477847 Α7 Β7 五、發明說明(1 ) 〔發明所屬之技術領域〕 本發明係有關於具備有使洗衣物賦予機械力之洗衣機 (請先閱讀背面之注咅?事項再填寫本頁) 〔習知技術〕 洗衣機爲了除去污垢除了含在洗劑的界面活性劑效果 外,還需有機械加的效果。包含在界面活性劑的污垢是以 此機械力自衣類剝離,自衣類洗掉污垢。此機械力是使得 設置在洗衣槽底面的旋轉翼做反轉來攪拌洗衣用水中的衣 類,藉此以衣類間互相摩擦時的摩擦力等形式而賦予衣類 。總之,附著在換洗衣物的污垢是用洗劑的化學加與洗衣 機的機械加之相乘效果洗掙的。然後,機械力大致上是以 調節器的驅動速度與時間之積爲比例。具有旋轉翼的調節 器之洗衣機大致上是以旋轉翼的旋轉速度與時間之積爲比 例。 經濟部智慧財產局員工消費合作社印製 通常,洗衣機的旋轉翼是用連接在商用電源的單相感 應電動機來驅動的。此時,旋轉翼的旋轉速度是以商用電 源頻率與電動機的極數以及電動機的旋轉軸與插入旋轉翼 間的減速機構來決定的。因而,通常的洗衣機,其旋轉速 度爲一定,以時間來調整機械力。因以旋轉速度來調整此 機械力,故例如將記載於日本特開平第3 - 1 9 8 8 9 9 號公報的PWM方式的轉換電路搭載於洗衣機,即可改變 電動機驅動的電源頻率。 記載在上述公報之洗衣機,不管換洗衣物量多寡,賦 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -- 477847 A7 ____ B7 五、發明說明(2 ) 予換洗衣物相同的機械力,利甩換洗衣物量來控制旋轉翼 的旋轉速度。 具有記載在上述公報的旋轉翼的可變速機構之洗衣機 ,並未顧及到因換洗物量的污垢量,來改變賦予換洗衣物 的機械力。亦即,並未顧及到對應污垢程度來調節旋轉速 度。換言之,洗滌極髒的換洗衣物時、和洗滌污垢少的換 洗衣物時,若換洗衣物量相同,加在換洗衣物的機械力也 還是相同的。因而,無法期待對污垢少的換洗衣物以減少 傷布料來洗滌,或者儘可能減少傷布料而充分洗淨極髒的 換洗衣物污垢的效果。 另一方面,含於洗衣用水中的硬度分份的鈣離子、鎂 離子、的二價陽離子會使洗劑的洗淨力受到巨大的影響。 該些離子與洗劑中的界面活性劑發生反應生成非水溶性的 金屬皂,減才有助於洗掙的界面活性劑的量,使洗淨力降 低。而所生成的金屬皂爲非水溶性,洗的不夠時會殘留在 衣服上,變成白色斑點而被看見。 記載在日本特開平第4 一 2 0 3 9 5號公報之洗衣機 ,在對洗衣槽的給水經路途中設置離子除去機構。而於此 公報開揭採用離子交換樹脂和活性碳的離子除去機構。更 準備有與離子除去機構並列的給水經路,選擇性的使用來 延長活性碳的壽命。 但記載在日本特開平第4 一 2 0 3 9 5號公報的離子 除去手段,並未顧及到洗衣用水給水所需的流量、離子交 換樹脂量、粒徑,或是離子除去效率。亦即,爲確保流量 本紙張尺度適用中國國家標準(CNS)A4規格(210 x297公釐) _ & - (請先閱讀背面之注意事項再填寫本頁) -裝--------訂--------- 經濟部智慧財產局員工消費合作社印製 477847 A7 B7 五、發明說明(3 ) (請先閱讀背面之注意事項再填寫本頁) 必需多量的離子交換樹脂,難以將離子除去機構收納在洗 衣機內部,或做成精巧的構成。另一方面,減才離子交換 樹脂量達到離子交換機構的小型化:就很難得到通常所需 的流量。而此公報並未顧及到賦予洗衣槽內衣服的機械力 〔用以解決課題之手段〕 本發明之第1目的在於提供一即使沒有麻煩的手洗等 的前處理,還是能儘量在短時間獲得高洗淨效果的同時, 減少傷及換洗衣物之洗衣機。 本發明之第2目的在於提供一除達成上述目的外,精 巧地配備有以每分鐘1 0 L以上的流量除去含在洗衣用水 的陽離的離子除去機構之洗衣機。 爲達成上述第1目的,本發明之洗衣機具備有在對洗 衣槽內的給水經路的途中,減低含在給水的水中的鈣離子 和鎂離子的硬度成份的離子交換機構的同時,具備有改變 調節器的驅動速度的可變速控制機構的對換洗衣物賦予機 械力的調節器之控制機構。 經濟部智慧財產局員工消費合作社印製 按上述手段,可對應污垢程度改變調節器的驅動速度 ,縮短賦予換洗衣物機械力的時間。而藉由使用減低鈣離 子和鎂離子的洗衣水,提高洗淨效果,減輕機械力,亦即 ,變慢調節器的驅動速度,維持洗淨效果,減少洗衣時間 〇 而爲了達成上述第2目的,在離子交換機構具備有會g 本紙張尺庋適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 ___ B7 五、發明說明(4 ) 確保給水流量程度的量之離子交換能的素材,可一面再生 此素材的離子交換能一面使用。 〔本發明之實施形態〕 第1圖係有關本發明的全自動洗衣機之外觀圖,第2 圖係沿著第1圖AA線之縱斷面圖。外裝是利用鋼板製的 外框1與安裝在其上部的上蓋1 7等構成的。儲水槽的外 槽4是從外框1上部的四個角,利用以垂棒2及線圈彈簧 和滑動環製成的防振裝置3,以懸吊狀態支撐在外框1內 ,儲備洗衣過程的洗衣水以及洗刷過程的洗刷水(以下稱 洗衣水)。在外槽4內旋轉自如地設有不銹鋼製的洗衣兼 脫水槽5 (以下稱洗衣槽)。在洗衣槽5側面設有多數的 脫水孔5 a,在中央底部可旋轉地設有賦予換洗衣物機械 力的調節器之旋轉翼6,在上緣部設有平衡器5 b。在外 槽4的底面安裝支撐板1 〇,在支撐板1 〇固定驅動裝置 〇 驅動裝置是由組合三相感應電動機7、齒輪減速機構 、離合器機構及制動機構的傳動裝置9構成的,三相感應 電動機7的旋轉是用皮帶輪8 a與皮帶8 b傳達至傳動機 構9。傳動裝置9的輸出軸,以水密狀態貫通外槽4的底 壁,而突出於外槽4內,與旋轉翼6及洗衣槽5連接。驅 動裝置在洗衣過程及洗刷過程時會使洗衣槽5靜止,使旋 轉翼6向順時針方向(正)及逆時針方向(逆)旋轉。而 於脫水過程時,使洗衣槽5向單方向旋轉。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁)477847 Α7 Β7 V. Description of the invention (1) [Technical field to which the invention belongs] The present invention relates to a washing machine equipped with a mechanical force for imparting mechanical power to laundry (please read the note on the back? Matters before filling out this page) [Knowledge Technology] In order to remove dirt, in addition to the surfactant effect contained in the lotion, a mechanical effect is also required. The dirt contained in the surfactant is peeled from the clothes by this mechanical force, and the dirt is washed away from the clothes. This mechanical force reverses the rotating wings provided on the bottom surface of the washing tub to stir the clothes in the washing water, thereby imparting the clothes in the form of frictional force when the clothes rub against each other. In short, the dirt attached to the laundry is washed by the chemical effect of the lotion and the mechanical effect of the washing machine. Then, the mechanical force is roughly proportional to the product of the drive speed of the regulator and the time. A washing machine with a rotary wing regulator is roughly based on the product of the rotary speed and time of the rotary wing as a ratio. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Usually, the rotating wings of washing machines are driven by a single-phase induction motor connected to a commercial power source. At this time, the rotation speed of the rotary wing is determined by the frequency of the commercial power supply and the number of poles of the motor, and the speed reduction mechanism inserted between the rotary shaft of the motor and the rotary wing. Therefore, a normal washing machine has a constant rotation speed and adjusts the mechanical force with time. Since this mechanical force is adjusted at a rotational speed, for example, a PWM-type conversion circuit described in Japanese Patent Application Laid-Open No. 3-1 89 8 9 9 can be installed in a washing machine to change the power supply frequency of the motor drive. Regardless of the amount of laundry changed, the washing machine described in the above bulletin applies the Chinese national standard (CNS) A4 specification (210 X 297 mm) to this paper size-477847 A7 ____ B7 V. Description of the invention (2) Same as the laundry replacement The mechanical force can control the rotation speed of the rotary wing by changing the amount of laundry. A washing machine having a variable-speed mechanism with a rotary wing described in the above publication does not take into account the amount of dirt due to the amount of laundry to change the mechanical force imparted to the laundry. That is, the rotation speed is not adjusted in consideration of the degree of dirt. In other words, if the amount of laundry is the same when the laundry is extremely dirty and when the laundry is less soiled, the mechanical force applied to the laundry is the same. Therefore, it is impossible to expect the effect of changing the laundry with less dirt to reduce the damage to the cloth, or to fully clean the extremely dirty dirt of the laundry with the least possible damage to the cloth. On the other hand, the hardness fraction of calcium ions, magnesium ions, and divalent cations contained in the washing water will greatly affect the detergency of the lotion. These ions react with the surfactant in the lotion to form a water-insoluble metal soap, which reduces the amount of surfactant that contributes to washing and reduces the detergency. The resulting metal soap is water-insoluble and will remain on the clothes when not washed enough to become white spots and be seen. The washing machine described in Japanese Unexamined Patent Publication No. 4-2035 is provided with an ion removing mechanism in the way of feeding water to the washing tub. In this publication, an ion removal mechanism using an ion exchange resin and activated carbon is disclosed. Furthermore, a water supply path is provided in parallel with the ion removal mechanism, and selective use is used to extend the life of the activated carbon. However, the ion removal method described in Japanese Patent Application Laid-Open No. 4-2035 has not taken into consideration the flow rate, the amount of ion exchange resin, the particle size, or the ion removal efficiency required for the feed water for laundry water. That is, in order to ensure the flow rate, the paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) _ &-(Please read the precautions on the back before filling this page) -Packing ------- -Order --------- Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs' Consumer Cooperatives 477847 A7 B7 V. Description of Invention (3) (Please read the precautions on the back before filling this page) A large amount of ion exchange resin is required It is difficult to store the ion removing mechanism inside the washing machine or to make it compact. On the other hand, the amount of ion-exchange resin is reduced to reduce the size of the ion-exchange mechanism: it is difficult to obtain the required flow rate. However, this publication does not take into account the mechanical force imparted to the clothes in the washing tub. [Means to solve the problem] The first object of the present invention is to provide a pretreatment such as hand washing without trouble, which can obtain a high level of time as soon as possible. Washing effect while reducing washing and changing clothes. A second object of the present invention is to provide a washing machine that is delicately equipped with an ion removing mechanism that removes the positive ion contained in the washing water at a flow rate of 10 L or more in addition to the above object. In order to achieve the above-mentioned first object, the washing machine of the present invention is provided with an ion exchange mechanism that reduces hardness components of calcium ions and magnesium ions contained in the water in the way of the water supply path in the washing tub, and also has a change The variable speed control mechanism of the drive speed of the regulator is a control mechanism of the regulator that applies mechanical force to the laundry. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs According to the above-mentioned methods, the driving speed of the regulator can be changed according to the degree of dirt, and the time for mechanical force to change clothes can be shortened. By using washing water that reduces calcium and magnesium ions, the washing effect is improved, and the mechanical force is reduced, that is, the driving speed of the regulator is slowed, the washing effect is maintained, and the washing time is reduced. The ion exchange mechanism is equipped with a paper gage that is compatible with Chinese National Standard (CNS) A4 (210 X 297 mm) 477847 A7 ___ B7 V. Description of the invention (4) The amount of ion exchange energy that ensures the degree of water supply flow Material can be used while regenerating the ion exchange energy of this material. [Embodiment of the present invention] Fig. 1 is an external view of a full automatic washing machine according to the present invention, and Fig. 2 is a longitudinal sectional view taken along line AA of Fig. 1. The exterior is constituted by an outer frame 1 made of a steel plate, and an upper cover 17 mounted on the upper part thereof. The outer tank 4 of the water storage tank is supported from the four corners of the upper part of the outer frame 1 by using the anti-vibration device 3 made of the vertical rod 2 and the coil spring and the sliding ring. Washing water and washing water during washing (hereinafter referred to as washing water). A washing and dewatering tank 5 (hereinafter referred to as a washing tank) made of stainless steel is rotatably provided in the outer tank 4. A large number of dewatering holes 5a are provided on the side of the washing tub 5, a rotary wing 6 of an adjuster for imparting mechanical force to the laundry is rotatably provided at the center bottom, and a balancer 5b is provided on the upper edge portion. A support plate 1 〇 is installed on the bottom surface of the outer groove 4, and a driving device is fixed to the support plate 10. The driving device is composed of a transmission device 9 combining a three-phase induction motor 7, a gear reduction mechanism, a clutch mechanism and a braking mechanism. The rotation of the motor 7 is transmitted to the transmission mechanism 9 by a pulley 8 a and a belt 8 b. The output shaft of the transmission device 9 penetrates the bottom wall of the outer tank 4 in a watertight state, protrudes into the outer tank 4, and is connected to the rotary wing 6 and the washing tank 5. During the washing process and the washing process, the driving device will cause the washing tub 5 to stand still, and cause the rotary blade 6 to rotate clockwise (positive) and counterclockwise (reverse). During the dehydration process, the washing tub 5 is rotated in one direction. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)
