442392 A7 _________B7 五、發明説明（） 本發明係麟高賊熱雜聚氩s旨人造絲之·，尤指以不同 軟硬度種類的熱塑性聚氨酯彈性體⑽RMrethane ELASTOMERS )爲主成分，摻配以聚烯烴、聚氯乙埽、滑劑、填充劑 、著色赞]及改貧劑而成之配合料，經以T 一模押出機連續押出塑膠 膜，並於塑膠膜仍呈熱融狀態下與預熱或無預熱的基布贴合；或者 以混合機混煉後經軋輪機及壓延機之滾輪壓延成薄膜，於貼合壓花 機與預熱或甚預熱基布贴合壓花、冷卻聲成高強度人造皮革，此種 皮革具有較天然皮革或其他種類人造皮有更隹之对磨耗強度、剝離 強度，低溫对屈折等特點，適合多種後加工用途，且在製造過程中 無其他一般皮革製程中產生廢水、廢氣等環境污染問題。 〔習用技術之缺點〕 以往人造皮革之生產，主要以PU合成皮及pvc合成皮爲主體， PU合成皮製造使用之主要原料爲含高溶劑成份PU樹脂及稀釋溶劑 ;PVC合成皮製造使用之主要原料爲粉體之PVC粉及液體可塑劑， 利用塗佈、貼合等方式製成人造皮，其缺點爲： 經濟部中央標隼局員工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) ⑴PU合成皮使用高溶劑成份樹脂及稀釋溶劑爲主要原料，製造方 法主要是以塗佈機塗佈PU樹脂配方於基布上或離型紙上，利用 凝聚，水洗及乾燥等製程生產，PU樹脂配方中所用的溶劑，則 於製造過程中，衍生成爲廢水、廢氣，必須投資大量的經費於廢 水、廢氣等環境污染防範處理設備，否則將造成對環保生態之破 壞污染。 ⑵PVC合成皮使用粉體PVC樹脂及液體可塑劑爲主要原料，其 在混煉壓延過程中，由於操作是在長時間高溫開放系統中操作， 3 本紙張尺度適内中國®家標牟（CNS ) Μ規格（210x297公羡} 442392 經濟部中央標準局貝工消費合作社印製 A7 B7 五、發明説明（） 易產生粉塵及可塑劑揮發廢氣之污染，必需.投資大量的經費於粉 塵及廢氣處理設備，否則將造成對環保生態之破壞污染。 ⑶PU合成皮之耐水解性較差，欲改善耐水解物性時，其剝離強度 及表面对磨耗強度等物性相對變差，尤其底布爲尼龍(NY聊織 布時，剝離強度在0.5Kg/3Cm以下，實用性不大。 (4)PVC合成皮之低溫耐屈折及耐衝擊物性差，一般僅能耐低溫至 -10 C，要求更低溫時即極易破裂，若欲改善耐低溫物性時則表 面極易有可塑劑或添加助劑吐出之異常。且？乂匸製品垃圾焚化 時會產生世紀之毒戴奥辛、氣氣及重金屬微粒之疑慮，掩埋時重 金屬會析出污染環境，不符環保要求。 ⑸PU合成皮或PVC合成皮，使用於高磨擦撞擊用途場合’其表 面耐磨耗及剥離強度品質仍無法完全符合市場要求。 〔爲解決問題而採用的手段〕 本發明係以熱塑性聚氨酯彈性體樹脂爲主成份，摻配以聚烯烴、 聚氣乙烯、滑劑、塡充劑、著色劑及改質劑而成之組合物，其中聚 埽及聚氣乙烯可視需要而添加一種或兩種，其各别添加比例介於 0 PHR〜30 PHR ’ 一般以添加15 PHR以下爲宜，太多會影響成品之 耐磨耗性；滑劑可改良押出之加工性，添加量介於〇 PHR〜2〇 PHR ’ 一般以10 PHR以下爲宜，太多時會影響成品之耐磨耗性；填充 劑可降低成本，添加量介於〇 PHR〜20 PHR，一般以12 PHR以下 爲宜，太多時會影響耐磨耗性及撕裂、拉力強度；至於著色劑及改 質劑可依需要而添加。上述組成分可同時或分批加入槽中，以100 °C至240°C之溫度使其呈熔融狀態，經以T一模押出機連續押出塑 本紙張ΛΑ適用中國國家棟準（CNS )从麟（2丨〇><297公董） -- 0¾. (请先W讀背面之注意事項再填寫本頁)442392 A7 _________B7 V. Description of the invention () The invention is a kind of rayon, which is a thermal heteropoly argon of lingao thief, especially a thermoplastic polyurethane elastomer (RMrethane ELASTOMERS) with different soft hardness types as the main component. Olefins, polyvinyl chloride, lubricants, fillers, coloring agents] and additives to improve the poor, after continuous extrusion of plastic film with a T-die extruder, and the plastic film is still hot melt with the pre- Hot or non-preheated base fabrics are laminated; or after being kneaded by a mixer, rolled into a thin film by the rollers of a rolling mill and a calender, the laminated embossing machine and the preheated or even preheated base fabric are laminated and embossed, Cooling sound becomes high-strength artificial leather. This kind of leather has more characteristics such as abrasion resistance, peel strength, low temperature and inflection than natural leather or other types of artificial leather. It is suitable for a variety of post-processing purposes, and there is no other during the manufacturing process. Environmental pollution problems such as waste water and waste gas occur in the general leather manufacturing process. [Disadvantages of conventional technology] In the past, the production of artificial leather was mainly made of PU synthetic leather and PVC synthetic leather. The main raw materials used in the manufacture of PU synthetic leather were high-solvent PU resin and diluted solvents. The raw