580526 A7 ______B7 ____ 五、發明說明（> ) 常，使用一管或針來達成此目的，使得一氣態或液態內孔 流體從該管中噴出，因而佔據了該內孔空間，同時，該纖 維型心圍繞著該內孔流體從該噴絲板孔口中被擠伸出來。 針對熔解物旋轉，該新生的纖維能在一氣態或液態冷卻流 體中經由冷卻予以固化。針對溶液旋轉，該新生的纖維能 藉由該溶劑的蒸發或藉著將該纖維與一溶劑濃縮液體相接 觸而造成該聚合物溶液之凝結而來形成纖維壁來予以固化 Ο 一種典型的旋轉組件，例如英國第830,441號專利中 所說明之一種多成分纖維，其包括有：一彼此相隔開並彼 此相對的前後板，藉此在其間提供一液體溝道。該前板係 提供一穿透其間之擠伸孔口，並且該等板片的至少一板片 在其面對另一板片的那一側上係提供一高原式的低窪，以 壓縮該液體溝道在一圍繞該擠伸孔口入口區域之中，因而 ，使得該覆套形成材料的流動實質上輻射狀地朝該孔口入 口匯集。一管被放置在該孔口入口當中以供應該內孔流體 。然而，一項持續的問題爲在該多成分纖維成形的期間如 何均勻地供應該型心和覆套成形材料。大部分此類型的噴 絲板絕大部分係一次一個地由手工做成。結果，替一噴絲 板所製作的零件並不會總是適合另一個噴絲板。當零件並 不是可互相交換時’該噴絲板組件的一零件的任何損壞將 使得該整個組件無法使用。在組裝或淸洗傳統的雙成分或 中空纖維噴絲板時’其非常容易輕微地彎曲該流體注入管 或針，使得其偏離該旋轉孔口之中心。當此不幸發生時， ____4_____ 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 馨 訂---------線丨· 580526 五、發明說明（h ) 該噴絲板不能使用直到修好爲止。 另外一個傳統噴絲板的相關問題乃相關於該內孔和該 單一成分中空纖維的纖維壁之間以及額外的該多成分中空 纖維的該型心和該覆套之間的同中心性的產生。傳統的噴 絲板傾向於形成其中該內孔/纖維壁和型心/覆套並不同中 心的中空纖維。該覆套和型心的同中心性對於均勻纖維的 獲得係很重要的。該覆套和該型心的同中心性慣例係由控 制表面的調整以調節（控制）該聚合物的流動來獲得。該 等控制表面的產生係藉由兩表面的仔細加工以產生一將有 效控制聚合物當其被擠製時係處於一均勻壓力和流率之狹 窄開口。美國第3,458,615號專利揭露一種維持覆套/型心 同中心性的方法··以圍繞控制該將繞著該聚合物型心而將 被擠伸的聚合物覆套，該聚合物型心牽涉到繞著該軸向包 含流體流動的該覆套聚合物的環形楔形流動之形成。 爲了維持繞著該內孔的纖維壁之同中心性，其它噴絲 板已經提供有將該管和該噴絲板的內孔聚集於中心的元件 。例如，美國第4,493,629號專利說明了一種配合著多數 螺絲鑽過該噴絲板以便將該管和該噴絲板的孔口聚集於中 心之模組化噴絲板組件。此些調整螺絲並不可靠，並且當 該噴絲板被拆開、淸洗然後再組裝時，該等螺絲具有將該 管移出中心調整之傾向。許多裝置已經提出了確保該均質 覆套成形液體至一多孔口噴絲板的均勻供應，以達成產生 具有相同細度、重量和其它特性之同心層的多中空纖維之 目的。此類型之裝置通常牽涉到該等孔口和單一或多噴絲 ------ s____ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 一---- (請先閱讀背面之注意事項再填寫本頁) 一5J·- 丨線· 580526 A7 ______B7 __ 五、發明說明（々） 板的直徑或位置之變化。同中心性和均勻性的缺乏仍然是 製造此類單一成分或多成分纖維之問題所在。 現存噴絲板之另一個問題爲均勻地繞著位於該噴絲板 內的管或針傳送該聚合物液體或諸液體之能力。美國第 5,320,512號專利揭露一種噴絲板，其具有成形於該針四周 的複數個分開的材料通道，以便繞著該針輸送該聚合物液 體。當該聚合物流體橫流過該主聚合物流體通到時，從此 些各別通道出來之該聚合物液體必須匯集並熔解在一起， 以便形成一圍繞該管或針的單一環狀流動。如果無法獲得 完整的熔解物’則在該纖維長度的下方在該各別流體並不 完全匯集的界面處將形成裂縫。因此，我們需要一種噴絲 板設計，其將能夠產生具同心且均勻而無形成裂縫的危險 之纖維。 發明槪述 本發明提供一種適用於克服習知噴絲板線置之中空纖 維製造的改良型噴絲板。該創新之噴絲板組件因而能持續 地製造均勻尺寸的單一和多成分中空纖維，在該纖維當中 ，該纖維壁以一高精密度同心於該內孔。以此方式實施， 此些噴絲板組件能額外地減低中空纖維中的瑕疵、延伸中 空纖維製造的運作時間、減少噴絲板的保養時間和簡化噴 絲板的裝配。本發明特別適合於以一有效之方式製造具有 一個或更多覆套層的高品質多成分纖維。 爲了達成此些目的，本發明的第一樣態樣係一種用於 ________β__ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------·--------訂！ i (請先閱讀背面之注意事項再填寫本頁) 580526 A7 五、發明說明（< ) 形成中空纖維的噴絲板組件，該組件包括有： 成形於該噴絲板組件之中的擠伸孔口； 一以〜同心方式延伸穿過該每一個擠伸孔口以捧〜 在該濟伸孔口之中圍繞該針的環狀通道之中空針； 一形成與該每一個針之內部相聯通的內孔形成 道； 収颺遊 至少一成形於該噴絲板組件之中的型心形成材料通道580526 A7 ______B7 ____ 5. Description of the Invention (>) Often, a tube or needle is used to achieve this purpose, so that a gaseous or liquid internal-pore fluid is ejected from the tube, thereby occupying the internal-pore space, and at the same time, the fiber The core is squeezed out of the orifice of the spinneret around the inner hole fluid. As the melt rotates, the nascent fibers can be solidified by cooling in a gaseous or liquid cooling fluid. For solution rotation, the nascent fiber can be solidified by evaporation of the solvent or by causing the polymer solution to condense by contacting the fiber with a solvent-concentrated liquid to form a fiber wall. A typical rotating component For example, a multi-component fiber described in British Patent No. 830,441 includes a front plate and a front plate spaced apart from each other, thereby providing a liquid channel therebetween. The front plate provides an extruded aperture therethrough, and at least one of the plates provides a plateau-like depression on the side of the plate facing the other plate to compress the liquid The channel is in an area surrounding the entrance of the extrusion orifice, so that the flow of the sheath-forming material converges substantially radially towards the entrance of the orifice. A tube is placed in the orifice inlet to supply the bore fluid. However, a continuing problem is how to uniformly supply the core and sheath forming material during the formation of the multicomponent fiber. Most spinnerets of this type are mostly made by hand one at a time. As a result, parts made for one spinneret may not always fit another spinneret. When the parts are not interchangeable 'any damage to one part of the spinneret assembly will render the entire assembly useless. When assembling or washing a conventional two-component or hollow fiber spinneret ', it is very easy to bend the fluid injection tube or needle slightly so that it is offset from the center of the rotary orifice. When this misfortune happens, ____4_____ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -Line 丨 · 580526 5. Description of the Invention (h) The spinneret cannot be used until repaired. Another related problem of the traditional spinneret is related to the generation of concentricity between the inner hole and the fiber wall of the single-component hollow fiber and the additional core of the multi-component hollow fiber and the sheath. . Conventional spinnerets tend to form hollow fibers in which the inner holes / fiber walls and cores / claddings are not centered. The concentricity of the sheath and the core is important for obtaining a uniform fiber. The mantle and concentric conventions of the core are obtained by controlling the adjustment of the surface to regulate (control) the polymer flow. Such control surfaces are created by careful processing of both surfaces to produce a narrow opening that will effectively control the polymer when it is extruded at a uniform pressure and flow rate. U.S. Patent No. 3,458,615 discloses a method to maintain the concentricity of the mantle / core. To control the polymer mantle that will be extruded around the polymer mandrel, the polymer mandrel involves The formation of an annular wedge-shaped flow of the mantle polymer containing fluid flow around the axial direction. In order to maintain the concentricity of the fiber wall around the inner hole, other spinnerets have been provided with elements that centralize the tube and the inner hole of the spinneret. For example, U.S. Patent No. 4,493,629 describes a modular spinneret assembly that drills through the spinneret with most screws to gather the tube and the orifice of the spinneret in the center. These adjustment screws are not reliable, and when the spinneret is disassembled, washed, and then reassembled, the screws tend to move the tube out of the center for adjustment. Many devices have been proposed to ensure a uniform supply of the homogeneous sheath forming liquid to a perforated spinneret to achieve the goal of producing multiple hollow fibers with the same fineness, weight, and other