TW584681B - Method of producing fiber having functional mineral powder and fiber produced therefrom - Google Patents

Abstract

A method of producing fiber having functional mineral powders comprises the steps of a first pulverizing functional mineral which crystal form of is pinacoid, a second closely pulverizing the first pulverized functional mineral powders to be less than 1/3 granularity of desired fineness, mixing and synthesizing 0.1-10 weight% of the second pulverized functional mineral powders and 90-99.9 weight% of a chemical resin, and spinning the mixture of functional mineral powders and the chemical resin.

Description

584681

[Technical field to which the invention belongs and the conventional technology in the field] The present invention provides a related mineral powder-containing fiber and a method for manufacturing the same. In particular, it refers to the use of a single functional and crystalline form of a desktop (plate-like) ) Mineral powder, or choose a functional, crystalline (cleaved) polyhedron such as columnar, pyramidal, rhombohedral, or hexahedral, or octahedral, or dihedral. A method for producing functional fibers by mixing a certain amount of mineral powders after selection, and then selectively mixing inorganic antibacterial agents and a certain amount of chemical resins in the mixed powder, and a method for producing functional fibers Obtained functional fibers.

In the field of fiber technology that reflects the importance of functional products related to functional products, functional minerals have been added to create functional dimensions. For such functional minerals, most of them will be used such as barley, hornblende, rutile, zeolite, vermiculite, mullite, crystal, tourmaline, etc. There are many kinds of minerals synthesized by these natural minerals. These minerals can exert a variety of functions and effects such as far-infrared release, antibacterial, deodorization, electromagnetic wave blocking, ultraviolet blocking, adsorption, hygroscopicity, anion release, and prevention of static electricity, which are beneficial to the human body. The production of conventional functional fibers is based on the general manufacturing process of fibers. 'A certain amount of functional mineral powder is added to the chemical resin. After injection, stretching, false twisting, shredding or weaving, weaving and processing, And make functional fibers. However, in this conventional and functional manufacturing process, functional minerals added to chemical resins, because their crystal shapes are columnar, pyramidal

584681 V. Description of the invention (2) Shapes, rhombohedral shapes, hexahedral shapes, octahedral shapes, dodecahedral shapes, etc., so in the fiber manufacturing process, it is a device, such as a belt, The wear of rollers and guide rods is extremely frequent, and the surface of the raw silk produced using the mineral's inherent type is not uniform, resulting in the surface of the resulting fiber not being smooth, and situations such as wire breakage during the production of the raw silk. Quite frequently. In other words, on the production of functional fibers by adding mineral powder, because the mineral's determining structure is irregular and the hardness is high, the prepared raw silk has mineral particles protruding on the surface layer, and in the manufacturing process Because of friction, the injection, stretching, false capture, and textile processing equipment of Amberg will be lost, making normal production impossible. [Technical problem to be achieved by the invention] > β In view of this, in order to solve the lack of knowledge in the present invention, the invention has the first infrared release, blood pressure adjustment, pain relief, resistance, resistance, and beneficial to the human body. Long-distance blocking, ultraviolet blocking, absorptive power, and the combined functions and effects of electromagnetic wave elimination, using more than i kinds and what? Crystalline ^ release and other various (plate-like) or cover-like mineral powder, Π ^ is the desktop fat after mixing, using ordinary mixing or shooting ς $ and chemical tree stretching, false twisting, shredding, textile and After the injection / injection, the powder particles passing through are aligned in the same direction, so = because the raw silk is mixed and soft, compared with the conventional fiber, the productivity is smooth. The second object of the present invention is to Provide --- superior characteristics. Yes, and the crystalline form belongs to the tabletop shape of the first purpose described above, and the crystalline form belongs to the columnar shape, 584681 V. Description of the invention (3) 5 Ϊ 2: rhombohedral, or hexahedral Shaped, octahedral, dodecahedron-shaped, and shaped mineral powders, mixed with a certain amount, and then mixed with a certain amount of chemical tree mouth, and then injected by ordinary mixing or injection methods, after stretching, False twisting, shredding, and weaving can be used to make the production process smooth. Among the functions and effects of the produced fibers, in addition to the fibers and standards produced in the first purpose, they can complement their functions and effects. Compared with the conventional fiber, it has superior soft touch characteristics.

