TW557551B - Two-bit mask ROM device and fabrication method thereof - Google Patents
Two-bit mask ROM device and fabrication method thereof Download PDFInfo
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- TW557551B TW557551B TW091117642A TW91117642A TW557551B TW 557551 B TW557551 B TW 557551B TW 091117642 A TW091117642 A TW 091117642A TW 91117642 A TW91117642 A TW 91117642A TW 557551 B TW557551 B TW 557551B
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000000758 substrate Substances 0.000 claims abstract description 31
- 125000006850 spacer group Chemical group 0.000 claims abstract description 7
- 238000005468 ion implantation Methods 0.000 claims description 45
- 150000002500 ions Chemical class 0.000 claims description 44
- 108091026890 Coding region Proteins 0.000 claims description 15
- 229920002120 photoresistant polymer Polymers 0.000 claims description 12
- 238000002513 implantation Methods 0.000 claims description 9
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000011810 insulating material Substances 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- 238000005530 etching Methods 0.000 claims description 2
- 238000005498 polishing Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 108700026244 Open Reading Frames Proteins 0.000 claims 3
- -1 arsenic ions Chemical class 0.000 claims 3
- 229910052691 Erbium Inorganic materials 0.000 claims 2
- 229910052785 arsenic Inorganic materials 0.000 claims 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 1
- 235000011613 Pinus brutia Nutrition 0.000 claims 1
- 241000018646 Pinus brutia Species 0.000 claims 1
- 241000218683 Pseudotsuga Species 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims 1
- 239000012528 membrane Substances 0.000 claims 1
- 239000004576 sand Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000002019 doping agent Substances 0.000 abstract 2
- 238000009413 insulation Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 10
- 239000007943 implant Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 2
- 241000212376 Ammi Species 0.000 description 1
- 235000007034 Carum copticum Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- HAYXDMNJJFVXCI-UHFFFAOYSA-N arsenic(5+) Chemical compound [As+5] HAYXDMNJJFVXCI-UHFFFAOYSA-N 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
557551557551
本發明是有關於一種罩幕式士 、生方氺,曰牡卩丨s 士 a 式唯碩記憶體之結構及其製 le方法 且特別疋有關於一種雙伤_贸曾上 Α 結構及其製造方法。 凡罩幕式唯讀記憶體之 罩幕式唯讀記憶體是唯讀々斤 豆:}: |孫茲山桃7上士 ^1 °思體中最為基礎的一種0 其主要係猎由離子植入製程來調 λΤ ! , 、 3正具启欠始電壓(ThresholdThe present invention relates to a structure of a mask-style ceremonial priest, a birth square 氺, a 唯 shi shi a-type V-storage memory, and a method for manufacturing the same, and particularly relates to a double wound _ 曾 曾 上 Α structure and its Production method. The mask-only read-only memory of the mask-type read-only memory is a read-only jack:}: | Sun Zishan Tao 7 Sergeant ^ 1 ° The most basic type of thought 0 is mainly hunted by ion plants Into the process to adjust λΤ!,, 3 has a threshold voltage (Threshold
Voltage),而達到控制記憶單 :Minr 目的而虽罩幕式唯讀記憶體之產口古糾於姓士社制如 ^ ^ ^ t 〜座口口有所改變時,其製程 並不需要大幅的修改,而只要更改 μμ扑a $人 戈灵改所使用的一組光罩,因 此非韦適合大詈生產,其5开止在,】 士口兮/直生盈甚至了先製作部分製程已完成的半 成οσ ’待δ丁早到廠時,便可迅技U4r ll u ,〇 •干N跟丁 I』处逑將此些半成品進行程式化 CProgr ammi ng),而能有效縮短其出貨時間。 目前一種雙位元罩幕式唯讀記憶體已在積極的發展 中雙位元罩幕式唯讀A憶體顧名思義是一種可於單一記 胞中儲存二位元資料(two bit per cell)的記憶體元 件。關於此種記憶體元件之結構說明如下: 第1圖所示,其繪示為習知一種雙位元罩幕式唯讀記 憶體結構之剖面示意圖。 請參照第1圖,習知雙位元罩幕式唯讀記憶體包括一 基底10、一閘極結構16、一雙位元編碼區2〇、一埋入式汲 極1 8、一絕緣層2 2以及一字元線2 4。 其中’閘極結構1 6係配置在部分基底1 〇上,且閘極結 構1 6包括一閘極導電層i 4以及配置在閘極導電層丨4底下之 一閘氧化層1 2。此外,埋入式汲極1 8係配置在閘極結構1 6 兩側之基底1 0中。