445138 五、發明說明（i) A7 修正 89J1.2〇 本子月曰補充 本發明係與-種鞋底村料有關更詳而言之，特別是 指-種利用再生資源回收利用之具環保意義之鞋底材料製 造方法。 I!----------- S--- (請先閱讀背面之注意事項再填寫本頁) 知由於人_的過度使用塑膠、橡膠製品，且在塑膠、 橡勝製品無法有效θ收爯峰 双口收丹生利用的情況下，人類的生存垓 境曰益惡化，有緊於此，咨.κ 签於此貧源回收已成為現代人為保護生 存環境所必須積極解決的課題。 ;# 其中塑膠廢棄物包括塑膠容器（瓶類、盒類、包裝材 料、其他=類塑膠製品），而橡膠廢棄物包括鞋底、廢棄輪 L膠板等’尤其以廢棄輪胎為最大宗來源，雖然環保署 設有廢棄物目收單位，且在全國設有多冑之廢棄才勿處理 廠在·將塑膠、橡膠廢棄物回收後再生為塑膠、橡膠原料， 以供利用’惟’業界雖有採用該等再生材料，自皆將再生 材料用作填充料之性質，仍須配合大量的天然生膠或人造 生膠，對於再生材料並未大量使用，故在再生材料使用率 不高之狀態下，資源回收的工作亦受到阻礙。 有鑑於斯，本案發明人乃經詳思細索’並積多年從事 專業研究開發經驗，終而有本發明之誕生。 經濟部智慧財ii?員工消費合作社印製 即，本發明之主要目的在於提供一種具環保意義之鞋 底材料製造方法’係可有效並大量應用再生橡膠及再生塑 膠材料’不僅可減少使用天然生膠或人造膠生料，且可使 回收資源充份使用，而達到環境保護之目的π 緣是’依據本發明所提供之一種具環保意義之鞋底材 料製造方法’係選用再生橡膠原料為Α料、再生塑膠原料為 第3頁 本紙張尺度適用中囤國家標準（CNS)A4規格（210 X 297公釐） d4513 8 經濟部智慧財產局員工消費合作社印製 修正太嗖42〇 +年月日 補充 五、發明說明（2) 1料、填充劑為c料、加硫举。劣 ” 為D料，且再生橡膠原料之成 伤比為3 0 % ~ 8 5 % ’其係以天抄 入然橡膠、人造橡膠產品之廢棄 物再生而成；該再生塑膠原料 ' 竹成份比為1 0 %〜6 0 % ，其係以 聚苯乙烯（PS )、财撞擊平分 Η里罕+本乙烯（HIPS)、丙烯腈丁二 稀苯C稀聚合物（關㈣製品再生而成，該填充劑可為 黑煙白煙鈣石粉' 粘土粉’其成份比為0 %〜2 0 0 % ,該加 硫藥品可為硫磺系統、加硫劑、加硫促進劑、促進助劑， 接著將A料、B料、C料混合均勾，其混合溫度以1〇吖以上 為較佳，並冷卻至室溫再加入〇料，並使〇料與A料' β料、c 料再混合均勾，續將Α料' Β料、C料及D料依預定比例在冷 卻滾輪中進行混合且混練然後出片，且依模具大小、厚薄 而裁製.成適當尺寸之胚料，最後將上述之胚料置入具有花 紋之鞋底模具中，並經加熱加壓2〜丨5分鐘，其加熱溫度以 100°c 〜170°C為較佳，而施加壓力則以5kg /clfl2〜15〇kg /cm2 為較佳’當加硫完成即獲得強韌、耐磨之鞋底材料，另外， 採用材料中更可加入發泡劑，而可製成發泡鞋底材料。 有關本發明所採用之技術、手段及其功效，茲舉二較 佳實施例並配合圖式詳細說明如后，相信本發明上述之目 的、構造及特徵，當可由之得一深入而具體的瞭解。 圖式之簡單說明： 第一圖係本發明第一較佳實施例之製造流程圖。 第二圖係本發明第二較佳實施例之製造流程圖。 請配合參閱第一圖，本發明第一實施例具環保意義之 第4頁 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------ t ----訂-| — |!_^4· ί請先閱讀背面之注意事項再填寫本頁) 445138 修正 saR2〇 本年月 補充 五、發明說明（3 ) 鞋底材料製造方法，大Λ Α ω上包含下列步驟： 步驟一：選用下列材料： 1. Α料·為主原料，且為再生橡膠原料，成份比為3⑽ 〜85% ，實際使用量以40%〜65%為佳，其係以天穷 橡躍、人造橡膠等材質所製成產品之廢棄物再生市 成，例如廢棄輪胎、廢鞋底、廢橡膠板等。 2. B料：為次原料，且為再生塑膠原料，成份比為1 〇% 60% ，實際使用量以15%〜5〇%為佳，其係以聚輩 乙稀（PS) '耐撞擊聚苯乙烯（HIPS)、丙婦精丁 二烯苯乙烯聚合物（)等材質所製成塑膠製品 之廢棄物再生而成，例如塑膠瓶、塑膠容器、塑膠 •盒、包裝材料等。 3. C料：填充劑，如黑煙、白煙勞石粉、枯土粉，其成 份比為0%〜200 % ，係依所需硬軟度而加入適當之 成份比例，實際使用量以〇%〜丨〇〇%為佳’可免用 或高量填充補強，係因主原料 ^ ^ , 生膠源自廢輪胎 寺再生而來’而原來的材料配方中已含士 等填充劑，故在本配方中或可务 疋善之 兄用，如·每狂— 但如工作鞋底需要較大比重時， ，t底鲁 、Ί而較意 故以0¾〜100¾可適合各類鞋底材料戶充I 4 D料：加硫藥品，包含加硫劑、力 需 劑’該加硫劑如硫績及其衍生物 旬及促驾 (peroxi d類’如D、C、P等），抵为機场氣分 J 使用量氣 % ，可加硫架橋形成強大之高分子， 馬0·5% ，加 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） I! '裝--------訂---------^ (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印5< 445138 A7 B7445138 V. Description of the invention (i) A7 Amendment 89J1.2. This month said that the present invention is related to a kind of soles and village materials. More specifically, it refers to a kind of environmentally-friendly soles that use renewable resources for recycling. Material manufacturing method. I! ----------- S --- (Please read the precautions on the back before filling out this page) I know that due to excessive use of plastics and rubber products by people, In the case of effective theta harvesting and double-harvest harvesting, the survival environment of human beings is deteriorating, so it is urgent to stop here. Κ Signed here The recycling of poor sources has become a problem that must be actively solved by modern people in order to protect the living environment . ; # Where plastic waste includes plastic containers (bottles, boxes, packaging materials, other = plastic products), and rubber waste includes shoe soles, waste rubber sheets, etc. 