TW483841B - Hybrid inflater - Google Patents

Hybrid inflater Download PDF

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Publication number
TW483841B
TW483841B TW89120391A TW89120391A TW483841B TW 483841 B TW483841 B TW 483841B TW 89120391 A TW89120391 A TW 89120391A TW 89120391 A TW89120391 A TW 89120391A TW 483841 B TW483841 B TW 483841B
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Taiwan
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gas
patent application
hybrid inflator
inflator
fuel
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TW89120391A
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Chinese (zh)
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Nobuyuki Katsuda
Masayuki Yamazaki
Norimasa Hirata
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Daicel Chem
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  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)

Abstract

Providing a lighter and more compact hybrid inflater. The proportion of the mole ration (A/B) for a pressing medium (A mole) filled in a housing 102 to gas (B mole) produced by a gas combustion generation 22 is set from 8/2 to 1/9 in order to prevent an excessive internal pressure during operation.

Description

13841 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明(丨) [發明所屬技術領域] 本發明係關於汽車車輛之膨脹式安全系統,更詳言之, 係有關可迅速地膨脹氣囊,而且以可更小型化且輕量化的 混合式充氣器及使用此的氣囊裝置。 [先前之技術] 隨著汽車車輛之膨脹式安全系統用充氣器的發展,以倂 用加壓氣體與固形氣體產生劑的混合式充氣器被注目。並 於混合式充氣器,其主要設計要事係使氣囊有效果的作動 而需要在規定之時間膨脹規定之量不可,對於其構造在先 前有種種之提案,而作爲先前技術,有特開平8-282427號 公報、EPO 844148 、 USP 5,351,988 、 USP 5,882,036 、 USP 5,851,027、USP 3,868,124、113? 3,758,131等爲眾 所知。 又,混合式充氣器係以汽車車輛爲對象,特別是波及影 響汽車車輛重量的充氣器尺寸成爲重要的設計要事,故如 此之點亦需要加以考慮。 可是,在先前之倂用加壓氣體與固形氣體產生劑的混合 式充氣器,有時並不能充分滿足上述設計要事。例如,利 用由固形氣體產生劑之燃燒熱來增加內壓,擠出加壓氣體 用來膨脹氣囊者之際,爲了提高耐壓性需要加厚外殼之壁 厚。再者,使加壓氣體中含有氧氣時,有僅氧氣之分量加 重重量的缺失。又,亦有使用過氯酸鹽之氣體產生劑,作 爲加壓氣體以不包含氧氣構造之混合式充氣器,在宜情开多 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -----------SW0----- — 訂---------線·-----Ψ (請先閱讀背面之注意事項再填寫本頁) (3841 A7 B7 五、發明說明(L) ,由氣體產生劑之燃燒有對乘客產生有害微少物之缺失。 又,先前所使用的固氣體產生劑,係其主流爲R DX等之槍式 者。 [本發明之啓示] 本發明之目的,係在於提供以不降低作爲充氣器的功能 ,以更輕量化且予以小型化,高穩定性的混合式充氣器及 使用此的氣囊裝置。 本發明作爲一解決手段,係提供一種混合式充氣器,具 備有車輛之膨脹式安全系統的氣囊,其中具充氣器外殼; 收容於充氣器內的氣體產生器;以及連接於氣體產生器的 點火裝置室,其特徵爲,在該充氣器外殻內充塡含惰氣, 不含氧氣的加壓媒質,爲氣體產生器具有包含氣體產生裝 置的1或2以上之氣體產生室者,該加壓媒質之量(A莫耳) 與由氣體產生裝置之燃燒產生的氣體量(B莫耳)之莫耳比 (A/B),爲 8/2 〜1 /9 者。 如此予以調整充塡於混合式充氣器內的加壓媒質之量, 與由氣體產生劑之燃燒產生的氣體量之莫耳比,可減少加 壓媒質之充塡量,因而,減少外殼之容積[亦即,減少了外 殻之長度及/或寬度(直徑)]時,亦不至於增高加壓媒質之 充塡壓力(=外殻之內壓),可維持於與減少容積前同壓力 〇 A/B最好是8/2〜3/7。尙,於本發明之混合式充氣器, 其加壓媒質之重量(a)與氣體產生裝置之重量(b)的重量比 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 訂---------線 經濟部智慧財產局員工消費合作社印製13841 Printed by A7 B7, Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs 5. Description of Invention (丨) [Technical Field of Invention] The present invention relates to an inflatable safety system for automobiles, and more specifically, it relates to an airbag that can be inflated rapidly. In addition, a hybrid inflator that can be made more compact and lighter and an airbag device using the same are used. [Previous Technology] With the development of inflators for inflatable safety systems of automobiles and vehicles, a hybrid inflator using a pressurized gas and a solid gas generating agent has attracted attention. In addition to the hybrid inflator, its main design is to make the airbag act effectively, and it is necessary to inflate the prescribed amount at a prescribed time. For its structure, there have been various proposals. As a prior art, there is JP 8 -282427, EPO 844148, USP 5,351,988, USP 5,882,036, USP 5,851,027, USP 3,868,124, 113 to 3,758,131, etc. are known. In addition, the hybrid inflator is intended for an automobile vehicle, and in particular, the size of the inflator that affects the weight of the automobile vehicle becomes an important design issue. Therefore, this point also needs to be considered. However, in the conventional hybrid inflator using a pressurized gas and a solid gas generating agent, the above-mentioned design issues may not be sufficiently satisfied. For example, when the internal pressure is increased by the combustion heat of a solid gas generator, and when a pressurized gas is used to inflate an airbag, it is necessary to increase the wall thickness of the casing in order to improve the pressure resistance. Furthermore, when oxygen is contained in the pressurized gas, there is a lack of weight increase due to only the amount of oxygen. In addition, there is also a gas generator using perchlorate. As a pressurized gas, it is a hybrid inflator constructed without oxygen. It is available in many paper sizes in accordance with the Chinese National Standard (CNS) A4 (210 X 297). Mm) ----------- SW0 ----- — Order --------- line · ----- Ψ (Please read the precautions on the back before filling in this Page) (3841 A7 B7 V. Description of the Invention (L), the combustion of gas generating agents is deficient in the generation of harmful little things to passengers. In addition, the solid gas generating agents used previously are mainly guns such as R DX [Inspiration of the present invention] The object of the present invention is to provide a hybrid inflator that is more lightweight and miniaturized without reducing the function as an inflator, and an airbag device using the same. As a solution, the present invention provides a hybrid inflator provided with an airbag of an inflatable safety system of a vehicle, which has an inflator housing; a gas generator housed in the inflator; and an ignition connected to the gas generator. Device room, characterized in that the inflator shell is filled with inert A pressurized medium containing no oxygen is a gas generator having one or two or more gas generating chambers including a gas generating device, the amount of the pressurized medium (A mole) and the gas generated by the combustion of the gas generating device The molar ratio (A / B) of the amount (B mole) is 8/2 to 1/9. In this way, the amount of the pressurized medium filled in the hybrid inflator is adjusted with the amount of the gas generating agent. The molar ratio of the amount of gas produced by combustion can reduce the charge of the pressurized medium, and therefore, the volume of the shell [ie, the length and / or width (diameter) of the shell is reduced] will not increase. The filling pressure of the pressurized medium (= the internal pressure of the casing) can be maintained at the same pressure as before the volume reduction. OA / B is preferably 8/2 ~ 3/7. 尙, the hybrid inflator in the present invention The weight ratio of the pressurized medium (a) to the weight of the gas generating device (b) is in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm). (Please read the precautions on the back before reading) (Fill in this page) Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economics

