4§〇92 4 A7 ____B7__—__ 五、發明說明（|、） 【技術範疇】 本發明爲關於易受水分、氧氣或微生物影響，而產生 固化或著色等的性質狀態變化或品質劣化物質之包裝。 【習知技術】 將做爲醫藥品原料之氨基酸、抗生素或核酸相關物質 保存於容器內或製成產品出貨之際，這類物質先裝塡於塑 膠袋中，再置於外包裝內。亦即，這類物質多以雙重包裝 的狀態處理此時，係以塑膠類容器作爲內包裝，而紙製 圓桶或金屬罐等較堅固的容器則作爲外包裝》—般而言， 爲防止受潮，多在外包裝之紙製圖桶內面覆以鋁箔，或在 聚偏二氣乙烯、鋁箔、塑膠膜上蒸鍍金屬或氧化矽以作爲 能隔絕水分及氧氣之材料。 在塑膠膜上蒸鍍金屬或氧化矽的包裝材料係使用於商 業用途上。例如，特開平6—；100043號公報中有記載關於 使用不含金屬成分之厚紙板製圓桶外包裝和氧化矽蒸鍍膜 之內包裝做爲防潮重物的一種包裝型態。一般而言，多先 使用聚乙烯膜進行個別包裝，其次，使用氧化矽蒸鍍膜做 爲內包裝，最後再以紙製圖桶進行外包裝。 將受水分、氧氣或微生物影響，而易產生固化或著色 等性質、形狀變化或品質劣化之物質以一般包裝型態包裝 時’這類物質常因微生物增殖而產生固化，或因氧化而產 生著色等性質、形狀變化，造成品質劣化等現象》 【發明之揭示】 本發明之課題，即爲解決前述習知技術之問題點，提 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公* ) 請 先 Η 讀 背 意 事 項广 再V 填、 I裝 本 頁I -I I I I I I 訂 0 經濟部智慧財產局員工消费合作社印製 經濟部智慧財產局S工消费合作社印製 4δ〇92；4 α7 ___Β7__ 五、發明說明（；） 供一種能夠抑制內容物產生微生物增殖或固化、著色等性 質、形狀變化而使得品質劣化之包裝容器及包裝方法。 本發明之另一課題，爲提供一種能夠保持包裝內之平 均相對濕度在60%以下，以及包裝內之氧氣濃度爲0.1%以 下之包裝方法。 此外，本發明並提供以上述包裝容器及使用該容器之 包裝方法的保存方法。 此處所謂之保存，係指受水分、氧氣或微生物之影響 ，而易產生固化或著色等性質、形狀變化而使得品質劣化 之物質(以下，簡稱爲對象物)於製造後，該對象物在被包 裝後到開封前之密閉狀態。亦即，亦包含製品出廠後之運 輸過程。 本發明係關於下述(1)〜(23)之事項。 (1) 一種包裝容器，其特徵在於，具備：至少具有高透 濕性或高透氣性中之一種特性、由用來包裝固體或粉體之 包裝材(高透過性包裝材)所製成之分裝袋，及至少具有低 透濕性或低透氣性之中之一種特性、由用來收納分裝袋之 包裝材(低透過性包裝材)所製成之內裝袋，及置於分裝袋 與內裝袋間之乾燥劑或抗氧化劑，以及用來收納內裝袋之 外包裝。 (2) 如上述(1)之包裝容器，其中所謂高透濕性係指透濕 度在l〇〇g/m2 · day以上，而高透氣性係指透氧度在l〇,〇〇〇cc/ m2 · 24hrs · atm 以上。 (3) 如上述(1)之包裝容器，其中所謂低透濕性係指透濕 4 ----：--'-----裝 ----訂.！ ！°_ <锖先Μ讀背面之沒意事項再填寫本頁) 本紙張尺度適用中國0家標準（CNS〉A4規格（210 X 297公釐） 經濟部智慧財產局貝工消费合作社印製 五、發明說明（3 ) 度在3g/m2 · day以下，而低透氣性係指透氧度在3cc/m2 · 24hrs · atm 以下。 (4) 如上述(1)之包裝容器’其中前述分裝袋之透濕度在 100g/m2 . day以上’且前述內裝袋之透濕度在3g/m2 . day 以下。 (5) 如上述(1)之包裝容器，其中前述分裝袋之透氧度在 10,000cc/m2 . 24hrs . atm以上，且前述內裝袋之透氧度在 3cc/m2 * 24hrs · atm 以下。 (6) 如上述(1)之包裝容器，其中前述分裝袋之透濕度在 100g/m2 . day 以上，且透氧度在 i〇,〇〇〇cc/m2 . 24hrs . atm 以上，而前述內裝袋之透濕度在3g/m2 _ day以下，且內裝 袋之透氧度在3cc/m2 · 24hrs · atm以下。 (7) 如上述(1)之包裝容器，其中前述外包裝係選自紙製 圓桶、塑膠製圚桶、瓦楞紙箱、以及金屬罐所構成群中之 容器、或爲紙製或塑膠製之包裝袋β (8) 如上述(1)之包裝容器，其中前述固體或粉體，係受 水分、氧氣或微生物影響而易產生性質、形狀變化或品質 劣化之物質》 (9) 如上述(1)之包裝容器，其中前述固體或粉體，係受 選自絲狀菌、細菌、酵母菌所構成群中之微生物的影響， 而產生性質、形狀變化或品質劣化之物質。 (10) 如上述(1)之包裝容器，其中前述固體或粉體，係 受選自麵菌屬(Aspergillus)、分枝孢子菌屬(Cladosporium)、 青徽菌屬(Penicillium)、大腸桿菌屬(Escherichia)、桿菌屬 5 本紙張尺度適用中國國家標準（CNS)A4規格（210 297公釐〉 ^ I *1 I I ^ ^ Ϊ ^ ^ ^ I I» ^ ^ I Ϊ ^ ^ I ϋ — II (請先閱讀背面之注項再填寫本買) 4 5 〇 9 2 4 A7 B7 五、發明說明（★) (Bacillus)、念珠菌屬(Candida)、釀母菌屬(Saccharomyces)等 所構成群中所屬之微生物的影響，而產生性質、形狀變化 或品質劣化之物質。 (11) 如上述（1)之包裝容器，其中前述固體或粉體，係 選自食品、食品添加物、醫藥品、醫藥品原料、化妝品原 料、氨基酸、抗生物及核酸相關物質所構成群中之物質。 (12) —種保存方法，其特徵在於：係於上述(1)〜（11)中 任一項之包裝容器中，包裝固體或粉體加以保存。 (13) —種包裝方法，其特徵在於：係將固體或粉體包 裝於由至少具有高透濕性或高透氣性中之一種特性之包裝 材所製成之分裝袋，其次，再將該分裝袋包裝於至少具有 低透濕性或低透氣性中之一種特性之包裝材所製成之內裝 袋，於分裝袋與內裝袋間裝入乾燥劑或抗氧化劑後，將內 裝袋密封、收納於外包裝》 (14) 如上述(13)之包裝方法，其中所謂高透濕性係指透 濕度在l〇〇g/m2 · day以上，而高透氣性係指透氧度在 10,000cc/m2 · 24hrs atm 以上。 (15) 如上述(13)之包裝方法，其中所謂低透濕性係指透 濕度在3g/m2 · day以下，而低透氣性係指透氧度在3cc/m2 · 24hrs · atm 以下。 (16) 如上述（13)之包裝方法，其中前述分裝袋之透濕度 在100g/m2 · day以上，且前述內裝袋之透濕度在3g/m2 · day以下。 (Π)如上述（13)之包裝方法，其中前述分裝袋之透氧度 6 本紙張尺度適用中國國家標準（CNS>A4規格（210 297公釐） (請先朗讀背面 /1. - 之注意事項再填寫本頁) 裝 經濟部智慧財產局貝工消t合作社印製 45 092 4 a? B7 五、發明說明（t) 在10,000cc/m2 · 24hrs · atm以上，且前述內裝袋之透氧度 在 3cc/m2 · 24hrs · atm 以下。 (18) 如上述(13)之包裝方法，其中前述分裝袋之透濕度 在 100g/m2 day 以上，且透氧度在 l〇A〇〇cc/m2 . 24hrs · atm以上，而前述內裝袋之透濕度在3g/m2 · day以下’且 內裝袋之透氧度在3cc/m2 · 24hrs · atm以下。 (19) 如上述（13)之包裝方法，其中前述外包裝係選自紙 製圖桶、塑膠製圓桶、瓦楞紙箱、.金屬罐所構成群中之容 器，或爲紙製或塑膠製之包裝袋。 (20) 如上述(13)之包裝方法，其中前述固體或粉體係受 水分、氧氣或微生物之影響，而易產生性質、形狀變化或 品質劣化之物質。 (21) 如上述(13)之包裝方法，其中前述固體或粉體係受 選自絲狀真菌、細菌、酵母菌所構成群中之微生物的影響 ，而產生性質、形狀變化或品質劣化之物質。 (22) 如上述(13)之包裝方法’其中前述固體或粉體係受 選自麹菌屬、分枝孢子菌屬、青徽菌屬、大腸桿菌屬、桿 菌屬、念珠菌屬以及釀母菌屬所構成群所屬之微生物的影 響，而產生性質、形狀變化或品質劣化之物質。 (23) 如上述(13)之包裝方法，其中前述固體或粉體係選 自食品、食品添加物、醫藥品、轚藥品原料、化妝品原料 、氨基酸及核酸相關物質所構成群中之物質。 以下，說明本發明之實施形態。 眾所周知的’絲狀菌能夠較細菌、酵母菌等生存於更 本紙張尺度適用中國國家標準（CNS)A4規格（210 * 297公; ------------ό·裝— (請先《讀背面之注意事項再填寫本頁) 訂· 經濟部智慧財產局員工消费合作社印製 經濟部智慧財產局霣工消费合作社印製 45 092 4 A7 B7 五、發明說明（i?) 低的水分活性帶，通常水分活性在〇_64以下即無法生存， 而在水分活性0_65的環境下，亦僅有極少數稱爲淡藍色麴 菌(Aspergillus glaucus)之好稠性絲狀菌得以生存《此外，水 分活性與包裝內製品之平衡相對濕度（以下，簡稱爲平衡 RH)之關係幾等同於「水分活性X100=包裝內製品之平衡 RH」。因此，若採用能保持包裝內製品之平衡RH在60% 以下之包裝形態即可能防止微生物之生長》而包裝內之平 衡RH若在60%ώ上時，隨著內容物之不同，在保存期間 內恐將因微生物之增殖而產生固化等性質、形狀變化或品 質劣化。 引起對象物之性質、形狀變化及品質劣化之微生物， 有選自麴菌屬、分枝孢子菌靥、青撇菌靥、大腸桿菌屬、 桿菌屬、念珠菌靥及釀母菌屬所構成群所屬之微生物等。 根據以上所述，爲防止對象物之性質、形狀變化或品 質劣化，必須採取一定措施以保持包裝內之平衡RH在 60%以下。 此外，若顧慮保存中之對象物遭受氧化影響，爲防止 該情形產生，最好使保存中之包裝內的氧氣濃度在0.1%以 下。 以下說明本發明之包裝方法。 首先，將欲保存之對象物裝入分裝袋內並加以密封。 .該分裝袋係使用至少具有高透濕性或高透氣性之中之一種 特性之包裝材(以下，簡稱爲“高透過性包裝材”）所製成。 