TW565543B - Method for producing wet-type block-like white smoke-screen bomb - Google Patents

Method for producing wet-type block-like white smoke-screen bomb Download PDF

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Publication number
TW565543B
TW565543B TW88110613A TW88110613A TW565543B TW 565543 B TW565543 B TW 565543B TW 88110613 A TW88110613 A TW 88110613A TW 88110613 A TW88110613 A TW 88110613A TW 565543 B TW565543 B TW 565543B
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Taiwan
Prior art keywords
white smoke
bomb
latex
block
product
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TW88110613A
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Chinese (zh)
Inventor
Yung-Ming Wang
Original Assignee
204Th Arsenal Materiel Product
Yung-Ming Wang
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Priority to TW88110613A priority Critical patent/TW565543B/en
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Publication of TW565543B publication Critical patent/TW565543B/en

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Abstract

A method for producing a wet-type block-like white smoke-screen bomb comprises: uniformly mixing 30-40% of ammonium perchlorate, 30-40% of zinc oxide, 5-15% of ammonium chloride, 5-15% of lactose, and 15-25% of a polymer emulsion; forming the mixture in a mold; and removing the molding from the mold to be dried into a block; no heating is required during the processing and the dried product has an excellent structural strength without the need of being loaded into a container and has a high water resistance; the ignition temperature is higher than 230 DEG C and the product has a high storage safety. After being neatly stacked, the first block of product on top can be ignited and the combustion can continue downwards. The white fume generated after ignition has a low pollution characteristerics.

Description

565543 Μ 五、發明説明( 本發明為一種濕式塊狀白色煙幕彈之製法,係將過氯 酸氨、氧化鋅、氯化銨、乳糖以及高分子乳膠混合後置入 成型糢具中予以風乾成型,再與點火器結合而成,使得成 塊狀之煙幕彈成品不需另由容器裝填,而且防水性高、可 塑形,同時在引燃後具有低污染之特性。 訂 本發明為一種濕式塊狀白色煙幕彈之製法,係將過氣 酸銨、氧化辞、氯化銨、乳糖以及高分子乳膠均勻混合後, 置入成型模具中加壓成型,再取出乾燥成塊狀。加工過程 中不需加熱’故可節約成本並減少加工危險性。此種製法 所製造出之白色煙幕彈,乾燥後的成品結構 另由容器裝填,即可定型;而且防水性高;引燃溫= 230。(:以上,儲存安全性高。成品整齊堆疊後,由上方 第-塊成品引燃,可連續向下燃燒。引燃後所產生的氣體 具有低污染之特性。 傳統的白色煙幕彈的各式配方中分別含有六氯乙烧 (d)、六氯苯(C6C16)、磷或硫等成分,引燃時會產生 2污染性的氣體。而且傳統的煙幕彈f由容器裝填,才能 疋型。不含包裝的傳統煙幕彈半成品不*防潮性,一旦受 潮,將影響發煙性能。 本《月之主要目的’在於提供一種濕式塊狀白色煙幕 彈之製法,承該製法所製造出之白色煙幕彈在成型時,不 f加熱’成品不需另由容器裝填,即可Μ;而且防水性 二,同時在引燃後所產生之氣體具有低污染之特性,能有 效提昇白色煙幕彈的品質。565543 Μ 5. Description of the invention (The present invention is a method for manufacturing a wet block-shaped white smoke screen bomb, which is prepared by mixing ammonia perchlorate, zinc oxide, ammonium chloride, lactose, and polymer latex into a molding mold and air-drying. Combined with the igniter, the finished smoke screen bomb does not need to be filled by another container, and has high water resistance and plasticity. At the same time, it has the characteristics of low pollution after ignition. The invention is a wet block. The method of making white smoke screen bombs is that after homogeneous mixing of peroxyacid, oxidized acid, ammonium chloride, lactose and polymer latex, it is put into a molding mold for pressure molding, and then taken out and dried into a block. No heating is required during processing. 'Therefore, it can save costs and reduce the danger of processing. For the white smoke bomb manufactured by this manufacturing method, the finished product structure after drying is filled by a container and can be shaped; and it is highly waterproof; the ignition temperature = 230. (: above, High storage safety. After the finished products are neatly stacked, they will be ignited by the first piece of the upper product, which can be continuously burned down. The gas produced after ignition is of low pollution. Traditional The various formulas of white smoke bombs contain hexachloroethane (d), hexachlorobenzene (C6C16), phosphorus or sulfur, etc., which will generate 2 polluting gases when ignited. And the traditional smoke bomb f is filled by a container. The traditional smoke screen semi-finished product without packaging is not moisture-proof. Once wet, it will affect the smoking performance. The main purpose of this month is to provide a wet block white smoke screen bomb manufacturing method. When the white smoke bomb is formed, it is not heated. The finished product does not need to be filled by another container, which can be M; and it is water-resistant. At the same time, the gas generated after ignition has low pollution characteristics, which can effectively improve the quality of the white smoke bomb. .

