TW534981B - Apparatus and method for determining biological heat potential - Google Patents
Apparatus and method for determining biological heat potential Download PDFInfo
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- TW534981B TW534981B TW90110903A TW90110903A TW534981B TW 534981 B TW534981 B TW 534981B TW 90110903 A TW90110903 A TW 90110903A TW 90110903 A TW90110903 A TW 90110903A TW 534981 B TW534981 B TW 534981B
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534981 年月曰修正/更正/補充 A7 B7 0903-說明書E.doc-3/3 五、發明說明([) 【技術領域】 本發明係關於一種生物潛熱測定設備及方法,特 別是關於一種自發性高溫好氧處理(Autothermal534981 Revised / Corrected / Supplied A7 B7 0903-Instruction E.doc-3 / 3 V. Description of the invention ([) [Technical Field] The present invention relates to a biological latent heat measurement device and method, especially to a spontaneous 2. high temperature aerobic treatment
Aerobic Wastewater Treatment,以下簡稱為 ATAT) 系統所構成的生物潛熱測定設備及方法。 【先前技術】 高濃度廢水生物處理目前遭遇瓶頸在於高廢棄污 泥畺、低反應速率與低有機負荷,而自發性高溫好 氧處理適足以解決這些問題。自發性高溫好氧處理 10 系統(ATAT)操作於45 C以上高溫好氧條件,有別於 一般高溫厭氧之35 t或55 t。因此,根據vant iioff-Arrheruus定律,高溫條件能輕易提高反應速 率;而且,根據生物能量學觀點,高溫環境使能量 使用效率下降,促使生物反應過程中基質釋放能量 15 (請先閱讀背面之注意事項再填寫本頁) 走向維持細胞生存(maintenancehb例增加,走向細 胞合成(synthesis)減少,生長係數隨即變小,污泥 里可望減少,而此釋放能量即可提供反應槽的熱能 需求。 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 傳統上對於自發性高溫好氧處理系統(ATAT)的顧 2〇慮不外乎·一、高溫若不能由廢水分解反應自發產 ^,外加熱源成本相當高;二、高反應速率須輔以 n傳氧速率,然而高溫會降低氧氣在水中的溶解 度,、減緩傳氧速率。事實上經歐美地區多座高溫好 "亏泥 /肖化(aut〇thennal aerobic sludge 本紙張尺度適用中國iii^NS)A4規格(―x挪公爱 534981 年月日修正/更正/補充 0903-說明書E.doc - 4/4 五、發明説明(2 ) digestin’ ATAD)實廠成功經驗,ATAD已被美國環 保署(US EPA)列為成熟技術,而國内也有食品廢水 薇被證實為自發性高溫好氧處理系統(ATAT),因此 自發性高溫好氧處理系統(ATAT)可行性不容置疑, 當務之急在於建立成熟設備,以能精確測定此一生 物潛熱,據以提高自發性高溫好氧處理系統(ATAT) 可行性。 若以傳、、充貝驗至規模連績流訓化槽(ht) 進行自發性高溫好氧處理系統(ATAT)可行性研究可 月b 遇困難有:一、開放性系統可能造成大量蒸發 、熱損,不易評估反應產生熱值;二、以空氣曝氣可 能因傳氧速率小於基質降解需氧速率造成質傳限 制,若改以純氧曝氣則因屬開放系統而有氧氣爆炸 等安王顧慮,二、一般磁石攪拌效果有限亦容易造 成溶氧質傳限制;四、分析工作多利用〇卯與虬%分 析,分析方法耗時費力且精準性與再現性不佳。 【發明目的】 本發明所提供的生物潛熱測定設備為密閉系統, 且具有純氧曝氣、稀土(rare 磁石強力檀 2〇拌,以及可程式即時線上監控瞬間攝氧量等特性, 適足以克服上述困難。 本發明之目的即在於提供一種生物潛熱測定設 備,可以用來測量自發性高溫好氧處理系統(ΑΤΑΤ) 試驗的線上(on-line)攝氧數據(avs. 〇和補溫數 10 15 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公着) 83. 3.10,000 ^ J — (請先閲讀背面之注意事項再填寫本頁) • IWH ·κ - 534981 今次职日修正/更正/補充 A7Aerobic Wastewater Treatment (hereinafter referred to as ATAT) system is a biological latent heat measurement device and method. [Previous technology] The current bottlenecks in biological treatment of high-concentration wastewater are high waste sludge, low reaction rate, and low organic load, and spontaneous high-temperature aerobic treatment is adequate to solve these problems. Spontaneous high-temperature aerobic treatment 10 system (ATAT) operates at high-temperature aerobic conditions above 45 C, which is different from the 35 t or 55 t of ordinary high-temperature anaerobic conditions. Therefore, according to the vant iioff-Arrheruus law, high temperature conditions can easily increase the reaction rate; and from a bioenergetic point of view, the high temperature environment reduces the efficiency of energy use and promotes the matrix to release energy during the biological reaction 15 (Please read the precautions on the back first) Fill in this page again) Toward the maintenance of cell survival (increasing the number of cases of maintenanceh, to decrease the synthesis of cells, the growth factor will then decrease, and the sludge is expected to decrease, and this release of energy can provide the thermal energy requirements of the reaction tank. The Intellectual Property Bureau employee consumer cooperative prints traditionally concerns about the spontaneous high temperature aerobic treatment system (ATAT). First, if high temperature cannot be