TW442990B - Battery having printed label - Google Patents

Battery having printed label Download PDF

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Publication number
TW442990B
TW442990B TW088114330A TW88114330A TW442990B TW 442990 B TW442990 B TW 442990B TW 088114330 A TW088114330 A TW 088114330A TW 88114330 A TW88114330 A TW 88114330A TW 442990 B TW442990 B TW 442990B
Authority
TW
Taiwan
Prior art keywords
battery
current collector
space
label
printed
Prior art date
Application number
TW088114330A
Other languages
Chinese (zh)
Inventor
Gary R Tucholski
Original Assignee
Eveready Battery Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eveready Battery Inc filed Critical Eveready Battery Inc
Application granted granted Critical
Publication of TW442990B publication Critical patent/TW442990B/en

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/04—Cells with aqueous electrolyte
    • H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H01M6/08—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with cup-shaped electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/116—Primary casings; Jackets or wrappings characterised by the material
    • H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
    • H01M50/126—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/116—Primary casings; Jackets or wrappings characterised by the material
    • H01M50/117—Inorganic material
    • H01M50/119—Metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/131—Primary casings; Jackets or wrappings characterised by physical properties, e.g. gas permeability, size or heat resistance
    • H01M50/133—Thickness
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/147—Lids or covers
    • H01M50/148—Lids or covers characterised by their shape
    • H01M50/154—Lid or cover comprising an axial bore for receiving a central current collector
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/147—Lids or covers
    • H01M50/166—Lids or covers characterised by the methods of assembling casings with lids
    • H01M50/171—Lids or covers characterised by the methods of assembling casings with lids using adhesives or sealing agents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/172—Arrangements of electric connectors penetrating the casing
    • H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
    • H01M50/182—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for cells with a collector centrally disposed in the active mass, e.g. Leclanché cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/543—Terminals
    • H01M50/552—Terminals characterised by their shape
    • H01M50/559—Terminals adapted for cells having curved cross-section, e.g. round, elliptic or button cells
    • H01M50/56—Cup shaped terminals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/147—Lids or covers
    • H01M50/166—Lids or covers characterised by the methods of assembling casings with lids
    • H01M50/167—Lids or covers characterised by the methods of assembling casings with lids by crimping

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Primary Cells (AREA)

Abstract

An electrochemical cell constructed in accordance with the present invention includes a can for containing electrochemical materials including positive and negative electrodes and an electrolyte, the can having an open end and a closed end; a pressure relief mechanism formed in the closed end of the can for releasing internal pressure from within the can when the internal pressure becomes excessive; a first outer cover positioned on the closed end of the can to be in electrical contact therewith and to extend over the pressure relief mechanism; a second outer cover positioned across the open end of the can; and an insulator disposed between the can the second outer cover for electrically insulating the can from the second outer cover. According to another embodiment, the second cover is dielectrically isolated from a current collector.

Description

A7 > A42 9 9 0 B7 五、發明說明（1 ) 相關申請案交叉參考 本案係主張於1998年10月2日提出之60/102,951號及1998 年8月21日提出之60/097,445號美國專利暫時申請案。 發明背景 本發明大致係關於一種電化學電池結構，較特別的是本 發明關於用在一電化學電池如鹼性電池之容器及集流器總 成。 圖1揭示一習知C尺寸鹼性電池10之結構，如圖示，電池 10包括一具有開口端與封閉端之筒形罐體12，罐體12最好 由一導電材料製成，使得一外蓋體11熔接於罐醴丨2封閉端 處之一底表面14，而做爲電池之一電接觸端子。 電池10通常進一步包括一第一電極材料15，以做爲正極 (亦稱爲陰極），第一電極材料15可預先成型及嵌入罐體12 ，或可模塑定位以利接觸於罐體12之内表面。以一鹼性電 池而言，第一電極材料15通常包括二氧化錳（Mn〇2)，在第 一電極15提供於罐體12内之後，一分隔件17即嵌入由第一 電極15定義之空間内，分隔件17最好爲一非織布。分隔件 17係提供用於保持第一電極材料15以及電解質與—第二電 極材料20之混合物呈實質分隔，而容許電極材料間之離子 移送。 一旦分隔件17置入由第一電極丨5定義之孔穴内，一電解 質即配送入由分隔件17定義之空間内，且随同電解質與— 第二電極材料之混合物20,第二電極材料可做爲負極（亦稱 爲陽極）。電解質/第二電極材料混合物2〇較佳爲包括—膠 (請先閱讀背面之注意事項再填寫本頁)A7 > A42 9 9 0 B7 V. Description of the Invention (1) Cross-Reference to Related Applications This case claims US 60 / 102,951 filed on October 2, 1998 and US 60 / 097,445 filed on August 21, 1998 Patent provisional application. BACKGROUND OF THE INVENTION The present invention relates generally to an electrochemical cell structure. More particularly, the present invention relates to a container and a current collector assembly for an electrochemical cell such as an alkaline cell. FIG. 1 discloses the structure of a conventional C-size alkaline battery 10. As shown, the battery 10 includes a cylindrical can 12 having an open end and a closed end. The can 12 is preferably made of a conductive material such that The outer cover 11 is welded to a bottom surface 14 of the closed end of the can 2 and serves as an electrical contact terminal of the battery. The battery 10 generally further includes a first electrode material 15 as a positive electrode (also referred to as a cathode). The first electrode material 15 can be pre-molded and embedded in the can body 12, or can be molded and positioned to facilitate contact with the can body 12. The inner surface. For an alkaline battery, the first electrode material 15 usually includes manganese dioxide (MnO2). After the first electrode 15 is provided in the can body 12, a separator 17 is embedded in the area defined by the first electrode 15. In the space, the partition member 17 is preferably a non-woven fabric. The separator 17 is provided to keep the first electrode material 15 and the mixture of the electrolyte and the second electrode material 20 substantially separated, and to allow ion transfer between the electrode materials. Once the separator 17 is placed in the cavity defined by the first electrode 丨 5, an electrolyte is distributed into the space defined by the separator 17, and the electrolyte and the second electrode material mixture 20 can be used as the second electrode material. Is the negative electrode (also known as the anode). Electrolyte / Second Electrode Material Mixture 20 is preferably included-glue (please read the precautions on the back before filling this page)

-I ^濟部智慈財產局員工消費合作社印製 ^---------_ >---— u-I ^ Printed by the Consumer Cooperatives of the Ministry of Economic Affairs and Intellectual Property Bureau ^ ---------_ > ----- u

