TW503606B - Method to manufacture electric contact plate - Google Patents

Method to manufacture electric contact plate Download PDF

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Publication number
TW503606B
TW503606B TW090110932A TW90110932A TW503606B TW 503606 B TW503606 B TW 503606B TW 090110932 A TW090110932 A TW 090110932A TW 90110932 A TW90110932 A TW 90110932A TW 503606 B TW503606 B TW 503606B
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Taiwan
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manufacturing
scope
patent application
item
sheet
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TW090110932A
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Chinese (zh)
Inventor
Martin Wollny
Karl-Heinz Dulle
Jurgen Gegner
Thomas Borucinski
Reinhard Muller
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Krupp Uhde Gmbh
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Publication of TW503606B publication Critical patent/TW503606B/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/20Bonding
    • B23K26/32Bonding taking account of the properties of the material involved
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/20Bonding
    • B23K26/21Bonding by welding
    • B23K26/24Seam welding
    • B23K26/244Overlap seam welding
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60Constructional parts of cells
    • C25B9/65Means for supplying current; Electrode connections; Electric inter-cell connections
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2101/00Articles made by soldering, welding or cutting
    • B23K2101/36Electric or electronic devices
    • B23K2101/38Conductors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/08Non-ferrous metals or alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/08Non-ferrous metals or alloys
    • B23K2103/10Aluminium or alloys thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/08Non-ferrous metals or alloys
    • B23K2103/12Copper or alloys thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/08Non-ferrous metals or alloys
    • B23K2103/14Titanium or alloys thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/18Dissimilar materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/50Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Electrochemistry (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laser Beam Processing (AREA)
  • Connections Effected By Soldering, Adhesion, Or Permanent Deformation (AREA)

Abstract

The present invention relates to a method to manufacture electric contact plate an metallic wall, which is made of surface oxidation prone material, such as for example Titan thin plate or aluminium, and is especially used to manufacture electrolysis devices, a solution should be established, which provide for this the basic material, for example Titan thin plate, which itself does not contain especially good electric conductively and contact property, and is provided with an applied with a material that has very good electric conductivity. And this is achieved by the following manners; two conductive wires made of good electrically conductive materials are applied on a Titan thin plate by means of laser-print-soldering, and the contact plate thus produced is fixed on the to-be-prepared thin plate by means of laser-soldering in a well know manner.

