508368 A7 B7508368 A7 B7
五、發明說明（1 ) [發明所屬之技術領域] (請先閱讀背面之注意事項再填寫本頁} 本發明係關於一種使用電解離子水之方法，用以防止 使用於切削加工或研削加工等之水溶性切削油之腐敗、提 昇加工性能、並防止磨石所造成之孔堵塞。 [習知之技術] 切削加工係以較被加工物堅硬的刀具削掉被加工物中 不要的部份，以製成所期望之形狀的作業，但刀鋒容易因 摩耗而純化以致不能使用，此外，在切削點因變形會激烈 發熱，刀鋒因接觸高溫而將溶附碎屑或使刀鋒溶化。 研削磨石係將莫氏硬度9以上之研磨粒以結合劑固定 於圓板上，其表面則使少量的研磨粒的尖頭突出，以切削 工具來說，被認為是極多數之刀刃工具。其中一個研磨粒 切削被工作物的狀態係使研磨粒形成不規則形狀，且其大 小在5至4000μπι，但以其外框尺寸之數分之i形成從磨 石表面突出之刀刃。藉由刀刀之突出形態，以接近圓弧的 執跡進行摩擦擦過被工作物表面 '產生塑性變形、左右拱 起、取出切削屑之切削等作用。 經濟部智慧財產局員工消費合作社印製 雖然一般以切削工具切削之速度為10m至數1〇〇m/ 分，但研削時卻有1000至4800m/分左右之研削速度。因 而研磨粒刀刃附近之溫度達到1000。。以上的情況很多， 所以在各刀刃之間會發生切削屑等溶附而使磨石面之孔堵 塞。 很久以前因經驗累積，已知防止溶附或摩耗並減低摩 擦以油最為有利，亦已知在切削點上注下油即可獲得漂亮 311863 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作社印製 五、發明說明（2 ) — 的加工面。而現在， i ^ ^ 糸加上冲洗切削屑以及防止被加工物 肖，:作機械生錄等目的，切削加工時-定要使用油性之切 的單用油可分為習知所使用之鑛物油與動植物油 性齋f w 〇 /之非水溶性切削油；以及由鑛物油、介面活 類。’、胺類、無機系驗分、水等構成之水溶性切削油兩大 =㈣㈣料㈣油的非水溶㈣―㈣由 m械：程學的解析等而進一步改良，現在則販賣 上：二：]生此非常優良的切削油。但是’其基本的性質 亦：業時之冒煙、:引火、霧之產生等作業環境上的問題點 二：且’切削油的價格高昂，現在僅使用在重視加工 胃在“尺寸之齒輪’以及螺絲等整體形 之咖磨石、金剛石磨石之切削加工等有限: 之另一方面，因二次大戰後汽車產業及相關產業 二產方式確立連帶促使冷卻劑槽大型化而顯現預防 火之需要’石油危機所致之石油製m以Nc(以數 值控制進行零件加卫之工作機械）化及功能自動加工機器 (内藏自動工具交換裝置，也附有按照需要交換工具、且可 以以-台處理多種類之加工之工作機械裝置、也附有 裝置）為代表之自動化及省人卫化之潮流等，使水溶性切削 油大量破使用。現在之切削油之水溶性切削油佔有之 變得非常大。 … (請先閱讀背面之注意事項η I衣—— ί寫本頁) -151、» - 4 --線- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐 311863 508368 經濟部智慧財產局員工消費合作社印製 A7 五、發明說明（3 ) 另外，隨著水溶性切削油使用比率增加，因其 而產生腐敗的問題便接踵而至。水溶性切削油受到微生 的影響，將產生乳液之分離、凝集·沈殿之生成、惡臭物 白濁·變色、粘度降低、pH值的變化等現象、而降低： 水溶性切削油的性能、以致不得不進行更換。 … 、為解決這些問題而研討各種抗菌物質之添加，迄今雖 添加三哄系、嗎啉系、靖基甲院系、紛系等抗菌物質於水 溶性切削油中作為防腐劑，但即使藉由這些防腐劑的添 加，經過某段期間的使用，便經常可見腐敗之現象。 從腐敗之水溶性切削油，可檢驗出許多大腸桿菌 (Escherichia c〇li)、克雷白氏肺炎桿菌屬（幻化以以 pneumoniae) ' 副大腸桿菌種（Parac〇labactum sp )、普通變 形桿菌（Proteus vulgaris)、綠膿桿菌（Pseud〇m〇nas aeruginosa) ' 食油假單胞菌（pseud〇monas 〇ieovorans) ' 傷 冬桿菌（Salmonella typhosa)、金黃色葡萄球菌 (Staphylococcus aureus)等需氧性細菌。又，於週末等當機 械停止’液體不再流動時已知會繁殖脫硫脫硫弧菌 (Desulfovibrio desulfuricans)等厭氧性菌，並產生硫化氫而 成為惡臭之原因。甚至，綠膿桿菌、食油假單胞菌等之假 單胞菌屬菌係使以往之抗菌劑難以起作用，故需要可防止 這些細菌的繁殖之切削油。 [發明欲解決之課題] 於曰本特開2000-109865號揭示有一種藉由在水溶性 切削油中添加碘乙酸酯類及氨基配醣體類之某種藥劑，以 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 311863 裝--------訂---------線 (請先閱讀背面之注意事項再填寫本頁) 508368 A7 五、發明說明（4 防止水溶性切削油腐敗之方法。 仁疋，投入藥劑的方法，在腐敗的初期階段，雖可 延緩腐敗的進行，但卻難以有效地防止腐敗。而且，殺菌 力，的藥劑係混入之濃度_旦有誤，不僅作業者有危險， 在最後處理的時期，將有因為對活性污泥之微生物殺菌或 排水而對河川等生態帶來惡劣影響的危險。 此外，為稀釋水溶性切削油所使用的水因係地下水、 自來水、工業用水等，因此有混合前即有細菌存在等之問 題。 再者，為提昇切削性能，須要在切削油内添加乳化劑 以促進與水之乳化，但因水本身不具乳化作用，而無法進 行完全的乳液化，而有降低工具壽命的問題。 研削加工時，被加工物中的鐵與水溶性切削油中的水 反應時曰生成氫氧化亞鐵（Fe(〇H)2)，但此氫氧化亞鐵氧化 後會變成氫氧化鐵（Fe0(0H))。此氫氧化鐵因還原性強，所 以會生成如Fe-0-Fe之複合錯鹽，再縮合生成多核錯鹽， 然而此多核錯鹽因為係膠質狀之凝膠化物，因此由於2削 屑在磨石表面形成之凝膠化物附著於研磨粒之間，而成為 磨石之孔堵塞的原因。 本發明係以解決上述課題為目的。 [解決課題之方案] 本發明為達成上述之目的，提供一種水溶性切削油， 其特徵為：將氧化還原電位為_1〇〇mV至_1〇〇〇〇1^^之還原力 強的電解離子水混合於切削油中，以產生大量的氫氧化離 請 先 閱 讀 背 之 注 意 事 項V. Description of the invention (1) [Technical field to which the invention belongs] (Please read the precautions on the back before filling out this page} The present invention relates to a method of using electrolytic ionized water to prevent use in cutting processing or grinding processing, etc. Corrosion of water-soluble cutting oil, improve processing performance, and prevent blockage of holes caused by grinding stones. [Known Technology] Cutting is to remove unnecessary parts of the workpiece with a tool that is harder than the workpiece. The work is made into the desired shape, but the blade is easily purified due to wear and tear