materials are powdered PVC powder and liquid plasticizer, which are made of artificial leather by coating, laminating, etc. The disadvantages are: Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling in (This page) ⑴PU synthetic leather uses high-solvent resin and diluent as the main raw materials. The manufacturing method is mainly coated with PU resin on a base cloth or release paper by a coating machine, and produced by agglomeration, washing and drying processes. The solvents used in the formulation of PU resin are derived into waste water and waste gas during the manufacturing process, and a large amount of money must be invested in environmental pollution prevention and treatment equipment such as waste water and waste gas, otherwise it will cause environmental damage and pollution. ⑵PVC synthetic leather uses powdered PVC resin and liquid plasticizer as the main raw materials. During the mixing and calendering process, because the operation is performed in a long-term high-temperature open system, 3 papers are within the standard China® House Standard (CNS) Μ specifications (210x297 public envy) 442392 Printed by A7 B7, Shellfish Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () Pollution that is liable to generate dust and volatile waste gas from plasticizers is necessary. Invest a large amount of funds in dust and waste gas treatment equipment Otherwise, it will cause damage to the environment and ecology. ⑶PU synthetic leather has poor hydrolysis resistance. When you want to improve the hydrolytic resistance, its physical properties such as peel strength and abrasion resistance on the surface will be relatively poor, especially the base fabric is nylon (NY chat fabric) When cloth is used, the peel strength is below 0.5Kg / 3Cm, which is not practical. (4) PVC synthetic leather has poor low temperature resistance to buckling and impact resistance. Generally, it can only withstand low temperature to -10 C, and it is easy to break at lower temperatures. If you want to improve the properties of low temperature resistance, the surface will be very easy to have plasticizers or additives to spit out abnormalities. And? The waste of incinerated products will produce the poison of the century, dioxin, gas, etc. Concerns about heavy metal particles, heavy metals will be precipitated to pollute the environment during burial, which does not meet environmental protection requirements. ⑸PU synthetic leather or PVC synthetic leather is used in high friction impact applications. Its surface abrasion resistance and peel strength are still unable to fully meet market requirements. [Methods adopted to solve the problem] The present invention is a composition composed of a thermoplastic polyurethane elastomer resin as a main component and blended with a polyolefin, a polyethylene, a slip agent, a filler, a colorant, and a modifier. Among them, polyfluorene and polyethylene gas can be added one or two kinds as required, and their respective addition ratios are between 0 PHR ~ 30 PHR 'Generally it is better