This table shows that the developer supply start temperature of the present invention is lowered, and real-87- paper is provided. This t-degree applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 588213 A7 Γ ____ B7 V. Description of the invention (85) The sharp difference in quality improvement. Example 3 The following examples were carried out similarly to the previous examples, except that the developer preparation and coating format were mixed. The blended crystalline developer was prepared by the following ball milling steps. To a total of 10 grams of sample was added 1 gram of the mixed developer, 0.15 g of polyethylenepyrrolidone, 8.85 g of distilled water, and 10 ml of oxidized hammer beads. The slurry was ball milled for 24 hours. After ball milling, the germanium oxide beads were removed by filtration. Freeze the slurry before use. All coating examples were prepared according to the format listed in Table 3-1 below in various variations by varying the participating developer. Adjust the pH of the coating to generally 値 6.0. All coatings were prepared on poly (ethylene terephthalate) support with a thickness of 7 ears. ---------- ^ w— ------- Order · (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Form 3-1: Basic Format Components Deposited Silver (from emulsion E · 1) 0.86 g / m² Silver (from silver salt SS-1) 0.54 g / m² Coupling agent M-1 (from coupling agent dispersion CDM-1) 0.54 G / m2 salicylide aniline U) 8 g / m2 1-phenyl-5-weitetrazol 0.32 g / m2 Lime-treated gelatin 6.09 g / m2 developer 1.08 Millimoles / square meter melting pH 6.0, 2., / Gongshan ~ soil π ,, a &quot;, π ~ π straw field 5 yuan 5A and Lei Teng 2B filter 5500K filter 2.40 log Lux light source. Exposure time is 1.08%. This paper size is applicable to China National Standard (CNS) A4 (210 X 297 public love) A7

V. Description of the invention (86) There are few prints of employee cooperatives in the Intellectual Property Bureau of the Ministry of Economic Affairs. After the exposure, the coating was heat-treated by contacting the heated platen. Evaluation of paint heart Fresh image difference and high-cost raw materials. The high humidity storage test comparing the minimum density of fresh coatings with the minimum density of coatings was placed in a heating furnace at 5 (rc and 8G% relative humidity) for 24 hours. The results of this test are listed in

The data in the table clearly show that compared with the control example, this developer has excellent fresh image difference, and high humidity raw material storage. Coatings with very low differences do not produce enough density to record high humidity preservation signals. Example 4 The following examples include coatings prepared in a manner similar to Example 3. The coating format includes the changes listed below. According to the format listed in the following table 4-1, the developer can be changed in various ways by changing the mixed developer. -89- This paper size conforms to the family standard (CNS) A4 specification (210 X 297). -· # ------ —Order --------- i 丨 · (Please read the precautions on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives 588213 A7 _____B7 V. Description of the invention (87) All coating examples were prepared. Four developers of the present invention were compared. All coatings were prepared on a polyether (ethylene terephthalate) support with a thickness of 7¾. _ Table 4-1: Basic Format Components Deposited Silver (from Emulsion E-1) 0.86 g / m² Coupler C-2 (from Coupling Agent Dispersion CDC-2) 1.08 g / m² Developer 0.86 g / Anti-mist agent AF-1 15 mg / m 2 Hardener B-1 58 mg / m 2 Lime-treated gelatin 3.23 g / m 2 Developer 0.86 g / m 2 The layer was exposed to a 2.40 log Lux light source with a 5500K filter by daylight 5 A and a 5200K filter by a stepped mechanism. The exposure time was 丨 / 50 seconds. After exposure, the coating was applied. Immerse in activator A or B for 15 seconds, and laminate ^ as a passive coating containing 1.08 g / m² gelatin. Thereafter, the film package is contacted with a heated platen at 50 or 70 ° C for 10 seconds and processed. Observation Negative cyan dye images of blocked color developers D-28, D-3 8 and D-39. Observe the silver ratio images of blocked black and white developer D-30. The results are summarized in Table 4-2. Each coating The measured density of the layer is the red density of Status M. Activator A: (weight ratio concentration in distilled water) 2.65% sodium carbonate 0.63% sodium bicarbonate 0.1% sodium bromide 0.2% sodium sulfite Jing-90-— This paper scale applies to China Standard (CNS) A4 specification (210 X 297 mm) ------- Order --------- (Please read the precautions on the back before filling this page) 588213 A7 _B7 V. Description of the invention (88)

