TW570984B - Method for recovering stainless steel slag from EBT steel-discharging-type electric furnace - Google Patents

Method for recovering stainless steel slag from EBT steel-discharging-type electric furnace Download PDF

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TW570984B
TW570984B TW91110442A TW91110442A TW570984B TW 570984 B TW570984 B TW 570984B TW 91110442 A TW91110442 A TW 91110442A TW 91110442 A TW91110442 A TW 91110442A TW 570984 B TW570984 B TW 570984B
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Taiwan
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steel
electric furnace
slag
ebt
type electric
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TW91110442A
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Chinese (zh)
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Yu-Sheng Wei
Tzung-Shiau Lai
Sheng-Jou Hou
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Walsin Lihwa Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Abstract

A method for recovering stainless steel slag from an EBT steel-discharging-type electric furnace is used to recover precious metal from an EBT steel-discharging-type electric furnace during production of stainless steel, and comprises: tilting the EBT steel-discharging-type electric furnace so that the slag contained therein is pre-loaded into a steel containing barrel; returning the EBT steel-discharging-type electric furnace to its original status; moving the steel containing barrel containing slag to a position below the outlet of steel liquid of the EBT steel-discharging-type electric furnace; and opening the outlet of steel liquid of the EBT steel-discharging-type electric furnace to drain the stainless steel iron liquid in the EBT steel-discharging-type electric furnace into the steel containing barrel loaded with slag so that the molten stainless steel impinge on the slag in the steel containing barrel to form a mixing function. Thus, precious metal can be recycled at a high efficiency during production of stainless steel by an EBT steel-discharging-type electric furnace, thereby improving the economic efficiency of the process.

Description

570984570984

【發明範圍】 本赉明係有關於一種爐渣金屬回收方法,詳而言之, 尤才曰種應用於EBT出鋼式電爐(Escentric Bottom[Scope of the invention] The present invention relates to a method for recovering slag metal. In particular, it is particularly applicable to EBT Escentric Bottom electric furnaces.

Tapping),而使其生產不銹鋼之時,可達到並大為提升其 貴重金屬回收效益之EBT出鋼式電爐不銹鋼爐渣金屬回收、 方法。 【發明背景】 按,傳統提煉碳鋼所用之煉鋼爐如第1圖所示,係為 一種壺式電弧爐90,該電弧爐9〇上設有通以三向電流之電 極棒91,用以熔化廢鐵金屬,而其兩側則設有一作業口 9。2(或出潰^口)及出鋼口93,其中該作業口92並可於電熔過 私中輸入氧氣,以利電熔作業;而該廢鐵金屬在電弧爐⑽ 内電極熔化後會產生碳鋼鐵水94及浮於上面之爐渣95,該 爐渣95 —般係包括有Fe0、Mn〇、Si〇2、Α1Λ、㈤、_等 雜貝,因该爐渣95所含金屬之精煉回收成本效益不佳,且 其對碳鋼品質有不利影響,故一般皆將生產碳鋼之爐渣去 除,而其操作上係先將該電弧爐9〇往該作業口 92之一側傾 倒,使該爐渣95倒入一渣桶96中,再將該電弧爐9〇往該出 鋼口 93 —側傾倒,使該碳鋼鐵水94倒入一盛鋼桶97中。 而由於此種亞式電弧爐9 〇在將碳鋼鐵水g 4倒入盛鋼桶9 7 内%•,仍有部份爐渣9 5將一起隨之倒入該盛鋼桶g 7内,造 成不利碳鋼精煉之品質,故近期業界所用之煉鋼爐大多採 用 EBT 出鋼式電爐(EsCentric B〇u〇m Tapping),如第 2圖 所示,該EBT出鋼式電爐之電熔操作類似傳統壺式電弧Tapping), and when it is used to produce stainless steel, it can achieve and greatly improve its precious metal recovery efficiency. EBT tapping type stainless steel slag metal recovery method. [Background of the Invention] According to the traditional steel refining furnace used for refining carbon steel, as shown in Fig. 1, it is a pot-type electric arc furnace 90. The electric arc furnace 90 is provided with an electrode rod 91 through which a three-way current flows. It is used to melt the scrap iron metal, and there are an operation port 9.2 (or outlet) and a steel outlet 93 on both sides. The operation port 92 can be used to input oxygen in the electric melting pass to facilitate electricity. Melting operation; and when the scrap iron metal is melted in the inner electrode of the electric arc furnace, carbon steel 94 and slag 95 floating thereon will be generated. The slag 95 generally includes Fe0, Mn〇, Si〇2, A1Λ, ㈤ And other miscellaneous shellfish, because the refining and recovery of the metal contained in the slag 95 is not cost-effective, and it has an adverse effect on the quality of carbon steel, the slag for carbon steel production is generally removed, and its operation is to first The electric arc furnace 90 is poured to one side of the operation port 92, the slag 95 is poured into a slag bucket 96, and the electric arc furnace 90 is poured to the side of the tap hole 93, so that the carbon steel 94 is poured. Into a Sheng steel bucket 97. And because this type of Asian electric arc furnace 90 is pouring carbon steel molten steel g 4 into the steel drum 9 7%, some slag 9 5 will be poured into the steel drum g 7 together, resulting in The quality of carbon steel refining is unfavorable. Therefore, most of the steelmaking furnaces used in the industry recently use EBT EtCentric Boiler Tapping. As shown in Figure 2, the EBT's electric melting operation is similar. Traditional kettle arc