Voltage), to achieve the control of the memory list: Minr purpose, although the production of the read-only memory of the curtain type is corrected by the system of surnames such as ^ ^ ^ t ~ When the mouth is changed, the process does not need to be significantly Modification, and only need to change the set of photomasks used by μμ 扑 a $ 人 戈 灵 改, so Feiwei is suitable for production of Datong, its 5 opening and closing,】 Shikou Xi / Zheng Shengying even made part of the process first The semi-finished product οσ 'when δ Ding arrives at the factory early, Xunji U4r ll u, 〇 dry N and Ding I' can be programmed (CProgr ammi ng), which can effectively shorten its delivery time. At present, a two-bit mask-only read-only memory has been actively developed. A two-bit mask-only read-only memory is, as the name implies, a type of two-bit per cell that can store two bits of data in a single cell. Memory element. A description of the structure of such a memory element is as follows: As shown in FIG. 1, it is a schematic cross-sectional view of a conventional read-only memory structure of a two-bit mask type. Please refer to FIG. 1. The conventional double-bit mask type read-only memory includes a substrate 10, a gate structure 16, a double-bit coding area 20, an embedded drain 18, and an insulating layer. 2 2 and a character line 2 4. The gate structure 16 is disposed on a part of the substrate 10, and the gate structure 16 includes a gate conductive layer i 4 and a gate oxide layer 12 disposed under the gate conductive layer 丨 4. In addition, the buried drain 18 is disposed in the substrate 10 on both sides of the gate structure 16.
9236twf.ptd 第6頁 5575519236twf.ptd Page 6 557551
外,雙位元編 基底1 0中。在 為一邏輯狀態 植入的位元係 緣層2 2係配置 閘極結構16。 以使相同一列 而,由於習知 與雙位元編碼 漏電流(J unct 效應(Second 讀記憶體還存 易受到周圍其 式唯讀記憶體 容易產生第二 裕度(Ope ra t i 另 底下之 位元係 碼離子 絕 相鄰的 24,用 然 極接面 生接面 二位元 幕式唯 憶胞容 元罩幕 干擾且 之操作 雔20則是配置在閘極結構1 6兩側邊 位元編碼區20中有編碼離子植入之 ,而在雙位元編碼區2〇中未有編 為一邏輯狀態” 〇,,。 在埋入式汲極1 8之上方,用以隔離兩 而在閘極結構16上則是配置有字元绨 之閘極結構1 6彼此電性連接。 ,,兀罩幕式唯讀記憶體其埋入式汲 區是相連在一起的,因此非常容易發 ion Leakage)之情形,且容易產生苐 Bit Effect)。另外,習知雙位元罩 在有一問題,就是記憶體元件中之記 他記憶胞之干擾。而由於習知之雙位 之記憶胞容易受到周圍其他記憶胞之 位元效應之故,因此習知記憶體元件 〇 n W i n d 〇 w )較小。 因此,本發明的目的就是在提供一種雙位元罩幕式唯 讀記憶體之結構及其製造方法,以消除雙位元罩幕式^讀 記憶體中之第二位元效應。 邊In addition, the two-bit editing base 10. A gate structure 16 is arranged on the edge system 22 and the bit system 2 implanted for a logic state. In order to make the same column, due to the conventional and double-bit code leakage current (J unct effect (Second read memory is still susceptible to the surrounding read-only memory, it is easy to generate a second margin (Ope ra ti) The element code ions must be adjacent to each other. The two-dimensional screen with the positive electrode interface and the two-dimensional screen is only remembered by the cell volume. The operation is 20, which is arranged on the sides of the gate structure. There is a coded ion implanted in the coding region 20, and it is not programmed into a logic state in the two-bit coding region 20. It is above the buried drain 18 to isolate the two and The gate structure 16 is electrically connected to the gate structure 16 provided with the characters 绨. The buried-type read-only memory of the Wudang curtain-type read-only memory is connected together, so it is very easy to generate ion. Leakage), and it is easy to produce 。Bit Effect. In addition, there is a problem with the known dual bit mask, which is the interference of the memory cells in the memory element. Because the known dual bit cells are easily affected by the surroundings. Because of the bit effect of other memory cells, The memory element 〇n W ind 〇w) is small. Therefore, the object of the present invention is to provide a structure of a two-bit mask type read-only memory and a manufacturing method thereof, so as to eliminate the two-bit mask type read. The second bit effect in memory.