84 A7B7 經濟部智慧財產局員工消費合作社印製 五、發明說明(f) (a/b)爲o.i〜7,最好是0.5〜5。 i述之混合式充氣器,因欲更有效地顯現上述之作用效 ^ ’加壓媒質以不含氧氣者理想,再以作爲氣體產生裝置 Μ ί采用燃料及含氧化劑氣體產生劑爲理想。又,作爲氣體 ® &裝置採用燃料、氧化劑及含渣形成劑的氣體產生劑時 ’力Ρ上上述之作用效果,因對乘客可抑制有害的微少物之 產生故爲理想。 又上所述之混合式充氣器,係於氣體產生裝置之燃燒時 ,’可使次式:rb= α Ρη(式中、rb :燃燒速度、α :係數、 Ρ :壓力、η :壓力指數)所規定的壓力指數爲0 . 8以下者。 該壓力指數(η )以0 . 1〜0 . 8爲理想、更理想爲0 . 1〜0 . 7 〇 尙,壓力指數η,係在壓力7 0kg/cm2)之容器內測定燃 燒速度rb!,在壓力P2(100kg/cm2)之容器內測定燃燒速度 rb2後,自 rbi = α Ριη 與 rb2 = α P2n 之 2 式求出。 如此由於使壓力指數(η )在0 . 8以下,予以抑制在氣體產 生裝置之燃燒初期的燃燒速度之急遽上升,故外殻內壓之 上升小。因此,當減少外殻之壁厚時,亦可維持充分地耐 壓性。又,因外殼內壓之上升小(亦即,內壓之變化小)以 穩定地進行氣體產生裝置之燃燒,故不會產生氣體產生裝 置之燃燒殘留。 又本發明,作爲其他之解決手段,係提供一種混合式充 氣器,具備有車輛之膨脹式安全系統的氣囊’其中具充氣 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) ------訂---------線• 483841 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明(今) 器外殻;收容於充氣器內的氣體產生器;以及連接於氣體 產生器的點火裝置室,其特徵爲,在該充氣器外殻內充塡 含惰性热體的加壓媒質’氣體產生器具有含氣體產生裝置 的1或2以上之氣體產生室者’而該加壓媒質不含氧氣,該 氣體產生裝置爲包含燃料及氧化劑者。 再者,本發明作爲其他之解決手段,係提供一種混合式 充氣器’具備有車輛之膨脹式安全系統的氣囊,其中具充 氣器外殼’收容在充氣器內的氣體產生器;連接於氣體產 生器的點火裝置室’其特徵爲,在該充氣器外殼內充塡含 惰性氣體的加壓媒質’氣體產生器具有含氣體產生裝置的1 或2以上之氣體產生室者,而於該加壓媒質不含氧氣,該氣 體產生裝置之燃燒時的次式:r b = α Pn (式中,r b :燃燒 速度、α :係數、P :壓力、η ··壓力指數)所規定的壓力 指數爲0 . 8以下者。 本發明之混合式充氣器使用的加壓媒質,係由惰性氣體 所成者,實質上不包含氧氣。作爲惰性氣體,例如可採用 氬(A r )、氦(He ),此外亦可倂用氮(Ν ),於本發明稱惰性氣 體時也包含氮者。氬係作用促進加壓媒質之熱膨脹,若含 予氦則變成容易檢測加壓媒質之洩漏,所以可防止不良品 之流通至爲理想。加壓媒質之充塡壓力爲1 〇 , 000〜 70,000kPa , 20,000 〜60,000kPa 爲理想。 於本發明之混合式充氣器,氣體產生劑係以包含燃料及 氧化劑或燃料、氧化劑及渣形成劑者,因應於需要與結合 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ---------------^ (請先閱讀背面之注意事項再填寫本頁) 483841 經濟部智慧財產局員工消費合作社印製 A7 _JB7____ _ 五、發明說明(Ο 劑一起混合,採用成形爲所希望形狀者。 而在本發明之混合式充氣器,作爲氣體產生劑予以採用 具有1或2以上之、通? L或"非穿通? 的有孔圓筒狀者爲理 想。並由於採用此種有孔圓筒狀之氣體產生劑,可以促進 氣體產生劑之燃燒,故能提高混合式充氣器之作動性能。 如此之有孔圓同狀之氣體產生劑’可適當設定爲對混合 式充氣器的應用範圍之外徑(R)、內徑(d)及長(L)。具有1 個穿通孔的單孔圓筒狀者時,外徑爲6mm以下,對厚度 (W ) [ ( R - d ) / 2 ]的長度比(L / W )以1以上爲理想。其有2以上 穿通孔的多孔圓筒狀者時,對於外徑爲60mm以下,厚度(W)( 以均勻配置複數之孔時,孔與孔之距離未均勻配置時,取 各距離之平均値)的長度比(L / W )以1以上爲理想。再者,具 有1或2以上之非穿通孔者時,對於外徑60mm以下,厚度 (W)(與上述之多孔圓筒狀者同定義)的長度比(L/W)爲1以 上,非穿通孔部分之壁厚W ’(非穿通孔之底部至圓筒狀物之 底部之距離)與厚度W之比(W ’ / W )以0 . 5〜2爲理想。 本氣體產生劑,由其燃燒所發生的氣體,係與加壓媒質 一起對於氣囊之膨脹展開有用者。特別是於本發明,由於 採用含渣形成劑的氣體產生劑,可大幅度地減低自充氣器 排出的霧(m i s t )之量。 作爲燃料,最好是由硝基胍(NQ)、胍硝酸鹽(GN)、胍碳 酸鹽、胺基硝胍、胺基胍硝酸鹽、胺基胍碳酸鹽、二胺基 胍硝酸鹽、二胺基胍碳酸鹽、三胺基胍硝酸鹽等之胍衍生 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) . ·------訂---------線«Hill- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 483841 A7 _ _________ B7 五、發明說明(() 物等所選擇1或2以上。 作爲氧化劑,最好是由硝酸緦、硝酸鉀、硝酸銨、過氯 酸鉀、氧化銅、氧化鐵、鹼式硝酸銅所選擇1或2以上。 氧化劑之配合量係對於燃料1 〇〇重量份,以1 〇〜80重量 份爲理想,更理想爲2 0〜5 0重量份。 作爲渣形成劑’由酸性黏土、滑石、膨潤土、矽藻土、 高嶺土、矽石、氧化鋁、矽酸鈉、氮化矽、碳化矽、氯鈣 石及此等混合物選擇的1或2以上爲理想。 渣形成劑之配合量,對於燃料1 0 0重量份,以〇〜< 0重 量份爲理想,更理想爲1〜1 0重量份。 作爲結合劑,由羧甲基纖維素之鈉鹽,羥乙基纖維素、 澱粉、聚乙烯醇、胍橡膠、微結晶性纖維素、聚丙烯酸醯 胺、硬脂酸鈣等選擇的1或2以上爲理想。 結合劑之配合量係對於燃料1 00重量份,以0〜3 0重量 份爲理想,更理想爲3〜1 0重量份。 又,於本發明之壓力指數(η )爲0 . 8以上,例如並不是使 用RDX等之槍型的氣體產生劑,乃以採用上述壓力指數(η ) 爲0.8以下之氣體產生劑爲特徵者。 更於本發明之混合式充氣器,可以高張力鋼來形成充氣 器外殻,在此情況抗拉強度爲60kg/mm2以上,可以使用80 〜1 05kg/mm2者爲理想。 如此由於以高拉力鋼形成充氣器外殼,因可提高耐壓性 ,更可將外殻之壁厚作成薄而減少容積。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -·· . ------訂---------線 ΦΦ (請先閱讀背面之注意事項再填寫本頁) 媒濟部智慧財產局員工消費合作社印製 4^3841 A7 ______B7 五、發明說明(?) 又本發明作爲別的解決手段,係提供具充氣器外殼;收 容於充氣器外殼內的氣體產生器;以及連接氣體產生器的 點火裝置之具備氣囊,用於車輛之膨脹式安全系統的混合 式充氣器,其特徵爲,充塡加壓媒質於該充氣器外殼內, 氣體產生器,具包含氣體產生裝置的1或2以上之氣體產生 者,該加壓媒質之量(A莫耳)與由該氣體產生裝置之燃燒產 生的氣體量(B莫耳)的莫耳比(A/B),爲8/2〜1/9。 於本發明,A/B最好是8/2〜3/7。又,加壓媒質雖以不 包含氧氣者爲理想’但是爲了促進氣體產生劑之燃燒,加 壓媒質亦可包含氧氣。欲包含氧氣時之添加量以10莫耳% 以下爲理想,更理想是5莫耳%以下。 作爲氣體產生裝置’雖使用含有除了硝胺系化合物的非 疊氮基有機化合物者,但作爲包含疊氮基系化合物者,揭 示於美國專利第5,5 0 7,8 9 1號說明書,申請專利範圍所示列 舉推進劑組成物,例如,列舉包含環三亞甲基三硝胺 (cyclotrimethylene trinitramine(RDX)、環四亞甲基四 硝胺(cyclotetramethlene tetranitramine)(HMX)的組成 物。又,於其他,揭示在特開平8 - 2 8 2 4 2 7號公報,申請專 利範圍所示的推進劑,例如,記載於請求項第3 2項列舉的 二次炸藥及黏合劑(binder)系。二次炸藥列舉記載於同公 報請求項第34項的RDX、HMX、PETN、TAGN等,黏合劑系 記載於請求項第37、38項列舉的包含CA、CAB、CAP、EC 、PVA等結合劑者。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ------------·暴----- --訂------ (請先閱讀背面之注意事項再填寫本頁) 1— ^1 1 ΦΨ 483841 A7 B7 五、發明說明(F ) 除作爲硝胺系化合物外含有非疊氮基有機化合物的氣體 產生劑,可使用如次之含氮化合物。例如,列舉由三唑衍 生物、四唑衍生物、胍衍生物、偶氮甲醯胺衍生物 '肼衍 生物所選擇1或2以上之混合物。作爲該等之具體例,係列 舉5 -酮基-1,2, 4-三唑、四唑、5 -胺基四唑,5,5 -二-1H-四唑、脈、硝基胍、氰基胍、三胺基胍硝酸鹽、硝酸胍、 碳酸胍、縮二脲、偶氮甲醯胺、碳醯肼、碳醯肼硝酸鹽錯 合物、草醯肼、肼硝酸鹽錯合物等。 本發明,係可適用於氣體產生器,具有含氣體產生裝置 的1個氣體產生室者(單型)、具有2個氣體產生室者(雙型) 或具有3個以上氣體產生室者。氣體產生室有2以上時之配 置並未特別被限定,例如氣體產生室爲2個時,係2個氣體 產生室直排長度方向且隣接配置的構造者,可作成爲在長 度方向直排且離開配置的構造者,並排在寬度方向且鄰接 '配置的構造者,並排在寬度方向且離開配置的構造者等。 尙,並排於寬度方向的配置時,包含將2個氣體產生室配置 在同心圓,在一個氣體產生室之外側配置其他之氣體產生 室時或寬度方向之剖面爲2個半圓形之氣體產生室配置於 寬度方向時。 並於上述的混合式充氣器,可將氣體產生裝置構成爲保 持於常壓的環境中。如此將氣體產生裝置非於加壓環境而 保持在常壓環境中時,經過長期間中由壓力氣體產生裝置 不易被劣化所以理想。而由壓力受到劣化時’於燃燒時氣 -1 0 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) ♦ -ΦΦ----- -訂--------- 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 4f83841 A7 __B7 五、發明說明(T) 體產生裝置有時會變成容易崩壞。 於上述的本發明,「氣體產生器」,係由存在於氣體產 生室內的氣體產生裝置(氣體產生劑)之燃燒產生高溫燃燒 氣體,其意爲具有將該高溫燃燒氣體流出於充氣器外殼內 的氣體產生機能。又,混合式充氣器,乃在充氣器內含有 該氣體產生器者,「充氣器」係依自該氣體產生器流出的 高溫燃燒氣體之作用,使存在於充氣器外殻內及氣體產生 器外的加壓媒質流出外部,具有膨脹氣囊等的被膨脹性物 品功能者之意,/混合式」,係利用組合由氣體產劑之燃 燒的高溫燃燒氣體與加壓媒質之兩方之意。 更於本發明,係提供一種氣囊裝置,其特徵爲具備:由 衝擊感測器及控制單元所成作動信號輸出裝置;以及在箱 內收容該混合式充氣器與氣囊的模組箱。 本發明之混合式充氣器,係調整由加壓媒質之量與氣體 產生劑之燃燒所產生的氣體量的莫耳比,再由以調整加壓 媒質與氣體產生劑之組成及/或使用高抗力鋼提高耐壓性 ,比先前品可小型化且輕量化。 [圖式之簡單說明] 第1圖 表示本發明混合式充氣器之一實施形態縱剖面 圖。 第2圖 表示本發明混合式充氣器之其他實施形態縱剖 面圖。 [符號之說明] -1 1 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -------訂--------- (請先閱讀背面之注意事項再填寫本頁) 483841 A7 一__ B7五、發明說明(p) 100 混 合 式 充 氣器 102 充 氣 器 外 殼 110 氣 體 產 生 器 120 氣 體 產 生 室 122 氣 體 產 生 劑 130 點 火 器 132 升 壓 器 140 擴 散 器 142 擴 散 器 Ρ 148 主 破 裂 板 150 螺 樁 [發明之實施 形 態 ] (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 以下’依顯示本發明一實施例之圖面,詳細說明本發明 〇 第1圖’係氣體產生室以1個混合式充氣器1〇〇往長度方 向之剖面圖。 充氣器外殼10 2由筒狀容器所成者,由高拉力鋼形成。 在充氣器外殼102之內部空間103,以所要壓力充塡不含氧 氣的惰性氣體(A r、He及N2 )之加壓媒質。通常,加壓媒質 係從形成於連接充氣器1 0 2之一端側的輪殻1 〇 4的細孔1 〇 6 充塡,該細孔在充塡加壓媒質後由密封銷1 0 8閉塞。 氣體產生器110 ,具有筒狀氣體產生器外殼112、隔壁 1 1 4及亦具藥量調整功能的隔壁1 1 6;所形成的一個氣體產生 -12- m--------訂---------# 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 483841 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明(丨丨) 室120,在氣體產生室120之內部,充塡有由所要量之燃料 及氧化劑所成氣體產生劑1 22。於外殼1 1 2形成所要數量之 連通孔1 2 4,更因應於需要,在形成氣體產生室1 2 0內部側 之連通孔124的地方設過濾器/濾網亦可。氣體產生室120 之內部通過連通孔1 24流入有加壓媒質,故與充氣器外殼 1〇2之內部空間103保持於同壓力。 並於充氣器外殻1 02之一端側,對氣體產生器1 1 0連接點 火裝置,點火裝置係具有"點火器1 3 (f;由點火器之作動著火 燃燒之充塡於升壓器杯的升壓器(傳火藥)1 3 2,點火器1 3 0 與升壓器1 3 2之間設置破裂板1 3 4。1 3 6爲將點火器固定於 輪轂104用之起動軸環(initiator collar)。 在充氣器外殼102之另一端側連接擴散器140,擴散器140 具有:除去微粒子用之擴散器網144、146。於擴散器140 之充氣器1 02內部側,形成主破裂板1 48,在外表面側以焊 接固定連接氣囊模組用之螺樁1 5 0。 並於第1圖之混合式充氣器1 00,加壓媒質之量(A莫耳) 與由氣體產生劑122之燃燒產生的氣體量(B莫耳)之莫耳比 (A / B )設定爲8 / 2〜1 / 9,再者,設定壓力指數(η )爲0 . 8以 下。又,加壓媒質之重量(a)與氣體產生劑之重量(b)的重 量比(a/b)設定成爲0.1〜7。 因而,點火器130之作動,由升壓器132之著火使氣體產 生劑122燃燒時,予防止內壓之過度上升。而且由氣體產生 劑1 2 2之燃燒所產生的氣體,係通過連通孔1 2 4流入內部空 -1 3 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) *· ---------------- 丨訂--------- S4 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 483841 A7 _______B7___ 五、發明說明(h) 間103,與加壓媒質一起增高內壓,使主破裂板148破裂。 其後,從擴散器口 1 42噴射加壓媒質及產生氣體,用以作用 氣囊的膨脹展開。 其次’說明第2圖所示的混合式充氣器200。本混合式充 氣器200,係於第1圖所示加上相當於混合式充氣器1 00的 氣體產生室120之第1氣體產生室120,更具有第2氣體產 生室220,除具有連接於各個的第1點火器13〇與第2點火 器2 3 0外’乃成爲同一形態而同一作用者,故同一部分附予 與第1圖同樣號碼以省略說明。, 第2氣體產生室220,係由筒狀之氣體產生器外殻1 12、 隔壁1 16及輪較104形成,藉由第2破裂板2 3 4連接第2點 火器230。尙,222爲第2氣體產生劑,224爲連通孔,122 爲第1氣體產生劑,1 3 4爲第1破裂板。 並於上述實施形態之混合式充氣器,係氣體產生劑並不 是在加壓媒質中,可作成保持於常壓環境中的構造。