經濟部中央標準局負工消费合作杜印製 460562 A7 _____B7_ 五、發明説明（1 ) 本發明係有關一種無機反應生成物，即，具有耐火性 之耐火液及其製造方法，以及使用此耐火液之耐火材、耐 火建材及耐火性粘著劑。特別是有關一種能作爲建築材料 ’或門、桌子、椅子等製造家倶之部材，或冰箱、電視等 家電製品之外框或包裝材料等的耐火材，以及不僅具有耐 火性’而且具有優良隔音性、隔熱性之建材與具有優良耐 火性的粘著劑。 目前，已知市面上有無機材料反應而成的耐火複合材 (曰本特開平1 — 314157號）。另外，目前已知的 能作爲建築物內部裝璜及外觀之具有優良耐火性的材料有 1磚、石棉、礦棉等。而具有優良隔音性之材料有，發泡 合成樹脂、纖維板、石棉、礦棉等，又，已知的耐火性粘 著劑有水玻璃。 但，上述目前的耐火複合材除了使用之材料複雜分歧 外，其生成反應中會產生有害氣體》 . / 另外，目前之具有優良耐火性的材料之隔意性較差， 而隔音性較優良之材料則有耐火耐差的問題存在。至於同 時具有優良的耐火性及隔音性的石棉、礦棉，因其粉塵對 健康有不良影響，故限制使用。至於目前尙未出現一種適 用於形成建材用盡積材之具有耐火性的粘著劑。 又，目前作爲各種內外裝璜材料的合成樹脂除了耐火 性極差外，燃燒時會產生有毒氣體，故不適用於住宅建設 材料。 至於建築物結構體所廣泛使用的混凝土、鋼筋、鐵架 本紙張尺度適用中國國家揉準（CNS ) Α4規格（2丨〇 X 2<>7公釐）-4 - (請先閱讀背面之注意事項再填寫本頁) •裝DuPont Printing 460562 A7, Central Standards Bureau, Ministry of Economic Affairs, Du Printing 460562 A7 _____B7_ V. Description of the Invention (1) The present invention relates to an inorganic reaction product, that is, a refractory liquid with fire resistance and a manufacturing method thereof, and the use of the refractory liquid Refractories, refractory building materials and refractory adhesives. In particular, it relates to a refractory material that can be used as a building material or a door, table, chair and other furniture manufacturing materials, or an outer frame or packaging material of household appliances such as refrigerators and televisions, and has not only fire resistance but also excellent sound insulation 、 Heat-insulating building materials and adhesives with excellent fire resistance. Currently, there are known on the market refractory composite materials made of inorganic materials (Japanese Patent Publication No. 1-314157). In addition, currently known materials that have excellent fire resistance as the interior decoration and appearance of buildings include bricks, asbestos, mineral wool, and the like. Examples of materials having excellent sound insulation properties include foamed synthetic resins, fiberboards, asbestos, mineral wool, and the like, and known fire resistant adhesives include water glass. However, in addition to the complicated differences in the materials used in the above-mentioned current refractory composites, harmful gases are generated in the formation reaction. / In addition, the current materials with excellent fire resistance have poor barrier properties and materials with excellent sound insulation. Then there is the problem of poor fire resistance. Asbestos and mineral wool, which also have excellent fire resistance and sound insulation, are restricted in use because their dust has adverse effects on health. As yet, there is no fire-resistant adhesive suitable for forming exhausted building materials. In addition, synthetic resins, which are currently used as various interior and exterior decoration materials, have extremely poor fire resistance and generate toxic gases during combustion. Therefore, they are not suitable for residential construction materials. As for the widely used concrete, steel and iron frames of building structures, the paper size is applicable to the Chinese National Standard (CNS) Α4 specification (2 丨 〇X 2 < > 7mm) -4-(Please read the (Please fill in this page again)
，1T 經濟部中央標準局員工消費合作社印裝 460562 A7 ___B7五、發明説明（2 ) 等’於火災時會有急速降低其強度之問題存在。而目前之 各種粘著劑或密封劑等亦有耐火性差之問題。 而且至今尙未有一種具有優良耐火性、隔熱性、隔音 性之，具有一定強度且適用於切斷等加工過程之，不僅能 作爲建築材料，亦適用爲製造內、桌子、椅子等傢俱之部 材及冰箱、電視機等家電製品之外框，且可取代瓦楞紙、 發泡苯乙烯等成爲包裝用材料等之適用於各種用途的耐火 材提案。 因此，本發明利用氫氧化鉀、碳酸鈉、金屬矽及水起 反應，而得到的水溶性耐火液可解決上述各項問題。 即，本發明之耐火液係由氫氧化鉀、碳酸鈉、金屬矽 及水起反應而生成的耐火液。而所使用的氫氧化鉀爲粘末 狀或粒狀，碳酸鈉亦爲粉末狀或粒狀，至於金屬矽則爲塊 狀。又，此耐火液爲•將粉末狀或粒狀之氫氧化鉀投入反 應槽內後，再依序投入粉末狀或粒狀之碳酸鈉及金屬矽塊 ，最後投入水而於反應槽內自然起反應所生成之物。此生 成反應所需時間爲2小時〜1 0小時。若供給反應之氫氧 化鉀等之量較少時，其反應時間較短，又，氫氧化鉀等之 量較多時，爲了生成耐火液所需的反應時間會較長。若供 應給反應之水爲4 0°C至5 0°C之溫水時，可縮短反應時 間。 上述所使用之碳酸鈉又以碳酸鈉的酸酐（俗稱「碱灰 」）較佳。又，所使用之粉末狀或粒狀的氫氧化鉀、扮末 狀或粒狀之碳酸鈉的酸酐（碱灰）及塊狀之金屬矽均可爲 L.---------¾.-----:—訂.------'線 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用令國國家梂準（〇阳）六4規格（2丨0；<297公釐）-5 - A60562 經濟部中央標隼局員工消费合作社印裝 A7 _B7___五、發明説明（3 ) 市售之物。即，市售的粉末狀或粒狀之氫氧化鉀、碳酸鈉 酸酐（碱灰）及市售的塊狀金屬矽均可使用於本發明’至 於粉末、粒或塊的大小（直徑等）並無特別限制。 如上述般，本發明之耐火液係由粉末狀或粒狀之氫氧 化鉀、粉末狀或粒狀之碳酸鈉、金屬矽塊及水反應2〜 1 0小時時所生成。而反應時之溫度爲6 0°C〜9 0°C。 因生成之耐火液爲水溶性，故可利用供給反應之水量自由 調節所生成的耐火液濃度。 例如，單獨以此耐火液形成耐火層時，耐火液之濃度 需較大，因此，所供應之水量（重量）例如對氫氧化鉀及 碳酸鈉之重量總和較佳爲4倍左右。雖然以比前述較少之 水量，例如2 . 5倍之水量亦能得到濃度極大的耐火液。 但|此情形下將無法順利的進行耐火液生成反應，故此水 量不佳。 另外，若單獨塗布或吹附生成之耐火液時，此耐火液 濃度需較小，因此，所供應之水量（重量）例如對氫氧化 鉀及碳酸鈉的重量總和較佳爲4.4倍左右。當然亦可增 加少量，例如使用耐火液與油漆等塗布材料之混合物時， 所供應之水量（重量）對氫氧化鉀及碳酸鈉的重量總和可 爲4 . 7倍左右。但，當耐火液濃度過小時會降低耐火性 ，因此，所供應之水量（重量）對氫氧化鉀及碳酸鈉的重 量總和較佳爲控制於4.7倍左右。 又，將焦炭（1 0重量％程度）加入上述耐火液時， 可於塗布乾燥後生成光沢的被膜。 !τ----------裝------訂------線 - (請先閱讀背面之注意事項再域寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4現格（210X 297公釐> -6 - 經濟部中央標準局員工消費合作社印裝 A7 __ B7五、發明説明（4 ) 若將酪蛋白（1〜1 0重量％)加入上述耐火液時， 此耐火液將難溶於水。又1添加1 0重量％左右之焦炭及 1 0重量％左右之氟時，亦能使耐水液難溶於水。 另外，本發明係提供一種耐火材及其製造方法，其特 徵爲，使上述耐火液與紙類、稻殼、纖維質材料、木材片 、鋸屑（大鋸屑）中任何一種或多種混合後，再加壓使其 成型。 至於上述之耐火液與其他材料的混合比率較佳爲，耐 火液5〜1 5重量％，其他8 5〜9 5重量％ »若耐火液 之比率少於5重量％時，將會減少耐火性，又，耐火液比 率超過1 5重量％時，耐火性不會有太大變化，故就成本 對效果觀點 > 特別是紙類、稻殼、纖維質材料、木材片、 鋸屑（大鋸屑）般，產業上無法適用於其他之有效利用方 法的特殊部材之觀點下，耐火液比率較佳爲1 5重量％以 下。 又，如上述般將紙類、稻殼及纖維質材料混入耐火液 中以作爲耐火材時，其間混合比率較佳爲，耐火液5〜 15重量％、紙類75〜85重量％、稻殼3〜7重量％ 、纖維質材料3〜7重量％。至於耐火液比率較佳爲5〜 1 5重量％之理由如上述般。若紙類之混合比率少於7 5 重量％時，會減少製品之耐火材的柔軟性，故此比率不佳 。又，超過8 5重量％時會減少耐火性，故此比率亦不佳 。若稻殻之混合比率少於3重量％時，會減少製品之耐火 材的彈性，又，超過7重量％時會造成彈性過強，故兩比 本紙伕尺度適用t國國家標準（CNS ) Α4規格（210X 297公釐） ~ ----------參------ΐτ------.^ *h (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印衷 460562 A7 _____B7_ 五、發明説明（5 ) 率値均不宜1。若纖維質材料之混合比率少於3重量％時 ，會減少製品之耐火材的耐火性及柔軟性，又，超過7重 量％時會造成柔軟性過強，故兩比率値均不佳。 另外，僅於耐火液（5〜15重量％)中混合紙類（ 8 5〜9 5重量％ )時’亦可製成耐火材。但，同時混合 稻殼時，因稻殼所含的二氧化矽成分（矽（S i )成分） 能混入耐火材生成過程中，故可增加製品之耐火材的耐火 性及耐水性，又，可週整製品之耐火材的柔軟性而爲佳。 另外，混入纖維質材料之目的爲•除了可減少製品之耐火 材於燃燒時所產生的煙外，亦可調整製品之耐火材的柔軟 性。至於混入纖維質材料時，製品之耐火材於燃燒時所產 生的煙量比未混入纖維質材料時少8 0%左右。 所使用的紙類亦可爲舊新聞、舊雜誌等舊紙類，又， 爲了使此舊紙類能與耐火液等形成均勻混合物，其混入方 式較佳爲裁斷.物，但，無需除去舊雜誌上的釘針或消除墨 水之步驟。因這類舊新聞或舊雜誌等除了裁斷處理外無需 其他加工處理，故對舊紙類具有回收再利用的益處。 又，混用稻殼之目的爲，將其中所含二氧化矽成分（ 矽s 1 )成分）供應給本發明之耐火材的製造過程，故除 了稻殼外，亦可使用其他含二氧化矽成分（矽（S i )成 分）之植物種子或其殻類等。 所使用的纖維質材料例子如，中國棉、玻璃棉、不銹 鋼棉、陶瓷棉、礦棉、石棉、纖維素纖維板、陶瓷纖維板 等》 I . 批衣 ~訂 I - H ^ .- ί請先閱讀背面之注意事項再填寫本頁) 彳 本紙張尺度逋用中國固家梯準（CNS ) Α4规格（210Χ297公釐） -8 - 經濟部中央標準局員工消費合作社印製 c； B〇 562 .A7 B7 —__- - - - - — - - _ 五、發明説明（6 ) 本發明之耐火材亦可僅由耐火液及稻殼混合而製得。 而此情形下爲了考量製品之耐火材強度、柔軟性，此稻殼 之混合比率較佳爲7 0〜9 0重量％ (若此比率少於7 0 重量％時，會降低製品之耐火材的強度，又，超過9 0重 量％時，會使製品之耐火材變硬而缺乏柔軟性，故兩者均 不宜），耐火液之混合比率較佳爲10〜30重量％。如 上述般，於製造本發明之耐火材時，.就耐火性觀點耐火液 只需5重量％以上，其耐火性既充足，故混入之耐火液至 少爲5重量％以上時，可於適當調整前述之混合比率（耐 火液：10〜30重量％、稻殼：70〜90重量％)後 ，再加入其他如紙類、纖維質材料、木材片、鋸屑（大鋸 屑）中一種或多種，如此一來可調整耐火材之耐火性、不 燃性、燃燒時防止生煙之性能、耐火性、剛性、柔軟性、 彈性等。 又，本發明之耐火材亦可僅由木材片及耐火液混合而 製得。而此情形下之混合比率較佳爲，耐火液1 5〜35 重量％、木材片6 5〜8 5重量％。若木材片之混合比率 超過8 5重量％時，會增加耐火物之重量及形成堅硬之製 品，故就加工性觀點此比率不佳，又，少於6 5重量％時 ，會降低製品之耐火材的強度，故此値亦不佳。此情形下 亦可以鋸屑（大鋸屑），枯叶、落叶、杉木叶等取代木材 片，或與木材片倂用。即，無論使用任何一種材料均能有 效的利用無其他用途的木材片、鋸屑（大鋸屑）等。如上 述般*於製造本發明之耐火材時，就耐火性觀點耐火液之 本紙乐尺度適用中國國家標準（CNS ) A4現格（210X297公釐）-9- LV--------裝-----_--訂------線 (請先閲讀背面之注意事項再填寫本页} 4 60562 經濟部中央橾準局員工消費合作社印裝 A7 ___B7五、發明説明（7 ) 混合量只需爲5重量％以上’故混入至少5重量％以上之 耐火液後’除了可藉由適當調整前述之混合比率（耐火液 :15〜3 5重量％、木材片及/或鋸屑（大鋸屑）： 6 5〜8 5重量％)外’亦可混入如紙類、稻殼、纖維質 材料中一種或多種而調整耐火树之火性、不燃性、燃燒 時防止生煙之性能、耐水性、鋼性、柔軟性、彈性等。 由上述說明得知’本發明之耐火材可利用，於5〜 1 5重量％之使氫氧化鉀、碳酸鈉（碱灰）、金屬矽及水 反應而得的耐火液中，依據最後製品之耐火材所要求的種 種性能（耐火性、不燃性、燃燒時防止生煙之性能、耐水 性、鋼性、柔軟性'彈性、重.量、硬度等），而加入適量 的紙類、稻殼、纖維質材料、木材片、銀屑（大館屑）中 一種或多種，且其合計量爲8 5〜9 5重量％後，使其混 合、脫水、加壓成型而製得。 本發明之耐火材的製造方法可爲，利用已知和捏和機 '混合機等使紙類、稻殼、纖維質材料、木材片、鋸屑（ 大鋸屑）中一種或多種與耐火液混合後，利用壓縮等方式 使所得混合物進行脫水處理’再以溫壓或擠押成型方式使 其加壓成型而得製品之耐火材。 又，於上述方法中，混合材料後於脫水處理前可利用 1〇0〜170°(：煮沸（沸騰）30〜90分鐘。其因爲 ’此煮沸（沸騰）步驟可促進耐火液對紙類等之浸透，而 形成良好的混合狀態°又，增加煮沸（沸騰）步驟時，可 具有良好之溫壓等加壓成型步驟的作業性，結果所形成之 本紙伕尺度適用中國國家標準（CNS ) A4規格(210X297公釐) Γΐό^ ' ----------裝------訂------線 • I .、 (請先閲讀背面之洼意事項再填寫本頁) 460562 A7 B7__ 五、發明説明（8 ) 最終製品的耐火材之表面比未經煮沸（沸騰）步驟者更見 光沢，且加工後可成爲綺麗之物。若此煮沸（沸騰）溫度 低於前述範圍（1 0 0〜1 7 0°C )時，煮沸（沸騰）所 需時間會較長*又，高於此範圍時，煮沸（沸騰）過程中 會使混合物質變硬，故兩溫度値均不佳。另外，煮沸（沸 騰）時間少於前述範圍（3 0分鐘〜9 0分鐘）時，將無 法得到充分的利用煮沸（沸騰）而得到之效果（促進耐火 液對紙類等的浸透效果），又，比此範圍更長時，將無法 大幅提升效果，故較佳爲3 0〜9 0分鐘。 上述製造過程中進行脫水處理之目的爲，除了於成型 前去除多餘之液體外，還可增加製品之耐熱材的加工性。 雖可利用加熱、加溫等方式進行脫水處理，但，利用壓力 機脫水後，所擠出的液體（溶有最初混合後之耐火液及紙 類等成分者）可重覆使用於下一次製造耐火材之步驟中， 故可節省耐火液。