TW536791B - Trench flash memory device and the method of fabricating the same - Google Patents

Trench flash memory device and the method of fabricating the same Download PDF

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Publication number
TW536791B
TW536791B TW091112769A TW91112769A TW536791B TW 536791 B TW536791 B TW 536791B TW 091112769 A TW091112769 A TW 091112769A TW 91112769 A TW91112769 A TW 91112769A TW 536791 B TW536791 B TW 536791B
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Taiwan
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trench
layer
substrate
flash memory
type
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TW091112769A
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Chinese (zh)
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Ko-Hsing Chang
Chih-Wei Hung
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Powerchip Semiconductor Corp
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Abstract

A method of fabricating a trench flash memory device, where the method includes forming a patterned mask layer on the substrate and using it as the mask for form a trench in the substrate. Next, a source region is formed in the substrate around near the bottom of the trench, and followed by forming a tunnel oxide layer, a floating gate, a gate dielectric layer and a control in the trench. After removing the mask layer to expose the substrate, a drain region is further formed in the substrate. In this invention, since the trench flash memory device has a cylindrical shape with the tunnel oxide layer, the floating gate and the gate dielectric layer wrapping around the control gate, therefore the overlap area between the floating gate and the control gate is increased, resulting in a higher gate coupling rate (GCR), a lower required operation voltage and a higher device operation speed and efficiency.

Description

536791 五、發明說明(1) 本發明是有關於一種半導體元件之製造方法,且特別 是有關於一種溝渠式快閃記憶體及其製造方法。 記憶體,顧名思義便是用以儲存資料或數據的半導體 元件。當電腦微處理器之功能越來越強,軟體所進行之程 式與運算越來越龐大時,記憶體之需求也就越來越高,為 了製造容量大且便宜的記憶體以滿足這種需求的趨勢,製 作記憶體元件之技術與製程,已成為半導體科技持續往高 積集度挑戰之驅動力。 舉例來說,快閃記憶體元件由於具有可多次資料之存 入、讀取、抹除等動作,且存入之資料在斷電後也不會消 失之優點,所以已成為個人電腦和電子設備所廣泛採用的 一種記憶體元件。 典型的快閃記憶體元件,一般是被設計成具有堆疊式 閘極(Stack- Gate)結構,其中包括一穿隧氧化層,一用來 儲存電衍的多晶碎浮置閘極(Floating gate) ’ 一氧化碎/ 氮化石夕/氧化石夕(Oxide-Nitride-Oxide,0N0)結構的介電 層,以及一用來控制資料存取的多晶矽控制閘極(Control G a t e )。對此快閃記憶體元件進行程式化或抹除操作時, 係分別於源極區、汲極區與控制閘極上施加適當電壓,以 使電子注入多晶矽浮置閘極中,或將電子從多晶矽浮置閘 極中拉出。 一般而言,快閃記憶體元件常用之電子注入模式可分 為通道熱電子注入模式(Channel Hot-Electron Injection,CHEI)以及F-N 穿隨(Fowler-Nordheim536791 V. Description of the invention (1) The present invention relates to a method for manufacturing a semiconductor device, and more particularly to a trench type flash memory and a method for manufacturing the same. Memory, as its name implies, is a semiconductor device used to store data or data. As the functions of computer microprocessors become more and more powerful, and the programs and calculations performed by software become more and more large, the demand for memory will become higher and higher. In order to manufacture large-capacity and cheap memory to meet this demand The technology and process of making memory components have become the driving force for semiconductor technology to continue to challenge high accumulation. For example, flash memory components have become a personal computer and electronics because they can store, read, and erase data multiple times, and the stored data will not disappear even after the power is turned off. A memory element widely used in devices. A typical flash memory device is generally designed to have a stack gate structure, which includes a tunnel oxide layer and a polycrystalline floating gate for storing electrical derivatives. ) 'Dioxide oxide / nitride oxide / oxide oxide (0N0) structure dielectric layer and a polycrystalline silicon control gate (Control Gate) for controlling data access. When programming or erasing the flash memory device, an appropriate voltage is applied to the source region, the drain region, and the control gate, respectively, so that electrons are injected into the polycrystalline silicon floating gate, or electrons are removed from the polycrystalline silicon. Pull out the floating gate. Generally speaking, the electron injection modes commonly used in flash memory devices can be divided into Channel Hot-Electron Injection (CHEI) and F-N pass-through (Fowler-Nordheim

90691 w f.p t d 第5頁 536791 五、發明說>明(2) T u η n e 1 i n g )模式等等,而且元件的程式化與抹除操作模式 隨著電子注入與拉出之方式而改變。 在快閃記憶體的操作上,通常浮置閘極與控制閘極之 間的閘極I禺合率(Gate-Coupling Ratio,GCR)越大,其操 作所需之工作電壓將越低’而快閃記憶體的操作速度與效 率就會大大的提升。其中增加閘極搞合率的方法,包括了 增加、;孚置閘極與控制閘極間之重疊面積(〇 v e r 1 a p A r e a )、 降低浮置閘極與控制閘極間之介電層的厚度、以及增加浮 置閘極與控制閘極間之介電層的介電常數(D i e 1 e c t r i c Const ant ;k)等 〇 然而,隨著積體電路正以更高的集積度朝向小型化的 元件發展,所以必須縮小快閃記憶體元件之記憶胞尺寸以 增進其集積度。其中,縮小記憶胞之尺寸可藉由減小記憶 胞的閘極長度與資料線的間隔等方式來達成。但是,閘極 長度變小會縮短了穿隧氧化層下方的通道長度(Channel Length),容易造成汲極與源極間發生不正常的電性貫通 (Punch T h r 〇 u g h t),如此將嚴重影響此記憶胞的電性表 現。itb外,在快閃記憶體的製造過程中,微影製程也會有 所謂§1鍵尺寸之問題,而限制記憶胞尺寸的縮小。 有鑑於此,本發明之一目的在於提供一種溝渠式快閃 記憶體及其製造方法,藉由於溝渠内形成記憶胞,而可縮 小記胞之尺寸,增加元件集積度。 本發明之另一目的為提供一種溝渠式快閃記憶體及其 製造方法,可以增加浮置閘極與控制閘極之重疊面積,而90691 w fp td Page 5 536791 V. Invention > Ming (2) T u η ne 1 ing) mode and so on, and the programming and erasing operation modes of the components change with the way of electron injection and extraction . In the operation of flash memory, the larger the gate-coupling ratio (GCR) between the floating gate and the control gate, the lower the operating voltage required for its operation. The operation speed and efficiency of flash memory will be greatly improved. The methods for increasing the gate closing ratio include increasing the overlap area between the gate and the control gate (0ver 1 ap Area), and reducing the dielectric layer between the floating gate and the control gate. Thickness, and increasing the dielectric constant of the dielectric layer between the floating gate and the control gate (Die 1 ectric constant; k), etc. However, as integrated circuits are becoming smaller with higher integration, The development of modernized devices requires that the memory cell size of flash memory devices be reduced to increase their accumulation. Among them, reducing the size of the memory cell can be achieved by reducing the gate length of the memory cell and the interval between the data lines. However, a smaller gate length shortens the channel length under the tunneling oxide layer, which easily causes abnormal electrical penetration between the drain and source (Punch T hr ught), which will seriously affect Electrical performance of this memory cell. In addition to itb, in the flash memory manufacturing process, the lithography process also has the problem of the so-called §1 key size, which limits the reduction of memory cell size. In view of this, an object of the present invention is to provide a trench-type flash memory and a method for manufacturing the same, which can reduce the size of a memory cell and increase the degree of component accumulation by forming a memory cell in the trench. Another object of the present invention is to provide a trench type flash memory and a method for manufacturing the same, which can increase the overlapping area of the floating gate and the control gate, and