其次，將裝有對象物之分裝袋裝入內裝袋中，該內裝袋係4§〇92 4 A7 ____B7_____ 5. V. Description of the invention (|,) [Technical category] The present invention is a packaging for substances that are susceptible to moisture, oxygen, or microorganisms and cause changes in properties or states such as curing or coloring. . [Known technology] When amino acid, antibiotic or nucleic acid related substances are used as raw materials for pharmaceuticals, they are stored in containers or manufactured products for shipment. These substances are first packed in plastic bags and then placed in outer packaging. That is, such substances are mostly handled in a double-packed state. At this time, plastic containers are used as inner packaging, and paper drums or metal cans are used as outer packaging. Generally speaking, in order to prevent When it is wet, it is usually covered with aluminum foil on the inner surface of the paper drawing barrel of the outer packaging, or metal or silicon oxide is vapor-deposited on polyvinylidene chloride, aluminum foil, plastic film as a material that can isolate moisture and oxygen. Packaging materials that are vapor-deposited with metal or silicon oxide on plastic films are used for commercial purposes. For example, Japanese Unexamined Patent Publication No. Hei 6-10001000 describes a type of packaging in which a cardboard outer barrel made of a cardboard containing no metal component and an inner packaging of a silicon oxide vapor-deposited film are used as a moisture-proof weight. Generally speaking, polyethylene film is usually used for individual packaging, secondly, silicon oxide vapor-deposited film is used for inner packaging, and finally paper packaging barrels are used for outer packaging. Materials that are affected by moisture, oxygen, or microorganisms and are prone to produce properties such as curing or coloring, such as changes in shape or quality, are packaged in a general packaging type. Changes in properties, shapes, etc. cause deterioration in quality, etc. [Disclosure of the invention] The problem of the present invention is to solve the problems of the conventional technology mentioned above. The paper size is applicable to China National Standard (CNS) A4 (210 X 297). (Public *) Please read the introductory information first, then fill in the V, I install this page I-IIIIII Order 0 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the Consumer Cooperative of the Ministry of Economic Affairs, printed by the S-Consumer Cooperative, 4δ〇92; 4 α7 ___ Β7__ 5. Description of the invention (;) Provide a packaging container and a packaging method capable of inhibiting the content, microorganisms from multiplying, curing, coloring and other properties and shapes from changing, thereby deteriorating the quality. Another object of the present invention is to provide a packaging method capable of keeping the average relative humidity in the package below 60% and the oxygen concentration in the package below 0.1%. The present invention also provides a storage method using the above-mentioned packaging container and a packaging method using the same. The term “preservation” here refers to a substance (hereinafter, simply referred to as an object) which is subject to the influence of moisture, oxygen, or microorganisms, and is liable to produce properties such as curing or coloring, which deteriorates the quality (hereinafter referred to as “object”). After being packaged, it must be sealed before opening. That is, it also includes the transportation process after the product leaves the factory. The present invention relates to the following matters (1) to (23). (1) A packaging container, which is characterized by having at least one of high moisture permeability and high air permeability, and is made of a packaging material (high permeability packaging material) for packing solids or powders. Sub-bags, and at least one of the characteristics of low moisture permeability or low air permeability, inner bags made of packaging materials (low-permeability packaging materials) for storing sub-bags, and placed in sub-bags Desiccant or antioxidant between the bag and the inner bag, and used to store the outer bag. (2) The packaging container as described in (1) above, wherein the so-called high moisture permeability refers to a moisture permeability of 100 g / m2 · day or more, and the high gas permeability refers to an oxygen permeability of 10,000,000 / m2 · 24hrs · atm or more. (3) The packaging container as described in (1) above, where the so-called low moisture permeability refers to moisture permeability 4 ----: --'----- pack ---- order.! !! ° _ < 锖 Read the unintentional matter on the back before filling in this page) This paper size applies to 0 Chinese standards (CNS> A4 size (210 X 297 mm) Printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 3. Description of the invention (3) The degree is below 3g / m2 · day, and the low air permeability means the oxygen permeability is below 3cc / m2 · 24hrs · atm. (4) The packaging container according to the above (1), wherein The moisture permeability of the bag is above 100g / m2.day 'and the moisture permeability of the aforementioned internal bag is below 3g / m2.day. (5) The packaging container as described in (1) above, wherein the oxygen permeability of the aforementioned sub-packing bag is between 10,000cc / m2. 24hrs. Atm or more, and the oxygen permeability of the aforementioned inner bag is 3cc / m2 * 24hrs · atm or less. (6) The packaging container as described in (1) above, wherein the moisture permeability of the aforementioned sub-bag is between 100g / m2.day or more, and oxygen permeability above 〇〇〇〇〇〇cc / m2. 