201037124 六、發明說明： 【發明所屬之技術領域】 a本發明係與合成皮革有關，更詳而言之是指—種 環保合成皮革及其製法者。 【先前技術】 按《見之皮革可區分為兩大類：天然皮革與合 成皮革。天然皮革係取動物之皮膚製成，如羊皮、牛 〇皮等，而合成皮革係天然皮革式樣、質感製作，依其 原料大體上有聚氯乙烯（PVC)合成皮與聚氨醋（叫 合成皮兩大類。由於聚氨醋合成皮可藉由原料、製程 之調整而獲致與天然皮革最接近之特性，且，具有耐 用、質感佳、透氣性佳等優點，因此，用途較聚氯乙 烯合成皮更為廣泛。 習知聚氨酯合成皮依製作方式之不同一般可區分 為乾式合成皮與濕式合成皮。乾式合成皮較聚氣乙婦 U合成皮更輕且更像天然皮革，而且也不會發霉，但較 大的缺點是較無肉身，所以觸感較差，因Λ，通常會 再貼合-濕式合成皮，使其肉身飽滿。濕式合成皮係 以「濕式製程」製作而成，製作方式係先將基布（布 料）預浸潰於PU樹脂配合液中，再經ρυ樹脂塗佈、 濕式凝聚、水洗（於含二甲基甲醯胺DMF溶劑之槽體 内進行）及供箱烘烤，使附著於基布上之樹脂熟成固 化，即可製成濕式合成皮。而常見之聚氨酯合成皮即 3 201037124 利用黏著劑（如膠水）貼合濕式合成皮與乾式合成皮 而成。 由於濕式合成皮之製作過程中係使用DMF溶劑進 行水洗，DMF係有毒性之化學藥劑，不僅會溶於水而 造成水3染、有害環境，更會對人體健康造成傷害。 其次，貼合乾式合成皮與濕式合成皮之黏著劑亦會造 成環境之污染。因此，目前常用之聚氨5旨合成皮仍有 甚多缺點需加以改善。 其次，由於現今社會各種類型之廢棄物不論數量 及種類均日益增加’若能將回收之廢棄物運用於合成 皮革之製作上’不僅有助於環保，更可大幅降低製作 成本’不㉟’目前為止並未見有利用回收之廢棄物為 材料所製作之合成皮革以及相關之製作技術。..... 早一材料組成之廢棄物較易回 ，、處理再利用’如前述之橡膠廢料、寶特瓶、玻璃 ::;塑膠、金屬製品及紙類等，而複合材料用品（如 X之廢棄物回收再利用則需透過各種處 ::::材T，tt獲得可再利用之材料二相 材料廢畢物〇收处理專利’此處不予贅述。由於複合 材科廢棄物之回收處理過程中常需使用各種界 溶劑以分離組成材料(尤其是回收高價材質之情：或 反而產生更多有害環保之廢棄物，而人工分離複：材 料廢棄物甚為耗時，完全不符合經濟效益。σ 201037124 成之目前並無利用回收廢棄物為材料所製 解決習知複人材料麻奎你，旱裊作技*可同時 點。後口材枓廢棄物之回收處理所產生之諸缺 【發明内容j :::之主要目的即在提供一種可解決前 ^保口成皮革及其製法’其不僅可以回收之廢棄物 Ο f付t製作合成皮革，而大幅降低製作成本，/，、更 可同時解決習知複合材料廢畢物 叶尾案物之回收處理所產生之 僅二甚具環保概念；再者，其製成之合成皮革不 :::如同天然皮革之特性，更可解決 濕:物層製作過程中所產生之環境污染、毒 (生專問碭，甚具實用價值者。 緣是，為達成前述之目的，本 合成皮革，包含月係k供一種環保 、 廣係利用回收廢棄物混合 天，、、'、橡膠、各泡劑等發泡材料製成；一中介 ，以抗拉伸材料製成；-表；，貼置 於戎中，丨層底側’係乾式聚氨酯膜。 物二:步二’：性:係利用含有橡膠材料之回收廢棄 此5天然轉、發泡料發泡材料發泡而成。 進一步地，中介層係布料。 進一步地’各彈性層、中介層與表層係利用彈性層 原料中發泡劑受熱時起化學變化所產生之氣體壓力及 201037124 硫化過程之發泡力量黏接在一起。 進步地，更包含有一輔助層，係以彈性材料 成。 、 進一步地，輔助層係橡膠彈性體。 進步地，輔助層係塑膠彈性體。 此外，本發明更提供一種環保合成皮革之製法， 其步驟至少包含有··備料：備取聚氨酉旨 jj^yUrethane)、彈性材及抗拉伸材料等材料，該 ^材係包含天然橡谬、發泡劑及回收廢棄物之彈性 =㈣；混練：將該彈性材予以充分加壓揉捏混練； ^片豐合：分別將聚氨醋、彈性材擠壓呈片狀，並使 2拉伸材料疊合於片狀聚氨醋上、使片狀之彈性材 2於抗拉伸材料上；加硫發泡成型：加硫發泡疊合 之各該聚氨醋、彈性材、抗拉伸材料而使三者貼合在 起’俾獲致環保合成皮革。 進一步地，備料之步驟中， 物係嚯％ A —人 。亥弹性材之回收廢棄 物係選取自包含橡膠、塑膠 蓉心^ 戴維、皮革或燃燒殘渣 專材質之建築/工業廢棄物碎屑。 進一步地，該回收廢杳铷仫 糸衆物係選取自以適當方式將 不同成分材質分離後之廢棄物碎屑。 進一步地’係以分層分離 眉# 壬^ w ^ 離之方式使回收廢棄物碎 眉依比重之差異自動呈分層分離狀態。 進一步地’分層分離之 夂方式，係利用震動之方式 201037124 使不同成分之回收麼 分離。 '棄物碎屑依比重之差異自動分層 ★步&目收廢棄物並經殺菌處理。 理 、步地，係利用^ + 叹潑棄物予以殺菌處 處理 進乂地係'添加殺菌劑將回收廢棄物予 以殺菌 Ο Ο ^步地，壓片疊合與加硫發泡成型之步驟 更匕含有一柔化步驟，传將 〜. 將各该片狀之聚氨酯及第 —、弟—彈性材之對應面施以軟化處理。 步地’柔化之步驟中，係利用將 於各該片狀之聚氨酯及第―、第_ 佈 式進行軟化處理。 第-㈣材之對應面方 進一步地，柔化之步驟中，係利用高溫將各該片 狀之聚氨醋及第一、第二彈性材之對應面方式進行軟 化處理。 【實施方式】 以下，兹舉本發明數較佳實施例，並配合圖式做進 一步之詳細說明如後： 如第一圖所示，本發明一較佳實施例之環保合成 皮革10,包含有一彈性層12、一中間層14與一表層 16° §亥彈性層1 2 ’係利用含有橡膠材料之回收廢棄物 201037124 、(如運動鞋、運動墊等）混合天然橡膠、發泡劑等發 泡材料發泡成型。 、 杨^中間層14，貼置於該彈性層12頂側，係具抗拉 伸強度之材料，如布料。 =層16,貼置於該彈性層12頂側，係乾式聚氨 通曰（P〇im*ethane，PU)膜，其表面可施予耐候、耐 磨、耐刮、亮面、磨毛及壓紋等表面處理。 藉此，本發明該環保合成皮革1〇之特色及功效如 下· 省％保合成皮$ i 〇並未使用習知聚氨醋合成 革之濕式PU層，因此，製作過程中不會產生使用 基甲醯胺（DMF)所導致之水污染、高毒性及水解^缺 點。其次’該彈性層12係制时廢棄物混合橡鮮 泡^料發泡而成’可產生廢棄物回收再利用及減少垃 圾量之效果，更可解決f知含有濕式pu層之合成皮革 不易回收再利用之問題。再者，各該彈性層12、中間 層14與表層16利用彈性層12原料中發泡 化學變化所產生之氣體壓力及硫化過程中之發泡 = 黏接在一起，可省略黏著劑之使用，更具環保功效者。 如第二圖所示，係本創作另一較佳實施例之環保 合成皮革20,其結構大體上與該環保合成皮革1〇相 同，此處不重複贅述，不同處在於：其更包含有一輔 助層22,介於中介層24與彈性層26之間，係以彈性 201037124 材料製成’如具適當柔軟性之橡膠彈性體或塑膠彈性 •體’用以可調整該環保合成皮革2G之物性進 價值。 < 只用 此外，如第二圖所示，本發明該環保合成皮革1 〇 詳細之製法如下： 本發明之第—步驟係備料ug:備取聚氨酿、彈 性材及片狀之抗拉伸材料等材料，該彈性材係構成彈 〇性層12之天然橡膠及回收廢棄物之混合彈性材料。 本發明之第二步驟係混練120:係將彈性材予以 充分加壓揉捏混練。 本發明之第三步驟係壓片疊合130 :分別利用習 知i片機«氨_、彈性㈣成片狀，並將該片狀 之抗拉伸材料疊合於片狀聚氨酯上、使片狀之彈性材 疊合於抗拉伸材料上。 本發月之隶後步驟係加硫發泡成型14 〇 :將最人 〇之各該聚氨酯、彈性材及抗拉伸材料通過一習知力^ 發泡箱加硫發泡，使三者可利用彈性材中發泡劑受献 2起化學變化所產生之氣體壓力及硫化過程之發心 置黏貼在一起，俾獲致該環保合成皮革10。 其中’該壓片疊合130之步驟可於 ψ ^連續實施。