TW585749B - Shoe sole formed by single foaming process and having different hardness, method and mold for producing the same - Google Patents
Shoe sole formed by single foaming process and having different hardness, method and mold for producing the same Download PDFInfo
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五、發明說明(1) 【發明所屬之技術領域】 本發明係關於一種發泡成型之鞋底 並具有不同軟硬度之部位;且該鞋 並不會造成環境污染。 -<Ik過程 【先前技術】 按,現今之EVA發泡鞋底,其各個部位 ? ^ . ^ ^ ^ 4ΓΛ 重作用。由於習知之發泡鞋底係為單 物日年,雖能提供較佳之保護作用,惟,穿著 ^到硬 為減損,故難以兼顧其功能。、性即較 再者’習知EVA發泡鞋底之製作過程中所 m產生無法回收利用之廢料,而 邊角 另:專腿發泡鞋底均為單一顏色, 之產生。 ,故較不美觀。 人土夕禋顏色 【發明内容】 本發明旨於解決上錕纯从& & > % 種發泡成型鞋底,嗲鞋底夕、 L 目的在於提供一 ,兼具防護及舒適=广 外圍係具有不同軟硬度 底可ί::;;;:的在於提供-種發泡成型鞋底,該鞋 本,^之再—目的在於提供一種發 ,其可將裁㈣之廢料回收再纟,不會污染環境:之衣法 五 發明說明(2) 【實施方式】 以及所達成之功效委以;進-步瞭解本發明之目的、特徵 合圖式詳細說明於 I兹舉本發明—較佳實施例,並配 第-圖係本發nt二圖式之安排為: :一圖係顯不-滾軋裁切成之薄片。 ί二ϊ係顯:高、低硬度片材之疊接關係。 笛四闽係第二圖之片材疊置成一待發泡體之立體圖。 第五圖顯示本發明一較佳實施例之模具之下模。 ,六圖係模具合模進行抽真空之剖面圖。 第七圖係第六圖之模具完全合模之狀態。 第八圖係發泡成型之鞋底之立體圖。 第九圖係第八圖之剖面圖。 本發明所提供之一種發泡鞋底之製法,係使所製成 鞋底於不同位置具有不同之軟硬度,並可製成多種顏色。 本發明之製法包含下述步驟: 一、將多種化學物料混練成二種不同軟度之組成物: 首先取多種化學物料加以混練成二種不同軟硬度之化 學組成物。本實施例所使用之化學物料包括:EVA(乙歸醋 酸乙烯S旨樹脂)’聚乙烯(PE ’polyethylene) ;EPDM (ethylene propylene diene methylene,乙烯和丙稀之 共聚物),為一種人造膠,以及一業界稱為ENG AGE之化學 品(同樣為乙浠糸之物品’為杜邦公司近年來所開發之新 產品,尚無法找到正式學名),將上述顆粒狀之物料經捏V. Description of the invention (1) [Technical field to which the invention belongs] The present invention relates to a foam-molded shoe sole with different soft hardness parts; and the shoe does not cause environmental pollution. -< Ik process [Previous technique] Press, the current EVA foam sole, its various parts? ^. ^ ^ ^ 4ΓΛ heavy action. As the conventional foam sole is a single object, it can provide better protection, but it is difficult to take care of its functions because it is detrimental to wearing. "Sex is more important." Known EVA foam soles in the manufacturing process produce waste materials that cannot be recycled, and corners. In addition, the special-leg foam soles are of a single color. , So less beautiful. The color of the human soil [Inventive content] The present invention aims to solve the above-mentioned pure & & >% foam molding soles. With different soft hardness bottoms can be :: ;;; :: to provide-a kind of foam molding soles, the shoe, and ^-again-the purpose is to provide a hair, which can recycle the cut waste material, not Will pollute the environment: the fifth method of the invention (2) [Embodiment] and the achieved effect entrusted; further understanding of the purpose, features and drawings of the present invention are described in detail in the present invention-best practice For example, the arrangement of the second figure in the second figure is as follows:: A picture is a thin sheet that is cut and rolled. ϊThe second line is the overlapping relationship of high and low hardness sheets. The second sheet of Di Simin is a three-dimensional view of a foam to be stacked. The fifth figure shows a lower mold of a mold according to a preferred embodiment of the present invention. , Figure 6 is a sectional view of the mold clamping and vacuuming. The seventh figure is a state in which the mold of the sixth figure is completely closed. The eighth figure is a perspective view of a foamed sole. The ninth figure is a sectional view of the eighth figure. The manufacturing method of the foamed sole provided by the present invention is to make the manufactured sole have different soft hardness at different positions