24hrs.atm or more, and the moisture permeability of the inner bag is below 3g / m2 _day, and the oxygen permeability of the inner bag The degree is below 3cc / m2 · 24hrs · atm. (7) The packaging container as described in (1) above, wherein the outer packaging is selected from paper drums, plastic drums, and corrugated boxes. And containers in the group consisting of metal cans, or packaging bags made of paper or plastic β (8) The packaging container as described in (1) above, wherein the aforementioned solid or powder is easily affected by moisture, oxygen or microorganisms Substances that cause changes in properties, shape, or quality "(9) The packaging container as described in (1) above, in which the aforementioned solid or powder is affected by microorganisms selected from the group consisting of filamentous bacteria, bacteria, and yeasts (10) The packaging container as described in (1) above, wherein the solid or powder is selected from the group consisting of Aspergillus and Cladosporium ), Penicillium, Escherichia, Bacillus 5 This paper size applies to the Chinese National Standard (CNS) A4 specification (210 297 mm) ^ I * 1 II ^ ^ ^ ^ ^ ^ II »^ ^ I Ϊ ^ ^ I ϋ — II (Please read the notes on the back before filling out this purchase) 4 5 〇9 2 4 A7 B7 V. Description of the Invention (★) (Bacillus), Candida (Candida), The influence of microorganisms belonging to the group consisting of Saccharomyces, etc., and Substances that cause changes in properties, shape, or quality. (11) The packaging container as described in (1) above, wherein the solid or powder is selected from the group consisting of food, food additives, pharmaceuticals, pharmaceutical raw materials, cosmetic raw materials, and amino acids. 2. Substances in the group of anti-biotic and nucleic acid-related substances. (12) A preservation method, characterized in that: it is packed in a packaging container according to any one of (1) to (11) above, and the solid or powder is packaged and stored. (13) A packaging method, characterized in that the solid or powder is packed in a divided bag made of a packaging material having at least one of high moisture permeability or high air permeability, and then, The packaging bag is packed in a packaging bag made of packaging material having at least one of low moisture permeability or low air permeability. After the desiccant or antioxidant is filled between the packaging bag and the packaging bag, The inner bag is sealed and stored in an outer package "(14) The packaging method as described in (13) above, where the so-called high moisture permeability refers to a moisture permeability of 100 g / m2 · day or more, and high gas permeability refers to a transparent The oxygen level is above 10,000cc / m2 · 24hrs atm. (15) The packaging method according to the above (13), wherein the so-called low moisture permeability means that the moisture permeability is below 3g / m2 · day, and the low gas permeability means that the oxygen permeability is below 3cc / m2 · 24hrs · atm. (16) The packaging method as described in (13) above, wherein the moisture permeability of the aforementioned split bag is above 100g / m2 · day, and the moisture permeability of the aforementioned inner bag is below 3g / m2 · day. (Π) The packaging method as described in (13) above, in which the oxygen permeability of the aforementioned split bag is 6 paper standards applicable to the Chinese national standard (CNS > A4 specification (210 297 mm)) (please read the back / 1/1.-First Please fill in this page for further information.) Printed by the Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, 45 092 4 a? B7 V. Description of the invention (t) Above 10,000cc / m2 · 24hrs · atm, and The oxygen permeability is below 3cc / m2 · 24hrs · atm. (18) The packaging method as described in (13) above, wherein the moisture permeability of the aforementioned split bag is above 100g / m2 day, and the oxygen permeability is 10A〇〇 cc / m2. 24hrs · atm or more, and the moisture permeability of the inner bag is below 3g / m2 · day 'and the oxygen permeability of the inner bag is below 3cc / m2 · 24hrs · atm. (19) As above (13 ) Packaging method, wherein the aforementioned outer packaging is selected from the group consisting of paper cartons, plastic drums, corrugated boxes, metal cans, or paper or plastic packaging bags. (20) As described above (13) A packaging method in which the aforementioned solid or powder system is affected by moisture, oxygen, or microorganisms, and is liable to produce properties, (21) The packaging method according to the above (13), wherein the solid or powder system is affected by microorganisms selected from the group consisting of filamentous fungi, bacteria, and yeast, and produces properties, Substances with a change in shape or quality. (22) The packaging method as described in (13) above, wherein the aforementioned