Description

503606 五503606 five

本發明是有關於一種方法用於製 _迫由表面容易氧化 的材料所構成之金屬壁上之電件接觸 坟丨掏,此種材料像是 例如鈦薄片或鋁,尤其是用於製造電解裝置。 若沒有本發明之受限於以電解裝置^造~由稀薄齡— 國素-溶液所產生t鹵素氣體,則s其製造中會例如產 問題,因爲此裝置由半殻體所製成,其組成單元並且 然後組成封裝,其中各自後壁定位於前壁上,並且必須 確保由一壁至另一壁上之電性通路。 例如由申請案w Ο 9 8 / 1 5 0 7 5是所熟知的電解裝置與 其製造方法,其中在此設有在彼此接觸中所存在之壁上 之接觸片,其在雷射一焊接方法中塗佈。 若此製造方式已經具有顯著的優點,因而在其中存在 此問遇,即製造此種接觸片較爲昂貴。因此例如借助於 噴灑fe鍍而將鎳薄片塗佈在鈦薄片上,此由兩種金屬所 構成的板被切割成片,並且需在鎳層中在縱方向中銑切 成深的溝槽,使得位於其下的鈦薄片一起被銑切,因此 鎳片被定位於大約U型的鈦底座上。此接觸片然後被 焊接·於其上。關於習知技術請另外參閱美國專利文件 USP3610874,4108752,4414444,41687264,5315758,以及 德國專 ί;丨文件 D E - 2 4 4 8 7 1 3 - A 1 與 D E 3 9 0 1 3 1 9 - A 1。 @ 1H:相對的本發明的目的是建立一種解決方案,其對 此提供一種基本材料(例如是以上所提到的鈦薄片),其 本# Μ +具有特別良好之導電質接觸性質,具有所設或 塗層的材料,其非常良好之導電能力,以便產生最適之 ——_ g修正! I 丨 、u —、一: A、發明説明(2) ^ ® /t,具^以在此到處被使用(在該處使用金屬), 其用於容易氧化之表-面。 . 以、一ίΐ ί - Μ $台所插述特質的方法,此目的根據本發 曰月以以下的方式而解決,即借助於雷射-印刷_焊接,將兩 _$#«&纟?1^#料所構成的導線塗佈在鈦薄片上,並 & @ lit S t @接觸片,如同以本發明熟知的方式,借 助於雷射焊接固定於此等備製的薄片上。The present invention relates to a method for making electrical parts on a metal wall made of a material that is easily oxidized on the surface, such as, for example, titanium flakes or aluminum, especially for the manufacture of electrolytic devices. . If the invention is not limited to the use of an electrolytic device to manufacture ~ t halogen gas produced by a thin age-state-solution, there will be problems such as production, because this device is made of a half-shell, which The unit is composed and then packaged, with the respective rear wall positioned on the front wall, and an electrical path must be ensured from one wall to the other. For example, the application w 0 9 8/1 5 0 7 5 is a well-known electrolytic device and a method for manufacturing the same. Here, a contact piece on a wall existing in contact with each other is provided, which is used in a laser-welding method. Coated. If this manufacturing method already has significant advantages, there is a problem therein, that is, it is relatively expensive to manufacture such a contact sheet. Therefore, for example, a nickel foil is coated on a titanium foil by spraying Fe plating. This plate composed of two metals is cut into pieces, and deep grooves need to be milled in the nickel layer in the longitudinal direction. The titanium sheet underneath was milled together, so the nickel sheet was positioned on a U-shaped titanium base. This contact is then soldered onto it. Please refer to the US patent documents USP3610874,4108752,4414444,41687264,5315758, as well as the German patents for the conventional technology; 丨 documents DE-2 4 4 8 7 1 3-A 1 and DE 3 9 0 1 3 1 9-A 1. @ 1H: The object of the present invention is to establish a solution, which provides a basic material (such as the titanium flakes mentioned above), which has # Μ + which has particularly good conductive contact properties, Design or coating material, its very good electrical conductivity, in order to produce the most suitable --_ g correction! I 丨, u —, a: A, description of the invention (2) ^ ® / t, with ^ here and there Used (where metal is used) for surface-surfaces that are prone to oxidation. The method of traits interpolated by Yi, Yi ί ί-Μ $ 台, this purpose is solved according to the present month in the following way, that is, by means of laser-printing_welding, the two _ $ # «& 纟? The wire composed of the 1 ^ # material is coated on a titanium sheet, and the < lit litt > contact sheet is fixed to these prepared sheets by laser welding in a manner well known in the present invention.

