TW555638B - Rubber roll and making method thereof - Google Patents
Rubber roll and making method thereof Download PDFInfo
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- TW555638B TW555638B TW090107943A TW90107943A TW555638B TW 555638 B TW555638 B TW 555638B TW 090107943 A TW090107943 A TW 090107943A TW 90107943 A TW90107943 A TW 90107943A TW 555638 B TW555638 B TW 555638B
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555638 7363pif.doc/0〇8 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明(I) 發明領域 本發明是關於例如在影印機、雷射印表機、傳真機以 及自動提款機等所使用的橡膠滾輪,特別是關於具有發泡 橡膠層的橡膠滾輪。 枝術背景 影印機等的事務機械中,使用了帶電滾輪、顯像滾輪、 複印滾輪、供紙滾輪、運送滾輪以及固定滾輪等橡膠滾輪。 此事務機械在形成圖像的場合,首先以帶電滾輪使感光鼓 等的靜電潛像保持體均一的帶電。其次,使圖像曝光以使 靜電潛像保持體上形成靜電潛像。接著,以顯像滾輪供給 調色劑至靜電潛像保持體上,以形成調色影像。並且以供 紙滾輪以及運送滾輪將紙等被印刷體運送至靜電潛像保持 體,以複印滾輪將調色影像複印至被印刷體上。而調色影 像再以固定滾輪將之固定於被印刷體上。 帶電滾輪、顯像滾輪以及複印滾輪由於與靜電潛像保 持體接觸,並且爲了在與靜電潛像保持體之間得到適當的 漸增曲率,必須具有相當程度的柔軟度。而且,由提高被 印刷體的運送能力的角度觀點,供紙滾輪以及運送滾輪亦 必須具有相當程度的柔軟性。特別是近年對圖像的高精密 化以及高密度化的求日漸提高,而希望能夠得到更加柔軟 的橡膠滾輪。爲了達成賦予橡膠滾輪柔軟性的目的,使用 了發泡橡膠(請參照例如特開平11-201140號公報等)。 4 --- (請先閱讀背面之注意事項再填寫本頁) -J. 訂:555638 7363pif.doc / 0〇8 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Description of the Invention (I) Field of the Invention The present invention relates to, for example, photocopiers, laser printers, facsimile machines and automatic withdrawals. Rubber rollers used in machines and the like, particularly rubber rollers having a foamed rubber layer. Background of the branch technique In office machines such as photocopiers, rubber rollers such as a charging roller, a developing roller, a copy roller, a paper feed roller, a transport roller, and a fixed roller are used. When this office machine forms an image, first, an electrostatic latent image holder such as a photosensitive drum is uniformly charged with a charging roller. Next, the image is exposed so that an electrostatic latent image is formed on the electrostatic latent image holder. Next, toner is supplied onto the electrostatic latent image holder by a developing roller to form a toned image. Then, the printed object such as paper is conveyed to the electrostatic latent image holding body by a paper feed roller and a conveying roller, and the toned image is copied to the printed object by the copy roller. The toned image is then fixed to the object to be printed by a fixed roller. The charged roller, the developing roller, and the copy roller are in contact with the electrostatic latent image holder, and must have a certain degree of softness in order to obtain a proper gradual curvature with the electrostatic latent image holder. Further, from the viewpoint of improving the conveying capacity of the printed body, the paper feed roller and the conveying roller must also have a certain degree of flexibility. In particular, in recent years, the demand for high-precision and high-density images has been increasing, and more flexible rubber rollers are desired. For the purpose of imparting flexibility to rubber rollers, foamed rubber is used (see, for example, Japanese Patent Application Laid-Open No. 11-201140). 4 --- (Please read the notes on the back before filling this page) -J. Order:
本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 555638 A7 B7 7363pif.doc/008 五、發明說明ο) 具備有發泡橡膠層的橡膠滾輪的製造方法,首先將含 有發泡劑的橡膠組合物押出成形爲管狀物,其次將此管狀 物插入假芯中並投入加硫罐,加熱以使橡膠架橋的同時並 使發泡劑發泡,以得到發泡橡膠的成形體。其次將此發泡 橡膠的成形體由假芯拔出並插入軸芯(作爲最終成品之一 部份的芯),硏磨發泡橡膠成形體的的表面,得到由軸芯 以及發泡橡膠層所組成的橡膠滾輪。硏磨的目的在使發泡 橡膠表面平坦化、調整表面的粗細度。使用假芯的目的係 由於在後述架橋時管狀物內徑會擴徑,因此所使用的軸芯 直徑較假芯的直徑大。 以加硫罐架橋並發泡會使得管狀物的外徑膨脹,由於 管狀物與假芯之間具有空隙,以加硫罐的內壓使得管狀物 的內徑亦變大。此時內徑的擴徑量因部位而異,所得的發 泡橡膠成形體的內徑亦隨之變得不均一。內徑不均一的 話’軸芯與發泡橡膠層之間的部份會形成空氣層,使得軸 芯與發泡橡膠層之間的接著力變得不足夠。而且,空氣層 會使得橡膠滾輪的電阻値不均一。更加的,此空氣層在硏 磨時會發熱膨脹,即使在膨脹狀態將發泡橡膠層磨平,由 於其後在常溫時空氣層回復原來的體積,此空氣層之上的 發泡橡膠層會凹陷,發泡橡膠層表面上所產生的凹凸不平 將助長電阻値的不均一現象。 5 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -------------^ ^^裝--- (請先閱讀背面之注意事項再填寫本頁) 訂· 經濟部智慧財產局員工消費合作社印製 A7 555638 7363pif.doc/008 瓜 五、發明說明(i ) 特開平10-90975號公報中,揭示了 一種使用橫頭 (Crosshead)押出機在支撐軸上押出橡膠組成物,再將其加 硫架橋的製造方法。使用橫頭押出機所押出後的支撐軸與 橡膠組成物的間隙很小。但是,通常的橫頭押出的話,支 撐軸以及橡膠組成物不能夠密著,由於兩者之間依然會形 成空氣層,而殘留支撐軸與橡膠層的接著力不足,或橡膠 滾輪的外徑以及電阻値不均一的問題。 此接著力不足的問題以及不均一性的問題,例如在特 開平7-238923號公報、特開平7-295331號公報以及特開 平10-156917號公報中,亦揭示了所謂的以共押出的方式, 在發泡橡膠層上設置固形橡膠層(Solid rubber)的橡膠滾 發明槪述 有鑑於上述的問題,本發明的目的在提供一種橡膠滾 輪,此橡膠滾輪的軸芯與發泡橡膠層的接著力高、且外徑 以及電阻値具有優良的均一性。 