9069twl ptci 第6頁 536791 五、發明說明(3) 提高浮置閘極與控制閘極之閘極耦合率,使操作所需之工 作電壓降低,並且能夠提升元件操作速度與效率。 本發明之再一目的為提供一種溝渠式快閃記憶體及其 製造方法,可以藉由控制溝渠之深度以得到較長的垂直通 道長度,而能避免一般元件尺寸縮小時所產生的問題。 本發明提供一種溝渠式快閃記憶體之製造方法,此方 法係於基底上形成圖案化罩幕層後,以圖案化罩幕層為罩 幕以於基底中形成溝渠,並於溝渠底部周圍的基底中形成 源極區。然後,於溝渠中形成穿隧氧化層,並於溝渠中形 :成第一導體層,且第一導體層之上表面低於基底表面。之 後,於第一導體層上形成共形之閘極介電層,並於基底上 形成第二導體層,且第二導體層填滿溝渠。接著,移除溝 渠以外之第二導體層以暴露圖案化罩幕層的表面,並移除 罩幕層以暴露基底之表面。之後,於溝渠頂部周圍之基底 中形成 >及極區。 本發明於溝渠底部形成源極區之步驟係先於溝渠内形 成共形之摻雜絕緣層,並於溝渠底部形成第一光阻層,此 第一光阻層經過精準蝕刻後,並未填滿溝渠且暴露出部分 摻雜絕緣層。然後,移除未被第一光阻層覆蓋之摻雜絕緣 層,留下位於溝渠底部周圍之摻雜絕緣層,並於溝渠之側 壁上形成一帽蓋層。在移除第一光阻層後,進行一熱製 程,使摻雜絕緣層中的摻質擴散進入基底中而形成源極 區。之後,移除溝渠底部的摻雜絕緣層與溝渠側壁上之帽 蓋層。由於溝渠頂部側壁形成有帽蓋層,故可阻擋住在熱9069twl ptci Page 6 536791 V. Description of the invention (3) Increasing the gate coupling rate between the floating gate and the control gate, reducing the working voltage required for operation, and improving the speed and efficiency of component operation. Another object of the present invention is to provide a trench type flash memory and a manufacturing method thereof, which can control the depth of the trench to obtain a longer vertical channel length, and can avoid problems caused when the size of general components is reduced. The invention provides a trench flash memory manufacturing method. The method is to form a patterned mask layer on a substrate, and then use the patterned mask layer as a mask to form a trench in the substrate. A source region is formed in the substrate. Then, a tunneling oxide layer is formed in the trench, and a first conductor layer is formed in the trench, and the upper surface of the first conductor layer is lower than the surface of the substrate. Thereafter, a conformal gate dielectric layer is formed on the first conductor layer, a second conductor layer is formed on the substrate, and the second conductor layer fills the trench. Next, the second conductor layer outside the trench is removed to expose the surface of the patterned mask layer, and the mask layer is removed to expose the surface of the substrate. After that, > and polar regions are formed in the substrate around the top of the trench. The step of forming the source region at the bottom of the trench according to the present invention is to form a conformal doped insulating layer in the trench first, and form a first photoresist layer at the bottom of the trench. The trench is full and a portion of the doped insulating layer is exposed. Then, the doped insulating layer not covered by the first photoresist layer is removed, leaving the doped insulating layer around the bottom of the trench, and a capping layer is formed on the sidewall of the trench. After the first photoresist layer is removed, a thermal process is performed to diffuse the dopants in the doped insulating layer into the substrate to form a source region. After that, the doped insulating layer at the bottom of the trench and the capping layer on the sidewall of the trench are removed. A cap layer is formed on the top side wall of the trench to block heat

9069ΐ\νΓ. ptd 第7頁 536791 五、發明說明(4) 製程中,摻雜絕緣層中摻質的擴散,使源極區不致擴散過 大,而可限制在包圍住溝渠底部的範圍内。 而且,本發明於溝渠中形成上表面低於基底表面之第 一導電層的步驟係先於溝渠内形成第二光阻層,此第二光 阻層以精準的蝕刻控制,並未填滿溝渠且暴露出部分第一 導體層。接著移除未被第二光阻層覆蓋之第一導體層,並 移除第二光阻層。由於,第一導體層(浮置閘極)之上表面 低於基底表面,因此可以較容易在後續製程中形成連續的 第二導體層(控制閘極)。 itb外,本發明在形成穿隧氧化層之步驟前,更包括進 行一修補製程,以修補溝渠其側壁與底部在蝕刻製程所造 成之損壞,此修補製程之步驟係先進行一熱氧化製程,於 暴露的溝渠表面形成一層襯氧化層以修補^虫刻製程所造成 之損壞,然後再移除襯氧化層。 另外,本發明更包括於基底中形成與源極區連接之一 第一導電型第一井區,於第一導電型第一井區上形成一第 二導電型第二井區,並於基底中形成貫穿該第二導電型第 二井區而與該第一導電型第一井區連接之一第一導電型第 三井區。 冰發明係於基底中形成一溝渠後,於溝渠底部周圍之 基底寸形成源極區。接著於溝渠中依序形成穿隧氧化層、 浮置間極、閘極介電層與控制閘極,並於溝渠頂部周圍之 基底呤形成汲極區。然後利用井區連接源極區,並以溝渠 周圍位於汲極區與井區之間的區域做為通道區。由於,本9069ΐ \ νΓ. Ptd page 7 536791 V. Description of the invention (4) During the process, the dopant diffusion in the doped insulating layer prevents the source region from diffusing too much, but can be limited to the area surrounding the bottom of the trench. In addition, the step of forming a first conductive layer with an upper surface lower than the substrate surface in the trench according to the present invention is to form a second photoresist layer in the trench first. A portion of the first conductor layer is exposed. Then, the first conductive layer not covered by the second photoresist layer is removed, and the second photoresist layer is removed. Since the upper surface of the first conductor layer (floating gate) is lower than the surface of the substrate, it is easier to form a continuous second conductor layer (control gate) in subsequent processes. In addition to itb, before the step of forming the tunneling oxide layer, the present invention further includes a repairing process to repair the damage caused by the etching process on the sidewall and the bottom of the trench. The step of this repairing process is a thermal oxidation process. A lining oxide layer is formed on the exposed trench surface to repair the damage caused by the engraving process, and then the lining oxide layer is removed. In addition, the present invention further includes forming a first conductive type first well region connected to the source region in the substrate, forming a second conductive type second well region on the first conductive type first well region, and forming a second conductive type well region on the substrate. A third well region of the first conductivity type is formed through the second well region of the second conductivity type and connected to the first well region of the first conductivity type. The ice invention is that after forming a trench in the substrate, a source region is formed on the substrate around the bottom of the trench. Next, a tunneling oxide layer, a floating interlayer, a gate dielectric layer, and a control gate are sequentially formed in the trench, and a drain region is formed on the base substrate around the top of the trench. Then the well area is used to connect the source area, and the area around the trench between the drain area and the well area is used as the channel area. Thanks to this