--I--I — I 訂------— II %· 經濟部智慧財產局員工消費合作社印製 477847 A7 B7 五、發明說明(5 ) 在外槽4側面下方設有將外槽內的水壓傳達至水位感 應器1 1之水位感應管1 2。而在外槽4底面設有洗衣機 排水之排水閥1 3,用連接在排水閥的排水管1 6,將洗 衣水排出洗衣機外。 在外框1的上部設有上蓋1 7。上蓋1 7是以投入換 洗衣物的投入口 1 7 a、和收納離子除去機構、水道栓口 2 6、給水電磁閥等之後部收納箱1 7 b、和收納微電腦 等電子零件之前部操作箱1 7 c等所構成的。在投入口 1 7 a設有蓋子1 8。 在前部操作箱17 c的上面安裝有第3圖所示的操作 面板1 9 a,在其下設有內裝微電腦等之控制部1 9b。 而在前部操作箱1 7 c,內設有利用檢測外槽4內水壓, 判定水儲備到規定水位之水位感應器1 1。在操作面板 1 9 a配置有電源開關20、各種顯示器2 1、各種操作 按鈕2 2、蜂鳴器2 3等,使用者是用操作按鈕2 2來操 作洗衣機,而將其動作狀態用顯示器2 2、蜂鳴器2 3做 確認。還設有以顯示離子除去處理(軟水化)發光二極體 製成的軟水顯示2 4、和以催告顯示離子除去手段再生的 發光二極體製成的鹽投入顯示2 5、指示通常洗衣過程之 標準洗衣按鈕8 0、指示極髒的換洗衣物的洗衣過程之高 洗淨洗衣按鈕8 1。 第4圖係拆下有關本實施例主要構成的洗衣用水給水 的後部收納箱1 7 b的上蓋時的背面部分之俯視圖(第1 圖中以B B線所示之斷面)(省略前面)。在後部收納箱 本紙張尺度適用中國國家標準(CNS)A4規格(210x297公釐) -B - (請先閱讀背面之注意事項再填寫本頁)--I--I — I order ------— II% · Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 477847 A7 B7 V. Description of the invention (5) There is an inner slot inside the outer slot 4 The water pressure is transmitted to the water level sensing tube 12 of the water level sensor 1 1. A drain valve 13 for draining the washing machine is provided on the bottom surface of the outer tank 4. The drain pipe 16 connected to the drain valve is used to drain the washing water out of the washing machine. An upper cover 17 is provided on the upper part of the outer frame 1. The upper cover 1 7 is an input port 17 a for changing clothes, a rear storage box 1 7 b for storing ion removal mechanism, a water channel plug 2, a water supply solenoid valve, and a front operation box 1 for storing electronic components such as a microcomputer. 7 c and so on. A cover 18 is provided at the input port 17a. An operation panel 19a shown in FIG. 3 is mounted on the front operation box 17c, and a control unit 19b including a microcomputer and the like is installed under the operation panel 19a. The front operation box 17 c is provided with a water level sensor 11 which detects the water pressure in the outer tank 4 and determines that the water reserve reaches a predetermined water level. The operation panel 1 9 a is provided with a power switch 20, various displays 2 1, various operation buttons 2 2, a buzzer 2 3, etc. The user operates the washing machine with the operation buttons 22 and the operation status is displayed on the display 2 2. The buzzer 2 3 confirms. It also has a soft water display 2 made of light-emitting diodes with display ion removal treatment (soft hydration), and a salt input display 2 made of light-emitting diodes regenerated by means of reminding display ion removal. 5, indicating the normal laundry process The standard washing button 80, the high washing button 8 1 indicating the washing process of extremely dirty laundry. Fig. 4 is a plan view of the rear portion when the upper cover of the rear storage box 17b, which is the main structure of the water supply for washing water, according to this embodiment is removed (the cross section shown by the line BB in Fig. 1) (the front is omitted). In the rear storage box This paper size applies to Chinese National Standard (CNS) A4 (210x297 mm) -B-(Please read the precautions on the back before filling this page)
· I ^1 .1 I ϋ —i —Bi 一 -0, · ·1· I n ·ϋ 1 n 1 I 經濟部智慧財產局員工消費合作社印製 477847 Α7 _ Β7 五、發明說明(6 ) 1 7 b收納有自水道栓等連接水管之水道栓口 2 6、連接 於此,以給水電磁閥2 7及鹽水注水電磁閥6 3、圓筒容 器6 0所構成之離子除去機段2 8、.吸收洗澡水之洗澡水 吸水幫浦4 5、使洗衣水流下至洗衣槽5內之傾斜流路 4 6等。在傾斜流路4 6的上流側設有開口在流路4 6的 室A47、室A48。給水電磁閥27的出口是連接在離 子交換機構2 8的入水口 2 9 a,鹽注水電磁閥6 3的出 口是連接在離子交換機構2 8的鹽注水口 6 0 h。離子交 換機構2 8的吐出口 2 9 b是連接在室A4 7。 於第5圖詳細表示本實施例主要構成的離子除去機構 28。 (a)係離子除去機構28的整體立體圖,(b) 係其縱斷面圖。離子除去機構2 8是以圓筒容器6 0與蓋 子6 1所構成的。圓筒容器6 0分成五室。自上設有以鹽 投入室6 0 a與防止鹽粒流出濾網6 0 g隔開的鹽水室 60k、吐出口 29b之上部室60b、入水口 29 a與 吐出口 1 9 b之間的上下面以濾網2 9 d區隔之樹脂室 29e、入水口 29a之下部室60c。在入水〇29e 與吐出口 2 9 b之間(上部室6 0 b與下部室6 0 c之間 )的樹脂室2 9 e塡充鈉型強酸性陽離子交換樹脂3 1 ( 以下稱離子交換樹脂)。上述離子交換樹脂31除一般廣 泛使用的串珠狀外,亦可爲纖維狀。從濾網2 9 e是防止 異物進入樹脂室2 9 e內,和防止離子交換樹脂從樹脂室 2 9 e流出。而在離子交換樹脂3 1上部及下部設上部室 6 〇 b與下部室6 0 c是防止水只流過離子交換樹脂3 1 本紙張尺度.適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 裝---—— — —— 訂·---I I ! ·%· 經濟部智慧財產局員工消費合作社印製 477847 A7 B7 五、發明說明(7 ) 層的一部分,能將水均勻地流到離子交換樹脂層全體,效 率佳的吸附金屬離子。水是從入水口 2 9 a流入下部室 60c,流滿下部室60c之後,均勻地上昇到離子交換 樹脂31層內,流出至上部室60b ’流滿上部室60b ,從吐出口 2 9 b流出。上部室6 0 b是必需讓再生用食 鹽均勻地流至離子交換樹脂3 1層全體,暫時儲備鹽水。 在鹽投入室6 0 a內,先經使用者投入鹽6 2。投入 的鹽量約爲1 5 0 g。鹽量相當於後述的離子交換樹脂 3 1的再生處理一次所需的鹽量2 0 g的7次量,使用者 必需一週投入一次鹽6 2。在鹽投入室6 0 a與鹽水室 6 0 k之間配設有略與鹽投入室6 0 k內徑相等直徑的防 止鹽粒流出濾網6 0 g,防止鹽粒流出至鹽水室6 0 k。 藉此加大鹽粒流出濾網6 0 g的面積,鹽水會流經濾網全 面,流下至鹽水室60k,故可確保鹽水的流量。從鹽注 水口 6 0 h開始的鹽注水管6 0 i開口是在鹽投入室 60a。鹽水室60k與上部室60b是以隔壁60d分 開,在隔壁60d設有鹽水通過的孔60e。在此孔 60e的上、下室60b設有逆止閥60f ,逆止閥 6 0 ί是在對洗衣槽5給水時睹塞孔6 0 e,防止水從上 部室60b流入鹽水室60k。在下部室60c的底面設 有貫通後部收納箱1 7 b底面的鹽水排出口 2 9 c,連接 在鹽水排出口 2 9 c的鹽水排出管6 4如第2圖所示連接 在外槽4,將鹽水排出外槽內。在蓋子6 1的內圓周設有 凹溝6 1 a,在上面開設空氣孔6 lb。在圓筒容器60 本紙張尺度適用中國國家標準(CNS)A4規格(210x297公釐) (請先閱讀背面之注意事項再填寫本頁) · —Bv n 1 MmmM9 n §a§ n 一:口,· —.1 ϋ ι ϋ n ·ϋ · 經濟部智慧財產局員工消費合作社印製 477847 A7 一 B7 五、發明說明(8 ) (請先閱讀背面之注意事項再填寫本頁) 的上部外圓周有凸部6 1 j ,蓋子6 1是以嵌合凹溝 6 la的形式固定在圓筒容器60的凸部60 j 。蓋子 6 1做成自後部收納箱1 7 b的上面突出,易於開_蓋子 6 1。而蓋子6 1是丙烯樹脂的透明構件做的,易於確認 消耗在每一後述洗衣的離子交換樹脂的再生處理。 從水道栓開始的管是連接在水道栓口 2 6。水道水是 利用開關給水電磁閥2 7被導入圓筒容器6 0的入水口 2 9 a,流滿下部室6 0 c之後,邊上昇邊通過塡充離子 交換樹脂3 1的室2 9 e。水道水在此於軟化水,總之就 是除去鈣、鎂離子,流滿上部室60b,從吐出口 29b 流出。然後從室A 4 7流下至傾斜流路4 6,給水至外槽 4 (洗衣槽5)。來自洗澡的水是用連接在洗澡水給水口 4 5 a的管抽出的。洗澡水是先將來自水道栓口 2 6的水 道水,打開給水電磁閥2 7,通過離子除去機構2 8、室 A 4 7,將其中一部分從引水口 4 5 b,引水至洗澡吸水 幫浦4 5。然後使幫浦馬達旋轉’將洗澡水從洗澡水給水 口 4 5 a自行吸入,從吐出口 4 5 c介於室4 8導至傾斜 流路4 6,從這裡開始給水至洗衣槽5。 經濟部智慧財產局員工消費合作社印製 將以圓筒容器6 0構成的離子除去機構2 8,設置在 設有水道栓口 2 6的後部收納箱1 7 b,是能縮短給水配 管長度’削減流路損失,縮短流量亦即給水時間。給水會 因水道水通過塡充離子交換樹脂3 1的室2 9 e ,增力Π此 樹脂塡充的壓力損失。即使減少此損失還是希望自作爲蓋 子的水道栓口至圓筒容器6 0的配管長爲χ 〇 〇mm以下 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 B7 五、發明說明(9 ) 。習知洗衣機的給水流量也靠近水道水壓力,但是從1 〇 至1 5公升/分,上述考量必需以本實施例得到接近這的 流量。 . 第6圖(a )係以微電腦5 0爲中心構成的洗衣機控 制部之方塊圖。微電腦5 0是接收也與操作按鈕輸入電路 5 1和水位感應器1 1連接的使用者控鈕操作、洗衣槽內 的洗衣水水位的資訊信號。從微電腦5 0的輸出是連接在 驅動電路5 2,將商用電源供給至洗澡水幫浦4 5、給水 電磁閥27、排水閥13等,控制該些的開關或旋轉。而 使用告知洗衣機的動作,亦連接至蜂鳴器.2 3和顯示器 2 1等報知機構。電源電路5 3是將商用電流做整流平滑 ,作成微電腦5 0所要的直流電源。5 4是以亮燈顯示軟 水處理的發光二極體。發光二極體5 4是安裝在前部操作 箱1 7 c,通用至離子交換樹脂時亮燈,軟水化處理中是 以軟水化顯示2 4來告知使用者。而5 5是亮燈顯示鹽投 入之發光二極體。發光二極體5 5是安裝在前部操作箱 1 7 c,必需對離子除去機構投入鹽時亮燈,以鹽投入顯 示2 5來告知使用者投入鹽。 換流電路7 1是將商用電源做整流平滑,作成直流電 源,轉換電路7 2是從此直流電源做成三相交流電源,將 三相交流電源供給至三相感應電動機7。轉換電路7 2係 由I GBT模組7 3與PWM信號電路7 4製成的,在 I G B T的閘極端子外加P W Μ信號加以截波直流電源, 將三相交流電流供給至三相感應電動機7的各U V W捲線 本紙張尺度遴用中國國家標準(CNS)A4規格(210 X 297公釐) -Τ2Γ (請先閱讀背面之注意事項再填寫本頁) _裝 丨-—訂---------.^9— 經濟部智慧財產局員工消費合作社印製 477847 A7 _ B7 五、發明說明(10 ) 。而PWM信號電路7 4是連接在微電腦5 0,以來自微 電腦的指示,作成決定供給至三相感應電動機的三相交流 頻率以及壓壓或各UVW相的位相關係之PWM信號。於 第6圖(b)詳細表示轉換電路72周邊。UVW相在此 順序爲1 2 0度的位相關係,三相感應電動機7就會向順 時針方向旋轉,例如以先述U V相爲相反的位相關係會向 逆時針方向逆轉。 接著說明有關本實施例的離子除去機構2 8的動作。 本實施例是使用者將換洗衣物放入洗衣槽5,按下電 源開關1 9,操作標準洗衣按鈕8 0或高洗淨洗衣按鈕 8 1時,微電腦5 0是利用布量感應器測定換洗衣物的量 ,將對應測定結果的水量、洗劑量顯示在顯示部2 1,告 知使用者。使用者是將參考適量顯示的洗劑,投入洗衣槽 5。其後,微電腦5 0打開給水電磁閥2 7。水道水從水 道栓口 2 6通過給水電磁閥2 7,從入水口 2 9 a流入圓 筒容器6 0的下部室6 0 c。流入的水道水流滿下部室 60後,用其壓力上昇室29 e,在室29 e隔著濾網 2 9 d,通過塡充的鈉型強酸性離子交換樹脂3 1之間, 流出上部室60b。流滿上部室60b,從吐出口 29b 流出,通過室A47、傾斜路46,儲存在外槽4 (洗衣 槽5 )內。而一部分流入下部室6 0 C的水道水,並不會 通過離子交換樹脂3 1,會通過連接在鹽水排出口 2 9 c 的鹽水排水管6 4,流入外槽4內。鹽水排出口 2 9 c的 內徑爲2 m m時,給水流量1 5 /分之時通過鹽水排出管 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) _ (請先閱讀背面之注意事項再填寫本頁)· I ^ 1 .1 I ϋ —i —Bi a-0, · · 1 · I n · ϋ 1 n 1 I Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economy 477847 Α7 _ Β7 V. Description of the invention (6) 1 7 b contains the water pipe plug 2 connected to the water pipe such as the water pipe plug 2 6. It is connected here to the water supply solenoid valve 2 7 and the saline water injection solenoid valve 6 3 and the cylindrical container 6 0 constitutes an ion removal machine section 2 8 、 Bath water absorbing pump 4 that absorbs bath water 5. The washing water flows down to the inclined flow path 4 6 in the washing tank 5 and so on. The upstream side of the inclined flow path 46 is provided with a chamber A47 and a chamber A48 which are opened in the flow path 46. The outlet of the water feed solenoid valve 27 is connected to the water inlet 29a of the ion exchange mechanism 28, and the outlet of the salt water fill solenoid valve 63 is the salt water injection port 60h connected to the ion exchange mechanism 28. The discharge port 2 9 b of the ion exchange mechanism 28 is connected to the chamber A4 7. Fig. 5 shows in detail the ion removing mechanism 28 mainly constituted in this embodiment. (A) is an overall perspective view of the ion removing mechanism 28, and (b) is a longitudinal sectional view thereof. The ion removing mechanism 28 is composed of a cylindrical container 60 and a lid 61. The cylindrical container 60 is divided into five chambers. From above, a salt water chamber 60k separated by a salt input chamber 60a and a 60g grit preventing filter 60g, an upper chamber 60b at the outlet 29b, and an upper portion between the water inlet 29a and the outlet 9b are provided. The resin chamber 29e and the lower chamber 60c below the water inlet 29a are separated by a screen 2 9 d below. Resin chamber 2 9 between inlet 29a and discharge port 2 9 b (upper chamber 60 b and lower chamber 60 c) 2 9 e sodium-filled strong acidic cation exchange resin 3 1 (hereinafter referred to as ion exchange resin ). The ion exchange resin 31 may be in a fibrous form in addition to the bead form that is generally used widely. The screen 2 9e prevents foreign matter from entering the resin chamber 2 9e, and prevents the ion exchange resin from flowing out of the resin chamber 2 9e. The upper and lower parts of the ion exchange resin 3 1 are provided with an upper chamber 6 0b and a lower chamber 6 0 c to prevent water from flowing through the ion exchange resin 3 1 paper size. Applicable to China National Standard (CNS) A4 (210 X 297) (Mm) (Please read the precautions on the back before filling out this page) Packing ------- --- Ordering --- II! ·% · Printed by the Intellectual Property Bureau Staff Consumer Cooperative of the Ministry of Economic Affairs 477847 A7 B7 V. Description of the invention A part of the layer (7) can uniformly flow water to the entire ion exchange resin layer, and efficiently adsorb metal ions. Water flows into the lower chamber 60c from the water inlet 2 9a, and after it has filled the lower chamber 60c, it uniformly rises into the 31 layer of ion exchange resin, flows out to the upper chamber 60b, and flows into the upper chamber 60b, and flows out from the discharge port 2 9b. In the upper chamber 60b, it is necessary to allow the salt for regeneration to uniformly flow to the entire first floor of the ion exchange resin 31, and temporarily store the saline. In the salt input chamber 60 a, the user first inputs salt 62. The amount of salt input is about 150 g. The amount of salt is equivalent to 7 times of the amount of salt 20 g required for one regeneration treatment of the ion exchange resin 31 described later, and the user must input the salt 6 2 once a week. Between the salt input chamber 60a and the saltwater chamber 60k, a salt prevention filter 60g having a diameter slightly equal to the inner diameter of the salt input chamber 60k is provided to prevent salt particles from flowing out to the saltwater chamber 60. k. This will increase the area of 60 g of salt particles out of the screen, and the brine will flow through the entire screen and down to the salt water chamber 60k, so the flow of salt water can be ensured. The salt injection pipe 60 i starting from the salt injection port 60 h is opened in the salt injection chamber 60a. The salt water chamber 60k is separated from the upper chamber 60b by a partition wall 60d, and a salt hole 60e is provided in the partition wall 60d. The upper and lower chambers 60b of the hole 60e are provided with check valves 60f. The check valve 600 is used to prevent the water from flowing from the