爲了達成本發明上述的目的,本發明提供一種橡膠滾 輪的製造方法,此製造方法包含下列步驟:將含有發泡劑 的未架橋橡膠組成物所形成的管狀物,呈密著狀態的被覆 至軸芯的表面的被覆步驟;以及將此管狀物加熱以使橡膠 6 本紙張尺度ϊΐ用中國國家標準(CNS)A4規格(210 X 297公釐) " " ---------7------ (請先閱讀背面之注意事項再填寫本頁) 訂·This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 555638 A7 B7 7363pif.doc / 008 V. Description of the invention ο) The manufacturing method of a rubber roller with a foamed rubber layer, first of all The rubber composition of the foaming agent is extruded and formed into a tube, and then the tube is inserted into a dummy core and put into a vulcanization tank, and the foaming agent is foamed while heating to bridge the rubber to obtain a foamed rubber molded body . Next, this foamed rubber molded body is pulled out from the dummy core and inserted into the shaft core (the core as a part of the final product), and the surface of the foamed rubber molded body is honed to obtain a shaft core and a foamed rubber layer. Composed of rubber rollers. The purpose of honing is to flatten the surface of the foamed rubber and adjust the thickness of the surface. The purpose of using a dummy core is because the diameter of the tubular body will increase when the bridge is described later, so the diameter of the shaft core used is larger than the diameter of the dummy core. Bridging and foaming with a vulcanization tank will expand the outer diameter of the tube. Due to the gap between the tube and the dummy core, the inner pressure of the vulcanization tank will also increase the inner diameter of the tube. At this time, the amount of expansion of the inner diameter varies from site to site, and the inner diameter of the obtained foamed rubber molded body also becomes uneven. If the inner diameter is not uniform, an air layer is formed in the portion between the shaft core and the foamed rubber layer, and the adhesion between the shaft core and the foamed rubber layer becomes insufficient. Also, the air layer makes the resistance of the rubber roller uneven. Furthermore, this air layer will heat up and expand during honing. Even if the foamed rubber layer is smoothed in the expanded state, since the air layer returns to its original volume at normal temperature, the foamed rubber layer above this air layer will The depressions and irregularities on the surface of the foamed rubber layer will promote the unevenness of the electric resistance. 5 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------- ^ ^^ Packing --- (Please read the precautions on the back before filling (This page) Printed by the Consumers ’Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs A7 555638 7363pif.doc / 008 Description of the Invention (i) Japanese Unexamined Patent Publication No. 10-90975 discloses a crosshead extruder A manufacturing method of extruding a rubber composition on a support shaft and vulcanizing the rubber composition. The clearance between the support shaft and the rubber composition after being extruded using a cross-head extruder is small. However, if the horizontal head is pushed out normally, the support shaft and the rubber composition cannot be tightly adhered, because an air layer is still formed between the two, and the adhesion between the remaining support shaft and the rubber layer is insufficient, or the outer diameter of the rubber roller and The problem of uneven resistance. The problem of inadequate follow-up force and the problem of heterogeneity, such as in JP 7-238923, JP 7-295331, and JP 10-156917, have also revealed the so-called co-staking method. The invention of a rubber roller in which a solid rubber layer is provided on a foamed rubber layer is described in view of the above-mentioned problems. The object of the present invention is to provide a rubber roller, in which the shaft core of the rubber roller and the foamed rubber layer are bonded. High force and excellent uniformity of outer diameter and resistance. In order to achieve the above-mentioned object of the present invention, the present invention provides a method for manufacturing a rubber roller. The manufacturing method includes the following steps: a tubular object formed by an unbridged rubber composition containing a foaming agent is applied to the shaft in a tight state. A coating step of the surface of the core; and heating the tube to make the rubber 6 paper sizes use the Chinese National Standard (CNS) A4 specification (210 X 297 mm) " " --------- 7 ------ (Please read the notes on the back before filling this page) Order ·
經濟部智慧財產局員工消費合作社印製 555638 A7 B7 7363pif.doc/008 五、發明說明(α) 架橋的同時使發泡劑發泡的架橋步驟。 (請先閱讀背面之注意事項再填寫本頁) 此製造方法由於在被覆步驟中管狀物與軸芯呈密著狀 態,在架橋步驟中管狀物的內徑不會擴徑。因此軸芯與發 泡橡膠層之間不會形成空氣層。依此製造方法所得的橡膠 滾輪,其軸芯與發泡橡膠層的接著力高,而且不會產生空 氣層所引起的電阻値的不均一。更加的此橡膠滾輪不會因 硏磨時的空氣層膨脹產生外徑的不均一。尙且,此製造方 法中的「管狀物與軸芯呈密著狀態」,其意義係表示兩者 之間實質上未介入空氣層(包含氣泡)或其他異物。 此製造方法的話係將被覆步驟所使用的軸芯繼續使用 而成爲最終成品的一部份。因此,不須如同習知的製造方 法將假芯插入或拔脫而使得工程簡化。依此橡膠滾輪的製 造成本亦得以降低。 經濟部智慧財產局員工消費合作社印製 在被覆步驟中管狀物的內徑較佳爲軸芯外徑的0.5倍 以上、0.9倍以下。依此軸芯與管狀物能夠確實的成爲密 著狀態。將此內徑較軸芯的外徑小的管狀物被覆在軸芯上 的方法,可以使用壓入法,亦可以使用橫頭押出機將之押 出。使用橫頭押出機的場合將軸芯插入頭部中,在將管狀 物押出的同時被覆至軸芯上。尙且,使用橫頭押出機的場 合’在管狀物被押出且尙未插入軸芯時,此管狀物的內徑 爲軸芯外徑的0.5倍以上、〇.9倍以下。 7 玉紙張尺度適用中國國家標準(CNS)A4規格(2K) X 29?公釐) 555638 A7 B7 7363pif.doc/008 五、發明說明(t) 使用橫頭押出機的場合,較佳係以吸引的方式,一邊 使管狀物與軸芯之間呈負壓狀態,且將管狀物被覆至軸芯 上。依此的話,軸芯與管狀物能確實的成爲密著狀態。在 進行吸引的場合,管狀物的內徑亦可以超過軸芯外徑的0.9 倍。 此製造方法的話,不僅適用於由軸芯以及發泡橡膠層 形成橡膠滾輪,亦適合用於製造在發泡橡膠層上設置有固 形橡膠層、其他層的橡膠滾輪。尙且,固形橡膠層係爲實 質上不含氣泡的橡膠層。 圖式之簡單說明 第1圖所示爲本發明之一實施例的橡膠滾輪1的斜視 圖;以及 第2圖所示爲第1圖的橡膠滾輪1的被覆步驟的部份 剖面圖。 