570984 五、發明說明(2) 爐,其包括有一盤體狀之電爐80,該電爐8〇 一側之底緣係 設有-鋼水出口81,該鋼水出口81之啟閉係受一擋板82之 控制’:该擋板82抽出後,該電爐8〇内之碳鋼鐵水Μ即從 口81排出而流人—預置之盛鋼桶_ 八I之碳鋼鐵水83即能有效與浮在上層之爐潰 產 Q隔为離,而使碳鋼之精煉品質大為提升。 ,,,由於鋼鐵業者競爭日益激烈,為求獲利與生 !己屬;J樣ί乃一趨勢,故碳鋼及不銹鋼混合生產之工 因不銹鋼之生產過程需加入貴重金屬如 作中:ί氧=:1!貴重金屬於不錄鋼鐵水之機 作中曰與虱產生反應而成為Cr2 03、Ni0 份,故生產不銹鋼所產生之_ 马爐渣之4570984 V. Description of the invention (2) The furnace includes a plate-shaped electric furnace 80. The bottom edge of the electric furnace 80 is provided with a molten steel outlet 81, and the opening and closing system of the molten steel outlet 81 is blocked. Control of the plate 82: After the baffle 82 is drawn out, the carbon steel M in the electric furnace 80 is discharged from the mouth 81 and flows away-the preset steel drum _ eight I carbon steel 83 is effective The upper-floor furnace breaks the production Q and is separated, which greatly improves the refining quality of carbon steel. As the steel industry is becoming more and more competitive, in order to make a profit and live! It belongs to; J sample is a trend, so the production process of carbon steel and stainless steel due to the production process of stainless steel needs to add precious metals such as: ί Oxygen =: 1! Precious metals react with lice in a machine that does not record molten steel to become Cr2 03 and Ni0, so the production of stainless steel _ horse furnace slag 4

