經濟部中央標率局員工消費合作社印製 517084 kl B7 五、發明説明（i ) 技術範圍 本發明係關於含有微粒子磨磋劑之可傾倒的均勻磨磋 式水性液體淸潔劑組成物，彼乃適用於淸潔硬質表面。 發明背景 含有磨磋粒子之硬質表面淸潔劑已眾所週知。典型的 組成物包含一或多個界面活性劑溶液及多數個分散其內之 磨磋粒子。典型的磨磋物質包括礦物質，如方解石，或白 雲石及其他相當高密度之物質。在此技藝中，一般而言都 須確保磨磋粒子能以懸浮方式留在組成物中，以使組合物 在使用前不需要劇烈搖動，同時避免沈澱粒子之沈積，或 甚而硬化。 在這些組成物的副種類中，一或多個界面活性劑組份 通常係與溶解的電解質結合而充做爲懸浮劑。電解質的存 在可藉由層合相之建立而使該（等）界面活性劑組份增稠 。一般言之，這些組成物係在pH超過9·0下調合製成 ，其中方解石係用做爲磨磋劑。 在液體磨磋式淸潔劑中用做爲懸浮劑之界面活性劑包 括烷基苯磺酸鹽、醇磺酸鹽、羥乙基化醇、羥乙基化烷基 胺、脂肪酸皂、及二級烷基磺酸鹽。如此藝中所熟知般， 將這些界面活性劑與電解質結合，可用來形成懸浮系統。 通常，這些懸浮系統的精細結構係由直徑在0 . 0 5 至約1 0微米的球狀結構物所組成。頃相信，這些結構物 包含由薄水層隔開之界面活性劑所組成的同中心交替性雙 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ------:!·------'訂------f (請先閱讀背面之注意事項再填寫本頁) 517084 經濟部中央標準局員工消費合作社印裝 Α7 Β7 五、發明説明（2 ) 層殼。懸浮系統並非界面活性劑在水存在下可形成之唯一 結構。上文提及之界面活性劑也可形成黏稠但不能使粒子 懸浮之微胞構造。除此之外，界面活性劑與水的組合物也 可分開成二或多個具有不同物理特性之混合相。正確地說 ，經特殊界面活性劑混合物所採用之結構係受到組成物中 電解質的離子強度而強烈地影響，並且某些界面活性劑系 統在電解質的離子強度中會非常敏感地改變。 同時，也得知可使用存在著聚合物之混合型懸浮系統 。頃相信，在此類組成物中，由於聚合物的存在，各產品 的部份懸浮活性將會提高。 在任何使用界面活性劑做爲懸浮系統的商品化液體磨 磋式淸潔劑中，懸浮系統在使用溫度的全範圍內須呈安定 ，並須充份地懸浮以便在產品的使用壽命內使磨磋粒子維 持在懸浮狀態。在組成物的離子強度會隨溫度變化的情況 下，將難以預料某給定之添加劑是否會在產品所暴露之某 部份溫度範圍內停止粒子懸浮而擾亂了懸浮系統。 液體磨磋式淸潔劑的另一問題係其排除難以淸洗掉之 殘留物的傾向。若組成物含有不溶性磨磋劑時，此一問題 就較特別。所以，便需要減少磨磋劑的總量以增加淸洗性 能，及減少表面受磨磋劑損傷之可能性等方式來增進磨磋 式組成物的性能。 溶劑係非磨磋式淸潔組成物中所熟知的組份。用於淸 潔組成物中的典型溶劑包括醇類（如乙醇）、醚類（如丁 基乙二醇一乙醚〔TM〕）、鏈烷（如Isopar L [TM])、 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁) 、-5-口 經濟部中央標準局貝工消費合作社印裝 517084 A7 B7 五、發明説明（3 ) 酯類、及萜烯類（如d —萜二烯）。另一已知種類的溶劑 爲烷醇胺。EP503219A (P&G)係關於一含有 0 · 1 - 1 0 %烷醇胺之淸潔組成物。 吾人已判定：在液體磨磋式淸潔劑中欲以顯著量來包 含烷醇胺溶劑是較爲困難的。頃相信，烷醇胺具有電解質 及溶劑特性，並會影響懸浮相之結構。因此，當組成物在 貯存或運送期間的溫度改變時，組成物中有效電解質的量 也會改變，進而導致懸浮相的破壞及磨磋粒子之沈澱，甚 或導致組成物的相分離。 發明之簡略說明 經判定，假若有烴潛溶劑存在時，配合顯著量的C 2 -C6烷醇胺即可調製pH7 - 1 3之經改良液體磨磋式淸潔 劑。在烷醇胺可充做爲溶劑及鹼以促使困難污物之去除下 ，烷醇胺的存在係令人欣喜。 據此，本發明係提供一種PH7 — 1 3之液體磨磋式 淸潔劑組成物，彼含有： a) 0 · 1 — 20%wt —或多個可形成懸浮系統之 界面活性劑， b ) 2 - 8 0 % w t —或多個經懸浮之磨磋劑， c) 0 · 5 - 10%wt C2 - C6 烷醇胺，以及 d) 0 · 25 - 10%wt 烴潛溶劑， 頃相信，烷醇胺係充做爲鹼及溶劑，其可增進淸潔作 用’如此即可使該經懸浮之磨磋劑的量減少。依次地，頃 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ------：— :蝼II (讀先閲讀背面之注意事項再填寫本頁) 訂 -6 - 517084 經濟部中央標率局員工消費合作社印装 A7 __B7 五、發明説明（4 ) 相信，此舉可減少表面損傷的可能性及增進淸洗性能。又 相信，潛溶劑之存在是需要的，以便在承受溫度循環或極 W溫度之貯存時能維持該以院醇胺爲基之組成物的安定性 發明之詳細說明 爲了進一步明瞭本發明，本發明之具體實施例中各種 較佳及/或可選擇性之特性將如下文說明。 烷醇胺： 用於本發明之組成物中的烷醇胺可爲單-或多-官能 性（有關於以胺及羥基部份）。較佳的烷醇胺通常是爲化 學式H2N — Ri — OH，其中Ri表示具有2 — 6個碳原 子之直鏈或支鏈烷基。合適的烷醇胺包括： 2 —胺基一 2 —甲基一 1 —丙醇， 單一，二一及三一乙醇胺， 單一，二一及三一異丙醇胺，以及 二甲基一，二乙基或二丁基乙醇胺， 經審視，也可使用環狀烷醇胺，如嗎啉。 特別合適之烷醇胺包括：2 —胺基一 2 —甲基— 丙醇，單-乙醇胺及二乙醇胺。頃相信，這些物質都能增 進對堅硬或老化污物之淸潔作用。在這些物質中，又以2 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) --- ： ITφ— (請先閱讀背面之注意事項再填寫本頁) 517084 Α7 Β7 五、發明説明（5 ) 一胺基一2—甲基一1一丙醇更佳。 烷醇胺在本發明之組成物中的代表量係在1 - 5% w t範圍內。較高量的溶劑較不爲人喜歡，因爲彼等會攻 擊某些塑料物質。更佳地係使用1 一 3 %w t量之2 -胺 基一 2 —甲基一1 一丙醇，。 潛溶劑： 合適之潛溶劑包括飽和及不飽和直鏈或支鏈烴化合物 。較佳的物質有： C 1 Q Η 1 6蔽嫌，及 C i Q - H i 6直鏈鏈烷 更合適之萜烯涵蓋d —萜二烯。 更佳的鏈烷包括如〜Shellsol-T > 〔 T Μ〕之商品化物 質。 經濟部中央標準局員工消費合作社印製 ------ (請先閲讀背面之注意事項再填寫本頁) 潛溶劑的代表量在0.5-5%wt範圍內。更佳地 係使用量在1 一 3%w t之萜烯。某些此類萜烯物質，如 萜二烯具有另一優點，即彼等或許有雜質存在其內，而可 展現驅蟲性。經判斷，萜烯物質在p Η低於1 1時會有更 好的性能。直鏈鏈烷因較不會攻擊塑料製品，所以可在比 萜烯還高量下使用。頃相信，鏈烷化合物在ρ Η高於1 1 時會有更好的性能。 較佳地，烷醇胺對烴潛溶劑之比係在3:1—1:3 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） -8 - 經濟部中央標準局貝工消費合作社印製 517084 A7 B7 五、發明説明（6 ) 範圍內，更佳地爲3:1至1:1。一般而言，雖然在潛 溶劑的需求量中需要添加更多量的此組份（其正常地係做 爲淸潔組成物的香料成份），但較有利地係將一部份潛溶 劑充做爲香料組份。較佳地，萜烯類可依此方式而使用做 爲可選擇性萜烯類，例如，萜二烯具有令人愉悅的柑橘味 ，然而鏈烷通常是無味道的。 磨磋劑： 一分散之經懸浮微粒子相係爲如本發明之組成物的基 本成份。 較佳地，此分散之經懸浮微粒子相含有不溶於水相之 微粒子磨磋劑。在另一替代例子中，磨磋劑係以使磨磋劑 在水相中之溶解度超過限度而致會有固態磨磋劑存在於組 成物內之此一過量方式，溶解並存在該組成物中。 雖然較高硬度之磨磋劑可用於特殊應用上，但供用於 一般用途之組成物的較佳磨磋劑係具有低於6之莫氏（ Moh)硬度。較低硬度之物質通常有較少的表面損傷。 合適之磨磋劑可選自微粒子狀沸石、方解石、二氧化 矽、矽酸鹽、碳酸鹽、氧化鋁、碳酸氫鹽、硼酸鹽、硫酸 鹽、及聚合物質如聚乙烯。 磨磋劑之較佳的平均（重量平均）粒子大小係落在 0 · 5 — 200微米之間，而以約10 - 100微米爲較 佳。在此範圍內，使可在良好淸潔行爲與低基材損傷之間 達到一可接收的折衷。 冢紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ~" -9- _ 、訂 Φ— (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標隼局貝工消費合作社印製 517084 B7 五、發明説明（7 ) 磨磋劑的較佳量係5 - 7 0 % w t，相對於產物量， 較佳地係在2 0 — 4 0w t %範圍內，最佳地爲> 3 0 w t %。此量之磨磋劑可給予有效的淸潔性及良好的淸洗 〇 - 最佳的磨磋劑係碳酸鈣（如方解石），碳酸鈣與碳酸 鎂之混合物（白雲石），碳酸氫鈉，硫酸鉀，沸石，氧化 鋁，水合氧化鋁，長石，滑石及二氧化矽。 方解石及白雲石由於其低成本，合適之硬度及顏色， 所以更佳。 界面活性劑： 如本發明之組成物將含有淸潔劑有效物質，其通常係 選自陰離子性及非離子性淸潔劑有效物質。 合適之陰離子性淸潔劑有效化合物包括有機硫酸反應 產物之水溶性鹽，其在分子結構中具有8至2 2個碳原子 烷基，及一選自磺酸或硫酸酯基及彼等之混合物的基。 合適之陰離子性淸潔劑實例包括醇硫酸鈉及鉀，尤其 是那些藉使高碳醇（因還原牛脂或椰子油之甘油酯所製造 )硫酸化而製得者；烷基苯磺酸鈉及鉀，例如那些烷基爲 9至1 5個碳原子者；二級烷磺酸鈉及鉀；烷基甘油醚硫 酸鈉，尤其是那些衍生自牛油及椰子油之高碳醇的醚類； 椰子油脂肪酸-甘油硫酸鈉；一莫耳高碳脂肪醇與1至6 莫耳環氧乙烷之反應產物的硫酸酯之鈉鹽及鉀鹽；具有1 至8單元環氧乙烷分子及4至14個碳原子烷基之烷基酧 本紙張尺度適用中國國家標準（CNS ) Α4規格(210X297公釐)~： (請先閲讀背面之注意事項再填寫本頁) -10· 517084 經濟部中央標隼局貝工消費合作社印繁 A7 B7 五、發明説明（8 ) 氧化乙烯醚硫酸鹽的鈉鹽及鉀鹽；經2 -羥基乙磺酸酯化 再以氫氧化鈉中和之脂肪酸的反應產物，其中脂肪酸係衍 生自椰子油及彼之混合物。 較佳之水溶性合成的陰離子性淸潔劑有效化合物係爲 高碳烷基苯磺酸酯及烯烴磺酸酯與高碳烷基硫酸鹽之混合 物，以及高碳脂肪酸-甘油硫酸鹽的鹼金屬（如鈉及鉀） 鹽和鹼土金屬（如鈣及鎂）鹽。最佳的陰離子性淸潔劑有 效化合物是高碳烷基芳族磺酸鹽，例如在直鏈或支鏈烷基 中含有6至2 0個碳原子之高碳烷基苯磺酸鹽，特殊實例 有高碳烷基苯磺酸鈉鹽，或是高碳烷基甲苯，二甲苯或苯 酚磺酸鹽之鈉鹽，烷基萘磺酸鈉，二戊基萘磺酸銨，以及 二壬基萘磺酸鈉。 在如本發明之淸潔劑組成物中，合成之陰離子性淸潔 劑有效物質的使用量通常是1至2 5%，較佳地2至2 0 %，最佳地2至15重量％。 合適之非離子性淸潔劑有效化合物可廣泛說明爲那些 藉令親水性環氧烷基與脂肪族或烷基芳族等有機疏水性化 合物縮合所製得的化合物。該與特定疏水性基縮合之親水 性或聚氧化烯基的長度可輕易地調整，以產生在親水性與 疏水性元素間具有所需平衡度之水溶性化合物。 