圖示之標示說明_· 1 :橡膠滾輪 3 :軸芯 5:發泡橡膠層 7:橫頭押出機 9 :圓筒 8 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --------<----裝— (請先閱讀背面之注意事項再填寫本頁) 訂: 經濟部智慧財產局員工消費合作社印製 555638 經濟部智慧財產局員工消費合作社印製 A7 7363pif.doc/008 R7 ---------* ' 五、發明說明(乙) 11 :螺桿 13 :頭部 15 : 口部金屬 17 :內筒 19 :橡膠組成物 21 :管狀物 23 :插入口 鮫佳實施例之詳細說明 以下爲參照圖式對本發明的實施形態做說明。 第1圖所示爲本發明之一實施例的橡膠滾輪1的斜蜆 圖。此橡膠滾輪1具備有軸芯3以及發泡橡膠層5。軸芯 3的剖面爲圓形的棒狀、發泡橡膠層5爲圓筒狀。且軸芯 3的外周面及發泡橡膠層5的內周面互相接觸。 軸芯3的材質並沒有特別的限制,例如可使用合成樹 脂、金屬等。使用於帶電滾輪、顯像滾輪、以及影印滚輪 的場合,橡膠滾輪1必須具有導電性。由於此時軸芯3亦 必須具有導電性,軸芯3通常係使用金屬材料。 發泡橡膠層5係以橡膠組成物架橋形成。所使用的橡 膠例如是烯·丙烯-雙嫌三元共聚物(ethlene-propylene-diene copolymer)、丁二烯共聚物(styrene-butadiene copolymer)、 9 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公复) (請先閱讀背面之注音?事項再填寫本頁)Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 555638 A7 B7 7363pif.doc / 008 V. Description of the invention (α) The bridging step of foaming agent while bridging. (Please read the precautions on the back before filling in this page.) This manufacturing method does not expand the inner diameter of the tubular during the bridging step because the tubular is in close contact with the shaft core during the coating step. Therefore, no air layer is formed between the shaft core and the foam rubber layer. The rubber roller obtained by this manufacturing method has a high adhesion force between the shaft core and the foamed rubber layer, and does not cause unevenness in resistance 値 caused by the air layer. Furthermore, this rubber roller does not cause uneven outer diameter due to the expansion of the air layer during honing. In addition, the meaning of "the tubular object and the shaft core are in close contact" in this manufacturing method means that there is substantially no intervening air layer (including air bubbles) or other foreign matter between the two. In this manufacturing method, the shaft core used in the coating step is continued to be used as part of the final product. Therefore, it is not necessary to simplify the process by inserting or removing the dummy core as in the conventional manufacturing method. As a result, the cost of the rubber roller is also reduced. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs In the coating step, the inner diameter of the tube is preferably 0.5 times or more and 0.9 times or less the outer diameter of the shaft core. With this, the shaft core and the tubular body can be reliably brought into close contact. The method of coating the tubular core with a smaller inner diameter than the outer diameter of the shaft core may be a press-in method or a lateral extruder to extrude it. When using a cross-head extruder, insert the shaft core into the head and cover the shaft core while extruding the tube. In addition, in the case of using a horizontal extruder, when the tubular object is extruded and the shaft core is not inserted, the inner diameter of the tubular object is 0.5 times to 0.9 times the outer diameter of the shaft core. 7 Jade paper scale is applicable to Chinese National Standard (CNS) A4 (2K) X 29? Mm) 555638 A7 B7 7363pif.doc / 008 V. Description of the invention (t) Where a horizontal extruder is used, it is better to attract Method, while the tube and the shaft core are in a negative pressure state, and the tube is covered on the shaft core. According to this, the shaft core and the tubular body can be reliably brought into close contact. In the case of suction, the inner diameter of the tube may exceed 0.9 times the outer diameter of the shaft core. This manufacturing method is not only suitable for forming a rubber roller from a shaft core and a foamed rubber layer, but also suitable for manufacturing a rubber roller provided with a solid rubber layer and other layers on the foamed rubber layer. Moreover, the solid rubber layer is a rubber layer which is substantially free of air bubbles. Brief Description of the Drawings Fig. 1 is a perspective view showing a rubber roller 1 according to an embodiment of the present invention; and Fig. 2 is a partial cross-sectional view showing a coating step of the rubber roller 1 of Fig. 1. Explanation of the signs in the picture _ · 1: Rubber roller 3: Shaft core 5: Foam rubber layer 7: Cross-head extruder 9: Cylinder 8 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ) -------- < ---- install— (Please read the precautions on the back before filling out this page) Order: Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs 555638 Employee Consumption of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the cooperative A7 7363pif.doc / 008 R7 --------- * 'V. Description of the invention (B) 11: Screw 13: Head 15: Mouth metal 17: Inner tube 19: Rubber composition 21 : Tubular object 23: Detailed description of a preferred embodiment of the insertion port The following is a description of embodiments of the present invention with reference to the drawings. Fig. 1 is an oblique view of a rubber roller 1 