TW557255B - Decorating method and laminate of two-side adhesive sheet and foil-clad sheet for use in the method - Google Patents

Abstract

To the two sides of a two-side adhesive sheet 6 composed of an adhesive layer 3 and an extensible resin film 4 having adhesion weaker than that of the adhesive layer 3, a first release sheet 5 and a second release sheet 2 are adhered to form a laminate 1 of the two-side adhesive sheet. It is cut by a cutting machine to a slit of desired shape (step a). After the first release sheet 5a, 5b and the unwanted part 6b of the two-side adhesive sheet are removed, a transfer sheet 7 provided with an adhesive layer 8 is adhered onto a patterned two-side adhesive sheet (step b'), and thereafter peel off the transfer sheet 7 so that both the patterned two-side adhesive sheet and the transfer sheet 7 are peeled off the second release sheet 2 (step c'). The adhesive layer of the peeled two-side adhesive sheet is pressed and adhered to the coated body B, and then the transfer sheet is peeled off the two-side adhesive sheet (step d'). The surface of the two-side adhesive sheet on the coated body is adhered with the gold foil from the foil-clad sheet (step e).

Description

557255 A7 ----- B7 V. Description of the Invention (1) Technical Field The present invention relates to foils such as metal foils, foil foils and other foil sheets, and uses powders such as metal powder and pigment powder to form a decorative surface on the surface of an adherend. Or decorate the pattern. With this method, the two-sided adhesive sheet laminate layer 'and the foil are attached. Especially on the surface of various adherends such as signboards, interior walls, arts and crafts, sundries, tables and other objects, use foils such as gold foil, silver boxes, copper foils, or thin sheets of these metal foils, metal powder or pigment powder Method for forming a decorative surface or a decorative pattern by waiting for the powder, and a two-sided adhesive sheet laminate layer using the method, and a foil-attached sheet. [Background Art] Printed by employees' cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. Precious metal foils such as gold foil, precious metal foil flakes, precious metal powders, and pigment powders are used to form decorative patterns or characters on the surface of adherends. Examples of the decoration using such precious metal foils, foil sheets, and metal powders include the decoration of lacquered products such as handicrafts, sundries, furniture, Buddhist altars, and Buddhist utensils, display of window displays, and decoration of glass doors and other characters. , Interior wall surface decoration, sliding door partition decoration 'signboard text or decoration and so on. Devices using such precious metals and other materials require proficient technology, and currently rely on craftsmen with special skills. The reason is that, first, noble metal foils such as gold foils are extremely ductile, and the thickness of the formed foils is extremely thin, and the handling of the foils themselves is very difficult. Therefore, when such a difficult-to-handle foil is attached to the adherend, it is used as a choice of adhesive paint, glue, and other materials, adjustment of the adhesive liquid, coating, selection of the foil attachment period, and attachment technology. All require skilled technology, and in addition, the Chinese national standard (CNS) A4 specification (210 X 297 mm) is applicable to this paper size. 557255 A7 B7 5. Description of the invention (Please read the precautions on the back first to implement the required shape on the adherend. One of the reasons for decoration is to draw quite a lot of adhesive pictures made of glue, lacquer, etc. on the adherend. This is also one of the reasons. Also, the precious metal foil used is of high price and cannot be failed, which is also one of the reasons. Use The decoration of precious metal foil, precious metal powder and pigment powder is the same. In order to implement foil decoration without using a craftsman, a so-called adhesive sheet is proposed, that is, an adhesive layer is provided on both sides of a synthetic resin film to become a so-called double-sided adhesive tape. Or one of the two sides of the adhesive sheet is attached to an adhesive surface, and a precious metal foil such as gold foil is attached, and the other side is a release sheet such as release paper. This adhesive sheet is to cut the adhesive sheet into a desired shape. , Remove the release paper, you can stick the foil with the synthetic resin film to the desired position of the adherend, without special technology, you can easily adhere the foil to the adherend. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs However, the conventionally proposed adhesive sheet has extremely thin thickness of gold foil and the like on the surface, and there are cracks and gaps in the gold layer. When the adhesive sheet is adhered to the adherend (the object to be decorated), when the temperature of the decorative product rises in the surroundings, , The adhesive of the adhesive sheet will ooze on the surface of the foil. In addition, when the double-sided adhesive tape or the adhesive of the double-sided adhesive sheet oozes from the attached foil to the foil, the decorative surface will become sticky, and it will ooze to the surface of the foil. The adhesive will adhere to dust, etc., causing problems such as deteriorating the decorative effect. Therefore, when the adhesive sheet has poor ductility on both sides with foil adhesion, it is difficult to make the sheet cooperate with the curved surface of the adherend. As a result, the gold foil cannot be matched. The curved surface of the adherend is bonded, and the two-sided adhesive sheet is extensible. Even if the curved surface of the adherend is used, it can be extended and bonded. As the sheet is extended, the foil will be produced. Seam or gap, so that the product has no price. -4- This paper size applies the Chinese National Standard (CNS) A4 (210 X 297 mm) 557255 A7 B7 V. Description of the invention (3) For these problems, when using foil, Metal powders such as gold powder, pigment powders such as mineral powder, etc. also occur when they are carried on the surface of the sticky sheet. In view of the above situation, the present invention aims to provide a method for decorating the surface of an adherend, which can eliminate the conventional problems. That is, no special skills are needed. 'It is simple and the adhesive does not leak out of the decorative surface of the foil. Another object of the present invention is to provide a method for decorating the surface of an adherend. The metal foil or the like can be used to adhere to curved surfaces. The surface of the body is well decorated. Furthermore, another object of the present invention is to provide a two-sided adhesive sheet laminate suitable for the above method, and a foil-attached sheet. Invention: The present inventors conducted intensive research and review, and found that the adhesive layer side of the two-sided adhesive sheet formed by the adhesive layer is provided on the other side of the ductile resin film that exhibits adhesiveness on at least one side, and the decoration is performed. After the substrate (adhered body) is bonded, the foil, foil sheet, powder, etc. are adhered to the adhesive surface of the ductile resin film, the above-mentioned object can be solved, and the present invention is completed. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the present invention provides a method for decorating the surface of an adherend, which is characterized in that at least one side of the ductile resin film exhibiting adhesiveness is provided with two sides of which are formed by an adhesive layer. The adhesive layer of the sheet is adhered to the surface of the adherend, and the foil, foil sheet or powder is adhered to the adhesive surface of the ductile resin film. In the above-mentioned decoration method of the present invention, the cut-off ductile resin film cannot maintain the shape during the film moving process or the dross removal process of the two-sided adhesive sheet. 5- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297) 557255 A7 B7 5. Invention Description (When printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the obtained decorative pattern is different from the desired shape, although it achieves the intended purpose. In the method for decorating the surface of the adherend of the present invention, The use of stretched green resin film is used as a material for the two-sided adhesive sheet with boxes, sheets, powders, etc., which can be matched with the curved surface of the adherend, and it is easy to stick to the two-sided adhesive sheet. After the adherend, the foil, foil sheet, and powder are adhered to the adhesive surface of the ductile film, and the foil can be simply adhered to the adherend. In addition, the ductile resin film surface such as the foil is not adhered. The adhesive layer is present, and the adhesive will not leak out on the surface of the foil. In addition, the foil is not adhered until the two-sided adhesive sheet is attached to the adherend, so this can be prevented in advance. When the adhesive sheet of the foil is attached to an adherend having a curved surface, the foil cracks. The method for decorating the surface of an adherend of the present invention is preferably the following method. First, the first method is to extend the adhesiveness on at least one of the foregoing surfaces. On the other side of the resin film, the inside and outside of the two-sided adhesive sheet formed by the adhesive layer are set, and the first and second release sheets are provided to prepare a two-sided adhesive sheet laminate. This laminate having the first and second release sheets is laminated. , Cut into a desired shape, peel off the second release sheet on the side of the adhesive layer, adhere the adhesive layers of the two-sided adhesive sheet to the surface of the adherend, and peel off the first release sheet from the adhesive surface of the ductile resin film, Adhering to the adherend and sticking the foil, foil sheet or powder to the adhesive surface of the remaining ductile resin film. The second method is the same as the first method above. The second peeling sheet is prepared as a two-sided adhesive sheet product-6- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling: then fill in the page