Activator B: 74.5 g / L KOH 8 g / L sulfite 2 g / L Brominated clock 4-2 -91-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)- -------- ·-# ------- Order --------- (Please read the precautions on the back before filling this page) Coating developer activator / time / temperature Dmax 1-4-1 D-28 A / 10V70 C 0.53 A / 10V90 C 1.40 B / 10V50 C 0.40 B / 10V70 C 2.25 B / 10V90 C 4.92 1-4-2 D-38 A / 10V50 C 0.09 A / 10V70 C 0.89 A / 10V90 C 1.20 1-4-3 D-39 A / 10V70 C 0.56 A / 10V90 C 0.92 B / 10V70 C 0.43 B / 10V90 C 1.26 1-4-4 D-30 A / 10V50 C 0.21 A / 10V70 C 0.24 A / 10V90 C 0.26 B / 10V50 C 0.12 B / 10V70 C 0.19 B / 10, / 90 C 0.29 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 588213 A7 _____B7__ V. Description of the invention (89) Example 5 below The examples are similar to the previous examples, except that the blocked developer is removed from the emulsion-containing layer and placed in a separation layer. The coating was similarly activated in an alkali-containing bath. Examples of emulsion coatings were prepared according to the format listed in Table 5-1 below. The coating includes an emulsion layer with a gelatin overlay. All coatings were prepared on a poly (ethylene terephthalate) support with a thickness of 7 mils. (Please read the notes on the back before filling out this page) • ------- Order --------- Lu. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the component deposition developer 0.67 millimeters Equivalent / square meter Lime-treated gelatin 1.61 g / square meter Hardener B-1 29 mg / square meter-92- Table 5-1 Component deposited silver (from emulsion E-1) 0.86 g / square meter Coupling C-2 (from Coupling Dispersion CDC-2) 1.08 g / m² Anti-Haze Agent AF-1 15 mg / m² Lime-treated gelatin 3.23 g / m² Cover Layer Gelatin 0.43 g / m² Hardener B-1 66 mg / m² The laminated layer consists of a developer and gelatin and is coated according to the format listed in Table 5_2 below. Correct the molecular weight of the developer deposited and the equivalent amount of developer released per molecule. All coatings were prepared on a poly (ethylene terephthalate) support with a thickness of 7 pyrimole. ΕΛ The paper L degree applies to the Chinese National Standard (CNS) A4 specification (21 × χ297), 588213 A7 V. Description of the invention (91) Example 6 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, as shown in Figure 6-1 The multi-layer developing element described in the above shows that the developer of the present invention provides sufficient imaging capability to allow a full-color photothermographic element for capturing a lively scene. Figure 6-1 Covering layer U g / m 2 Gelatin g / m 2 Hardener] Yellow photosensitive layer 0.39 g / m 2 from emulsion EY—iiAgBrl 0.6 g / m 2 from emulsion ey-2 AgBrI 0.32 g / m2 silver benzotriazole from ss-1 0.32 g / m2 silver-1-phenyl-5-mercaptotetrazole 0.54 g / s from SS-2 Coupling agent Y-1 from dispersion CDY-1 0.86 g / m² developer d-28 0.86 g / m² Salicylamine 4.3 g / m² Gelatin green photosensitive layer 0.39 G / m2 AgBfl from emulsion EM-1 0.6 g / m2 AgBrI from emulsion EM-2 0.32 g / m2 silver benzotriazole from SS-1 0.32 g / m2 Ruler from silver -1-phenyl-5-SS-2 from SS-2 0.54 g / m2 coupling agent M-1 from dispersion CDM-1 0.86 g / m2 developer D -28 〇 · 86g / sqm salicylamine 4.3g / sqm gelatin -94- ---------------- ^ --------- · -· (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ) 588213 A7 --- B7______ 5. Description of the invention (92) Red photosensitive layer 0.39 g / m2 AgBrI from emulsion EC-1 0.6 g / m2 AgBrI 0.32 from emulsion EC-2 G / m2 benzotrisaliferous silver from SS-1 0.32 g / m2 silver -1-phenyl-5-2-¾¾ from SS-2 5.4 g / m2 from dispersion CDC Coupling agent of -1 ci 0.86 g / m2 developer D-28 