and cannot be used. In addition, the cutting point will be heated fiercely due to deformation. The blade will dissolve debris or melt the blade due to contact with high temperature. The abrasive particles with a Mohs hardness of 9 or more are fixed on the circular plate with a binding agent, and the surface of the abrasive particles protrudes a small number of abrasive particles. As a cutting tool, it is considered to be a very large number of blade tools. One of the abrasive particles The state of cutting the work is to make the abrasive particles have an irregular shape, and the size is 5 to 4000 μm, but it is formed from the surface of the grinding stone at a fraction of the size of the outer frame. With the protruding form of the knife, it rubs against the surface of the work object with friction near the arc, causing plastic deformation, arching left and right, and cutting chips. The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Although printing generally uses cutting tools to cut at a speed of 10m to 100m / min, the grinding speed is about 1000 to 4800m / min during grinding. Therefore, the temperature near the edge of the abrasive grain reaches 1000. The above conditions There are many, so the dissolution of cutting chips between the cutting edges will cause the holes of the grinding stone surface to block. A long time ago, due to the accumulation of experience, it is known that oil is the most beneficial to prevent dissolution or friction and reduce friction. It is also known to be used in cutting. You can get beautiful 311863 by injecting oil on the paper. The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm). Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. . And now, i ^ ^ 糸 plus flushing chips and preventing the object from being processed: for mechanical recording and other purposes, when cutting-must use a single oily cut It can be divided into conventionally used mineral oils and non-water-soluble cutting oils of animal and vegetable oily fastness fw 〇 /; and water-soluble cuttings composed of mineral oils, interface types. ', Amines, inorganic system test, water, etc. The two major oils are the non-aqueous solvents of the oil. The oil is further improved by the analysis of the mechanics: Cheng Xue and so on. Now it is sold on: Two:] This is a very good cutting oil. But its basic properties are also : Smoke in the industry,: Ignition, the generation of fog, and other problems in the operating environment. Point 2: "The price of cutting oil is high. Now it is only used to focus on the overall shape of the stomach, such as" size gears "and screws. Cutting of grinding stones and diamond grinding stones is limited: On the other hand, the need for fire prevention due to the establishment of secondary production methods in the automotive industry and related industries after World War II has led to the increase in the size of coolant tanks. Oil-based m is machined with Nc (working machine that reinforces parts by numerical control) and functions as an automatic processing machine (built-in automatic tool changer, also equipped with tool exchange as required, and can handle multiple units with one unit) Machining mechanical devices like the work, but also with the device) for the automation trend Province and other representatives of the health of the large number of