特殊實例包括具有8至2 2個碳原子直鏈或支鏈組態 之脂肪醇與環氧乙烷的縮合產物，例如具有每莫耳椰子醇 2至1 5莫耳環氧乙烷的椰子油氧化乙烯縮合物；含有6 至1 2個碳原子烷基之烷基酚與5至2 5莫耳環氧乙烷每 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ------：I-ΙΦ,II (請先閲讀背面之注意事項再填寫本頁)Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 517084 kl B7 V. Description of the Invention (i) Technical Scope The present invention relates to a pourable homogeneous aqueous liquid detergent composition containing microparticle abrasives. Suitable for cleaning hard surfaces. BACKGROUND OF THE INVENTION Hard surface cleaners containing abrasive particles are well known. A typical composition comprises one or more surfactant solutions and a plurality of abrasive particles dispersed therein. Typical abrasive materials include minerals such as calcite, or dolomite and other relatively high density materials. In this technique, in general, it is necessary to ensure that the abrasive particles can remain in the composition in a suspended manner, so that the composition does not need to be shaken vigorously before use, and at the same time to avoid the deposition of precipitated particles, or even hardening. Among the subtypes of these compositions, one or more surfactant components are usually used as a suspending agent in combination with a dissolved electrolyte. The presence of an electrolyte can thicken the (or other) surfactant component by the establishment of a laminated phase. Generally speaking, these compositions are prepared by blending at a pH exceeding 9.0, and the calcite series is used as a grinding agent. Surfactants used as suspension agents in liquid abrasive detergents include alkylbenzene sulfonates, alcohol sulfonates, hydroxyethylated alcohols, hydroxyethylated alkylamines, fatty acid soaps, and Alkyl sulfonate. As is well known in the art, combining these surfactants with an electrolyte can be used to form a suspension system. Generally, the fine structure of these suspension systems consists of spherical structures with a diameter of 0.05 to about 10 microns. It is believed that these structures contain concentric alternating double papers composed of surfactants separated by a thin water layer, which are applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) ------ :! · ------ 'Order ------ f (Please read the notes on the back before filling out this page) 517084 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Α7 Β7 V. Description of Invention (2) shell. Suspension systems are not the only structures that surfactants can form in the presence of water. The surfactants mentioned above can also form microcellular structures that are viscous but cannot suspend particles. In addition, the surfactant and water composition may be separated into two or more mixed phases having different physical properties. To be precise, the structure adopted by the special surfactant mixture is strongly affected by the ionic strength of the electrolyte in the composition, and some surfactant systems will change very sensitively in the ionic strength of the electrolyte. At the same time, it is also known that hybrid suspension systems with polymers can be used. It is believed that in such compositions, due to the presence of the polymer, some of the suspension activity of each product will increase. In any commercial liquid abrasive cleaners that use surfactants as a suspension system, the suspension system must be stable over the full range of operating temperature and must be fully suspended in order to allow abrasives to be used over the life of the product. The particles remain in suspension. In the case where the ionic strength of the composition changes with temperature, it will be difficult to predict whether a given additive will stop the suspension of particles within a part of the temperature range exposed by the product and disrupt the suspension system. Another problem with liquid abrasive cleaners is their tendency to exclude residues that are difficult to rinse off. This problem is particularly problematic when the composition contains an insoluble abrasive. Therefore, it is necessary to reduce the total amount of the abrasive to increase the cleaning performance and reduce the possibility of damage to the surface by the abrasive to improve the performance of the abrasive composition. Solvents are well-known components in non-abrasive cleaning compositions. Typical solvents used in cleaning compositions include alcohols (such as ethanol), ethers (such as butyl ethylene glycol monoethyl ether [TM]), alkanes (such as Isopar L [TM]), and this paper is applicable to China National Standard (CNS) Λ4 specification (210X297 mm) (Please read the precautions on the back before filling out this page), -5-Printed by the Bayer Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 517084 A7 B7 5. Description of the invention (3 ) Esters, and terpenes (such as d-terpene diene). Another known kind of solvent is alkanolamine. EP503219A (P & G) relates to a cleaning composition containing 0.1 to 10% alkanolamine. I have determined that it is more difficult to include alkanolamine solvents in significant amounts in liquid abrasive cleaners. It is believed that alkanolamines have electrolyte and solvent properties and will affect the structure of the suspended phase. Therefore, when the temperature of the composition is changed during storage or transportation, the amount of effective electrolyte in the composition will also change, leading to the destruction of the suspended phase and the precipitation of abrasive particles, or even the phase separation of the composition. Brief description of the invention It has been determined that if a hydrocarbon latent solvent is present, a significant amount of C 2 -C 6 alkanolamine can be used to adjust the improved liquid