upper chamber 60b into the salt water chamber 60k when the water is fed to the washing tub 5. The bottom surface of the lower chamber 60c is provided with a salt water discharge port 2 9 c penetrating the bottom surface of the rear storage box 1 7 b, and a salt water discharge pipe 6 4 connected to the salt water discharge port 2 9 c is connected to the outer tank 4 as shown in FIG. 2. The brine is discharged into the outer tank. A groove 6 1 a is provided on the inner circumference of the cover 6 1, and an air hole 6 lb is provided on the groove. In the cylindrical container 60 paper size, the Chinese National Standard (CNS) A4 size (210x297 mm) is applicable (please read the precautions on the back before filling this page) · —Bv n 1 MmmM9 n §a§ n One: mouth, · —.1 ι ι ϋ n · ϋ · Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 477847 A7-B7 V. Description of the invention (8) (Please read the precautions on the back before filling this page) The upper outer circumference has The convex portion 6 1 j and the lid 61 are fixed to the convex portion 60 j of the cylindrical container 60 in the form of a fitting groove 61a. The lid 61 is made to protrude from the top of the rear storage box 17b, and it is easy to open the lid 61. On the other hand, the cover 61 is made of a transparent member made of acrylic resin, and it is easy to confirm the regeneration process of the ion exchange resin consumed in each of the laundry described later. The pipe starting from the water plug is connected to the water plug 2 6. The water channel water is introduced into the water inlet 2 9 a of the cylindrical container 60 by using the switch feed water solenoid valve 2 7, and after filling the lower chamber 60 0 c, it passes through the ion-filled ion exchange resin 3 1 chamber 2 9 e while rising. Channel water is here to demineralize water. In short, it removes calcium and magnesium ions, flows into the upper chamber 60b, and flows out from the outlet 29b. It then flows down from the chamber A 4 7 to the inclined flow path 46 and feeds water to the outer tank 4 (washing tank 5). The water from the bath is drawn out by a pipe connected to the bath water supply opening 4 5 a. The bath water is the water from the water pipe outlet 26, the water supply solenoid valve 2 7 is opened, and through the ion removal mechanism 2 8 and the room A 4 7, a part of the water is drawn from the water inlet 4 5 b to the bath suction pump 4 5. Then, the pump motor is rotated, and the bath water is sucked in from the bath water supply port 4 5 a by itself, and the discharge port 4 5 c is guided from the chamber 4 8 to the inclined flow path 4 6, and the water is supplied to the washing tank 5 from here. The Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs printed an ion removal mechanism 28 composed of a cylindrical container 60 and installed it in a rear storage box 1 7 b provided with a water channel spout 26 to reduce the length of the water supply pipe. Loss of flow path, shortening the flow, that is, the water supply time. The feedwater will lose pressure due to the charging of the resin due to the passage of water through the chamber 2 9 e of the ion-filled ion exchange resin 31. Even if this loss is reduced, it is desirable that the piping length from the waterway spigot as the cover to the cylindrical container 60 is less than χ 〇mm. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 477847 A7 B7 5. Description of the invention (9). The water supply flow rate of the conventional washing machine is also close to the water pressure of the water channel, but from 10 to 15 liters / minute, the above considerations must be used to obtain a flow rate close to this in this embodiment. Fig. 6 (a) is a block diagram of a washing machine control section composed of a microcomputer 50 as a center. The microcomputer 50 receives an information signal of a user control button operation also connected to the operation button input circuit 51 and the water level sensor 11, and the washing water level in the washing tub. The output from the microcomputer 50 is connected to the drive circuit 52, and supplies commercial power to the bath water pump 4, the water supply solenoid valve 27, the drain valve 13, and the like, and controls these switches or rotation. The use of the washing machine is also connected to the notification mechanism such as the buzzer. 2 3 and the display 2 1. The power supply circuit 53 is to rectify and smooth the commercial current to make a DC power source required by the microcomputer 50. 5 4 is a light-emitting diode that displays soft water treatment with a light on. The light emitting diode 5 4 is installed in the front operation box 17 c, and is generally used when the ion exchange resin is turned on. In the softening process, the user is informed by a softening display 2 4. 5 5 is a light-emitting diode that lights up to show the salt input. The light-emitting diode 5 5 is installed in the front operation box 1 7 c. It is necessary to light up when the salt is put into the ion removal mechanism, and the user is informed by the salt input display 2 5. The commutating circuit 71 is a rectified and smooth commercial power source to make a DC power source. The converting circuit 71 is a three-phase AC power source from the DC power source and supplies the three-phase AC power source to the three-phase induction motor 7. The conversion circuit 7 2 is made of I GBT module 7 3 and PWM signal circuit 7 4. A PW signal is added to the gate terminal of the IGBT to cut off the DC power supply. The three-phase AC current is supplied to the three-phase induction motor 7. The paper size of each UVW coil is selected from Chinese National Standard (CNS) A4 (210 X 297 mm) -T2Γ (Please read the precautions on the back before filling this page) _ 装 丨 -—Order ----- ----. ^ 9—Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 477847 A7 _ B7 V. Invention Description (10). The PWM signal circuit 74 is connected to the microcomputer 50 and generates a PWM signal that determines the three-phase AC frequency and voltage or phase relationship of the UVW phases to be supplied to the three-phase induction motor according to instructions from the microcomputer. The surroundings of the conversion circuit 72 are shown in detail in FIG. 6 (b). The phase relationship of the UVW phase in this order is 120 degrees, and the three-phase induction motor 7 will rotate clockwise. For example, the phase relationship of the UV phase as the opposite phase will reverse in the counterclockwise direction. Next, the operation of the ion removing mechanism 28 according to this embodiment will be described. In this embodiment, when the user puts the laundry change in the washing tub 5, presses the power switch 19, and operates the standard laundry button 80 or the high-washing laundry button 81, the microcomputer 50 uses a cloth sensor to measure the laundry change. The amount of water and washing amount corresponding to the measurement result are displayed on the display section 21 to inform the user. The user puts the lotion shown on the reference into the washing tub 5. Thereafter, the microcomputer 50 opens the water supply solenoid valve 27. Water channel water flows from the water channel bolt port 2 6 through the water supply solenoid valve 2 7 and from the water inlet port 2 9 a into the lower chamber 60 c of the cylindrical container 60. After the inflow water has flowed to the lower chamber 60, the pressure rises in the chamber 29e, and the screen 29e is separated by a screen 2 9 d through the filled sodium strong acidic ion exchange resin 31 and flows out of the upper chamber 60b. . The upper chamber 60b overflows, flows out from the discharge port 29b, passes through the chamber A47 and the inclined path 46, and is stored in the outer tank 4 (washing tank 5). A part of the water flowing into the lower chamber 60 C does not pass through the ion exchange resin 31 and flows into the outer tank 4 through the brine drain pipe 6 4 connected to the brine discharge port 2 9 c. When the inner diameter of the salt water discharge port 2 9 c is 2 mm, the feedwater flow rate is 15 / min through the salt water discharge tube. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) _ (Please read first (Notes on the back then fill out this page)
· ϋ i_i ϋ n n I n^OJi n n 1 n n ϋ I I 經濟部智慧財產局員工消費合作社印製 477847 A7 ___ B7 五、發明說明(11 ) 64的流量約爲〇 · 5L/分。此量是在給水量3%的程 度’影響少。鹽水排出口 2 9 c的內徑更小時,影響更少 ’但因毛細管現象就難以排出再生用鹽水,故上述2 mm 最適合。無成本和空間問題時,當然可以在鹽手排出管 6 4的途中設閥,構成在給水中關閉此閥的方式爲佳。 水道水通過離子交換樹脂3 1的期間,以離子交換作 用除去含在其中的鈣離子、鎂離子。在該洗衣給水中,發 光二極體5 4會亮燈,用軟水化顯示2 4或蜂鳴器2 3進 行離子除去中的顯示或通知。給水中,水道水流滿離子交 換機構2 8的上部室6 0 b,逆止閥6 0 f的浮球會因此 壓力上昇堵塞孔60e。因,此給水中,水道水不會侵入 鹽水室60k。除給水時以外,上部室60b成爲大氣壓 的緣故,逆止閥6 0 f的浮球因自重掉落,令孔6 0 e成 爲打開的狀態。 以下說明高洗淨洗衣按鈕8 2被下淸洗極髒的換洗衣 物的情形。以水位感應器1 1告知規定量的洗衣水供應至 外槽4內的微電腦5 0,會關上給水電磁閥2 7,停止給 水。然後使旋轉翼6正逆旋轉的緣故,對PWM信號電路 繼續所定的頻率、電壓、位相關係的三相電源,輸出供給 至三相感應電動機7的資訊。其結果,旋轉翼6會開始正 逆旋轉,開始洗衣。此時’若按下高洗掙洗衣按鈕8 2開 始洗衣,三相電源的頻率設定的比按下標準洗衣按鈕8 0 洗衣時的設定頻率高。 如周知,感應電動機旋轉數是以輸入頻率爲比例。總 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公爱) (請先閱讀背面之注意事項再填寫本頁) · I — 11--—訂-------- 經濟部智慧財產局員工消費合作社印製 477847 A7 ___ B7 五、發明說明(12 ) 之就是用感應電動機驅動的旋轉翼6的旋轉速度是以此頻 率爲比例。例如按下標準洗衣按鈕8 0時的頻率設定爲 50Hz ,旋轉翼旋轉速度爲li〇rpm的話,按下高 洗淨洗衣按鈕8 1時設定爲6 8 Η z,旋轉翼旋轉速度就 爲1 5 0 r pm。但一般一定保持電壓與頻率比具相同轉 矩旋轉數特性的緣故,希望頻率增加電壓也增加。 供應到洗衣槽5內的洗衣水未含鈣、鎂等陽離子的緣 故,會與投入的洗劑中界面活性劑反應,生成非水溶性的 金屬皂,不會減少有助於洗淨的界面活性劑量,降低洗淨 力。給水結束後,殘留在離子交換機構2 8內的水,會從 連接在鹽水排出口 2 9 e的鹽水排出管6 4慢慢排出外槽 4。 以上結果,在洗衣時會成爲增加界面活性劑在洗衣槽 內的洗衣用水中的化學力之狀態。而旋轉翼的旋轉速度會 從標準洗衣的1 1 〇 r p m設定到至1 5 0 r p m的狀態 。然後在溶解洗劑的洗衣用水中攪拌換洗衣物進行洗衣工 作。隨著此化學力增加與旋轉速度增加的機械力增加的相 乘效果,得到後述的高洗淨力。 鈉型強酸性陽離子交換樹脂3 1,如周知爲在架橋的 三次元高分子基體以化學結合使如磺酸基的離子交換基結 合的合成樹脂。含有鈣、鎂等二價陽離子的水道水流經陽 離子交換樹脂間時,陽離子交換樹脂的陽離子交換基的磺 酸基與水道水中的陽離子會被陽離子交換,結果會除去水 道水中的陽離子。於化1、化2表示鈉型強酸性離子交換 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 裝------- —訂-------- 經濟部智慧財產局員工消費合作社印製 477847 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明(13 ) 樹脂的離子交換反應式。 【化1】 R(S03Na)2 + CaCI, R(S03)2Ca + 州仰 【化2】 R(S03Na)2 + MgCI2 士 R(S03)2 M^+ 2Na〇 此例,R爲離子交換樹脂的高分子基體。納型離子交 換樹脂是以一 S 〇3的陰離子爲固定離子,以N a陽離子爲 對離子,利用離子的選擇性,除去含在水中的鈣、鎂等多 價陽離子。離子選擇性在低濃度,常溫下,強酸性陽離子 交換樹脂的情況,價數高的離子愈大,相同價數,原子編 號小的愈大。含在天然水中的離子爲化3的順序。 