TW467984B - Method for producing elastic synthetic leather - Google Patents

Method for producing elastic synthetic leather Download PDF

Info

Publication number
TW467984B
TW467984B TW86112460A TW86112460A TW467984B TW 467984 B TW467984 B TW 467984B TW 86112460 A TW86112460 A TW 86112460A TW 86112460 A TW86112460 A TW 86112460A TW 467984 B TW467984 B TW 467984B
Authority
TW
Taiwan
Prior art keywords
polymer
solvent
synthetic leather
elastic
item
Prior art date
Application number
TW86112460A
Other languages
Chinese (zh)
Inventor
Shi-Chin Luo
Original Assignee
Feng Shern Entpr Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Feng Shern Entpr Co Ltd filed Critical Feng Shern Entpr Co Ltd
Priority to TW86112460A priority Critical patent/TW467984B/en
Application granted granted Critical
Publication of TW467984B publication Critical patent/TW467984B/en

Links

Landscapes

  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The present invention provides a method for producing an elastic synthetic leather, which mainly comprises forming a polymer on at least one face of a knitted substrate containing an elastic fiber, thereby endowing the product with a better elasticity and forming property.

Description

五、發明説明(1 ) 本發明傺與一種的合成皮之製成方法有關,更詳而言 之,特別是指一種製造簡單且具有較佳彈性及成型性之彈 性合成皮之製造方法。 按,習用一種合成皮之製造方法,主要是利用辊軋方· 式形成一皮膜層,再另外製造一编織層,且利用膠合熱壓 固結成一體。 經濟部中央標準局負工消費合作社印製 誠然,上述之合成皮已被各業界普遍應用,然在各項 應用中經常面臨三大問題點,那就是合成皮的加工性、舒 適性與耐用性,皆與天然皮革有相當程度的差距,這種情 形在製鞋工業上特别明顯;舉例來説,一般傅統的合成皮 在梆鞋過程中,因其不具有結構上的彈性,而較易在某些 受力點產生應力殘啻,特別是在直角或大角度彎曲時,常 會有凸角、皺折的倩況,因此,當製成鞋子成品時,加工 後之合成皮鞋面外觀即不如真皮製品美戡,再者,合成皮 革因其結構上的限制,在使用過程中產生過多之應力,使 其應力殘留部份極易因穿著時的曲折動作而破裂t故不如 真皮耐用,再者,傳統合成皮製成的鞋面,因其不具備有 結構上之彈性,所以在穿箸上便不如天然皮革製品般地具 有隨腳形調整其適合度,故亦不如真皮舒適。 且,以上述製造方法製成之合成皮,其製造程序並無 法以一貫作業完成t徒增製程上的麻煩。 有鑒於斯,本案發明人乃經詳思細索,並積多年從事 專業研究開發經驗,終而有本發明之誔生。 即,本發明之主要目的在於提供一種彈性合成皮之製 83. 3. 10,000 (谙先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐)V. Description of the invention (1) The present invention relates to a method for making synthetic leather, and more specifically, it refers to a method for manufacturing elastic synthetic leather that is simple to manufacture and has better elasticity and moldability. According to the practice, a synthetic leather manufacturing method is used, which mainly uses a rolling method to form a film layer, and then manufactures a braided layer, which is consolidated by gluing and hot pressing. It is true that the above-mentioned synthetic leather has been widely used in various industries by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives. However, it often faces three major problems in various applications, namely the processability, comfort and durability of synthetic leather. , Both have a considerable gap with natural leather, this situation is particularly obvious in the shoe industry; for example, the general Futong synthetic leather in the shoe lasting process, because it does not have structural elasticity, it is easier Stress residues occur at certain stress points, especially when bent at right angles or at large angles, often with convex corners and wrinkles. Therefore, when finished into finished shoes, the appearance of synthetic leather uppers after processing is not as good as Genuine leather products are beautiful. Furthermore, due to structural limitations, synthetic leather generates excessive stress during use, making the stress residues easily rupture due to tortuous movements during wearing. Therefore, it is not as durable as genuine leather. The upper made of traditional synthetic leather, because it does not have structural elasticity, so it is not as natural leather as it is to adjust its fit with the shape of the foot, so it is not Leather comfortable. Moreover, the manufacturing process of the synthetic leather made by the above-mentioned manufacturing method is not able to complete the trouble of the manufacturing process by a consistent operation. In view of this, the inventor of this case has pondered carefully and accumulated many years of professional research and development experience, and finally has the invention of this invention. That is, the main purpose of the present invention is to provide a system of elastic synthetic leather. 83. 3. 10,000 (谙 Please read the precautions on the back before filling in this page) This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm)

