448103 經濟部中央標準局員工消費合作杜印製 Α7 Β7 五、發明説明（丨） 本發明係有關於建枒、電氣製品等街使尾之聚氯乙燒 被覆金屬板及其製造方法，P而言之，係有關於藉由将含 有耝粒聚氯乙烯樹脂之聚氯乙烯甚覆'以彩或表靣具有□ 凸筷樣之聚氯乙烯被覆金屬扳及其製造方法= 以往，聚氯乙烯被覆金屬扳，係藉甴將各種模樣彤或 於皮膜表面以陚予圖案，係以建材、家電製品等領域爲中 心面被使芾著。 對聚氯乙烯被覆金屬扳賦予圖案性之方法，係在聚氯 乙烯皮膜的表面，藉B施如印刷以彩成模樣，如此以賦予 圖案性；或將彫刻有各種篌樣之金屬'輥壓著在經加熱之聚 氯乙烯被覆鋼板的皮膜表面，藉龀以將彫刻楔樣轉寫在皮 膜上而賦予圖案性；或倂罔前述2種方法而賦予圖案性。 然而，藉由印刷而陚予圖案惶之方法，因印刷步驟之 加入會造成成本提高；又，藉由金屬輥以賦予圖案牲之方 法，金屬輥之製作成本高；又，爲了將模樣轉寫在皮膜上 ，因必須彩成相當程度的皮膜厚度，故皮膜的成本會變高 〇 本發明係爲了解洪上述之缺點而提出一種聚氯乙烯 被覆金屬板，係藉由跨含有粗粒聚氯乙.烯樹脂之聚氯乙烯 皮膜被覆在金屬扳的表層，面不使吊經彭刻之金屬輥等1 IP可簡單且便宜地彤成凹凸筷樣，旦就算在薄漢上亦丐具 有Η凸感；並提烘該裉覆金屬板之製造方法。 本發明之聚氯乙烯被覆金屬扳，係莅經表面處理之金 屬板的表層，介甴接著層以設置凹凸模樣ζ聚氯乙烯皮膜 _3 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） .(諳先聞讀背面之注意事項再填寫本頁)448103 Consumption cooperation by employees of the Central Bureau of Standards, Ministry of Economic Affairs, Du printed A7, B7 V. Description of the invention (丨) The present invention relates to polyvinyl chloride-coated metal plates and their manufacturing methods for construction and electrical products. In other words, it is related to a polyvinyl chloride-coated metal plate having a □ convex chopstick-like shape and a manufacturing method by coating a polyvinyl chloride containing a polyvinyl chloride resin containing 耝 particles of polyvinyl chloride resin in a color or surface = conventionally, polyvinyl chloride The coated metal plate is used to apply various patterns to the surface of the film with a pattern, and is centered on the construction material, home appliances, and other fields. The method for imparting pattern to the PVC-coated metal plate is to apply the pattern on the surface of the polyvinyl chloride film by printing, so as to impart the pattern; or to emboss various kinds of engraved metals The patterned surface is imparted on the film surface of the heated polyvinyl chloride-coated steel sheet by transferring the engraved wedge pattern to the film; or the patterning is imparted by the two methods described above. However, the method of giving a pattern by printing increases the cost due to the addition of a printing step; and the method of imparting a pattern to a pattern by a metal roller, the production cost of the metal roller is high; and in order to transfer the pattern On the film, because the film thickness must be colored to a considerable degree, the cost of the film will increase. The present invention proposes a polyvinyl chloride-coated metal plate in order to understand the above-mentioned disadvantages. The vinyl film of vinylene resin is coated on the surface of the metal plate, and the surface does not allow the metal rollers such as the pendant to be suspended. 1 IP can be easily and cheaply formed into a concave and convex chopsticks. Convex sensation; and a method for manufacturing the coated metal plate. The polyvinyl chloride-coated metal plate of the present invention is a surface layer of a metal plate that has been surface-treated, followed by an adhesive layer to set a concave-convex pattern. Ζ Polyvinyl chloride film_3 This paper size applies to China National Standard (CNS) A4 specification (210 × 297) Mm). (谙 First read the notes on the back before filling out this page)
448 I Ο 3 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（乙） 1其特徵在於，前述聚氯乙烯皮膜係含有平均粒徑20〜200 ,u m的耝粒聚氯乙烯樹脂1種以上，凹凸模樣之凸部膜厚 的最大値m)係滿足下式①两代表钓關係' 其與凹菡膜 厚的最亡値y( // m)之比係满足5式②珩代表的關係，面得 出圖案惶、加工悭、經濟性優異的聚氯乙烯被覆金屬板， 及提误該被覆金屬扳之製造方法。 2 0 <x <40 0 …① 0.1 0 < \7 X <0.95 …② 亦即，本發明係對於聚氯乙烯皮膜的庋膜構成及製造 條件針入地琛討，而發現岀圖案性、’加工慳、經濟性優異 的聚氯乙烯被覆金屬板，及其製造方法。 【發明之實施形態】 以下，詳細地說明本發明。 本發玥中珩罔之經表靣處理的金屬板係包含，在金屬 表靣單獨鍍鋅、鎳、鉻、鋁、銅、錫者，或經施加含有前 述金屬之合金電鍍、複合電鍍者*或經施加鉻酸鹽處理、 磷酸Μ處理等化成處理或塗布型的化成處理者。又，將前 述表面處理如以組合也可以。當然，對金屬板的表裡施加 不同的表面處理亦可。 接著，對於二述經表靣處埕之金屬扳·在Β戚含有粗 粒聚氯乙燒之聚氯乙烯樹詣皮膜之記，係先塗葙接著劑。 本發明所吊之接著劑，雖然沒有特別的限定，一般以 丙烯諛系或聚酯系者爲適當。 