polishing detergent of pH 7-13. The presence of alkanolamines is pleasing when alkanolamines can be used as solvents and bases to facilitate removal of difficult contaminants. Accordingly, the present invention provides a liquid abrasive detergent composition of PH7-13, which contains: a) 0 · 1-20% wt-or a plurality of surfactants capable of forming a suspension system, b) 2-8 0% wt—or multiple suspended abrasives, c) 0 · 5-10% wt C2-C6 alkanolamine, and d) 0 · 25-10% wt hydrocarbon latent solvent, it is believed that Alkanolamines are used as a base and a solvent, which can improve the cleaning effect, so that the amount of the suspended abrasive can be reduced. In turn, the paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) ------:-: 蝼 II (Read the precautions on the back before filling this page) Order -6-517084 Printed by A7 __B7 of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the Invention (4) I believe that this will reduce the possibility of surface damage and improve cleaning performance. It is also believed that the existence of a subsolvent is needed in order to maintain the stability of the alcohololamine-based composition when it is subjected to temperature cycling or extreme temperature storage. Detailed description of the invention To further understand the invention, the invention Various preferred and / or optional characteristics of the specific embodiments will be described below. Alkanolamines: The alkanolamines used in the compositions of the present invention may be mono- or poly-functional (with regard to the amine and hydroxyl moieties). The preferred alkanolamines are generally of the formula H2N-Ri-OH, where Ri represents a straight or branched chain alkyl group having 2 to 6 carbon atoms. Suitable alkanolamines include: 2-amino- 2-methyl-1 -propanol, mono-, di- and tri-ethanolamine, mono-, di- and tri-isopropanolamine, and dimethyl mono-, di- Ethyl or dibutylethanolamine. Cycloalkanolamines such as morpholine can also be used upon review. Particularly suitable alkanolamines include 2-amino- 2-methyl-propanol, mono-ethanolamine and diethanolamine. It is believed that these substances can increase the cleaning effect on hard or aged dirt. Among these substances, the Chinese national standard (CNS) A4 specification (210X297 mm) is applied to 2 paper sizes ---: ITφ-- (Please read the precautions on the back before filling this page) 517084 Α7 Β7 V. Description of the invention (5) Monoamino-2methyl-1propanol is more preferred. The representative amount of alkanolamine in the composition of the present invention is in the range of 1-5% w t. Higher amounts of solvents are less desirable because they attack certain plastic substances. More preferably, 2-amino-1,2-methyl-1,1-propanol is used in an amount of 1 to 3% wt. Latent solvents: Suitable latent solvents include saturated and unsaturated linear or branched hydrocarbon compounds. The preferred materials are: C 1 Q Η 16 and C i Q-H i 6 straight chain alkanes. More suitable terpenes include d-terpene diene. More preferred paraffins include commercial substances such as ~ Shellsol-T > [TM]. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs ------ (Please read the precautions on the back before filling this page) The representative amount of latent solvent is in the range of 0.5-5% wt. More preferably, terpenes are used in an amount of 1 to 3% wt. Some of these terpene materials, such as terpene diene, have the additional advantage that they may have impurities in them and can exhibit insect repellency. It is judged that terpenes will have better performance when p p is lower than 11. Linear alkanes are less likely to attack plastic products, so they can be used at higher levels than terpenes. It is believed that paraffin compounds will perform better when ρ Η is higher than 1 1. Preferably, the ratio of the alkanolamine to the hydrocarbon latent solvent is 3: 1—1: 3. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -8-Shellfish consumption by the Central Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative 517084 A7 B7 5. In the scope of the invention description (6), it is more preferably 3: 1 to 1: 1. Generally speaking, although a larger amount of this component needs to be added to the required amount of the latent solvent (which is normally used as the fragrance component of the cleaning composition), it is more advantageous to fill a part of the latent solvent. Is a fragrance component. Preferably, terpenes can be used in this manner as selectable terpenes. For example, terpenes have a pleasant citrus flavor, whereas paraffins are generally tasteless. Milling agent: A dispersed suspended particulate phase is the basic ingredient of the composition according to the present invention. Preferably, the dispersed suspended microparticle phase contains a microparticle milling agent which is insoluble in the water phase. In another alternative example, the abrasive is dissolved and present in the composition in such an amount that the solubility of the abrasive in the aqueous phase exceeds the limit so that a solid abrasive is present in the composition. . Although higher hardness abrasives can be used for special applications, preferred abrasives for compositions for general use have a Moh hardness of less than 6. Lower hardness materials usually have