produced spontaneously by the decomposition reaction of wastewater ^, the cost of external heating sources is quite high; High reaction rate must be supplemented by n oxygen transfer rate. However, high temperature will reduce the solubility of oxygen in water and slow down the oxygen transfer rate. In fact, high temperatures in many places in Europe and the United States are good " authentic aerobic sludge This paper size is applicable to China iii ^ NS) A4 specification (―x Norway public love 534981 amendment / Correct / Supplement 0903-Instruction E.doc-4/4 5. Description of the invention (2) Digestin 'ATAD) Successful experience in the factory, ATAD has been listed as a mature technology by the US Environmental Protection Agency (US EPA), and domestic food Wastewater Wei has been confirmed as the spontaneous high-temperature aerobic treatment system (ATAT), so the feasibility of the spontaneous high-temperature aerobic treatment system (ATAT) is unquestionable. The urgent task is to establish mature equipment to accurately measure this biological latent heat, thereby improving the The feasibility of the spontaneous high-temperature aerobic treatment system (ATAT). The feasibility study of the spontaneous high-temperature aerobic treatment system (ATAT) can be carried out on a continuous basis with a continuous flow test tank (ht). The difficulties are: First, the open system may cause a large amount of evaporation and heat loss, and it is not easy to evaluate the heating value of the reaction; Second, the aeration with air may cause the mass transfer limitation due to the oxygen transfer rate being less than the matrix degradation oxygen demand rate. If it is changed to pure oxygen exposure Because gas is an open system, there are concerns about Anwang, such as the explosion of oxygen. Second, the limited magnet stirring effect can easily cause the limitation of dissolved oxygen and mass transfer. Fourth, the analysis work uses 卯 and 虬% analysis. The analysis method is time-consuming and laborious, and its accuracy and reproducibility are not good. [Objective of the Invention] The biological latent heat measurement device provided by the present invention is a closed system, and has pure oxygen aeration, rare earth (rare magnet strong sandalwood 20), and The program's real-time online monitoring of instant oxygen uptake and other characteristics are adequate to overcome the above difficulties. The object of the present invention is to provide a biological latent heat measurement device that can be used to measure the on-line (AT-AT) test of a spontaneous high-temperature aerobic treatment system (ΑΤΑΤ). line) Oxygen uptake data (avs. 〇 and temperature supplement number 10 15) This paper size applies Chinese National Standard (CNS) A4 specification (210X297) 83. 3.10,000 ^ J — (Please read the notes on the back before filling (This page) • IWH · κ-534981 Amendments / Corrections / Additional A7 to this working day
i--------— (請先閲讀背面之注意事項再填寫本頁) ^ n n · 訂 534981 年λ r修正八史土 /補.¾ δΐ. 9.-5 A7 - ---- B7__ 〇9〇3-說明書 E.doc 五、發明說明(4 ) :所、·且成’其特徵在於具有可程式即時線上監控大 里瞬間攝乳與補溫加熱數據等功能,可用於進行比 ^^•^(speclflc blologlc heat p〇tentlal> ^ M法與熱平衡分析’以瞭解生物反應熱力學特性 5與自發性高溫好氧處理系統(ATAT)可行性研究。本 發明也有關-種使用上述本發明生物潛熱測定設備 經由比生物潛熱⑻演算法與熱平衡分析測定生物潛 熱之方法。 【圖式簡單說明】 10 請參閱以下有關本發明一較佳實施例之詳細說明 及其附圖’將可進一步瞭解本發明之技術内容及其 目的功效,有關該實施例之附圖為: 圖1為本發明生物潛熱測定設備之主要系統示意 圖; 15i --------— (Please read the notes on the back before filling out this page) ^ nn · Order 534981 λ r correction eight historical soil / supplement. ¾ δΐ. 9.