而作 爲如此的混合式充氣器,例如,於存在加壓媒質的空間(稱 此空間爲「加壓媒質充塡室」)與氣體產生室之間配置搪胃纟 遥’以隔壁及破裂板完全隔開加壓媒質充塡室與擴散器, 將加壓媒質充塡室內保持於加壓環境,可列舉保持氣體產 生室內在常壓環境者。該混合式充氣器,係由氣體產生室 內的氣體產生劑之燃燒予以破壞破裂板時,通過被破壞的 加壓媒質充塡室內之加壓媒質的破裂板從擴散器排出,使 氣囊膨脹。 -1 4- 紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ~ ^^ Φ3------ —訂--------- $φ (請先閱讀背面之注意事項再填寫本頁) 483841 A7 ____B7__ 五、發明說明(U ) 本發明之氣囊裝置,係具備有:衝擊感測器及控制單元 所成作動信號輸出裝置;以及在模組箱內收容混合式充氣 器與氣囊的模組箱者。例如,第1圖之混合式充氣器1 〇 〇, 係在點火器1 3 0側連接於作動信號輸出裝置(衝擊感測器及 控制單元),於安裝氣囊的模組箱內,以螺合螺樁1 5〇來連 接固定。 本發明之混合式充氣器,係對於上述以外之構成因素經 由業者可適當地進行通常例行的改變。因而,破裂主破裂 板1 4 8的手段並非利用氣體壓力之手段,公知之機械方式的 破裂裝置,例如採用銳利形狀之發射體方式者,或電氣方 式的破裂裝置,例如變更爲採用破裂板用點火器方式者等 可進行改變。 [實施例] 以下,由實施例更加詳細說明本發明,但本發明並非由 此等所限定者。尙,於以下採用的氣體產生劑,爲單孔圓 筒狀,外徑5.4mm、內徑0.7mm、長度5mm者。 (實施例1 ) 製造第1圖所示形態之混合式充氣器1 00。詳細係如下述 〇 充氣器外殻102係採用高拉力鋼(抗拉強度90kg/mm2)所 製作。加壓媒質採用氬及氦混合氣體[Ar :He = 96 : 4(莫耳比 )]2.6莫耳(100g)(內壓3 2,000kPa)、氣體產生劑採用由硝 基胍:硝酸緦:羧甲基纖維素:酸性黏土( 3 4 : 5 0 : 9 : 7 )所成 -1 5 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) •^11-------訂---------φ· 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 483841 A7 _B7 五、發明說明(W) 者40g(相當於產生氣體量ι·〇莫耳)的(A/B = 7 8)。加 壓媒質與氣體產生劑之重量比(a/b)爲2.5。因此,作動時 可予以利用合計3 · 6莫耳之氣體’而作動前之加壓媒質與氣 體產生劑之合計重量爲140g。尙,此氣體產生劑之壓力指 數(η )爲 0 · 6。 由以上構成所成的混合式充氣器1〇〇,係爲直徑59mm、 長度156mm(除掉螺樁150的長度。螺樁15〇之長度2〇mm), 充氣器外殼102之壁厚2.5mm,全重量爲ii〇〇g。予作動如 此的混合式充氣器1 0 0,結果內壓成爲4 4 1 00 k P a。 (比較例1 ) 製造第1圖所示形態之混合式充氣器丨00。其詳細如下。 充取益外威102採用通常之鋼(抗拉強度40kg/mm2)製作 。加壓媒質採用氬及氦混合氣體[〇2:Ar: He = 20 :76:4(莫 耳比)]3 · 6莫耳(140g)(內壓32,000 kPa),氣體產生劑採用 由RDX與聚丙烯酸酯彈性體所成者8g(相當於產生氣體量 〇 · 39莫耳)(A/B = 9 . 2 / 1 )。加壓媒質與氣體產生劑之重量比 (a/b)爲17.5。自加壓媒質與氣體產生劑之產生氣體,在作 動時由於反應成爲合計3 . 7 8莫耳。氣體產生劑係爲使所有 3 · 7 8莫耳之氣體利用於膨脹氣囊用能充分發熱者。因而’ 加壓媒質與氣體產生劑之合計重量成爲147g。尙’氣體產 生劑之壓力指數(η )爲1 · 〇。 由以上之構成所成的混合式充氣器100,爲了確保實用上 的耐壓性使充氣器外殻之壁厚爲3 · 3 mm ,所以直徑成爲 -1 6 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --- (請先閱讀背面之注意事項再填寫本頁) tT---------^9—φ. 經濟部智慧財產局員工消費合作社印製 483841 A7 _____B7__ 五、發明說明(、5Γ) 60 · 6min。又,加壓媒質之充塡量多,並爲使與實施例1成 同壓力,長度成爲178.7mm(去掉螺樁150的長度。而螺樁 150之長度20mm),混合式充氣器之全重量爲1680g。以作 動如此的混合式充氣器1〇〇,結果內壓成爲5 8 8 00kPa。 (實施例2 ) 製造與實施例1同樣的混合式充氣器1 0 0。但是,內容積 以0 . 1 6L,收容氣體產生劑的氣體產生器容積,係調整爲可 收容所使用的氣體產生劑量。其他之構成因素如下所述。 加壓媒質:氬與氯之混合氣體[Ar:He = 96M(莫耳比)1.6 莫耳(62g)(內壓 3 2,000kPa) 氣體產生劑:與實施例1同樣者80g(產生氣體量2 . 0莫耳) A/B : 1·6/2·0 a/b : 62/80 = 0.775 作動時之合計氣體量:3 · 6莫耳 作動如此的混合式充氣器結果,內壓爲6 8,0 0 0 k P a。 (實施例3 ) 於實施例2,以氣體產生器作耐壓性容器,使收容氣體產 生劑之氣體產生室爲常壓以外係同樣製造了混合式充氣器 。尙,爲保持氣體產生室在常壓,於氣體產生室與充氣室 外殻之間設置破裂板。作動如此的混合式充氣器之結果, 獲得大致與實施例2同樣結果。 (實施例4 ) 製造第2圖所示形態之雙型混合式充氣器200。其詳細如 -1 7 - 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ------------------訂--------- (請先閱讀背面之注意事項再填寫本頁) 483841 Α7 Β7 五、發明說明(β) 下。 充氣器外殻102係採用局抗拉鋼(抗拉強度90kg/mm2)製 作。 加壓媒質採用氬及氦混合氣體[A r : H e = 9 6 ·· 4 (莫耳比 )]2·6莫耳(100g)(內壓32,000kPa),氣體產生劑,由硝基 胍:硝酸緦:羧甲基纖維素:酸性粘土( 3 4 ·· 5 0 ·· 9 : 7 )所成者 ,使用第1氣體產生室20g,第2氣體產生室20g(計40g而 相當於產生氣體量1.0莫耳)(A/B = 7.2/2.8)。加壓媒質與 氣體產生劑之重量比(a / b )爲2 · 5。因此,在作動時可予利 用合計3 . 6莫耳之氣體’其作動前之加壓媒質與氣體產生劑 之合計重量爲140g 。尙’此氣體產生劑之壓力指數(n)爲 0 · 6 〇 由以上之構成所成混合式充氣器200,爲直徑59111111,長 度156mm(去掉螺樁150的長度。螺樁15〇之長度2 0 mm),充 氣器外殻102之壁厚2.5mm,全重量爲i2〇〇g。將如此的混 合式充氣器200,由第1點火器與第2點火器同時著火作動 的結果,內壓成爲8,OOOkPa。 (實施例5 ) 於實施例1作爲加壓媒質,除採用氬、氧及氦混合氣體 [A r : 〇2 : H e = 9 3 : 3 : 4 (莫耳比)]以外依同樣,製造了混合式 充氣器。予作動此混合式充氣器的結果,除一部分生成的 C〇及Η2變換爲C 02及Η2 0以外,獲得與實施例1同樣的結果 〇 -18- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公爱) (請先閱讀背面之注意事項再填寫本頁) --------訂---------φ 經濟部智慧財產局員工消費合作社印製84 A7B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (f) (a / b) is o.i ~ 7, preferably 0.5 ~ 5. The hybrid inflator described in the above, because it is desired to show the above-mentioned effects more effectively ^ 'The pressurized medium is ideal if it does not contain oxygen, and then it is ideal to use a fuel and an oxidant-containing gas generator as the gas generating device. In addition, when a fuel generator, an oxidant, and a slag-forming agent-containing gas generator is used as the gas ® device, the above-mentioned effects and effects are preferable because the occurrence of harmful minute substances can be suppressed for passengers. In addition, the hybrid inflator described above is used for combustion of a gas generating device, and the following formula can be used: rb = α Ρη (where, rb: combustion speed, α: coefficient, P: pressure, η: pressure index ) The prescribed pressure index is below 0.8. The pressure index (η) is preferably from 0.1 to 0.8, and more preferably from 0.1 to 0.7 7, and the pressure index η is measured in a container at a pressure of 70 kg / cm2), the combustion rate rb! , After measuring the combustion speed rb2 in a container with a pressure P2 (100kg / cm2), calculate it from the formula 2 of rbi = α Pιη and rb2 = α P2n. In this way, since the pressure index (η) is set to 0.8 or less, a rapid increase in the combustion speed in the initial combustion period of the gas generating device is suppressed, so that the increase in the internal pressure of the casing is small. Therefore, when the wall thickness of the casing is reduced, sufficient pressure resistance can be maintained. In addition, since the increase in the internal pressure of the casing is small (that is, the change in the internal pressure is small) to stably perform the combustion of the gas generating device, the combustion residue of the gas generating device is not generated. The present invention, as another means for solving the problem, provides a hybrid inflator equipped with an airbag of an inflatable safety system of a vehicle, wherein the paper is inflated and the paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) ) (Please read the notes on the back before filling out this page) ------ Order --------- line • 483841 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention ( The present invention), a gas generator housed in an inflator, and an ignition device room connected to the gas generator, characterized in that the inflator housing is filled with a pressurized medium containing an inert hot gas. The generator has one or two or more gas generating chambers containing a gas generating device, and the pressurized medium does not contain oxygen, and the gas generating device includes a fuel and an oxidant. Furthermore, as another solution, the present invention provides a hybrid inflator 'airbag provided with an inflatable safety system of a vehicle, which has an inflator housing' a gas generator housed in the inflator; connected to the gas generator The ignition device chamber of the device is characterized in that a pressurized medium containing an inert gas is filled in the casing of the inflator. The gas generator has a gas generating chamber containing 1 or 2 or more of gas generating devices. The medium does not contain oxygen, and the following equation during combustion of the gas generating device: rb = α Pn (where, rb: combustion speed, α: coefficient, P: pressure, η ·· pressure index) The pressure index specified is 0 . 