0.86 g / m2 salicylamide 4.3 g / m2 gelatin support poly (ethyl terephthalate) support (Thickness 7 mils) f Please read the precautions on the back before filling out this page} The resulting coating is exposed through a stepped machine to 2 · 40 of 5500K filtered by Yueguang 5 A and Lei Teng 2B. log Lux light source. The exposure time is 0.01 seconds. After the exposure ', the film package was heat-pressed by contacting a heated platen at 145 ° C for 20 seconds. The coating was then immersed in 15. (: As much as 2 minutes in the color fixing solution. Use status MU color profile to independently take the cyan, magenta and yellow densities to produce the densities listed in Table 6-1 below. Essentially formed from all three color frequencies The full image density clearly shows that the coating is a useful photographic element for capturing multi-color information. ------- Order --------- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 2 1 Recorded Dmin Dmax Cyan 0.58 1.43 Fuchsia 0.8 2.12 Yellow 0.64 1.68 The film element of this example is loaded into the single eye of the device 50 亳 m / η · 7 lens -95- This paper standard applies to China National Standard (CNS) A4 (210 X 297 mm) 588213 A7 B7 Five inventions printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (93) Slim camera. Set the camera's exposure control to asa⑽, ^: This photographic element captures vivid sceneries" ^丨 The price is heated to develop the document to produce a clearly identifiable negative image, and then the component is fixed in the liquid. U Ba Yishen will produce a t image to a Kodak photo disc scanner. The resulting digital image is loaded At Ado be Photoshop (version 5.0.2), which uses digital ancient ten correction, adjusts the tone scale and color saturation, and thus obtains an acceptable image: use a computer monitor to view the image as software. Then send the image file to Kodak 865 〇Dye-sublimation printers, with hard copy output of acceptable quality. This illustrates the use of components containing the compounds of the present invention in a complete development chain. Example 7 A multi-layer development component as shown in Figure 7-1 was produced for display The developer of the present invention provides sufficient imaging capability to allow full-color photothermographic elements to be used to capture vivid scenes. The multilayer element of this example produces images without a wet processing step. Overlay 1 · 1 g / m² gelatin 〇32g / m2 hardener_2 Fast yellow 0.54g / m2 AgBrI from emulsion EΥ-3 〇17g / m2 silver benzotriazole from SS-1 Silver-1_phenyl-5-mercaptotetrathiazine from SS-2 0.29 g / m2 Coupler γβ1 from dispersion CDY-1 0.46 g / m2 developer d- 28.46 g / m2 Salicylamine 2.3 / Square meter gelatin 96- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) · ^^^ ------- tr --------- (Please (Read the notes on the back before filling out this page)

Description of the Invention (94) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 锾 Slow yellow 〇27g / m2 AgBrI from emulsion EY-4 〇16g / m2 AgBrI from emulsion EY-5 〇 15g / m2 silver benzotriazole from SS_i 0.15g / m2 silver-1-phenyl-5-mercaptotetrazole from SS_2 0.25g / m2 from dispersion CDY Coupler of -1 Y-1 0.40 g / m2 developer d-28 0.40 g / m2 salicylamine 2.0 g / m2 gelatin yellow filter 0.08 G / m2 SY-2 1.07 g / m2 gelatin fast purple red 0.54 g / m2 AgBrI from emulsion εμ-3 0 · π g / m2 benzo from SS-1 Silver triazole silver 0.1 g / m² Silver -1-phenyl-5-mercaptotetrazole from SS-2 0.29 g / m² Coupling agent M-2 from dispersion cdM-2 46g / m2 developer d-28 〇46g / m2 salicylamine ------ g / m2 gelatin slow yellow 〇27g / m2 from emulsion em-4 AgBrI 〇 · 16 g / m 2 AgBrI from emulsion em-5 ο · 1〗 g / Square meter silver benzotriazole from SS-1 0.15 g / m2 Silver j · phenyl-5_mercaptotetrazole from ss_2 0.25 g / m2 from dispersion cdM-2 Coupling agent M-2 0 · 40 g 7 m 2 developer D-28 0 · 40 g / m 2 salicylamine -----— g / m 3 gelatin Q7-J sheets