上述金屬扳表靣 > 係孩成含有粗粒聚氯乙烯之聚氯乙 (請先閱讀背面之注意事項再填寫本頁) 訂 3 1 A7 B7 五、發明説明（$ ) 烯樹脂皮膜•該聚氯乙烯樹脂皮膜之彩成，係在塗布聚氣 乙烯溶膠後，實施加熱、冷卻以進行之。 (請先閱讀背面之注意事項再填寫本頁) 前述聚氯乙烯溶謬之配合，係3計100重量部之聚氯 乙烯樹脂與可塑劑10〜100重量部、稀釋劑5〜100重量部戶斤 構成，亦可配合其他之著色劑等侄意的配合劑。前述計100 重量部之聚氯乙烯樹脂*係將平均粒徑1〜10 m之聚氯 乙烯樹脂10〜95重量部與平均粒徑20〜200 a m之聚氯乙烯 樹脂1種以上90〜5重量部相混合者。 平均粒徑1〜1 〇 # m之聚氯乙烯樹脂竝沒有特別的限 定，宜爲經乳化聚合所製造忠者。若平均粒徑小於1 # m 以下則溶膠之粘度將增加，塗裝性會變差面不佳。若大於 10 # m，將不易成爲溶膠而不佳。又，其配合量宜爲10 重量部〜95重量部，若小於10重量部，溶膠之流動性將變 差，塗裝性會變差而不佳。若大於95重量部，將缺乏凹凸 感而不佳。 經濟部中央標準局一貝工消費合作社印製 平均粒徑20〜200 μ m之耝粒聚氯乙烯樹脂並沒有特 別的限定，宜爲懸濁聚合所製造出者。若平均粒徑小於20 # m，則皮膜將缺乏凹凸感，若大於200 # m，因一般並 無此種規格的市售品故成本將變高而不佳。其酝合量宜爲 90〜5重量部，若大於90重童部，由於溶膠之流動特性將 變差，塗裝性會變差，又凹凸感並不會成比例垲提高故不 佳：若小於5重量部，則將缺乏凹凸感故不佳。又粗粒聚 氯乙烯樹脂係經著色、交聯者亦可。莅粗粒聚氯乙烯樹脂 爲經交聯之場合，因皮膜表靣之光澤度恁，故可得吊消齄 5 本紙張尺度適用中國國家標準（CNS ) A4规格（210 X 297公釐） 4 4b I ϋ 經濟部中央標準局一貝工消費合作社印製 Α7 Β7 五、發明説明（咚） 的表面；在聚氯乙烯樹脂經不同於其本身的顏色著色之場 合，除了凹凸篌樣以外亦可形成花玟模樣， 可塑劑，可使兩鄰苯二甲酸二-(2-乙基己基）酯（以下 珞稱「DOP」）、鄰茏二曱駿二丁酯（以下珞稱「DBP」） 等鄰苯二甲駿酯系，二辛基己二酸酯（以下珞稱「DO A」） 、二異癸基己二駿酯（以下珞稱「DIDA」）等直鏈二鹼駿 酯系，磷酸三曱苯酚酯（以下略稱「TC.P」）、磷漦E茏酚 二茏酯（以下略稱「CDP」）等磷酸酯系，偏苯三酸：三-2-乙基己酯（以下，略稱「TOMT」）等偏苯三酸酯系等，只 要是一般甩於作爲聚氯乙烯溶膠后的可塑劑那可。其配合 量*宜爲10〜100重量部，若小於10重量部則加工性將變 差 > 若大於1〇〇重量部則皮膜會變得過柔軟，又因在經時 中皮膜表面有可能產生可塑劑之漏出，故不佳。 稀釋劑，竝沒有特別的限定，可使芾乙基溶纖劑、石 洩腦、磺泊精等，只要是一般罔於作爲聚氯乙烯溶膠的稀 釋劑即可。其配合量宜爲5~1 00重量部，若小於5重量部 ，則加熱膠化後之如熱殘分多，將缺乏凹凸感;若大於1〇〇 重量部，因加熱膠化時稀釋劑之漭騰，將造成膠化後的皮 膜產生微細的孔洞，故不佳， - 著色m，只要是一般m於作爲聚氯乙烯溶謬的著色劑 即可，係由無機顏嵙或有機顏料及分散劑所樽成。無機顏 料係包含二氧化鈦、鈦黑等。有機顏料係包含鈦靑藍、二 噁0#紫等。分散劑係包含一般罔以作爲聚氯乙烯溶膠的分 散劑等。其配合量宜爲5〜50重量部，若小於5重量部則皮 6 本紙張尺度適用中國國家標準（CNS ) Α4規格（2! 0 X 297公釐） ----------------訂 (讀先閱讀背面之注意事項再填寫本頁) 448103 經濟部中央標準局負工消費合作杜印製 A7 B7 五、發明説明（s) 膜之遮蔽性將變差' 若大於5 0重量部則因配合過剩·反而 造成皮膜成本的提高·故不佳。 將上述聚無乙烯溶謬塗葙在金屬钣表面的方法竑沒 有特別的限定，可使，吊一般金屬钣塗裝所尾之輥塗、流塗 等塗裝方法。圖2係顯示使周輥塗的製造步驟之珞圖。使 芾接著劑塗布輥5以將接著劑塗葙在金薆板1的表面後1 使周烘烤加熱爐6以違行洪烤，使用冷卻裝置7以進行冷 卻，而形成接著劑層2後，使稆溶謬輥1 0以將含粗粒聚氯 乙烯樹脂9之聚氯乙烯溶膠8塗葙之。瓧時，溶膠輥1 0與 塗膠量控制輥11之間隙，必須設定成'膠化後的皮膜可滿足 式Φ及式②的條伶。在溶膠塗有後，使用焐烤力Π熱爐12面 在板溫200〜2 20 °C下加熱，在膠化後藉由冷卻裝置13之冷 卻而製作盅具有凹凸模樣之聚氯乙烯被覆金屬板。 在圖2之製造步驟中，可將溶膠輥1 0及塗膠置控制輥 11所構成之輥塗機改成流塗機或其他的塗裝裝置·相同於 前述之輥塗機中，藉由調整溶膠輥1 0與塗膠量控制輕11 之間隙，以使得膠化後的皮膜滿足式①及式②的關係；在 使周流塗機之場合，必須將塗裝頭的裂口尺寸調整成膠化 後的皮膜可滿足式①及式②之關係般。.在其他塗裝裝置中 ，亦必須將塗裝條悍設定成謬化後的皮獏可滿巨式①及式 2·'之關係。 圖1係顯示依上述方法所製作出之聚氣乙烯被覆金屬 扳的斷面圖。本發明之具有凹凸模樣的聚氯乙烯被覆金屬 扳，係圖1所示的凹凸模樣之凸部膜厚的最大値X( # m) 7 本紙浪尺度適用中國國家標準（CNS ) A4規格（210 X 297公绝） (請先閱讀背面之注意事項再镇寫本頁)448 I Ο 3 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (B) 1 It is characterized in that the aforementioned polyvinyl chloride film contains an aggregated polyvinyl chloride resin with an average particle diameter of 20 to 200 μm One or more types, the maximum thickness of the convex part film thickness 凹凸 m) satisfies the following formula ① the relationship between the two representative fishings', and the ratio of the maximum thickness y (// m) to the concave rugged film thickness satisfies the formula 5 珩The representative relationship is that the PVC coated metal plate with pattern 惶, processing 悭, and excellent economic efficiency can be obtained, and the manufacturing method of the coated metal plate is wrong. 2 0 < x < 40 0… ① 0.1 0 < \ 7 X < 0.95… ② That is to say, the present invention studies the film structure and manufacturing conditions of polyvinyl chloride film into the ground, and found that Polyvinyl chloride-coated metal plate with excellent patternability, processing properties, and economy, and a method for producing the same. [Embodiments of the invention] Hereinafter, the present invention will be described in detail. The surface-treated metal plates in this publication include those that have been individually plated with zinc, nickel, chromium, aluminum, copper, or tin on the surface of the metal, or have been plated with an alloy or composite plating containing the aforementioned metals * Or a chemical conversion treatment such as a chromate treatment, a phosphoric acid M treatment, or a