characteristics as a concentric layer. This type of device usually involves these orifices and single or multiple spinnerets ------ s____ This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) One-(Please Read the precautions on the back before filling this page) 5J ·-丨 Line · 580526 A7 ______B7 __ 5. Description of the invention (々) Changes in the diameter or position of the board. The lack of concentricity and homogeneity remains the problem in making such single- or multi-component fibers. Another problem with existing spinnerets is the ability to transfer the polymer liquid or liquids evenly around a tube or needle located within the spinneret. U.S. Patent No. 5,320,512 discloses a spinneret having a plurality of separate material channels formed around the needle to transport the polymer liquid around the needle. When the polymer fluid flows through the main polymer fluid, the polymer liquids coming out of these individual channels must be pooled and melted together to form a single annular flow around the tube or needle. If a complete melt cannot be obtained, cracks will form below the fiber length at the interface where the respective fluids do not fully collect. Therefore, we need a spinneret design that will produce fibers that are concentric and uniform without the risk of cracks. Summary of the Invention The present invention provides an improved spinneret suitable for manufacturing hollow fiber that overcomes the conventional spinneret wire. The innovative spinneret assembly thus enables the continuous production of uniformly sized single and multi-component hollow fibers in which the fiber wall is concentric with the inner hole with a high degree of precision. Implemented in this way, these spinneret assemblies can additionally reduce defects in hollow fibers, extend the operating time of hollow fiber manufacturing, reduce spinneret maintenance time, and simplify spinneret assembly. The present invention is particularly suitable for producing high-quality multi-component fibers having one or more sheaths in an efficient manner. In order to achieve these objectives, the first aspect of the present invention is a ________ β__ paper size applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) ----------- -· -------- Order! i (Please read the precautions on the back before filling out this page) 580526 A7 V. Description of the invention (<) A spinneret module forming a hollow fiber, the assembly includes: the extrusion formed in the spinneret module An orifice; a hollow needle that extends through each of the extruded orifices in a concentric manner to hold ~ a circular channel surrounding the needle in the orifice; The interconnected inner hole forms a channel; at least one core forming material channel formed in the spinneret assembly is retracted.
其中該每一個型心形成材料通道，其包括有：〜從^ 組件表面延伸至該組件內部之型心形成材料入口和至少Z 從該型心形成材料口延伸至該每一個環形通道之橫向通道 0 線· 該創新之噴絲板組件能被適用於提供具有一被一管狀 覆套層向外輻射圍繞的管狀內型心纖維壁所界定之一開口 內孔的混合之中空纖維。適用性要求在該上述噴絲板組件 上增加一第一覆套形成材料通道，該通道包括有：位於該 噴絲板表面的第一覆套形成材料口，其中該第一覆套形成 材料通道係延伸到該每一個環狀通道處。 本發明之另一個樣態係一用於形成一中空纖維的方法 ’該方法係包括有下列步驟： 輸送一型心形成材料到位於一噴絲板組件之中的每一 個環形通道處’該型心形成材料經由一個或更多個型心形 成材料入口進入該噴絲板組件之中，然後經過該組件的內 部到達一橫向通道，該橫向通道的一部分以一連續的方式 ___ ___2______ 本紙張尺度適用由國國家標準（CNS)A4規格（210 X 297公釐） 580526 A7 _B7_ 五、發明說明（V ) 整個地圍繞每一個針，並經由一環狀通道與一擠伸孔口相 聯通； 將該型心材料擠伸通過該擠伸孔口並圍繞該每一個針 將一型心形成液體注入每一個針，藉此，提供一纖維 ，其包括有一位於該型心形成材料中心之中的內孔形成液 體，當其經由該擠伸孔口離開該噴絲板組件時； 應用冷卻、溶劑蒸發或溶劑萃取等固化該中空纖維， 和 選擇性地，在固化該中空纖維之前，將該新製成的擠 伸中空纖維通過一空氣間隙。 將透過一較佳的具體實施例和其附圖來說明本發明。 圖式之簡單說明 圖1A係根據本發之一噴絲板適用於製造單一成分中 空纖維的一較佳具體施例之上視圖。 圖1係根據本發的另一噴絲板適用於製造多種成分中 空纖維的另一較佳具體施例之上視圖。 圖2A係沿者圖1A的該具體貫施例中之線A-A所取 的一表示一擠伸裝置之剖面圖。 圖2係沿著圖1的該具體實施例中之線A-A所取的一 表示一擠伸裝置之剖面圖。 圖3係一噴絲板體的第一較佳具體實施例適用於製造 多種成分中空纖維之一替代結構。 ___s_ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) I ^_ew.--1--- I 訂·--------I . 580526 A7 _B7___ 五、發明說明（1 ) 圖4係本發明的另一較佳具體實施例用於從一單一型 心形成材料通道旋轉多纖維絲之一上視圖。以及 圖5係本發明的另一較佳具體實施例用於旋轉多覆套 中空纖維之一剖面圖。 (請先閱讀背面之注意事項再填寫本頁) -------訂 *--------'^丨· 元件編號說明 100 噴絲板組件 110 噴絲板體 111 針裝載孔 112 內孔形成流體通道 112， 內孔形成流體通道 113 內孔形成流體入口 114 第二內孔形成流體通道 115 裝載孔 120 底板 130 針 131 固定器 132 孔 140 夾鐵 141 間隙 142 覆套形成材料入口 143 覆套形成材料通道 144 溝渠 145 溝渠 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 580526 A7 _B7 五、發明說明（《） 150 型心形成材料通道 151 型心形成材料口 152 橫向通道 153 、 154 環狀通道 155 擠伸孔口 156 向外張開凹處 210 噴絲板體 212，a 、 212，b 溝渠 213 內孔形成流體入口 214a、214b 內孔形成液體通道 220 底板 230a、230b 針 240 夾鐵 241 間隙 241a、241b 間隙 242 覆套形成材料入口 243 覆套形成材料通道 244 、 245 溝渠 250 型心形成材料通道 252a > 252b 橫向通道 253a 、 253b 環狀通道 254a 、 254b 環狀通道 255a、255b 擠伸孔口 300 噴絲板組件 _ 10 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ———---------·--------訂·！ ！f Φ (請先閱讀背面之注意事項再填寫本頁) 580526 A7 B7 五、發明說明（1 ) 310 噴絲板體 311 針裝載孔 312 內孔形成流體通道 313 內孔形成流體入口 314 內孔形成流體通道 320 底板 330 針 332 孔 331 固定器 340a、340b 夾鐵 341a、341b 間隙 342a 第一覆套形成材料入口 342b 第二覆套形成材料入口 343a 第一覆套形成材料通道 343b 第二覆套形成材料通道 344a、344b、 345a、345b 溝渠 350 型心形成材料通道 351 型心形成材料入口 352 橫向通道 353 、 363 、 354 環狀通道 356 向外張開凹處 360 中間板 ---------------------訂---------*5^ —AWI (請先閱讀背面之注意事項再填寫本頁) 本發明具體實施例的詳細說明 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 580526 A7 _____B7 _ 五、發明說明） (請先閱讀背面之注意事項再填寫本頁) 本發明係被導引至多用途的中空纖維之製造，尤其是 用於薄膜分離設備，並且特別是用於氣體分離。在一基本 的形式當中，該中空纖維係一末端開放、圓柱管狀、其管 壁具有均勻成分。此類型式之中空纖維有時候稱爲一”單一 成分”纖維。定義該纖維的該中空部分的中心通路偶而稱作 ”內孔”。”多成分”中空纖維亦能被製作。該名詞”多成分” 意指：該中空纖維壁係由混合層所形成。該最內層，即相 鄰於該內孔者在此處係稱爲該纖維的”型心”部分。圍繞一 多成分纖維的該型心層的該等外層係稱爲”覆套”部分。習 慣上已經採用將向外輻射狀相鄰於該型心層的膜層指稱爲 該”第一覆套”層或部分。接連的外膜層被標稱爲該”第二覆 套”、”第三覆套”層或部分等等。爲了維持應用術語的一慣 性，一單一成分中空纖維之該膜壁部分在此處仍稱爲該纖 維的型心，雖然該單一成分纖維並沒有覆套部分。 如圖1A和2A所示，在本發明之用於多數單一成分中 空纖維的擠伸之該第一較佳具體實施例當中，一噴絲板組 件100包括有：一噴絲板體110、一底板120和針130。如 圖1A中所示的該特定裝置係用於同時擠伸12個中空纖維 ，但是該噴絲板組件100能依據需求被修改爲製造單一纖 維絲或任何數目的多數纖維絲。每個針130的該中央端被 固定在一由鑽孔或其它加工程序而成形於該噴絲板體110 當中的各別針裝載孔111之中。該針130的中央端的該外 直徑和該裝載孔Π1的直徑較佳地被制訂尺寸，使得針 130的中央端能以壓力被套入針裝載孔111當中，以確保 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 580526 A7 ^____B7 五、發明說明u ) 針130到噴絲板110處於一無洩漏的狀態之中。針130可 以任何合適之方式被固定到該噴絲板體no，該方式允許 位於針130中央端的內孔與位於噴絲板體110中的內孔形 成流體通道112相接觸。藉由一類似螺栓或者是螺紋穿孔 132之固定器131，而將該底板120固定於該噴絲板體110 。向外張開凹處156成形於底板120之中以允許多數個被 擠伸的纖維無干擾地離開該噴絲板組件。在該較佳的具體 實施例當中，該多數擠伸裝置係安置於一線性或圓形之形 式。 內孔形成流體通道112係成形噴絲板體110當中並延 伸穿過噴絲板體110至一各別的針裝載孔111處以便與穿 過針130而成形的通道相聯通。每一個內孔形成流體通道 112包括有：一位於噴絲板體110表面處的內孔形成流體 入口 113。該結構允許一內孔形成流體被引進一擠伸的纖 維當中以保持該擠伸纖維之中空結構，於下下文中說明。 型心形成材料通道150被成形該噴絲板體110當中， 經過該噴絲板體Π0,一類似聚合物材料之型心形成材料 被輸送至該擠伸孔口 155處。每一個該型心形成材料通道 150包括有：入口 151，該入口 151係一以實質上平行於針 130的方向而延伸之孔。每一個型心形成材料通道150亦 包括有··一橫向通道152，該橫向通道152從型心形成入 口 151延伸到一界定擠伸孔口 155上方部分之環狀通道 153的上頂部分處。該橫向通道152藉由一塞入穿過型心 形成材料口 151的工具在該噴絲板體110中形成一後切部 丨丨！