4679B A A7 B7 補充j 經濟部t央標準局員工消费合作社印製 五、發明説明(2) 适方法,傜應用簡單之製程,促使合成皮結構具有高度的 彈性,且能表現出高度之成型性、舒適性及耐磨性。 本發明之另一目的在於提供一種彈性合成皮之製造方 法,俗利用内含彈性纖維的針織基材與合成皮製造技術相 結合,促使高彈性合成皮具有製造容易之功效。 緣是,依據本發明所提供之一種彈性合成皮之製造方 法,俗在一針織基材至少其中一面形成有一高分子聚合體 ;其中,該針纗基材是以經緯圈替代以經緯纱交錯結合方 式織製而成,且在該針鎌基材僳在織造的過程中,混織有 彈性纖M,該彈性纖雒是以PU分裂面製成的彈性餓雒, 以包覆織法或裸織法所織成針織物,包覆法是彈性纗維的 外部包覆有一層聚酷餓維或尼龍缕維,該聚醋纖維外部亦 可再包覆一層天然纗維(或天然聚酯混合缕維),裸織法是 在未經包覆的倩況下,將彈性纖維和聚酯鐵維(或天然聚 酯混合纖維)直接在針織機上鏃製而成,而該高分子聚合 體,是將該高分子聚合物依特定比例溶於溶劑中而形成一 溶液,將此溶液至少彤成一次於該針織基材之至少其中一 面上,且在針織基材表面形成預定厚度;再將已塗佈完成 有高分子聚合體之針纈基材,含浸到含有一種溶劑和一種 非溶劑之配合液中,並留置一定時間,使得高分子聚合體 中之溶劑和配合液之非溶劑在内部產生置換作用,造成塗 怖層之高分子聚合體凝固並形成一開放式多微孔性結構; 繼之,用水清洗表面有凝固高分子聚合物之針雜基材殘餘 之溶劑,最後,施以乾燥步驟,卽可裂成一彈性合成皮。 (請先間讀背面之注項再填寫本頁) " 訂个· 本纸張尺度適用中國國家標準(CNS ) A4規格(210X297公釐〉 83. 3.10,000 •止 •止 m 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明(3) 有圈本發明所採用之技術、手段及其功效,玆舉二較 佳實施例並配合圖式詳細説明於后,相信本發明上述之目 的、構迪及特徴,當可由之得一深入而具體的瞭解。 圔式之簡單説明: 第一圔偽本發明一較佳實施例之製造流程示意圔。 第二圖你本發明另一較佳實施例之製造流程示意圈。 第三圔偽本發明上述較佳實施例之彈性合成皮結構示 意圖。 圖式中之參照號數: ίο...針織基材 (請先聞讀背面之注意事項再填寫本頁) 請配合參閲第一圖,本發明實施例彈性合成皮之製造 方法,主要是以塗覆方式(Coating)製成,包含下列製程 20.. .高分子聚合體 1.. .脱漿槽 4(5)...滾輪 7.. .凝固槽 9.. .烘乾裝置 U…槽 2A(2A')...軋輪 4A(4A’)...滾輸 SA...塗佈裝置 8A...水洗槽 2(3)...軋輪 6.. .塗佈裝置 8.. .水洗槽 3A...第一凝固槽 5Α(5ΑΊ ...滾輪 7Α...第二凝固槽 9Α...供乾裝置 本紙張尺度適用中國國家標隼(CNS ) A4規格(210X297公釐) 83. 3.10,0004679B A A7 B7 Complement j Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (2) Appropriate methods, using simple processes, promote the high elasticity of the synthetic leather structure, and can exhibit a high degree of moldability , Comfort and wear resistance. Another object of the present invention is to provide a method for manufacturing elastic synthetic leather, which conventionally utilizes a knitted substrate containing elastic fibers and a synthetic leather manufacturing technology, so as to promote easy manufacturing of highly elastic synthetic leather. The reason is that, according to a method for manufacturing an elastic synthetic leather provided by the present invention, a high molecular polymer is generally formed on at least one side of a knitted base material; wherein the needle base material is replaced by warp and weft loops and warp and weft yarns are staggered and combined. Weaving method, and during the weaving process of the needle sickle base material, an elastic fiber M is woven, and the elastic fiber material is an elastic fiber made of a PU split surface, which is covered with a weaving method or bare. Knitting fabric made by weaving. The covering method is that the outer part of the elastic fiber is covered with a layer of polyurethane or nylon. The polyester fiber can also be covered with a layer of natural fiber (or a mixture of natural polyester). Stranding), naked weaving method is made by elastic fiber and polyester iron (or natural polyester mixed fiber) directly on the knitting machine under uncovered conditions, and the polymer is Is to dissolve the high-molecular polymer in a solvent according to a specific ratio to form a solution, and to form the solution at least once on at least one side of the knitted substrate, and form a predetermined thickness on the surface of the knitted substrate; Has been coated with a polymer The Val substrate is impregnated in a complex solution containing a solvent and a non-solvent, and is left for a certain period of time, so that the solvent in the polymer polymer and the non-solvent of the complex solution have an internal displacement effect, resulting in a polymer coating layer. The polymer solidifies and forms an open microporous structure. Next, the solvent remaining on the surface of the solid substrate of the solidified polymer is washed with water, and finally, a drying step is performed to crack into an elastic synthetic leather. (Please read the note on the back before filling out this page) " Order · This paper size applies to China National Standard (CNS) A4 specification (210X297 mm> 83. 3.10,000 • Only • Only m Central Printed by the Consumer Bureau of Standards Bureau A7 B7 V. Description of the invention (3) The technology, methods and effects of the present invention are circled. Two preferred embodiments are described in detail below with the help of the drawings. I believe the above of the present invention The purpose, construction, and special features of the present invention can be obtained through a deep and specific understanding. Brief description of the formula: The first is a schematic illustration of the manufacturing process of a preferred embodiment of the present invention. The second picture shows another aspect of the present invention. The manufacturing process of the preferred embodiment is schematically illustrated. The third is a schematic diagram of the elastic synthetic leather structure of the above-mentioned preferred embodiment of the present invention. The reference number in the figure: knitting substrate (please read the back first Please fill in this page again) Please refer to the first figure. The manufacturing method of the elastic synthetic leather according to the embodiment of the present invention is mainly made by coating, and includes the following processes: .. Desizing tank 4 (5) ... roll 7 .. Freezing tank 9. Drying device U ... Tank 2A (2A ') ... Roller 4A (4A') ... Rolling SA ... Coating device 8A ... Washing tank 2 (3) ... Roller 6 ... Coating device 8 ... Water washing tank 3A ... First coagulation tank 5A (5ΑΊ ... Roller 7Α ... Second coagulation tank 9Α ... For drying The paper size of this device is applicable to China National Standard (CNS) A4 (210X297 mm) 83. 3.10,000