〔化3〕· Ϋ i_i ϋ n n I n ^ OJi n n 1 n n ϋ I I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 477847 A7 ___ B7 V. Description of the invention (11) 64 The flow rate is approximately 0.5 L / min. This amount has less influence at a level of 3% of the water supply amount. The smaller the inner diameter of the salt water discharge port 2 9 c is, the less the influence is. However, it is difficult to discharge the salt water for regeneration due to the capillary phenomenon, so the above 2 mm is most suitable. When there is no cost and space problem, of course, a valve may be provided in the middle of the salt-hand discharge pipe 64, and it is preferable that the valve is closed in the feedwater. While the water channel passes through the ion exchange resin 31, calcium ion and magnesium ion contained therein are removed by ion exchange. In this laundry supply water, the light emitting diode 5 4 is turned on, and the softening display 24 or the buzzer 23 is displayed or notified during ion removal. In the feedwater, the water in the water channel is filled with the upper chamber 6 0 b of the ion exchange mechanism 28, and the float of the check valve 60 f causes the pressure to rise to block the hole 60e. Therefore, the water in the feedwater will not enter the brine chamber 60k. Except when the water is supplied, the upper chamber 60b becomes atmospheric pressure, and the floating ball of the check valve 60f is dropped by its own weight, so that the hole 60e is opened. Next, a description will be given of a case where the high-cleaning washing button 8 2 is washed down and the extremely dirty laundry is changed. The water level sensor 11 informs the microcomputer 50 in the outer tank 4 that a predetermined amount of washing water is supplied, and the water supply solenoid valve 27 is closed to stop the water supply. Then, due to the forward and reverse rotation of the rotary wing 6, the three-phase power source of the predetermined frequency, voltage, and phase relationship is continued to the PWM signal circuit, and the information supplied to the three-phase induction motor 7 is output. As a result, the rotary wing 6 starts to rotate forward and backward, and laundry is started. At this time, if the high washing button 8 2 is pressed to start washing, the frequency of the three-phase power supply is set higher than the frequency set when the standard washing button 80 is pressed to wash. As is well known, the number of rotations of an induction motor is proportional to the input frequency. The total paper size applies to the Chinese National Standard (CNS) A4 specification (210 x 297 public love) (Please read the precautions on the back before filling out this page) · I — 11 --— Order -------- Economy Printed by the Ministry of Intellectual Property Bureau's Consumer Cooperatives 477847 A7 ___ B7 V. Description of the Invention (12) The rotation speed of the rotary wing 6 driven by an induction motor is proportional to this frequency. For example, when the standard laundry button 80 is pressed, the frequency is set to 50 Hz, and the rotation speed of the rotary wing is li0 rpm. When the high washing button 8 1 is pressed, it is set to 6 8 Η z, and the rotational speed of the rotary wing is 1 5 0 r pm. However, in general, it is necessary to keep the voltage and frequency ratio to have the same torque rotation number characteristics. It is desirable that the frequency increases and the voltage also increases. Because the washing water supplied into the washing tank 5 does not contain cations such as calcium and magnesium, it will react with the surfactant in the lotion to form a water-insoluble metal soap, which will not reduce the interfacial activity that is helpful for washing. Dose to reduce detergency. After the water supply is completed, the water remaining in the ion exchange mechanism 28 will be slowly discharged from the outer tank 4 through the brine discharge pipe 6 4 connected to the brine discharge port 2 9 e. As a result, the chemical force of the surfactant in the washing water in the washing tub is increased during washing. And the rotation speed of the rotary wing will be set from 110 rpm to 150 rpm. Then, the laundry is stirred and changed in the washing water in which the detergent is dissolved. The synergistic effect of the increase in the chemical force and the increase in the mechanical force due to the increase in the rotational speed results in a high cleaning force to be described later. The sodium-type strongly acidic cation exchange resin 31 is a synthetic resin known as a bridged three-dimensional polymer matrix to chemically bond an ion exchange group such as a sulfonic acid group. When aqueduct water containing divalent cations such as calcium and magnesium flows between cation exchange resins, the sulfonic acid group of the cation exchange group of the cation exchange resin and the cations in the water are exchanged with cations. As a result, cations in the water are removed. Yu Hua1 and Hua 2 indicate sodium-type strongly acidic ion exchange. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page). Loading ---- --- —Order -------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 477847 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (13) Ion exchange reaction of resin. [Chemical 1] R (S03Na) 2 + CaCI, R (S03) 2Ca + State [Chemical 2] R (S03Na) 2 + MgCI2 + R (S03) 2 M ^ + 2Na. In this example, R is an ion exchange resin Polymer matrix. Nano-type ion exchange resins use an anion of S03 as a fixed ion and a Na cation as a counter ion, and use the selectivity of the ions to remove polyvalent cations such as calcium and magnesium contained in water. The ion selectivity is at a low concentration and at room temperature. In the case of a strongly acidic cation exchange resin, the higher the valence, the larger the ion, and the larger the valence, the smaller the atom number. The ions contained in natural water are in the order of H3. 〔Chemical 3〕
Na+<K + <Mg2 + <Ca2 + 通過離子交換樹脂水中的鈣、鎂離子會從化1、化2 的左邊向右邊反應,吸附樹脂而被除去。反之,在吸附鈣 、鎂離子的樹脂流過高濃度鹽水時,會從化1、化2的右 邊向左邊反應脫落鈣、鎂離子,樹脂會回到再生原來的狀 態。 · 實驗室等使用的市售小型軟水化裝置,一般離子交換 樹脂量爲1至2 L,處理流量爲每小時10 L (每分鐘 0 · 16L)程度的能力。如前所述,家庭用洗衣機中, 爲了縮短給水時間,直接從水道栓,每分鐘1 0 L以上的 流量,供應到洗衣槽。因此如上述的市售小型軟水化裝置 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -10- I I I I I I *1 I I I H 1 n n H ϋ 1 · 1 I n ϋ 1 ϋ ϋ I - (請先閱讀背面之注意事項再填寫本頁) 477847 A7 B7 五、發明說明(14 ) (請先閱讀背面之注意事項再填寫本頁) 的處理流量由於給水時間過長,利用衣以外的時間整批處 理,一旦暫時儲備在貯水槽後就無法利用。而離子樹脂量 1至2 L,容積對搭載(內裝)在家庭用洗衣機就過大。 總之就是家庭用洗衣機必需解決上述離子交換樹脂的處理 流量、樹脂量的問題。 根據日本國內過去實施的水道統計,調查的件數中, 所有硬度4 0 p pm以下的件數爲全體的半數,超過 lOOppm的件數爲也有15%,相加平均爲54·5 p p m 〇 經濟部智慧財產局員工消費合作社印製 於第7圖將日本國內淨水硬度分佈(來自日本水道協 會發行的平成6年度水道統計)和使用小型放入沸石的市 售合成劑時的洗淨率的硬度關係,以參數表示洗劑濃度。 硬度分佈是考慮各淨水場一日的淨水量,例如全淨水量約 2 0%瞭解在4 0至5 0 P pm之間。各淨水場的淨水量 與家庭數作爲比例時,全家庭約2 0%是使用4 0至5 0 ppm的水道水。全國平均硬度爲52·9ppm,全體 9 8%爲1 0 0 P pm以下。洗淨率方面,洗廠商指定洗 劑量的洗劑度0 · 0 6 7wt% (重量度)是將平均硬度 52 · 9ppm減半,洗淨率也增加約50%。而硬度 lOOppm是將此減半,得到與洗劑量爲兩倍時同等的 洗淨率。總之就是降低硬度以標準洗劑量得到洗劑量(濃 度)爲標準兩倍時的洗淨率。此種除去硬度成份的鈣離子 、鎂離子,可大幅改善洗衣機的洗淨率。而與依然使用水 道水時同等洗淨率的話,就可利用軟化水削減洗劑使用量 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 B7 五、發明說明(15 ) 。進而,在硬度4 0 p p m以上的地區,不必使用需要以 下的洗劑量,對環境的影響也少。 (請先閱讀背面之注意事項再填寫本頁) 如第7圖所示,硬度爲4 0 P pm以下,洗淨率大體 上爲一定,在此以上的硬度,洗淨率降低。硬度在4 0 p pm以下,含在合成洗劑的沸石,大致上會全部吸附硬 度成份,界面活性劑充分作用的緣故,洗淨率大致上爲一 定,在此以上的硬度,沸石量不足,一部分的界面活性劑 與硬度成份反底,生成金屬皂,那部分界面活性劑量減少 的緣故,洗淨率降低。因而,洗衣使用放入沸石的合成洗 劑時,希望到此4 0 p pm程度爲止,從洗衣除去硬度成 份的鈣離子、鎂離子。另一方面,金屬皂與第7圖相異, 硬度增加的同時,洗淨率降低的緣故,最好儘量除去硬度 除份。 經濟部智慧財產局員工消費合作社印製 離子交換樹脂的離子交換性能,是以離子交換容量、 離子交換速度等來決定。在洗衣機離子交換樹脂時,如上 所述,求得處理流量每分鐘1 0至1 5 L,樹脂量儘量減 少到能搭載在洗衣機。因此,極力增大離子交換速度,確 保處理流量,增大離子交換容量,就可減少樹脂量。離子 交換容量、離子交換速度是經由離子交換樹脂的架橋度、 樹脂構造(凝膠型、多孔性)和樹脂徑等加以變化。但架 橋度高的一方,離子交換容量增加,但離子交換速度降低 ,爲多孔性時,離子交換速度上昇比凝膠型快,但離子交 換容量減少。此種以離子交換樹脂的架橋和構造,難以同 時提升兩方性能。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 ___ B7 五、發明說明(16 ) (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 第8圖係就爲了硬水軟化使用最一般的架橋度8%的 鈉型強酸性離子交換樹脂方面,將針對通水量的漏洩離子 濃度變化,以參數實驗離子交換樹脂量與樹脂徑的結果。 原水的全硬度爲1 0 Oppm,流量爲1 5L/分。實驗 的樹脂量、樹脂徑,無論什麼情況都會漏洩硬度成份,其 濃度因樹脂量、樹脂徑而異。通水初期階段的漏洩離子濃 度是同一樹脂徑,樹脂量愈多愈小,樹脂量相同時,樹脂 徑小的一方爲小。第9圖對離子交換樹脂的全表面積(計 算値)整理修正第8圖中的通水初期階段的漏洩離子濃度 的結果。由圖可知,漏洩離子濃度略以離子交換樹脂的全 表面積爲反比例,離子交換速度,以離子交換樹脂的全表 面積爲比例。離子交換樹脂的全表面積,以離子交換樹脂 量爲比例,以離子交換樹脂徑爲反比例,樹脂徑小,藉此 減少樹脂量。漏洩離子濃度的變化,在通水初期階段大致 上爲一定濃度,但會從通水量增加的點急速增加,終究會 失去離子交換能力,成爲與原水相同的濃度。離子交換容 量是以在漏洩離子濃度線與原水離子濃度線範圍的面積( 例如樹脂量100mL、樹脂徑〇 · 1至〇 · 2mm時, 在圖中AB CA範圍的面積)來表示,但樹脂徑沒有關, 只以樹脂量爲比例。 | 第8圖的離子交換樹脂的離子交換容量爲2 · 0 meQ/ml - R (相當於離子交換樹脂lmL2 · 0合 理的量),樹脂相當於lmL,以CaC〇3換算可除去 1 0 m g的硬度成份。目前考慮以流量1 5 L /分流下全 -- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 B7 五、發明說明(17 ) (請先閱讀背面之注意事項再填寫本頁) 硬度1 0 0 p pm的水道水’將定格容量9 k g的全自動 洗衣機高水位一次的水量8 8成爲軟化水。放入沸石合成 洗劑的洗淨力不會受到軟化水影響,.若可以到4 0 p p m ,可除去的硬度成份爲5 · 28g (CaC〇3換算),只 認爲離子交換量需要最少樹脂量5 2 · 8minL的少量即 可。實際上如第8圖’樹脂徑〇·1至〇·2mm時爲 lOOmL,樹脂徑 0 · 3 至 0 · 5mm 爲 i50mL, 樹脂徑0 · 3至1 · 1mm沒有2 6 0mL的樹脂量時, 就無法在40ppm以下。但樹脂徑爲0 · 1至〇 · 2 mm和〇 · 3至0 · 5mm,處理流量每分鐘1 5L,能 減少1 0 0至1 5 OmL樹脂量,就可搭載在家庭用洗衣 機。 經濟部智慧財產局員工消費合作社印製 第1 0圖係在使用樹脂徑〇· 1至〇 · 2mm、樹脂 量1 0 OmL的離子交換樹脂的離子除去機構,以流量 1 5 L分流出水道水(全硬度1 0 0 P pm)時的漏洩離 子濃度與通水量的關係。圖中籲記號爲初次通水時,亦即 離子交換樹脂爲新品的情況。通水量到5 0 L,漏洩離子 濃度約1 2 0 p pm時爲一定。由從開始增加漏洩離子濃 度,但通水量至1 0 0 L,漏洩離子濃度則維持在4 0 p pm以下。然後,通水量爲1 5 0 L就失去離子交換能 力,漏洩離子濃度與原水硬度同。因而,必需利用上述的 鹽水做再生處理。對此再生處理做後述。在定格容量9 k g的全自動洗衣機供水到高水位(水量8 8 L )時,洗 衣水硬度,如圖中_記號約爲1 8 p pm,不會因硬度引起 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 ___ B7 五、發明說明(18 ) 洗淨性能降低。 於第1 1圖以參數表示,以被規定在利用習知商用電 源遠流長5 Ο Η Z )驅動單相感應電動機的人工污染布洗 淨(J I S規定的洗衣機之洗淨性能評估法)爲基準,用 旋轉翼旋轉數、時間、離子除去機構的洗衣用水軟水化爲 參數實施的結果之洗淨力。比較基準(以a表示的旋轉翼 旋轉速度11 0 r pm、時間9分鐘、洗衣用水硬1 0 0 ??1!1、洗淨力1),其他條件與a同,旋轉翼旋轉速度 僅1 · 36倍(15〇rpm)時(以b表示),洗淨力 爲1 · 25。同樣時間只爲兩倍(18分)時,洗淨力爲 1 · 2 9。在離子除去機構用硬度下降6 0%的水作爲洗 衣機用水時(以d表示),洗淨力爲1 · 2 6。同樣洗劑 量亦即洗劑濃度爲1 · 2倍時(以e表示),洗淨率爲 1 · 0 9 ° 由此結果了解,達到離子除去機構洗淨的效果,具有 與機械力爲基準兩倍大致相同效果。而旋轉翼速度爲 1 · 3 6倍會增加機械力與時間爲兩倍會增加機械力得到 對洗淨同樣效果。 另一方面,袖子等污垢,在前述實驗的洗淨力無法到 達1 · 6時,主婦利用主婦監視器的主觀評估得到無法獲 得洗掉污垢印象的結果。總之就是主婦打消習知洗衣機無 法洗掉Y襯衫等衣襟、袖子污垢的念頭,對不滿意的污垢 部分浸泡高濃度洗劑以手洗等之後,解決用洗衣機洗的情 形,顯示實驗的洗淨力需爲1 · 6。 本紙張尺嚷適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) -裝--------·訂---------" 經濟部智慧財產局員工消費合作社印製 -21 - 477847 A7 _ B7 五、發明說明(19 ) 爲了得到此洗淨力,光靠機械力,由第1 1圖的結果 ’基準與旋轉速度需相同,時間必需爲3 0倍程度。而基 準與時間需相同,旋轉速度需約兩倍左右。 但增加機械力,連帶會使換洗衣物增加布傷,換洗衣 物精度惡化。進而也增加布絞在一起的緣故,洗衣結束後 ,從洗衣槽取出衣物,需要較多的勞力。甚至隨著旋轉速 度增加,也會因噪音增加及時間增加而增加耗電量。總之 就是光靠機械力不太能現實。 本實施例,除以利用離子除去機構的軟水化提高洗淨 力外,以旋轉翼實用的旋轉速度1 . 3倍化,如第1 1圖 以f所示,洗淨力大槪得以達成1 · 5 7的洗淨力。 對於洗衣用水軟水化的效果,是增加洗劑起泡爲佳。 特別是洗衣粉很顯著。更藉由提高旋轉速度,洗衣用水經 常攪拌,促進空氣的水中溶解,進而起泡爲佳。因此,換 洗衣物會包在泡沬中浮起來,即使少量洗衣用水也能增加 換洗衣物間接觸摩擦的機會。亦即用很少的洗衣用水就能 增加賦予換洗衣物的機械力。 在標準洗衣機使用對換洗衣物5kg,水56,洗劑 濃度0 · 067wt%的洗劑量37g的話,高洗淨洗衣 對相同換洗衣物5 k g,水4 L,用相同洗劑量3 7 g, 洗劑濃度可爲1 · 2倍的0 · 0 8 w t %。因此如第1 1 圖以g所示,得到洗淨力1 · 6 2 %的高洗淨力。 如以上說明,本實施例,對極髒的換洗衣物,設有高 高洗淨洗衣行程,針對定格容量的6至7成(約5 k g ) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) _1 mmmmm mmm— ϋ 1 ϋ ·1 一-ον · 1· I t I —ai 1 I » 經濟部智慧財產局員工消費合作社印製 477847 A7 __ B7 五、發明說明(20 ) 的換洗衣物,藉由利用離子除去機構的洗衣用水的軟水化 與增加旋轉翼旋轉速度來發揮高洗淨力。 (請先閱讀背面之注意事項再填寫本頁) 洗衣過程結束的話,微電腦5 0會打開排水閥1 3, 將外槽4內的洗衣水加以排水。排水結束後,移行至脫水 行程。在脫水工程,微電腦5 0是控制傳動裝置9的螺形 線圈9 a,以三相感應電動機7高速旋轉洗衣槽5。此期 間排水閥1 3被打開。 經濟部智慧財產局員工消費合作社印樂 脫水過程結束後,排水閥1 3關上,接著移行至洗刷 過程。洗刷過程,也根據該方法,通常由一次進行兩次。 一旦水儲備在外槽4後,就使旋轉翼6旋轉,稀釋殘留在 衣服的洗劑,所謂的洗刷,必需與先前洗衣給水略相同水 量。因而,通過離子除去手段2 8的水量,爲先前洗衣給 水的88L,在此洗刷的88L?兩次的合計264L。如 第10圖所示,以通水量150L,會失去離子交換能力 的緣故,從第一次洗刷給水途中,硬度是與原水相同。但 洗刷過程,硬度不受影響的緣故,供應硬度高的水沒關係 。洗刷過程時的給水,除最後洗刷過程以外,與洗衣過程 時完全相同,所以此例係就將水儲備在外槽4進行最後的 洗刷過程時,最後洗刷過程中進行的離子交換樹脂3 1的 再生處理做說明。先打開給水電磁閥27,與前述洗衣給 水同樣地將水道水通過離子除去機構2 8,將洗刷水供應 至外槽4內。水道水流滿離子除去機構的上部室6 0 b, 逆止閥6 0 f爲堵塞孔6 0 e狀態(此爲打開給水電磁閥 2 7後判斷經過所定時間)的話,微電腦5 0就會打開鹽 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 _ B7 五、發明說明(21 ) (請先閱讀背面之注意事項再填寫本頁) 注水電磁閥6 3。水道水通過鹽注水電磁閥6 3,從鹽注 水口 60h、鹽注水管60 i ,流入鹽投入室60a。鹽 注水管6 0 i的開口部,最好成爲讓水道水以淋浴狀注水 至鹽6 2的形狀。此注水量6 0至7 OmL的少量就足夠 。此量至少要從一槽(8 8 L )的洗衣水在硬度4 0 P P m以下的必要鹽量加以設定。注水量是以縮小鹽注水 管6 0 i的內徑,進入縮至鹽注水經路的途中(圖未表示 )等來縮小流路,減少流量的同時,控制鹽注水電磁閥 6 3的打開時間來做調整。經過所定量注水例如6 0 m L (至第5圖中虛線B )時間的話,微電腦5 0,會控制鹽 注水電磁閥6 0停止注水。此時,再打開給水電磁閥2 7 ,繼續給水。注入鹽投入室6 0 a的水道水,在蓋子6 1 的上面設空氣孔6 1 b的緣故,鹽6 2會一邊溶解一邊通 過防止鹽粒流出過濾網6 0 g,流入鹽水室6 0 k,但逆 止閥6 0 f堵塞孔60 e的緣故,鹽水室6 0 k滿時就停 止流入。 經濟部智慧財產局員工消費合作社印製 用水位感應器1 1檢測所定量的水供應至外槽4時, 微電腦5 0會關上給水電磁閥2 7停止給水,使旋轉翼6 正逆旋轉,攪拌換洗衣物開始洗刷。在此洗刷過程,不需 要機械力的緣故,旋轉翼的旋轉速度與標準洗衣同爲佳。 停止給水時,圓筒容器6 0內的水道水,會藉由因水道水 水面(第5圖中虛線A)與鹽水排出管6 4出口的高度差 頭部,從鹽水排出口 29c,通過鹽水排出管64,緩緩 地流出。同時空氣從吐出口 29b進入上部室60b,上 -24- 本紙張尺度.適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 五、發明說明(22 ) 部室6 0 b成爲大氣壓的緣故,逆止閥6 0 f的浮球會因 自重而落下,打開孔60e。於是鹽水室60e內的鹽水 ,會緩緩地從孔60 e流下至上部室6 0 b內·從此部分 鹽水投入室6 0 a溶解鹽6 2的鹽水會補給到鹽水室6 0 k。此會繼續到注水至鹽投室6 0 a的水道水沒有爲止。 此時,流入鹽水室6 0 k的鹽水溶解約2 0至2 2 g的鹽 ,濃度約爲2 6w t %。此濃度大致上與鹽的飽和濃度( 鹽的溶解度相當水100mL35 .7g、0°C時)相等 。此後鹽水流下至離子交換樹脂3 1層,經下部室6 0 c ,從鹽水出口 2 9 c通過鹽水排出管6 4,排出至流入洗 刷用水的外槽4內,以洗刷水稀釋。鹽水流到離子交換樹 脂3 1內,引起從化1、化2的右邊向左邊反應,置換成 給水時通過水道水而被離子交換的鈣離子、鎂離子與鹽水 中的鈉離子。於此再生離子交換樹脂3 1,令復活離子交 換能力,就可在下一次洗衣時的洗衣過程的給水而利用。 鈣離子、鎂離子會與鹽水一同排出至洗刷水中。 對再生程度,於鹽投入室6 0 a內的鹽6 2平均約消 耗2 0 g,慢慢減少。使用者透過透明的蓋子6 1來確認 殘留在鹽投入室6 0 a的鹽量,沒有就逐次打開蓋子6 1 加以補充。 鹽水會在洗刷過程的攪拌時間(3至4分鐘)內全部 流下至外槽4內。此時,來自鹽水排出管6 4的鹽水排出 量少於來自鹽水室6 0 k的鹽水供給量爲佳。此時,鹽水 會儲備在上部室80b。