---------··!!1丨訂！ ！！線|伞 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 580526 A7 B7 五、發明說明（ 分所界定。該橫向通道152整個地圍繞針130而延伸以允 許該型心形成材料能均勻地分佈於針130四周，並且均勻 地引進環狀通道153和154之中。 參考圖1和圖2將能瞭解適用於製造多數多成分中空 纖維的本創新之噴絲組件的另外一個較佳具體實施例。不 同圖式的類似零件將以相同的編號標示。成形於噴絲板體 110底面中的溝渠144和145係與界定於噴絲板體11〇和 底板120之間的間隙141相聯通。配置於噴絲板體11〇和 底板120之間的夾鐵140界定該間隙141之尺寸，當該型 心形成材料分別地流過該環狀通道153和154時，能以一 同心的方式圍繞著該型心形成材料提供該覆套形成材料均 勻的輸送。 覆套形成材料入口 142和覆套形成材料通道143在噴 絲板體110中被成形以便與溝渠144相聯通進而允許該覆 套形成材料能經由覆套形成材料入口 142、覆套形成材料 通道H3、溝渠Η4和1C、間隙Μ1而被輸送。當該覆套 形成材料離開間隙141之時，其在間隙141和環狀通道 154交叉處圍繞型心形成材料均勻地分佈。 現在將討論該創新之噴絲板組件的操作。其假設該中 空纖維係以多成分被成形。爲製造單一成分中空纖維，覆 套形成操作和設備將在下列討論中被省略。 在操作當中’使用一類似螺栓的合適固定機構穿過裝 載孔II5，將該噴絲板組件110裝載到—旋轉η 該機器的一內孔形成流體供應、—型心形成材料=應i 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） (請先閱讀背面之注意事項再填寫本頁) ·. 訂---------線丨 580526 A7 ---------- - B7 _____ 五、發明說明（ή ) 覆套形成材料供應分別被耦合至該內孔形成液體入口 113 、該型心形成材料入口 151和該覆套形成材料入Q 142處 。注意’針對每一個擠伸孔口 155僅有一內孔形成材料入 口 113和〜型心形成材料入口 151 ;然而，一個覆套形成 材料入口 142經由覆套形成材料通道143、溝渠144和145 、間隙141提供到每一個擠伸孔口的覆套形成材料的供應 。這些口能以任何方式或數目被安裝，只要其能適當地將 該等材料輸送到合適的通道處。針對該中空纖維的旋轉， 一型心形成材料、一覆套形成材料和一內孔形成流體以已 知的壓力和流量同時被輸送至噴絲板1〇〇之中以擠伸(亦即 ’旋轉）中空纖維。典型地，該型心形成材料以約300-5〇〇psig壓力注入，該覆套形成材料以約150_300psig壓力 注入’而該內孔形成流體以約4-5psig壓力注入。 該型心形成材料流經型心形成材料入口 151、型心形 成材料通道150、進入橫向通道152，然後進入上方環狀通 道153。同時，覆套形成材料流經覆套形成材料入口 142、 覆套形成材料通道143，然後進入溝渠144。其應該注意到 ’該溝渠144之尺寸被設計在每一個溝渠145的入口處以 基本上相同的壓力提供覆套形成材料，以便經由間隙 提供均勻的覆套形成材料的輸送。在間隙141之出口處， 該覆套形成材料流動圍繞地與在各別上方和下方環狀通道 153和154之間的間隙處的型心形成材料的流動相橫向交 叉’致使繞著該型心形成材料的外表面同心地形成該覆套 形成材料的一均勻膜層或塗佈。並且’經由該噴絲板組件 __________ —-------— ------- 本紙張尺度適用中國國家標準（CNS) A4規格（210 χ 297公/έ ) ——，---------·--------訂---------f命 (請先閱讀背面之注意事項再填寫本頁) 580526Each of the core-forming material passages includes: ~ a core-forming material inlet extending from the surface of the component to the inside of the component and at least Z a lateral channel extending from the core-forming material opening to the each annular channel Line 0 · This innovative spinneret assembly can be adapted to provide a hybrid hollow fiber with an open inner hole defined by a tubular inner core fiber wall surrounded by a tubular sheath of outward radiation. Applicability requires that a first cover-forming material channel be added to the spinneret assembly, and the channel includes a first cover-forming material port on the surface of the spinneret, wherein the first cover forms a material channel. The system extends to each of these annular channels. Another aspect of the present invention is a method for forming a hollow fiber. The method includes the following steps: Conveying a core-forming material to each annular channel located in a spinneret assembly. The core-forming material enters the spinneret assembly through one or more core-forming material inlets, and then passes through the interior of the assembly to a lateral channel, a portion of which is in a continuous manner ___ ___2______ This paper size Applicable by the national standard (CNS) A4 specification (210 X 297 mm) 580526 A7 _B7_ V. Description of the invention (V) Encloses each needle entirely, and communicates with an extruded orifice through a circular channel; The core material is extruded through the extrusion orifice and a core-forming liquid is injected around each of the needles, thereby providing a fiber including an inner core located in the center of the core-forming material. The hole forms a liquid when it leaves the spinneret assembly through the extruded orifice; the cooling, solvent evaporation, or solvent extraction is used to solidify the hollow fiber, and optionally, in the solid state Before the hollow fiber was quantified, the newly produced extruded hollow fiber was passed through an air gap. The invention will be explained by means of a preferred embodiment and its drawings. Brief Description of the Drawings Figure 1A is a top view of a preferred embodiment of a spinneret suitable for manufacturing a single-component hollow fiber according to the present invention. Fig. 1 is a top view of another preferred embodiment of a spinneret suitable for manufacturing multi-component hollow fibers according to the present invention. Fig. 2A is a cross-sectional view taken along a line A-A in the specific embodiment of Fig. 1A, showing an extrusion device. Fig. 2 is a cross-sectional view of an extrusion device taken along line A-A in the embodiment of Fig. 1. FIG. Fig. 3 is a first preferred embodiment of a spinneret body suitable for manufacturing an alternative structure of a multi-component hollow fiber. ___s_ This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) I ^ _ew .-- 1 --- I Order · ---- ---- I. 580526 A7 _B7___ 5. Description of the invention (1) Figure 4 is a top view of another preferred embodiment of the present invention for rotating one of the multi-fiber filaments from a single core-forming material channel. And Fig. 5 is a cross-sectional view of another preferred embodiment of the present invention for rotating a multi-cover hollow fiber. (Please read the precautions on the back before filling in this page) ------- Order * -------- '^ 丨 · Component number description 100 Spinneret assembly 110 Spinneret body 111 Needle loading Hole 112 Inner hole forms fluid channel 112, Inner hole forms fluid channel 113 Inner hole forms fluid inlet 114 Second Inner hole forms fluid channel 115 Loading hole 120 Base plate 130 Needle 131 Holder 132 Hole 140 Clip iron 141 Clearance 142 Cover forming material Inlet 143 Cover forming material channel 144 Channel 145 Channel ditch The paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 580526 A7 _B7 V. Description of the invention (") 150 core forming material channel 151 core forming Material port 152 Lateral channel 153, 154 Ring channel 155 Extrusion opening 156 Opening recess 210 Opening of spinneret body 212, a, 212, b Channel 213 Inner hole forms fluid inlet 214a, 214b Inner hole forms liquid channel 220 Bottom plate 230a, 230b Needle 240 Clip iron 241 Clearance 241a, 241b Clearance 242 Cover forming material inlet 243 Cover forming material channel 244, 245 Channel 250 core forming material Channel 252a > 252b Lateral channel 253a, 253b Ring channel 254a, 254b Ring channel 255a, 255b Extrusion orifice 300 Spinneret assembly _ 10 This paper size applies to China National Standard (CNS) A4 (210 X 297 male) Li) ———--------- · -------- Order ·! !! f Φ (Please read the precautions on the back before filling this page) 580526 A7 B7 