and can be made into multiple colors. The manufacturing method of the present invention includes the following steps: 1. Kneading a plurality of chemical materials into two compositions with different softness: First, a plurality of chemical materials are mixed and kneaded to form two chemical compositions with different soft hardness. The chemical materials used in this embodiment include: EVA (PE 'polyethylene); EPDM (ethylene propylene diene methylene, a copolymer of ethylene and propylene), which is an artificial rubber, And a chemical called ENG AGE in the industry (the same product of acetylene is a new product developed by DuPont in recent years, and the official scientific name has not yet been found), the above-mentioned granular material is kneaded
585749 五、發明說明(3) 合抵:(混練機)加以混合密峡# 料密練成低硬度及高硬;ΐ檀:=二本發明係以上述物 中,高硬度組成物之軟硬度之組成物。其 ^ ENGAGE 24:3; \tnM ;: 29^ 發泡劑、填充劑、架橋劑=:咖:4〜1〇%,其餘為 铷夕士八+ k 4各式加工助劑。而低硬度組成 S i:與該高硬度組成物㈣,差別在於成份之比例 二;:如’將觀GE之重量百分比提高,譬如⑼韻, 而來乙烯之含量則降低,例如7〜15%,惟低硬度组成物之 與I乙古稀之^…以此為限。於本發〜中所^之 又”间硬度組成物,係為相對的關係,就EVA、 聚乙三種物料之物性而言,E隱e之硬度最低 (即最幻’而聚乙烯之硬度最高,而m之軟硬度係居中 對於”玄高硬度組成物"之組成比例*言,適當的提高 降低聚乙稀之含量,即可成為"低硬度組 成二。另須說明的是’於實施上該二組成物不以具有 ENGAGE為必要,可由EVA、聚乙烯、EpDMA加工助劑組成 即可,當聚乙烯之重量百分比較高時,即成為高硬度組成 物;而EVA之含量較低時’則為低硬度組成物。 又’該二化學組成物於混練時可加入色料,使混練後 之该一組成物形成不同顏色。 二、將該二化學組成物分別滾軋、裁切成薄片: 、上述之二組成物經密練完成後,復經由滾輪機及出片 機滚軋、冷卻以及裁斷成多數之薄片(丨〇 ),如第二圖所示 。於實施例中,各薄片之厚度約I 5〜2 . 〇mm。585749 V. Description of the invention (3) Compatible: (kneading machine) mixed with Mixia # material is densely mixed into low hardness and high hardness; tan sandalwood: = This invention is based on the above, the hardness and hardness of the high hardness composition Degree of composition. ^ ENGAGE 24: 3; \ tnM ;: 29 ^ Foaming agent, filler, bridging agent =: coffee: 4 ~ 10%, the rest are all kinds of processing aids. The low-hardness composition S i: differs from the high-hardness composition ㈣, the difference is in the ratio of the two components; for example, if the weight percentage of GE is increased, such as the rhyme, and the content of ethylene is decreased, for example, 7 to 15% However, the difference between low hardness components and I ^^ is limited to this. The hardness composition in the present invention is a relative relationship. In terms of the physical properties of EVA and polyethylene, the hardness of E is the lowest (that is, the most magical and the hardness of polyethylene is the highest). The soft hardness of m is in the middle. For the composition ratio of "high hardness composition", if the content of polyethylene is appropriately increased and reduced, it will become "low hardness composition 2." It must also be stated that ' In practice, the two compositions do not need to have ENGAGE. They can be composed of EVA, polyethylene, and EpDMA processing aids. When the weight percentage of polyethylene is high, it becomes a high hardness composition; When it is low, it is a low-hardness composition. Also, when the two chemical compositions are mixed, a colorant may be added so that the one composition after the mixing forms a different color. Second, the two chemical compositions are rolled and cut separately. Cut into thin slices: After the above two compositions have been condensed, they are rolled, cooled, and cut into a large number of slices (丨 0) by a roller and a sheet extruder, as shown in the second figure. In the embodiment, , The thickness of each sheet is about I 5 ~ 2. 0mm .