solid or powder system is selected from the group consisting of Pseudomonas, Mycospora, Penicillium, E. coli, Bacillus, (23) The packaging method as described in (13) above, wherein the aforementioned solid or powder system is selected from food , Food additives, pharmaceuticals, pharmaceutical raw materials, cosmetic raw materials, amino acids, and nucleic acid-related substances. In the following, embodiments of the present invention will be described. The well-known 'filamentous bacteria can survive bacteria, yeasts, etc. As of this paper size, the Chinese National Standard (CNS) A4 specification is applicable (210 * 297 male; ------------ ό · installation — (please read the precautions on the back before filling this page)· Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 45 092 4 A7 B7 V. Description of the invention (i?) Low water activity band, usually water activity below 0_64 Can not survive, and in the environment of water activity 0_65, there are only a few good thick filamentous fungi called Aspergillus glaucus. In addition, the balance of water activity and the relative humidity of the packaged products The relationship (hereinafter referred to as "balanced RH") is almost equivalent to "water activity X100 = balanced RH of packaged products". Therefore, if the packaging form that can keep the balance RH of the products in the package below 60% is possible to prevent the growth of microorganisms "and if the balance RH in the package is 60% free, with the difference in content, during the storage period Internal fear may cause changes in properties, shape changes or quality deterioration due to the proliferation of microorganisms. Microorganisms that cause properties, shape changes, and quality deterioration of the object are selected from the group consisting of Pleurotus, Mycosporium, Pseudomonas spp., Escherichia coli, Bacillus, Candida, and Bacteroides Belonging microorganisms, etc. According to the above, in order to prevent the nature, shape change or quality deterioration of the object, certain measures must be taken to keep the balance RH in the package below 60%. In addition, if you are concerned about the oxidative effects of the objects being stored, in order to prevent this, it is best to keep the oxygen concentration in the packaging during storage below 0.1%. The packaging method of the present invention will be described below. First, put the object to be stored in a separate bag and seal it. The packaging bag is made of a packaging material (hereinafter, simply referred to as a "high-permeability packaging material") having at least one of the characteristics of high moisture permeability or high air permeability. Next, the sub-bag containing the object is put into an inner bag, and the inner bag is
S 本纸張尺度適用中困困家標準(CNS)A4規格（210 X 297公釐） ----------I ^(1 -----I ^il---!l^wi . <請先*讀背面之注$項典赛寫本頁) 45 092 4 7/ /t\ 明說 明發五 使用至少具有低透濕性或低透氣性之中之一種特性之包裝 材(以下，簡稱爲“低透過性包裝材”）所製成。接著，在分 裝袋與內裝袋之間裝入乾燥劑或抗氧化劑。亦即，分裝袋 與內裝袋之間包含乾燥劑或抗氧化劑。最後再將內裝袋密 封，並將該內裝袋裝入外袋中。 藉由裝入乾燥劑，本發明能使保存中之包裝袋內的平 衡RH維持在60%以下，防止保存中之對象物的品質產生 變化。 此外，藉由以抗氧化劑取代乾燥劑，本發明能使保存 中之包裝袋內的氧氣濃度維持在0.1%以下，防止保存中之 對象物的品質產生變化。 過去的包裝形態，無論是包裝固體或粉體，若測量分 裝袋內之平衡RH，可得出其測量値從10%以下至90%以上 ，變動範圍極大。本發明人，觀察到此現象亦起因於對象 物之物性。此外，亦觀察到包裝內之平衡RH愈高，微生 物愈容易增殖，或對象物易產生固化或著色等性質、形狀 變化而使得品質劣化。有時則因氧化而產生對象物變色的 情形。 若在一般之的包裝形態中，裝入抗氧化劑以取代乾燥 劑時，所測得包裝內之氧氣濃度爲16%。此一情況下之氧 氣濃度，藉由使用本發明之包裝容器及包裝方法，可使包 裝內之氧氣濃度降至0.1%以下。包裝袋內之氧氣濃度若能 保持在0.1%以下，即能防止對象物之性質、形狀變化或品 質劣化。 9 本紙張尺度適用中國困家楳準（CNS>A4现格（210 x 297公釐） (请先和讀背面之注$項再填寫本頁> ''·.裝-------- 訂------- 經濟部智慧财產局貝工消费合作社印製 經濟部智慧財產局貝工消费合作社印製 45 092:4 五、發明說明（浐） 將濕度計插入包裝袋內可測得包裝袋內之相對濕度 (RH)。同樣，將氧氣濃度計插入包裝袋內將可測得包裝袋 內之氧氣濃度。 以下，就本發明之包裝容器及包裝方法詳加說明。 < υ分裝袋 分裝袋係用來包裝對象物，凡至少具有高透濕性或高 透氣性之中之一種特性之包裝材均可使用之。例如，可使 用塑膠製之微多孔質薄片、微多孔膜、或有孔膜等。又例 如，聚丙烯製之微多孔薄片、聚乙烯製之微多孔膠膜、或 有孔塑膠製膜等。分裝袋之包裝材，若爲高透濕性時，該 包裝材之透濕度至少應在100g/m2 _ Day以上，最好是在 500g/m2 · Day以上，若能在1000g/m2 Day以上則最爲理 想。分裝袋之包裝材若爲高透氣性時，該包裝材之透氧度 必須在10,000cc/m2 · 24hrs · atm以上，如有更高者尤佳。 <2>乾燥劑 做爲乾燥劑，可使用一般用來做爲乾燥劑之任一者。 具體來說，可使用矽膠、氯化鈣、鹸石灰、矽鋁系乾燥劑 等。 〈3>抗氧化劑 做爲抗氧化劑，可使用一般做爲抗氧化劑之任一者皆 。具體來說，可使用活性金屬粉末、連二亞硫酸鹽、維他 命C、硫酸鐵、連二亞硫酸蘇打、金屬偶合血紅蛋白類似 構造水不溶性氧氣吸收塑膠等。 〈4>內包裝 !!_0·裝--------訂----- {請先《讀背面之注ί項再填窝本買) ΟΊ. 本紙張尺度適用中困0家標準（CNS>A4規格（210 X 297公釐> 經濟部智慧財產局貝工消费合作社印製 45 092 4 五、發明說明（j) 內包裝係用來包裝分裝袋β內包裝之包裝材，凡至少 具有低透濕性或低透氣性中之一種特性的包裝材均可使用 β亦即，只要是水蒸氣阻斷性或氧氣阻斷性高之低透過性 包裝材均適宜。例如，常使用的有塑膠製之氧化矽蒸鍍膜 、鋁積層膜、或氧化鋁蒸鍍膜。內包裝之包裝材，若爲低 透濕性時，該包裝材之透濕度以在3g/m2 · day以下者較佳 。若爲低透氣性時，該包裝材之透氧度以在3cc/m2 · 24hrs .atm以下者較佳，若在lcc/m2 · 24hrs * atm以下則更佳。 <5>外包裝 外包裝，凡可用來包裝內包裝者均可使用。可使用爲 外包裝之容器，例如有紙製圓桶、塑膠製圖桶、瓦楞紙箱 、或金屬罐等容器、或紙袋、塑膠袋等。 以上述包裝方法包裝之對象物，如未經開封保存於一 般環境之下，對象物將不致產生性質、形狀變化或品質劣 化，而得以長時間保存。 【發明之最佳實施形態】 以下，根據實施例具體說明本發明，但並非意味著本 發明僅隈定於以下實施例。 實施例1 (1)使用紙製圓桶(直徑443mmX高657mm)做爲外包裝 。使用低透濕度之塑膠膜製氧化矽蒸鍍袋(寬710mmx長 l，300mm、厚80/zm、透濕度：3g/m2，day以下)做爲內包 裝。使用高透濕度之聚丙烯系微多孔質袋(寬700mmX長 l，300mm、厚 200em ' 透濕度：l〇,〇〇〇g/m2 · day)做爲分裝 本纸張尺度適用令國困家標準（CNS)A4现格（210 X 297公* ) -I H 1* ϋ ϋ I « ϋ I l> n n n I n I (锖先和讀背β之注意事項再填寫本1> A7 經濟部智慧財產局員工消费合作社印製 45 092 4 ____B7____ 五、發明說明（/〇 ) 袋。 