Ni算)m“、二其所含貴重金屬(如Cr、 f)之口收逐成為重要課題,1該爐渣中貴重金 收率更係代表生產不銹鋼利潤之重要指標。、一 然,生產不銹鋼所伴隨之爐渣其^ 時,需有與不錄鋼鐵水攪拌混人之勒=丁貝重金屬回收 用,而EBT出鋼式電濟因之動力才能達其還原效 /、有不錄鋼鐵水與爐渣之攪#、、曰八你田而 無法有效將爐渣中之貴重全屬;;見拌此6作用,而 屬之回收而將現行普遍使用J二回收。而若考慮貴重金 壺式電弧爐(具有鋼水與電爐更改為傳統 對業者造錢大設備經、^壓;1,傾因倒3混合之功能),更將 遍使用之EBT出鋼式電爐解決盆生產因如何針對目前普 收之困難問題’進而開發出 鱗鋼時貴重金屬回 文具貝重金屬回收效益之Ni calculation) m ", two, the oral collection of precious metals (such as Cr, f) has become an important issue. 1 The yield of precious gold in the slag is an important indicator of the profit of stainless steel production. Yiran, the production of stainless steel When the accompanying slag is ^, it needs to be mixed with the non-recorded molten iron = Dingbei heavy metal recovery, and the power of EBT tapping type electric energy can reach its reduction effect. Furnace slag # ,, said that you can not effectively belong to the valuables in the slag; see the 6 role, and the recovery of the general use of the current J 2 recovery. And if you consider the precious gold pot electric arc furnace (It has the function of changing molten steel and electric furnace to traditional money-making equipment for the industry; 1, the function of pouring and mixing 3), and the EBT steel-type electric furnace will be used to solve the problem of basin production due to the current general income. Difficult problem ', and then developed the precious metal recycling benefits of heavy metals in stationery when scale steel

第5頁 57〇984 五、發明說明(3) =法,誠是業者應努力研發、突破之重點方向。 【發明之概述】 本务月之主要目的在於提供一 時,能有效將其爐涪中鋼式電爐在生產不錄銅 解決EBT出鋼式電焯—生' 金屬加以還原回收,而徹底 本發明Λ Λ在= 鋼爐渣金屬回收方法iϋ,、—種ΕΒΤ出鋼式電爐不鱗 指貴重金屬之缺㉟,且其貴重金屬之回收 夏;ίη 電弧爐應用於不銹鋼生產之方式,而 具有積極提升經濟效益之功效。 ^ 爐出ί:下i::::f ϊ術特徵係先將-盛鋼桶置於電 = f之盛鋼桶移至相對該電爐鋼水出口之下 入該盛鋼2中,水出口而使不銹鋼鐵水從該鋼水出口洩流 錄鋼i水、f ❿t於該盛鋼桶已預先盛有爐渣,故當不 而使兮愤嗜:而I%將與該爐渣產生衝擊式之攪拌混合, 如― > 如 02+4〇 作用,*心2〇3 + 择作古本成叮丄 Lr2〇3 +3C-— — >3c〇 +2Cr ;藉此 : /可達到生產不銹鋼所伴隨之爐涪A中貴重全屬 如Cr、Ni等還;f古对专门& "皿座八τ貝里至屬 *銦切:Γ: 之功效,而徹底解決現行ebt 錄鋼時其爐渔中貴重金屬難以回收之嚴 為使本發明之目的、技術特徵及其他功效有進一步的Page 5 57〇984 V. Description of the invention (3) = law, sincerity is the key direction for industry players to strive for R & D and breakthrough. [Summary of the invention] The main purpose of this month is to provide a one-time, can effectively reduce the steel in the furnace electric furnace in the production of copper does not record EBT tapping-type electric steel-raw 'metal recovery and recovery, and thoroughly the invention Λ Λ in = steel slag metal recovery method i, a kind of ΕΒΤ steel-type electric furnace does not refer to the lack of precious metals, and the recovery of precious metals; ίη the application of electric arc furnace to stainless steel production, and has a positive economic improvement Benefits. ^ Furnace ί: 下 i :::: f The technique feature is to first place the -Steel drum in electricity = f the Sheng steel drum and move it below the electric furnace molten steel outlet into the Sheng Steel 2, the water outlet The stainless steel molten iron is discharged from the molten steel outlet to record the molten steel i, f❿t in the steel ladle, which has slag in advance, so it will not make you angry: I% will have an impact with the slag. Stir and mix, such as ― > Act as 02 + 4〇, * Heart 203 + can be selected as the ancient version of Ding Dong Lr2〇3 + 3C --- > 3c〇 + 2Cr; by this: / can reach the production of stainless steel Accompanied by all the valuables in furnace A such as Cr, Ni, etc .; F ancient to special & " pedestal eight τ berry to belong to * indium cut: Γ :, and completely solve the current ebt recording steel its The difficulty of recovering precious metals in furnace fishing is to further improve the purpose, technical characteristics and other effects of the present invention.