JiUI » Ϋ t方法步驟可以達成,將此借助於雷 ¥ -φ刷-焊接所塗佈之導線(其例如是由銅所構成)以最 @ @ ~方β @ f,而沒有介於鈦薄片與銅之間的氧化物層 的存在。 1 itb K _ Ψ設有,此由鈦薄片所構成之接觸片與銅錳 (CuMn)線在電射-印刷-焊接方法中製成。此根據本發 曰月Ji述的方、法,使得可以藉由將薄片或線圈之線展開而 實施連續的製造。 丰艮丨廉# {吏用目的是可以合理地另外設有焊料,其中此 # Μ & it @是根據以銀爲主,它可以直接作爲接觸材料 $胃作s介於基本材料(像是例如鈦),與原來真正的接 觸材料(像是例如鎳)之間的中間層。 ‘.· ^遮1合使用具有可結合氧之成份之金屬作爲接觸材 料,像是錳或鋁,以建立無氧化物之結合區。 · 以下述方式設計:感應式加熱區連接於各材 料*之連結區之前,及/或連結區以及預先加熱區保持在 保護氣體或真空下以防止大氣之侵入。 503606 五、發明説明(3 ) 本發明以下根據圖式作進一步說明。 圖式之簡單說明 * 第1至4圖是經由雷射-印刷-焊接之接觸片之橫截 面,此片具有其扁平位於其上以雷射焊接之在電解裝置 之鈦製後壁上之連結。 第5與6圖是彈性實施變化例之橫截面。 此簡化描述之截面圖式共同顯示,以1代表接觸片, 其由具有焊接於其上之銅線3之鈦薄片2所構成,其中 此接觸片2/3在未進一步說明之電解裝置之以4代表 之後壁上,借助於連續的雷射焊接經由接縫5而固定, 並且在此以6代表的電流隔片的區域中,或許再度的由 鈦所構成。 在第1圖中說明雷射焊接,而在第2圖中說明接觸片 2之雷射-印刷-焊接,其在這方面功能相同的部份在圖 中具有相同的參考號碼。 除了在第1與2圖中說明之外,在第3與4圖中說明 此接觸片作爲矩形橫截面之片,它在此具有參考號碼3’, 其中在第4圖中以及還有在第5與6圖中另外設有介 於接觸片3或3 ’與鈦薄片2之間的共同以7代表之另 外的焊料。 當然,此所說明的本發明之實施例還有在多方面之修 改是沒有背離其基本思想。因此本發明並未受到在此 所描述之幾何形狀的限制,亦不受各個材料之限制,其 中此在說明書中提及者在此特別適合。 503606 五、發明説明(4 ) 符號說明 1 ...接觸片 2.. .鈦薄片 3 ...銅線JiUI »Ϋ t method steps can be achieved, this is achieved by means of thunder ¥ -φ brush-welding of the coated wire (which is made of copper, for example) with the most @ @ ~ 方 β @ f without intervening in titanium The presence of an oxide layer with copper. 1 itb K _ It is provided that the contact sheet composed of titanium flakes and copper-manganese (CuMn) wires are made in the radio-printing-welding method. According to the method and method described in the present invention, continuous manufacturing can be performed by unfolding a sheet or coil wire.丰 根 丨 廉 # {The purpose of the official use is to reasonably provide additional solder, where # M & it @ is based on silver, which can be directly used as a contact material. Stomach is used as a basic material (like (Such as titanium), an intermediate layer between the original real contact material (such as, for example, nickel). ^. ^ 1 uses a metal with a component that can bind oxygen as the contact material, such as manganese or aluminum, to establish an oxide-free bonding zone. · Designed as follows: the induction heating zone is connected before the connection zone of each material *, and / or the connection zone and the pre-heating zone are kept under a protective gas or vacuum to prevent the intrusion of the atmosphere. 503606 V. Description of the invention (3) The invention will be further described below with reference to the drawings. Brief description of the drawings * Figures 1 to 4 are cross sections of a contact sheet via laser-print-welding, which has a flat connection on the titanium rear wall of the electrolytic device, which is flat and laser-welded. . Figures 5 and 6 are cross-sections of modified examples of elasticity. The simplified cross-section diagrams together show that 1 represents a contact piece, which is composed of a titanium sheet 2 with a copper wire 3 welded thereto, wherein this contact piece 2/3 is used in an electrolytic device that is not further explained 4 represents the rear wall, which is fixed by means of continuous laser welding via seam 5, and in the area of the current separator represented by 6, it may be composed of titanium again. The laser welding is illustrated in FIG. 1, and the laser-printing-welding of the contact piece 2 is illustrated in FIG. 2. The parts having the same functions in this regard have the same reference numbers in the drawings. In addition to the illustrations in Figures 1 and 2, this contact piece is illustrated in Figures 3 and 4 as a rectangular cross-section piece, which has the reference number 3 ', which is shown in Figure 4 and also in Figure 4. In Figs. 5 and 6, there is additionally provided another solder, commonly represented by 7, between the contact piece 3 or 3 'and the titanium sheet 2. Of course, the embodiment of the present invention described here can be modified in many aspects without departing from its basic idea. Therefore, the present invention is not limited by the geometric shapes described herein, nor is it limited by the individual materials, among which those mentioned in the specification are particularly suitable here. 503606 V. Description of the invention (4) Symbol description 1 ... contact sheet 2. .. titanium sheet 3 ... copper wire

3 ’…片 4…後壁 5…接縫 6 ...電流隔片 7.. .焊料 -6-3 ’… piece 4… rear wall 5… seam 6… current separator 7 .. solder -6-

Claims (1)