又，就其後之成型步驟的作業性及製品 之耐火材的加工性等觀點，此脫水處理較佳爲，能使混合 物中的液體成分成爲4 0〜5 0重量％者。 若製造過程中係利用溫壓進行加壓成型時，其方式較 佳爲，150〜180 °C進行30〜90分鐘。此加壓成 型除了可利用溫壓、壓延成型、擠押成型外，亦可使用已 知的各種加壓成型方法。 因本發明之耐火材係由，使氫氧化鉀.碳酸鈉（碱灰 )、金屬矽及水反應而得到耐火液後，加入紙類、稻殼1 纖維質材料、木材片、鋸屑（大鋸屑）中一種或多種，再 本紙張尺度通用中國闺家標率（CNS ) Α4規格（210X297公釐）-11 - l·—.—-----#t±衣-----—.π.------、線 (請先閲讀背面之注#^項再填寫本頁) 經濟部中央標準局貝工消費合作社印製 460562 A7 B7 五、發明説明（9 ) 加壓成型而製得，故可利用溫壓、壓延成型、擠押成型等 方式使其疋型爲板狀、柱狀、棒狀等各種形狀。又，成型 之耐火材除了具有耐火性外，還具有一定強度，故易以切 斷等方式進行加工，因此，除了作爲建築材料外，還可使 用於門、桌子、椅子等傢俱製品之部材，或冰箱、電視機 等外框，或取代瓦楞紙、發泡苯乙烯等之包裝材料等各種 用途上。另外亦可作爲目前以不銹鋼所製成之廚具等的換 氣管部材、啤酒箱框、柏青哥台框、厚紙盒（銀行、商店 等付錢、放錢的盒子）等製造用材料。 即，本發明之耐火材除了可取代目前以木材製作之部 材外，還可取代金屬、合成樹脂等製作之部材及，一切要 求耐火材之部材。 又’本發明係提供一種耐火建材，其特徵爲，混合上 述耐火液及植物粒子後加壓成.型，其中又以1 8 0〜 經濟部中央標準局員工消費合作社印衷 (诗先閱讀背面之注意事項真 C本頁) 2 0 0 °C之溫壓爲佳。以及另一種耐火建材，其特徵爲， 混合耐火液及皂土、纖維後，將所得粘稠液層積於木板、 紙板、金屬板、合成板之單面或雙面上而形成。因此，使 用本發明之耐火液例如製造膠合板時，因不使用目前膠合 板所使用的福爾馬林，故能製得無害的膠合板。 即，將上述本發明之耐火液塗布於木板、合成木板、 集成板、紙板（例如加壓成型紙板）或金屬板等之單面或 雙面後，此木板等可作爲耐火建材。例如，於厚5〜1 0 mm之木板表面上塗布厚1〜3 mm的本發明之耐火液後 •乾燥2〜10小時，再將塗布面靠近氣體燃燒器（ 本紙張尺度通用中国國家標皁（CNS )人4規_格（210X297公釐）-12 - ά R0562 Α7 ___Β7 五、發明説明（10 ) 1 0 0 0 °C)以進行加熱，結果1〜3分鐘內不會有燃燒 情形。而爲了對照前述試驗而將未塗本發明之耐火液的同 質木板（厚5〜1 Omm)靠近氣體燃燒器（1 〇 〇 〇°c )，結果2〜5秒後會有燃燒情形。 又，本發明係提供一種使用上述本發明之耐火液而兼 具優良之耐火性、隔音性及隔熱性的耐火性建材，另外， 本發明係提供一種使用本發明之耐火液而具有優良耐火性 的粘著劑。 即·，將皂土及中國棉加入本發明之耐火液以生成混合 物後，利用介有此混合物之方式將不燃棉板（外層）粘著 於基板上，可形成具有優良之耐火性及隔音性的耐火性建 材。又，所使用的基板可爲紙板、木板、玻璃板、金屬板 或混凝土，而不燃棉板例子如，不銹鋼板、陶瓷棉。也就 是基板可爲任何可燃材（例如紙板、木板、合成板、玻璃 板）或不燃板（混凝土、金屬材、陶瓷成型板）。至於所 使用之不燃棉亦可爲金屬棉、礦棉、石棉或玻璃棉。另外 ，亦可使用任何於火災等高溫下亦不燃燒，而能保有原有 形狀的纖維所形成之不燃棉= 經濟部中央榡準局員工消资合作社印裝 (請先閱讀背面之注意事項再填寫本頁) 又，將皂土、中國棉及樹脂3 1加入上述的本發明之 耐火液中，攪拌使其均勻混合後，可生成具有優良耐火性 之粘著劑。 如上述般利用本發明之耐火液生成具有優良耐火性之 粘著劑時，對耐火液之中國棉係以0 . 5重量％〜1 . 5 重量％，對耐火液之樹脂3 1係以1重量％〜2 . 5重量 本紙張尺度逋用中®國家標準（CNS ) A4AII格（2丨0X297公釐）-13 - f 460562 經濟部中央標隼局貝工消費合作杜印製 A7 B7 五、發明説明（11 ) %，對耐火液之石墨係以0·1〜0,3重量％，對耐火 液之碳纖維係以0·05〜0.1重量％等方式加入此耐 火液中，攪拌後可提供具有優良耐火性之粘著劑。 又，利用上述方法生成之本發明具有優良耐火性的粘 著劑，可使鋸屑、稻殼、軟木塞屑、紙肩、合成樹脂粘碎 物（廢物再生）等成型爲板狀=而此類由鋸屑、大鋸屑、 稻殼等所形成的板狀則具有優良之隔音性及不燃性。 若以上述方法所生成之本發明具有優良耐火性的粘著 劑作爲製造膠合板之粘著劑時，，因。不使用目前所使用之 福爾馬林•故能製得無害的膠合板。 另外，利用上述方法所生成之本發明具有優良耐火性 的粘著劑，粘著具有極佳之隔音性的紙、纖維、鋸屑等以 成型爲紙板、纖維板、鋸屑板等時，可提供一種同時具有 優良之隔音性及耐火性的建材。 如上述般，本發明之耐火性粘著劑可同上述耐火液般 r 使用於建材上，除此之外，亦可於可燃建材、不燃建材等 各種材料間產生強力粘著效果。 又，以石墨及碳纖維取代中國棉及樹脂3 1而得到的 本發明之耐火性粘著劑可作爲耐火性油灰或接頭材。於火 災時因此接口材不會產生微小裂痕或收縮，故有防止火災 延燒之優點 因本發明之耐火液可利用簡單的製造方法而大量生產 及，易以廉價原材料而製得，故可將耐火液之製造成本壓. 至極低。又•將本發明之耐火液塗布於木板或紙板等單面 本紙張尺度適用十囷國家標準（CNS > A4说格（210X 297公釐)-T4 - ' -----------餐------.1T------^ ' . -Λ (請先閱讀背面之注意事項再镇寫本貫) 4 經濟部中央揉準局員工消費合作社印製 60562 A7 _____B7五、發明説明（u) 或雙面上時，可使成型品具有難燃性或比原先更不易燃性 〇 本發明之耐火液爲水溶性，因此，可利用調整供應反 應之水量的方式，而自由調節所生成之反應液濃度。其次 ’可利用若干處理而成爲具光澤之溶液，而且具有加熱時 亦不會產生有毒氣體等特質。 另外，於基板上塗布一定厚度之本發明耐火液並使其 乾燥，或塗布一定厚度之含本發明耐火液的油漆類並使其 乾時，可將可燃材變成不燃建材。又，將此耐火液層積於 金屬棉等耐火材料時，可得具有優良耐火性、隔音性之耐 火建材。 利用本發明可提供一種除了具有耐火性、隔熱性、隔 音性外，還具有一定強度之適用於切斷等加工過程的，適 用於建築材料，或門、桌子、椅子等製造傢倶用部材》或 冰箱、電視機等家電製品外框·，或包裝材料等各種用途上 之耐火材。即，本發明之耐火材除了可取代目前以木材製 得之部材外，還可取代金屬、合成樹脂等所製得之要求耐 火性的部材。 本發明之耐火材因可使用紙類、稻殼、纖維質材料、 木材片、鋸屑（大鋸屑）等而製得，故可將成本降至極低 ，又，利用牝方式可達到廢物利用及捉進再生之優點。 將使用後之本發明耐火材埋在土中，約1 〇年時間可 使其分解返回土壤內，且對人體無量= 又，因本發明之建材於高溫加熱下亦不會產生有毒氣 J-----------装------1T------.^ (請先閲讀背面之注意事項再：^寫本頁) 本紙张尺度適用中國國家標準（CNS ) A4说格（210X297公釐）-15 - 60 562 A7 ___B7 五、發明説明（13 ) 體，故可保證人體生命及財產。另外，因可利用鋸子等工 具自由切斷，故爲一種成型性良好之優良耐火建材。 至於使用本發明之耐火液所生成的耐火性粘著劑除了 對各種材料具有優良之粘著性外 > 亦具有使用於建築等之 油灰或接頭等的效果。 .圖1爲，本發明之耐火建材的部分剖面圖，圖2爲， 本發明之另一耐火建材的剖分剖面圖》 (實施例1 ) 依序將粒狀氫氧化鉀8 kg，粉末狀碳酸鈉（碱灰）（ 旭硝子（股）公司製）7 kg、金屬矽塊3 0 kg投入反應槽 內。其次再投入水6 0 <，以開始自然的反應。 又，此反應可由最下層之氫氧化鉀的激烈反應，而由 下方對流到上方得到確認。而反應時溫度會自然生升，又 以8 0°C〜9 0°C時反應最激烈。並且，反應溫度之最高 限爲9 2 °C。 經濟部中央標準局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁} 1 Q小時後反應結束，分離出固體成分後可得本發明 之耐火液約(約70kg)。 殘留的固體成分爲金屬矽塊，以水洗淨後約得2 2 kg 左右之金屬矽塊。其後再追加約8 kg之金屬矽塊，以合計 爲3 0kg之方式供塵約第2次反應。 即*同第一次般，將粒狀氫氧化鉀8 kg、粉末狀碳酸 鈉（碱灰）（旭硝子（股）公司製）7 kg投入反應槽內後 ，再投入第一次反應般殘留2 2 kg的金屬矽塊及追加的新 本紙乐尺度適用中國國家標準（CNS ) A4規格（210X297公釐） -16 - 經濟部中央標準局負工消費合作社印裝 A60562 A7 __B7_ 五、發明説明（14 ) 金屬矽塊8 kg，其次，再投入水6 0《以開始第2次耐火 液的生成反應" 又，對此實施例中生成本發明之耐火液的方式而言最 佳爲，最先投入粒狀氫氧化鉀，再於其上依序投入粉末狀 碳酸鈉（碱灰）、金屬矽塊及水。其因爲，最下層之氫氧 化鉀於反塵過程中最先反應，因此可產生上下激烈的對流 0 至於此實施例所生成的耐火液濃度較高，因此，可將 其層積於可燃性板狀物，例如木板上，而得被覆耐火層之 耐火材。又，將此耐火材靠近氣體燃燒器（1 0 0 o°c) 並經30分鐘後仍未產生燃燒情形。 另外，除了同上述實施例.般投入同量的粒狀氫氧化鉀 、粉末狀碳酸鈉（碱灰）、金屬矽塊外，亦可將投入的水 量改爲70 <。若水量增加爲70 <時，所生成之耐火液 濃度較低=接著，混合所得耐火液7 0重量％、市售塗料 2 0重量％及中國棉1 0重量％後，可得建築物之內部裝 璜用耐火塗料。又，即使底層爲可燃性材料，只需塗布此 耐火塗料3〜5次（厚度爲2〜3mm)後，亦可形成耐 火壁。 隨著投入水量的增加*於耐火液之生成反應結束後所 殘留的金屬矽量亦會增加。例如|投入同量之粒狀氫氧化 鉀，粉未狀碳酸鈉（碱灰）、金屬矽塊後，再投入70 < 水，結果所殘留之金屬砂塊量爲2 5 kg。 本紙張尺度適用中國國家標準（CNS > Α4規格（2丨0X297公釐）-17 - d-------------批衣------1T------線 - -. (請先閱讀背面之注意事項再填寫本頁) 4 60 562 A7 B7 五、發明説明（15 ) (實施例2 ) (請先閱讀背面之注意事項再>寫本頁) 放入粉末狀氫氧化鉀3kg、粒狀碳酸鈉（碱灰）2 kg 1金屬矽塊1 5 kg及水2 0 kg，以進行反應。反應溫度則 上升至80°C〜90°C，又，2〜5時後反應結束，得本 發明之耐火液2 2 kg〜2 6 kg。 至於反應所使用之金屬矽並未完全使用完，因反應後 仍有一定量殘留，故洗淨後只需追加部分金屬矽，以使其 量合計爲1 5 kg，即可供應給第2次的生成反應。 上述所生成的耐火液爲，pH 1 0〜1 2之水溶液。 若混合所得耐火液70重量％、市售塗料20重量％ 及中國棉1 0重量％後，可得建築物內部裝璜用耐火塗料 。雖然不添加中國棉亦能得到耐火塗料，但，爲了增強耐 火性，又以添加中國棉爲佳。 將此耐火塗料作爲裝璜用塗料塗布3〜5次（厚爲2 〜3mm)後，可使可燃性底層形成耐火壁。 又，減少供應反應之水量時，可使生成之耐火液的粘 稱性增加。而增加水量時，可使生成之耐火液變淡而利於 塗布。 經濟部中央標準局負工消費合作社印装 除了使用因上述此實施例之氫氧化鉀、碳酸鈉（碱灰 )、金屬矽量外，將水量增加爲2 4kg，結果可生成恰好 符合混合塗料等塗布材料之濃度的耐火液。 (實施例3 ) 將水3 2 <加入粒狀氫氧化鉀4 kg、粒狀碳酸鈉（碱 本紙張尺度通用中國國家梯準（CNS ) A4規格（210X297公釐） -18 - 562 Α7 Β7 五、發明説明（16) 灰）3 kg、金屬矽塊8kg中’以開始反應。反應度則上升 至6 0 eC〜9 0 °C，又，4小時後結束反應。反應後分離 出固體成分，得本發明之耐火液1 8 <〜2 5 約3 2 kg )。 所分離出之固體成分爲最初投入之金屬矽的殘留物。 洗淨此殘留之金屬矽後再追加新的金屬矽，使分計量爲8 kg，以供應給第2次生成反應。 另外，將4 <水加入所生成之耐火液中，均勻攪拌後 若塗布於基扳上，可形成具有耐火層之耐火建材。 (實施例4 ) 將小3 3《加入粉末狀氫氧化鉀4 · 5 mg、粉末狀碳 酸鈉（碱灰）3 . 5竑、金屬矽塊9 kg中，以開始反應。 反應溫度會上升至7 0〜9 0°C，4小時後結束反應。反 應結束後分離出固體成分，得本發明之耐火液2 0〜2 7 < (約 3 3 kg )。 經濟部中央標隼局員工消費合作社印装 (請先閱讀背面之注意事項再填寫本頁) 所分離出之固體成分爲最初投入之金屬矽的殘留物。 洗淨此殘留之金屬矽後，再追加新的金屬矽，使其合計量 爲9 kg後，以供應給第2次生成反應》 (實施例5 ) 將實施例1所製得之耐火液1 0重量％、裁斷的舊紙 (舊新聞）80重量％、稻殼5重量％、中國棉5重量％ 投入生成槽，使其充分混合。 本紙張尺度逋用中國國家標丰（CNS ) Α4規格（2ΙΟΧ297公釐）-19 - 經濟部中央標準局員工消費合作社印装 S ^ 5 62 A7 __B7___ 五、發明説明（17) 其次，利用壓力機擠壓此混合物，使其脫水成含水量 4 5重量％之物，再以約1 8 Ot之溫壓方式加壓6 0分 鐘，得板狀之本發明的耐火材（長·· 30cm、寬：30 cm、厚：1 · 5cm、重量：2 kg)。結果此耐火材具 有耐火性，且如此大尺寸之板狀物重量極輕。 (實施例6 ) 將實施例1所製得之耐火液1 0重量％、裁斷之舊紙 (舊新聞）80重量％、稻殼5重量％、中國棉5重量％ 投入生成槽中使其充分混合。 其後，以1 1 0°C〜1 30°C方式煮沸6 0分鐘。冷 卻至常溫1 2 0°C )後擠壓混合物，使其脫水爲含水量 4 5重量％之物，再利用約1 8 0°C之溫壓加壓約6 0分 鐘，得本發明之耐火材（長：30cm、寬：30cm、 厚：1 . 5cm、重量：1 . 5kg)。結果此耐火材亦具 有耐火性|且極輕。 又，比較實施例5所形成之本發明耐火材及，實施例 6所形成之本發明耐火材，結果實施例6之耐火材表面具 有光澤，且加工品較好看。 (實施例7 ) 將實施例2所製得之耐火液2 0重量％及稻殻8 0重 量％投入生成槽使其充分混合。 其後擠壓此混合物，使其脫水至含水量4 0重量％， ------------裝------訂------線 - . -'- (请先閱讀背面之注意事項再埴寫本頁) 本紙法尺度適用中國國家標率（CNS ) A4说格（210X297公釐） * 20 - 經濟部t央榡準局員工消费合作社印¾ d6〇562 A7 --—_____B7____ 五、發明説明（H。） '18 f 再1利用已知的擠押成型機，製得棒狀的本發明之耐火材（ 直徑 1 . Ocm、長：30cm、重量 〇 . 6 kg)。 (實施例8 ) 將實施例2所製得之耐火液20重量％、稻殼80重 量％投入生成槽使其充分混合。 其後’以1 10°C〜120 t方式煮沸60分鐘、冷 卻至常溫（2 0°C)後擠押此混合物，使其脫水至含水量 4 0重量％ ’再利用已知的擠押成型機，製得棒狀本發明 之耐火材（直徑：2 Ocm、長：30cm、重量： 1 . 2 kg ) 。 (實施例9 ) 將實施例3所製得之耐火液25重量％、木材片75 重量％投入生成槽使其充分混合。 其後，擠押此混合物，使其脫水至含水量4 5重量％ ，再利用約1 8 Ot之溫壓加壓約6 0分鐘，得柱狀之本 發明的耐火材（長：30cm、寬：2 . Ocm、厚： 3 . Ocm、重.量：0 . 8kg)。 (實施例1〇） 將實施例3所製得之耐火液25重量％、木材片75 重量％投入生成槽使其充分混合。 其後以1 10 °c〜120 °C方式煮沸60分鐘。冷卻 本紙伕尺度適闲_國國家棉準（CNS >八4!兄掊（210X 297公)Γ5 ^ -21 - (請先閱讀背面之注意事項再砂本頁) .裝. 訂 線 d 60562 A7 B7 五、發明説明（19 ) 至常溫（2 0 °C )後擠押此混合物，使其脫水至含水量 4 5重量％，再利用約1 8 0°C之溫壓加壓約6 0分鐘， 得柱狀本發明之耐火材（長：30 cm、寬：3 . 〇cm 、厚：3.0<：111、重量：]_.3咕）。 (試驗例1 ) . 利用實施例5〜1 〇所得的本發明之耐火材，以進行 其性能之各種試驗。 首先，觀察將耐火材表面靠近1，5 0 0°C之氣體燃 燒器的火焰3 0分鐘間之變化。結果經1 0分鐘時，任何 一種耐火材的表面均陶瓷化。3 0分鐘後切斷各耐火材以 觀察其內部變化，結果任何一種耐火材靠近火焰之表面側 約0 · 8mm之部分已進化爲陶瓷化》又，既使實施例5 、6之厚1 . 5 cm的板狀耐火材，火焰亦無法通至背面 0 其次，將實施例5、 6所製得之板狀耐火材放置於地 經濟部中央標辛局舅工消費合作社印裂 (請先閱讀背面之注意事項再磕寫本頁) 板上，再由高約8 0 cm處使高爾夫球自然落下，結果撞 擊耐火材的高爾夫球幾乎不會彈回。因此，本發明之耐火 材具有優良的衝擊吸收能力。 又，利用實施例5所製得之本發明的板狀耐火材製作 箱子，並將開著聲音（開關開著之狀態）的收音機密封於 箱中，結果於箱子外側幾乎無法聽到收音機聲音。因此， 本發明之耐火材具有優良的隔音性。 接著•利用敲釘子、旋螺絲.鋸或刀切等方式對實施 本紙俵尺度逍用中國國家揉準（CNS ) A4现格（210 X 297公釐） · 22 - ύ 60562 A7 B7 五、發明说明（20) 例5〜1 0所得的本發明之耐火材進行加工性檢討。結果 將釘子敲入實施例5〜1 0所得之本發明的耐火材中時’ 能順利地將釘子敲入。又’對實施例5〜1 0所得之本發 明的耐火材而言均可順利地旋入螺絲。 另外，鋸子、刀子等均易進行切斷加工。因此’對實 施例5〜1 0所得的本發明之耐火材而言’可利用鋸子或 刀子等製作各種形狀，例如可簡單地加工成家庭用冰箱之 外框、電視機外殼、取代目前之厚紙板或發泡苯乙烯等包 裝材料、製造桌或椅之部他’其他各種住宅資材等。 (實施例1 1 ) 將實施例2所得之耐火液.5 0重量％投入鋸屑、稻殼 中一種或混合物5 0重量％中，使其均勻混合液，利用溫 壓之1 8 0t〜2 0 0°C進行加壓成型，得厚1 0mm之 耐火板。又，將此耐火板靠近氣體燃燒火焰（1 〇 〇 〇 °C )以加熱3 0分鐘後’並未產生燃燒情形。