於該分裝袋內塡充氨基酸之L-丙氨酸50公斤，並於 對象物L-丙氨酸之中央處插入濕度感測器，再以橡皮圈束 緊分裝袋。接著將分裝袋裝入內裝袋中，並於分裝袋上方 放置2個做爲乾燥劑用之重500公克之矽膠袋，再以橡皮 圈束緊內裝袋並加以密封。最後，再將此內裝袋裝入做爲 外包裝之紙製圖桶並加蓋之。 將經上述包裝處理之紙製圓桶置於室溫(20〜25°C)下 ，測定了分裝袋內製品之RH »其結果爲，塡充包裝後立即 測量時爲RH80%以上，但7日後降爲RH40%，14日後再下 降爲35%。亦即，約一星期時間便可確認下降至微生物、 特別是絲狀菌無法增殖之RH60%以下。此時，雖曾試圖自 L·丙氨酸的結晶中分離出微生物，特別是絲狀菌，其結果 完全檢測不到絲狀菌。此外，繼績保存6個月後，開封觀 察內容物之L·丙氨酸結晶，確認結晶仍保持顆粒狀態，完 全未產生固化現象。 (2)比較例 使用紙製圓桶(直徑443mmX高657mm)做爲外包裝。 使用低透濕度之塑膠膜製氧化矽蒸鍍袋（寬710mmX長 l，300mm、厚80#m、透濕度：3g/m2 . day以下)做爲內包 裝。使用低透濕度之低密度聚乙烯膜袋（寬700mmx長 l，300mm、厚80"m、透濕度：4〜8g/m2 . day)做爲分裝袋 〇 於分裝袋內塡充一種氨基酸L·丙氨酸50公斤，並於 本紙張尺度適用中B國家標準（CNS)A4規格（210 X 297公* ) !!ci-----——tr---------ο-------------------------- (請先《讀背面之注f項再填窵本I) A7 .45 092 4 ____B7___ 五、發明說明（/ / ) 內裝物L-丙氨酸之中央處插入濕度感測器，再以橡皮圈束 緊分裝袋。接著將分裝袋裝入內裝袋中，並於分裝袋上方 放置2個做爲乾燥劑用之重500公克之矽膠袋，再以橡皮 圈束緊內裝袋並加以密封。最後，再將此內裝袋裝入做爲 外包裝之紙製圖桶並加蓋之》 將經上述包裝處理之紙製圓桶置於室溫(20〜25°C)下 ，測定了分裝袋內製品之RH。其結果爲，塡充包裝5曰後 RH爲80%以上，30日後RH仍爲80%以上。 此外，繼續保存6個月後，開封觀察內容物之L·丙氨 酸結晶，確認有部份結晶產生固化現象。 將該固化部份取出，並以實施例1同樣方法，試圖自 丙氨酸的結晶中分離出微生物，特別是絲狀菌，其結果 爲檢測出多數的絲狀菌。 該微生物經觀察並依據形態學判定爲青黴菌屬之絲狀 菌。 實施例2 (1)使用紙製圓桶(直徑443mmx高657mm)做爲外包裝 。使用低透濕度之塑膠膜製氧化矽蒸鍍袋(寬710mmX長 l，300mm、厚80弘m、透濕度：3g/m2 ♦ day以下)做爲內包 裝。使用一面爲高透濕度之聚丙烯系微多孔質布(厚200私 m、透濕度：10,000g/m2 · day)、另一面爲低密度之聚乙烯 膜所熱封形成的袋子(寬700mmx長UOOmm、平均透濕度 :1000g/m2 · day)做爲分裝袋。 於分裝袋內塡充一種氨基酸L-酥氨酸(threonine)50公 X 297公釐） 4..* ... kL ----------^----Γ-裝·丨— (請先《續背面之注$項再填寫本萸) 訂· .ά_ 經濟部智慧財產局A工消费合作社印製 經濟部智慧財產局m工消费合作社印製 45 0 9 2 4 a? ___B7_____ 五、發明說明（/i) 斤，並於內容物L·酥氨酸之中央處插入濕度感測器，再以 橡皮圈束緊分裝袋。接著將分裝袋裝入內裝袋中，並於分 裝袋上方放置2個做爲乾燥劑用之重500公克之矽膠袋， 再以橡皮圈束緊內裝袋並加以密封。最後，再將此內裝袋 裝入做爲外包裝之紙製圓桶並加蓋之。 將經上述包裝處理之紙製圓桶置於室溫(20〜25°C)下 ，測定了分裝袋內製品之RH。其結果爲，塡充包裝立即測 量時RH爲80%以上，7日後降爲RH36%，14日後再下降 爲31%。亦即，約一星期時間便可確認下降至微生物、特 別是絲狀菌無法增殖之RH60%以下。 此外，繼續保存6個月後，開封觀察內容物之L-酥 氨酸結晶，確認結晶仍保持顆粒狀態，完全未產生固化現 象。 實施例3 (1)使用紙製圓桶(直徑443mmX高657mm)做爲外包裝 β使用低透氧度之塑膠膜製氧化矽蒸鍍袋（寬710mmX長 l，300mm、厚 80 仁 m、透濕度：lcc/m2 . 24hrs atm 以下）做 爲內包裝。使用高透氣性、高密度之聚乙烯不織布袋（寬 700mm X長l，300mm、平均厚度165 β m、透氣度： 22S/100CC)做爲分装袋。此處，由於分裝袋之透氣性過高， 無法測定其透氧度，故以透氣度表示。 於分裝袋內塡充一種氨基酸之醋酸L-賴氨酸50公斤 ，再以橡皮圈束緊分裝袋。接著將分裝袋裝入內裝袋中， 竑於分裝袋上方放置5個氧氣吸收量爲6000毫升之抗氧化 本紙張尺度適用中0國家標準（CNS)A4規格（210 X 297公* > -----r--1C ·裝------ 訂---- (請先Μ讀背面之注f項再填寫本頁) V - C. 規濟部智慧財產局貝工湞费合作社印製 -45 092 4 A7 五、發明說明（丨、） 劑(Ageless Z-6000PT ;三菱氣體化學社製），再以橡皮圈束 緊內裝袋或以熱封加以密封。最後，再將此內裝袋裝入做 爲外包裝之紙製圖桶並加蓋之。 將經上述包裝處理之紙製圓桶置於恆溫恆濕室(40°C、 RH75%)內，7日後將氧氣濃度計之感應部插入包裝內測定 其氧氣濃度，結果氧氣漉度爲0.08% »此外，繼續保存6 個月後，開封觀察內容物之醋酸L·賴氨酸結晶，確認仍爲 白色結晶，而未產生品質變化。 (2)比較例 使用紙製圖桶(直徑443mmX高657mm)做爲外包裝。 使用低透氧度之塑膠膜製氧化矽蒸鍍袋（寬710mmX長 l，300mm、厚 80/zm、透濕度：lcc/m2 · 24hrs · atm 以下)做 爲內包裝。使用高密度之聚乙烯膜袋（寬700mm X長 l，300mm、平均厚度 165jtim、透氧度：l，900cc/m2 . 24hrs . atm)做爲分裝袋。 於分裝袋內塡充一種氨基酸之醋酸L·賴氨酸50公斤 ，再以橡皮圈束緊分裝袋。接著將分裝袋裝入內裝袋中， 並於分裝袋上方放置5個氧氣吸收置爲6000毫升之抗氧化 劑(Ageless Ζ-6000ΡΤ ;三菱氣體化學社製），再以橡皮圈束 緊內裝袋。最後，再將此內裝袋裝入做爲外包裝之紙製圓 桶並加蓋之》 將經上述包裝處理之紙製圓桶置於恆溫恆濕室(40°C、 RH75%)內，7日後將氧氣濃度計之感應部插入包裝內測定 其氧氣濃度，結果氧氣濃度爲16% »此外，繼續保存6個 本纸張尺度適用中B困家標準（CNS)A4規格<210 X 297公釐） -----：—^----裝— (請先Μ讀背面之注$項再填S本頁> >SJ· 45 092 4 a? ____B7__ 五、發明說明（外） 月後，開封觀察內容物之醋酸賴氨酸結晶’確認結晶變 爲淡黃色，品質產生了變化。 【產業上之可利用性】 本發明可提供一種使分裝袋內之相對濕度降低，將該 分裝袋內之相對濕度保持於較低狀態的包裝容器及使用該 包裝容器之包裝方法。 此外，本發明可提供一種可使分裝袋內之氧氣濃度降 低*將該分裝袋內之氧氣瀵度保持於較低狀態的包裝容器 及使用該包裝容器之包裝方法。 藉由使用上述包裝容器或包裝方法，提供一種受水分 、氧氣或微生物之影響而易產生性質、形狀或品質變化之 物質，於保存中不致產生性質、形狀變化或品質劣化之包 裝。 先 Η 讀 背S This paper size is applicable to the Standard for Difficulties (CNS) A4 (210 X 297 mm) ---------- I ^ (1 ----- I ^ il ---! L ^ wi. < Please read the note on the back of this page to write this page) 45 092 4 7 / / t \ Indicate that the use of packaging that has at least one of low moisture permeability or low air permeability (Hereinafter referred to as "low permeability packaging material"). Next, a desiccant or antioxidant is placed between the divided bag and the inner bag. That is, a desiccant or an antioxidant is contained between the divided bag and the inner bag. Finally, the inner bag is sealed, and the inner bag is filled into the outer bag. By incorporating the desiccant, the present invention can maintain the balance RH in the storage bag under 60%, and prevent the quality of the object during storage from changing. In addition, by replacing the desiccant with an antioxidant, the present invention can maintain the oxygen concentration in the storage bag under 0.1% or less, and prevent the quality of the object during storage from changing. In the past packaging forms, whether it was packaging solids or powders, if the equilibrium RH in the packaging bag was measured, it could be concluded that the measurement range was from 10% to 90% or more, with a wide range of variation. The inventors have observed that this phenomenon also results from the physical properties of the object. In addition, it has been observed that the higher the equilibrium RH in the package, the more easily micro-organisms proliferate, or the objects are likely to undergo changes in properties and shapes such as curing or coloring, which degrades the quality. In some cases, the object may become discolored due to oxidation. When the antioxidant is used to replace the desiccant in the general packaging form, the measured oxygen concentration in the packaging is 16%. In this case, the oxygen concentration in the package can be reduced to less than 0.1% by using the packaging container and the packaging method of the present invention. If the oxygen concentration in the packaging bag can be kept below 0.1%, it can prevent the nature, shape change or quality deterioration of the object. 