9069twf.pt d 第8頁 536791 五、發明言兒明(5) 發明之溝渠式快閃記憶體之記憶胞是成柱狀,亦即穿隧氧 化層、浮置閘極與閘極介電層環繞包覆著控制閘極,因 此,可以增加浮置閘極與控制閘極之重疊面積,而提高浮 置閘極與控制閘極之閘極耦合率,以降低操作所需之工作 電壓,並提升元件操作速度與效率。 本發明另外提出一種溝渠式快閃記憶體,此溝渠式快 閃記t意體是由具有溝渠之基底、閘極結構、源極區與汲極 區所構成。其中,閘極結構設置於溝渠中,閘極結構在溝 渠中由外而内依序設置有穿隧氧化層、浮置閘極、閘極介 電層與控制閘極,且穿隧氧化層、浮置閘極與閘極介電層 環繞包覆著控制閘極。源極區設置於溝渠底部周圍之基底 中。汲極區設置於溝渠頂部周圍之基底中。 而且,本發明之溝渠式快閃記憶體更具備有:設置於 該基底中並連接該源極區之深η型井區、設置於深η型井區 上之ρ型井區,設置於基底中並貫穿ρ型井區而與深η型井 區連寺妾之η型井區。 本發明之溝渠式快閃記憶體之記憶胞是成柱狀之立體 結構,亦即穿隧氧化層、浮置閘極與閘極介電層環繞包覆 著控牵J閘極,因此可以增加浮置閘極與控制閘極之重疊面 積,而提高浮置閘極與控制閘極之閘極耦合率,以降低操 作所需之工作電壓,並提升元件操作速度與效率。 而且,本發明之溝渠式快閃記憶體的通道區是設置於 環繞溝渠外側之基底中(垂直式通道區),因此可以增加元 件集移度,而且可以藉由控制溝渠之深度準確的控制通道9069twf.pt d p. 8 536791 V. Inventor's Note (5) The memory cell of the trench flash memory of the invention is columnar, that is, the tunnel oxide layer, the floating gate and the gate dielectric layer The control gate is surrounded by the surrounding. Therefore, the overlapping area of the floating gate and the control gate can be increased, and the gate coupling ratio between the floating gate and the control gate can be increased to reduce the operating voltage required for operation. Improve component operation speed and efficiency. The present invention further provides a trench flash memory. The trench flash memory is composed of a substrate having a trench, a gate structure, a source region, and a drain region. The gate structure is arranged in the trench, and the gate structure is provided with a tunneling oxide layer, a floating gate, a gate dielectric layer and a control gate in this order from the outside to the inside, and the tunneling oxide layer, The floating gate and the gate dielectric layer surround the control gate. The source region is disposed in a substrate around the bottom of the trench. The drain region is disposed in a substrate around the top of the trench. Moreover, the trench type flash memory of the present invention further includes: a deep η-type well region disposed in the substrate and connected to the source region, and a ρ-type well region disposed on the deep η-type well region, and disposed on the substrate. The middle and through ρ-type well area and the deep η-type well area are connected to the η-type well area. The memory cell of the trench flash memory of the present invention has a columnar three-dimensional structure, that is, a tunneling oxide layer, a floating gate, and a gate dielectric layer are surrounded by a gated J gate, so it can be increased. The overlap area of the floating gate and the control gate increases the gate coupling rate of the floating gate and the control gate to reduce the operating voltage required for operation and increase the speed and efficiency of component operation. In addition, the channel area of the trench flash memory of the present invention is set in the substrate surrounding the trench (vertical channel area), so the component migration can be increased, and the channel can be accurately controlled by controlling the depth of the trench.

9069twΓ. pt ci 第9頁 536791 五、發明說明(6) 長度,進而能避免元件尺寸縮小時所產生的問題。此外, 柱狀之記憶胞結構可以提高電流密度,並提升記憶體元件 之程式化/抹除操作之效率。 為讓本發明之上述目的、特徵、和優點能更明顯易 懂,下文特舉一較佳實施例,並配合所附圖式,作詳細說 明如下: 圖式之標號說明: 1 00、2 0 0、3 0 0 :基底 1 02 :墊氧化層 1 04 :罩幕層 1 0 6、1 2 6 :溝渠 1 0 8、1 0 8 a :摻雜絕緣層 1 1 0、1 2 0 :光阻層 1 1 2 :帽蓋層 1 1 4、1 3 0 :摻雜區 1 1 6、3 1 4 ··穿隧氧化層 1 18、1 18a 、124 :導體層 122 >318 :閘極介電層 1 2 8、3 2 4 ·•隔離結構 132、202、302 :深η 型井區 1 34、3 04 : ρ型井區 1 36、3 22 :通道區 138、312 ·· η 型井區 2 0 4 :主動區9069twΓ. Pt ci Page 9 536791 V. Description of the invention (6) The length can avoid the problems caused when the component size is reduced. In addition, the columnar memory cell structure can increase the current density and improve the efficiency of the programming / erasing operation of the memory elements. In order to make the above-mentioned objects, features, and advantages of the present invention more comprehensible, a preferred embodiment is given below in conjunction with the accompanying drawings to make a detailed description as follows: Symbols of the drawings: 1 00, 2 0 0, 3 0 0: substrate 1 02: pad oxide layer 1 04: mask layer 1 0 6, 1 2 6: trench 1 0 8, 1 0 8 a: doped insulating layer 1 1 0, 1 2 0: light Barrier layer 1 1 2: Cap layer 1 1 4, 1 3 0: Doped region 1 1 6, 3 1 4 ·· Tunneling oxide layer 1 18, 1 18a, 124: Conductor layer 122 > 318: Gate Dielectric layer 1 2 8, 3 2 4 • Isolation structures 132, 202, 302: Deep η-type well area 1 34, 3 04: ρ-type well area 1 36, 3 22: Channel area 138, 312 ·· η type Well area 2 0 4: Active area

9069twf ptd 第10頁 536791 五、發明彭匕明(7) 2 0 6、W〇、Wi、W2 ••字元線 2 0 8 :記憶胞 2 1 0 、 D〇 、 Di 、 D2 :資料線 3 0 6 :閘極結構 3 0 8 :源極區 3 1 0 ·>及極區 3 1 6 :浮置閘極 3 2 0 :控制閘極9069twf ptd Page 10 536791 V. Inventing Peng Zhiming (7) 2 0 6, W0, Wi, W2 •• Character line 2 0 8: Memory cell 2 1 0, D0, Di, D2: Data line 3 0 6 : Gate structure 3 0 8: Source region 3 1 0 > and Pole region 3 1 6: Floating gate 3 2 0: Control gate

Qnl、Qn2、Qn3、Qn4、Qn5、Qn6、Qn7、Qn8、Qn9 ·吕己憶胞 實施侈 第1 A圖至第1 I圖所示為根據本發明一較佳實施例之一 種溝渠式快閃記憶體元件之製造流程剖面圖。 首先請參照第1 A圖,提供一基底1 0 0,例如是半導體 矽基底,於基底100表面依序形成一層墊氧化層102 —層罩 幕層1 0 4後,進行微影蝕刻製程圖案化罩幕層1 0 4與墊氧化 層102以形成暴露基底100之開口(未圖示)。墊氧化層102 之材質例如是氧化矽,形成墊氧化層1 0 2之方法例如是熱 氧化 去(Thermal Oxidation)。罩幕層104之材質例如是氮 化矽,形成罩幕層1 0 4之方法例如是化學氣相沉積法 (Chemical Vapor Deposition,CVD) 〇 接著,以罩幕層1 〇 4為罩幕,進行蝕刻製程,以在基 底1 0 0中形成複數個溝渠1 0 6。在基底1 0 0中蝕刻出溝渠1 0 6 之方法,包括乾式蝕刻法,例如是反應性離子蝕刻法。 接著,於基底1 0 0形成一層共形之摻雜絕緣層1 0 8,此Qnl, Qn2, Qn3, Qn4, Qn5, Qn6, Qn7, Qn8, Qn9 Lu Jiyi's cell implementation Figures 1A to 1I show a trench flash according to a preferred embodiment of the present invention A cross-sectional view of the manufacturing process of a memory device. First, please refer to FIG. 1A to provide a substrate 100, such as a semiconductor silicon substrate. A pad oxide layer 102—a masking layer 104 is sequentially formed on the surface of the substrate 100, and then patterned by a lithography process. The cover layer 104 and the pad oxide layer 102 form an opening (not shown) that exposes the substrate 100. The material of the pad oxide layer 102 is, for example, silicon oxide, and a method of forming the pad oxide layer 102 is, for example, thermal oxidation. The material of the mask layer 104 is, for example, silicon nitride, and a method of forming the mask layer 104 is, for example, a chemical vapor deposition method (Chemical Vapor Deposition, CVD). Then, using the mask layer 104 as a mask, An etching process is performed to form a plurality of trenches 106 in the substrate 100. A method for etching the trench 100 in the substrate 100 includes a dry etching method, such as a reactive ion etching method. Next, a conformal doped insulating layer 108 is formed on the substrate 100.