A third object of the present invention is to provide a functional fiber described in the first or second object, in order to remove iron powder mixed with minerals, in a precise pulverization process, use electromagnets and borrow Method for producing fine mineral powder with a desired diameter through a filter under pressure by using a 'mixture of inorganic antibacterial agent by adding silver (Ag) to zeolite, calcium phosphate, or thallium phosphate And enhance the fiber's antibacterial properties. [Invention structure and function] In order to achieve the first object of the present invention, the present invention is to use a suitable amount of crystal structure as a table-top and functional mineral, preferably a foliate silicate mineral (layer structure type). ), After mixing with a chemical resin, injection is performed by a common mixing or injection method, and then functional fibers are produced by stretching, false twisting, cutting, and spinning.

In order to achieve the second object of the present invention, the present invention is a polyhedron such as a columnar, pyramidal, rhombohedral, or hexahedral, or octahedral, or dodecahedral crystal structure with an appropriate amount of crystal structure. And functional mineral powder, mixed with a certain amount of this silicate mineral, and then mixed with an appropriate amount of chemical tree, and then injected using the usual mixing or injection method, and then pulled 584681

V. Description of the invention (4) Draw, false twist, shred, and weave to make functional fibers. In order to achieve the third object of the present invention, the present invention replaces silver (Ag), which is usually used as an antibacterial agent, and uses a mixture of zeolite, calcium phosphate, or acetic acid to carry silver (Ag) ions. After being properly mixed with the tabletop mineral (which may be leaf-shaped silicate mineral) powder, an appropriate amount of chemical resin is mixed, and then injection is performed by a general mixing or injection method. Twisting, shredding, and weaving to produce functional fibers, and the tabletop mineral and crystal structure are columnar, pyramidal, rhombohedral, hexahedral, or octahedral, dodecahedral. After the polyhedron-like mineral powder is moderately mixed, an appropriate amount of chemical resin is mixed, and then the injection method is used to inject, and the functional fiber is produced by stretching, false twisting, shredding, and weaving. Although the crystal structure described in the second object of the present invention has a function of a polyhedron shape such as a columnar shape, a pyramid shape, a rhombohedral shape, a hexahedral shape, an octahedral shape, a dodecahedral shape, etc., Minerals, but when used alone, it will cause production process problems that are not possible with conventional technologies. Therefore, it is best to use table-like minerals for crystal structure, and it is best to use them in moderation with an appropriate amount of phyllosilicate minerals. .

Schematic diagram of various crystal forms of minerals shown in Figure 1. (A) is a table-like shape, (b) is a columnar shape, (c) is a rhombohedral shape, (d) is a hexahedral shape, (e) is an octahedral shape, and (f) is a dodecahedral shape. Split case. The types of minerals classified according to the types (a), (b), (c), (d), (e), and (f) are exemplified as follows: (a) Table top: chalcopyrite, magnetic sulfur Iron stone, pyrite, Hui'an copper and silver

Page 7 584681 Magnetite, spar, stone, scale # 5 spodumene, sodium mica, red mica, monoclinic green, medium green mud, ban copper ore antimony silver ore, galena, Mongolian, Lilan Stone, brookite, tourmaline, syrian, amphibole, sodium ordinary feldspar, scorodite, sapphire, turquoise, sparite, rhodolite, peridotite, dolomite, stone, green, etc. Corundum rock glauberite, periclase, chloridite azurite, amphibole,, micro-slanted, malarite, wheat, vermiculite, magnesite, polyhalite heterophyllite, brown cordierite, Shi Xihui Stone, mother stone, vine stone, mother stone, chlorite, chlorite, chlorite, halloysite, rutile, azurite, apatite, hafnium, plagioclase, albedite, stone, Rod porphyry, stone, aragonite, chrysoparite, aragonite, pyroxene, refractory hectorite feldspar zeolite, amphibole V. Description of the invention (5) Mine, apatite, ore, aluminite Magnesite, calcite, ocherite, patina, talc, mother, biotite, stone, chlorophyllite soil, pyrophyllite zeolite, bundle zeolite (b) columnar: ore, feldspar, calcium oblsite, Hyalite, recording stone, redstone, obsidian, stone, ochreite, pyroxene, pyroxene, ordinary amphibole, bluestone, anorthite, salt stone, goethite, dense waxite, crystals, tourmaline gold deposits, Niobium yttrium, hard chlorite, stone, chlorite, muscovite, leaf muscovite, phlogopite Saponite, chlorite, kaolin, feldspar, flakes, azurite, iron arsenite, erythrobenzite, diaphragmite, square pillar fabble, diabase, Tremolite,, amphibole, kasuga, cancene, zeolite, anzolite, mullite, water (c) rhombohedral: calcite, muscovite, etc. (d) Hexahedral: rock salt, etc. (e) Octahedron: scallop, etc.