詳言之，先利用習知押片機將聚氨醋擠 壓為片狀後置於持續運轉之輸送帶上，待片狀聚氨醋 被輸送帶輸送一距離後，將片狀之抗拉伸材料抵貼於 201037124 T氨s曰而置於持續運轉之輸送帶上，待疊合之片狀聚 氨=與抗拉伸材料被輸送帶輸送一距離後，該彈性材 則受另:押片機擠壓為片狀並抵貼於抗拉伸材料上， 最2 _且合之片狀聚氨酯、第一、第二彈性材再受輸 送π輸达通過習知加硫發泡烤箱加硫發泡成型。 此外，如第四圖所示，該備料11〇步驟中回收 棄物之備取方式如下： ' 第一步驟係回收粉碎210 :係選取自塑膠袋、廢 輪胎、鞋類、油封、塑膠管、廢布或皮革、家具及燃 燒f逢等包含橡膠、塑膠、纖維、皮革或燃燒殘潰等 材質之建築/工業廢棄物碎屑’廢棄物碎屑係利用習知 切碎機將回收之廢棄物粉碎後獲得。 、第二步驟係分層*離220:利用震動方式使不同 成分之廢棄物碎屑依比重之差異自動分層分離 將廢棄物碎屑擺置於習知輸送設備之輸送带上之—六 器内，再利用輸送带輸送容器之過程所產生之震： 不同成分之廢棄物碎屑依比重之差異自動於容器 成分層分離之狀態。當然，亦可利用其他震動^ ^ 磁力吸附、磁場及過篩等方式使不同成分之 二， 屑依比重之差異自動分層分離。 〜碎 第三步驟係殺_ 230 ··為了避免廢 有細菌而造成使用上之衛生問題，自 内含 物碎屑中選取適當材料後再經殺菌處理， 奢棄 你利用高溫 10 201037124 或添加殺菌劑將回收之廢牵 ， 殿棄物予以殺菌處理，殺菌處 理後之回收廢棄物即可混合 材。 天Μ橡膠而備置第二彈性 雖，回收廢棄物碎肩無法完整分離為個一 成为’但不同成分構成之 M ms, 外眉了仏添加於發泡材料中 如’以橡膠材料為主之廢棄物碎屬 Ο Ο =1:可作為發泡原料之彈性調整材料， 以塑膠材料為主之廢棄物 度調整材料，而以纖維材料為主泡原料之硬 劑或補強劑’如回收材料中有油酯成 田作軟化劑使用而不用加以清洗或分離。 之設H於本發明更可依該環保合成皮革1〇物理性質 °又；彈性材之原料中添加以纖 I:;:::為主之不同比例廢棄物碎屑= ::::2皮革1〇更有彈性，可提高該彈性材中以 保二成皮：：廢棄物碎屬添加量’而若欲提高該環 為:之度’可增加該彈性材中以塑膠材料 更射麻: 上碎屑用量，而若欲使該環保合成皮革10 料為主=調整其重量’可提高該彈性材中以金屬材 成二 棄物碎屑添加量，若回收廢棄物中有油酯 刀可以當作軟化劑使用而不用加以清洗或八 換言之’任何成分之回收廢:彈2。 屌粗B4 J丨F馬邊蜂性材之 原枓及调整其物性之用。 201037124 a個η:明該環保合成皮革利用不需完全分離 為個別早-材料之碎屑狀回收廢棄物作為彈性材料及 防滑材料，不僅可減少天麸梭 太w稼膠專彈性材料之使用量 而大幅降低製作成本，且#且 曰 +且更具備廢物利用、減少垃圾 I之效果。 其次，如第五圖所示，壓片叠合130與加硫發泡 成型140之步驟之間可增加一矛 J J J日加木化135之步驟，係利 用習知軟化劑塗佈於各該片妝 合°豕月狀之聚虱酯、彈性材及抗 拉伸材料之對應面，或利用高溫將各該片狀之聚氨 醋、彈性材及抗拉伸材料之對應面予以適當軟化。藉 此’可增進各該聚氨醋、彈性材及抗拉伸材料之結合 強度。 、綜上所4 ’本發明所提供之環保合成皮革及立製 法，其不僅可以回收之廢棄物為材料製作合成皮革， 而大幅降低製作成本，I，更可同時解決習知複人材 :廢棄物之回收處理所產生之諸缺點、甚具環：概 必，再者，其製成之合成皮革不僅可保持如同天然皮 革之特1± ’更可解決習知聚氨醋合成皮中濕式PU層製 作過程中所產生之環境污染、毒性等問題，甚具實用 價值；緣是，本發明確實符合發明專利之規^，^依 法提出申請。 201037124 【圖式簡單說明】 圖係本發明第一較佳實施例之立體組合圖。 第—圖係本發明第二較佳實施例之立體組合圖。 第三圖係本發明第—較佳實施例之製作流程圖。 第四圖係本發明第—較佳實施例中部份流程示意 圖。 第五圖係本發明第—較佳實施例中部份流程示意 圖。 ❸ 【主要元件符號說明】 彈性層12 中介層14 環保合成皮革2 〇辅助層2 2 環保合成皮革1 〇 表層16 備料110 柔化135 分層分離220 中介層24 彈性層26 混練120 壓片疊合13〇201037124 VI. Description of the invention: [Technical field to which the invention pertains] a The present invention relates to synthetic leather, and more particularly to an environmentally-friendly synthetic leather and a method for producing the same. [Prior Art] According to "See the leather can be divided into two categories: natural leather and synthetic leather. Natural leather is made from the skin of animals, such as sheepskin, burdock, etc., while synthetic leather is made of natural leather and texture. According to its raw materials, it is made of polyvinyl chloride (PVC) synthetic leather and polyurethane. Two types of leather. Because the polyurethane synthetic skin can be obtained by the adjustment of raw materials and processes, it has the closest characteristics to natural leather, and has the advantages of durability, good texture and good gas permeability. Therefore, the application is more synthetic than polyvinyl chloride. The skin is more extensive. The conventional polyurethane synthetic skin can be divided into dry synthetic skin and wet synthetic leather. The dry synthetic leather is lighter and more like natural leather than the polyethylene synthetic skin. It will be mildewed, but the bigger disadvantage is that it is less fleshy, so the touch is worse. Because of it, it usually fits again-wet synthetic skin to make it full. The wet synthetic leather is made by "wet process". In the production method, the base fabric (cloth) is pre-impregnated in the PU resin compounding liquid, and then coated with ρυ resin, wetly coagulated, and washed with water (in a tank containing dimethylformamide DMF solvent). ) and for