經濟部中央標準局貝工消費合作社印製 (1) 準備一種以經緯圈替代以經緯纱交錯結合方式織 製之針織基材10,該針雜基材10可採用包覆織法或裸織法 織成針織物,包覆法是彈性纖維的外部包覆有一層聚酯縝 維或尼龍纖維,該聚酷纖維外部亦可再包覆一層天然纗維 (或天然聚酯混合纖維),裸織法是在未經包覆的情況下, 將彈性纖維和聚酯纖維(或天然聚酷混合缴維)直接在針織 機上織製而成,且當以裸織法織成具彈性之針織基材10時 ,該針織基材10是由一 70丹尼的聚酯纖維和一 70丹尼的S 撚聚醋纖雒加上一 70丹尼的彈性鐵維雜製而成,該彈性_ 維是以PU分裂面製成的彈性纖維。 (2) 針戡基材10先經過一脱漿槽1,俾將針織基材10 中少量之漿予以脱除〇 (3) 脱漿後之針織基材10經過軋輪2、3滾軋而將水份 擠出;再經過具有加熱功能之滾輪4、5滾軋,且其加熱溫 度為100〜150XJ,俥將剩餘之水份烫乾並锼平,使得針鍇 基材10内之水份含量約為10%左右。 (4) 乾、捷平之針锇基材10經過一塗佈裝置6,且 如第三圖所示,傲將一高分子聚合睡20塗附在針織基材10 表面,並形成有預定厚度,該高分子聚合體20是利用高分 子聚合物依特定比例溶於溶劑中而形成一溶液,其中,該 高分子聚合物為一液型PU,最好是由軟質段與硬質段相 間排列之序列式結構構成線形結構,而該高分子聚合物溶 劑為二甲基甲酿按(Dimethyl Formamide簡稱DM F), (請先閎讀背面之注意事項再填寫本頁) ." 訂卜 本紙張尺度逋用中國國家標準(CNS ) A4规格(210X297公釐) —6 — 83. 3.10,000 d67984 A7 B7 早 經濟部中央標準局員工消費合作社印製 五、發明説明(5 ) 且該高分子聚合物比例為4.8〜11.4% ,而溶劑比例為95. 2〜57.1%,且可依皮質需要而添加木質鐵維素0〜11.4% 、陽離子界面活性劑0〜2.9%、陰離子界面活性劑0〜2. 9郏、色料0〜11.4%、水0〜2.9%。 (5) 將被覆有高分子聚合體20之針織基材10輸送至内 部裝有配合液之一凝固槽7中,歴時約5〜10分,該配合液 之成份為溶劑(DM F>和非溶劑(為水),溶劑之份量可從 0〜30%,而非溶劑佔大部份(溶剤之份童可為0),俥當被 覆有高分子聚合艟20之針織基材10通過凝固槽7時,利用 水與溶剤(DMF)之相溶特性,使得高分子聚合體20中之 溶劑和配合液之非溶劑會在内部產生置換作用(combined action),亦即高分子聚合體20中之溶劑(DMF)自内部 釋出且溶於非溶劑(水)中,而溶劑(D M F )釋出後所形成 之空間會由非溶劑(水)填入,即可造成塗佈層之高分子聚 合體20凝固並形成一開故式多微孔性結構,其撖孔直徑介 於18〜80 mm之間,此一凝固過程中可將凝固槽恆定溫度 控制在25〜30¾之間,如此可使成品維持最佳彈性。 (6) 將由凝固槽7輸出之被覆有高分子聚合體20之針 織基材10進入一水洗槽8,水洗槽8内為非溶劑之水,其作 用為洗去殘留於針織基材10上之溶劑。 (7>將由水洗槽8輸出之被覆有高分子聚合體20之針 織基材10進入一烘乾裝置9,以進行乾燥。 (8)製成彈性合成皮。 再如第二圄所示,葆為本發明另一實施例,像以浸漬 <請先閱讀背面之注意事項再填寫本頁)Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Shelley Consumer Cooperative (1) Prepare a knitted base material 10 with warp and weft loops instead of weaving warp and weft yarns. The needle base material 10 can be covered or bare Woven into a knitted fabric, the covering method is that the outer part of the elastic fiber is covered with a layer of polyester fiber or nylon fiber, and the outer layer of the cool fiber can also be covered with a layer of natural fiber (or natural polyester mixed fiber). The method is to woven an elastic fiber and a polyester fiber (or a natural polyurethane mixed divisor) directly on a knitting machine without covering, and when the bare knitting method is used to form an elastic knitted base Material 10, the knitted base material 10 is made of a 70 denier polyester fiber and a 70 denier S-twisted polyester fiber plus a 70 denier elastic iron fiber. The elasticity It is an elastic fiber made of PU split surface. (2) The needle-punched base material 10 first passes through a desizing tank 1, and a small amount of pulp in the knitted base material 10 is removed. (3) The desizing knitted base material 10 is rolled by rolling wheels 2, 3, and Squeeze out the water; then roll through the rollers 4 and 5 with heating function, and the heating temperature is 100 ~ 150XJ, 烫 iron the remaining water and flatten it, so that the water in the needle base material 10 The content is about 10%. (4) The dry and flat needle-knitting base material 10 