8 or less. The pressurized medium used in the hybrid inflator of the present invention is made of an inert gas and does not substantially contain oxygen. As the inert gas, for example, argon (A r) or helium (He) can be used. In addition, nitrogen (N) can also be used. When the inert gas is referred to in the present invention, nitrogen is also included. The argon-based action promotes the thermal expansion of the pressurized medium, and if helium is contained, it becomes easy to detect the leakage of the pressurized medium, so it is ideal to prevent the flow of defective products. The charge pressure of the pressurized medium is 10,000 ~ 70,000kPa, and 20,000 ~ 60,000kPa is ideal. In the hybrid inflator of the present invention, the gas generating agent is composed of fuel and oxidant or fuel, oxidant and slag forming agent. According to the needs and combination of this paper standard, China National Standard (CNS) A4 specification (210 X 297) (%) --------------- ^ (Please read the notes on the back before filling this page) 483841 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _JB7____ _ V. Description of the invention ( 〇 The agents are mixed together and shaped into a desired shape. In the hybrid inflator of the present invention, a holed cylinder having a diameter of 1 or 2 or higher, L or "non-through" is used as a gas generating agent. The shape is ideal. And because this kind of hole-shaped cylindrical gas generating agent can promote the combustion of the gas generating agent, it can improve the operating performance of the hybrid inflator. 'The outer diameter (R), inner diameter (d), and length (L) can be appropriately set for the application range of the hybrid inflator. For a single-hole cylindrical shape with one through hole, the outer diameter is 6 mm or less , For thickness (W) [(R-d) / 2] length The ratio (L / W) is preferably 1 or more. For a porous cylindrical shape with 2 or more through holes, the thickness (W) (for uniformly arranged plural holes, the diameter of the holes is 60 mm or less) When the distances are not uniformly arranged, the length ratio (L / W) of the average distance 値) is preferably 1 or more. In addition, when the non-through hole has 1 or 2 or more, the thickness ( W) (Same definition as the above porous cylindrical shape) The length ratio (L / W) is 1 or more, and the wall thickness W 'of the non-through hole portion (the distance from the bottom of the non-through hole to the bottom of the cylindrical object) The ratio (W '/ W) to the thickness W is preferably from 0.5 to 2. The gas generating agent, the gas generated by its combustion, is useful for the inflation and deployment of the airbag together with the pressurized medium. Especially In the present invention, since a slag-forming agent-containing gas generating agent is used, the amount of mist (mist) discharged from the inflator can be greatly reduced. As the fuel, nitroguanidine (NQ) and guanidine nitrate ( GN), guanidine carbonate, aminoguanidine nitrate, aminoguanidine nitrate, aminoguanidine carbonate, diamine guanidine nitrate Derivatives of guanidine, diamine guanidine carbonate, triamine guanidine nitrate, etc. The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). ----- line «Hill- (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 483841 A7 _ _________ B7 V. Invention Description (() Objects, etc. 1 or 2 or more. As the oxidizing agent, 1 or 2 or more selected from thorium nitrate, potassium nitrate, ammonium nitrate, potassium perchlorate, copper oxide, iron oxide, and basic copper nitrate is preferred. The blending amount of the oxidizing agent is preferably 100 to 80 parts by weight, and more preferably 20 to 50 parts by weight. As a slag forming agent 1 or 2 selected from acid clay, talc, bentonite, diatomaceous earth, kaolin, silica, alumina, sodium silicate, silicon nitride, silicon carbide, chlorite and mixtures thereof ideal. The compounding amount of the slag forming agent is preferably 0 to < 0 parts by weight, and more preferably 1 to 10 parts by weight, for 100 parts by weight of the fuel. As the binding agent, 1 or 2 selected from the sodium salt of carboxymethyl cellulose, hydroxyethyl cellulose, starch, polyvinyl alcohol, guanidine rubber, microcrystalline cellulose, polyacrylamide, calcium stearate, etc. The above is ideal. The blending amount of the binder is 100 to 100 parts by weight of the fuel, preferably 0 to 30 parts by weight, and more preferably 3 to 10 parts by weight. The pressure index (η) of the present invention is 0.8 or more. For example, instead of using a gun-type gas generator such as RDX, it is characterized by using a gas generator having a pressure index (η) of 0.8 or less. . Furthermore, the hybrid inflator of the present invention can be made of high-tensile steel to form an inflator housing. In this case, the tensile strength is 60 kg / mm2 or more, and it is desirable to use 80 to 105 kg / mm2. In this way, because the inflator shell is formed of high tensile steel, the pressure resistance can be improved, and the wall thickness of the shell can be made thin to reduce the volume. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)-··. ------ Order --------- Line ΦΦ (Please read the precautions on the back before (Fill in this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Media and Economics 4 ^ 3841 A7 ______B7 V. Description of the invention (?) As another solution, the present invention provides an inflator housing; A gas generator; and a hybrid inflator provided with an airbag of an ignition device connected to the gas generator and used for an expansion safety system of a vehicle, characterized in that a pressurized medium is filled in the inflator housing, the gas generator, With a gas generator containing 1 or 2 or more gas generators, the molar ratio of the amount of pressurized medium (A mole) to the amount of gas (B mole) produced by the combustion of the gas generator (A / B), from 8/2 to 1/9. In the present invention, A / B is preferably 8/2 to 3/7. The pressurized medium is preferably one which does not contain oxygen ', but in order to promote the combustion of the gas generating agent, the pressurized medium may also include oxygen. The amount of oxygen to be added is preferably 10 mol% or less, and more preferably 5 mol% or less. As a gas generating device, although a non-azide-based organic compound containing a compound other than a nitramine-based compound is used, a device containing an azide-based compound is disclosed in U.S. Patent No. 5,507,89.1 The scope of the patent includes propellant compositions, for example, a composition containing cyclotrimethylene trinitramine (RDX), cyclotetramethlene tetranitramine (HMX), and the like. Others are disclosed in Japanese Patent Application Laid-Open No. 8-2 8 2 4 2 7 and the propellants shown in the scope of the patent application are, for example, the secondary explosives and binders listed in item 32 of the claim. Sub-explosives are listed in RDX, HMX, PETN, TAGN, etc. of the same item as in claim 34 of the same bulletin. Adhesives are listed in CA, CAB, CAP, EC, PVA, and other binders listed in items 37 and 38 of the request. . This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ------------ · Burst ----- --Order ------ (Please Read the notes on the back before filling in this page) 1— ^ 1 1 ΦΨ 483841 A7 B7 Description (F) In addition to the nitrazine-based compound, a gas generating agent containing a non-azide-based organic compound can be used as a nitrogen-containing compound. Examples include triazole derivatives, tetrazole derivatives, and guanidine derivatives. 