本紙張尺度適用中國國家櫟準<CNS)A4規格（210 X 297公董） * 442990 A7 _________ B7 五、發明說明（2 ) 質劑，以一般之鹼性電池而言，混合物2〇係由水溶液氫氧 化卸（KOH)電解質與鋅之混合物形成，鋅係做爲第二電極 材料，水與其他添加物亦可包括於混合物2〇内。 一旦第一電極15、分隔件17、電解質、及混合物2〇已形 成於罐體12内，一預先组裝之集流器總成25即嵌入罐體12 之開口端内。罐體12通常在其開口端呈略爲推拔狀，此推 拔用於在集流器總成定位之前可支承其於一要求方位上。 集流器總成25嵌入後，一外蓋體45即置於集流器總成25上 ’集流器總成25藉由將罐逋沿徑向擠壓於集流器總成25而 定位，外蓋體45随後放置且接觸於集流器總成25上。罐體 1 2之端緣1 3摺縐於集流器總成2 5之環緣上，藉以固定外蓋 體45與集流器總成25於罐體12末端内。如下所述，集流器 總成25之一功能在於對電化學電池提供一第二外部電接觸 件，此外，集流器總成25需封合罐體12之開口端，以防止 其内之電化學材料漏出此電池〇再者，集流器總成25需展 現足夠強度，以承受電池所面對之物理性誤用，此外，因 爲電化學電池會產生氫氣，因此集流器總成25應可容許内 部產生之氩氣穿透而逸出至電化學電池之外部。另，集流 器總成25應包括某些型式之壓力釋放機構，以利於電池内 之此壓力過大時可釋放之，此情況係發生在電化學電池以超 過内部生成氫氣可穿透集流器總成至電池外之速度產生時。 圖1所ττ之集流器總成25包括一密封30、一集流器釘針 40、_内蓋體44、一華司50、及複數鐵距52，所示之密 封30包括一中央轂32，其具有一孔供集流器釘針40嵌入》 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） <請先閱讀背面之注意事項再填窝本頁) -_ "If · ! ! — 11 訂----11111 ) 綏濟部智慧財產局員工消f合作社印製 經濟部智,€財產局員工消費合作社印製 ^ 44^ y 9 ϋ Α7 ___Β7____ 五、發明說明（3 ) 密封30進一步包括一 V形部34，其可接觸第一電極15之一 上表面1 6。 密封30亦包括一沿周邊之直立壁36，其係以環形方式沿 著密封30之周邊向上延伸’周邊直立壁36不僅用於做爲集 流器總成25與罐鱧12介面之間之密封，亦做爲一電絕緣體 以防止短路發生於電池之正罐體與負接觸端子之間。 由一硬質金屬製成之内蓋體44係用於增加硬度及支承集 流器總成2 5之徑向壓縮，藉此改善密封效率。如囷1所示 ，内蓋體44係建構以接觸中央轂部32及周邊直立壁36，依 此建構集流器總成25則内蓋趙44可容許集流器釘針40壓縮 中央轂部32 ’而亦支承罐體12内表面對周邊直立壁36之壓 縮。 外蓋髏45通常以鎳鍍鋼製成，且係建構以延伸自一由密 封30之環緣直立壁36定義之區域及呈電接觸於集流器釘針 40之一頭部42，外蓋體4 5可熔接於集流器釘針40之頭部 42 ’以防止任何接觸損失。如围1所示，當集流器總成25 嵌入罐體12之開口端時，集流器釘針40即深入電解質/第 二電極混合物20内，而於其間建立充分之電接觸《圖1所 示之範例中，外蓋髏45包括一環緣47，係沿外蓋體45之周 邊而向上延伸，藉由形成密封30之周邊直立壁36長度大於 環緣47者，周邊直立壁36之一部份可在摺縐期間摺至環緣 47上，以利防止罐體12上緣13之任意部份接觸於外蓋體 45 ° 密封30較佳由尼龍製成，在圖1之結構中，一壓力釋放 • 6 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公漦） U—·-------->裝--------訂---------蜱V· (請先閱讀背面之注§項再填寫本頁) · 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（4 ) 機構係提供當内部壓力過大時可釋放之，再者，内蓋體“ 與外蓋體45通常備有孔43可容許氫氣逸出至電池1〇外。圖 示之機構包括一環形金屬華司5〇與複數鐵距52，係提供於 密封30與内蓋體44之間，複數鐵距52各包括一尖端53 , 係壓抵於密封30之一薄中間部38。鐵距52偏壓於内蓋體 44之下内表面，使得當電池1〇之内壓增高且密封3〇逐漸因 向上壓向内蓋體44而變形時，鐵距w之尖端53即貫穿密封 30之薄中間部38，藉此碎裂密封3〇而容許内部生成之氣體 經過孔4 3逸出。 儘管上述集流器總成25可令人滿意地執行上述要求功能 ，但是由其截面構形可知，此特殊之集流器總成佔去電池 10内之大量空間，由於電化學電池之外部規格大體上係由 美國國家標準協會（ANSI)固定，因此，集流器總成佔用之 空間越大則電池内可用於電化學材料之空間越少。結果， 提供於電池内之電化學材料量減少，導致電池較短之使用 壽命’因此有必要增大一電化學電池内之空間，以用於電 化學活性成分。 ' 應注意的是圖1中之結構僅爲一電池結構例子，其他集流 器總成存在有較小構形且佔用電池内較少空間，惟，此集 流器總成通常是在犧牲集流器總成之密封特徵或壓力釋放 機構之性能與穩定性，而達成減少佔用空間。因此，有必 要構成_種電化學電池，其中集流器總成佔用之空間與容 器體積佔用之空間皆達到最小，而仍能保持適當之密封特 徵及一穩定之壓力釋放機構。 衣紙張尺度適用中國國家標準（CNS>A4规格（210 X 297公釐） U----------J 裝·！ I 訂·! ^---1*------------ * * 4 (靖先閱讀背面之注意事項再填寫本頁> 經濟部智慧財產局員工消費合作社印製 r 442990 at _____B7_______ 五、發明說明（5 ) 本案申請日以前之一般電池所測得之外部與内部空間係 列示於圖2A、2B之列表中’其列示出用於D、c、八八及 AAA尺寸電池之空間（cc)。圖2A中亦提供可用於容納電化 學活性材料之内部空間所佔之總電池空間百分比，總電池 空間包括電池之所有空間，即包含任意内部空隙，以圖 示之電池而言，理想上總空間包括圖3A中之所有陰影線區 域，電池之「内部空間」則由囷3B中之陰影線區域表示。 本文中之内部空間係電池内可容納電化學活性材料之空間 ，以及拘限於電池密封空間内之任意空隙與化學惰性材料（ 不同於集流器釘針），此化學惰性材料可包括分隔件、導體 、及電極中之任意精性添加物。本文中之Γ電化學活性材 料J包括正、負極及電解質。 集流器總成空間包括集流器釘針、密封、内蓋禮，及負 蓋體底表面與密封之間之任意空間（如圖3C中之陰影線區 域所示），可以瞭解的是，内部空間、集流器總成空間、及 容器空間之總和係等於總空間，據此，用於電化學活性材 料之内部空間可由測量集流器總成空間與容器空間，及將 集流器總成空間與容器空間除以測得之電池總空間而確定 。容器空間包括罐體、標籤、負蓋體之空間，標籤與負蓋 體、正蓋體之間之空間，及正蓋體與罐體之間之空間（如圖 3D中之陰影線區域所示）β若標籤延伸至負蓋體上且與之 接觸，則存在於標籤與負蓋體之間之空間即包括於容器空 間内，因此亦視爲總空間之一部份，否則該空間即不包括 於容器空間或總空間内。集流器總成空間及構成集流器總 -8- 本紙張尺度適用中國國家標準（CNS)A4规格（210 X 297公* ) «κ — irlll·! — — * ·1111111 « — — — — — I — ·· (請先閲婧背面之注意事項再填寫本頁) 442990 A7 經濟部智慧財產局員工消費合作社印製 B7 五、發明說明（6 ) 成空間之總電池空間百分比係提供於圖2 b中，以用於圖 2 A所列示之一般電池。 用於各電池電化學活性材料之内部空間、總電池空間、 及集流器總成空間可藉由觀察一電腦輔助設計（CAD)圖、 一照片’或包覆於環氧樹脂内且取縱向截面之電池實際截 面而決定之，利用CAD圖、照片、或實際縱向截面以觀察 及測量電池規格即可供涵蓋所有可能存在於電池内之空間 。欲測量總電池空間時，沿中央縱向對稱軸線而取之電池 截面圖係取出，且利用幾何計算以測量整個空間β欲測量 用於電化學活性材料之内部空間時，沿中央縱向對稱軸線 而取之電池截面囷係取出，且利用幾何計算以測量内部空 間之構成成分’包括電化學活性材料、空隙量及拘限於電 池密閉空間内之化學惰性材料（不同於集流器釘針）。同樣 ，欲決疋集流器總成之空間時，沿中央縱向對稱抽線而取 之電池截面囷係取出，且利用幾何計算以測量集流器總成 空間之構成成分’包括集流器釘針、密封、内蓋體、及定 義於負蓋嫌底表面與密対之間之任意空間，容器空間同樣 可由電池之中央縱向截面觀察而測量，且計算由罐體、標 籤、負蓋趙、標籤與負蓋體及正蓋髏之間之空間、及正蓋 體與罐體之間之空間所耗用之空間。 空間之測量係藉由沿其縱向對稱私線而觀察電池之一截 面取得，此舉可提供一準確之空間測量，因爲電池與其組 件通常呈軸向對稱。爲了取得一電池截面之幾何圖，電池 先置入環氧樹脂内，且在環氧樹脂固化後，置入之電池與 本紙張尺度適用中國國家標準（CNS)A4洗格（210 X 297公漦〉 — — — — ^ - I------^- — — 11 —---^ ^1--HIUIIIII1! — — •4 (請先閲讀背面之注$項再填寫本頁) 442990 A7 _____B7________ 五、發明說明（7 ) 其組件即研磨至通過對稱轴線之中央截面。較特別的是電 池係先置入環氧樹脂中再磨短中央截面，其次，所有内部 組件例如陽極、陰極、及分隔紙皆去除，以利測量完成後 之截面，電池随後清理任意殘留之碎屑，進行空氣乾燥， 且剩餘之空間填入環氧樹脂，以於完成研磨及拋光至其中 央之前賦與電池些許之整體性。電池再次研磨及抛光直到 其中央截面爲止，隨後繪成圖式及自由測出其空間。 在將電池置入環氧樹脂之前，電池之測量係以厚度計測 出整體高度、摺縐高度、及電池之頂、底、中央處之外徑 ，此外，一相同之電池予以分解且其组件進行測量，分解 電池之組件測量包括集流器釘針之直徑、集流器釘針之長 度、集流器釘針至負蓋體之長度、及電池無標籤存在時之 頂、底、及中央處之外徑。 一旦電池完成瓶裝於環氧樹脂中及研磨至縱向對稱軸線 中央時，電池之截面圖即可做成一續·圖，一具有QC- 4000軟 體之Mitutoyo光學比較器即用於螬出電池及其個別組件之輪 廓，以利產生電池之中央截面囷。此時，電池係固定於定 位且電池組件之輪廓存於一格式，而在随後可用於固體模 組化軟體中，以利計算出電池之有利空間，惟，在取得任 意之空間測量値之前，闽式可經調整以補償未準確對齊於 電池中央之任意電池组件，此可利用截取電池之前取自電 池之値及取自分解同型電池之値而達成。例如，集流器釘 針之直徑與長度、電池之整體外徑可藉由調整圖式以包括 對應之已知截面積而較精確地構形該圖式，以利使圖式較 -10- 本紙張尺度適用中國固家標準（CNS)A4規格（210 X 297公釐> (請先閱讀背面之注意事項再填窝本頁) >裝------丨丨訂--------μ 經濟部智慧財產局員工消費合作社印製 "442990 d7 ____ B7 五、發明說明（8 > 準確地用於空間測量，密封、蓋體、及摺縐區域之細部結 構則用在其續·示於光學比較器上時。 <請先Μ讀背面之注意事項再瑱寫本頁) 欲計算空間測量尺寸時，圖式係輸入固體模組化敕體中 ’ 一固體三維空間表示藉由相關於縱向對稱軸線轉動左、 右側上之截面輪廓180度而產生。據此，各可用區域之空間 可由軟體計算’利用轉動左、右側18〇度及決定出左、右空 間相加之平均空間，此對於電池具有非對稱特性時尤爲有 利°包括任意非對稱特性之空間可依需要調整，以取得較 準確之空間測量値〇 發明概述 經濟部智慧財產局員工消費合作社印製 據此，本發明之一内容在於利用省略電池之集流器總成 而仍維持其功能，或提供一具有較低構形之集流器總成而 藉以佔用一電化學電池内較少空間，以解決上述問題。本 發明之另一内容在於提供電池結構具有長期較習知總成爲 少之水份損失’藉以増加電池之殼體壽命。本發明之又— 内容在於提供一具有壓力釋放機構之電池，且該機構不佔 去顯著百分比之可用電池空間。本發明之再一内容在於提 供較易製造且需用較少材料之電池結構，藉此可具有較低 製造成本。本發明之另一内容在於提供電池結構，其需要 罐體施加較少之徑向壓縮力以適度密封電池，藉此容許使 用一具有較薄側壁之罐體，因而生成較大之内部電池空間β 爲了達到上述及其他内容與優點，本發明之一電池包含 一罐體，用以容納電化學材料，包括正與負極及一電解質 ’罐體具有一第一端 '一開口式第二端、延伸於第—與第 -11- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公« ) 經濟部智慧財產局員工消費合作社印製 Γ 442990 Α7 _____Β7___ 五、發明說明（9 > 二端之間之侧壁、及一延伸過第一端之端壁；一蜃力釋放 機構’係形成於罐雜之端壁中’可在内部壓力逐漸過大時 用於自罐體内釋放之；一第一外蓋體，設於罐體之端壁上 而與之呈電接觸’及延伸過壓力釋放機構；一第二外蓋體 ’設於通過罐髏之開口式第二端；及一絕緣體，係設於罐 體與第二外蓋體之間，供將罐體呈電絕緣於第二外蓋體。 此外’部份之上述内容與優點可由本發明之一電池達成 ’其包含一罐體，用於容纳電化學活性材料，包括至少庀 與負極及一電解質，罐體具有一第一端、—開口式第>端 、延伸於第一與第二端之間之侧壁、及一延伸過第一端之 端壁’罐體進一步具有一突緣，係自罐體之開口式第二端 向外延伸向第一端；一蓋體，用於密封罐體之開口端，蓋 趙具有一環緣以環繞於突緣，且摺縐於突緣與罐體側璧外 表面之間；及電絕緣體，係提供於突緣與蓋趙環緣之間以 及罐體與環緣之間，電絕緣材料最好呈塗層型式，且真接 積置於罐體與外蓋體之至少一者上。 此外，部份之上述内容及優點亦可由本發明之一電化學 電池達成，其包含一罐嫌，用以容納電化學活性材料，包 括至少正與負極及一電解質，罐體具有一開口端及一封閉 端，及延伸於開口端與封閉端之間之側壁；—第一外蓋體 ’定位通過罐體之開口端；一集流器，係電权合於第〆外 蓋體及延伸於罐體内，以電接觸於正、負極其中一者；及 一環形密封，具有一L形截面，設於罐體與第一外蓋禮之 間，以將罐體呈電絕緣於第一外蓋體，且產生一密封於第 12· 本紙張尺度適用中國固家標準（CNS)A4規格（210 X 297公* ) l·------------y装--------訂---------1^--/---^--il·---------- (請先Μ讀背面之注意事瑣矜Λ寫本黃) * 442990 A7 B7 五、發明說明（10 一外蓋體與罐體之間，密封可進一步包括一沿垂直方向％ 伸之構件，以形成一 J形截面。依據此實例，一壓力釋放機 構較佳爲形成於罐體之一表面中，以於内部壓力過大 自罐體内釋放之。 再者，部份之上述内容及優點可由本發明之一電化學t 池達成，其包含一罐體，用以容納電化學活性材料，包括 至少正與負極及一電解質，罐體具有一開口端、— 封閉端 經濟部智慧財產局員工消費合作社印製 、及延伸於開口端與封閉端之間之側壁；一蓋體，係定位 通過罐體之開口端及連接於罐體，蓋體具有一貫穿孔. 集流器，係延伸通過蓋體中之孔，立延伸於罐趙内以呈電 接觸於正與負極其中一者；及一絕緣材料，設於集流器與 蓋體之間，以將集流器呈電絕緣於蓋體且產生—密封於集 流器與蓋體之間。此外，電化學電池最好包括—第_接觸 端子以電耦合於集流器，及一電介質材料設於第—接觸端 子與蓋體之間，以將蓋體呈電絕緣於第一接觸端子。本案 亦提供一種製造一電化學電池之方法，其包括以下步驟. 配送活性電化學材料於一具有一封閉端與一開口端之罐體 内；設置一集流器通過一設於一蓋體内之孔；提供_電介 質絕緣材料於蓋體與集流器之間，以提供其間之電絕緣； 及組合蓋體與集流器於罐體之開口端》 ’ 再者，部份之上述内容與優點可由本發明之一電池達成 ，其包含一罐體，用以容纳電化學活性材料，包括正與負 極及一電解質’及一標籤直接印於罐體之—外表面上。組 合一電池之方法亦提供於此，其包括以下步碟：形成—具 (請先閱讀背面之注意事項再填寫本頁> ^裳--------訂---------·" 13- 442990 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（11 ) 有-開口端與-封閉端之罐體，形成—外蓋體，配送電化 學活性材料於罐趙内，以外蓋體密封罐體之開口端而於其 間提供-電絕緣層，及直接印刷一標籤於罐體之外表面上 。依此實例，罐狀隸可對應地增大，以料電池内部 空間之大幅增加，而仍保持一預定之總外徑。 本發明I上述及其他特性、優點、及目的可由習於此技 者參考以下説明書、申請範圍、及附囷而進—步瞭解及肯 定。 選_式簡單説明 圖式中： 圖1係一習知C尺寸鹼性電化學電池之截面圖； 圖2A係一列表，揭示相對之總電池空間及可用於電化學 活性材料之内部電池空間，係測自本案提出申請時—般 取得之電池； 圖2B係一列表，揭示相對之總電池空間及集流器總成空 間，係測自圖2 A之一般可取得電池； 囷3 A- 3D係一習知C尺寸鹼性電化學電池之截面圖，說明 整個電池及不同之组件空間； 圖4係一C尺寸鹼性電化學電池之截面圖，其具有依本發 明第一實例構成之低構形密封； 圖5係用於一 AA尺寸電池之第一實例調整方式局部截面 ’相較於目前用於一AA尺寸電池之習知結構調整方式局部 截面； 圖6係一C尺寸鹼性電化學電池之截面圖，其具有依本發 -14 本紙張尺度適用中困國家標筚<CNS>A4规格（210 X 297公 l· I--. θ^------ - -訂-------- (請先閱讀背面之注意事項再填寫本頁) A7 I' 442 9 9 ο B7________ 五、發明說明（12 ) 明第二實例構成之超低構形密封； 圖7係一C尺寸鹼性電化學電池之截面圖，其具有依本發 明第三實例構成之超低構形密封及成型正蓋體突起； 圖8 A係依本發明第四實例構成之一 C尺寸鹼性電化學電 池截面圖，其具有一捲回式蓋體、一環形之L形或J形密封 、及一設於罐體底表面中之壓力釋放機構； 圖8B係依本發明第w實例構成之一C尺寸鹼性電化學電 池頂部截面圖，其具有一捲回式蓋體及進一步包括一L形 環形密封； 圖8C係圖8A所示電化學電池之立體分解圖，説明集流器 密封與蓋體總成之組合情形； 圖9係一電池罐體之底視圖，其具有一形成於罐體封閉端 内之壓力釋放機構； 圖10係沿圖9所示罐體通氣口之χ-χ線而取之截面圖； 圖11係一C尺寸鹼性電化學電池之截面圖，其具有依本 發明第五實例構成之飲料罐體式結構； 圖12A係圖11所示電池之局部立禮分解圖； 圖12B、12C係圖11所示電池一部份之截面囷，説明製成 飲料罐體式結構之方法； 圖12D係圖11所示電池一部份之放大截面圖； 圈13係一 C尺寸鹼性電化學電池之截面圖，其具有依本 發明第六實例構成之飲料罐體式結構； 圖14A係一列表，揭示依本發明構成之不同電池之計算所 得全部與内部電池空間； -15- 本紙張尺度適用中國國家楳準（CNS>A4規格（210x 297公着）— -l·----------)裝--------訂------11,¾.^ {請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 442 9 9 〇 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（13 ) 圖14B係一列表，揭示依本發明構成之不同電池之計算所 得全部空間與集流器總成空間； 圖1 5係一C尺寸鹼性電化學電池之截面圖，其具有依本 發明第七實例構成之集流器饋送通過結構； 圖1 6係囷1 5所示電化學電池之分解組合囷；及 圖1 7係一流程圖，説明圖1 5、1 6所示電化學電池之—组 合方法。 較佳實例詳細説明 如上所述’本發明之一基本目的係在加大—電池中可用 之内部空間’供容置電化學活性材料於先前未取得之空間 ’爲了達成此目的而不致於不利地減少電池中所提供壓力 釋放機構之穩定性及不致於增加電池漏損之可能性，以下 即建議多項新穎性之調整，以用於多種尺寸之電池結構， 以下所述之調整方式可分開或併合於一電池中實施，以改 善其空間效率。 如以下進一步之詳述，可取得較大内部空間以容置電化 學活性材料之本發明多種調整方式係包括一低構形密封（如 囷4)、一超低構形密封（如圖5)、一正外蓋體突起直接設於 罐體之封閉端中以併合於超低構形密封（如囷6)或低構形密 封 '一罐體通氣口設於電池罐體封閉端中（如圖7-9)且包括 —L形與J形之環形密封（如圖8A-8C)、一飲料罐體式結構 使用併合於一罐體通氣口（如囷11)、及一飲料罐體式結構 具有一集流器餚送通過（如圖15-17)。 此外，藉由使用上述之結構，電池罐體可設有較薄之壁 -16- 本紙張尺度通用令國國家標準（CNS)A4規格（210 * 297公« ) -l·-------裝 i — — I — 11 訂 *-----!_-"w {靖先W讀背面之注意事項再填寫本頁) 442990 Α7 經濟部智慧財產局員工消費合作社印製 五、發明說明（14 ) 面，如4-8密爾，因爲以下所述之結構技術並不需如習知電 池使用較厚壁面以確保足夠之摺縐與密封°再者’依本發 明所示，一標籤可直接利用石版印刷於電池罐體之外表面 上，藉由使罐體壁面變薄及直接以石版印刷標籤於罐體外 部上，則電池之内部空間可進一步增加’因爲吾人不必考 量標籤基材之厚度即可構成一符合ANSI外部尺寸標準之電 池。 低構形密封 圖4揭示一種使用本發明第一實例低構形密封而構成之電 池，相似於圖1所示電池的是電池100包括一導電罐體112且 罐體具有一封閉端114及一供一集流器總成125與負蓋體145 定位之開口端。再者，電池100包括一正極115以接觸於罐 體112之内壁面及接觸於一分隔層117,且分隔層位於正極 115與一負極120之間。電池1〇〇進一步包括一正外蓋趙in ，係接附於罐體112封閉端之一底表面。 電池1 0、100之間差異在於集流器總成125與蓋體145，雖 然密封130相似於密封30之處爲其包括一直立壁136與一中 央轂132，且轂内設有一孔以容置一集流器釘針14〇之頭部 142 ’但是密封130不同於密封30之處爲密封30之V形部34 係呈倒置而向上延伸向内蓋體144，如编號134所示。藉由 倒置此V形部，集流器總成125可以較充分地靠置於正極115 之一上表面116上，再者，由電池10V形部34佔用之空間可 供電化學活性材料使用》 爲了再次減少集流器總成125所佔用之内部空間，内蓋體 -17- 本紙張尺度適用中賴家揉準<CNS)A4規格⑵G χ 297公爱）— -l·-------Θ 裝--------訂-----I ! ^---!|-1------------------- • * - C請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 442990 A7 ____B7_ 五、發明說明（15 > 144即構成較貼服於外蓋體145之内表面，以利消除電池1 〇 内之外蓋體45與内蓋體44之間空隙。此外，藉由將集流器 總成125穩固地靠置於正極115之上表面116上，外蓋體145 之環緣147可呈平坦狀，而非電池1 〇中之向上延伸狀。藉由 將環緣147平置’集流器總成125可進一步定位接近電池；i〇〇 末端。 電池100之集流器總成125進_步不同於電池10集流器總 成25之處爲省略鐵距52與華司50，而集流器總成125係利 用在密封130内形成一緊鄰於轂132之薄化段138而具有一穩 定之壓力釋放機構。密封130之一增厚環形部139係鄰設於 薄化段138 ’而令薄化段138位於增厚環形部139與較厚轂 132之間，因此當電池1〇〇之内壓過大時，密封13〇即在薄化 部138之處裂開。依電池1〇之結構所示，内部產生之氣體係 經由内蓋體144與外蓋體145中形成之孔143逸出。 可用於容納電化學活性材料於一 D尺寸電池中且具有圖1 所示習知結構之内部空間爲44.16 cc，此爲50.38 cc總空間 之87_7%(請見圖2A列表中之對應數據）。若同樣之電池係 以圖4所示之低構形密封結構構成，則内部電池空間可増大 至44.67 cc，代表總空間50.07 cc之89.2%。以本發明低構形 密封構成之電池之内、外空間係用於—具有1〇密爾罐趙厚 度之電池，再者，藉由增大罐體壁面之厚度，其甚至可取 得較大之内部電池空間。 上述之低構形密封可見於由Gary R· Tucholski在1997年6 月27日提出之〇8/882,572號「用於電池之一 v形替片」美國 -18- 本紙張尺度適用中國國家標準<CNS>A4規格（210 X 297公釐） l·------ y 裝-------訂-----------^----ψ—---------- <請先閱讀背面之注意事項再填寫本頁) A7 442990 B7__ 五、發明說明（彳6 ) 專利申請案，其内文在此可供參考。 圖5揭示用於一AA尺寸電池100,之低構形密封調整方式相 較於圖1所示結構用於一 AA尺寸電池1〇,之一般方式，相同 於電池100集流器總成（如圖4)之處爲電池1〇〇,之集流器總 成包括一密封130，且密封具有一倒置v形部134、一轂部 132、及一薄化部138設於較部132與一増厚部139之間。 電池100與100,之集流器總成間之基本差異在於省略電池 100之内蓋件144 ’爲了確保有足夠之徑向壓縮力施加於密 封130之直立腿件136，電池100,係使用一捲回式蓋體145ι以 替代突緣式蓋體145於電池100中且亦使用—固持件15〇。由 圖4、5可知，一捲回式蓋體不同於一突緣式蓋體之處在於 一突緣式蓋體145之環緣147呈平坦狀，而一捲回式蓋體145, 之環緣147'則沿軸向向下延伸且亦沿軸向向上折疊。捲回式 蓋想145'係在徑向提供一足狗之彈性力，以利於正常使用期 間保持密封130之直立腿件136壓於罐體112之内壁。 固持件150係提供於密封130之轂部132上部上方及周側， 以將轂部132壓於集流器釘針140，同時藉由建構固持件150 具有一 J形或L形截面，固持件150之下徑向延伸段可確使密 封130在内部歷力達到一過大程度時可在薄化部138附近破 裂。 超低構形密封 圖6揭示依本發明第二實例構成之電池，其係使用一超低 構形密封，相同於囷1所示習知電池10之處爲電池200亦包 括一筒形罐體212,係以導電材料製成。再者，一第一電極 -19- 本紙張尺度適用中國國家標準（CNSM4規格（210 X 297公釐） l·------------ In--— 訂！ -"y {請先閱讀背面之注意事項再填窝本頁) ♦ 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局貝工消費合作社印製 442 9 9 0 A7 _____B7_ 五、發明說明（17 ) 215最好係以模塑而形成抵靠於罐體212之内壁面，一分隔 件217亦同樣嵌入由第一電極材料215定義之凹穴内，及一 第二電極與電解質之混合物220提供於由分隔件217定義之 凹穴内。 如圖6所示，集流器總成225包括一體成型之密封/内蓋體 總成228及一集流器240通過一體成型密封/内蓋體總成228 中所設之中央孔236，集流器240較佳爲一銅釘，其包括一 頭部242與一固持突緣241，固持突緣可配合一速度螺帽250 ’以固定集流器釘針240於一體成型密封/内蓋體總成228之 中央孔236内。 一體成型之密封/内蓋體總成228包括一硬質之内蓋體210 及一利用模塑或疊層而直接形成於硬質内蓋體210上之密封 230 ’密封230較佳爲氣丁橡膠、丁基或乙晞丙晞橡膠製成 ，而硬質之内蓋體210較佳由低碳鋼1008或1010製成。由於 橡膠比一般使用於此集流器總成中之尼龍或聚丙烯材料更 易於壓縮，因此硬質内蓋體210之徑向壓縮強度不需如此大 ’内蓋體因而可用較薄及/或較軟之金屬製成，再者，金屬 以外之材料亦可採用。另，密封230可由其他材料製成，例 如呈化學惰性、防滲水、可壓縮者，且有能力結合所用之 材料以形成硬質内蓋雜210。 此外，藉由減少壓縮密封之周邊直立壁所需之徑向力， 則罐體壁之厚度可自0.010吋（1 0密爾）減小至大約0.006吋 (6密爾），或甚至可能的話爲0.004吋（4密爾）。 藉由提供一結構使橡膠材料如氣丁橡膠及丁基橡膠可做 -20· 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） I------*----!^裝！|訂·!--1!·^T •· (請先閱讀背面之注意事項再填寫本頁) A7 4^-990 _____B7__ 五、發明說明（18 ) 爲密封材料’則集流器總成之滲水率可大幅減少，而藉由 減低電池之滲水率，電池之曰常保養應可增高。 硬質之内蓋體210概呈碟形且具有一中央孔218形成於其 中央以及具有複數其他孔217’中央孔218及其他孔217係自 其上表面通過硬質内蓋體2H)至其底表面。若以金屬製成， 則硬質内蓋體210較佳由壓製一片金屬而產生，惟，内蓋體 210可利用其他習知製造技術製成，隨後硬質之内蓋體21〇 可進行一表面粗化過程，例如噴砂或化學蚀刻，以加強随 後形成於硬質内蓋體210與密封230之間之結合強度。以C尺 寸電池而言，硬質内蓋禮210較佳爲〇·〇ΐ5至0.030吋厚。 硬質内蓋體210已做壓製及表面處理後，其較佳爲嵌入一 轉移模具壓床内，且製成密封230之橡膠可随後供給至其内 ’轉移模具較佳爲容許供給橡膝形成一通過硬質内蓋體 底表面之層232，層232之厚度在o.oio與〇〇2〇吋之間，且較 佳爲0,016吋》橡膠亦流入孔217而形成栓塞238，橡膠同時 流入中央孔218内以觀於中央孔218表面，但是不致完全塡 滿孔，故可提供一中央孔236供集流器釘針240随後插入。 中央孔236之直徑最好充分小於集流器釘針240之直徑，使 得襯於中央孔218内之橡膠可在集流器釘針240堪使穿過中 央孔236時明顯地壓縮於孔218内。藉由提供一固持件241於 集流器240上且壓靠於密封23〇之底層2：32，則當集流器釘針 240驅送於定位時，其速度螺帽250與固持件241配合而亦在 垂直方向壓縮其間之橡膠層232部份。藉此方式壓縮橡膠密 封於集流器釘針240附近，則集流器釘針240與一體成型密封 -21- 本纸張尺度適用中國國家摞準（CNS)A4規格（210 X 297公釐） l·-----------W 裝--------訂---------^.’Ύ (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作杜印製 442990 A7 __B7___ 五、發明說明（19 ) /内蓋體總成228之間介面所發生之漏茂可能性即可大幅降低。 藉由上述方式以橡膠密封栓塞238填入孔217内，即可提 供一恩力釋放機構，其不僅功能穩定，且在内部壓力釋放 後可有效地重覆密封。當内部壓力達到視爲過量之程度時 ，過量之壓力在至少其中一栓塞238處破裂，以利迅速释放 内部產生之氣體。發生破裂時之壓力可依選用於密封之材 料、密封材料之厚度、及孔217之直徑而做控制，再者，由 於橡膠密封材料之彈性，因此橡腰栓塞238大體上可在恩力 釋放後假設爲其原始狀態，故其不同於習知集流器總成所 用通氣機構，本發明之壓力釋放機構不致於集流器總成内 產生一永久性之孔使電化學材料循此漏失，再者，其大爲 減低電池内部成分惡化，因此可延長電池使用壽命。 雖然只有栓塞238中之一孔217需提供做爲一壓力釋放機 構，但是增添之穩定性可藉由提供複數牧此栓塞孔而取得 ，不同於先前技藝之釋放機構結構的是，本發明容許複數 可獨立操作之釋放機構。即使是包括複數鐵距之圖1所示壓 力釋放機構仍依賴華司50倒置用於任意鐵距，以貫穿密封 ，惟，本發明集流器總成中所提供之各栓塞孔並不相互依 存，故其整體上可用於一較穩定之壓力釋放機構。 如圖6所示，密封230具有一直立壁235，係直接形成於硬 質内蓋體210之一環緣上，藉由提供此直立壁235，一充分 密封可在集流器總成225嵌入罐體212時產生。此密封可藉 由形成密封230之外徑大於罐體212之内徑而增強，使内蓋 體210將直立壁235壓縮抵靠於罐體212之内表面。 -22- 本紙張尺度適用中困國家摞準（CNS)A4規格（210 * 297公釐） l·--丨丨丨 t___!^裝------- 丨訂----l__!^r (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作杜印製 442990 Α7 Β7 五、發明說明（20 ) 密封230可另外形成包括直立壁235之一延伸部237，其沿 垂直方向向上延伸通過内蓋體21 〇之上表面，藉由提供延伸 段237，密封230可使用做爲罐體212摺縐端224與外蓋體245 環緣之間之一電絕緣體。This paper size applies to China National Quercus < CNS) A4 specification (210 X 297 public directors) * 442990 A7 _________ B7 V. Description of the invention (2) As a general alkaline battery, the mixture 20 is dehydrated by aqueous solution (KOH) electrolyte Formed with a mixture of zinc, zinc is used as the second electrode material, water and other additives can also be included in the mixture 20. Once the first electrode 15, the separator 17, the electrolyte, and the mixture 20 have been formed in the can body 12, a pre-assembled current collector assembly 25 is embedded in the open end of the can body 12. The can body 12 is generally slightly pushed at its open end, and this push is used to support the current collector assembly in a desired orientation before positioning it. After the current collector assembly 25 is embedded, an outer cover 45 is placed on the current collector assembly 25. 'The current collector assembly 25 is positioned by pressing the tank 于 in the radial direction to the current collector assembly 25. Then, the outer cover 45 is then placed and contacts the current collector assembly 25. The end 12 of the tank body 12 is folded on the peripheral edge of the current collector assembly 25, thereby fixing the outer cover 45 and the current collector assembly 25 in the end of the tank body 12. As described below, one of the functions of the current collector assembly 25 is to provide a second external electrical contact to the electrochemical cell. In addition, the current collector assembly 25 needs to seal the open end of the tank 12 to prevent The electrochemical material leaked out of the battery. Furthermore, the current collector assembly 25 needs to show sufficient strength to withstand the physical misuse faced by the battery. In addition, because the electrochemical cell generates hydrogen, the current collector assembly 25 should The internally generated argon gas can be allowed to penetrate and escape to the outside of the electrochemical cell. In addition, the current collector assembly 25 should include some types of pressure release mechanisms to facilitate the release of this pressure when the pressure in the battery is too large. This situation occurs in electrochemical cells that can penetrate the current collector beyond the internally generated hydrogen. When the assembly is out of battery speed. The current collector assembly 25 of ττ shown in FIG. 1 includes a seal 30, a current collector pin 40, an inner cover 44, a washer 50, and a plurality of iron pitches 52. The seal 30 shown includes a central hub 32, which has a hole for the current collector pin 40 to be embedded "This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) < Please read the notes on the back before filling in this page) -_ " If ·!! — 11 Order ---- 11111) Employees of the Intellectual Property Bureau of the Ministry of Suiji Cooperative printed by the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperative ^ 44 ^ y 9 ϋ Α7 ___ Β7 ____ 5. Description of the Invention (3) The seal 30 further includes a V-shaped portion 34 that can contact one of the upper surfaces 16 of the first electrode 15. The seal 30 also includes an upright wall 36 along the periphery, which extends upward along the periphery of the seal 30 in a circular manner. The 'peripheral upright wall 36 is not only used as a seal between the current collector assembly 25 and the interface of the tank 12 It also acts as an electrical insulator to prevent short circuits from occurring between the positive can of the battery and the negative contact terminals. The inner cover 44 made of a hard metal is used to increase the rigidity and support the radial compression of the current collector assembly 25, thereby improving the sealing efficiency. As shown in 囷 1, the inner cover 44 is constructed to contact the central hub 32 and the peripheral upright wall 36. Based on this, the current collector assembly 25 is constructed. The inner cover 44 allows the current collector pin 40 to compress the central hub. 32 'and also supports the inner surface of the tank 12 to compress the peripheral upright wall 36. The outer cover 45 is usually made of nickel-plated steel, and is constructed to extend from an area defined by a ring-shaped upright wall 36 of the seal 30 and a head 42 which is in electrical contact with a current collector pin 40. The outer cover The body 45 can be welded to the head 42 'of the current collector pin 40 to prevent any contact loss. As shown in Figure 1, when the current collector assembly 25 is embedded in the open end of the tank 12, the current collector pin 40 penetrates into the electrolyte / second electrode mixture 20 and establishes sufficient electrical contact therebetween. In the example shown, the outer cover 45 includes a peripheral edge 47 that extends upward along the periphery of the outer cover 45. By forming the seal 30, the peripheral upright wall 36 is longer than the peripheral edge 47, and one of the peripheral upright walls 36 The part can be folded to the ring edge 47 during the creping to prevent any part of the upper edge 13 of the can body 12 from contacting the outer cover body. The seal 30 is preferably made of nylon. In the structure of FIG. 1, One pressure release • 6-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 cm) U— · -------- > Loading -------- Order- ------- Tick V · (Please read the note § on the back before filling out this page) · Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Invention Description (4) Institutions provide internal pressure It can be released when it is too large. Furthermore, the inner cover body 45 and the outer cover body 45 are usually provided with holes 43 to allow hydrogen to escape outside the battery 10. The mechanism shown includes a ring metal The company 50 and the plurality of iron distances 52 are provided between the seal 30 and the inner cover 44. Each of the plurality of iron distances 52 includes a tip 53 that is pressed against a thin middle portion 38 of the seal 30. The iron distance 52 is biased Under the inner surface of the inner cover 44, when the internal pressure of the battery 10 increases and the seal 30 is gradually deformed by pressing upward toward the inner cover 44, the tip 53 of the iron distance w penetrates the thin middle portion of the seal 30 38, thereby breaking the seal 30 and allowing the internally generated gas to escape through the hole 43. Although the above-mentioned current collector assembly 25 can satisfactorily perform the above-mentioned required function, it can be known from its cross-sectional configuration that this special The current collector assembly takes up a lot of space in the battery 10. Since the external specifications of the electrochemical cell are generally fixed by the American National Standards Institute (ANSI), the larger the space occupied by the current collector assembly, the larger the space inside the battery. The less space available for electrochemical materials. As a result, the amount of electrochemical materials provided in the battery is reduced, resulting in a shorter battery life ', so it is necessary to increase the space in an electrochemical battery for electrochemical activity Composition. 'It should be noted that The structure is only an example of a battery structure. Other current collector assemblies have smaller configurations and occupy less space in the battery. However, this current collector assembly is usually sacrificed to the sealing feature or pressure of the current collector assembly. Releasing the performance and stability of the mechanism to reduce the occupied space. Therefore, it is necessary to constitute a kind of electrochemical battery, in which the space occupied by the current collector assembly and the space occupied by the container volume are minimized, while still maintaining an appropriate Sealing characteristics and a stable pressure release mechanism. Applicable to Chinese national standard (CNS > A4 specification (210 X 297 mm)) U ---------- J Packing! I order! ^ --- 1 * ------------ * * 4 (Jing first read the precautions on the back and then fill out this page> Printed by the Employee Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 442990 at _____B7_______ V. Description of the invention (5) The series of external and internal spaces measured by ordinary batteries before the application date of this case is shown in the list of Figures 2A and 2B. The size of the battery space (cc). Figure 2A also provides the percentage of the total battery space occupied by the internal space that can be used to accommodate the electrochemically active material. The total battery space includes all the space of the battery, that is, contains any internal voids. For a battery, ideally the total space includes all the hatched areas in Figure 3A, and the "internal space" of the battery is represented by the hatched area in Figure 3B. The internal space in this article is where the electrochemically active material can be contained in the battery Space, and any voids and chemically inert materials (unlike current collector pins) confined in the battery sealed space, this chemically inert material can include separators, conductors, and any delicate additives in the electrodes. Γ Electric The active material J includes the positive and negative electrodes and the electrolyte. The current collector assembly space includes the current collector pin, seal, inner lid, and any space between the bottom surface of the negative cover and the seal (see the shadow in Figure 3C). Line area), it can be understood that the sum of the internal space, the collector assembly space, and the container space is equal to the total space. According to this, the internal space for the electrochemically active material can be measured by the current collector assembly The space is determined by dividing the space of the current collector assembly and the space of the container by the total space of the battery. The space of the container includes the space of the tank, the label, and the negative cover, and the label and the negative cover and the positive cover. The space between the positive cover and the tank (as shown by the hatched area in Figure 3D) β If the label extends onto and contacts the negative cover, it exists in the label and the negative cover The space between them is included in the container space, so it is also considered as a part of the total space, otherwise the space is not included in the container space or the total space. The current collector assembly space and the current collector -8 -This paper size applies to China Standard (CNS) A4 specifications (210 X 297 male *) «κ — irlll ·! — — * · 1111111« — — — — — I — ·· (Please read the notes on the back of Jing before filling this page) 442990 A7 Printed by the Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs B7 V. Description of the invention (6) The percentage of the total battery space provided in the space is provided in Figure 2b for the general battery shown in Figure 2A. For each battery The internal space of the electrochemically active material, the total battery space, and the current collector assembly space can be observed by looking at a computer-aided design (CAD) drawing, a photo ', or the actual battery in a longitudinal section taken in epoxy resin. The cross-section is determined. Using CAD drawings, photos, or actual longitudinal cross-sections to observe and measure the battery specifications can cover all the spaces that may exist in the battery. When you want to measure the total battery space, take a cross-sectional view of the battery along the central longitudinal symmetrical axis and use geometric calculations to measure the entire space. Β To measure the internal space for electrochemically active materials, take along the central longitudinal symmetrical axis The cross section of the battery is not taken out, and geometrical calculations are used to measure the constituents of the internal space ', including electrochemically active materials, the amount of voids, and chemically inert materials confined to the enclosed space of the battery (unlike current collector pins). Similarly, to determine the space of the current collector assembly, take out the cross section of the battery taken symmetrically along the central longitudinal line, and use geometric calculations to measure the components of the current collector assembly space. Needle, seal, inner lid body, and any space defined between the bottom surface of the negative cover and the seal. The container space can also be measured by observing the central longitudinal section of the battery, and the calculation is made by the tank body, label, negative cover, The space consumed by the space between the label and the negative cover and the positive cover, and the space between the positive cover and the tank. The measurement of the space is obtained by observing a cross section of the battery along its longitudinal symmetrical private line. This can provide an accurate measurement of the space because the battery and its components are usually axially symmetric. In order to obtain a geometrical cross-section of the battery, the battery is first placed in epoxy resin, and after the epoxy resin is cured, the inserted battery and this paper size are applicable to China National Standard (CNS) A4 Washing (210 X 297 cm) 〉 — — — — ^-I ------ ^-— — 11 —--- ^ ^ 1--HIUIIIII1! — — • 4 (Please read the note on the back before filling this page) 442990 A7 _____B7________ 5. Description of the invention (7) Its components are ground to the central section passing through the axis of symmetry. The more special is that the battery is first placed in epoxy resin and then the central section is short. Second, all internal components such as anode, cathode, Both the separator and the separation paper are removed to facilitate the measurement of the cross-section after the completion. The battery then cleans up any remaining debris and air-dries. The remaining space is filled with epoxy resin to be applied before grinding and polishing are completed to the center. The battery has a little integrity. The battery is ground and polished again until it has a central section, and then it is drawn into a diagram and the space can be freely measured. Before the battery is placed in the epoxy resin, the battery measurement is based on the thickness of the battery. Crease Degrees, and the outer diameter of the top, bottom, and center of the battery. In addition, the same battery is disassembled and its components are measured. The component measurement of the disassembled battery includes the diameter of the current collector pin and the length of the current collector pin. , The length from the current collector pin to the negative cover, and the outer diameter of the top, bottom, and center of the battery when no label is present. Once the battery is bottled in epoxy resin and ground to the center of the longitudinal symmetry axis, the battery The sectional view can be made into a continuum. A Mitutoyo optical comparator with QC-4000 software is used to extract the outline of the battery and its individual components, so as to generate the central section of the battery. At this time, the battery system It is fixed in position and the outline of the battery component is stored in a format, which can be used later in the solid modular software to calculate the favorable space of the battery. However, before obtaining any space measurement Adjust to compensate for any battery component that is not accurately aligned in the center of the battery. This can be achieved by taking the battery from the battery before taking the battery and disassembling it from the same type of battery. For example, a current collector pin The diameter and length, and the overall outer diameter of the battery can be more accurately configured by adjusting the drawing to include the corresponding known cross-sectional area, so that the drawing is more than -10- This paper size applies to Chinese solid standards (CNS) A4 specifications (210 X 297 mm) (Please read the precautions on the back before filling in this page) > Packing -------- 丨 丨 Order -------- μ Ministry of Economic Affairs Printed by the Intellectual Property Bureau's Consumer Cooperatives " 442990 d7 ____ B7 V. Description of the invention (8) Accurately used for space measurement, the detailed structure of the seal, cover and crease area is used in its continuation Comparator time. < Please read the notes on the back before writing this page) To calculate the dimensions of the space, the diagram is entered into the solid modular body. A solid three-dimensional space is represented by the left and right rotations related to the longitudinal symmetry axis. The profile on the right is 180 degrees. According to this, the space of each available area can be calculated by software. 