9069 twf.p t d 第11頁 536791 五、發明說明(8) 摻雜絕緣層1 〇 8之材質例如是摻質為珅離子之氧化石夕層, 形成捧雜絕緣層1 0 8之方法例如是以臨場(I η - S i t u )摻雜離 子之方式,利用化學氣相沈積法以形成之。 然後,於溝渠1 0 6底部形成一層光阻層1 1 0,其中光阻 層1 1 0經過回蝕刻後,並未填滿溝渠1 〇 6,且光阻層丨〇 6之 表面係位於基底1 〇 〇表面之下。於丨冓渠106底部形成一層光 阻層1 1 0之步驟例如是先於基底丨〇 〇上塗佈一層光阻層(未 圖示)後,進行回钱刻製程,移除基底1 0 0表面之光阻層與 部分溃渠1 0 6内之光阻層,而只留下溝渠1 0 6底部之光阻層 110° 揍著,請參照第1 B圖,移除未被光阻層1 1 0覆蓋之部 分摻雜絕緣層丨〇 8,而只於溝渠丨〇 6底部留下絕緣摻雜層 1 0 8 a。移除摻雜絕緣層丨〇 8之方法例如是濕式蝕刻法,係 以缓衝氫氟酸(Buffei< HF,BHF)或稀釋的氫氟酸(Diluted H F ’ D H F )為蝕刻劑。然後,將溝渠丨〇 6底部之光阻層丨丨〇去 除’並於在溝渠1〇6之側壁上形成一帽蓋層丨丨^^^9069 twf.ptd Page 11 536791 V. Description of the invention (8) The material of the doped insulating layer 1 08 is, for example, a oxidized stone layer doped with erbium ions, and the method of forming the doped insulating layer 108 is, for example, to The method of in-situ (I η-S itu) doping ions is formed by chemical vapor deposition. Then, a photoresist layer 1 10 is formed at the bottom of the trench 1 06. The photoresist layer 1 10 does not fill the trench 1 06 after the etch back, and the surface of the photoresist layer 〇0 is located on the substrate. Below the surface. The step of forming a photoresist layer 1 1 0 on the bottom of the trench 106 is, for example, firstly coating a photoresist layer (not shown) on the substrate 丨 00, and then performing a cashback process to remove the substrate 1 0 0 The photoresist layer on the surface and part of the photoresist layer in the channel 106, leaving only the photoresist layer at the bottom of the channel 106, held by 110 °. Please refer to Figure 1B to remove the non-photoresist layer The part covered by 1 10 is doped with the insulating layer 008, and only the bottom of the trench 206 is left with the insulating doped layer 10 8 a. The method of removing the doped insulating layer is, for example, a wet etching method, using buffered hydrofluoric acid (Buffei < HF, BHF) or diluted hydrofluoric acid (Diluted H F 'D H F) as an etchant. Then, remove the photoresist layer 丨 丨 〇 at the bottom of the trench 丨 〇 6 and form a capping layer on the sidewall of the trench 106 丨 ^^^

Layer)。帽蓋層丨12之材質例如是以四-乙基—鄰—矽酸酯 (J2ra Ethyl 0r th。Silicate,TEOS)/ 臭氧(〇3)為反應 氣體源=用化學氣相沈積法所形成之氧化矽。 崎紹Ϊ著請參照第1 C圖’對基底1 0 0進行一熱製程,使摻 1带士層108a中的雜質擴散進入溝渠106底部之基底100中 夕、、^ k摻雜區1 1 4 ’此摻雜區11 4即作為溝渠式快閃記憶體 玎=、二區。此外’由於溝渠1 0 6側壁形成有帽蓋層11 2 ’故 备住播雜絕緣層1 〇 8a中摻質的擴散,使摻雜區丨丨4不Layer). The material of the capping layer 12 is, for example, tetrakis-ethyl-o-silicic acid (J2ra Ethyl 0. Silicate, TEOS) / ozone (〇3) as a reaction gas source = formed by a chemical vapor deposition method Silicon oxide. Please refer to FIG. 1C to perform a thermal process on the substrate 100 to diffuse the impurities in the doped layer 108a into the substrate 100 at the bottom of the trench 106. The doped region 1 1 4 'This doped region 11 4 is used as a trench flash memory. In addition, since the cap layer 11 2 is formed on the sidewall of the trench 10 6, the diffusion of the dopant in the impurity insulating layer 108a is prevented, so that the doped region 丨 4 does not

536791 五、發明ΐ兒明(9) 致擴莆文過大,而可限制在包圍住溝渠1 〇 6底部的範圍内。 然後,移除溝渠1 〇 6底部的摻雜絕緣層1 〇 8 a與帽蓋層1 1 2。 移除溝渠1 0 6底部的摻雜絕緣層1 0 8 a與帽蓋層1 1 2之方法例 如是纟晶式#刻法,係以緩衝氫氟酸或稀釋的氫敗酸為餘刻 劑。 辛多除溝渠1 0 6底部的摻雜絕緣層1 0 8 a與帽蓋層1 1 2之步 驟後,更包括進行一修補製程,以修補溝渠1 〇 6其側壁與 底部在蝕刻製程所造成之損壞,此修補製程之步驟例如是 先進个亍一熱氧化製程,於暴露的溝渠1 〇 6表面形成一層襯 氧化層(Linear Layer)(未圖示)以修補餘刻製程所造成之 損壞,然後再移除襯氧化層。 孝妾著請參照第1 D圖,於基底1 0 0上形成一層共形的介 電層1 1 6以覆蓋溝渠1 0 6。介電層1 1 6之材質例如是氧化 矽,幵3成介電層1 1 6之方法例如是熱氧化法或低壓化學氣 相沉矛#法。此介電層1 1 6係作為快閃記憶體之穿隧氧化 〇 寺妾著,於基底100上形成一層共形之導體層118,此導 體層1 1 8之材質例如是摻雜多晶矽,其厚度例如是5 0 0埃左 右,幵3成導體層1 1 8之方法例如是以臨場摻雜離子之方 式,矛U用化學氣相沈積法以形成之。之後,於基底1 〇 0上 塗佈另一層光阻層(未圖示)後,進行一回蝕刻製程,移除 基底100表面之光阻層與部分溝渠106内之光阻層,而於溝 渠106内形成光阻層120,且光阻層120之上表面低於基底 1 00 t上表面。536791 V. The invention of Er Erming (9) caused the expansion script to be too large, but it could be limited to the range surrounding the bottom of the trench 106. Then, the doped insulating layer 108 and the cap layer 1 12 at the bottom of the trench 106 are removed. The method for removing the doped insulating layer 1 0 8 a and the cap layer 1 1 2 at the bottom of the trench 1 0 6 is, for example, a crystalline #etching method, which uses buffered hydrofluoric acid or diluted hydrofluoric acid as a post-etching agent. . After the steps of removing the doped insulating layer 10 8 a and the cap layer 1 12 at the bottom of the Sindor trench 106, a repair process is performed to repair the sidewall 106 and the bottom of the trench 100 caused by the etching process. The damage process, such as the advanced thermal oxidation process, forms a linear layer (not shown) on the exposed trench 106 surface to repair the damage caused by the remaining process. Then remove the liner oxide layer. Please refer to Fig. 1D, and form a conformal dielectric layer 1 16 on the substrate 100 to cover the trench 106. The material of the dielectric layer 1 16 is, for example, silicon oxide, and a method for forming the dielectric layer 1 16 by, for example, a thermal oxidation method or a low-pressure chemical gas phase sinking spear method. This dielectric layer 116 is used as a tunneling oxide for flash memory. A conformal conductive layer 118 is formed on the substrate 100. The material of this conductive layer 1 18 is, for example, doped polycrystalline silicon. The thickness is, for example, about 500 angstroms, and the method of forming the conductive layer 1 18 by 3 is, for example, a method of doping ions in the field, and forming the spear U by a chemical vapor deposition method. After that, another photoresist layer (not shown) is coated on the substrate 100, and then an etching process is performed to remove the photoresist layer on the surface of the substrate 100 and the photoresist layer in some of the trenches 106, and then to the trenches. A photoresist layer 120 is formed in 106, and the upper surface of the photoresist layer 120 is lower than the top surface of the substrate 100 t.