to add 15 PHR or less, too much will affect the wear resistance of the finished product; Lubricant can improve the extrusion processability, the addition amount is between 0PHR ~ 2〇PHR 'Generally it is appropriate to be less than 10 PHR, too much will affect the wear resistance of the finished product; filler can reduce the cost, the addition amount is between 〇PHR ~ 20 PHR, generally less than 12 PHR is appropriate, too much will affect the abrasion resistance and tear, tensile strength; as for colorants and modifiers can be added as needed. The above composition It can be added to the tank at the same time or in batches, and it can be melted at a temperature of 100 ° C to 240 ° C. The plastic paper can be continuously extruded by a T-die extruder ΛΑ for China National Building Standard (CNS) Conglin (2丨 〇 > < 297 public director)-0¾. (Please read the precautions on the back before filling this page)
T % 翅濟部中夬榡率局貝工消費合作杜印製 A7 B7 i、發明说明（) 膠膜，並於塑膠膜押出仍呈熱融狀態下與已預熱或無預熱底布貼合 ;或者以混合機混煉後經軋輪機及壓延機之滚輪壓延成薄膜，於貼 合壓花機與預熱或無預熱底布貼合，上述並可同時於貼合時使用一 般鐵製壓花輪壓出紋路，或者於特殊壓花機使用特殊材質壓花輪壓 花，製造出表面高耐磨耗、高剝離強度及对低温特性之高強度人造 皮革之製造方法，本發明係利用一、二、三層或多層T—模共押出 機或壓延機滾輪壓延薄膜製程製造人造皮革，製造中因使用之主要 原料爲1.00%固形分之粒狀TPU膠粒，不需再以任何溶劑稀釋溶解 ’可直接投入使用，不會產生廢氣、廢水、粉塵等環境污染問題； 依塑膠層薄膜厚度、物性、軟硬度要求，決定選擇以何種製程生產 ’以製造出低成本符合要求之高物性人工皮革，適合多種加工用途 。本發明係利用一、二、三層或多層T—模共押出機或壓延機滾輪 壓延薄膜製造人造皮革之方法，以下分别説明不同押出機之操作方 式。 ―、對—層押出機而言： ⑴以熱塑性PU彈性體爲主體之組成份配方，直接押出淋膜於底布上 ，熱塑性PU彈性體本身兼具糊層膠膜及面層膠膜之雙重功用。 二、對二層共押出機而言： ⑴接近貼合底布之一層爲熱塑性PU彈性體爲主體之組成份配方原料 (以下簡稱糊層膠膜），主要爲促進底布接著強度。 ⑵鄰接糊層膠膜之一層爲熱塑性PU彈性體爲主體之組成份配方原 料，作爲表面塑膠膜層（以下簡稱面層膠膜）。 二、對三層或三層以上共押出機而言： 本纸張尺度適用中囷國家橾率（) A4規格（2 i Ο X 297公釐） ----------1^-------.玎------線 (請先聞讀背面之注意事項再填寫本頁) 經濟部中央搮準局貝工消费合作社印裝 / 442392 A7 ____B7 五、發明説明（） ⑴接近貼合底布之一層爲熱塑性PU彈性體爲主體之配合料（同二 屠押出機糊層’以下簡稱_膠膜），主要_級進底布接著 強度。 ⑵最上方之一層爲表面塑膠層（以下簡稱面層膠膜），其原料爲熱 塑性PU彈性體爲主體之配合料，面廣膠膜之主要功用爲賦與表 面所需物性及手感。 ⑶界於糊層膠膜及面層膠膜之一層或多層爲熱塑性PLi彈性體或聚 烯fe或聚氣乙烯爲主體之配合料，作爲中間塑膠層（以下簡稱中 層膠膜），以調整產品厚度及軟硬度用。 四、對壓延機製程而言： (1)基布經缝接燙平後，於上糊機塗佈糊劑於基布上，使於貼合時能 與熱塑性PU彈性體爲主體之配合料接著良好。 ⑵依要求之軟硬度選擇適當的熱塑性PU彈性體爲主體之配合料， 利用恩延機之滾輪壓延成所需厚度之薄膜，直接於出料處由壓花 輪签花與糊布貼合，或者於貼合壓花機再與預熱或無預熱之上糊 底布壓花贴合。 各層膠膜所用之熱塑性PU彈性體糊劑原料，主要成份爲熱塑 性PU彈性體，其硬度介於20〜100 sh〇re A，比重介於丨〇〇〜 1‘40，熔融流動指數1〜50 gm/10分，融點區間爲8〇»c〜19〇<>c ; 另外依各種性能需要可添加滑劑'抗氧化劑、紫外線吸收劑、耐 燃劑、靜電防止劑、㈣、觀劑、可共顧合之_及其他性 能改良劑。 本紙張尺度逋用中蹰國家揉率（CNS ) A4规格（210x297公着） 6 ^n- —h I— - - ^^1 fi n ^^^1 n^i -- n^— t - ^SJIt ^^^1 ^^1· 1 (請先聞讀背面之注意事項再填寫本\B〇 4^2392 經濟部中央樣準局貞工消費合作衽印¾ A7 B7 五、發明説明（） 本發明之製程如下：T% The Ministry of Economy and Trade of the People's Republic of China, the Ministry of Economics and Industry of the People's Republic of China, printed the A7 B7 i, the description of the invention () the plastic film, and the plastic film extruded with the preheated or non-preheated base cloth Laminating; or rolling into a film by a roller and a calender after mixing with a mixer, and laminating with a pre-heated or non-pre-heated base cloth at the laminating embossing machine. The above can be used at the same time. The embossing wheel is used to emboss the texture, or the special material embossing wheel is used to emboss on a special embossing machine