297 mm) (Please read the notes on the back before filling this page) # ------- ^ --------- Turtle- ♦. 588213 Α7 __________ Β7 V. Description of the Invention (95) Printed inner layer 1.07 g / m² gelatin fast cyan 0.54 g / m² AgBrI from emulsion EC-3 〇.17 g / m² benzotriazole from SS-1 Silver 0.17 g / m² Silver -1-phenyl-5-mercaptotetrazole from SS-2 0.29 g / m² Coupling agent CM from dispersion CDC-1 0.46 g / m² Developer D-28 0.46 g / m2 Salicylamine 2.3 g / m2 Gelatin slow cyan layer 0.27 g / m2 AgBrI from Emulsion EC-4 0.16 g / m2 Emulsion EC-5 AgBrI 0.15 g / m2 silver benzotriazole from SS-1 0.15 g / m2 silver -1-phenyl · 5-mercaptotetrasulfa from SS-2 0.25 G / m2 from coupling agent CM of dispersion CDC-1 CM40.40g / m2 developer d-28.40g / m2 salicylamamine 2.0 g / m2 gelatin anti-halo Layer 0. 05 g / m2 carbon 1.6 g / m2 Ruler gelatin support poly (ethyl terephthalate) support (thickness 7 mils) The resulting coating is exposed through a stepped mechanism to a light of 5500K with a light filter of 5A and a Leighton 2B. log Lux light source. The exposure time is 0 ^ seconds. After exposure ', the film package was contacted with a heated platen at 14 5 C for 20 seconds and hot-pressed. Use status Μ color profile to take cyan, magenta and yellow density separately, produce -98- --------- Φ · ------- Order (Please read the precautions on the back before filling this page) ρβ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 588213

A7 Description of Invention (96) The densities listed in Table 7-2 are given below. It is clear from the actual human image density formed in all two color frequencies of the ancient ^ n ^ ， that the coating is the 上 上 王 摄影 元 #. Stomach is useful for multi-touch information. The film element of Example 5 was loaded in a mm / fl 7 lens- ^ telescopic camera. Set the camera's exposure control to asa, and use this camera to capture vivid scenes. Taking at 145. 〇Heating for 20 seconds to develop the element &apos; produces a clearly identifiable negative image, and then the element is processed without processing. The resulting image is scanned with a Nikon LS2000 film scanner. The resulting digital image was loaded into Adobe Photoshop (version 5.0.2), which was digitally corrected, adjusted tonal ratio and color saturation, so that an acceptable image was obtained. Use a computer monitor to view images like software. Thereafter, the image file was sent to a Kodak 8650 dye sublimation indene film processor, and an acceptable hard copy output was obtained. This illustrates the use of a device containing a compound of the invention in a complete development chain. Example 8: Measurements were performed in a model system to study the unblocked power of the developer of the present invention. Use two kinds of separation technology to get the information of these dynamics: 1 · Will block the developer Dn in formazan (DMS0, Aldrich -99-) This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back before filling out this page} Φ ------ —Order -------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs which is 213 A7 V. Description of the invention (97) 99.8 +% anhydrous) (MmM solution is heated under nitrogen atmosphere at 13 ° C or other set temperature. After blocking the developer disappears, aliquots are taken at different time intervals and rapidly cooled in cold water And analyzed by high pressure liquid chromatography (HPLC). Then the rate constant (k) and half-life (t1 / 2) of the deblocking reaction are obtained. 2 · Detecting the released color developer can also complete the monitoring of the pyrolysis reaction Take an aliquot of the reaction solution in DMSO and convert the released developer to a dye with coupling agent C-3 at pH 10. The dye can be quantified with a spectrometer at ~ 568 μm in a 1 cm chamber, and the reaction can be obtained. The rate constant. Representative results are listed in Table 8-1 below. After blocking the developer, any of the detection methods produced by t 丨, 2 値 are lower than the control example. (丨, the lower the 2 値 is, the more active the 7F developer is, which is expected. Group blocking developer DC-3 (control) DC-4 (control) D-6 (invention) D-16 (invention) ------- D-28 (invention) # Table 8-1 minutes, method 1 6.83 20,16 0.944 0.587 ^ 1/2 J minutes, method 2 7.60 18.2 0.893 0.722 (Please read the notes on the back before filling this page) _! Order -------- Printed by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs -100-

Claims (1)