至於混入（或 單獨混入）稻殼之物於加熱後’此耐火板表面呈玻璃化。 (實施例1 2 ) 將混入實施例2所得之耐火液40重量％、皂土45 重量％及中國棉15重量％且攪拌均勻而成的粘稠液’塗 布於厚10mm之木板表面上’使其厚成爲2 . 5mm後 予以自然乾燥，得耐火板。再以塗布耐火液之一側靠近氣 體燃燒火焰（ 1 000 °C) ’結果5分鐘後仍未燃燒。 本紙張尺度適/l丨中囤國家標率（CNS ) Α4現格（210X297公釐） ----------裝------ΐτ------^ . - : (請先閱讀背面之注意事項再填艿本I) -23- 460562 A7 __________________B7__ 五 '發明説明（21 ) (實施例1 3 ) (讀先閱讀背面之注意事項再>爲本育) 將混合實施例2所生成之本發明的耐火液及塗料而成 的塗料，塗布於厚1 〇mm之木板上下兩面上，得具有厚 2〜3mm之塗層2、2a的耐火建材3 (圖1) » 其次對此耐火建材3之表面吹附氣體燃燒火焰（ 1000 aC )，結果3分鐘內未曾發生燃燒。 又，爲了比較對照，而對未塗覆上述塗層之厚1 0 mm木板吹附氣體燃燒火焰（1〇〇 〇°c)，結果3秒就 發生燃燒。 (實施例1 4 ) 混合實施例2所生成的本發明之耐火液6 0 (重量） %、中國棉1 . 0 (重量）％、皂土 30 (重量）％、樹 脂3 1 9 (重量）％後，攪拌以生成耐火性粘著劑。其後 ，於厚10mm之木板1上塗布厚2 . 5mm的此耐火性 粘著劑以生成耐火層4，接著於其上重疊固著厚1 0mm 之金屬棉板（外殼）5 (市售品，製造：新日鐵（股）公 司或伊斯蘭特（股）公司），得本發明之耐火建材6 (圖 2 ) ° 將此耐火建材6靠近氣體燃燒器（1 0 0 0°C)並吹 附火焰，結果2分鐘後金屬棉變成赤熱狀，但，3 0分鐘 後木板化未燃燒。 本紙乐尺度過州屮阄團家標準（CNS >A4#見格（210X 297公釐） -24- 4 6 〇 5 62 、 B7 五、發明説明（22) (實施例1 5 ) 將皂土 2 . 5kg，中國棉40g及作爲增粘劑之80 g樹脂3 1加入實施例2所生成之本發明的耐火液4 <中 ，均勻混合後可得本發明之耐火性粘著劑8〜1 〇 kg。 (實施例1 6 ) 將2 . 5kg之皂土、40g之中國棉、80g之樹月旨 3 1、4 g之石墨及2 g的碳纖維加入實施例2所生成之 本發明之耐火液4 <中，均勻混合後可得本發明之耐火性 接頭材8蛣〜8.511层。 .^n ^^^^1 I..... - 1 - - -I ^^^1 --- I n^i ---- ^^^1 VJ -,° (锖先閱讀背面之注意事項ΙΪ-填本頁) 經米部中火4|準x;h.T消赍合作.τι印絮 本紙張尺度適川中國囤家標準（CNS ) Μ規格（2l〇X 297公釐） -25-, 1T Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 460562 A7 ___B7 V. Invention Description (2) etc. ’There will be a problem that its strength will be rapidly reduced during a fire. The current various adhesives or sealants also have poor fire resistance. And so far, there is no one with excellent fire resistance, heat insulation and sound insulation, which has a certain strength and is suitable for cutting and other processing processes.It can be used not only as a building material, but also for manufacturing interior, table, chair and other furniture. Proposals for refractory materials that are suitable for various applications, such as parts, and outer frames of household appliances such as refrigerators and televisions, and can replace corrugated paper and expanded styrene as packaging materials. Therefore, the present invention uses potassium hydroxide, sodium carbonate, metallic silicon and water to react, and the water-soluble refractory liquid obtained can solve the above problems. That is, the refractory liquid of the present invention is a refractory liquid produced by reacting potassium hydroxide, sodium carbonate, silicon metal, and water. The potassium hydroxide used is sticky or granular, and the sodium carbonate is also powdery or granular, while the silicon metal is lumpy. In addition, the refractory liquid is: After powder or granular potassium hydroxide is put into the reaction tank, powder or granular sodium carbonate and metal silicon blocks are sequentially added, and finally water is added into the reaction tank to naturally start The product of the reaction. The time required for this reaction is 2 hours to 10 hours. If the amount of potassium hydroxide or the like supplied for the reaction is small, the reaction time will be short, and when the amount of potassium hydroxide or the like is large, the reaction time required to generate a refractory liquid will be longer. If the water supplied to the reaction is warm water at 40 ° C to 50 ° C, the reaction time can be shortened. The sodium carbonate used above is preferably the anhydride of sodium carbonate (commonly known as "alkali ash"). In addition, the powdered or granular potassium hydroxide used, the acid anhydride (alkali ash) of sodium carbonate in the form of powder or granules, and the bulk silicon metal can be L .--------- ¾ .-----:-Order .------ 'line (please read the notes on the back before filling this page) This paper size is applicable to the national standard (〇 阳) 6 4 specifications (2丨 0; < 297 mm) -5-A60562 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs A7 _B7___ V. Invention Description (3) Commercially available items. That is, commercially available powdered or granular potassium hydroxide, sodium carbonate anhydride (alkali ash), and commercially available bulk metallic silicon can be used in the present invention. As for the size (diameter, etc.) of the powder, granule, or mass, and No special restrictions. As described above, the refractory liquid of the present invention is produced by reacting powdered or granular potassium hydroxide, powdered or granular sodium carbonate, metallic silicon blocks, and water for 2 to 10 hours. The temperature during the reaction is 60 ° C ~ 90 ° C. Since the refractory liquid produced is water-soluble, the concentration of the refractory liquid produced can be freely adjusted by the amount of water supplied to the reaction. For example, when the refractory layer is formed by using this refractory liquid alone, the concentration of the refractory liquid needs to be large. Therefore, the amount of water (weight) to be supplied, for example, the total weight of potassium hydroxide and sodium carbonate is preferably about 4 times. Although a smaller amount of water than the foregoing, for example, 2.5 times the amount of water, a refractory liquid with a very high concentration can be obtained. However, in this case, the refractory fluid generation reaction will not proceed smoothly, so the amount of water is not good. In addition, if the refractory liquid produced is applied or blown separately, the concentration of the refractory liquid needs to be small. Therefore, the amount of water (weight) to be supplied, for example, the total weight of potassium hydroxide and sodium carbonate is preferably about 4.4 times. Of course, a small amount can also be added. For example, when using a mixture of a refractory liquid and a coating material such as paint, the amount of water (weight) supplied can be about 4.7 times the total weight of potassium hydroxide and sodium carbonate. However, when the concentration of the refractory liquid is too small, the fire resistance will be reduced. Therefore, the amount of water (weight) supplied is preferably controlled to about 4.7 times the total weight of potassium hydroxide and sodium carbonate. In addition, when coke (approximately 10% by weight) is added to the refractory liquid, a coating film can be formed after coating and drying. ! τ ---------- install ------ order ------ line- (please read the precautions on the back before writing this page) This paper size applies Chinese national standards ( CNS) A4 (210X 297mm) -6-Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 __ B7 V. Description of the invention (4) If casein (1 to 10% by weight) is added to the above fire resistance When it is liquid, the refractory liquid will be difficult to dissolve in water. When the coke and about 10% by weight of fluorine are added, the refractory liquid will also be difficult to dissolve in water. In addition, the present invention provides a refractory The material and its manufacturing method are characterized in that the refractory liquid is mixed with any one or more of paper, rice husk, fibrous material, wood chips, and sawdust (large sawdust), and then pressurized to form it. The mixing ratio of the refractory liquid and other materials is preferably 5 to 15% by weight of the refractory liquid, and 85% to 95% by weight. »If the ratio of the refractory liquid is less than 5% by weight, the fire resistance will be reduced. When the ratio of refractory liquid exceeds 15% by weight, the fire resistance will not change much, so from the viewpoint of cost and effect, especially From papers, rice hulls, fibrous materials, wood chips, and sawdust (large sawdust), the refractory fluid ratio is preferably 15% by weight or less from the viewpoint of special materials that cannot be applied to other effective utilization methods in the industry. When the paper, rice husk and fibrous material are mixed into the refractory liquid as the refractory material as described above, the mixing ratio is preferably 5 to 15% by weight of the refractory liquid, 