第6頁 570984 五、發明說明(4) 了解’絲配合圖示詳細說明如下: 【實施說明】 =閱第3圖,本發明EBT出鋼式電爐不錢鋼 回收方法’其所應用之EBT出鋼式電爐包括有金屬 支撐裝置20及連動裝置30,該電爐1〇上方設有上笔-11 ’該上蓋裝置i i上係設有電擊棒及相關通道設;: 熔化廢鐵金屬,該電爐10 一側之底緣係設有— 及作業口13,該鋼水出口12處係設有一檔板“,用以二 該鋼水出口12之啟閉,而該作業口13係可作為爐、、查出二, 而該鋼水出口12及作業口13之下方係分別為—盛鋼桶位置 A及爐渣桶位置B,其中該盛鋼桶位置A係可置放一盛鋼桶 40 γ而該電爐10經電熔操作後,其内係具有不銹鋼鐵水15 及浮於上層之爐渣16。該支撐裝置2〇係包括有一設於該電 爐10底緣之支撐架21及與該支撐架21齒動連結之齒動^構 22 ;而該連動裝置30係連結於該電爐1〇底源之支撐架21, 用以進行該電爐1 〇傾斜之操作。 繼請參閱第4、5圖,本發明應用於生產不銹鋼鐵水i 5 時’其爐渣1 6中之貴重金屬回收還原之操作方法如下: 1 ·將該盛鋼桶40置於相對該電爐丨〇出渣口丨3之一側 (即該爐渣桶位置B),啟動該連動裝置3〇使該電爐1〇依該 支撐裝置20轉動而傾斜。 2 ·將該爐渣1 6倒入該盛鋼桶4 0中,繼而回復該電爐1 〇 之原先位置狀態。 3.將該盛有爐渣1 6之盛鋼桶4 0移至相對該電爐1 〇鋼水Page 6 570984 V. Description of the invention (4) Understand the detailed description of the "wire matching diagram" as follows: [Implementation Note] = Please refer to Figure 3, the EBT tapping type electric furnace stainless steel recycling method according to the present invention and its applied EBT output The steel-type electric furnace includes a metal supporting device 20 and a linkage device 30. The electric furnace 10 is provided with a pen -11 '. The upper cover device ii is provided with an electric stun rod and related passages; A bottom edge on one side is provided with—and an operating port 13—a baffle plate 12 is provided at the molten steel outlet 12 for opening and closing the molten steel outlet 12. The operating port 13 can be used as a furnace, Check two, and the lower part of the molten steel outlet 12 and the operation port 13 are respectively-the ladle position A and the slag barrel position B, where the ladle position A can place a ladle 40 γ and the After the electric furnace 10 is electrofused, it has stainless steel molten iron 15 and slag 16 floating on the upper layer. The supporting device 20 includes a supporting frame 21 provided at the bottom edge of the electric furnace 10 and teeth of the supporting frame 21. Dynamically linked teeth move structure 22; and the linkage device 30 is connected to the support of the electric furnace 10 source 21. It is used to perform the operation of tilting the electric furnace 10. Following referring to Figs. 4 and 5, when the present invention is applied to the production of stainless steel molten iron 5, the operation method of recovering and reducing precious metals in its slag 16 is as follows: 1 Place the steel bucket 40 on one side of the electric furnace 丨 0 slag outlet 丨 3 (ie, the slag bucket position B), start the linkage device 30, and make the electric furnace 10 tilt according to the support device 20 rotation 2 · Pour the slag 16 into the steel bucket 40, and then return to the original position of the electric furnace 10. 3. Move the steel bucket 40 containing the slag 16 to the electric furnace 1 〇 Molten steel