584681 V. Description of the invention (6) (f) Dodecahedron-like flash memory. In the cleavage state and mineral characteristics of the mineral, the present invention can be exemplified by the monoclinic ore represented by the following: Hui'an Iron and Silver Mine, Feather Lead Ore, Celosia, Emerald, Cryolite, Manganese Ore, Malachite, Water, Antimony Ore, Trona, Borax, Orthorite, Boronite, Calcium Stearate, 2 Pack: Needle alone Travertine, celestite, kanolite, hard chlorite schist, granite, titanite, scopolite, thorium ore, wollastonite, carbon, anatase, chloridite, brown feldspar, leaf Fibrestone, obsidian smectite, variable pyroxene, pyroxene, calcinite, pyroxene, Syrian pyroxene, general amphibole, basket stone, sodium amphibole, albsonite, talc, sodium mica, white emperor ::, green phosphorus Stone, pearl mica, | mica, biotite, red; mica, phyllite, chlorite, saponite, vermiculite, chlorite, monoclinic, vermicular, olivine, scale Chlorite, serpentine, two = cotton, chlorite, halloysite, palygorskite, coesite, periclase, stone, hard shed, Mud stone, stagnant stone, stagnate stone, carbon iron ball andalusite, oblique buddha stone, phosphorite stone. From the detailed description, it is known that the wear condition of the conventional manufacturing equipment is quite frequent. The present invention :: =:: grinding: = =: high hardness and more === which is; = The hardness is low, preferably less than 4, and more than 2 from the above point of view. It is sturdy, and it is a split-shaped tabletop and clear two: the best early oblique Japanese system of minerals, It must also be of low hardness. 584681 V. Description of the invention (7) ____ However, although the minerals used in the present invention are cleaved-a, other factors may not be considered in the present invention. The genus Tabletop is like a well-known mineral that meets the above conditions (phyl losisicates). , Phyllostearate ◎ phyllosilicate-pyrophyll (pyrophy 1 1 i te) -Al2Si401 () (〇H) 2 talc-Mg3Si401G (0H) 2-muscovite group; 1 .Nano mica (叩 1 ^ 211〇11: 〇1 ^ 12 (eight 1,8 ^) 〇1〇 (〇11) 2 2 · muscovite-KAl2 (AlSi3) 〇i〇 (〇H f) 2 3 · Glauconite (gaiuconi te) — (k, Na) (Al, Fe + 3Mg) 2 (Al Si) Lu 〇i〇 (〇H) 2 '4 4 · 绿绿 石 (ceiad〇nite)- K (Mg, Fe) (Fe, Al) Si4 〇1Q (〇u) 5. Pearl mica (Birth & 1 ^ & 1 ^ 7 6)-03 8 12 (8 12812) 0. (〇11 ) 2 6 · Mica Schist (micaschist) 7. Iron Mica (16 卩 1 (1011161 & 116)-^ 6 person 1810 (011 ,?) a biotite (biotite) group 1 · phlogopite- KMg3 (AlSi3) 〇10 (〇, 0H) 2 · Lepidolite-K (Li, Al) 3 (Si, Al) 4010 (F, OH) 2 3 · Iron Bell Mica (zinnwaldite) -KliFe + 2Al (Al, Si3) O10 (F, 0H) 2 4 · (stipnomelane) -K (Fe + 2, Fe + 3, Al) 1G Si22 03Q (0H) 12 -MONMOLILLONAITE (montmori1 Ionite) group

