TW494061B - Additive biocalcareous elastorubber material - Google Patents

Abstract

This invention is an additive biocalcareous elastorubber material. It consists of up layer and down layer which is fabric or nonwoven or netting fabric. The middle layer is the nature biomaterial that has additive sulfur rubber slice or bubbled rubber which are mixed and becomed an additive biocalcareous elastorubber material. It has two sides with the coating bioadhesive to contract with up layer and down layer. The characteristics are: (1) bioadditive sulfur rubber slice; the sulfur rubber is made of mixing shellfish and spiral shell which was additived to use no fixed weight of certain percentage. (2) Biobubbled rubber; the rubber is made of mixing shellfish and spiral shell which was additived to use no fixed weight of certain percentage. (3) Bioadhesive; the adhesive is made of mixing shellfish and spiral shell which was additived to use no fixed weight of certain percentage and no affect to the bonding strength. The structure of this biomaterial can make product to reduce waste material, meet environment protection, increase original properties and reduce cost. The product is applicated to diving suit, surfing suit, fishing wader, protected knee pads, shoe and lining mat or other sports equipment.

Description

^ 4061

[Field of the invention]: The date and month of this issue are based on a #timing> biotransformation = ", which is composed of biorecyclable materials, rubber (plastic) rubber materials and beans ~ two = together, through a vulcanizing machine or The foaming machine is shaped as follows: ^ 4. Additive tablets or biological elastomers with biological foams, and then vulcanized rubber: two: coating and blending with bio-recyclable materials, and then with cloth The traditional traditional rubber (plastic) rubber foam body is attached as described in the previous technology. The structure is shown in Figure 1. Its structure contains a cell 11 and calcium carbonate Γ, ^, as a requirement to increase its physical properties. During the preparation, the fillers (carbonic acid words, white clay) of σ and σσ are used to achieve an incremental effect or blended with 1 = Juhua treatment reinforcement (active calcium carbonate, stone dioxide, etc.) ^ Most of the sources are taken from natural minerals And it is separately refined, which has a serious impact on both self-deficit and environmental protection, not to mention that fillers have a reinforcing effect = low, only for the effect of increasing and reducing costs, while foams are more commonly used in split $ An uneven structure with a concave surface is formed on the surface. Up effect, who must rely on the adhesive solid content itself, ... (solid content) 'relatively uneconomical cost considerations, and is the ^

Excellent bonding effect of cloth ’The solid component in the bonding agent must have a keying effect on the hole formation of the foam body.

Cheng Shi '4 The proportion of glue must be increased and its cost will increase. [Objective of the invention]: "Biological elastic body, when developed into a human waste discarded as a biological (plastic) glue additive, can be said The main purpose is to describe the lack of fittings of the biological vitality of biological organisms whose structures are different from those of other biological materials-a kind of "technological thing, from the emphasis on foaming materials to materials that have biological elasticity and elasticity." The physical properties are mentioned in the Sheng style. If you talk about the full "production of the rubber loss problem, you can make progress in recycling. In this life, you add this hair, which means" reducing the elasticity of the body and providing the integration of the two bodies to achieve production. " The shell of Taiwan ’s shell is a ground plastic (plastic) colloid. ”The lack of calcium in this hair has replaced the original cost in the waste disposal plan, as shown in the figure. In the southwestern part of waste reduction, 'there is no material, physical material foam'. At the same time, in view of the foregoing requirements of rubber (plastic) rubber foaming to reduce waste and reduce costs, the structure of elastic rubber The resources on the earth are transformed into a consciousness project, so that if the waste produced by living things is used in industry, it can be called 'add this biological material to the synthetic materials of oak or natural resources and reduce waste The “section” or other special function 2 is a cross-sectional view of the elastic material of the physical material of the present invention, which is mainly an adhesive and adheres to the cloth surface layer. It is also added with biological materials to improve% guarantee and reduce costs. Function. Sea oysters, shellfish, clams, and edibles are not discarded as waste. However, in view of this, recycling in the chemical industry is as good as combining the chemical industry. Features:

494061 V. Description of the invention (3) (1). To solve the problem of inability to decompose shell waste and occupy the shoreline and cause pollution. (2). Can fully recover biological materials. (3). Solve the dilemma that fishermen cannot discard abandoned shells and beautify the scenery of the coast of Taiwan. (4). Reinforcing the physical properties of raw rubber (plastic) rubber foam. (5) Reduce costs. (6) Reduce the ecological environment damage caused by mining. The content of the present invention is illustrated with the illustrations and figures below: [Icons and figures]: [Icons] ... Figure 1: Sectional view of the original foam Figure 2: Department of the biological elastomer of the present invention (Rubber Foam) Cross-sectional view Figure 3 · Flowchart for the manufacture of biological materials Figure 4: Structural drawing of the elastic product with biological materials of the present invention— [Figure No.]:

494061 V. Description of the invention (4) 1 Γ Bio-rubber elastic products calcium carbonate 1 1, 1, 1-, Cells 11 Cloth layer 12 Bio-adhesive layer 13 Bio-elastomer 13? Bio-material A Upper layer B Middle Layer C Bottom Bi Biomaterial The present invention is an elastic rubber material with added biocalcium. As shown in Figure 4, the upper layer A and the lower layer C are both cloth layers 11, and the middle layer B includes biological properties on both sides. Next, the layer 12 and the biological elastomer 1 3, wherein the biological elastomer 13 shown in FIG. 2 contains a biological material 13 ′ and a cell 1 3 π, and the biological material of the present invention The elastic elastomer 1 3 of the elastic product 1 is mainly composed of a mixture of rubber (plastic) rubber material, biological material, biological adhesive and additives, and the rubber (plastic) rubber material is SBR rubber, NBR oil resistant Rubber, CR rubber, PVC polythene, TPE thermoplastic rubber, PU resin, E V A ..., etc., or two or more of them can be mixed to make the biological properties as shown in Figure 3 Material (B i) manufacturing method, and the main biological

Page 10 494061 V. Description of the invention (5) The materials (Bi) are: shells other than marine organisms (mud shell, mussel shell, clam shell, snail shell, shell ...) . It is supplied at 110C for drying and is conveyed to Baobushanliu-ν 'l- ^ u by conveyor belt. It is stored in the heart, or after being crushed by a coarse crusher, it is evacuated to a collecting tank by an exhaust fan for aggregate processing. Then, it is ground into a fine powder by a pulverizer to complete the finished product. The main additives are Accelerator, stab-ilizer and Plasticizer, Blowing ag-ent, Vulcanizing agent, Pigment, Antioxidant ( Antioxide agent) ........... etc. The biological adhesive is composed of PU adhesive, CR adhesive, acrylic adhesive, etc., and other adhesives are mainly composed of biological adhesives. The embodiment of the present invention is described as follows. Example 1 An example of making a bio-elastomer with rough shell powder as a reinforcing filler is as follows: 1. SBR rubber formula SBR rubber natural rubber calcium acid breaking group weight (kg) 30 9 Rough shell powder group (kg) 30 9 ΙΒΗΠ ^ · 494061 V. Description of the invention (6) BR rubber 6 6 Sulfur yellow 0.5 5 0. 5 Sulfur accelerator 0.2 2 0.2 Anti-aging agent 2. 1 2. 1 Stearic acid 0.8 8 Zinc oxide 1. 5 1. 5 Carbon black 10 10 Softened oil 12 12 Calcium carbonate 40 0 Mud shell powder 0 40 Other additives 15 15 Total weight = 127 · l (kg) 127.l (kg) The rubber material is first smelted with a double-roller machine at the time of manufacture, and then the biological material and other additives of oyster shell powder are added to the rubber material and mixed with a lina machine (kneader). It is then extruded through an extruder and then vulcanized by a vulcanizing machine to complete it. The comparison between the rugged shell powder group and the calcium carbonate group is as follows: (a) · Viscosity (Muni value)-calcium carbonate group _ rugged shell powder group

ML (l + 4) l00t 15. 8M_15. 8M

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494064 V. Explanation of IT (8) From the above numerical analysis, it can be known that the tensile strength, tear strength and modulus of 200% have all increased significantly. From this, it can be determined that the rough crust powder group has more than the calcium carbonate group. Reinforcing effect. [Example 2] An example of a biological elastomer using a mixed biological material as a reinforcing filler is as follows: 2. Foam rubber side: calcium carbonate group rough shell powder group weight (kg) weight (kg) CR rubber 57 57 Anti-aging agent 2. 0 2. 0 EUR 0.25 0. 25 Zinc oxide 3 3 Carbon black 10 10 Softening oil 12 12

Page 14 494061 V. Description of the invention (9) Rough shell powder 0 25 Nine-hole shell powder 0 10 Mussel shell powder 0 3 Barnacle shell powder 0 2 Foaming agent 4 4 Other additives 2. 85 2. 85 Total weight: 1 31 · 1 (kg) 131.l (kg) During the production process, rubber rollers are smelted on a double-roller machine. The knees L ^, u, ^ j ». The shell powder and barnacle shell powder are added to the rubber material, and the raw materials are extruded and molded by the lina machine, followed by the vulcanization of the vulcanizer, and then extruded. Foaming and finishing. Then compare the foaming machine with the biological material group and the calcium carbonate group: (a) · Viscosity (Muni value

ML (l + 4) 100 ° C

8. 7M

Material Group 9 · OM During the above manufacturing process, test its viscosity (r value of Mooney Viscometer at 100 ° C). Compared with the addition of calcium carbonate and biological materials, a / L rotor Test, slightly rising, but in terms of the operation of the extruder, imitate the stickiness of the 4 king materials. W 热压} · μ π Α