passes through a coating device 6 and, as shown in the third figure, a high molecular polymer sleep 20 is coated on the surface of the knitted base material 10 and formed into a predetermined thickness. The polymer 20 is formed by dissolving a polymer in a solvent at a specific ratio to form a solution. The polymer is a liquid PU, preferably a sequence in which soft segments and hard segments are arranged in phase. The formula structure forms a linear structure, and the polymer solvent is dimethyl formamide (DM F), (please read the precautions on the back before filling this page). &Quot;逋 Use Chinese National Standard (CNS) A4 specification (210X297 mm) — 6 — 83. 3.10,000 d67984 A7 B7 Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Early Economic Affairs 5. Description of the invention (5) and the polymer The ratio is 4.8 ~ 11.4%, and the solvent ratio is 95.2 ~ 57.1%, and lignoflavin 0 ~ 11.4%, cationic surfactant 0 ~ 2.9%, and anionic surfactant 0 ~ 2 can be added according to the needs of the cortex. . 9 郏, pigment 0 ~ 11.4%, water 0 ~ 2.9%. (5) The knitted base material 10 covered with the polymer polymer 20 is transported to a coagulation tank 7 containing a compounding liquid for about 5 to 10 minutes, and the composition of the compounding liquid is a solvent (DM F > and Non-solvent (for water), the amount of solvent can be from 0 to 30%, and most of the non-solvent (the amount of solvent can be 0), when the knitted substrate 10 coated with high molecular polymer 20 is solidified In tank 7, the compatibility between water and solvent soluble (DMF) is used, so that the solvent in the polymer polymer 20 and the non-solvent of the complex solution will have a combined action inside, that is, the polymer polymer 20 The solvent (DMF) is released from the inside and is dissolved in non-solvent (water), and the space formed after the solvent (DMF) is released will be filled by the non-solvent (water), which can cause the polymer of the coating layer The polymer 20 solidifies and forms an open-type micro-porous structure. The diameter of the pores is between 18 and 80 mm. During this solidification process, the constant temperature of the solidification tank can be controlled between 25 and 30¾. Maintain the best elasticity of the finished product. (6) Needle coated with polymer 20 that is output from the solidification tank 7 The woven substrate 10 enters a water-washing tank 8, and the non-solvent water in the water-washing tank 8 is used to wash away the solvent remaining on the knitted substrate 10. (7 > The polymer discharged from the water-washing tank 8 is covered with a polymer The knitted base material 10 of 20 enters into a drying device 9 for drying. (8) Made of elastic synthetic leather. As shown in the second item, the example is another embodiment of the present invention. (Read the notes on the back and fill out this page)