9 This paper size applies to China ’s poor family standards (CNS > A4 now (210 x 297 mm) (please read the note on the back and then fill out this page > -Order -------- Printed by Shelley Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs Printed by Shelley Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 45 092: 4 V. Description of the invention (浐) Insert the hygrometer into the packaging bag The relative humidity (RH) in the packaging bag can be measured inside. Similarly, the oxygen concentration in the packaging bag can be measured by inserting an oxygen concentration meter into the packaging bag. Hereinafter, the packaging container and the packaging method of the present invention will be described in detail. < υ Repacking bags Repacking bags are used to pack objects. Any packaging material that has at least one of high moisture permeability or high air permeability can be used. For example, microporous materials made of plastic can be used. Flakes, microporous membranes, or porous membranes, etc. For example, polypropylene microporous flakes, polyethylene microporous adhesive membranes, or porous plastic membranes. When moisture permeability, the moisture permeability of the packaging material should be at least 100g / m2 _ Day and more preferably 500g / m2 · D Above ay, it is most ideal if it can be more than 1000g / m2 Day. If the packaging material of the split bag is highly breathable, the oxygen permeability of the packaging material must be above 10,000cc / m2 · 24hrs · atm, if any The higher is better. ≪ 2 > As the desiccant, any one generally used as the desiccant can be used. Specifically, silicone, calcium chloride, lime, and aluminous silica can be used for drying. Antioxidants, etc. <3> Antioxidants are used as antioxidants, and any one generally used as antioxidants can be used. Specifically, active metal powder, dithionite, vitamin C, iron sulfate, dithionine can be used. Sodium sulfite, metal-coupled hemoglobin are similar to water-insoluble oxygen-absorbing plastics, etc. <4> Inner packaging !! _ 0 · Packing -------- Order ----- {Please read the "Note on the back" first Refill the book and buy it) 〇Ί. This paper size is applicable to 0 hardship standards (CNS > A4 size (210 X 297 mm) & printed by Shelley Consumer Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 45 092 4 5. Description of the invention (j ) Inner packaging is used for packaging of β-inner packaging, which has at least low moisture permeability. Or low-permeability packaging materials can be used β, that is, as long as it is a low permeability packaging material with high water vapor barrier or oxygen barrier properties. For example, plastic oxidation is commonly used Silicon vapor-deposited film, aluminum laminated film, or aluminum oxide vapor-deposited film. If the inner packaging material has low moisture permeability, the moisture permeability of the packaging material is preferably less than 3g / m2 · day. If it is low gas permeability In terms of properties, the oxygen permeability of the packaging material is preferably less than 3cc / m2 · 24hrs .atm, and more preferably less than lcc / m2 · 24hrs * atm. < 5 > Outer packaging Outer packaging can be used by anyone who can use it for inner packaging. Can be used as an outer packaging container, such as paper drums, plastic cartons, corrugated boxes, or metal cans, or paper bags, plastic bags, and so on. If the object packaged by the above-mentioned packaging method is stored in an ordinary environment without being opened, the object will not be changed in nature, shape or quality, and can be stored for a long time. [Best Mode for Carrying Out the Invention] Hereinafter, the present invention will be specifically described based on examples, but it does not mean that the present invention is limited to the following examples. Example 1 (1) A paper drum (443 mm in diameter X 657 mm in height) was used as the outer packaging. Use a low-moisture vapor-deposited silicon oxide vapor-deposited bag (width 710mm x length 1, 300mm, thickness 80 / zm, moisture permeability: 3g / m2, less than day) as the inner package. Use high-permeability polypropylene microporous bags (700mm wide, 300mm long, 200em thick, and 200em 'moisture permeability: 10, 000g / m2 · day) as the packaging for this paper Home Standard (CNS) A4 is now available (210 X 297 male *) -IH 1 * ϋ ϋ I «ϋ I l > nnn I n I Printed by the Consumer Cooperative of the Property Bureau 45 092 4 ____B7____ 5. Description of the invention (/ 〇) bag. 50 kg of amino