426739 A7 __B7_ 五、發明説明（丨） 本發明偽有關可同時鞣製與上油預鞣製皮革和生皮之 新穎姐成物，有關製造該等組成物之方法及該等组成饬於 製造皮革和生皮的用途。 在製造皮革中，預鞣的皮革通常先涇中和，然浚鞣製 ，上油，若需要的話，隨後染色及進一步處理：K中和開 始之操作通常在分別的浴中進行或連缜在一個浴中進行， 但也可同時在同一個浴内發生。該等操作中所使民的產物 通常画別使用於固體或液體的形式，因為不易製備均勻同 質温合物。上油劑*事實上，幾乎僅限於液態或至少蠟狀 且K現存的方法與固體成分，例如中和劑和鞣製劑不能加 工得到其中成分均勻分佈和於足夠畏時間及變化溫度中可 確保滿意的儲存安定性的混合物。 現己發現新穎製法，其允許皮革的濕法修整明顯簡化 ，因為只要使用一種組成物就有可能同時完成鞣製與油K 及，如果逋當的話，進一步的處理。原因在於該等組成物 包括於鞣劑與上油劑加入至少八倍的1Q至6 (TC的水中產生 均勻混合物之形式。 經濟部中央標準局員工消費合作社印製 (束先閱讀背面之注意事項再填寫本頁} 令入驚訝地，當使用新穎組成物時產生協同效應。相 對於其中使用各別化學品之步驟•其可能明顯減少所使用 之鞣劑與上油劑，不論習知鞣劑與上油劑姻使用之事實：_ 當使用新穎組成物時，特別地，改良脂肪乳化作甩|旦可 使用較少量的上油劑。新穎組成物具顥著儲存安定性和在 固體組成物之情況為防凍的 -3- 本紙张尺度適用中國國家標準（CNS ) Λ4規格（210X.297公釐} 經濟部中央標準局員工消費合作社印裝 426739 A7 ___B7五、發明説明（1 ) 再者，如與在個別處理步驟中使用特定組成物比較. 當使用斩穎姐成物時，其可能顯著地減少運和儲存的要 求，且操作被大地藺單it :竝且，組成物具有酣省高至 百分之六十Z水量和時間且有利所產生之皮革的品質之 I 再琨性。此外，使用新顆組或物加速殳/或加強ib學製品 滲透和分沛至皮革中這等致，例如，皮革的較佳染科滲 透·、同時K有利方式產生影響皮革其池重要性質，例如防 水，霧化行為，修整薄膜之黏著強度，伸展和強度性質， 和每單位面積之質量。 因此本發明提供製造皮革和生皮的組成物，芭括 a) 一種鞣劑與 b) —種上油劑Μ反，若有需要的話， c ) 進一步的添加劑 且Μ加入到至少八倍的1 0至i5 Of的水中時產生均勻混合钧 的形式存在。 新穎組成物較佳於Μ使組成物可經由習知合併Μ攪伴 均勻地分佈於U至6 rc的水中，Κ形成在皮革處理期間是 適合的懸浮液或分散液之形式：在這裏經由攪拌的習知合 併涤指使用皮革工業中所使用的攪拌器簡簞地授伴 新額組成物較佳於當添加於水中時它們形成S括鞣劑 與上油劑的微泡之形式。 分散液或懸浮液中，較佳5 ϋ %之粒子含有低於丨5微米 的大小。特诖為該等靳穎組成物在添加至水中時肜成徽泡 本紙張尺度適用中國國家標準（CNS ) Α4規格（2iOx297公釐) _("請先閱讀背面之注意事項再填寫本頁) 4 2 67 3 9 a7 B7五、發明説明（、） 理 處 的 品 成 ' 半 小-V.7 大 1 的修 米法 微濕 ο 勺 4 0 ΑΖ 田丹 TT1D 低所 有於 含 合 子 適 粒物 之 成 ¾組 90潁 中新 其 般 前 ΠΠ 為 子 ' 例 皮 的 il適 白 合 和 皮源 濕來 0 的. , 成 如合 Μ 或 ’ 然 革天 皮為 輮可 預劑 ,0 如 例 劑 鞣 脂 澍 劑 鞣 成 Γ-4口 0 族鞣 芳 合 , 聚 劑和 鞣劑 性鞣 物性 植物 如礦 冽 , 物劑 合鞣 fb性 的 應 闬反 使 ， 木等 橡 該 ’ 為 木 劑 堅鞣 白性 , 物 草 植 羞 的 含 適 自 合 得地 為 別。 洌特者 實,,鼢 劑劑茶 鞣鞣兒 性之或 物皮酸 植樹子 的松倍 適或五 <1口 樹 焦 栗含 , 包 芳 的 適 合 7 及 的醛 物甲 或 獨 單 或 尿 鞣 ί、 所 纟S縮. 族ί素 <10 和 fb-族 芳 ib 酸 磺 由 經 ί 等Γ疋物 g常： 為 uih 例ti的 0^0 劑ί&獲 物 」u *SI— 族 芳 ib 磺 β, 是 常 通 萘 為 例 實 物 合 化 族 芳之V 的4' DH 4 此 ’ 合齡 適甲 酚 θ· 硼 基 苯 二 羥 萘 間 笨Γ 1二 , 聯苯 - 基 苯控 聯 二 (請先閣讀背面之注意事項再填寫本頁) 雙謎 2-基 2’笨 » 甲 sip二 二 和 苯魅 基苯 -二ft 如酸 例磺 被 0 中 基法 芳 方 二 的 和知 烷已 丙身 本 在 可 其 基 苯 基 羥 物 成 <□ 的 歹 下 是 劑 鞣 成 族 芳 子 鋪 陰 的 適 合 別 特 -裝------訂------ί 線-- 經濟部中央標準局員工消費合作社印製 物 產 合 縮 ’ 之物 0 產 甲 <1〇 和 縮 鼢之 甲醛 或甲 酚和 化酸 酸磺 靖 萘 之 酸 0 基 芳 \l·/ 基 (M 或 酸 0 基 芳 與 0 基 苯 二 羥 物 產 合 縮 醛 甲 合 m 0 甲 之 物 ft 鹵 基 垸 芳 與 物 <! 口 ib 基 羥 族 芳 * 基 磺物 含產 本紙張尺度適用中國國家橾準（CNS ) A4規格（210 X 297公釐） 經濟部中央標準局員工消費合作社印製 426739 A7 B7五、發明説明（) { V) 酚和酚磺酸之脲醛縮合產物 (v I)酚和磺酸劏之反應產物，其中冥耳比率（酚）：（s ΰ 3 ) 為 U ) : ( ί 至 2 . 2 )。 (V I I )磺酸ft二芳基醚和甲醛之嫌含產物， (V I I I )磺酸化聯苯或聯三苯基和甲醛之縮合產物， (IX ) H -二羥二苯基題和磺酸ib 4，彳’-二羥二苯基硿的 與甲醛之縮合產物， (X) 二芳基謎磺酸和4 , 4 ’ -二羥二苯基颯的甲醛縮合產物 1 (X I )酚和芳棊磺酸或羥基芳基磺酸之甲醛縮合產物：· 這些縮合產物在游離酸的形式，較疰為磺酸或圼鹽， 特別是銨，鋰，鉀或，特別是鈉鹽的肜式-· 疸竖縮合產初為已知1洌如從0 1 1 m a η n s E n z y k 1 〇 p a d i e der technischen Chemie第 1δ冊（4)，第 138頁至第 14(]頁（ 1979)，或可藉由其中所示之參考資料所述的方法來製造。 合適的樹脂鞣劑的實洌為含氮有機成化合物，例如尿 素，硫脲，二氟胺或聚氟胺，與甲醛或其把單钝銅基化合 物的陽離子締合產物。 