'Using the left and right sides of 180 degrees and determining the average space of the left and right space addition, this is particularly beneficial when the battery has asymmetric characteristics. Including any asymmetric characteristics The space can be adjusted as needed to obtain a more accurate space measurement. Summary of the Invention Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs According to this, one of the contents of the present invention is to use a current collector assembly that omits the battery and still maintain it. Function, or to provide a current collector assembly with a lower configuration to occupy less space in an electrochemical cell to solve the above problems. Another aspect of the present invention is to provide a battery structure that has less water loss than conventional ones for a long time, thereby increasing the battery case life. Another aspect of the present invention is to provide a battery with a pressure release mechanism, which does not occupy a significant percentage of the available battery space. Yet another aspect of the present invention is to provide a battery structure that is easier to manufacture and requires less materials, thereby enabling lower manufacturing costs. Another aspect of the present invention is to provide a battery structure that requires the can body to apply less radial compression force to properly seal the battery, thereby allowing the use of a can body with a thinner sidewall, thereby generating a larger internal battery space β In order to achieve the above and other contents and advantages, a battery of the present invention includes a can body for containing electrochemical materials, including positive and negative electrodes and an electrolyte. The can body has a first end, an open second end, and an extension. On the first and the eleventh- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 public «) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy Γ 442990 Α7 _____ Β7 ___ V. Description of the invention (9 > II A side wall between the ends, and an end wall extending past the first end; a pressure release mechanism 'formed in the end wall of the tank can' can be used for release from the tank when the internal pressure gradually increases; A first outer cover body provided on the end wall of the tank body in electrical contact therewith and extending through the pressure release mechanism; a second outer cover body provided on the second end of the opening through the skull; and Insulator Between the can body and the second outer cover body, the can body is electrically insulated from the second outer cover body. In addition, the above-mentioned content and advantages of the part can be achieved by a battery of the present invention, which includes a can body for Accommodates an electrochemically active material, including at least tritium, a negative electrode, and an electrolyte. The can body has a first end, an open-end > end, a side wall extending between the first and second ends, and an extension over the first The end wall at one end of the tank body further has a flange extending outward from the open second end of the tank body toward the first end; a cover body for sealing the open end of the tank body, and the cover Zhao has a ring edge. It surrounds the flange and creases between the flange and the outer surface of the side of the tank body; and an electrical insulator is provided between the flange and the ring edge of the lid and between the tank body and the flange, an electrical insulating material It is best to be a coating type, and it is really placed on at least one of the can body and the outer cover body. In addition, some of the above contents and advantages can also be achieved by an electrochemical cell of the present invention, which includes a canister. For containing electrochemically active materials, including at least positive and negative electrodes and an electrolyte, The body has an open end and a closed end, and a side wall extending between the open end and the closed end;-the first outer cover body is positioned through the open end of the tank body; a current collector, which is electrically connected to the first The outer cover body and the body extend from the can body to make electrical contact with one of the positive and negative electrodes; and a ring seal with an L-shaped cross section is provided between the can body and the first outer cover body to form the can body It is electrically insulated from the first outer cover and produces a seal on the 12th. This paper size is applicable to China Solid Standard (CNS) A4 (210 X 297 male *) l · ----------- -y outfit -------- order --------- 1 ^-/ --- ^-il · ---------- (please read the back first) Cautionary matters (矜 Λ yellow) * 442990 A7 B7 V. Description of the invention (10 Between the outer cover and the tank, the seal may further include a member extending in the vertical direction to form a J-shaped cross section. According to this example, a pressure release mechanism is preferably formed in one surface of the tank body to release it from the tank body when the internal pressure is too high. Furthermore, part of the above contents and advantages can be achieved by an electrochemical cell of the present invention, which includes a tank body for containing electrochemically active materials, including at least a positive electrode, a negative electrode, and an electrolyte. The tank body has an open end —— — Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs and the side wall extending between the open end and the closed end; a cover is positioned through the open end of the tank and connected to the tank, the cover has a consistent A perforator. A current collector extends through a hole in the cover and stands vertically inside the tank to make electrical contact with one of the positive and negative electrodes; and an insulating material is provided between the current collector and the cover to The current collector is electrically insulated from the cover and is produced-sealed between the current collector and the cover. In addition, the electrochemical cell preferably includes a first contact terminal to be electrically coupled to the current collector, and a dielectric material is provided between the first contact terminal and the cover to electrically insulate the cover from the first contact terminal. The present invention also provides a method for manufacturing an electrochemical cell, which includes the following steps. Distributing active electrochemical materials in a tank having a closed end and an open end; providing a current collector through a cover body; Hole; provide _ dielectric insulation material between the cover and the current collector to provide electrical insulation therebetween; and combine the cover and current collector at the open end of the tank "" Furthermore, part of the above content and The advantages can be achieved by a battery of the present invention, which comprises a can body for containing electrochemically active materials, including positive and negative electrodes and an electrolyte 'and a label printed directly on the outer surface of the can body. The method of combining a battery is also provided here, which includes the following steps: forming-tools (please read the precautions on the back before filling out this page > ^ 尚 -------- Order ------ --- · " 13- 442990 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (11) The tank with -open end and -closed end, forming -outer cover, distributing electrochemical activity The material is inside the can, the outer end of the can is sealed with an outer cover and an electrical insulation layer is provided therebetween, and a label is directly printed on the outer surface of the can. According to this example, the can shape can be correspondingly increased, It is expected that the internal space of the battery is greatly increased, while still maintaining a predetermined total outer diameter. The above and other characteristics, advantages, and purposes of the present invention can be made by those skilled in the art with reference to the following description, application scope, and attachments —Step-by-step understanding and affirmation. The formula is briefly explained in the figure: Figure 1 is a cross-sectional view of a conventional C-size alkaline electrochemical cell; Figure 2A is a list that reveals the relative total battery space and can be used for electrochemical activity The internal battery space of the material was measured when the application was filed in this case— Figure 2B is a list that reveals the relative total battery space and current collector assembly space. It is measured from the general available battery in Figure 2A; 囷 3 A-3D is a conventional C-size alkaline A cross-sectional view of an electrochemical cell, illustrating the entire cell and different component spaces; Figure 4 is a cross-sectional view of a C-size alkaline electrochemical cell with a low-profile seal constructed according to the first example of the present invention; Figure 5 is for In the first example of an AA-size battery, the adjustment method of the partial cross section is compared with a partial cross section of a conventional structure adjustment method currently used for an AA size battery; FIG. 6 is a cross-sectional view of a C size alkaline electrochemical cell, which has According to this issue-14 this paper size applies to the national standards < CNS > A4 specifications (210 X 297 male l · ---- θ ^ --------order -------- (Please read the precautions on the back before filling this page) A7 I '442 9 9 ο B7________ V. Description of the invention (12) Explains the ultra-low configuration seal of the second example; Figure 7 is a cross-sectional view of a C-size alkaline electrochemical cell, which has a structure according to the third example of the present invention. Figure 8 A is a sectional view of a C-size alkaline electrochemical cell constructed according to a fourth example of the present invention, which has a roll-back cover and a ring-shaped L-shape. Or J-shaped seal, and a pressure release mechanism provided in the bottom surface of the tank; FIG. 8B is a top sectional view of a C-size alkaline electrochemical cell constructed according to the wth example of the present invention, which has a roll-back cover And further includes an L-shaped annular seal; FIG. 8C is an exploded perspective view of the electrochemical cell shown in FIG. 8A, illustrating the combination of the current collector seal and the cover assembly; FIG. 9 is a bottom view of a battery can, which It has a pressure release mechanism formed in the closed end of the tank; Figure 10 is a cross section taken along the χ-χ line of the tank vent shown in Figure 9 Figure 11 is a cross-sectional view of a C-size alkaline electrochemical cell, which has a beverage can-type structure constructed according to the fifth example of the present invention; Figure 12A is a partial exploded view of the battery shown in Figure 11; Figure 12B, 12C is a cross section of a part of the battery shown in FIG. 11, which illustrates a method for making a beverage can body structure; FIG. 12D is an enlarged cross-sectional view of a part of the battery shown in FIG. 11; A cross-sectional view of a battery, which has a beverage can body structure constructed in accordance with the sixth example of the present invention; FIG. 14A is a list showing all the calculated and internal battery space of different batteries constructed in accordance with the present invention; -15- This paper size applies China National Standards (CNS > A4 specifications (210x 297))--l -----------) installed -------- order ----- 11, ¾. ^ {Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 442 9 9 〇 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (13) Figure 14B A list that reveals all the calculated space and currents of different batteries constructed according to the present invention Assembly space; Figure 15 is a cross-sectional view of a C-size alkaline electrochemical cell, which has a current collector feed structure constructed according to the seventh example of the present invention; Figure 16 is a series of electrochemical cells shown in Figure 15 Decomposing and combining 囷; and FIG. 17 is a flowchart illustrating the combination method of the electrochemical cell shown in FIGS. 15 and 16. The preferred embodiment is explained in detail as described above. 'One of the basic objects of the present invention is to increase the internal space available in the battery' to accommodate the electrochemically active material in a previously unobtained space. 'To achieve this purpose, it is not disadvantageous. Reduces the stability of the pressure release mechanism provided in the battery and does not increase the possibility of battery leakage. The following is a suggestion of a number of novel adjustments for battery structures of various sizes. The adjustment methods described below can be separated or combined. Implemented in a battery to improve its space efficiency. As described in further detail below, the various adjustment methods of the present invention that can obtain a large internal space to accommodate electrochemically active materials include a low-profile seal (such as 囷 4) and an ultra-low-profile seal (see Figure 5). 1. A positive outer cover protrusion is directly provided in the closed end of the can body to be combined with an ultra-low configuration seal (such as 囷 6) or a low-profile seal. A can vent is provided in the closed end of the battery can (such as (Figures 7-9) and includes-L-shaped and J-shaped ring seals (as shown in Figures 8A-8C), a beverage can body structure used in a can body vent (such as 囷 11), and a beverage can body structure has A stream of food is delivered (Figure 15-17). In addition, by using the above-mentioned structure, the battery can body can be provided with a thinner wall. -16- This paper has a common national standard (CNS) A4 specification (210 * 297 male «) -l · ----- --Install i — — I — 11 order * -----! _- " w {Jingxian W read the notes on the back before filling out this page) 442990 Α7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Description of the invention (14) surface, such as 4-8 mils, because the structure technology described below does not need to use a thicker wall surface as in the conventional battery to ensure sufficient creasing and sealing. Furthermore, according to the present invention, A label can be directly printed on the outer surface of the battery can with a lithograph. By thinning the wall of the can and printing the label directly on the outside of the can with a lithograph, the internal space of the battery can be further increased because I don't have to consider the label. The thickness of the substrate can constitute a battery that meets the ANSI external size standards. Low Configuration Seal FIG. 4 discloses a battery constructed using the low configuration seal of the first example of the present invention. Similar to the battery shown in FIG. 1, the battery 100 includes a conductive can 112 and the can has a closed end 114 and a An open end for positioning a current collector assembly 125 and a negative cover 145. Furthermore, the battery 100 includes a positive electrode 115 to contact the inner wall surface of the can body 112 and a separator 117, and the separator is located between the positive electrode 115 and a negative electrode 120. The battery 100 further includes a positive outer cover Zhaoin, which is attached to a bottom surface of a closed end of the can body 112. The difference between the batteries 10 and 100 is the current collector assembly 125 and the cover 145, although the seal 130 is similar to the seal 30 in that it includes a vertical wall 136 and a central hub 132, and a hole is provided in the hub to accommodate The head 142 ′ of the current collector staple 14 is different from the seal 30 in that the V-shaped portion 34 of the seal 30 is inverted and extends upward toward the inner cover 144, as shown by reference numeral 134. By inverting the V-shaped portion, the current collector assembly 125 can be fully abutted on one of the upper surfaces 116 of the positive electrode 115. Furthermore, the space occupied by the 10V-shaped portion 34 of the battery is available for use as an electrochemically active material. Reduce the internal space occupied by the current collector assembly 125 again, the inner cover body -17- < CNS) A4 specifications ⑵ G χ 297 public love) — -l · ------- Θ equipment -------- order ----- I! ^ ---! | -1- ------------------ • *-C Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 442990 A7 ____B7_ V. Invention Explanation (15 > 144 means that it is more conformable to the inner surface of the outer cover 145, so as to eliminate the gap between the outer cover 45 and the inner cover 44 inside the battery 100. In addition, by collecting the current collector The element 125 firmly rests on the upper surface 116 of the positive electrode 115, and the peripheral edge 147 of the outer cover 145 may be flat instead of extending upward in the battery 10. By placing the peripheral edge 147 flat, the current is collected. The battery assembly 125 can be further positioned close to the battery; the end of the battery 100. The current collector assembly 125 of the battery 100 is different from the battery 10 current collector assembly 25 in that the iron distance 52 and the washer 50 are omitted, and The current collector assembly 125 has a stable pressure release mechanism by forming a thinned section 138 adjacent to the hub 132 in the seal 130. One of the seals 130, the thickened annular portion 139 is adjacent to the thinned section 138 ' The thinning section 138 is located at the thickened annular portion 139 and Between the hubs 132, when the internal pressure of the battery is too large, the seal 13 is cracked at the thinned portion 138. According to the structure of the battery 10, the internal gas system passes through the inner cover 144 It escapes from the hole 143 formed in the outer cover 145. The internal space that can be used to hold the electrochemically active material in a D-size battery and has the conventional structure shown in Figure 1 is 44.16 cc, which is 87_7 of the total space of 50.38 cc % (See the corresponding data in the list in Figure 2A). If the same battery is constructed with a low-profile sealed structure as shown in Figure 4, the internal battery space can be as large as 44.67 cc, representing 89.2% of the total space of 50.07 cc. The inner and outer space of the battery formed by the low-profile seal of the present invention is used for a battery with a thickness of 10 mil cans. Furthermore, by increasing the thickness of the wall of the can body, it can even obtain a larger Internal battery space. The above low-profile seal can be found in Gary R. Tucholski's June 08, 1997 No. 08 / 882,572 "V-shaped replacement plate for batteries" US-18-This paper size applies Chinese National Standard < CNS > A4 specification (210 X 297 mm) l · ------ y equipment --------- order ------------- ^ ---- ψ ----- --------- < Please read the notes on the back before filling this page) A7 442990 B7__ V. Description of Invention (彳 6) Patent application, the contents of which are here for reference. Figure 5 reveals that the low-profile seal adjustment method for an AA-size battery 100 is compared to the general method for the structure shown in Figure 1 for an AA-size battery 10, which is the same as the battery 100 current collector assembly (such as Figure 4) shows the battery 100. The current collector assembly includes a seal 130, and the seal has an inverted v-shaped portion 134, a hub portion 132, and a thinned portion 138.増 Thickness between 139. The basic difference between the batteries 100 and 100, the current collector assembly is that the inner cover member 144 of the battery 100 is omitted. In order to ensure that sufficient radial compression force is applied to the upright leg member 136 of the seal 130, the battery 100 uses a The roll-back cover 145m is used in place of the flanged cover 145 in the battery 100 and also uses a holding member 150. It can be seen from FIGS. 4 and 5 that a roll-back cover is different from a flanged cover in that the ring 147 of the flanged cover 145 is flat, and the ring of the roll-back cover 145 is flat. The edge 147 'extends axially downwards and also folds axially upwards. The roll-back cover 145 'is to provide a dog's elastic force in the radial direction, so as to keep the upright leg member 136 of the seal 130 pressed against the inner wall of the tank body 112 during normal use. The holder 150 is provided above and around the upper portion of the hub portion 132 of the seal 130 to press the hub portion 132 against the current collector pin 140. At the same time, the holder 150 has a J-shaped or L-shaped cross-section. The radial extension below 150 can surely cause the seal 130 to break near the thinned portion 138 when the internal force reaches an excessive degree. Ultra-low configuration seal Figure 6 reveals a battery constructed in accordance with the second example of the present invention, which uses an ultra-low configuration seal, which is the same as the conventional battery 10 shown in Figure 1 except that the battery 200 also includes a cylindrical can. 212, made of conductive material. Furthermore, a first electrode -19- This paper size applies to the Chinese national standard (CNSM4 specification (210 X 297 mm) l · ------------ In --— Order!-&Quot; y (Please read the notes on the back before filling in this page) ♦ Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the Shell ’s Consumers ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 442 9 9 0 A7 _____B7_ V. Description of the Invention 215 is preferably formed by molding to abut the inner wall surface of the tank body 212, a partition 217 is also embedded in the cavity defined by the first electrode material 215, and a mixture 220 of a second electrode and an electrolyte is provided by The partition 217 defines a cavity. As shown in FIG. 6, the current collector assembly 225 includes an integrated seal / inner cover assembly 228 and a current collector 240 through a central hole 236 provided in the integrated seal / inner cover assembly 228. The current collector 240 is preferably a copper nail, which includes a head 242 and a retaining flange 241. The retaining flange can be matched with a speed nut 250 'to fix the current collector nail 240 in an integrated seal / inner cover. Inside the central hole 236 of the assembly 228. The integrally formed seal / inner cover assembly 228 includes a hard inner cover 210 and a seal 230 formed directly on the hard inner cover 210 by molding or lamination. The seal 230 is preferably a gas-butadiene rubber, The butyl or acetonitrile rubber is made, and the hard inner cover 210 is preferably made of low carbon steel 1008 or 1010. Since rubber is easier to compress than nylon or polypropylene materials commonly used in this current collector assembly, the radial compressive strength of the rigid inner cover 210 need not be so large. The inner cover can therefore be thinner and / or Made of soft metal. Furthermore, materials other than metal can be used. In addition, the seal 230 may be made of other materials, such as being chemically inert, impermeable to water, compressible, and capable of combining the materials used to form the hard inner cover 210. In addition, by reducing the radial force required to compress the perimeter upright wall of the seal, the thickness of the tank wall can be reduced from 0.010 inches (10 mils) to about 0.006 inches (6 mils), or even if possible It is 0.004 inches (4 mils). By providing a structure to make rubber materials such as air-butadiene rubber and butyl rubber -20 · This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) I ------ *- -! ^ Install! | Order ·!-1! · ^ T • · (Please read the precautions on the back before filling out this page) A7 4 ^ -990 _____B7__ 5. Description of the invention (18) is a sealing material 'The current collector assembly The water leakage rate can be greatly reduced, and by reducing the water leakage rate of the battery, the daily maintenance of the battery should be increased. The hard inner cover 210 is generally dish-shaped and has a central hole 218 formed in the center and a plurality of other holes 217 '. The central hole 218 and other holes 217 pass from the upper surface to the bottom surface of the hard inner cover 2H). . If it is made of metal, the hard inner cover 210 is preferably produced by pressing a piece of metal. However, the inner cover 210 can be made by other known manufacturing techniques, and then the hard inner cover 21 can be roughened. A chemical process, such as sand blasting or chemical etching, is used to enhance the bonding strength between the hard inner cover 210 and the seal 230 which is subsequently formed. For a C-size battery, the hard inner cover 210 is preferably from 0.05 to 0.030 inches thick. After the hard inner cover 210 has been pressed and surface-treated, it is preferably embedded in a transfer mold press, and the rubber made into the seal 230 can be subsequently supplied therein. The transfer mold is preferably to allow the supply of rubber knees. A layer 232 is formed on the bottom surface of the hard inner lid body, and the thickness of the layer 232 is between 0.oio and 002 inches, and preferably 0,016 inches. The rubber also flows into the hole 217 to form a plug 238, and the rubber flows into the center at the same time The inside of the hole 218 looks at the surface of the central hole 218, but the hole is not completely filled. Therefore, a central hole 236 can be provided for the current collector pin 240 to be inserted later. The diameter of the central hole 236 is preferably sufficiently smaller than the diameter of the collector pin 240 so that the rubber lined in the central hole 218 can be significantly compressed in the hole 218 when the collector pin 240 can pass through the central hole 236. . By providing a retaining member 241 on the current collector 240 and pressing against the bottom 2:32 of the seal 23, the speed nut 250 cooperates with the retaining member 241 when the current collector pin 240 is driven in position. Also, the rubber layer 232 is compressed in the vertical direction. In this way, the compression rubber is sealed near the current collector pin 240, and then the current collector pin 240 and the integrated seal are sealed. -21- This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) l · ----------- W Pack -------- Order --------- ^. 'Ύ (Please read the notes on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by Du 442990 A7 __B7___ V. The possibility of leakage in the interface between the description of the invention (19) / inner cover assembly 228 significantly reduce. By filling the hole 217 with the rubber sealing plug 238 in the above manner, an energizing release mechanism can be provided, which is not only functionally stable, but also can effectively seal again after the internal pressure is released. When the internal pressure reaches a level deemed excessive, the excessive pressure ruptures at least one of the plugs 238 to facilitate the rapid release of internally generated gases. The pressure at the time of the rupture can be controlled according to the material selected for sealing, the thickness of the sealing material, and the diameter of the hole 217. Furthermore, due to the elasticity of the rubber sealing material, the rubber waist plug 238 can be substantially released after the release of the force. It is assumed to be in its original state, so it is different from the conventional ventilation mechanism used in the current collector assembly. The pressure release mechanism of the present invention does not cause a permanent hole in the current collector assembly to cause the electrochemical material to leak through this. Or, it greatly reduces the deterioration of the internal components of the battery, so it can prolong the battery life. Although only one of the holes 217 in the plug 238 needs to be provided as a pressure release mechanism, the added stability can be obtained by providing a plurality of plug holes. Unlike the prior art release mechanism structure, the present invention allows multiple Independently operated release mechanism. Even the pressure release mechanism shown in FIG. 1 including a plurality of iron distances still relies on the Washer 50 inverted for arbitrary iron distances to penetrate through the seal. However, the plug holes provided in the current collector assembly of the present invention are not interdependent. Therefore, it can be used for a more stable pressure release mechanism as a whole. As shown in FIG. 6, the seal 230 has an upright wall 235 formed directly on a peripheral edge of the hard inner cover 210. By providing this upright wall 235, a sufficient seal can be embedded in the tank body 212 in the current collector assembly 225. Generated. This seal can be enhanced by forming the outer diameter of the seal 230 larger than the inner diameter of the tank body 212, so that the inner cover body 210 compresses the upright wall 235 against the inner surface of the tank body 212. -22- This paper size is applicable to the standard of the poor countries (CNS) A4 (210 * 297 mm) l ·-丨 丨 丨 t ___! ^ Packing ------- 丨 Order ---- l__! ^ r (Please read the notes on the back before filling out this page) Duty printing of employee cooperation of Intellectual Property Bureau of the Ministry of Economic Affairs 442990 Α7 Β7 V. Description of the invention (20) The seal 230 can additionally form an extension 237 including one of the upright walls 235 , Which extends vertically upward through the upper surface of the inner cover 21 〇, by providing an extension 237, the seal 230 can be used as an electrical insulator between the crease end 224 of the tank 212 and the ring edge of the outer cover 245 .