503606503606 六、申請專利範圍 第901 1 0932號「電性接觸片之製造方法」專利案 (91年7月修正) 六申請專利範圍 1· 一種電性接觸片之製造方法,此片在金屬壁上,由表面 容易氧化的材料,例如由鈦薄片或鋁所構成,其特別是 用於製造電解裝置,其特徵爲, 借助於雷射-印刷-焊接,將兩個由導電良好之材料所 構成之導線塗佈在鈦薄片上, 且這樣所產生的接觸片,借助於雷射焊接,以已爲人 所熟知的方式固定於此待備製的薄片上。 2. 如申請專利範圍第1項之製造方法,其中 由鈦薄片所構成的接觸件與銅錳(CuMn)線以雷射-印刷 -焊接方法製成。 3. 如申請專利範圍第1或2項之製造方法,其中 連續地藉由薄片或線圈之線的展開來進行此種製造方 法。 4·如申請專利範圍第1項之方法,其中另外塗佈一種以銀 爲主的焊接材料。 5.如申請專利範圍第1或2項之製造方法,其中接觸材料 係使用具有可結合氧之成份之金屬(如錳或鋁),以設立 無氧化物之連結區。 6·如申請專利範圍第5項之製造方法,其中感應式加熱區 連接於各材料之連結區之前。 7·如申請專利範圍第6項之製造方法,其中此連結區及/ 503606 、申請專利範圍 或預先加熱區是保持在保護氣體或真空下以防止大氣侵 入。 8.如申請專利範圍第1或2項之製造方法,其中藉由基本 材料之預先變形(例如成爲V形)而與彈簧作用形成接觸。 -2-6. Application for Patent Scope No. 901 1 0932 “Method for Manufacturing Electrical Contact Sheet” (Amended in July 91) 6. Application for Patent Scope 1. A method for manufacturing electrical contact sheet, this sheet is on a metal wall, It is composed of a material that is easily oxidized on the surface, such as titanium flakes or aluminum. It is especially used in the manufacture of electrolytic devices. It is coated on a titanium sheet, and the contact sheet thus produced is fixed on the sheet to be prepared in this manner by means of laser welding. 2. The manufacturing method according to item 1 of the scope of patent application, wherein the contacts made of titanium flakes and copper-manganese (CuMn) wires are made by laser-printing-welding method. 3. The manufacturing method according to item 1 or 2 of the patent application scope, wherein the manufacturing method is performed continuously by unfolding of a sheet or a coil wire. 4. The method according to item 1 of the patent application scope, wherein a coating material mainly composed of silver is additionally coated. 5. The manufacturing method according to item 1 or 2 of the scope of patent application, wherein the contact material is a metal (such as manganese or aluminum) with a component that can bind oxygen to establish an oxide-free connection zone. 6. The manufacturing method according to item 5 of the patent application range, wherein the induction heating zone is connected before the connection zone of each material. 7. The manufacturing method according to item 6 of the scope of patent application, wherein the connection area and / 503606, the scope of patent application or the pre-heating area are kept under a protective gas or vacuum to prevent atmospheric invasion. 8. The manufacturing method according to item 1 or 2 of the scope of patent application, wherein the contact with the spring action is made by the pre-deformation of the basic material (for example, becoming a V shape). -2-
TW090110932A 2000-05-09 2001-05-09 Method to manufacture electric contact plate TW503606B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10022604A DE10022604A1 (en) 2000-05-09 2000-05-09 Production of electrical contact strips on metallic walls made from materials having tendency towards surface oxidation comprises applying two conductor wires onto sheet titanium strip, and fixing using laser welding

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Publication Number Publication Date
TW503606B true TW503606B (en) 2002-09-21

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AR (1) AR028433A1 (en)
AU (1) AU2001268990A1 (en)
DE (1) DE10022604A1 (en)
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WO (1) WO2001085388A1 (en)

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US10407783B2 (en) 2016-05-26 2019-09-10 Calera Corporation Anode assembly, contact strips, electrochemical cell, and methods to use and manufacture thereof

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AU2001268990A1 (en) 2001-11-20
DE10022604A1 (en) 2001-11-29
AR028433A1 (en) 2003-05-07

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