75 to 85% by weight of the paper, and 3 to 3% by weight of the rice husk. 7% by weight and 3 ~ 7% by weight of the fibrous material. The reason why the refractory liquid ratio is preferably 5 ~ 15% by weight is as described above. If the mixing ratio of paper is less than 75% by weight, the product will be reduced. The softness of the refractory material makes this ratio not good. Also, when it exceeds 85% by weight, the fire resistance is reduced, so the ratio is also not good. If the mixing ratio of rice husk is less than 3% by weight, the product's refractory material will be reduced. Elasticity, if it exceeds 7% by weight, the elasticity will be too strong. Therefore, the national standard (CNS) Α4 specification (210X 297 mm) of the two-sheet paper size is applicable. ----- ΐτ ------. ^ * h (Please read the notes on the back before filling Page) Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 460562 A7 _____B7_ V. Description of the invention (5) The ratios are not suitable 1. If the mixing ratio of the fibrous materials is less than 3% by weight, the refractory of the products will be reduced And softness, and if it exceeds 7% by weight, the flexibility will be too strong, so both ratios are not good. In addition, only paper (8 5 ~ 9 5) is mixed in the refractory liquid (5 ~ 15% by weight). (% By weight) can also be made of refractory materials. However, when the rice husks are mixed at the same time, because the silicon dioxide component (silicon (Si) component) contained in the rice husks can be mixed into the refractory production process, the product can be increased. The refractory and water resistance of the refractory, and the softness of the refractory of the finished product is better. In addition, the purpose of mixing fibrous materials is to: • In addition to reducing the smoke generated by the refractory material of the product during combustion, the softness of the refractory material of the product can also be adjusted. As for the mixing of fibrous materials, the smoke produced by the refractory products of the products when burning is about 80% less than when the fibrous materials are not mixed. The paper used can also be old paper such as old news, old magazines, etc. In order to form a homogeneous mixture of this old paper and refractory liquid, the mixing method is preferably cutting. However, it is not necessary to remove the old paper. Staples on magazines or steps to remove ink. This type of old news or magazines does not require any processing other than the cutting process, so it has the benefit of recycling used paper. In addition, the purpose of mixing rice husks is to supply the silicon dioxide component (silicon s 1) contained therein to the manufacturing process of the refractory material of the present invention. Therefore, in addition to rice husks, other silicon dioxide-containing components can also be used. (Si (Si) component) plant seeds or their shells. Examples of the fibrous materials used are, for example, Chinese cotton, glass wool, stainless steel cotton, ceramic wool, mineral wool, asbestos, cellulose fiber board, ceramic fiber board, etc. I. Approval ~ Order I-H ^ .- Please read first Note on the back, please fill in this page again.) 彳 This paper size is based on China Gujia Ladder Standard (CNS) Α4 size (210 × 297 mm) -8-Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs c; B〇562 .A7 B7 —__--------_ V. Description of the invention (6) The refractory material of the present invention can also be made only by mixing refractory liquid and rice husk. In this case, in order to consider the strength and softness of the refractory of the product, the mixing ratio of the rice husk is preferably 70 to 90% by weight (if this ratio is less than 70% by weight, the product's refractory will be reduced. Strength, more than 90% by weight, will make the refractory of the product hard and lack flexibility, so both are not suitable), the mixing ratio of refractory liquid is preferably 10 ~ 30% by weight. As described above, when manufacturing the refractory material of the present invention, the refractory liquid only needs to be 5% by weight or more from the viewpoint of fire resistance, and the fire resistance is sufficient. Therefore, when the refractory liquid mixed is at least 5% by weight or more, it can be appropriately adjusted After the aforementioned mixing ratio (refractory liquid: 10 ~ 30% by weight, rice husk: 70 ~ 90% by weight), one or more of other materials such as paper, fibrous material, wood chips, and sawdust (large sawdust) are added. In order to adjust the fire resistance, non-combustibility of the refractories, the performance of preventing smoke during combustion, fire resistance, rigidity, flexibility, elasticity, etc. In addition, the refractory material of the present invention can also be produced only by mixing a wood chip and a refractory liquid. In this case, the mixing ratio is preferably 15 to 35 wt% of the refractory liquid and 65 to 85 wt% of the wood chip. If the mixing ratio of the wood chips exceeds 85% by weight, the weight of the refractory will increase and a hard product will be formed. Therefore, this ratio is not good from the viewpoint of processability, and if it is less than 65% by weight, the fire resistance of the product will be reduced. The strength of the wood is not good. In this case, sawdust (large sawdust), dead leaves, deciduous leaves, fir leaves, etc. can also be used instead of or in conjunction with wood chips. That is, no matter what kind of material is used, it can effectively use wood chips, sawdust (large sawdust), etc. that are not used for other purposes. As mentioned above * When manufacturing the refractory material of the present invention, the Chinese paper standard of refractory liquid for refractory point of view applies the Chinese National Standard (CNS) A4 (210X297 mm) -9- LV -------- Install -----_-- Order ------ line (please read the precautions on the back before filling out this page) 4 60562 Printed by the Consumers' Cooperatives of the Central Procurement Bureau of the Ministry of Economic Affairs A7 ___B7 V. Invention Description ( 7) The mixing amount only needs to be 5% by weight or more. 'After mixing at least 5% by weight or more of the refractory liquid', in addition to adjusting the aforementioned mixing ratio (refractory liquid: 15 ~ 35% by weight, wood chips and / or Sawdust (large sawdust): 65 to 85% by weight) In addition, it can also be mixed with one or more of paper, rice husk, and fibrous materials to adjust the fire resistance, non-combustibility of fire-resistant trees, and the performance of preventing smoke during combustion , Water resistance, rigidity, flexibility, elasticity, etc. According to the above description, it is known that the refractory material of the present invention can be used, and potassium hydroxide, sodium carbonate (alkali ash), silicon metal and In the refractory liquid obtained by the reaction of water, various properties (fire resistance, Non-combustibility, performance of preventing smoking during burning, water resistance, rigidity, flexibility, elasticity, weight, hardness, etc.), and add an appropriate amount of paper, rice husks, fibrous materials, wood chips, silver chips ( One or more of them, and the total amount thereof is 85 to 95% by weight, and then mixed, dehydrated, and press-molded to obtain the refractory material. Kneader 'Mixer, etc., after mixing one or more of paper, rice hulls, fibrous materials, wood chips, sawdust (large sawdust) with refractory liquid, and decompressing the resulting mixture by means of compression, etc.' In addition, in the above method, after the materials are mixed, before the dehydration treatment, 100 to 170 ° (: boiling (boiling)) can be used for 30 to 90 minutes. The reason is that 'this boiling (boiling) step can promote the penetration of the refractory liquid into paper and the