585749 五、發明說明(4) 三、 將該二化學組成物之薄片分別裁切成一種高硬度 片材及一種低硬度片材: 經過上述步驟後,該二組成物可分別被製成多數薄片 ,接著復於該二組成物之薄片(1 0)再分別裁斷成類似鞋形 之初形片材,可得第三圖所示之多數高硬度片材(1 2)及低 硬度片材(1 6)。 四、 將多數高硬度片材疊接成一初體,並使該初體頂 面具有一内凹空間: 於裁切成該二種不同硬度之片材(12) (16)後,依所要 製成之鞋體之重量取用適當數量之該二種片材以便疊接成 第四圖所示之待發泡體(3 0 )。其中,請參閱第三圖,多片 (如八至十片)之高硬度片材(12)係疊接成一初體(20),於 該初體頂面並設一内凹空間(2 5 )。於本實施例,係將位於 該初體(20)上半部之若干片材(12)(例如四片)各裁切出一 内孔(1 4),藉由該等内孔(1 4)形成該内凹空間(2 5)。該初 體(2 0)之周緣得另以電熱器適當的電灼出若干個固定部位 (26),使該等片材(1 2)被初步固定,令初體不會輕 離。 、声須說明的是,於上述步驟二中,所製成之各薄片(1 〇) 尚未發泡,故裁切出片材(12) (16)後所產生之廢料<17丨χ 2切内孔⑴)所形成之廢料(19)均可再回收使;= 料經由滾輪機之滾軋及出片機之冷卻、裁斷,可再 成溥片(1 0 ),以供再裁切成片材。 、 五、將若干低硬度片材置入該初體之内凹空間内,形585749 V. Description of the invention (4) 3. Cut the two sheets of the chemical composition into a high-hardness sheet and a low-hardness sheet: After the above steps, the two compositions can be made into a plurality of sheets, respectively. Then, the sheets (1 0) compounded with the two compositions are cut into original shoe-like sheets, and most high-hardness sheets (12) and low-hardness sheets (see Figure 3) can be obtained. 1 6). 4. Superimpose most of the high-hardness sheets into a primordial body, and make the top mask of the primal body have a recessed space: After cutting into two sheets of different hardness (12) (16), make as required For the weight of the finished shoe body, an appropriate number of the two sheets are used to overlap to form the to-be-foamed body (30) shown in the fourth figure. Among them, please refer to the third figure, a plurality of pieces (such as eight to ten pieces) of high-hardness sheets (12) are stacked to form a primitive body (20), and a concave space (2 5 is provided on the top surface of the primitive body). ). In this embodiment, an inner hole (1 4) is cut out from each of a plurality of sheets (12) (for example, four pieces) located on the upper part of the primitive body (20), and the inner holes (1 4) ) To form the recessed space (2 5). The perimeter of the primary body (20) may be additionally ignited with a plurality of fixing parts (26) by an appropriate electric heater, so that the sheets (1 2) are initially fixed, so that the primary body will not be detached. It must be stated that in the above step 2, each sheet (10) produced has not been foamed, so the waste material generated after cutting out the sheet (12) (16) < 17 丨 χ 2 Cut the inner hole ⑴) The waste material (19) formed can be recycled again; = the material is cooled and cut through the rolling of the roller machine and the tablet machine, and can be re-formed into a cymbal (1 0) for re-cutting Into sheet. Fifth, put a number of low hardness sheets into the recessed space of the original body, shape
第7頁 585749 五、發明說明(5) 成一待發泡體: (如二於該初體(20)形成後,復將若干片低硬度片材(16) 、、/#7^置入初體(20)之内凹空間(25)中,而完成該待發 1 。各該低硬度片材(1 6 )係為一内部完整之片體, ”大小約等於該内孔(1 4)。 六、將該待發泡體置入模具中發泡: 中 ,著將該待發泡體(30)移入模具之模穴内以發泡。i 本發明所使用之模具係具有其特別之處。 八 穴 請t閱第五圖,模具(40)之上、下模係各設有若干模 和古^松具於其中一模體,例如下模(42),之合模面係埋 圈橡膠材質之密封圈(44),模穴(45)係位於該密封 圃所圍成之範圍内,此外,模具之至少一模體於密封Page 7 585749 V. Description of the invention (5) Form a foam to be prepared: (For example, after the initial body (20) is formed, put several pieces of low hardness sheet (16), / # 7 ^ into the beginning The recessed space (25) of the body (20) completes the ready-to-go 1. Each of the low-hardness sheets (16) is an internally complete sheet body, and the size is approximately equal to the inner hole (1 4). 6. The foam to be foamed is placed in a mold: In the process, the foam to be foamed (30) is moved into the cavity of the mold to foam. I The mold used in the present invention has its special features. Eight holes please read the fifth picture, the mold (40) above and below the mold system are equipped with a number of molds and ancient slack tools in one of the mold body, such as the lower mold (42), the clamping surface of the mold is buried ring The sealing ring (44) made of rubber and the cavity (45) are located in the area enclosed by the sealing garden. In addition, at least one of the mold bodies of the mold is sealed.