to produce a surface with high abrasion resistance, high peel strength and high-strength artificial leather with low temperature characteristics. The present invention uses a , Two, three or more layers of T-die co-extrusion machine or calender roll calendering film manufacturing artificial leather. The main raw material used in the manufacturing is 1.00% solid TPU rubber particles, which do not need to be diluted with any solvent. Dissolve 'can be put into use directly without causing environmental pollution problems such as waste gas, waste water, dust, etc .; according to the requirements of the thickness, physical properties, and hardness of the plastic layer film, decide which process to choose for production' to produce a high cost that meets the requirements Physical property Artificial leather, suitable for many processing purposes. The present invention is a method for manufacturing artificial leather by using one, two, three or more layers of T-die co-extrusion machine or calender roll calendar film. The operation modes of different extruder machines will be described separately below. ― 、 For the extruder: ⑴The composition formula is based on thermoplastic PU elastomer, and the coating is directly extruded on the base fabric. The thermoplastic PU elastomer itself has both the double layer adhesive film and the top layer adhesive film. function. 2. For the two-layer co-extrusion machine: (1) One layer close to the bottom fabric is made of thermoplastic PU elastomer as the main component (hereinafter referred to as the paste film), mainly to promote the adhesion of the bottom fabric. (1) One layer of the adhesive film adjacent to the paste layer is composed of thermoplastic PU elastomer as the main component, and is used as the surface plastic film layer (hereinafter referred to as the surface layer film). 2. For co-extrusion machines with three or more layers: The paper size is applicable to the Central China country rate (A4) (2 i 〇 X 297 mm) ---------- 1 ^ -------. 玎 ------ line (please read and read the notes on the back before filling this page) Printed by the Central Consumers' Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives / 442392 A7 ____B7 V. Description of the invention () 之一 One layer close to the base fabric is made of thermoplastic PU elastomer as the main compound (same as the second sludge extruder paste layer 'hereinafter referred to as _adhesive film), mainly _ graded base fabric adhesion strength.之一 The top layer is the surface plastic layer (hereinafter referred to as the surface layer film). Its raw material is thermoplastic PU elastomer as the main compound. The main function of the surface wide film is to impart the physical properties and feel required on the surface. (3) One or more layers of the paste film and the surface film are made of thermoplastic PLi elastomer or polyolefine or polyethylene as the main compound, as an intermediate plastic layer (hereinafter referred to as the middle layer film) to adjust the product For thickness and softness. Fourth, for the calendering process: (1) After the base fabric is seamed and seamed, apply a paste to the base fabric on a pasting machine so that it can be used as the main compound with thermoplastic PU elastomer when bonding. Then good.