TW519682B - Method of preventing peeling of shallow trench isolation layer on wafer - Google Patents

Method of preventing peeling of shallow trench isolation layer on wafer Download PDF

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Publication number
TW519682B
TW519682B TW90132254A TW90132254A TW519682B TW 519682 B TW519682 B TW 519682B TW 90132254 A TW90132254 A TW 90132254A TW 90132254 A TW90132254 A TW 90132254A TW 519682 B TW519682 B TW 519682B
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Taiwan
Prior art keywords
wafer
shallow trench
trench isolation
isolation layer
high temperature
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TW90132254A
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Chinese (zh)
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Ching-Shan Lu
Kuo-Bin Huang
Jih-Churng Twu
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Taiwan Semiconductor Mfg
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Publication of TW519682B publication Critical patent/TW519682B/en

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Abstract

This invention provides a method of preventing peeling of a shallow trench isolation layer on a wafer suitable to be used for a high temperature furnace. The high temperature furnace has a wafer cassette, with a plural number of positions, installed to carry wafers. The method comprises the following steps: loading at least one monitor wafer into at least the first position of the wafer cassette; loading at least one wafer into the second position of the wafer cassette, in which there is a shallow trench isolation structure on the wafer and the deposited layer on the back side of the monitor wafer is the same as that of the wafer; performing a high temperature treatment on the wafer cassette carrying the monitor wafer and the wafer in the high temperature furnace.

Description

519682 五、發明說明(l) 發明領域 本發明係有關於晶圓之淺溝隔離結構,特別 種避免晶圓外緣的淺溝隔離層剝離的方法。 f於一 發明背景 隨著半導體積體電路製造技術的發展,元件的 因積集度的提昇而不斷地縮小。元件尺寸雖然縮小,2, 片中各個元件間仍必須做適當地絕緣或隔離,方可得3晶 好的70件性質。這方面的技術一般稱為元件隔離技彳=s良 (device isolation technology),其主要目的係在各元 件之間形成隔離物,並且在確保良好隔離效果的情況下, 儘量縮小隔離物的區域,以空出更多的晶片面積來容納更 多的元件。 在各種元件隔離技術中,目前淺溝隔離區(shal low tfeneh isolation)製程因具有隔離區域小和完成後仍保 持基底平坦性等優點,更是近來頗受重視的半導體製造技 術。 一般淺溝隔離區的製造方法,乃在半導體基底的特定 區域形成淺溝槽(s h a 1 1 0 w t r e n c h ),接著填入絕緣材料 (insulator),如氧化層,於此淺溝槽中以形成淺溝槽隔 離區的技術’已廣泛地被使用於半導體積體電路的製程 中。並且’此淺溝槽隔離物也已成功地用來隔絕半導體元 件。 然而在實際製程中發現,晶圓在高溫爐管進行處理後 ’晶圓外緣區域的淺溝隔離層氧化物產生剝落的問題。參519682 V. Description of the Invention (l) Field of the Invention The present invention relates to a shallow trench isolation structure for a wafer, and in particular, a method for avoiding peeling of the shallow trench isolation layer on the outer edge of a wafer. f. Background of the Invention With the development of semiconductor integrated circuit manufacturing technology, components have been continuously reduced due to the increase in the degree of accumulation. Although the size of the components is reduced, each component in the chip must still be properly insulated or isolated to obtain the good properties of 70 crystals. This technology is generally called device isolation technology. Its main purpose is to form spacers between components, and to minimize the area of the spacers while ensuring good isolation. Free up more chip area to accommodate more components. Among various component isolation technologies, the current shallow low tfeneh isolation process is a semiconductor manufacturing technology that has received much attention recently because of its advantages such as small isolation area and maintaining flatness of the substrate after completion. Generally, the manufacturing method of a shallow trench isolation region is to form a shallow trench (sha 1 1 0 wtrench) in a specific region of a semiconductor substrate, and then fill an insulating material (such as an oxide layer) in the shallow trench to form a shallow trench. The technology of trench isolation regions has been widely used in the fabrication of semiconductor integrated circuits. And 'this shallow trench spacer has also been successfully used to isolate semiconductor elements. However, in the actual manufacturing process, it was found that after the wafer is processed in the high-temperature furnace tube, the problem of spalling of the oxide in the shallow trench isolation layer in the outer edge region of the wafer occurs. Participate