-5 A7----- B7__ 〇09〇3-Instruction Manual E.doc V. Description of the Invention (4): So, and it is characterized by programmable real-time online monitoring of instantaneous breastfeeding and heating data in Dali, and can be used for comparison ^ ^ • ^ (speclflc blologlc heat potentelal > ^ M method and thermal equilibrium analysis' to understand the thermodynamic characteristics of biological reactions 5 and the feasibility study of spontaneous high temperature aerobic treatment system (ATAT). The present invention is also related to-using the above-mentioned invention Method for determining biological latent heat by means of specific biological latent heat calculation algorithm and thermal equilibrium analysis. [Brief description of the drawings] 10 Please refer to the following detailed description of a preferred embodiment of the present invention and the accompanying drawings' for further understanding The technical content of the present invention and its effects are as follows. The drawings related to this embodiment are: FIG. 1 is a schematic diagram of the main system of the biological latent heat measuring device of the present invention; 15
圖2為培養作為提供所有自發性高溫好氧處理系 統UTAT)試驗士子氧性菌種植種來源所用的本發明自 行設計之馴化槽示意圖; X 圖3為本發明由自發性高溫好氧處理系統(ATAT) 所構成的生物潛熱測定設備示意圖; 20 θ圖4為使用本發明生物潛熱測定設備用葡萄糖測 得之攝氧曲線圖;以及 ^圖5為使用本發明生物潛熱測定設備用葡萄糖測 得之補溫曲線圖。 【主要部分代表符號】 本紙張尺度適用中國國冢標準(CNS)A4規格⑵〇 χ 297公髮) 534981 A7 B7 0903-說明書E.doc - 7/7 經濟部智慧財產局員工消費合作社印製 五、發明說明(ξ 10 11 12 13a 13b 14 15 16 17 18 19 20 21 22 23 24 25 30 31 32 33 34 35 39 馴化槽 反應瓶 供氧單元 外界溫度控制器 補溫溫度控制器 生物潛熱計算單元 補溫比計算單元 空氣泵 曝氣石 溫度測棒 加熱棒 加重型稀土磁石 磁力攪拌器 冷凝回流管 基質玻璃瓶 營養鹽玻璃瓶 螺動泵 反應瓶 氧氣監測器 控制閥 供氧源 二氧化碳吸收瓶 氣體循環泵 溫度測棒 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 534981 年月日修正/更正/補充FIG. 2 is a schematic diagram of the domestication tank designed by the present invention used as a source for the cultivation of aerobic bacteria for providing all spontaneous high-temperature aerobic treatment systems (UTAT); X FIG. 3 is a spontaneous high-temperature aerobic treatment system of the present invention (ATAT) Schematic diagram of biological latent heat measurement equipment; 20 θ Figure 4 is an oxygen uptake curve measured with glucose using the biological latent heat measurement equipment of the present invention; and Figure 5 is a glucose measurement using the biological latent heat measurement equipment of the present invention The temperature compensation curve. [Representative Symbols of Main Parts] This paper size is applicable to China National Tomb Standard (CNS) A4 Specification ⑵〇χ 297 issued 534981 A7 B7 0903-Instruction Manual E.doc-7/7 Description of the invention (ξ 10 11 12 13a 13b 14 15 16 17 18 19 20 21 22 23 24 25 30 31 32 33 34 35 39 domestic tank reaction bottle oxygen supply unit external temperature controller temperature compensation temperature controller biological latent heat calculation unit supplement Temperature ratio calculation unit air pump aeration stone temperature measuring rod heating rod heavy duty rare earth magnet magnetic stirrer condensate return tube substrate glass bottle nutrient glass bottle screw pump reaction bottle oxygen monitor control valve oxygen source carbon dioxide absorption bottle gas circulation pump Temperature probe (please read the precautions on the back before filling this page) This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 534981 Correction / Correction / Supplement
