TW550866B - Self-aligned process method of ridge shape waveguide semiconductor laser - Google Patents

Self-aligned process method of ridge shape waveguide semiconductor laser Download PDF

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TW550866B
TW550866B TW91105970A TW91105970A TW550866B TW 550866 B TW550866 B TW 550866B TW 91105970 A TW91105970 A TW 91105970A TW 91105970 A TW91105970 A TW 91105970A TW 550866 B TW550866 B TW 550866B
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Taiwan
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layer
ridge
semiconductor
self
dielectric
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TW91105970A
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Chinese (zh)
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Chung-Lung He
Jia-Ru Lin
Wen-Jang He
Jr-Wang Liau
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Chunghwa Telecom Co Ltd
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Abstract

A kind of self-aligned process method of ridge shape waveguide semiconductor laser is disclosed, which uses dielectric planarization to achieve the purpose of self-aligned process. A dielectric layer with sufficient thickness is deposited onto the semiconductor wafer surface with ridge shape waveguide structure formed thereon, in which the derived ridge shape dielectric layer surface forms a flat surface after a self-stopped dielectric polishing. The top portion of the semiconductor ridge structure is then exposed by using global etch-back process to etch the dielectric flat surface.

Description

550866550866

【技術領域】 本發明係關於-種脊狀波導半導體雷射之自我 狀波導半導體雷射 【先前技術】 請參閱圖-a及圖-b所示,此為兩種習知脊狀波導半導體雷 射的結構。兩者之蟲晶結構皆包含-半導體基板順㈣型半^ 體基板)、第一半導體波導(waveguide)層1〇1、第一半導體侷限 (confinement)層 102、一半導體主動(active)層區 1〇3、第二半 10導體侷限層104、第二半導體波導層1〇5、以及一半導體歐姆接觸 (ohmic contact)層106 ;而兩者之元件結構則皆包含一介電質純 化層107a(passivation)或107b、—P型金屬電極⑽滅⑺此、以 及一N型金屬電極109。 兩種元件結構皆始於利用標準曝光顯影(phot〇1 i th〇graphy) 15製程於晶圓上定義光阻圖案,經由蝕刻製程,如活性離子I虫刻 (reactive ion etching,RIE),形成如圖式之雙槽(doubletrench) 結構 110 。 接著沈積介電質層 i〇7a 或 i〇7b 於整個晶圓表面 經 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 作為半導體表面鈍化之用。於脊頂(ridge top)開出一接觸窗 (contact window),暴露出歐姆接觸層後,鍍上p型金屬電極 20 l〇8a或108b使之與歐姆接觸層1〇6接觸。最後再於經研磨拋光 (lapping and polishing)後之晶圓背面鍍以N型金屬電極109。 為降低雷射工作的閥值電流(thresho 1 d current)且為使雷 射輸出維持單橫向模(single transverse mode),一般脊寬W約 選擇在2微米左右。欲在如此窄的脊頂上開出一接觸窗暴露出歐[Technical Field] The present invention relates to a self-guided waveguide semiconductor laser of a kind of ridge waveguide semiconductor laser. [Prior art] Please refer to FIGS. -A and -b, which are two conventional ridge waveguide semiconductor lasers. Shot structure. The worm crystal structure of both includes a semiconductor substrate (semi-type semiconductor substrate), a first semiconductor waveguide layer 101, a first semiconductor confinement layer 102, and a semiconductor active layer region. 103, the second semi-conductor confinement layer 104, the second semiconductor waveguide layer 105, and a semiconductor ohmic contact layer 106; and the element structure of both includes a dielectric purification layer 107a (passivation) or 107b, the P-type metal electrode is eliminated, and an N-type metal electrode 109. Both types of element structures begin with the use of standard exposure development (phot〇1 ithography) 15 processes to define photoresist patterns on wafers, and through etching processes such as reactive ion etching (RIE) to form Doubletrench structure 110 as shown in the figure. A dielectric layer i07a or i07b is then deposited on the entire wafer surface and printed by the Consumer Affairs Agency of the Intellectual Property Office of the Ministry of Economic Affairs for passivation of semiconductor surfaces. A contact window is opened at the ridge top, and after the ohmic contact layer is exposed, a p-type metal electrode 20 108a or 108b is plated to contact the ohmic contact layer 106. Finally, the back surface of the wafer after lapping and polishing is plated with an N-type metal electrode 109. In order to reduce the threshold current (thresho 1 d current) of laser operation and to maintain the laser output in a single transverse mode, the ridge width W is generally selected to be about 2 microns. To open a contact window on the top of such a narrow ridge exposes Europe

550866 A7550866 A7

550866 A7 B7 經 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 移除此光阻遮罩使得脊頂歐姆接觸層顯露出來,此時晶圓上其他 表面仍覆於介電質層下。因歐姆接觸層的曝露不需光罩對準與曝 光顯影製程,故謂此方式為「自我對準」。雖然這類方法可達到 製私簡化與歐姆接觸層最大利用等目的,保留光阻遮罩使得介電 5質的沈積必須在較低溫下(〜1〇〇。〇進行,介電質層的品質因此受 到影響;此外,為使光阻遮罩於介電質層沈積完後易於移除,半 導體脊須具有-適當之TK(undemjt)剖面形狀,此加深了製程 的複雜程度。 第二種,如 U.s· Pat· No· 5,208,183、U.S· Pat· No· 10 5,474,954、U.S. Pat. Να 5,658,823、及 U.S· Pat. No. 6,171,876,利用了光阻或polyimide的平坦化能力。當光阻或 polyimide旋轉塗佈於具脊狀結構之晶圓表面時,其流體性質使 知位於脊頂上的光阻或p〇lyimide厚度遠較其他平面上的厚度來 的薄。藉由全面回蝕製程,如RIE,脊頂可最先被暴露出來,而 其他表面則仍覆於光阻或polyimide之下,整個脊頂因此可用與 金屬電極接觸。使用光阻與Polyimide的差異在於於脊頂暴露出 後polyimide會保留在晶圓表面上,且作為平坦化絕緣介電質 層’ p型金屬與其裝訂墊便直接形成於其上。是以使細lyimide 會是較直接了當的作法。此外,藉由p〇lyimide的平坦化,脊狀 波導半導體雷射亦可採用單脊(single—ridge)結構,如此可避免 雙才曰、、、Ό構所遭遇之金屬披覆問題。然而,即便已經過熱硬化處 理p〇lyimide膜仍保有些許可拉伸的特性,於雷射鏡面劈裂 時,邊緣受到拉伸的polyimide膜可能對雷射輸出面造成干擾, 影響元件特性及均勻性。 五、發明說明(550866 A7 B7 Printed by the Consumer Affairs Agency, Intellectual Property Office of the Ministry of Economic Affairs Remove this photoresist mask to expose the ohmic contact layer at the top of the ridge. At this time, other surfaces on the wafer are still covered by the dielectric layer. Since the exposure of the ohmic contact layer does not require mask alignment and exposure development processes, this method is referred to as "self-alignment". Although this type of method can achieve the purpose of simplifying the manufacturing process and maximizing the use of the ohmic contact layer, the retention of the photoresist mask makes the deposition of the dielectric 5 must be performed at a lower temperature (~ 100.00, the quality of the dielectric layer). Therefore, in order to make the photoresist mask easy to remove after the dielectric layer is deposited, the semiconductor ridge must have a proper TK (undemjt) cross-sectional shape, which deepens the complexity of the process. Second, Such as Us Pat No 5,208,183, US Pat No 10 5,474,954, US Pat. Να 5,658,823, and US Pat No. 6,171,876, which utilize the flattening ability of photoresist or polyimide. When the photoresist or When polyimide is spin-coated on the surface of a wafer with a ridge structure, its fluid properties make it known that the thickness of the photoresist or poliimide on the top of the ridge is much thinner than the thickness on other planes. Through a full etch-back process, such as RIE, the ridge top can be exposed first, while other surfaces are still covered by photoresist or polyimide, so the entire ridge top can be contacted with metal electrodes. The difference between using photoresist and Polyimide is that polyimide is exposed after the ridge top is exposed. Association On the wafer surface, the p-type metal and its binding pad are directly formed thereon as a planarized insulating dielectric layer. Therefore, it is more straightforward to make fine lyimide. In addition, by using polimide The planarization of the ridge waveguide semiconductor laser can also adopt a single-ridge structure, so as to avoid the metal coating problems encountered by dual-cavity structures. However, even if it has been overheat-hardened, p〇 The lyimide film still has some characteristics that allow for stretching. When the laser mirror is split, the polyimide film stretched at the edges may cause interference with the laser output surface, affecting the characteristics and uniformity of the device.