like, and form a good mixed state. Moreover, when the boiling (boiling) step is added, it can have a good pressure forming step such as temperature and pressure Sex The size of this paper is applicable to China National Standard (CNS) A4 specification (210X297 mm) Γΐό ^ '---------- installation ------ order ------ line (Please read the indentation on the back before filling this page) 460562 A7 B7__ 5. Description of the invention (8) The surface of the refractory of the final product is more visible than those without the boiling (boiling) step, and it can become Beautiful thing. If the temperature of boiling (boiling) is lower than the above range (100 ~ 170 ° C), the time required for boiling (boiling) will be longer *. Above this range, boiling (boiling) ) In the process, the quality of the mixture will be hardened, so both temperatures are not good. In addition, when the boiling (boiling) time is shorter than the aforementioned range (30 minutes to 90 minutes), the effect obtained by using the boiling (boiling) cannot be fully obtained (promoting the penetration effect of the refractory liquid on paper and the like), and If it is longer than this range, the effect cannot be greatly improved, so it is preferably 30 ~ 90 minutes. The purpose of the dehydration treatment in the above manufacturing process is to not only remove excess liquid before molding, but also to increase the workability of the heat-resistant material of the product. Although the dehydration treatment can be performed by heating, heating, etc., after the dehydration by the press, the extruded liquid (the one containing the initially mixed refractory liquid and paper components) can be reused for the next production In the step of refractory, refractory liquid can be saved. From the viewpoints of workability in the subsequent molding steps and workability of the refractory material of the product, the dehydration treatment is preferably one in which the liquid component in the mixture can be 40 to 50% by weight. If the press molding is performed using warm pressing during the manufacturing process, the method is preferably 150 to 180 ° C for 30 to 90 minutes. In addition to this press molding, various known press molding methods can be used in addition to warm pressing, calendering, and extrusion molding. The refractory material of the present invention is obtained by reacting potassium hydroxide, sodium carbonate (alkali ash), metallic silicon and water to obtain a refractory liquid, and then adding paper, rice hull 1 fibrous material, wood chips, sawdust (large sawdust) One or more of them, and the standard of this paper is the standard of Chinese girl standard (CNS) Α4 (210X297 mm) -11-l · —.—----- # t ± 衣 -----—. Π .------, line (please read the note # ^ on the back before filling this page) Printed by the Shell Standard Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 460562 A7 B7 V. Description of the invention (9) Compression molding Therefore, it can be made into various shapes such as a plate shape, a column shape, and a rod shape by using methods such as warm pressing, calendering, and extrusion molding. In addition, the formed refractory has a certain strength in addition to its fire resistance, so it can be easily processed by cutting. Therefore, in addition to being a building material, it can also be used as parts of furniture products such as doors, tables, and chairs. It can be used for various purposes such as refrigerators, televisions, and other packaging materials instead of corrugated paper and expanded styrene. In addition, it can also be used for manufacturing materials such as ventilation pipe parts, beer box frames, pachinko frames, and thick cartons (boxes that pay and store money in banks and shops) made of stainless steel. That is, the refractory material of the present invention can replace parts made of wood, and parts made of metal, synthetic resin, etc., and all parts that require refractory. The present invention also provides a refractory building material, which is characterized by mixing the above refractory liquid and plant particles and pressing it into a shape. Among them, it is 180-150 ~ from the Consumers' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. Precautions are true on this page) A temperature and pressure of 2 0 ° C is preferred. And another refractory building material, which is characterized in that after mixing the refractory liquid, bentonite, and fiber, the obtained viscous liquid is laminated on one or both sides of a wooden board, cardboard, metal plate, or composite board. Therefore, when the refractory liquid of the present invention is used to manufacture plywood, for example, since no formalin conventionally used in plywood is used, harmless plywood can be produced. That is, after the refractory liquid of the present invention is coated on one or both sides of a wood board, a synthetic wood board, a laminated board, a paper board (such as a press-formed paper board), or a metal plate, the wood board or the like can be used as a fire-resistant building material. For example, after coating the refractory liquid of the present invention with a thickness of 1 to 3 mm on a wooden board with a thickness of 5 to 10 mm, dry it for 2 to 10 hours, and then place the coated surface close to a gas burner. (CNS) Person 4 Regulations _ grid (210X297 mm) -12-ά R0562 Α7 ___ Β7 V. Description of the invention (10) 1 0 0 0 ° C) for heating, as a result, there will be no burning situation within 1 ~ 3 minutes. In order to compare the aforementioned tests, a homogeneous wooden board (thickness 5 to 10 mm) not coated with the refractory liquid of the present invention was brought close to a gas burner (1000 ° C). As a result, there was a burning situation after 2 to 5 seconds. The present invention also provides a refractory building material using the above-mentioned refractory liquid of the present invention and having excellent fire resistance, sound insulation and heat insulation properties. In addition, the present invention provides a refractory liquid using the refractory liquid of the present invention and has excellent fire resistance. Sexual adhesive. That is, after adding bentonite and Chinese cotton to the refractory liquid of the present invention to form a mixture, the non-combustible cotton board (outer layer) is adhered to the substrate by using the mixture to form an excellent fire resistance and sound insulation. Refractory building materials. The substrate used may be cardboard, wood board, glass plate, metal plate or concrete, and examples of non-combustion cotton plates include stainless steel plates and ceramic cotton. That is, the substrate can be any combustible material (such as cardboard, wood, composite, glass) or non-combustible (concrete, metal, ceramic molding). As for the non-combustible cotton used, it can also be metal wool, mineral wool, asbestos or glass wool. In addition, any non-combustible cotton formed by fibers that do not burn at high temperatures such as fire, but can retain the original shape = printed by the Consumers' Cooperative of the Central Government Standards Bureau of the Ministry of Economy (please read the precautions on the back before (Fill in this page) In addition, bentonite, Chinese cotton, and resin 31 are added to the above-mentioned refractory liquid of the present invention and stirred to uniformly mix to form an adhesive with excellent fire resistance. When using the refractory liquid of the present invention to produce an adhesive having excellent fire resistance as described above, 0.5% to 1.5% by weight of the refractory liquid of Chinese cotton is used, and 1 of the refractory liquid resin is based on 1 Weight% ~ 2.5% This paper is in use in China® National Standard (CNS) A4AII grid (2 丨 0X297 mm) -13-f 460562 A7 B7 printed by the shellfish consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs Description of the invention (11)%, for the refractory liquid graphite system is added to the refractory liquid in the range of 0. 