Baking, the resin attached to the base fabric is cured and cured, and the wet synthetic skin can be prepared. The common polyurethane synthetic skin is 3 201037124, which is adhered to the wet synthetic skin and the dry synthetic skin by using an adhesive (such as glue). Since the wet synthetic leather is washed with DMF solvent during the production process, DMF is a toxic chemical agent, which not only dissolves in water, but also causes water 3 to be dyed, harmful to the environment, and harmful to human health. Adhesives that adhere to dry synthetic skin and wet synthetic skin can also cause environmental pollution. Therefore, there are still many shortcomings in the commonly used polyaluminum 5 synthetic skin that need to be improved. Second, due to various types of waste in today's society. Regardless of the quantity and type, the use of recycled waste in the production of synthetic leather not only contributes to environmental protection, but also significantly reduces production costs. Synthetic leather made of materials and related production techniques..... The waste of the first material is easier to return, and it is treated and reused. Waste, PET bottles, glass::; plastics, metal products and paper, etc., and composite materials (such as X waste recycling and reuse through a variety of places:::: material T, tt can be reused The material of the second-phase material waste material collection and treatment patent 'will not be repeated here. Because of the recycling process of composite materials, it is often necessary to use various boundary solvents to separate the constituent materials (especially the recovery of high-priced materials: or instead More harmful environmentally-friendly waste, and manual separation: material waste is very time-consuming and completely inconsistent with economic benefits. σ 201037124 Cheng Zhi does not currently use recycled waste as material to solve the conventional compound material Ma Kui You, the drought and phlegm technique can be simultaneously. The defects caused by the recycling of the waste material and the waste material [The content of the invention:::: The main purpose is to provide a solution to the former 'It can not only recycle the waste Ο f pay t to make synthetic leather, but greatly reduce the production cost, /, can also solve the problem of the recycling of the traditional composite waste waste leaf tail case It has the concept of environmental protection; in addition, the synthetic leather made by it is not::: like the characteristics of natural leather, it can solve the problem of wetness: environmental pollution and poison produced during the production process of the layer (special question, very practical value) By. The reason is that, in order to achieve the above-mentioned purpose, the synthetic leather, including the monthly k, is made of a kind of environmentally-friendly, wide-ranging recycling waste, and a foaming material such as rubber, foaming agent, etc.; Made of anti-stretch material; - table; placed in the crucible, the bottom side of the crucible layer is a dry polyurethane film. Item 2: Step 2: Sex: It is made of recycled rubber containing rubber material. Further, the interposer is a cloth. Further, the elastic layers, the interposer and the surface layer are bonded together by the gas pressure generated by the chemical change of the foaming