本發明的另一目的是提供一種雙位元罩幕式唯讀記隱 體之結構及其製造方法,以避免雙位元記憶胞會受到周^ 其他記憶胞之干擾。 。 本發明提出一種雙位元罩幕式唯讀記憶體之結構,勺 括一基底、一閘極結構、一雙位元編碼區、至少二間隙匕Another object of the present invention is to provide a structure of a two-bit mask type read-only memory and a method for manufacturing the same, so as to prevent the two-bit memory cells from being interfered by other memory cells. . The invention provides a structure of a dual-bit mask-type read-only memory, which includes a base, a gate structure, a dual-bit coding area, and at least two gaps.
子。繼之,再以此光阻層為罩幕進行—第一義 :雔:iLi中形成一摻雜區,㊣中摻雜區4 二Γ= 之離子型態相反,且摻雜區4 又位兀、、扁碼區之離子濃度高。然後,將光阻肩 557551 五、發明說明(3) 壁、一埋入式汲極、一摻雜區、一絕 其中,閘極結構係配置在部分基、丄及- ;:編碼離子植入者具有-邏輯狀態冬而元未編 J =結:之兩側,而埋入式沒極另係二 明中,摻雜區之=起: 且摻雜區之離子濃度較雙 層是配置在埋入式没極之上方= -置在相同一列之閘極結構上。其中,字 夕層:㊁:】f在多晶矽層表面之一金屬矽化物層 法,ί::?出一種雙位元罩幕式唯讀記憶體的 去此方法係首先在一基底上形成一閘極社 括:閘極導電層以及形成在間“電層 ^ 日=接著,在基底上形成圖案化之一光阻 一雙位7L編碼區,之後以此光阻層為一植入罩 子位ίΓ 馬:植步驟二以在雙位元編碼區中植入child. Then, the photoresist layer is used as a mask—first meaning: 雔: a doped region is formed in iLi, the doped region 4 in ㊣ is different from the ion type of Γ =, and the doped region 4 is in place The ion concentration in the U-shaped and O-shaped areas is high. Then, the photoresistor shoulder 557551 V. Description of the invention (3) A wall, a buried drain, a doped region, and a gate electrode. The gate structure is arranged on a part of the base, ytterbium and-; It has the logic state of winter and the element is not edited. J = the two sides of the junction, and the buried type electrode is in the other two, the doped region is equal to: and the ion concentration of the doped region is more than that of the double layer. Above the buried poles =-placed on the same gate structure. Among them, the word layer: ㊁:] f is a metal silicide layer method on the surface of the polycrystalline silicon layer, and a method of removing a two-bit mask type read-only memory is to first form a substrate on a substrate. The gate electrode includes: the gate conductive layer and the "electrical layer" formed on the substrate. Next, a patterned photoresist and a dual 7L coding region are formed on the substrate, and then the photoresist layer is used as an implant cover. ΓΓ Horse: Step 2 of Implanting in Double Bit Coding Region
I 字元線。 結構包括 配置在閘 瑪區中, ¥編碼離 1是配置 壁兩側之 碼區之 。在本發 子型態相 濃度高。 元線則是 由一多晶 所構成。 製造方 其中此閘 底下之一 層,暴露 幕進行一 一編碼離 植入步 子型態係 子濃度較 除。並且I character line. The structure includes configuration in the Zama area, ¥ code away 1 is the code area on both sides of the configuration wall. The concentration of the hair-type phase is high. The element wire is composed of a polycrystal. The manufacturer has a layer under this gate, and the exposed screen is coded one by one. and
^236twf.ptd 第8頁^ 236twf.ptd Page 8
557551 五、發明說明(4)557551 V. Description of Invention (4)
在閘極結構之兩側形成至少一間隙壁。之後,以閘極結構 與間隙壁為一離子植入罩幕,進行一第二離子植入步騍, 以在間隙壁兩側之基底中形成一埋入式汲極,而形成數個 雙位元編碼記憶胞。其中每一雙位元編碼記憶胞中,有、输 碼離子植入之位元係為一邏輯狀態”丨”,而未有編碼離孑 植入之位元係為一邏輯狀態” 〇”。最後,於埋入式汲極之 ^方形成一絕緣層,並且在相同一列之閘極結構上形成/ 字元線。本發明所形成之摻雜區,在歷經後續次埶製耩 之後,會幾乎將雙位元編碼包圍起來。 …、 、、 本發明之雙位元罩幕式唯讀記憶體之結構及其製造方 法由於雙位元編碼區幾乎被摻雜區所包圍,因此可避免 記憶胞之間互相干擾。 碼區^ ^ ^ ^雙位%罩幕式唯讀記憶體中,由於雙位元編 此S由、及L 4 3離子型癌、且濃度較高的摻雜區所包圍’因 L : = Λ 障降低效應(Drain Ιη —d Barrier L應〇w:nng)可消除雙位元罩幕式唯讀記憶體之第二位元效 本發明之雙位元操作复 元記憶胞之間不會互相罩^唯讀記憶體,由於雙位 應可消除雙位元罩H :擾,且精由汲極誘導阻障降低效 玎提南記憶體元件之操作裕度。