1 ~ 0,3% by weight, and in the refractory liquid carbon fiber system in the range of 0.05 to 0.1% by weight. Adhesive with excellent fire resistance. In addition, the adhesive with excellent fire resistance of the present invention produced by the above method can be used to form sawdust, rice hulls, cork chips, paper shoulders, synthetic resin stickies (waste recycling), etc. into a plate shape. The plate shape formed by sawdust, large sawdust, rice husk, etc. has excellent sound insulation and non-combustibility. If the adhesive having excellent fire resistance of the present invention produced by the above method is used as an adhesive for manufacturing plywood, it is because. It is possible to produce harmless plywood without using formalin which is currently used. In addition, when the adhesive of the present invention having excellent fire resistance produced by the above method is used to form paper, fiberboard, sawdust, and the like having excellent sound insulation properties, the paper can be provided at the same time. Building materials with excellent sound insulation and fire resistance. As mentioned above, the fire-resistant adhesive of the present invention can be used on building materials in the same way as the above-mentioned refractory liquid. In addition, it can also produce a strong adhesion effect between various materials such as combustible building materials and non-combustible building materials. The fire-resistant adhesive of the present invention obtained by replacing graphite and carbon fiber with Chinese cotton and resin 31 can be used as a fire-resistant putty or a joint material. The interface material does not generate micro-cracks or shrinkage during a fire, so it has the advantage of preventing fire from being burned. The refractory liquid of the present invention can be mass-produced using a simple manufacturing method and is easily made with cheap raw materials. The manufacturing cost of the liquid is extremely low. Also • Apply the refractory liquid of the present invention to single-sided paper or board, etc. The paper size is applicable to the Ten Standards (CNS > A4 Standard (210X 297 mm) -T4-'--------- --Meal ------. 1T ------ ^ '. -Λ (Please read the notes on the back before writing this book) 4 Printed by the Consumers Cooperative of the Central Government Bureau of the Ministry of Economic Affairs 60562 A7 _____B7 V. Description of the invention (u) When on or on both sides, the molded product can be made flame-resistant or less flammable than before. The refractory liquid of the present invention is water-soluble. Therefore, the method of adjusting the amount of water for reaction can be used. The concentration of the reaction solution generated can be freely adjusted. Secondly, it can be made into a glossy solution by using several treatments, and has the characteristics of not generating toxic gases when heated. In addition, the substrate is coated with a certain thickness of the refractory liquid of the present invention When it is dried, or when a certain thickness of paint containing the refractory liquid of the present invention is applied and dried, the combustible material can be changed into a non-combustible building material. When the refractory liquid is laminated on refractory materials such as metal wool, Refractory building materials with excellent fire resistance and sound insulation. Can provide a fire resistance, heat insulation, sound insulation, but also has a certain strength, suitable for cutting and other processing processes, suitable for building materials, or doors, tables, chairs, and other furniture manufacturing materials "or refrigerator The outer frame of household appliances such as televisions and televisions, or refractory materials for various purposes, such as packaging materials. That is, the refractory material of the present invention can replace parts made of wood, metal, synthetic resin, etc. The refractory material is obtained. The refractory material of the present invention can be made by using paper, rice husk, fibrous material, wood chips, sawdust (large sawdust), etc., so the cost can be reduced to a very low level. The method can achieve the advantages of waste utilization and capture and regeneration. The refractory material of the present invention after being used is buried in the soil, and it can be decomposed and returned to the soil in about 10 years, and it is immeasurable to the human body. No toxic gas will be produced under high temperature heating J ----------- load ------ 1T ------. ^ (Please read the precautions on the back before writing: ^ write (This page) The paper size is applicable to China National Standard (CNS) A4 Grid (210X297 mm) -15-60 562 A7 ___B7 V. Description of the invention (13) It can guarantee human life and property. In addition, it can be cut freely with a tool such as a saw, so it is excellent in moldability Refractory building materials. As for the refractory adhesive produced by using the refractory liquid of the present invention, in addition to having excellent adhesion to various materials, it also has the effect of putty or joints used in construction, etc. Figure 1 shows, A partial cross-sectional view of the refractory building material of the present invention, FIG. 2 is a sectional cross-sectional view of another refractory building material of the present invention (Example 1) Sequentially, granular potassium hydroxide 8 kg, powdery sodium carbonate (alkali ash) ) (Manufactured by Asahi Glass Co., Ltd.) 7 kg and 30 kg of silicon metal block were put into the reaction tank. Then add water 6 0 < to start a natural response. In addition, this reaction can be confirmed by the drastic reaction of potassium hydroxide in the lowermost layer and the convection from the lower portion to the upper portion. The temperature naturally rises during the reaction, and the reaction is most intense at 80 ° C ~ 90 ° C. The upper limit of the reaction temperature is 92 ° C. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) 1 Q hours after the reaction is completed, the solid refractory liquid of the present invention can be obtained (about 70kg). The solid component is a metal silicon block. After washing with water, about 22 kg of metal silicon blocks are obtained. After that, about 8 kg of metal silicon blocks are added, and the total amount of dust is about 30 kg for the second reaction. That is, as in the first time, 8 kg of granular potassium hydroxide and 7 kg of powdered sodium carbonate (alkaline ash) (manufactured by Asahi Glass Co., Ltd.) are put into the reaction tank, and then the first reaction-like residue is added. 