Page 10 584681 V. Description of the invention (8) 2 · ηΗ20, 2 · Montmorillonite- (Na, Ca) 〇33 (Al, Mg) 2Si4 〇10 (〇H) 2 · ηΗ20 3 · Green soap (Nonironi te) -Na0 33Fe2 + 3 (Al, Si) 401 (3 (0H) 2 · ηΗ20, 4 · sapponite)-(Ca / 2, Na ^ JMg, Fe) 3 (Si , Al) 4O10 (OH) 2 · 4H20, 5 · vermiculite-(Mg, Fe, A1) 3 (A1, Si) 4O10 (OH) 2 · 4H20-Chlorite group 1 · leaf Chlorite (penninite) 2. Monoclinic chlorite (.1) [11〇.111 (^ 6)-(11 Taboo,? 62+) 5 people 1 (81, people 1) 4 〇i〇 (〇 H) 8 3 · Prochlorite- (Mg, Fe + 2) 5Al (Si, A1) 401 (i (OH) 8 '4 · chamos i te--Fe2 +, Mg , Fe3 +) 5A 1 (S i3A 1) 〇i〇 (〇H) 8 5. Bowl thuringite-kaolinite: kaolinite-serpentine group 1. kaolinite-Al2Si205 (0H ) 4, 2 · antigorite- (Mg, Fe) 3Si205 (0H) 4, 3 · chrysotile-Mg3Si205 (0H) 4, 4 · amesite- (Mg2Al) (AlSi) 05 (0H) 4, 5. cronstedtite 6. halloysite-Al2Si205 (0H) 2Η20

584681 V. Description of the invention (10) 90 ~ 99 · 9% by weight (S105), and then use the common injection method to perform general injection or composite (double-layer nozzle) injection (S1 07), and then stretch and false twist , Cutting and weaving to produce fibers (S109). Fig. 3 is a flow chart showing another method for manufacturing the fiber by adding mineral powder according to the present invention. As shown in the figure, according to the present invention, when the fiber is added with mineral powder, the functional and crystalline forms are columnar, pyramidal, rhombohedral, 2 hexahedral, or octahedral. The body-shaped mineral powder and the monoclinic mineral powder having a functional form and a table-like crystal form are pulverized by a pulverizer twice (S201), and then the pulverized mineral powder is subjected to seven times. The blanket was pulverized to a diameter of less than 1/3 of the required fineness of the raw silk (g203).

In addition, the monoclinic functional mineral powder having a crystal form of a table top is columnar, pyramidal, rhombohedral, or hexahedral, octagonal, or dodecahedral. The body-shaped mineral powder is mixed (205). Among the mixed mineral powder (0.10% by weight), 3% by weight of human resin (S2G7) is used, and the general injection method is used. After ordinary injection or composite (double-layer nozzle) injection (S209), the fiber is produced by drawing, false twisting, shredding, and weaving (S2 11).

= In the manufacturing method of the fibers shown in Figures 2 and 3 above, an inorganic antibacterial agent powder was added for the purpose of "2" bacterial properties, but such an inorganic antibacterial agent powder was included as a sample of Xinwei's bacteriostatic agent. When mixed with inorganic 4 ^ amount of knowledge, the manufacture of inorganic antibacterial agents is based on the selection of silver ions 05 ~ 5 body 9 ° 5 'ί selected from the group consisting of pyrophyllite, calcium phosphate, or phosphonium phosphate ^ Defective 95 ~ " .5% by weight. You 1

