TW567148B - Ballpoint pen using water based ink - Google Patents
Ballpoint pen using water based ink Download PDFInfo
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- TW567148B TW567148B TW091104178A TW91104178A TW567148B TW 567148 B TW567148 B TW 567148B TW 091104178 A TW091104178 A TW 091104178A TW 91104178 A TW91104178 A TW 91104178A TW 567148 B TW567148 B TW 567148B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K7/00—Ball-point pens
- B43K7/005—Pen barrels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K7/00—Ball-point pens
- B43K7/02—Ink reservoirs; Ink cartridges
- B43K7/08—Preventing leakage
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K7/00—Ball-point pens
- B43K7/10—Arrangements for feeding ink to the ball points
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- Pens And Brushes (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
經濟部智慧財產局員工消費合作社印製 567148 μ ________ Β7 五、發明説明(d 發明範圍 本發明係關於一種使用水基墨水的原子筆。更特定言 之’本發明係關於一種使用假塑性水基墨水的原子筆。 先前技藝 關於利用如下原子筆尖之使用水基墨水的原子筆,其 中筆尖是藉由放入金屬薄管,並在一黏稠點強力地使之向 內變形,以形成一球接收座之向內突出部份,然後向內塡 塞住該點之間隙邊緣而製得;有些提案業以揭示(日本專 利特許公開申請案第7 - 2 9 9 9 8 8案號,等)。 然而,由於這些利用金屬薄管之使用水基墨水的原子 筆,是使用油脂性向後滲漏防止劑,所以會有某些問題, 即防止向後滲漏之效果並不安全,而且當筆尖向上放置時 會漸漸引起向後滲漏,甚而在平常書寫的情況下,亦即筆 尖是向下的,其防止向後滲漏之油脂在墨水消耗的同時將 粘附並殘留在貯墨水管內壁,藉此於書寫期間防止向後滲 漏之油脂終將缺乏而致墨水向後滲漏。除此之外,若裝塡 很多油脂以使向後滲漏防止劑不虞匱乏時,墨水的流出將 大大地減少,因此,在比平常速度快兩倍以上的快速書寫 時,就會導致斷水。 而且,在未使用具有切剪稀釋特性之墨水的情況中, 若合適的黏度値可控制以使墨水在未書寫期間不會從筆端 滴落時,晝線時引起的分裂及斷水就很容易發生。相反地 ,若墨水之黏度値在書寫時係視爲重要的,其在未書寫時 本紙張尺度適用中國國家標準(CNS ) A4規格(2]0〆297公缝") ^ 裝 Ί n 訂 II 级 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 567148 A7 B7_ 五、發明説明(2) 墨水便易於滴落,所以,想維持平穩的品質將變得非常困 難。 於是,本申請人提供在原子筆尖與貯墨水管之間使用 一具有檢查閥機制的接頭,並提供使用具有切剪稀釋特性 之墨水,以便完全地防止如上所述使用水基墨水的原子筆 時墨水的向後滲漏((日本專利特許公開申請案第8 -230374案號)。 然而,根據稍後之硏究卻有些問題,即引用此防止向 後滲漏閥機制之原子筆其一般性的墨水向後滲漏雖可有效 防止,但當原子筆掉落時來自貯墨水管後端的墨水散開就 無法防止。縱使在貯墨水管後面部份已裝備慣用之由油脂 製成的墨水從動件,以及具有檢查閥機制的接頭,此情況 也沒有改善。而且,當使用已知之由油脂製成的墨水從動 件,快速書寫時墨水的隨動性也很差。再者,對此類使用 水基墨水的原子筆而言,尙無法成功地提供符合原子筆原 本應有的所有其他需求,如書寫的觸感、墨水的流出量、 濺污、劃線的羽毛邊、墨水流出量的穩定性及源於輕微撞 擊的斷水。 眾所皆知,沃斯田不銹鋼S U S 3 0 4係用做爲慣用 筆尖所屬之金屬薄管材料。SUS304材料的碳含量乃 定爲0. 08%或更少,典型地是大於或等於〇.〇3% 。.然而,本發明人頃發現到一問題即,由碳含量〇 . 〇 3 %或更高之材料所製造的球接收座將易於因書寫時(若使 用顏料做爲著色劑時)接收座的磨損而使球沉入。 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公楚 1 ^ ' ~ L-------- 1¾衣----Ί--、玎------^ (請先閲讀背面之注意事項再填寫本頁) 經濟部智慈財產局員工消f合作社印製 567148 A7 B7 _ 五、發明説明(3) 本發明的目標係解決上述問題,並提供一種使用水基 墨水的原子筆,輕微碰觸即能平順地書寫,並且幾乎不會 發生濺污及分裂,在比一般速度快二或多倍的書寫速度下 也不會發生斷水,其穩定的墨水流出量能持續到最後,縱 使筆尖向上直立且筆帽卸下時墨水一點也不會向後滲漏。 發明摘述 本發明係提供下列之原子筆以解決上述問題。 (1 ) 一種使用水基墨水的原子筆,其包含: 一藉由形成球屋所製得之原子筆尖,其是在金屬薄管 的端點附近經由向內擠壓變形以形成球接受座的向內突出 部份並把成品切下,然後於該球屋中放入一球使之向內塡 塞住該端點的間隙邊緣而組合成; 一貯墨水管; 一連接該原子筆尖與該貯墨水管之接頭,此接頭具有 防止墨水向後滲漏機制,其包括塞子及接收座; 假塑性水基墨水,其黏度在剪切速率3 8 . 4 sec-1下是20至600 m Pa · sec:,而在剪切速 率 384sec 一 1 (25t)下是 1〇 至 i2〇mPa · s e c ;以及 一墨水從動件,其是裝塡在貯墨水管中墨水的後端, 並且角周率在0 · 1至650弧度/秒(rad/sec )的整個範圍內,其正切(5 ( t a η (5 )値的模數是 0.2 至 2.0(25 1)。 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X 297公釐)~~'Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 567148 μ ________ B7 V. Description of the invention (d. Scope of the invention The invention relates to a ball pen using water-based ink. More specifically, the invention relates to a method using pseudoplastic water-based A ballpoint pen for ink. The previous technique used a ballpoint pen using water-based ink using the following ballpoint pen tip, in which the pen tip was placed in a thin metal tube and strongly deformed inwardly at a sticky point to form a ball receiver. It is made by protruding the seat inward, and then plugging the gap edge of the point inward; some proposals have been disclosed (Japanese Patent Laid-open Application No. 7-2 9 9 9 8, etc.). However, since these water-based ink ball pens using thin metal tubes use a grease-based backward leakage preventive agent, there are some problems, that is, the effect of preventing backward leakage is not safe, and when the pen tip is placed upward It will gradually cause backward leakage, even in the case of ordinary writing, that is, the pen tip is downward, which prevents the backward leakage of grease while the ink is consumed. Adheres and remains on the inner wall of the ink storage tube, thereby preventing the backward leakage of oil during writing and eventually causing the ink to leak backward. In addition, if a lot of grease is installed to prevent the backward leakage preventive agent When it is scarce, the outflow of ink will be greatly reduced, so it will cause water cut-off when writing at a speed that is more than twice as fast as normal. Also, if the ink with cutting-thinning characteristics is not used, if appropriate The viscosity 値 can be controlled so that when the ink does not drip from the pen end during unwriting, the splitting and water breakage caused by daylight are easy to occur. On the contrary, if the viscosity 墨水 of the ink is considered important when writing , Its paper size applies to Chinese National Standard (CNS) A4 specification (2) 0〆297 cm ") when not writing ^ Decoration n Order II (please read the precautions on the back before filling this page) Economy Printed by the Consumer Cooperatives of the Ministry of Intellectual Property Bureau 567148 A7 B7_ V. Description of the invention (2) The ink is easy to drip, so it will be very difficult to maintain a stable quality. Therefore, the applicant provided the ballpoint pen tip A joint with a check valve mechanism is used between the ink storage tubes, and the ink with cutting-thinning characteristics is provided to completely prevent the backward leakage of the ink when using a water-based ink ball pen as described above ((Japanese Patent License Published application No. 8-230374). However, according to the later research, there are some problems, that is, the general pen backward leakage of the ballpoint pen using this mechanism to prevent the backward leakage valve mechanism can effectively prevent, but When the ball pen is dropped, the ink from the rear end of the ink storage tube cannot be prevented from spreading out. Even if the conventional ink follower made of grease and the joint with a check valve mechanism are equipped on the rear part of the ink storage tube There is no improvement. Moreover, when using a known ink follower made of grease, the ink's followability is poor when writing quickly. Furthermore, for this type of ball-point pen using water-based ink, 尙 cannot successfully provide all the other requirements that the ball-point pen should have, such as the feel of writing, the amount of ink flowing out, splashing, and lined feathers. The stability of the edge, the amount of ink outflow, and the water cutoff from slight impact. It is well-known that Vostian stainless steel S U S 304 is used as a thin metal tube material to which a conventional nib belongs. The carbon content of the SUS304 material is set to 0.08% or less, and is typically greater than or equal to 0.03%. However, the present inventors have discovered that a ball receiving seat made of a material having a carbon content of 0.03% or more will be easily affected by the receiving seat when writing (if a pigment is used as a colorant). Worn and sink the ball. This paper size applies to China National Standard (CNS) A4 specifications (210X297) 1 ^ '~ L -------- 1¾ clothing ---- Ί--, 玎 ------ ^ (Please Read the notes on the back before filling in this page) Printed by the staff of the Intellectual Property Office of the Ministry of Economic Affairs and printed by the cooperative 567148 A7 B7 _ V. Description of the invention (3) The object of the present invention is to solve the above problems and provide a water-based ink The ballpoint pen can be written smoothly with a slight touch, and almost no splattering and splitting occur, and water will not break at a writing speed two or more times faster than the normal speed. Its stable ink flow can Continue to the end, even if the pen tip is upright and the cap is removed, the ink will not leak back at all. SUMMARY OF THE INVENTION The present invention provides the following ball pens to solve the above problems. (1) A ball pen using water-based ink, It includes: an atomic pen tip made by forming a ball house, which is deformed by pressing inward near the end of a thin metal tube to form an inwardly protruding portion of a ball receiving seat and cutting the finished product, and then Put a ball in the ball house so that it plugs inward An ink storage tube; a joint connecting the atomic pen tip and the ink storage tube, which has a mechanism for preventing ink from leaking backwards, including a plug and a receiving seat; a pseudoplastic water-based ink, its viscosity 20 to 600 mPa · sec at a shear rate of 38.4 sec-1, and 10 to i20mPa · sec at a shear rate of 384sec-1 (25t); and an ink follower , Which is the rear end of the ink contained in the ink storage tube, and the angular rate is in the entire range of 0.1 to 650 radians / second (rad / sec), and its tangent (5 (ta η (5) 値The modulus is 0.2 to 2.0 (25 1). This paper size is applicable to the Chinese National Standard (CNS) Α4 size (210X 297 mm) ~~ '
Hr n I, n I 1— n n 1 m m m n !! I— T Hi---n ——I-----------1 (請先閲讀背面之注意事項再填寫本頁} 經濟部智慈財產局員工消費合作社印製 567148 A7 _ B7 五、發明説明(4) (2 )如第(1 )項所述之使用水基墨水的原子筆, 其中該假塑性水基墨水的表面張力係3 2 m N /m或更少 (2 5 °C )。 (3 )如第(1 )或(2 )項所述之使用水基墨水的 原子筆,其中該墨水從動件的黏度在剪切速率2 〇 〇 sec-1 及 25°C 下是 500 至 8,OOOmPa · s e c 〇 (4 )如第(1 )至(3 )項中任一項所述之使用水 基墨水的原子筆,其中該原子筆尖的金屬薄管係由碳含量 小於0 · 0 3 %之沃斯田不銹鋼所製成。 圖之簡略說明 圖1 ·是如本發明實施例之一,使用水基墨水之原子 筆其主要部份的縱向截面圖,此圖係顯示筆尖向下的狀態 〇 圖2 .是如本發明實施例之一,使用水基墨水之原子 筆其主要部份的縱向截面圖,此圖係顯示筆尖向上的狀態 〇 圖3 ·是如本發明實施例之一,使用水基墨水之原子 筆其主要部份的縱向截面圖。 圖4·是圖3·A-A部份的橫切面圖。 元件對照表 A:A — A段 1:原子筆尖 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) IT I I I ϋ I I L/ Ki - —i I I 1· _ T n _ _ _ n _ 良 0¾ . TP 繞 (請先閲讀背面之注意事項再填寫本頁) 567148 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明説明(7) 接收座2 5的防止向後滲漏機制。在此方式中,雖然接頭 具有塞子可防止向後滲漏,但較佳地該防止向後滲漏機制 應包括金屬球及接收座,如此墨水從貯墨水管後端沿著插 銷3 1方向滲漏的現象就可防止,甚而書寫時筆身向上直 立且筆帽卸下所引起的向後滲漏現象也可防止。 在如圖所示之實施例的接頭2 2中,原子筆尖1係緊 壓地嵌入接頭前端,而接收元件2 1則緊壓地嵌入接頭後 端,並且貯墨水管1 0是緊壓地嵌入該接頭後端旁側的外 部。此接頭2 2及接收元件2 1之主體可由具彈性可變形 之合成樹脂製造。 再者,閥室2 3係放置於接頭2 2的中段部位,而該 可防止向後滲漏之塞子2 0則寬鬆地接合於該閥室中。塞 子2 0是由比重大於墨水1 1之可移動塞子所組成。較佳 .地,金屬球是不銹鋼球。由於突出物2 4是於閥室2 3前 側邊形成,當筆尖側面向下時,球塞子2 0將鎖住突出物 2 4,而墨水可從突出物之間流入在原子筆尖1中的墨水 進料路徑6內,藉此就可書寫了。 除此之外,由於錐形或球形接收座2 5係提供在該緊 壓地嵌入接頭2 2後端的接收元件2 1前側邊;所以當筆 尖側面向上時,塞子2 0將與接收座緊密地接觸以便封住 墨水,如此墨水就不會向後滲漏,縱使是向上書寫,球2 下面的墨水用盡時亦然。 (墨水) ---------^卜裝-- (請先閲讀背面之注意事項再填寫本頁) 、11 線 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) ;10: 567148 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明説明(8) 用於如本發明之使用水基墨水的原子筆,其墨水係一 假塑性水基墨水,其黏度在剪切速率3 8 . 4 s e c — 1下 是20至600 m Pa · sec,而在剪切速率384 sec-1 (25 °C)下是 10 至 120 m Pa · sec , 較佳地,在剪切速率38 · 4 s e c—1下是5 0至3 5 0 mPa· sec ,而在剪切速率384sec一 )下是1 5至8 OmPa · s e c。經由使用如上所特定 之假塑性水基墨水,剪切力將經由原子筆(其中該筆尖係 由金屬製得)書寫時,筆尖點球的旋轉而施加到墨水上以 減低墨水黏度,如此,像使用水基墨水之一般原子筆一樣 平滑地書寫就變得可行,進而在紙面上產生優秀的字體。 而且,由於墨水在不書寫時黏度很高,墨水從筆端點的濺 污便可防止,如此,墨水就可直接裝入貯墨水管中,筆的 構造也可簡化,而且墨水剩餘量也可藉由貯墨水管所用之 透明物質而觀察到。