according to an embodiment of the present invention. This rubber roller 1 includes a shaft core 3 and a foamed rubber layer 5. The cross section of the shaft core 3 has a circular rod shape, and the foamed rubber layer 5 has a cylindrical shape. The outer peripheral surface of the shaft core 3 and the inner peripheral surface of the foamed rubber layer 5 are in contact with each other. The material of the shaft core 3 is not particularly limited, and for example, synthetic resin, metal, or the like can be used. In the case of using a charging roller, a developing roller, and a photocopying roller, the rubber roller 1 must be conductive. Since the shaft core 3 must also be conductive at this time, the shaft core 3 is usually made of a metal material. The foamed rubber layer 5 is formed by bridging with a rubber composition. The rubbers used are, for example, ethlene-propylene-diene copolymer, styrene-butadiene copolymer, 9 This paper is in accordance with China National Standard (CNS) A4 (210 X 297 public reply) (Please read the phonetic on the back? Matters before filling out this page)
555638 A7 B7 7363pif.doc/008 五、發明說明()) 天然橡膠、丁二烯橡膠(butadiene rubber)、聚異戊二烯橡 膠(isoprene rubber)、石夕橡膠(silicon rubber)、丙嫌腈-丁二 烯共聚物(acrylonitrile-butadiene copolymer)、氫化丙稀月青-丁二烯共聚物、氯丁二烯橡膠(chloroprene rubber)、丙烯 酸橡膠(acrylic rubber)、聚氨脂橡膠(urethane rubber)、環 氧氯丙院橡膠(epichlorohydrin rubber)等如上列舉者。 發泡材料層5含有氣泡。此氣泡係以發泡劑的發泡所 形成。適合使用的發泡劑例如是偶氮甲醯胺 (azodicrabonamide)、N,N-二亞硝基五甲撐四胺(N,N-dinitrosopentamethylene)等如上所列舉的化學反應型有機 發泡劑。通常在橡膠的加熱、架橋反應的同時產生發泡。 化學反應型發泡劑發泡劑的配合量(質量比),相對於橡膠 1〇〇部,其爲3部以上、12部以下左右。配合量未滿上記 的範圍則發泡倍率降低,使得橡膠滾輪1的柔軟性不足夠。 反之配合量超過上述的範圍的話,發泡劑會妨害架橋反應 使得橡膠滾輪1的強度不足夠。 發泡橡膠層5的發泡倍率較佳是在2倍以上、15倍以 下。特別是在3倍以上、6倍以上更佳。發泡倍率未滿上 記的範圍,橡膠滾輪1的柔軟性變得不足夠。反之發泡倍 率超過上述的範圍的話,橡膠滾輪1的強度會不足夠。 發泡橡膠層5的厚度並沒有特別的限制,通常在2mm 10 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --------J---4 裝--- (請先閱讀背面之注意事項再填寫本頁) 訂· 經濟部智慧財產局員工消費合作社印製 555638 7363pif.doc/008555638 A7 B7 7363pif.doc / 008 V. Description of the invention ()) Natural rubber, butadiene rubber, isoprene rubber, silicon rubber, propionitrile- Butadiene copolymer (acrylonitrile-butadiene copolymer), hydrogenated propylene moon-butadiene copolymer, chloroprene rubber (chloroprene rubber), acrylic rubber (acrylic rubber), polyurethane rubber (urethane rubber), Epichlorohydrin rubber and the like are listed above. The foamed material layer 5 contains air bubbles. The bubbles are formed by foaming of a foaming agent. Suitable foaming agents include, for example, azodicrabonamide, N, N-dinitrosopentamethylenetetramine (N, N-dinitrosopentamethylene), and the like as the chemically reactive organic foaming agents listed above. Foaming usually occurs at the same time as rubber heating and bridging reactions. The compounding amount (mass ratio) of the chemically reactive foaming agent foaming agent is about 3 or more and 12 or less based on 100 parts of the rubber. If the blending amount is less than the range described above, the foaming ratio is reduced, and the flexibility of the rubber roller 1 is insufficient. Conversely, if the blending amount exceeds the above range, the foaming agent may hinder the bridging reaction and the strength of the rubber roller 1 may be insufficient. The foaming ratio of the foamed rubber layer 5 is preferably 2 times or more and 15 times or less. Especially, it is more preferably 3 times or more and 6 times or more. When the expansion ratio is less than the above range, the flexibility of the rubber roller 1 becomes insufficient. On the other hand, if the expansion ratio exceeds the above range, the strength of the rubber roller 1 becomes insufficient. The thickness of the foamed rubber layer 5 is not particularly limited, usually at 2mm 10 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- J --- 4 Pack --- (Please read the notes on the back before filling out this page) Order Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 555638 7363pif.doc / 008
五、發明說明) 以上、10mm以下。厚度未滿上述的範圍會損及橡膠滾輪 的柔軟性,反之超過上述的範圍橡膠滾輪丨的度會不足。 經濟部智慧財產局員工消費合作社印製 使用於W電滚輪、顯像滾輪、以及複印滾輪的場合, 發泡橡膠層5必須具有導電性。通常爲配合碳黑、金屬粉 末等的電子導電性物質,賦予發泡橡膠層5導電性。而且, 使用丙細丁一燦共聚物、氫化两烯賭_丁二嫌共聚物、 氯丁二烯橡膠、丙烯酸橡膠、聚氨脂橡膠、環氧氯丙烷橡 膠等具有離子導電性、高分子本身的電氣抵抗小的橡膠, 而給予發泡橡膠層導電性。使用此些橡膠的場合不須配合 電子導電性物質。當然,亦可以使用離子導電性的橡膠再 配合電子導電性物質。 此橡膠滾輪1由軸芯3以及發泡橡膠層5所構成,亦 可以在發泡橡膠層5上設置固形橡膠層。而且,發泡橡膠 層5以及固形橡膠層之間,或固形橡驂層之上,亦可視需 要設置其他層。 第2圖所示爲第1圖的橡膠滾輪1的被覆步驟的部份 剖面圖。此圖所示爲橫頭押出機。此塽頭押出機7具備有 圓筒9、螺桿11、頭部Π、口部金屬丨5、內筒丨7。圓筒 9內塡充含有發泡劑的橡膠組成物19(發泡性橡膠組成 物)。橡膠組成物19以螺桿11的回轉,向前方(第2圖中 的右方)前進到達頭部I3。此橡膠組成物19在頭部13改 11 -------.---Ί·裝--------訂· (請先閱讀背面之注意事項再填寫本頁) % 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) — 555638 A7 B7 7363pif.doc/008 五、發明說明(^ ) 變進行方向爲朝下方,由口部金屬15押出以形成管狀物 21。一方面,由圓筒17的插入口 23將軸芯3插入。此軸 芯3通過內筒17並由口部金屬15排出並向下方前進。由 口部金屬15的附近、軸芯3的外周圍被覆管狀物21。 管狀物21的內徑(管狀物21被押出且尙未插入軸芯3 時的內徑),較佳爲軸芯3外徑的〇.5倍以上、0.9倍以下。 亦即是此橡膠滾輪1中,管狀物21的內徑扣以及軸芯3 的外徑彡s,較佳爲能滿下記數學式(1)。 