broken water-soluble cutting oil use. The current water-soluble cutting oil of cutting oils has a very large share. … (Please read the precautions on the back first) -151, »-4 --line-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm 311863 508368) Economy Printed by the Intellectual Property Bureau of the Ministry of Intellectual Property Co., Ltd. A7. V. Invention Description (3) In addition, as the use rate of water-soluble cutting oils increases, the problem of corruption caused by them will follow. Water-soluble cutting oils are affected by microbiotics. It will cause the separation of the emulsion, the formation of agglomeration, the formation of Shen Dian, the white odor of the foul substance, the discoloration, the decrease in viscosity, the change in pH, etc., and reduce the performance of water-soluble cutting oil, so that it has to be replaced ... The problem is to study the addition of various antibacterial substances. Although so far, antibacterial substances such as three-coated system, morpholine system, Jingji academy system, and various systems have been added to water-soluble cutting oils as preservatives, but even with the addition of these preservatives, After a certain period of use, the phenomenon of corruption is often seen. From the corrupt water-soluble cutting oil, many Escherichia coli and Klebsiella pneumoniae rods can be detected. Genus Pneumoniae 'Paracolabactum sp', Proteus vulgaris, Pseudomonas aeruginosa 'Pseudomonas oeieovorans ) 'Salmonella typhosa, Staphylococcus aureus and other aerobic bacteria. Also, on weekends, when the machine stops, the liquid is no longer flowing and it is known to breed Desulfovibrio desulfuricans ) And other anaerobic bacteria, and generate hydrogen sulfide to cause malodor. Even Pseudomonas strains such as Pseudomonas aeruginosa, Pseudomonas edodes, and the like make it difficult for conventional antibacterial agents to work, so they need to be prevented. Cutting oil for propagation of these bacteria. [Problems to be Solved by the Invention] In Japanese Patent Application Laid-Open No. 2000-109865, there is disclosed a certain medicine by adding iodoacetates and aminoglycosides to water-soluble cutting oil. In accordance with this paper size, the Chinese National Standard (CNS) A4 specification (210 X 297 mm) is applicable. 311863 Packing -------- Order --------- line (please read the precautions on the back first) (Fill in this page again) 50 8368 A7 V. Explanation of the invention (4 Methods to prevent the water-soluble cutting oil from spoiling. Renji, a method of putting medicine, although it can delay the progress of corruption in the early stages of corruption, it is difficult to effectively prevent corruption. Moreover, bactericidal power The concentration of the medicament system is wrong. Once the operator is in danger, in the final treatment period, there will be a danger of adverse effects on the river and other ecology due to sterilization or drainage of microorganisms in activated sludge. In addition, the water used to dilute the water-soluble cutting oil is groundwater, tap water, industrial water, etc., so there are problems such as the presence of bacteria before mixing. Furthermore, in order to improve cutting performance, it is necessary to add an emulsifier to the cutting oil to promote emulsification with