· IIII Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557255 A7 B7 V. Description of the invention (5) Laminated body. This laminated body with the first and second release sheets laminated is cut into the required shape. The surface of the first release sheet of the laminated body is combined with the transfer sheet, and the second release sheet of the adhesive layer is peeled off. After the adhesive layer is adhered to the surface of the adherend, the adhesiveness of the transfer sheet and the stretchable resin film is adhered. The first release sheet on the surface is peeled off together, adheres to the adherend, and adheres the foil, foil sheet, or powder to the adhesive surface of the remaining ductile resin film. The third method is to provide first and second release sheets on the inside and outside of the two-sided adhesive sheet ... to prepare a two-sided adhesive sheet laminate, cut the laminate having the first and second release sheets laminated into a desired shape, and After the first release sheet on the stretchable resin film of the double-sided adhesive sheet is peeled off, the transfer sheet is bonded to the adhesive surface of the stretchable resin film of the double-sided adhesive sheet, and then the second release sheet on the adhesive layer side is peeled off. After the adhesive layer of the two-sided adhesive sheet is adhered to the surface of the adherend, the transfer sheet is peeled off, adhered to the adherend, and the foil, foil sheet or powder is adhered to the surface of the adherent of the remaining ductile resin film. A fourth method is to provide first and second release sheets on the inside and outside of the two-sided adhesive sheet to prepare a two-sided adhesive sheet laminate. The laminate having the first and second release sheets laminated thereon is obtained from a ductile resin film. On the side of the first release sheet on the adhesive surface, according to the desired shape of the crack, but without cutting the second release sheet on the back, remove the unnecessary part of the first release sheet and the two-sided adhesive sheet. After the transfer sheet is bonded to the release film surface, the laminated body and the transfer sheet are peeled off from the second release sheet, and the two-sided adhesive sheet and the first release sheet having the desired shape are transferred to the paper size to which the Chinese National Standard (CNS) is applied. ) A4 size (210 X 297 mm)

The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed 557255 A7 B7 i. Description of the invention (6) Print the sheet, and then adhere the adhesive side of the adhesive sheet transferred to the two sides of the transfer sheet to the adherend, and then the transfer sheet Peel off with the first release sheet, adhere to the adherend, and adhere the foil, foil sheet, or powder to the adhesive surface of the remaining extensible resin film. A fifth method is to provide first and second release surfaces on the inside and outside of the two-sided adhesive sheet, to prepare a two-sided adhesive sheet laminate, and to laminate the first and second release sheets from the ductile resin film. The first release sheet side on the adhesive surface is cracked in the desired shape, but the second release sheet on the back is not cut. The first release sheet with the cracked part in the desired shape, and the first part One peeling sheet and the two-sided adhesive sheet are removed, and after the transfer sheet is combined with the remaining adhesive surface of the ductile resin film having the desired shape, the second peeling sheet is peeled off and the two sides having the desired shape forming a crack are adhered. Sheet, transferred to the transfer sheet, and then transferred to the adhesive surface of the adhesive sheet on both sides of the transfer sheet, and after being adhered to the adherend, the transfer sheet is peeled off from the adhesive surface of the adhesive sheet on both sides and adhered to The adherend adheres the foil, foil sheet, or powder to the surface of the remaining ductile resin film. In the method for decorating the surface of an adherend of the present invention, when the foil, foil sheet, or powder is adhered to the adhesive surface of the ductile resin film, it is preferable to wipe the adhesive surface of the ductile resin film with alcohol, and then adhere to the surface. Wait. Wiping the adhesive surface with alcohol can improve the activity of the adhesive surface, thereby increasing the adhesive force, and can definitely adhere the foil, foil sheet, and powder. In addition, if necessary, the adherend can be warmed, and both sides of the adhesive sheet can be warmed to strengthen the adhesion. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

557255 A7 B7 5. Explanation of the invention () In addition, in the above-mentioned method for decorating the surface of the adherend of the present invention, when the foil is adhered to the adhesive surface of the ductile resin film, a foil attached to the carrier film on one side is suitable The foil side of the foil-attached sheet is adhered to the adhesive surface of the ductile resin film, and then the body film is peeled from the foil-attached sheet. When the foil sheet or powder is adhered to the adhesive surface of the ductile resin film, 'if the foil sheet or powder is dropped or sprayed on the adhesive surface, etc.', the foil sheet or powder can be easily adhered to the adhesive surface. As far as foil is concerned, it can be understood that gold foil is taken as an example. Since the foil itself is very difficult to handle directly, it is not easy to stick the foil directly. In the case of the foil attached as mentioned above, it is easier to adhere the foil by adhering the foil to the adhesive surface. In this case, the foil-attached sheet is a foil that is bonded to one side of the carrier film, but the bonding strength between the carrier film and the foil is smaller than the adhesive force of the adhesive surface of the ductile resin film, so it must be more than the ductile resin. The adhesive force of the adhesive layer of the film is small. Otherwise, after the foil-attached sheet adheres to the adhesive surface of the ductile resin film, when the carrier film is removed from the foil-attached sheet, the foil may peel off from the adhesive surface, or the adhesive layer of the ductile resin film and the surface of the adherend The adhesive part will peel. Furthermore, in the method for decorating an adherend of the present invention, from the standpoint of ease of handling and correct decoration pattern formation, it is preferable to use the above-mentioned double-sided adhesive sheet laminate obtained by combining the release sheet on both sides of the double-sided adhesive sheet. The above-mentioned two-sided adhesive sheet laminated body preferably used in the present invention has, for example, an extensible resin film having an adhesive surface on at least one side, and a first stripper is provided on the adhesive surface of one side of the ductile resin film. Paper size applies to China National Standard (CNS) A4 (210 x 297 public love) (Please read the precautions on the back before filling in page d)