less surface damage. Suitable milling agents may be selected from particulate zeolites, calcite, silica, silicates, carbonates, aluminas, bicarbonates, borates, sulfates, and polymeric materials such as polyethylene. The preferred average (weight average) particle size of the abrasive is between 0.5-200 microns, and preferably about 10-100 microns. Within this range, an acceptable compromise can be achieved between good cleaning behavior and low substrate damage. The mound paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) ~ " -9- _, order Φ— (Please read the notes on the back before filling this page) Printed by the cooperative 517084 B7 V. Description of the invention (7) The preferred amount of the milling agent is 5-70% wt, relative to the amount of the product, it is preferably within the range of 20-40wt%, the best ≫ 3 0 wt%. This amount of abrasive can give effective cleaning and good washing. The best abrasive is calcium carbonate (such as calcite), a mixture of calcium carbonate and magnesium carbonate (dolomite), sodium bicarbonate, Potassium sulfate, zeolite, alumina, hydrated alumina, feldspar, talc and silica. Calcite and dolomite are better because of their low cost, suitable hardness and color. Surfactant: The composition of the present invention will contain a detergent active substance, which is usually selected from anionic and nonionic detergent active substances. Suitable anionic detergent effective compounds include water-soluble salts of organic sulfuric acid reaction products, which have 8 to 22 carbon atoms in the molecular structure, an alkyl group selected from sulfonic acid or sulfate groups, and mixtures thereof Base. Examples of suitable anionic detergents include sodium and potassium alcoholates, especially those made by sulphating high-carbon alcohols (made by reducing glycerides of tallow or coconut oil); sodium alkylbenzenesulfonates and Potassium, such as those having 9 to 15 carbon atoms in alkyl groups; sodium and potassium secondary alkane sulfonates; sodium alkyl glyceryl ether sulfates, especially those higher alcohol alcohols derived from tallow and coconut oil; Coconut oil fatty acid-sodium glycerol sulfate; sodium and potassium salts of the sulfate ester of the reaction product of one mole of high-carbon fatty alcohol with 1 to 6 mole of ethylene oxide; having 1 to 8 units of ethylene oxide molecules and 4 to Alkyl alkane with 14 carbon atoms alkyl This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 mm) ~: (Please read the precautions on the back before filling this page) -10 · 517084 Central Standard of the Ministry of Economic Affairs隼 Bureau Shellfish Consumer Cooperatives India Fan A7 B7 V. Description of the invention (8) Sodium and potassium salts of oxidized vinyl ether sulfate; fatty acid reaction products which are esterified with 2-hydroxyethanesulfonic acid and neutralized with sodium hydroxide Among them, fatty acids are derived from coconut oil and their mixtures. Preferred water-soluble synthetic anionic detergent effective compounds are high-carbon alkylbenzene sulfonate and a mixture of an olefin sulfonate and a high-carbon alkyl sulfate, and a high-carbon fatty acid-glycerol sulfate alkali metal ( (Such as sodium and potassium) salts and alkaline earth metal (such as calcium and magnesium) salts. The best anionic detergent effective compound is a high-carbon alkyl aromatic sulfonate, such as a high-carbon alkylbenzene sulfonate containing 6 to 20 carbon atoms in a linear or branched alkyl group. Special Examples are the high-carbon alkylbenzenesulfonic acid sodium salt, or the high-carbon alkyltoluene, xylene or phenolsulfonic acid sodium salt, sodium alkylnaphthalenesulfonate, ammonium dipentylnaphthalenesulfonate, and dinonyl Naphthalene sulfonate. In the detergent composition according to the present invention, the amount of the synthetic anionic detergent effective substance used is usually 1 to 25%, preferably 2 to 20%, and most preferably 2 to 15% by weight. Suitable non-ionic detergent effective compounds can be broadly described as those prepared by condensing a hydrophilic epoxy alkyl group with an organic hydrophobic compound such as an aliphatic or alkyl aromatic compound. The length of the hydrophilic or polyoxyalkylene group condensed with a specific hydrophobic group can be easily adjusted to produce a water-soluble compound having a desired balance between hydrophilic and hydrophobic elements. Specific examples include the condensation products of fatty alcohols with ethylene oxide in a straight or branched chain configuration of 8 to 22 carbon atoms, such as coconut oil oxidation with 2 to 15 moles of ethylene oxide per mole of coconut alcohol Ethylene condensate; Alkyl phenols containing alkyl groups of 6 to 12 carbon atoms and 5 to 25 moles of ethylene oxide Each paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) ---- -: I-ΙΦ, II (Please read the precautions on the back before filling this page)