若黏度在剪切速率38 . 4 s e c·1 下超過600 m Pa · sec或是在剪切速率384 s e c_1下是1 20mPa · s e c時,在比平常速度快 二或多倍的書寫速度下墨水的隨動性將會惡化。再者,劃 線分裂(劃線時會分裂成多線條的現象)及濺污等也較容 易引起。另一方面,若黏度在剪切速率38 · 4 s e c — 1 下小於2〇mPa · sec或在剪切速率384sec 一1 下小於1 0 m P a · s e c時,來自筆端點的墨水濺污便 易於引起,且劃線時更易於弄污而不淸楚。 而且,藉由將假塑性水基墨水的表面張力限定在3 2 本紙張尺度適用中國國家標準(CNS ) A4規格(2】〇Χ297公H * (請先閱讀背面之注意事項再填寫本頁) -裝- 訂 線 567148 A7 B7 五、發明説明(d 基纖維素、竣甲基纖維素之鈉鹽、阿拉伯膠、蟲膠之鹼鹽 、聚氧化乙燃、藻蛋白酸鈉、黃蓍膠、瓜爾膠( guar gum ) 、刺梧桐樹膠,等。 供本發明所用之水基墨水的著色劑包括所有可溶於或 分散於水中之染料、二氧化鈦及所有已知之無機和有機顏 料、藉用染料及白色塑性顏料使樹脂乳化液染色所製備之 假顏料。如特定之實施例,染料包括酸性染料如曙紅、焰 紅、水黃# 6 - C、酸性紅、水藍# 1 〇 5、亮藍F C F 、尼格NB,直接染料如直接黑154、直接天藍5B、 紫BB,鹼性染料如若丹明及甲基紫。舉例之,無機顏料 包括碳黑、金屬粉。有機顏料包括偶氮湖、不可溶偶氮顏 料、螯合偶氮顏料、酞菁顏料、茈顏料、橘黃顏料、蒽n 顏料、奎吖啶酮顏料、染料湖、硝基顏料、亞硝基顏料。 特定而言,彼等還包括無機顏料如碳黑、鈦黑、氧化鋅、 紅氧化鐵、三氧化鉻、黑氧化鐵、鈷藍、黃氧化鐵、鉻綠 、硫化鋅、鋅鋇白、鎘黃、銀硃、鎘紅、鉻黃、鉬酸鹽橘 、鉻酸鋅、鉻酸緦、白碳、黏土、滑石、群青、沉澱之硫 酸鋇、重晶石粉、碳酸鈣、、白鉛、普魯士藍、錳紫、錦 粉、黃銅粉、C · I ·顏料藍1、c _ I ·顏料藍1 5、 C· I .顏料藍17、C· I ·顏料藍27、C· I ·顏 料紅5、C · I ·顏料紅2 2、C · I ·顏料紅3 8、 C · I .顏料紅4 8、C . I ·顏料紅4 9、C . I ·顏 料紅5 3、C · I ·顏料紅5 7、C · I ·顏料紅8 1、 C · I ·顏料紅1 〇 4、C · I ·顏料紅1 4 6、 L-----------^裝-- (請先閱讀背面之注意事項再填寫本頁)Hr n I, n I 1— nn 1 mmmn !! I— T Hi --- n ——I ----------- 1 (Please read the notes on the back before filling this page} Economy Printed by the Employees' Cooperative of the Ministry of Intellectual Property Bureau 567148 A7 _ B7 V. Description of the invention (4) (2) The ball-point pen using water-based ink as described in item (1), wherein the surface of the pseudoplastic water-based ink is The tension is 3 2 m N / m or less (2 5 ° C). (3) A ball pen using water-based ink as described in item (1) or (2), wherein the viscosity of the ink follower 500 to 8, 000 mPa · sec at a shear rate of 2000 sec-1 and 25 ° C (4) Atoms using water-based inks as described in any one of items (1) to (3) Pen, wherein the thin metal tube of the atomic pen tip is made of Vostian stainless steel with a carbon content of less than 0.33%. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is one of the embodiments of the present invention. A longitudinal cross-sectional view of the main part of the ball pen, this figure shows a state where the pen tip is downward. FIG. 2 is a longitudinal cross-sectional view of the main part of the ball-point pen using water-based ink as one of the embodiments of the present invention. Shows the state of the pen tip upwards. Fig. 3 is a longitudinal sectional view of a main part of a ball pen using water-based ink as one of the embodiments of the present invention. Fig. 4 is a cross-sectional view of Fig. 3AA. Component comparison table A: A — A: 1: Paper size of ballpoint pen tip is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) IT III ϋ IIL / Ki-—i II 1 · _ T n _ _ _ n _ Good 0¾. TP winding (please read the precautions on the back before filling this page) 567148 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (7) Receiving seat 2 5 The mechanism for preventing backward leakage. In this method, although the joint has a plug to prevent backward leakage, preferably the mechanism for preventing backward leakage should include a metal ball and a receiving seat, so that the ink leaks from the rear end of the ink storage tube in the direction of the bolt 31. It can prevent even the backward leakage caused by the pen body standing upright and the cap removed when writing. In the connector 2 2 of the embodiment shown in the figure, the ballpoint pen tip 1 is tightly pressed into the front end of the connector. And the receiving element 21 is pressed It is embedded in the rear end of the joint, and the ink storage tube 10 is tightly embedded in the outside of the side of the rear end of the joint. The main body of the joint 22 and the receiving element 21 may be made of a synthetic resin having elastic deformation. Further, the valve The chamber 23 is placed in the middle part of the joint 22, and the plug 20 for preventing backward leakage is loosely engaged in the valve chamber. The stopper 20 is composed of a removable stopper having a larger specific gravity than the ink 1 1. Preferably, the metal ball is a stainless steel ball. Since the protrusion 24 is formed on the front side of the valve chamber 23, when the side of the pen tip is downward, the ball plug 20 will lock the protrusion 24, and the ink can flow into the ballpoint 1 from between the protrusions. In the ink feed path 6, writing is possible. In addition, since the conical or spherical receiving seat 2 5 is provided at the front side of the receiving element 2 1 which is tightly fitted into the rear end of the joint 2 2; when the pen tip side is upward, the plug 20 will be tight with the receiving seat Touch the ground to seal the ink so that the ink does not leak backwards, even when writing up, the ink under the ball 2 runs out. (Ink) --------- ^ 卜 装-(Please read the precautions on the back before filling this page), 11-line paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) ); 10: 567148 Printed by A7 B7, Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (8) Ballpoint pen used for water-based ink as in the present invention, the ink is a pseudoplastic water-based ink, its viscosity 20 to 600 mPa · sec at a shear rate of 38.4 sec-1, and 10 to 120 mPa · sec at a shear rate of 384 sec-1 (25 ° C), preferably at At a shear rate of 38 · 4 sec-1, it is 50 to 350 mPa · sec, and at a shear rate of 384 sec-1), it is 15 to 8 OmPa · sec. By using a pseudo-plastic water-based ink as specified above, the shearing force will be applied to the ink to reduce the viscosity of the ink by writing the ballpoint pen (where the nib is made of metal) to the ink to reduce the viscosity of the ink. It is possible to write smoothly with water-based ink like a general ballpoint pen, and then produce excellent fonts on paper. In addition, because the ink has a high viscosity when not writing, the ink splashing from the pen end point can be prevented. In this way, the ink can be directly filled into the ink storage tube, the structure of the pen can be simplified, and the remaining amount of ink can be borrowed. Observed by the transparent substance used in the ink storage tube. If the viscosity exceeds 600 m Pa · sec at a shear rate of 38.4 sec · 1 or 1 20 mPa · sec at a shear rate of 384 se c_1, the ink is written at a writing speed two or more times faster than usual. The follow-up will deteriorate. In addition, line-splitting (split into multiple lines when scribing) and splashing are also more likely to be caused. On the other hand, if the viscosity is less than 20 mPa · sec at a shear rate of 38 · 4 sec — 1 or less than 10 m P a · sec at a shear rate of 384 sec-1, ink from the end of the pen will stain. It is easy to cause, and it is easier to be smudged without being confused when scribing. Moreover, by limiting the surface tension of the pseudoplastic water-based ink to 3 2 this paper size applies the Chinese National Standard (CNS) A4 specification (2) 0 × 297 male H * (Please read the precautions on the back before filling this page) -Packing- Thread 567148 A7 B7 V. Description of the invention (d-based cellulose, sodium methyl cellulose, acacia, alkali salt of shellac, polyethylene oxide, sodium alginate, tragacanth, Guar gum, sycamore gum, etc. The colorants for the water-based inks used in the present invention include all dyes that are soluble or dispersible in water, titanium dioxide and all known inorganic and organic pigments, borrowed dyes And white plastic pigments are fake pigments prepared by dyeing resin emulsions. As a specific example, dyes include acid dyes such as eosin, flame red, and water yellow # 6-C, acid red and water blue # 1 〇05, bright Blue FCF, Niger NB, direct dyes such as direct black 154, direct sky blue 5B, violet BB, basic dyes such as rhodamine and methyl violet. For example, inorganic pigments include carbon black and metal powder. Organic pigments include azo lake Insoluble azo pigment , Chelating azo pigments, phthalocyanine pigments, perylene pigments, orange pigments, anthracene pigments, quinacridone pigments, dye lakes, nitro pigments, and nitroso pigments. In particular, they also include inorganic pigments such as Carbon black, titanium black, zinc oxide, red iron oxide, chromium trioxide, black iron oxide, cobalt blue, yellow iron oxide, chrome green, zinc sulfide, zinc barium white, cadmium yellow, silver vermillion, cadmium red, chrome yellow, Molybdate orange, zinc chromate, europium chromate, white carbon, clay, talc, ultramarine, precipitated barium sulfate, barite powder, calcium carbonate, white lead, Prussian blue, manganese purple, bromide powder, brass powder , C · I · Pigment Blue 1, c _ I · Pigment Blue 1 5, C · I. Pigment Blue 17, C · I · Pigment Blue 27, C · I · Pigment Red 5, C · I · Pigment Red 2 2 , C · I · Pigment Red 3 8, C · I. Pigment Red 4 8, C. I · Pigment Red 4 9, C. I · Pigment Red 5 3, C · I · Pigment Red 5 7, C · I · Pigment Red 8 1, C · I · Pigment Red 1 〇4, C · I · Pigment Red 1 4 6, L ----------- ^ Pack-(Please read the precautions on the back first (Fill in this page)
、1T 線 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(21 Οχ 297公釐) -Ιό 567148 經濟部智慈財產局8工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(2!〇X297公釐) A7 B7 五、發明説明(y c · I ·顏料紅2 4 5、C · I ·顏料黃;[、c ·;[.顏 料頁3、C_ I·顏料黃12、c·丨·顏料黃13、 c.I,顏料頁i4、c.I·顏料黃17、c·I·顏 料頁34、C.I·顏料黃55、C·I·顏料黃74、 C·I·顏料黃83、c·I·顏料黃95、c·〗·顏 料頁166、C. I ·顏料黃167、C· I .顏料橘5 、C· 1 ·顏料橘 I3、c· I ·顏料橘 16、c,;[, 顏料紫1、C· I ·顏料紫3、c· I ·顏料紫;[9、 C_ I ·顏料紫23、C. I _顏料紫5〇、c.;[.顏 料綠7。 而且,著色劑之使用量可隨劃線的強度而適當地變化 ’較佳地是0 · 1至4 0重量%,相對於墨水總量。 再者,可摻入以增進書寫觸感及一段時間後之穩定性 的水溶性液體介質包括多元醇如丙二醇、甙油、聚乙二醇 、甙油之烯化氧加成物、及三羥基丙烷之烯化氧加成物以 及彼等之混合物。 除此之外,可摻入做爲潤滑劑及潤濕劑,以控制表面 張力並增進書寫觸感之表面活性劑包括聚氧化乙烯、氧化 乙烯-氧化丙烯之衍生物如氧化乙烯月桂基醚、甙油衍生 物、二甙油或聚甙油如四甙油基二硬脂酸酯、糖類衍生物 如山梨糖醇酐一油酸酯、具有氟化烷基之表面活性劑如全 氟烷基磷酸酯、聚醚-未變性矽酮如二甲基聚矽氧烷之聚 乙二醇加成物、硬化蓖麻油、磷酸酯基之表面活性劑、氟 基表面活性劑、鉀皂,等。 - I--------------Ί--1T------ (請先閱讀背面之注意事項再填寫本頁) 567148 Α7 Β7 經濟部智慧財1局P貝工消費合作社印說 五、發明説明(d 此外,相關於其他添加劑,可使用的有做爲顏料用分 散劑之水溶性聚合物如苯乙烯-馬來酸共聚物之銨鹽、苯 乙烯-丙烯酸共聚物之銨鹽,以及做爲防止物揮發質之主 要含有麥芽糖醇之還原糖、主要含有山梨糖醇之還原糖、 還原寡糖、還原之麥芽-寡糖、還原糊精、還原之麥芽一 糊精、α -環糊精、^ -環糊精、麥芽糖基環糊精,等。 若需要還可各別地使用苯駢三唑、皂草甙做爲防銹劑 ’及使用氫氧化鉀、磷酸鈣、胺甲基丙醇等做爲ρ Η調整 劑,以及啶化鈉、苯駢異噻唑啉等做爲防腐劑。 如本發明之原子筆所用之水基墨水可藉由一邊加熱( 右需要’可配合混合、擾泮及過漉)一邊溶解上述成份而 製得,若需要,可配合混合、攪拌及過濾。除此之外,相 較於其他原子筆所用之水基墨水的製備方法,並不需要特 別小心操作,而且只要攪拌溫度及過濾程序之條件是在原 子筆之水基墨水的實際範圍內,就沒有任何問題。 (墨水從動件) 可用於如本發明之使用水基墨水的原子筆之墨水從動 件係限制爲角周率在0 . 1至6 5 0弧度/秒(r a d / s e c )的整個範圍內,其t a η 5値(是表示爲損失模 數對儲存模數之比)的模數是0 · 2至2 · 0 ( 2 5 °C ) 。