0503-7159TWf ; TSMC200M002 ; Peggy.ptd 第4頁 :)丄0503-7159TWf; TSMC200M002; Peggy.ptd Page 4 :) 丄

落。“域14的淺溝隔離結構常常有氧化物層的剝 淺溝隔 好發於 直式爐 中,設 合自動 時,通 代一般 是未塗 操作之 這種 後發現其 通常採垂 石英爐管 而為了配 裝載晶圓 wafer)取 致,通常 機械手臂 設定之用 ,π構的氧化物層剝落,經過不斷的檢測 Ϊ圓經高溫爐管處理之後。目前高溫爐管 官設計(vertical type)。在垂直式高溫 置有垂直式反應的晶舟以承載多片晶圓。 $製程或自動機械手臂的操作,在晶舟中 f在固定的位置以檢控#(m〇nit〇rdrop. "The shallow trench isolation structure of the domain 14 often has an oxide layer. The shallow trench separation is easy to occur in a vertical furnace. When it is set up automatically, it is generally uncoated and it is found that it usually adopts vertical quartz furnace tubes. For the purpose of loading wafer wafers, it is usually set by a robotic arm, and the π-structure oxide layer is peeled off. After continuous inspection, the roundness is processed by the high temperature furnace tube. At present, the high temperature furnace tube official design (vertical type). A vertical boat with vertical reaction is placed at vertical high temperature to carry multiple wafers. $ Process or the operation of an automatic robotic arm, at a fixed position in the boat to detect # (m〇nit〇r

晶圓。此類檢控片的大小與同批晶圓一 佈任何鍍膜材料的裸晶圓,僅用做自動化 參考點或標定點,或者自動化製程測試或 ,仏控片下方的晶圓邊緣的淺溝隔離層的剝離,通常 跟f管中晶圓表面的溫度梯度(temperature gradient)以 及,體/;IL動情形(gas flow pattern)有關。在檢控片下方 $晶圓’往往由於微環境與其他晶圓與晶圓的不同,導致 寿双控片下方的晶圓容易在的回火(anneaHng)溫度 下被其中通入的氮氣氮化(nitridize),進而導致淺溝Wafer. The size of this type of control wafer is the same as that of a bare wafer with any coating material on the same batch of wafers. It is only used as an automatic reference point or calibration point, or an automated process test. The peeling is usually related to the temperature gradient of the wafer surface in the f-tube and the gas flow pattern. The wafer under the prosecution wafer is often different from other wafers and wafers, which causes the wafer under the Shou Shuanghuan wafer to be easily nitrided by the nitrogen gas passing through it (anneaHng) temperature ( nitridize)

隔離層的剝離。造成同一批晶圓中,在檢控片下的晶圓良 率偏低。 發明簡述 為了解決上述晶圓外緣產生淺溝隔離層的脫落問題, 本發明的一個目的在於提供一種避免淺溝隔離層剝離之方Peeling of the isolation layer. As a result, in the same batch of wafers, the wafer yield under the prosecution wafer is low. Brief Description of the Invention In order to solve the problem of peeling off the shallow trench isolation layer on the outer edge of the wafer, an object of the present invention is to provide a method for avoiding the peeling of the shallow trench isolation layer.