雖然圖示之密封230包括一連續層232通過内蓋體210之整 個底表面，但是習於此技者可瞭解到密封230並不需要形成 於内蓋體210之整個底表面上，特別是若内蓋體210由惰性 塑膠材料製成時。依據製成密封23〇與内蓋體210之材料特 徵，一結合劑可施加於内蓋想210表面，使該表面接觸且結 合於密封材料23(M —旦密封230已模塑於内蓋體210且集流器釘針240穿過一 體成型密封/内蓋腫總成228之中央孔236及穿過固持件240 時，外蓋體245即放置於集流器總成225之上表面上，且較 佳爲熔接於集流器釘針240之頭部242。随後，接附有外蓋 體245之集流器總成225係嵌入電池罐體212之開口端内，爲 了在摺縐前將集流器總成225定位，集流器總成225之底表 面即靠置於第一電極215之一上表面216上，因此集流器總 成225可用一定程度之施力以嵌入，使密封230之底層232可 在開口於電極215上表面216上之電池罐體内均衡地停置。 若第一電極215係利用模塑定位於罐體212内而形成，則 第一電極215之構成方式最好如同共同讓與之Gary R. Tucholski多人在1998年3月6日提出之09/036,115號「使用電 極支承件用於密封之電化學電池結構」美國專利申請案所 示，以防止第一電極215模塑所生之閃光干涉於集流器總成 -23 - 本紙張尺度適用中國國家標準（CNS)A4规格（210 X 297公釐〉 -i— I -- I !^裝！|訂· — — —---— 轉》 (請先閱讀背面之注意事項再填寫本頁) A7 442990 ___B7___ 五、發明說明（21 ) 提供之正確對齊與密封，此09/036 115號美國專利申請案内 文在此可供參考。 藉由靠置集流器總成225於電極215上，罐體212可在其開 口端處摺縐，以提供一抵於電極215之朝下施力，因此，用 於圖1所示習知電池結構中之較高構形摺縐可改代以一低構 形之摺縐，藉此在電池内產生大約〇·〇6〇吋以上之空間。 具有圖6所示結構之一集流器總成225具有遠低於圖1所示 習知集流器總成者之構形，因此，使用集流器總成225之電 池200可包括較大量之電化學材料215、220，JL電池之使用 壽命因而增加，除了其低構形外，集流器總成225亦有足夠 封閉與電絕緣性〇此外，本發明之集流器總成提供一壓力 釋放機構，不僅穩定且具有多重可獨立操作式壓力釋放機 構之優點，及當通氣後可局部再次密封，以防止電化學材 料随後漏出電池外。再者，本發明之集流器總成提供改善 之滲水性特徵，以增加電池之使用保養。 利用囷6所示超低構形密射而構成之不同尺寸電池可用於 容納電化學活性材料之計算所得總空間（cc)及内部空間（cc) 皆提供於圖14A之列表中，由闽14A之列表可知，用於此電 池之内部電池空間大致上係大於習知一般電池者，例如一 使用超低構形密封之D尺寸電池具有45.53 cc内部空間供容 納電化學活性材料，此爲50.07 cc總空間之90.9%，其大於 圖2A所列示習知電池任一者測得之内部空間。再者，對於 具有8或6密爾厚度之電池而言，内部電池空間可進一步大 幅增加，計算所得之總空間（cc)進一步揭示於圏14B之列表 -24- 本紙張尺度適用中國國家標準（CNS>A4规格（210 X 297公釐〉 y ί ! β I i I i y *' (請先閱婧背面之注#^項再填寫本頁) 經濟部智慧財產局具工消費合作社印製 A7Although the illustrated seal 230 includes a continuous layer 232 passing through the entire bottom surface of the inner cover 210, those skilled in the art can understand that the seal 230 does not need to be formed on the entire bottom surface of the inner cover 210, especially if When the inner cover 210 is made of an inert plastic material. According to the material characteristics of the seal 23 and the inner cover 210, a bonding agent can be applied to the surface of the inner cover 210, so that the surface is in contact with and bonded to the seal material 23 (M—the seal 230 has been molded into the inner cover 210 and the current collector pin 240 passes through the central hole 236 of the integrally formed seal / inner cap swelling assembly 228 and the retaining member 240, the outer cover 245 is placed on the upper surface of the current collector assembly 225, And it is preferably welded to the head 242 of the current collector pin 240. Then, the current collector assembly 225 with the outer cover 245 attached to the open end of the battery can 212, in order to fold The current collector assembly 225 is positioned, and the bottom surface of the current collector assembly 225 rests on one of the upper surfaces 216 of the first electrode 215. Therefore, the current collector assembly 225 can be embedded with a certain degree of force, so that The bottom layer 232 of the seal 230 can be evenly rested in the battery can body opening on the upper surface 216 of the electrode 215. If the first electrode 215 is formed by being positioned in the can body 212 by molding, the structure of the first electrode 215 The best way is to share it with Gary R. Tucholski, which was proposed by many people on March 6, 1998, No. 09 / 036,115 The electrode support is used to seal the structure of the electrochemical cell, "as shown in the US patent application, to prevent the flash generated by the molding of the first electrode 215 from interfering with the current collector assembly-23-This paper size applies to Chinese national standards (CNS ) A4 specification (210 X 297 mm) -i— I-I! ^ 装! | Order · — — — ——————— ”(Please read the precautions on the back before filling this page) A7 442990 ___B7___ 5 2. The correct alignment and sealing provided by the description of the invention (21), the content of this US Patent Application No. 09/036 115 is hereby available for reference. By placing the current collector assembly 225 on the electrode 215, the tank 212 can be The open end is folded to provide a downward force against the electrode 215. Therefore, the higher configuration folded used in the conventional battery structure shown in FIG. 1 can be replaced with a low configuration folded Crease, thereby creating a space of approximately 0.060 inches or more in the battery. The current collector assembly 225 having one of the structures shown in FIG. 6 has a far lower value than the conventional current collector assembly shown in FIG. 1. Configuration, therefore, the battery 200 using the current collector assembly 225 may include a larger amount of electrochemical materials 215, 220, JL batteries The service life is increased. In addition to its low configuration, the current collector assembly 225 is sufficiently closed and electrically insulated. In addition, the current collector assembly of the present invention provides a pressure release mechanism, which is not only stable but also has multiple independent functions. The advantages of the operating pressure release mechanism, and it can be partially resealed when vented to prevent subsequent leakage of electrochemical materials out of the battery. Furthermore, the current collector assembly of the present invention provides improved water permeability characteristics to increase the battery's Use and maintenance. Different sizes of batteries formed by the ultra-low profile dense shot shown in 囷 6 can be used to accommodate the calculated total space (cc) and internal space (cc) of the electrochemically active material are provided in the list of Figure 14A. It can be known from the list of Fujian 14A that the internal battery space used for this battery is roughly larger than those of conventional batteries. For example, a D-size battery sealed with an ultra-low configuration has an internal space of 45.53 cc for containing electrochemically active materials. It is 90.9% of the total space of 50.07 cc, which is larger than the internal space measured by any of the conventional batteries listed in FIG. 2A. In addition, for batteries with a thickness of 8 or 6 mils, the internal battery space can be further increased significantly. The calculated total space (cc) is further disclosed in the list of 圏 14B-24. This paper size applies Chinese national standards ( CNS > A4 specification (210 X 297 mm) y ί! Β I i I iy * '(please read the note # ^ on the back of Jing first and then fill out this page) Printed by A7, Intellectual Property Cooperative of Intellectual Property Bureau, Ministry of Economic Affairs

