574158 A7 B7 五、發明說明（ 【創作領域】 本發明是有關於一種製成玻璃陶瓷或釉藥之方法，特 別是指一種可大量利用再生資源的回收顯示幕玻璃料製成 玻璃陶瓷或釉藥之方法。 【習知技藝說明】 玻璃陶兗」指的是含有玻璃相的多晶固體材料，其 製造由玻璃熔解開始，經過玻璃成形，再施予控制結晶熱 處理’使其結晶化而形成多晶固體。玻璃陶瓷材料可經由 化學組成與結晶熱處理的調整，改變晶體的種類、結晶量 及各種微結構，可配置出性質寬廣且優異的材料，諸如超 低或特定之熱膨脹性、高機械強度、化學抗蝕、易加工性 以及特殊的光電特性等。因此玻璃陶瓷在各方面的應用相 當廣泛，已成為陶瓷工業中極為重要的材料。例如家中必 備$電視顯示幕或電腦的顯示幕，更是佔玻璃陶瓷原料消 費量之大宗，其衍生出來的廢棄物處理問題也顯得袼外重 要。重要的是，上述玻璃陶一亮的製程必須注意氣泡或針孔 的產生、及平整度的控制，且成本較高、製程時間也明顯 較長。 . 【創作概要】 消 f請先閱讀背面之注音？事項再填寫本頁} 因此，本發明之目的，即在提供一種可大量回收所有 廢棄顯示幕產生的玻璃廢料，以大幅降低生產成本，並提 供最佳的控制技術解決氣泡、針孔或釉縮等問題的回收顯 示幕玻璃料製成玻璃陶瓷或釉藥之方法。 ‘ 於疋’本發明之目收顯示幕玻璃料製成玻璃冑兗之方 1____ 第3頁 本紙張尺度適用中國國家標準（CNS)A4規格 574158 五、發明説明（， 碎料。步：列步驟.步驟-：將回收的顯示幕玻璃料製成 一二二料:：55t (請先聞讀背面之注意事項再填寫本頁) 添加材料，置^的結晶材料及有色 將上if “中進行乾粉式混合。步驟=: 將上述粉末裝人_高溫容器内，以高溫加 ^ 平板，並：驟四：依照尺寸需求切割上述 +板相磨平板表面’製成平面玻璃陶宪碑之成品。 本發明之回收顯示幕玻璃料製成釉藥之方法包 =步驟：步驟一：將回收的顯示幕玻璃料粉碎t，進行第 -次乾式粉末研磨，製成粉末狀玻璃料。步驟二：以成份 比45〜90%的粉末狀玻璃料、成份比1〇〜2〇%的含氧化鋁= 料、成份比10-15%的有機懸浮材料、成份比〇 的無 機懸浮材料及成份比5-20%增溫或降溫材料置入乾粉攪拌 機中進行乾粉式混合。步驟三：將上述混合粉末置入内裝 高紹竟球的球磨機中，以水式研磨成250目〜3 2〇目的細 度。步驟四：以篩網過濾出上述細粉狀的混合粉末。步驟 七：將上述細粉狀的混合粉末送經乾燥處理，製成乾粉式 釉藥之成品。 經濟部中央標準局員工消費合作社印製 【圖式之簡單說明】 本發明所採用之技術、手段及優點，在以下配合參考 圖式之較佳實施例的詳細說明中，將可清楚的明白，在圖 式中： 第一圖是一流程圖，說明本發明一回收顯示幕玻璃料 製成玻璃陶瓷之方法；及 頁 第 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） 574158 A7 B7 五、發明説明（, 第二圖是一流程圖，說明本發明—回收顯示幕玻璃 製成釉藥之方法。 【較佳實施例之詳細說明】 (請先閲讀背面之注意事項再填寫本頁) 二參閱第一圖，本發明之回收顯示幕玻璃料製成玻璃陶 瓷之方法的較佳實施例是包含下列步驟： 步驟一：備料 “選用廢棄顯示幕回收之玻璃才斗，主要來源是電視、電 腦顯示幕…·等等，將上述玻璃料製成玻璃廢碎料此時， 玻璃碎料仍保有完整的材料物性。 步驟二：配料混合 經濟部中央標準局員工消費合作社印製 以成份比60-85%的玻璃碎料、成份比15〜4〇%的含氧 化鋁材料、成份比共5〜20%的結晶材料及有色添加材料， 乾粉攪拌機中進行乾粉式混合。該含氧化鋁材料可以 是间嶺土、氫氧化鋁…其中一種，具有耐熱震、降低膨脹 系數的特性，可以改變玻璃陶究的強度與韌度。該結晶材 料可以是氧化鋅、氧化鎂、氧化鈦、氧化鐵、碳酸鈣、碳 酸鋰…其中一種，可供形成玻璃陶瓷的花紋及改變結構。 該有色添加材料可以是各種無機色料、有色氧化物其中一 種，可供製造各種色調的玻璃陶瓷。 步驟三•·高溫燒成 將上述粉末裝入耐高溫容器（可以是高溫匣妹、輕質纖 維高紹、高鎂質容器的其中一種）内，以12〇(rc以上的燒 結溫度鬲溫加熱1到8小時，使新加入的配料與顆粒狀廢 料經融熔以後完成組織的重建，燒結成耐熱震、低膨脹系 頁 第 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇><297公釐 4574158 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（ 數、咼強度與軔性而可加工彎曲的平板，且該平板可具有 花紋及各種色調。 步驟五：切割與研磨 依照尺寸需求切割上述平板，並研磨平板表面，製成 平面玻璃陶瓷磚之成品，藉此，該玻璃陶瓷碑可做為建材 使用’或加熱彎曲製成各種實用的器皿。 參閱第二圖，本發明之回收顯示幕玻璃料製成釉藥之 方法的較佳實施例是包含下列步驟·· 步驟一：備料 選用廢棄顯示幕回收之玻璃料，主要來源是電視、電 月包顯示幕—等等，將上述玻璃料製成玻璃廢碎料後，置入 雷矇機内進行乾式研磨，此時，粉末狀玻璃料仍保有完整 的材料物性。 步驟二：配料混合 以成份比45〜90%的粉末狀玻璃料、成份比10〜2〇%的 含氧化紹材料、成份比1 〇_ 1 5%的有機懸浮材料、成份比 〇· 1〜0.3%的無機懸浮材料及成份比5-20%增溫或降溫材料 置入乾粉授拌機中進行乾粉式混合。該無機的含氧化紹材 料可以疋葉長石、鋰輝石、高嶺土、氫氧化紹…其中一種， 具有耐熱震、降低膨脹系數的特性，可改變玻璃材料的強 度與軔度（可加工彎曲），可以增加釉藥燒成時的粘度及流 動性的調整。該有機的懸浮材料可以是乳膠懸浮液，該無 機的懸浮材料可以是滑石、碳酸鎂、矽酸鍅、碳酸約、納 硼酸鈣、氯化物…其中一種。該增溫或降溫材料可以是氧 第6頁 本紙張尺度適用中國國料g (CNS)A4規格（210 X 297公釐) " " --------訂----------線· (請先閱讀背面之注意事項再填寫本頁) 574158 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（5 ) 化鐵、氧化敛、氧化姑…荨金屬氧化物其中一種，可以提 高或降低釉藥燒成的溫度，且能提供釉藥顏色成為有色添 加材料，及可供形成結晶材料。 步驟三：水式研磨 將上述混合粉末置入内裝高鋁瓷球（硬度7 _ 7 5)的球 磨機中，以水式研磨成250目〜320目的細度。 步驟六：過濾 以篩網過濾出上述細粉狀的混合粉末。 步驟七：乾燥 將上述細粉狀的混合粉末送經乾燥處理，製成乾粉式 釉藥之成品，該乾燥處理可以是喷霧、壓濾或離心方法其 中一種，其中，該喷霧式乾燥處理可以獲得渔度6%的乾粉 式釉藥，但燃料成本較高，該壓濾式乾燥處理可以獲得= 度20-25%的乾粉式釉藥，該離心式乾燥處理可以獲得溼度 20_25%的乾粉式轴藥，另外，該壓濾式及離心式乾燥處理 可以和陶究、碑廠或焚化爐配合，善用餘熱以洪乾或晒乾 方式完成。而該乾粉式釉藥伴隨器孤送入燒結時，就能= 新加入的配料與玻離廢料經融熔以後完成組織的重建，具 有低膨脹系數、高粘度及流動性的特性，使釉藥不會有氣 泡、針孔或釉縮等問題產生。 、 另外，在步驟一之後可包含一抽樣檢查的步驟，該抽 樣檢,的步驟主要是預先取樣少量的粉末狀廢#，先：標 準劑量的配料試作成成品，並經檢測後，若符合標準即： 以每500噸廢棄玻璃料為一個單位大量生產，若不符桿； 第7頁 本紙張尺錢时目目規格⑽ -------------衣--------訂-----1---線 (請先閱讀背面之注音？事項再填寫本頁} 574158 A7 B7 6 五、發明說明（ 則在調整配料之比例及配方銘 万後’再經分析至符合標準而倉| 大量生產為止。 (請先閱讀背面之注意事項再填寫本頁) 右要製成不具色彩的翻龜 J柚樂，可以在步驟三之後增加一 除鐵的步驟，該除鐵的步驟 7鄉主要是在製成溼式的細粉狀洁 合物後，以除鐵機吸收溼彳,h 座式細粉狀混合物内含的鐵質4 份。