9069twf. pt cl 第13頁 536791 五、發明說明 (10) 接著,請參照第1 E圖, 被光阻層120覆蓋之導體層丨 矛、基底100上與溝渠106中未 體層1 1 8 a ,移除部分導體\ ,而只於溝渠1 〇 6中留下導 法。此導體層1 1 8 a即作為^ $之方法例如是乾式蝕刻 由於,導體層1 1 8a(浮置閘極1式快閃記憶體之浮置閘極。 此在後續製程中容易製造出 ^上表面低於基底表面,因 除光阻層1 2 0後,在導體屉u Q績的導體層(控制閘極)。移 形的介電層1 2 2,此介電^丨2 3 (洋置閘極)上形成一層共 矽/氧化矽等,且其厚度二士 B之材質例如是氧化矽/氮化 電層122之形成方法例如是==60埃/ 70埃/6〇埃左右,介 層1 2 2係作為溝渠式快閃記悟j化學氣相沈積法。此介電 電層1 2 2之材質也可以是氧^ 之閘極介電層。當然,介 接著請參照第1 F圖,於/夕層、氧化矽/氮化矽層等。 1 2 4填滿溝渠1 0 6。此導體屉^底1 0 0上形成另一層導體層 矽,此導體層1 24即作為溝曰渠之材質例如是摻雜多晶 形成導體層1 2 4之步驟例如是、二快記憶體之控制閘極。 利用化學氣相沈積法於基底丨〇 〇 T f雜離子之方式, ^ π 一、 L μ… 低1 ϋ 0上形成填滿溝渠之一層導 體層(未圖示),然後利用化學機械研磨法(Chemical9069twf. Pt cl Page 13 536791 V. Description of the invention (10) Next, referring to FIG. 1E, the conductor layer covered by the photoresist layer 120, the spear, the substrate 100 and the body layer 1 1 8 a in the trench 106, Remove some of the conductors and leave the method in the trench only. The conductive layer 1 1 8 a is a method such as dry etching. For example, the conductive layer 1 1 8 a (floating gate 1 type flash memory floating gate. This is easy to manufacture in subsequent processes.) The upper surface is lower than the surface of the substrate. After removing the photoresist layer 120, the conductor layer (control gate) of the conductor Q. The deformed dielectric layer 1 2 2, this dielectric ^ 丨 2 3 ( A layer of co-silicon / silicon oxide, etc. is formed on the gate), and the thickness of the material is 2 Å. For example, the method of forming the silicon oxide / nitride layer 122 is, for example, == 60 angstroms / 70 angstroms / 6 angstroms The dielectric layer 1 2 2 is a trench type flash memory chemical vapor deposition method. The material of the dielectric layer 1 2 2 can also be a gate dielectric layer of oxygen ^. Of course, please refer to Section 1 F for details. Figure, Yu / Xi layer, silicon oxide / silicon nitride layer, etc. 1 2 4 fills the trench 1 06. Another conductor layer silicon is formed on this conductor drawer ^ bottom 100, and this conductor layer 1 24 is used as a trench. The material of the channel is, for example, the step of doping polycrystalline silicon to form the conductor layer 12. For example, the control gate of the second fast memory is used. The chemical vapor deposition method is used on the substrate. Type, ^ π a, form a conductor layer (not shown), and then using a chemical mechanical polishing method (Chemical trench fill on the lower L μ ... 1 ϋ 0

Meehan i cal Polishing,CMP)移除溝渠1〇6以外之部分導 體層與介電層116直到暴露罩幕層1〇4之表面。 接著’請參照第1 G圖’於基底上形成一隔離結構 1 2 8,此隔離結構1 2 8例如是場氧化層或淺溝渠隔離結構, 隔離結構1 2 8係用以定義出主動區,且隔離結構1 2 8例如是 成條狀的佈局。在本實施例中,隔離結構1 2 8係以淺溝渠Meehan i cal Polishing (CMP) removes part of the conductor layer and the dielectric layer 116 other than the trench 106 until the surface of the mask layer 104 is exposed. Next, please refer to FIG. 1G. An isolation structure 1 2 8 is formed on the substrate. The isolation structure 1 2 8 is, for example, a field oxide layer or a shallow trench isolation structure. The isolation structure 1 2 8 is used to define an active area. And the isolation structure 1 2 8 is, for example, a strip-shaped layout. In this embodiment, the isolation structure 1 2 8 is a shallow trench.

9069t\vf .ptd 第14頁 536791 五、發明說明(11) 隔離結構為實例作說明。形成隔離結構1 2 8之步驟例如是 先利用微影與蝕刻技術使罩幕層1 0 4與墊氧化層1 0 2圖案 化,然後以圖案化罩幕層1 0 4為罩幕,於相鄰記憶胞之基 底1 0 0中蝕刻出一溝渠1 2 6 ,蝕刻方法例如是電漿蝕刻法 (Plasma Etching)。然後,於基底1 Ο 0上形成填滿溝渠1 2 6 之一層絕緣層(未圖示)。此絕緣層之材質例如是氧化矽, 形成♦邑緣層方法例如是先以四_乙基-鄰-碎酸S旨/臭氧為反 應氣體源,利用化學氣相沈積法形成一層氧化矽層後,進 行密實化製程以使氧化石夕層之結構更為緻密,接著利用罩 幕層1 0 6當作研磨終止層進行化學機械研磨製程,直至暴 露罩幕層106之表面。 接著請參照第1 Η圖,移除罩幕層1 0 4以暴露部分墊氧 化層1 0 2之表面。移除方法包括等向性蝕刻法例如是溼式 蝕刻洼等。其係利用墊氧化層1 〇 2當作蝕刻終止層,以熱 磷酸;?容液作為溼式蝕刻之蝕刻液進行蝕刻,直至暴露墊氧 化層102之表面。接著,移除塾氧化層102,以暴露基底 1 0 0之表面。移除部分墊氧化層1 0 2之方法包括等向性蝕刻 法例如是溼式蝕刻法等,其係利闬基底1 0 0當作蝕刻終止 層,以氫氟酸溶液作為溼式蝕刻之蝕刻液進行蝕刻,直至 暴露基底100之表面。而且,在移除罩幕層106與墊氧化層 1 0 2日芋,也會移除部分隔離結構1 2 8使得隔離結構1 2 8之上 表面低於導體層1 2 4之表面,且導體層1 2 4頂部側壁之部分 介電肩1 1 6也會被移除,因而使得導體層1 2 4 (控制閘極)突 出溝桀106。9069t \ vf .ptd Page 14 536791 V. Description of the invention (11) The isolation structure is described as an example. The step of forming the isolation structure 1 2 8 is, for example, first patterning the mask layer 10 and the pad oxide layer 102 using lithography and etching techniques, and then using the patterned mask layer 104 as a mask, A trench 1 2 6 is etched into the substrate 100 adjacent to the memory cell. The etching method is, for example, plasma etching (Plasma Etching). Then, an insulating layer (not shown) is formed on the substrate 100 to fill the trenches 1 2 6. The material of this insulating layer is, for example, silicon oxide, and the method of forming the edge layer is, for example, firstly using tetraethyl-o-ortho-acid S / ozone as a reactive gas source, and then forming a silicon oxide layer by chemical vapor deposition Then, a densification process is performed to make the structure of the oxidized stone layer more dense, and then a chemical mechanical polishing process is performed using the mask layer 106 as a polishing stop layer until the surface of the mask layer 106 is exposed. Then, referring to the first figure, remove the mask layer 104 to expose part of the surface of the pad oxidation layer 102. The removal method includes an isotropic etching method such as a wet etching depression. It uses the pad oxide layer 102 as an etch stop layer, and uses hot phosphoric acid; the capacitor liquid is used as an etching solution for wet etching to etch until the surface of the pad oxidation layer 102 is exposed. Next, the hafnium oxide layer 102 is removed to expose the surface of the substrate 100. Methods for removing a part of the pad oxide layer 102 include an isotropic etching method such as a wet etching method, which uses a base substrate 100 as an etching stop layer and a hydrofluoric acid solution as a wet etching etching. The liquid is etched until the surface of the substrate 100 is exposed. In addition, when removing the cover layer 106 and the pad oxide layer 102, part of the isolation structure 1 2 8 is also removed so that the upper surface of the isolation structure 1 2 8 is lower than the surface of the conductor layer 1 2 4 and the conductor A part of the dielectric shoulder 1 1 6 on the top side wall of the layer 1 2 4 is also removed, so that the conductor layer 1 2 4 (control gate) protrudes from the trench 106.