V. Description of the invention (1) 310 Spinneret 311 Needle loading hole 312 Inner hole forming fluid channel 313 Inner hole forming fluid inlet 314 Inner hole forming Fluid channel 320 Base plate 330 Needle 332 Hole 331 Holder 340a, 340b Iron 341a, 341b Clearance 342a First cover forming material inlet 342b Second cover forming material inlet 343a First cover forming material channel 343b Second cover forming Material channels 344a, 344b, 345a, 345b Channels 350 core-forming material channels 351 core-forming material inlets 352 transverse channels 353, 363, 354 annular channels 356 open outward recesses 360 intermediate plate --------- ------------ Order --------- * 5 ^ —AWI (Please read the precautions on the back before filling out this page) Detailed description of specific embodiments of the present invention This paper Standards apply to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 580526 A7 _____B7 _ V. Description of the invention) (Please read the precautions on the back before filling this page) The invention is directed to multi-purpose hollow fiber Made In particular for membrane separation apparatus, and in particular for gas separation. In a basic form, the hollow fiber system has an open end, a cylindrical tube shape, and a uniform wall composition. This type of hollow fiber is sometimes referred to as a "single-component" fiber. The central pathway defining the hollow portion of the fiber is occasionally referred to as the "inner hole". "Multi-component" hollow fibers can also be made. The term "multi-component" means that the hollow fiber wall is formed by a mixed layer. The innermost layer, i.e., the one adjacent to the inner hole, is referred to herein as the "core" portion of the fiber. The outer layers of the core layer surrounding a multi-component fiber are referred to as "covered" portions. It has conventionally been used to refer to the "radiation" layer or portion of the membrane layer that is radially adjacent to the core layer. Successive outer film layers are labeled as the "second cover", "third cover" layer or portion, and so on. In order to maintain the inertia of the application term, the membrane wall portion of a single-component hollow fiber is still referred to herein as the core of the fiber, although the single-component fiber has no sheath portion. As shown in FIGS. 1A and 2A, in the first preferred embodiment of the present invention for the extrusion of most single-component hollow fibers, a spinneret assembly 100 includes: a spinneret body 110, and a bottom plate. 120 and Needle 130. This particular device, as shown in Figure 1A, is used to extrude 12 hollow fibers simultaneously, but the spinneret assembly 100 can be modified to produce a single fiber filament or any number of majority fiber filaments as required. The central end of each needle 130 is fixed in a respective needle loading hole 111 formed in the spinneret body 110 by drilling or other processing procedures. The outer diameter of the central end of the needle 130 and the diameter of the loading hole Π1 are preferably dimensioned, so that the central end of the needle 130 can be sleeved into the needle loading hole 111 under pressure to ensure that the paper size applies to Chinese national standards ( CNS) A4 specification (210 X 297 mm) 580526 A7 ^ ____ B7 V. Description of the invention u) The needle 130 to the spinneret 110 is in a state of no leakage. The needle 130 may be fixed to the spinneret body no in any suitable manner that allows the inner hole located at the central end of the needle 130 to contact the inner hole located in the spinneret body 110 to form a fluid passage 112. The bottom plate 120 is fixed to the spinneret body 110 by a fixing device 131 similar to a bolt or a threaded hole 132. An outwardly extending recess 156 is formed in the base plate 120 to allow the majority of the extruded fibers to exit the spinneret assembly without interference. In the preferred embodiment, the majority of the extrusion devices are arranged in a linear or circular form. The inner hole forming fluid channel 112 is formed in the spinneret body 110 and extends through the spinneret body 110 to a respective needle loading hole 111 so as to communicate with the channel formed through the needle 130. Each of the inner holes forming the fluid passage 112 includes: an inner hole forming a fluid inlet 113 at a surface of the spinneret body 110. This structure allows an inner hole-forming fluid to be introduced into an extruded fiber to maintain the hollow structure of the extruded fiber, as described below. A core-forming material channel 150 is formed in the spinneret body 110, and through the spinneret body Π0, a core-forming material similar to a polymer material is transported to the extrusion orifice 155. Each of the core forming material channels 150 includes an inlet 151 which is a hole extending in a direction substantially parallel to the direction of the needle 130. Each core-forming material channel 150 also includes a lateral channel 152 that extends from the core-forming inlet 151 to an upper top portion of an annular channel 153 that defines an upper portion of the extrusion orifice 155. The lateral channel 152 forms a back-cut portion in the spinneret body 110 by a tool which is inserted through the core-forming material opening 151! --------- · !!!! 1 丨 Order! !! !! Thread | Umbrella (Please read the notes on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 580526 A7 B7 V. Description of the invention (defined by the branch. The horizontal channel 152 extends entirely around the needle 130 to allow the core-forming material to be evenly distributed around the needle 130 and evenly introduced into the annular channels 153 and 154. Referring to Figures 1 and 2 it will be understood that it is suitable for manufacturing the majority Another preferred embodiment of the innovative spinneret of the multi-component hollow fiber. Similar parts with different drawings will be labeled with the same number. The trenches 144 and 145 formed in the bottom surface of the spinneret body 110 are bounded and defined. The gap 141 between the spinneret body 11 and the bottom plate 120 communicates with each other. The clip 140 disposed between the spinneret body 11 and the bottom plate 120 defines the size of the gap 141. When the core forming material is separately When flowing through