water. However, since water itself does not have an emulsifying effect, it cannot be completely emulsified, and there is a problem of reducing tool life. During the grinding process, iron in the workpiece reacts with water in the water-soluble cutting oil to form ferrous hydroxide (Fe (〇H) 2), but this ferrous hydroxide becomes iron hydroxide (Fe0) when oxidized. (OH)). This ferric hydroxide has strong reducing property, so it will generate complex complex salts such as Fe-0-Fe, and then condensate to form multi-core complex salts. However, this multi-core complex salt is a gelatinous gel, so the The gel formed on the surface of the grindstone adheres between the abrasive particles and becomes the cause of the clogging of the grindstone pores. This invention aims at solving the said subject. [Solution to solve the problem] In order to achieve the above-mentioned object, the present invention provides a water-soluble cutting oil, which is characterized in that the redox potential is from 100 mV to 100,000. Electrolyzed ion water is mixed with cutting oil to generate a large amount of hydroxide. Please read the precautions below.
頁 線 經濟部智慧財產局員工消費合作社印製 508368 A7 B7 經 濟 部 智 慧 財 產 局 員 工 消 費 合 社 印 製 五、發明說明（5 ) 子（OH )並包圍超越負電荷而與細菌混雜之構造蛋白質， 並藉由靜電力於相同符號之電荷間產生相互之排斥力，使 構？蛋白質剝落’使内部之核物質⑽A)亦流出，並消滅 細菌以防止液體的腐敗。 —而且，如第2圖所示，在低氧化還原電位的狀態，已知 菌無法生存。（參照東京大學出版會、「微生物生態入 服部勉著）。 」 又，本發明之水溶性切削油，其特微為：將水予以電解 而產生電解現象，以破壞氫的結合，使分子中之原子間距 離與Η-0-Η的角度產生些微的變化，並生成具有如陰離子 介面活性物質形狀之經基離子，由於該離子之介面活性作 用容易乳化，且使用電解離子水，而可促進乳化並提昇加 工性能 '而延長工具壽命。 ^外，本發明之水溶性切削油之特徵為：在研削加工 時，藉由使用還原性高之電解離子水，可抑制磨石與被加 ::::產生之氫氧化二鐵之氧化的產生，並抑制成為孔 土原因的多核錯鹽的生成，以防止磨石之孔堵塞。 本發明之水溶性切削油係藉由電解離子水生成裝置工 所獲得之水的PH值在8.0以上至13 〇以下，及/或 化退原電位為携mV至·⑽㈣之電解離子水以液面 液面管理’而送水於混合槽3内，當液面感測 器感測到適量時’則停止電解離子水的送水，再以定量泵 述切削油從切削油槽5送入’並以授掉機6邊授 拌邊此合而成者。 頁 訂 線 297公釐） 311863 508368 A7 --------- -- B7__五、發明說明（6 )[發明之實施形態] 以下說明發明之實施形態。 、在此使用之電解離子水係於原料使用自來水’將此水 通入軟水機2(日本練水（株）製ME_5S型、使用離子交換樹 脂：苯乙稀系強酸性離子交換樹脂（納形）），使妈離子濃度及 鎮離子濃度成為0.005mmol/dm3以下。並在此添加碳酸 鋼使奴酸納濃度成為2.0mmol/dm3。 於電解離子水生成裝置1之有隔膜電解槽進行上述之 水的電解，可獲得驗性水作$電解離子水。電解之條件係 施加電壓DC60V、電流密度]L〇A/dm2、生成量1L/分。 又，為比較而使用自來水（滋贺縣東淺井郡琵琶町之自來水）。 請 先 閱 讀 背 面 之 注 意 事 項Printed on page 508368 A7 by the Consumer Property Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Printed on the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 5. Description of the invention (5) (OH) and surrounded by structural proteins that are mixed with bacteria beyond negative charges. And the electrostatic force generates mutual repulsive force between the charges of the same sign, so that the structure? Protein exfoliation 'also causes the internal nuclear material ⑽A) to flow out and destroy bacteria to prevent liquid spoilage. -Furthermore, as shown in Figure 2, in a state of low redox potential, known bacteria cannot survive. (Refer to the Press Conference of the University of Tokyo, "Encouraged by the Microbial Ecology Service Department." In addition, the water-soluble cutting oil of the present invention is particularly characterized in that electrolysis is caused by electrolysis of water to break down the bond of hydrogen and make molecules in the molecule The distance between the atomic distance and the angle of Η-0-Η produces a slight change, and generates a radical ion with the shape of an active material such as an anionic interface. The surface active effect of the ion is easy