0503-7159TWf ; TSMC200M002 ; Peggy.ptd 第5頁 519682 五、發明說明(3) 一 法,適用於咼溫爐官,可防止在經過高溫爐管處理後,晶 圓邊緣產生淺溝隔離層剝離的問題。 根據本电明之種避免晶圓淺溝隔離層剝離之方法, 適用於一咼溫爐官,該尚溫爐管中設置一具有複數位置用 以承載晶圓之晶舟,係包含下列步驟:在該晶舟中之至少 一第一位置載入至少一檢控片;在該晶舟中之至少第二位 置載入至少一晶圓,其中,該晶圓上具有淺溝隔離結構, 且该控片之背面鍍層與該晶圓之背面鍍層相同;將承載該 檢控片與該晶圓之該晶舟在該高溫爐管中進行一高溫處 理。 在上述方法中,該控片可採用晶圓裸片,其背面鍍層 與該晶圓之背面鍍層可以為氮化矽(s丨N )鍍層。而上述晶 舟可以垂直方式設置於該高溫爐管中。 為了讓本發明之上述目的、特徵、及優點能更明顯易 懂,以下配合所附圖式,作詳細說明如下: 圖式簡單說明 第1圖所示為習知晶圓淺溝隔離層剝離之好發區域示 意圖。 第2.A與2B圖所示為垂直式高溫爐管之結構示意圖。 第3圖所示為依據本發明之一實施例之避免晶圓淺溝 隔離層剝離之方法流程。 第4 A與4 B圖中所示為根據本發明之一實施例中,分別 以空白晶圓裸片與背面具有氮化矽鍍層的晶圓作為檢控片 ’其下方晶圓的淺溝隔離層量測厚度增加值。0503-7159TWf; TSMC200M002; Peggy.ptd Page 5 519682 V. Description of the invention (3) One method, applicable to high temperature furnace officials, can prevent the shallow trench isolation layer from peeling off at the edge of the wafer after high temperature furnace tube processing. problem. The method for avoiding the stripping of the shallow trench isolation layer of the wafer according to the present invention is applicable to a high-temperature furnace. A wafer boat having a plurality of positions for carrying a wafer is set in the temperature-stabilizing furnace tube. The method includes the following steps: At least a first position in the wafer boat is loaded with at least one control chip; at least a second position in the wafer boat is loaded with at least one wafer, wherein the wafer has a shallow trench isolation structure, and the control wafer The backside coating is the same as the backside coating of the wafer; the wafer boat carrying the inspection sheet and the wafer is subjected to a high temperature treatment in the high temperature furnace tube. In the above method, the control chip may be a wafer die, and the back surface plating layer and the back surface plating layer of the wafer may be a silicon nitride (s) N coating. The boat can be installed in the high-temperature furnace tube in a vertical manner. In order to make the above-mentioned objects, features, and advantages of the present invention more comprehensible, the following detailed description is given in conjunction with the accompanying drawings: The drawings are briefly explained. FIG. 1 shows the occurrence of the conventional wafer shallow trench isolation layer peeling. Area schematic. Figures 2.A and 2B show the structure of the vertical high-temperature furnace tube. FIG. 3 is a flowchart of a method for avoiding stripping of a shallow trench isolation layer of a wafer according to an embodiment of the present invention. Figures 4A and 4B show a shallow trench isolation layer for the wafer below the blank wafer die and the wafer with a silicon nitride coating on the back as inspection sheets according to one embodiment of the present invention. Measure the thickness increase.

0503-7159TWf ; TSMC2001-1002 ; Peggy.ptd 519682 五、發明說明(4) 符號說明 10〜 晶圓, 1 4〜 淺溝隔離結構剝 離區; 20〜 南溫爐官, 22〜 晶圓; 2 4〜 晶舟, 24A - ^ 2 4 C〜檢控片位 置; 3 0 2〜3 0 6 :流程步驟; A〜B 〜晶圓。 實施例 首先參見第2A圖,說明一垂直式高溫爐管結構。在石 英爐管20中,設置有垂直式反應的晶舟24,用以承載多片 晶圓2 2。而為了配合自動化製程或自動機械手臂的^ 在晶舟24中除了裝載晶圓的位置外時,通常在特…呆作’ 以檢控片(monitor wafer)取代一般晶圓,如曾疋的伋置 位置24Α、24Β與24C,分別位於垂直式晶舟24的 同中的 下三個固定位置 接著參見 ’表面已經完 高溫爐管處理時 程。首先進行 爐管中2 0的晶 配的高溫爐管而定 的晶圓。 接著進行 背面鍍層與晶 中承載晶圓的 上、中、 第3圖,詳細說明依據本發明之—^ 成淺溝隔離結構的晶圓,在上述第貧施例中 種防止晶圓淺溝隔離層制離2圖中的 步驟3 0 2 ··在晶舟2 4中載入複數曰。方去流 舟24乃設計用以承載多片晶圓。高溫 而定,内有溝槽,可以承裝多诖彳c小隨著搭 建150片以上 置中栽入 步驟3 0 4 ··在該晶舟2 4中的既定仇 圓相同的檢控片。在較佳情況中,^ - 晶舟,會設定在晶舟上的數個既^向溫壚管 既义仇置, 如0503-7159TWf; TSMC2001-1002; Peggy.ptd 519682 V. Description of the invention (4) Symbol description 10 ~ wafer, 1 ~ 4 ~ shallow trench isolation structure peeling area; 20 ~ Nanwen furnace official, 22 ~ wafer; 2 4 ~ Crystal boat, 24A-^ 2 4 C ~ position of the prosecution sheet; 3 02 ~ 3 06: process steps; A ~ B ~ wafer. Example First, referring to Fig. 2A, a vertical high-temperature furnace tube structure will be described. In the quartz furnace tube 20, a vertical reaction wafer boat 24 is provided to carry a plurality of wafers 22. And in order to cooperate with the automated process or robotic arm ^ In addition to the wafer loading position in the wafer boat 24, it is usually used as a special ... to replace the general wafer with a monitor wafer, such as Zeng's sink Positions 24A, 24B, and 24C are respectively located at the lower three fixed positions of the vertical wafer boat 24 in the same position. See also 'The surface has finished the high-temperature furnace tube processing schedule. First, perform wafer matching with 20 high-temperature furnace tubes in the furnace tube. Next, the upper, middle, and third drawings of the backside plating and the wafer carried in the crystal are described in detail. According to the present invention, a wafer with a shallow trench isolation structure is formed. In the above-mentioned poor embodiment, the wafer is prevented from being isolated from the shallow trench. Step 3 2 in the layer separation 2 picture. Load plural numbers in the crystal boat 24. The square flow boat 24 is designed to carry multiple wafers. Depending on the high temperature, there are grooves inside, which can hold more than 150 pieces. It is planted in more than 150 pieces and placed in the center. Step 3 0 4 ·· The predetermined prosecution pieces in the crystal boat 2 4 are the same. In a better case, ^-crystal boat, will be set on the crystal boat a number of ^ to the Wen Yi tube, the righteousness, such as