agent in the elastic layer raw material and the foaming force of the 201037124 vulcanization process. Progressively, it also includes an auxiliary layer made of elastic material. Further, the auxiliary layer is a rubber elastic body. Progressively, the auxiliary layer is a plastic elastomer. In addition, the present invention further provides a method for preparing an environmentally-friendly synthetic leather, the method comprising at least: preparing a material for preparing a polyurethane material, an elastic material, a tensile material, and the like, and the material comprises a natural rubber. Elasticity of enamel, foaming agent and recycled waste = (4); kneading: the elastic material is fully pressurized and kneaded and kneaded; ^The film is rich: the polyurethane and the elastic material are respectively extruded into a sheet shape, and 2 The stretched material is laminated on the flaky polyurethane to make the sheet-like elastic material 2 on the anti-stretch material; the sulphur-foaming molding: the sulphur-foamed and laminated each of the polyurethane, the elastic material, and the anti-stretching Stretching the material and making the three fit together to 'get environmentally friendly synthetic leather. Further, in the step of preparing the material, the system is 嚯% A - human. The recycled materials of the elastic materials are selected from the rubber/plastic cores of the rubber, the leather, or the burning residue. Further, the recycling waste system is selected from waste debris which is separated from the materials of different compositions in an appropriate manner. Further, the layered separation eyebrows are separated by a layered separation of the eyebrows. Further, the method of stratified separation is to use the method of vibration 201037124 to separate the different components. 'Disposable debris is automatically layered according to the difference in specific gravity. ★Step & collect waste and sterilize. Rationally, step by step, use ^ + sighs and spoils to treat the sterilizing department into the sputum system. 'Adding bactericide to recycle the waste to be sterilized Ο 步 Step, the process of laminating and vulcanization molding is more The crucible contains a softening step, and the corresponding surface of each of the sheet-like polyurethane and the first and second elastic materials is softened. In the step of softening, the polyurethane is applied to each of the sheets, and the first and second sheets are softened. Corresponding surface of the first-(four) material Further, in the step of softening, the sheet-like polyurethane and the corresponding surface of the first and second elastic materials are softened by high temperature. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS In the following, a preferred embodiment of the present invention will be further described in detail with reference to the drawings. As shown in the first figure, an environmentally-friendly synthetic leather 10 according to a preferred embodiment of the present invention includes a The elastic layer 12, an intermediate layer 14 and a surface layer 16° § eh elastic layer 1 2 ' are foamed by using recycled rubber 201037124 containing rubber material, such as sports shoes, sports mats, etc., mixed with natural rubber, foaming agent, etc. Material foam molding. , Yang ^ intermediate layer 14, attached to the top