适当 Select the appropriate thermoplastic PU elastomer as the main compound according to the required softness and hardness, and use the rollers of the Enyan machine to roll into a film with the required thickness. Or embossing and laminating on the laminating embossing machine with pre-heated or non-pre-heated top cloth. The raw materials of thermoplastic PU elastomer paste used for each layer of film, the main component is thermoplastic PU elastomer, its hardness is between 20 ~ 100 shore A, the specific gravity is between 丨 〇〇 ～ 1'40, and the melt flow index is 1 ~ 50 gm / 10 points, melting point range is 8〇 »c ~ 19〇 <c; In addition, lubricants, such as antioxidants, ultraviolet absorbers, flame retardants, antistatic agents, antimony agents, spectators, can be added according to various performance needs. , Can be considered together _ and other performance improvers. This paper uses the Central and South China Kneading Rate (CNS) A4 (210x297) 6 ^ n- —h I—--^^ 1 fi n ^^^ 1 n ^ i-n ^ — t-^ SJIt ^^^ 1 ^^ 1 · 1 (Please read the notes on the back before filling in this book \ B〇4 ^ 2392 Seal of the Central Labor Bureau of the Ministry of Economic Affairs and Consumption Cooperative Seal of Printing ¾ A7 B7 V. Description of the Invention () This The process of the invention is as follows:
以下配合酬進―步説明本發明之技_容，本伽製造方法 之加工製程凊參照圖1 (以一層共押出機爲範例），兼具糊層膠膜 及面層膠膜雙重功用之熱塑性PU彈性體爲主體之配合料，由膠膜 押出機1押出，加工溫度範園爲1〇〇1〇〜24()它；押出機加工溫度 低於溫度範園時，樹脂押出延伸性差，生產性不佳，押出機加工溫 度高於溫度範圍時，樹脂容易過熱分解，並且造成橫向厚度分佈差 異’生羞性也不佳。 押出膠膜厚度爲0.02〜6.0mm ;低於膠膜厚度範園時，橫向厚 度差異易導致貼合強度不佳，且影響表面物性，膠膜層厚度高於厚 度範園時’成品用料量多且售價較高，市場接受程度小。 本紙張尺度適用中國國家棣準（CNS )从此格（210X297公羞） ----------~裝-------訂------線 <請先閲讀背面之注意事項再填窝本頁) 7 A7 ------ - B7 五 '發明説^〜^ 底布7經預熱設備2預熱後進入貼合橡膠鉍4及墨花輪5與自 T一模3押出熔融塑膠瞑，貼合壓花後再經冷卻輪6冷卻後，即可 成爲塑膠膜成品8 ;底布預熱溫度範圍可爲室溫〜2⑻C，底布預 熱溫度視布種耐熱性不同而變化，主要目的爲增加貼合強度，底布 可不經預熱即行貼合押出塑膠膜，但貼合剝離強度較差，底布預熱 溫度愈高成品貼合強度愈佳，底布預熱溫度高低視需要貼合剝離強 度及布種而定，但預熱溫度不可超過底布耐熱溫度，否則發生收縮 及炫融現象’一般聚丙烯（ΡΡ；)材質底布預熱溫度爲室溫〜13〇-c， 尼龍(NYLON)材質底布爲室溫〜160 ，聚酯（POLYESTER)、嫘縈 (RAYON )及棉（COTTON)等材質底布，其預熱溫度範園爲室溫〜 200 °C ’底布預熱溫度在室溫以下會影響貼合強度，不予考慮；在 最高溫度範園以上，因容易引起底布收縮及熔融現象，生產性差， 亦不考慮；壓花輪及冷卻輪可通冷卻水，而橡修輪不需冷卻。 經濟部中央標準局男工消f合作社印製 以上述方式生產之塑膠皮成品結構請參照圖2，11爲兼具面層 及糊層雙重功用之膠膜，12爲底布；塑膠皮表面可再施以印刷或表 面色澤光霧度處理，以增加產品高級感及附加價値。 依本發明方法所製得的人造皮革塑膠皮具有下列特點： ⑴人造皮革（底布所用纖維材質包括尼龍、聚酯、嫘縈、棉、聚丙 本紙張尺度逋用中國國家標率（CNS ) A4规格（210X297公釐） 4^2392 經濟部中央標隼局員工消費合作社印製 Α7 Β7 五、發明説明（） 烯、聚丙烯腈、羊毛、麻等材質 > 其塑膠膜唐和底布間之剝離強 度可達9.6 Kg/3cm以上。 ⑵人造皮革表面之耐磨耗強度極佳，依门S-K 6328法試驗，可達 #H22砂輪X丨Kg X 10000次以上，丧面不會破裂。 ⑶耐屈曲物性佳’常溫可達125⑻(）次以上，-丨〇。〇可達30(.)0()次 以上，經70°C X 95¾ RH X 1星期耐水解試驗後，依jis-K 6545 法試驗其常溫耐屈曲物性仍可達125000次以上。 ⑷以貼合壓花輪貼合押出塑膠膜與底布之同時，可以依壓花輪紋路 變化壓製成具有美麗花紋之人造皮革。 ⑸貼合後之人造皮革，可以作印刷或任意光霧度處理。 發明人爲使貴審查委員進一步明瞭本索之技術内容，如何以 熱塑性PU彈性體樹脂配合料之配方，製造本發明之人造皮革，兹 以下述實施例説明本發明之技術内容，惟並非以此限定本發明之範 疇。 實施例1 採用一層共押出機製造，所用配方、押出厚度與底布種類如表 1所示，押出機軸缸溫度由低溫區130-C至高溫區I90ec，τ模溫度 爲190tJ，底布預熱溫度爲100-C，底布預熱後送至貼合壓花輪（ 本紙張尺度適用中國明家棣準（CNS ) ί 210X297公弟1 I---------—裝-- (请先聞讀背面之注意事項苒填寫本页) ，?