因此,鹽水不會只通過離子交換 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐)Na + < K + < Mg2 + < Ca2 + The calcium and magnesium ions in the ion exchange resin water react from the left and right sides of the chemistries 1 and 2 to be adsorbed and removed. Conversely, when the resin that absorbs calcium and magnesium ions flows through high-concentration saline, the calcium and magnesium ions will fall off from the right side of the chemical reaction 1 and chemical reaction 2 to the left, and the resin will return to its original state. · A commercially-available small-scale softening device used in laboratories, etc., with a capacity of 1 to 2 L of ion exchange resin and a processing flow rate of about 10 L per hour (0 · 16 L per minute). As mentioned above, in order to shorten the water supply time in domestic washing machines, a flow rate of 10 L or more per minute is directly supplied to the washing tub. Therefore, as mentioned above, the paper size of the commercially available small-scale softening device applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) -10- IIIIII * 1 IIIH 1 nn H ϋ 1 · 1 I n ϋ 1 ϋ ϋ I -(Please read the precautions on the back before filling out this page) 477847 A7 B7 V. Description of the invention (14) (Please read the precautions on the back before filling out this page) The processing flow rate is too long due to the water supply. Time batch processing, once it is temporarily stored in the water tank, it cannot be used. While the amount of ionic resin is 1 to 2 L, the volume is too large to be installed (built-in) in a domestic washing machine. In short, it is necessary for the domestic washing machine to solve the above-mentioned problems of the flow rate and the amount of resin of the ion exchange resin. According to the statistics of watercourses that have been implemented in Japan in the past, the number of surveyed pieces is half of the total hardness of 40 p pm or less, 15% of the number exceeds 100 ppm, and the average is 54.5 ppm. Printed on Figure 7 by the Ministry of Intellectual Property Bureau's Consumer Cooperative, which compares the hardness distribution of purified water in Japan (from the Heisei 6 Waterway Statistics issued by the Japan Water Works Association) and the cleansing rate when a commercially available synthetic agent containing zeolite is used. Hardness relationship, the lotion concentration is expressed by parameters. The hardness distribution is to consider the amount of water purification in each water purification field for one day. For example, the total amount of water purification is about 20%. It is understood that it is between 40 and 50 P pm. When the amount of clean water in each water purification plant is proportional to the number of households, about 20% of the whole household uses 40 to 50 ppm of water from the channel. The national average hardness was 52.9 ppm, and 98% of the total hardness was 100 P pm or less. In terms of cleaning rate, the detergent amount specified by the washing manufacturer is 0 · 0 6 7 wt% (weight), which halves the average hardness of 52 · 9ppm, and the cleaning rate also increases by about 50%. The hardness of 100 ppm is halved to obtain the same washing rate as when the washing amount is doubled. In short, reduce the hardness and use the standard washing amount to get the washing rate (concentration) twice as standard. The removal of the calcium ions and magnesium ions from the hardness components can greatly improve the washing rate of the washing machine. If the washing rate is the same as when the water is still used, you can use demineralized water to reduce the amount of detergent. The paper size applies the Chinese National Standard (CNS) A4 (210 X 297 mm) 477847 A7 B7 V. Description of the invention ( 15). Furthermore, in areas with a hardness of 40 p p m or more, it is not necessary to use the following lotions, and the impact on the environment is also small. (Please read the precautions on the back before filling in this page.) As shown in Figure 7, the hardness is below 40 P pm, and the cleaning rate is generally constant. If the hardness is above this, the cleaning rate will decrease. The hardness is below 40 p pm. The zeolite contained in the synthetic detergent will almost completely absorb the hardness components. Because of the full function of the surfactant, the cleaning rate is almost constant. For hardness above this, the amount of zeolite is insufficient. Part of the surfactant and the hardness component are reversed to form a metal soap. Because of the decrease in the amount of the surfactant, the cleaning rate is reduced. Therefore, when a synthetic detergent containing zeolite is used for laundry, it is desirable to remove calcium ions and magnesium ions having a hardness component from the laundry to about 40 ppm. On the other hand, metal soap is different from Figure 7 in that the hardness is increased and the cleaning rate is reduced. Therefore, it is better to remove as much hardness as possible. Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives The ion exchange performance of ion exchange resins is determined by the ion exchange capacity, ion exchange speed, etc. In the case of ion exchange resins for washing machines, as described above, the processing flow rate is determined to be 10 to 15 L per minute, and the amount of resin is minimized so that the resin can be installed in the washing machine. Therefore, increasing the ion exchange rate as much as possible, ensuring the processing flow rate, and increasing the ion exchange capacity can reduce the amount of resin. The ion exchange capacity and ion exchange speed are changed by the bridge degree of the ion exchange resin, the resin structure (gel type, porosity), and the resin diameter. However, the higher the bridging degree, the higher the ion exchange capacity, but the lower the ion exchange rate. When it is porous, the ion exchange rate increases faster than the gel type, but the ion exchange capacity decreases. This type of bridge and structure with ion exchange resin makes it difficult to improve both performances at the same time. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 477847 A7 ___ B7 V. Description of the invention (16) (Please read the precautions on the back before filling this page) Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs The eighth figure printed by the cooperative uses the most common sodium-type strong acidic ion exchange resin with a bridging degree of 8% for softening of hard water. In response to the change of the leaking ion concentration of water flow, the parameters of the ion exchange resin amount and the resin diameter are tested. result. The full hardness of the raw water is 10 Oppm, and the flow rate is 15 L / min. The amount of resin and resin diameter in the experiment will leak hardness components in any case, and the concentration will vary depending on the amount of resin and resin diameter. The concentration of leaking ions in the initial stage of water passing is the same resin diameter, and the smaller the resin amount, the smaller the resin diameter is when the resin amount is the same. Fig. 9 collates the total surface area (calculated) of the ion exchange resin and corrects the leaked ion concentration in the initial stage of water passing in Fig. 8. As can be seen from the figure, the leakage ion concentration is slightly inversely proportional to the total surface area of the ion exchange resin, and the ion exchange speed is proportional to the total surface area of the ion exchange resin. The total surface area of the ion exchange resin is proportional to the amount of the ion exchange resin and inversely proportional to the diameter of the ion exchange resin. The resin diameter is small, thereby reducing the amount of resin. The change in the concentration of leaking ions is about a certain concentration in the initial stage of water flow, but it will increase rapidly from the point where the water flow volume increases. After all, it will lose the ion exchange capacity and become the same concentration as the raw water. The ion exchange capacity is expressed by the area between the leaked ion concentration line and the raw water ion concentration line (for example, the area in the AB CA range in the figure when the resin amount is 100 mL and the resin diameter is 0.1 to 0.2 mm), but the resin diameter It doesn't matter, it is only proportional to the amount of resin. The ion exchange capacity of the ion exchange resin in Figure 8 is 2 · 0 meQ / ml-R (equivalent to 1 mL2 · 0 of the ion exchange resin), the resin is equivalent to 1 mL, and 10 mg can be removed by CaC〇3 conversion. Hardness component. At present, it is considered that the flow rate is 15 L per shunt-this paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 477847 A7 B7 V. Description of the invention (17) (Please read the precautions on the back first (Fill in this page again) The water channel water with a hardness of 1 0 0 p pm will make the full-automatic washing machine with a fixed capacity of 9 kg at a high water level of 8 8 times into softened water. The cleaning power of the zeolite synthetic detergent will not be affected by demineralized water. If it can reach 40 ppm, the removable hardness component is 5 · 28g (calculated as CaC03). Only the ion exchange amount is considered to require a minimum of resin. A small amount of 5 2 · 8minL is sufficient. Actually, as shown in Fig. 8, when the resin diameter is 0.1 to 0.2 mm, it is 100 mL, the resin diameter is 0.3 to 0.5 mm, and the resin diameter is 50 mL. When the resin diameter is 0.3 to 1.1 mm, there is no resin amount of 260 mL. It cannot be below 40ppm. However, resin diameters of 0. 1 to 0. 2 mm and 0. 3 to 0. 5 mm, and a processing flow rate of 15 L per minute, can reduce the amount of resin from 100 to 150 OmL, and can be installed in a household washing machine. Printed in Figure 10 by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is an ion removal mechanism using an ion exchange resin with a resin diameter of 0.1 to 0.2 mm and a resin volume of 10 OmL, which flows out of the water channel at a flow rate of 15 L. The relationship between the leakage ion concentration and the amount of water flow at the full hardness (100 P Ppm). The call sign in the picture is the first time water is passed, that is, the ion exchange resin is a new product. When the water flow rate reaches 50 L, the leakage ion concentration is constant at about 120 p pm. The leakage ion concentration was increased from the beginning, but the water flow rate reached 100 L, and the leakage ion concentration was maintained below 40 p pm. Then, when the water flow rate is 150 L, the ion exchange capacity is lost, and the leakage ion concentration is the same as the hardness of the raw water. Therefore, it is necessary to use the above-mentioned brine for regeneration processing. This reproduction process will be described later. When the full-automatic washing machine with a fixed capacity of 9 kg supplies water to a high water level (water volume 8 8 L), the hardness of the washing water is as shown in the figure. The _ symbol is about 1 8 p pm, which will not cause the paper size to apply Chinese national standards ( CNS) A4 specification (210 X 297 mm) 477847 A7 ___ B7 V. Description of the invention (18) Degraded cleaning performance. Figure 11 shows the parameters, and is based on the manual pollution cleaning of a single-phase induction motor that is required to drive a single-phase induction motor using a conventional commercial power supply (5 Η Η Z). The softening of the washing water using the number of rotations of the rotary wing, time, and the ion removal mechanism is the result of the washing force. Comparison benchmark (rotating speed of rotating wing indicated by a is 11 0 r pm, time is 9 minutes, washing water is hard 1 0 0 ?? 