'T 訂-_ 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 83. 3.10,000 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明(6 ) 方式(Dipping)後再配合塗覆方式(Coating)製成,其製程 為:當針織基材10進入一槽1A,並含浸高分子聚合物配合 液,接著,針織基材10隨即通過軋輪2A、2A’滾軋,如此 可控制基材上含浸配合液之厚度,並使多餘之配合液流回 槽1A中,隨後含浸配合液之針織基材10進入第一凝固棰3A 中,使其凝固並形成一開放式多微孔性結構,再經過滾輪 4A、4A’滾軋將多餘水份擠出,又經過具有加熱功能之滾 輪5A、5A’,俥將剩餘之水份烫乾並燙平,使得針織基材1 0内之水份含量約為5〜10%,然後,表面凝固有配合液之 針織基材10通過一塗佈裝置6A,俥在其上塗上第二層配合 液,其中第一層和第二層含浸、塗佈上去之樹脂可為相同 或不同之樹脂,隨後,再經第二凝固槽7A凝固、水洗槽8A 水洗、烘乾装置9A烘乾,亦可形成另一種彈性合成皮。 藉由以上所述之二實施例説明可知,本發明之彈性合 成皮,係可利用一貫作業方式製程,製程完整,且因其基 材結構中含有彈性餓維之作用,而可表現出和莫皮裡層極 為近似的結構彈性,當其受力拉引,可以完全伸張,在拉 力消失時,又可迅速的回復到受力前的狀態,使得應用本 發明之彈性合成皮加工製成的產品,不會因使用者的使用 而容易產生變形,也因此提高了其成形性及耐用性,且該 彈性皮可依使用者之需求而作不同之處理,使其具有不同 之外觀,例如磨面皮、小牛皮、鏡面皮...等等,亦可再 進一步加工使其表面及花色符合使用者之需求,例如: (1)以研磨物質處理基材表面,而得到磨面皮效果〇 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 83. 3.10,000 :------‘衣-- (請先閲讀背面之注意事項再填寫本頁) 訂-,,Γ > 46^984 ,. 修正; A7 i年月1 1 B7 補充丨 五、發明説明(7 ) (2) 印刷所要之花樣及顔色。 (3) 塗佈或轉寫PU薄膜,或有色聚合物膜到合成皮 上而得到想要之表皮效果。 (4) 以凹販或凸販輪將預定花紋壓印在合成皮上,.而 獲得所需之皮感。 另外,在合成皮製成中,各流程之配合事項為: 1. 第一實施例之凝固槽7,最好的張力是控制在lkg /cm2以下,且塗佈層窿避免和惰輪接觸,因在塗佈層上未 完全凝固,通遇的塗佈層結構會被擠壓而造成結構上的彈 性降低。 2. 當被覆有高分子聚合體20之針鏰基材10输送至内部 凝固槽7中後,其上所塗佈之高分子聚合體20也已凝結, 當再進入水洗槽8時,可利用非溶劑將尚殘留在塗佈層多 孔結構中之溶劑洗淨,如此才完成全部凝固過程。 3. 在進入烘乾裝置9進行乾燥時,可調整至預定溫度 ,使得可以烘乾完全,而又不傷害產品(溫度上限為150Τ )〇 4. 經烘乾後,產品是由捲取輪捲取。 藉由以上之説明可知,利用本發明製造方法所製成之 彈性合成皮不僅具有較佳之彈性、成塱性、舒適性及耐磨 性,且極具有產業上利用價值。 綜上所逑,本發明在同類產品中實有其極佳之進步實 用性,同時遍查國内外關於此類結構之技術資料、文獻中 亦未發現有相同的技術手段存在在先,是以,本發明實已 本紙乐尺度適用中國國家標隼(CNS ) A4規格(210X297公釐) ---^------,.裝-- (請先聞讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印製 83. 3.10,000 A7 B7 正 五、發明説明(8) 具備發明專利要件,爰依法提出申請。 唯,以上所述者,僅係本發明之較佳可行實施例而已 ,故舉凡應用本發明説明書及申請專利範圍所為之等效結 構變化,理應包含在本發明之專利範圍内。 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印装 本紙張尺度適用中國國家標準(CNS ) A4规格(210X297公釐) —10, S3. 3.10,000'T Order-_ This paper size is applicable to Chinese National Standard (CNS) A4 (210X297 mm) 83. 3.10,000 Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of Invention (6) Method (Dipping) It is then made with a coating method. The process is as follows: when the knitted substrate 10 enters a slot 1A, and is impregnated with a polymer polymer compound solution, the knitted substrate 10 is then rolled through the rollers 2A, 2A '. Rolling, so as to control the thickness of the impregnated compound solution on the substrate, and allow the excess compound solution to flow back into the groove 1A, and then the knitted substrate 10 impregnated with the compound solution enters the first solidification 棰 3A, so that it solidifies and forms an opening Type microporous structure, and then the rollers 4A, 4A 'roll to squeeze out the excess water, and then through the heating function rollers 5A, 5A', the remaining water is ironed and ironed, so that the knitted base The moisture content in the material 10 is about 5 to 10%. Then, the knitting substrate 10 with the compounding liquid solidified on the surface is passed through a coating device 6A, and a second layer of the compounding liquid is applied thereon. The second layer of impregnated and coated resin can be the same or different Resin, then re-solidified 7A through the second coagulating bath, water washing tank 8A, 9A drying device drying, may also be formed of another elastic synthetic leather. According to the description of the two embodiments described above, it can be known that the elastic synthetic leather of the present invention can be processed by a consistent operation method, the process is complete, and because its base structure contains the effect of elasticity, it can show harmony The skin layer has a very similar structural elasticity. When it is pulled by force, it can be fully