【數學式1】 X 0.5 <φτ <<psx 0.9 ............(I)5. Description of the invention) Above and below 10mm. If the thickness is less than the above range, the flexibility of the rubber roller will be impaired, and if the thickness exceeds the above range, the degree of the rubber roller will be insufficient. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. For use in W electric rollers, development rollers, and copy rollers, the foamed rubber layer 5 must be conductive. Generally, an electrically conductive material such as carbon black or metal powder is blended to impart conductivity to the foamed rubber layer 5. In addition, acrylic copolymers, hydrogenated diene copolymers, chloroprene copolymers, chloroprene rubber, acrylic rubber, polyurethane rubber, epichlorohydrin rubber, etc. are used, which have ion conductivity and polymers themselves. The electrical resistance of the rubber is small, while imparting conductivity to the foamed rubber layer. The use of these rubbers does not require the use of electronically conductive materials. Of course, an ion-conducting rubber may be used in combination with an electron-conducting substance. This rubber roller 1 is composed of a shaft core 3 and a foamed rubber layer 5. A solid rubber layer may be provided on the foamed rubber layer 5. In addition, other layers may be provided between the foamed rubber layer 5 and the solid rubber layer, or on the solid rubber layer. Fig. 2 is a partial sectional view showing a coating step of the rubber roller 1 of Fig. 1. This picture shows a horizontal head extruder. This hoe extruder 7 is provided with a cylinder 9, a screw 11, a head Π, a mouth metal 丨 5, and an inner cylinder 丨 7. The cylinder 9 is filled with a rubber composition 19 (foamable rubber composition) containing a foaming agent. With the rotation of the screw 11, the rubber composition 19 advances forward (to the right in FIG. 2) to the head I3. This rubber composition 19 is changed from the head 13 to the 11 -------.----------------------- Order (Please read the precautions on the back before filling this page)% of this Paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) — 555638 A7 B7 7363pif.doc / 008 V. Description of the invention (^) Change the direction of the downward direction, extrude from the mouth metal 15 to form a tube物 21. On the other hand, the shaft core 3 is inserted through the insertion port 23 of the cylinder 17. This shaft core 3 passes through the inner cylinder 17 and is discharged by the mouth metal 15 and advances downward. A tubular object 21 is covered by the vicinity of the mouth metal 15 and the outer periphery of the shaft core 3. The inner diameter of the tube 21 (the inner diameter when the tubular object 21 is pushed out and the shaft core 3 is not inserted) is preferably 0.5 times or more and 0.9 times or less the outer diameter of the shaft core 3. That is, in this rubber roller 1, the inner diameter buckle of the tubular object 21 and the outer diameter 轴 s of the shaft core 3 are preferably to satisfy the following mathematical formula (1). [Mathematical formula 1] X 0.5 < φτ < < psx 0.9 ............ (I)
依此管狀物21的內徑小於軸芯3的外徑,將管狀物21 強制的插入軸芯3。以此將軸芯3與管狀物21之間的空氣 排擠出,使軸芯3與管狀物21之間成爲密著狀態。管狀 物21的內徑超過軸芯3的外徑的0.9倍,排擠出空氣的效 果變得不充分。反之,管狀物21的內徑未滿軸芯3的外 徑的〇·5倍,在被覆作業上會變得困難。依此觀點的話, 管狀物21的內徑更佳爲軸芯3的外徑的0.6倍、以上〇.85 倍以下,特別是更佳的爲0.65倍以上、0.8倍以下。尙且, 軸芯3與管狀物21的密著狀態,必須能夠包含完成製品 全部的有效長度。 Q 12 冢紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ^ -- --------1----^ 裝--- (請先閱讀背面之注意事項再填寫本頁) 訂· 經濟部智慧財產局員工消費合作社印製 555638 7363pif.doc/008 A7 B7 五、發明說明(Ο 較佳的是由插入口 23 —邊進行吸引並押出。依此在 口部金屬15附近的管狀物21及軸芯3之間成爲負壓狀態’ 兩者能確實的成爲密著狀態。進行吸引的場合,管狀物21 的內徑亦可以超過軸芯3外徑的〇·9倍。當然’在進行吸 引的場合,管狀物21的內徑爲軸芯3的外徑的0.5倍、以 上0.9倍以下時,管狀物21與軸芯3能確實的達成密著狀 態。 第2圖爲僅由發泡性橡膠組合物形成管狀物21,然而 亦可以使用所謂的共押出,以形成具備有發泡性橡膠組成 物所構成的內層、以及固形橡膠組成物所構成的外層的管 狀物。此場合亦由插入口 23插入軸芯3,向軸芯3上被覆 管狀物。而且,亦可以使用橫頭押出機17僅以發泡性橡 膠組成物形成管狀物,再於此管狀物表面覆蓋固形橡膠組 成物。 T----^ 裝--- (請先閱讀背面之注意事項再填寫本頁) 訂· % 經濟部智慧財產局員工消費合作社印製 而且,亦可以使用未具備內筒17的押出機將管狀物 押出,再將此管狀物強制押入軸芯3。在此場合,管狀物 的內徑亦爲軸芯3的外徑的〇·5倍、以上〇·9倍以下、特 別是軸芯3的外徑的0.6倍以上、〇.85倍以下,特別是更 佳的是0.65倍以上、0.8倍以下,以將軸芯3與管狀物間 的空氣排擠出’達成兩者的密著狀態。強制壓入時,以作 爲潤滑劑的水、酒精等,塗佈在軸芯3的外周面以及管狀 本紙張尺度適用中國國家標準(CNS)A4規格(2]0 X 297公髮) 555638 A7 B7 7363pif.doc/008 五、發明說明(") 物的內周面。而且,亦可以在吹入壓縮空氣的同時,進行 機械的強制壓入。 被覆在軸芯3上的管狀物21以加熱進行架橋(架橋步 驟)。架橋可以使用金屬模具進行’而且亦可以使用加硫 罐進行。架橋時發泡劑進行發泡而形成發泡橡膠層5。 以下舉出實施例的說明,以使本發明的功效更加令人 明瞭,然而此實施例的的記載並不能解釋爲用於限定本發 明。尙且,以下配合量的記載中「部」所表示的數値係以 質量爲基準的比値。 [實施例1] 將丙烯膀-丁二烯共聚物(日本合成橡膠公司的商品名 「N215SL」)80部、烯-丙烯-雙烯三元共聚物(三井石油化 學公司的商品名「EPT4021」)20部、碳黑(東海碳公司的 商品名「Seast3」)5部,甘油三硬脂酸酯(stearic acid)(日 本油脂公司)1部,發泡劑(永和化成工業公司的商品名 「VINYFOR AC#3」)7部,其他的發泡劑(永和化成工業 公司的商品名「NEOCELLBORN N5000」)3部,硫磺(鶴 見化學公司的商品名「粉末硫黃」)1.5部做爲加硫促進劑 的二硫代四乙基秋蘭姆(tetraethylthiuram disulfide)(大內新 興化學工業公司的商品名「諾克席拉TET」)1.5部,作爲 其他加硫促進劑的 2-氫硫基苯并P塞唑(2- 14 ^紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --------1---^ 裝--- (請先閱讀背面之注意事項再填寫本頁) 訂· 經濟部智慧財產局員工消費合作社印製 555638 7363pif.doc/008 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明((q mecaptobenzothiazol)(大內新興化學工業公司的商品名「諾 克席拉M」)1部以及作爲其他加硫促進劑的N-環己基-2-次擴醯胺苯并 □塞哗 (N-cyclohexyl-2-benzthiazolesulfenamide)(大內新興化學工業社的商品名 「諾克席拉CZ」)0.6部混練,得到發泡性的橡膠組合物。 