吕丁 15 20 張尺度適用 X 297公釐) 線 A7 550866 五、發明說明( 由此可見,上述習用物品仍有諸多缺失,實非一良善 之設計者,而亟待加以改良。 本案發明人鑑於上述習用脊狀波導半導體雷射之自我 對準式製程方法所衍生的各項缺點,乃亟思加以改良創 新,並經多年苦心孤詣潛心研究後,終於成功研發完成本 件脊狀波導半導體雷射之自我對準式製程方法。 【發明目的】 本發明之目的即在於提供一種脊狀波導半導體雷射之 自我對準式製程方法,係利用一自我終止之氧化層拋磨 (self-terminated oxide polish,往後簡稱ST〇P)技術,於施行 此stop技術前,先沈積一厚氧化層,以Si〇x為例,於整個具有脊 訂 狀結構之晶圓表面,其厚度大於半導體脊之高度;接著即利用 stop技術將所衍生形成具脊列地貌之Si〇x表面抛磨至一平整 表面。此拋磨過程一開始迅速移除極窄(例如窄於1〇微米)脊 15 經 濟 部 智 慧 財 產 局 員 工 消 費 合 社 印 製 20 的咼度,然而當拋磨面到達Si〇x平面時,其移除&如厚度的速率 大為降低,近乎停滯,如此的行駿得整鑛Qx表面最後可達到 相當平整的表面。藉由選擇適當的拋磨條件,其平整度可以決定 於沈積Si〇x的機制而非拋磨的過程。 疋 【技術内容】 可達成上述發明目的之脊狀波導半導體雷射之自我對 準式製程方法’係利用介電質(dlelectncs)平坦化 (planarization)來達到自我對準的製程,此製程沈積一足夠厚 度之介電負層覆蓋於已形成脊狀波導結構之半導體晶圓表面,所 衍生出具脊列地貌之介電質表面經自我終止之介電質拋磨後成一 本紙張尺度適用中國國家標準(CNSM4規了各(21〇 x 297公髮) 550866 Λ7Lu Ding 15 20 scales are applicable to X 297 mm. Line A7 550866 5. Description of the invention (It can be seen that there are still many shortcomings in the above-mentioned conventional articles, which are not a good designer, and need to be improved. In view of the above Various shortcomings derived from the self-aligned manufacturing method of the ridge waveguide semiconductor laser are eager to improve and innovate. After years of painstaking and meticulous research, finally successfully developed the self-alignment of this ridge waveguide semiconductor laser. [Objective of the invention] The purpose of the present invention is to provide a self-aligned manufacturing method of a ridge waveguide semiconductor laser, which uses a self-terminated oxide polish, and thereafter For short (ST0P) technology, before implementing this stop technology, a thick oxide layer is deposited. Taking Si0x as an example, the thickness of the entire wafer surface with a ridge-like structure is greater than the height of the semiconductor ridge. The stop technology was used to polish the SiOx surface formed into a ridged landform to a flat surface. This polishing process quickly removed the poles at the beginning. (For example, narrower than 10 microns) Ridge 15 Printed by the Consumer Intellectual Property Association of the Intellectual Property Bureau of the Ministry of Economic Affairs to print 20 degrees. However, when the polished surface reaches the Si0x plane, the rate of its removal & thickness is greatly reduced. It is almost stagnant, so that the XQ surface of the entire ore can reach a fairly flat surface. By selecting the appropriate polishing conditions, the flatness can be determined by the mechanism of SiOx deposition rather than the polishing process. 疋[Technical content] The self-aligned process method of the ridge waveguide semiconductor laser that can achieve the above-mentioned object of the invention is to use dielectric planarization to achieve a self-aligned process. The thickness of the dielectric negative layer covers the surface of the semiconductor wafer on which the ridge-shaped waveguide structure has been formed. The dielectric surface with the ridge landform derived from the self-terminating dielectric is polished into a paper with a standard applicable to Chinese national standards ( CNSM4 regulations (21〇x 297 issued) 550866 Λ7

經濟部智慧財產局員工消費合作社印製 五、發明說明(<f) 平坦面;藉由全面回蝕(etch-back)製程蝕刻此—介電質平坦面 可使半導體脊狀結構的頂部均勻暴露出來。 【圖式簡單說明】 請參閱以下有關本發明一較佳實施例之詳細說明及其 5附圖,將可進一步瞭解本發明之技術内容及其目的功效/.、 有關該實施例之附圖為: 圖一A為傳統雙槽結構脊狀波導半導體雷射之剖面圖; 圖- B為利用習知自我對準技術製作之雙槽結構货 導體雷射之剖面圖; 10 圖二A〜N為利用該脊狀波導半導體雷射之自我對 製程方法之第一實施例元件剖面圖; 、> / 圖三A〜P為利用該脊狀波導半導體雷射之自我對準 製程方法之第二實施例元件剖面圖; ,工 圖四為於貫施自我終止氧化層拋磨技術過程中,&〇表面 15 地貌之變化情形的示意圖。 【主要部分代表符號】 100半導體基板 101第一半導體波導層 102第一半導體侷限層 103半導體主動層區 104第二半導體侷限層 105第二半導體波導層 106半導體歐姆接觸層 107a介電質鈍化層 297公釐) 請 先 閱 讀 背 之 注 意 事 項 再 填Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (&f; flat surface); this is etched by a full etch-back process-the dielectric flat surface can make the top of the semiconductor ridge structure uniform. Exposed. [Brief description of the drawings] Please refer to the following detailed description of a preferred embodiment of the present invention and its 5 drawings, which will further understand the technical content of the present invention and its purpose / effects. The drawings related to this embodiment are: : Figure 1A is a cross-sectional view of a conventional double-slot structure ridge waveguide semiconductor laser; Figure-B is a cross-sectional view of a double-slot structure cargo conductor laser manufactured using a conventional self-alignment technique; 10 Figures 2A ~ N are A cross-sectional view of a first embodiment of the self-alignment process method using the ridge waveguide semiconductor laser; > / Fig. 3 A to P are the second implementation of the self-alignment process method using the ridge waveguide semiconductor laser Example component cross-section; Figure 4 is a schematic diagram of the change in the topography of surface 15 during the process of self-stopping oxide layer polishing. [Representative symbols of main parts] 100 semiconductor substrate 101 first semiconductor waveguide layer 102 first semiconductor confinement layer 103 semiconductor active layer region 104 second semiconductor confinement layer 105 second semiconductor waveguide layer 106 semiconductor ohmic contact layer 107a dielectric passivation layer 297 Mm) Please read the notes before filling in