coating type conversion treatment. The aforementioned surface treatments may be combined. Of course, different surface treatments may be applied to the front and back surfaces of the metal plate. Next, in the case of the second-mentioned metal sheet that passes through the surface of the sheet, the polyvinyl chloride tree film containing coarse polyvinyl chloride is contained in β, and the adhesive is applied first. Although the adhesive used in the present invention is not particularly limited, it is generally suitable to use an acrylic resin or a polyester resin. The above-mentioned metal watch gt > is a polyvinyl chloride containing coarse-grained polyvinyl chloride (please read the precautions on the back before filling out this page) Order 3 1 A7 B7 5. Description of the invention ($) Ethylene resin film • The The coloring of the polyvinyl chloride resin film is performed after applying a polyvinyl aerosol, and then heating and cooling. (Please read the precautions on the back before filling out this page.) The aforementioned PVC miscible combination is 3 to 100 weight parts of polyvinyl chloride resin, 10 to 100 weight parts of plasticizer, and 5 to 100 weight parts of thinner. It can also be mixed with other negligible additives such as coloring agents. The above 100 parts by weight of polyvinyl chloride resin * is a combination of 10 to 95 parts by weight of polyvinyl chloride resin having an average particle size of 1 to 10 m and polyvinyl chloride resin having an average particle size of 20 to 200 am by 90 to 5 weight. Ministry of Mixers. The polyvinyl chloride resin having an average particle diameter of 1 to 10 mm is not particularly limited, and it is suitable for manufacturing by emulsion polymerization. If the average particle diameter is less than 1 # m, the viscosity of the sol will increase, and the paintability will be poor. If it is larger than 10 # m, it will not easily become a sol. The blending amount is preferably from 10 parts by weight to 95 parts by weight. If it is less than 10 parts by weight, the fluidity of the sol will be deteriorated, and the paintability will be poor. If it is more than 95 parts by weight, the unevenness will be lacking and it will be unfavorable. Printed by the Central Standards Bureau of the Ministry of Economic Affairs, a Shellfish Consumer Cooperative, there is no particular limitation on the poly (vinyl chloride) resin with an average particle size of 20 to 200 μm, and it should be made by suspension polymerization. If the average particle diameter is less than 20 # m, the film will lack the unevenness, and if it is larger than 200 # m, the cost will be unsatisfactory because there are generally no commercially available products of this specification. The amount of preparation is preferably 90 to 5 parts by weight. If it is more than 90 parts by weight, the flow characteristics of the sol will be deteriorated, the paintability will be deteriorated, and the unevenness will not be proportionally increased. It is not good: If it is less than 5 parts by weight, the unevenness will be lacking, which is not good. Coarse-grained polyvinyl chloride resins may be colored or crosslinked. When the coarse-grained polyvinyl chloride resin is cross-linked, it can be suspended due to the gloss of the surface of the film. 5 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 4 4b I 印 Printed by the Central Standards Bureau of the Ministry of Economic Affairs, a Shellfish Consumer Cooperative, A7, B7 5. The surface of the invention description (咚); In the case where the polyvinyl chloride resin is colored with a color different from itself, it can be used in addition to bumps. Forming calyx shape, plasticizer, can make di- (2-ethylhexyl) phthalate (hereinafter referred to as "DOP"), ortho-dioxane dibutyl (hereinafter referred to as "DBP") Isophthalate esters, linear dibasic esters of dioctyl adipate (hereinafter referred to as "DO A"), diisodecyl adipate (hereinafter referred to as "DIDA") , Phosphonic acid triphosphate (hereinafter abbreviated as "TC.P"), phosphoric acid E phenol diacetate (hereinafter abbreviated as "CDP") and other phosphates, trimellitic acid: tri-2-ethylhexyl Esters (hereinafter referred to as "TOMT"), such as trimellitate, etc., as long as it is generally used as a plasticizer after polyvinyl sol . The blending amount * should preferably be 10 to 100 parts by weight. If it is less than 10 parts by weight, the workability will be worse. ≫ If it is more than 100 parts by weight, the film will become too soft. Leakage of plasticizer is generated, so it is not good. The diluent is not particularly limited, and it may be used as a diluent which is generally used as a polyvinyl chloride sol, such as ethylcellosolve, diarrhea, sulphorporin. The blending amount should be 5 to 100 parts by weight. If it is less than 5 parts by weight, there will be a lack of unevenness if there is too much heat residue after heating and gelling; if it is more than 100 parts by weight, the diluent is caused by heating. It will cause fine pores in the gelatinized film, so it is not good.-Color m, as long as it is generally used as a coloring agent for polyvinyl chloride, it is made of inorganic pigment or organic pigment and Dispersant is made into bottles. The inorganic pigments include titanium dioxide, titanium black, and the like. Organic pigments include titanium osmium blue, dioxin 0 # violet, and the like. The dispersant system includes a dispersant generally used as a polyvinyl chloride sol. The blending amount should be 5 to 50 parts by weight. If it is less than 5 parts by weight, 6 sheets of paper are applicable to China National Standard (CNS) A4 specifications (2! 0 X 297 mm) ---------- ------ Order (read the precautions on the reverse side before filling out this page) 448103 Duty printing A7 B7 by the Central Bureau of Standards of the Ministry of Economic Affairs 5. Printed description of the invention (s) The shielding of the film will become worse. If it is more than 50 parts by weight, the coating cost is increased due to excessive blending, which is unfavorable. There is no particular limitation on the method of applying the above-mentioned polyvinyl-free coating on the surface of the metal sheet, and it is possible to suspend the coating method such as roll coating and flow coating on the tail of a general metal sheet coating station. FIG. 2 is a schematic diagram showing the manufacturing steps of applying a peripheral roll. After the adhesive coating roller 5 is applied to apply the adhesive to the surface of the gold sheet 1, the peripheral baking heating furnace 6 is used for flooding, and the cooling device 7 is used for cooling to form the adhesive layer 2. Then, the roller 10 is dissolved to coat the polyvinyl chloride sol 8 containing the coarse-grained polyvinyl chloride resin 9. At this time, the gap between the sol roll 10 and the coating amount control roll 11 must be set to 'the gelled film can satisfy the formula Φ and formula ②. After coating with sol, use 12-side heating furnace to heat the plate at 200 ~ 2 20 ° C. After gelling, it is cooled by the cooling device 13 to make a cup with a concave-convex PVC-coated metal. board. In the manufacturing steps of FIG. 2, the roll coater composed of the sol roll 10 and the glue setting control roll 11 can be changed to a flow coater or other coating device. The same as the aforementioned roll coater, by Adjust the gap between the sol roller 10 and the coating