the annular passages 153 and 154, the sheath forming material can be uniformly conveyed around the core forming material in a concentric manner. The sheath forming material inlet 142 and the sheath forming material passage 143 are sprayed. The wire body 110 is shaped so as to communicate with the trench 144 to allow the sheath-forming material to be conveyed through the sheath-forming material inlet 142, the sheath-forming material passage H3, the trenches 4 and 1C, and the gap M1. As the sleeve-forming material leaves the gap 141, it is evenly distributed around the core-forming material at the intersection of the gap 141 and the annular channel 154. The operation of the innovative spinneret assembly will now be discussed. It is assumed that the hollow fiber The composition is shaped. In order to manufacture a single-component hollow fiber, the sheath forming operation and equipment will be omitted in the following discussion. In the operation, 'the appropriate fixing mechanism similar to a bolt is passed through the loading hole II5, and the spinneret assembly 110 is used. Loading to—rotation η An inner hole of this machine forms a fluid supply, — core forming material = shall i This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) (Please read the precautions on the back first (Fill in this page again.) ·. Order --------- line 丨 580526 A7 -----------B7 _____ V. Description of the invention (price) The supply of sheath forming materials is coupled to The inner hole forming fluid Inlet 113, the core forming material inlet 151, and the cover forming material inlet Q 142. Note that there is only one inner hole forming material inlet 113 and ~ core forming material inlet 151 for each extrusion orifice 155; however, A sheath-forming material inlet 142 provides a supply of sheath-forming material to each of the extrusion orifices via the sheath-forming material channels 143, trenches 144 and 145, and gaps 141. These ports can be installed in any manner or number, as long as It can properly transport the materials to the appropriate channels. In response to the rotation of the hollow fiber, a core-forming material, a sheath-forming material, and an inner hole-forming fluid are simultaneously conveyed into the spinneret 100 at a known pressure and flow rate for extrusion (i.e., ' Spinning) hollow fiber. Typically, the core-forming material is injected at a pressure of about 300-500 psig, the sheath-forming material is injected at a pressure of about 150-300 psig 'and the bore forming fluid is injected at a pressure of about 4-5 psig. The core forming material flows through the core forming material inlet 151, the core forming material passage 150, enters the lateral passage 152, and then enters the upper annular passage 153. At the same time, the sheath-forming material flows through the sheath-forming material inlet 142, the sheath-forming material channel 143, and then enters the trench 144. It should be noted that the dimensions of the trenches 144 are designed to provide the sheath-forming material at substantially the same pressure at the entrance of each trench 145 so as to provide uniform delivery of the sheath-forming material through the gap. At the exit of the gap 141, the sheath-forming material flows laterally and intersects laterally with the mobile phase of the core-forming material at the gap between the respective upper and lower annular channels 153 and 154, so as to surround the core. The outer surface of the forming material forms a uniform film layer or coating of the sheath forming material concentrically. And 'via the spinneret assembly __________ —--------- ------- This paper size is applicable to China National Standard (CNS) A4 specifications (210 χ 297 male /) ——,- -------- · -------- Order --------- f Life (Please read the notes on the back before filling this page) 580526
五、發明說明（a) 1〇〇的該型心形成材料和覆套形成材料的供應的同時，一 內孔形成流體被注入該內孔形成流體入口 1 i 3、經由該內 孔形成流體通道112，然後流入針13〇之中。該內孔流體 以一位於擠伸孔口 155的下游之內之位置處或剛好位於濟 伸孔口 155下游之位置處從該針13〇的末梢端處出現。因 爲該型心形成材料和覆套形成材料正同時地且同心地繞著 針130和從該針處出來的內孔形成流體經由該下方環狀通 道丨54和從該擠伸孔口 155處擠伸出來，所以該形成的擠 伸件係一纖維，其包括一在其中心的內孔形成流體，該內 孔流體同心地被一型心形成材料所圍繞，而且該型心形成 材料係同心地被塗佈一覆套形成材料。 如圖1和圖2所最佳地表示，該橫向通道152係一具 有一以一連續方式整個地圍繞針13〇的終端部分的後切部 分且與上方環狀通道153相聯通。此結構消弭了該型心形 成材料均勻地圍繞針130而分佈的問題。其同時亦消弭了 該纖維壁下方如美國第5,320,512號專利所揭露的由於在 該環狀通道範圍內該複數個型心材料流動未完全混合所造 成的縦向裂縫之問題。同時，當該噴絲板組件從該旋轉機 器被移開時，因爲該型心形成材料通道150和橫向通道 152已經可接觸得到的，所以該噴絲板的淸理相當地簡單 。此將方便淸理並減少該噴絲板反轉的時間。同時，該型 心形成材料通道150能在該噴絲板體11〇之中經由鑽孔而 被輕易地加工，同時，該橫向通道152能輕易地和精確地 由使用一環狀電極的放電加工（亦稱爲”EDM”)技術來成形 ______ 16 本’或張尺度國家標準（aNS)A4規格（21〇 χ 297公） --------------------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 580526 A7 --------- -B7____ 五、發明說明（) 。並且’因爲該針130係穩定地固定於該噴絲板體處深入 裝載孔111之中，所以該針同心地對準於該上方和下方環 狀通道153和154將被確保，並且，因而費力且繁瑣的對 準程序將被省略，藉此，將更減少反轉的時間。 與傳統的噴絲板相比較，該較佳具體實施例的噴絲板 組件100具有較少的零件並較容易被製造。圖3表示該更 加簡化該噴絲板製造程序的第一較佳具體實施例的該噴絲 板體的一替代結構。在圖2所繪製的該第一較佳具體實施 例當中’該型心流體通道112必須被加工，譬如被鑽孔， 以一角度和一高度的精密度在不損壞該具有一非常小直徑 的針裝載孔111的整體性的考慮下與針裝載孔111相遇而 相聯通。圖3的該噴絲板體具有一消弭此繁瑣加工步驟並 因而減少製造一噴絲板之成本的替代設計。特別地，一第 二內孔形成流體通道114係被加工以實質上平行於該型心 形成材料通道150，並從該噴絲板體110表面延伸至針裝 載孔111處，同時，係與該針裝載孔111同心。因爲該第 二內孔形成流體通道114係與針裝載孔111同軸，所以該 加工程序係大大地被簡化。該內孔形成流體通道112’在該 噴絲板體Π0內被加工，使得其方向對準內孔形成流體入 口 113並與第二內孔形成流體通道114在一實質上從針裝 載孔111處移除的點相橫向交叉。具有角度的內孔形成流 體通道112’係已經被加工以便與第二內孔形成流體通道 114相聯繫(該內孔形成流體通道114可在加工該具有角度 的通道112’之前先被加工），因爲與該針裝載孔111之直徑 _______ 17 _____ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) _·--------訂·！ i — 580526 A7 B7____ 五、發明說明（Λ ) 相比較，該具有角度的通道112’和通道114的直徑相對地 大。該第二內孔形成流體通道114在該噴絲板體110的表 面處之開口能在該噴絲板組件100被裝載於該旋轉機器之 期間或之際被塞住或者密封’以避免該內孔形成流體之洩 漏。圖3的替代設計的其它樣態相類似於上述圖2中之設 計。 依據本發明之一•第一^較佳具體貫施例被表不於圖4之 中，圖4繪製一以兩倍增加每一個噴絲板的纖維數之方法 。爲了淸楚地表示，使用在圖4中的元件編號係圖1、圖2 和圖3中相對應之元件編號再加100。圖4爲噴絲板體210 之上視圖。此具體實施例與繪製在圖1、圖2和圖3中的 具體實施例的顯著差異在於：針對每一個型心形成材料通 道250，兩個橫向通道252a和252b被成形，且每一個係 以一後切部分來成形。每一個橫向通道252a和252b被各 別提供一環狀通道253a和253b (相對應於圖2和圖3中 的環形通道）和針230a和230b(相對應於圖2和圖3中的 針130)。相似地，繪製在圖1、圖2和圖3之中的噴絲板 體110和底板120之中的其它特徵被當成噴絲板體210和 底板220的相對應特徵來被提供。因而，參考圖3和圖4 ’該等橫向通道252a和252b從該型心形成材料通道250 延伸至圍繞著該相對應的擠伸孔口的每一個針230a和 230b之環形通道253a和2531)的邊緣處。複數個針23〇a 和230b被配置在該噴絲板體21〇之中並與內孔形成液體通 道214a和214b相聯通。每一個針延伸穿過一分別由該圓 ---------------------------------- - . 