to emulsify, and the use of electrolytic ionized water can promote Emulsify and improve processability 'while extending tool life. ^ In addition, the water-soluble cutting oil of the present invention is characterized in that: during the grinding process, the use of highly reducing electrolytic ionized water can inhibit the grinding stone and the added ferric hydroxide :::: Generates and suppresses the formation of multi-nucleus staggered salt, which is the cause of pore soil, to prevent the pores of the millstone from being blocked. The water-soluble cutting oil of the present invention is obtained by electrolyzed ionized water generating equipment, the pH value of the water is 8.0 or more and 1300 or less, and / or the ionization potential of the electrolyzed ionized water with mV to · ⑽㈣ The surface and liquid level are managed and water is sent to the mixing tank 3. When the liquid level sensor detects an appropriate amount, the water supply to the electrolytic ion water is stopped, and the cutting oil is fed from the cutting oil tank 5 with a quantitative pump. The machine 6 was blended while mixing. Page ordering 297 mm) 311863 508368 A7 ----------B7__V. Description of the invention (6) [Inventive embodiments] The following describes the embodiments of the invention. 2. The electrolytic ion water used here is based on the use of tap water as the raw material. This water is passed into a water softener 2 (ME_5S type manufactured by Nippon Nissui Co., Ltd.). Ion exchange resin is used: styrene-based strong acid ion exchange resin (nanoform )), So that the mother ion concentration and the town ion concentration are less than 0.005mmol / dm3. Carbonic acid steel was added here so that the concentration of sodium flavate was 2.0 mmol / dm3. The electrolysis of the above water was carried out in a diaphragm electrolyzer with an electrolytic ion water generating device 1, and test water was obtained as the electrolytic ion water. The conditions for the electrolysis were an applied voltage of DC60V, a current density of LOA / dm2, and a production amount of 1L / min. For comparison, tap water (tap water in Biwa-cho, Higashi Asai-gun, Shiga Prefecture) was used. Please read the notes on the back first
頁 切削油槽5内之切削油，係以規格為JISK 224i之评工 種之乳液型（emulsion type)與W2種之透明孔液型（s〇iubie type)分別作為水溶性切削油A、B。 經 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 如第1圖所示，以液面感測器7進行液面管理而由電 解離子水生成裝置1將上述電解離子水送入混合槽3内，當液面感測器7感測到適量時，則停止電解離子水的送 水，再以定量泵浦4將上述切削油從切削油槽5送入，並 以攪拌機6 —面攪拌一面混合而製造。此時之濃度為 至 20% 〇 將由上述製造裝置所製造之水溶性切削液，以進給泵 浦8送入需要切削液之車床加工機、多功能自動加機床等 加工機。 線The cutting oil in the cutting oil tank 5 is based on JISK 224i evaluation type emulsion type and W2 transparent hole fluid type (soiubie type) as water-soluble cutting oil A and B, respectively. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs as shown in Figure 1. The liquid level sensor 7 is used for liquid level management, and the electrolytic ionized water generation device 1 sends the electrolytic ionized water into the mixing tank 3. When the surface sensor 7 senses an appropriate amount, the water supply to the electrolytic ion water is stopped, and the above-mentioned cutting oil is fed from the cutting oil tank 5 by a fixed pump 4 and mixed with the agitator 6 while mixing. The concentration at this time is to 20%. ○ The water-soluble cutting fluid manufactured by the above-mentioned manufacturing device is fed into a processing machine such as a lathe processing machine, a multifunctional automatic processing machine, etc., which requires a cutting fluid, by a feed pump 8. line