之第-位兀效應,因此 為讓本發明之上 顯易懂,下文特兴一舻’二 的、特徵、和優點能更明 細說明如下:牛乂佳貫施例’並配合所附圖式,作詳At least one gap wall is formed on both sides of the gate structure. After that, the gate structure and the gap wall are used as an ion implantation mask, and a second ion implantation step is performed to form an embedded drain in the substrate on both sides of the gap wall to form several double-bits. Meta-coded memory cells. In each of the two-bit coded memory cells, the bit line with and without the code ion implantation is in a logical state "丨", and the bit line without any coded ion implantation is in a logical state "0". Finally, an insulating layer is formed on the square of the buried drain, and a / word line is formed on the gate structure of the same column. The doped region formed by the present invention will almost surround the double-bit code after undergoing subsequent hafnium fabrication. ... The structure and manufacturing method of the double-bit mask-type read-only memory of the present invention and the manufacturing method of the double-bit masked area are almost surrounded by the doped region, so that the memory cells can avoid mutual interference. Code region ^ ^ ^ ^ In the dual-bit mask read-only memory, due to the dual-bit encoding of this S, it is surrounded by the doped regions with higher concentration and L 4 3 ion-type cancer. 'Cause L: = Λ barrier reduction effect (Drain ln—d Barrier L should be 0w: nng) can eliminate the second bit effect of the two-bit mask-type read-only memory. The two-bit operation of the present invention does not cause mutual interaction between the memory cells. The mask ^ read-only memory, because the two bits should eliminate the two-bit mask H: interference, and the drain-induced barriers reduce the operating margin of the Titan memory element. The first-position effect, so in order to make the present invention easier to understand, the following special features, features, and advantages can be explained in more detail as follows: Niu Jia Jia Guan Example 'with the accompanying drawings Detailed
557551557551
圖式之標示說明: 10、100 :基底 1 2、1 0 2 :閘氧化層 14、104 .閘極導電層 1 6、1 0 5 ·•閘極結構 1 8、1 2 4 :埋入式汲極 20 :雙位元編碼區 2 2、1 2 6 ··絕緣層 24、128 :字元線Description of the drawing: 10, 100: substrate 1 2, 1 0 2: gate oxide layer 14, 104. Gate conductive layer 1 6, 1 0 5 • gate structure 1 8, 1 2 4: buried Drain 20: Double-bit coding area 2 2, 1 2 6Insulation layers 24, 128: Word lines
106 . 口袋型離子植入步驛 108 : 口袋型摻雜區 11 0 :光阻層 Π 2 ·雙位元編碼佈植步驟 11 4 :雙位元編碼區 116、122 :離子植入步驟 11 8 ·換雜區 1 2 0 :間隙壁 實施例 第2A圖至第2E圖,其繪示為依照本發明一較佳實施例 之雙位元罩幕式唯讀記憶體之製造流程剖面示意圖。 請參照第2 A圖,首先在一基底1 〇 〇上形成一閘極結構 1 0 5。其中,閘極結構1 〇 5包括一閘極導電層1 〇 4以及形成 在閘極導電層104底下之一閘氧化層102。在本實施例中, 間極導電層1 04之材質例如是多晶矽,且閘氧化層1 02之厚106. Pocket-type ion implantation step 108: Pocket-type doped region 11 0: Photoresist layer Π 2 · Double-bit code implantation step 11 4: Double-bit code region 116, 122: Ion implantation step 11 8 • Miscellaneous area 12: Figures 2A to 2E of the embodiment of the partition wall, which are schematic cross-sectional views showing the manufacturing process of the dual-bit mask read-only memory according to a preferred embodiment of the present invention. Referring to FIG. 2A, a gate structure 105 is first formed on a substrate 100. The gate structure 105 includes a gate conductive layer 104 and a gate oxide layer 102 formed under the gate conductive layer 104. In this embodiment, the material of the inter-electrode conductive layer 104 is, for example, polycrystalline silicon, and the gate oxide layer 102 is thick.