、-IT -11 - 517084 A7 B7 五、發明説明（9 ) 莫耳烷基酚的縮合物；乙二胺及環氧丙烷之反應產物與環 氧乙烷的縮合物，此縮合物含有4 0至8 0%重量比之聚 氧化乙烯基且分子量爲5，000至1 1，〇〇〇 ;結構 式爲R 3 N 0之三級胺化氧，其中一個R基表示8至1 8個 碳原子烷基，而其他R基則個別表示甲基，乙基或羥乙基 ，舉例之有二甲基十二烷基胺化氧；結構式爲R3P 0之三 級膦化氧，其中一個R基表示1 0至1 8個碳原子烷基， 而其他者可個別表示1至3個碳原子之烷基或羥烷基，舉 例之有二甲基十二烷基膦化氧；以及結構式爲R2 S 0之二 烷基亞硕，其中一個R表示1 0至1 8個碳原子烷基，而 另一個則表示甲基或乙基，舉例之有甲基十四烷基亞硕； 脂肪酸烷醇醯胺；脂肪酸烷醇醯胺與烷硫醇之環氧烷縮合 物。 非離子性淸潔劑有效物質在本發明之淸潔劑組成物的 使用量通常係0 . 5至1 5%，較佳地1至1 0%，最佳 地1至8重量％。 經濟部中央標準局員工消費合作社印^ (請先閲讀背面之注意事項再填寫本頁) 較佳地，該等組成物可含有經選擇之陰離子性及非離 子性淸潔劑有效物質，在電解質存在時即可提供一結構型 液體淸潔劑組成物，也就是說，a自身"即可增稠無需使 用任何其他增稠劑。 陰離子性淸潔劑對非離子性淸潔劑有效物質之重量比 可變化，並係視彼等本質而定，但較佳地係在1:9至9 :1範圍內，理想地爲1:4至4:1。 根據可解說此觀今之較佳具體實施例，該等淸潔劑組 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -12- 517084 經濟部中央標準局員工消費合作社印^ A7 B7 五、發明説明（10) 成物將包含2至1 0重量％在分子中含有8至2 2個碳原 子烷基之水溶性合成之陰離子性硫酸化或磺化淸潔劑鹽， 及0 · 5至8重量％衍生自分子中有8至2 2個碳原子之 脂肪族醇與環氧乙烷之縮合作用的氧化烯型非離子性淸潔 劑，如此該縮合物便具有2至1 5莫耳環氧乙烷每莫耳脂 肪族醇。 視情況需要也可將兩性，陽離子性或兩性離子性淸潔 劑有效物質涵蓋於如本發明之組成物中。 可選擇性使用之合適的兩性淸潔劑有效化合物有，具 有8至1 8個碳原子之脂肪族二級及三級胺與經陰離子性 水溶解性基取代之脂肪族基的衍生物，實例爲3 -十二烷 胺基丙酸鈉，3 -十二烷胺基丙烷磺酸鈉，及N - 2 -羥 基十二烷基一N-甲基牛磺酸鈉。 合適之陽離子性淸潔劑有效化合物包括具有8至18 個碳原子脂肪族基之四級銨鹽，實例爲溴化十六烷基三甲 基銨。 可選擇性使用之合適的兩性離子淸潔劑有效化合物包 括脂肪族四級銨，具有8至1 8個碳原子之銃及銹化合物 與經陰離子性水溶解性基取代之脂肪族基的衍生物，實例 爲3 — (N，N —二甲基一 N —十六烷基銨）丙烷一 1 一 磺酸酯甜菜鹼，3 -（十二烷基甲基銃）丙烷一 1 一磺酸 酯甜菜鹼，及3 -（十六烷基鐵）乙烷磺酸酯甜菜鹼。 合適之淸潔劑有效化合物的進一步實例係已知之 Schwartz 和 Perry 編著之教科書 > Surface Active Agents’ 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） ： !φ^ITΦΊ— (請先閱讀背面之注意事項再填寫本頁) -13- 經濟部中央標準局員工消費合作社印^ 517084 A7 B7 五、發明説明（H ) 第 I 冊及 Schwartz，Perry 及 Berch 編著之 & Surface Active Agents and Detergents 〃第二冊中所揭示之常用做爲界面活 性劑的化合物。 在如本發明之淸潔劑組成物中所用的淸潔劑有效化合 物總量通常係1 · 5至30%，較佳地2至15重量％。 本發明的重要特徵係該組成物能穩定地懸浮磨磋劑粒 子，如此消費者就不需要在使用前攪動此組成物（例如搖 晃），使沈積之粒子再懸浮及再分佈。基於此目的，該組 成物在切削速率3 X 1 0— 5 s e c— 1下具有至少5 0 0 0 Pas之200 °C時黏度（如Stokes Law測量）。通常， 此一黏度便足以確使磨磋劑粒子在2 0 0°C下靜置一個月 後不會沈積超過lcm。 如本發明之組成物也應維持充份地流質，如此當需要 使用時才能輕易地從瓶子中或其他容器中倒出。爲了此一 目的，該組成物較佳地應具有在切削速率2 1 s e c—1下 不超過1 0 P a s的2 0 0°C時黏度，其係藉使用旋轉黏 度計測量。較佳地，在2 1 s e c — 1切削速率下2 0 0 °C 黏度係不大於5Pas。 符合這些判據的合適流變條件可經由判斷選擇陰離子 性及非離子性淸潔劑體，及/或經由使用適當量的替代性 結構劑（如此藝中所熟知）以提供具有所需懸浮特性之結 構型液體。 聚合物： 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） ------：I-"蝼II (請先閲讀背面之注意事項再填寫本頁) -5 -14 - 經濟部中央標隼局員工消費合作社印繁 517084 kl B7_____ 五、發明説明（12 ) 如本發明之組成物可選擇性地含有能幫助提供適當流 變特性之聚合物結構劑，以使不溶解鹽或鹽類均勻地分佈 在組成物中，並提高組成物對欲淸潔之硬質表面的分佈及 黏著。 較佳的結構劑包括多糖類，如羧甲基纖維素鈉及其他 商品化之改質纖維素物質，漢生膠及其他非絮凝結構物如 美國專利第4 3 2 9 448案號中有關之Biopolymer PS 87。某些聚合物，如與多官能試劑交聯之丙烯酸聚合物 (舉例之爲CARB〇P0Lr )也可用做爲結構劑。此類結構劑 若使用時，其在如本發明之組成物中的使用量可如 0 · 0 0 1 % —樣少，較佳地至少0 · 0 1重量％之該組 成物量。 一般而言，本發明之組成物可視需要含有0 · 1 - 1 %的聚合物。 可選擇性成份： 如本發明之組成物可含有其他能促進淸潔性能之成份 。舉例之，該組成物可含不同於本文所定義之特殊水溶性 鹽的淸潔劑助洗劑，例如氮川二醋酸鹽，聚羧酸鹽，檸檬 酸鹽，二羧酸類，水溶性磷酸鹽，尤其是聚磷酸鹽，正-與焦磷酸鹽之混合物，沸石，及彼等之混合物。此助洗劑 若以超過其水溶解度之過量存在時，可額外作用爲磨磋劑 。通常，若使用不同於該特殊水溶性鹽之助洗劑時，較佳 地係爲0·1至25重量％該組成物量。 本纸張尺度適用中國國家標準（CNS ) A4規格（210X297公釐) ： IT------ψί (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印^ 517084 A7 B7 五、發明説明（13) 若金屬離子多價螫合劑，例如乙二胺四酯酸鹽，胺基 -聚磷酸鹽（DEQUESTR)及磷酸鹽，以及寬廣種類之其他 多官能有機酸及鹽類，能與磨磋物質相容時，也可選擇性 地使用。 另外可用於如本發明之組成物（彼在使用時易於產生 過多的肥皂泡沬）的可選擇性成份係肥皂泡沬調節物質。 肥皂泡沬調節物質的實例之一係肥皂。肥皂類係爲脂肪酸 之鹽類，並包括鹼金屬皂，例如含有約8至約2 4個碳原 子（較佳地約1 0至約2 0個碳原子）之高碳脂肪酸的鈉 鹽，鉀鹽及銨鹽。特別有效用者是衍生自椰子油及磨碎堅 果油之脂肪酸混合物的鈉鹽及鉀鹽，以及單-，二一及三 乙醇胺鹽。若使用肥皂時，其量可爲至少0·005%， 較佳地0 . 5 %至2重量％該組成物量。頃發現，如Prifac 7 9 0/〔 TM〕之脂肪酸皂也可適用於此目的上。 肥皂泡沫物質之另一實例係二氧化矽或矽酮油。若如 本發明之烴類化合物係以相當高量存在的情況下，彼等本 身即可提供某些或部份所需之防泡活性。 如本發明之組成物除了可含有上文提及之各成份外， 同時還可包含各種其他之可選擇性成份，例如著色劑，增 白劑，可選擇性增亮劑，污物懸浮劑，淸潔酵素，可相容 漂白劑（尤其是次鹵酸鹽），凝膠控制劑，另外之凍結熔 化安定劑，殺菌劑，防腐劑（如1，2，苯駢異塞唑啉一 3 -酮），以及水溶助長劑。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本頁)、 -IT -11-517084 A7 B7 V. Description of the invention (9) Condensate of mol alkylphenol; Condensate of reaction product of ethylenediamine and propylene oxide and ethylene oxide, this condensate contains 40% To 80% by weight of polyoxyethylene and molecular weight of 5,000 to 11,000; a tertiary amination oxygen having a structural formula of R 3 N 0, wherein one R group represents 8 to 18 carbons Atomic alkyl groups, and other R groups individually represent methyl, ethyl, or hydroxyethyl, for example, dimethyldodecyl aminated oxygen; a tertiary phosphine oxide of the structural formula R3P 0, one of which R Group represents an alkyl group of 10 to 18 carbon atoms, and the others may individually represent an alkyl group or hydroxyalkyl group of 1 to 3 carbon atoms, such as dimethyldodecylphosphine oxygen; and a structural formula R2 S 0 is a dialkyl aceto, one of R represents an alkyl group of 10 to 18 carbon atoms, and the other represents methyl or ethyl, for example methyl tetradecyl aceto; Alkanolamines; alkylene oxide condensates of fatty acid alkanolamines and alkylthiols. The amount of the non-ionic detergent effective substance used in the detergent composition of the present invention is usually 0.5 to 15%, preferably 1 to 10%, and most preferably 1 to 8% by weight. Printed by the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ^ (Please read the notes on the back before filling out this page) Preferably, these compositions may contain selected anionic and non-ionic detergent active substances in the electrolyte When present, a structured liquid detergent composition can be provided, that is, a itself can be thickened without using any other thickener. The weight ratio of the anionic detergent to the effective substance of the non-ionic detergent can vary and depends on their nature, but is preferably in the range of 1: 9 to 9: 1, and ideally 1: 4 to 4: 1. According to a preferred embodiment that can explain this concept, the paper size of these detergents is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -12- 517084 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ^ A7 B7 V. Description of the invention (10) The product is an anionic sulfated or sulfonated