訂 線 經濟部智慧財產局員工消費合作社印製 550866 A7 B7 PAU1U4JU.UUU - 0/^1 五、發明說明(j^7 ) 107b介電質鈍化層 108a P型金屬電極 108b P型金屬電極 109 N型金屬電極 110雙槽結構 200填化銦基板 201 N型InP波導層 202 N型砷化鋁銦侷限層 203含多重量子井之活性區 204砷化铭銦侷限層 205 P型InP波導層 206高摻雜P型砷化銦鎵接觸層 206a高摻雜P型InO.53GaO.47As接觸層頂部 207 SiNx層 207a SiNx層 208光阻遮罩 209 SiOx鈍化層 210 SiOx層 210b SiOx 210a SiOx平面 210b SiOx 211光阻 212a金屬 212b金屬 本紙張尺度適用中國國家標準(CNS)A4規格(210 χ 297公爱) 14 1— J— I I J I I I I — — — — — — — ·11111111 I 一 (請先閱讀背面之注意事項再填寫本頁) 550866 Λ7 B7Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 550866 A7 B7 PAU1U4JU.UUU-0 / ^ 1 V. Description of the invention (j ^ 7) 107b Dielectric passivation layer 108a P-type metal electrode 108b P-type metal electrode 109 N Type metal electrode 110 double slot structure 200 filled with indium substrate 201 N-type InP waveguide layer 202 N-type aluminum indium arsenide confinement layer 203 active region containing multiple quantum wells 204 indium arsenide indium confinement layer 205 P-type InP waveguide layer 206 high Doped P-type indium gallium arsenide contact layer 206a Highly doped P-type InO.53GaO.47As contact layer top 207 SiNx layer 207a SiNx layer 208 photoresist mask 209 SiOx passivation layer 210 SiOx layer 210b SiOx 210a SiOx plane 210b SiOx 211 Photoresist 212a metal 212b metal This paper scale is applicable to Chinese National Standard (CNS) A4 specifications (210 x 297 public love) 14 1— J— IIJIIII — — — — — — — 11111111 I I (Please read the precautions on the back first (Fill in this page again) 550866 Λ7 B7

kauiu4^u.uuo - y/^ I 五、發明說明(1) 213金屬電極 300基板 301 N型InP波導層 302 N型 In0.52A10.48As侷限層 303含多重量子井之活性區 304 In0.52A10.48As侷限層 305 P型InP波導層 305a InP層 306高摻雜P型InO.53GaO.47As接觸層 306a I nO.53GaO.47As層 307 SiNx層 307a SiNx層 308光阻 309 SiOx鈍化層 310 SiOx層 310a SiOx平面 310b SiOx 經濟部智慧財產局員工消費合作社印製 311光阻 312a金屬 312b金屬 313金屬電極 400晶圓 401區域範圍 402 Si Ox平面 -9- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公餐) 550866 A7 五、發明說明(< ;-1U/^1 403脊 403a Si Οχ脊列 【較佳實施例】 本發明所提供之脊狀波導半導體雷射之自我對準式製 程方法,可供製作脊狀波導半導體雷射之用,更明確言之,此 自我對準類之製程技術利用了 一種所謂自我終止之氧化層拋磨技 術(STOP) ’精以對具脊列地貌之氧化層表面作平坦化。以下說明 以電漿增盈化學氣相沈積(plasma—enhanced chemicai vap〇r deposition,PECVD)所沈積之SiOx為例。 此製程藉由PECVD先全面沈積一足夠厚度之si〇x層於已蝕刻 出半導體脊狀結構之晶圓表面。為使經拋磨後可得到一平坦且全 然為SiOx層之表面,所沈積si〇x層其厚度須大於半導體脊高。由 於PECVD等型性沈積(conformai deposition)的性質,原先具脊 列地貌之半導體表面往上延伸成具脊列地貌之Si〇x表面。藉由拋 磨製私,具脊列地貌之Si〇x表面終可成一平坦面。為避免造成不 均勻之SiOx表面(如傾斜面)或過度拋磨,應用一般拋磨設備於此 15 技術之關鍵在於調整適當壓力施加於拋磨面,使得於拋磨的 過紅中,相當窄的Si〇x,(例如窄於1〇微米)其高度下降迅速;然 而當拋磨觸及較大且平坦之Si〇x表面(例如寬於3〇〇微米)時,拋 磨移除Si0x厚度的行為近乎停滯。如此因面積差異造成迥異之拋 磨行為即可形成一相當平坦之Si〇x表面,·且於此平坦面形成同 時,拋磨Si0x厚度的行為已幾乎停滯,如同自我終止般,這正是 此技術命名為自我終止之氧化層拋磨的原因。接下來的全面回蝕 Si0x製程便得以均勻暴露出半導體脊頂。此Si〇x全面回钱製程可 本紙張尺度適用中國國家標 10 訂 線 20kauiu4 ^ u.uuo-y / ^ I V. Description of the invention (1) 213 metal electrode 300 substrate 301 N-type InP waveguide layer 302 N-type In0.52A10.48As confined layer 303 active region with multiple quantum wells 304 In0.52A10 .48As confinement layer 305 P-type InP waveguide layer 305a InP layer 306 Highly doped P-type InO.53GaO.47As contact layer 306a I nO.53GaO.47As layer 307 SiNx layer 307a SiNx layer 308 Photoresistor 309 SiOx passivation layer 310 SiOx layer 310a SiOx plane 310b SiOx Printed by the Consumer Cooperative of the Ministry of Economic Affairs Intellectual Property Bureau 311 Photoresist 312a Metal 312b Metal 313 Metal electrode 400 Wafer 401 Area 402 Si Ox plane -9- This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 meals) 550866 A7 V. Description of the invention (<;-1U / ^ 1 403 ridges 403a Si Οχ spine column [Preferred embodiment] Self-alignment of the ridge waveguide semiconductor laser provided by the present invention Method, which can be used to make ridge waveguide semiconductor lasers. More specifically, this self-aligning process technology uses a so-called self-terminating oxide layer polishing technology (STOP). Planar surface oxide surface flattened The following description takes SiOx deposited by plasma-enhanced chemicai vapor deposition (PECVD) as an example. In this process, a sufficient thickness of SiOx layer is firstly deposited by PECVD on the etched out The surface of the wafer with a semiconductor ridge structure. In order to obtain a flat and completely SiOx layer surface after polishing, the thickness of the deposited SiOx layer must be greater than the height of the semiconductor ridge. Due to conformai deposition such as PECVD ), The original semiconductor surface with ridge landforms extends upwards to form a Si0x surface with ridge landforms. By polishing, the Si0x surface with ridged landforms can eventually become a flat surface. To avoid Causes uneven SiOx surfaces (such as inclined surfaces) or excessive polishing. The key to applying general polishing equipment here is to adjust the appropriate pressure to the polishing surface, so that the Si in the polishing is too narrow. 〇x, (for example, narrower than 10 microns), its height decreases rapidly; however, when the polishing touches a larger and flat SiOx surface (for example, wider than 300 microns), the behavior of removing the thickness of Si0x by polishing is almost Stagnation. In this way, the very different polishing behavior caused by the area difference can form a fairly flat Si0x surface. At the same time when the flat surface is formed, the polishing behavior of Si0x thickness has almost stagnated, as it is self-termination. The technology is named for the reason for self-terminating oxide layer polishing. The subsequent full etch-back Si0x process can uniformly expose the semiconductor ridges. This Si0x full cashback process is available. The paper size is applicable to the Chinese national standard 10