2 2 kg of silicon metal blocks and additional new paper scales are applicable to the Chinese National Standard (CNS) A4 (210X297 mm) -16-Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A60562 A7 __B7_ V. Description of the invention (14 ) 8 kg of metallic silicon block, followed by water 60. "In order to start the second refractory liquid production reaction", and in this embodiment, the method of generating the refractory liquid of the present invention is the best, the first Add granular potassium hydroxide, and then sequentially Powdery sodium carbonate (alkaline ash), metallic silicon block and water. Because the lowermost potassium hydroxide reacts first in the anti-dusting process, it can generate up and down intense convection. As for the refractory liquid generated in this example The concentration is high, so it can be laminated on a flammable plate, such as a wooden board, to obtain a refractory covered with a refractory layer. In addition, this refractory is close to a gas burner (100 ° C) and After 30 minutes, no combustion occurred. In addition, the same amount of granular potassium hydroxide, powdered sodium carbonate (alkaline ash), and silicon metal blocks were used as in the above example, and the amount of water input could be changed. For 70 <. If the amount of water increases to 70 < When the concentration of the refractory liquid produced is low = Then, 70% by weight of the obtained refractory liquid, 20% by weight of a commercially available coating material, and 10% by weight of Chinese cotton are mixed to obtain a refractory for interior decoration of a building. coating. In addition, even if the bottom layer is a flammable material, the refractory wall can be formed only after applying the refractory coating 3 to 5 times (thickness of 2 to 3 mm). With the increase of the amount of water input, the amount of metallic silicon remaining after the reaction of the refractory liquid formation is also increased. For example | Add the same amount of granular potassium hydroxide, powdered sodium carbonate (alkali ash), metal silicon block, then add 70 < Water, as a result, the amount of metal sand remaining was 2 5 kg. This paper size applies to Chinese national standards (CNS > Α4 size (2 丨 0X297mm) -17-d ------------- batch clothes ------ 1T ---- --Line--. (Please read the precautions on the back before filling this page) 4 60 562 A7 B7 V. Description of the invention (15) (Example 2) (Please read the precautions on the back before writing this page) ) Put 3 kg of powdered potassium hydroxide, 2 kg of granular sodium carbonate (alkaline ash) 1 15 kg of silicon metal block and 20 kg of water for reaction. The reaction temperature rises to 80 ° C ~ 90 ° C. In addition, after 2 to 5 hours, the reaction is completed, and the refractory liquid of the present invention is 22 kg to 26 kg. As for the metal silicon used in the reaction, the silicon silicon used in the reaction is not completely used, and there is still a certain amount of residual after the reaction. It is necessary to add a part of metal silicon so that the total amount is 15 kg, and then it can be supplied to the second generation reaction. The refractory liquid produced above is an aqueous solution having a pH of 10 to 12. If the resulting refractory liquid is mixed 70 After weight percent, 20% by weight of commercially available coatings, and 10% by weight of Chinese cotton, fire-resistant coatings for interior decoration of buildings can be obtained. Although fire-resistant coatings can also be obtained without the addition of Chinese cotton, Fire resistance, it is better to add Chinese cotton. Applying this refractory coating as decoration coating 3 ~ 5 times (thickness 2 ~ 3mm) can make the flammable bottom layer form a refractory wall. Also, reduce the water supply reaction In this case, the viscosity of the produced refractory fluid can be increased. When the amount of water is increased, the produced refractory fluid can be made lighter and more convenient for coating. In addition to the use of the above-mentioned embodiment, the printing of the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs In addition to the amount of potassium hydroxide, sodium carbonate (alkali ash), and silicon metal, the amount of water was increased to 24 kg, and as a result, a refractory liquid that exactly matched the concentration of coating materials such as mixed paint was produced. (Example 3) Water 3 2 < Add 4 kg of granular potassium hydroxide, granular sodium carbonate (basic paper size common Chinese National Standard (CNS) A4 specification (210X297 mm) -18-562 Α7 Β7 V. Description of the invention (16) ash) 3 kg, metal silicon block 8 kg 'to start the reaction. The reaction degree rose to 60 eC to 90 ° C, and the reaction was completed after 4 hours. After the reaction, the solid component was separated to obtain the refractory liquid 1 8 of the present invention. < ~ 2 5 (approximately 3 2 kg). The separated solid content is the residue of the metal silicon that was initially charged. After the remaining metallic silicon was washed, a new metallic silicon was added to make the weight of 8 kg to supply the second generation reaction. In addition, the 4 < Water is added to the resulting refractory liquid, and after uniform stirring, if coated on a base plate, a refractory building material with a refractory layer can be formed. (Example 4) A small amount of 3.3 was added to powdery potassium hydroxide (4.5 mg), powdery sodium carbonate (alkali ash) (3.5 mg), and metal silicon block (9 kg) to start the reaction. The reaction temperature will rise to 70 ~ 90 ° C, and the reaction will end after 4 hours. After the reaction is completed, the solid component is separated to obtain the refractory liquid of the present invention 2 0 to 2 7 < (approximately 3 3 kg). Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) The solid content separated is the residue of the original silicon metal. After the remaining metallic silicon was washed, a new metallic silicon was added to make the total amount to 9 kg, and then it was supplied to the second generation reaction. (Example 5) The refractory liquid 1 obtained in Example 1 was used. 0% by weight, 80% by weight of cut old paper (old news), 5% by weight of rice husks, and 5% by weight of Chinese cotton were put into a production tank and mixed thoroughly. This paper uses China National Standards Corporation (CNS) A4 specification (2ΙΟ × 297 mm) -19-Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs S ^ 5 62 A7 __B7___ 5. Description of the invention (17) This mixture was extruded to be dehydrated to a content of 45% by weight, and then pressed at a temperature and pressure of about 18 Ot for 60 minutes to obtain a plate-shaped refractory material of the present invention (length · 30cm, width : 30 cm, thickness: 1.5 cm, weight: 2 kg). As a result, the refractory has fire resistance, and such a large-sized plate is extremely lightweight. (Example 6) 10% by weight of the refractory liquid prepared in Example 1, 80% by weight of cut old paper (Old News), 5% by weight of rice husks, and 5% by weight of Chinese cotton were put into a production tank to make it fully mixing. After that, boil at 110 ° C to 130 ° C for 60 minutes. After cooling to room temperature (120 ° C), the mixture is extruded to be dehydrated to a content of 45% by weight, and then pressurized at a temperature of about 180 ° C for about 60 minutes to obtain the fire resistance of the present invention. Material (length: 30cm, width: 30cm, thickness: 1.5cm, weight: 1.5kg). As a result, this refractory is also refractory | and extremely lightweight. In addition, the refractory material of the present invention formed in Example 5 and the refractory material of the present invention formed in Example 6 were compared. As a result, the surface of the refractory material of Example 6 was shiny and the processed product looked good. (Example 7) 20% by weight of the refractory liquid and 80% by weight of rice hull prepared in Example 2 were put into a production tank and thoroughly mixed. Thereafter, the mixture was extruded to be dehydrated to a water content of 40% by weight. (Please read the notes on the reverse side before copying this page) The paper scale is applicable to China National Standards (CNS) A4 scale (210X297 mm) * 20-Printed by the Ministry of Economic Affairs and the Central Government Bureau of Consumers' Cooperative ¾ d6〇 562 A7 ---_____ B7____ V. Description of the invention (H.) '18 f Then 1 using a known extrusion molding machine to obtain a rod-shaped refractory material of the present invention (diameter 1.0 cm, length: 30 cm, weight 〇 6 kg). (Example 8) 20% by weight of the refractory liquid prepared in Example 2 and 80% by weight of rice hulls were put into a production tank and thoroughly mixed. Then 'boil at 1 10 ° C ~ 120 t for 60 minutes, cool to normal temperature (20 ° C) and squeeze the mixture to dehydrate it to 40% by weight of water.'Reuse known extrusion molding Machine to obtain a rod-shaped refractory