stretched. When the tensile force disappears, it can quickly return to the state before the force. This makes the product manufactured by applying the elastic synthetic leather of the present invention. , It will not be easily deformed due to the use of the user, and therefore its formability and durability are improved, and the elastic leather can be treated differently according to the needs of the user, so that it has a different appearance, such as nubuck leather , Calfskin, mirror leather, etc., can be further processed to make the surface and color match the user's needs, such as: (1) the surface of the substrate is treated with abrasive material, and the effect of grinding leather is obtained. Applicable to China National Standard (CNS) A4 specification (210X297 mm) 83. 3.10,000: ------ 'clothing-(Please read the precautions on the back before filling this page) Order-,, Γ > 46 ^ 984,. Repair ; A7 i 1 1 B7 date added Shu V. Description of the Invention and color patterns (7) (2) to the printing. (3) Apply or transfer PU film or colored polymer film to synthetic leather to get the desired skin effect. (4) Embossing a predetermined pattern on the synthetic leather with a concave or convex wheel to obtain the desired skin feel. In addition, in the production of synthetic leather, the cooperation of each process is as follows: 1. The coagulation tank 7 of the first embodiment, the best tension is controlled below 1kg / cm2, and the coating layer 窿 avoids contact with the idler. Because the coating layer is not completely solidified, the structure of the coating layer encountered will be squeezed and the elasticity of the structure will be reduced. 2. After the needle-wound base material 10 covered with the polymer polymer 20 is transported to the internal solidification tank 7, the polymer polymer 20 coated thereon has also coagulated. When it enters the water washing tank 8 again, it can be used The non-solvent cleans the solvent remaining in the porous structure of the coating layer, thus completing the entire solidification process. 3. When entering the drying device 9 for drying, it can be adjusted to a predetermined temperature so that it can be completely dried without harming the product (the upper temperature limit is 150T). 4. After drying, the product is wound by a take-up roll. take. From the above description, it can be known that the elastic synthetic leather made by the manufacturing method of the present invention not only has better elasticity, scourability, comfort and abrasion resistance, but also has great industrial application value. In summary, the present invention has excellent progress and practicality among similar products. At the same time, it has not been found in the literature that the same technical means existed in the literature at home and abroad. The present invention has been adapted to the Chinese National Standard (CNS) A4 specification (210X297 mm) in this paper. --- ^ ------, .---- Please read the precautions on the back before filling in this Page) Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 83. 3.10,000 A7 B7 Form V. Description of Invention (8) With the requirements for invention patents, apply in accordance with the law. However, the above are only the preferred and feasible embodiments of the present invention. Therefore, any equivalent structural changes made by applying the description of the present invention and the scope of patent application should be included in the patent scope of the present invention. (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs This paper is sized for China National Standard (CNS) A4 (210X297 mm) — 10, S3. 3.10,000