amount control light 11 so that the gelled film satisfies the relationship of formulas ① and ②; in the case of a circulation coating machine, the crack size of the coating head must be adjusted to The gelled film can satisfy the relationship of formula ① and formula ②. In other painting equipments, the painting bar must also be set to the relationship between ① and 2 · 'which can be filled with leather. Fig. 1 is a cross-sectional view showing a gas-coated polyethylene-coated metal wrench produced by the above method. The polyvinyl chloride-coated metal plate with a concave-convex pattern according to the present invention is the maximum film thickness of the convex portion of the concave-convex pattern shown in FIG. 1 (X m # 7). X 297 male and female) (Please read the notes on the back before writing this page)
B7 五、發明说明（ΐ?) 必須滿足式Φ所代表的關係*其輿E部膜厚的最0値y( Μ m)Z比必須滿昆式0珩代表的關係。在式①中，由於所配 合之耝粒聚氯乙烯的平均粒徑之最恁値爲20 μ m，郑X 最低値爲20 # m，又因粗粒聚氯乙烯的平均粒g之最大 僅爲200 # m，西爲了得迅可満廷式（Z；的絛件之具有凹凸 惑的皮嘆，X之最大値必須爲4 0 0 μ m。若X之最大値超 過400 # m，則將被垤入平均粒徑200 // m之粗粒聚氯乙 烯皮膜中，而無法得出如滿足式@的條件般之具有四凸感 S.胃。 又，式©中，若y/X小於0.1，員ij耝粒聚氯乙烯樹脂所 彩成的凸部將易自皮膜脫落，若大於0.95，則將缺乏凹凸 感，而無法得出與一般使泻經彫刻金屬輥而轉寫岀之凹凸 皮膜相等程度的凹凸感，故其圖案惶將變差而不佳。 本發玥之鲷板，係依據以下所承之方法，以對溶膠塗 裝性、凹凸感、拆齒加工性、粗粒聚氯乙烯樹脂對被膜的 密著倥實施評價，並測定凹凸皮膜之凸部厚最大値X與凹 部膜厚的最小値y之比y/x、先澤度。 (1) 溶膠塗裝悝之評價方法 經濟部中央標準局負工消費合作社印製 .(請先閱讀背面之注意事項再填寫本頁) 藉甴目視以評價聚氯乙烯溶膠塗裝後之表Μ拔態。 [評價]〇：良好（無塗裝缺陷） X :不良（有塗裝缺陷） (2) 凹凸感的評價方法 藉白2維粗度計之測定庋膜表面的β心線苧均粗度 Ra衙違行評價。評價基準·係跨彫宽有砂目漠樣之金屬輥 8 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） 4 4Β υ Α7 Β7 五、發明説明（q) 的楔樣轉寫之一般壓紋加工聚氯乙烯皮膜內，以中心線平 均粗度最低程度（Ra= 1.0从m)者爲基準，中心線粗度在該 値以上之場合爲凹凸感良好1在未滿該値之場合則爲不良 [評價]〇 :良好（RPl.O m) X :不良（R a < 1.0 仁 m) (3) 折齒加工惶之評價方法 將經90 °折曲試驗之加工部的皮膜裂開藉由目視評 價之。 [評價]〇：良好（無皮膜裂開）’ X :不良（有皮膜裂開） (4) 粗粒聚氯乙烯樹脂對被膜的密著性之評價方法 以硬幣刮被膜表面，以目視觀察之後皮膜表靣凹凸的 凸部狀態。 [評價]〇：良好（凸部無脫落） X :不良（凸部有脫落） (5) 凹凸皮膜的凸部獏厚之最大値X與凹部的膜厚之 最小値y的比y/χ之測定方法 經濟部中央標準局J工消費合作社印製 (諳先閱讀背面之注意事項再填寫本頁) 凹凸皮膜的凸部膜厚的最大値X係藉囱依微量器 之膜厚測定以求出•凹部膜厚之最小値y，係藉由2維粗 度計以求出最大高Rmax，再岜X減去Rmax以求出》泫以 上的方法所求tH之X及y値，面求ϋί y / X之値15 (6) 光澤度之測定方法 藉由光澤度計以進行光澤度（6〇ύ )之測定。 本紙張尺度適用中國國家標準（CNS > Λ4規格（210 X邛7公釐） 4 4 8 1 u A7 B7 五、發明説明（又） 【實施例】 以π，藉S實施例以說明玄發明， (實跑例1 ~ 8 ) 绔接著_ 5 V m(乾燥獏厚：)塗a在經施坊電鍍處理、 化或處理之技厚〇.5mm之軟鐧板表面後，使.¾煤氣爐而在 扳溫220 ΐ下進行燒烤，經空氣泠部浚，使m輥塗機以塗 布表1、2所示配合之聚氯乙烯溶膠，之後使s煤氣爐而 在扳溫200〜2 20 °C下進行如熱，之後進行水冷而製作出聚 氯乙烯被覆金屬板。 (諳先閲讀背面之注意事碩再填寫本頁) 經濟部中央標準扃I工消費合作社印製 【表1】 i 配合! 聚氯乙烯樹脂 1 粗粒聚氯乙烯樹脂 1 1 | 平均粒徑 配合量 交聯、著 平均粒徑 配合量1 No. ( (U m) (重量部） !色之有無 (β m) (重量部）1 ! 1 ! 1 10 !無 20 90 ! 1 2 1 10 95 ： 無 200 5 丨本 3 ί 10 60 , 無 70 40 I 一 1發 4 ! 2 80 無 35 20 ί !明 5 ! 5 60 & , ν> 35 20 !的 i ' 70 20 ! 丨實 j 20 10 ! 丨施 6 ； 5 70 無 35 10 | 丨例 1 1 70 10丨 7 ! 2 80 交聯 35 20 ! I 8 3 70 ΛΑ* /7, 著色 150 30 (靑系） ί 【表2】 10 本紙張尺度適用中國國家標率（CNS ) A4規格（2丨0XM7公釐） ^ 4 48 1 〇 Λ7 B? 五、發明説明（^) I No. 配合 可塑劑 厂 (重量部）丨 本 發 明 的 實 施 1 10(TOTM) i 2 30(DOP) j il— 40(DBP) 4 35(DOP) ! 「5 20(TOTM) ! 15(DOA) 10(DOP) 6 15(TCP) ! j 15(D1DA) ! 著色劑 _ (重量部） ! 稀釋劑 丨 ；(電量部）1 __ 20(黑系） i 50ί乙基溶纖劑Η _ 50(白系） 5(石油腦）i __ 5(黑系） Ι 1〇(擴油精）； _ 40(茶系） 20(礦油精> ! 5〇(黃系） 1 40(石油腦 > 丨 例 7 i 25(DOP) i | 15(CDP) | 8 lOO(TOTM)厂 2〇(黑系） 丨100(乙基溶纖劑）i 1〇(黑系) | 50(石油腦） 1 」___ - 50(白系） _j 50(礦油精）丨 I1倫例1〜S 之聚氯乙烯被覆 釦表3所示殺，本發明的3、— 鋼板，係具有優異的溶膠塗裝性、凹凸感、折齒加工T玍 【表3】 {請先閱讀背面之注意事項再填寫本頁) 經濟部中央榇準局員工消費合作社印製 ~ 塗裝性 x y ! y/x 凹凸ΐ No. {U m) i η») I 一 1 〇 20 ίο I o.so c 本 、2 〇 (400 J80 ! 0.9s 〇 發 3 〇 75 52 : 0.69 o 明 4 〇 — 36 26 * 0*72 c 的 5 〇 78 50 ! 0.64 〇 實 6 〇 80 8 I 0.10 〇 施 7 〇 3S 25 | Φ.66 c 例 〇 ISO 145 | 0.81 o 〇 C 將接著劑5 μ m(乾燥膜厚）塗葙在經施如電鍍處理' 化或處理之枝厚〇. 5mm之軟鋼板表固後’ 谋興^ 1二 (比較例1〜4) 密著性 [仙丄一 丨〇 C ί -—~ 40.5 ίο ο ! 27.0 "! c 一 cl 36.0 〇 !