對使用金屬薄管之原子筆而言,具有此特定t a η 5値 之墨水從動件,不必依賴墨水流速及書寫速度便有穩定的 隨動性,並可擦去貯墨水管內壁的墨水,同時書寫期間並 (請先閲讀背面之注意事項再填寫本頁), 1T line Ministry of Economics Intellectual Property Bureau Employees' Cooperative Cooperatives Print this paper scale to apply Chinese National Standard (CNS) A4 specification (21 〇χ 297mm)-Ιό 567148 Ministry of Economic Affairs Intellectual Property Bureau 8 Industry Consumer Cooperatives print this paper scale Applicable to China National Standard (CNS) A4 specification (2.0 × 297 mm) A7 B7 V. Description of invention (yc · I · Pigment Red 2 4 5, C · I · Pigment Yellow; [, c ·; [.Pigment Page 3. C_I · Pigment Yellow 12, c · 丨 · Pigment Yellow 13, cI, Pigment Page i4, cI · Pigment Yellow 17, c · I · Pigment Page 34, CI · Pigment Yellow 55, C · I · Pigment Yellow 74 , C · I · Pigment Yellow 83, c · I · Pigment Yellow 95, c ··· Pigment Page 166, C.I · Pigment Yellow 167, C · I.Pigment Orange 5, C · 1 · Pigment Orange I3, c · I · Pigment Orange 16, c ,; [, Pigment Violet 1, C · I · Pigment Violet 3, c · I · Pigment Violet; [9, C_ I · Pigment Violet 23, C. I _ Pigment Violet 5〇, c .; [Pigment Green 7. Moreover, the amount of the colorant may be appropriately changed depending on the strength of the scribing line, 'preferably from 0.1 to 40% by weight relative to the total amount of ink. Furthermore, may be Incorporate to improve writing touch and for a while Later stable water-soluble liquid media include polyhydric alcohols such as propylene glycol, glycoside oil, polyethylene glycol, alkylene oxide adducts of glycoside oils, and alkylene oxide adducts of trihydroxypropane, and mixtures thereof. In addition, surfactants that can be incorporated as lubricants and wetting agents to control surface tension and improve writing touch include polyethylene oxide, ethylene oxide-propylene oxide derivatives such as ethylene oxide lauryl ether, Glycoside derivatives, diglycoside oils or polyglycoside oils such as tetraglycoside distearate, sugar derivatives such as sorbitan monooleate, surfactants with fluorinated alkyl groups such as perfluoroalkyl groups Phosphate esters, polyether-unmodified silicones, such as polyethylene glycol adducts of dimethylpolysiloxane, hardened castor oil, phosphate-based surfactants, fluorine-based surfactants, potassium soap, and the like. -I -------------- Ί--1T ------ (Please read the precautions on the back before filling in this page) 567148 Α7 Β7 Ministry of Economic Affairs 1 Industrial and Consumer Cooperatives Co., Ltd. V. Invention Description (d In addition, related to other additives, it can be used as a pigment dispersant Water-soluble polymers such as ammonium salts of styrene-maleic acid copolymers, ammonium salts of styrene-acrylic acid copolymers, and reducing sugars mainly containing maltitol as reduction substances, mainly reducing sugars containing sorbitol Sugar, reduced oligosaccharide, reduced malto-oligosaccharide, reduced dextrin, reduced malto-dextrin, α-cyclodextrin, ^ -cyclodextrin, maltosylcyclodextrin, etc., if required Separate use of benzotriazole and saponin as rust inhibitors, and potassium hydroxide, calcium phosphate, amine methylpropanol, etc. as ρ 剂 regulators, and sodium pyridinium, phenyl isothiazoline Wait as a preservative. The water-based ink used in the ballpoint pen of the present invention can be prepared by dissolving the above ingredients while heating (required to the right to mix, scramble, and pass), and if necessary, can be mixed, stirred and filtered. In addition, compared to other water-based ink preparation methods used for ballpoint pens, no special care is required, and as long as the conditions of the stirring temperature and filtration process are within the actual range of water-based inks for ballpoint pens, There is no problem. (Ink follower) The ink follower which can be used in the ball-point pen using water-based ink according to the present invention is limited to an angular rate in the entire range of 0.1 to 650 radians / second (rad / sec) The modulus of ta η 5 値 (expressed as the ratio of the loss modulus to the storage modulus) is 0 · 2 to 2 · 0 (2 5 ° C). For the ball-point pen using a thin metal tube, the ink follower with this specific ta η 5 , has stable followability without relying on the ink flow rate and writing speed, and can wipe off the ink on the inner wall of the ink tube. , While writing and (Please read the notes on the back before filling this page)
- 5 _ n ΙΓ 111 jf ---- - !- SI I 1, VI 訂 線 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X297公釐) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X297公釐) 567148 A7 ___B7 五、發明説明(d 不會有部份的從動件黏附殘留在壁上。而且,墨水從動件 也不會因施加到筆身的碰撞而散開,墨水及墨水從動件的 位置也不會因此顛倒。除此之外,從動件原先的功能,即 藉由在墨水與外在大氣之間的阻斷以防止墨水揮發也就變 得可行了。 再者,在使用金屬薄管之原子筆中,墨水進料路徑的 直徑比似管殻之筆尖還細小,所以墨水的流動性變得遲緩 ,以致於在平常速度的二或多倍下書寫劃線時易引起跳線 。除此之外,在使用已知之防止向後滲漏油脂的原子筆中 ,其油脂本身的流動性很差,所以劃線的跳線經常會發生 。另一方面,使用含有塞子及接收座之防止墨水向後滲漏 機制,及使用角周率在0 · 1至6 5 0弧度/秒的整個範 圍內其t a η 5値的模數是〇 · 2至2 · 0之墨水從動件 的原子筆,對墨水流動性無不良影響,所以在快速書寫時 流動性並不會減低,劃線時也不會產生跳線。 若角周率在特定範圍內或在0 · 1至6 5 0弧度/秒 之整個範圍內,從動件之t a η δ値模數係小於〇 · 2 ( 2 5 °C ),墨水從動件的彈性就變得相當強,以致於很難 將墨水裝塡到貯墨水管中,所以變得無實際用途。 更甚者,若角周率在特定範圍內或在〇.1至650 弧度/秒之的整個範圍內,其t a η 5値模數超過2 . 〇 時,墨水從動件在回應貯墨水管中墨水的消耗將變差,並 且當碰撞施加上筆身時會有易於散開的問題。 除此之外,若墨水從動件之黏度在2 5 °C及剪切速率 -16 - — —ί i-- I- I II— I I — - - - n D n m 111 j— j II 丁 . ---m I . n ! (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印紫 567148 A7 B7-5 _ n ΙΓ 111 jf -----!-SI I 1, VI The size of this paper is applicable to the Chinese National Standard (CNS) Λ4 specification (210X297 mm). The paper is printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs. The scale applies to the Chinese National Standard (CNS) Λ4 specification (210X297 mm) 567148 A7 ___B7 V. Description of the invention (d. There will be no part of the follower sticking to the wall. In addition, the ink follower will not be caused by application. The position of the ink and the ink follower will not be reversed due to the collision of the pen body. In addition, the original function of the follower is to prevent the ink from blocking the external atmosphere. Ink volatilization becomes feasible. In addition, in the ball-point pen using a thin metal tube, the diameter of the ink feed path is smaller than the tip of the tube-like pen, so the fluidity of the ink becomes slow, so that It is easy to cause jumpers when writing underlines at two or more times the speed. In addition, in the use of ball pens that are known to prevent backward leakage of grease, the grease itself has poor fluidity, so the underlined jumpers It often happens. Another Surface, using a mechanism for preventing ink from leaking backwards including a stopper and a receiving seat, and using an angular rate of the entire range from 0 · 1 to 6 50 radians / second, the modulus of ta η 5 値 is 0.2 to 2 · The ball-point pen of the ink follower of 0 has no adverse effect on the fluidity of the ink, so the fluidity will not be reduced during fast writing, and the jumper will not be generated when the line is drawn. If the angular rate is within a specific range or In the entire range of 0 · 1 to 6 50 radians / second, the ta η δ 値 modulus of the follower is less than 0.2 (2 5 ° C), and the elasticity of the ink follower becomes quite strong. So that it is difficult to fill the ink into the ink storage tube, so it becomes useless. Furthermore, if the angular rate is within a specific range or the entire range of 0.1 to 650 radians / second, its When the ta η 5 値 modulus exceeds 2.0, the ink follower's response to the ink consumption in the ink storage tube will become worse, and there will be a problem of easy spreading when the pen body is impacted. In addition, if Ink follower viscosity at 25 ° C and shear rate -16-— — i- I- I II— II —---n D nm 111 j— j II Ding. --- m I. n! (Please read the notes on the back before filling in this page) Employees ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Printing Purple 567148 A7 B7
五、發明説明(U SOOsec — 1下較佳地係落在500至8,0 0 0 m Pa· sec範圍內,更佳地1〇〇〇至6, 000 m P a · s e c時,墨水從動件便可確保墨水的優異流動 性,並且可防止當碰撞施加到筆身時易於發生的散開。若 墨水從動件之黏度在2 5 °C及剪切速率2 0 0 s e c—1下 低於5 0 0 m P a · s e c時,將會有墨水從動件容易散 開而致墨水從筆身滲出的可能性,當碰撞施加到筆身時便 藉此弄污了周圍環境如衣服。而且,若墨水從動件之黏度 在如上所述之相同條件下超過8, OOOmPa · sec 時,書寫時從動件幾乎不能跟隨著墨水,所以在劃線時可 能會發生斷水。 本發明之墨水從動件其特徵爲,角周率在〇.1至 6 5 0弧度/秒的整個範圍內t a η 5値的模數是〇 . 2 至2 _ 0 ( 2 5 °C ),較佳地,t a η 5値在上述範圍內 爲0 · 2至2 · 0 (25°C),並且墨水從動件之黏度在 25 t:及剪切速率2 00 s e c 一1下係500至 8,0 0 0 m P a · s e c。如本發明之墨水從動件的此 類特徵可藉由合適地選擇用於墨水從動件之基礎油類及增 稠劑的種類及摻合量而獲得,同時若需要,可藉由合適地 選擇如下文所說明之製造條件而獲得。 較佳的是使用黏度在2 5 °C及剪切速率1至4 0 0 s e c - 1下爲5 P a · s e c之非水溶性有機溶劑做爲如 本發明之墨水從動件的基礎油。如本發明墨水從動件所用 之基礎油的特性原本就是不溶水或幾乎不溶水,然而,爲 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公- 17二 ' —ί - II - I I I ^_士1^----I I 丁 _ I I___ —良 . 、\吞 % (請先閲讀背面之注意事項再填寫本頁) 567148 A7 B7 五、發明説明(4 (請先閱讀背面之注意事項再填寫本頁} 了達到防止墨水從後端向後滲漏的效果,黏度値才是基礎 油最重要的因素,其也是本發明的特徵。可做爲基礎油之 溶劑幾乎都展現了牛頓黏度(黏度和剪切力無關,係一常 數),以致於黏度都可在1至4 0 0 sec-1範圍內的任 一剪切速率下測量,所以應使用黏度在2 5 °C下爲5 Pa · sec或更少,較佳地爲2Pa · sec或更少, 更佳地0.5至1·5Pa· sec之溶劑。含有黏度超 過5 P a · s e c之基礎油的墨水從動件,其在高剪切速 率範圍時會有高黏度,如此幾乎無法裝塡到貯墨水管內。 再者,引用此類墨水從動件之原子筆在書寫時墨水的隨動 性會減低,藉此將使斷水的問題升高。 經濟部智慧財產局員工消費合作社印製 當混合某些種類之基礎油時,應將黏度値控制在前文 所述範圍內。可當基礎油之特定溶劑包括聚丁烯(其分子 量約6 0 0或更多)、礦物油、矽酮油及其類似者。在二 或三年中可揮發達數個重量%之溶劑,如數均分子量小於 6 0 0之聚丁烯並不被視爲原子筆超過一長時間後的好性 能。較佳的是其揮發損失量約1重量%或更少之溶劑,其 揮發損失量之測量係於大氣壓下將約1 0克的單一或混合 基礎油放置在直徑約4 0公釐之陪替氏培養皿上,並在開 放空氣中於5 0°C下靜置1 4天。再者,黏度會因氧化而 增加之溶劑也是較不爲人喜愛的。 聚丁烯之特定商品包括Nissan聚丁烯200N、聚丁烯 3 0 N ( N 0 F Corporation公司:商品名)、聚丁烯 Η V —1 5 (Nippon Petrochemicals Co·,Ltd:商品名)、聚丁烧 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(21〇X:297公釐) 567148 A7 _B7 __ 五、發明説明(讫 3 5 R ( Idemitsu kosan Co.,Ltd:商品名)° 礦物油之特定商品包括Diana處理油MC - 32S、 M C — W 9 0 ( Idemitsu kosan Co·,Ltd:商品名)。 矽酮油之特定商品包括T F S 4 5 1 ·系列、T S F 456 系列、TSF458 系列(TOSHIBA Silicone Co· Ltd :商品名)。 關於本發明之墨水從動件,較佳的是使用如下物質做 爲增稠劑,舉例之有磷酸酯之鈣鹽、細粒二氧化矽、聚苯 乙烯-聚乙烯丁烯-聚苯乙烯成塊共聚物、聚苯乙烯一聚 乙烯丙烯-聚苯乙烯成塊共聚物、氫化聚苯乙烯丁二烯橡 膠、聚苯乙烯-聚乙烯丁烯-聚烯烴結晶成塊共聚物、聚 烯烴結晶-聚乙烯丁烯-聚烯烴結晶成塊共聚物、聚苯乙 烯- 丁二烯橡膠-聚苯乙烯成塊共聚物、聚苯乙烯-異戊 間二烯橡膠-聚苯乙烯成塊共聚物、二烷基化乙醯基烷氧 基鋁。彼等可以二或多個種類組合使用。 通常,這些增稠劑可歸納爲以聚合物爲基者及以無機 物(非聚合物)爲基者;聚合物爲基之增稠劑可各別歸類 成聚苯乙烯-聚乙烯丁烯-聚苯乙烯成塊共聚物、聚苯乙 烯-聚乙烯丙烯-聚苯乙烯成塊共聚物、氫化聚苯乙烯丁 烯橡膠、聚苯乙烯-聚乙烯丁烯-聚烯烴結晶成塊共聚物 、聚烯烴結晶-聚乙烯丁烯-聚烯烴結晶成塊共聚物、聚 苯乙烯-丁烯橡膠-聚苯乙烯成塊共聚物及聚苯乙烯-異 戊間二烯橡膠-聚苯乙烯成塊共聚物,而無機物類(非聚 合物)增稠劑可各別歸類成磷酸酯之鈣鹽、細粒二氧化石夕 ' ' L-------------批衣----Γ--1T-------^ (請先閲讀背面之注意事項再填寫本頁) 567148 A7 B7 五、發明説明(0 及二烷基化乙醯基烷氧基鋁。 (請先閲讀背面之注意事項再填寫本頁) 磷酸酯之鈣鹽的特定商品包括Crodax DP_301LA(CRODA JAPAN Κ·Κ·公司/商品名卜 細粒二氧化矽可再歸類成親水性細粒二氧化矽及疏水 性細粒二氧化矽,而親水性細粒二氧化矽之特定商品包括 AEROSIL-300'AEROSIL-380 ( Nippon Aerosil Co·,Ltd公司/商品名),疏水性細粒二氧 化矽之特定商品包括AEROS I L - 9 74D、 AEROSIL— 9 7 2 (Nippon Aerosil Co·,Ltd 公司 / 商品名) ο 聚苯乙烯-聚乙烯丁烯-聚苯乙烯成塊共聚物之特定 商品包括Kraton FG— 19〇lX、Krato G -1 6 5 0 ' Kraton G — 1 6 5 1、Kraton G - 1 6 5 2 、Kraton G — 1 6 5 4 X 'Kraton G — 1 6 5 7 X 'V. Description of the invention (U SOOsec — 1 is preferably in the range of 500 to 8,000 m Pa · sec, more preferably 1000 to 6,000 m Pa · sec. The moving parts can ensure the excellent fluidity of the ink, and can prevent the dispersion that is easy to occur when the impact is applied to the pen body. If the viscosity of the ink follower is low at 25 ° C and the shear rate is 2 0 0 sec-1 At 500 m Pa · sec, there is a possibility that the ink follower will spread easily and cause the ink to leak out of the pen body. When the collision is applied to the pen body, it will stain the surrounding environment such as clothes. If the viscosity of the ink follower exceeds 8,000 mPa · sec under the same conditions as described above, the follower can hardly follow the ink when writing, so water breakage may occur during scribing. Ink of the present invention The follower is characterized in that the modulus of ta η 5 値 is 0.2 to 2 _ 0 (2 5 ° C) in the entire range of 0.1 to 6 50 radians / second, preferably , Ta η 5 値 is 0 · 2 to 2 · 0 (25 ° C) in the above range, and the viscosity of the ink follower is 25 t: and the shear rate is 2 00 sec-1 The lower line is 500 to 8,000 m Pa · sec. Such characteristics of the ink follower of the present invention can be selected by appropriately selecting the type of base oil and thickener used for the ink follower and The blending amount is obtained, and if necessary, it can be obtained by appropriately selecting manufacturing conditions as described below. It is preferable to use the viscosity at 25 ° C and the shear rate of 1 to 4 0 0 sec-1 A water-insoluble organic solvent of 5 Pa · sec is used as the base oil of the ink follower of the present invention. The characteristics of the base oil used in the ink follower of the present invention are originally insoluble or almost insoluble. However, Applies Chinese National Standard (CNS) A4 specifications (210X 297 male-17 two '— ί-II-III ^ _ 士 1 ^ ---- II 丁 _ I I___ —good. Read the precautions on the back before filling this page) 567148 A7 B7 V. Description of the invention (4 (Please read the precautions on the back before filling in this page) To prevent the ink from leaking from the back end, the viscosity is 値The most important factor of base oil, which is also a feature of the present invention, can be used as a base oil Almost all exhibited Newtonian viscosity (viscosity is not related to shear force, a constant), so that viscosity can be measured at any shear rate in the range of 1 to 4 0 0 sec-1, so viscosity should be used at 2 5 Pa · sec or less, preferably 2 Pa · sec or less, more preferably 0.5 to 1.5 Pa · sec at 5 ° C. Ink followers that contain base oils with a viscosity exceeding 5 Pa · s e c will have high viscosity at high shear rate ranges, making it almost impossible to fit them into the ink tank. Furthermore, ball pens that use such ink followers will reduce the ink's followability during writing, which will increase the problem of water breakage. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. When mixing certain types of base oils, the viscosity 値 should be controlled within the range described above. Specific solvents that can be used as base oils include polybutene (whose molecular weight is about 600 or more), mineral oil, silicone oil, and the like. Solvents that can be volatile up to several weight percent in two or three years, such as polybutene with a number average molecular weight of less than 600 are not considered to be good performance after a long period of time. Preferably, the solvent whose volatilization loss is about 1% by weight or less is measured by placing about 10 g of a single or mixed base oil at a pressure of about 40 mm in a spare at atmospheric pressure. On a petri dish and left in open air at 50 ° C for 14 days. Furthermore, solvents whose viscosity increases due to oxidation are also less desirable. Specific products of polybutene include Nissan polybutene 200N, polybutene 3 0 N (N 0 F Corporation: trade name), polybutene Η V — 1 5 (Nippon Petrochemicals Co., Ltd: trade name), The size of the polybutadiene paper is in accordance with the Chinese National Standard (CNS) A4 (210X 297 mm). The printed paper is in accordance with the Chinese National Standard (CNS) A4 (21〇X: 297 mm). 567148 A7 _B7 __ 5. Description of the invention (讫 3 5 R (Idemitsu kosan Co., Ltd: trade name) ° Specific products of mineral oil include Diana treatment oil MC-32S, MC — W 9 0 (Idemitsu kosan Co , Ltd: trade name). Specific products of silicone oil include TFS 4 5 1 · series, TSF 456 series, TSF458 series (TOSHIBA Silicone Co · Ltd: trade name). Regarding the ink follower of the present invention, the preferred The following materials are used as thickeners, for example, calcium salts of phosphate esters, fine-grained silica, polystyrene-polyvinylbutene-polystyrene block copolymers, polystyrene-polyethylene propylene- Polystyrene block copolymer, Polystyrene butadiene rubber, polystyrene-polyethylene butene-polyolefin crystal block copolymer, polyolefin crystal-polyethylene butene-polyolefin crystal block copolymer, polystyrene-butadiene Rubber-polystyrene block copolymer, polystyrene-isoprene rubber-polystyrene block copolymer, dialkylated ethenyl alkoxy aluminum. They can be combined in two or more kinds In general, these thickeners can be summarized as polymer-based and inorganic (non-polymer) -based; polymer-based thickeners can be individually classified as polystyrene-polyethylene butyl Olefin-polystyrene block copolymer, polystyrene-polyethylene propylene-polystyrene block copolymer, hydrogenated polystyrene butene rubber, polystyrene-polyethylene butene-polyolefin crystalline block copolymer Polyolefin crystalline-polyethylene butene-polyolefin crystalline block copolymer, polystyrene-butene rubber-polystyrene block copolymer, and polystyrene-isoprene rubber-polystyrene block Copolymers, while inorganic (non-polymer) thickeners can be individually classified as phosphate esters Salt, fine-grained dioxide dioxide '' L ------------- batch coat Γ--1T ------- ^ (Please read the precautions on the back first (Fill in this page again) 567148 A7 B7 V. Description of the invention (0 and dialkylated ethynyl aluminum alkoxide. (Please read the notes on the back before filling out this page) Specific products of calcium salts of phosphate esters include Crodax DP_301LA (CRODA JAPAN KK · KK · Company name) Fine-grained silica can be further classified into hydrophilic fine-grained silica and hydrophobic fine-grained silica, and specific products of hydrophilic fine-grained silica Including AEROSIL-300'AEROSIL-380 (Nippon Aerosil Co., Ltd company / trade name), specific products of hydrophobic fine-grained silica include AEROS IL-9 74D, AEROSIL— 9 7 2 (Nippon Aerosil Co., Ltd. Company / Product Name) ο Specific products of polystyrene-polyvinylbutene-polystyrene block copolymers include Kraton FG—190 × L, Krato G -1 6 5 0 'Kraton G — 1 6 5 1. Kraton G-1 6 5 2, Kraton G — 1 6 5 4 X 'Kraton G — 1 6 5 7 X'
Kraton G - 1 7 2 6 X、Kraton FG - 1092X (Kraton G-1 7 2 6 X, Kraton FG-1092X (
Shell Japan Ltd.公司 / 商品名),SEPTON 8 0 0 7、 SEPTON 8 0 0 4、 SEPTON 8 0 0 6 ( Kuraray Co., 經濟部智慈財產局員工消費合作社印製Shell Japan Ltd. / company name), SEPTON 8 0 0 7, SEPTON 8 0 0 4, SEPTON 8 0 0 (Printed by Kuraray Co., Employees ’Cooperative of Intellectual Property Office, Ministry of Economic Affairs
Ltd.公司 / 商品名),Tuftec M — 1 9 4 3、Tuftec M -19 11' Tuftec M - 1 9 1 3 ( Asahi Kasei 〇011011〖丨011公司/商品名)。Ltd. company / trade name), Tuftec M — 1 9 4 3. Tuftec M -19 11 'Tuftec M-1 9 1 3 (Asahi Kasei 〇011011 〖011 company / trade name).
聚苯乙烯-聚乙烯丙烯-聚苯乙烯成塊共聚物之特定 商品包括 Kraton G - 1 7 3 0 ( Shell Japan Ltd·公司 / 商 品名),SEPTON 2002、 SEPTON 2005、 SEPTON 2006' SEPTON 2007' SEPTON -20 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公漦) 經濟部智慧財產局員工消費合作社印製 567148 A7 __ B7 五、發明説明(4 2043、 SEPTON 2063、 SEPTON 2104、 SEPTON 4033' SEPTON 4055' SEPTON 4 0 7 7 ( Kuraray Co·,Ltd·公司 / 商品名)。 氫化聚苯乙烧丁二條橡膠之特定商品包括DYNARON 1 320P、DYNARON 1 321 P(JSR Corporation公司 / 商品名), Tuftec Η 1 〇 6 2、Tuftec Η 1 〇 5 2、Tuftec Η 1 1 4 1、Tuftec Η 1 〇 4 1、Tuftec Η 1 〇 5 3、 Tuftec Η 1 〇 4 3 ' Tuftec Η 1 2 7 2 ( Asahi KaseiSpecific products of polystyrene-polyethylene propylene-polystyrene block copolymers include Kraton G-1 7 3 0 (Shell Japan Ltd./company name), SEPTON 2002, SEPTON 2005, SEPTON 2006 'SEPTON 2007' SEPTON -20-This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 gong) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 567148 A7 __ B7 V. Description of the invention (4 2043, SEPTON 2063, SEPTON 2104, SEPTON 4033 'SEPTON 4055' SEPTON 4 0 7 7 (Kuraray Co., Ltd. / company name). Specific products of hydrogenated polystyrene butadiene rubber include DYNARON 1 320P, DYNARON 1 321 P (JSR Corporation / product name) , Tuftec Η 1 〇6, Tuftec Η 1 〇5, Tuftec Η 1 1 4 1, Tuftec Η 1 〇4 1, Tuftec Η 1 〇3, Tuftec Η 1 〇4 3 'Tuftec Η 1 2 7 2 ( Asahi Kasei
Corporation公司/商品名)。 聚苯乙烯-聚乙烯丁烯-聚烯烴結晶成塊共聚物之特 定商品包括DYNAR0N 4 6 0 〇 P (JSR corp〇rati〇n 公司 /商品名)。 聚烯烴結晶-聚乙燃丁烯-聚烯烴結晶成塊共聚物之 特定商品包括DYNAR0N 1 3 2 1 P ( ;fSR Col.pol.ation& 司/商品名)。 聚苯乙燒-丁二燃橡膠-苯乙烯成塊共聚物之特定商 品包括 Kraton D - 1 1 0 1 , Kraton D - 1 1 0 2、 Kraton D - 1 1 5 5 ^ Kraton D - K X 4 0 5 ' Kraton D - K X 4 0 8、Kraton D K X 4 i 〇 . Kraton D - K X 4 1 4 ' Kraton D - κ X 6 5 s、Kraton D -K X 4 0 3 P、Kraton D ^ K χ χ 3 g s . Kraton D 一 KXl55P、Kl.atC)nD—lll8、Km〇nD- 1116^ Kraton D - 1 1 8 8 X , Kraton D -1 1 2 2 X ' Kraton D ~ 1 3 〇 〇 χ . Cariflex T R - 本紙張中ΐ國家標準(CNS ) A4規格(210 x2^^--r2T=- ,------------τ——IT------0 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印焚 567148 A7 __B7_ 五、發明説明(4 1 1 0 1 S、Cariflex T R — 1 1 8 4、Cariflex TR- 1 1 8 6 、Cariflex TR — 4113P、Cariflex TR- 4 1 2 2 P、 Cariflex TR - 4 2 6 0 P (Shell JapanCorporation). Specific products of the polystyrene-polyvinylbutene-polyolefin crystalline block copolymer include DYNARON 4 600 (JSR Corp./trade name). Specific products of polyolefin crystalline-polyethylene butene-polyolefin crystalline block copolymers include DYNARON 1 3 2 1 P (; fSR Col.pol.ation & Division / Trade Name). Specific products of polystyrene-butadiene rubber-styrene block copolymers include Kraton D-1 1 0 1, Kraton D-1 1 0 2, Kraton D-1 1 5 5 ^ Kraton D-KX 4 0 5 'Kraton D-KX 4 0 8, Kraton DKX 4 i 〇. Kraton D-KX 4 1 4' Kraton D-κ X 6 5 s, Kraton D -KX 4 0 3 P, Kraton D ^ K χ χ 3 gs Kraton D-KXl55P, Kl.atC) nD—ll8, KmOnD-1116 ^ Kraton D-1 1 8 8 X, Kraton D -1 1 2 2 X 'Kraton D ~ 1 3 〇〇χ. Cariflex TR- In this paper, the national standard (CNS) A4 specification (210 x2 ^^-r2T =-, ------------ τ——IT ------ 0 (please read the back first) Please note this page before filling in this page) Employees ’Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs printed 567148 A7 __B7_ V. Description of the invention (4 1 1 0 1 S, Cariflex TR — 1 1 8 4, Cariflex TR- 1 1 8 6, Cariflex TR — 4113P, Cariflex TR- 4 1 2 2 P, Cariflex TR-4 2 6 0 P (Shell Japan
Ltd·公司 / 商品名),Tufprene - A、Tufprene — 1 2 5 、Tufprene— 1 2 6、Tufprene- 3 1 5、Tufprene- T 一 4 1 1、Tufprene— T — 4 1 4、Tufprene- T — 4 1 6、 Tufprene— T - 4 0 6、Tufprene— T — 4 7 5、Asaprene —丁一 4 7 5、Asaprene— T — 4 2 0、Asaprene—T — 4 3 0、Asaprene— T — 4 3 1、Asaprene— T - 4 3 2、Ltd./company name), Tufprene-A, Tufprene — 1 2 5, Tufprene — 1 2 6, Tufprene — 3 1 5, Tufprene — T — 4 1 1, Tufprene — T — 4 1 4, Tufprene — T — 4 1 6, Tufprene— T-4 0 6, Tufprene— T — 4 7 5, Asaprene — Ding 4 7 5, Asaprene— T — 4 2 0, Asaprene—T — 4 3 0, Asaprene— T — 4 3 1. Asaprene— T-4 3 2.