五、發明說明(b) 經濟部智慧財產局員工消費合作社印製 4 0加熱棒 41加重型稀土磁石 42磁力攪拌器 4 3訊號數據監控處理系統 44熱損加熱溫控系統 【較佳實施例】 明參閱圖一 ’本發明所提供之生物潛熱測定設 備,主要係使用一馴化槽1 〇培養好氧性菌種,並將 囷種植入一反應瓶丨丨中,藉以實現期望的生物反 5應,使用一外界溫度控制器丨3a可控制及加熱該反應 瓶11外界至一设定溫度值,可控制該反應瓶丨丨外壁 高溫’減少反應瓶U内外壁溫差,以降低反應㈣ 在進行生物反應時之熱損失;藉由一供氧單元12提 供及紀錄反應瓶所需的攝氧量,供氧單元12所輸出 的數據為-即時攝氧數據(avs·並由一補溫溫 度控制器1 3b控制及加熱反應瓶丨2内部至一設定溫度 值,同時紀錄輸出一即時補溫數據(/人vs. 〇,上述 攝氧數據及補溫數據由一生物潛熱計算單元Η計筲 出生物潛熱和熱損通量(Λ),最後由一補溫°比; 算單元15計算出即時補溫比(Γ),同時求得操作期 内的最小補溫比(仏),藉以評估自發性高溫〆 理系統的反應自發性。 ^ I生物潛熱演算 比生物潛熱h乃指一生物反應攝取單位氧氣質量 -8 - 本紙張尺度適用中國國家標準(CNS)A4規格(21G x 297公^ 10 15 Γ— — — — — — — — — — - I I I I (請先閱讀背面之注意事項再填寫本頁) ---訂--------- 534981 0903-說明書E.doc - 9/9 五、發明說明(Μ ) 戶_之熱量,單位仟卡/克氧(κ_剩,為自 發性咼溫好氧處理系統(ATAT)可行性之重要指標, 配合自發性高溫好氧處理系統(A T A T )熱平衡分析可 以瞭解自發性高溫好氧處理系統(ATAT)如何產生自 5务性同/皿。對自發性高溫好氧處理系統而 °利用補μ與熱損加熱溫控系統將反應瓶内外分 別控制在兩不同值溫下,當系統達穩態(steady state’ 刼作時,其熱平衡分析可考量反應 員(reaction)、熱損項(i〇ss)與補溫項 10 (compensation)表示成 hbi j0 dHc 〇— di - + dt reaction L0SS compensation (1) 15 其中九為比生物潛熱,單位仟卡/克氧;α為累 積攝氧1,單位g ;人為熱損通量,單位仟卡/分 (Kcal/mm);凡為累積補溫加熱量,單位仟卡 (Kcal)。將式(1)以初始條件··當卜〇,^―—〇且 价二〇,代入積分可得V. Description of the invention (b) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 40 heating rods 41 heavy-duty rare earth magnets 42 magnetic stirrers 4 3 signal data monitoring and processing systems 44 heat loss heating temperature control systems [preferred embodiments] Refer to FIG. 1 for details. The biological latent heat measurement device provided by the present invention mainly uses an acclimation tank 10 to cultivate aerobic bacteria, and plant 囷 into a reaction flask 丨 丨 to achieve the desired biological reaction. Therefore, an external temperature controller 3a can be used to control and heat the outside of the reaction bottle 11 to a set temperature value, which can control the reaction bottle 丨 丨 high temperature of the outer wall 'reduce the temperature difference between the inner and outer walls of the reaction bottle U to reduce the reaction. Heat loss during biological reaction; the oxygen uptake required by the reaction bottle is provided and recorded by an oxygen supply unit 12, and the data output by the oxygen supply unit 12 is-real-time oxygen uptake data (avs · and controlled by a supplemental temperature) The controller 1 3b controls and heats the reaction bottle 丨 2 to a set temperature value, and records and outputs an instant temperature supplement data (/ person vs. 〇, the above oxygen uptake data and temperature supplement data are provided by a biological latent heat calculation unit) The biological latent heat and heat loss flux (Λ) are extracted, and finally a temperature-added ° ratio is calculated; the calculation unit 15 calculates the instant temperature-added temperature ratio (Γ), and at the same time, the minimum temperature-added ratio (仏) during the operation period is obtained, thereby Assess the spontaneity of the response of the spontaneous high-temperature thermal management system. ^ I Latent heat calculation ratio Latent heat h refers to a unit of biological reaction uptake of oxygen mass -8-This paper size applies to China National Standard (CNS) A4 (21G x 297 mm) ^ 10 15 Γ — — — — — — — — — — — IIII (Please read the notes on the back before filling out this page) --- Order --------- 534981 0903-Instruction E.doc- 9/9 V. Description of the invention (M) Household heat, unit 户 cal / gram of oxygen (κ_ remaining, is an important indicator of the feasibility of spontaneous high temperature aerobic treatment system (ATAT), combined with spontaneous high temperature aerobic The thermal balance analysis of the processing system (ATAT) can understand how the spontaneous high-temperature aerobic processing system (ATAT) generates self-contained services. For the spontaneous high-temperature aerobic processing system, the use of supplementary μ and heat loss heating temperature control system will The inside and outside of the reaction flask are controlled at two different temperature values. When the system reaches a steady state (ste ady state 'operation, the thermal equilibrium analysis can consider the reaction, heat loss (i0ss) and temperature compensation term 10 (compensation) expressed as hbi j0 dHc 〇-di-+ dt reaction L0SS compensation (1 ) 15 Among them, nine are specific latent heat, in units of calories / gram of oxygen; α is cumulative oxygen uptake 1, in units of g; man-made heat loss flux, in units of calories / minute (Kcal / mm); , Unit Kcal. By using formula (1) under the initial conditions: · When 〇, ^--0 and valence 20, substituting points can be obtained