本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 6 311863 )〇8368 A7 B7 五、發明說明（7 ) [實施例1] 關於細菌的繁殖、產生臭味之評定，係如下所述。 請 先 閱 讀 背 Sj 之 注 意 事 項 再* % * f裝 本 頁 將經過電解離子水及自來水稀釋之各水溶性切削油 A、B移至30ml之玻璃器皿中，並以取下各玻璃器皿之蓋 子的狀態放置於屋外24小時後，蓋上蓋子，並保持在37〇c 之恒溫槽内4天及7天。 然後，將上述各液體，按照標準瓊脂平板培養法檢測一 般細菌數（生菌數），而按照GAM瓊脂平板厭氧培養法分別 進行測1，關於臭氣，則係將水溶性切削液放置於容量2〇L 之槽内，並於測量臭氣時，使液體起泡而產生空氣並使用 臭氣計測器（創造系統股份有限公司之c_GC_329高感度氧 訂 化錫系、熱線型燒結半導體感測器）而將該空氣的臭氣數值 化。將其結果顯示於表1。 | [表1] 如表1所示，將電解離子水與自來水比較，其滅菌率 ^ 在99%以上，可知隨天數經過，其繁值率亦低。又，關於 | 臭氣，比較7天後之切削油a時，相對於自來水的臭氣 | 緩濟邹智慧財產局員工消費合作社印製 1879，電解離子水的臭氣215為其ι/8以下，因此可知有 |This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 6 311863) 08368 A7 B7 V. Description of the invention (7) [Example 1] Evaluation of the reproduction of bacteria and the production of odor, It is as follows. Please read the precautions for backing Sj first. *% * F This page will move each water-soluble cutting oil A, B diluted with electrolytic ion water and tap water to 30ml glassware, and remove the cover of each glassware. After being left outside for 24 hours, the lid was closed and kept in a constant temperature bath at 37 ° C for 4 and 7 days. Then, each of the above liquids was tested for the general number of bacteria (the number of bacteria) according to the standard agar plate culture method, and each of them was measured according to the GAM agar plate anaerobic culture method. For the odor, the water-soluble cutting fluid was placed in In a tank with a capacity of 20L, and when measuring odor, the liquid is bubbled to generate air, and an odor measuring device (c_GC_329 high-sensitivity oxygen-ordered tin-based, hot-wire sintered semiconductor sensor of Chuang GC) is used. Device) and the odor of this air is quantified. The results are shown in Table 1. [Table 1] As shown in Table 1, when comparing electrolytic ion water with tap water, the sterilization rate ^ is more than 99%. It can be seen that the value rate is also low with the passage of days. Regarding the odor, compared with the odor of tap water when cutting oil a 7 days later, it was printed by Yuji Zou Intellectual Property Bureau employee consumer cooperative 1879, and the odor of electrolytic ion water was 215/8 or less , So we know that |
抑制臭氣發生的效果。 IThe effect of suppressing the occurrence of odor. I
[實施例2] ! 關於加工性能、工具壽命，係利用以電解離子水及自 | 來水稀釋之各水溶性切削油a、b，以多功能自動加工機 i 床連續進行鑽孔加工，並且以鑽頭（drillbit)的壽命來判 | 斷。鑽頭係使用直徑6mm、旋轉數為28〇〇rpm、進給速度 | 311863 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐 508368 A7 五、發明說明（8 ) 為0.1mm/次來進行。被加工之鋼鈑的材質係S4〇〇、厚度 為 3〇mm 〇 將其結果顯示於表2。 [表2] 如表2所示’從工具壽命方面來看，與自來水比較， 可知與切削油之乳化性佳的電解離子水可進行2倍以上之 孑匕力ϋ J1 〇 [實施例3] 關於研削性、磨石孔堵塞，係利用以電解離子水及自 來水稀釋之各水溶性切削油A、Β，以橫軸角桌平面磨床， 利用A46K磨石連續進行研磨加工，並藉由因磨石之孔堵 塞所進行之整修次數來判斷。磨石輪直徑係使用p 2〇5mm、圓周速度為1500〇1/分、進給速度為〇 lmm/次來 進行研磨。被加工之鋼鈑的材質為S400，厚度為3〇mm。 結果如表3所示。 [表3] 如表3所示，從磨石之孔堵塞方面來看，與自來水比 經濟部智慧財產局員工消費合作社印製 較起來，可知還原力高的電解離子水可不需整修而進行研 削加工。 [發明之效果] 本發明之效果，係由於使用電解離子水做為水溶性切 削油之溶媒，而可消除細菌的繁殖或隨著細菌繁殖而來的 異臭。而且，因不須添加有害的防腐劑，可有一個對於人 和環境融和之工作場所。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 8 311863 A7 五、發明說明（9 ) 而且，在加; _i_ 曲中’即使水溶性切削油中之乳化劑消 失電解離子水所保有之乳化性仍將持續，因此亦可不降 低加 〖生犯而延長工具壽命，而提供更能適應於自動控制 加工機之水溶性切削油。 