τ 經濟部中央揉準局貝工消費合作社印装 44239 2 A7 — 扪 ------------------___. 五溫發期説閉:+50¾，壓花輪轉速爲6碼/分）與押出塑膠膜貼合 成厚度爲1.4腿之塑膠皮，經冷卻輪（溫度為28 C )冷卻後直 接裁檢，以每梱50碼捲取包裝，即爲成品；成品底布刺離強度爲12The following is a step-by-step explanation of the technology of the present invention. The manufacturing process of the Benjamin manufacturing method is shown in FIG. 1 (taking a layer of co-extrusion machine as an example). The thermoplastic has both the functions of the paste film and the top film. The PU elastomer is the main compound. It is extruded by the film extruder 1 and the processing temperature range is from 100 to 24 (). When the extruder processing temperature is lower than the temperature range, the resin extrudes poorly and produces. Poor performance. When the extrusion processing temperature is higher than the temperature range, the resin is easily overheated and decomposed, and the difference in lateral thickness distribution is caused. Extruded film thickness is 0.02 ~ 6.0mm; when the film thickness is less than the film thickness range, the difference in lateral thickness can easily lead to poor bonding strength and affect the surface physical properties. More and higher prices, less acceptance in the market. This paper size applies to China National Standards (CNS) since then (210X297 public shame) ---------- ~ installed ------- order ------ line < read first (Notes on the back page will be refilled on this page) 7 A7 -------B7 Five 'invention said ^ ~ ^ The base cloth 7 is preheated by the preheating device 2 and enters the rubber bismuth 4 and the ink wheel 5 T mold 3 extrudes the molten plastic 瞑. After laminating and embossing, it is cooled by the cooling wheel 6 to become a plastic film finished product 8; the pre-heating temperature range of the bottom cloth can be from room temperature to 2⑻C. This kind of heat resistance varies and the main purpose is to increase the bonding strength. The base fabric can be laminated without extruding the plastic film, but the bonding peel strength is poor. The higher the preheating temperature of the base fabric, the better the bonding strength of the finished product. The preheating temperature of the cloth depends on the peel strength and the type of cloth, but the preheating temperature cannot exceed the heat resistance temperature of the base fabric, otherwise shrinkage and dazzling will occur. 'General polypropylene (PP;) base fabric preheating temperature is Room temperature ~ 13〇-c, nylon (NYLON) base cloth is room temperature ~ 160, polyester (POLYESTER), 嫘 萦 (RAYON) and cotton (COTTON) and other base cloth, Thermal temperature Fanyuan is from room temperature to 200 ° C 'The pre-heating temperature of the base fabric below room temperature will affect the bonding strength, which is not considered; above the highest temperature, it is easy to cause the base fabric to shrink and melt, resulting in poor productivity It is also not considered; the embossing wheel and the cooling wheel can pass cooling water, but the rubber repairing wheel does not need to be cooled. The structure of the finished plastic leather produced by the Men ’s Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Please refer to Figure 2. 