此橡膠組成物投入螺桿徑90mm,螺徑比(L/D)爲18 的橫頭押出機(中田Engineering社製)的圓筒中。然後以螺 桿的溫度40°C、圓筒的溫度40°C、頭部的溫度40°C、螺 桿的回轉速度lOrpm等條件,押出內徑爲5.5mm的管狀 物。一方面,由插入口插入外徑爲0.6mm的軸芯,由插入 口一邊吸引,而在此軸芯的表面被覆管狀物。 其次,將此軸芯以及管狀物投入加硫罐,加熱以使管 狀物架橋。在架橋的同時發泡劑進行發泡,以形成發泡橡 膠層。此發泡橡膠層的表面以通常的方法使用磨石進行硏 磨,而得到實施例1的橡膠滾輪。 [實施例2] 不經由插入口進行吸引,其他的實施條件與實施例1 相同,以得到實施例2的橡膠滾輪。 [實施例3] 以通常的押出機將與實施例1相同的橡膠組成物押 出,得到內徑5.5mm的管狀物,在一邊留意不使管狀物變 形的情形下,強制壓入與實施例1相同的軸芯(外徑 15 (請先閱讀背面之注意事項再填寫本頁) 訂·· ;線- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 555638 7363pif.doc/008 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明 0.6mm)。強制壓入時使用乙醇作爲潤滑劑,其後如同實施 例1將管狀物管狀物架橋,形成發泡橡膠層。此發泡橡膠 層使用與實施例1相同的方法硏磨,以得到實施例3的發 泡橡膠層。 [比較例] 以通常的押出機將與實施例1相同的橡膠組成物押 出,以得到內徑5.5mm的管狀物,將此管狀物插入外徑 2.0mm的假芯,吊置於加硫罐中進行架橋,以得到由發泡 橡膠層所構成的圓筒體。將此圓筒體強制壓入與實施例1 相同的軸芯(外徑〇.6mm)。強制壓入時使用乙醇作爲潤滑 劑。此發泡橡膠層使用與實施例1相同的方法硏磨,以得 到比較例的發泡橡膠層。 [表面平滑性的評價] 將橡膠滾輪置於表面平坦的平臺上。然後以與軸方向 垂直的方向照光,以目視觀察橡膠滾輪與平臺間露出的光 線。完全沒有露出光線者以「◎」表示,幾乎沒有露出光 線者「〇」表示,外露很多光線者以「X」表示。此結果 表示如下記的表1。 [加工性的評價] 在表面硏磨時評價其加工性。軸芯和發泡橡膠層的密 著性(接著力)相當的高,大量生產時可靠度高者以「◎」 16 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) L 裝--- (請先閱讀背面之注意事項再填寫本頁) 訂·According to this, the inner diameter of the tubular object 21 is smaller than the outer diameter of the shaft core 3, and the tubular object 21 is forcibly inserted into the shaft core 3. As a result, the air between the shaft core 3 and the tubular body 21 is exhausted, and the shaft core 3 and the tubular body 21 are brought into a close state. The inner diameter of the tubular body 21 exceeds 0.9 times the outer diameter of the shaft core 3, and the effect of exhausting the air becomes insufficient. On the other hand, if the inner diameter of the tubular object 21 is less than 0.5 times the outer diameter of the shaft core 3, it becomes difficult to perform coating work. From this viewpoint, the inner diameter of the tube 21 is more preferably 0.6 times or more and 0.85 times or less, and more preferably 0.65 times or more and 0.8 times or less. In addition, the close state of the shaft core 3 and the tubular object 21 must be able to cover the entire effective length of the finished product. Q 12 The size of the mound paper is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) ^--------- 1 ---- ^ Loading --- (Please read the precautions on the back first Refill this page) Order · Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 555638 7363pif.doc / 008 A7 B7 V. Description of the invention (0 It is better to be attracted and pushed out by the insertion port 23-click here Negative pressure exists between the tubular object 21 and the shaft core 3 near the metal part 15 'Both can be reliably brought into close contact. When suctioning, the inner diameter of the tubular object 21 may exceed the outer diameter of the shaft core 3 by 〇 · 9 times. Of course, when the inner diameter of the tubular body 21 is 0.5 times or more and 0.9 times or less the outer diameter of the shaft core 3 when the suction is performed, the tubular body 21 and the shaft core 3 can be reliably adhered to each other. FIG. 2 shows a tubular body 21 formed only of a foamable rubber composition. However, a so-called co-extrusion may be used to form an inner layer composed of a foamable rubber composition and a solid rubber composition. Outer tube. In this case, insert the shaft core 3 through the insertion port 23, and cover the tube with the shaft core 3. In addition, you can also use the cross-head extruder 17 to form a tube only from the foamable rubber composition, and then cover the surface of the tube with a solid rubber composition. T ---- ^ 装 --- (Please read first Note on the back, please fill in this page again.) Order% Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Also, you can use an extruder without inner tube 17 to extrude the tube, and then force the tube into the core 3 In this case, the inner diameter of the tubular object is also 0.5 times or more and 0.9 times or less of the outer diameter of the shaft core 3, especially 0.6 times or more and 0.85 times or less of the outer diameter of the shaft core 3. In particular, it is more preferably 0.65 times or more and 0.8 times or less, in order to squeeze out the air between the shaft core 3 and the tubular object to achieve a close state of both. When forcedly pressed, water, alcohol, etc., which are used as lubricant , Coated on the outer peripheral surface of the shaft core 3 and the size of the tube This paper applies the Chinese National Standard (CNS) A4 specification (2) 0 X 297 issued 555638 A7 B7 7363pif.doc / 008 V. Description of the invention The inner peripheral surface of the machine. Also, the machine can be machined