588213 4 ·. '. ____ ~ 一' Patent Application No. 08912 ^ 841 '' is the application of the patent application. (April 1993) 8 8 8 8 A B c D Benefits: Photographic or photothermographic developing elements, which include a developing layer related to the structure I compound: W (w) X PUG-(LINK 1) ι- (TIME) m- (LTNK 2) n- \ I where: PUG is a base that can be used for photography; LINK 1 and LINK 2 are bond groups; TIME is Timing base; 1 is 0 or 1; m is 0, 1 or 2; η is 0 or 1; Υ is C, N, 0 or S; X is an electron-withdrawing group; W is hydrogen, self-primed or substituted or unsubstituted Substituted alkyl, cycloalkyl, aryl or heterocyclyl, or W can combine with T or R12 to form a ring. W is 0 to 3 when Υ is C, and w is 0-2 when Y is N. When Y is 〇 or 3, \ ¥ is Οι, when W is 2, the two W groups can combine to form a ring, when W is 3, the two W groups can combine to form a ring, or the three W groups can Combined to form a bicyclic substituent; R12 is hydrogen, or a substituted or unsubstituted alkyl, ring, alkyl, aryl or heterocyclic group, or R12 can combine with T to form a ring; this paper size applies Chinese national standards (CNS) A4 specification (210X 297 mm) Patent application scope: substituted or unsubstituted alkyl, cycloalkyl, aryl or six-membered group, t is 0, the limitation is that if 乂 is a sulfone group And &amp; and 1 are 1, and m and n are each 0, then or 2; If z is 2 then the two T groups can be combined to form a ring; X is monovalent, a is 1 or 2, and b is 1; and LINK1 &amp; L IN K 2 independently has the structure π: u) -〆 ·, II where X represents carbon or sulfur; Υrepresents oxygen or ethics, the center of which is a substituted or unsubstituted fire group, or a substituted or unsubstituted aryl group; P is 1 or 2 Z represents carbon, oxygen, or sulfur; r is 0 or 1; the restriction is that when X is carbon, 卩 and ^ are both i, when χ is sulfur and γ is oxygen, ρ is 2 and r is 0; # means Bonded to PUG (about LINK 1) or TIME (about LINK 2); $ means bonded to TIME (about LINk 1) or T⑴ substituted carbon (about LINK 2). -2-This paper size applies to China National Standard (CNS) A4 specification 588213 2. The developing element according to item 1 of the scope of the patent application, wherein puG is a coupling agent 'development inhibitor, bleach accelerator, bleach inhibitor, inhibitor release developer, dye precursor, developer, silver ion fixative 'Electron transfer agent, silver halide solvent, silver halide complex, reduction § Same as' image reconciler, pre-processing or post-processing image stabilizer' hardener, tanning agent, misting agent, ultraviolet radiation absorber Nucleating agents' chemical or spectral sensitizers, desensitizers, surfactants, or precursors thereof. 3. The developing element according to item 1 or 2 of the scope of the applied patent, wherein τΙΜΕ is a time-selection base, which can be chosen freely (1) using aromatic nucleophilicity to replace the reaction base; (2) using a semi-shrinking base while cleavage reaction; (3) the base of the electron transfer reaction using a conjugated system; and (4) the base of the reaction is replaced by intermolecular nucleophilicity. 4 · The developing element according to item 1 or 2 of the scope of patent application, wherein the compound of the structure I has the structure III: III Among which: Z is 0Η or NR ^ R3 'wherein R2 and R3 are independently chlorine or substituted or unused 3- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 588213 8 8 8 8 AB c D, patent application scope, to substituted alkyl, or heart-to-heart connection to form a ring; / 5, R6'R々R8 is independently hydrogen, from the prime 'hydroxyl, amino group &quot; oxygenation, carbon fermentation Amine group, horizontal amino group, continuous amino group or alkyl group, 3 can be connected to WRA 'and / recognized that it can be connected to Ml and the shape T is substituted or unsubstituted alkyl group, cycloalkyl group, aryl group Or six-membered hetero% group group, t is 0, 丨 or 2, with the restriction that if χ4 飒 group and a and 1 are each Bu and π ^ η are each 0 ′ then t4l or 2; and if ... then two T group can be combined to form a ring; Ru is hydrogen, or substituted or unsubstituted alkyl, cycloalkyl, aryl or heterocyclic group or can be combined with τ or W to form a ring; X is an electron-withdrawing group; Υ is C, N, 0 or s; X is divalent and a is 1 or 2; b is 1; W is hydrogen, from prime, or substituted or unsubstituted alkyl, cycloalkyl, aryl or Heterocyclyl, or w can interact with T Combined to form a ring, when Y is C, w is 0 to 3, when Y is _w is 0-2, when ¥ is 0 or 0-1, and when w is 2, two W groups can be combined to form Ring, when ~ is 3, one W group can be combined to form a ring, or three w groups can be combined to form a bicyclic substituent. 