〇 〇 34.5 〇! 35,0 ΟB7 V. Explanation of the invention (ΐ?) The relationship represented by the formula Φ must be satisfied * The maximum 0 値 y (Μ m) Z ratio of the film thickness of the E part must be the relationship represented by the formula 0 珩. In formula (1), the average particle size of the mixed polyvinyl chloride is 20 μm, and the minimum value of Zheng X is 20 # m. It is 200 # m. In order to obtain a quick and easy-to-use (Z;) file, the maximum size of X must be 400 μm. If the maximum size of X exceeds 400 #m, the It was immersed in a coarse-grained polyvinyl chloride film with an average particle size of 200 // m, and it was not possible to obtain the S. stomach with a four-convex sensation as the condition @ was satisfied. Also, in the formula ©, if y / X is less than 0.1, the convex parts made of PVC resin particles will easily fall off from the film. If it is greater than 0.95, the unevenness will be lacking. The film has the same degree of unevenness, so its pattern will become poor and unfavorable. The sea bream plate of this hairpin is based on the following methods to apply sol coating, unevenness, tooth removal processability, and coarse particles. The polyvinyl chloride resin evaluates the adhesion of the film, and measures the ratio y / x of the maximum thickness X of the convex part of the uneven film to the minimum thickness y of the film thickness of the concave part. (1) Evaluation method for sol coatings Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. (Please read the precautions on the back before filling out this page) Visually evaluate the PVC sol coatings The following table shows the drawing state. [Evaluation] 〇: Good (without coating defects) X: Defective (with coating defects) (2) Evaluation method of unevenness Measure the β on the surface of the film with a white 2-dimensional roughness meter Heart line 苎 average thickness Ra 衙 evaluation of violations. Evaluation criteria · It is a cross-carved metal roll with sand grains and a desert-like metal roll. 8 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 4 4B υ Α7 Β7 V. Wedge-shaped transfer of the general description of the invention (q) In the general embossed polyvinyl chloride film, the minimum thickness of the center line (Ra = 1.0 from m) is used as the benchmark. Above 値, the unevenness is good. 1 If it is less than 値, it is bad. [Evaluation] 〇: Good (RPl.0 m) X: Bad (R a < 1.0 kernel m) (3) Folding teeth processing 惶Evaluation method The film of the processed portion subjected to the 90 ° bending test was cracked and evaluated visually. [Evaluation] 0: Good (No film cracking) 'X: Defective (with film cracking) (4) Evaluation method of the adhesion of the coarse-grained polyvinyl chloride resin to the film The surface of the film was scratched with a coin, and the protrusions on the surface of the film were visually observed [Evaluation] 〇: Good (no protrusion in the convex portion) X: bad (the protrusion in the convex portion falls) (5) The ratio of the maximum thickness of the convex portion of the uneven film 値 X to the minimum film thickness of the concave portion y / Measured by χ Printed by J Industry Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs (谙 Please read the precautions on the back before filling in this page) The maximum film thickness of the convex part of the uneven film Calculate the minimum 凹 y of the film thickness of the recessed part to obtain the maximum height Rmax by using a two-dimensional thickness meter, and then 岜 X minus Rmax to find the X and yt of tH obtained by the method above. Find ϋ y / X 値 15 (6) Gloss measurement method Gloss meter is used to measure gloss (6〇ύ). This paper size applies the Chinese national standard (CNS > Λ4 specification (210 X 邛 7 mm) 4 4 8 1 u A7 B7 V. Description of the invention (again) [Example] Take π and S examples to explain the mysterious invention (Experimental examples 1 to 8) 绔 Then _ 5 V m (dry 貘 thickness :) coated a on the soft slab surface