550866 五 、發明說明(夕 藉由RIE付到-相當平坦之晶圓表面,同樣水平之卿層環繞於 暴露出之半導體_四周。町兩健佳實補詳細說明利 用此自我對準式製程進行脊狀波導半導體雷射的製作。 圖-A至圖二_示在第一較佳實施例中,各個製程步驟中半 5導體雷射元件之剖面示意圖。圖二靖示為成長於N型之碟化鋼 (InP)基板200之元件蠢晶結構,其包含(由下至上):一频祕波 導層201、-N型石申化細(In〇 52A1〇 48As)偈限層2〇2、含多重 畺子井(multiple quantum wells,MQWs)之活性區203、一砷化 鋁銦(In〇.52Al〇.48AS)侷限層204、一 1.5-微米厚之P型InP波導 10層205、及-0.2微米厚之高摻雜P型石申化銦鎵(In〇 53Ga〇.47As) 接觸層206。元件製程始於利用PECVDK25〇t下沈積一2〇〇〇—又之 SiNx層207於晶圓表面,如圖所示。藉由光罩對準與曝光顯影 製私於3丨^層上定義出2微米寬之光阻遮罩2〇8圖案,如圖二c所 示,作為接下來侧製程的遮罩。藉由RIE使用CF4氣體钱刻掉未 叉光阻保護之SiNx層,如圖二D所示。於移除光阻遮罩208後,此 時π件結構如圖二E所示,且原先2微米寬之光阻圖案已轉移至 Si%層207a。晶圓經過表面清洗及去氧化層後置入RiE製程腔 (process chamber),利用已定義之SiN}^作為蝕刻遮罩,以及 使用1 CH4: 5 H2的氣體組成,將未受SiNx保護之半導體層蝕刻 至約1· 6〜1.7微米的深度,形成半導體脊狀結構,如圖二?所示。 移除的半導體層包括全部厚度的In〇· 53Ga〇· 47As歐姆接觸層206 以及部分厚度之P型InP波導層205。為得到一適當之蝕刻地貌(亦 即近乎垂直的半導體脊及鏡面般的晶圓表面),於姓刻半導體脊 過程中必須穿插利用〇2及Ar之混和氣體移除蝕刻過程中產生之聚550866 V. Description of the Invention (Paid by RIE-a fairly flat wafer surface, the same level of green layer surrounds the exposed semiconductor _ all around. Really detailed description of the use of this self-aligned process Fabrication of a ridge waveguide semiconductor laser. Figures -A to II_ show the cross-sectional schematic diagrams of the semi-conductor laser element in each process step in the first preferred embodiment. Figure II shows the growth of the N-type The element stupid structure of the dished steel (InP) substrate 200 includes (from bottom to top): a frequency secret waveguide layer 201, a -N-type Shishenhua fine (In〇52A1048As) confinement layer 202, Contains multiple quantum wells (MQWs) active region 203, an indium aluminum arsenide (In.52Al.48AS) confinement layer 204, a 1.5-micron thick P-type InP waveguide 10 layer 205, and -0.2 micron thick doped P-type indium gallium (In〇53Ga〇.47As) contact layer 206. The device process begins by depositing a 2000-SiNx layer 207 on the crystal using PECVDK2500t A round surface, as shown in the figure. A 2 micron wide photoresist mask is defined on the 3 ^ layer by mask alignment and exposure development. The mask 208 pattern, as shown in Figure 2c, is used as a mask for the next side process. The CFN gas is used by RIE to etch the SiNx layer protected by the uncrossed photoresist, as shown in Figure 2D. After the photoresist mask 208, the π structure is shown in Figure 2E, and the original 2-micron-wide photoresist pattern has been transferred to the Si% layer 207a. After the wafer is cleaned and deoxidized, it is placed in the RiE process. Process chamber, using the defined SiN} ^ as an etching mask, and using a gas composition of 1 CH4: 5 H2, the semiconductor layer not protected by SiNx is etched to a depth of about 1.6 to 1.7 microns to form A semiconductor ridge structure, as shown in Figure 2 ?. The removed semiconductor layer includes the entire thickness of In53.GaAs 47As ohmic contact layer 206 and a portion of the thickness of the P-type InP waveguide layer 205. In order to obtain a suitable etching topography (That is, nearly vertical semiconductor ridges and mirror-like wafer surfaces), in the process of engraving semiconductor ridges, it must be interspersed with a gas mixture of 0 2 and Ar to remove the polymer generated during the etching process.