Hc 二 Jj-h〇u (2) 經濟部智慧財產局員工消費合作社印製 20 利用自發性高溫好氧處理系統(ATAT)可以獲得大 量攝氧數據(仏vs. 〇與補溫數據(丛vs· 〇,運用 於式(2)配合複迴歸(muitiple Hnear 最小平方法(least SqUare meth〇d)可用以求取熱損 通里(Λ)與比生物潛熱(h)之實驗估計值。對於—段 試驗期間,可依下式定出補溫比(厂)·· 又 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公釐 534981 年月 日修正/更正/補充Hc II Jj-h〇u (2) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 20 Using the spontaneous high temperature aerobic treatment system (ATAT) to obtain a large amount of oxygen uptake data (仏 vs. 〇 and temperature supplement data (bundle vs. · 〇, applied to formula (2) and complex regression (muitiple Hnear least square method (least SqUare meth〇d) can be used to obtain the experimental value of heat loss Tongli (Λ) and specific biological latent heat (h). For- During the test period, the temperature compensation ratio (factory) can be determined according to the following formula: The paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm 534981)
五 ◦903-說明書 E.doc- 10/10 經 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 發明說明(公) r 二 HJ J〇t (3) Γ值的大小指示出自發性高溫好氧處理系統(ATAT) 的反應自發性(react i〇n sp〇ntanei )。尸愈小,用 貫驗規模自發性高溫好氧處理系統(ATAT)系統所能 達到的反應自發性愈大。 南溫剔化培卷 本發明自行設計高溫馴化槽以培養好氧性菌種, 其裝置如圖2所示,特點包括:在10升反應瓶11中可 操作容積達9升,靠空氣泵16打入空氣經瓶底之曝氣 石Π曝氣以維持溶氧丄―2毫克/升;依溫度測棒18測 值可以比例積分微分(PID)補溫溫度控制器13b連動 加熱棒19以維持高溫55°C,精確度〇· pc ;反應瓶u 底置一加重型稀土磁石20以磁力攪拌器2丨強力攪拌 以維持反應瓶Π内溶氧與溫度均勻分布;為避免大 里拎刀洛舍,反應瓶11頂部連接一冷凝回流管2 2 ; 基質與營養鹽為避免酸敗分置兩4升玻璃瓶23、24 中,利用蠕動泵2 5依設定流速同時連續進流到反應 瓶11中,並罪反應瓶11出流口維持液面高度以控制 污泥齡(SRT)。 20 實施 _化培養 高溫馴化培養操作先自北部某食品油脂自發性高 溫好氧處理系統(ATAT)實廠之高溫好氧曝氣池取回 10公升菌種植入反應瓶中,再以1〇g/L c〇D葡萄糖人 -10 - 10 15 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公釐) (請先閱讀背面之注意事項再填寫本頁) 年 0903-說明書E.doc · 11/11 經濟部智慧財產局員工消費合作社印製 五、發明說明(^ ) 二二樣控制SRT二10天進流,定期由出流水取樣分析 、PH與MLSS,並觀察污泥沈降性、顏色、泡珠與 頸微鏡菌相,以監控馴化情形。 本發明須以高溫剛化培養經由常態性操作以提供 5 ::有:發性高溫好氧處理系統(ATAT)試驗植種來 '紅作至所有自發性高溫好氧處理系統(ATAT)試 驗完成為止。 自發性高溫好氧處理系統(Α τ A τ)試驗為本發明之 10核心實驗’所使用設備如圖3所示,乃由反應瓶組 純乳供氣系統、補溫加熱溫控系統、熱損加熱溫控 :統、磁力齡Ή,與訊號數據監控處理系統等 六大部分所組成,具有可程式即時線上監控大量瞬 間攝氧與補溫加熱數據等功能,可用於進行比生物 ’曰熱’ ^ m與熱平衡分析,以㈣生物反應執 力學特性與自發性高溫好氧處理系統(A τ A τ)可行性 研究。 曰其中,純氧供氣系統可設定反應瓶30頂空間氧含 里’根據乳氣監測器31測量值,以電腦程式依開/關 控制方式連動控制閥32由供氧源33供氧,控制閥32 每開〃人可疋里供氧,電腦程式紀錄累積開放次數 可換算成攝氧量,氧化所產生二氧化碳由一吸收瓶 34中之強鹼溶液所吸收,另外尚裝有_氣體循環系 35以利反應瓶30頂部空間與純氧供氣系統連通管線 -11 15 20Five 903-Instruction E.doc- 10/10 Description of invention printed by the Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs (public) r Two HJ J〇t (3) The value of Γ indicates the spontaneous high temperature aerobic treatment system ( ATAT) reacts spontaneously (react inon spontanei). The smaller the corpse, the greater the spontaneous response that can be achieved with the autonomic scale autonomic aerobic treatment system (ATAT) system. South temperature picking culture roll The present invention designs a high-temperature domestication tank to cultivate aerobic bacteria by itself. The device is shown in FIG. 2. The features include: an operating volume of 9 liters in a 10 liter reaction bottle 11, and an air pump 16 Inject the air through the aeration stone Π at the bottom of the bottle to maintain dissolved oxygen 丄 2 mg / L; according to the measured value of the temperature probe 18, the proportional integral derivative (PID) temperature supplementary temperature controller 13b can be connected to the heating rod 19 to maintain High