Hi範圍内係設#若干抽氣孔(46),該等抽氣孔⑽ 另\丨驻、體之合模面上,而非位於模穴(45)内,並以真空 吸引裝置連接於該等抽氣孔(46)。 ^ 广欲發泡時,將各待發泡體(3〇)置入於各模穴(45)内, U、:丨Ιϊ?1)(42)合模,本發明於模具位置設有感應 槿,測口模狀態。合模過程中’當感應器感應到位於下 圈(44)接觸到上模⑷)日夺,如第六圖戶斤*,模具 伟25 =合模動作’此時’密封圈(44)所圍繞之範圍 Π 真空吸引裝置並經由該等抽氣孔(46)將密 以成=抽真空’則上下模之模穴(45)即可 广。俟真空狀態完成後,模具合模成第七圖之閉合狀 心。该模具(40)於至少一模體之各模穴(45)周圍係設有凹Within the Hi range are #exhaust holes (46). These exhaust holes are located on the mold closing surface of the body, instead of being located in the cavity (45), and connected to the exhaust by a vacuum suction device. Stomata (46). ^ When you want to foam, place each to-be-foamed body (30) in each cavity (45), and U ,: 丨 Ιϊ? 1) (42) close the mold. The present invention is provided with a sensor at the position of the mold. Hibiscus, measuring die status. During the mold clamping process, 'when the sensor senses that the lower ring (44) is in contact with the upper mold ⑷), as shown in the sixth figure *, mold mold 25 = mold clamping action' at this time 'the seal ring (44) The range around the vacuum suction device and the vacuum suction device (46) through the air suction holes (46) will be dense = vacuuming, then the cavity (45) of the upper and lower molds can be wide.俟 After the vacuum state is completed, the mold is closed to form the closed center of the seventh figure. The mold (40) is provided with recesses around each cavity (45) of at least one mold body.
第8頁 585749 五、發明說明(6) 唇緣(48) ’故模穴(45)密合時,上下模之合模面間並 =全閉合,仍保有間隙,故合模後,密封圈(44)僅被壓 細變形,不會損毁。 扠具合模後,復經適當的溫度(如丨7〇艺)及時間(如J 〇 分鐘)、,使各待發泡體(30)於模穴内發泡。各模穴之大小 、、、勺為初胚之積體,於模塑過程中,該等片材(12)(16)會受 熱溶f呈液態於模穴内流動,由於模穴内係呈真空狀態, 使,態之化學組成物易於流動,並使熱量容易傳導,以增 加杈塑效果。由於該待發泡物(3 〇 )之構形已使得高硬度及 低車人硬度片材(1 2)(1 6)各排列於適當位置,故模塑過程中 ,該等物體(12) (16)會於其定位處產生化學反應。液態狀 之熔融物於模穴内流動時會流向壓力最小之處,故待發泡 體(30)下半部之該等高硬度片材(12)(即未設内孔(14)者) 會往該内凹空間(25)流動,並擠向低硬度片材(16)下方; 低硬度片材(16)則受到内凹空間(25)之侷限,保持於内凹 空間内產生反應。於反應過程中,目高、低硬度片材 (16)之成份相同,故會完全交融。於本實施例中,低硬度 片材及高硬度片材係具有相同之發泡倍 :位之發泡率—致,以達成良好之發泡效果並減少内=各 七、將模具開模使發泡物發泡成型: 於f泡時間完成後,模穴内之發泡物體已完成化學反 應’令模具(40)開模|,發泡物即跳離模穴,於模且外依 模穴之形狀而發泡定型。本實施例係為丨點6倍之發泡率, 585749 五、發明說明(7) 成型品之體積為模穴之丨.6倍大。成型後之鞋底(5〇)如第 八、九圖所不,實物照片如附件。於鞋底頂面中央區域係 為低硬度片材(16)所發泡完成之軟區域(52)(照片上所示 之淺綠色區域),而鞋底之周圍及底面則為高硬度片材所 發泡成之硬區域(54)(照片上之藍色部份)。穿著時,該軟 區域(52)係對應於腳掌之處,其物性較軟,使腳掌感受到 柔軟之觸感,以提供穿著之舒適性;而硬區域(54)之物性 較硬’可對足部提供良好的防護作用並具良好的抓地力。 本叙明之製法所提供之鞋底具有如下功效: 一、 本發明係使發泡物發泡完成後,同時兼具有不同 軟硬度之區域,兼具舒適性及防護性之要求,^業界之首 創。且由附件之照片所示可知,軟區域(52)及硬區域(⑷ 具有完全的接合性,且交接面平整無落差。 二、 如同照片所示,軟、硬區域可為不同顏色,婵加 發泡物之美觀。此外,於置入模且恭、ώ y β π入",w 發泡前,可於待發泡物 色#’成型後之鞋底頂面即可具 有不同顏色之色塊’如照片上之橘色 等色塊所形成之分佈狀態於每一鞋底 =色寺遠 性。而最主要者,本發明係發泡完:彳種=特 無須發泡後進行上色作業。 ,、百夕種顏色, 三、 本:明於製造過程中所裁切之廢 角料均可反覆回收利用再製,不會造成(一17九)(19)、邊 明亦可省卻而許多傳統製法之上膠、修酋兄且本發 高污染製造程序。 "磨邊等煩雜之 585749 五、發明說明(8) 四、本發明用以抽真空之抽氣孔係設於模體之合模面 上,而非設於模穴内,不會受到待發泡物之阻塞,故無需 清理抽氣孔,且不會有誤判真空狀態之狀況。 綜上所陳,本發明係為一首創之技術手段,具高度創 作性及合於產業上之利用性,並具進步性功效,爰依法提 出申請。