Asaprene-丁 — 4 3 6 ( Asahi Kasei Corporation公司 / 商品 名),JSR — TR-l〇〇〇、JSR — TR-2000、JSR - TR - 2003、JSR-TR -2250、JSR-TR-2601、JSR-TR~ 2606、J SR-TR-2787、JSR - TR -2827、J SR-TR - 2600、JSR - TR -1 0 8 6、J SR — TR — 1 6 0 0 (JSR Corporation公司 / 商品名),Europrene SOLT-161 ( Tosoh Corporation公司/商品名)。 聚苯乙烯-異戊間二烯橡膠一聚苯乙烯成塊共聚物之 特定商品包括 Kraton D-KX-400P ' Kraton D — 1 1 1 3 X、Kraton D - 1 1 1 4 χ > Kraton D - 1 1 2 5 X ' Kraton D - 1 3 2 0 X、Kraton D- 110 7' Kraton D - 1 1 1 2、Kraton D - 1 1 l 3 、Kraton ϋ - 1 1 1 7、Kraton D - 1 1 1 9、Kraton 本紙張尺度適用中國國家;( CNS ) A4規袼(210x 2S)7公楚;) ~ 22 - 一 "' ------------1¾衣----Ί--IT------^ (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局資工消費合作社印製 567148 Μ Β7 五、發明説明(2b D - 1 1 2 4 ' Kraton D - 1 1 6 1、Kraton D — 1 1 1 1、Kraton D — K X 4 0 6、Kraton D - K X 6 0 3 ' Cariflex T R - 1 1 0 7 ( Shell Japan, Ltd. 公司 / 商品名)’ Solprene — 4 1 8 ( Asahi Kasei (!!〇1-?〇111^〇11公司//商品名)’】311 — 8 18 — 5 0 0 0 ( J S R Corporation公司 / 商品名),Quintac — 3 4 2 1 、Quintac— 3 4 2 2、Quintac— 3 4 3 5、Quintac — 3 5 3 0、Quintac— 3 4 5 0 ( Nippon Zeon Co.,Ltd公司 /商品名)。 二烷基化乙醯基烷氧基鋁之特定商品包括PLENACT AL-M(Aj inomoto Fine-Techno Co.,Inc公司)。 這些增稠劑的量若合適時,可提供彈性或結構性黏度 的效果,同時可行的是,藉由控制摻合量而控制t a η 5 値在0 · 2 - 2 · 0 (25°C)。再者,若需要時,黏土 增稠劑或金屬皂也可與前述增稠劑一起使用。至於這些增 稠劑的使用量,當彼等單獨使用時,較佳地係各別使用2 至2 5重量%之磷酸酯鈣鹽、3至1 2重量%之聚苯乙烯 一聚乙烯丁烯一聚苯乙烯成塊共聚物及/或〇.3至10 重量%之聚苯乙烯-聚乙烯丙烯-聚苯乙烯成塊共聚物、 1 . 0至2 0重量%之氫化聚苯乙烯丁二烯橡膠} · 〇至 2 5重量%之聚苯乙烯-聚乙烯丁烯-聚烯烴結晶成塊共 聚物或聚燒烴結晶-聚乙燦丁嫌一聚燃烴結晶成塊共聚物 、1 · 0至2 0重量%之聚苯乙烯一 丁烯橡膠—聚苯乙烯 成塊共聚物(更佳地,1·〇至15重量%) 、1.〇至 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) H — I 1^ . 裝 ^ 訂 I I線 (請先閲讀背面之注意事項再填寫本頁) 567148 A7 ____ B7__ 五、發明説明(2)| 2 5重量%之聚苯乙烯-異戊間二烯橡膠-聚苯乙烯成塊 共聚物(更佳地,2 · 0至20重量%)及2 · 0至20 重量%之二烷基化乙醯基烷氧基鋁。 若每一成份係以比前述量還低的量摻合時,從動件將 無法提供足夠的黏彈性,如此墨水從動件將會散開,且僅 因輕微碰撞就會引起筆身內的墨水向後滲漏。再者,墨水 從動件會藉由常溫的改變而減低黏度,並僅因爲筆端點向 上就使墨水向後滲漏。另一方面,若摻合量超過前述量時 ,從動件會具有超過合適範圍之較高的黏彈性,如此墨水 從動件會變硬,並會因爲書寫時墨水的不良隨動性而致劃 線時斷水。 除此之外,若需要時,可摻入增稠劑輔助劑(黏土增 稠劑、金屬皂,等)、用於墨水從動件之隨動性增進劑( 表面活性劑,等)及抗氧化劑。然而,某些抗氧化劑會大 大地增加t a η 5値。若非必要地摻入這些物質,縱使增 稠劑係以規定量加入,也可能會使t a η 5値超過2,所 以,必須注意此類摻合。 如本發明之使用水基墨水的原子筆所用之墨水從動件 ,其製造方法很簡單,是在室溫下預先揉和所有成份如基 礎油、墨水從動件用表面活性劑,然後,若還使用了如疏 水性二氧化矽之無機增稠劑時,可藉由分配器如軋製機及 揉和機再揉合。再者,當使用室溫下幾乎不溶解或分散的 聚合物時,若需要可邊加熱邊攪拌揉和。除此之外,可行 的是,可藉由進一步加熱並藉助於分配器如軋製機及揉和 -—Asaprene-Ding — 4 3 6 (Asahi Kasei Corporation / trade name), JSR — TR-100, JSR — TR-2000, JSR-TR-2003, JSR-TR-2250, JSR-TR-2601, JSR-TR ~ 2606, J SR-TR-2787, JSR-TR -2827, J SR-TR-2600, JSR-TR -1 0 8 6, J SR — TR — 1 6 0 0 (JSR Corporation / Products Name), Europrene SOLT-161 (Tosoh Corporation / trade name). Specific products of polystyrene-isoprene rubber-polystyrene block copolymer include Kraton D-KX-400P 'Kraton D — 1 1 1 3 X, Kraton D-1 1 1 4 χ > Kraton D -1 1 2 5 X 'Kraton D-1 3 2 0 X, Kraton D- 110 7' Kraton D-1 1 1 2, Kraton D-1 1 l 3, Kraton ϋ-1 1 1 7, Kraton D-1 1 1 9. Kraton This paper size applies to China; (CNS) A4 regulations (210x 2S) 7 Gongchu;) ~ 22-一 " '------------ 1¾ clothing- --Ί--IT ------ ^ (Please read the notes on the back before filling out this page) Printed by the Industrial Property Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 567148 Μ B7 V. Description of the invention (2b D-1 1 2 4 'Kraton D-1 1 6 1, Kraton D — 1 1 1 1, Kraton D — KX 4 0 6, Kraton D-KX 6 0 3' Cariflex TR-1 1 0 7 (Shell Japan, Ltd. company / Trade name) 'Solprene — 4 1 8 (Asahi Kasei (!! 〇1-? 〇111 ^ 〇11 company // trade name)'] 311 — 8 18 — 5 0 0 0 (JSR Corporation / trade name), Quintac — 3 4 2 1, Quintac — 3 4 2 2, Quintac — 3 4 3 5, Quintac — 3 5 3 0, Quintac 3 4 5 0 (Nippon Zeon Co., Ltd./trade name). Specific products of the dialkylated ethynyl aluminum alkoxide include PLENACT AL-M (Aj inomoto Fine-Techno Co., Inc.). These If the amount of thickener is appropriate, it can provide the effect of elasticity or structural viscosity, and it is also feasible to control ta η 5 0 at 0 · 2-2 · 0 (25 ° C) by controlling the blending amount. Furthermore, if necessary, clay thickeners or metal soaps can also be used together with the aforementioned thickeners. As for the amount of these thickeners, when they are used alone, it is preferable to use 2 to 2 respectively. 5% by weight of calcium phosphate salt, 3 to 12% by weight of polystyrene-polyvinylbutene-polystyrene block copolymer and / or 0.3 to 10% by weight of polystyrene-polyethylene propylene -Polystyrene block copolymer, 1.0 to 20% by weight of hydrogenated polystyrene butadiene rubber} · 0 to 25% by weight of polystyrene-polyethylene butene-polyolefin crystal block copolymerization Polymer or sintered hydrocarbon crystals-polyethylene terephthalate is a polycrystalline hydrocarbon crystalline block copolymer, 1 · 0 to 20% by weight of polystyrene monobutylene rubber — Polystyrene block copolymer (more preferably, 1.0 to 15% by weight), 1.0 to this paper size Applies to Chinese National Standard (CNS) A4 specification (210X297 mm) H — I 1 ^. Order II line (please read the notes on the back before filling this page) 567148 A7 ____ B7__ V. Description of the invention (2) | 2 55% by weight of polystyrene-isoprene rubber-polystyrene block copolymerization (More preferably, 2.0 to 20% by weight) and 2.0 to 20% by weight of a dialkylated ethenyl aluminum alkoxide. If each component is blended in a lower amount than the aforementioned amount, the follower will not provide sufficient viscoelasticity, so the ink follower will spread out, and the ink in the pen body will be caused only by slight collision. Leaked backwards. Furthermore, the ink follower will reduce the viscosity by changing the normal temperature, and the ink will leak backward only because the pen end point is upward. On the other hand, if the blending amount exceeds the aforementioned amount, the follower will have a higher viscoelasticity than the appropriate range, so that the ink follower will harden, and will be caused by the poor followability of the ink when writing. Water cut off when marking. In addition, if necessary, thickener auxiliary agents (clay thickeners, metal soaps, etc.), follower enhancers (surfactants, etc.) for ink followers, and Oxidant. However, some antioxidants greatly increase t a η 5 値. If these substances are added unnecessarily, even if the thickener is added in a prescribed amount, t a η 5 値 may exceed 2; therefore, it is necessary to pay attention to such blending. The manufacturing method of the ink follower for the ball-point pen using water-based ink according to the present invention is simple. It is to knead all ingredients such as base oil and surfactant for the ink follower in advance at room temperature, and then, if When an inorganic thickener such as hydrophobic silica is also used, it can be kneaded by a dispenser such as a rolling machine and a kneader. Furthermore, when using a polymer that hardly dissolves or disperses at room temperature, it can be kneaded while being heated, if necessary. In addition to this, it is possible, by further heating and by means of dispensers such as rolling mills and kneading-
In I- ! ί -- -- —^ ir I 1-- I (請先閲讀背面之注意事項再填寫本頁) 、-|1 經濟部智慧財產局g;工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 567148 A7 B7 五、發明説明(2j (請先閲讀背面之注意事項再填寫本頁)In I-! Ί--^ ir I 1-- I (Please read the notes on the back before filling this page),-| 1 Intellectual Property Bureau of the Ministry of Economic Affairs g; Industry and consumer cooperatives print this paper to apply the standard Chinese National Standard (CNS) A4 specification (210X297 mm) 567148 A7 B7 V. Invention description (2j (Please read the precautions on the back before filling this page)
剪切速率:38 · 4sec 一 384sec — 測量時間:6 Ο 0 s e c 測量溫度:2 5 °C •墨水從動件之物理特性的測量 (1 ) t a η 5値模數之測量 測量設備: 動態分光計R D S — I I (Rheo metric Scientific Co., Ltd) 測量條件(頻率依屬性) 幾何學:平行板 5 0公釐Φ 動態測量 掃視形態:周率掃視 頻率範圍:0·06-650弧度/秒 測量間隔:5度/癸烷 扭變:1 0 0 % 經濟部智慧財產局員工消費合作社印製 測量溫度:2 5 °C 大氣:氮氣中 (2 )黏度値測量 測量設備:Shear rate: 38 · 4sec-384sec — Measuring time: 6 〇 0 sec Measuring temperature: 2 5 ° C • Measurement of the physical characteristics of the ink follower (1) ta η 5 値 Modulus measurement measuring equipment: dynamic spectrometry RDS — II (Rheo metric Scientific Co., Ltd) Measurement conditions (frequency-dependent) Geometry: Parallel plate 50 mm Φ Dynamic measurement Sweep shape: Cycle sweep Video rate range: 0 · 06-650 radians / second measurement Interval: 5 degrees / decane distortion: 100% Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Measurement temperature: 25 ° C Atmospheric: (2) viscosity in nitrogen Nitrogen measurement equipment:
E形式旋轉黏度計 DIGITAL VISCOMETER DUV-E 本紙張尺度適用中國國家標準(CNS ) A4規格(2】OX 297公釐) 經濟部智慧財產局員工消費合作社印製 567148 A7 __B7 _ 五、發明説明(2含 (Tokyo Keiki Co·,LTD公司製造) 測量條件(頻率依屬性) 錐形:1 ° * R 1 4 剪切速率:200 sec—1 測量時間:6 0 0 s e c 測量溫度:2 5 °C •筆身之評估 經由原子筆在紙上螺旋狀書寫並藉由下列判據來評估 書寫觸感,每支原子筆皆具有〇 . 5公釐直徑之球,並係 根據每一規格製備。 〇:平滑且穩定之書寫觸感。 △:輕微粗糙且堅硬之書寫觸感。 X :粗糙且堅硬之書寫觸感,並有跳線及方向的誤差 (2 )墨水流出量 經由原子筆在紙上螺旋狀書寫並藉由下列判據來評估 墨水流出量,每支原子筆皆具有0 . 5公釐直徑之球,並 係根據每一規格製備。 〇:充足的墨水流出,並且可淸晰看到所劃之線。 △:墨水流出相對地少些,但所劃之線還可看到。 X :墨水流出明顯地少,且所劃之線很難看到。 (3 )濺污之評估 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X 297公釐) 裝 ^ 訂__. I 線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210 X 297公釐) 567148 A7 B7 五、發明説明( 經由原子筆在紙上螺旋狀書寫並藉由下列判據來評估 濺污,每支原子筆皆具有〇 · 5公釐直徑之球,並係根據 每一規格製備。 Ο:幾乎沒有任何濺污。 △:有些微濺污,但在可允許限度內。 X :嚴重濺污,且所劃之線不淸晰。 (4)劃線時羽毛邊之評估 經由原子筆在紙上螺旋狀書寫並藉由下列判據來評估 羽毛邊,每支原子筆皆具有0 · 5公釐直徑之球,並係根 據每一規格製備。 Ο:幾乎沒有任何羽毛邊。 X :嚴重羽毛邊,且所劃之線不淸晰。 (5 )快速書寫時隨動性之評估 根據I S〇標準法,經由原子筆在紙上以正常速度及 兩倍速度徒手劃線,並藉由下列判據來評估劃線,每支原 子筆皆具有〇 . 5公釐直徑之球,並係根據每一規格製備 〇 〇:可平滑及安穩地書寫。 △:在兩倍速度下,劃線時會分裂。 X :在正常速度下,劃線時會分裂。 (6 )墨水流出之穩定性 -29 - ----------—裝----Ί--1T------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局8工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X 297公釐) 567148 A7 ____B7 _ 五、發明説明(2》 〇:在螺旋狀書寫一輪內,可再書寫且不會斷水。 △:在螺旋狀書寫三輪內,可再書寫且不會斷水。 X :在螺旋狀書寫三輪內,無法再書寫。 (8 )因輕微碰撞之墨水散開 將每支皆具有0 · 5公釐直徑之球,並根據每一規格 製備的原子筆以筆端點向上方式從1,5公尺高掉落至一 具有2公分厚度之柳杉板上,然後以目視觀察落下來之筆 身。 墨水散開到貯墨水管外面的程度可藉由下列判據來評 估。 〇:墨水沒有散開,而且墨水與墨水從動件之間的界 面很淸楚。 X :可明顯觀察到墨水散開。 (9 )抗向後滲漏特性 使用每支皆具有0·5公釐直徑之球,並根據每一規 格製備的原子筆,並以筆端點向上螺旋狀書寫直到無法完 成書寫爲止,然後以筆端點向上讓筆直立。1小時後,目 視觀察墨水的向後滲漏。 〇:沒有觀察到向後滲漏。 X :觀察到向後滲漏。 (10)筆尖之耐磨損性 - Κ--------^—1^----Ί--1Τ------^ (請先閲讀背面之注意事項再填寫本頁) 567148 A7 __ B7 五、發明説明( 藉助於書寫試驗機在下列條件下,並根據I S〇標準 法讓原子筆(每支皆具有〇 . 5公釐直徑之球,並根據每 ~ ^格製備)在紙上以螺旋狀書寫7 0 0公尺,然後藉由 $ _擇之顯微鏡觀察書寫後筆尖之球接收座的磨損狀態。 書寫條件: 書寫速度:4·5公尺/分鐘 書寫角度:6 0 ° 書寫負重·100公克 〇 :觀察到球接收座幾乎沒有磨損,且可書寫到 7 〇 0公尺。 △:觀察到球接收座有磨損,且可書寫到5 0 〇公尺 ,------------Ί--IT------0 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慈財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 567148 \Ί Β7 五、發明説明(^ 經濟部智莛財產局8工消費合作社印^ 表1 實施例之墨水配製及特忡 墨水1 墨水2 墨水3 墨水4 實施例 實施例 實施例 實施例 墨水顏色 黑色 藍色 黑色 黑色 著色劑碳黑Printex 25 (Dequssa公司之商品名)顏料 顏料 7.00 7.00 醜菁藍 Chromofine Blue 4965 (Dainichiseika Color & Chemicals Mfg. Co·, Ltd.公司之商品名 _ )顏料 7.50 著色劑水黑 R455 (Orient Chemical Industries,Ltd.公 ^料 司之商品名)染料 7.00 水黃 6C (Orient Chemical Industries,Ltd.公W 一 之商品名)染料 1.00 顏料 苯乙烯馬來酸樹脂銨鹽 2.00 2.00 竺熬劑苯乙烯丙烯酸樹脂銨鹽 2.30 液體 丙二醇 18.00 15.00 15.00 ^ 甙油 10.00 10.00 二甙油之氧化丙烯4莫耳加成物 10.00 防止揮麥芽糖醇 發物質 5.00 5.00 5.00 5.00 表面活性鉀皂 劑 0.50 0.40 0.50 (潤麵)麵麵 0.20 0.40 全氣烷基磷酸酯 0.20 0.10 _ 以氣爲基之院基醋 0.30 0.20 防腐劑 啶化鈉 0.10 0.10 0.10 0.10 酵劑 皂草甙 0.10 0.10 0.10 0.10 PH調 胺甲基丙醇 整劑 0.30 0.30 .030 0.20 黏度 漢生膠 KELXZAN HP (SANSHO Co.,Ltd.公 控制劑司之商品名) 0.30 0.30 0.40 0.20 交聯形式之聚丙烯酸Hiviswako 105 (Wake Pure Chemical Industries Ltd.公司之商品名) 0.10 0.20 聚乙烯基吡咯烷酮PVP-K90(GAFCo.,Ltd.公 司之商品名) 5.00 離子交換水 66.50 58.60 70.40 59.50 總量 100.00 100.00 100.00 100.00 在25^,38.4 86(^下之墨水黏度(mPa.sec) 130 200 320 400 至25°C,384 sec·1 下之墨水黏度(mPa.sec) 25 40 30 80 在25°C下之墨水表面張力(mN/m) 28.0 30.5 23.5 25.4 備註 本發明 之墨水 本發明 之墨水 本發明 之墨水 本發明 之墨水 ϋ I I— i I I-..... = I I» L· 士^ —II n = - ---—ϋ 1^1 n ϋ— ^ i 結 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS) A4規格(210X 297公釐) 567148E-type Rotary Viscometer DIGITAL VISCOMETER DUV-E This paper size applies to Chinese National Standard (CNS) A4 specifications (2) OX 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 567148 A7 __B7 _ V. Description of the invention (2 Including (manufactured by Tokyo Keiki Co., Ltd.) Measurement conditions (frequency dependent properties) Cone: 1 ° * R 1 4 Shear rate: 200 sec—1 Measurement time: 60 0 0 sec Measurement temperature: 2 5 ° C • The evaluation of the pen body was performed by spirally writing on the paper with ball-point pens and evaluating the writing touch by the following criteria. Each ball-point pen has a ball of 0.5 mm in diameter and is prepared according to each specification. 0: Smooth And stable writing feel. △: Slight rough and hard writing feel. X: Rough and hard writing feel, with jumper and direction error (2) Spiral ink writing on paper via ballpoint pen The following criteria are used to evaluate the ink outflow. Each ball pen has a ball with a diameter of 0.5 mm and is prepared according to each specification. 〇: sufficient ink outflow, and the strokes can be clearly seen The line. △: The water outflow is relatively small, but the line drawn is still visible. X: The ink outflow is significantly less, and the line drawn is difficult to see. (3) Evaluation of splashes The paper dimensions are subject to Chinese national standards (CNS ) Λ4 specification (210X 297 mm) Binding __. I line (Please read the notes on the back before filling out this page) Printed on the paper standard of the China National Standards (CNS) Λ4 specification (210 X 297 mm) 567148 A7 B7 V. Description of the invention (Writing spirally on a paper with a ball pen and using the following criteria to evaluate the splash, each ball pen has a 0.5 mm diameter ball , And prepared according to each specification. 〇: There is almost no splashing. △: Slight splashing, but within the allowable limit. X: Severe splashing, and the line drawn is not clear. (4) Scoring The feather edges are evaluated by writing on the paper spirally with a ball pen and the following criteria are used to evaluate the feather edges. Each ball pen has a ball with a diameter of 0.5 mm and is prepared according to each specification. 〇: There are hardly any feather edges. X: Serious feather edges And the line drawn is not clear. (5) Evaluation of follow-up during fast writing According to the ISO standard method, a freehand line is drawn on the paper at a normal speed and twice the speed by a ball pen, and evaluated by the following criteria Scribing, each ball pen has a ball with a diameter of 0.5 mm, and is prepared according to each specification. 00: Can write smoothly and securely. △: At double speed, it will split when scribing. X : At normal speed, it will split when scribing. (6) Stability of ink outflow -29------------- Load ---- Ί--1T ------ line (Please read the notes on the back before filling out this page) The paper size printed by the 8th Industrial Cooperative Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs applies the Chinese National Standard (CNS) Α4 specification (210X 297mm) 567148 A7 ____B7 _ V. Description of the invention (2 >> 〇: In a spiral writing round, you can write again without water cut. △: Within three rounds of spiral writing, you can write again without stopping the water. X: Within three rounds of spiral writing, no more writing. (8) Each ink ball with a diameter of 0.5 mm is scattered due to the light collision of the ink, and the ballpoint pens prepared according to each specification are dropped from a height of 1,5 meters to one with a pen tip length of 2. The thickness of the cedar board is about a centimeter thick, and then the pen body that falls down is observed visually. The extent to which the ink spreads out of the ink tank can be evaluated by the following criteria. 〇: The ink did not spread, and the interface between the ink and the ink follower was clear. X: Dispersion of the ink was clearly observed. (9) Anti-backward leakage characteristics Use ball pens each with a diameter of 0.5mm, prepared according to each specification, and write spirally with the pen end point upwards until writing is impossible, and then use the pen end point Keep the pen upright. After 1 hour, the backward leakage of the ink was visually observed. ○: No backward leakage was observed. X: Backward leakage was observed. (10) Abrasion resistance of nib-Κ -------- ^ — 1 ^ ----- 1--1Τ ------ ^ (Please read the precautions on the back before filling in this page ) 567148 A7 __ B7 V. Description of the invention (with the help of a writing tester under the following conditions and according to the IS0 standard method let ball pens (each with a 0.5 mm diameter ball, and prepared according to each ~ ^ grid ) Write 700 meters in a spiral shape on the paper, and then observe the wear state of the ball receiving seat of the pen tip after writing with a $ _ microscope. Writing conditions: Writing speed: 4.5 meters / minute Writing angle: 6 0 ° Writing load · 100g 0: Observe that the ball receiving seat is almost free of wear, and can be written to 7000 meters. △: Observe that the ball receiving seat is worn, and can write up to 500 meters,- ---------- Ί--IT ------ 0 (Please read the notes on the back before filling out this page) Printed by the Consumer Goods Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper applies to China National Standard (CNS) A4 specification (210X 297 mm) 567148 \ Ί Β7 V. Description of the invention (^ Printed by the 8th Industrial Cooperative Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ Table 1 Ink Preparation of the Examples Special Ink 1 Ink 2 Ink 3 Ink 4 Example Example Example Example Ink Color Black Blue Black Black Colorant Carbon Black Printex 25 (trade name of Dequssa Company) Pigment Pigment 7.00 7.00 Chromofine Blue 4965 (Dainichiseika Color & Chemicals Mfg. Co., Ltd.'s trade name_) Pigment 7.50 Colorant Water Black R455 (trade name of Orient Chemical Industries, Ltd.) dye 7.00 Water Yellow 6C (Orient Chemical Industries, Ltd . The product name of the public W) dye 1.00 pigment styrene maleic acid resin ammonium salt 2.00 2.00 Zhuzhu agent styrene acrylic resin ammonium salt 2.30 liquid propylene glycol 18.00 15.00 15.00 ^ glycoside oil 10.00 10.00 propylene oxide of diglycoside oil 4 mol Additives 10.00 Prevent maltitol volatile substances 5.00 5.00 5.00 5.00 Surface active potassium soap 0.50 0.40 0.50 (moisturizing) noodles 0.20 0.40 full gas alkyl phosphate 0.20 0.10 _ gas-based courtyard vinegar 0.30 0.20 antiseptic Sodium pyridinate 0.10 0.10 0.10 0.10 Enzyme saponin 0.10 0.10 0.10 0.10 PH Amine Methyl Propanol Monomer 0.30 0.30 .030 0.20 Viscosity Chinese rubber KELXZAN HP (trade name of Sansho Co., Ltd. Public Control Agent Division) 0.30 0.30 0.40 0.20 Polyacrylic acid Hiviswako 105 (Wake Pure Chemical) in crosslinked form Trade name of Industries Ltd.) 0.10 0.20 Polyvinylpyrrolidone PVP-K90 (trade name of GAFCo., Ltd.) 5.00 Ion exchange water 66.50 58.60 70.40 59.50 Total 100.00 100.00 100.00 100.00 In 25 ^, 38.4 86 (^ Ink viscosity at mPa.sec 130 200 320 400 to 25 ° C, 384 sec · 1 Ink viscosity at mPa.sec 25 40 30 80 Ink surface tension at 25 ° C (mN / m) 28.0 30.5 23.5 25.4 Remarks Ink of the present invention Ink of the present invention Ink of the present invention Ink of the present invention II—i I I -..... = II »L · 士 ^ —II n =------- 1 ^ 1 n ϋ— ^ i knot (please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210X 297 mm) 567148