detergent salt containing 2 to 10% by weight of a water-soluble synthetic alkyl group containing 8 to 22 carbon atoms in the molecule, and 0.5 to 8% by weight of an alkylene oxide type nonionic detergent derived from the condensation of an aliphatic alcohol having 8 to 22 carbon atoms in the molecule with ethylene oxide, so that the condensate has 2 to 15 Molar ethylene oxide per Molar aliphatic alcohol. Amphoteric, cationic or zwitterionic detergent effective substances may be included in the composition according to the present invention as the case requires. Suitable amphoteric detergent effective compounds which can be used selectively are derivatives of aliphatic secondary and tertiary amines having 8 to 18 carbon atoms and aliphatic group substituted with anionic water-soluble groups, examples Sodium 3-dodecylaminopropionate, sodium 3-dodecylaminopropanesulfonate, and N-2 -hydroxydodecyl-N-methyltaurine sodium. Suitable cationic detergent effective compounds include quaternary ammonium salts of aliphatic groups having 8 to 18 carbon atoms, an example being cetyltrimethylammonium bromide. Suitable zwitterionic detergent effective compounds that can be used selectively include derivatives of aliphatic quaternary ammonium, hydrazones having 8 to 18 carbon atoms, and rust compounds and aliphatic radicals substituted with anionic water-soluble groups Examples are 3- (N, N-dimethyl-N-hexadecylammonium) propane-1 monosulfonate betaine, 3- (dodecylmethylfluorene) propane-1 monosulfonate Betaine, and 3- (hexadecyl iron) ethanesulfonate betaine. Further examples of suitable effective compounds for detergents are known textbooks by Schwartz and Perry > Surface Active Agents' This paper is sized to the Chinese National Standard (CNS) A4 specification (210 × 297 mm):! Φ ^ ITΦΊ— (Please Please read the notes on the back before filling this page) -13- Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^ 517084 A7 B7 V. Description of Invention (H) Book I and Schwartz, Perry and Berch & Surface Active Agents and Detergents 〃 The compounds commonly used as surfactants disclosed in Book II. The total effective amount of the detergent effective compound used in the detergent composition according to the present invention is usually 1.5 to 30%, preferably 2 to 15% by weight. An important feature of the present invention is that the composition can stably suspend abrasive particles, so that the consumer does not need to agitate the composition (such as shaking) before use to resuspend and redistribute the deposited particles. For this purpose, the composition has a viscosity at a cutting rate of 3 X 1 0-5 s e c-1 at 200 ° C of at least 5 0 0 Pas (as measured by Stokes Law). Generally, this viscosity is sufficient to ensure that the abrasive particles do not deposit more than 1 cm after standing at 200 ° C for one month. The composition of the present invention should also maintain sufficient liquidity so that it can be easily poured out of a bottle or other container when needed. For this purpose, the composition should preferably have a viscosity at 20 ° C of not more than 10 Pas at a cutting rate of 21 s e c-1, which is measured by using a rotary viscometer. Preferably, the viscosity at 2000 ° C at a cutting rate of 21 s e c -1 is not greater than 5 Pas. Appropriate rheological conditions that meet these criteria can be determined by selecting anionic and non-ionic detergent bodies and / or by using appropriate amounts of alternative structurants (as is well known in the art) to provide the desired suspension characteristics Structured liquid. Polymer: This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) ------: I- " 蝼 II (Please read the precautions on the back before filling this page) -5 -14 -Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, Yinfan 517084 kl B7_____ V. Description of the Invention (12) If the composition of the present invention can optionally contain a polymer structurant that can help provide appropriate rheological properties to make it insoluble Salt or salts are evenly distributed in the composition, and improve the distribution and adhesion of the composition to the hard surface to be cleaned. Preferred structurants include polysaccharides, such as sodium carboxymethylcellulose and other commercial modified cellulose materials, xanthan gum, and other non-flocculating structures such as Biopolymer in U.S. Patent No. 4 3 2 9 448. PS 87. Certain polymers, such as acrylic polymers cross-linked with polyfunctional reagents (for example, CARBOPOLLr) can also be used as structurants. When such a structurant is used, its use amount in the composition according to the present invention may be as small as 0 · 0 0 1%-preferably at least 0 · 0 1% by weight of the composition. In general, the composition of the present invention may contain from 0.1 to 1% of a polymer as required. Optional ingredients: For example, the composition of the present invention may contain other ingredients that can promote cleaning performance. For example, the composition may contain detergent builders other than the special water-soluble salts defined herein, such as nitrogen diacetate, polycarboxylates, citrates, dicarboxylic acids, water-soluble phosphates , Especially polyphosphates, mixtures of ortho- and pyrophosphates, zeolites, and mixtures thereof. This