5. The developing element according to item 1 of the scope of application for a patent, which is a photothermographic element, a photographic element, or a thermosensitive element. 6 · —A kind of imaging method, including the full-image exposure according to the patent application model paper size applicable to China National Standard (CNS) A4 specifications (210X 297 mm). A B c D 588213, the scope of application for patents The development steps of item 1 or 2 are developed. 7. The method according to item 6 of the patent application scope, wherein the developing comprises processing the full-image exposure element at a temperature between 90 ° C and 180 ° C for a time of 0.5 to 60 seconds. 8. An imaging method comprising the steps of scanning the developing element according to item 1 or 2 of the scope of the patent application after exposure and development of the full image to form a first electronic image representation of the full image exposure. 9. An imaging method comprising the steps of digitizing the generated first electronic image representation and the full-image exposure, development, and scanning of the developing elements described in item 1 or 2 of the scope of the patent application to form a digital image. 10. An imaging method comprising the steps of: thermally developing a developing element according to item 1 or 2 of the patent application scope after full image exposure to form a developed image; scanning the developed image to form a developed image from the developed image A first electronic image representation; digitizing the first electronic record to form a digital image; adjusting the digital image to form a second electronic image representation; and storing, transmitting, printing, or displaying the second electronic image representation. 11. A photographic or photothermographic developing element comprising a developing layer related to the compound of structure I: I j. PUG -— (LINK 1), —— (TIME) m —— (LINK 2) n ~ i ^ 12 -5- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 588213 A8 B8 C8 D8 Six. Patent application scope Among them: PUG is a base that can be used for photography; LINK 1 and LINK 2 are bonding groups; TIME is a timing base; 1 is 0 or 1; m is 0, 1 or 2; η is 0 or 1; Υ is C, N, 0 or S; X is an electron-withdrawing group; W is hydrogen, from a prime or substituted or unsubstituted alkyl, cycloalkyl, aryl or heterocyclic group, Or W can form a ring by combining T or R12. When Υ is C, w is 0 to 3, when Y is N, w is 0-2, when Y is 0 or 3, \ ¥ is 〇ι, and when w is 2 The two W groups can be combined to form a ring. When w is 3, the two W groups can be combined to form a ring, or the three W groups can be combined to form a bicyclic substituent; R12 is hydrogen, or substituted or unsubstituted. Substituted alkyl, cycloalkyl, aryl or heterocyclyl, or R12 can combine with T to form a ring; T is substituted or unsubstituted alkyl, cycloalkyl, aryl or six-membered heterocyclyl, t is 0, 1 or 2, and if t is 2, two T groups can be combined to form a ring; X is divalent, a is 2, and b is 1; and LI NK 1 and LI NK 2 are independent With structure 11: -6-This paper is of suitable size China National Standard (CNS) A4 specification (210 X 297 mm) 588213 8 8 8 8 AB c D 6. Patent application scope ⑺P II 3 X $ II where X represents carbon or sulfur; Υ represents oxygen, sulfur or N-Ri , Where 1 ^ is a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group; p is 1 or 2; Z represents carbon, oxygen, or sulfur; I · is 0 or 1; When X is carbon, both p and r are 1, when X is sulfur and Y is oxygen, p is 2 and r is 0; # indicates bonding to PUG (about LINK 1) or TIME (about LINK 2); $ Denotes bonding to TIME (about LINK 1) or T⑴ substituted carbon (about LINK 2). This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)