A B 五、發明説明(表2 比較性實施例之墨水配製及特性 經濟部智慧財產局員工消費合作社印製 墨水5 墨水6 墨水7 墨水8 比較1生 實施例 比較性 實施例 比較性 實施例 比較性 實施例 墨水顏色 黑色 藍色 黑色 黑色 著色劑 碳黑Piintex 25 (Dequssa公司之商品名)顏料 顏料 7.00 7.00 7.00 駄菁藍Chromofine Blue 4965 (Dainichiseika Color & Chemicals Mfg. Co.,Ltd.公司之商品 名)顏料 7.50 著色劑水黑 R455 (Orient Chemical Industries,Ltd. 染料 公司之商品名)染料 水黃 6C (Orient Chemical Industries,Ltd.公 司之商品名)染料 顏料 苯乙烯馬來酸樹脂銨鹽 2.00 2.00 2.00 分散劑 苯乙烯丙烯酸樹脂銨鹽 2.30 液體 丙二醇 , 15.00 18.00 介質 甙油 10.00 10.00 10.00 二甙油之氧化丙烯4莫耳加成物 10.00 10.00 防止揮麥芽糖醇 發物質 5.00 5.00 5.00 5.00 表面活 鉀皂 扯漸| 0.40 0.50 0.50 (fit劑)箆纖鉀 0.20 全氟烷基磷酸酯 0.10 0.20 以氣爲基之焼基醋 0.20 0.20 防腐劑 啶化鈉 0.10 0.10 0.10 0.10 防銹劑 皂草甙 0.10 0.10 0.10 0.10 pH調 胺甲基丙醇 整劑 0.30 0.30 0.30 0.20 黏度 漢生膠 KELXZAN HP (SANSHO Co.,Ltd. 控制劑公司之商品名) 0.60 0.10 交聯形式之聚丙備酸Hiviswako 105 (Wake Pure Chemical Industries Ltd.公司之商品名) 0.10 0.02 0.20 聚乙烯基吡咯烷酮PVP-K90 (GAF Co.,Ltd. 公司之商品名) 8.00 15.00 離子交換水 56.70 58.98 51.60 64.80 總量 100.00 100.00 100.00 100.00 在SStWjsec·1下之墨水黏度(mPa.sec) 650 18 350 30 在25°C,384 sec·1 下之墨水黏度(mPa.sec) 80 7 200 8 在25°C下之墨水表面張力(mN/m) 28.6 29.7 30.9 25.5 備註 38.4 sec'1 黏度ΐ 38.4 sec'1 黏度i 384 sec·1 黏度1 38.4 sec·1 黏度丨 384 sec“ 黏度i 个表示比本發明之範圍還高,丨表示比本發明之範圍 還低。 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 絮- 、-口 絲 567148 A7 B7 五、發明説明(3全 表3 實施例之墨水從動件之配製及特性 經濟部智慧財產局員工消費合作社印製 從動件A 從動件B 從動件C 從動件D 實施例 實施例 實施例 實施例 墨水從動件 調備物 基礎油:聚丁烯平均分子量1350注解1 50.0 基礎油:礦物油平均分子量740注解2 96.5 92.0 94.0 44.0 基礎油:聚丁烯平均子量580注解3 增稠劑:磷酸酯之鈣鹽 注解4 3.5 增稠劑:細粒二氧化矽 注解5 增稠劑:聚苯乙烯-聚乙烯丁烯-聚苯乙烯 成塊共聚物 注解6 3.0 增稠劑:氫化苯乙烯丁二烯橡膠注解7 2.5 增稠劑:聚苯乙烯-聚乙烯丁嫌-聚傭烴結晶 成塊共聚物 注解8 5.0 增稠劑:聚烯烴結晶·聚乙烯丁烯-聚烯烴結 晶 成塊共聚物 注解9 1.0 增稠劑:聚苯乙嫌-丁燃橡膠-聚苯乙烯 成塊共聚物注解10 7.5 增稠劑:聚苯乙烯-異戊間二烯橡膠-聚苯乙 烯 成塊共聚物 注解11 增稠劑:二-甲基二-十八烷基銨澎潤土 注解12 添加劑:以氟爲基之表面活性劑 注解13 0.5 0.5 墨水從動件 特性 Ταηδ値(25°C)0.06弧度/秒 086 0,86 0.94 0.55 Tan6値(25°C)0.25弧度/ί少 1.08 0.87 0.95 0.58 Tan6値(25°C)0.63弧度/秒 0.98 0.91 0.90 0.72 TaW値(25。〇 1.0弧度傲 0.87 0.91 0.89 0.85 Tan6値(25°C)4.0弧度渺 0.92 0.94 0.88 1.09 Tan5値(25。〇6.3弧度傲 0.91 0.96 0.85 1.61 Tan6値(25°C) 10弧度/?少 0.78 1.01 0.81 1.24 Tan5値(25°C)40弧度/1 少 0.67 1.05 0.78 1.02 Tan5値(25〇C)63弧度/秒 0.65 1.22 0.81 0.97 Τηηδ値(25°C) 100弧度少 0.69 1.42 I 0.81 0.98 Tan5値(25°C)400弧度/秒 0.75 1.50 1 0.83 1.03 Tan5値(25〇C)600弧度漱 0.82 1.55 1.14 丨 0.90 Tan5値(25°C)650弧度/秒 丨 0.83 1.58 1.15 丨 0.92 在20(^(^下之黏度値如?3义〇) 5050 3970 3240 ' 6020 --------ί丨裝----Ί--訂------線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) Λ^4規格(21〇X 297公釐) 567148AB V. Description of the invention (Table 2 Ink formulation and characteristics of the comparative examples Ink printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Consumer Cooperatives Printed ink 5 Ink 6 Ink 7 Ink 8 Comparison 1 Example Comparative Example Comparative Example Comparative Example Example Ink Color Black Blue Black Black Coloring Agent Carbon Black Piintex 25 (trade name of Dequssa Company) Pigment Pigment 7.00 7.00 7.00 Chromofine Blue 4965 (Dainichiseika Color & Chemicals Mfg. Co., Ltd. company trade name ) Pigment 7.50 Colorant Water Black R455 (trade name of Orient Chemical Industries, Ltd. dye company) dye water yellow 6C (trade name of Orient Chemical Industries, Ltd. company) dye pigment styrene maleic acid ammonium salt 2.00 2.00 2.00 Dispersant Styrene acrylic resin ammonium salt 2.30 Liquid propylene glycol, 15.00 18.00 Medium glycoside oil 10.00 10.00 10.00 Dipropylene oil propylene oxide 4 mol adduct 10.00 10.00 Prevent maltitol volatile substances 5.00 5.00 5.00 5.00 Surface active potassium soap pulls 0.40 0.50 0.50 (fitting agent) Potassium 0.20 Perfluoroalkyl phosphate 0.10 0.20 Gas based vinegar 0.20 0.20 Preservative sodium pyridinium 0.10 0.10 0.10 0.10 Rust inhibitor saponin 0.10 0.10 0.10 0.10 pH adjuster methyl propanol monoblock 0.30 0.30 0.30 0.20 Viscosity KELXZAN HP (trade name of Sansho Co., Ltd. control agent company) 0.60 0.10 Polyisopropionate Hiviswako 105 (trade name of Wake Pure Chemical Industries Ltd.) 0.10 0.02 0.20 polyvinyl based Pyrrolidone PVP-K90 (trade name of GAF Co., Ltd.) 8.00 15.00 Ion-exchanged water 56.70 58.98 51.60 64.80 Total 100.00 100.00 100.00 100.00 Ink viscosity (mPa.sec) at SStWjsec · 1 650 18 350 30 at 25 Ink viscosity (mPa.sec) at ° C, 384 sec · 1 80 7 200 8 Ink surface tension (mN / m) at 25 ° C 28.6 29.7 30.9 25.5 Remarks 38.4 sec'1 viscosityΐ 38.4 sec'1 viscosity i 384 sec · 1 viscosity1 38.4 sec · 1 viscosity 丨 384 sec "viscosity i means higher than the range of the present invention, 丨 means lower than the range of the present invention. This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X297 mm) (please read the precautions on the back before filling this page).---Mouth silk 567148 A7 B7 V. Description of the invention (3 full table 3 Examples) Preparation and characteristics of the ink follower Printed follower A Follower B Follower C Follower D Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economics Example Example Example Example Ink Prepared Material Base oil: Polybutene average molecular weight 1350 Note 1 50.0 Base oil: Mineral oil average molecular weight 740 Note 2 96.5 92.0 94.0 44.0 Base oil: Polybutene average molecular weight 580 Note 3 Thickener: Phosphate calcium salt Note 4 3.5 Thickener: Fine-grained silica Note 5 Thickener: Polystyrene-polyvinylbutene-polystyrene block copolymer Note 6 3.0 Thickener: Hydrogenated styrene butadiene rubber Note 7 2.5 Thickening Agent: Polystyrene-Polybutylene-Polymer crystalline block copolymers Note 8 5.0 Thickener: Polyolefin crystalline · Polybutylene-Polyolefin crystalline block copolymers Note 9 1.0 Thickener: Poly Acetophenone Notes on rubber-polystyrene block copolymers 10 7.5 Thickener: Polystyrene-isoprene rubber-polystyrene block copolymers Note 11 Thickener: Di-methyldi-octadecane Annotation of ammonium ammonium bentonite 12 Additive: Annotation of surfactant based on fluorine 13 0.5 0.5 Characteristics of ink follower Tαηδ 値 (25 ° C) 0.06 radians / second 086 0,86 0.94 0.55 Tan6 値 (25 ° C) 0.25 radians / less 1.08 0.87 0.95 0.58 Tan6 値 (25 ° C) 0.63 radians per second 0.98 0.91 0.90 0.72 TaW 値 (25.1.0 radians 0.87 0.91 0.89 0.85 Tan6 値 (25 ° C) 4.0 radians 0.92 0.94 0.88 1.09 Tan5 値 (25.〇6.3 radians proud 0.91 0.96 0.85 1.61 Tan6 値 (25 ° C) 10 radians /? 0.77 1.01 0.81 1.24 Tan5 値 (25 ° C) 40 radians / 1 less 0.67 1.05 0.78 1.02 Tan5 値 (25 〇C) 63 radians / second 0.65 1.22 0.81 0.97 Tηηδ 値 (25 ° C) 100 radians less 0.69 1.42 I 0.81 0.98 Tan5 値 (25 ° C) 400 radians / second 0.75 1.50 1 0.83 1.03 Tan5 値 (25 ° C) 600 Radius 0.82 1.55 1.14 丨 0.90 Tan525 (25 ° C) 650 radians / second 丨 0.83 1.58 1.15 丨 0.92 at 20 (^ (^ 下 之 之Viscosity (such as 3 meanings) 5050 3970 3240 '6020 -------- ί 丨 ---------- Order ------ (Please read the precautions on the back before filling in this Page) This paper size is applicable to Chinese National Standard (CNS) Λ ^ 4 specification (21〇X 297 mm) 567148
AA
7 B 五、發明説明(3各 表4 比較性實施例之墨水從動件之配製及特性 經濟部智慧財產局員工消費合作社印製 從動件Ε 從動件F 從動件G 從動件Η 比較性 實施例 比較性 實施例 比較性 實施例 比較性 實施例 墨水從動件 調備物 基礎油:聚丁烯平均分子量1350注解1 99.1 50.0 基礎油:礦物油平均分子量740注解2 99.2 19.5 基礎油:聚丁烯平均分子量580注解3 97.5 增稠劑:磷酸酯之鈣鹽 注解4 0.3 增稠劑:細粒二氧化矽 注解5 2.5 增稠劑:聚苯乙像聚乙烯丁嫌-聚苯乙烯 成塊共聚物注解6 增稠劑:氫化苯乙烯丁二烯橡膠注解7 0.9 0.4 增稠劑:聚苯乙舔聚乙烯丁舔聚纟希烴結晶 成塊共聚物注解8 增稠劑:聚烯烴結晶-聚乙烯丁烯-聚烯烴結 晶 成塊共聚物 注解9 增稠劑:聚苯乙漆丁烯橡膠-聚苯乙烯 成塊共聚物 注解10 27.0 增稠劑:聚苯乙烯-異戊間二烯橡膠-聚苯乙 烯 成塊共聚物 注解11 3.0 增稠劑:二-甲基二·十八烷基敍澎潤土 注解12 添加劑:以氟爲基之表面活性劑 注解13 0.5 墨水從動件 特性 Tan5値(25°C)0.06弧度渺 22.52 0.84 1.51 0.08 Tan6値(25°C)0.25弧度渺 22.54 0.86 1.53 0.09 Tan5値(25°C)0.63弧度/秒 24.92 0.92 1.40 0.09 Ταηδ値(25t) 1.0弧度/秒 27.16 0.99 1.34 0.12 Tan5値(25°C)4.0弧度少 31.85 1.06 1.27 0.13 ΤΣίηδ値(25t)6.3弧度/?少 28.49 1.20 1.21 0.24 Tan5値(25〇C)10弧度/秒 25.03 1.28 1.15 0.39 Tan5値(25°C)40弧度/秒 23.99 1.39 1.00 0.41 Tan5値(25°C)63弧度/秒 22.14 1.63 0.96 0.48 Ταηδ値(25°C) 100弧度 30.39 2.04 1.02 0.53 Tan5値(25°C)400弧度 31.43 2.99 1.61 0.62 Tan5値(25°C)600弧度/秒 32.64 2.50 2.56 0.74 - Tan5値(25°C)650弧度/ί少 32.55 2.50 2.57 0.89 在20(^(:*丨下之黏度値(11^父(:) 2000 2800 490 12500 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 經濟部智慈財產局員工消費合作社印製 567148 A7 B7 五、發明説明( 表3及表4之注解如下所列: 注解1:聚丁烯30N(NOFC〇RP〇RATI〇N公司:商品名) 注解 2:Diana 處理油 PW-38 (Idemitsu Kosan Co. Ltd.: 商品名) 注解 3:Nissan聚丁烯 015N (N〇F CORPORATION公司: 商品名) 注解 4:Crodax DP-30 (CRODA JAPAN K.K.公司:商品名 ) 注解 5:AER〇SIL-974D (Nippon Aerosil Co·,Ltd公司:商 品名) 注角军 6:DEPT〇N 8007 (KURARAY C〇.LTD.公司:商口口口名 ) 注解 7:Tuftec H1141 (ASAHI KASEI Corporation公司:商 品名) 注解8:DYNAR〇N 4600P (JSR C〇.LTD.公司:商品名) 注解 9:DYNARON 6200P (JSR CO. LTD.公司:商品名) 注解 10:Asaprene T-431 (ASAHI KASEI Corporation公司: 商品名) 注解 ll:Solprene-418 (ASAHI KASEI Corporation公司:商 品名) 注解 12: Ben ton 34 (Wilbur-ellis C〇.LTD.公司:商品名) 注解 13:EFtop. EF-801 (MITUBISHI MATERIALS (:〇1^?〇1^八丁1〇1^公司:商品名) 本紙張尺度適用中國國家標準(CNS ) Λ4規格(210X 297公釐) I I I I n批衣 Ί -訂 I 線 (請先閱讀背面之注意事項再填寫本頁) 567148 A7 B7 (8)因輕微碰撞之墨水散開 五、發明説明(3& 表5 實施例 墨水 墨水從動件 接頭 筆尖 (1)書寫觸感 (2)墨水流出量 (3)濺污之評估 (4)劃線之羽毛邊 (5)快速書寫之隨動性 (6)墨水流出之穩定性 (7)因輕微碰撞之斷水 (9)抗向後滲漏特性 (10)筆尖之耐磨損性 實施例7 B V. Description of the invention (3 Tables 4) Preparation and characteristics of the ink follower of the comparative example Printed follower E Follower F Follower G Follower G Comparative Example Comparative Example Comparative Example Comparative Example Ink Follower Preparation Base Oil: Polybutene Average Molecular Weight 1350 Note 1 99.1 50.0 Base Oil: Mineral Oil Average Molecular Weight 740 Note 2 99.2 19.5 Base Oil : Polybutene average molecular weight 580 Note 3 97.5 Thickener: Phosphate calcium salt Note 4 0.3 Thickener: Fine-grained silica Note 5 2.5 Thickener: Polystyrene like polyethylene butadiene-polystyrene Notes to block copolymers 6 Thickener: Hydrogenated styrene butadiene rubber Note 7 0.9 0.4 Thickener: Polystyrene styrene Polybutylene polyisocyanate Crystal block copolymer Note 8 Thickener: Polyolefin Crystalline-polyvinylbutene-polyolefin crystalline block copolymer Note 9 Thickener: Polystyrene butadiene rubber-polystyrene block copolymer Note 10 27.0 Thickener: Polystyrene-isoprene Ene rubber-poly Ethylene Block Copolymer Note 11 3.0 Thickener: Di-methyldi · octadecyl Supentonite Note 12 Additive: Fluorine-based Surfactant Note 13 0.5 Ink Follower Characteristics Tan5 値 (25 ° C) 0.06 radians 22.52 0.84 1.51 0.08 Tan6 値 (25 ° C) 0.25 radians 22.54 0.86 1.53 0.09 Tan5 値 (25 ° C) 0.63 radians / second 24.92 0.92 1.40 0.09 ταηδ 値 (25t) 1.0 radians / second 27.16 0.99 1.34 0.12 Tan5 値 (25 ° C) 4.0 radians less 31.85 1.06 1.27 0.13 ΤΣίηδ 値 (25t) 6.3 radians /? 