其他合適的樹脂鞣劑為陰離子ib合物，其隱由含氮之 有機成化合物，例如尿素 > 碇呢*二氰胺或聚氛胺*和甲 醛或其ib m純陋基化合物及與陰雛子ib合物|例如酚，芳 族磺酸之鹼金屬盟，磺基酿胺，木質素磺酸鹽，亞硫酸鹽 或氯亞硫酸鹽之縮合產物所獲得的： --------^ -裝-----—.11---_--f 猓 先鬩讀背面之注意事項再填寫本頁) 本紙张尺度適用中國國家標隼（CNS > A4規格（210'Χ297公釐> 426739 經濟部中央標準局員工消f合作社印製 A7 B7五 '發明説明（<；) 持佳澍脂鞣朝為尿素與甲醛之緬合產物，和R二氮基 二醯胺為基質之樹脂鞣劑： 合適的反應性輮劑的實洌為單，二和多莛 > 持別是戊 二醛，多官能性異氮酸酷，烷基磺基氛化物，較高分子質 I I 量之烷基磺酸酯以及單體乙烯基衍生物和丙烯酸衍生物及 其聚合物。 合適礦物性鞣劑為已知的詻，鋁，鏺或銬詡，例如氯 化鉻（I I I )或碲酸鉻（I I I )，珞磺明礬，非鹼或鹼性氮it鋁 或硫酸鋁 > 氛化鐵（I I I )或硫酸鐵（11 I)，氧氣（b i告和硫酸 合適的聚合性鞣劑之實例為聚丙烯酸酯，包拮丙烯酸 酯*聚胺基甲酸酷或聚丁二晞之共聚物。 這些鞣劑是已知的和可從商業上大量獲得： 在新穎組成物中，所使用的鞣劑較佳為植物性鞣劑> 芳族含成鞣劑或反應性鞣劑」 合適的上油劑為一般甩於皮革的上油之慣用試劑，較 诖地 a)以動物油脂為基礎的上油劏，例如魚油·牛足油，羊毛 油或豬油， b ) Μ植物油脂為基礎的上油劑，洌如Μ麻油，椰子油或敵 攬油， c )含成性上油_·例如鐽垸徑之氮化作用或疏磺荃氣化作 用之產物；合成性脂肪酸酯和酯類油，或 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家楳準（CNS ) Α4規格< 210X297公釐） 經濟部t央標準局員工消費合作社印裂 4267 3 9 A7 ______87_ 五、發明説明（b ) d )礦物油或石油ft學產物： 這些上油劏較佳為从磺酸化，亞疏gg出改質或形成磺 酸之形式，因此其可溶解或乳化於水中：同陡地可能使用 上油混合物’其之部份具育乳化性質且作為其餘部份之乳 I , ί匕劑：’適含這個目的產物之宮例為磺酸化脂肪醇 上油劏較佳Μ水溶液或乳it；液使罔： 用於製造皮革的组成物，在各情形中可包含輩一的中 和劑’鞣劑和上油劑，或者在各情形中可包括二画或多涸 該等成汾的混合物。事實上這是—般的倩形，因為這些化 合物為極纯的物質，但是代替包括多數的技術混合物，多 少相（W之化合物。 除了鞣劑和上油劑以外，新穎皮革處理組成物可包括 進一步的添外物，网如中和劑，戰劑，著色劑，凑透劑， 修整劑和加修整铺助劑。 適合的中和劑為已知的fb合物，使用其可溫和地中和 強酸’預鞣製皮革。中和劑包括該等提高強酸性預鞣皮革 的P Η值，例如至4，5，而不能達到7的中性ρ η值之化旮物 。用於新穎‘组成物之適合中和劑實例是無饍或有镄弱酸的 鹼金屬鹽；芳族磺酸，或脂族酸單戎二羧酸其較佳包括 碳酸氫納或抨，甲酸或乙酸訥或钾，草酸，丙二酸納或押 ’或縮合確基化酚：持別地適合者為碳酸氫钠，甲酸納， 乙酸，已二酸或磺化二笨基碾 合適載劑之實例為氯fb納，芒硝，甲酸納，蛋白霄扮 --------y裝-----—訂---_---豫 (諫先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 4267 3 9 A7 B7 五、發明説明（1 ) 末，殿粉，高嶺土，多醣，葡萄糖或明膠： 適當著色劑為一般使用的皮革著色劑，洌如天然著色 劑，以反合成著色劑*例如陰離子性染料，金_錯合物染 料•直接染料·陽離子染料或硫化染料·著色劑t包括產 t 料，亦即，大量不溶於水中之著色劏 滲透萷同漾地為已知使用於皮革工業的組成％ •例如 防水劑，防有搔性溶劑或防油劑或防a劑1用於改善抗磨 損、刮傷或别的餞械性損壞之試劑，改善溫度安定性或光 堅牢性的試劑，和降低可燃性，或抗靜電性的試劑。 合適的修整劑之實例是底（b ◦ 1.1 q m i n g )劑|洌如聚丙 烯酸酯，丁二烯共聚物或聚胺基甲酸酯，.或整理劑，洌如 酩蛋白，硝基纖維素或聚胺基甲酸酷製劑。 合適的修整輔助劑為同漾已知和被實際上利用的產品 ，例如滲透劑，底漆和填料，抗黏劑，增稠劑和安定劑， 軟化劑，消光劑，操怍劑和固色劑3 用於製造皮革的新穎組成物較佳包括 a )丨0至8 0重量％之鞣劑· b ) 5至5 0重量％之上油劑，及 c ) 0至5 5重童％之進一步添加劑。 而較佳組成物在4 0 °C溫度Μ下為固體，可能採用在適 當溶劑（較佳地是在水中之溶液）分散液或溶解彤式的新 組成物， 持別適合於製造皮革之新頡組成物S括 -9 - 本紙浪尺度適用中國國家橾準（CNS ) A4規格（2!〇X297公釐） I ^ I裝-----—訂-----γ 银 ¢^-先閱讀背面之注意事項再填寫本頁) 經濟部中夬標隼局員工消费合作社印製 426739 A7 B7五、發明説明（？） a ) 1 G至6 Ο重量％之鞣劑-b ) 1 (]至彳5重量％之上油劑， c ) 1 Q至4 Q重量％之中和劑，及 d ) 0至4 Q重量％之進一步添加劑。 其中*持佳為該等組成物包括 ；〇2卩至6(]重量％之鞣劑， b ) 1 ϋ至4 Q重量％之上油劑， c ) 1 0至2 5重量％之中和劑，及 d)2至35重量％之進一步添加劑。 在各情形中百分比是以處理皮革之組成物的全部重量 為基準， 新穎組成物是Μ本身已知的方式製造*例如琨合於未 稀釋形式之鞣劑，上油劑與，若需要的話，進一步的添加 劑和另一成分。在此情形中必須選擇所存在之鞣劑和上油 劑及進一步添加劑以使所產生的組成物在加入到至少八倍 於1 f]至6 0 f的水中時得到均勻混合物。 然而|較佳採用如溶液或懸浮液，或者分散液之鞣劑 ，上油劑和任何其他添加劑，溫合他們，然後使混合物乾 燥0 在溶薛，懸浮液和分散液之情形中，較洼使用之溶劑 為水，雖然有餞性溶劑*洌如簞或多元醇或烴類《也是合 適的。 產生混合，例如，在1 α至6 G υ之間的溫度，担較佳地 -1 0 - 本紙張尺度適用中國國家標举（CMS ) Α4規格（210 X 297公釐） --------J!.