'Especially waste tires are the largest source, although The EPA has a waste collection unit, and there are multiple waste disposal plants throughout the country. Recycling plastic and rubber waste into plastic and rubber raw materials for recycling. These recycled materials all use the nature of recycled materials as fillers. They must still be used with a large amount of natural or artificial raw rubber. There is not a large amount of recycled materials used. Therefore, in the state where the utilization rate of recycled materials is not high, Recycling efforts have also been hampered. In view of this, the inventor of this case has carefully thought out and accumulated many years of professional research and development experience, and finally the invention of this invention was born. Printed by the Ministry of Economic Affairs ii? Printed by employee consumer cooperatives, that is, the main purpose of the present invention is to provide an environmentally-friendly manufacturing method for sole materials 'can effectively and widely use recycled rubber and recycled plastic materials' not only can reduce the use of natural raw rubber Or synthetic rubber raw materials, and can make full use of recycled resources to achieve the purpose of environmental protection. The reason is that 'a method for manufacturing sole materials with environmental significance according to the present invention' is selected from recycled rubber raw materials as material A, Recycled plastic raw materials are on page 3. This paper is applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) d4513 8 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. 2. Description of the invention (2) 1 material, filler is material c, and sulfur is added. “Inferior” is D material, and the damage ratio of recycled rubber raw materials is 30% ~ 85%. It is regenerated from wastes of natural rubber and artificial rubber products; the recycled plastic raw materials ’bamboo content ratio It is 10% ~ 60%. It is made of polystyrene (PS), birilyn + biethylene (HIPS), acrylonitrile butadiene benzene C dilute polymer (reproduced from Seki products). The filler can be smoky white baconite powder 'clay powder' whose composition ratio is 0% ~ 200%. The sulfurized medicine can be a sulfur system, a sulfurization agent, a sulfurization accelerator, and a promoter. Then, Mix material A, material B and material C together, and its mixing temperature is preferably above 10 ac, and cool to room temperature before adding material 0, and mix material 0 with material A, β and material C. Hook, continue to mix material A, material B, material C, and material D in a cooling roller according to a predetermined ratio and knead them out, and then cut out the pieces, and cut them according to the size and thickness of the mold. The blank is placed in a mold with a patterned sole and heated and pressed for 2 to 5 minutes. The heating temperature is preferably 100 ° c to 170 ° C. The applied pressure is preferably 5kg / clfl2 ~ 150kg / cm2. When the vulcanization is completed, a strong and wear-resistant sole material is obtained. In addition, a foaming agent can be added to the material to make the hair. Sole material. Regarding the technology, means and effects used in the present invention, two preferred embodiments are described in detail below with reference to the drawings. It is believed that the above-mentioned purpose, structure and characteristics of the present invention can be obtained in-depth. And the specific understanding. Brief description of the drawings: The first figure is a manufacturing flowchart of the first preferred embodiment of the present invention. The second figure is the manufacturing flowchart of the second preferred embodiment of the present invention. Please refer to the first for cooperation. Figure, page 4 of the first embodiment of the present invention with environmental significance. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------------ t --- -Order- | — |! __ 4 · ί Please read the notes on the back before filling in this page) 445138 Amendment saR2〇 Supplement this month, 5. Description of the invention (3) Manufacturing method of sole material, large Λ Α ω contains The following steps: Step 1: Select the following materials: 1. Α material · main raw material, It is a recycled rubber raw material with a composition ratio of 3% to 85%, and the actual use amount is preferably 40% to 65%. It is a waste recycling market for products made of materials such as Tianqiongyue and artificial rubber, such as waste. Tires, waste shoe soles, waste rubber sheets, etc. 2. Material B: is a secondary material and is a recycled plastic material, with a composition ratio of 10% to 60%, and the actual usage is preferably 15% to 50%, which is based on Polyethylene (PS) 'impact resistant polystyrene (HIPS), polybutadiene styrene polymer () and other plastic products made of plastic waste, such as plastic bottles, plastic containers, Plastic boxes and packaging materials. 3. Material C: Filler, such as black smoke, white smoky stone powder, and dry earth powder. Its composition ratio is 0% ~ 200%. It is added according to the required hardness and softness, and the appropriate composition ratio is added. The actual amount used is 0%. ~ 丨 〇〇% is better 'can be used free or high-volume filling reinforcement, because the main raw materials ^ ^, raw rubber comes from waste tire temple regeneration' and the original material formula already contains fillers and other fillers, so This formula may be used by good brothers, such as · Every crazy—but if the sole of the work requires a large proportion, t Dilu, Ί and deliberately with 0¾ ~ 100¾ can be suitable for various types of sole material household charge I 4 Material D: Vulcanized medicines, including vulcanizing agents and demand agents 'The vulcanizing agent such as sulfur performance and its derivatives and driving promotion (peroxi d' such as D, C, P, etc.), can be regarded as airport gas It can be used as gas% in J. It can be bridging with sulfur to form a strong polymer, 0.5% in horsepower. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm). I! ----- Order --------- ^ (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5 & 445 138 A7 B7
修正u明.11. 2G 本年月曰 補充 五、發明說明（4 ) 傳統所用者同，如D、DM、Μ、CZ、TT、TS等，使用 量為0, 5%〜5% 、促進助劑如硬脂酸、軟脂睃、松 脂、氧化辞、氧化鎂' 氧化鈣、硬脂酸鋅等，使用 量為1 %〜1 0 % ，有機過氧化物、加硫促進劑、促 進助Η1丨係依需要而調整劑量，促進劑在本配方中或 可免用’俾因Β料為塑膠，故可經由氧化物直接架 橋而呈強韌之網狀巨大分子。 步驟二：將上述Α料、Β料、C料混合均勻，其混合溫度 以10 0 C以上為較佳，並冷卻至室溫再加入〇料，才不致於 發生繞焦現象，並使D料與a料、β料、C料再混合均勻。 步碌三：將A料' B料' C料及D料依預定比例在冷卻滾 輪中進行混合且混練然後出片’且依模具大小、厚薄而裁 製成適當尺寸之胚料將A料、B料、c料及D料依預定比例在 >部'袞輪中進行混合且混練然後出片，且依模具大小、厚 4而裁製成適當尺寸之胚料。 步驟四：將上述之胚料置入具有花紋之鞋底模具中， 二加熱加壓2 ~ 1 5分鐘，其加熱溫度以1 〇 〇 〇c 11 7 〇。匸為較 佳’而施加壓力則以5kg /cm2〜150kg /cm2為較佳。 步驟物：加硫完成即獲得強韌、耐磨之鞋底材料。 藉由以上步驟所製成之鞋底材料，具有以下功效： (一）本發明所應用的材料A料及B料均是資源回收再 1原料，A料為棄輪胎、廢鞋底、廢橡膠板等製成之再生橡 躍，而B料為塑膠瓶、塑膠容器、塑膠盒、包裝材料等製成 之塑膠再製料，再與C料、！)料等配合製成，既經濟又環保、 國家標準（CNS)A4 規格（210 --^----------- 1--------訂—-------,^* (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 297公釐） 445138 A7 B7 五、發明說明（5) 清潔。 (二）傳統之鞋底製造技術中， 修正拟Η 2# 本畀月Β 補充 s ^ 鞋底材料雖或有採用 再生橡膠，然其材料地位是填充料 κ， 寸之性質，仍須配合大量 主原料之天然生膠或人造膠生料， , ^ _有再生膠單獨使用情 形’更未有混合塑膠再生料之使用& 用吻例，與本發明相較， 再生橡膠為主原料，使用量大。 (三） 填充料實為補強材料之性質，在傳統的鞋底製 造過程中，填充料是必需使用的材科，在成本及比重上均 會增…本發明之製造方法中亦可完全不使用填充劑， 俾因Α料為再生橡膠’而再生橡膠之大宗來源又取自廢輪 月〇 /、原本成伤上均有具備，故本發明不加填充料乃絕對 可行’·進而可降低製造成本。 · (四） 傳統製作鞋底材料時’必需使用硫磺物為主加 硫劑，而本發明亦可選擇性使用，但亦可改用有機過氧化 物為加硫劑而不需促進劑，因本發明材料構成之B料為塑 膠故可經由過氧化物直接架橋而呈強韌之網狀巨大分子之 故；是以，亦可減少促進劑的使用。 另外，當欲製作發泡鞋底材料時，如第二圖所示，其 製造步驟大致上與上述實施例相同，惟不同的是，構成要 素中添加一 E料，該E料為發泡劑，如D P T、A D C A等，成份比 為1 % ~ 5 %為佳，且是在A料、B料、C料混合均勻且冷卻後 再與D料同時加入，俾藉£：斜之添加，及應用各步騾之搭配， 可製成發泡鞋底。 