557551557551
度例如是45埃左右。 接著’進行一 口袋型離子植入步驟丨〇 6,以在閘極結 構105兩侧之基底1〇〇中形成一口袋型摻雜區1〇8。在本實 施例中’ 口袋型摻雜區1 〇 8中所植入之離子例如是砷離 子’ 口袋型離子植入步驟1 〇 6之一離子植入劑量例如為1 χ l〇13/cm2,口袋型離子植入步驟1〇6之一離子植入能量例如 為50 KeV,且口袋型離子植入步驟丨〇6之一離子植入角度 例如為4 5度。 一 之後,請參照第2B圖,在基底1 〇〇上形成一圖案化之 光阻層11 0,暴露出一雙位元編碼區丨丨4。之後,以光阻層 no—為一植入罩幕進行一雙位元編碼佈植步驟112,以在雙 位το編碼區1 1 4中植入一編碼離子。在本實施例中,雙位 元、、爲碼區11 4中所植入之編碼離子例如是石申離子,且雙位 元編碼佈植步驟U 2之一離子植入劑量例如為2 χ 二ν’雙位元編碼佈植步驟112之一離子植人能量例如 、 e 且雙位元編碼佈植步驟1 1 2之一離子植入角度 例如為45度。 絶说f 1 1 也例中,在閘極結構1 〇 5兩側邊底下之雙位元 、、扁馬£114中,有編碼離子植入 輯狀態,,Γ之位开,而去亡站 交,你彳乍為八有邏 ^ ^ ^ M ^ 而未有編碼離子植入者在後續係作為 具有一邏輯狀離"η "夕Ar s , 、* 一 ^低別Γ 而由於在先前步驟中,已有 進订口袋型離子棺人舟n 植入之雙位分A 乂驟10 6,因此,在此未有編碼離子 缺 士 、、扁碼區之處係為口袋型摻雜區i08。 …明參照第2C圖,再以光阻層11 0為一植入罩幕 557551 五、發明說明(?) 進行一第一雛早 區118。复中子/入步驟116 ’以在基底100中形成一摻雜 11 4之離子型能/雜區11 8之離子型態係與雙位元編碼區 碼區11 4之離^ ^反,且摻雜區1 1 8之離子濃度較雙位元編 入之離子例如二度高。纟本實施例中’摻雜區118中所植 子植入劑旦制二2離子,且第一離子植入步驟116之一離 -是5xi°i3/cm2,第-離子植入步驟之 ,植入此I例如為40 KeV。 極紝構上明參照第2D圖,將光阻層11 0移除之後,在閘 120°之厚二:側形成至少一間隙壁120。其中,間隙壁 之例如是4 00埃至6〇〇埃,較佳的是5〇〇埃左右。且 二点Η Γ之材質可以是氮化石夕或氧化石夕等介電材質。而 未壁二之方法 冤層C未、,會不),之後再回蝕刻此介電層而形成。 之後,請繼續參照第2D圖,以間隙壁12〇與閘極結構 1 0 5為植入罩幕進行一第二離子植入步驟1 2 2,以在間隙 壁1 2 0兩側之基底1 〇 〇中形成一埋入式汲極1 2 4,而形成數 個雙位元編碼記憶胞。其中,每一雙位元編碼記憶胞中, 有編碼離子植入之位元係為一邏輯狀態"丨”,而未有編碼 離子植入之位元係為一邏輯狀態"〇”。在本實施例中,埋 入式汲極124中所植入之離子例如是bf2+離子,且第二離子 植入步驟1 2 2之一離子植入劑量例如是1 χ 1 〇15 / cm2,第二 離子植入步驟1 2 2之一離子植入能量例如是1 〇 κ e V。 接著’請參照第2 E圖,在埋入式汲極1 2 4之上方形成 一絕緣層1 2 6,用以隔離相鄰的兩閘極結構丨〇 5。其中,絕The degree is, for example, about 45 angstroms. Next, a pocket-type ion implantation step is performed to form a pocket-type doped region 108 in the substrate 100 on both sides of the gate structure 105. In this embodiment, the ion implanted in the pocket-type doped region 108 is, for example, an arsenic ion. The ion implantation dose in the pocket-type ion implantation step 106 is, for example, 1 x 1013 / cm2, The ion implantation energy of one of the pocket-type ion implantation steps 106 is 50 KeV, and the ion-implantation angle of one of the pocket-type ion implantation steps 106 is 45 degrees, for example. After that, referring to FIG. 2B, a patterned photoresist layer 110 is formed on the substrate 1000, and a double-bit coding region 丨 4 is exposed. After that, a photoresist layer no- is used as an implant mask to perform a double-bit code implanting step 112 to implant a code ion in the double-bit το coding region 1 1 4. In this embodiment, the coded ions implanted in the code region 114 are, for example, Shi Shen ions, and the ion implantation dose of one of the coded implantation steps U 2 is, for example, 2 x 2 The ion implantation energy of one of the two-bit code implantation steps 112 is, for example, e, and the ion implantation angle of one of the two-bit code implantation steps 1 1 2 is, for example, 45 degrees. In the example of f 1 1, there is a coded ion implantation state in the double bit, £ 114 under the sides of the gate structure 105, and the position of Γ is opened, and the station is dead. Turn, you have a logic ^ ^ ^ M ^ without encoding the ion implanter in the subsequent line as having a logical separation " η " Xi Ar s,, * a ^ low difference Γ and because