欲達成上述目的之特徵,係將係將30—40%的過氯酸 銨、30-40%的氧化鋅、5 —15%的氯化銨、5 —15%的乳糖以及 15-25%的高分子乳膠均勻混合後,置入成型模具中加壓成 型’再取出乾燥成塊狀。 本發明之其它目的與詳細之構造,將藉由以下詳細說 明而使之更為明確,同時參閱所附各圖,俾可使本發明之 技術内容更進一步地揭示明瞭: ,首先如第一圖所示,本發明「濕式塊狀白色煙幕彈之 製法」,係將過氯酸氨(Nh4C1〇4 )、氧化辞(Zn〇)、氯化 銨(nh4ci)、乳糖(Cl2H22H2〇)以及高分子乳膠混合後置 入成型糢具中予以風乾成塊狀,再與點火器結合而成。 經由本發明者多次實驗後,各原料最佳的比例分別 為:過氯酸氨:30-40% ;氧化辞·· 3(M〇% ;氯化銨:1〇 25 %,乳糖·· 0-10% ;高分子乳膠:15 25%,其中,高分 子乳膠之作用主要在於高溫狀態下溶解後,回到常溫時能 將各原料凝結成塊狀,其成分可為粉末由溶劑稀釋後所 成;而乳糖可由蔗糖或殿粉代替。 本發明利用過氯酸銨與氧化辞反應可生成氣化辞白色 煙幕的化學特性,將過氣酸銨與氧化鋅作為燃燒反應的主 要材料;也利用到反應熱可昇華出氣化銨白色煙幕的物理 特性,將氯化銨作為緩燃劑以避免燃燒反應過度破壞白色 煙幕的特性;再利用高分子及乳糖内含大量碳、氫元素的 特性,以高分子乳膠及乳糖作為燃燒反應的燃料來源;又 利用南分子乳膠凝結的特性,將所有的粉末一起凝結成塊 565543 A7 —— ----- - B7 五、發明説明() : 狀。因為各種粉末經過高分子乳膠包覆乾燥後產生彳方水 性,故增加了產品的防潮性能。而成品受高分子粘結的影 響,結構強度大增,故不再需要其他容器承裝,即已定型, 郎省了產π口的包裝成本,也解決了容器回收的問題。 綜上所述,本發明「濕式塊狀白色煙幕彈之製法」, 前所未見,此種製法所製造出之白色煙幕彈在成型時,不 需加熱,成品結構強度佳,不需另由容器裝填,即可定型· 而且防水性高;引燃溫度在230。0以上,儲存安全性高: 成品整齊堆疊後,由上方第一塊成品引燃,可連續向下辦 燒。引燃後所產生的氣體具有低污染之特性。種種的特性, 均顯示出本發明較習用者為佳,符合專利申請之要件,爰 依法提出專利申請。 圖示說明: 第一圖為本發明之流程示意圖。 (請先閱讀背面之注意事項再填寫本頁} 經濟部中央標隼局β工消費合作社印製 本紙張尺度適用中國國豕標準(CNS ) Α4規格(210 X 297公參)To achieve the above characteristics, 30-40% ammonium perchlorate, 30-40% zinc oxide, 5-15% ammonium chloride, 5-15% lactose, and 15-25% After the polymer latex is uniformly mixed, it is put into a molding mold and press-molded, and then taken out and dried into a block. The other objects and detailed structure of the present invention will be made clearer by the following detailed description, and referring to the accompanying drawings, the technical content of the present invention will be further revealed: As shown in the figure, the "method for producing a wet block-shaped white smoke screen" according to the present invention comprises ammonium perchlorate (Nh4C104), oxidation (Zn〇), ammonium chloride (nh4ci), lactose (Cl2H22H2〇), and a polymer. After the latex is mixed, it is put into a molding mold and air-dried into a block, and then combined with an igniter. After several experiments by the inventor, the optimal ratios of each raw material are: ammonia perchlorate: 30-40%; oxidative chemistry ... 3 (MO%; ammonium chloride: 105%, lactose ...) 0-10%; polymer latex: 15 25%, of which the role of polymer latex is mainly after dissolving at high temperature, the raw materials can be coagulated into agglomerates when returned to normal temperature, and its composition can be powder diluted by solvent The lactose can be replaced by sucrose or rice flour. The present invention uses the chemical properties of ammonium perchlorate and oxidation reaction to form a white smoke screen, and uses ammonium peroxyacid and zinc oxide as the main material for the combustion reaction; The heat of reaction can be used to sublimate the physical characteristics of the white smoke screen of gasified ammonium, and ammonium chloride is used as a flame retarder to avoid the excessive combustion reaction from destroying the characteristics of the white smoke screen; Polymer latex and lactose are used as fuel sources for the combustion reaction; and the coagulation characteristics of the South Molecular Latex are used to coagulate all the powders together to form a block 565543 A7 —— ------B7 V. Description of the invention (): Shape. Because of various After being dried by polymer latex coating, it will produce square water, which increases the moisture resistance of the product. The final product is affected by polymer bonding and the structural strength is greatly increased. Therefore, it is no longer necessary to load in other containers. Lang saves the packaging cost of producing π mouths, and also solves the problem of container recycling. In summary, the "wet block white smoke screen bomb manufacturing method" of the present invention has never been seen before, and the white smoke screen bomb manufactured by this manufacturing method has never been seen before. During molding, no heating is needed, and the finished product has good structural strength. It can be shaped without filling in another container. And it has high water resistance. The ignition temperature is above 230.0, and the storage safety is high. The first finished product can be ignited and can be burned continuously. The gas produced after ignition has low pollution characteristics. All the characteristics show that the present invention is better than the conventional one and meets the requirements of patent application. File a patent application. Illustration: The first picture is a schematic diagram of the process of the invention. (Please read the precautions on the back before filling out this page} Printed by the Central Standards Bureau of the Ministry of Economic Affairs Paper-scale hog suitable for China's national standard (CNS) Α4 Specifications (210 X 297 Counselor)