1, 1 or 2 selected from the hydrazine derivatives and hydrazine derivatives. As specific examples of these, 5-keto-1,2,4-triazole, tetrazole, 5-amine Tetrazolium, 5,5-bis-1H-tetrazole, vein, nitroguanidine, cyanoguanidine, triaminoguanidine nitrate, guanidine nitrate, guanidine carbonate, biuret, azomethamine, carbohydrazone Hydrazine, carbohydrazine nitrate complex, grass hydrazine, hydrazine nitrate complex, etc. The present invention is applicable to a gas generator and has a gas generating chamber containing a gas generating device (single type) 2. Those with two gas generating chambers (double type) or those with three or more gas generating chambers. The configuration of the gas generating chambers with two or more is not particularly limited. For example, when there are two gas generating chambers, two gases are used. Constructors that produce chambers that are arranged in the longitudinal direction and are adjacent to each other can be used as structures that are arranged in the longitudinal direction and are separated from each other. The builders are arranged side by side in the width direction and adjacent to the 'arranged structure', and the builders are arranged side by side in the width direction and separated from the layout. 尙 When the side by side is arranged in the width direction, the two gas generating chambers are arranged in concentric circles. When other gas generating chambers are arranged outside one gas generating chamber or when two semicircular gas generating chambers with a cross section in the width direction are arranged in the width direction. In the above-mentioned hybrid inflator, the gas generating device can be configured as Keep in a normal pressure environment. When the gas generating device is maintained in a normal pressure environment other than a pressurized environment in this way, the pressure gas generating device is not easily deteriorated over a long period of time, so it is preferable. When degraded by pressure, 'at the time of combustion-1 0-This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page) ♦ -ΦΦ ----- -Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 4f83841 A7 __B7 V. Description of the invention (T) It can easily break down. In the present invention described above, the "gas generator" is a high-temperature combustion gas generated by the combustion of a gas generating device (gas generator) existing in the gas generation chamber, which means that the high-temperature combustion gas flows out of the inflator housing. Gas generating function. In addition, the hybrid inflator contains the gas generator in the inflator. The "inflator" is based on the action of the high-temperature combustion gas flowing out of the gas generator, so that it exists in the inflator shell and the gas generator. The external pressurized medium flows out and has the function of an inflatable article such as an inflation bladder. "Hybrid type" refers to the use of both the high-temperature combustion gas and the pressurized medium that are combusted by the gas generating agent. Furthermore, the present invention provides an airbag device, which is characterized by comprising: an operation signal output device formed by an impact sensor and a control unit; and a module case that houses the hybrid inflator and the airbag in a box. The hybrid inflator of the present invention adjusts the molar ratio of the amount of pressurized medium and the amount of gas generated by the combustion of the gas generating agent, and then adjusts the composition of the pressurized medium and the gas generating agent and / or uses a high Resistant steel improves pressure resistance and can be made smaller and lighter than previous products. [Brief description of the drawings] Fig. 1 shows a longitudinal sectional view of an embodiment of the hybrid inflator of the present invention. Fig. 2 is a longitudinal sectional view showing another embodiment of the hybrid inflator of the present invention. [Explanation of Symbols] -1 1-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------- Order --------- (Please read the back first Please pay attention to this page and fill in this page again) 483841 A7 __ B7 V. Description of the invention (p) 100 Hybrid inflator 102 Inflator housing 110 Gas generator 120 Gas generation chamber 122 Gas generator 130 Igniter 132 Booster 140 Diffuser 142 Diffuser P 148 Main rupture plate 150 Screw pile [Implementation mode of the invention] (Please read the precautions on the back before filling this page) The following is printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs: The drawing of the example illustrates the present invention in detail. Fig. 1 is a sectional view of the gas generating chamber in the longitudinal direction with one hybrid inflator 100. The inflator housing 102 is formed of a cylindrical container and is formed of high tensile steel. The inner space 103 of the inflator housing 102 is filled with a pressurized medium containing oxygen-free inert gases (Ar, He, and N2) at a desired pressure. Generally, the pressurized medium is filled with a small hole 1 06 formed in a wheel housing 1 04 connected to one end side of the inflator 102, and the fine hole is closed by a sealing pin 108 after the pressurized medium is filled. . The gas generator 110 has a cylindrical gas generator housing 112, a partition wall 1 1 4 and a partition wall 1 1 6 which also has a function of adjusting the amount of medicine; a formed gas generates -12-m -------- order --------- # This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 483841 Printed by A7 B7, Consumer Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs V. Description of Invention (丨 丨) The chamber 120 is filled with a gas generating agent 122 made of a desired amount of fuel and an oxidant inside the gas generating chamber 120. A desired number of communication holes 1 2 4 are formed in the housing 1 12, and a filter / strainer may be provided at a place where the communication holes 124 on the inner side of the gas generation chamber 1 20 are formed as needed. The inside of the gas generating chamber 120 flows into the pressurized medium through the communication hole 12 and is maintained at the same pressure as the internal space 103 of the inflator housing 102. An ignition device is connected to the gas generator 1 10 at one end side of the inflator housing 02. The ignition device has " ignition device 1 3 (f; charged by the action of the ignition device and charged with a booster). The cup booster (powder gunner) 1 3 2 is provided with a rupture plate 1 3 4 between the igniter 1 3 0 and the booster 1 3 2. 