1! 1, washing force 1), other conditions are the same as a, rotating speed of rotating wing is only 1 · At 36 times (15 rpm) (indicated by b), the cleaning power is 1.25. When the time is only twice (18 minutes), the cleaning power is 1 · 2 9. When the ion removal mechanism uses water with a hardness drop of 60% as the washing machine water (indicated by d), the cleaning power is 1. 2 6. The same amount of detergent, that is, when the detergent concentration is 1.2 times (expressed as e), the washing rate is 1.09 °. From this result, we know that the effect of cleaning the ion removal mechanism is achieved. Times the same effect. The speed of the rotary wing is 1 · 3 and 6 times will increase the mechanical force and twice the time will increase the mechanical force to obtain the same effect on washing. On the other hand, when the detergency of the dirt such as a sleeve cannot reach 1 · 6 in the previous experiment, the housewife uses the subjective evaluation of the housewife monitor to obtain the result that the dirt cannot be washed out. In short, the housewife eliminated the idea that the washing machine could not wash off the dirt on the shirts and sleeves of Y shirts, etc. After soaking the unsatisfactory dirt with a high concentration of lotion and washing it by hand, the situation of washing with a washing machine was resolved, showing that the experimental cleaning power needs Is 1 · 6. The size of this paper is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -Packing -------- · Order ----- ---- & Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -21-477847 A7 _ B7 V. Description of the Invention (19) In order to obtain this cleaning force, mechanical force alone is used. The reference and rotation speed must be the same, and the time must be about 30 times. The reference and time must be the same, and the rotation speed needs to be about twice. However, increasing the mechanical force will increase the damage of the laundry and deteriorate the accuracy of the laundry. It also increases the reason that the cloths are twisted together. After the laundry is finished, it takes more labor to remove the laundry from the washing tub. Even as the rotation speed increases, power consumption increases due to increased noise and time. In short, mechanical force alone is not practical. In this embodiment, in addition to using the soft water of the ion removal mechanism to improve the cleaning force, the practical rotation speed of the rotary wing is 1.3 times. As shown in FIG. 11 and f, the cleaning force can be increased to 1 · 5 7 detergency. For the softening effect of washing water, it is better to increase the foam of the lotion. Especially laundry detergent is remarkable. Furthermore, by increasing the rotation speed, the washing water is often stirred to promote the dissolution of air in the water, and then foaming is better. Therefore, the change of clothes will float up in the foam, and even a small amount of washing water can increase the chance of contact and friction in the change room. That is, the mechanical force imparted to the laundry can be increased by using less washing water. In a standard washing machine, use 5kg of laundry change, water 56, and a washing amount of 37g at a concentration of 0 · 067wt%. For high-clean laundry, use the same laundry change of 5kg, 4L of water, and the same amount of 37g, lotion. The concentration may be 1 · 2 times 0 · 0 8 wt%. Therefore, as shown in Fig. 11g, a high cleaning power of 1.62% was obtained. As explained above, in this embodiment, a very high washing cycle is provided for extremely dirty laundry changes. For 60% to 70% of the fixed capacity (approximately 5 kg), the paper size applies the Chinese National Standard (CNS) A4 specification ( 210 X 297 mm) (Please read the notes on the back before filling out this page) _1 mmmmm mmm— ϋ 1 ϋ · 1 一 -ον · 1 · I t I —ai 1 I Printed 477847 A7 __ B7 V. The laundry change of the invention description (20), by using the softening of the washing water of the ion removal mechanism and increasing the rotation speed of the rotary wing to exert high cleaning power. (Please read the precautions on the back before filling this page.) When the washing process is finished, the microcomputer 50 will open the drain valve 1 3 to drain the washing water in the outer tank 4. After draining, move to the dehydration stroke. In the dehydration process, the microcomputer 50 is a spiral coil 9a controlling the transmission device 9, and the washing tank 5 is rotated at a high speed by a three-phase induction motor 7. During this period the drain valve 1 3 is opened. After the dehydration process was completed, the drain valve 13 was closed, and then moved to the scrubbing process. The scrubbing process, also according to this method, is usually performed twice at a time. Once the water is stored in the outer tank 4, the rotary wing 6 is rotated to dilute the detergent remaining on the clothes, so-called scrubbing, which must have a slightly same amount of water as the previous washing water supply. Therefore, the amount of water by the ion removal means 28 is 88L of the previous washing water supply, and 88L of the washing here is 264L in total twice. As shown in Figure 10, at a flow rate of 150 L, the ion exchange capacity will be lost. The hardness during the first scrubbing water supply is the same as that of the raw water. However, during the washing process, the hardness is not affected, so it is okay to supply high hardness water. The water supply during the washing process is the same as that during the washing process except for the final washing process, so this example is the regeneration of the ion exchange resin 31 during the final washing process when the water is stored in the outer tank 4 for the final washing process Processing is explained. First, the water supply solenoid valve 27 is opened, and the water channel water is passed through the ion removing mechanism 28 in the same manner as the above-mentioned laundry water supply, and the washing water is supplied into the outer tub 4. The water flow is full of the upper chamber 6 0 b of the ion removal mechanism, the check valve 6 0 f is in the state of blocking the hole 6 0 e (this is the predetermined time after the water solenoid valve 2 7 is opened), and the microcomputer 50 0 will open the salt. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 477847 A7 _ B7 V. Description of the invention (21) (Please read the precautions on the back before filling this page) Water injection solenoid valve 6 3. The water channel water passes through the salt water injection solenoid valve 63, flows from the salt water injection port 60h, and the salt water injection pipe 60i, and flows into the salt input chamber 60a. It is preferable that the opening of the salt water injection pipe 60 i be shaped so that the water channel water is injected into the salt water in a shower shape to the salt 62. A small amount of water injection of 60 to 70 mL is sufficient. This amount should be set at least from the necessary amount of salt in a tank (88 L) of washing water with a hardness of 40 P P m or less. The amount of water injection is to reduce the inner diameter of the salt water injection pipe 6 0 i and enter the way to the salt water injection path (not shown) to reduce the flow path and reduce the flow rate. At the same time, control the opening time of the salt water injection solenoid valve 63 To make adjustments. After a certain amount of water injection time, for example, 60 m L (to dotted line B in Fig. 5), the microcomputer 50 will control the salt water injection solenoid valve 60 to stop water injection. At this time, open the water supply solenoid valve 2 7 and continue the water supply. Water is injected into the water channel of the salt input chamber 60 a, and an air hole 6 1 b is provided on the cover 6 1. The salt 6 2 will dissolve while preventing the salt particles from flowing out of the filter 60 g and flowing into the salt water chamber 60 k. However, due to the blockage of the hole 60e by the check valve 60f, the inflow of the brine chamber 60k is stopped. When the water consumption sensor 11 printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs detects the amount of water supplied to the outer tank 4, the microcomputer 50 will close the water supply solenoid valve 2 7 to stop the water supply, and cause the rotary wing 6 to rotate forward and backward, and stir Change clothes and start washing. During the scrubbing process, no mechanical force is required, and the rotation speed of the rotary wing is the same as that of standard laundry. When the water supply is stopped, the water in the cylindrical container 60 passes through the head due to the height difference between the water surface of the water channel (dotted line A in Fig. 5) and the outlet of the brine discharge pipe 64, and passes through the brine discharge outlet 29c The discharge pipe 64 flows out slowly. At the same time, the air enters the upper chamber 60b from the outlet 29b, up to -24- this paper size. Applicable to China National Standard (CNS) A4 (210 X 297 mm) 477847 V. Description of the invention (22) Department 60b becomes atmospheric pressure For this reason, the floating ball of the check valve 6 0 f may drop due to its own weight, and the hole 60e is opened. Therefore, the brine in the brine chamber 60e will slowly flow down from the hole 60e to the upper chamber 60b. From this part, the brine dropped into the chamber 60a will dissolve the salt 62 and the brine will be replenished to the brine chamber 60k. This will continue until the water in the salt casting chamber 60 a is empty. At this time, the brine flowing into the brine chamber 60 k dissolves about 20 to 22 g of salt at a concentration of about 26 w t%. This concentration is approximately equal to the saturated concentration of salt (the solubility of salt is equivalent to 100 mL of water, 35.7 g, 0 ° C). Thereafter, the saline solution flows down to the 31 layer of ion exchange resin, passes through the lower chamber 60c, and passes through the brine discharge pipe 64 from the brine outlet 29c, and is discharged into the outer tank 4 flowing into the washing water and diluted with the washing water. The salt water flows into the ion exchange resin 31, causing a reaction from the right to the left of the chemical exchange 1 and the chemical reaction 2 to be replaced with calcium ions, magnesium ions, and sodium ions which are ion-exchanged through the water channel when the water is supplied. Here, the ion exchange resin 31 is regenerated, so that the ion exchange capacity can be revived and can be used in the water supply during the next washing process. Calcium and magnesium ions are discharged into the washing water together with the brine. Regarding the degree of regeneration, the salt 6 2 in the salt input chamber 60 a consumes about 20 g on average, and gradually decreases. The user confirms the amount of salt remaining in the salt input chamber 60 a through the transparent cover 61, and opens the cover 6 1 one by one to replenish it. The brine will flow down into the outer tank 4 within the stirring time (3 to 4 minutes) of the scrubbing process. At this time, it is preferable that the amount of brine discharged from the brine discharge pipe 64 is smaller than the amount of brine supplied from the brine chamber 60 k. At this time, the brine is stored in the upper chamber 80b. Therefore, salt water will not only pass through ion exchange. The paper size applies to China National Standard (CNS) A4 (210 X 297 mm)