28.49 1.20 1.21 0.24 Tan5 値 (25 ° C) 10 radians per second 25.03 1.28 1.15 0.39 Tan5 値 (25 ° C) 40 radians / second 23.99 1.39 1.00 0.41 Tan5 値 (25 ° C) 63 radians / second 22.14 1.63 0.96 0.48 ταηδ 値 (25 ° C) 100 radians 30.39 2.04 1.02 0.53 Tan5 値 (25 ° C) 400 radians 31.43 2.99 1.61 0.62 Tan5 値 (25 ° C) 600 radians / second 32.64 2.50 2.56 0.74-Tan5 値 (25 ° C) 650 radians / less less 32.55 2.50 2.57 0.89 Viscosity below 20 (^ (: * 丨 the viscosity 値 (11 ^ parent ( :) 2000 2800 490 12500 (Please read the precautions on the back before filling this page) This paper ruler Applicable to China National Standard (CNS) A4 specifications (210X297 mm) Printed by the Employees ’Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs 567148 A7 B7 V. Description of the invention (Notes to Tables 3 and 4 are listed below: Note 1: Polybutadiene 30N (NOFC〇RP〇RATION company: trade name) Note 2: Diana treatment oil PW-38 (Idemitsu Kosan Co. Ltd .: trade name) Note 3: Nissan polybutene 015N (N〇F Corporation: Trade name) Note 4: Crodax DP-30 (CRODA JAPAN KK: trade name) Note 5: AER〇SIL-974D (Nippon Aerosil Co., Ltd .: trade name) Note Army 6: DEPT〇N 8007 (KURARAY C〇.LTD. Company: Shangkou mouth name) Note 7: Tuftec H1141 (ASAHI KASEI Corporation: trade name) Note 8: DYNARON 4600P (JSR C〇.LTD. Company: trade name) Note 9: DYNARON 6200P (JSR CO. LTD. Company: trade name) Note 10: Asaprene T-431 (ASAHI KASEI Corporation: trade name) Note ll: Solprene-418 (ASAHI KASEI Corporation: trade name) Note 12: Ben ton 34 ( Wilbur-ellis Co., Ltd .: Trade name) Note 13 : EFtop. EF-801 (MITUBISHI MATERIALS (: 〇1 ^? 〇1 ^ 八 丁 1〇1 ^ company: trade name) This paper size applies to Chinese National Standard (CNS) Λ4 specifications (210X 297 mm) IIII n batch订-Order I line (please read the precautions on the back before filling this page) 567148 A7 B7 (8) The ink spread due to slight collision 5. Description of the invention (3 & Table 5 Example ink ink follower connector nib (1 ) Writing feel (2) Amount of ink outflow (3) Evaluation of splattering (4) Feather edge of scribing (5) Follow-up of fast writing (6) Stability of ink outflow (7) Break due to slight collision Water (9) Backward Leakage Resistance (10) Wear Resistance of Pen Tips Example
HI ί im— n« n tmri.n In If (請先閲讀背面之注意事項再填寫本頁) 經濟部智慈財產局員工消費合作社印製HI ί im— n «n tmri.n In If (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Office of the Ministry of Economic Affairs
567148 五、發明説明(^ 經濟部智慈財產局員工消費合作社印製 (表6 )比較性實施例 比較性實施例 11 12 13 14 15 16 17 18 19 20 21 22 23 墨水 (5) ⑹ ⑺ ⑻ ⑴ ⑴ ⑴ ⑶ ⑴ ⑴ ⑵ ⑶ ⑹ 墨水從動件 A A A A E F G Η Ε A C Η F 接頭 ⑴ ⑴ ⑴ ⑴ ⑴ ⑴ ⑴ ⑴ ⑵ ⑴ ⑴ ⑴ ⑵ 筆尖 ⑴ ⑴ ⑴ ⑴ ⑴ ⑴ ⑴ ⑴ ⑴ ⑵ ⑵ ⑵ ⑵ (1)書寫觸感 X 〇 X 〇 〇 〇 〇 Δ 〇 X X Δ X ⑵墨水流出量 X 〇‘ X 〇 〇 〇 〇 X 〇 △ Δ X Δ (3)濺污之評估 〇 Δ 〇 Δ 〇 〇 Δ 〇 〇 〇 〇 X Δ ⑷劃線之羽毛邊 〇 X 〇 X 〇 〇 〇 〇 〇 〇 〇 〇 X ⑶快速書寫之隨動性 X 〇 X 〇 Δ 〇 〇 Δ △ 〇 〇 X 〇 ⑹墨水流出之穩定性 〇 〇 〇 〇 〇 〇 〇 〇 〇 △ Δ 〇 Δ ⑺因輕微碰撞之斷水 〇 Δ Δ Δ 〇 〇 〇 〇 〇 〇 〇 Δ △ ⑻因輕微碰撞之墨水散開 〇 〇 〇 〇 X X X 〇 X 〇 〇 〇 〇 ⑼抗向後滲漏特性 〇 〇 〇 〇 〇 〇 〇 〇 X 〇 0 〇 X (10)筆尖之耐磨損性 0 〇 〇 〇 〇 〇 〇 〇 〇 Δ △ 〇 △ !- 1 - - —is - - - - ϋ- ί —1· - ϋ (請先閱讀背面之注意事項再填寫本頁) ·- 絲 i 本紙張尺度適用中國國家標準(CNS ) A4規格(210x 297公釐) 567148 A7 ______B7_ 五、發明説明(d 根據本發明,使用水基墨水之原子筆可以低成本生產 ’輕微接觸即可平滑地書寫且劃線時幾乎不會發生濺污和 分裂。再者,其比平常速度快二或多倍下書寫也不會引起 斷水’縱使以筆端點向上直立並卸下筆帽一點也不會向後 滲漏。根據本發明之更佳實施例,使用水基墨水之原子筆 ,到最後還都能獲得穩定的墨水流出。 (請先閲讀背面之注意事項再填寫本頁) 經濟部智慈財產局員工消費合作社印製 ^4 0 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)567148 V. Description of the invention (^ Printed by the Consumer Cooperatives of the Intellectual Property Office of the Ministry of Economy (Table 6) Comparative Example Comparative Example 11 12 13 14 15 16 17 18 19 20 21 22 23 Ink (5) ⑹ ⑺ ⑻ ⑴ ⑴ ⑶ ⑶ ⑶ ⑴ ⑶ ⑶ ⑹ Ink follower AAAAEFG Η AC AC Η F connector Writing touch X 〇X 〇〇〇〇〇 △ 〇XX Δ X ⑵Ink efflux X 〇 'X 〇〇〇〇〇X 〇 △ Δ X Δ (3) Evaluation of staining 〇Δ 〇Δ 〇〇Δ 〇〇〇 〇X Δ ⑷Frayed feather edge 〇X 〇X 〇〇〇〇〇〇〇〇〇X ⑶ follow-up fast writing X 〇X 〇Δ 〇〇Δ △ 〇〇X 〇⑹ stability of ink out 〇〇 〇〇〇〇〇〇〇〇 △ △ 〇Δ 断 water due to slight collision △ Δ Δ 〇〇〇〇〇〇〇〇〇 △ △ ⑻ due to light collision ink spread out XXXXXX 〇X 〇〇〇〇〇〇⑼ Anti-backward leakage characteristics 〇〇〇 〇〇〇〇〇〇〇〇〇〇〇 (10) Wear resistance of the pen tip 0 〇〇〇〇〇〇〇〇〇Δ △ 〇 △!-1---is----ϋ- ί —1 ·- ϋ (Please read the notes on the back before filling this page) ·-Silk i This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210x 297 mm) 567148 A7 ______B7_ 5. Description of the invention (d According to the present invention, use Water-based ink ball pens can be produced at low cost. 'Slight contact makes writing smooth and there is almost no splatter and splitting when scribing. Moreover, it does not cause breaks when writing two or more times faster than usual. Water will not leak back even if the pen end is upright and the cap is removed. According to a more preferred embodiment of the present invention, a stable ink outflow can be obtained in the end using a water-based ink ball pen. (Please (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Office of the Ministry of Economic Affairs ^ 4 0-This paper size is applicable to China National Standard (CNS) A4 (210X297 mm)
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001063872A JP4522007B2 (en) | 2001-03-07 | 2001-03-07 | Water-based ballpoint pen |
Publications (1)
Publication Number | Publication Date |
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TW567148B true TW567148B (en) | 2003-12-21 |
Family
ID=18922789
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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TW091104178A TW567148B (en) | 2001-03-07 | 2002-03-06 | Ballpoint pen using water based ink |
Country Status (4)
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JP (1) | JP4522007B2 (en) |
KR (1) | KR100440527B1 (en) |
CN (1) | CN1247386C (en) |
TW (1) | TW567148B (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4676147B2 (en) * | 2004-02-27 | 2011-04-27 | 株式会社日本礦油 | Ink backflow preventive composition for ballpoint pens |
EP2223979B1 (en) * | 2007-11-20 | 2013-06-26 | Zebra Co., Ltd. | Writing ink composition |
JP5483891B2 (en) * | 2009-01-23 | 2014-05-07 | 三菱鉛筆株式会社 | Ink follower and water-based ballpoint pen using the same |
JP2012017437A (en) * | 2010-07-09 | 2012-01-26 | Mitsubishi Pencil Co Ltd | Water-based ball-point pen |
CN106325048B (en) * | 2015-06-30 | 2018-10-09 | 深圳市雷诺表业有限公司 | A kind of low-cost energy-saving environmental protection oiling pen and preparation method thereof |
CN109294084B (en) * | 2018-11-14 | 2020-11-03 | 上海晨光文具股份有限公司 | Silicone grease and preparation method thereof, ink follow-up agent applying silicone grease and preparation method of ink follow-up agent |
CN110872459B (en) * | 2019-12-20 | 2022-06-14 | 上海晨光文具股份有限公司 | Water-based ink |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2859068B2 (en) * | 1993-02-26 | 1999-02-17 | 三菱鉛筆株式会社 | Aqueous ballpoint pen and ink follower |
JPH06312596A (en) * | 1993-04-28 | 1994-11-08 | Teiboo Kk | Ballpoint pen tip for water base ink and manufacture thereof |
JP3590913B2 (en) * | 1994-04-29 | 2004-11-17 | パイロットインキ株式会社 | Ballpoint pen tip |
JP2865586B2 (en) * | 1995-02-28 | 1999-03-08 | 三菱鉛筆株式会社 | Ballpoint pen |
JP3596154B2 (en) * | 1996-03-29 | 2004-12-02 | ぺんてる株式会社 | Writing implement |
JPH1142884A (en) * | 1997-07-28 | 1999-02-16 | Mitsubishi Pencil Co Ltd | Ink follow-up material gelled product for water-based ball-point pen |
JP2000218984A (en) * | 1998-05-27 | 2000-08-08 | Mitsubishi Pencil Co Ltd | Writing utensil |
JP3439665B2 (en) * | 1998-08-21 | 2003-08-25 | 株式会社パイロット | Knock ballpoint pen |
JP2000096033A (en) * | 1998-09-24 | 2000-04-04 | Mitsubishi Pencil Co Ltd | Ink follow-up body composition for aqueous ballpoint pen |
KR20010001692A (en) * | 1999-06-08 | 2001-01-05 | 김충경 | Wear resistance treatment nethod of ball-pen tip |
JP2001030676A (en) * | 1999-07-16 | 2001-02-06 | Pilot Ink Co Ltd | Writing instrument |
GB2373251B (en) * | 1999-12-24 | 2004-03-31 | Mitsubishi Pencil Co | Ink for ball pen and ball pen |
JP4387044B2 (en) * | 2000-06-12 | 2009-12-16 | 三菱鉛筆株式会社 | Ink follower and water-based ballpoint pen having the same |
JP2002046384A (en) * | 2000-08-02 | 2002-02-12 | Mitsubishi Pencil Co Ltd | Ballpoint pen tip made of metal |
-
2001
- 2001-03-07 JP JP2001063872A patent/JP4522007B2/en not_active Expired - Fee Related
-
2002
- 2002-03-06 TW TW091104178A patent/TW567148B/en not_active IP Right Cessation
- 2002-03-07 CN CNB021068917A patent/CN1247386C/en not_active Expired - Fee Related
- 2002-03-07 KR KR10-2002-0012129A patent/KR100440527B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR100440527B1 (en) | 2004-07-19 |
CN1247386C (en) | 2006-03-29 |
JP2002264580A (en) | 2002-09-18 |
JP4522007B2 (en) | 2010-08-11 |
CN1374202A (en) | 2002-10-16 |
KR20020071781A (en) | 2002-09-13 |
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