570984570984

五、發明說明(5) 出口 12之下方(即該盛鋼桶位置A )。 4 ·將該擋板1 4抽出以開啟該鋼水出口 1 2,並使該不產秀 鋼鐵水1 5從該鋼水出口 1 2洩流入該盛鋼桶4 〇中。 由於該盛鋼桶4 0已預先盛有該爐渣1 6,故當該不鱗麵 鐵水1 5洩流而下時將與該爐渣1 6產生衝擊式之授掉混人 而使該爐渣1 6中之貴重金屬得以產生還原作用,如 2Cr2 03 + 3Si >3Si02 + 4Cr Cr2 03 + 3C----->3C0 +2Cr 法,藉該盛鋼桶 該盛有爐渣之盛 以進行不銹鋼鐵 生產不錄鋼之爐 收之功效,而徹 爐渣貴重金屬難 之貴重金屬回收 產不錄鋼以回收 盈之功效。 綜合上述, k出專利申請。 舉凡熟悉本案技 效修飾或變化, 【圖式符號說明 90 電弧爐 明EBT出鋼式電爐不銹鋼爐渣金屬回收方 先置放該爐渣桶位置而盛置爐渣後,再將 鋼桶移至鋼水出口 1 2下方之盛鋼桶位置, 水15衝擊攪拌混合之操作方式,確可達到 渣中其貴重金屬如Cr、…等還原高效率回 底解決現行EBT出鋼式電爐生產不銹鋼其 以回收之嚴重缺點;且本發明該操作方法 f標甚至更優於利用傳統壺式電弧爐來生 貴重金屬之方式,而具有積極提升經濟效 本發明確已符合發明專利之要件,爰依法 =’以上所述僅為本發明之較佳實施二’, 右之人士援依本發明之發明精神所 皆應涵蓋在本申請專利範圍内。 、5. Description of the invention (5) Below the outlet 12 (that is, the position A of the steel ladle). 4 · Draw out the baffle 14 to open the molten steel outlet 12 and let the non-produced molten steel 15 leak from the molten steel outlet 12 and flow into the steel ladle 40. Since the steel bucket 40 already contains the slag 16 in advance, when the non-scaly hot metal 15 leaks down, it will cause impact mixing with the slag 16 to make the slag 1 The precious metals in 6 can be reduced, such as 2Cr2 03 + 3Si > 3Si02 + 4Cr Cr2 03 + 3C ----- > 3C0 + 2Cr method, the steel drum should be filled with slag for stainless steel Iron production does not record the effects of steel collection, while the recovery of precious metals, which are difficult to slag precious metals, does not record steel to recover the profit. To sum up, k patent applications. For example, if you are familiar with the modification or change of the technical effect of this case, [Schematic symbol description 90 EBT EBT tapping type electric furnace stainless steel slag metal recovery side first put the slag bucket position and hold the slag, then move the steel bucket to the molten steel outlet 1 2 The position of the steel drum below 2 and the operation mode of 15 water stirring and mixing can indeed achieve the high-efficiency reduction of the precious metals such as Cr, ... in the slag. Disadvantages; and the standard f of the operation method of the present invention is even better than the traditional pot-type electric arc furnace for generating precious metals, and has a positive economic efficiency. The present invention has indeed met the requirements of the invention patent, according to the law = 'the above It is only the preferred implementation of the present invention 2 ', and anyone who is right to rely on the spirit of the present invention should be covered by the scope of this application patent. ,

570984 五、發明說明(6) 91 電極棒 92 作業口 93 出鋼口 94 碳鋼鐵水 95 爐渣 96 渣桶 97 盛鋼桶 80 電爐 81 鋼水出口 82 擋板 83 碳鋼鐵水 84 盛鋼桶 85 爐渣 10 電爐 20 支撐裝置 30 連動裝置 11 上蓋裝置 12 鋼水出口 13 作業口 14 擋板 A 盛鋼桶位置 B 爐渣桶位置 15 不錄鋼鐵水 16 爐渣570984 V. Description of the invention (6) 91 Electrode rod 92 Working port 93 Steel outlet 94 Carbon molten steel 95 Slag 96 Slag bucket 97 Steel drum 80 Electric furnace 81 Steel water outlet 82 Baffle 83 Carbon steel 84 Steel drum 85 Slag 10 Electric furnace 20 Support device 30 Linkage device 11 Cover device 12 Molten steel outlet 13 Working port 14 Baffle A Ladle position B Slag barrel position 15 No molten steel 16 Slag