訂 15 20 本紙張尺度_ (CNS)A4祕⑵ 線 11 - ίο 15 550866 五、發明說明 合物或含碳生成物。蝕刻出半導體脊狀結構後,經過晶圓表面清 洗及去氧化層步驟,利用PECVD於250°C下全面沈積一3000-A之 Si〇x純化層209於晶圓表面上,如圖二g所示。 至此階段,元件製程皆經由習知的半導體製程步驟。而以下 5所述利用STOP技術達成自我對準型製程則為此發明之精髓。 經過表面成長SiOx鈍化處理後,晶圓置入另一PECVD製程 腔,於35(TC下以每分鐘2750又快速沈積3微米厚之SiOx層210, 如圖二Η所示。此厚SiOx層全面覆蓋了晶圓表面,其下的半導體 脊列造成SiOx表面亦形成脊列地貌。藉由一般具負載調整(如〇至 1.5公斤)之拋磨設備,調整適當負載施加於拋磨面(施加之負載 與拋磨面積有關,於本實施例中施加之壓力約為每平方公分〇. 1 公斤)’原先具脊列地貌之Si〇x表面可以拋磨至如圖二I之“(^平 面210a。現今超大型積體電路(VLSI)製程中的平坦化製程需要相 當精準之的拋磨設備,如化學機械式拋磨 polish,CMP)設備,但在應用此發明中所需之設備則可為一般用 以晶圓背面研磨拋光之設備。藉由施加適度壓力於拋磨面,極窄 之SiOx脊列其高度可以迅速的拋磨移除,然而較大之&〇χ平面則 幾乎不受拋磨影響。在所有的SiOx脊同時或依序平坦化後,廣大 的SiOx平面使得拋磨SiOx厚度的動作近乎停滯,如同自我終止 20般’因此可獲致如圖二1之Si〇x平面。接著以謂採用⑽氣體全 面回姓SiOx平面直到半導體脊頂之In〇.53Ga〇47As歐姆接觸層均 勻暴露出來。由於於本實施例之蝕刻條件下,蝕刻Si〇x的速率 (約每分鐘300又)較蝕刻SiNx(約每分鐘1〇〇〇又)慢,所暴露出高 摻雜P型In〇· 53Ga〇· 47As接觸層頂部206a會較周遭之約 ______-12- 本紙張尺度_; _鮮(CNS)A4祕⑵G χ观公爱「 . i ~ -----------------^ I _ (請先閱讀背面之注意事項再填寫本頁) A7 550866 五、發明說明(、\ ) 懷一‘ 低1000又,如圖二J所示。如此的結構可使脊頂完全利用於與金 屬電極作歐姆接觸,同時提供較大的過度蝕刻容忍度。 接下來的製程亦屬於習知之半導體製程,與本發明無直接關 係然而,利用刖述stop拋磨技術與全面回钱製程所形成之平面 5結構卻有助於以下製程的進行,並可提高製程良率。 於半導體脊頂之1n〇.53Ga〇.47As歐姆接觸層均勻暴露出來之 後,利用光罩對準與曝光顯影製程定義出p型金屬區,如圖二K所 示。必須注意的是為有助於金屬掀離製程(lift—〇ff pr〇cess), 光阻211必須具一近似反梯狀(inverse—tapered)之剖面。接著 10 5〇〇a的鈦(Ti)、500又的鉑(pt)、及4〇〇〇又的金(Au)依序鍍 上曰日圓表面,如圖二L所示。利用丙酮(acet〇ne)溶解光阻211圖 案進而移除其上附著之金屬2i2b,達成金屬掀離的目的,所餘留 之金屬212a與暴露出之in〇 53Ga〇 47As層接觸,作為p型金屬電 經濟部智慧財產局員工消費合作社印製 極’如圖二Μ所示。值得強調的是利用ST〇p拋磨技術與全面回蝕 15製程所形成之平面結構對於上述之P型金屬製程而言最為理想; 反之,傳統之非平面雙槽結構則易造成金屬披覆上的問題,同時 亦不利於金屬掀離。經過在42(TC、氮氣環境下對晶圓上之p型金 屬作20秒之快速熱退火(rapid仕iermai anneaHng,rta)之後, 將晶圓自背面研磨及拋光至約剩1〇〇微米之晶圓厚度(2〇〇a),並 20依序洛鑛丨000又之金鍺(Ge)鎳(Ni)合金(84%Au、12%Ge、4%Ni)及 4000a之金於其上作為N型金屬電極213,如圖二N所示。再於39() °C下對此N型金屬電極進行2〇秒之RTA。兩次對金屬電極之RTA用 意皆在於降低歐姆接觸電阻。 圖三A至圖三p顯示在第二較佳實施例中,各個製程步驟中半Order 15 20 This paper size_ (CNS) A4 secret line 11-ίο 15 550866 V. Description of the invention Compounds or carbon-containing products. After the semiconductor ridge structure is etched, after the wafer surface cleaning and deoxidation steps, a 3000-A SiOX purification layer 209 is fully deposited on the wafer surface at 250 ° C using PECVD, as shown in Figure 2g. Show. At this stage, the device manufacturing process has all gone through the conventional semiconductor process steps. The self-aligned process using STOP technology described in the following 5 is the essence of this invention. After the surface-growth SiOx passivation treatment, the wafer is placed in another PECVD process chamber, and a 3 micron-thick SiOx layer 210 is quickly deposited at 35 ° C at 2750 per minute, as shown in Figure 2 (b). This thick SiOx layer is comprehensive Covering the wafer surface, the semiconductor ridges underneath cause the SiOx surface to also form a ridge landform. With a general polishing equipment with a load adjustment (such as 0 to 1.5 kg), adjust the appropriate load to the polishing surface (apply the The load is related to the polishing area. The pressure applied in this embodiment is about 0.1 kg per square centimeter.) The original Si0x surface with ridged landforms can be polished to "(^ Plane 210a) The current planarization process in very large scale integrated circuit (VLSI) processes requires quite accurate polishing equipment, such as chemical mechanical polishing (CMP) equipment, but the equipment required in the application of this invention can be Generally used for polishing and polishing the back of wafers. By applying moderate pressure to the polishing surface, the extremely narrow SiOx ridges can be quickly polished and removed, but the larger & 〇χ plane is almost unaffected. Polishing effect. On all SiOx ridges After being flattened in time or sequentially, the broad SiOx plane makes the action of polishing the thickness of SiOx almost stagnant, as if self-terminating 20 '. Therefore, the SiOx plane shown in Figure 2 can be obtained. The SiOx plane up to the semiconductor ridge top of the In0.53Ga〇47As ohmic contact layer is uniformly exposed. Because the etching conditions of this embodiment, the rate of etching SiOx (about 300 again per minute) is higher than that of SiNx (about every minute). 〇〇〇〇) Slow, the exposure of the highly doped P-type In〇. 53Ga〇 47As contact layer top 206a will be about ______- 12- paper size _; _ fresh (CNS) A4 secret G χ 观 公 爱 「. i ~ ----------------- ^ I _ (Please read the notes on the back before filling this page) A7 550866 V. Description of the invention (, \ ) Huaiyi's low 1000, as shown in Figure II J. Such a structure allows the ridge top to be fully used for ohmic contact with metal electrodes, while providing greater tolerance for excessive etching. The next process is also known The semiconductor process is not directly related to the present invention. However, the use of the described stop polishing technology and the full cash back process The planar 5 structure formed is helpful for the following processes and can improve the process yield. After the 1n0.53Ga.47As ohmic contact layer of the semiconductor ridge top is uniformly exposed, the mask alignment and exposure development are used. The process defines a p-type metal region, as shown in Figure 2K. It must be noted that in order to facilitate the lift-off process of the metal (lift-〇ff pr〇cess), the photoresist 211 must have an approximately inverse-ladder shape (inverse- tapered) section. Then 1500a of titanium (Ti), 500% of platinum (pt), and 4,000% of gold (Au) are sequentially plated on the surface of the Japanese yen, as shown in Figure 2L. . Use acetone to dissolve the photoresist 211 pattern and remove the metal 2i2b attached to it to achieve the purpose of metal lift-off. The remaining metal 212a is in contact with the exposed in〇53Ga〇47As layer as a p-type The printed poles of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Metals and Electricity Economy are shown in Figure 2M. It is worth emphasizing that the planar structure formed by STOP polishing technology and comprehensive etch-back 15 process is the most ideal for the P-type metal process described above; on the contrary, the traditional non-planar double-groove structure is easy to cause metal coating The problem is also not conducive to metal lift-off. After rapid thermal annealing (rapid iermai annea Hng, rta) of the p-type metal on the wafer under 42 (TC, nitrogen environment for 20 seconds), the wafer was ground and polished from the back to about 100 microns Wafer thickness (200a), and 20 in sequence Luo gold 丨 000 gold germanium (Ge) nickel (Ni) alloy (84% Au, 12% Ge, 4% Ni) and 4000a gold on it As the N-type metal electrode 213, as shown in FIG. 2N, the N-type metal electrode was subjected to RTA for 20 seconds at 39 () ° C. The RTA of the metal electrode was intended to reduce the ohmic contact resistance twice. FIG. 3A to FIG. 3P show the half of each process step in the second preferred embodiment.