•· 9 3 Q B7__«««««_ 五、發明說明（22 ) 中，以比較於利用圖6所示超低構形密封製成之不同尺寸電 池之集流器總成空間。此處定義之集流器總成空間包括集 流器釘針、内蓋體、及負蓋體底表面與密封之間之任意空 間，而此處定義之容器空間包括罐體、標籤、負蓋體所用 之空間、標籤與負蓋體、正蓋體之間之空間、及正蓋體與 罐體之間之空間。可以瞭解的是，電池之總空間係等於可 用於電化學活性材料之内部空間、集流器總成空間、及容 器空間之總和，電池之總空間、集流器總成空間、及容器 空間則由電池之中央縱截面圉之CAD圖觀察決定。由圖14B 之列表可知，集流器總成空間大致上小於任一習知電池者 ，應瞭解的是集流器總成空間係利用超低構形密封結構而 減小，例如在超低構形密封中消耗之集流器總成空間爲 1.89 cc，此爲圖14B所示50.07 cc總空間之3.8% ;反之，其 小於囷2 B所列示習知電池測得之任意集流器總成空間。容 器空間亦可減小，同樣，對於具有一較小罐髏厚度爲8或6 密爾之電池而言，内部電池空間可進一步大幅增加，而容 器空間減小。 上述超低構形密封及超低構形密封之多個變換實例可見 於共同讓與之由Gary R_ Tucholski在1998年3月6EI提出之 09/036,208號「用於一包括一體成型密封/内蓋體之電化學 電池之集流器總成」美國專利申請案中，其内文在此可供 參考。 具有形成正突起之低構形密封及超低構形密封 如圖7所示’圖6中之第二實例可調整爲具有突起270 ,做 -25 - 本紙張尺度適用中國國家標準（CNS)A4规格(210 X 297公爱1 ~ l·-----il— y裝·ί I--—訂*---11 I I I •· (請先閲讀背面之沒意事項再填寫本頁) 經濟部智慧財產局員Η消費合作社印製 經濟部智慧財產局員工消費合作社印製 ^ 442990 -' A7 _______B7 五、發明說明（23 ) 爲直接設於罐體212封閉端214’内之正電池端子，依此，存 在於罐體212封閉端214與正外蓋體211之間之空間（如圖6) 可用於容納電化學活性材料，或提供空間用於氣體之收集 ’否則氣體會存在於電池内。習於此技者可進—步瞭解， 圖4中之第一實例同樣可做調整’即正外蓋體突起直接形成 於罐趙112底部，雖然直接形成突起於罐趙底部中而取得之 増加電池空間並未示於圖14 A之列表中，但是習於此技者應 瞭解到内部空間通常僅大於列表中所示超低構形密封或低 構形密封空間1%，而其係設有一分離式蓋體。 盘_成於罐體底部且具有L形密封之懕力錄放嫌Μ 依本發明第四實例製成之一電化學電池3〇〇係揭示於囷 8Α至8C，電池300不同於習知電池結構之處在於一壓力釋 放機構370形成於罐體312之封閉端314中，因此，複雜之集 流器/密封總成可代之以耗用較少空間且具有較少組件之集 流器總成，因而可取得大幅改善之内部電池空間效率β如 圖8Α、8Β、9、10所示，壓力釋放機構370係藉由提供一 槽道372於罐趙312底表面中而形成，此槽道之形成則利用 鑄造罐體312之一底表面、在底表面中切削出一槽道、或在 模製出正極時於罐體底表面中模製稽道〇以_ ΑΑ尺寸之電 池而言，鑄造槽道底部之金屬厚度大約2密爾，而以一；〇尺 寸之電池而言，轉造槽道底部之金屬厚度大約3密爾。槽道 可形成爲一大約300度之弧形，藉由保持槽道形成之形狀略 呈開口狀，壓力釋放機構將具有一實用之榧接。 槽道372外接區域之尺寸較佳爲經過選定，使得一旦因過 • 26- f紙張尺度適ώ中國國家標準<CNS)A4規格（210 * 297公漦) l·--ίίί — !^裝 i I! — 訂！！---始 -* (請先閱讀背面之注意事項再填寫本頁) Α7 442 9 9 Ο Β7 五、發明說明（24 ) 大内部壓力而造成破裂時，槽道372内之區域可在外蓋體 311之正突起内之極接處框轉，而不致干涉到外蓋件3Π。 大體上，由槽道372定義之區域尺寸以及槽道之選定深度係 依據罐體直徑及壓力釋放機構欲破裂時之壓力而定，且容 許内部產生之氣體逸出。 不同於先前技藝將壓力釋放機構形成於罐體側邊或末端 内’本發明之壓力釋放機構370係定位於外蓋體311下方， 以防止當破裂時電化學材料有害地自電池直接喷出。再者 ，若電池串聯於其他電池而使用，使得電池正端子之末端 壓抵於另一電池之負端子，外蓋體31 i提供於壓力釋放機構 370上即容許機構370在正突起下方向外弩曲且最後斷裂。 若外蓋體311未存在於此環境下，二電池之間之接觸即可防 止壓力釋放機構破裂。再者，若外蓋體311未提供於壓力釋 放機構370上方’則位於電池正端處之壓力釋放機構較易於 受損。外蓋體311亦遮蔽壓力釋放機構370免於受到周侧環 境之腐蚀，因而減少過早通氣及/或漏淺之可能性，因此， 藉由形成壓力釋放機構於外蓋體下方，則本發明可克服相 關於先前技藝結構之問題，且其提供一廣用之壓力釋放機 構於一電池β 因爲一壓力釋放機構形成於一電池罐體底表面中可不需 要一複雜之集流器/密封總成，因此電池之開口端可利用結 構技術加以密閉，其先前未利用是因爲需供氣體逸出壓力 釋放機構至電池外。例如®8Α、8Β所示，罐體312之開口 端可藉由放置一 J形截面之尼龍密封330或一 L形截面之尼龍 -27- 本紙張尺度適用中國國家標準<CNS)A4規格<210 * 297公藿） I I τ I I Hf I I I 1 . - I I I I I I I 一^«— — — — — — I— ^ •* {請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作杜印製 442990 Α7 Β7 五、發明說明（25 ) 密封330'於罐體312開口端内而封閉之，並嵌入一具有捲回 式環緣347之負外蓋體345於尼龍密封330或330·内，及隨後 摺縐罐體312之外緣313以定位密封330或33(V與蓋體345。爲 了協助定位密封330或330'，一頸緣316可形成於罐髏312開 口端周侧，尼龍密封330或330'可塗覆以柏油，以防護於電 化學活性材料及提供較佳之密封性。 請特別參閲圖8 A、8 C，環形尼龍密封330係揭示設有一 J 形截面，其包括一位於最外緣之延伸垂直壁332及一位於密 封徑向向内側之較短垂直壁336，五具有一形成於垂直壁 332、336之間之水平基件334。藉由設有短垂直段336，環 形密封可視同具有一J形或L形截面，應可瞭解的是J形尼 龍密封330亦可不具有短垂直段336，而形成圖8B所示之平 坦狀L形截面。 經濟部智慧財產局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁> 請特別參考圖8 C，説明圖8 A所示電化學電池之組合情形 。筒形罐體312設有側壁以定義開口端與頸緣316，可在罐 體封閉之前用於容置内部之電池材料。罐體312内設有活性 電化學電池材料，包括正、負電極與電解質，以及分隔件 及任意添加物》外蓋體345備有集流器釘針340熔接或固定 於蓋體345之底表面，其與環形尼龍密封330皆组裝及嵌入 罐體312之開口端，以封閉罐體312。集流器釘針340最好以 點熔料342熔接於外蓋體345之底侧，集流器釘針340與蓋體 345結合於密封330而構成集流器總成，集流器總成則嵌入 罐體312内，使外蓋體345之捲回式環緣347抵於用以支承密 封330之頸緣316上方之環形密封330内側壁面。集流器總成 -28- 本紙張尺度適用中國國家標準（CNS)A4蜆格（210 X 297公釐） 五、發明說明（26 ) 強迫留置於罐體312之開口端内，以利緊密結合及封閉罐體 之開口，罐體312之外緣313随後向内摺，而在軸向迫使密 封330與外蓋體345定位。 復參閲囷8Β，外蓋體345之内側表面及集流器釘針34〇之 至汐一頂部係進一步揭示塗覆一抗腐蚀之塗層344，抗腐蚀 塗層344包括在電化學性上相容於陽極之材料，此電化學性 相容材料之範例包括環氧樹脂、鐵弗龍<»、聚缔烴、尼龍、 彈性材料、或其他任意惰性材料、單獨或與其他材料之併 合。塗層344可用喷塗或塗覆的，且其較佳爲覆蓋於曝露在 電池正、負電極上方空隙區域中活性材料之外蓋體345内侧 表面與集流器釘針340部份，亦應瞭解的是，蓋體345之内 側表面可鍍以錫、銅或其他同樣在電化學性上相容之材料 。藉由提供抗腐蝕塗層344，外蓋體345與集流器釘針340之 腐蝕即可減少及/或避免’其有利於減少發生在電化學電池 内之氣體量，而減少電池内之產氣即可減少内部壓力建立。 如圖14Α所示’在「罐體底部之壓力釋放」及「含有薄壁 之罐體底部中壓力釋放」諸列中，使用圖8Α所示結構之一 D尺寸電池在罐體壁面爲10密爾厚度時係具有一呈93.5%空 間之内部空間，且當罐礅壁面爲8密爾厚度時則具有一呈 94.9%空間之内部空間》如圖14Β所示，使用圖8Α所示結構 之一 D尺寸電池在罐體壁面爲1〇及8密爾厚度時則具有2 % 總空間之一集流器總成空間。具有相似結構之C、ΑΑ、 ΑΑΑ尺寸電池在内部空間效率上亦呈現顯著之改善，如圖 14 Α之列表所示。 -29- 本紙張尺度適用中國國家標準（CNS)A4规格（210 X 297公釐） <請先閱讀背面之注意事項再填寫本頁) >裝 訂---------嫜 經濟部智慧財產局員工消費合作社印製 A7 B7 »<44299 0 五、發明說明（27 ) 飲料罐體式結槿 圖8 A-10所示壓力釋放機構之使用可進一步容許圖11所 示飲料罐體式結構之使用，所示飲料罐體式結構不同於其 他型式電池密封結構之處在於其並不需要任何型式之尼龍 密封廢入罐體412之開口端内，而是負外蓋體445利用習知 將一食物或飲料罐體頂部封合至罐體筒形部之密封技術， 以固接於罐體412之開口端，此種密封結構先前並未考慮用 於封閉電池，因爲其並未能穩定地容許負外蓋體絕緣於罐 體。 製造一具有囷11所示結構之電池的方法將參考圖12A_ 12D而説明之。在將負外蓋體445接附於罐鱧412開口端之前 ’ 一集流器釘針440係溶接於蓋想445之内表面，其次如圖 12A所示，蓋體445之内表面以及蓋體445上表面之周迻部係 塗以一層電絕緣材料475，例如環氧樹脂、尼龍、鐵弗龍® 、或乙烯基。延伸於蓋體445底部與負極/電解質混合物12〇 之間空隙區域内之集流器釘針440部份亦塗以電絕緣物，此 外，罐體412之内與外表面亦在罐體開口端之區域中塗覆。 此塗層475可利用喷霧、浸潰、或靜電沉積而直接施加於罐 體與蓋體，藉由提供此一塗層，負外蓋體445即可電絕緣於 罐體412。 藉由施加絕緣塗層於接近電池内部空間内空隙區域之電 池罐體、蓋體及集流器釘針等區域，諸區域即可免於腐蝕 ，雖然由上述單層環氧樹脂、尼龍、鐵弗龍®、或乙烯基材 料組成之一塗層可用於防止此腐蝕，但是可知的是塗層亦 -30- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公* ) (請先閱讀背面之注$項再填寫本 Θ裝------- 1訂---------轉 經濟部智慧財產局員工消費合作社印製 442 9 9 〇 A7 B7 經濟部智慧財產局員工消費合作社印？4 五、發明說明（28 ) :禾用—不同材料層施加’或由單層不同材料施加於不同 成分區而製成。例如蓋體之周邊區可塗以單層材料，以做 爲一電絕緣體及-抗蚀廣，而蓋體内表面上之中央部可塗 以單層材料’以做爲抗蝕層但是無電絕緣體功能，此材料 例如包括柏油或聚酿胺。另者，罐體或蓋體任—者可塗以 一材料，做爲一電絕緣體及抗蝕層，而此二組件之另一者 則塗以一材料，而僅做爲一抗蝕層。依此，電絕緣可依需 要處而提供（即蓋體/罐體介面之間），而局部定義出電池内 部空間中空隙區域之表面仍可防護於電池内之電化學材料 腐蝕效應。再者，藉由使用不同材科，材料可經選定，而 以較低成本或呈現理想特徵達成所需功能。 欲協助外蓋體445封閉於罐體412，一習知之密封劑473可 施加於蓋體445環緣470之底表面，一旦密封程序完成時， 密封劑473即移入圖12D所示之位置。 一旦集流器釘針440己接附於外蓋體445且電絕緣塗層已 施加後，外蓋體445即置放於罐體412之開口端上，如圖12B 所示。罐體412最好具有一向外延伸之突緣450形成於其開 口端處’再者，外蓋體445最好具有一略爲彎曲之環緣47〇 且貼服於突緣450之形狀。一旦外蓋體445已置放於罐體412 之開口端上，一接合夹頭500放置於外蓋體445上，使接合 夾頭500之一環形向下延伸部502由一形成於外蓋體445内之 環形凹穴472容置。其次，一第一接合捲510在一徑向移向 蓋體445之環緣470，當第一接合捲510移向環緣470及突緣 450時，其弧形表面使環緣470摺繞於突緣450 ;再者，當第 31 本紙張尺度適用中國國家標单<CNS)A4规格（210 χ 297公爱） l·—：--------> 裝--------訂 * (請先閲讀背面之注意事項再填寫本頁)• · 9 3 Q B7 __ «« «« «_ 5. In the description of the invention (22), the space of the current collector assembly of batteries of different sizes made by using the ultra-low profile seal shown in Fig. 6 is compared. The current collector assembly space defined here includes the current collector pins, the inner lid, and any space between the bottom surface of the negative lid and the seal, and the container space defined here includes the tank, label, and negative lid. The space used by the body, the space between the label and the negative cover, the space between the positive cover, and the space between the positive cover and the tank. It can be understood that the total space of the battery is equal to the sum of the internal space, current collector assembly space, and container space available for electrochemically active materials. The total space of the battery, current collector assembly space, and container space are It is determined by the CAD drawing of the central longitudinal section of the battery. As can be seen from the list in FIG. 14B, the space of the current collector assembly is substantially smaller than that of any conventional battery. It should be understood that the space of the current collector assembly is reduced by using an ultra-low configuration sealing structure, for example, in the ultra-low configuration. The space consumed by the current collector assembly in the hermetic seal is 1.89 cc, which is 3.8% of the total space of 50.07 cc shown in Figure 14B; otherwise, it is less than the total current measured by any of the conventional batteries listed in 所列 2 B. Into space. The container space can also be reduced. Similarly, for a battery with a smaller can with a thickness of 8 or 6 mils, the internal battery space can be further increased significantly, while the container space is reduced. Examples of the above-mentioned ultra-low profile seals and multiple transformations of ultra-low profile seals can be found in the jointly assigned No. 09 / 036,208 proposed by Gary R. Tucholski at 6EI on March 1998. The current collector assembly of a bulk electrochemical cell is incorporated herein by reference. The low-profile seal and ultra-low-profile seal with positive protrusions are shown in Figure 7. 'The second example in Figure 6 can be adjusted to have protrusions 270, made -25-This paper size applies Chinese National Standard (CNS) A4 Specifications (210 X 297 Public Love 1 ~ l · ----- il— y equipment · ί I --— order * --- 11 III • · (Please read the unintentional matter on the back before filling this page) Economy Printed by members of the Intellectual Property Bureau of the Ministry of Consumers ’Cooperatives and printed by the Consumer Cooperatives of the Ministry of Economy ’s Intellectual Property Bureau ^ 442990-'A7 _______B7 V. Description of the invention (23) is a positive battery terminal directly located in the closed end 214' of the tank 212. Therefore, the space existing between the closed end 214 of the tank body 212 and the positive outer cover body 211 (as shown in FIG. 6) can be used to accommodate the electrochemically active material, or to provide space for the collection of the gas, or the gas will exist in the battery. Those skilled in the art can further understand that the first example in FIG. 4 can also be adjusted. That is, the protrusions of the positive outer cover are directly formed on the bottom of the tank Zhao 112, although the protrusions formed directly on the bottom of the tank Zhao are added. Battery space is not shown in the list in Figure 14 A, but those skilled in the art should The internal space is usually only 1% larger than the ultra-low profile seal or low-profile seal space shown in the list, and it is equipped with a separate cover. The disc is formed at the bottom of the tank and has the force of an L-shaped seal Recording and playback of an electrochemical cell 300, which is made according to the fourth example of the present invention, is disclosed in 囷 8A to 8C. The battery 300 differs from the conventional battery structure in that a pressure release mechanism 370 is formed in the can body 312. Terminal 314, therefore, a complex current collector / seal assembly can be replaced with a current collector assembly that consumes less space and has fewer components, thus achieving a significantly improved internal battery space efficiency β as shown in Figure 8A As shown in Figures 8B, 9, and 10, the pressure release mechanism 370 is formed by providing a channel 372 in the bottom surface of the tank Zhao 312. The channel is formed by casting one of the bottom surfaces of the tank body 312 on the bottom surface. Cut a channel in the middle, or mold the channel in the bottom surface of the tank when the positive electrode is molded. For a battery of the size _AA, the metal thickness at the bottom of the casting channel is about 2 mils, and one; For sized batteries, the metal thickness at the bottom of the conversion channel is large 3 mil. The channel can be formed into an arc of about 300 degrees. By keeping the shape of the channel slightly open, the pressure release mechanism will have a practical connection. The size of the outer area of the channel 372 is better To be selected so that once it has passed • 26-f paper size is suitable for Chinese National Standards < CNS) A4 size (210 * 297 Gong) l · --ίίί —! ^ 装 i I! — Order! !! --- Begin- * (Please read the precautions on the back before filling in this page) Α7 442 9 9 〇 B7 V. Description of the invention (24) When the internal pressure is broken, the area inside the channel 372 can be on the outer cover The pole inside the positive protrusion of 311 is frame-turned without interfering with the outer cover member 3Π. Generally, the size of the area defined by the channel 372 and the selected depth of the channel are determined according to the diameter of the tank and the pressure when the pressure release mechanism is to be broken, and the gas generated inside is allowed to escape. Different from the prior art, the pressure release mechanism is formed in the side or the end of the tank body. The pressure release mechanism 370 of the present invention is positioned under the outer cover 311 to prevent the electrochemical material from harmfully ejecting directly from the battery when it is broken. Furthermore, if the battery is used in series with other batteries, the end of the positive terminal of the battery is pressed against the negative terminal of another battery, and the outer cover 31 i is provided on the pressure release mechanism 370 to allow the mechanism 370 to outward under the positive protrusion. Crossbow and finally broke. If the outer cover 311 does not exist in this environment, the contact between the two batteries can prevent the pressure release mechanism from breaking. Furthermore, if the outer cover 311 is not provided above the pressure release mechanism 370 ', the pressure release mechanism located at the positive end of the battery is more likely to be damaged. The outer cover 311 also shields the pressure release mechanism 370 from being corroded by the surrounding environment, thereby reducing the possibility of premature ventilation and / or leakage. Therefore, by forming a pressure release mechanism under the outer cover, the present invention It can overcome the problems related to the prior art structure, and it provides a widely used pressure release mechanism in a battery β. Because a pressure release mechanism is formed in the bottom surface of a battery tank, a complicated current collector / seal assembly is not required. Therefore, the open end of the battery can be sealed using structural technology, which was not previously used because the gas needs to be released from the pressure release mechanism to the outside of the battery. For example, as shown in 8A and 8B, the open end of the can body 312 can be placed with a J-shaped nylon seal 330 or an L-shaped nylon-27. This paper size applies to Chinese national standards < CNS) A4 specifications < 210 * 297 public 藿) II τ II Hf III 1.-IIIIIII a ^ «— — — — — — I— ^ • * {Please read the notes on the back before filling out this page) Staff Consumption of Intellectual Property Bureau of the Ministry of Economic Affairs Cooperative Du printed 442990 Α7 Β7 V. Description of the invention (25) Seal 330 'is closed inside the open end of the tank 312, and a negative outer cover 345 with a roll-back ring 347 is sealed in a nylon seal 330 or 330 Inner and subsequently crease the outer edge 313 of the can body 312 to position the seal 330 or 33 (V and lid 345. To assist in positioning the seal 330 or 330 ', a neck rim 316 may be formed on the periphery of the open end of the canister 312 Nylon seal 330 or 330 'can be coated with asphalt to protect against electrochemically active materials and provide better sealing. Please refer to Figures 8A and 8C in particular. The ring nylon seal 330 is disclosed with a J-shaped cross section. It includes an extended vertical wall 332 at the outermost edge and a radial seal The inner short vertical wall 336, five has a horizontal base member 334 formed between the vertical walls 332, 336. By providing a short vertical section 336, the annular seal can be regarded as having a J-shaped or L-shaped cross section, which should be able to It is understood that the J-shaped nylon seal 330 may not have a short vertical section 336, but forms a flat L-shaped cross-section as shown in Figure 8B. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling in this Page> Please refer to FIG. 8C in particular for the combination of the electrochemical cells shown in FIG. 8A. The cylindrical tank 312 is provided with a side wall to define the open end and the neck edge 316, and can be used for containing the tank before the tank is closed. Internal battery material. The tank body 312 is provided with active electrochemical battery materials, including positive and negative electrodes and electrolytes, as well as separators and any additives. The outer cover 345 is equipped with a current collector pin 340 for welding or fixing to the cover. The bottom surface of the body 345, which is assembled with the annular nylon seal 330, is embedded in the open end of the can body 312 to close the can body 312. The current collector pin 340 is preferably welded to the outer cover body 345 with a spot melt 342. On the bottom side, the current collector pin 340 is connected to the cover 345 Combined with the seal 330 to form a current collector assembly, the current collector assembly is embedded in the tank 312, so that the roll-back ring 347 of the outer cover 345 abuts the ring above the neck 316 used to support the seal 330 Seal the inner wall surface of 330. Collector assembly -28- This paper size applies to Chinese National Standard (CNS) A4 grid (210 X 297 mm) V. Description of the invention (26) Forced to stay in the open end of tank 312 In order to tightly combine and close the opening of the can body, the outer edge 313 of the can body 312 is then folded inward, and the seal 330 is axially forced to position with the outer cover 345. Referring back to 囷 8B, the inner surface of the outer cover 345 and the top of the current collector pin 340 to the top of the XI are further disclosed to apply a corrosion-resistant coating 344, which is electrochemically included Anode-compatible materials. Examples of this electrochemically compatible material include epoxy resin, Teflon < », polyalkylene, nylon, elastomer, or any other inert material, either alone or in combination with other materials. . The coating layer 344 can be sprayed or applied, and it is preferable to cover the inner surface of the cover 345 and the portion of the current collector pin 340 outside the active material in the gap area above the positive and negative electrodes of the battery. It is understood that the inner surface of the cover 345 can be plated with tin, copper, or other materials that are also electrochemically compatible. By providing an anti-corrosive coating 344, the corrosion of the outer cover 345 and the current collector pins 340 can reduce and / or avoid 'it is beneficial to reduce the amount of gas that occurs in the electrochemical cell and reduce the production in the cell Gas reduces internal pressure build-up. As shown in FIG. 14A, among the columns of “pressure release at the bottom of the tank” and “pressure release at the bottom of the tank with thin walls”, a D-size battery having a structure shown in FIG. It has an inner space with a thickness of 93.5%, and an inner space with a space of 94.9% when the wall thickness of the tank is 8 mils. "As shown in Figure 14B, one of the structures shown in Figure 8A is used. D-size batteries have a current collector assembly space of 2% of the total space when the tank wall is 10 and 8 mils thick. C, ΑΑ, ΑΑΑ size batteries with similar structure also show significant improvements in internal space efficiency, as shown in the list of Figure 14A. -29- This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) < Please read the notes on the back before filling this page) > Binding --------- 嫜 Economy Printed by the Ministry of Intellectual Property Bureau's Consumer Cooperatives A7 B7 »< 44299 0 V. Description of the invention (27) Beverage can body type Figure 8 A-10 The use of the pressure release mechanism can further allow the beverage can body type shown in Figure 11 The use of the structure, the beverage can body structure shown is different from other types of battery seal structure in that it does not require any type of nylon seal waste into the open end of the can body 412, but the negative outer cover 445 A sealing technique for sealing the top of a food or beverage can body to the cylindrical part of the can body to be fixed to the open end of the can body 412. This type of sealing structure has not been previously considered for closing the battery because it has not been stable. Allow the negative cover to be insulated from the tank. A method of manufacturing a battery having the structure shown in Fig. 11 will be described with reference to Figs. 12A-12D. Before attaching the negative outer cover 445 to the open end of the tank 412, a current collector pin 440 is fused to the inner surface of the cover 445, and as shown in FIG. 12A, the inner surface of the cover 445 and the cover The top surface of 445 is covered with a layer of electrically insulating material 475, such as epoxy, nylon, Teflon®, or vinyl. The portion of the current collector pin 440 extending in the space between the bottom of the lid 445 and the anode / electrolyte mixture 12 is also coated with electrical insulation. In addition, the inner and outer surfaces of the can 412 are also at the open end of the can Area. The coating 475 can be directly applied to the can body and the cover body by spraying, dipping, or electrostatic deposition. By providing this coating layer, the negative outer cover body 445 can be electrically insulated from the can body 412. By applying an insulating coating to the battery can, lid, and current collector pins near the void area in the battery's internal space, the areas can be protected from corrosion. A coating made of Furon® or vinyl material can be used to prevent this corrosion, but it is known that the coating is also -30- This paper size applies to Chinese National Standard (CNS) A4 (210 X 297mm *) (Please Read the note $ on the back before filling in this Θ package --------- 1 order --------- Transferred to the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the employee consumer cooperative 442 9 9 〇 A7 B7 Wisdom of the Ministry of Economic Affairs Printed by the staff of the Property Bureau, Consumer Cooperatives? 4 V. Description of the invention (28): Grain-applied with different material layers or made of a single layer of different materials applied to different composition areas. For example, the peripheral area of the cover body can be coated with a single layer Material to be used as an electrical insulator and anti-corrosive, and the central part of the inner surface of the cover can be coated with a single layer of material 'as a resist but has no electrical insulator function. This material includes, for example, asphalt or polyurethane In addition, either the tank or the lid can be coated with a material as a Insulator and resist, while the other of the two components is coated with a material and serves only as a resist. Accordingly, electrical insulation can be provided where needed (that is, between the lid / tank interface) ), And the surface that defines the void area in the internal space of the battery can still be protected from the corrosion effect of the electrochemical materials in the battery. Furthermore, by using different materials, the materials can be selected, and the cost can be lower or present ideal Features to achieve the required function. To help the outer cover 445 be closed to the tank 412, a conventional sealant 473 can be applied to the bottom surface of the ring 470 of the cover 445. Once the sealing process is completed, the sealant 473 is moved to FIG. 12D Once the current collector pin 440 has been attached to the outer cover 445 and the electrical insulation coating has been applied, the outer cover 445 is placed on the open end of the tank 412, as shown in FIG. 12B The tank body 412 preferably has an outwardly extending flange 450 formed at the open end thereof. Furthermore, the outer cover 445 preferably has a slightly curved ring edge 47 and conforms to the shape of the flange 450. Once the outer cover 445 has been placed on the open end of the tank 412, The chuck 500 is placed on the outer cover 445, so that an annular downward extension 502 of the engagement chuck 500 is accommodated by an annular recess 472 formed in the outer cover 445. Second, a first engagement roll 510 A ring 470 moves radially toward the cover 445. When the first joint roll 510 moves to the ring 470 and the flange 450, its curved surface causes the ring 470 to be folded around the flange 450; 31 This paper size applies to China National Standards < CNS) A4 specification (210 χ 297 public love) l · — ： -------- > Packing -------- Order * (please first (Read the notes on the back and fill out this page)