side of the elastic layer 12, is a material with tensile strength, such as cloth. = layer 16, attached to the top side of the elastic layer 12, is a dry polyammonium (P〇im*ethane, PU) film, the surface of which can be applied to weather resistance, wear resistance, scratch resistance, bright surface, sanding and Surface treatment such as embossing. Therefore, the characteristics and effects of the environmentally-friendly synthetic leather of the present invention are as follows: • The %% synthetic leather $i 〇 does not use the wet PU layer of the conventional polyurethane synthetic leather, so the base armor is not produced during the production process. Water pollution, high toxicity and hydrolysis caused by guanamine (DMF). Secondly, 'the elastic layer 12 is made of waste mixed with fresh foam and foamed material', which can produce waste recycling and reduce the amount of waste. It can also solve the problem that synthetic leather containing wet pu layer is difficult to be solved. Recycling issues. Furthermore, each of the elastic layer 12, the intermediate layer 14 and the surface layer 16 is bonded by the gas pressure generated by the foaming chemical change in the raw material of the elastic layer 12 and the foaming during the vulcanization process, and the use of the adhesive can be omitted. More environmentally friendly. As shown in the second figure, the environmentally-friendly synthetic leather 20 of another preferred embodiment of the present invention has a structure substantially the same as that of the eco-synthetic synthetic leather, and is not repeated here, except that it further includes an auxiliary. The layer 22, between the interposer 24 and the elastic layer 26, is made of elastic 201037124 material, such as rubber elastic or plastic elastic body with appropriate flexibility, to adjust the physical properties of the environmentally-friendly synthetic leather 2G. value. < In addition, as shown in the second figure, the environmentally-friendly synthetic leather 1 本 of the present invention is prepared in the following manner: The first step of the present invention is a preparation ug: preparing a polyurethane, an elastic material and a sheet-like tensile force. A material such as a material that constitutes a mixed elastic material of the natural rubber of the elastic layer 12 and the recycled waste. The second step of the present invention is the kneading 120: the elastic material is sufficiently pressurized and kneaded. The third step of the present invention is a tablet lamination 130: respectively, using a conventional i-plate machine «ammonia_, elastic (four) into a sheet shape, and laminating the sheet-like anti-stretch material on the sheet-like polyurethane to make a sheet The elastic material is laminated on the tensile resistant material. The post-subsequent steps of this month are sulphur foaming molding 14 〇: The most versatile polyurethane, elastic and tensile materials are sulphur-foamed through a conventional foaming box to make the three available. The foaming agent in the elastic material is adhered to the gas pressure generated by the chemical change and the core of the vulcanization process, and the environmentally-friendly synthetic leather 10 is obtained. The step of 'the tablet stack 130' can be carried out continuously in ψ ^. In detail, the polyurethane is first squeezed