1 〇 __ 本紙張尺度適用中國國家標準（CNS)A4規格（21〇 x 297公釐 (請先閱讀背面之注意事項再填寫本頁)V. Description of the invention (a) At the same time as the supply of the core forming material and the sheath forming material of 100, an inner hole forming fluid is injected into the inner hole forming a fluid inlet 1 i 3. A fluid channel is formed through the inner hole 112 and then into needle 13. The inner hole fluid emerges from the distal end of the needle 130 at a position located immediately downstream of the extrusion orifice 155 or at a position immediately downstream of the extension orifice 155. Because the core-forming material and the sheath-forming material are simultaneously and concentrically forming a fluid around the needle 130 and the inner hole exiting the needle through the lower annular channel 54 and from the extrusion orifice 155 It extends, so the formed extruder is a fiber, which includes an inner hole forming fluid in its center, the inner hole fluid is concentrically surrounded by a core forming material, and the core forming material is concentrically A cover-forming material is applied. As best shown in Figs. 1 and 2, the transverse channel 152 has a back-cut portion that completely surrounds the terminal portion of the needle 130 in a continuous manner and communicates with the upper annular channel 153. This structure eliminates the problem that the core-forming material is evenly distributed around the needles 130. At the same time, it also eliminates the problem of heading cracks caused by the incomplete mixing of the plurality of core material flows within the annular channel as disclosed in U.S. Patent No. 5,320,512 under the fiber wall. Meanwhile, when the spinneret assembly is removed from the rotating machine, since the core forming material passage 150 and the lateral passage 152 are already accessible, the spinneret management is relatively simple. This will facilitate arranging and reduce the reversal time of the spinneret. At the same time, the core-forming material channel 150 can be easily processed through the hole in the spinneret body 110, and at the same time, the lateral channel 152 can be easily and accurately processed by electrical discharge using a ring electrode (Also known as "EDM") technology to shape ______ 16 books or national standard (aNS) A4 specifications (21〇χ 297) ----------------- --- Order --------- line (please read the precautions on the back before filling this page) 580526 A7 --------- -B7 ____ 5. Description of the invention (). And 'Because the needle 130 is stably fixed in the loading hole 111 at the spinneret body, the needle's concentric alignment with the upper and lower annular channels 153 and 154 will be ensured, and therefore laborious And the tedious alignment procedure will be omitted, thereby reducing the reversal time even more. Compared to a conventional spinneret, the spinneret assembly 100 of this preferred embodiment has fewer parts and is easier to manufacture. Fig. 3 shows an alternative structure of the spinneret body of the first preferred embodiment which further simplifies the spinneret manufacturing process. In the first preferred embodiment illustrated in FIG. 2 'the core fluid passage 112 must be machined, such as drilled, with an angle and a high degree of accuracy without damaging the very small diameter Considering the integrity of the needle loading hole 111, the needle loading hole 111 meets the needle loading hole 111 and communicates with it. The spinneret body of Fig. 3 has an alternative design that eliminates this cumbersome processing step and thus reduces the cost of manufacturing a spinneret. In particular, a second inner hole forming fluid passage 114 is processed to be substantially parallel to the core forming material passage 150, and extends from the surface of the spinneret body 110 to the needle loading hole 111. The needle loading holes 111 are concentric. Since the second inner hole forming fluid passage 114 is coaxial with the needle loading hole 111, the processing procedure is greatly simplified. The inner hole forming fluid passage 112 'is processed in the spinneret body Π0 so that its direction is aligned with the inner hole forming fluid inlet 113 and forms a fluid passage 114 with the second inner hole at a position substantially from the needle loading hole 111. The removed points intersect laterally. The angled inner hole forming fluid passage 112 'has been processed so as to be associated with the second inner hole forming fluid passage 114 (the inner hole forming fluid passage 114 may be processed before machining the angled passage 112'), Because of the diameter of the needle loading hole 111 _______ 17 _____ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) _ · --- ----- Order! i — 580526 A7 B7____ 5. Description of the Invention (Λ) Compared with the angle, the diameter of the channel 112 'and the channel 114 are relatively large. The opening of the second inner hole forming fluid channel 114 at the surface of the spinneret body 110 can be plugged or sealed during or while the spinneret assembly 100 is being loaded in the rotating machine to avoid the inner Pore-forming fluid leaks. Other aspects of the alternative design of Figure 3 are similar to the design of Figure 2 above. According to the first embodiment of the present invention, the first preferred embodiment is shown in FIG. 4, which plots a method of increasing the number of fibers per spinneret by a factor of two. For the sake of clarity, the component numbers used in FIG. 4 are the corresponding component numbers in FIG. 1, FIG. 2 and FIG. 3 plus 100. FIG. 4 is a top view of the spinneret body 210. The significant difference between this specific embodiment and the specific embodiments drawn in Figures 1, 2 and 3 is that for each core forming material channel 250, two lateral channels 252a and 252b are formed, and each is connected with A back cut part is formed. Each of the lateral channels 252a and 252b is provided with an annular channel 253a and 253b (corresponding to the annular channel in FIGS. 2 and 3) and needles 230a and 230b (corresponding to the needle 130 in FIGS. 2 and 3). ). Similarly, other features drawn in the spinneret body 110 and the base plate 120 drawn in FIGS. 1, 2 and 3 are provided as corresponding features of the spinneret body 210 and the base plate 220. Thus, referring to FIGS. 3 and 4 'the lateral channels 252a and 252b extend from the core forming material channel 250 to the annular channels 253a and 2531 surrounding each of the needles 230a and 230b of the corresponding extrusion orifice) At the edge. A plurality of needles 23a and 230b are arranged in the spinneret body 21o and communicate with the inner hole forming liquid channels 214a and 214b. Each needle extends through a circle by the circle -----------------------------------. 1 〇_ _ This paper size is applicable to China National Standard (CNS) A4 (21 × 297 mm) (Please read the precautions on the back before filling this page)