經濟部智慧財產局員工消費合作社印製 ^42 990 A7 ___B7_____ 五、發明說明（29 ) 一接合捲510朝徑向向内移動時，接合央頭50〇、罐體412、 及外蓋趙445皆相關於一中心輕線旋轉，使環緣470相關於 罐體412之全部周邊而摺繞於突緣45〇 ;又，當第一接合捲 510繼績朝徑向向内移時，突緣45〇及環緣47〇即向下摺至圖 12C所示之位置。 在環緣470及突緣450已摺至圖12C所示之位置後，第一接 合捲510係自罐體412移開，且一第二接合捲52〇沿徑向朝内 移向突緣450及環緣470。第二接合捲520具有一不同於第一 接合捲510者之構形，第二接合捲52〇施加足夠之力於突緣 450及環緣470，以將摺疊之突緣與環緣壓扁於罐體412之外 表面，i其係由接合央頭5〇〇支承。此程序之結果爲罐體 412之環緣470摺繞於突緣450下方，且摺縐於突緣450與罐 體412壁面外表面之間，如圖u、12D所示，一密閉封合因 而可由此程序形成。 爲了説明此密封型式之密閉性質，依本發明實例而構成 之一D尺寸罐體係填入水，—如囷〗所示以習知密封構成之 D尺寸罐體，二罐體皆保持在71。〇且經稱重以判斷水份自 罐體損耗之量，習知結構爲每星期損耗27〇毫克，而本發明 之結構在相同時間内並未失去任何重量。此結果可利用 KOH(氫氧化鉀）電解質予以確認，習知結構每星期損耗5〇 毫克，而本發明之結構仍未損失任何重量。 習於此技者可知，飲料罐體式結構使用電池内部最少之 空間，減少製造電池所需之製程步驟數量，及大幅減低材 料成本與製程成本，此外，罐醴之厚度可大幅減小至6密爾 •32- 本紙張尺度適用中國國家楳準<CNS>A4规格<210 X 297公《 ) l·------- Θ&· — !----t-------I . ^ (請先閲讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs ^ 42 990 A7 ___B7_____ V. Description of the invention (29) When the joining roll 510 is moved radially inward, the joining center 50, the tank 412, and the outer cover 445 are all In relation to a center light line rotation, the ring edge 470 is related to the entire periphery of the tank body 412 and is folded around the flange 45. Also, when the first joining volume 510 continues to move radially inward, the flange 45 〇 and the ring edge 47〇 are folded down to the position shown in FIG. 12C. After the ring 470 and the flange 450 have been folded to the position shown in FIG. 12C, the first joint roll 510 is removed from the tank body 412, and a second joint roll 52 is moved radially inward to the flange 450. And the ring 470. The second bonding roll 520 has a configuration different from that of the first bonding roll 510. The second bonding roll 52 applies sufficient force to the flange 450 and the ring 470 to flatten the folded flange and the ring to The outer surface of the tank body 412 is supported by the joint head 500. The result of this procedure is that the ring 470 of the tank 412 is folded below the flange 450, and is folded between the flange 450 and the outer surface of the wall of the tank 412, as shown in Figures u and 12D. Can be formed by this program. In order to illustrate the sealed nature of this sealed type, one of the D-size tank systems constructed according to the examples of the present invention is filled with water—as shown in Figure 囷, the D-size tanks with conventional seals are constructed, and both tanks are kept at 71. 〇Weighed to determine the amount of water lost from the tank, the conventional structure loses 27 mg per week, and the structure of the present invention does not lose any weight in the same time. This result can be confirmed using a KOH (potassium hydroxide) electrolyte. The conventional structure loses 50 mg per week, and the structure of the present invention has not lost any weight. Those skilled in the art can know that the beverage can body structure uses the minimum space inside the battery, reducing the number of process steps required to manufacture the battery, and greatly reducing the material and process costs. In addition, the thickness of the can can be greatly reduced to 6 mils • 32- This paper size is applicable to China's national standards < CNS > A4 specifications < 210 X 297 male ") l · ------- Θ & ·-! ---- t ----- --I. ^ (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