into a sheet by a conventional tableting machine and placed on a conveyor belt that is continuously running. After the sheet of polyurethane is conveyed by the conveyor belt for a distance, the sheet-like tensile force is applied. The stretched material is placed on the continuous running conveyor belt against the 201037124 T ammonia sputum. The sheet-like polyurethane to be superimposed = after the stretch-resistant material is transported by the conveyor belt, the elastic material is subject to another The tablet is extruded into a sheet and adhered to the anti-stretch material. The most flaky polyurethane, the first and second elastic materials are transported by π and transported through a conventional sulfurized foaming oven. Foam molding. In addition, as shown in the fourth figure, the preparation method for recovering the waste in the step 11 of the preparation is as follows: 'The first step is to recover the crushed 210: the selected from the plastic bag, the waste tire, the footwear, the oil seal, the plastic tube, Waste/leather, furniture, and fire-fighting materials/construction wastes containing rubber, plastic, fiber, leather, or burnt debris. Waste debris is recycled from conventional shredders. Obtained after crushing. The second step is layering * away from 220: using the vibration method to separate the waste debris of different components according to the difference of specific gravity, and separating the waste debris on the conveyor belt of the conventional conveying equipment. Inside, the vibration generated by the process of transporting the container by the conveyor belt: the waste debris of different components is automatically separated from the component layer of the container according to the difference in specific gravity. Of course, other vibrations, magnetic fields, and sieving can also be used to separate the two components of the different components, and the chips are automatically separated by the difference in specific gravity. ~ The third step is to kill _ 230 ·· In order to avoid the use of bacteria and cause health problems, select appropriate materials from the inclusions and then sterilize, use your high temperature 10 201037124 or add sterilization The agent will recycle the waste, and the waste material will be sterilized, and the waste after the sterilization treatment can be mixed. Although the second elastic is prepared for the rubber of the scorpion, the waste shoulders cannot be completely separated into one piece, but the MMS is composed of different components. The outer eyebrow is added to the foaming material, such as the waste material mainly based on rubber materials. The material is Ο Ο =1: It can be used as the elastic adjusting material for foaming raw materials, the waste material adjusting material mainly for plastic materials, and the hardener or reinforcing agent for fiber materials as the main raw material, such as recycled materials. The oil ester field is used as a softener without being washed or separated. In the present invention, according to the environmentally-friendly synthetic leather, the physical properties of the leather can be further increased; the raw materials of the elastic material are added with different ratios of fiber I:;::: waste debris = :::: 2 leather 1〇 is more flexible, can improve the elastic material to protect the second skin:: the