while blowing compressed air. Forced press-in. The tubular object 21 coated on the shaft core 3 is bridged by heating (bridging step). The bridge can be performed by using a metal mold, and it can also be performed by a vulcanization tank. When the bridge is bridged, the foaming agent is foamed to form Foamed rubber layer 5. The following is a description of examples to make the effect of the present invention more clear, but the description of this example cannot be interpreted to limit the present invention. Also, the following description of the blending amount The numbers shown in the "Ministry" are ratios based on mass. [Example 1] 80 parts of acryl-butadiene copolymer (trade name of Nippon Synthetic Rubber Co., Ltd. "N215SL") and ene-propylene -20 diene terpolymers (Mitsui Petrochemical Corporation's trade name "EPT4021"), 5 carbon blacks (Tokai Carbon Corporation's trade name "Seast3"), glycerol tristearate (stearic acid) (Japan Oil and Fat Company) 1, foaming agent (Yonghe Chemical Industry Co., Ltd. "VINYFOR AC # 3") 7, other foaming agent (Yonghe Chemical Industry Co., Ltd. "NEOCELLBORN N5000") 3, sulfur ( Tsurumi Chemical Company's trade name "powder sulphur") 1.5 parts of diethyltetrathithuram disulfide as a vulcanization accelerator (trade name "Nokishila TET" of Onai Shinko Chemical Industry Co., Ltd.) Part 1.5, 2-Hydroxythiobenzopyrazole as other vulcanization accelerator (2- 14 ^ paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------- -1 --- ^ Attachment --- (Please read the precautions on the back before filling out this page) Order · Printed by the Intellectual Property Bureau Staff Consumer Cooperative of the Ministry of Economic Affairs 555638 7363pif.doc / 008 A7 B7 Printed by the cooperative 5. A description of the invention ((q mecaptobenzothiazol) (trade name "Nokishila M" of Onai Shinko Chemical Industry Co., Ltd.) and N-cyclohexyl-2-time expansion as other vulcanization accelerators N-cyclohexyl-2-benzthiazolesulfenamide (trade name "Nokhira CZ" by Onai Shinko Chemical Co., Ltd.) was kneaded to obtain a foamable rubber composition. This rubber composition was put into a cylinder of a cross-head extruder (manufactured by Nakata Engineering) having a screw diameter of 90 mm and a screw diameter ratio (L / D) of 18. Then, with a temperature of 40 ° C for the screw, 40 ° C for the cylinder, 40 ° C for the head, and 10rpm for the rotation speed of the screw, the tubular with an inner diameter of 5.5mm was extruded. On the one hand, a shaft core having an outer diameter of 0.6 mm is inserted through the insertion port, and is attracted by one side of the insertion port, and the surface of the shaft core is covered with a tubular object. Secondly, the shaft core and the tube are put into a vulcanization tank and heated to bridge the tube. The foaming agent is foamed while bridging to form a foamed rubber layer. The surface of this foamed rubber layer was honed using a grindstone in a usual manner to obtain the rubber roller of Example 1. [Example 2] The suction is not performed through the insertion port, and other implementation conditions are the same as those of Example 1 to obtain a rubber roller of Example 2. [Example 3] The same rubber composition as in Example 1 was extruded using a general extruder to obtain a tubular object having an inner diameter of 5.5 mm. While paying attention to the situation where the tubular object was not deformed, it was forcibly pushed in as in Example 1. The same shaft core (outer diameter 15 (please read the precautions on the back before filling in this page) Order · ·; Line-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 555638 7363pif.doc / 008 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention 0.6mm). Ethanol was used as the lubricant during forced pressing, and the tube was bridged in the same manner as in Example 1 to form a foamed rubber layer. This foamed rubber layer was honed in the same manner as in Example 1 to obtain a foamed rubber layer of Example 3. [Comparative Example] The same rubber composition as in Example 1 was extruded with a general extruder to obtain a tubular body having an inner diameter of 5.5 mm, and this tubular body was inserted into a dummy core having an outer diameter of 2.0 mm, and was hung in a sulfurization tank Bridging was carried out to obtain a cylindrical body composed of a foamed rubber layer. This cylindrical body was forced into the same shaft core (outer diameter 0.6 mm) as in Example 1. Ethanol is used as the lubricant when forcibly pressing. This foamed rubber layer was honed in the same manner as in Example 1 to obtain a foamed rubber layer of a comparative example. [Evaluation of Surface Smoothness] The rubber roller was placed on a flat surface. Then illuminate the light in a direction perpendicular to the axis direction, and visually observe the light exposed between the rubber roller and the platform. Those who have not exposed the light at all are indicated by "◎", those who have hardly exposed the light are indicated by "0", those who have exposed a lot of light are indicated by "X". The results are shown in Table 1 below. [Evaluation of Workability] The workability was evaluated during honing. The adhesion (adhesion force) of the shaft core and the foamed rubber layer is quite high, and those with high reliability during mass production are marked with "◎". 16 This paper size is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm). L Pack --- (Please read the precautions on the back before filling this page) Order ·