9069iw f.pt d 第15頁 536791 五、發明言兒明(12) ---- 接=請參照,圖,以導體層124為罩幕,進行一離 子植=衣权,於V體層124周圍之基底丨 形成栘雜區1 3 0,此摻雜F】Q n如从丸、塞 T m " 汲極區。植入之摻質3 丄作、ί!渠式快閃之 个工抑胜々士 Μ Α ^如疋坤(As )離子,植入能量為5〇仟 電子伙特左右,植入劑量為4 X 101 5原子/平方公分左右。 接著,,ϊί底1形成深n型井區132,此深η型井區I” 連接戶斤有基底中之摻雜區114。然*,於此井區132 上形成Ρ型井區134,因此,在溝渠106側壁四周之基底100 中,、丑位於摻雜區130與深η型井區132之間的區域即作為 溝渠式快閃§己丨思體之通道區丨3 6。之後,於基底1 〇 〇中形成 貫穿ρ型井區134而連接至深η型井區132之η型井區138。後 續完咸快閃記憶體之製程為習知技藝者所周知,在此不再 贅述。 第2圖為繪示本發明之分離閘極快閃記憶體之電路簡 圖。名第2圖中繪示複數個記憶胞Qnl至Qn9、資料線DG至資 料線D2、以及字元線WG至字元線^。其中,字元線WG連接記 憶胞Qnl、Qn2、Qn3之控制閘極,字元線1連接記憶胞Qn4、9069iw f.pt d page 15 536791 V. Inventor's Note (12) ---- Connect = Please refer to the figure, the conductor layer 124 is used as the screen, and an ion implantation = clothing right is placed around the V body layer 124 A doped region 1 3 0 is formed on the substrate, and this doping F] Q n is like a drain region and a T m " drain region. The implanted dopant 3 works, and the d! Channel flashing workmanship M Α ^ such as As Kun (As) ions, the implantation energy is about 50 仟 electrons, the implantation dose is 4 X 101 is about 5 atoms / cm². Next, the bottom 1 forms a deep n-type well region 132, and the deep n-type well region I "connects the doped region 114 in the substrate. However, a P-type well region 134 is formed on this well region 132. Therefore, in the substrate 100 around the sidewall of the trench 106, the region between the doped region 130 and the deep n-type well region 132 is used as a channel flash region. An n-type well region 138 is formed in the substrate 100 that penetrates the p-type well region 134 and is connected to the deep n-type well region 132. The subsequent process of completing the flash memory is well known to those skilled in the art, To repeat. Figure 2 is a circuit diagram showing the split gate flash memory of the present invention. Name Figure 2 shows a plurality of memory cells Qnl to Qn9, data lines DG to data lines D2, and word lines. WG to word line ^. Among them, word line WG is connected to the control gates of memory cells Qnl, Qn2, Qn3, and word line 1 is connected to memory cells Qn4,

Qn5、Qn6之控制閘極,字元線^連接記憶胞Qn7、Qn8、Qn9之控 制閘才δ。記憶胞Qni至Qn9之源極區接叙至共地線(Comm ο η Ground)。資料線D〇連接記憶胞Qnl、Qn4、Qn7之汲極區,資 料線Di連接記憶胞1、Qn5、Qn8之汲極區,資料線02連接記 憶胞Qn3、Qn6、Qn9之汲極區。 第3圖為繪示本發明之分離閘極快閃記憶體之上視 圖0The control gates of Qn5, Qn6, and the word line ^ are connected to the control gates of memory cells Qn7, Qn8, and Qn9. The source regions of memory cells Qni to Qn9 are connected to the common ground (Comm ο η Ground). Data line D0 is connected to the drain regions of memory cells Qnl, Qn4, Qn7, data line Di is connected to the drain regions of memory cells 1, Qn5, Qn8, and data line 02 is connected to the drain regions of memory cells Qn3, Qn6, and Qn9. FIG. 3 is a top view showing the split gate flash memory of the present invention. FIG. 0

隱 1Hidden 1

MSIMSI

9069twl ptcl 第16頁 536791 五、發明說明(13) 請參照第3圖本發明分離閘極快閃記憶體是由基底 2 0 0、隔離結構2 〇 2、主動區2 0 4、字元線2 0 6、記憶胞2 0 8 所構成。其中隔離結構2 0 2設置於基底2 0 0中,用以定義出 主動區204。字元線206設置於基底200上’且垂直於主動 區2 0 4。記憶胞2 0 8設置於字元線2 0 6橫跨主動區2 〇 4之基底 2 0 0下方,且記憶胞2 〇 8係設置於基底2 0 0之溝渠内。設置 於同一主動區204中之^己fe胞2 0 8之〉及極區輕接至資料線 2 10。 第4圖所繪示為本發明之溝渠式快閃記憶體之結構剖 面圖,且第4圖係為第3圖之I - Γ線剖面圖。請參照第4 圖,本發明之快閃記憶體是由基底3 0 0、深η型井區3 0 2、p 型井區3 0 4、閘極結構3 0 6、源極區3 0 8、汲極區3 1 0、與η 型井區3 1 2所構成。 閘極結構3 0 6形成於基底之溝渠3 1 3中,其由外而内分 別是由穿隧氧化層3 1 4、浮置閘極3 1 6、閘極介電層3 1 8、 控制閘極3 2 0所構成,且穿隧氧化層3 1 4、浮置閘極3 1 6與 閘極介電層3 1 8環繞包覆著控制閘極3 2 0。 深η型井區302位於基底3〇〇中。ρ型井區304位於深η型 井區中。閘極結構3 0 6位於基底3〇〇中,且閘極結構3 0 6貫 穿Ρ型井區3 0 4與深η型井區3 0 2。源極區3 0 8位於閘極結構 3 0 6底部周圍之深η型井區3 〇 2中。汲極區3 1 〇位於閘極結構 306頂部周圍之基底300中,且汲極區31〇與深η型井區338 之間的區域即作為溝渠式快閃記憶體之通道區3 2 2。η型井 區312貫穿ρ型井區304而連接至深η型井區302。9069twl ptcl Page 16 536791 V. Description of the invention (13) Please refer to FIG. 3 The present invention separates the gate flash memory from the substrate 2 0, the isolation structure 2 0 2, the active area 2 0 4 and the word line 2 0 6, memory cell 2 0 8 is composed. The isolation structure 202 is disposed in the substrate 200 to define the active area 204. The word line 206 is disposed on the substrate 200 'and is perpendicular to the active area 204. The memory cell 208 is disposed below the base line 2000 of the word line 206 across the active area 208, and the memory cell 208 is disposed in the trench of the base 208. The two active cells set in the same active area 204 and the polar area are lightly connected to the data line 2 10. FIG. 4 is a cross-sectional view showing the structure of a trench flash memory according to the present invention, and FIG. 4 is a cross-sectional view taken along the line I-Γ in FIG. 3. Please refer to FIG. 4. The flash memory of the present invention is composed of a substrate 3 0 0, a deep n-type well area 3 0 2, a p-type well area 3 0 4, a gate structure 3 0 6, and a source area 3 0 8 , Drain region 3 1 0, and n-type well region 3 1 2. The gate structure 3 0 6 is formed in the trench 3 1 3 of the substrate, which is controlled by a tunnel oxide layer 3 1 4, a floating gate 3 1 6, and a gate dielectric layer 3 1 8 from the outside to the inside. The gate electrode 3 2 0 is formed, and the tunnel oxide layer 3 1 4, the floating gate electrode 3 1 6 and the gate dielectric layer 3 1 8 surround the control gate electrode 3 2 0. The deep n-well region 302 is located in the basement 300. The p-well area 304 is located in a deep n-well area. The gate structure 306 is located in the substrate 300, and the gate structure 306 penetrates through the P-type well area 304 and the deep n-type well area 302. The source region 308 is located in a deep n-type well region 300 around the bottom of the gate structure 306. The drain region 3 10 is located in the substrate 300 around the top of the gate structure 306, and the area between the drain region 31 and the deep n-type well region 338 is used as the channel region 3 2 of the trench flash memory. The n-type well region 312 penetrates the p-type well region 304 and is connected to the deep n-type well region 302.