material of the present invention (diameter: 2 cm, length: 30 cm, weight: 1.2 kg). (Example 9) 25% by weight of the refractory liquid and 75% by weight of a wood chip obtained in Example 3 were put into a production tank and thoroughly mixed. Thereafter, the mixture was extruded, dehydrated to a moisture content of 45% by weight, and then pressurized with a temperature and pressure of about 18 Ot for about 60 minutes to obtain a columnar refractory material of the present invention (length: 30cm, width : 2.0 cm, thickness: 3.0 cm, weight: 0.8 kg). (Example 10) 25% by weight of the refractory liquid and 75% by weight of a wood chip obtained in Example 3 were put into a production tank and thoroughly mixed. After that, boil at a temperature of 1 10 ° C to 120 ° C for 60 minutes. Cool the paper with the appropriate size _ National Cotton Standard (CNS > 8 4! Brother 掊 (210X 297 male) Γ5 ^ -21-(Please read the precautions on the back before sanding this page). Binding. D 60562 A7 B7 V. Description of the invention (19) After normal temperature (20 ° C), the mixture is squeezed to dehydrate to a water content of 45% by weight, and then pressurized at a temperature of about 180 ° C for about 60. Minutes, the columnar refractory of the present invention (length: 30 cm, width: 3.0 cm, thickness: 3.0 <: 111, weight:] _. 3)). (Experimental example 1). The refractory of the present invention obtained in Examples 5 to 10 was used to perform various tests on its performance. First, observe the change in the flame of a gas burner near the refractory surface at 1,500 ° C for 30 minutes. As a result, the surface of any refractory material was ceramicized after 10 minutes. After 30 minutes, each refractory material was cut to observe its internal changes. As a result, the portion of any refractory material that was close to the flame's surface side of about 0.8 mm had evolved into ceramics. Also, even the thicknesses of Examples 5 and 6 were 1. 5 cm plate-shaped refractories, the flame can not pass through to the back. 0 Second, the plate-shaped refractory materials produced in Examples 5 and 6 were placed in a crack at the Central Labor Bureau of the Ministry of Land and Economy. Please read it first. Note on the reverse side of this page) The golf ball will fall naturally from a height of about 80 cm. As a result, the golf ball hitting the refractory material will hardly rebound. Therefore, the refractory material of the present invention has excellent impact absorption ability. Furthermore, the box was made of the plate-shaped refractory material of the present invention obtained in Example 5, and the radio with the sound (the switch is on) was sealed in the box. As a result, the radio sound was hardly heard outside the box. Therefore, the refractory material of the present invention has excellent sound insulation properties. Then • Use nails, screws, saws, or knives to implement the standard of this paper. Chinese National Standard (CNS) A4 (210 X 297 mm) · 22-ύ 60562 A7 B7 V. Description of the invention (20) The refractories of the present invention obtained in Examples 5 to 10 were reviewed for workability. Results When nails were driven into the refractory material of the present invention obtained in Examples 5 to 10, the nails could be driven smoothly. The screws of the refractory material of the present invention obtained in Examples 5 to 10 can be smoothly screwed. In addition, a saw, a knife, and the like are easily cut. Therefore, 'for the refractory material of the present invention obtained in Examples 5 to 10', various shapes can be made by using a saw or a knife, for example, it can be easily processed into the outer frame of a domestic refrigerator, a TV casing, and the present thick paper. Packaging materials such as boards or expanded styrofoam, parts for manufacturing tables or chairs, and other various housing materials. (Example 1 1) 50% by weight of the refractory liquid obtained in Example 2 was put into one of sawdust and rice husk or 50% by weight of the mixture, and the mixture was uniformly mixed. The temperature and pressure were used for 180 to 2 0 Pressure forming at 0 ° C to obtain a refractory plate with a thickness of 10mm. In addition, this refractory plate was brought close to a gas combustion flame (1000 ° C) to be heated for 30 minutes' and no combustion occurred. As for the matter mixed into (or mixed into) the rice husk after heating, the surface of the refractory board is vitrified. (Example 1 2) A viscous liquid obtained by mixing 40% by weight of refractory liquid, 45% by weight of bentonite, and 15% by weight of Chinese cotton and mixing it with Example 2 was 'coated on the surface of a 10 mm thick wooden board' so that After its thickness became 2.5 mm, it was naturally dried to obtain a refractory plate. Then, one side of the coated refractory liquid was close to the gas burning flame (1 000 ° C), and as a result, it did not burn after 5 minutes. The size of this paper is suitable / l 丨 National standard rate (CNS) Α4 is now (210X297 mm) ---------- installation ------ ΐτ ------ ^.- : (Please read the precautions on the back before filling in this copy) -23- 460562 A7 __________________B7__ Five 'invention description (21) (Example 1 3) (Read the precautions on the back before reading > for this education) will The paint obtained by mixing the refractory liquid and paint of the present invention produced in Example 2 was applied on the upper and lower sides of a 10 mm thick wood board to obtain a refractory building material 3 having a coating 2 and 2a with a thickness of 2 to 3 mm (Fig. 1). ) »Secondly, a gas combustion flame (1000 aC) was blown onto the surface of this refractory building material 3. As a result, no combustion occurred within 3 minutes. For comparison, a gas combustion flame (1000 ° C) was blown onto a 10 mm thick wood board not coated with the above coating, and as a result, combustion occurred within 3 seconds. (Example 1 4) The refractory liquid of the present invention produced in Example 2 was mixed with 60% by weight, Chinese cotton 1.0% by weight, bentonite 30% by weight, and resin 31.9% by weight. After%, stir to form a fire-resistant adhesive. Thereafter, this fire-resistant adhesive having a thickness of 2.5 mm was coated on a wood board 1 having a thickness of 10 mm to form a fire-resistant layer 4, and then a metal cotton board (casing) 5 having a thickness of 10 mm was superposed thereon (commercial product) , Manufacturing: Nippon Steel (stock) company or Islam (stock) company), obtained the refractory building material 6 of the present invention (Figure 2) ° Close this refractory building material 6 near the gas burner (100 ° C) and blow With the flame, the metal wool became red hot after 2 minutes, but the wood became unburned after 30 minutes. The scale of this paper has passed the standards of the Chinese Communist Party (CNS > A4 # See grid (210X 297 mm) -24- 4 6 〇5 62, B7 V. Description of the invention (22) (Example 1 5) 2.5 kg, 40 g of Chinese cotton and 80 g of resin as a tackifier 3 1 Add the refractory liquid of the present invention 4 produced in Example 2 < Medium, 8 to 10 kg of the fire-resistant adhesive of the present invention can be obtained after uniform mixing. (Example 16) 2.5 kg of bentonite, 40 g of Chinese cotton, 80 g of tree moon purpose 3, 4 g of graphite and 2 g of carbon fiber were added to the refractory liquid 4 of the present invention produced in Example 2. < The layers of the fire-resistant joint material of the present invention, 8 蛣 to 8.511, can be obtained after uniform mixing. . ^ n ^^^^ 1 I .....-1---I ^^^ 1 --- I n ^ i ---- ^^^ 1 VJ-, ° (锖 Please read the note on the back first Matters IΪ-Fill in this page) After the Ministry of Fire and Fire 4 | quasi x; hT elimination cooperation. Τι printed paper size suitable for Sichuan China Store Standards (CNS) M specifications (2 l0X 297 mm) -25-