------ Order --------- Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs of the Qin Dynasty, printed 557255 A7 B7 i. Description of the invention (8) Off-film, the ductile resin film is set on the other side An adhesive layer and a second release sheet provided on the surface of the adhesive layer. This ductile resin film has the characteristic that when the surface is adhered with foil, foil sheet or powder to form a decorative surface, the components of the ductile resin film do not bleed out on the decorative surface such as foil. The resin film having these characteristics is made of a material that is more difficult to exude resin than the adhesive used in the conventional double-sided adhesive tape or double-sided adhesive sheet. These resin materials can use resins with a larger average molecular weight than the resins used in conventional adhesives, or by selecting the copolymerization components of the resins used, and have structural characteristics that are not easy to bleed out due to the characteristics of the resin itself. Suitable methods such as mixture with resin. A resin with a large average molecular weight, a resin with structural characteristics that are not easily exuded, or a mixture consisting of a resin and an adhesive that are not easily exuded, is generally weaker in adhesion than conventional double-sided adhesive tapes or double-sided adhesive sheets on the market. However, the adhesive force of the surface of the ductile resin film to which the foil, foil sheet, or powder is adhered does not need to be so large that it is necessary to stick the ductile resin film to the adherend. On the other hand, in order to ensure the compliance of the resin film with the curved surface of the adherend, the ductile resin film ′ constituting the two-sided adhesive sheet laminate must have ductility. In order to impart ductility, the thickness of the resin film and the material of the resin film must meet these characteristics. The ductile resin film should have adhesiveness on at least one side. The resin film may be composed of a single-layer resin film, or a resin film forming an adhesive or non-adhesive surface may be present on the other side of the resin film, and has a laminated structure. Film thickness of ductile resin film, -10- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 public love) (Please read the precautions on the back before filling in the page) Order ------- --Line ¢. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557255 Α7 Β7 V. Description of the invention () Usually 50 ~ 150 μηι, and the elongation of the ductile resin film, from the viewpoint of compliance with curved surfaces, The elongation is preferably 70 to 200%. With such an elongation, even the surface of an adherend with a complicated shape can easily be adhered to the two-sided adhesive sheet with its curved surface. The elongation at this time is measured in accordance with the tensile test method of JIS K7 1 1 3 plastic. The measurement conditions are a pulling speed of 200 m / m i η, a sample width of 15 m m, a clamp distance of 100 m, and a room temperature of 20 to 25 ° C. In addition, the adhesive force of the two-sided adhesive sheet laminate on the surface of the ductile resin film should be weaker than that of the adhesive layer. With such a relationship of adhesion, the ductile resin film can be reliably adhered to the surface of the adherend. The adhesive force of the stretchable resin film and the adhesive layer, specifically, based on the adhesive force measured based on Jis Z02 37, are 40 ~ 280g / cm (100 ~ 700g / 25mm) and 400g / cm ( 1000g / 25mm) or more is preferred. In the present invention, the adhesive force of the ductile resin film is preferably 40 to 120 g / cm (100 to 300 g / 25 mm), and the adhesive force of the adhesive layer is about 400 to 600 g / cm (1000 to 1500 g / 25 mm). Better. The measurement conditions for the adhesive force (180 ° peel test on stainless steel) are "room temperature 2 4-2 5 ° C, peel speed 3 0 0 m m / m i η, after 1 hour". Furthermore, the properties of the ductile resin film have an affinity with the adhesive layer. A ductile resin film material meeting these various characteristics is preferably made of a mixture of an adhesive and a resin. A resin film made of such materials has suitable surface adhesion and ductility, and does not cause the adhesive to ooze out of the film, and a film with good adhesion to the adhesive layer can be obtained. The common adhesive used with the aforementioned resin is -11. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm). (Please read the precautions on the back before filling- ------ Order ---------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557255 A7 _ B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs On the other hand, the resin includes acrylic resin, vinyl acetate resin, cellulose resin (such as ethyl cellulose, nitro cellulose, etc.), polyester resin 'vinyl acetate-vinyl chloride graft copolymer resin, and ethylene- Either vinyl acetate copolymer resin, amine ester resin, or a mixture of two or more is preferred. The ratio of the acrylic adhesive to the resin (acrylic adhesive: resin) is 2.5: 1 to 3.5: 1 When the adhesive dose is lower than this range, the adhesive force of the ductile resin film is weakened, and the sufficient adhesive force may not be obtained when the foil is adhered. When it is more than the above range, the adhesive force on the surface of the ductile resin film may be too high. Large, adhesive oozing, In some cases, problems occur in film formability and film ductility. In addition, the resin must have compatibility with an adhesive such as an acrylic adhesive. Furthermore, as long as the material of the ductile resin film of the present invention has the above characteristics, There is no limitation on the mixture of the adhesive and the resin, of course, the resin can be used alone, or a plasticizer can be added to the resin. The material of the adhesive layer, all known acrylic acid-based adhesives, mayanone-based adhesives, rubber-based adhesives All are available, of which acrylic adhesive is preferred. The thickness of the adhesive layer is usually about 10-50 μm. Thus, the adhesive layer and the ductile resin film having the above-mentioned adhesiveness constitute a double-sided adhesive sheet. Extension The flexible resin film is composed of a plurality of films. When the adhesive force on one side of the ductile resin film is 400g / cm (1,000g / 25 mm) or more, the adhesive layer can be omitted, and the adhesive ductile film is necessary if necessary. Adhesive layer can also be provided. Use multiple resin film laminates to form a stretchable resin film. When the adhesive layer is omitted, it is adhered to the decoration. -12- Chinese paper standard (CNS) A4 applies Specifications (210 X 297 mm) First (Please read the notes on the back and then fill in 3 pages) Then fill out --- ΜΨ. 557255 A7 -------_ B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Description of the invention (11) The resin film obtained from the body 'directly has the adhesive layer function of the double-sided adhesive sheet of the present invention. In addition,' to protect the ductile resin film surface and the adhesive layer, a release sheet can also be used. Protective extension The first release sheet used on the surface of the flexible resin film is composed of a resin film such as polyethylene terephthalate (PET), which is usually about 30 to 150 μιη in thickness, and more preferably about 40 μηι in thickness. The two release sheet is a release paper having a generally release surface. In addition, 'the cut double-sided adhesive sheet or the double-sided adhesive sheet laminated body is used as a temporary adhesive transfer sheet, and PET' polypropylene (PP), cellulose acetate, polyethylene, chlorine is provided with an adhesive layer on the surface. Resin film such as vinyl tree moon purpose paper or resin-impregnated paper is preferred. The transfer film can be used with or without ductility, but it is usually better if it is not ductile because the two-sided adhesive sheet after cutting will not be deformed. The material and thickness of this resin film can be used as long as the adhesive strength is within the range of achieving the purpose of the present invention. On the other hand, the "advantageous sheet preferably used in the method for decorating an adherend of the present invention" is composed of a carrier film and a foil on which the carrier film is bonded on one side. / cm. When the peeling strength is less than 0.001 g / cm, since the bonding between the carrier film and the foil is insufficient, the foil and the carrier film are easily peeled, and handling is difficult. In addition, when it exceeds 2 5 g / cm, it becomes difficult to peel the carrier film from the foil, making it difficult to securely adhere the foil to the adhesive surface of the ductile resin film. Therefore, the bonding strength of the foil and the carrier film must be smaller than that of the ductile resin film on the adhesive surface in the double-sided adhesive sheet laminate. If there is adhesive force on an adhesive surface -13- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 public love) (Please read the precautions on the back before filling this page)