使用還原性高的電解離子水，可抑制磨石與被加丨 工物之間所產+ > , $ 〖 ^ 氧氧化亞鐵之氧化的產生，並抑制成為： 土的原因之多核錯鹽的生成，以防止磨石之孔堵塞。 此外自於係產生具有如陰離子介面活性物質之形狀的羥 :離子®其表面張力小、浸透性優良，故可獲得除去切 削屑之最高效果。 [圖式之簡單說明] 第1圖係將電解離子水與水溶性切削油混合並製造之 步驟之說明圖。 第2圖係相對於水之pH值與氧化還元電位之細菌之 ··[元件符號說明] 電解離子水生成裝置 混合槽 切削油槽 液面感測器 生存範圍（斜線部）的說明圖。 5 7 軟水機 定量泵浦 攪拌機 進給泵浦 311863 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 508368 五、發明說明（10 ) j希釋水 切削油 切削油雜 (%) 曰數 —'fe細菌數 (個/ml> 厭氧性培養菌數 (個/ml} 臭氣 電解離子水 ------- A 5 初期值 0 0 0 5 4日 1.6x 102 3·6χ 10 15丰 5 7曰 2.3x 102 5.6χ 10 215 B 5 初期值 σ 0 0 5 4曰 3.6χ 102 4.6χ ΙΟ2 278 5 7曰 4·3χ ΙΟ2 5.1χ ΙΟ2 380 自來水 A 5 初期值 4.2χ ΙΟ7 2.5χ 1〇6 982 5 4 9. 5,2χ ΙΟ9 4.6χ ΙΟ9 1286 5 7 B 7.8χ ΙΟ12 S.4x ία11 1879 B 5 相斯值 5.6χ 10^ 5.2χ ΙΟ6 1232 5 4 a 3.1χ 1〇8 7.5χ ΙΟ8 1589 5 7 & 5.&χ ΙΟ11 2.7χ ΙΟ11 1972 (請先閱讀背面之注意事項再填寫本頁) 切削油 A (emulsion type、 JIS K 2241 W1 種） 切削油 B (soluble type、 JIS K 2241 W2 種） [表2] 1 孓希驊水 切削油 切削油:¾¾ (%) 鑽孔加工數 (部位） 電解離子水 A 、5 256 B 5 225 自來水 A 5 123 B 5 110 經濟部智慧財產局員工消費合作社印製 切削 _ A (emulsion type、 JIS K 2241 W1 種） 切削冷 B (soluble type、JIS K 2241 W2 種） 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 10 311863 508368 A7 _B7 五、發明說明（11 ) [表3] 希釋水 切削油 切削油 (%) 整修次數 (次） 電解離子水 A 5 0 B 5 0 自來水 A 5 5 B 5 7 切肖U 油 A (emulsion type、 JIS K 2241 W1 種） 9 切削油 B (soluble type、 JIS K 2241 W2 種） -------------— (請先閱讀背面之注意事項再填寫本頁) .. 丨線· 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 11 311863[Example 2]! For machining performance and tool life, the water-soluble cutting oils a and b diluted with electrolytic ion water and tap water were used to continuously perform drilling operations on a multifunctional automatic processing machine i bed, and Judging by the life of the drillbit The drill bit uses a diameter of 6mm, the number of rotations is 2800 rpm, and the feed speed | 311863 This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm 508368 A7) 5. Description of the invention (8) is 0.1mm / The results are shown in Table 2. [Table 2] As shown in Table 2, 'From the perspective of tool life, compared with tap water, the results are shown in Table 2.' It can be seen that the electrolytic ionized water with good emulsifying property with cutting oil can be doubled. J1 〇 [Example 3] About the grindability and clogging of grindstone holes, each of them is diluted with electrolytic ionized water and tap water. Water-soluble cutting oil A, B, horizontal axis angle table surface grinder, using A46K grinding stone for continuous grinding, and judged by the number of repairs due to the blockage of the grinding stone. The diameter of the grinding wheel uses p 2 〇5mm, peripheral speed is 1500/1 / min, and feed speed is 0.001mm / time for grinding. The material of the processed steel sheet is S400 and the thickness is 30mm. The results are shown in Table 3. [Table 3 ] As shown in Table 3, in terms of the blockage of the pores of the millstone, compared with the tap water Compared with the printing by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, it can be seen that electrolytic ionized water with high reducing power can be processed without refurbishing. [Effects of the Invention] The effect of the present invention is due to the use of electrolytic ionized water for water-soluble cutting. It is a solvent for oil, which can eliminate the breeding of bacteria or the odor caused by the breeding of bacteria. In addition, because it does