藉此，該乾燥後的蘚扒_ 乾私式釉樂經燒結後就會形成透明 狀態。 歸納上述，纟發明t目收顯示幕玻璃才斗製成玻璃陶資 或釉藥之方法實已具有如下所列之優點及功效： 本發明可大量回收所有廢棄顯示幕產生的玻璃廢料， 不但能大幅降低生產成本，並可有效提供最佳的控制技掏 解決以天然材料製成玻璃陶瓷或釉藥所產生的氣泡、針孔 或釉縮等問題，使本發明製成的玻璃陶瓷具有耐熱震、低 膨脹系數、高強度與軔性而可加工彎曲，而適用為建材， 且具有花紋及各種色調，同時使本發明製成的釉藥具有低 膨服系數、南枯度及流動性的特性。 經濟部智慧財產局員工消費合作社印製 惟以上所述者，僅為本發明之較佳實施例而已，當不 能以此限定本發明實施之範圍，即大凡依本發明申請專利 範圍及創作說明書内容所作之簡單的等效變化與修飾，皆 應仍屬本發明專利涵蓋之範圍内。 第 頁 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）574158 A7 B7 V. Description of the invention ([Creative Field] The present invention relates to a method for making glass ceramics or glazes, in particular to a glass ceramics or glazes made of recycled display glass frit which can make extensive use of renewable resources. [Know-how] [Glass ceramic pottery] refers to a polycrystalline solid material containing a glass phase. The manufacture of glass ceramics begins with the melting of the glass, passes through the glass forming, and then applies a controlled crystallization heat treatment to cause it to crystallize to form a polycrystalline solid. Crystal solids. Glass ceramic materials can be adjusted by chemical composition and crystallization heat treatment to change the type, amount of crystals and various microstructures of crystals, and can be configured with broad and excellent materials, such as ultra-low or specific thermal expansion, high mechanical strength , Chemical resistance, processability, and special optoelectronic characteristics. Therefore, glass ceramics are widely used in various aspects and have become extremely important materials in the ceramic industry. For example, the necessary TV display screen or computer display screen in the home, more It is the bulk of glass ceramic raw material consumption, and the waste disposal problems derived from it also appear It is important. It is important that the above-mentioned glass ceramic Yiliang production process must pay attention to the generation of bubbles or pinholes, and the control of flatness, and the cost is higher, and the process time is significantly longer. [Creation summary] Please read the back Note to note? Please fill out this page again} Therefore, the purpose of the present invention is to provide a large amount of glass waste that can be recycled from all waste display screens, to greatly reduce production costs, and to provide the best control technology to solve air bubbles and pinholes. Method for recycling display screen frit to make glass ceramics or glazes for problems such as shrinking or glaze. 'Yu' The method of making the display screen frit made of glass according to the invention 1____ Page 3 This paper is applicable to China National Standard (CNS) A4 Specification 574158 V. Description of the invention (, scraps. Steps: Steps. Steps :: Make the recovered display screen glass material into one or two materials: 55t (please read the precautions on the back first) (Fill in this page again) Add materials, set crystalline material and colored powder to mix dry powder. If step =: Put the above powder in a _ high temperature container, add ^ plate at high temperature And: Step 4: Cut the above + plate phase grinding flat surface to make the finished product of the flat glass pottery stele in accordance with the size requirements. The method of recycling the display screen frit to make the glaze medicine package = steps: step one: The