• lej · I I I I Hua; 557255 A7 B7 V. Description of the invention () When the strength is equal to or higher than the same, it is difficult for the foil to adhere to the adhesive surface. In addition, the bonding strength of the foil and the carrier film must of course be smaller than the adhesive force of the adhesive layer of the ductile resin film. Otherwise, after the foil adheres to the adhesive surface of the ductile resin film, the carrier film is removed from the foil. , Will peel from the adhesive layer of the ductile film and the adhesive part on the surface of the adherend. The foil itself used in the present invention is not particularly limited in its structure when the foil is bonded to the carrier film. For example, when the carrier film itself has an adhesive surface, the foil can be directly bonded to the carrier film, and when the carrier film itself does not have an adhesive surface, a single layer of the carrier film can be provided with a bonding layer such as a paste or an adhesive to paste the foil on The bonding layer. On the other hand, when a foil is formed on a carrier film by a sputtering method called "vacuum evaporation method" or a shovel method described later, a foil with a release agent interposed between the carrier film and the foil can be used to peel the foil from the carrier film. In short, when the foil is adhered to the adhesive surface of the ductile resin film, the carrier film can be surely peeled off from the foil-attached sheet in this state, so as to achieve a state where the foil is adhered to the adhesive surface. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Then, the foil with the foil is preferably formed by a sputtering method, a vacuum evaporation method, or a plating method. A foil can be prepared like a gold foil and combined with a carrier film to form a foil, but the foil itself is difficult to handle and it is not easy to form a foil. Here, a sputtering method, a vacuum evaporation method, and a plating method can be used to easily form a foil with a foil when the carrier film is formed into a foil. When using these methods to form foils, foils with overall uniformity, that is, pinholes without cracks and crepe-like foils, can easily control the thickness of the foil. When using this method to form a foil, it can be directly formed on the surface of the carrier film. -14- ^ Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) _ ~ " " 557255 A7 B7 Ministry of Economy Wisdom Printed by the Consumer Cooperative of the Property Bureau V. Description of the invention (13) For foil formation, it is advisable to apply a release agent on the surface of the carrier film to ensure the peeling off of the carrier film and foil. For example, the sputtering method, the vacuum evaporation method, and the plating method are used to directly form a foil on the surface of a carrier film, and it is easy to make the bonding strength of the foil and the carrier film so strong that sometimes the foil and the carrier film cannot be peeled off. The release agent may be generally known, such as silicone resin, polyvinyl alcohol, paraffin, rhenium, and the like. The foil material of this foil includes, for example, Au, Ag, Cu, Pt, Pd, [r, Rh, Ru, Al, Ni, or any two or more alloys thereof. These metals or alloys are suitable as decorative materials, and should be appropriately selected and used to meet the purpose of the city. Representative examples of the alloy include Au-Ag, Au-Cu, Ag-Cu, Au-Ag-Cu, Au-Pt, Pt-Pd, Pt_Ir, and the like. The carrier film with the foil can be made of various materials such as resin material, paper material, rubber material, and metal material. Appropriate selection of various materials to form foils suitable for decoration purposes can more easily decorate the surface of the adherend. The material of the carrier film is resin. For rubber materials, transparent (including translucent) resin materials or rubber materials can be used. At least one side of the film can be colored or printed. It can simply distinguish the inside and outside of the attached foil, and the ductility When the adhesive surface of the resin film is adhered to the foil, it is possible to prevent inadvertent adhesion to the carrier film side. Brief Description of the Drawings Figure 1 is a cross-sectional view of a specific example of a laminated body of two-sided adhesive sheet of the present invention, and Figure 2 is a step diagram illustrating a specific example of a surface decoration method of an adherend of the present invention; China National Standard (CNS) A4 Specification (210 X 297 mm) _ '(Please read the precautions on the back before filling this page) L .. > ul > L \ Γ IT -------- -MW. 557255 A7 B7 V. Description of the invention (14) Figure 3 is a step diagram illustrating another specific example of the surface decoration method of the adherend of the present invention; Figure 4 is a diagram illustrating the surface decoration method of the adherend of the present invention. Sectional view with gold foil. Specific embodiments of the present invention The preferred embodiments of the present invention are described in detail below with reference to the drawings. Fig. 1 shows a cross-sectional view of a two-sided adhesive sheet laminate preferably used in the method for decorating an adherend of the present invention. In FIG. 1, the double-sided adhesive sheet laminate 1 includes a ductile resin film 4, and a first release sheet 5 provided on one side 4 a of the ductile resin film 4 having adhesive properties is provided on the other side of the ductile resin film 4. The adhesive 3 of 4 b is a second release sheet 2 provided on the adhesive layer 3, and the two-sided adhesive sheet 6 is composed of a ductile resin film 4 and an adhesive layer 3. · Attach one side 4a of the stretchable and adhesive resin film 4 and finally adhere the foil such as metal foil, foil sheet such as metal foil sheet, powder such as metal powder or pigment powder. However, when the surface of the ductile resin film 4 is adhered to a foil, foil sheet, or powder to form a decorative surface, the composition of the ductile resin film 4 on the decorative surface is formed of a material having impermeability. In this example, the ductile resin film 4 is made of a 3: 1 mixture of acrylic adhesive Shao polyester resin, measured in accordance with JIS Z02 37, and has a surface adhesion of about 80 g / cm, a thickness of about 70 μm, and an elongation of 70. ~ 200%. The acrylic adhesive layer having the adhesive layer 3 having a thickness of 40 µm has an adhesive force of the adhesive layer 3 of about 500 g / cm. • 16- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back? Please fill in the matter and then fill in