acid L-alanine is filled in the dispensing bag, and the center of the object L-alanine Insert the humidity sensor at the place, and then tighten the packing bag with a rubber ring. Then fill the packing bag into the inner bag, and place 2 silicone bags weighing 500 grams above the packing bag as a desiccant. Then, the inner bag is tightened with a rubber ring and sealed. Finally, the inner bag is put into a paper drawing bucket as an outer packaging and sealed. The paper drum treated with the above packaging is placed in a chamber The RH of the products inside the split bag was measured at a temperature (20 ~ 25 ° C). As a result, the RH was 80% or more when measured immediately after filling and packaging, but fell to 7 days later. RH is 40%, and it will drop to 35% after 14 days. That is, it can be confirmed that the drop of microorganisms, especially filamentous bacteria, can not be reduced to below 60% in about one week. Microorganisms, especially filamentous fungi, were isolated from the crystals. As a result, filamentous fungi were not detected at all. In addition, after 6 months of storage, the contents of L · alanine crystals were opened and observed to confirm that the crystals remained granular (2) The comparative example uses a paper drum (443 mm in diameter X 657 mm in height) as the outer packaging. A silicon oxide vapor deposition bag made of plastic film with low moisture permeability (width 710 mm × length 1, 300 mm, thickness 80 # m, moisture permeability: 3g / m2. Day or less) as inner packaging. Use low-density low-density polyethylene film bag (width 700mm x length 1, 300mm, thickness 80 " m, moisture permeability: 4 ~ 8g / m2. day) as a repacking bag. Fill the repacking bag with 50 kg of an amino acid L · alanine, and apply the National Standard B (CNS) A4 (210 X 297 male *) in this paper size! ! ci -----—— tr --------- ο -------------------------- (Please first Read note f on the back and fill in I) A7 .45 092 4 ____B7___ 5. Description of the invention (/ /) Insert the humidity sensor at the center of the content L-alanine, and tighten the packing bag with a rubber band. Then fill the packing bag into In the inner bag, place two silicone bags with a weight of 500 g as the desiccant above the split bag. Then tighten the inner bag with a rubber ring and seal it. Finally, the inner bag was put into a paper drawing bucket as an outer package and covered. The paper drum treated with the above packaging was placed at room temperature (20 ~ 25 ° C), and the packaging was measured. RH inside the bag. As a result, the RH of the filling and packaging after 5th day was 80% or more, and the RH was 30% or more after 30 days. After 6 months of storage, the L · alanine crystals of the contents were opened and observed, and it was confirmed that some crystals had solidified. The solidified portion was taken out, and in the same manner as in Example 1, an attempt was made to isolate microorganisms, particularly filamentous bacteria, from the crystals of alanine. As a result, most filamentous bacteria were detected. This microorganism was observed as a filamentous fungus of the genus Penicillium based on morphology. Example 2 (1) A paper drum (443 mm in diameter x 657 mm in height) was used as the outer packaging. Use low-moisture-permeability silicon oxide vapor-deposited bags (width 710mm × length 1, 300mm, thickness 80mm, moisture permeability: 3g / m2 ♦ or less) for inner packaging. A polypropylene microporous cloth with a high moisture permeability on one side (200 μm thick, moisture permeability: 10,000 g / m2 · day), and a heat-sealed bag formed by a low-density polyethylene film on the other side (700 mm wide x 700 mm long) UOOmm, average water vapor transmission rate: 1000g / m2 · day) are used as split bags. Fill a packed bag with an amino acid L-threonine (50 km X 297 mm) 4 .. * ... kL ---------- ^ ---- Γ-pack · 丨 — (please fill in the "$" on the back of the page before filling in this book) Order. ? ___B7_____ 5. Description of the invention (/ i) kg, and insert a humidity sensor at the center of the content L · Trecine, and then tightly pack the bags with rubber bands. Then put the packing bag into the inner bag, and place two 500 g silicone bags as desiccant on top of the packing bag, and then tighten the inner bag with a rubber band and seal it. Finally, the inner bag is put into a paper drum as an outer package and covered. The paper drum subjected to the above packaging treatment was placed at room temperature (20 ~ 25 ° C), and the RH of the products in the divided bags was measured. As a result, the RH of the filling and filling package was measured immediately above 80%, it was reduced to RH36% after 7 days, and then decreased to 31% after 14 days. That is, it can be confirmed that it takes less than one week to reduce the RH to 60% of the microorganisms, especially the filamentous bacteria, which cannot proliferate. In addition, after