555638 A7 Β7 7363pif.doc/008 五、發明說明(丨)〇 表示,密著性高且在硏磨時幾乎不會產生問題者以「〇」 表示。此結果表示如下記的表1。 [製造成本] 製造成本方面相當有利者以「◎」表示,略微有利者 以「△」表示,有必要改善者以「X」表示。此評價表示 如下記的表1。 表1555638 A7 Β7 7363pif.doc / 008 5. The invention description (丨) 〇 indicates that those with high adhesion and hardly causing problems during honing are indicated by “〇”. The results are shown in Table 1 below. [Manufacturing costs] Those who are quite favorable in terms of manufacturing costs are indicated by "◎", those that are slightly favorable are indicated by "△", those who need improvement are indicated by "X". This evaluation is shown in Table 1 below. Table 1
實施例1 實施例2 實施例3 比較例 押出機 橫頭押出機 橫頭押出機 通常押出機 通常押出機 被覆方法 架橋前 架橋前 架橋前 架橋後 押出被覆 押出被覆 強制壓入 強制壓入 押出時的吸引 有 Μ — 一 表面平滑性 ◎ ◎ 〇 〇 加工性 ◎ 〇 〇 〇 製造成本 ◎ ◎ 〇 X 由表1各實施例的橡膠滾輪與比較例的橡膠滾輪相 比,能夠了解總合評價較爲優良。依此評價的結果,更能 確認了本發明的優越性。 如上述所說明的,本發明之橡膠滾輪的軸芯與發泡橡 17 --------f--- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製Example 1 Example 2 Example 3 Comparative Example Extruder Crosshead Extruder Crosshead Extruder Normal Extruder Usually Extruder Covering Method Crossing Front Bridge Front Front Bridge Front Crossing Bridge Front Extrusion Covering Extrusion Covering Forced Pressing Forced Pressing Attracted by M — surface smoothness ◎ 〇〇 workability ◎ 〇〇 manufacturing cost ◎ ◎ XX From the rubber roller of each example in Table 1 and the rubber roller of the comparative example, it can be understood that the overall evaluation is better . As a result of this evaluation, the superiority of the present invention was confirmed. As explained above, the shaft and foam rubber of the rubber roller of the present invention 17 -------- f --- (Please read the precautions on the back before filling this page) Staff of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Consumer Cooperatives
本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 555638 7363pif.doc/008 五、發明說明((ί ) 膠層的接著力高 均一性優良。 A7 B7 並且,此橡膠滾輪的外徑以及電阻値的 ^1 ^1 ϋ — ·1 i^· —ϋ (請先閱讀背面之注意事項再填寫本頁) 訂· 線· 經濟部智慧財產局員工消費合作社印製 8 11 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 555638 7363pif.doc / 008 V. Description of the invention (()) The adhesive force of the adhesive layer is high and uniform. A7 B7 And, this rubber roller ^ 1 ^ 1 値 — · 1 i ^ · —ϋ (Please read the precautions on the back before filling out this page) Order · Thread · Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 8 11 copies Paper size applies to China National Standard (CNS) A4 (210 X 297 mm)
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2000126991A JP2001310362A (en) | 2000-04-27 | 2000-04-27 | Method for manufacturing rubber roller, and rubber roller |
Publications (1)
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TW555638B true TW555638B (en) | 2003-10-01 |
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Family Applications (1)
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TW090107943A TW555638B (en) | 2000-04-27 | 2001-04-03 | Rubber roll and making method thereof |
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JP (1) | JP2001310362A (en) |
CN (1) | CN1320516A (en) |
HK (1) | HK1040667A1 (en) |
TW (1) | TW555638B (en) |
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JP4731914B2 (en) * | 2004-01-13 | 2011-07-27 | キヤノン株式会社 | Conductive roller manufacturing method and conductive roller manufacturing apparatus |
JP4908782B2 (en) * | 2005-06-10 | 2012-04-04 | ヤマウチ株式会社 | Method for producing elastic-coated roller |
JP5777546B2 (en) * | 2012-03-14 | 2015-09-09 | サンコール株式会社 | Manufacturing method of stepped paper discharge roller |
JP5893195B2 (en) * | 2015-05-22 | 2016-03-23 | サンコール株式会社 | Manufacturing method of stepped paper discharge roller |
CN111805865B (en) * | 2020-09-02 | 2021-01-01 | 临朐瑞星塑胶制品有限公司 | Flame-retardant adhesive tape forming die |
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2000
- 2000-04-27 JP JP2000126991A patent/JP2001310362A/en active Pending
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2001
- 2001-04-03 TW TW090107943A patent/TW555638B/en active
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CN1320516A (en) | 2001-11-07 |
HK1040667A1 (en) | 2002-06-21 |
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