值得一提的是，在上述實施例中’亦可添加部份新料 第7頁 本纸張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------------* 裂·! I — 1 — — — !^ C請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 445 1 38 A7 B7 修正 S幻L Μ 本导月日 補充 五、發明說明（6) 以取代Α料及Β料。 藉由以上之說明可知，本發明可大量使用再生橡膠及 再生塑膠原料，並應用於產量極大之鞋底材料上，不僅可 減少使用天然生膠、人造勝生料等，且最重要的是可利用 廢棄物回收而再生資源，對於環境的保護產生極大之助 益，且極具產業上利用價值。 綜上所述，本發明之技術思想確屬高度創作，同時查 遍國内外關於此類結構之技術資料、文獻中亦未發現有相 同的構造的技術存在在先’是以’本發明實已具備發明專 利要件，爰依法提出申請。 雖然本發明已關於被梘為是最實用和最佳實施例來說 明’但是可瞭解的是本發明不被限制於所揭露之實施例 中’而是用來涵蓋包括於本發明精神和最廣解釋範圍内的 各種設計’以便囊括所有此種的改良和同等設叶。 (請先閱讀背面之注意事項再填寫本頁) --!訂！---I I . 經濟部智慧財產局員工消費合作社印5取 本紙張尺度適用中國國家標準（CNS>A4規格（210 X 297公釐）Amend u Ming. 11.2G This month, the fifth supplementary description of the invention (4) Traditional users are the same, such as D, DM, M, CZ, TT, TS, etc., the usage is 0, 5% ~ 5%, promote Auxiliaries such as stearic acid, palmitate, turpentine, oxidizing agent, magnesium oxide, calcium oxide, zinc stearate, etc., used in an amount of 1% to 10%, organic peroxides, sulfurization accelerators, promoting aids Η1 丨 is to adjust the dosage as needed. Accelerators may be used in this formula. 俾 Because the B material is plastic, it can be bridged by oxides to form a strong network of giant molecules. Step 2: Mix the above materials A, B, and C evenly, and the mixing temperature is preferably 100 C or more, and then cool to room temperature and then add 0, so that the coking phenomenon does not occur, and D material Mix with material a, material β and material C evenly. Step three: Mix material A, material B, material C and material D in a cooling roller according to a predetermined ratio and knead and then produce tablets. And cut the material into the appropriate size according to the mold size and thickness. Material A and B Material, material C and material D are mixed and kneaded in the > part 'round according to a predetermined ratio, and then the tablets are produced, and the blank is cut into an appropriate size according to the mold size and thickness 4. Step 4: Put the aforementioned blank into a patterned sole mold, and then heat and press for 2 to 15 minutes. The heating temperature is set to 1000 c 1 17. "Is better" and the pressure is preferably from 5 kg / cm2 to 150 kg / cm2. Steps: Tough and wear-resistant sole material is obtained after sulfurization. The sole material made by the above steps has the following effects: (1) The materials A and B used in the present invention are all raw materials for resource recovery, and the material A is made of discarded tires, waste soles, and waste rubber plates. Cheng's recycled rubber leap, and the B material is a plastic re-material made of plastic bottles, plastic containers, plastic boxes, packaging materials, etc., and then with the C material ,! ) Materials and other materials, both economical and environmentally friendly, national standard (CNS) A4 specifications (210-^ ----------- 1 -------- order ------ ---, ^ * (Please read the notes on the back before filling out this page) 297 mm printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 445138 A7 B7 V. Description of the invention (5) Clean. (2) In the traditional shoe sole manufacturing technology, amend Η 2 # this month B supplement s ^ Although the sole material may use recycled rubber, its material status is the filler κ, the nature of the inch, must still be matched with a large number of main raw materials Natural rubber or synthetic rubber raw materials, ^ _recycled rubber is used alone ', and there is no use of mixed plastic recycled materials & use case. Compared with the present