〇503-7159TWf ; TSMC2001-1002 ; Peggy.ptd 519682〇503-7159TWf; TSMC2001-1002; Peggy.ptd 519682

晶舟的前後端24A與24C與中間位置24β,用 而非一般晶圓。檢控片通常作為監測高溫八載^控片 片,用以獲得該爐管裝置20内立f 二吕條件的測試 者作為定位片,供自動化機相關資訊,或 卸載之用。而一般晶圓在先以:;:固中由=二 佈既定的鍍層,如氮化矽(Si N)鍍層。在較佳實施例中'土 可採用跟一般晶圓具有相同背面鍍層的晶圓作為檢栌片。 例如採用與進行製造晶圓同一批,背面具有厚度162;入的 氮化矽(S i N)鍍層的空白晶圓作為檢控片。 接著進行步驟30 6 :將承載檢控片與晶圓之晶舟24在 高溫爐管2 0中進行一高溫處理。在較佳實施例中,採用的 咼溫爐管為垂直式高温爐管20,而晶舟24為垂直式進行高 溫處理。 在一實施例中,分別利用空白晶圓裸片與背面具有厚 度1 6 2 5 Λ的氮化矽(S i N)鑛層的晶圓作為檢控片進行比 較,並量測檢控片下方晶圓的淺溝隔離層,其結果如第4 圖與第一表。 第一表 檢控片 晶圓增加厚度 _屬準偏差(STD) 一 空白晶圓裸片 - 3.71 1625A氨化矽 (SiN)鍍層晶圓 一一"2.90 0.30The front and rear ends of the wafer boat 24A and 24C and the middle position 24β are used instead of ordinary wafers. The control film is usually used to monitor the high-temperature eight-year-old control film, and the tester who obtains the conditions of the internal tube f 20 of the furnace tube device 20 is used as the positioning film for the relevant information of the automation machine or for unloading. For general wafers, the following coatings are used: :: Solid coatings, such as silicon nitride (Si N) coatings. In the preferred embodiment, a wafer having the same backside plating as a general wafer can be used as the inspection wafer. For example, a blank wafer with the same thickness as the manufacturing wafer and a back surface with a thickness of 162; and a silicon nitride (SiN) coating is used as the inspection sheet. Then, step 30 6 is performed: the wafer boat 24 carrying the control sheet and the wafer is subjected to a high temperature treatment in the high temperature furnace tube 20. In the preferred embodiment, the high-temperature furnace tube is a vertical high-temperature furnace tube 20, and the wafer boat 24 is a vertical type for high-temperature processing. In an embodiment, a blank wafer die and a wafer with a silicon nitride (SiN) mineral layer with a thickness of 1625 Λ on the back are used as comparison sheets, and the wafers under the detection sheets are measured. The results of the shallow trench isolation layer are shown in Figure 4 and the first table. The first table is the control wafer. The thickness of the wafer is increased. It is a quasi deviation (STD)-a blank wafer die-3.71 1625A silicon ammonia (SiN) coated wafer-one " 2.90 0.30