Page 8 585749 V. Description of the invention (6) Lip (48) 'When the mold cavity (45) is tightly closed, the clamping surfaces of the upper and lower molds are fully closed and there is still a gap, so after the mold is closed, the seal ring (44) It will be crushed and deformed without damage. After the fork is closed, the appropriate temperature (such as 丨 70 art) and time (such as J 0 minutes) are repeated to foam each to-be-foamed body (30) in the cavity. The size of each cavity is the product of the original embryo. During the molding process, the sheets (12) (16) will be heated and melted to form a liquid and flow in the cavity, because the interior of the cavity is in a vacuum state. The chemical composition of the state is easy to flow, and the heat is easily conducted to increase the plastic effect. Because the configuration of the foam to be foamed (30) has made the high hardness and low rider hardness sheets (1 2) (16) each in an appropriate position, during the molding process, these objects (12) (16) A chemical reaction occurs at its location. The liquid melt will flow to the minimum pressure when flowing in the mold cavity, so the high hardness sheets (12) (that is, those without inner holes (14)) for the lower half of the foam (30) will Flow toward the recessed space (25) and squeeze below the low-hardness sheet (16); the low-hardness sheet (16) is limited by the recessed space (25) and remains in the recessed space to generate a reaction. During the reaction, the high and low hardness sheets (16) have the same composition, so they will completely blend. In this embodiment, the low-hardness sheet and the high-hardness sheet have the same foaming ratio: the same foaming ratio, so as to achieve a good foaming effect and reduce the internal = each. Foam molding: After the foaming time is completed, the foamed object in the mold cavity has completed the chemical reaction. 'Mold (40) opens the mold |, and the foam will jump out of the mold cavity and follow the mold cavity. Shape. In this example, the foaming rate is 6 times the point, 585749 V. Description of the invention (7) The volume of the molded product is 6 times as large as the cavity. The molded sole (50) is not as shown in Figures 8 and 9, and the actual photo is as attached. The central area on the top surface of the sole is the soft area (52) (the light green area shown in the photo) foamed by the low-hardness sheet (16), while the periphery and bottom of the sole are issued by the high-hardness sheet. Foamed hard area (54) (blue part on the photo). When worn, the soft area (52) corresponds to the sole of the foot, and its physical properties are relatively soft, so that the sole feels a soft touch to provide comfortable wearing; while the hard area (54) is relatively hard. The feet provide good protection and good grip. The sole provided by the manufacturing method of this description has the following effects: 1. The present invention is to make the foamed material foamed at the same time, it also has areas of different soft hardness, and has both comfort and protection requirements. First. And as can be seen from the attached photo, the soft area (52) and the hard area (⑷ have complete bonding, and the interface is flat and free of drops. 2. As shown in the photo, the soft and hard areas can be of different colors. The beauty of the foam. In addition, before the mold is placed, and it is respectful and free, you can have different colors of color blocks on the top surface of the sole after the foam is colored # 'after molding. 