丨丨丨I*丨丨丨·——丨—•丨丨丨 (請先閱讀背面之注意事項再填寫本頁) 一5J« — — — — — — I — 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 477847 A7 _ B7 五、發明說明(23 ) 樹脂3 1層的一部分,會均勻地通過,進行效率良好的再 生。因此, (1 )加大鹽水通過傷害防止鹽粒流出過濾網6 0 g的面 積,通過足夠量的鹽水。實施例的鹽水約通過一分鐘以內 〇 (2 )將孔徑6 0 e的直徑做得比鹽水排出口 2 0 C的內 徑或鹽水排出管6 4的內徑大。實施例的孔6 0 e的直徑 爲3mm,鹽水排出口 2 0 c的內徑爲2mm。 而根據鹽水排出管6 4的出口 6 4 a的位置,鹽水流 下時間不同。此乃利用鹽下流下圓筒容器6 0內的鹽水水 面與鹽水排出管6 4的出口 6 4 a頭部決定的緣故。因而 ,出口 6 4 a離下部室6 0 c底部愈遠,鹽水流下時間就 愈短。鹽水排出口 2 0 c的內徑2mm的情況下,出口 6 4 a爲從下部室6 0 c底部1 5 Omm程度時,在供給 的6 OmL,溶解2 0 g的鹽的鹽水大部份會在3至4分 鐘從圓筒容器6 0內流下至外槽4內。再者,實際因表面 張力,鹽水會稍微的殘留在離子交換樹脂間,但下一次洗 衣時幾乎不會受影響。當然鹽水流下後,會打開給水電磁 閥2 7,通過1至2 L的水道水/追加洗衣流水過程殘留 在離子交換樹脂間的鹽水亦可。最後洗刷過程與離子交換 樹脂再生過程結束的話,洗刷水排水後,進行脫水過程, 結束所有洗衣過程。 本實施例,給水時水從下部室6 0 c向上部室6 0 b 流至上方,再生時,鹽溶解的水從上部室6 0 b向下部室 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -----.---,----裝---- (請先閱讀背面之注意事項再填寫本頁) 一6!,11111111 %, 477847 A7 ______ B7 五、發明說明(24 ) 6 0 c流至下方(給水時與再生時水的流向相反)。再生 用水流至下方,能以重力流下再生用水的緣故,離子除去 機構2 8的構造能夠簡單化。而向上方流出給水,是從上 部室6 0 b向下部室6 0 c流出的情形下,會在上部室 60b作用水道壓力(0.3至8kg f/m2),逆止閥 8 0 f必需爲能耐得住此壓力的構造,所以連帶的構造複 雜化和可靠度下降。進而在給水時與再生時水的流動相反 ,在再生效率點很有利,爲一般所知的。 在上述對再生處理的離子交換樹脂3 1,將在下次給 水時通過水道水(全硬度1 0 0 p pm)時的漏洩離子濃 度以第1 0圖記號做表示。通水開始之後的漏洩離子濃 度,與初次(新品時)同等,但比初次更快增加,6 0 L 爲弱,超過4 0 p p m,約9 0 L就沒有離子交換能力。 洗衣給水中,會超過硬度4 0 p pm,但儲備在外槽4的 洗衣水硬度,如第1 0圖中□記號所示,高水位(水量 888L)也在約38ppm。因而,藉由進行上述再生 處理,使用放入沸石合成洗劑的情形,洗衣性不會下降的 硬度4 0 p ρ m以下的洗衣水,能得到高水位一槽份。接 著在洗刷過程,離子交換能力沒有的緣故,供給的水硬度 與原水同,但洗刷性能不會受影響。亦即,離子交換樹脂 量,設定在洗衣給水的離子交換能力飽和的緣故,由於無 法吸附必要以上的離子,連帶可減少離子除去機構的小型 化與再生用的鹽量。 再者,第二次以後的漏洩離子濃度比初次多,表示前 本紙張尺奉適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) 胃· tmmm mmim 1 i·— ϋ ϋ ·ϋ 一:^· n ϋ Βϋ I ·ϋ «ϋ ·%, 經濟部智慧財產局員工消費合作社印製 -ΖΓ- 477847 經濟部智慧財產局員工消費合作社印製 A7 _ ____B7___ 五、發明說明(25 ) 述再生處理不能全部再生離子交換基。由第1 〇圖求得初 次離子交換容量時’約爲(CaC〇3換算)°將這 個全部與鹽水中的鈉離子做交換’用化1、化2就須 1 2 g鹽程度。在上述再生處理而供給的鹽量均2 0至 22g,爲足夠的量。對鹽的注入水比60mL少時’ 8 8 L給水時的硬度會超過4 0 p pm。 因此,對鹽的注水量最低必需爲6 0 m L。再生處理 後的第二次以後,離子交換容量約爲5 · 5 g ( C a C〇3 換算),再生率爲55%。爲提高此再生率,增加注水量 和增加鹽水爲佳。但如上所述再生率5 5 %正好可處理一 槽(8 8 L )份的緣故,再生率提高到這個以上,鹽會無 故地消耗掉。因而,對鹽的注水量6 0 m L,即使還有裕 度,到7〇mL就足夠。 按本再生方法,量少但能與高濃度的鹽一同在洗刷水 中加入離子交換的鈣離子、鎂離子。因此,洗刷水的硬度 比供給的高。但硬度成份不會影響到洗刷性能的緣故,所 以沒有問題。而溶解在鹽6 OmL的水的2 0 g中約 6 . 5 g可使用離子交換樹脂再生,洗刷水中排出 1 3 · 5g。但以大量洗刷水稀釋的緣故,並未在構成洗 衣槽5的不銹鋼等發生錡的疑慮。附帶說明一下,容量8 k g的全自動洗衣機的用水量爲2 5至8 8 L程度,但用 此水稀釋,濃度即爲0 · 054至0 . 015wt%.比 生理食鹽水0.9%低。 如以上說明,本發明將離子交換樹脂的樹脂徑與樹脂 本紙張尺度適用中國國家標準(CNS)A4規格(210 x 297公釐) ·此_ (請先閱讀背面之注意事項再填寫本頁) * n n 1 ·- ϋ ·1 · ·1 —me mamMW immw ϋ« · · 477847 A7 B7 五、發明說明(26 ) (請先閱讀背面之注意事項再填寫本頁) 量做最適化的緣故,可實現以給水流量1 5 L/分,具有 洗衣給水時只所定量的離子除去性能的小型便宜的離子除 去機構’可搭載在洗衣機。而洗刷給水時沒有離子除去能 力就不吸附剩下的離子的緣故,再生用鹽量減少。就離子 交換樹脂的再生處理方面,無論使用溶解哪個家庭的鹽的 鹽水,在最後洗刷過程中爲自動性的進行。因此,使用者 只要一週一次(洗衣7次就一次)將約1 5 0 g鹽投入鹽 投入室的簡單操作就可,不會浪費時間。而鹽非常便宜的 緣故,幾乎沒什麼再生成本。 然後,通過此離子除去機構的洗衣用水,其硬度會大 幅減少,可提高洗劑的化學力,大大提升洗淨性能。進而 ’對極髒的換洗衣物而言,以電動機的可速控制機構來提 高旋轉翼的旋轉速度,提高機械力,以與先前提升化學力 的相乘作用將洗淨力提高6 0%。此時,因離子除去機構 的化學力提升會增加洗衣時間,一邊提高抑制增加洗衣的 消耗電力的效果,抑制傷害換洗衣物布料、絞衣的範圍, 習知難以手洗做前處理Y襯衫等衣襟、袖子污垢,能只用 洗衣機洗掉。 經濟部智慧財產局員工消費合作社印製 旋轉翼的旋轉速度(調節器的驅動速度)提昇洗淨效 果的緣故高的剛好,考慮夜間使用的情形,反之,就旋轉 速度低加以控制(調整),藉此需實現噪音位準小的安靜 的運轉(運轉馬達),此種運轉馬達(洗衣馬達),防止 洗淨效果下降的緣故,以利用軟水化的洗淨效果的提昇來 補充加在換洗衣物的機械力的下降。藉此減低洗衣時間( 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 _ B7 五、發明說明(27 ) 機械力賦予時間)的增加之同時,得到高洗淨效果。 以上說明,在最後洗刷過程的給水中進行對鹽6 2的 的水道水的注水,但即使在下次進行還是可得到同樣的效 果。打開給水電磁閥2 7,將最後洗刷過程的水供應至外 槽4內。用水位感應器1 1檢測所定量的水供給至外槽4 時,微電腦50會關上給水電磁閥27,停止給水,使旋 轉翼6正逆旋轉,攪拌換洗衣物開始洗刷。給水停止時, 圓筒容器6 0內的水道水,會通過吐出口 2 9 b與鹽水排 出管6 4加以流出,上部室6 0 b內的水位下降來進行的 。同時,逆止閥6 0 f的浮球因自重而落下,打開孔6 0 e,上端室6 Ob內的水位比吐出口 2 9 b低時,水道水 會全部從鹽水排出管6 4流出。然後,上部室6 0 b內的 水位比吐出口 2 9 b低的話(第5圖中虛線A ),微電腦 5 0會打開鹽水注水閥6 3,將規定量的水供給至鹽投入 室60a。供應到鹽投入室60a的水,會邊溶解鹽62 邊通過防鹽粒流出過濾網6 0 g,流入鹽水室6 0 k,慢 慢從孔6 0 e流下至上部室6 0 b內。此時,上部室6 0 b內的水位,比吐出口 2 9 b更下方的緣故,流下至上部 室6 0 b的鹽水會從吐山口 2 0 b流出不浪費,供應的鹽 水會全部通過離子交換樹脂3 1內。因此,具有效率良好 的進行離子交換樹脂31的再生之優點。 而旋轉翼驅動電動機以三相感應電動機爲例示,但可 理解的直流電動機等其他形式的電動機亦可。此時,作爲 電動機的可變速控制機構,設有可改變對電動機的外加電 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先閱讀背面之注意事項再填寫本頁) ▼裝--------訂--------- 經濟部智慧財產局員工消費合作社印製 477847 f A7 B7 五、發明說明(28 ) (請先閱讀背面之注意事項再填寫本頁) 壓之電路等,可改變外加電壓來控制電動機的旋轉速度的 構成爲佳。此外,將電動機的旋轉速度是浮球元件等旋轉 感應器來檢測,介於微電腦,反饋至轉換電路,實現高精 度旋轉速度的構成亦可。 其他,本發明並不限定在上述實施例,在不脫離主旨 範圍內做種種變更而實施者。 按上述實施例,因設有精巧地構成具有離子交換能的 素材,且以安裝在洗衣機的狀態,可再生處理而用之離子 除去機構、和根據換洗衣物的污垢來改變旋轉翼的旋轉速 度之可變控制機構,所以一同提高洗淨的化學力與機械力 ,藉由其相乘效果,不增加時間及耗電量,提供一具備有 高洗淨能力之洗衣機。然後能洗掉習知洗衣機難以洗掉的 Y襯衫等衣襟、袖子污垢。 按有關本發明之上述實施例,對應污垢的程度,改變 調節器的驅動速度,賦予換洗衣物機械力的時間不長,會g 提高洗淨效果。而減弱含在洗衣水中的洗淨效果,減低離 子,藉此因提升洗淨效果而減輕機械力降低,即使減慢調 節器的驅動速度,還是能減低增加洗衣時間。 經濟部智慧財產局員工消費合作社印製 以短時間再生具有離子交換能的素材而使用,離子交 換機構或離子除去機構可小型地設在洗衣機。 〔圖面之簡單說明〕 第1圖係利用本發明的全自動洗衣機之外觀立體圖。 第2圖係利用本發明的全自動洗衣機之縱斷面圖。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 B7 五、發明說明¢9 ) 第3圖係利用本發明的全自動洗衣機之操作面板圖。 第4圖係利用本發明的後部收納箱內部之俯視圖。 第5圖係利用本發明的離子除去機構之立體圖與縱斷 面圖。 第6圖係利用本發明的全自動洗衣機之電氣連接方塊 圖。 第7圖係表示硬度與洗淨率之關係圖。 第8圖係表示通水量與漏洩硬度之關係圖。 第9圖係表示離子交換樹脂表面積與漏洩硬度之關係 圖。 第1 0圖係表示初次與再生後的通水量與漏洩硬度之 關係圖。 第1 1圖係表示根據洗衣條件的洗淨力相異之圖。 〔符號之說明〕 (請先閱讀背面之注意事項再填寫本頁) ,裝------- —訂---------· 經濟部智慧財產局員工消費合作社印製 4 • • · .外槽 5 • • · .洗衣兼 脫水槽 7 • • · •三相感 應 電動 1 7 b . .後部收 納 箱 2 6 • · .水道栓 P 2 7 • · .給水電 磁 閥 2 9 a · •入水口 2 9 b . •吐出口 2 9 c · .鹽水排出 □ 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 477847 A7 _ 五、發明說明(30 ) 2 9 d · ·濾網 2 9 e · ·樹脂室 (請先閱讀背面之注意事項再填寫本頁) 3 1 ...離子交換樹脂 5 0 · · ·微電腦 6 0 ...圓筒容器 6 0 a ··鹽投入室 6 0 b · ·上部室 6 0 c · ·下部室 6 0 d · ·隔壁丨 丨 丨 I * 丨 丨 丨 —————— • 丨 丨 丨 (Please read the precautions on the back before filling this page) 5J «— — — — — — I — Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and Economics 477847 A7 _ B7 V. Description of the invention (23) A part of the resin 31 layer will pass evenly for efficient regeneration. Therefore, (1) increase the salt water to prevent the salt particles from flowing out of the 60 g area of the filter through injury, and pass a sufficient amount of salt water. The saline solution of the example passes within about one minute. (2) The diameter of the pore diameter 60 e is made larger than the inner diameter of the brine discharge port 20 C or the inner diameter of the brine discharge pipe 64. The diameter of the hole 60 e in the example was 3 mm, and the inner diameter of the saline discharge port 20 c was 2 mm. However, depending on the position of the outlet 64a of the brine discharge pipe 64, the saline flow down time is different. This is because the head of the salt water surface and the outlet 64 4 a of the salt water discharge pipe 64 are flown down in the cylindrical container 60 under the salt. Therefore, the farther the outlet 64a is from the bottom of the lower chamber 60c, the shorter the downflow time of the brine. When the inner diameter of the salt water discharge port 20 c is 2 mm, when the outlet 6 4 a is approximately 15 mm from the bottom of the lower chamber 60 c, most of the salt water in which 20 g of salt is dissolved will be supplied at 6 OmL. It flows down from the inside of the cylindrical container 60 to the inside of the outer tank 4 in 3 to 4 minutes. In addition, due to the actual surface tension, the salt water will remain in the ion exchange resin slightly, but it will be hardly affected in the next washing. Of course, after the salt water flows down, the water supply solenoid valve 2 7 will be opened, and the salt water remaining in the ion exchange resin through the 1 to 2 L of water channel / additional laundry flow may be used. At the end of the washing process and the ion exchange resin regeneration process, after the washing water is drained, the dehydration process is performed to end all washing processes. In this embodiment, the water flows from the lower chamber 6 0 c to the upper chamber 6 0 b to the upper side when the water is supplied. During regeneration, the salt-dissolved water flows from the upper chamber 6 0 b to the lower chamber. The paper size applies the Chinese National Standard (CNS) A4 specification. (210 X 297 mm) -----.---, ---- install ---- (Please read the precautions on the back before filling this page) A 6 !, 11111111%, 477847 A7 ______ B7 V. Description of the invention (24) 6 0 c flows to the bottom (the direction of water flow is opposite to that during regeneration). Since the regeneration water flows downward and the regeneration water can flow down by gravity, the structure of the ion removing mechanism 28 can be simplified. In the case where the feed water flows upward from the upper chamber 60 b to the lower chamber 60 c, the water channel pressure (0.3 to 8 kg f / m2) acts on the upper chamber 60b, and the check valve 8 0 f must be resistant. The structure that can withstand this pressure complicates the structure and reduces the reliability. Furthermore, it is generally known that the flow of water during feeding is opposite to that during regeneration, which is advantageous at the point of regeneration efficiency. In the above-mentioned regeneration-exchanged ion exchange resin 31, the leaked ion concentration when passing through water channel (full hardness 100 p pm) at the next water supply is represented by the figure 10 mark. The concentration of leaking ions after the start of water flow is the same as the first time (in the case of new products), but it increases faster than the first time. 60 L is weak, exceeding 40 p p m, and about 90 L has no ion exchange capacity. The washing water will exceed the hardness of 40 p pm, but the hardness of the washing water stored in the outer tank 4 is indicated by the □ mark in Figure 10, and the high water level (water volume 888L) is also about 38 ppm. Therefore, when the zeolite synthetic detergent is used for the regeneration process described above, washing water having a hardness of 40 p ρ m or less without deterioration in laundry properties can be obtained at a high water level. Next, during the scrubbing process, because the ion exchange capacity is not available, the hardness of the supplied water is the same as the original water, but the scrubbing performance will not be affected. That is, because the amount of ion-exchange resin is set to the saturation of the ion-exchange capacity of the laundry feed water, it is not possible to adsorb more ions than necessary, which can also reduce the size of the ion-removal mechanism and the amount of salt for regeneration. In addition, the leaked ion concentration after the second time is higher than the first time, which means that the previous paper rule is applied to the Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Stomach · tmmm mmim 1 i · — ϋ ϋ · ϋ One: ^ · n ϋ Βϋ I · ϋ% ϋ%, printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs -ZΓ- 477847 Preparing A7 _ ____B7___ 5. Description of the Invention (25) The regeneration process described above cannot fully regenerate ion exchange groups. When the first ion exchange capacity is obtained from the graph of FIG. 10 ', it is approximately (calculated as CaC03). To exchange all of this with sodium ions in saline', it is necessary to use 12 g of salt for chemical conversion 1, chemical conversion 2. The amount of salt supplied in the above-mentioned regeneration process is 20 to 22 g each, which is a sufficient amount. When the amount of water injected into the salt is less than 60 mL, the hardness at the time of '8 8 L water supply exceeds 40 p pm. Therefore, the minimum amount of water injected into the salt must be 60 ml. After the second time after the regeneration process, the ion exchange capacity was approximately 5.5 g (in terms of C a C03), and the regeneration rate was 55%. To increase this regeneration rate, it is better to increase the amount of water injected and increase the amount of saline. However, as mentioned above, the regeneration rate of 55% is just enough to handle one tank (88 L). If the regeneration rate is increased above this, the salt will be consumed for no reason. Therefore, a water injection amount of 60 m L to the salt, even if there is a margin, is sufficient to 70 mL. According to this regeneration method, ion exchanged calcium ions and magnesium ions can be added to the washing water with a small amount but with a high concentration of salt. Therefore, the hardness of the washing water is higher than that of the supplied water. However, the hardness component does not affect the washing performance, so there is no problem. Approximately 6.5 g of 20 g dissolved in 60 mL of salt can be regenerated with ion exchange resin, and 1 3 · 5 g is discharged from the washing water. However, there is no doubt that the stainless steel or the like constituting the washing tub 5 is diluted with a large amount of washing water. Incidentally, the water consumption of a full-automatic washing machine with a capacity of 8 kg is about 25 to 88 L, but when diluted with this water, the concentration is 0. 