Show bad feelings 1

494061 V. Description of the invention (ίο) (b). The value of the vulcanization curve-TS5 TC90 MS ML MC m CURE RATE white clay + other groups 10 minutes 56 seconds 21 minutes 6 seconds 7.4 2.4 19.6 21.5 10 minutes 40 seconds I biological material group 9 minutes and 16 seconds | 22 minutes and 18 seconds 7.2 2.2 23.7 26.1 13 minutes and 2 seconds According to the above test values, the sulfurization time increased by about 2 minutes and 22 seconds, but in the comparison of MC and MH, it was found that the biological material group The higher the value, the better effect can be expected in terms of physical properties. (C). The numerical value of physical property comparison. For the above two groups of vulcanized rubber products, the following physical property comparison numerical results are shown in the following table: Item ^ \ _ 白 土 τ Other groups of biological material group | Elongation ⑸ j 500 452 Rally Strength (kg / cm2) 6 7.5 Tear strength (kg / cm) 3 3.2 Hardness (Asker C) | 6 6 200% ^ Mo (1 ^ / 〇112) 2.8 2.9 Specific gravity | 0.19 0.2

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From the above numerical analysis, it can be known that the tensile strength and the tearing modulus of 200% have all increased significantly. From this, it is possible to determine the degree of bioavailability, and to have a reinforcing effect. The biological bombardment completed by the embodiment is used. The acid side coating formula is as follows: Body's two formulas: CR resin 10 0 hardener 3 accelerator 3 rough shell) _y. Total weight: 1 16 (kg) The standard 'fits nylon cloth and undergoes a simple peel test, As a result, the material was broken and adhered to nylon cloth (Nylon). The present invention is a kind of elastic calcium rubber-added rubber material. The above-mentioned biological foam or bio-vulcanized rubber sheet is used as the middle 3; an adhesive layer is coated on both sides of the middle layer and a cloth layer is applied. # Hom above Γ 杳 # / », ^, from, = L consistently known examples] It is known that the physical properties of foams with biological materials such as tin are significantly better than the foams shown, provided by the place Yu shoe orange $% & u seven or two mouthpieces into a wide range of sports or sports materials. An elastic rubber material with biological calcium added to the present invention has been applied for the patent of U.K. ^^ and has met the requirements of the "Month" patent.

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Claims (1)

Lianna- i · -Species with added biological calcium— ~ ^ 二: …… :: 丨.: Jingxia lower layer, each of which is a woven layer or 5 rubber materials, including:-upper ;: Department of natural biological quality: Cloth two = cloth layer, and the center; one of the above ... The material layer, the winning material, and other additives are layered with the upper and lower layers, and its characteristics are coated with adhesive rubber on both sides Tablets: It is composed of rubber material and eight dagger additives. The percentage of physical calcium material is 5-50% by weight, and Ap + two-biological biomass material accounts for weight% by weight; "Dagger additives account for 20% to 35% by weight. (2). Biological foam rubber: It is composed of rubber materials and other additives. Percentage of calcareous materials-which: Timli II = weight wt ° / 〇; to the knife ratio 20 ~ 35 (3). Biological adhesive agent: It consists of adhesive agent and biological agent: in which the weight of biological material is 2% by weight. The above-mentioned biological vulcanized rubber sheet Shengshi t / 0, sulfur engineering 'And biological foam rubber is manufactured; = = =: processing process' The above structure with biological calcium material, low cost of foaming waste and Reinforcing physical properties, more environmentally friendly: ΐ: Reduced energy into wetsuits: surf suits, fishing pants, knee pads and wrist support shoes, pads or other materials used on sports equipment. Page 19 494061 6. Application Patent scope 2. The elastic rubber material described in item 1 of the scope of patent application, wherein the rubber material can be SBR rubber, BR rubber, CR rubber, TPE thermoplastic rubber, EVA and other rubbers. The elastic rubber material according to item 1, wherein the rubber material may be one or more rubber materials. 4. The elastic rubber material according to item 1 of the scope of the patent application, wherein the biological calcareous materials are oyster shells, mussel shells, abalone shells, clam shells, and various shells of snails and shellfish. 5. The elastic rubber material according to item 1 of the scope of patent application, wherein the bio-quality material # 5 can be one or more bio-quality materials. 6. The elastic rubber material according to item 1 of the scope of patent application, wherein the upper and lower layers of the cloth surface layer may be woven or knitted or non-woven layers. 7. The elastic rubber material according to item 1 of the scope of patent application, wherein the surface layer of the biological elastomer can be coated with a coating of a mixture of a biological calcium material and a coating to form a thin film layer on the surface. 8. The elastic rubber material according to item 1 of the scope of the patent application, wherein the adhesive of the adhesive layer may be a PU adhesive, a CR adhesive, or an acrylic adhesive. Page 20 494061 6. Scope of patent application Adhesive and mixed with biological calcium material Page 21