Claims (1)

467984 公 资 令;467984 public order; mju 經濟部中央標隼局員工消費合作社印製 六、申請專利範圍 1. 一種彈性合成皮之製迪方法,其步驟包含: 一、 準備一種以經緯圈替代以經縴纱交錯結合方式雜 製之針織基材,該針雜基材中必須含有彈性餓維; 二、 準備一種高分子聚合物,將此聚合物依特定比例 溶於溶劑中而形成一溶液,將此溶液至少形成一次於該針 織基材之至少其中一面上,且在針雜基材表面形成一高分 子聚合體; 三、 將已塗佈完成有高分子聚合腥之針鍇基材,浸泡 到含有一種溶劑和一種非溶劑之配合液中,促使該高分子 聚合體中之溶劑與配合液之非溶劑在内部產生置換作用, 且高分子聚合體中之溶劑與配合液之非溶劑交換後,會在 高分子聚合體中形成開放式多微孔性結構,且直到凝固為 止; 四、 用水清洗表面有凝固高分子聚合物之針織基材; 五、 乾燥; 藉由以上各步驟,卽可製成一彈性合成皮。 2. 依據申諸專利範圍第1項所逑之彈性合成皮之製造 方法,其中該針織基树葆在織造的過程中,混雜有彈性餓 維,該彈性纗維是以PU分裂面製成的彈性繼維,用包覆 法或裸雜法鑼製而成。 3. 依據申諳專利範圍第2項所述之彈性合成皮之製造 方法,其中該彈性纖維外部包覆有一聚酯纖維,該聚酯缕 維外部可再包覆一層天然雜維或天然聚酯混合鑛維。 4. 依據申請專利範圍第3項所述之彈性合成皮之製造 衣紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 一 11; (請先間讀背面之注意事項再填寫本貫) .訂Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 6. Scope of Patent Application 1. A method for making elastic synthetic leather, the steps include: 1. Prepare a hybrid made of warp and weft instead of warp-fiber yarns. Knitted base material, the needle base material must contain elasticity; 2. Prepare a high molecular polymer, dissolve this polymer in a solvent at a specific ratio to form a solution, and form this solution at least once in the knitting At least one side of the substrate, and a polymer polymer is formed on the surface of the needle substrate; 3. Soak the needle-coated substrate that has been coated with the polymer polymer, and soak it in a solvent containing a solvent and a non-solvent. In the compound liquid, the solvent in the polymer polymer and the non-solvent of the compound liquid are caused to replace internally, and after the solvent in the polymer polymer is exchanged with the non-solvent of the compound liquid, it will form in the polymer polymer. Open microporous structure, until solidification; 4. Wash the knitted substrate with solidified polymer on the surface with water; 5. Dry; Each of the above steps can be made of a resilient synthetic leather calipering. 2. The elastic synthetic leather manufacturing method according to item 1 of the claimed patent scope, wherein the knitted base tree cymbal is mixed with an elastic dimension during weaving, and the elastic dimensional is made of a PU split surface Elastic follow-up, made by coating method or bare hybrid method. 3. The manufacturing method of elastic synthetic leather according to item 2 of the patent claim, wherein the elastic fiber is covered with a polyester fiber on the outside, and the polyester strands may be further covered with a layer of natural hetero-dimensional or natural polyester. Mixed mine dimension. 4. According to the scope of the patent application, item 3 of the elastic synthetic leather manufacturing paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm)-11; (Please read the precautions on the back before filling in this document ) Order 46 7984 έ! C8 ________ D8 六、申請專利範圍 方法,其中該彈性纖維外部所包覆纖雜可為;gu缕,維c 5. 依據申請専利範圍第1項所逑之彈性合成皮之製迪 方法,其中該高分子聚合物為一液型Ρϋ,且可由軟質段 與硬質段柑間排列之序列式結構構成線形結構。 6. 依據申請專利範圍笫1項所述之彈性合成皮之製造 方法,其中該高分子聚合物溶劑為二甲基甲醯胺(Dimethyl F ο πβ a m i d e 簡稱 D M F )。 7. 依據申請專利範圍第1項所述之彈性合成皮之製造 方法,其中該高分子聚合物之非溶劑為水。 8. 依據申請專利範圍第1項所述之彈性合成皮之製造 方法,其中形成溶液之高分子聚合物比例為4.8〜11.4% ,而溶劑比例為95.2〜57.1%,另外可依需要而添加木質 繼維素0〜11.4% 、陽離子界面活性劑〇〜2.9%、陰離子 界面活性劑0〜2.9%、色料0〜11.4%、水〇〜2.9%。 經濟部中央標準局負工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) Α4規格(210 X 297公釐) 一丄 2 一:"46 7984 !! C8 ________ D8 VI. Method of applying for patent scope, where the elastic fibers covered by the elastic fiber can be: gu strand, dimension c 5. According to the application of the elastic synthetic leather in item 1 of the application scope In the method, the high-molecular polymer is a liquid type PZ, and a linear structure can be formed by a sequential structure arranged between a soft segment and a hard segment. 6. The method for manufacturing an elastic synthetic leather according to item 1 of the scope of the patent application, wherein the polymer solvent is dimethyl formamide (Dimethyl F ο πβ a m i d e is abbreviated as D M F). 7. The method for manufacturing an elastic synthetic leather according to item 1 of the scope of patent application, wherein the non-solvent of the high molecular polymer is water. 8. According to the manufacturing method of the elastic synthetic leather described in item 1 of the scope of the patent application, wherein the proportion of the polymer forming the solution is 4.8 to 11.4%, and the proportion of the solvent is 95.2 to 57.1%. In addition, wood can be added as required Following vitamins 0 to 11.4%, cationic surfactants 0 to 2.9%, anionic surfactants 0 to 2.9%, colorants 0 to 11.4%, and water 0 to 2.9%. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs This paper is sized to the Chinese National Standard (CNS) Α4 (210 X 297 mm) 1 2 2: "
TW86112460A 1997-08-30 1997-08-30 Method for producing elastic synthetic leather TW467984B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
TW86112460A TW467984B (en) 1997-08-30 1997-08-30 Method for producing elastic synthetic leather