1 3 6 is a starting collar for fixing the igniter to the hub 104 (Initiator collar). A diffuser 140 is connected to the other end side of the inflator housing 102. The diffuser 140 includes: diffuser nets 144 and 146 for removing fine particles. Inside the inflator 102 of the diffuser 140, a main rupture is formed. The plate 1 48 is connected to the screw pile 150 for the airbag module by welding on the outer surface side. The hybrid inflator 100 shown in Fig. 1 has a quantity of pressurized medium (A mole) and a gas generating agent. The molar ratio (A / B) of the amount of gas (B mole) produced by the combustion of 122 is set to 8/2 to 1/9, and the pressure index (η) is set to 0.8 or less. Furthermore, pressurization The weight ratio (a / b) of the weight of the medium (a) to the weight of the gas generating agent (b) is set to 0.1 to 7. Therefore, the operation of the igniter 130, When the fire of the booster 132 causes the gas generating agent 122 to burn, excessive increase in the internal pressure is prevented. Moreover, the gas generated by the combustion of the gas generating agent 1 2 2 flows into the internal space through the communication hole 1 2 4-1 3 -This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) * · ---------------- 丨 Order --------- S4 (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 483841 A7 _______B7___ V. Description of the invention (h) 103, increase the internal pressure with the pressurized medium, and make the main rupture plate 148 Rupture. Thereafter, pressurized medium and gas are sprayed from the diffuser port 1 42 to expand and deploy the airbag. Next, the hybrid inflator 200 shown in FIG. 2 will be described. The first gas generating chamber 120 corresponding to the gas generating chamber 120 of the hybrid inflator 100 is added to the first figure, and the second gas generating chamber 220 is provided in addition to the first igniter 13 connected to each. It has the same form and the same effect as the second igniter 2 3 0, so the same part is attached The same number is used in FIG. 1 to omit the description. The second gas generating chamber 220 is formed by a cylindrical gas generator housing 1 12, a partition wall 1 16 and a wheel 104, and is connected to the second gas rupture plate 2 2 4 2 igniter 230. Well, 222 is a second gas generator, 224 is a communication hole, 122 is a first gas generator, and 1 3 4 is a first rupture plate. In the hybrid inflator of the above embodiment, the gas generating agent is not in a pressurized medium, and can be constructed to be maintained in a normal pressure environment. As such a hybrid inflator, for example, a stomach-eating bellow is placed between a space where a pressurized medium exists (referred to as a "pressurized medium filling chamber") and a gas generating chamber, with the partition wall and the rupture plate completely The pressurized medium charge chamber and the diffuser are separated, and the pressurized medium charge chamber is maintained in a pressurized environment. Examples include those who maintain a gas generating room in a normal pressure environment. In the hybrid inflator, when the rupture plate is destroyed by the combustion of the gas generating agent in the gas generation chamber, the rupture plate of the pressurized medium filled with the pressurized medium in the chamber is discharged from the diffuser to expand the airbag. -1 4- Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ~ ^^ Φ3 ------ —Order --------- $ φ (Please read the back first Please pay attention to this page before filling in this page) 483841 A7 ____B7__ V. Description of the invention (U) The airbag device of the present invention is provided with: an impact signal output device made by an impact sensor and a control unit; Modular inflator and airbag module. For example, the hybrid inflator 100 shown in Fig. 1 is connected to an actuating signal output device (impact sensor and control unit) on the 130 side of the igniter, and is screwed in a module box installed with an airbag. Screw pile 150 to connect and fix. The hybrid inflator according to the present invention can be changed in a routine manner by a person skilled in the art with regard to the constituent factors other than the above. Therefore, the method of rupturing the main rupture plate 1 48 is not a method using gas pressure. Known mechanical rupture devices, such as those using sharp-shaped emitters, or electrical rupture devices, for example, are changed to use rupture plates. Ignition mode can be changed. [Examples] Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited thereto. That is, the gas generating agent used in the following is a single-hole cylindrical tube having an outer diameter of 5.4 mm, an inner diameter of 0.7 mm, and a length of 5 mm. (Example 1) A hybrid inflator 100 of the form shown in Fig. 1 was manufactured. The details are as follows. The inflator housing 102 is made of high tensile steel (tensile strength 90kg / mm2). A mixed medium of argon and helium is used as the pressurized medium [Ar: He = 96: 4 (mole ratio)] 2.6 mol (100 g) (internal pressure 3 2,000 kPa), and the gas generating agent is nitroguanidine: osmium nitrate: carboxyl Methylcellulose: acid clay (3 4: 5 0: 9: 7)-1 5-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the note on the back first Please fill in this page for matters) • ^ 11 ------- Order --------- φ · Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by 483841 A7 _B7 5. Description of the invention (W) 40g (equivalent to the amount of gas produced ι · 〇mol) (A / B = 7 8). The weight ratio (a / b) of the pressurized medium to the gas generating agent is 2.5. Therefore, a total of 3.6 moles of gas' can be used during operation, and the total weight of the pressurized medium and the gas generating agent before operation is 140 g. Alas, the pressure index (η) of this gas generating agent is 0 · 6. The hybrid inflator 100 formed by the above structure is 59mm in diameter and 156mm in length (excluding the length of the screw pile 150. The length of the screw pile 15 is 20mm), and the wall thickness of the inflator housing 102 is 2.5mm. The total weight is iiOOg. When the hybrid inflator of this type was operated in advance, the internal pressure became 4 4 1 00 k P a. (Comparative Example 1) A hybrid inflator 00 in the form shown in Fig. 1 was manufactured. The details are as follows. Benefits Weiwei 102 is made of ordinary steel (tensile strength 40kg / mm2). A mixed gas of argon and helium is used for the pressurized medium [〇2: Ar: He = 20: 76: 4 (mole ratio)] 3. 6 mol (140g) (internal pressure of 32,000 kPa). 