In the previous step, the double-position A of the pocket-type ion coffin n implantation has been ordered. Step 10 6; therefore, there is no pocket-type doping in the place where there is no code ion, and the flat code region District i08. … Refer to Figure 2C, and then use the photoresist layer 110 as an implant mask 557551 V. Description of the invention (?) A first embryonic area 118 is performed. The complex neutron / enter step 116 'to form an ion energy of the doped ionic energy / hetero region 11 8 in the substrate 100 and the separation of the digit code region 114 of the double bit coding region ^ ^, and The ion concentration of the doped region 1 1 8 is higher than that of the two-bit ion by, for example, two degrees.纟 In this embodiment, the implanted implant in the doped region 118 is made of two ions, and one of the first ion implantation steps 116 is -5xi ° i3 / cm2, which is the first ion implantation step. This I implantation is, for example, 40 KeV. Referring to FIG. 2D, the electrode structure is cleared, and after removing the photoresist layer 110, at least one spacer 120 is formed on the gate at a thickness of 120 °. Among them, the gap wall is, for example, 400 angstroms to 600 angstroms, and preferably about 500 angstroms. In addition, the material of the two points Η Γ may be a dielectric material such as a nitride stone or an oxide stone. However, the method of the second wall (the layer C is not, will not), and then the dielectric layer is formed by etching back. After that, please continue to refer to FIG. 2D, and perform a second ion implantation step 12 using the spacer wall 120 and the gate structure 105 as the implant mask to form the substrate 1 on both sides of the spacer wall 120. 〇〇 formed an embedded drain 1 24, and formed a number of double-bit coded memory cells. Among them, in each of the two-bit coded memory cells, the bit system with a coded ion implantation is a logic state ", " and the bit system without a coded ion implantation is a logic state ". In this embodiment, the ions implanted in the buried drain 124 are, for example, bf2 + ions, and the ion implantation dose in one of the second ion implantation steps 1 2 2 is, for example, 1 x 10 15 / cm 2 The ion implantation energy of one of the two ion implantation steps 1 2 2 is, for example, 10 kV. Next, please refer to FIG. 2E. An insulating layer 1 2 6 is formed above the buried drain electrode 1 2 4 to isolate two adjacent gate structures. Of which, absolutely
9236twf.ptd9236twf.ptd
557551 五 發明說明(8) __ ,,126之材質例如是氧化梦。且形成絕緣声Y^ S ί在基底1G Q上形成—絕緣材f層(未繪示),之ϋ例 ii:T〇5,之後再以-化學機械研磨法或-回:ί ί 移除部分够緣;g W傲刻法 刀,,色,.水材貝層,直到閘極結構105暴露出來。 ,後,在閘極結構丨05上形成一字元線128 =列之閘極結構1()5彼此電性連接 用=相 材質例如是多晶矽。另,本發明更子70線128之 兀線128表面形成一金屬矽化物層(曰材貝之字 元線128之電阻值。 θ ^错以降低字 值得注意的疋,本發明之罩幕式唯讀記憶體中之 區ns在歷經後續數次熱製程之後,摻雜區118幾乎會將: 位兀編碼區114包圍起來。換言之,雙位元編碼區丨ΐ4 ς 會被離子型態相反且較高濃度的摻雜區118包圍起來。如 此一來,藉由汲極誘導阻障降低效應便可以消除雙位元 幕式唯讀記憶體之第=位元效應,並且可減少記憶胞之間 的互相干擾,進而提高元件之操作裕度。 综合以上所述,本發明具有下列優點: 1 ·本發明之雙位元罩幕式唯讀記憶體之結構及其製造 方法’可避免憶胞之間互相干擾。 2 ·本發明之雙位元罩幕式唯讀記憶體之結構及其製造 方法,可消除雙位兀罩幕式唯讀記憶體之第二位元效應。 3 ·本發明之雙位疋罩幕式唯讀記憶體之結構及其製造 方法,可提高記憶體元件之操作裕度。 