not need to add harmful preservatives, it can have a workplace that is harmonious with people and the environment. This paper size applies to Chinese national standards (CNS) A4 specification (210 X 297 mm) 8 311863 A7 V. Description of the invention (9) Moreover, in addition; _i_ Quzhong 'even if the emulsifier in the water-soluble cutting oil disappears, the emulsification retained by the electrolytic ionized water is still It will last, so it can also extend the tool life without reducing the production of offenses, and provide a water-soluble cutting oil that is more suitable for automatic control of processing machines. The use of highly reduced electrolytic ionized water can suppress grinding stones and processing Produced between objects + >, $ 〖^ Oxidation of ferrous oxide and inhibition of the formation of: Multi-nucleus-salt formation of soil causes to prevent the formation of millstones The pores are clogged. In addition, since the hydroxy: ion®, which has the shape of an active material such as an anionic interface, is produced, the surface tension is small and the permeability is excellent, so the highest effect of removing cutting chips can be obtained. [Simplified description of the drawing] Figure 1 It is an explanatory diagram of the manufacturing process of mixing electrolytic ion water with water-soluble cutting oil. The second figure is the bacteria of the pH value and redox potential of water. [Element symbol description] Mixing tank of electrolytic ion water generating device Explanatory diagram of the survival range (slashed line) of the liquid level sensor of the cutting oil tank. 5 7 Water softener metering pump Mixer feed pump 311863 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 508368 V. Description of the invention (10) j Greek release water cutting oil cutting oil miscellaneous (%) number-'fe bacteria number (pcs / ml > number of anaerobic culture bacteria (pcs / ml) odor gas ionized water --- ---- A 5 initial value 0 0 0 5 4 days 1.6x 102 3 · 6χ 10 15 Feng 5 7 2.3x 102 5.6χ 10 215 B 5 initial value σ 0 0 5 4 3.6 3.6 102 4.6χ ΙΟ2 278 5 7th 4 · 3χ ΙΟ2 5.1χ ΙΟ2 380 Tap water A 5 Initial value 4.2 χ ΙΟ7 2.5χ 1〇6 982 5 4 9. 5, 2χ ΙΟ9 4.6χ IO9 1286 5 7 B 7.8χ ΙΟ12 S.4x ία11 1879 B 5 Phase value 5.6χ 10 ^ 5.2χ IO06 1232 5 4 a 3.1χ 1 〇8 7.5χ ΙΟ8 1589 5 7 & 5. & χ ΙΟ11 2.7χ ΙΟ11 1972 (Please read the precautions on the back before filling this page) Cutting oil A (emulsion type, JIS K 2241 W1) Cutting oil B ( soluble type, JIS K 2241 W2) [Table 2] 1 孓 Greek water cutting oil cutting oil: ¾¾ (%) Number of drilling operations (parts) Ionized water A, 5 256 B 5 225 Tap water A 5 123 B 5 110 Printed by a consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs_ A (emulsion type, JIS K 2241 W1 type) Cutting cold B (soluble type, JIS K 2241 W2 type) This paper size applies Chinese National Standard (CNS) A4 specifications ( 210 X 297 mm) 10 311863 508368 A7 _B7 V. Description of the invention (11) [Table 3] Greek release water cutting oil Cutting oil (%) Number of repairs (times) Ionized water A 5 0 B 5 0 Tap water A 5 5 B 5 7 Cutting oil U (Amulsion type, JIS K 2241 W1) 9 Cutting oil B (soluble type, JIS K 2241 W2) -------------— (Please read the precautions on the back before filling this page). China National Standard (CNS) A4 Specification (210 X 297 mm) 11 311863