invention, recycled rubber is the main raw material and the amount is large. . (3) Filling material is really a reinforcing material. In the traditional shoe sole manufacturing process, the filling material is a material material that must be used, which will increase in cost and proportion ... The manufacturing method of the present invention can also not use filling at all. Agent, because the A material is recycled rubber, and the major source of recycled rubber is taken from the waste wheel month, and it is originally available on the original wound. Therefore, it is absolutely feasible without the filler in the present invention, and the manufacturing cost can be reduced. . (4) Traditional manufacturing of sole materials must use sulfur as the main vulcanizing agent, and the present invention can also be used selectively, but organic peroxides can also be used as vulcanizing agents instead of accelerators. The B material composed of the invention material is plastic, so it can be bridged by peroxide to form a strong network-like giant molecule; therefore, the use of accelerators can also be reduced. In addition, when a foamed sole material is to be manufactured, as shown in the second figure, the manufacturing steps are substantially the same as the above embodiment, except that an E material is added to the constituent elements, and the E material is a foaming agent. For example, DPT, ADCA, etc., the composition ratio is preferably 1% to 5%, and it is added after the materials A, B, and C are evenly mixed and cooled, and then added with material D at the same time. The combination of each step can be made into a foam sole. It is worth mentioning that in the above embodiment, 'some new materials can also be added. Page 7 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -------- ------ * Cleavage! I — 1 — — —! ^ C Please read the notes on the back before filling out this page) Printed by the Intellectual Property Bureau Employee Consumer Cooperatives of the Ministry of Economic Affairs 445 1 38 A7 B7 Amend S Magic L Μ This guide will supplement V. Invention Description (6) to replace materials A and B. From the above description, it can be known that the present invention can use a large amount of recycled rubber and recycled plastic raw materials and apply it to shoe sole materials with great output. Not only can reduce the use of natural raw rubber, artificial raw materials, etc., but most importantly, it can be used and discarded Recycling resources and regenerating resources have great benefits for the protection of the environment and have great industrial utilization value. In summary, the technical idea of the present invention is indeed highly creative. At the same time, we have searched domestic and foreign technical information on such structures, and have not found that the same structure of the technology exists in the literature. With the requirements of invention patents, apply according to law. Although the present invention has been described with regard to what is considered to be the most practical and preferred embodiment, it is to be understood that the invention is not limited to the disclosed embodiments, but is intended to encompass the spirit and broadest aspects of the invention. Explain the various designs within the scope 'in order to encompass all such improvements and equivalence. (Please read the notes on the back before filling this page)-! Order! --- I I. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, 5 copies This paper size applies to Chinese national standards (CNS > A4 specifications (210 X 297 mm)