Claims (1)

565543 12565543 12 六、申請專利範圍 /、一種濕式塊狀白色煙幕彈之製法,係將30%-40%(重量百 分比)的過氯酸銨(NH4C104)、30%40%(重量百分比)的氧 化鋅(Zn〇)、5%45%(重量百分比)的氯化錢(NhCI)、 59M5%(重量百分比)乳糖(0¾ · ΗΌ)及15%-25%(重量百 分比)的水溶性高分子乳膠;其中,水溶性高分子乳膠可 爲壓克力共聚乳膠(Acrylic Copo丨ymer Emulsion)、聚苯乙 嫌乳膠(Polys-tyrene Emulsion)、乙烯-醋酸乙烯共聚合乳 膠(Vinyl Acetate-ethylene Copolymer Emulsion),混合後置 入成型模中加壓成型,再取出乾燥成塊狀,成品整齊堆 疊後,由上方第一塊成品引燃,可連續向下燃燒者,點 火燃燒時能連續發出白色煙幕爲其特徵。 ---------- (請先閱讀背而之注意事項再填寫本頁) Λ1Τ 丨· Μ濟部中央標準局乃工消f合作社印製 私 1明家_ (⑽)Λ4規格(2H)X 297公f )Scope of Patent Application 〇), 5% 45% (wt%) of chlorinated chloride (NhCI), 59M5% (wt%) of lactose (0¾ · ΗΌ) and 15% -25% (wt%) of water-soluble polymer latex; among them, The water-soluble polymer latex can be acrylic copolymer latex (Polymer-Emulsion), polystyrene-tyrene latex (Polys-tyrene Emulsion), ethylene-vinyl acetate copolymer latex (Vinyl Acetate-ethylene Copolymer Emulsion), after mixing It is put into a molding mold for pressure molding, and then taken out and dried into a block shape. After the finished product is neatly stacked, it is ignited by the first piece of the upper product. ---------- (Please read the precautions below and then fill out this page) Λ1Τ 丨 · Μ The Central Standards Bureau of the Ministry of Economic Affairs is a private printing company that prints _ (⑽) Λ4 specifications (2H) X 297 male f)
TW88110613A 1999-06-24 1999-06-24 Method for producing wet-type block-like white smoke-screen bomb TW565543B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2571752C1 (en) * 2014-10-22 2015-12-20 Акционерное Общество "Чебоксарское Производственное Объединение Им. В.И. Чапаева" Pyrotechnic composition of white signal

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2571752C1 (en) * 2014-10-22 2015-12-20 Акционерное Общество "Чебоксарское Производственное Объединение Им. В.И. Чапаева" Pyrotechnic composition of white signal

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