584681 V. Description of the invention (ll) In addition, in order to remove the impurities contained in the mineral, the mineral can be maintained at a certain temperature, and it is best to add a plasticity process at 60 0 1 ~ 12001 = two but if This procedure can be omitted considering the mineral particle purity. Such procedures can also be carried out after the micronization of minerals. The secondary precision pulverization of mineral powder, although it can be wet pulverization or dry pulverization, but in the case of dry pulverization "Yihongdan, Nissinyi ^ ^ When you wish, you will combine the mineral powder with water. In the M 5 type state, use the magnetite once to remove the gold: raw powder, and then use the Qingli 2 times to pass through the filter membrane, then you can get = mind method, use the larger powder to pretend to use this in addition to other sinks The larger particles and smaller particles of the Xuangan liver are treated with 8M heat to disperse the fine powder particles. To remove them with a knife, you can only receive a smaller mixing ratio of the mineral, and only produce 3 deniers or more. In the case of less than 1 mm, the diameter of the mineral powder is set at different mixing ratios when shooting. This is particularly below the shot of 3 deniers. In the case of demineralization of 1 micron or less, the mineral powder is preferably 3 micrometers of mineral powder, and it is better to mix it when the raw silk with a diameter of less than this kind is produced; when it is two resins, its mixing ratio In the genus 3 Danny, the purpose of the present invention is as much as possible, and the mineral powder is added. 3% by weightIt is better to soften the original silk, to restore 5 functions, and to produce productive and soft denier yarns, plus mineral powder 1.5 to 2.5% by weight. It is 3, and it is preferable to add 2 to 6% by weight. Then, mineral powder can be added to 10% by weight, which is a schematic cross-sectional view of the part shown in Figures 4 to 5. Fibre made by the manufacturing method of diagrams Page 14 584681

As shown in the figure, the fibers are arranged along the length of the fiber (丨 〇〇), the table-like first mineral (200) is arranged in order, and the surface of the fiber (100) is covered thereon. The interior is irregularly distributed with a variety of polygonal second minerals (30 0). However, since the second mineral (300) is external to the fiber (100) and blocked by the first mineral (200), the fiber (100) can be as shown in Fig. 4 / , Not only soft and good touch, and can faithfully play the characteristics of the first mineral (200), and the characteristics of the second mineral (300). Hereinafter, the present invention will be described in detail through examples. (Example 1) In order to produce a 2-denier fiber system with good emissivity and good silk quality, which emits far-infrared rays that are beneficial to the human body, the plate-shaped muscovite was pulverized once in a 325 sieve to remove foreign matter. The plasticity is performed at 800 t, and the powder is wet-precision pulverized to obtain a powder having a maximum diameter of 1 μm or less. Then, in a wet state, the electromagnet removes the metal powder, and then passes through the filter membrane with two pressures to make a fine powder of mineral powder. Then, 'mix the inorganic antibacterial powder with 7% by weight in muscovite powder', and mix the mixed powder in the polymerization process of polyester. 1 Injection temperature is 283 ° C ± 1 ° C. General injection method Injection: The raw yarn containing 2% by weight of the mixed powder is produced. After stretching and false twisting, it can be mass-produced without wearing auxiliary equipment, without broken wires, high productivity, and fiber surface = smooth. Composite functional fibers. Surface (Example 2) The same manufacturing method as in Example 1 was used instead of polyester, and instead polyamine was used, and fibers were manufactured by a general injection method.

P.15 584681 Fifth invention description (14) Using the same manufacturing method as in Example 4, instead of sticky modification, it is mixed with the acetic acid raw material f, and it is removed by general injection to obtain 2 weights of mixed powder. % Complex sexual function. (Example 7) The mineral powders selected by human fibers are crushed to 70% by weight of mineral dolomite moxibustion, which is a powder with a maximum diameter of 5 microns or less, and 15% by weight of non-platelet tourmaline powder. mixing. In the mixed powder, the mixed zeolite powder containing 2% by weight of silver p = 2 ° was mixed with 20% by weight of the mixed powder, and the corpse was re-dissolved with polyacetic acid ^, and the mother pieces were made. After mixing 25% by weight of the mother pieces and 75% by weight of the vinegar fragments, 'using ordinary drying, injection: f, and after stretching, false twisting, shredding, and weaving, the result can be: no damage to auxiliary equipment, Non-broken fiber, high productivity, A functional fiber with anti-static effect on fiber surface. Above, in the examples of minerals used in the present invention, although only natural minerals are mentioned, the present invention is not limited to this. In other aspects of the present invention, 1 ^ $ minerals or synthetic minerals can also be used. It also belongs to the above-mentioned embodiments of the present invention, and the implementation of the present invention is only limited to the description of the preferred embodiments of the present invention. It is not limited to this. Variety. [Effect of the invention] The present invention is to make a functional and crystalline obstruction-like obstacle, and