570984570984

第ίο頁 570984 圖式簡單說明 第1圖係傳統壺式電弧爐之操作示意圖。 第2圖係習知EBT出鋼式電爐之操作示意圖。 第3圖係本發明所應用之EBT出鋼式電爐示意圖。 第4圖係本發明之操作方法示意圖一。 第5圖係本發明之操作方法示意圖二。 1 ίϊΐ ϊPage ί 570984 Brief description of the drawings Figure 1 is a schematic diagram of the operation of a traditional pot-type electric arc furnace. Figure 2 is the operation diagram of the conventional EBT tapping electric furnace. Fig. 3 is a schematic diagram of an EBT tapping type electric furnace applied in the present invention. FIG. 4 is a first schematic view of the operation method of the present invention. Figure 5 is the second schematic diagram of the operation method of the present invention. 1 ίϊΐ ϊ

Claims (1)

570984 六 、申請專利範圍 、一種ΕΒΐ 出 _ ' ΕΒΤ出鋼式電爐^生^不不錄鋼爐士渣金屬回收方法,係藉一 收’其包括有下列步驟:化進行貴重金屬之還原回 a·將該ΕΒτ屮細』Α上 b.繼將不銹鋼、Λ Λ内之产渣傾倒入一盛鋼桶中; 該不銹鋼鍇k 1 Ζ :入5亥盛有爐渣之盛鋼桶内,以使 混合作用哉水與該盛鋼桶内之爐逢產生衝擊式之授拌 2、 如申請專利範圍第1項所述之EBT出鋼式電爐不銹鋼爐 產金屬回收方法,其中進行該步驟b前,先將該EBT出鋼 式電爐回復至原先狀態。 3、 如申請專利範圍第i項所述之EBT出鋼式電爐不銹鋼爐 渣金屬回收方法,其中進行該步驟b前,先將該盛有爐 渣之盛鋼桶移至該EBT出鋼式電爐之一鋼水出口下方。 4、 如申請專利範圍第}項戶斤述之EBT出鋼式電爐不銹鋼爐 渔金屬回收方法,其中進行該步驟匕前,先將該ΕΒΤ出鋼 式電爐之鋼水出口開啟。570984 VI. Scope of patent application, a kind of ΕΒΐ _ _ ΕΒΤ steel-type electric furnace ^ ^ ^ non-recorded steel furnace metal slag metal recovery method, borrowing a collection ', which includes the following steps: chemical conversion of precious metals back to a · The ΕΒτ 屮 细 "A on b. Continue to pour the slag produced in stainless steel and Λ Λ into a steel drum; The stainless steel 锴 k 1 Zn: into a steel drum with slag in 5 Hai, so that The mixing action of simmering water and the furnace inside the steel drum produces an impact type of mixing 2. As described in the item 1 of the scope of the patent application, the metal recovery method of the stainless steel furnace of the EBT tapping type electric furnace, before performing step b, The EBT tapping electric furnace is restored to its original state. 3. According to the method of recovering stainless steel slag metal from an EBT tapping electric furnace described in item i of the scope of the patent application, before performing step b, the steel bucket containing the slag is moved to one of the EBT tapping electric furnaces. Below the molten steel outlet. 4. The method for recovering fishery metals from the stainless steel furnace of the EBT tapping type electric furnace described in item} in the scope of the patent application, wherein before carrying out this step, the molten steel outlet of the EBT tapping type electric furnace is opened.
TW91110442A 2002-05-17 2002-05-17 Method for recovering stainless steel slag from EBT steel-discharging-type electric furnace TW570984B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI602924B (en) * 2013-08-31 2017-10-21 Daido Steel Co Ltd Electric arc furnace
CN118089403A (en) * 2024-04-26 2024-05-28 山西臻世锦节能科技有限公司 Reduction furnace for comprehensively modifying steel slag, equipment and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI602924B (en) * 2013-08-31 2017-10-21 Daido Steel Co Ltd Electric arc furnace
CN118089403A (en) * 2024-04-26 2024-05-28 山西臻世锦节能科技有限公司 Reduction furnace for comprehensively modifying steel slag, equipment and method

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