recovered display screen frit is pulverized, and is subjected to the first dry powder grinding to make a powdery glass frit. Step 2: The powdery glass frit with a composition ratio of 45 to 90% and a content of 10 to 20% Alumina = raw materials, organic suspended materials with a composition ratio of 10-15%, inorganic suspended materials with a composition ratio of 0, and warming or cooling materials with a composition ratio of 5-20% are placed in a dry powder mixer for dry powder mixing. Step 3: Put the above The mixed powder is placed in a ball mill containing Gao Shaojing balls and ground with water to a fineness of 250 mesh to 3 20 mesh. Step 4: Filter out the fine powdery mixed powder with a sieve. Step 7: Send the above-mentioned fine powdery mixed powder to a drying process to make a finished product of a dry powder glaze. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economics [Simplified illustration of the scheme] The technology, means and advantages used in the present invention will be clearly understood in the following detailed description of the preferred embodiment with reference to the diagram. In the drawings: The first figure is a flowchart illustrating a method for making glass ceramics by recycling the display screen frit according to the present invention; and the page size of this paper applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 574158 A7 B7 V. Description of the invention (, The second figure is a flowchart illustrating the present invention-method for recycling display screen glass to make glaze. [Detailed description of the preferred embodiment] (Please read the precautions on the back before filling (This page) Referring to the first figure, the preferred embodiment of the method for recycling display screen frits to make glass ceramics according to the present invention includes the following steps: Step 1: Prepare the material "Select the glass bucket recycled from the waste display screen, the main source It is a TV, computer display screen, etc., etc. The above glass frit is made into glass waste and scrap. At this time, the glass scrap still retains the complete material properties. Materials Co-operation of the Central Standards Bureau of the Ministry of Economics and Workers' Consumer Cooperative printed glass scraps with a composition ratio of 60-85%, alumina-containing materials with a composition ratio of 15-40%, crystalline materials with a total composition of 5-20%, and colored additions Materials, dry powder mixing in a dry powder mixer. The alumina-containing material can be one of metamorphite, aluminum hydroxide, etc., which has the characteristics of thermal shock resistance, reduced expansion coefficient, and can change the strength and toughness of glass ceramics. The crystalline material can be one of zinc oxide, magnesium oxide, titanium oxide, iron oxide, calcium carbonate, lithium carbonate, etc., which can be used to form the pattern and change the structure of glass ceramics. The colored additive material can be various inorganic colorants and colored oxides. One of them can be used to make glass ceramics of various shades. Step Three: High temperature firing Put the above powder into a high temperature resistant container (which can be one of high temperature box sister, lightweight fiber Gao Shao, high magnesium container), Heating at