builder, if present in excess in excess of its water solubility, can additionally act as a grinding aid. In general, when a builder other than the special water-soluble salt is used, it is preferably from 0.1 to 25% by weight of the composition. This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm): IT ------ ψί (Please read the precautions on the back before filling this page) Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^ 517084 A7 B7 V. Description of the invention (13) If metal ion polyvalent couplers, such as ethylene diamine tetraester, amine-polyphosphate (DEQUESTR) and phosphate, and a wide variety of other polyfunctional organic acids and Salts can also be used selectively when they are compatible with abrasive substances. In addition, an optional ingredient which can be used in the composition of the present invention (which is liable to produce excessive soap bubbles when used) is a soap bubble regulator. One example of a soap foaming regulator is soap. Soaps are salts of fatty acids and include alkali metal soaps, such as the sodium and potassium salts of high-carbon fatty acids containing about 8 to about 24 carbon atoms (preferably about 10 to about 20 carbon atoms). Salts and ammonium salts. Particularly effective are sodium and potassium salts of fatty acid mixtures derived from coconut oil and ground nut oil, as well as mono-, di- and triethanolamine salts. If soap is used, the amount may be at least 0.005%, preferably 0.5 to 2% by weight of the composition. It was found that fatty acid soaps such as Prifac 790 / [TM] are also suitable for this purpose. Another example of a soap foam material is silicon dioxide or silicone oil. If the hydrocarbon compounds of the present invention are present in relatively high amounts, they can provide some or part of the antifoaming activity required. For example, the composition of the present invention may contain various other optional ingredients in addition to the above-mentioned ingredients, such as a coloring agent, a whitening agent, a selective brightening agent, and a dirt suspending agent. Detergent enzyme, compatible bleach (especially hypohalite), gel control agent, other freeze-stabilizing stabilizers, bactericides, preservatives (such as 1, 2, Benzamidine Isoxazoline 3- Ketones), and hydrotropes. This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page)
-16 - 517084 A7 B7 五、發明説明（^ ) 14 pH: 如本發明之組成物可調製在鹼性P Η範圍，且當方解 石用做爲磨磋劑時，通常pH是在9 · 5至12 · 5，較 佳地約1 0至1 2。若使用其他磨磋劑時，pH會降低， 但一般而言，pH應該在一 1之上（烷醇胺之pKa値）， 且較佳地係在烷醇胺的p Ka値之上。 若需要時可使用鹼化劑，如氫氧化鈉及碳酸鈉，以及 酸類如氫氯酸來調整並緩衝P Η時。 較佳之組成物： 如本發明之較佳組成物包含： a) 1 — 5%wt鹼金屬碳酸鹽及/或碳酸氫鹽， b) l — 5%wt烷基苯磺酸鹽， c) 〇 — l%wt脂肪酸， d ) 1 - 3 % w t羥乙基化醇非離子性界面活性劑， e) 0 · 5 — 2 · Owt%選自：2 —胺基一2 —甲 經濟部中央標率局貝工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 基一 1 一丙醇，單一，二一及三一乙醇胺，單一，二一及 三一異丙醇胺，二甲基一，二乙基一或二丁基一乙醇胺， 以及彼等之混合物的烷醇胺， f) 0 · 5 — 2 · 0%wt 選自：Ci〇H16 萜烯，-16-517084 A7 B7 V. Description of the invention (^) 14 pH: If the composition of the present invention can be adjusted in the alkaline PΗ range, and when calcite is used as a grinding agent, the pH is usually in the range of 9 · 5 to 12 · 5, preferably about 10 to 12. If other milling agents are used, the pH will decrease, but in general, the pH should be above 1 (pKa 値 of alkanolamine), and preferably above pKa 値 of alkanolamine. If necessary, alkalizing agents such as sodium hydroxide and sodium carbonate, and acids such as hydrochloric acid can be used to adjust and buffer PP. Preferred composition: For example, the preferred composition of the present invention comprises: a) 1 to 5% by weight alkali metal carbonate and / or bicarbonate, b) 1 to 5% by weight alkylbenzene sulfonate, and c). — 1% wt fatty acid, d) 1-3% wt hydroxyethylated alcohol nonionic surfactant, e) 0 · 5-2 · Owt% selected from: 2-amine group 2-central standard of the Ministry of Economic Affairs Printed by the Bureau of Shellfish Consumer Cooperative (please read the precautions on the back before filling this page). 1-propanol, mono, di and triethanolamine, mono, di- and tri-isopropanolamine, di Methyl mono, diethyl mono or dibutyl monoethanolamine, and alkanolamines of mixtures thereof, f) 0 · 5-2 · 0% wt selected from: CiOH 16 terpenes,
Ci。一 C16直鏈鏈烷，及彼等之混合物的潛溶劑， g) 20—40%選自：碳酸鈣，碳酸鎂，沸石，氧 化鋁，水合氧化鋁，長石，滑石，二氧化矽，及彼等之混 合物的磨磋劑，以及 本紙張尺度適用中國國家標準（CNS ) A4規格（21〇Χ29*7公釐） -17- 517084 A7 ____B7 五、發明説明（15 ) h) 0 · 1 - 2%wt不同於萜烯之香料組份，而其 餘組份則包含較不重要組份及水。 爲了使本發明更易明瞭，本文以下，將參考下列不受 限制之實施例來說明： 實施例 藉使用下列基底組成份（如表1所示），並配合3夂變 如表2所示之熔劑量以進行實施例。如表i所示，組成物 係在ρΗ1〇及pH12下製備。 (請先閱讀背面之注意事項存填寫本頁) 經濟部中央標準局員工消費合作社印製 準 標 家 |國 國 中 用 適 度 尺一錄 I本 一雜Ci. A C16 linear alkanes, and their latent solvents, g) 20-40% selected from: calcium carbonate, magnesium carbonate, zeolite, alumina, hydrated alumina, feldspar, talc, silica, and others And other blending agents, and this paper size applies the Chinese National Standard (CNS) A4 specification (21〇 × 29 * 7 mm) -17- 517084 A7 ____B7 V. Description of the invention (15) h) 0 · 1-2 % wt is different from the terpene perfume component, while the remaining components contain less important components and water. In order to make the present invention easier to understand, the following text will be described with reference to the following non-limiting examples: The examples use the following base components (as shown in Table 1), and 3% of the flux shown in Table 2 Amount to carry out the examples. As shown in Table i, the composition was prepared at pH 10 and pH 12. (Please read the notes on the back and fill in this page first.) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs.