584681 V. Description of the invention (] 5)--cone = tree t = hexian to make fibers, or polyhedrons with functional and crystalline shapes such as polygons, or hexahedrons, or octahedra The shape and twelve materials are mixed, and the Γ ^ thing 'and the functional and crystal-like obstacles are attached to it :: Characteristics ::::: fat, and the manufacture of fibers' produces smooth and softness i: Function 'At the same time, it is softer than ordinary fibers and cuts out of the outer edge'. The invention can smoothly perform fiber manufacturing procedures such as injection, stretching, false twisting, knives 4 or weaving, weaving, etc. With blood pressure adjustment, pain relief, antibacterial, deodorant, electrical static: prevention, ultraviolet blocking, anion release, adsorption functional fibers. And Ding continues to play these special features Page 18 ^ 〇 " + O〇i

[The diagram is simple and clear] Figure 1 is a mining private eve ^ ^ ^ Figure 2 You are too diverse crystalline map. Illustration. 'The process of inventing a method for producing a fiber by adding mineral powders FIG. 3 is a process diagram of the present invention. Figure 4 shows another method for manufacturing fibers with mineral powder added. FIG. 5 is a schematic view according to FIG. 3. Partial side cross-section of the fiber produced by the manufacturing method. Partial side cross-section of the fiber produced by the manufacturing method.

[Illustration of symbols] 1 0 0 fiber 2 0 0 first mineral 3 0 0 second mineral

Page 19

Claims (1)

584681 I, Case No. 90108109 VI. Application for patent scope 1. A method for manufacturing functional fibers, including: will be selected from pyrophyllite, talc, muscovite group, biotite group, green The first mineral in the group of soil (chi 〇r it e), or kaolin inerite = stone (kaol ini te-serpentine) group, which is crystallized in a table-like or zebra-like group, is crushed once; & amp ”The mineral powder is finely pulverized twice to a step of the required diameter of the original fibril; the float is less than 1/3 !! The material ^ powder 〇 · 卜 10 ％ by weight, and the chemical resin 90 ~ 99 9 weight! ¾ mixing step; and Ug Trang / 〇 the first mineral powder and the chemical resin step. For the month, the compound, the injection step 2 · As in the scope of the patent application彳 $ | contains an additional method for manufacturing the m ^ f-functional fiber, such as the scope of the patent application; a step of plasticity, wherein the method of manufacturing the functional fiber in the plasticity step, 4 For example, the scope of the patent application scope is 60 (TC. The manufacturing method of the secondary finely crushed 22f energy-saving fiber, a step of antibacterial agent 3 to 30% by weight. The first mineral powder is additionally mixed with inorganic I 5. Zhongyi i ί antibacterial agent is an existing compound of the method for producing silver (in energy fiber). It is supported on stone and phosphonic acid. The said functional secret general name ΛΑ 4 丨 Μ Ding will be subjected to the second precision chopping of this sexual fiber manufacturing method, the style is sad, the use of electromagnets, after the first physical powder remove the metallic powder ， 第 20 页 584584681 _Case No.90108109 Secret M: Said: Amendment VI, Shen Fen Patent Chapter *, one-· one '… .. one pass through the filter membrane with 2 pressures, and extract The step of producing a fine powder. 7. The method for producing functional fibers as described in the first item of the patent application scope, which additionally includes the first mineral powder which has been finely pulverized twice, and uses a precipitation method or a centrifugation method. Separate larger particles from smaller particles and collect only the smaller fine powder after separation 8. The method for manufacturing a functional fiber as described in item 1 of the scope of the patent application, wherein the chemical resin is made of polyester, polyamide, polypropylene, polyacrylonitrile, viscose, acetate萦, etc. 9. The method for manufacturing functional fibers as described in item 1 of the scope of patent application, The first mineral powder is mixed with a raw material substance of a chemical resin selected from polyester or polyamide, and polymerized and then injected. 10. The method for manufacturing a functional fiber according to item 9 of the scope of the patent application, wherein the content of the first mineral powder is 0.1 to 10% by weight, and after polymerization, other than the first mineral powder, The content of the chemical resin is 90 to 99.9% by weight. 11. The method for manufacturing a functional fiber as described in item 1 of the scope of the patent application, is to carry out the first mineral powder with a raw material selected from polyacrylonitrile, viscose rhenium, or acetic acid. Mix and shoot. Page 21