temperature 55 ° C, accuracy 0 · pc; reaction bottle u is equipped with a heavy-duty rare earth magnet 20 at the bottom and magnetic stirrer 2 丨 strong stirring to maintain uniform distribution of dissolved oxygen and temperature in the reaction bottle Π; A reaction reflux tube 2 2 is connected to the top of the reaction bottle 11; the substrate and nutrients are separated into two 4 liter glass bottles 23 and 24 to avoid rancidity, and the peristaltic pump 25 is continuously fed into the reaction bottle 11 at a set flow rate at the same time. The outflow port of the reaction bottle 11 maintains the liquid level to control the sludge age (SRT). 20 Implementation _ High-temperature domesticated cultivation operation of chemical culture First, 10 liters of bacteria were recovered from the high-temperature aerobic aeration tank of a spontaneous high-temperature aerobic treatment system (ATAT) plant in a northern food oil planted in a reaction bottle, and then 10 g / L c〇D glucose person -10-10 15 This paper size is applicable to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling this page) Year 0903-Manual E .doc · 11/11 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the Invention (^) Two or two samples are controlled for SRT inflow for 20 days, and the outflow water is sampled and analyzed regularly, pH and MLSS, and the sludge sedimentation is observed Sex, color, vesicles, and microscopic mirror of the neck to monitor domestication. The present invention is required to provide high temperature rigidified culture through normal operation to provide 5 :: Yes: hairy high temperature aerobic treatment system (ATAT) test seed to 'red crop' until all spontaneous high temperature aerobic treatment system (ATAT) test is completed until. The spontaneous high-temperature aerobic treatment system (Α τ A τ) test is the 10 core experiments of the present invention. The equipment used is shown in Figure 3, which consists of the pure milk gas supply system of the reaction bottle group, the heating and temperature control system, Loss heating temperature control: composed of six major parts: system, magnetic age, and signal data monitoring and processing system. It has programmable real-time online monitoring of a large number of instantaneous oxygen uptake and temperature supplement heating data. It can be used to perform biological heating ^ m and thermal equilibrium analysis, the feasibility study of the biological reaction performance and spontaneous high temperature aerobic treatment system (A τ A τ). Among them, the pure oxygen gas supply system can set the oxygen content in the top space of the reaction bottle 30. According to the measured value of the milk gas monitor 31, the control valve 32 is linked to the oxygen supply source 33 by the computer program according to the on / off control mode. Valve 32 can supply oxygen for every person who opens. The computer program records the cumulative number of openings and can be converted into oxygen uptake. The carbon dioxide produced by the oxidation is absorbed by the strong alkaline solution in an absorption bottle 34. In addition, a gas circulation system is also installed. 35 Eli reaction bottle 30 head space and pure oxygen gas supply system communication line -11 15 20
-------------會 (請先閱讀背面之注意事項再填寫本頁) --------坏----- i 拳. 本紙張尺度適用中國國家標準(CNS)A4^T(21〇 x 297公釐) 534981------------- Yes (Please read the notes on the back before filling this page) -------- Bad ----- i Boxing. This paper size applies to China Standard (CNS) A4 ^ T (21 × x 297 mm) 534981