550866 A7550866 A7

550866 A7 五 、發明說明(I7 移至SiNx層307a。晶圓經過表面清洗及去氧化層後,利用已定義 之SiNx層料侧鮮,進行濕絲聰程㈣解導體脊。首 先利用混和均勻之1 H_ ·· 1 _2 : 2G _溶液移除未受 S:lNx保護之高摻雜p型In(U3G晚伽接觸層,其制速率約為 每分鐘0.25微米,同時對InP層具有高選擇性。近乎等向性 (is〇tr〇pic)之蝕刻造成此In〇 53Ga〇 47As層施無可避免地 有些許下切產生,如圖三_示。以i HF : 1〇 H2〇移除叫遮罩 後’ In〇.53Ga〇.47As層306a(圖三〇現為接下來钱刻p型Inp波導 層之_遮罩。InP的侧是利用混和均勾之1 ΗΠ ·· 3咖以 溶液作為侧劑,其姓刻InP的速率高達每分鐘〇 6微米,同時對 In〇.53Ga(U7AS層具有高選擇性。於Inp波導層則後,元件結 構剖面如同圖却所示,InP層305a呈現一些許倒梯狀之剖面,此 與料體脊走向有關,祕此實施财,轉體脊走向為平行於 晶圓之次平面(minor flat)。此倒梯狀之剖面,加上半導體層的 下切,形成此半導體脊具有較寬之脊頂,同時保有較窄之脊底以 疋義電流注入之活性區,於此實施例中約為2微米寬。於半導體 脊蝕刻完成後,於250t下全面沈積一3000又之Si〇x鈍化層3〇9於 晶圓表面上,如圖三I所示。 至此階段,元件製程皆經由習知的半導體製程步驟。而以下 即利用STOP技術,配合全面回餘製程,達成自我對準型製程。 經過表面成長SiOx鈍化處理後,晶圓置入另一pECVD製程 腔,於350°C下以每分鐘2750又快速沈積3微米厚之3丨(^層31〇,如 圖二J所示。此厚3丨〇)(層全面覆蓋了晶圓表面,其下的半導體脊 列造成SiOx表面亦形成脊列地貌。藉由一般之拋磨設備,如前實 I_—__- 15- 本紙張尺度顧中研家標準(CNS)A4則297公釐) 5 10 15 20 550S66 A7 五、發明說明( 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 施例中所述,原先具脊列地貌之Si0x表面可以抛磨至如圖^之 SiOx平面310a。接著以RIE採用CF4氣體全面回蝕Si〇x平面直到 半導體脊頂之In〇. 53Ga〇. 47As歐姆接觸層均勻暴露出來。為進一 步增加將來金屬電極可接觸面積,整個111〇.5_.4細欠姆接觸 層306a,包括其側邊,均被暴露出來,如圖三匕所示。因此,相 反於先前之實施例,脊頂之接觸層會高於周遭環繞之Si〇x31〇b。 接下來的製程亦屬於習知之半導體製程,與本發明無直接關 係。然而,如前實施例般,利用本發明所造成之平面結構卻有助 於往後製程的進行。 於半導體脊頂之In〇· 53Ga〇· 47As歐姆接觸層均勻暴露出來之 後,利用光罩對準與曝光顯影製程定義出p型金屬區,如圖三Μ所 示。光阻311近似反梯狀(inverse—之剖面可有助於金屬 掀離製程。接著50〇X的鈦(Ti)、500又的鉑(Pt)、及4〇〇〇又的金 (Au)依序艘上晶圓表面,如圖三n所示。利用丙酮溶解光阻圖案 15 311進而移除其上附著之金屬312b,完成金屬掀離,所餘留之金 屬312a與暴露出之In〇.53Ga〇e47As層接觸,作為p型金屬電極, 如圖三0所示。經過在420。(:、氮氣環境下對此p型金屬電極作2〇 秒之快速熱退火(rapid thermal annealing,RTA)之後,將晶 圓自背面研磨及拋光至約剩1〇〇微米之晶圓厚度(300a),並依序 蒸鍍1000又之金鍺(Ge)鎳(Ni)合金及4000又之金於其上,作為n型 金屬電極313,如圖三P所示。再於390°C下對此N型金屬電極進行 20秒之RTA。 於上述二實施例中,皆使用STOP拋磨技術對具脊列地貌之 SiOx表面進行平坦化。圖四所示為實施ST0P拋磨技術過程中义如550866 A7 V. Description of the invention (I7 moved to SiNx layer 307a. After the wafer has been cleaned and deoxidized, the SiNx layer is used to clean the conductor ridges by wet wire decontamination. First, use the mixed uniform 1 H_ ·· 1 _2: 2G _ Solution removes highly doped p-type In (U3G late-gamma contact layer that is not protected by S: lNx, its rate is about 0.25 microns per minute, and it has high selectivity for the InP layer The nearly isotropic (is〇tr〇pic) etching caused this In〇53Ga〇47As layer to inevitably be slightly undercut, as shown in Figure 3_. I HF: 1〇H2〇 to remove the mask Behind the mask 'In.53Ga.47As layer 306a (Figure 30 is now the next mask of the p-type Inp waveguide layer engraved. The side of the InP is the use of mixed uniform 1 之 Π ·· 3 coffee solution The side agent has a rate of InP as high as 0.6 micrometers per minute, and has a high selectivity to the In.53Ga (U7AS layer. After the Inp waveguide layer, the cross-section of the element structure is as shown in the figure, and the InP layer 305a appears Some of the ladder-like cross sections are related to the ridge direction of the material body. The secret is implemented, and the rotation ridge direction is parallel to the wafer. Minor flat. This inverted ladder-shaped cross section, combined with the undercut of the semiconductor layer, forms a semiconductor ridge with a wider ridge top, while maintaining a narrow ridge bottom with an active area injected by a sense current, and is implemented here. In the example, it is about 2 micrometers wide. After the semiconductor ridge etching is completed, a 3000 SiOx passivation layer 309 is fully deposited on the wafer surface at 250t, as shown in FIG. III. At this stage, the device manufacturing process All are through the conventional semiconductor process steps. The following is the use of STOP technology and the full back-up process to achieve a self-aligned process. After surface growth SiOx passivation, the wafer is placed in another pECVD process cavity at 350 ° A layer of 3 micrometers in thickness of 3 丨 (^ layer 31 〇, as shown in Figure 2 J. This thickness 3 丨 0) is quickly deposited at 2750 C per minute (the layer completely covers the wafer surface, and the semiconductor ridges below it cause Ridge formations are also formed on the surface of SiOx. With ordinary polishing equipment, as before I _—__- 15- This paper size is based on the standard of CNS (A4, 297 mm) 5 10 15 20 550S66 A7 V. Invention Explanation (Employees' Consumption Cooperation As described in the printed example, the Si0x surface with the original ridge landform can be polished to the SiOx plane 310a as shown in Fig. ^. Then, the Si0x plane is completely etched back with CF4 gas up to In0. 53Ga〇. 47As ohmic contact layer is uniformly exposed. In order to further increase the contact area of the metal electrode in the future, the entire 1110.5.4 fine ohmic contact layer 306a, including its sides, is exposed, as shown in Figure 3 Show. Therefore, in contrast to the previous embodiment, the contact layer at the top of the ridge is higher than the surrounding Si0x31b. The subsequent process is also a conventional semiconductor process and has no direct relationship with the present invention. However, as in the previous embodiment, the planar structure created by the present invention is helpful for the subsequent processes. After the In.53Ga.47As ohmic contact layer at the top of the semiconductor ridge is uniformly exposed, a p-type metal region is defined using a photomask alignment and exposure development process, as shown in Fig. 3M. Photoresist 311's approximately inverse-shaped profile can help metal lift off the process. Then 50x titanium (Ti), 500mm platinum (Pt), and 4,000mm gold (Au) The surface of the wafer in order is shown in Fig. 3n. The photoresist pattern 15 311 is dissolved with acetone to remove the metal 312b attached to it, and the metal is lifted off. The remaining metal 312a and the exposed In. The .53GaOe47As layer is contacted as a p-type metal electrode, as shown in Fig. 30. After rapid thermal annealing (RTA) of this p-type metal electrode for 20 seconds under a 420 nitrogen atmosphere (RTA) ) After that, the wafer was ground and polished from the back to a wafer thickness (300a) of about 100 micrometers, and 1,000 g of gold germanium (Ge) nickel (Ni) alloy and 4,000 g of gold were sequentially evaporated. On the other hand, as the n-type metal electrode 313, as shown in FIG. 3P, RTA is performed on the N-type metal electrode at 390 ° C for 20 seconds. In the above two embodiments, the STOP polishing technology is used to align the tool. The SiOx surface of the ridge landform is flattened. Figure 4 shows the meaning of the process of implementing the STOP polishing process.