-裝------ 訂---1--- - - · (背先閱讀背面之注意事項再填寫本頁) 4267 3 9 A7 B7 經濟部中央橾隼局員工消费合作杜印製 五、發明説明 〔^ ' I 1 是 在 室 溫 下 就 是 在 約 1 ί 至 1 5 之 間 '3 ift 合 之 後 * 較 佳 地 - 1 1 I » 其 必 需 均 勻 分 苘 所 欲 存 在 之 懸 浮 或 散 液 的 組 或 % 如 杲 1 I 需 要 的 話 可 W 由 合 適 的 處 置 例 如 t 使 用 持 疋 的 m 伴 器 或 請 £ 1 1 閱 | 超 音 波 處 理 達 成 讀 背 | 1 έ 乾 m Μ 習 知 方 法 產 生 但 是 應 在 其 中 雄 持 混 合 物 之 組 之 注 1 I 意 i | 成 的 均 勻 分 佈 m 件 下 正 常 地 進 行 0 如 果 所 有 的 成 分 容 易 溶 項 1 解 於 水 中 或 容 易 乳 fb 或 分 散 則 乾 缲 的 方 法 是 Μ 11 的 C 再 填 1 寫 本 裝 較 佳 使 用 其 中 很 快 速 地 產 生 乾 燥 的 方 法 頁 1 乾 燥 較 佳 藉 由 在 約 80 至 1 4 0 °〇 持 別 是 從 1 〇 0至1 2 0 1 1 之 噴 m 乾 燥 而 進 行 〇 1 1 其 亦 可 能 將 溶 液 懸 浮 液 或 分 散 液 噴 m 到 taT m 初 進 料 之 1 訂 載 m 原 料 例 如 氯 化 納 芒 硝 甲 酸 納 蛋 白 質 粉 末 澱 I 粉 且 同 時 或 隨 後 進 行 乾 i桑 0 1 根 據 這 jib 方 法 新 穎 組 成 物 獲 得 r； 纷 末 或 m 粒 的 形 式 1 1 其 可 採 用 於 此 形 式 以 製 餚 用 於 皮 革 製 造 之 水 溶 液 組 成 線 1 1 物 為 非 粉 壟 ib i 容 易 均 分 沛 於 水 中 且 即 使 在 延 長 儲 存 和 在 约 4 0 V K 上 的 溫 度 下 保 持 S 由 流 動 如 果 不 使 用 載 劑 1 原 料 或 者 使 甩 非 m 狀 化 合 物 當 載 劑 原 料 i 則 新 穎 組 成 物 可 Μ 鹽 或 低 形 式 製 造 其 也 有 利 r- 進 — 丄ii· ：> 的 加 工 洌如 1 ί 在 同 時 或 隨 後 染 色 之 情 況 和 減 少 環 境 的 負 擔 1 新 顆 組 成 物 適 合 於 製 造 不 同 種 類 的 皮 革 m 如 山 羊 * 1 1 羊 牛 或 豬 的 全 粗 面 輕 或 重 預 m 皮 革 或 绒 面 革 ，: 使 1 1 用 這 組 成 物 可 能 製 造 出 適 用 於 所 有 應 用 m 如 鞋 子 家 1 t - 11 - 1 1 本紙張尺度適用中國國家標準（CNS ) A4規格（2I0X297公釐） 426739 經濟部中央標準局員工消费合作社印製 A7 B7五、發明説明（) 具，汽車，和皮包製品之皮革-新顆組成物同樣也合適於 生皮的鞣製和上油，且皮毛的保留極不受影響: 皮革的製造可於習知用於濕法修整之所有糙器中，例 如料缸，Dosamat，鞣器或混合器中道行。 I I 製造 > 例如，經由進料預鞣皮革|例如藍濕皮或白濕 皮，在1 0至5 (TC百分之5 Q至3 I] ΰ %的水，Μ基質的重量為 基礎，然後加入5至3 D %的新_組成物及將其於設定溫度 留置3 0至1 δ 0分鐘，同時循環。其次，如果須要的話，經 i 5分鐘期間二部分加入卜3 %之甲酸及袴壤處理4 Q至6 0分 鐘。然後排出水溶液，皮革在1 0 G至3 Q 0 %的水中洗滌5至 1 0分鐘，排出洗液，與皮革如習知地完成> 如果除了鞣劑和上油劑以外不包含其（也活性物質的新 顆組成物被製成，則其次的處理步驟，如中和，染色和修 整，可如習知地進行。 本發明因此額外提供一種製造皮革和生皮的方法，其 包括在水溶液中以包括下列成份之組成物處理預鞣皮革或 生皮 a ) —種鞣劑與 b ) —種上油劑Μ及，若需要的話， c)進一步添加劏 且於加至[Q至6 G t至少八倍之水量中時製得均勻混合物之 形式存在。 藉由根揀本發明的方法*獲得與在分別步.琢中W鞣劑 -1 2 - 本紙張尺度適用中國國家標準（CNS ) A4规格（2I0X297公釐） ^ *裝 訂 ^ > (贫先閱讀背面之注意事項再填寫本頁) 經濟部中央標隼局貝工消費合作杜印製 426739 A7 B7五、發明説明（v\ ) 和上油劑進行處理製得之皮革的情形相同或更佳品質的皮 革。 下列實例說明本明而不用K限制本發明：份及百分比 Μ重量計ΰ溫度M °C表示。 I 實例1 :在室溫下混合下例成份Μ形成一種均勻溫合物： 1 2 . 5份的中和劑（芳族磺酸與脂族二羧酸之混合韧的约3 5 水溶液）， 1 2 . 3份的滲透輔助劑（芳族磺酸的縮合產物之約5 Q %水溶 液）， 1 0 . 0份的鞣劑（植物性鞣劑和具有鞣製作用之芳族碉的混 合物之約5 0 %水溶液）， 1 5 . 0份的鞣劑（酚硼酸和芳族羥基厢的縮合產物之约5 5 % 水溶液）* 4 7 . 5份的上油劑（以亞硫酸化天然和合成性脂肪為基礎的 上油劑之約5 G %水溶液）和 2 . 5份用於上油劑之安定劑（硫酸化脂肪醇）， 混合物在大氣壓和在1 1 ΰ QC下噴菘乾燥以產生一1粉 末，其逋合於藍濕皮和白濕皮的濕法修整，特刖是用於袈 造家具和汽車装飾皮革K及鞋子皮革。 實例2 ··在室溫下混合下例成份以形成一種均勻混合物： 1 2 . 5份的中和劑（芳族磺酸與脂防族二梭酸之溫合物的約 3 5 %水溶液） i 2 . 5份的滲透铺助劑（芳族磺酸的縮咅產物之約5 Q %/水溶 -1 3 - 本紙張尺度適用中國國家標準（CNS )八4規格（210X297公釐） ~~ --------^ 裝-----.