a sintering temperature of 120 ° C or higher for 1 to 8 hours, after the newly added ingredients and granular waste are melted, the tissue reconstruction is completed and sintered into Thermal shock, low expansion series page size of this paper applies Chinese National Standard (CNS) A4 specifications (21〇 > < 297 mm 4574158 A7 B7 Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs It can be processed into a curved flat plate with high strength and rigidity, and the flat plate can have patterns and various colors. Step 5: Cutting and grinding Cut the above flat plate according to the size requirements, and grind the surface of the flat plate to make a finished glass ceramic tile. Therefore, the glass-ceramic tablet can be used as a building material or made of various practical utensils by heating and bending. Referring to the second figure, the preferred embodiment of the method for recycling the display screen frit to make a glaze according to the present invention includes the following steps: ·· Step 1: Select the glass frit recovered from the waste display screen as the material preparation. The main source is the TV, electric monthly display screen—etc. After the above glass frit is made into glass waste and scrap, put it in Raymond machine for dry grinding. At this time, the powdered glass frit still retains complete material properties. Step 2: Mix the ingredients with powdered glass frit with a composition ratio of 45 ~ 90%, oxide-containing materials with a composition ratio of 10 ~ 20%, organic suspension materials with a composition ratio of 〇_ 1 5%, and a composition ratio of 0.1 ~ 1 0.3% inorganic suspended materials and ingredients with 5-20% warming or cooling materials are placed in a dry powder blender for dry powder mixing. The inorganic oxide-containing material can be one of feldspar, spodumene, kaolin, hydroxide, etc., which has the characteristics of thermal shock resistance and reduction of expansion coefficient, and can change the strength and intensity of glass materials (processable and bendable). Increase viscosity and fluidity adjustment during glaze firing. The organic suspension material may be a latex suspension, and the inorganic suspension material may be one of talc, magnesium carbonate, rhenium silicate, carbonic acid, calcium nanoborate, chloride ... The temperature increasing or cooling material can be oxygen. Page 6 This paper size applies to China National Standard g (CNS) A4 (210 X 297 mm) " " -------- Order ----- ----- Line · (Please read the notes on the back before filling out this page) 574158 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (5) Iron, Oxidation, Oxidation ... One of the metal oxides can increase or decrease the firing temperature of the glaze, and can provide the glaze color as a colored additive material, and can be used to form a crystalline material. Step 3: Water grinding Put the above mixed powder into a ball mill with high-alumina porcelain balls (hardness 7 _ 7 5), and water-mill to a fineness of 250 mesh to 320 mesh. Step 6: Filtering out the above fine powdery mixed powder through a sieve. Step 7: Drying The fine powdery mixed powder is sent to a drying process to make a finished product of a dry powder glaze. The drying process may be one of spraying, filtering, or centrifuging methods. The spraying drying process Dry powder glazes