I 10 訂 線 20 -16- 本紙張尺度適用+國國家標準(CNS)A4規格⑵0x 297公爱) 550866 a? B7 PA010430 υοζΓΠΤΤΣΤ 五、發明說明( 表面地貌的變化情形。(Α)係為進行拋磨前,晶圓400上SiOx表面 具脊列之地貌。如上述兩個實施例中,這些脊403的起始高度皆 約為1.6至1· 7微米,此高度遠超過一般拋磨設備所能達到的均勻 度(約±5微米)。因此,如(B)所示,使用一般之拋磨機器,經 5 過剛開始數分鐘的拋磨後,在某一區域範圍401中,SiOx脊列 403a的高度並未均勻地移除。然而,藉由於拋磨面施加壓力的調 整可使得SiOx平面402的拋磨移除速率近乎停滯;相反的,由於 SiOx脊極小的拋磨面積,其高度的拋磨移除可以相當的迅速,約 可達每分鐘0· 15微米。是以於拋磨製程持續進行時,此些Si〇x* 10將可在不影響SiOx底平面402的情形下依序被完全拋磨移除,如 (C)即(D)所示。亦即當所有的Si〇x脊皆被拋除後,拋磨si〇x層的 速率便近乎停滯,如同自我終止般。因此,最後表面的平坦 度將會與Si〇x的沈積機制,而非與拋磨製程,有較大關連;也因 此可明顯看出本發明適用於對製程均勻性及良率要求均高之量產 15 環境。 【特點及功效】 本發明所提供之脊狀波導半導體雷射之自我對準式製 經濟部智慧財產局員工消費合作社印製 程方法,與前述引證案及其他習用技術相互比較時,更具 有下列之優點: 20 (1)簡易且可靠之製程··傳統之雙槽結構需要至少三道的光 罩對準與曝光顯影製程,然而利用本發明所提出之自我對準式製 程,則只需兩道。此外,若半導體脊之剖面形狀不適當,如倒梯 形(inverse-tapered)或下切狀,傳統之雙槽結構會有金屬披覆 上的問題’因為金屬電極必須由脊頂往下披覆至槽底再往上披覆 -17 - x 297^17 m張尺度適用 550866 B7 五、發明說明(^) ''A0I04J0 D(5c -18/21 經 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 至裝訂墊區,不當剖面形狀可能導致過大的阻值甚至斷路情形。 過大的阻值將導致不必要的寄生及熱效應,而斷路則使得元件失 去裝訂墊,兩者皆造成元件良率下降。相反的,平面型元件則無 此類問題;且由於整個脊頂(甚至些許脊側)可用與金屬電極接 5觸,元件阻值可達最佳之情況,以減少熱效應。再者,藉由ST〇p 技術的使用,較乾式蝕刻(dry etching)方便之化學濕式蝕刻 (chemical wet etching)亦可用於形成半導體脊。 (2) 絕佳的製程均勻性··實施ST〇p拋磨技術,對具脊列地貌 之si〇x表面進行平坦化,可使Si〇x平面的平整度取決於沈積Si〇x 10的機制,一般情形下此沈積平整度可達土 1%以下(晶圓邊緣除 外),故可獲致絕佳之製程均勻度。 (3) 賦予元件高速操作之潛力:由於裝訂墊置於厚層 上’其所造成之寄生電容因此可以較傳統雙槽結構來的小,也因 此提高其受RC限制之頻寬。 15 ⑷賦予元件覆晶鍵合(flip-chip bonding)之潛力:由於平 面型元件結構,其賦予元件作p側向下之覆晶鍵合能力,如此將 有助於半導體雷射散熱。此外,亦可利用覆晶鍵合與其他光電主 被動元件作準單石化(qUasi-m〇n〇H仕整合。 上列詳細說明係針對本發明之一可行實施例之具體說 20明’惟該實施例並非用以限制本發明之專利範圍,凡未脫 離本發明技藝精神所為之等效實施或變更,均應包含於本 案之專利範圍中。 綜上所述,本案不但在技術思想上確屬創新,並能較 習用物品增進上述多項功效,應已充分符合新穎性及進步I 10 Alignment 20 -16- This paper size is applicable + National National Standard (CNS) A4 specifications (0x 297 public love) 550866 a? B7 PA010430 υοζΓΠΤΤΣΤ 5. Description of the invention (changes in surface topography. (Α) is for throwing Before grinding, the topography of the SiOx surface on the wafer 400 has ridges. As in the above two embodiments, the starting height of these ridges 403 is about 1.6 to 1.7 microns, which is much higher than that of ordinary polishing equipment. The achieved uniformity (about ± 5 microns). Therefore, as shown in (B), using a general polishing machine, after 5 minutes of polishing for the first few minutes, in a certain area range 401, SiOx ridges The height of 403a is not removed uniformly. However, the polishing removal rate of the SiOx plane 402 is almost stagnant due to the adjustment of the pressure applied by the polishing surface. On the contrary, due to the extremely small polishing area of the SiOx ridge, the Removal by polishing can be quite rapid, up to about 0.15 micron per minute. When the polishing process is continued, these SiOx * 10 will be able to be sequentially without affecting the SiOx bottom plane 402 It was completely removed by grinding, as shown in (C) or (D). That is, after all SiOx ridges have been removed, the rate of polishing the SiOx layer is almost stagnant, as if it were self-terminating. Therefore, the flatness of the final surface will be related to the SiOx deposition mechanism instead of It is greatly related to the polishing process; therefore, it can be clearly seen that the present invention is suitable for mass production environments with high requirements on process uniformity and yield. [Features and Effects] The ridge waveguide semiconductor provided by the present invention Laser's self-aligned manufacturing method of the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economics has the following advantages when compared with the aforementioned citations and other customary techniques: 20 (1) Simple and reliable process ·· Traditional The double-groove structure requires at least three mask alignment and exposure development processes, but using the self-aligned process proposed by the present invention requires only two. In addition, if the cross-sectional shape of the semiconductor ridge is not appropriate, such as inverted Trapezoidal (inverse-tapered) or undercut, the traditional double-slot structure has the problem of metal coating. 'Because the metal electrode must be coated from the top of the ridge to the bottom of the groove and then coated -17-x 297 ^ 17 m ruler Applicable to 550866 B7 V. Description of the invention (^) '' A0I04J0 D (5c -18/21) The employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed to the binding pad area. Improper cross-sectional shape may lead to excessive resistance or even disconnection. The resistance value will cause unnecessary parasitics and thermal effects, while the disconnection will cause the component to lose the binding pad, both of which will cause the component yield to decline. In contrast, flat components have no such problems; and because the entire spine top (even a little Ridge side) can be used in contact with the metal electrode, the component resistance value can reach the best situation to reduce the thermal effect. Furthermore, by using the STOP technology, chemical wet etching, which is more convenient for dry etching, can also be used to form semiconductor ridges. (2) Excellent process uniformity. · Implementing ST〇p polishing technology to flatten the SiOx surface with ridge landforms. The flatness of the SiOx plane depends on the deposition of SiOx 10. Mechanism, under normal circumstances, the flatness of this sediment can reach less than 1% of soil (except for wafer edges), so it can achieve excellent process uniformity. (3) Give the component the potential for high-speed operation: Because the binding pad is placed on a thick layer, the parasitic capacitance caused by it can be smaller than that of the traditional two-slot structure, which also increases its RC-limited bandwidth. 15 ⑷ Potential for flip-chip bonding: Due to the planar device structure, it gives the device p-side flip-chip bonding capability, which will help semiconductor laser heat dissipation. In addition, flip-chip bonding can also be used for quasi-monolithic integration of other optoelectronic active and passive components (qUasi-m0n0H). The detailed description above is specific to one of the feasible embodiments of the present invention. The embodiments are not intended to limit the scope of the patent of the present invention, and any equivalent implementations or changes that do not depart from the technical spirit of the present invention should be included in the scope of the patent in this case. In summary, this case is not only technically ideological Innovative, and can improve the above-mentioned multiple effects over conventional items, which should fully meet the novelty and progress

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II

I 550866 A7 B7 --- PA010430.DOC - 19/21 五、發明說明(f|) 性之法定發明專利要件,爰依法提出申請,懇請貴局核 准本件發明專利申請案,以勵發明,至感德便。 (請先閱讀背面之注意事項再填寫本頁) _ _ _ _ _ _ _ n 1« I fliBi 1_§ |_1 ϋ · 1> ·ϋ e^tm n· i^i ai-i I n _ =口 /¾ j 經濟部智慧財產局員工消費合作社印製 -19- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)I 550866 A7 B7 --- PA010430.DOC-19/21 V. Description of invention (f |) statutory invention patent elements, apply in accordance with law, and kindly ask your office to approve this invention patent application to encourage invention Deben. (Please read the notes on the back before filling this page) _ _ _ _ _ _ _ n 1 «I fliBi 1_§ | _1 ϋ · 1 > · ϋ e ^ tm n · i ^ i ai-i I n _ =口 / ¾ j Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -19- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)

Claims (1)