—訂---^---f 線 - ' . . {^先閱讀背面之注意事項再填寫本頁) 426739 A7 B7 經濟部中夬標準局員工消費合作杜印製426739 A7 __B7_ V. Description of the invention (丨) The present invention relates to novel products that can be tanned and oiled pre-tanned leather and hides at the same time. The method of manufacturing these compositions and the composition of these materials use. In the manufacture of leather, pre-tanned leather is usually first neutralized, then tanned, oiled, and then dyed and further processed if necessary: the operation of K neutralization is usually performed in separate baths or in a continuous bath It takes place in a bath, but it can also happen in the same bath at the same time. The products produced in such operations are usually not intended for use in solid or liquid form, because it is not easy to prepare homogeneous, homogeneous warm compounds. Oiling agent * In fact, it is almost limited to liquid or at least waxy and existing methods and solid ingredients, such as neutralizers and tanning preparations cannot be processed to obtain a uniform distribution of the ingredients and sufficient satisfaction in time and temperature Storage stable mixture. A novel manufacturing method has been discovered which allows the wet finishing of leather to be significantly simplified, as it is possible to complete tanning with oil K and, if appropriate, further processing using only one composition. The reason is that these compositions include tanning agent and oiling agent added at least eight times 1Q to 6 (TC in water to produce a homogeneous mixture. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (Before reading the precautions on the back) Refill this page} To your surprise, there is a synergistic effect when using novel compositions. Compared to the steps in which individual chemicals are used • It may significantly reduce the use of tanning agents and oiling agents, regardless of conventional tanning agents Facts of use with oiling agents: _ When using novel compositions, in particular, improved fat emulsification can be used in smaller amounts. Once the new composition is used, it has excellent storage stability and solid composition. The condition of the material is antifreeze -3- This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X.297 mm) printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 426739 A7 ___B7 V. Description of the invention (1) As compared with the use of specific compositions in individual processing steps. When using the cut chopsticks, it may significantly reduce the requirements for transportation and storage, and the operation is singled out by it: and, The finished product has a water content and time that is as high as 60%, and is beneficial to the quality of the leather produced. In addition, the use of new particles or objects to accelerate the penetration and / or increase the distribution of IB products To the leather, for example, the better dye penetration of the leather, and at the same time, K has an advantageous way to affect important