amount of waste is added 'and if you want to increase the ring: the degree 'can increase the elastic material in the plastic material more shot: If the amount of debris is to be used, if the environmentally-friendly synthetic leather is used as the main material = the weight is adjusted, the amount of scrap added to the metal material in the elastic material can be increased, and if there is an oil ester knife in the recycled waste, Used as a softener without cleaning or in other words, 'recycling waste of any ingredient: bomb 2'. Upsetting the original nature of B4 J丨F horse bee and its physical properties. 201037124 a η: The use of environmentally-friendly synthetic leather does not need to be completely separated into individual early-material waste-like wastes as elastic materials and non-slip materials, which can not only reduce the use of gluten-free rubber The production cost is greatly reduced, and the effect of waste utilization and waste reduction I is further improved. Next, as shown in the fifth figure, a step of adding a spear JJJ day plus wood 135 between the steps of the tablet lamination 130 and the vulcanization foam molding 140 may be applied to each of the sheets by using a conventional softener. The surface of the polyurethane, the elastic material and the tensile resistant material of the moon-like shape, or the corresponding surface of each of the sheet-like polyurethane, the elastic material and the tensile material are appropriately softened by high temperature. By this, the bonding strength of each of the polyurethane, the elastic material and the tensile resistant material can be enhanced. In view of the above, the environmentally-friendly synthetic leather and the vertical method provided by the present invention can not only produce recycled leather as raw materials, but also greatly reduce the production cost, and can simultaneously solve the conventional complex materials: waste. The shortcomings of the recycling process are very different: it must be, in addition, the synthetic leather made by it can not only maintain the special 1±' of natural leather, but also can solve the wet PU layer in the synthetic polyurethane skin. The problems of environmental pollution and toxicity generated in the process are of practical value. The reason is that the invention is in compliance with the regulations of the invention patents, and the application is made according to law. 201037124 BRIEF DESCRIPTION OF THE DRAWINGS The drawings are perspective assembled views of a first preferred embodiment of the present invention. The first drawing is a perspective assembled view of a second preferred embodiment of the present invention. The third drawing is a flow chart of the production of the first preferred embodiment of the present invention. The fourth figure is a partial flow diagram of a preferred embodiment of the present invention. Figure 5 is a partial flow diagram of a preferred embodiment of the present invention. ❸ [Main component symbol description] Elastic layer 12 Interposer 14 Eco-friendly synthetic leather 2 〇 Auxiliary layer 2 2 Eco-friendly synthetic leather 1 〇 Surface layer 16 Preparation 110 Softening 135 Layer separation 220 Interposer 24 Elastic layer 26 Kneading 120 Pressing lamination 13〇
加硫發泡成型140回收粉碎21〇 殺菌230 13Sulfurized foam molding 140 recovery pulverization 21 〇 sterilization 230 13