雖然本發明已以較佳貫施例揭露如上,然其並非用以557551 Five invention description (8) __ ,, 126 The material is, for example, oxidized dream. In addition, an insulating sound Y ^ S is formed on the substrate 1G Q—an insulating material f layer (not shown), Example ii: T〇5, and then -chemical mechanical polishing method or -back: ί ί remove Partially enough fate; g Wao carved knife, color, water layer, until the gate structure 105 is exposed. Then, a word line 128 is formed on the gate structure 05 = the gate structures 1 (5) of the column are electrically connected to each other with a phase material of, for example, polycrystalline silicon. In addition, a metal silicide layer is formed on the surface of the first and second lines 70 and 128 of the present invention (the resistance value of the zigzag character line 128. θ ^ is wrong to reduce the value of the word 值得注意), the mask of the present invention After several subsequent thermal processes in the read-only memory, the doped region 118 will almost surround: the bit coding region 114. In other words, the two-bit coding region 丨 ΐ4 will be reversed by the ion type and A higher concentration of the doped region 118 surrounds it. In this way, the drain-induced barrier reduction effect can eliminate the bit effect of the two-bit curtain read-only memory and reduce the memory cell Interference with each other, thereby improving the operating margin of the component. In summary, the present invention has the following advantages: 1 · The structure of the dual-bit mask-type read-only memory of the present invention and its manufacturing method can avoid the memory cell The two-bit mask-type read-only memory structure and manufacturing method of the present invention can eliminate the second-bit effect of the two-bit mask-type read-only memory. 3 Structure and read-only memory of dual-bit screen Manufacturing method, can increase the operating margin of the memory element. Although the present invention has been disclosed in terms of preferred embodiments consistent application above, they are not intended
9236twf.ptd 第 13 頁 557551 五、發明說明(9) 限定本發明,任何熟習此技藝者,在不脫離本發明之精神 和範圍内,當可作些許之更動與潤飾,因此本發明之保護 範圍當視後附之申請專利範圍所界定者為準。9236twf.ptd Page 13 557551 V. Description of the invention (9) The invention is limited. Any person skilled in the art can make some changes and retouch without departing from the spirit and scope of the invention. Therefore, the scope of protection of the invention It shall be subject to the definition in the appended patent application scope.
9236twf.ptd 第14頁 557551 圖式簡單說明 第1圖為習知一種雙位元罩幕式唯讀記憶體結構之剖 面示意圖;以及 第2A圖至第2E圖是依照本發明一較佳實施例之雙位元 罩幕式唯讀記憶體之製造流程剖面示意圖。 磷9236twf.ptd Page 14 557551 Brief description of the drawings Figure 1 is a schematic cross-sectional view of a conventional read-only memory structure of a two-bit mask; and Figures 2A to 2E are a preferred embodiment of the present invention. The schematic diagram of the manufacturing process of the dual-bit mask read-only memory. phosphorus
9236twf.ptd 第15頁9236twf.ptd Page 15
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