054 to 0.015 wt%. It is lower than 0.9% of physiological saline. As explained above, the resin diameter and resin paper size of the ion exchange resin according to the present invention apply the Chinese National Standard (CNS) A4 specification (210 x 297 mm). * nn 1 ·-ϋ · 1 · · 1 —me mamMW immw ϋ «· · 477847 A7 B7 V. Description of the invention (26) (Please read the precautions on the back before filling in this page) A small and inexpensive ion removal mechanism that achieves a feed water flow rate of 15 L / min and has only a certain amount of ion removal performance during laundry water supply can be installed in a washing machine. In the case of scrubbing the feed water, the remaining ions are not adsorbed without the ability to remove ions, and the amount of regeneration salts is reduced. Regarding the regeneration process of the ion exchange resin, regardless of which family salt is used, the brine is automatically processed in the final washing process. Therefore, the user only needs to put about 150 g of salt into the salt room once a week (once the laundry is washed 7 times), and the time is not wasted. Because salt is very cheap, there is almost no regeneration cost. Then, the hardness of the washing water through this ion removing mechanism will be greatly reduced, which can increase the chemical force of the lotion and greatly improve the cleaning performance. Furthermore, for extremely dirty laundry, the speed control mechanism of the electric motor is used to increase the rotation speed of the rotary wing, increase the mechanical force, and multiply the cleaning force by 60% by multiplying the previous chemical force. At this time, the chemical power of the ion removal mechanism will increase the washing time. At the same time, it will increase the effect of suppressing the increase in power consumption of the laundry and suppress the range of damage to change the fabric and the sweater. The sleeve is dirty and can be washed off only with a washing machine. The rotation speed of the rotary wing (drive speed of the regulator) printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is just high to improve the cleaning effect. Considering the use at night, on the contrary, the rotation speed is controlled (adjusted). Therefore, it is necessary to realize quiet operation (operation motor) with low noise level. This operation motor (washing motor) prevents the reduction of the washing effect, and uses the improvement of the softening and washing effect to supplement the laundry. The decline of mechanical force. This reduces the washing time (this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 477847 A7 _ B7. V. The description of the invention (27) Mechanical force imparting time) increases, and high washing is achieved effect. It has been explained above that the water supply to the salt water 2 of the salt water 2 is performed in the feed water in the final washing process, but the same effect can be obtained even next time. The water supply solenoid valve 2 7 is opened to supply the water in the final scrubbing process into the outer tank 4. When the water level sensor 11 detects that a predetermined amount of water is supplied to the outer tank 4, the microcomputer 50 closes the water supply solenoid valve 27, stops the water supply, rotates the rotary blade 6 in the forward and reverse directions, and stirs the laundry to start washing. When the water supply is stopped, the water in the cylindrical container 60 will flow out through the discharge port 29b and the brine discharge pipe 64, and the water level in the upper chamber 60b will drop. At the same time, the float ball of the check valve 60 0 f falls due to its own weight. When the hole 60 e is opened and the water level in the upper chamber 6 Ob is lower than the discharge outlet 2 9 b, all the water in the channel will flow out of the brine discharge pipe 64. Then, if the water level in the upper chamber 60b is lower than the discharge port 29b (dotted line A in Fig. 5), the microcomputer 50 opens the brine injection valve 63 and supplies a predetermined amount of water to the salt input chamber 60a. The water supplied to the salt input chamber 60a flows out of the filter 60 g through the anti-salt particles while dissolving the salt 62, flows into the salt chamber 60 k, and slowly flows down from the hole 60 e to the upper chamber 60 b. At this time, because the water level in the upper chamber 60 b is lower than the spit outlet 2 9 b, the brine flowing down to the upper chamber 60 b will flow out of the turret pass 2 0 b without waste, and the supplied brine will all pass through ion exchange. Resin 3 1 inside. Therefore, there is an advantage that the regeneration of the ion exchange resin 31 is performed efficiently. The rotary wing drive motor is exemplified by a three-phase induction motor, but it is understood that other types of motors such as a DC motor are also possible. At this time, as a variable-speed control mechanism for the motor, the paper size that can be applied to the motor can be changed. The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling in this Page) ▼ Packing -------- Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 477847 f A7 B7 V. Invention Description (28) (Please read the note on the back first Please fill in this page for more information.) It is better to change the applied voltage to control the rotation speed of the motor. In addition, the rotation speed of the motor is detected by a rotation sensor such as a floating ball element, and it is interposed between the microcomputer and the feedback circuit to realize a high-precision rotation speed. In addition, the present invention is not limited to the above embodiments, and can be implemented by making various changes without departing from the gist. According to the above-mentioned embodiment, since the material having ion exchange energy is delicately constructed and installed in a washing machine, the ion removing mechanism can be used for regenerative processing, and the rotation speed of the rotary wing is changed according to the dirt of the laundry change. The variable control mechanism improves the chemical and mechanical forces of the washing together, and provides a washing machine with high washing capacity by multiplying the effects without increasing time and power consumption. Then you can wash off the dirt on the blouses and sleeves of Y shirts, which are difficult to wash off by conventional washing machines. According to the above-mentioned embodiment of the present invention, the driving speed of the regulator is changed in accordance with the degree of dirt, and the mechanical force for changing clothes is not long, which will increase the cleaning effect. While weakening the washing effect contained in the washing water, the ions are reduced, thereby reducing the mechanical force reduction by improving the washing effect. Even if the driving speed of the regulator is slowed, the washing time can be reduced. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. It can be used to regenerate materials with ion exchange energy in a short time. [Brief Description of Drawings] FIG. 1 is an external perspective view of a fully automatic washing machine using the present invention. Fig. 2 is a longitudinal sectional view of a fully automatic washing machine using the present invention. This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 477847 A7 B7 V. Description of the invention ¢ 9) Figure 3 is a diagram of the operation panel of a fully automatic washing machine using the present invention. Fig. 4 is a plan view of the inside of the rear storage box using the present invention. Fig. 5 is a perspective view and a longitudinal sectional view of an ion removing mechanism using the present invention. Fig. 6 is a block diagram of the electrical connection of the fully automatic washing machine using the present invention. Fig. 7 is a graph showing the relationship between hardness and washing rate. Fig. 8 is a graph showing the relationship between the water flow rate and the leak hardness. Fig. 9 is a graph showing the relationship between the surface area of the ion exchange resin and the leak hardness. Fig. 10 is a graph showing the relationship between the water flow rate and the leak hardness after the first time and after the regeneration. Fig. 11 is a graph showing different washing powers depending on washing conditions. 〔Explanation of Symbols〕 (Please read the precautions on the back before filling this page), installed -------------- Order --------- · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs • •.. Outer tank 5 • • •. Laundry and dehydration tank 7 • • • • Three-phase induction motor 1 7 b... Rear storage box 2 6 • ·. a · • Water inlet 2 9 b. • Spit outlet 2 9 c ·. Brine discharge □ This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 477847 A7 9 d · · filter 2 9 e · · resin chamber (please read the precautions on the back before filling in this page) 3 1 ... ion exchange resin 5 0 · · microcomputer 6 0 ... cylindrical container 6 0 a ·· Salt input chamber 6 0 · · Upper chamber 6 0 c · · Lower chamber 6 0 d · · Next door
6 0 e · ·孑L 6 0 f · ·逆止閥 6 0 g ..防止鹽粒流出濾網 6 0 h . ·鹽注水口 6 0 i . ·鹽注水管 6 0 k ·.鹽水室 6 0 r · ·空氣孔 經濟部智慧財產局員工消費合作社印製 • . ······ 11234124 6 6 6 6 6 7 7 76 0 e · · 孑 L 6 0 f · · Check valve 60 g: Prevent salt particles from flowing out of the screen 60 h. · Salt water injection port 6 0 i. · Salt water injection pipe 6 0 k ·. Salt water chamber 6 0 r · · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Air Hole Ministry of Economic Affairs ·... 11234124 6 6 6 6 6 7 7 7
路 閥 電 磁管 號 電出路路信 孔 水排電電M 子氣 注水流換W 蓋空鹽鹽鹽換轉 P 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -όό - 477847 A7 _B7 五、發明說明(31 ) 80 ...標準洗衣按鈕 81 ...高洗淨洗衣按鈕 經濟部智慧財產局員工消費合作社印製 ---丨丨I·----_裝---- (請先閱讀背面之注意事項再填寫本頁) 訂--------- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -34 -Road valve Solenoid No. Electric outlet Luxin Kong Water drainage electricity M Gas injection water exchange W Cover empty salt salt salt change P This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -όό- 477847 A7 _B7 V. Description of the invention (31) 80 ... Standard laundry button 81 ... High-washing laundry button Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economy --- 丨 丨 I · ----_ 装- --- (Please read the notes on the back before filling out this page) Order --------- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -34-