11 is a plastic film with dual functions of surface layer and paste layer, 12 is the base cloth; the surface of the plastic leather may be Then apply printing or surface color and haze treatment to increase the sense of high quality and additional price of the product. The artificial leather plastic leather prepared according to the method of the present invention has the following characteristics: ⑴Artificial leather (the fiber material used in the base fabric includes nylon, polyester, rayon, cotton, polypropylene paper, and China National Standard (CNS) A4 Specifications (210X297 mm) 4 ^ 2392 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs Α7 Β7 V. Description of the invention () Materials such as olefin, polyacrylonitrile, wool, linen, etc.> Between its plastic film and the base fabric Peeling strength can reach more than 9.6 Kg / 3cm. ⑵The abrasion resistance of the surface of artificial leather is very good. According to the SK 6328 method, it can reach # H22 Grinding Wheel X 丨 Kg X more than 10,000 times, and the mourning surface will not break. Good buckling properties' can reach 125⑻ () times or more at room temperature,-丨 〇.〇 can reach 30 (.) 0 () times or more, after 70 ° CX 95¾ RH X 1 week hydrolysis resistance test, according to jis-K 6545 method Tested, its normal temperature resistance to buckling can still reach more than 125,000 times. 同时 At the same time, the plastic film and the base fabric are laminated with the embossing embossing wheel, and can be pressed into artificial leather with a beautiful pattern according to the embossing wheel pattern change. Artificial leather, can be printed or used Haze treatment. In order to make your reviewing committee understand the technical content of this cable, the inventors will use the formulation of thermoplastic PU elastomer resin compound to manufacture the artificial leather of the present invention. The following examples are used to illustrate the technical content of the present invention. However, this does not limit the scope of the present invention. Example 1 It is manufactured by using a layer of co-extrusion machine. The formula, thickness and base fabric used are shown in Table 1. The temperature of the cylinder of the extruder ranges from low temperature region 130-C to high temperature region I90ec. The temperature of the τ mold is 190tJ, the pre-heating temperature of the base fabric is 100-C, and the base fabric is pre-heated and then sent to the laminating embossing wheel (this paper size is applicable to China Mingjiazhen Standard (CNS)) 210X297 male brother 1 I --- -------- Installation-(Please read the notes on the back 苒 Fill this page first),? Τ Printed by the Central Government Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, 44239 2 A7 — 扪 ------ ------------___. Shut down at five temperature periods: + 50¾, embossing wheel speed is 6 yards / minute) and extruded plastic film to paste a plastic leather with a thickness of 1.4 legs, after cooling wheel (The temperature is 28 C.) After cooling, it will be cut and inspected directly. The package will be rolled up at 50 yards per roll. 12 degrees