經濟部智慧財產局員工消費合作社印製 五、發明說明((υ) 中氣體,使之均勾分布;補溫加熱溫控系統可設定 ,内的'服度,依溫度測棒3 9測值以開/關控制 方式連動加熱棒40以一固定功率補溫,紀錄加熱棒 侧啟累積時^卩可換算補溫加熱量;反應瓶加底 置加重型稀土磁石41可以磁力攪拌器42強力驅動 攪拌’不易脫速,轉速可調整;訊號數據監控處理 系統43是利用界面控制商業軟體撰寫之程式,可以 線上即時監控攪拌轉速、溫度、累積攝氧量、累積 補皿加熱里等數據,並可繪製成線上即時動態圖; 熱損加熱溫控系統44依反應瓶3〇外壁所置溫度測棒 1溫度測值’用以連動—加熱線圈,並經—風扇循 衰氣机’可控制反應瓶3 〇外壁高溫,減少反應瓶如 内外壁溫差,以降低反應瓶30熱損失。 進行自發性高溫好氧處理系統(ΑΤΑΤ)試驗時,先 自高溫馴化槽植種至反應瓶30中,採半連續進流操 作,每日以針筒依所控制之SRT換算抽取定量污泥廢 棄,隨即添加等體積葡萄糖人工水樣,待每日累積 攝氧趨勢達穩定再現,即可終止該批試驗。 舞果與討論 圖4和5分別顯示出队和从曲線。可以看出仏曲線 逐曰變異。而/人曲線則在一天的試驗期間内較具有可 重複性。仏和从數據都是用方程式(3)以複線性迴歸 法進行分析而估計出生物潛熱(/7,)和熱損通量(heat loss flux) ( Λ)供比較所用。迴歸結果顯示出仏的 -12 - 10 15 20 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) _裝i丨丨丨丨丨丨訂·--------- 534981 年月日修正/更正/補充 A7 B7 五、發明説明(丨() 值,除了第3-6天之外,通常係在3· 82 —4· 53仟卡/克 (請先閱讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description ((υ) The gas is distributed uniformly; the temperature control system of the supplementary heating can be set, and the internal temperature is determined by the temperature measuring rod 3 9 The on / off control mode is used to connect the heating rod 40 to supplement the temperature with a fixed power, and record the accumulated heating time when the heating rod is turned on side. ^ 卩 can be used to convert the temperature to supplement the heating amount. Stirring 'is not easy to take off speed, and the speed can be adjusted; the signal data monitoring and processing system 43 is a program written using interface control business software, which can monitor real-time data such as stirring speed, temperature, accumulated oxygen uptake, accumulated dish heating, etc. Draw into a real-time dynamic graph online; Heat loss heating temperature control system 44 According to the temperature measurement rod 1 placed on the outer wall of the reaction bottle 30, the temperature measurement value 'is used to link the-heating coil, and via the fan through the attenuator' to control the reaction bottle 〇 The temperature of the outer wall is high, and the temperature difference between the inner and outer walls of the reaction bottle is reduced to reduce the heat loss of the reaction bottle 30. When performing the spontaneous high-temperature aerobic treatment system (ATAT) test, first adjust the tank from high temperature. Seeded in the reaction bottle 30, semi-continuous inflow operation is adopted, and the quantitative sludge is extracted by the syringe according to the controlled SRT daily. Then, an equal volume of glucose artificial water sample is added, and the daily cumulative oxygen uptake trend reaches a stable reproduction. The batch of experiments can be terminated. Figures 4 and 5 show the team and the curves respectively. You can see that the 仏 curve varies from day to day. The / person curve is more repeatable during the one-day test period.仏 and the data are both analyzed by equation (3) using complex linear regression method to estimate the biological latent heat (/ 7,) and heat loss flux (Λ) for comparison. The regression results show that 仏-12-10 15 20 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page) _ 装 i 丨 丨 丨 丨 丨 丨 Order · --------- 534981 month / day correction / correction / addition A7 B7 V. Description of the invention (丨) Values, except for the 3rd to 6th days, are usually 3.82-4.53. Cards / gram (please read the notes on the back before filling this page)