550866 申請專利範圍 A8 B8 C8 D8 卩 A01W3Q_m 10 15 經濟部智慧財1局員工消費合作社印製 20 2. ―種脊狀波導半導體雷射之自我料式製程方法, 其中至少包含下列步驟: 步驟 提供一磊晶成長之多層雷射結構,其包含一半導 體基板帛彳導體波導層、第-半導體侷限層、-半導 體活|±層區、第二半導體偈限層、第二半導體波導層、及 一半導體歐姆接觸層; 步驟-·全面沈積第_介電質層於步驟—之半導體歐姆接 觸層之上; 步驟一·藉由於步驟二之第—介電質層定義出圖案,作為 餘刻遮罩,並進行_製程,以碱半導齡狀結構; 步驟四:全面沈積第二介電f層於步驟三之已形成脊狀結 構之半—上’作解導體表面之鈍化處理; 步驟五·全面沈積第三介電質層於步驟四之已具脊狀結構 並作介電質鈍化處理之晶圓表面上; 步驟六··對步驟五之第三介電f層之表行平坦化; 步驟七:施行全面回蝕製程均勻地移除介電質層厚度,直 到半導體脊頂之歐姆接觸層均勻暴露出來為止; 步驟八:艘上第-金屬層及第二金屬層,該第一金屬層與 步驟七中暴露出之半導體脊頂之歐姆接觸層作接觸,作為 元件於晶圓表面上之電極;而第二金屬層則錢於經研磨拋 光之晶圓背面,作為元件於晶圓背面上之電極。 如申請專利範圍第1項所述之脊狀波導半導體雷射之 自我對準式製程方法,其中該步驟二所述之第一介電質 層,可為SiOx、SiNx、或Si〇xNy。 請 先 閱 面 之 注 I 訂 [紙張尺度適用中國CNS) ^50866 A8 B8 C8 D8 申請專利範圍 PA010430.DOC 21m 3· 5 5. 10 6. 15 8. 經濟部智慧財產局員工消費合作社印製 20 如申請專利範圍第1項所述之脊狀波導半導體雷射之 自我對準式製程方法,其中該步驟三所述之半導體脊狀 結構之蝕刻,可為濕式蝕刻、乾式蝕刻、或兩者之組合。 如申請專利範圍第1項所述之脊狀波導半導體雷射之 自我對準式製程方法,其中該步驟四所述之 層,可為SH)X、SlNx、或Sl〇xNy。 一 ^ 如申請專利範圍第1項所述之脊狀波導半導體雷射之 自我對準式製程方法,其中該步驟五所述之第三介電質 層,其厚度較脊高為大,可為Si〇x或Sic〇H。 、 如申凊專利範圍第彳項所述之脊狀波導半導體雷射之 自。我對準式製程方法,#中該步驟六所述之平坦化製 程’可採用貞載可赋瓣設備所進行之拋磨製程。 如申請專利範圍第!項所述之脊狀波導半導體雷射之 1我對準式製程方法,其中該步驟七所述之對已平坦之 介電質表面作全面⑽製程,可為濕式㈣、乾式制、 或兩者之組合。 女申明專利範圍第彳項所述之脊狀波導半導體雷射之 ^我對準式製程方法,其巾於步驟三之後步驟四之前, 可以先進行移除作輕刻遮罩之第—介電質層的步驟。550866 Applicable patent scope A8 B8 C8 D8 卩 A01W3Q_m 10 15 Printed by the Consumer Cooperatives of the Smart Finance 1 Bureau of the Ministry of Economic Affairs 20 2. ―A kind of self-made manufacturing method for ridge waveguide semiconductor lasers, which includes at least the following steps: Steps provide a An epitaxial growth multilayer laser structure, which includes a semiconductor substrate, a conductor waveguide layer, a first semiconductor confinement layer, a semiconductor active layer, a second semiconductor confinement layer, a second semiconductor waveguide layer, and a semiconductor. Ohmic contact layer; step- · deposit a comprehensive _ dielectric layer on the semiconductor ohmic contact layer in step- one; step one-by-define the pattern due to the second-dielectric layer in step two, as a mask for the remainder, And carry out the _ process, with alkaline semiconducting age-like structure; Step 4: Fully deposit a second dielectric f layer on the third half of the ridge-like structure formed in Step 3 as passivation treatment on the surface of the conductor; Step 5 · Comprehensive Deposit a third dielectric layer on the wafer surface that has a ridge structure and dielectric passivation treatment in step 4; step 6 · flatten the surface of the third dielectric f layer in step 5 Step 7: Perform a comprehensive etch-back process to uniformly remove the thickness of the dielectric layer until the ohmic contact layer on the top of the semiconductor ridge is uniformly exposed; Step 8: The first-metal layer and the second metal layer on board, the first A metal layer is in contact with the ohmic contact layer of the semiconductor ridge top exposed in step 7 as the electrode of the component on the wafer surface; and the second metal layer is on the back of the polished wafer as the component on the wafer Round electrode on the back. According to the self-aligned process method of the ridge waveguide semiconductor laser described in item 1 of the scope of the patent application, the first dielectric layer described in step 2 may be SiOx, SiNx, or SiOxNy. Please read the note I above [Paper size is applicable to China CNS] ^ 50866 A8 B8 C8 D8 Patent application scope PA010430.DOC 21m 3 · 5 5. 10 6. 15 8. Printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 20 According to the self-aligned process method of the ridge waveguide semiconductor laser described in item 1 of the scope of the patent application, the etching of the semiconductor ridge structure described in step 3 may be wet etching, dry etching, or both. Of combination. The self-aligned manufacturing method of the ridge waveguide semiconductor laser as described in the first item of the patent application scope, wherein the layer described in the fourth step may be SH) X, SlNx, or SlOxNy. ^ The self-aligned process method of the ridge waveguide semiconductor laser described in item 1 of the scope of the patent application, wherein the thickness of the third dielectric layer described in step 5 is larger than the ridge height, which can be SiOx or SicoH. The ridge waveguide semiconductor laser as described in item (2) of the patent application. In the alignment process method, the flattening process described in step 6 in # can use the polishing process performed by a chuck-type flapping device. Such as the scope of patent application! The ridge-waveguide semiconductor laser described in item 1 of the self-aligning process method, wherein the step 7 is a comprehensive process of the flat dielectric surface, which can be wet-type, dry-type, or both. Of the combination. The female claims that the ridge waveguide semiconductor laser described in the item 彳 of the patent scope of the ^ self-alignment process method, the towel can be removed as a light-shielded first-step dielectric before step three after step four. Steps in the stratum. 請 先 閱 讀 背 面 之 注 意 事 項 t I m 訂Please read the notes on the back first.
TW91105970A 2002-03-27 2002-03-27 Self-aligned process method of ridge shape waveguide semiconductor laser TW550866B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103066026A (en) * 2011-10-21 2013-04-24 稳懋半导体股份有限公司 High-breaking-strength semiconductor wafer improved structure and manufacture method thereof
TWI480941B (en) * 2011-10-21 2015-04-11 Win Semiconductors Corp A structure of semiconductor chips with enhanced die strength and a fabrication method thereof
TWI814937B (en) * 2019-11-06 2023-09-11 晶智達光電股份有限公司 Laser device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103066026A (en) * 2011-10-21 2013-04-24 稳懋半导体股份有限公司 High-breaking-strength semiconductor wafer improved structure and manufacture method thereof
TWI480941B (en) * 2011-10-21 2015-04-11 Win Semiconductors Corp A structure of semiconductor chips with enhanced die strength and a fabrication method thereof
CN103066026B (en) * 2011-10-21 2015-10-21 稳懋半导体股份有限公司 High breaking strength semiconductor transistor elements structure-improved and manufacture method thereof
TWI814937B (en) * 2019-11-06 2023-09-11 晶智達光電股份有限公司 Laser device

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