properties of the leather, such as water resistance, fogging behavior, adhesive strength of the trimming film, stretch and strength properties, and each Mass per unit area. Therefore, the present invention provides a composition for manufacturing leather and hides, including a) a tanning agent and b) an oiling agent M, if necessary, c) further additives and M added to at least Eight times the presence of 10 to i5 Of in water when a homogeneous mixture is produced. The novel composition is better than M so that the composition can be evenly distributed in water from U to 6 rc through the conventional combination of M, and K is formed in the form of a suitable suspension or dispersion during leather processing: here by stirring The conventional combination of polyester and polyester refers to the simple use of agitators used in the leather industry to accompany new amounts of composition preferably when added to water. They form microbubbles of S tanning agent and oiling agent. In a dispersion or suspension, preferably 5 ϋ% of the particles contain a size of less than 5 microns. Specially formulated for these Jin Ying compositions when added to water, the paper size of the paper is adapted to the Chinese National Standard (CNS) A4 specification (2iOx297 mm) _ (" Please read the precautions on the back before filling this page ) 4 2 67 3 9 a7 B7 V. Description of the invention (,) The processing of the product is' Semi-small-V.7 Large 1's rice repair method slightly wet ο spoon 4 0 ΑZ Tian Dan TT1D lower than all zygotes to ¾ group was of 90 Ying new front which like ΠΠ sub 'embodiment transdermal il suitable white Hopewell skin source wet to 0., into such engagement Μ or' natural leather TOPLIFT of wheel band may be pre-agent, 0 as Example agent Tanning tincture tanned into Γ-4 mouth 0 family tanning aromatic, polymeric agent and tanning agent tanning physical plants such as mineral tincture, physical agent tanning fb reaction should be used, wood and other rubber should be 'wood The agent is hard-tanned, and the content of plants and plants is suitable for others. Specialty, tincture, tea-tanned, or tannin-like pine trees, or five < 1 mouthful of tree chestnut containing, including aromatic aldehydes suitable for 7 and or alone or Urinary tanning, serotonin sulfide. Family flavones < 10 and fb-group aromatic ib acid sulfonyl sulfide 由 等 g g g 常 常 常 常 常 常 常 常 ^ ^ 0 0 agent til & Aromatic sulphonic beta is 4 'DH 4 of the compound V of aromatic compound in Changtong naphthalene as an example. This age is suitable for cresol θ · borylbenzene dihydroxy naphthalene Γ 1,2, biphenyl-phenylbenzene control Second (please read the precautions on the back before filling out this