with a fishing degree of 6% can be obtained, but the fuel cost is high. The filter-filtration drying treatment can obtain dry powder glazes with a degree of 20-25%, and the centrifugal drying treatment can obtain dry powders with a humidity of 20_25%. In addition, the filter press and centrifugal drying treatment can be combined with the ceramic research, monument factory or incinerator, and the waste heat can be used to complete the drying or drying process. When the dry powder glaze companion is sent into sintering alone, the structure of the newly added ingredients and glassy waste can be reconstructed after melting, which has the characteristics of low expansion coefficient, high viscosity and fluidity, making the glaze No air bubbles, pinholes, or glaze problems will occur. In addition, after step 1, a step of sampling inspection may be included. The step of sampling inspection is mainly to sample a small amount of powdery waste in advance. First: the standard dose of ingredients is tested into a finished product. After testing, if it meets the standard, That is, mass production is made for every 500 tons of waste glass frit as a unit, if it does not meet the requirements; page 7 The specifications of this paper when measuring the amount of money ⑽ ------------- 衣 ----- --- Order ----- 1 --- Line (Please read the phonetic on the back? Matters before filling out this page} 574158 A7 B7 6 V. Description of the invention (then after adjusting the proportion of ingredients and the formula name, then After analysis until it meets the standard, the warehouse is in mass production. (Please read the precautions on the back before filling in this page.) To make the uncolored Turtle J Yule, you can add an iron removal step after step 3. The step 7 of removing iron is mainly to prepare 4 parts of iron contained in the fine powdery mixture of the h-type fine powdery mixture after being made into a wet-type fine powdery clean compound. The dried moss grill _ dried private glaze will become transparent after sintering. The method of making glass pottery or glaze by Licaidou has the following advantages and effects: The present invention can recycle a large amount of glass waste generated from all abandoned display screens, which can not only greatly reduce the production cost, but also provide the most effective Good control technology solves the problems of bubbles, pinholes, or glaze shrinkage caused by glass ceramics or glazes made of natural materials, so that the glass ceramics produced by the invention have thermal shock resistance, low expansion coefficient, high strength and flexibility. It can be processed and bent, and is suitable for building materials, and has patterns and various colors. At the same time, the glaze produced by the invention has the characteristics of low swelling coefficient, southern dryness and fluidity. The above are only the preferred embodiments of the present invention. When the scope of implementation of the present invention cannot be limited by this, that is, the simple equivalent changes and modifications made in accordance with the scope of the patent application and the content of the creative specification of the present invention , All should still fall within the scope of the invention patent. Page size of this paper applies Chinese National Standard (CNS) A4 (210 X 297 mm)