'The distribution state formed by color blocks such as orange color in the photo is in the sole of each shoe = color temple remoteness. And the most important thing is that the present invention is foaming: 彳 species = no need to carry out coloring after foaming. The color of Baixi is three. This: The waste scraps cut during the manufacturing process can be recycled and reused repeatedly, which will not cause (1179) (19). Bianming can also save many traditions. The manufacturing method is to glue, repair the chief and make the high-pollution manufacturing process. &Quot; Erasing and other troublesome 585749 5. Description of the invention (8) 4. The exhaust holes for vacuuming according to the present invention are provided in the mold clamping body. The surface, instead of being set in the cavity, will not be blocked by the foam, so no cleaning is required Suction holes, and there will be no misjudgment of the state of vacuum. In summary, the present invention is a pioneering technical means, highly creative and industrially applicable, and has progressive effects, according to the law Application.
第11頁 585749Page 11 585749
圖式簡單說明 \圖係本發明—較佳實施例之製造流程圖。 Ϊ亡Γ系顯示二滚軋裁切成之薄片。 f二圖係顯示高、低硬度片材之疊接關係。 ,四圖係第三圖之片材疊置成一待發泡體之立體圖 第五圖顯示本發明一較佳實施例之模具之下模。 第六圖係模具合模進行抽真空之剖面圖。 第七圖係第六圖之模具完全合模之狀態。 第八圖係發泡成型之鞋底之立體圖。 第九圖係第八圖之剖面圖。Brief Description of the Drawings \ The drawing is a manufacturing flowchart of the present invention-a preferred embodiment. The die Γ shows two rolls cut into thin slices. The second graph f shows the overlapping relationship between high and low hardness sheets. The fourth figure is a perspective view of the third figure in which the sheets are stacked into a foam to be foamed. The fifth figure shows the lower mold of a preferred embodiment of the present invention. The sixth figure is a sectional view of the mold clamping and vacuuming. The seventh figure is a state in which the mold of the sixth figure is completely closed. The eighth figure is a perspective view of a foamed sole. The ninth figure is a sectional view of the eighth figure.
圖號簡單說明: 薄片(1 0) 高硬度片材(1 2 ) 初體(20) 固定部位(26) 模具(40) 密封圈(44) 抽氣孔(46) 軟區域(52) 内孔(1 4) 低硬度片材(1 6 ) 内凹空間(2 5 ) 待發泡體(30) 上、下模(41)(42) 模穴(4 5 ) 鞋底(5 0 ) 硬區域(5 4)Brief description of drawing number: Sheet (1 0) High hardness sheet (1 2) Primitive body (20) Fixing part (26) Mold (40) Sealing ring (44) Exhaust hole (46) Soft area (52) Inner hole ( 1 4) Low hardness sheet (1 6) Recessed space (2 5) To be foamed (30) Upper and lower mold (41) (42) Cavity (4 5) Sole (5 0) Hard area (5 4)
第12頁Page 12
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TW92109873A TW585749B (en) | 2003-04-28 | 2003-04-28 | Shoe sole formed by single foaming process and having different hardness, method and mold for producing the same |
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TWI625100B (en) * | 2016-10-04 | 2018-06-01 | Tae Kwang Industrial Co Ltd | Metal mold for sole molding |
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US11700911B2 (en) * | 2018-05-18 | 2023-07-18 | Asics Corporation | Shoe sole including laminate-structured midsole |
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TWI625100B (en) * | 2016-10-04 | 2018-06-01 | Tae Kwang Industrial Co Ltd | Metal mold for sole molding |
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