page) Double Enigma 2-Base 2'Stupid »Mesip Diphenyl and Benzene Benzene-Di-ft such as acid and sulfonium 0 The stilbene body itself is suitable for the special tanning ------- ordering ---- line under the urethane phenyl hydroxy group formation of <lt -Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, the product is' condensed '0 formaldehyde <10, and shrunken formaldehyde or cresol and acid acid sulfonyl naphthalene acid 0 group Aryl \ l · / group (M or acid 0-based aromatic and 0-based benzene dihydric product acetal methyl m 0 methyl of ft halo fluorene aromatic compound <! ib hydroxy hydroxyl aromatic sulfide The paper size of this paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 426739 A7 B7 V. Description of the invention () {V) Phenol and phenolsulfonic acid Urea-formaldehyde condensation product (v I) is the reaction product of phenol and sulfonium sulfonate, in which the morin ratio (phenol): (s ΰ 3) is U): (ί to 2.2). (VII) Suspected product of sulfonic acid ft diaryl ether and formaldehyde, (VIII) sulfonated biphenyl or bitriphenyl condensation product with formaldehyde, (IX) H-dihydroxydiphenyl ether and sulfonic acid ib Condensation products of 4, ''-dihydroxydiphenylphosphonium with formaldehyde, (X) Formaldehyde condensation products of diarylhydrosulfonic acid and 4, 4'-dihydroxydiphenylphosphonium 1 (XI) phenol and aromatic Formaldehyde condensation products of sulfonic acid or hydroxyaryl sulfonic acid: · These condensation products are in the form of free acid, which is more sulfonic acid or sulfonium salt, especially ammonium, lithium, potassium or, especially sodium salt of the formula- · The vertical contraction of jaundice is known at the beginning of birth. For example, from 0 1 1 ma η ns E nzyk 1 〇 padie der technischen Chemie Volume 1δ (4), pages 138 to 14 () (1979), or can be borrowed Manufactured by the method described in the reference materials shown therein. Suitable resin tanning agents are nitrogen-containing organic compounds such as urea, thiourea, difluoroamine or polyfluoroamine, and formaldehyde A cationic association product of a copper-based compound. Other suitable resin tanning agents are anionic ib compounds, which are hidden from organic compounds containing nitrogen, such as Element > tartar * dicyandiamide or polyamine * and formaldehyde or its ibm pure compound and ib compound with female chicks | such as phenol, alkali metal alliance of aromatic sulfonic acid, sulfonylamine, wood Condensation product of quality sulfonate, sulfite or chlorosulfite: -------- ^-装 -----—. 