9069twf.ptd 第17頁 536791 五、發明言兒明(14) 你I照本發明實施例所述,本發明係於基底中形成一溝 渠後,於溝渠底部周圍之基底中形成源極區。接著於溝渠 中依/芋形成穿隧氧化層、浮置閘極、閘極介電層與控制閘 極,立i於溝渠頂部周圍之基底中形成汲極區。然後利用井 區連接源極區,並以溝渠周圍位於汲極區與井區之間的區 域做為通道區。由於,本發明之溝渠式快閃記憶體之記憶 胞是成柱狀立體結構,亦即穿隧氧化層、浮置閘極與閘極 介電層環繞包覆著控制閘極,因此本發明與習知的堆疊閘 極式个夬閃記憶體相比較,可以增加浮置閘極與控制閘極之 重疊函積,而提高浮置閘極與控制閘極之閘極耦合率,降 低操竹所需之工作電壓,進而提升元件操作速度與效率。 雨且,本發明之溝渠式快閃記憶體的通道區是設置於 環繞潘渠外側之基底中(垂直式通道區),因此可以增加元 件集韻度,而且可以藉由控制溝渠之深度準確的控制通道 長度,進而能避免元件尺寸縮小時所產生的問題。此外, 柱狀之記憶胞結構可以提高電流密度,並提升記憶體元件 之程式化/抹除操作之效率。 雖然本發明已以一較佳實施例揭露如上,然其並非用 以限定本發明,任何熟習此技藝者,在不脫離本發明之精 神和歲圍内,當可作各種之更動與潤飾,因此本發明之保 護範31當視後附之申請專利範圍所界定者為準。9069twf.ptd Page 17 536791 V. Inventor (14) According to the embodiment of the present invention, the present invention forms a trench in a substrate, and then forms a source region in the substrate around the bottom of the trench. Next, a tunnel oxide layer, a floating gate, a gate dielectric layer, and a control gate are formed in the trench, and a drain region is formed in a substrate around the top of the trench. Then, the well area is used to connect the source area, and the area around the trench between the drain area and the well area is used as the channel area. Because the memory cells of the trench flash memory of the present invention have a columnar three-dimensional structure, that is, the tunneling oxide layer, the floating gate, and the gate dielectric layer surround the control gate, so the present invention and Compared with the conventional stacked gate type flash memory, the overlap function of the floating gate and the control gate can be increased, and the gate coupling rate of the floating gate and the control gate can be increased, which reduces the operation of the bamboo gate. The required operating voltage improves the speed and efficiency of component operation. Moreover, the channel area of the trench flash memory of the present invention is set in a substrate surrounding the outside of the Pan channel (vertical channel area), so the rhyme of the component set can be increased, and the depth of the channel can be controlled accurately by controlling the depth of the channel. Controlling the length of the channel can avoid problems caused when the component size is reduced. In addition, the columnar memory cell structure can increase the current density and improve the efficiency of the programming / erasing operation of the memory elements. Although the present invention has been disclosed as above with a preferred embodiment, it is not intended to limit the present invention. Any person skilled in the art can make various modifications and decorations without departing from the spirit and age of the present invention. The protection scope of the present invention 31 shall be determined by the scope of the attached patent application.

9069 twf. p t cl 第18頁 536791 圖式簡單說明 第1 A圖至第1 I圖所繪示為本發明溝渠式快閃記憶體元 件之製造流程剖面圖。 第2圖為繪示本發明之溝渠式快閃記憶體之電路簡 圖。 第3圖為繪示本發明之溝渠式快閃記憶體之上視圖。 第4圖所繪示為本發明之溝渠式快閃記憶體之結構剖 面圖。9069 twf. P t cl Page 18 536791 Brief description of drawings Figures 1A to 1I are cross-sectional views of the manufacturing process of the trench flash memory device of the present invention. FIG. 2 is a circuit diagram of a trench flash memory according to the present invention. FIG. 3 is a top view illustrating a trench flash memory according to the present invention. FIG. 4 is a cross-sectional view showing a structure of a trench flash memory according to the present invention.

9069t\\f .ptd 第19頁9069t \\ f .ptd Page 19

Claims (1)