Kg/3cm以上，可供下游加工廠作爲鞋類加工之用途。其與比較用之 P\;C及Plj塑膠皮之物性如表2所示" .表1 配合料組成 (重量比） TPU膠粒 .100 PHR 色 粒 8 PHR 抗氧化劑 0.5 PHR 硬脂酸 0.2 PHR 膠膜厚度（rnn) 0.35 底 布 聚酯不織布（布厚度1.0麵）. 成品總厚度（mm) 1,40 + 0.05 PHR:每百分樹脂重量（Part Hundred Resin) 表 2 1.4mm鞋用製品 本發明之 TPU製品 濕式PU製品 '— PVC製品 拉力強度（Kg/3nm) 45个 35个 35t^ 伸長率（％ ) 100小 1001 10〇i 撕裂強度（Kg) 9.5个 9.5个 9.5f~ 剝離強度（Kg/3cm) 9.6个 8.6个 9.〇t^ 耐磨耗次數（#H22 X 1 kg) 10000次个 800次小 1000 耐水解（75% RH x 75°C x 14 天） 通過 通過 通過 漲破強度Kg/cnf 26 25 24〜 耐寒性-10 ec 3_次个 2_次个 20000次个 ---- 本纸張又度逍用中國S家橾準（CNS ) A4洗格（210X297公釐） --------II-------^------^ *- C請先W讀背面之注意事項再填窝本頁} 442392 A7 B7 五圖凳a#萆说明） 圖1爲與本發明有關的製造方法之加工製裎 2 1膠膜押出機 >預熱設備 3 T —模 4 5 6 7 8 •貼合橡輪 •壓花輪 •冷却輪 •底布 •膠膜成品 圖2爲以與本發明有關的製造方法製得的塑膠皮成品結構 11 12 •兼具面層及糊層雙重功用之膠膜 1底布 ----------裝-------訂一------線 (請先Μ讀背面之注意事項再填寫本貫) 經濟部中央標準局貝工消費合作社印製 本紙ft尺度通用中國國家揉準（CNS ) A4洗格（210X297公釐） 12Above Kg / 3cm, it can be used by downstream processing plants for footwear processing. Its physical properties compared with those of P \ C and Plj plastic leather are shown in Table 2. Table 1 Compound composition (weight ratio) TPU rubber particles. 100 PHR color particles 8 PHR antioxidant 0.5 PHR stearic acid 0.2 PHR film thickness (rnn) 0.35 Polyester non-woven fabric for base cloth (cloth thickness 1.0 side). Total thickness of finished product (mm) 1,40 + 0.05 PHR: Part Hundred Resin Table 2 1.4mm shoe products The TPU product wet PU product of the present invention'—PVC product tensile strength (Kg / 3nm) 45 35 35t ^ elongation (%) 100 small 1001 10 〇i tear strength (Kg) 9.5 9.5 9.5f ~ Peeling strength (Kg / 3cm) 9.6 8.6 9.〇t ^ Abrasion resistance (# H22 X 1 kg) 10,000 times 800 times small 1000 Resistance to hydrolysis (75% RH x 75 ° C x 14 days) Pass Through bursting strength Kg / cnf 26 25 24 ~ Cold resistance -10 ec 3_times 2_times 20,000 times ---- This paper has been used again in China S standard (CNS) A4 210X297 mm) -------- II ------- ^ ------ ^ *-CPlease read the precautions on the back before filling in this page} 442392 A7 B7 Five pictures Stool a # 萆 Explanation) Figure 1 is a system related to the present invention Manufacturing method 2 1 Film extrusion machine> Preheating equipment 3 T—Die 4 5 6 7 8 • Laminated rubber wheel • Embossing wheel • Cooling wheel • Base fabric • Film finished product Figure 2 is based on this The finished structure of the plastic leather made by the manufacturing method related to the invention 11 12 • Adhesive film with a dual function of a surface layer and a paste layer 1 base cloth ------------ install -------- order one ------ line (please read the notes on the back before filling in this document) The paper printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives, printed on the paper in ft dimensions, is generally China National Standard (CNS) A4 (210X297 mm) ) 12