11 ---_-- f 猓 Read first Note on the back, please fill in this page again.) This paper size applies to the Chinese national standard (CNS > A4 size (210 '× 297 mm > 426739), printed by the staff of the Central Standards Bureau of the Ministry of Economic Affairs, A7, B7, and F5' invention description. <;) A good resin fat tanning agent is a product of urea and formaldehyde, and R-diazide diamine is used as a resin tanning agent. Suitable reactive tinctures are mono, di and poly > Hold glutaraldehyde, polyfunctional isotonic acid, alkyl sulfonate, alkyl sulfonate with higher molecular weight II as well as monomer vinyl derivatives and acrylic acid derivatives and their polymerization Suitable mineral tanning agents are known rhenium, aluminum, rhenium or shackles, such as chromium (III) chloride or chromium tellurate, sulfonium alum, non-alkali or alkaline nitrogen it aluminum Aluminum sulfate > Ammonia iron (III) or iron sulfate (11 I), oxygen (bisulfate and sulfuric acid. Examples of suitable polymerizable tanning agents are polyacrylates, including acrylate * polyurethane or polybutadiene These tanning agents are known and commercially available in large quantities: In the novel composition, the tanning agent used is preferably a vegetable-based tanning agent > an aromatic tanning agent or a reactive tanning agent A suitable oiling agent is a conventional oiling agent generally thrown on leather. A) Oiling oil based on animal fats, such as fish oil, cattle foot oil, wool oil or lard, b) M plant Grease-based oiling agents, such as sesame oil, coconut oil, or dioxin, c) Containing organic oils, such as the products of nitriding or sulphurization of synthetic oils; synthetic fats Esters and ester oils, or (please read the notes on the back before filling this page) This paper size is applicable to China National Standards (CNS) A4 specifications < 210X297 mm) Printed by the Consumers' Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs Crack 4267 3 9 A7 ______87_ V. Description of the invention (b) d) Mineral oil or Oil product: These oiling products are preferably modified from sulfonated or subsulfated or formed into a sulfonic acid form, so they can be dissolved or emulsified in water: it is also possible to use oiling mixtures. Part of milk I with emulsifying properties and as the remaining part: "A suitable example of a product containing this purpose is sulfonated fatty alcohol oiling, preferably an aqueous solution of M or milk, it is used to make: The composition of the leather may include a neutralizer, a tanning agent, and an oiling agent in each case, or may include a mixture of two or more paints in each case. In fact, this is like a peculiar shape, because these compounds are extremely pure substances, but instead of including most technical mixtures, how many phases (W compounds). In addition to tanning