Order --------- Line I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557255 A7 __ B7 V. Description of the invention () Furthermore, the first release sheet 5 uses poly-p-phenylene diene with a thickness of about 40 μηι Diethyl formate, and the second release sheet 2 uses a release paper having a release layer on the surface. The double-sided adhesive sheet laminated body 1 used in the present invention can be manufactured by any conventional method, and a specific example of the method for manufacturing the double-sided adhesive sheet laminated body 1 is described below. First, the first release sheet 5 is coated with a composition containing a ductile resin. The coating of the resin of the film and the adhesive is dried to form a ductile resin film 4, and a paper separator is laminated on the surface of the ductile resin film to make an intermediate laminate. On the other hand, an adhesive is coated on the second release sheet 2 to form an adhesive layer 3. On the surface of the adhesive layer 3, the extensibility of a pre-made intermediate laminate is affixed through a peelable paper separator. Resin film surface. A specific example of a method of using the double-sided adhesive sheet laminated body 1 of the present invention to perform decoration using gold foil on the surface of an adherend is described below with reference to FIG. 2. First, the first release sheet 5 having the sheet laminated body 1 adhered to both sides is cut from above with a cutting machine such as a computer cutter or a cutter, and cut into a desired pattern. This item is cut to a depth halfway through the thickness of the second release sheet 2 (step a). Secondly, after removing (deslagging) the unnecessary portions 5b and 6b of the first release sheet 5 and the double-sided adhesive sheet 6, the transfer sheet 7 carrying the adhesive layer 8 with an appropriate adhesive force on one side is pressed to make the rotation The printed sheet 7 is adhered to the first release sheet 5 having a desired pattern (step b). Tear off the transfer sheet 7 and form the -17th sheet with the transfer sheet 7 into the required pattern. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back first Refill ^ Refill 1T --------- Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed 557255 A7 B7 V. Description of the invention (16 Strips 5a Strips 2 Stripped employees of the Ministry of Economics and Intellectual Property Bureau The consumer cooperative prints a double-sided adhesive sheet cut into the desired shape on the adhesive layer 8 of the transfer sheet 7 (step c). Repeat these steps if necessary and repeat the process on the same transfer sheet 7 as required Arranged to cut out the two-sided adhesive sheet pattern. When the pattern thus obtained is pressed from the adhesive layer 3 side to the adherend B, the pattern consisting of the two-sided adhesive sheet 6 and the first release sheet 5 is adhered to The desired position of the adherend B is then peeled off from the transfer sheet 7 together with the first release sheet 5 (step d). The adhesive surface 4a of the ductile resin film may be wiped with alcohol as needed to activate the adhesive surface 4a. Adhere the gold foil G to the adhesive surface 4 a and press it with a cotton swab or finger The gold foil G is brushed with bristles to remove unnecessary portions of the gold foil G to form a surface decorated with the gold foil G (step e). If necessary, the gold foil G may be coated with a transparent lacquer to protect the gold foil G to present a decorative pattern. Here Although the method of directly adhering the gold foil G itself has been described, it is also possible to adhere the gold foil to the ductile resin film by using a gold foil sheet as described later. Then, referring to FIG. 3, another explanation is to use gold foil to decorate the surface of the adherend. Method. Step (a) of Fig. 3 is the same as step (a) of Fig. 2 and its description is omitted.... Note: The paper size of the paper is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 557255 A7 B7 V. Description of the invention (17) Remove the pattern part 5a and the unnecessary part 5b of the first release sheet 5, And the unnecessary part 6b of the double-sided adhesive sheet 6 'except for the transfer sheet 7 which bears the adhesive layer 8 having an appropriate adhesive force on one side, and presses the adhesive surface 4a of the ductile resin film 4 remaining on the second release sheet, Adhere the desired pattern to both sides of the adhesive sheet 6 (Step b '). Next, the peeling transfer sheet 7' peels the patterned two-sided adhesive sheet from the second peeling sheet 2 and transfers it to the adhesive layer 8 of the transfer sheet 7. These steps can be repeated as necessary. A plurality of two-sided adhesive sheet patterns are arranged in a desired arrangement on the same transfer sheet 7 (step c '). The pattern thus obtained is pressed from the side of the adhesive layer 3 to the adherend b, and the two-sided adhesive sheets 6 are constituted. The pattern is adhered to the desired position of the adherend B, and then the transfer sheet 7 is peeled off, and the pattern is transferred to the adherend B (step d '). If necessary, the adhesive surface of the ductile resin film 4 4 a can be wiped with alcohol to activate the adhesive surface 4a, and the gold foil G is adhered to the adhesive surface 4a. Press the gold foil G with a cotton swab or a finger, and remove part of the gold foil G with bristles, etc., and use the gold foil G to form a decorative surface (Step e). Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. If necessary, the gold foil G can also be coated with a transparent lacquer to protect the gold foil G in accordance with the method in Figure 2 to form a decorative pattern. In this method, the direct adhesion method of the gold foil G itself is used for explanation. A gold foil sheet may also be used as described later, such as gold foil sticking to a ductile resin film. In addition, in Figures 2 and 3, the laminated sheet on both sides is -19- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 557255 A7 B7 V. Description of the invention (18) 1 Although the cutting is deep up to the middle of the thickness of the second release sheet 2, it may be penetrated through the second release sheet 2 or cut into a pattern with scissors or the like, and the second release sheet 2 cut into the pattern may be peeled off, and this may be peeled off. After the surface is adhered to the surface of the adherend B, the first release sheet is peeled off, and gold foil G or the like is adhered to the adhesive surface 4a. Here, if necessary, the second peeling sheet 2 cut into a pattern may not be peeled off, and after the first peeling sheet 5 is peeled off, or any one of the second peeling sheet 2 and the first peeling sheet 5 is not peeled off, Cut into a pattern and stick it once, arrange it on the transfer sheet 7, and then arrange multiple patterns on the transfer sheet 7 in the same order. Then peel off the second release sheet 2 and perform the above steps d or d '. Adhesive B formed a complex pattern of adhesive surfaces last time. Furthermore, when the decoration range of the adherend covers the entire surface of the adherend, if necessary, the two-sided adhesive sheet 6 attached to the first release sheet 5 can be used to cover the entire surface of the adherend, and then the size of the adherend is combined. The peeling sheet and the double-sided adhesive sheet are cut off, and finally, an adhesive surface 4 a of the stretchable film 4 that can constitute the double-sided adhesive sheet 6 when it must be decorated is present. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Although not shown in the figure, for example, two-sided adhesive sheet 6 can be stuck on the surface of the recess, and the two-sided adhesive sheet laminated body 1 can be cut into a shape slightly larger than the size of the decorative part. After the first and second peeling sheets are peeled off, the two-sided adhesive sheet is coated on the decorative part, and the through-hole surface of the adherend is penetrated to the hole provided on the back surface, and a vacuum is drawn from the back of the adherend to use the two-sided adhesive sheet. By stretching, the two-sided adhesive sheet 6 is closely adhered to the surface of the recess. Then, the above-mentioned step (e) is performed, and decoration is applied using gold foil or the like. '-20- This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 557255 Α7 Β7 i. Description of the invention (19) Also, in the decoration method of the present invention, a transfer sheet 7 can be used if necessary. However, the adhesive strength of the surface of the first release sheet 5 of this transfer sheet 7 or the adhesive surface 4a of the ductile resin film 4 of this transfer sheet 7 is higher than that of the adhesive layer 3 and the second release sheet. The adhesive strength of 2 'and the adhesive strength of the adhesive surface 4a of the ductile resin film 4 and the first release sheet 5 are stronger than the adhesive strength of the adhesive layer 3 and the surface of the adherend b. In addition, the adhesive surface 4a is activated by using the above-mentioned alcohol, but the adhesive surface 4a may be activated by heating. In addition, when the adherend B is a cloth or the like, the adherend B can be warmed, or the adhesive layer 3 can be heated to increase the adhesion strength to the adherend B, and the adhesion of the two-sided adhesive sheet to the adherend B can be improved. Sex. The above figures 2 and 3 are printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The gold foil is used as a decorative material, but other than gold foil, such as silver, copper, aluminum, tin, or alloys of these metals, and stainless steel foil, etc. Any single metal or alloy foil can be used arbitrarily. The surface of the foil may be subjected to an oxidation treatment, a vulcanization treatment, or the like. Conventionally, the thickness of gold foil can be extremely thin. However, when the thickness of the gold foil is about 1 to 10 μm, for example, when the gold foil is processed with a thicker object, the foil can be simply processed. Even if you are not a skilled expert, you can use gold foil to easily decorate the surface of the adherend. Examples of the oxidized foil include yellow silver foil, red silver foil, blue silver foil, and black silver foil. In addition, although the above figures 2 and 3 take the direct adhesion of gold foil as an example, the method of adhesion with gold foil as shown in figure 4 is used. 21- This paper standard applies Chinese National Standard (CNS) A4 (210 X 297 mm) 557255 A7 __ B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (20) 'The gold foil G can be adhered more easily. The gold-coated foil sheet 'shown in Fig. 4 is formed on the carrier film 10 with gold foil G bonded on one side. The gold foil G side with the gold foil sheet 9 is pressed against the adhesive surface 4a of the ductile resin film 4 as shown in FIG. 2 and FIG. 3, and the gold foil G can be extremely easily adhered when the carrier film 10 is peeled off. . At this time, although the thickness of the gold foil G is very thin, a carrier film 10 is present. Compared with the case where the gold foil G itself is directly processed, it is extremely easy to handle, and the adhered gold foil G hardly has wrinkles. The carrier film 10 with gold foil 9 is preferably composed of organic materials such as plastic. Specific examples of the organic materials are resins such as polyethylene terephthalate (PE T) and polypropylene (PP), but others Such as paper, rubber, metal, etc., the material of the foil provided with the carrier film 10 or the material and shape of the adherend B for decoration purpose can be appropriately selected. In addition, the thickness of the carrier film 10 is preferably 5 to 100 μm. When it is thinner than 5 μm, the carrier film 10 itself is weak, and it is difficult to handle the foil 9 itself, or the carrier film 10 is difficult to tear off. On the other hand, when it is thicker than 100 μm, it is difficult to mix the foil and the ductile resin film 4 The adhesive surface 4a is adhered. In addition, the carrier film 10 can be made of transparent or translucent resin or rubber material. If the carrier film 10 is colored on one side, or when printing patterns or characters, it is easy to distinguish the inside and outside of the gold foil 9 to prevent work. The carrier film 10 side with the gold foil 9 is accidentally adhered to the adhesive surface 4 a of the ductile resin film 4. Therefore, the bonding strength between the carrier film 10 and the gold foil G in the gold foil 9 is, for example, in accordance with the method of IS 8 5 04 welding adhesion strength measurement, -22- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm)

Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 557255

、 Explanation of the invention (Using a thin-line tensile type 5 inspection machine 'boring a 15 m rn wide carrier film ι 〇 and Jinbo G tear off g-type inspection test 疋 値' as long as there is 〇 丨 ～ 2 5 g / cm tear off The strength is sufficient, preferably 0.1 to 5 g / cm, and practically 0.3 to 3 g / cm. In addition, when a gold-plated sheet 9 having a bonding strength within this range is formed, the gold foil G and the carrier 0 and 1 G The bonding strength must be less than the adhesive surface 4a of the ductile resin film 4 in the double-sided adhesive sheet laminate 1, and of course it must be lower than the adhesive layer 3 of the ductile resin film 4. Otherwise, 'from gold foil When the sheet 9 is peeled off the carrier film ι, the gold foil G cannot be surely adhered to the adhesive surface 4a of the ductile resin film 4, otherwise the adhesive sheet 6 adhered to both sides of the adherend B will be peeled from the adherend. Although Fan 9 is an example of gold fan, other metal or alloy foils are also applicable. When using a metal foil containing gold foil to form a foil, the thickness of the foil is 0.05 to 50 μm, preferably 0.1 to 20 μm, and more preferably 0.1 to 1 μm. Foil When the thickness is less than 0.05 μm, the foil is prone to defects such as pinholes, and the adhesive oozes out. When the thickness exceeds 50μιη, the flexibility of the foil itself is impaired, and the formation of small curved surfaces is not good. The gold foil sheet 9 can be formed by directly pasting the gold foil G on one side of the carrier 10, or it can be sprayed. The vacuum evaporation method and the plating method are combined to form a predetermined thickness of gold foil on one side of the carrier 10. There are two methods for directly attaching the gold foil G to the carrier film 10 to form a gold foil sheet 9. The first method, When the carrier film 10 has an adhesive surface, it is directly superposed on one side of the carrier film 10 and combined with a gold foil G prepared in advance to form a gold foil sheet 9. Thus, it has adhesion -23- This paper size applies to Chinese national standards (CNS ) A4 size (210 X 297 mm) '" "