with a thickness of 0.5mm after electroplating, chemical treatment or treatment by Shifang. ¾ gas The oven was grilled at a temperature of 220 ° C. After being air-dried, the m roll coater was used to coat the polyvinyl chloride sol compounded in Tables 1 and 2. Then, the gas stove was heated at a temperature of 200 ~ 2 20. It is heated at ° C and then water-cooled to produce a PVC-coated metal sheet. (谙 Read the cautions on the back before filling in this page) Printed by the Central Standard of the Ministry of Economic Affairs I Industrial Consumer Cooperatives [Table 1] i Mixing! Polyvinyl chloride resin 1 Coarse-grained polyvinyl chloride resin 1 1 | Average particle size blending amount Crosslinked, average particle size blending amount 1 No. ((U m) (weight part)! Is there a color (β m)? (Weight part) 1! 1! 1 10! No 20 90! 1 2 1 10 95: No 200 5 丨 Ben 3 ί 10 60, No 70 40 I One 1 round 4! 2 80 No 35 20 ί! Ming 5! 5 60 &, ν > 35 20! i '70 20! 丨 real j 20 10! 丨 Shi 6; 5 70 without 35 10 | 丨 Example 1 1 70 10 丨 7! 2 80 Cross-linking 35 20! I 8 3 70 ΛΑ * / 7, coloring 150 30 (靑 system) ί [Table 2] 10 This paper size is applicable to China National Standards (CNS) A4 specification (2 丨 0XM7 mm) ^ 4 48 1 〇 Λ7 B? V. Description of the invention (^) I No. Coordination with plasticizer factory (weight part) 丨 Implementation of the invention 1 10 (TOTM) i 2 30 (DOP) j il—40 (DBP) 4 35 (DOP)! "5 20 (TOTM)! 15 (DOA) 10 (DOP) 6 15 (TCP)! J 15 (D1DA)! Colorant _ (weight part)! Thinner 丨; (electricity part) 1 __ 20 (black) i 50ί ethyl fibrinolytic agent _ 50 (white) 5 (petroleum) i _ 5 (black) Ι 10 (oleagin); _ 40 (tea) 20 (mineral spirits)! 5〇 (Yellow series) 1 40 (Petroleum brain)> Example 7 i 25 (DOP) i | 15 (CDP) | 8 100 (TOTM) plant 20 (black series) 100 (ethyl cellosolve) i 1〇 (Black series) | 50 (petroleum brain) 1 ”___-50 (white series) _j 50 (mineral spirit) 丨 I1 case 1 ~ S polyvinyl chloride coating buckle As shown in 3, the steel plate of 3 of the present invention has excellent sol coating properties, unevenness, and crease processing. T 玍 [Table 3] {Please read the precautions on the back before filling this page) Central Ministry of Economic Affairs Printed by the Consumer Affairs Cooperative of the Associate Bureau ~ Paintability xy! Y / x Concave and convex ΐ No. (U m) i η ») I-1 〇20 ίο I o.so c book, 2 〇 (400 J80! 0.9s 〇 Issue 3 〇75 52: 0.69 o Ming 4 〇—36 26 * 0 * 72 c 5 〇 78 50! 0.64 〇 Real 6 〇80 8 I 0.10 〇 Application 7 〇3S 25 | Φ.66 c Example 〇ISO 145 0.81 o 〇C The adhesive 5 μm (dry film thickness) was coated on the surface of a mild steel plate with a thickness of 0.5mm after being treated by electroplating, etc. Mou Hing ^ 12 (Comparative Example 1 ~ 4) Adhesiveness [仙 丄 一 丨 〇C ί -— ~ 40.5 ίο ο! 27.0 "! c one cl 36.0 〇! 〇〇34.5 〇! 35,0 Ο
C 10.0 28.0 板溫2 2 0 r工進行烘烤，經空氣冷鹆後’便帛輕塗機以塗 本紙垠尺度適用中國國家楳準（CNS ) Α4現格（2l〇X四7公釐） A7 B7 苻表4 五、發明説明（ 衔示配合之聚氯乙烯溶膠 在钣溫200〜2 2 0 °C下進行加熱，之後進行水冷而製佇岀聚 氯乙烯按覆金屬扳= 【表Ο 配合 聚氯乙烯樹脂 粗粒聚氯乙烯樹脂C 10.0 28.0 Plate temperature 2 2 0 r Baking, air-cooled, and then “coated with light paper, coated with paper. The scale is applicable to China National Standards (CNS). A4 (2l0 × 47mm) A7 B7 苻 Table 4 V. Description of the invention (The blended polyvinyl chloride sol is heated at a sheet temperature of 200 ~ 220 ° C, and then water-cooled to make the polyvinyl chloride. Press the metal cover = [表 〇 Coarse-grained polyvinyl chloride resin