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW86112460A TW467984B (en) 1997-08-30 1997-08-30 Method for producing elastic synthetic leather

Publications (1)

Publication Number Publication Date
TW467984B true TW467984B (en) 2001-12-11

Family

ID=21626944

Family Applications (1)

Application Number Title Priority Date Filing Date
TW86112460A TW467984B (en) 1997-08-30 1997-08-30 Method for producing elastic synthetic leather

Country Status (1)

Country Link
TW (1) TW467984B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6773752B2 (en) * 2002-10-30 2004-08-10 Feng Shern Enterprise Co., Ltd. Method for making synthetic leather

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6773752B2 (en) * 2002-10-30 2004-08-10 Feng Shern Enterprise Co., Ltd. Method for making synthetic leather

Similar Documents

Publication Publication Date Title
CN110093788A (en) A kind of preparation method of double-sided plush artificial leather
KR100974443B1 (en) Wrinkled double textiles and Method for manufacturing the same
TW467984B (en) Method for producing elastic synthetic leather
JP3034120B2 (en) Artificial leather with elasticity
KR100700627B1 (en) Fabricating method of artificial leather using knit
KR101152380B1 (en) Synthetic Leather Manufacturing Method having a Air Permeability
JPS6350580A (en) Production of leather-like material having grain texture
KR100962324B1 (en) Process Of Producing Circular Knit Type Base Fabric For Artificial Leather
KR20080042309A (en) Coating resin for the waterproof and breathable, a dry-typed non-porous fabric using thereof and a method of preparing the same
KR100513964B1 (en) A method of manufacturing an irregular wrinkled textile fabric and a textile fabric manufactured by thereof
JP4002102B2 (en) High stretch dyed nonwoven fabric and method for producing the same
JP2004332173A (en) Method for producing artificial leather
KR100997120B1 (en) A surface treatment method for artificial leathers, and artificial leathers having the surface treated by the same
JPH11256484A (en) Production of lustered flock-implanted sheet
KR20180028995A (en) Vintage fabric
KR20080010484A (en) Manufacturing method of artificial leather having cutting fiber and artificial leather using the same
KR100465590B1 (en) Method for producing suede-like fabric with pattern
JPS5947072B2 (en) Manufacturing method of fiber sheet
JP4110800B2 (en) Artificial leather excellent in warp direction stretchability and manufacturing method thereof
KR101756877B1 (en) A method of processing a feeling of washing on leather fabrics and leather fabrics manufactured thereby
JPH0120273B2 (en)
JPH11117181A (en) Production of synthetic leather
JPS6242076B2 (en)
JPS6075683A (en) Water-repellent and oil-repellent artificial leather having highly entangled layer
CN1316118C (en) Artificial leather and manufacturing process thereof