BpDr範圍之内。對於所有8個試驗天所得〇·92 —〇·95之 R值顯不出完美的線性,甚至第3 —6天亦然。^在第 3-6天發生較大變異的原因仍有待研究。根據推斷其 5可能是該嗜熱性微生物系統與試驗條件下的不完全 馴化相關聯的動態本質所致。因為^在第7 — 8天自動 地回歸到基線值(第卜3天)之故,所以不可能是自發 性高溫好氧處理系統(ATAT)測定系統的設備問題所 致。 10 迴歸結果亦顯示出熱損速率(Λ)係在0.43-0 55 仟分的相當窄範圍内變異。當系統在第5-6天經 歷較低的生物熱釋放時該熱損即減少約丨〇%。 使用h的平均值(4. 28仟卡/克认)和平均埶 量值(柳.5〇仔卡/分),可以定出方程式3所定義的 15補溫比,其在24小時試驗期間的第12小時達到89 2% ^1. 之最低值。 ’ 【特點及功效】 20 本發明所提供之生物潛熱測定設備可以用來測量 自發性高溫好氧處理系統(ΑΤΑΤ)試驗的線上(⑽—Within BpDr. For all 8 test days, the R values of 0.92 to 0.95 did not show perfect linearity, even on the 3rd to 6th days. ^ The reason for the large variation on days 3-6 remains to be studied. It is inferred that it may be due to the dynamic nature of the thermophilic microbial system associated with incomplete domestication under test conditions. Because ^ automatically returns to the baseline value on the 7th to 8th day (Day 3), it is unlikely to be caused by equipment problems of the spontaneous high-temperature aerobic treatment system (ATAT) measurement system. The regression results also show that the heat loss rate (Λ) varies within a relatively narrow range of 0.43-0 55 仟. When the system experienced a lower biological heat release on days 5-6, the heat loss was reduced by about 0%. Using the average value of h (4.28 kcal / gram recognition) and the average krypton volume value (willow. 50 kcal / minute), the 15 supplement temperature ratio defined by Equation 3 can be determined, which is during the 24-hour test period At the 12th hour, the lowest value was 89 2% ^ 1. ’[Features and effects] 20 The biological latent heat measurement device provided by the present invention can be used to measure the on-line (⑽—
Une)攝氧數據认和補溫數據几。本發明也提出一種 生物潛熱測定方法,其包括使 寻 使線性迴歸法從熱 十衡換型可以測定出自 ^ ^ 出目《性问·好軋處理系統(ATAT) 尤驗的生物潛熱⑹和熱損通量(人)。 明系統為一種有用的自發…且貫本务 J曰I f生间/皿好虱處理系統(atat) ____ - 13 - 本纸張尺度適用中國國家標準(CNS) M規格 534981 A7 B7 五、發明説明([Zj 0003 侧書 10 研究工具。當系統以丨〇克c〇D/公升進流葡萄糖和操 作在10天的污泥齡(SRT)時,測定出^為428仟卡/克 B〇Dr。該自發性高溫好氧處理系統(ATAT)系統的熱損 通里經測疋為〇 · 5 〇仟卡/分,且其補溫比(厂)為 89·2°/〇。 上列詳細說明係針對本發明之一可行實施例之具 體說明,惟該實施例並非用以限制本發明之專利範 圍,凡未脫離本發明技術精神所為之等效實施或變 更’均應包含於本案之專利範圍中。 综上所述,本案不但在技術思想上確屬創新,並 能較習用物品增進上述多項功效,應已充分符合新 賴性及進步性之法定發明專利要件,麦依法提出申 請’懇請t局核准本件發明專财請案,以勵發 明,至感德便。 (請先閲讀背面之注意事項再填寫本頁) —. -訂 經濟部智慧財產局員工消費合作社印製 用 適 度 尺 張 紙 本Une) There are several oxygen uptake data and temperature data. The present invention also proposes a method for measuring biological latent heat, which includes the use of a seeker linear regression method to determine the biological latent heat and heat from the heat-stable balance change. Loss flux (person). Ming system is a kind of useful spontaneous ... and the implementation of this service J f I / 好 good lice treatment system (atat) ____-13-This paper size applies Chinese National Standard (CNS) M specifications 534981 A7 B7 V. Invention Explanation ([Zj 0003 Side Book 10 Research Tool. When the system is infused with glucose at 0 g / liter and the sludge age (SRT) is operated at 10 days, it is determined to be 428 kcal / g B. Dr. The thermal loss of this spontaneous high temperature aerobic treatment system (ATAT) system has been measured to be 0.50 kcal / min, and its temperature compensation ratio (factory) is 89 · 2 ° / 〇. The detailed description is a specific description of a feasible embodiment of the present invention, but this embodiment is not intended to limit the patent scope of the present invention. Any equivalent implementation or change that does not depart from the technical spirit of the present invention should be included in this case. In summary, the case is not only technically innovative, but also enhances the above-mentioned multiple effects over conventional items. It should have fully complied with the new and progressive statutory invention patent requirements, and Mai applied for it according to law. ' I urge the Bureau to approve this patent application for invention. Inventions, to a sense of ethics will be (Please read the notes on the back of this page to fill out) - - Order Ministry of Economic Affairs Intellectual Property Office employees consumer cooperatives printed with moderately-foot sheets of paper
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