536791 六、申請專利範圍 1 . 一種溝渠式快閃記憶體之製造方法,該方法包括 下列步驟: 揭:供一基底; 於該基底上形成圖案化之一罩幕層; 以圖案化之該罩幕層為罩幕,於該基底中形成一溝 渠; 於該溝渠底部周圍的該基底中形成一源極區; 於該溝渠中形成一穿隧氧化層; 於該溝渠中形成一第一導體層,該第一導體層之上表 面低於該基底表面; 於該第一導體層上形成共形之一閘極介電層; 於該基底上形成一第二導體層,該第二導體層填滿該 溝渠; 移除該溝渠以外之該第二導體層與該閘極介電層以暴 露圖案化之該罩幕層的表面; 移除圖案化之該罩幕層以暴露該基底之表面;以及 於該溝渠頂部周圍之該基底中形成一汲極區。 2 ·如申請專利範圍第1項所述之溝渠式快閃記憶體之 製造方法,其中於該溝渠底部周圍的該基底中形成該源極 區之步驟包括: 於該溝渠内形成共形之一摻雜絕緣層; 於該溝渠底部形成一第一光阻層,該第一光阻層並未 填滿該溝渠且暴露出部分該摻雜絕緣層; 移除未被該第一光阻層覆蓋之該摻雜絕緣層,留下位536791 VI. Scope of patent application 1. A method for manufacturing a trench flash memory, the method includes the following steps: exposing a substrate; forming a patterned mask layer on the substrate; and patterning the mask The curtain layer is a mask, which forms a trench in the substrate; a source region is formed in the substrate around the bottom of the trench; a tunneling oxide layer is formed in the trench; a first conductor layer is formed in the trench An upper surface of the first conductor layer is lower than the surface of the substrate; a conformal gate dielectric layer is formed on the first conductor layer; a second conductor layer is formed on the substrate, and the second conductor layer is filled Fill the trench; remove the second conductor layer and the gate dielectric layer outside the trench to expose the surface of the patterned mask layer; remove the patterned mask layer to expose the surface of the substrate; And forming a drain region in the substrate around the top of the trench. 2. The method of manufacturing a trench-type flash memory as described in item 1 of the scope of the patent application, wherein the step of forming the source region in the substrate around the bottom of the trench includes: forming one of the conformals in the trench A doped insulating layer; forming a first photoresist layer at the bottom of the trench, the first photoresist layer not filling the trench and exposing a portion of the doped insulating layer; removing the first photoresist layer The doped insulating layer, leaving a bit 9069twf.pt d 第20頁 536791 六、申請專利範圍 於該溝渠底部周圍之該摻雜絕緣層; 於該溝渠之側壁上形成一帽蓋層: 移除該第一光阻層; 進行一熱製程,使該摻雜絕緣層中的摻質擴散進入該 基底中而形成該源極區;以及 移除該溝渠底部的該摻雜絕緣層與該溝渠之側壁上之 該帽蓋層。 3 .如申請專利範圍第2項所述之溝渠式快閃記憶體之 製造方法,其中該摻雜絕緣層之材質包括摻雜砷離子之氧 化石夕。 4.如申請專利範圍第1項所述之溝渠式快閃記憶體之 製造方法,其中於該溝渠中形成一第一導體層,且該第一 導體層之上表面低於該基底表面之步驟包括: 於該溝渠内形成一第二光阻層,該第二光阻層並未填 滿該溝渠且暴露出部分該第一導體層; 移除未被該第二光阻層覆蓋之該第一導體層;以及 移除該第二光阻層。 5 .如申請專利範圍第1項所述之溝渠式快閃記憶體之 製造方法,其中於該溝渠底部周圍的該基底中形成該源極 區之步驟之後與於該溝渠中形成該穿隧氧化層之步驟之前 更包括進行一修補製程。 6 .如申請專利範圍第5項所述之溝渠式快閃記憶體之 製造方法,其中該修補製程包括: 進行一熱氧化製程,以在該溝渠的側壁與表面形成9069twf.pt d page 20 536791 6. The patent application scope is the doped insulating layer around the bottom of the trench; forming a capping layer on the sidewall of the trench: removing the first photoresist layer; performing a thermal process To diffuse the dopant in the doped insulating layer into the substrate to form the source region; and remove the doped insulating layer at the bottom of the trench and the cap layer on the sidewall of the trench. 3. The method for manufacturing a trench flash memory as described in item 2 of the scope of the patent application, wherein the material of the doped insulating layer includes arsenic ion-doped oxidized fossils. 4. The method for manufacturing a trench-type flash memory as described in item 1 of the scope of patent application, wherein the step of forming a first conductor layer in the trench and the upper surface of the first conductor layer is lower than the surface of the substrate The method includes: forming a second photoresist layer in the trench, the second photoresist layer not filling the trench and exposing part of the first conductor layer; removing the first photoresist layer not covered by the second photoresist layer; A conductive layer; and removing the second photoresist layer. 5. The method for manufacturing a trench type flash memory as described in item 1 of the scope of patent application, wherein the tunnel oxidation is formed in the trench after the step of forming the source region in the substrate around the bottom of the trench. Before the step of layering, a repair process is performed. 6. The method for manufacturing a trench-type flash memory as described in item 5 of the scope of the patent application, wherein the repair process includes: performing a thermal oxidation process to form a sidewall and a surface of the trench. 9069twl ptd 第21頁 536791 六、申請專利範圍 一襯氧化層;以及 移除該襯氧化層。 7 .如申請專利範圍第1項所述之溝渠式快閃記憶體之 製造方法,其中更包括: 汾該基底中形成與該源極區連接之一第一導電型第一 井區; 汾該第一導電型第一井區上形成一第二導電型第二井 區;以及 力^該基底中形成貫穿該第二導電型第二井區而與該第 一導電型第一井區連接之一第一導電型第三井區。 8 .如申請專利範圍第1項所述之溝渠式快閃記憶體之 製造方法,其中圖案化之該罩幕層與該基底間更包括一墊 氧化。 9 .如申請專利範圍第1項所述之溝渠式快閃記憶體之 製造方法,其中移除該罩幕層以暴露該基底之表面的步驟 之後與於該溝渠頂部之該基底中形成該汲極區的步驟之 前,更包括於該基底中形成一隔離結構,以定義出一主動 區。 10. —種溝渠式快閃記憶體,該溝渠式快閃記憶體包 括: 一基底,該基底中具有一溝渠; 一閘極結構,該閘極結構設置於該溝渠中,該閘極結 構在該溝渠中由外而内依序設置有一穿隨氧化層、一浮置 閘極、一閘極介電層與一控制閘極,且該穿隧氧化層、該9069twl ptd Page 21 536791 6. Scope of patent application: a liner oxide layer; and remove the liner oxide layer. 7. The method for manufacturing a ditch flash memory as described in item 1 of the scope of the patent application, further comprising: forming a first conductive type first well region in the substrate that is connected to the source region; A second conductivity type second well region is formed on the first conductivity type first well region; and a force is formed in the substrate to penetrate the second conductivity type second well region and connect to the first conductivity type first well region. A first conductivity type third well region. 8. The method for manufacturing a trench-type flash memory as described in item 1 of the scope of patent application, wherein the patterned mask layer and the substrate further include a pad oxidation. 9. The method for manufacturing a trench-type flash memory as described in item 1 of the patent application scope, wherein the step of removing the mask layer to expose the surface of the substrate is followed by forming the drain in the substrate on top of the trench. Before the step of polar region, it further includes forming an isolation structure in the substrate to define an active region. 10. A trench-type flash memory, the trench-type flash memory includes: a substrate having a trench in the substrate; a gate structure disposed in the trench, and the gate structure being A through oxide layer, a floating gate electrode, a gate dielectric layer and a control gate electrode are sequentially arranged in the trench from the outside to the inside. 9069 twf. p t cl 第22頁 536791 六、申請專·利範圍 浮置閘極與該閘極介電層環繞包覆著該控制閘極; 一源極區,該源極區設置於該溝渠底部周圍之該基底 中;以及 —;及極區’該 >及極區設置於該溝渠頂部周圍之該基底 中 〇 1 1 .如申請專利範圍第1 0項所述之溝渠式快閃記憶 體,其中更包括: ——第一導電型第一井區,該第一導電型第一井區設置 於該基底中並連接該源極區; ——第二導電型第二井區,該第二導電型第二井區設置 於該第一導電型第一井區上;以及 ——第一導電型第三井區,該第一導電型第三井區設置 於該基底中,並貫穿該第二導電型第二井區而與該第一導 電型苐一井區連接。 1 2.如申請專利範圍第1 1項所述之溝渠式快閃記憶 體,其中該第一導電型第一井區包括一深η型井區。 1 3.如申請專利範圍第1 1項所述之溝渠式快閃記憶 體,其中該第二導電型第二井區包括一ρ型井區。 1 4.如申請專利範圍第1 1項所述之溝渠式快閃記憶 體,其中該第一導電型第三井區包括一 η型井區。 1 5.如申請專利範圍第1 0項所述之溝渠式快閃記憶 體,其中該閘極介電層包括氧化矽/氮化矽/氧化矽層。 1 6.如申請專利範圍第1 0項所述之溝渠式快閃記憶 體,其中該浮置閘極之頂部低於該基底表面。9069 twf. Pt cl Page 22 536791 VI. Application for a patent-specific floating gate and the gate dielectric layer surround the control gate; a source region is located at the bottom of the trench In the surrounding substrate; and-; and the polar region 'the > and the polar region are disposed in the substrate around the top of the ditch. The channel-type flash memory described in item 10 of the scope of patent application , Which further includes:-a first conductive type first well region, the first conductive type first well region being disposed in the substrate and connected to the source region;-a second conductive type second well region, the first A second-conductivity-type second well region is disposed on the first-conductivity-type first well region; and-a first-conductivity-type third well region is disposed in the substrate and runs through the substrate The second well type of the second conductivity type is connected to the first well type of the first conductivity type. 1 2. The trench-type flash memory according to item 11 of the scope of patent application, wherein the first conductive type first well area includes a deep n-type well area. 1 3. The trench-type flash memory according to item 11 of the scope of patent application, wherein the second conductive type second well area includes a p-type well area. 14. The trench-type flash memory according to item 11 of the scope of patent application, wherein the first conductive type third well area includes an n-type well area. 1 5. The trench type flash memory according to item 10 of the patent application scope, wherein the gate dielectric layer includes a silicon oxide / silicon nitride / silicon oxide layer. 16. The trench type flash memory according to item 10 of the patent application scope, wherein the top of the floating gate is lower than the surface of the substrate. 9069twf . pt ci 第23頁 5367919069twf .pt ci p. 23 536791 90691 w f.p t d 第24頁90691 w f.p t d p.24
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