580526 A7 B7 五、發明說明（A ) 柱狀上方和下方ig狀通道253a和253b、254a和254b所界 定之擠伸孔口 255a和255b。成形於該噴絲板體21〇底表 面之中的溝渠244和245係與界定在噴絲板體21〇和底板 220之間的間隙241a和241b相聯通。配置在嗜絲板體21〇 和底板220之間的夾鐵240界定該間隙241之尺寸，該間 隙241以一同心的方式在該間隙241a和241b分別和環狀 通道254a和254b的橫向交叉處圍繞著該型心成形材料提 供覆套形成材料的均勻輸送。覆套形成材料入口 242和覆 套形成材料通道243係成形於噴絲板體21〇之中與溝渠 244相聯通以允許覆套形成材料從覆套形成材料入/口 242 和覆套形成材料通道243，經由溝渠244和245、和間隙 241a和241b來輸送。該內孔形成流體經由內孔形成流體 入口 213供應給噴絲板體210。該內孔形成流體從每一個 內孔形成k體入口 213經過溝渠212’a和212，b被分配到 母個內孔形成^體通道214a和214b。按，該噴絲板組 件200能被附屬到該同樣的旋轉機器以製造兩倍的纖維。 熟悉此類技藝者能根據上述的具體實施例設計出額外的具 體實施例以旋轉出大於兩倍（如，3, 4, 5)之纖維。 圖5表示一適用於製造三種成分之中空纖維的本發明 之第二較佳具體貫施例。爲了淸楚地表示，使用在圖5中 相對應於圖1、圖2和圖3中的元件之元件編號爲圖丨、圖 2和圖3中的元件編號再加2〇〇。噴絲板組件3〇〇包括噴絲 板體310、底板320、複數個針33()(其中的一個可在圖5 中被淸楚地看到）和配置在噴絲板體31〇和底板32〇之間 (請先閱讀背面之注意事項再填寫本頁) .·------- 丨訂---------線丨--------- 本紙張尺度適用中國國家標準（CNS)A4規格（210 297公釐） 580526 A7 _____B7___ 五、發明說明（^ ) 的中間板360。夾鐵340a被配置於噴絲板體310和該中間 板360之間，且夾鐵340b被配置在該中間板360和底板 320之間。噴絲板體310、中間板360、底板320、夾鐵 340a和340b將如下詳述般地在使用期間被組裝在一單一 體當中。每一個針330的一中央端例如藉由一壓力套合被 固定在一以鑽孔或其它加工程序而成形於噴絲板體310之 中的各別的針裝載孔311之中。底板320和中間板360藉 由類似螺栓穿過孔332的固定器331被固定在噴絲板體 310處，並具有界定一間隙341a的夾鐵340a。此外，夾鐵 340b在該中間板360和該底板320之間界定一間隙341b。 相對於該環狀通道353, 363和354的該等孔口係各別 地成形於噴絲板體、中間板和底板之中，一型心形成材料 、一型心形成材料加一第一覆套形成材料和一型心形成材 料加一第一和第二覆套形成材料分別地經由該等孔口被擠 伸。向外張開的凹處356係成形於該底板32〇的一底表面 之上以允許每一個被擠伸纖維無干擾地離開噴絲板組件 300，更進一步地被該噴絲板組件3〇〇裝載於其上的旋轉機 器所處理。溝渠344a和345a被成形於噴絲板體310的一 底表面之中，並且與間隙341a相聯繫。溝渠344b和345b 被成形於底板320的一頂表面之中，並與間隙341b相聯通 〇 型心形成材料通道35〇係成形於噴絲板體31G之中， -類似聚合娜料咖祕成簡穿__㈣310被 引進母-個濟伸孔口之中。每—個型心形成材料通道 (請先閱讀背面之注意事項再填寫本頁) 丄-o· 線丨· 本紙張尺度適用中國國家標準(CNS)A4^i'(2i〇 297公釐） 580526 A7 _-__B7______ 五、發明說明（A ) 皆包括一型心形成材料入口 351，其係一以實質上平行於 該擠伸孔口的方向而延伸的孔。每一個型心形成材料通道 350同時包括一橫向通道352，其從型心形成材料入口 351 延伸到一定義該擠伸孔口的一上方部分的環狀通道353的 一頂部分。該橫向通道352係由藉著一工具塞入穿過型心 形成材料入口 350而成形於噴絲板體310之中的一後切部 分所定義，並且整體地圍繞針330而延伸，以便允許該型 心形成材料被均勻地引進環狀通道353之中。 內孔形成流體入口 313和內孔形成流體通道312和 314係成形於噴絲板體310之中，以便與針裝載孔311開 放地聯繫。此裝配允許一內孔形成流體被引進一被擠伸的 纖維之中，以下述的方式保持該被擠伸纖維的中空結構。 一第一覆套形成材料入口 342a係成形於噴絲板體31〇 之中與溝渠344a相聯繫，以允許一類似聚合物材料的一第 一覆套形成材料被引進該第一覆套形成材料入口 342a之中 ，經過第一覆套形成材料通道343a，進入溝渠34如和 345a，經過間隙34la，然後進入環狀通道363之中。 相似地，一第一覆套形成材料入口 342b係成形於底板 320之中，並與溝渠344b相聯繫，以允許一類似聚合物材 料的一第一覆套形成材料被引進該第二覆套形成材料入口 342b之中，經過第二覆套形成材料通道34补，進入溝渠 3輪和遍，經過間隙34lb，然後進入環狀通道Μ4之 中。該第二較佳具體貫施例的其它樣態係相似於該第一較 佳具體實施例，且相似的元件皆標上相似的號碼，但尾部 (請先閱讀背面之注意事項再填寫本頁) -------^ ---------I tAW--I---------580526 A7 B7 5. Description of the invention (A) Extruded orifices 255a and 255b defined by ig-shaped channels 253a and 253b, 254a and 254b above and below the column. The grooves 244 and 245 formed in the bottom surface of the spinneret body 21 are connected to the gaps 241a and 241b defined between the spinneret body 21 and the bottom plate 220. An iron 240 disposed between the serigraphic plate body 21 and the bottom plate 220 defines the size of the gap 241. The gap 241 is in a concentric manner at the transverse intersections of the gaps 241a and 241b and the annular channels 254a and 254b, respectively. A uniform delivery of the sheath forming material is provided around the core forming material. The sheath-forming material inlet 242 and the sheath-forming material channel 243 are formed in the spinneret body 21 and communicate with the trench 244 to allow the sheath-forming material to pass from the sheath-forming material inlet / outlet 242 and the sheath-forming material channel. 243 is conveyed via the trenches 244 and 245 and the gaps 241a and 241b. This inner hole forming fluid is supplied to the spinneret body 210 via the inner hole forming fluid inlet 213. The inner hole forming fluid is distributed from each of the inner hole forming k-body inlets 213 through the trenches 212'a and 212, b to the female inner hole forming body channels 214a and 214b. In turn, the spinneret assembly 200 can be attached to the same rotating machine to make twice as much fiber. Those skilled in the art can design additional specific embodiments based on the specific embodiments described above to spin out more than twice (e.g., 3, 4, 5) fibers. Fig. 5 shows a second preferred embodiment of the present invention which is applicable to the production of three-component hollow fibers. For the sake of clarity, the component numbers in Figure 5 corresponding to those in Figures 1, 2, and 3 are the component numbers in Figures 1, 2, and 3, plus 200. The spinneret assembly 300 includes a spinneret body 310, a bottom plate 320, a plurality of pins 33 () (one of which can be seen clearly in FIG. 5), and a spinneret body 31 and a bottom plate. Between 32〇 (Please read the precautions on the back before filling in this page) ..------- 丨 Order --------- Line 丨 --------- This paper The dimensions are applicable to the Chinese National Standard (CNS) A4 specification (210 297 mm) 580526 A7 _____B7___ 5. The intermediate plate 360 of the invention description (^). The clamp iron 340a is arranged between the spinneret body 310 and the intermediate plate 360, and the clamp iron 340b is arranged between the intermediate plate 360 and the bottom plate 320. The spinneret body 310, the intermediate plate 360, the bottom plate 320, and the iron 340a and 340b will be assembled in a single body during use as described in detail below. A central end of each needle 330 is fixed in a respective needle loading hole 311 formed in the spinneret body 310 by drilling or other processing procedures, for example, by a pressure fitting. The bottom plate 320 and the middle plate 360 are fixed to the spinneret body 310 by a holder 331 similar to a bolt passing hole 332, and have clip irons 340a defining a gap 341a. In addition, the clamp iron 340b defines a gap 341b between the intermediate plate 360 and the bottom plate 320. The orifices opposite to the annular channels 353, 363 and 354 are respectively formed in the spinneret body, the middle plate and the bottom plate, a core forming material, a core forming material plus a first cover The sleeve-forming material and a core-forming material plus a first and second sheath-forming material are extruded through the orifices, respectively. The outwardly recessed recess 356 is formed on a bottom surface of the bottom plate 32o to allow each extruded fiber to leave the spinneret module 300 without interference, and further, the spinneret module 3o. 