8 g of RDX and polyacrylate elastomer (equivalent to the amount of gas generated 0.39 mol) (A / B = 9. 2/1). The weight ratio (a / b) of the pressurized medium to the gas generating agent was 17.5. The gas generated from the pressurized medium and the gas generating agent becomes 3.8 mol in total due to the reaction during the operation. The gas generating agent is to make all 3.78 mols of gas used for inflating the airbag enough to generate heat. Therefore, the total weight of the pressurized medium and the gas generating agent becomes 147 g. The pressure index (η) of 尙 'gas generating agent is 1.0. In order to ensure the practical pressure resistance, the hybrid inflator 100 formed by the above structure has a wall thickness of the inflator shell of 3 · 3 mm, so the diameter becomes -1 6-This paper size applies Chinese national standards ( CNS) A4 specification (210 X 297 mm) --- (Please read the notes on the back before filling out this page) tT --------- ^ 9—φ. Consumer Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printing 483841 A7 _____B7__ 5. Description of the invention (, 5Γ) 60 · 6min. In addition, the pressurized medium has a large filling capacity, and has the same pressure as in Example 1, and has a length of 178.7 mm (the length of the screw pile 150 is removed. The length of the screw pile 150 is 20 mm). The total weight of the hybrid inflator It is 1680g. When such a hybrid inflator 100 was operated, the internal pressure became 5 8 800 kPa. (Example 2) The same hybrid inflator 100 as in Example 1 was manufactured. However, the volume of the gas generator containing the gas generating agent is 0.16L, and the volume of the gas generator is adjusted to accommodate the gas generating dose used. The other constituent factors are described below. Pressurized medium: a mixed gas of argon and chlorine [Ar: He = 96M (molar ratio) 1.6 mol (62g) (internal pressure 3 2,000kPa) Gas generating agent: 80g same as Example 1 (generating gas amount 2 0 mole) A / B: 1 · 6/2 · 0 a / b: 62/80 = 0.775 Total gas volume when operating: 3 · 6 moles As a result of operating such a hybrid inflator, the internal pressure is 6 8, 0 0 0 k P a. (Example 3) In Example 2, a hybrid inflator was similarly manufactured using a gas generator as a pressure-resistant container and a gas generating chamber containing a gas generating agent at a pressure other than normal pressure. Alas, in order to keep the gas generating chamber at normal pressure, a rupture plate is provided between the gas generating chamber and the casing of the plenum. As a result of operating such a hybrid inflator, the same results as in Example 2 were obtained. (Example 4) A dual-type hybrid inflator 200 having a configuration shown in Fig. 2 was manufactured. The details are as follows: 1 7-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------------ Order ----- ---- (Please read the precautions on the back before filling out this page) 483841 Α7 Β7 V. Description of the invention (β). The inflator housing 102 is made of local tensile steel (tensile strength 90kg / mm2). The pressurized medium is a mixed gas of argon and helium [A r: H e = 9 6 ·· 4 (mole ratio)] 2. 6 mol (100g) (internal pressure 32,000kPa), a gas generating agent, and : Samarium nitrate: Carboxymethylcellulose: Acid clay (3 4 ·· 5 0 ·· 9: 7), using 20 g of the first gas generating chamber and 20 g of the second gas generating chamber (40 g is equivalent to generating Gas volume 1.0 mol) (A / B = 7.2 / 2.8). The weight ratio (a / b) of the pressurized medium to the gas generating agent is 2.5. Therefore, a total of 3.6 moles of gas' can be used during the operation, and the total weight of the pressurized medium and the gas generating agent before the operation is 140 g.尙 'The pressure index (n) of this gas generating agent is 0 · 6 〇 The hybrid inflator 200 formed by the above structure is 59111111 in diameter and 156mm in length (the length of the screw pile 150 is removed. The length of the screw pile 15 is 2 0 mm), the wall thickness of the inflator housing 102 is 2.5 mm, and the total weight is 200 g. When the hybrid inflator 200 was fired by the first igniter and the second igniter simultaneously, the internal pressure became 8,000 kPa. (Example 5) In Example 1, a pressurized medium was manufactured in the same manner except that a mixed gas of argon, oxygen, and helium [A r: 〇2: He = 9 3: 3: 4 (molar ratio)] was used. Hybrid aerator. The results of pre-operation of this hybrid inflator obtained the same results as in Example 1 except that a part of the generated C0 and Η2 was converted into C02 and Η2 0. 0-18- This paper size applies the Chinese National Standard (CNS) A4 Specifications (210 X 297 public love) (Please read the precautions on the back before filling out this page) -------- Order --------- φ Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

Claims (1)

、申請專利範圍 第8 9 1 2 0 3 9 1號「混合式充氣器」專利案 (91年3月5日修正) 、、申請專利範圍: 1 · 一種混合式充氣器,係用於具備氣囊的車輛之膨脹式 安全系統,其中具充氣式外殼;收容於充氣器外殼內 的氣體產生器;以及連接於氣體產生器的點火裝置, 其特徵爲,該充氣器外殼內充塡有含惰性氣體不含氧 氣的加壓媒質,氣體產生器爲具有含氣體產生裝置1 或2以上之氣體產生室者,該加壓媒質之量(A莫耳) 與由氣體產生裝置之燃燒產生的氣體量(B莫耳)之莫 耳比(A/B)爲8/2〜1/9。 2 .如申請專利範圍第1項之混合式充氣器,其中a / B爲 8/2〜3/7 ° 3 ·如申請專利範圍第1項之混合式充氣器,其中氣體產 生裝置爲含燃料及氧化劑的氣體產生劑。 4 .如申請專利範圍第2項之混合式充氣器,其中氣體產 生裝置爲含燃料及氧化劑的氣體產生劑。 5 ·如申請專利範圍第1項之混合式充氣器,其中氣體產 t ®胃含燃料、氧化劑及渣形成劑的氣體產生劑。 6 ·如申請專利範圍第2項之混合式充氣器,其中氣體產 Ig ®爲含燃料、氧化劑及渣形成劑的氣體產生劑。 7 .如申請專利範圍第3項之混合式充氣器,其中燃料爲 胍衍生物。 483841 申請專利範圍 8 .如申請專利範圍第4項之混合式充氣器,其中燃料爲 胍衍生物。 9 .如申請專利範圍第5項之混合式充氣器,其中燃料爲 胍衍生物。 1 〇 .如申請專利範圍第6項之混合式充氣器,其中燃料 爲胍衍生物。1. Patent application No. 8 9 1 2 0 3 9 1 "hybrid inflator" patent case (as amended on March 5, 91). Patent application scope: 1 · A hybrid inflator for airbags The inflatable safety system of the vehicle includes an inflatable casing; a gas generator housed in the inflator casing; and an ignition device connected to the gas generator, wherein the inflator casing is filled with an inert gas. Gas generator without oxygen, the gas generator is a gas generator with gas generator 1 or 2 or more, the amount of the pressure medium (A mole) and the amount of gas generated by the combustion of the gas generator ( B mole) The mole ratio (A / B) is 8/2 ~ 1/9. 2. The hybrid inflator according to item 1 of the patent application, where a / B is 8/2 ~ 3/7 ° 3 · The hybrid inflator according to item 1 of the patent application, wherein the gas generating device is fuel-containing And oxidant gas generator. 4. The hybrid inflator according to item 2 of the patent application scope, wherein the gas generating device is a gas generating agent containing a fuel and an oxidant. 5 · The hybrid inflator according to item 1 of the patent application, wherein the gas producing gas ® contains a fuel, an oxidant and a slag-forming gas generator. 6 · The hybrid inflator according to item 2 of the patent application, wherein the gas-producing Ig ® is a gas generator containing fuel, oxidant and slag-forming agent. 