519682 五、發明說明(6) 在第4圖中,代表晶圓A盥8,曰 離層的量測厚度增加值。由圖曰曰0上的數字為淺溝隔 作為測試片的下方晶圓A,晶圓A上的圓:片 厚度值增加值(13.65、8 91、5的尽度,佈不均,邊緣 般值,顯然邊緣部分有淺溝_ •HI間7一 下方晶圓B,則可以看出i ; N曰> ^之晶圓作為檢控片的 勻。 ]叮以看出整片晶_的厚度分佈均相當均 I化:(由二一上中更可以看出,以背面具有厚度1625 A的 2二: 晶圓作為檢控片,下方晶圓的淺溝隔 —曰、予度均勻,晶圓上各部分的厚度標準偏差(〇. 3 )顯 著小於曰曰圓裸片者(3 . 71 ),有效的避免淺溝隔離層的剝離 問題。 將承載於晶舟24中,具有相同背面鍍層的檢控片與下 方晶圓在高溫爐管2 0中進行高溫處理時,由於檢控片的背 面鑛層與其他進行製造的晶圓相同,因此,檢控片背面的 條件與其他晶圓相同,在高溫爐管2 0中,相鄰的檢控片與 晶圓間的微環境條件與其他晶圓與晶圓間相同,因而玎以 大幅降低檢控片下方的晶圓,其外緣所常發生的淺溝隔離 層剝離問題。 本發明的優點在於,可利用最經濟的方式,對於高浪 爐管中,晶舟設置有檢控片時,有效的改善可能導致的f 圓的淺溝隔離層剝離問題。本發明可節省一般額外購買檢 控片的支出,直接以同批具有相同背面鍍層的晶圓直操作519682 V. Description of the invention (6) In the fourth figure, it represents the wafer A and the thickness increase of the measured thickness of the separation layer. From the figure, the number on 0 is the shallow trench as the lower wafer A of the test piece. The circle on wafer A: the increase in the thickness of the wafer (13.65, 8 91, 5), uneven distribution, edge-like Value, it is clear that there is a shallow groove at the edge of the wafer. • The wafer B below the HI 7 can be seen as the uniformity of the control wafer.] Ding Yi can see the thickness of the entire wafer The distributions are all fairly uniform: (It can be seen from the top of the top of the middle that the back has a thickness of 1625 A of 22: the wafer is used as the inspection piece, and the shallow trench of the lower wafer is uniform, that is, the degree of predicate is uniform, and the wafer The thickness standard deviation (0.3) of the upper part is significantly smaller than that of a round die (3.71), which effectively avoids the problem of peeling off the shallow trench isolation layer. It will be carried in the wafer boat 24 and has the same back plating. When the prosecution sheet and the lower wafer are subjected to high temperature processing in the high temperature furnace tube 20, the back layer of the prosecution sheet is the same as that of other manufactured wafers. Therefore, the conditions on the back of the prosecution sheet are the same as those of other wafers. In tube 20, the micro-environmental conditions between adjacent prosecution pieces and wafers are the same as those of other wafers and between wafers. In order to greatly reduce the problem of peeling off the shallow trench isolation layer often occurring on the outer edge of the wafer under the inspection sheet, the advantage of the present invention is that the wafer boat is provided with inspection and control in the high-wave furnace tube in the most economical way. In the case of wafers, the problem of f-round shallow trench isolation layer peeling can be effectively improved. The invention can save the cost of purchasing additional inspection wafers and directly operate the same batch of wafers with the same backside plating directly.