r Λ Λ ；：" 9 U A7 ______B7____ 五、發明說明（30 ) 以下，因此可増加用於容納電化學活性材料之内部空間。 例如以一 D尺寸電池而言，用於容納電化學活性材料之總 電池空間百分比可高至97%空間，而集流器總成空間可低 至1 · 6 %空間，其他尺寸電池之空間係包括於圖τ 4A、〗46之 列表中。 藉由使用本發明之密封結構，不僅罐體之壁厚可減小， 可用於形成罐體之材料數量亦因減低罐體展示所需之強度 要求而増加，例如上述之本發明結構可以鋁或塑膠用於罐 體，而非目前所用之鍍鎳鋼。 飲料罐體結構之一變化型式係揭示於圖13中，在揭述之 實例中電池罐體先形成一具有二開口端之管件，管件可利 用習知技術抽拉、溶接、焊接、黏接，管件可由鋼、鋁、 或塑膠製成。如圖13所示，管件定義出罐體612之側壁614 ’管件之一第一開口端随後利用上述之飲料罐體密封技術 固接一内蓋雜616而封閉之，不同的是内蓋禮616與侧壁614 之間不需要電絕緣。一正外蓋體618可熔接或固接於内蓋體 616之外表面，電池隨後填充且一負外蓋體645以相同於上 述方式固接於罐體612之第二開π端。 罐體上之印刷橾碑 如上所示，本發明之電池結構可併合用於一印刷標籤， 而非目前使用之標籤基材，現有之標籤基材具有3密爾厚度 ，由於此標籤基材重疊而沿電池長度形成一接缝，諸習知 標籤實質上增加大約10密爾直徑及13密爾電池摺縐高度， 結果電池罐體需具有一經過選定以配合標籤接缝厚度之直 -33 - 本紙張尺度適用中國國家標準（CNS)A4规格（210 X 297公釐） L--If--Γ---- I I--- 訂------— ·'" -* (請先閱讀背面之注意事項再填寫本頁) f A4299 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（31 ) 杈，以符合ANSI尺寸標準。惟，藉由依據本發明將—石版 印刷標籤直接印於罐體之外表面上，罐體之直徑可對應地 増大至大約10密爾，罐體之此項直徑增加則可増大電池之 内部空間。除了飲料罐體結構外，圖14A、14B列表中之所 有電池皆包括基材標籤’具有基材標籤之電池之内部空間 可對一D尺寸電池增加2%(1‘〇2 cc)、對一 C尺寸電池增加 2.6%(〇.65 cc)、對一 AA尺寸電池增加3.9%(0.202 cc)、及對 一八八八尺寸電池增加5.5%(0.195(^)，且標籤係直接印於罐 體外部上。標籤亦可利用轉印技術以印於罐體上，其中標 籤之影像先印於一轉移介質上，随後直接轉移至罐體外部 上。扭曲之石版印刷亦可使用，使得故意扭曲之圖案印於 平坦材料上’以利於平坦材料形成電池罐體之管件或筒件 時可配合平坦材料之後績應力扭曲。 在印製石版印刷標籤之前，罐體之外表面最好先予以清 潔，爲了強化印刷物對罐體之黏接，底漆之底塗層可施加 於罐體之外表面，印刷標籤随後直接利用習知之石版印刷 技術以施加於罐體上之底塗層頂面上。一亮光漆覆層最好 施加於印刷標籤上，以覆蓋及防護印刷標籤，且亦做爲一 電絕緣層。印刷標籤可利用高溫加熱或紫外線技術固化。 由於使用印刷標籤，一習知標籤基材之厚度係大幅減小 至大約0.5密爾之最大厚度，特別是底塗層之厚度爲大約 0.1至0.2密爾’印刷層具有大約。^密爾厚度，及亮光漆 覆層具有大約0.1至0.2密爾厚度，藉由減小標籤厚度，罐 禮可増大直徑，藉此提供增加活性電池材料之可用空間， -34- 本紙張尺度適用中國國家標準（Cns)A4規格（210 X 297公轚） l·--Γ — —·------ ---I I--—訂·1 — 1 — *^v • · <請先閱讀背面之注意事項再填寫本頁) ^ 4429 9 Ο Α7 _Β7___ 五、發明說明（32 ) 而保持電池之一預定外徑。 具有饋送通過集流器之飲料鏘艚 參閲圖1 5，一電化學電池700係揭示設有一依據本發明第 七實例之饋送通過集流器，相似於具有圖i i所示飲料罐體 式結構之電化學電池400的是，電化學電池700包括一導電 罐禮712 ’其具有一封閉端314及一開口端供一小空間集流 器總成725與外負蓋體750組裝於内。電化學電池7〇〇包括一 正極115，以接觸於罐體712之内壁，以及接觸一位於一正 極115與一負極120之間之分隔件117，正極115在此亦稱爲 陰極，而負極120稱爲陽極❶應瞭解的是，材料類型及其在 電化學電池内之位置可在不脱離本發明内容下改變。 電化學電池700亦包括一形成於罐體712封閉端314中之壓 力釋放機構370，此可供採用小空間之集流器總成725 ,而 比習知之集流器總成消耗較少之空間，因此可取得改善之 内部電池空間。壓力釋放機構370可形成如圖8A、8B、9 、10所示之槽道狀，此外，一正外蓋體311連接於罐體712 之封閉端且重疊於壓力釋放機構370 ,正外蓋體311之組合 與位置係相關於囷8A之説明。 電化學電池700包括一集流器總成725，用於封閉罐體712 之開口端，集流器總成725包括一呈電接觸於負極120之集 流器釘針740，集流器總成725内亦包括一第一或内蓋體745 ，其内部形成一中央孔751，集流器釘針740即設於及穿過 内蓋體745中之孔751。一電介質絕緣材料744係設於集流器 釘針740與第一蓋體745之間，以提供電介質絕緣於其間， -35- 本紙張尺度遇用中國國家楳準（CNS)A4规格（210 297公* ) <請先閲讀背面之注意事項再填寫本頁) ^裝--------訂---------蜱 經濟部智慧財產局員工消費合作社印製 4429 9 Ο 經濟部智慧財產局員工消費合作社印製 Α7 Β7___ 五、發明說明（33 ) 據此，集流器釘針740呈電隔離於内蓋體745。電介質絕緣 村料744係一有機巨分子材料，例如一有機聚合物，且可包 括環氧樹脂、橡膠、尼龍、或可抗氫氧化鉀侵蝕且在鹼性 電池t氫氧化鉀存在情況下不致腐蝕之其他電介質材料， 電介質絕緣材料係依以下說明方式組合。 内蓋體745依序連接及封閉於罐體712之頂開口端，内蓋 體745可藉由形成一雙重接合於環緣45〇、47〇處而嵌入罐體 712及封合於罐體712，如圖U_13所示，本發明第七實例 雖然配合一雙重接合之罐體_蓋體封閉件做説明，但是可以 瞭解的是其他罐體-蓋體封閉件在不脱離本發明内容下仍可 採用。 依據第七實例以直接連接於罐體7n與内蓋體？45之間之 電化學電池700最好提供一壓力密封於其間，但是在内蓋體 745與罐體712侧壁之間並不需要做電隔離，而是集流器釘 針740絕緣於内蓋體745，使電化學電池之負與正端子相互 呈電隔離。罐體712與内蓋體745之間雖然不需要保持電隔 離’但是其較佳爲一密封劑施加於將罐體接合於蓋體之封 閉件處’以利適當密封罐體，適合之密封劑可如圖1 J _丨2D 所示電池中使用者。可以瞭解的是，沿著絕緣材料之封閉 件可内部建立之壓力，且此大於壓力釋放機構37〇釋壓時之 通氣壓力。 爲了依照可接受之電池標準而提供一可接受之外部電池 端子’電化學電池700進一步包括一呈電接觸於集流器釘針 740之外蓋體750，外蓋體750可利用點熔接物742熔接，或 l· I —Γ— ΙΓ------ ---— I 訂·！ 轉v '1 (請先閱讀背面之注意事項再填寫本頁) 1 36 本紙張尺度適用中國國家標準（CNS)A4規格（21〇 X 297公釐） A7 ^ 442990 B7 五、發明說明（34 ) 者電連接於集流器釘針74〇 β爲了確使外蓋體75〇與内蓋體 745之間有正確之電絕緣，一電介質材料如環形墊748係設 於外負蓋體750與内蓋體745之間，適合之電介質材料包括 尼龍' 其他彈性材料、橡膠、及環氧樹脂，係施加於内蓋 體745頂表面上或外蓋體750底表面上，據此，一可接受之 標準電池端子即可提供於電化學電池7〇〇之負端。 本發明第七實例之電化學電池7〇〇組合情形係説明於圖1 6 之組合圖中，且其進一步揭示於圖丨7之流程圖中。電化學 電池700之組合方法770包括提供罐體712,且罐體設有一封 閉之底端及開口之頂端。步驟774包括放置活性電化學材料 於罐體712内，其包括負極、正極、及一電解質，以及分隔 件與其他電池添加物一旦活性電化學電池材料置入罐體 712内時，罐體712即準備以集流器總成725封閉及密封，封 閉罐體之前，集流器總成係依步驟776藉由先將集流器釘針 740沿著一絕緣材料環，而置入一設於内蓋體745中之孔751 内。集流器釘針740放入絕緣環744之開口 742内，絕緣環包 括一環形或碟形環氧樹脂，可提供電介質絕緣及可加熱以 再成型與定置於内蓋體745與集流器釘針740之間。另者， 其他有機巨分子電介質絕緣材料可用於替代環氧樹脂，例 如一橡膠環、一彈性材料、或可在集流器釘針740與内蓋體 745之間形成適當絕緣之其他電介質材料。内蓋體745中亦 設有一凹穴755，其係位於頂表面内且相關於孔751而位於 中央處^ 依據較佳實例，絕緣材料環744係位於内蓋體745頂部上 _ 37 本紙張尺度適用中國國家標準(CNS>A4規格⑵0X 297公~ K---fllf--------I I---^ίιιιιί·^ • * (請先閱讀背面之注§項再填寫本頁) 經濟部智慧財產局貝工消费合作社印製 經濟部智慧財產局員工消費合作社印數 442990 A7 ______B7_____ 五、發明說明（35 ) 之凹穴755内，且集流器釘針740之頂頭部位於其上方。在 步驟778中，絕緣環744组合於集流器釘針740與蓋體745， 且絕緣環744加熱至相當高之溫度，而足以熔化圈環744， 使圈環744再次成型及流入蓋體745中之孔751，以利提供連 續式電介質絕緣於集流器釘針740與内蓋體745之間。以一 由環氧樹脂製成之圈環744而言，2 0 °C至200°C溫度持續數 秒至24小時即可適度再成型及固化絕緣材料，一旦電介質 材料744形成適度絕緣於集流器釘針740與内蓋體745之間時 ，絕緣材料最好在步驟780中冷却。在加熱與冷却步驟778 、780期間，集流器釘針740定位於孔751内之中央，使針針 740不致接觸到蓋體745。隨後在步驟782中，一電介質絕緣 墊748如一環形電介質誓係設於内蓋體745頂部上，且自釘 針740周邊沿徑向向外延伸。在步驟784中，集流器針針740 與墊片748頂部上設有一導電性負蓋體750，其係熔接或形 成電接觸於集流器釘針740。一旦集流器總成完全組合時， 集流器總成隨後連接於罐體，以密封由步骤786中提供之開 口端。罐體封閉可採用一雙重接合封閉，或其他適當之罐 體封閉技術。此外，組合方法770包括連接一第二外蓋體至 罐體封閉端之步骤788，且其最好重疊於壓力釋放機構3 7〇。 本發明雖然在前述中主要應用於驗性電池，但是習於此 技者可知，相似效益可在使用本發明於其他電化學系統之 電池中取得。例如本發明結構可用於基本系統中，例如碳 鋅及錢電池及可充電式電池中，例如鎳鎘、金屬氫化物、 及鋰電池。再者，本發明之特定結構可用於未加工之電池 -38- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） --------Γ--— ！-^裝------ 訂-------梭 (請先閲讀背面之注意事項再填寫本頁) ir 442 9 9 0 A7 B7_ 五、發明說明（36 ) 内（即電池組或多單元式電池中所用之無標籤電池）。此外 ，雖然本發明已相關於筒形電池做説明，但是本發明之特 定結構仍可用於構成稜鏡形電池。 上述説明應僅視爲較佳實例，本發明之調整型式可由習 於此技者及達成或利用本發明者爲之，因此，可以瞭解到 圖式及前述之實例係僅供説明，而非偈限本發明之範固， 其應依專利法規定而由以下申請範園定義之。 l·--k- — —f!·! W 裝---！！— 訂·—11 — -M'^- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 3Θ 本紙張尺度適用中國國家標準（CNS)A4规格（210 X 297公« )r Λ Λ;: " 9 U A7 ______B7____ V. Description of the invention (30) Below, it can be added to the internal space used to accommodate electrochemically active materials. For example, for a D-size battery, the percentage of the total battery space used to hold the electrochemically active material can be as high as 97%, and the current of the current collector assembly can be as low as 1.6%. The space of other sizes of batteries is Included in the list of Figures τ 4A, 〖46. By using the sealing structure of the present invention, not only the wall thickness of the can body can be reduced, but also the amount of materials that can be used to form the can body can be increased by reducing the strength requirements required for the can body display. For example, the structure of the present invention described above can be made of aluminum or Plastic is used in tanks, not nickel-plated steel, which is currently used. A variation of the structure of the beverage can body is disclosed in FIG. 13. In the disclosed example, the battery can body is first formed with a pipe with two open ends. The pipe can be drawn, melted, welded, and glued using conventional techniques. The fittings can be made of steel, aluminum, or plastic. As shown in FIG. 13, the pipe defines a side wall 614 ′ of the can body 612, and a first open end of the pipe is subsequently closed by using an inner lid 616 and fixed by the above-mentioned beverage can sealing technology. The difference is the inner lid No electrical insulation is required between 616 and sidewall 614. A positive outer cover 618 can be welded or fixed to the outer surface of the inner cover 616, the battery is then filled and a negative outer cover 645 is fixed to the second open π end of the can 612 in the same manner as described above. The printed inscription on the can body is as shown above. The battery structure of the present invention can be combined for a printed label instead of the currently used label substrate. The existing label substrate has a thickness of 3 mils. When a seam is formed along the length of the battery, the conventional tags substantially increase the diameter by about 10 mils and the crepe height of the 13 mil battery. As a result, the battery can body must have a straight line selected to match the thickness of the seam of the label -33- This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) L--If--Γ ---- I I --- Order -------- '' "-* ( Please read the precautions on the back before filling out this page) f A4299 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs (5) Invention Note (31) to meet the ANSI size standard. However, by printing the lithographic label directly on the outer surface of the can body according to the present invention, the diameter of the can body can be correspondingly increased to about 10 mils, and the increase in the diameter of the can body can enlarge the internal space of the battery. . In addition to the beverage can structure, all the batteries in the list of Figures 14A and 14B include the substrate label. The internal space of the battery with the substrate label can increase 2% (1 '02 cc) for a D-size battery. C-size battery increased by 2.6% (.65 cc), AA size battery increased by 3.9% (0.202 cc), and 18.8 size battery increased by 5.5% (0.195 (^), and the label is directly printed on the can The label can also be printed on the can using transfer technology. The image of the label is first printed on a transfer medium and then directly transferred to the outside of the can. The twisted lithography can also be used to make it intentional. Twisted patterns printed on flat materials' to facilitate flat materials to form tube or tube parts of battery cans. The flat materials can be used to distort stress after printing. Before printing lithographic labels, the outer surface of the cans should be cleaned first. In order to strengthen the adhesion of the printed matter to the can body, the undercoat layer of the primer can be applied to the outer surface of the can body, and the printed label is then directly applied to the top surface of the undercoat layer on the can body by using the conventional lithographic printing technique. .A bright lacquer coating It can be applied to printed labels to cover and protect the printed labels, and also as an electrical insulation layer. The printed labels can be cured by high temperature heating or ultraviolet technology. Because of the use of printed labels, the thickness of a conventional label substrate is greatly reduced. The maximum thickness is as small as about 0.5 mil, especially the thickness of the undercoat layer is about 0.1 to 0.2 mil. The printed layer has a thickness of about ^ mil, and the lacquer coating has a thickness of about 0.1 to 0.2 mil, by By reducing the thickness of the label, the diameter of the can can be increased to increase the available space for active battery materials. -34- This paper size applies to China National Standard (Cns) A4 (210 X 297 cm) l · --Γ — — · ------ --- I I --— Order · 1 — 1 — * ^ v • · < Please read the notes on the back before filling this page) ^ 4429 9 〇 Α7 _Β7 ___ V. Description of the invention (32) While maintaining one of the batteries with a predetermined outer diameter. Beverage having feed through a current collector 锵 艚 Referring to FIG. 15, an electrochemical cell 700 discloses that a feed through current collector according to a seventh example of the present invention is provided, which is similar to a beverage can-type structure shown in FIG. Ii The electrochemical cell 400 is that the electrochemical cell 700 includes a conductive can 712 ′ having a closed end 314 and an open end for a small space current collector assembly 725 and an outer negative cover 750 to be assembled inside. The electrochemical cell 700 includes a positive electrode 115 to contact the inner wall of the can 712 and a separator 117 between a positive electrode 115 and a negative electrode 120. The positive electrode 115 is also referred to herein as the cathode and the negative electrode 120 It is known as anode anode that the type of material and its position within the electrochemical cell can be changed without departing from the present invention. The electrochemical cell 700 also includes a pressure release mechanism 370 formed in the closed end 314 of the tank 712, which can be used in a small space current collector assembly 725, which consumes less space than a conventional current collector assembly , So you can get improved internal battery space. The pressure release mechanism 370 can be formed in a channel shape as shown in FIGS. 8A, 8B, 9, 10. In addition, a positive outer cover 311 is connected to the closed end of the tank 712 and overlaps with the pressure release mechanism 370. The combination and position of 311 is related to the description of 囷 8A. The electrochemical cell 700 includes a current collector assembly 725 for closing the open end of the tank 712. The current collector assembly 725 includes a current collector pin 740 electrically contacting the negative electrode 120, and the current collector assembly 725 also includes a first or inner cover 745. A central hole 751 is formed in the inside, and a current collector pin 740 is disposed in and passes through the hole 751 in the inner cover 745. A dielectric insulation material 744 is provided between the current collector pin 740 and the first cover 745 to provide dielectric insulation therebetween. -35- This paper standard meets China National Standard (CNS) A4 specification (210 297 (Public *) < Please read the precautions on the back before filling out this page) ^ Installation -------- Order --------- Printed by the Consumer Consumption Cooperative of the Intellectual Property Bureau of the Ministry of Economy 4429 9 〇 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 Β7 ___ 5. Description of the Invention (33) According to this, the current collector pin 740 is electrically isolated from the inner cover 745. Dielectric insulation material 744 is an organic macromolecular material, such as an organic polymer, and may include epoxy resin, rubber, nylon, or resistant to potassium hydroxide and non-corrosive in the presence of potassium hydroxide in alkaline batteries. Other dielectric materials and dielectric insulation materials are combined in the following manner. The inner cover 745 is sequentially connected and closed to the top open end of the tank 712. The inner cover 745 can be embedded in the tank 712 and sealed in the tank 712 by forming a double joint at the rims 45 and 47. As shown in Figure U_13, although the seventh example of the present invention is described with a double-joint can-lid closure, it can be understood that other can-lid closures still do not depart from the content of the present invention. Available. According to the seventh example, to directly connect the tank body 7n and the inner cover body? The electrochemical cell 700 between 45 is preferably provided with a pressure seal therebetween, but the inner cover 745 and the side wall of the tank 712 do not need to be electrically isolated, but the collector pin 740 is insulated from the inner cover. The body 745 electrically isolates the negative and positive terminals of the electrochemical cell from each other. Although there is no need to maintain electrical isolation between the can body 712 and the inner lid body 745, it is preferred that a sealant is applied to the closure member that joins the can body to the lid body to facilitate proper sealing of the can body, a suitable sealant As shown in Figure 1 J _ 丨 2D battery users. It can be understood that the pressure that can be established internally along the closure of the insulating material is greater than the venting pressure when the pressure relief mechanism 37 is released. In order to provide an acceptable external battery terminal in accordance with acceptable battery standards, the electrochemical cell 700 further includes a cover 750 that is in electrical contact with the current collector pin 740, and the outer cover 750 may utilize a spot weld 742 Welding, or l · I —Γ— ΙΓ ------ ---— I Order ·! Go to v '1 (Please read the notes on the back before filling in this page) 1 36 This paper size is applicable to the Chinese National Standard (CNS) A4 (21〇X 297 mm) A7 ^ 442990 B7 V. Description of the invention (34) In order to ensure proper electrical insulation between the outer cover 75 and the inner cover 745, a dielectric material such as a ring pad 748 is provided between the outer negative cover 750 and the inner Among the cover bodies 745, suitable dielectric materials include nylon, other elastic materials, rubber, and epoxy resin, which are applied on the top surface of the inner cover body 745 or the bottom surface of the outer cover body 750. According to this, an acceptable A standard battery terminal can be provided at the negative end of the electrochemical cell 700. The combination of the electrochemical cell 700 according to the seventh example of the present invention is illustrated in the combination diagram of FIG. 16, and it is further disclosed in the flowchart of FIG. 7. The method 770 of combining the electrochemical cells 700 includes providing a tank body 712, and the tank body is provided with a closed bottom end and an open top end. Step 774 includes placing an active electrochemical material in the can body 712, which includes a negative electrode, a positive electrode, and an electrolyte, and a separator and other battery additives. Once the active electrochemical cell material is placed in the can body 712, the can body 712 is The current collector assembly is to be closed and sealed with a current collector assembly 725. Before closing the tank, the current collector assembly is first placed in a set in accordance with step 776 by first placing the current collector pin 740 along a ring of insulating material. Inside the hole 751 in the cover 745. The current collector pin 740 is placed in the opening 742 of the insulation ring 744. The insulation ring includes a ring-shaped or dish-shaped epoxy resin, which can provide dielectric insulation and can be heated to be reshaped and fixed in the inner cover 745 and the current collector nail. Between needles 740. In addition, other organic macromolecular dielectric insulating materials may be used in place of epoxy resins, such as a rubber ring, an elastic material, or other dielectric materials that can form an appropriate insulation between the current collector pin 740 and the inner cover 745. The inner cover 745 is also provided with a recess 755, which is located in the top surface and is located at the center in relation to the hole 751. ^ According to a better example, the insulating material ring 744 is located on the top of the inner cover 745. 37 paper size Applicable to Chinese National Standards (CNS > A4 specifications⑵0X 297 male ~ K --- fllf -------- I I --- ^ ίιιιιί · ^ • * (Please read the note § on the back before filling this page ) Printed by the Shelley Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, and printed by the Consumer Cooperatives of the Ministry of Economic Affairs. In step 778, the insulating ring 744 is combined with the current collector pin 740 and the cover 745, and the insulating ring 744 is heated to a relatively high temperature, which is sufficient to melt the ring 744, so that the ring 744 is formed again and flows into the cover. The hole 751 in the body 745 is to provide continuous dielectric insulation between the current collector pin 740 and the inner cover 745. For a ring 744 made of epoxy resin, 20 ° C to 200 ° C temperature for several seconds to 24 hours can moderately reshape and cure the insulating material, once the dielectric When the material 744 forms a moderate insulation between the current collector pin 740 and the inner cover 745, the insulating material is preferably cooled in step 780. During the heating and cooling steps 778 and 780, the current collector pin 740 is positioned at The center of the hole 751 prevents the needle 740 from contacting the cover 745. Subsequently, in step 782, a dielectric insulation pad 748 is placed on the top of the inner cover 745 like a ring-shaped dielectric, and extends along the periphery of the nail 740. It extends radially outward. In step 784, a conductive negative cover 750 is provided on the top of the current collector needle 740 and the gasket 748, which is welded or formed in electrical contact with the current collector nail 740. Once the current collector When the container assembly is fully assembled, the current collector assembly is then connected to the tank to seal the open end provided in step 786. The tank can be closed using a double-joint closure, or other suitable tank closing technique. In addition, The combination method 770 includes a step 788 of connecting a second outer cover body to the closed end of the tank body, and it is preferably overlapped with the pressure release mechanism 37. Although the present invention is mainly applied to the test battery in the foregoing, it is customary here. The artist knows that similar benefits Obtained in batteries using the present invention in other electrochemical systems. For example, the structure of the present invention can be used in basic systems, such as carbon zinc and coin batteries and rechargeable batteries, such as nickel-cadmium, metal hydride, and lithium batteries. In particular, the specific structure of the present invention can be used for unprocessed batteries -38- This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) -------- Γ ----!-^ Install ------ order ------- shuttle (please read the precautions on the back before filling out this page) ir 442 9 9 0 A7 B7_ V. Instruction (36) of the invention (ie battery pack or more Unlabeled batteries used in unit batteries). In addition, although the present invention has been described in relation to a cylindrical battery, the specific structure of the present invention can still be used to form a 稜鏡 -shaped battery. The above description should only be regarded as a good example. The adjustment type of the present invention can be made by those skilled in the art and achieved or used by the present inventor. Therefore, it can be understood that the drawings and the foregoing examples are for illustration only, not 偈Limited to the scope of the present invention, it shall be defined by the following application domains in accordance with the provisions of the Patent Law. l · --k- — —f! ·! W equipment ---! !! — Order · —11 — -M '^-(Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 3Θ This paper size applies to China National Standard (CNS) A4 (210 X 297 male «)