〇 Processed by a rotating machine mounted on it. The trenches 344a and 345a are formed in a bottom surface of the spinneret body 310 and are connected to the gap 341a. The trenches 344b and 345b are formed in a top surface of the bottom plate 320, and communicate with the gap 341b. The core-forming material channel 35 is formed in the spinneret 31G. Wearing __㈣310 was introduced into the female-Geshen orifice. Each core-forming material channel (please read the precautions on the back before filling this page) 丄 -o · Line 丨 · This paper size applies to Chinese National Standard (CNS) A4 ^ i '(2i〇297mm) 580526 A7 _-__ B7______ 5. The invention description (A) all include a core forming material inlet 351, which is a hole extending substantially parallel to the direction of the extrusion orifice. Each core forming material channel 350 also includes a lateral channel 352 extending from the core forming material inlet 351 to a top portion of an annular channel 353 defining an upper portion of the extrusion orifice. The transverse channel 352 is defined by a back-cut portion formed in the spinneret body 310 by being inserted through a core-forming material inlet 350 through a tool, and extends integrally around the needle 330 so as to allow the The core forming material is uniformly introduced into the annular passage 353. The inner hole forming fluid inlet 313 and the inner hole forming fluid passages 312 and 314 are formed in the spinneret body 310 so as to openly communicate with the needle loading hole 311. This assembly allows an inner hole-forming fluid to be introduced into an extruded fiber, maintaining the hollow structure of the extruded fiber in the following manner. A first sheath-forming material inlet 342a is formed in the spinneret body 31 and is connected to the trench 344a to allow a first sheath-forming material of a similar polymer material to be introduced into the first sheath-forming material. In the inlet 342a, a material channel 343a is formed through the first sheath, enters the trenches 34 and 345a, passes through the gap 34la, and then enters the annular channel 363. Similarly, a first sheath-forming material inlet 342b is formed in the bottom plate 320 and is associated with the trench 344b to allow a first sheath-forming material of a similar polymer material to be introduced into the second sheath. In the material inlet 342b, the material cover 34 is formed through the second covering, enters the trench for 3 rounds and passes, passes through the gap 34lb, and then enters the annular channel M4. The other aspects of the second preferred embodiment are similar to the first preferred embodiment, and similar elements are marked with similar numbers, but at the end (please read the precautions on the back before filling this page) ) ------- ^ --------- I tAW--I ---------
580526 A7 -----_ -- R7__ 五、發明說明（/ ) 附加一”3，，。 該第三較佳具體實施例的操作係相似於該第一較佳具 體貫施例。但是，該第二覆套形成材料流過該第二覆套形 成材料入口 342b，經過第二城套形成材料通道343b，進入 溝渠344b和345b，經過間隙341b，然後進入環狀通道 354。當第二覆套形成材料進入環狀通道354之時，其均勻 地圍繞著從環狀通道363 (例如，將該型心材料塗佈第一 覆蓋形成材料）流進環狀通道354的材料而被放置。按， —具有一型心的中空纖維、一均勻放置在該型心之上的第 一覆套和一均勻放置在該第一覆套和型心之上的第二覆套 皆以一同心的方式被成形。 該上述位於噴絲板組件之中的各種口、溝渠和通道能 以任何的形式被成形，並可爲任何的數目，以製造具有複 數覆套和型心的纖維。例如，該型心形成材料通道能爲任 何形狀或構型，且能包括複數個溝渠或僅一單一溝渠。該 噴絲板組件能使用任何熟知的技術，例如，鑽孔、放電加 工(EDM)或其它任何合適的程序來加工。其能夠有任何數 目的擠伸孔口的存在。各種的角度和尺寸能加以變化以適 合特殊的應用。該噴絲板組件可以任何合適的材料，例如 ，鋼、蒙耐合金、鈦、鋁或其合金來製造。該型心形成材 料和該覆套形成材料可爲任何適合擠伸的類型，例如，聚 合物熔解物或溶液、陶瓷糊，等類似物。該內孔形成流體 可爲類似一惰性氣體或液體。 本發明已經經由若干較佳具體實施例來加以說明。但 ----- 99 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐1 '一~' --- (請先閱讀背面之注意事項再填寫本頁)580526 A7 -----_-R7__ V. Description of the Invention (/) A "3" is added. The operation of the third preferred embodiment is similar to the first preferred embodiment. However, The second covering forming material flows through the second covering forming material inlet 342b, passes through the second covering forming material passage 343b, enters the trenches 344b and 345b, passes through the gap 341b, and then enters the annular passage 354. When the second covering When the sleeve-forming material enters the annular channel 354, it is placed uniformly around the material flowing into the annular channel 354 from the annular channel 363 (for example, coating the core material with the first covering forming material). — Hollow fiber with a core, a first cover evenly placed on the core and a second cover evenly placed on the first cover and the core are all in a concentric manner Shaped. The various openings, trenches and channels in the spinneret assembly described above can be shaped in any form and can be any number to make fibers with multiple sheaths and cores. For example, this type Heart-forming material channels can be of any shape or configuration And can include multiple trenches or only a single trench. The spinneret assembly can be processed using any well-known technique, such as drilling, electrical discharge machining (EDM), or any other suitable process. It can have any number The existence of extruded orifices. Various angles and sizes can be changed to suit special applications. The spinneret assembly can be made of any suitable material, such as steel, Monel, titanium, aluminum or its alloys. The core-forming material and the sheath-forming material may be of any type suitable for extrusion, such as polymer melts or solutions, ceramic pastes, and the like. The inner hole-forming fluid may be similar to an inert gas or liquid. The present invention has been described through several preferred embodiments. However, the paper size of this paper is applicable to China National Standard (CNS) A4 (210 X 297 mm 1 'a ~') --- (please first (Read the notes on the back and fill out this page)
580526 A7 _B7_ 五、發明說明（Μ) 是，各種修飾仍能在不偏離如後所附的申請專利範圍所定 義的本發明的範疇之內來家施行。 (請先閱讀背面之注意事項再填寫本頁) IAW--------訂---------'^丨. -n n n ! n n n n I n n n n n n ϋ n n l> n n < _ 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）580526 A7 _B7_ 5. Description of the Invention (M) Yes, various modifications can still be implemented within the scope of the present invention as defined by the scope of the attached patent application. (Please read the precautions on the back before filling this page) IAW -------- Order --------- '^ 丨. -Nnn! Nnnn I nnnnnn ϋ nn l > nn < _ This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)