557255 A7 __B7 V. Description of the invention (22) The carrier film 10 on the surface, or the film itself has adhesiveness, or an adhesive layer is provided on the film to make the surface adhesive. When the film itself has adhesiveness, there are, for example, vinyl acetate-vinyl chloride graft copolymer resin, ethylene-vinyl acetate copolymer resin 'acrylic resin, etc., but it does not have adhesiveness by itself, and the plasticizer only has adhesiveness. For example, vinyl chloride resin, fiber derivative resins such as nitrocellulose, amine ester resins, and the like. In addition, when the carrier 10 itself does not have an adhesive surface, the carrier 10 may be coated with a paste, an adhesive, or a double-sided tape to form a bonding layer, and then the bonding layer may be formed on the bonding layer. Attached gold box piece 9. When this bonding layer is provided, although not shown in the figure, the gold foil 9 shown in FIG. 4 may have a state in which a bonding layer exists between the carrier film 10 and the gold foil G. In addition, a gold foil sheet can be formed by a sputtering method, for example, as follows. First prepare a PET (or PP) sheet with a thickness of 0.02 to 0.2 mm as a carrier film 10, and apply silicone resin on one side as a release agent. The carrier film on which the release agent is applied is set in the chamber of the spraying device, and the vacuum degree is 1 · 5 to 3_75xl0_5Pa (2 to 5xl (T3T0rr)). After being left for about 100 seconds, the power is applied to 0.1 ~ 0.2 仟Tile, spraying for about 10 minutes, depositing a gold film with a thickness of about 2000 A on the carrier film 10 to form a gold foil 9. A gold target with a purity of 99.9 9% can be used in this spraying. Also, this spraying method is used. Although it is not shown in the figure, the gold foil 9 in FIG. 4 may be in a state where a release agent exists between the carrier film 10 and the gold foil G. In addition, when the gold foil is formed by the vacuum evaporation method, the above-mentioned splash In the same situation, prepare a PET (or PP) sheet with a thickness of 0.02 ~ 0.2mm. -24- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling in this page)

I n ϋ 1_1 nn 1 sip, n 印 Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 557255 A7 B7 V. Invention Description (23 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economy, printed as a carrier film 10, on one side A silicone resin coated with a release agent. A carrier film 10 coated with the release agent was set in a chamber of a vacuum evaporation apparatus under a pressure of 1.0 to 3.0 × 10-3 Pa, 2 (TC nitrogen). After being left in the atmosphere for about 100 seconds, it was heated to a predetermined temperature of the gold evaporation source (purity 99.99%) to evaporate the gold, and a gold film of about 2000 A was deposited on the carrier film 10 to form a gold foil. 9. When this vacuum evaporation method is used, although not shown in the figure, the gold foil sheet 9 shown in FIG. 4 may be in a state where a release exists between the carrier film 10 and the gold foil G. Then, the film is formed by the method of adhesion. In the case of gold foil, the gold foil layer can be formed, for example, as follows. First, a titanium (or SUS) drum is immersed in a gold plating solution, and the drum is used as a cathode to deposit gold on the drum surface (film thickness 2000A). The gold plating solution used is a weakly alkaline high-purity gold plating solution with a gold concentration of 10 g / l and a specific gravity of 12 to 25 Be. The temperature is 50t, pH 8. In addition, the current density is set in the range of 0 · 2 ~ 0 · 6 A / d m2, and the gold / platinum anode is used for gold plating. The gold-plated drum is then taken out of the gold plating solution and subjected to gold plating. After washing and drying, put a carrier film 10 made of PET with double-sided tape on one side, overlap the double-sided tape side on the gold-plated surface of the drum, and peel off the gold plating from the drum to form a gold-plated foil 9. As mentioned above It is said that the decorative material adhered to the adhesive surface 4 a of the ductile resin film 4 of the adherend B can be a foil, but other metal foils such as gold foil sheets, silver foil sheets, metal powders such as gold powder, silver powder, and pigment powder. It can also be applied in the same way. In the case of flakes or powder materials, after falling on the adhesive surface for 4 years, you can press with your fingers to remove unnecessary flakes and powders. -25- ^ The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling in and then fill in the pages ------ order --------- line Qin 557255 A7

V. Description of the invention (24) The adherend B material that can be decorated according to the method of the present invention may be metal, plastic, stone, wood, glass, fiber products, paper, lacquer products, leather, etc. The surface of the adherend B may be flat , Can also have bumps. The effect of the invention is as detailed above. According to the present invention, no skilled technique is required, and in a dry state, metal foils such as gold foil, metal flakes such as metal foil, metal powders such as gold powder, and pigment powder can be used. The adherend is decorated. In addition, with the method of the present invention and the double-sided adhesive sheet laminate, the adhesive does not ooze out on the decorative surface, and the decoration can be performed at any time. However, since the two-sided adhesive sheet of the present invention is flexible and ductile, even if the adherend is curved, it can be matched accordingly. Furthermore, even if the foil is extremely thin, the surface of the adherend can be decorated very easily. I test symbol description 1 ..... laminated sheet on both sides 2 ..... 2 peeling sheet 3 ..... adhesive layer 4 .... Printed 5 ..... First release sheet 6 ..... Both sides adhesive sheet 7 ..... Transfer sheet 8 ..... Adhesive layer 9 ..... With foil 10 .... Carrier film · -26- This paper size applies to China National Standard (CNS) A4 (210 x 297 mm)

Claims (1)