No. 本發 配合量i交聯、著i平均粒徑 (重量部）i色之有無！ m) 配合量 (重量部） i平均粒徑 ί (β m) I ίο «fiTC 無 12 的較列 明比f 2 ! 2-. 5 jfnt Μ 1 70 95 3 ί (lQ ) 90 Μ ΤΤνί ί ί·.、 10 4 ί. 1 10 無 I ν5〇·" 90 TJ 5 表 α 辅_臟例 配合 可塑劑 丨 (重量部）i 著色劑 (重量部） 稀釋劑 (重量部） 1 30(DOP) 2〇(黑系） 5〇(石油腦） 2 50(DIDA) ! ί〇(黑系） 1〇〇(礦油精） 3 5(DBP) j 5〇(白系） 5(礦油精） 4 ΙΟ(ΤΟΤΜ) ; 40孫系） 150(乙基溶纖劑) i n ’- 1 II -- - —γ..^--- if I -- τ f t 、νό t請先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消费合作社印製 诩表6 m示般，本發明的比較例1〜4之聚氯乙烯被覆 鐵板，译無法同時滿足溶膠塗裝性、G£j凸感、折曲加工性 【表6】 i No. 試驗 塗裝性 • X (μ m> ! y 1 J 1 (/ί m) i y/x 凹凸感 . 折曲 加工性 粗粒 密著性 光澤度 ;本丨 1 〇丨 16 I 16 ί 1,00 X 〇 〇 85.0 丨發明丨 2 X ( 1 無法 丨無法1 無法 無法 無法 無法 無法 的ί ； 測定 丨測定1 測定 評價 評價 評價 評價 丨比較; 3 〇 1 39S I 374 ^ 0.94 〇 X 〇 32.0 例 4 ο ί 58 rvi 0.05 〇 〇 X 27.0 苯發荚之具有凹凸模樣的聚氯乙烯祛覆金屬极之圖 案性及扼工性·優異，又·泫玄發明之製造方法·不需使罔 12 本紙張尺度適用中國國家標準（CNS > A4規格（2ί〇Χ297公釐） 4 4- « ···· j Α7 Β7 五、發明説明（ί丨） 彫刻有模樣之金羼輥等即可形成□凸篌樣；又*就算在使 用彫刻有模樣之金屣輥以轉寫模樣之方法中轉寫困難之 薄膜，由於仍可賦予凹凸感，故其經濟拄極優·西極適於 作爲建材、家電製品用之化粧鋼枝= r ' 【圖式之簡單說明】 j圖1係本發玥之聚氯乙烯铵覆金屬扳的新面 圖2係本發明钓聚氯乙烯被覆金屬I反製造步驟的模式 圖。 【符號之說明】 1〜金屬板，2〜接著劑層，3〜聚氯乙烯被覆層，4〜展 捲機，5〜接著劑塗布輥，6〜烘烤加熱爐，7〜冷卻裝置.， 8〜聚氯乙烯溶膠，9〜耝粒聚氯乙烯樹脂，10〜溶膠輥， 11〜塗膠量控制輥，12〜烘烤加熱爐，13〜冷卻裝置，14〜 捲繞機。 (讀先閲讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印裝 本紙張尺度適用中國國家標準（CNS ) A4规格（21〇XW7公釐）No. This product Is the amount of i cross-linked, the average particle size of i (weight part), the presence or absence of i color! m) blending amount (weight part) i average particle size ί (β m) I ίο «fiTC no more than the specified ratio f 2! 2-. 5 jfnt Μ 1 70 95 3 ί (lQ) 90 Μ ΤΤνί ί ·., 10 4 ί. 1 10 No I ν5〇 · " 90 TJ 5 Table α Auxiliary_Dirty example of plasticizer 丨 (weight part) i Colorant (weight part) Thinner (weight part) 1 30 (DOP ) 2〇 (black) 5〇 (petroleum brain) 2 50 (DIDA)! Ί〇 (black) 1〇〇 (mineral spirit) 3 5 (DBP) j 5〇 (white) 5 (mineral oil) 4 ΙΟ (ΤΟΤΜ); 40 grandchildren) 150 (ethyl cellosolve) in '-1 II--—γ .. ^ --- if I-τ ft, νό t Please read the notes on the back first (Fill in this page again.) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. The table 6 m shows that the PVC-coated iron plates of Comparative Examples 1 to 4 of the present invention cannot meet the requirements of sol coating properties and G £. jConvexity, bending workability [Table 6] i No. Test paintability • X (μ m >! y 1 J 1 (/ ί m) iy / x Roughness. Bending workability Coarse grain adhesion Gloss; this 丨 1 〇 丨 16 I 16 ί 1,00 X 〇〇85.0 丨 invention 丨 2 X (1 cannot丨 Impossible 1 Impossible Impossible Impossible; Determination 丨 Determination 1 Determination Evaluation Evaluation Evaluation Comparison 丨 Comparison; 3 〇1 39S I 374 ^ 0.94 〇X 〇32.0 Example 4 ο 58 rvi 0.05 〇〇X 27.0 Polyvinyl chloride with metal embossed pattern has excellent patternability and sturdiness. It is also excellent in manufacturing method invented by Xuan Xuan. No need to use 罔 12 This paper size is applicable to Chinese national standards (CNS > A4 size (2ί) 〇Χ297mm) 4 4- «···· j Α7 Β7 V. Description of the Invention (ί 丨) Gold engraved rollers with patterns can be engraved with embossed patterns; and * even when using engraved gold The roll film is difficult to transfer in the method of transfer mode, because it can still give a bumpy feeling, so it is very economical. West is suitable as a cosmetic steel stick for building materials and home appliances = r '[Schematic Brief description] Figure 1 is a new view of the PVC ammonium-coated metal plate of the present invention. Figure 2 is a schematic diagram of the anti-manufacturing steps of the PVC-coated metal I of the present invention. [Explanation of the symbols] 1 ~ Metal plate, 2 ~ adhesive layer, 3 ~ PVC cover Coating, 4 ~ roller, 5 ~ adhesive coating roll, 6 ~ baking heating furnace, 7 ~ cooling device., 8 ~ polyvinyl chloride sol, 9 ~ powder polyvinyl chloride resin, 10 ~ sol roll, 11 ~ applicable amount control roller, 12 ~ baking heating furnace, 13 ~ cooling device, 14 ~ winding machine. (Read the precautions on the back before you fill in this page.) Order Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs This paper applies the Chinese National Standard (CNS) A4 specification (21 × W7 mm)