the storage was continued for 6 months, the contents were observed for L-glycine crystals, and it was confirmed that the crystals remained in a granular state, and no solidification occurred. Example 3 (1) A paper drum (443 mm in diameter X 657 mm in height) was used as the outer packaging. A silicon oxide vapor deposition bag (710 mm in width X 1,300 mm in thickness, 80 mm in thickness, and 100 mm in thickness) with low oxygen permeability was used. Humidity: lcc / m2 (below 24hrs atm) as inner packaging. Use a high-breathability, high-density polyethylene non-woven bag (700mm wide x 300mm long, average thickness 165 β m, air permeability: 22S / 100CC) as the split bag. Here, since the air permeability of the dispensing bag is too high, the oxygen permeability cannot be measured, so it is expressed as the air permeability. Fill a separate bag with 50 kg of L-lysine acetate, an amino acid, and tighten the bag with a rubber band. Then put the sub-bag into the inner bag. 放置 Place 5 anti-oxidants with an oxygen absorption capacity of 6,000 ml on top of the sub-bag. The paper size is applicable to the national standard (CNS) A4 size (210 X 297 male * >); ----- r--1C · Equipment ------ Order ---- (Please read the note f on the back before filling this page) V-C. Shellman, Intellectual Property Bureau, Ministry of Economic Affairs Printed by Cooperative Cooperatives-45 092 4 A7 V. Description of the invention (丨,) agent (Ageless Z-6000PT; manufactured by Mitsubishi Gas Chemical Co., Ltd.), and then the inner bag is tightened with a rubber band or sealed by heat sealing. Finally, Then put the inner bag into the paper drawing barrel as the outer packaging and cover it. Put the paper drum treated with the above packaging in a constant temperature and humidity room (40 ° C, RH75%), and then put it in The sensing part of the oxygen concentration meter was inserted into the package to measure its oxygen concentration. As a result, the oxygen concentration was 0.08%. »In addition, after 6 months of storage, the contents of L·lysine acetate crystals were opened and observed to confirm that they were still white crystals. No quality change occurred. (2) Comparative examples used paper cartons (443mm in diameter X 657mm in height) as outer packaging. Silicon oxide made of plastic film with low oxygen permeability Plating bag (width 710mm × length 1, 300mm, thickness 80 / zm, moisture permeability: lcc / m2 · 24hrs · atm or less) as inner packaging. Use high-density polyethylene film bag (width 700mm X length 1, 300mm, average Thickness 165jtim, oxygen permeability: 1,900cc / m2. 24hrs.atm) as the packing bag. Fill the packing bag with 50 kg of L-lysine acetate, which is an amino acid, and tighten the packing with rubber bands. Then, put the sub-bag into the inner bag, and place 5 antioxidants (Ageless ZO-6000PT; manufactured by Mitsubishi Gas Chemical Co., Ltd.) with an oxygen absorption of 6000 ml on top of the sub-bag, and bundle them with rubber bands. Tighten the inner bag. Finally, put the inner bag into a paper drum as the outer packaging and cover it. Place the paper drum treated with the above packaging in a constant temperature and humidity chamber (40 ° C, RH75%), after 7 days, insert the sensing part of the oxygen concentration meter into the package to measure its oxygen concentration, the result is that the oxygen concentration is 16% »In addition, continue to save 6 paper standards applicable to the China Standard B (ABS) A4 specification < 210 X 297 mm) ----- ： — ^ ---- 装 — (please read the note on the back and fill in the S page > > SJ · 45 092 4 a? ____B7__ V. Description of the invention (outside) Months, the contents of lysine acetate crystals in Kaifeng were observed to confirm that the crystals turned pale yellow and the quality changed. [Industrial Applicability] The present invention can Provided are a packaging container that reduces the relative humidity in a divided bag, keeps the relative humidity in the divided bag to a low state, and a packaging method using the packaging container. In addition, the present invention can provide a packaging container which can reduce the oxygen concentration in the packaging bag * and keep the oxygen level in the packaging bag to a low state, and a packaging method using the packaging container. By using the above-mentioned packaging container or packaging method, a substance which is susceptible to changes in properties, shape, or quality under the influence of moisture, oxygen, or microorganisms is provided, and the packaging does not cause changes in properties, shape, or quality during storage. Read first
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I 訂 • I I I 曝 I I I I 經濟部智慧財產局員工消费合作社印製 ,6 本紙張尺度適用中Η _家揉準（CNS)A4規格（210 X 297公釐）Order I • I I I Exposure I I I I Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, 6 paper sizes are applicable to the Chinese standard _ Jia Shuang Zhuan (CNS) A4 (210 X 297 mm)