7. The hybrid inflator according to claim 3, wherein the fuel is a guanidine derivative. 483841 Patent application scope 8. The hybrid inflator of item 4 of the patent application scope, wherein the fuel is a guanidine derivative. 9. The hybrid inflator according to claim 5 in which the fuel is a guanidine derivative. 10. The hybrid inflator according to item 6 of the patent application, wherein the fuel is a guanidine derivative. 1 1 .如申請專利範圍第3項之混合式充氣器,其中燃料 爲除掉硝胺系化合物的非疊氮基有機化合物。 1 2 ·如申請專利範圍第4項之混合式充氣器,其中燃料 爲除掉硝胺系化合物的非疊氮基有機化合物。 i 3 .如申請專利範圍第5項之混合式充氣器,其中燃料 爲除掉硝胺系化合物的非疊氮基有機化合物。 1 4 ·如申請專利範圍第6項之混合式充氣器,其中燃料 爲除掉硝胺系化合物的非疊氮基有機化合物。 1 5 .如申請專利範圍第1至1 4項中任一項之混合式充氣 器,其中氣體產生裝置之壓力指數爲0.8以下者。1 1. The hybrid inflator according to item 3 of the patent application scope, wherein the fuel is a non-azide-based organic compound from which a nitramine compound is removed. 1 2 · The hybrid inflator according to item 4 of the patent application range, wherein the fuel is a non-azide-based organic compound from which a nitramine compound is removed. i 3. The hybrid inflator according to item 5 of the patent application, wherein the fuel is a non-azide organic compound from which a nitramine compound is removed. 1 4 · The hybrid inflator according to item 6 of the patent application scope, wherein the fuel is a non-azide-based organic compound from which a nitramine compound is removed. 15. The hybrid inflator according to any one of claims 1 to 14 in the scope of patent application, wherein the pressure index of the gas generating device is 0.8 or less. 1 6 · —種混合式充氣器,係用於具備氣囊的車輛之膨脹 式安全系統,其中具充氣器外殼;收容於充氣器外殻 內的氣體產生器,以及連接於氣體產生器的點火裝置 室,其特徵爲,該充氣器外殻內充塡有含惰性氣體的 加壓媒質,氣體產生器爲具有含氣體產生裝置的1或 2以上之氣體產生室者,該加壓媒質爲不含氧氣,氣 體產生裝置爲含燃料及氧化劑的氣體產生劑。 483841 六、申請專利範圍 1 7 ·如申請專利範圍第 1 6項之混合式充氣器 其 中 氣 體 產生裝置,爲含燃料 、氧化劑及渣形成劑 的 氣 體 產 生 劑。 1 8 · —種混合式充氣器 ,係用於具備氣囊的 車 輛 之 膨 脹 式安全系統,其中具 充氣器外殼;收容於 充 氣 器 外 殻 內的氣體產生器;以 及連接於氣體產生器 的 點 火 裝 置 室,其特徵爲,該充 氣器外殼內充塡有含 惰 性 氣 體 的 加壓媒質,氣體產生 器爲具有含氣體產生 裝 置1 的 1 或 2以上之氣體產生室 者,該加壓媒質不含 氧 氣 , 氣 體 產生裝置之壓力指數 爲〇 · 8以下者。 1 9 . 一種混合式充氣器 ,係用於具備氣囊的 車 輛 之 膨 脹 式安全系統,其中具 充氣器外殼;收容於 充 氣 器 外 殼 內的氣體產生器,以 及連接於氣體產生器 的 點 火 裝 置 ,其特徵爲,該充氣 器外殻內充塡有加壓 媒 質 , 氣 體 產生器爲具有含氣體 產生裝置的1或2以 上 之 氣 體 產 生室者,該加壓媒質 之量(A莫耳)與由氣 體 產 生 裝 置 之燃燒產生的氣體量 (B莫耳)之莫耳比(A/B)爲 8/2 1 /9 ° 20.如申請專利範圍第 1 9項之混合式充氣器 , 其 中 A/B 爲 8/2〜3/7 。 2 1 .如申請專利範圍第 19或20項之混合式 充 氣 器 其 中氣體產生裝置爲含 燃料及氧化劑的氣體) 奎i 左劑 〇 22.如申請專利範圍第 19或20項之混合式 充 氣 器 其 中氣體產生裝置爲含 ;燃料、氧化劑及渣形 -3- 成 劑 的 氣 體 483841 六、申請專利範圍 產生劑。 2 3 .如申請專利範圍第2 1項之混合式充氣器,其中燃料 爲胍衍生物。 24 .如申請專利範圍第22項之混合式充氣器,其中燃料 爲胍衍生物。 2 5 .如申請專利範圍第2 1項之混合式充氣器,其中燃料 爲除掉硝胺系化合物的非疊氮基有機化合物。 26.如申請專利範圍第22項之混合式充氣器,其中燃料 爲除掉硝胺系化合物的非疊氮基有機化合物。 27 ·如申請專利範圍第1 9項之混合式充氣器,其中氣體 產生裝置之壓力指數爲0.8以下者。 28 .如申請專利範圍第1 9項之混合式充氣器,其中充氣 器外殼由高拉力鋼所成。 2 9.如申請專利範圍第28項之混合式充氣器,其中高拉 力鋼爲抗拉強度60kg/mm2以上者。 30·如申請專利範圍第1,8, 10及11項中任一項之混合 式充氣器,其中氣體產生裝置爲保持於常壓環境中。 3 1 .如申請專利範圍第30項之混合式充氣器,其中氣體 產生裝置之形狀爲有孔圓筒狀。 3 2 · —種氣囊裝置,其特徵爲具備:由衝擊感測器及控 制單元所成的作動信號輸出裝置;以及在箱內收容如 申請專利範圍第1至31項中任一項之混合式充氣器 與氣囊的模組箱。1 6 · — A hybrid inflator is an inflated safety system for vehicles with airbags, which includes an inflator housing; a gas generator housed in the inflator housing, and an ignition device connected to the gas generator The chamber is characterized in that the inflator shell is filled with a pressurized medium containing an inert gas, and the gas generator is a gas generating chamber having 1 or 2 or more gas-containing devices, and the pressurized medium is free of The oxygen and gas generating device is a gas generating agent containing a fuel and an oxidant. 483841 VI. Scope of Patent Application 1 7 · If the hybrid inflator of the item No. 16 of the patent application scope, the gas generating device is a gas generator containing fuel, oxidant and slag forming agent. 1 8 · A hybrid inflator, which is an inflated safety system for vehicles with airbags, which has an inflator housing; a gas generator housed in the inflator housing; and an ignition device connected to the gas generator The chamber is characterized in that the inflator shell is filled with a pressurized medium containing an inert gas, and the gas generator is a gas generator with 1 or 2 or more gas generators containing a gas generating device 1, and the pressurized medium does not contain oxygen The pressure index of the gas generating device is below 0.8. 19. A hybrid inflator, which is an inflated safety system for a vehicle having an airbag, which has an inflator housing; a gas generator housed in the inflator housing, and an ignition device connected to the gas generator. It is characterized in that the shell of the inflator is filled with a pressurized medium, and the gas generator is a gas generating chamber having 1 or 2 or more gas generating devices, and the amount of the pressurized medium (A mole) and the gas The molar ratio (A / B) of the amount of gas (B mole) produced by the combustion of the generating device is 8/2 1/9 ° 20. For example, the hybrid inflator of item 19 in the scope of patent application, where A / B It is 8/2 ~ 3/7. 2 1. If the hybrid inflator of the scope of patent application 19 or 20 in which the gas generating device is a gas containing fuel and oxidant) Kui i left agent 02. Such as the hybrid inflator of scope 19 or 20 of the patent application The gas generating device is a gas containing fuel, oxidant and slag-forming agent 483841. 6. Generating agent in the scope of patent application. 2 3. The hybrid inflator according to item 21 of the patent application scope, wherein the fuel is a guanidine derivative. 24. The hybrid inflator according to claim 22, wherein the fuel is a guanidine derivative. 25. The hybrid inflator according to item 21 of the patent application scope, wherein the fuel is a non-azide organic compound from which a nitramine compound is removed. 26. The hybrid inflator according to claim 22, wherein the fuel is a non-azide-based organic compound from which a nitramine compound is removed. 27. If the hybrid inflator of item 19 of the patent application scope, wherein the pressure index of the gas generating device is 0.8 or less. 28. The hybrid inflator according to item 19 of the patent application scope, wherein the inflator shell is made of high tensile steel. 2 9. The hybrid inflator according to item 28 of the patent application scope, wherein the high tensile steel is a tensile strength of 60 kg / mm2 or more. 30. The hybrid inflator according to any one of claims 1, 8, 10 and 11, wherein the gas generating device is maintained in a normal pressure environment. 31. The hybrid inflator according to item 30 of the patent application, wherein the shape of the gas generating device is a cylinder with a hole. 3 2 · — An airbag device, comprising: an operation signal output device made of an impact sensor and a control unit; and a hybrid type, such as any one of claims 1 to 31, in a box Modular box for inflator and airbag.
TW89120391A 1999-10-01 2000-09-30 Hybrid inflater TW483841B (en)

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