557 Patent Application No. 9 0 1 0 4 5 4 0 “Patent method for decoration and laminated surface of two-sided adhesive sheet and foil with this method” (Amended on June 27, 1992) A. Application Patent scope: too. Or71a! .. i. &%;% 子 # The original 1. A method of decorating the surface of an adherend ', which is characterized in that an adhesive is provided on one side of the ductile resin film (4) with adhesiveness Layer (3) to form a double-sided adhesive sheet (6), cut it into a desired shape, attach the adhesive layer of the cut-out two-sided adhesive sheet to the adherend, and adhere the foil, foil sheet or metal powder On the adhesive surface of the ductile resin grease (4), remove any foil, foil sheet or metal powder that is not attached to the adhesive surface. 2. The method for decorating the surface of an adherend, such as in the scope of patent application No. 1, wherein the two-sided adhesive sheet maintains the desired shape during the film moving process or the dross removing process. 3. For example, the method for decorating the surface of an adherend in the scope of application for a patent, wherein the two-sided adhesive sheet is formed by providing first and second release sheets on the inside and outside thereof, and laminating the first and second release sheets. The laminated body is cut into a desired shape, and the second release sheet on the adhesive layer side is peeled off. After the side surface of the adhesive layer is adhered to the surface of the adhesive body, the first release sheet is peeled off from the adhesive surface of the ductile resin film. Adhesion to the adherend, to the adhesive surface of the remaining ductile resin film, to the foil, foil sheet or powder. 4. For the decoration of the surface of the adherend in the first scope of the patent application 557255 Sixth, the scope of the patent application method, wherein the two-sided adhesive sheet is formed by the first and second release sheets on the inside and outside, The laminated body obtained by laminating the second release sheet with the second release sheet is cut into a desired shape, and then the first release sheet surface of the laminated body is combined with a transfer sheet, and then the second release sheet on the adhesive layer side is peeled off, and the adhesive is removed. After the layer-side surface is adhered to the surface of the adherend, the transfer sheet is peeled off from the ductile resin film together with the first release sheet on the adhesive surface of the ductile resin film, adheres to the adherend, and remains in the remaining extension. Adhesive surface of the resin film, foil, foil sheet or powder. 5. For example, the method for decorating the surface of an adherend in the scope of application for a patent, wherein the two-sided adhesive sheet is formed by providing first and second release sheets on the inside and outside thereof, and laminating the first and second release sheets. The laminated body is cut into a desired shape, and after the first release sheet on the ductile resin film of the two-sided adhesive sheet is peeled off, the adhesive surface of the ductile resin film of the two-sided adhesive sheet is combined with the transfer sheet, and then the adhesive is peeled off. The second release sheet on the layer side adheres the adhesive layer of the two-sided adhesive sheet to the surface of the adherend, and then peels off the transfer sheet, adheres to the adherend, and adheres the foil on the adhesive surface of the remaining ductile resin film. , Foil or powder. 6. The method for decorating the surface of an adherend, such as in the scope of patent application item 1, wherein the two-sided adhesive sheet is formed by providing first and second release sheets on the inside and outside thereof, where the first and second release sheets are laminated 557255 Sixth, apply for a patent application 丨 The laminated body obtained from the ductile resin film on the adhesive surface of the first-the release sheet side cracks in the desired shape > but the second release sheet without cutting the back to remove unnecessary parts of the- The release sheet and the double-sided adhesive sheet are combined with the transfer sheet on the first layer of the remaining laminate. The laminate and the transfer sheet are peeled from the second release sheet after the transfer sheet is combined with the transfer sheet. The double-sided adhesive sheet and the first release sheet having a desired shape are transferred. Print on the transfer sheet and then stick the adhesive on both sides of the transfer sheet to the adherend. Then peel off the transfer sheet and the first release sheet together and adhere to the adherend. QJjL The remaining ductility Adhesive surface of lipid film) Adhesive foil \ foil sheet or powder 0 7. If you string the method of decorating the surface of the adherend in the first item of the patent scope 1, where the two-sided adhesive sheet is provided with a first and Formed by the second release sheet j The laminated α / αι body where the first and second release sheets are laminated > From the first release sheet side J on the adhesive surface of the ductile resin film J is cracked in a desired shape without cutting Second peeling sheet 1 that passes through the back surface 1 peel off the first peeling sheet with a desired shape crack part and the other unnecessary parts — peeling sheet and double-sided adhesive sheet to remove the adhesiveness to the remaining ductile resin film After the surface is bonded to the transfer sheet, it is peeled off, and the two-sided adhesive sheet having the desired shape to form a crack is transferred to the transfer sheet 1 Next, the transfer sheet is transferred to both sides of the transfer sheet-3 Surface > adhesion with six 557,255, patented scope of the adhesive member after the transfer sheet is peeled off, the adhesive is adhered to the body, the ductility of the remaining surface of the resin film, an adhesive foil, sheet or foil by powder. 8. The method for decorating the surface of an adherend according to any one of claims 1-7, wherein the foil, foil sheet or powder is adhered to the adhesive surface of the ductile resin film, which is on the surface of the ductile resin film. Adhesive surface is wiped with alcohol. 9. The method for decorating the surface of an adherend according to any one of claims 1 to 7, wherein the foil is adhered to the adhesive surface of the ductile resin film, which is obtained by combining the carrier film with the foil on one side and the foil. After the foil surface is adhered to the adhesive surface, the carrier is peeled from the foil-attached sheet. 10. A double-sided adhesive sheet laminate comprising a ductile resin film having an adhesive surface on at least one side, a first release sheet provided on the adhesive surface of one side of the ductile resin film, and provided on the ductile resin film. An adhesive layer on one side and a second release sheet provided on the surface of the adhesive layer. 1L is the double-sided adhesive sheet laminate of item 10 in the scope of patent application, in which the elongation of the double-sided adhesive sheet composed of the ductile resin film and the adhesive layer is 70 to 200%. 12 For example, the two-sided adhesive sheet laminates of item 10 or 11 in the scope of patent application, in which the adhesive force of the ductile resin film is greater than that of the adhesive layer -4- 557255 6. The scope of patent application is that the adhesive force is smaller. ia If the two-sided adhesive sheet laminate of item 12 of the scope of the patent application, the adhesive force of the ductile resin film measured according to IS Z0237 is 40 ~ 280 g / cm (100 ~ 700g / 25mm), the adhesive of the adhesive layer The adhesive force is above 400g / cm (1000g / 25mm). 14. The double-sided adhesive sheet laminated body according to any one of claims 10 to 13 of the scope of the patent application, wherein the ductile resin film is composed of a mixture of an adhesive and a resin. 15. For example, the double-sided adhesive sheet laminate of item 14 of the scope of patent application, wherein the adhesive is composed of an acrylic adhesive, and the ratio of the acrylic adhesive to the resin, that is, the acrylic adhesive is 2.5: 1. ~ 3.5: 1. 16. For example, the double-sided adhesive sheet laminate of item Nos. 14 or 15 of the patent application g, wherein the adhesive is an acrylic adhesive, and the resin is an acrylic resin 'vinyl acetate resin, a cellulose resin, and a polyacetate resin. 'Vinyl acetate-vinyl chloride graft copolymer resin, ethylene-vinyl acetate copolymer resin, amine ester resin, or a mixture of two or more. 17 · —A kind of foil with a sheet is adhered to the adhesive surface of a laminated body with a double-sided adhesive sheet as described in any one of the scope of application patent No. 丨 〇_ 丨 6. The box-attached sheet is composed of a carrier film and is bonded to the carrier surface One-sided foil constitutes' foil bonding strength, which is peel strength, which is 0.01 ~ 25g / cm 557255 6. Those who apply for patents. 18. The attached foil according to item 17 of the scope of patent application, wherein the bonding strength between the carrier film and the foil is weaker than the adhesive force of the adhesive surface of the ductile resin film on both sides. (For example, the attached foil with the scope of patent application No. 17 or 18, in which the foil is formed by the sputtering method, the vacuum evaporation method or the plating method. 20. For example, the attached foil in any of the items 17 to 19 of the scope of patent application, wherein the material of the fan is An, Ag, Cu, Pt, Pd, Ir, Rh, Ru, A1, Ni, or any two of them. More than one alloy. 21. The foil sheet according to any one of claims 17-20, wherein the material of the carrier film is resin, paper, rubber or metal. 22. For the foil attached with item 21 of the patent application, in which the carrier film is made of transparent resin or rubber, at least one side can be colored or printed.