519682 五、發明說明(7) 為檢控片使用。由於在晶圓製造中,同一批晶圓中,具有 相同晶圓背面鍍層的晶圓相當容易取得,其經濟效益或取 得的方便性均優於額外購買檢控片,並可有效改善高溫製 程後的晶圓淺溝隔離層剝離的問題。 雖然本發明以較佳實施例揭露如上,然其並非用以限 定本發明,任何熟悉此項技藝者,在不脫離本發明之精神 和範圍内,當可做些許更動與潤飾,因 '此本發明之保護範 圍當視後附之申請專利範圍所界定者為準。519682 V. Description of Invention (7) It is used for prosecution film. In wafer manufacturing, in the same batch of wafers, the wafers with the same backside coating are quite easy to obtain. The economic benefits or the convenience of obtaining are better than purchasing additional control wafers, and can effectively improve the high-temperature process. The problem of wafer shallow trench isolation layer peeling. Although the present invention is disclosed in the preferred embodiment as above, it is not intended to limit the present invention. Anyone skilled in the art can make some modifications and retouching without departing from the spirit and scope of the present invention. The scope of protection of the invention shall be determined by the scope of the attached patent application.

0503-7159TWf ; TSMC2001-1002 ; Peggy.ptd 第10頁0503-7159TWf; TSMC2001-1002; Peggy.ptd page 10

Claims (1)

519682 六、申請專利範圍 1 · 一種避免晶圓淺溝隔離層剝離之方法,適用於一高 溫爐管,該高溫爐管中設置一具有複數位置用以承載晶圓 之晶舟,係包含下列步驟: 在該晶舟中之至少一第一位置載入至少一檢控片; 在該晶舟中之至少第二位置載入至少一晶圓,其中, 該晶圓上具有淺溝隔離結構,且該控片之背面鍍層與該晶 圓之背面鍍層相同; 將承載該檢控片與該晶圓之該晶舟在該高溫爐管中進 行一高溫處理。 2. 根據申請專利範圍第1項所述之避免晶圓淺溝隔離 層剝離之方法,其中該控片之背面鍍層與該晶圓之背面鍍 層為氮化矽(S i N)。 3. 根據申請專利範圍第2項所述之避免晶圓淺溝隔離 層剝離之方法,其中該控片為背面具有氮化矽(S i N)鍍層 之晶圓裸片。 4. 根據申請專利範圍第2項所述之避免晶圓淺溝隔離 層剝離之方法,其中該氮化矽(S i N )厚度為1 6 2 5 A。 5. 根據申請專利範圍第1項所述之避免晶圓淺溝隔離 層剝離之方法,其中該晶舟以垂直方式設置於該高溫爐管 中 〇 6. 根據申請專利範圍第5項所述之避免晶圓淺溝隔離 層剝離之方法,其中至少一晶圓載入該控片下方位置。519682 6. Scope of patent application1. A method for avoiding the stripping of the shallow trench isolation layer of the wafer is applicable to a high temperature furnace tube. A high temperature furnace tube is provided with a wafer boat having a plurality of positions for carrying wafers. The method includes the following steps: : Loading at least one control sheet at at least a first position in the wafer boat; loading at least one wafer at at least a second position in the wafer boat, wherein the wafer has a shallow trench isolation structure, and the The back plating of the control wafer is the same as the back plating of the wafer; the wafer boat carrying the inspection wafer and the wafer is subjected to a high temperature treatment in the high temperature furnace tube. 2. The method for avoiding the stripping of the shallow trench isolation layer of the wafer according to item 1 of the scope of the patent application, wherein the backside plating of the controller and the backside plating of the wafer are silicon nitride (SiN). 3. The method for preventing stripping of the shallow trench isolation layer of the wafer according to item 2 of the scope of the patent application, wherein the control chip is a bare wafer with a silicon nitride (SiN) coating on the back. 4. The method for avoiding stripping of the shallow trench isolation layer of the wafer according to item 2 of the scope of the patent application, wherein the thickness of the silicon nitride (S i N) is 16 2 5 A. 5. The method for avoiding the stripping of the shallow trench isolation layer of the wafer according to item 1 of the scope of the patent application, wherein the wafer boat is arranged in the high temperature furnace tube in a vertical manner. A method for avoiding stripping of a shallow trench isolation layer of a wafer, in which at least one wafer is loaded into a position below the control piece. 0503-7159TWf ; TSMC2001-1002 ; Peggy.ptd 第11頁0503-7159TWf; TSMC2001-1002; Peggy.ptd page 11
TW90132254A 2001-12-25 2001-12-25 Method of preventing peeling of shallow trench isolation layer on wafer TW519682B (en)

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