It 公 7 9 2 517084 A7 B7 五、發明説明（16 ) 表1 經濟部中央標準局員工消費合作社印製 基底組成物 pHIO pH12 碳酸鈉 3.13% 3.13%- 碳酸氫鈉 0.53% 0.53% 方解石 35.0% 35.0% [OMY Acarb 30-AV:TM 取自OMYA公司] 烷基苯磺酸鹽 3.00% 3.00% [Petrelab 550:TM 取自Petresa公司] 椰子脂肪酸 0.48% 0.48% [Prifac 7901:TM 取自Unichema公司] 非離子性7E〇 1.50% 1.50% [Dobanol 23-6.5EO: 取自Shell公司] 氫氯酸 0.26% - [2M取自Fisons公司] 氫氧化鈉 0.42% 1，2,苯駢異噻唑 啉-3-酮 .016% .016% [Proxel GXL:TM 取自 ICI公司] 香料 0.50% 0.50% [CL318A:TM 取自 Quest 公司] 水 至 100% 至 100% 使用表1之組成物，下表2的實施例便可藉由添加總 量2%之溶劑（其係爲2%胺基一甲基丙醇（AMP)或 1 %胺基甲基丙醇加入潛溶劑）而製成。該等組成物的安 本紙張尺度適用中國國家標準（CNS ) A4規格（210X 297公釐） (請先閱讀背面之注意事項再填寫本頁) Γ -19 - 517084 B7 五、發明説明（17) 定性係於5週貯存期間在常溫條件及在多種變化的溫度條 件下測量。變化的溫度條件爲： a )在攝氏一 1 5以下1 6小時及在攝氏2 5度8小 時下進行10次凍結熔化循環。 b)在攝氏4度下進行5週貯存。 c )在攝氏3 7度下進行5週貯存。 表2中，在開頭爲~ temp /那欄內標記失敗者係表示 試樣在至少一個有變化的溫度條件下貯存時會分開成二或 多個相。在開頭爲~ ambi /之攔內標記失敗係表示試樣在 常溫條件下貯存時會分開成二或多個相。具有Shellsol T及 萜二烯之實施例係本發明之具體實施例，而具有苄基醇， Butyl Digol [TM](二乙二醇單正—丁基醚）及 Dowanol PnB [TM](丙二醇單正-丁基醚）之實施例係比較性的，其可 顯示出，並非所有溶劑都可適用於本發明之實施。 -------- 會 II (請先閲讀背面之注意事項再填寫本頁)It public 7 9 2 517084 A7 B7 V. Description of the invention (16) Table 1 Printed substrate composition pHIO pH12 Sodium carbonate 3.13% 3.13%-Sodium bicarbonate 0.53% 0.53% Calcite 35.0% 35.0 % [OMY Acarb 30-AV: TM from OMYA] Alkylbenzene sulfonate 3.00% 3.00% [Petrelab 550: TM from Petresa] Coconut fatty acid 0.48% 0.48% [Prifac 7901: TM from Unichema] Non-ionic 7E〇1.50% 1.50% [Dobanol 23-6.5EO: from Shell company] Hydrochloric acid 0.26%-[2M from Fisons company] Sodium hydroxide 0.42% 1,2,3,3,3,3-tetraisothiazoline-3 -Ketones.016% .016% [Proxel GXL: TM from ICI] Fragrance 0.50% 0.50% [CL318A: TM from Quest] Water to 100% to 100% Use the composition of Table 1, and the composition of Table 2 below The embodiment can be made by adding a total of 2% of the solvent (which is 2% amino monomethylpropanol (AMP) or 1% amino methyl propanol added to the latent solvent). The Aberdeen paper size of these compositions applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) (Please read the precautions on the back before filling this page) Γ -19-517084 B7 V. Description of the invention (17) Qualitative measurements are made at room temperature and under varying temperature conditions during a 5-week storage period. The changing temperature conditions are: a) 10 freeze-thaw cycles are performed at a temperature of -15 ° C for 16 hours and at 25 ° C for 8 hours. b) Storage for 5 weeks at 4 ° C. c) Storage for 5 weeks at 37 ° C. In Table 2, failures marked in the column beginning with ~ temp / indicate that the sample will separate into two or more phases when stored under at least one changing temperature. The failure to mark in the box beginning with ~ ambi / means that the sample will separate into two or more phases when stored under normal temperature conditions. The embodiment with Shellsol T and terpene diene is a specific embodiment of the present invention, and has benzyl alcohol, Butyl Digol [TM] (diethylene glycol mono-n-butyl ether) and Dowanol PnB [TM] (propylene glycol mono The examples of n-butyl ether) are comparative, and it can be shown that not all solvents are applicable to the practice of the present invention. -------- Meeting II (Please read the notes on the back before filling this page)
、1T 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） -20- 517084， 1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs This paper size applies to China National Standard (CNS) Α4 specification (210X297 mm) -20- 517084
7 B 五、發明説明（18 ) 表2 :貯存結果 組成物 pHIO Ambi pHIO Temp pH12 Ambi pH12 Temp 基底+2% AMP 通過 失敗 通過 失敗 基底+1% AMP+1% ShellSol T 通過 通過 失敗 失敗 基底+1% AMP+1%萜二烯 失敗 失敗 通過 通過 基底+1% AMP+1% Dowanol PnB 通過 失敗 失敗 失敗 基底+1% AMP+1%苄基醇 失敗 失敗 通過 失敗 基底+1% AMP+1% Butyl Digol 失敗 失敗 失敗 失敗 (請先閲讀背面之注意事項再填寫本頁) 、r Γ 經濟部中央標準局員工消費合作社印裝 從上述結果中可看出，在Ρ Η 1 〇呈安定之組成物可 使用鏈烷（Shellsol Τ)做爲潛溶劑。在較高pH下，萜二 烯係較有效的潛溶劑。具有Shellsol-T及萜二烯之組成物二 者在堅硬污物上皆展現可接受的淸潔性能。以Dowanol PnB ，芊基醇，及Butyl Digol製備之組成物則在不同於常溫之 一或多個條件下都呈現不安定性。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐）7 B V. Description of the invention (18) Table 2: Storage results Composition pHIO Ambi pHIO Temp pH12 Ambi pH12 Temp substrate + 2% AMP failed to pass failed substrate + 1% AMP + 1% ShellSol T failed to pass failed substrate +1 % AMP + 1% Terpene Diene Failure Pass Pass Base + 1% AMP + 1% Dowanol PnB Pass Failure Fail Pass Base + 1% AMP + 1% Benzyl Alcohol Failure Fail Pass Pass Base + 1% AMP + 1% Butyl Digol Failure Failure Failure (please read the precautions on the back before filling out this page), r Γ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. From the above results, it can be seen that the stable composition in P Η 10 Alkanes (Shellsol T) were used as the latent solvent. At higher pH, terpene diene is a more effective latent solvent. Both the composition with Shellsol-T and terpene diene exhibit acceptable cleaning performance on hard soils. Compositions made with Dowanol PnB, fluorenyl alcohol, and Butyl Digol are unstable under one or more conditions different from normal temperature. This paper size applies to China National Standard (CNS) A4 (210X297 mm)