Claims (1)

442990 六、申請專利範圍 經濟部智慧財產局員工消费合作社印製 —種電池，包括： 一罐體，用於容納電化學活性材料，包括正與負極及 —電解質；及 一標籤，係直接印於該罐體之—外表面上。 如申請專利範圍第1項之電池，其中該標籤包含一石版 印刷標籤。 如申請專利範園第1項之電池，其中該罐體包含金屬。 如申請專利範圍第3項之電池，其中該罐體包含鋼。 如申請專利範圍第1項之電池’其中該標籤係利用—轉 印技術印製，其中標籤之一圖像係印於一轉印介質上且 随後直接轉印至該罐體之該外表面。 如申請專利範園第1項之電池，其中該標籤具有一〇 5密 爾之最大厚度。 1 如申請專利範圍第1項之電池 層，係由一電絕緣層覆蓋。 8.如申請專利範固第7項之電池 一直接施加於該罐體上之底漆層，其中該印刷層係直 施加於該底漆層頂面上。 9 一種組合一電池之方法，包含以下步骤： 形成一罐體，具有一開口端及一封閉端； 配送電化學活性材料於罐體内；及 直接印刷一標籤至罐體外表面上。 10.如申請專利範圍第9項之方法，其中標籤係利用石版印 刷術以印至罐髏之外部上。 2. 3. 6. 其中該標籤包括—印刷 其中該標籤進一步包括 L--— 1--ΙΪΙ!)裝-!1!1 訂 — — 始^— (請先閱讀背面之注意事項再填寫本頁) -40- K紙張尺度適用中國國家楳準（CNS>A4规格（210 X 297公釐） '442990442990 VI. Scope of Patent Application: Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs-a kind of battery, including: a tank for containing electrochemically active materials, including positive and negative electrodes and-electrolyte; and a label printed directly on On the outside of the tank. For example, for a battery in the scope of patent application, the label includes a lithographic label. For example, the battery of the patent application No. 1 wherein the can body contains metal. For example, the battery of claim 3, wherein the can body comprises steel. Such as applying for the battery of item 1 of the patent, wherein the label is printed using a transfer technology, and an image of the label is printed on a transfer medium and then directly transferred to the outer surface of the can body . For example, the battery of the patent application No. 1 wherein the label has a maximum thickness of 105 mils. 1 The battery layer of item 1 of the scope of patent application is covered by an electrically insulating layer. 8. For the battery of item 7 of the patent application, a primer layer directly applied to the can body, wherein the printing layer is directly applied to the top surface of the primer layer. 9 A method for assembling a battery, comprising the following steps: forming a can body with an open end and a closed end; distributing an electrochemically active material into the can body; and printing a label directly on the outer surface of the can body. 10. The method of claim 9 in which the label is lithographically printed on the outside of the skull. 2. 3. 6. Where the label includes—printing where the label further includes L --— 1--ΙΪΙ!) Pack-! 1! 1 Order — — Start ^ — (Please read the precautions on the back before filling out this Page) -40- K paper size applies to China National Standards (CNS > A4 size (210 X 297 mm) '442990 申請專利範圍 標籤係 利用轉印技 12.如申請專利範圍第9項之方法，其中印啊 驟包括： 知藏之轅 步 .如申請專利範圍第9項之方法，其中 術以印至罐體之外部上。 驟包括 印刷一印刷層至該罐體上；及 施加一電絕緣層至該印刷層之頂面上。 如申請專利範圍第項之方法，其中印刷—榡 驟進一步包含施加一底漆層於該印刷層與該罐體又該步 I4·如申請專利範圍第9項之方法，其中該標籤具:間》 爾之最大厚度》 〇‘5密 ----J--»----W·裳-- f請先閑讀背面之注意事項再填寫本 訂 .-¾ 經濟部智慧財產局員工消費合作社印製 -41 本紙張尺度逍用中國國家梯準（CNS ) A4規格（210X297公釐）The patent application scope label uses transfer technology. 12. The method of applying for the scope of the patent, item 9, where the printing step includes: Steps of knowing how to hide. As the method of applying for the scope of the patent, the method includes printing to the tank. On the outside. The steps include printing a printed layer on the can body; and applying an electrically insulating layer to the top surface of the printed layer. For example, the method of applying for the scope of the patent, wherein the printing-step further comprises applying a primer layer to the printing layer and the can body, and the step I4. The method of the scope of applying for the scope of the patent, wherein the label has: 》 The maximum thickness of》 〇'5 dense ---- J-»---- W · Shang-- f Please read the notes on the back before you fill out this order.-¾ Staff Consumption of Intellectual Property Bureau, Ministry of Economic Affairs Printed by the cooperative -41 This paper is scaled to the Chinese National Standard (CNS) A4 (210X297 mm)
TW088114330A 1998-08-21 1999-08-21 Battery having printed label TW442990B (en)

Applications Claiming Priority (3)

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US9744598P 1998-08-21 1998-08-21
US10295198P 1998-10-02 1998-10-02
US29311499A 1999-04-16 1999-04-16

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US6465887B1 (en) 2000-05-03 2002-10-15 The United States Of America As Represented By The Secretary Of The Navy Electronic devices with diffusion barrier and process for making same
JP6516197B2 (en) * 2016-05-27 2019-05-22 パナソニックＩｐマネジメント株式会社 Sealed battery and battery case

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JPH034546A (en) * 1989-06-01 1991-01-10 Matsushita Electric Ind Co Ltd Semiconductor mounting device
GB9000806D0 (en) * 1990-01-13 1990-03-14 Ultramark Adhesive Products Li Battery casings
DE19643011A1 (en) * 1996-10-18 1998-04-23 Varta Batterie Directly overprinted galvanic element
DE69607173T2 (en) * 1996-11-08 2000-09-28 Rotanotice Soyaux Protection and jewelry tickets, especially for electric batteries

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