agents and oiling agents, novel leather treatment compositions can include Further additives, nets such as neutralizing agents, warfare agents, colorants, penetrating agents, finishing agents and finishing finishing additives. Suitable neutralizing agents are known fb compounds, which can be used for mild neutralization And strong acid 'pretanned leather. Neutralizers include such compounds that increase the PΗ value of strong acid pretanned leather, for example, to 4,5, but not to reach a neutral ρ η value of 7. For novel composition Examples of suitable neutralizing agents are alkali metal salts without meals or weak acids; aromatic sulfonic acids, or aliphatic acids, monocarboxylic acid, which preferably include sodium bicarbonate or sodium bicarbonate, formic acid or sodium or potassium acetate, Oxalic acid, sodium malonate or ammonium or condensed phenols: Individually suitable are sodium bicarbonate, sodium formate, acetic acid, adipic acid or sulfonated dibenzyl. Examples of suitable carriers are sodium chloride fb , Glauber's salt, sodium formate, protein Xiao dress up -------- y outfit ------- order ---_--- yu (谏 Please read the notes on the back before filling in this page) Consumption cooperation by the Central Bureau of Standards of the Ministry of Economic Affairs 4267 3 9 A7 B7 V. Description of the invention (1) At the end, palace powder, kaolin, polysaccharides, glucose or gelatin: proper coloring The agent is a leather coloring agent generally used, such as a natural coloring agent, and a synthetic coloring agent * such as an anionic dye, a gold-complex dye, a direct dye, a cationic dye, or a sulfur dye. That is, a large amount of insoluble pigments in water are permeated and the composition is known to be used in the leather industry.% For example, water-repellent, anti-repellent solvent or oil-proof agent or anti-a agent Scratching or other mechanical damage agents, agents that improve temperature stability or light fastness, and agents that reduce flammability, or antistatic properties. Examples of suitable dressing agents are primers (b ◦ 1.1 qming) | As polyacrylates, butadiene copolymers or polyurethanes, or finishing agents, such as prion protein, nitrocellulose or polyurethane formulations. A suitable finishing aid is Tong Yang Already And products that are actually utilized, such as penetrants, primers and fillers, anti-sticking agents, thickeners and stabilizers, softeners, matting agents, fixatives and fixing agents3 novel compositions for the manufacture of leather It preferably includes a) 0 to 80% by weight of a tanning agent, b) 5 to 50% by weight of an oiling agent, and c) 0 to 55% by weight of a further additive. The preferred composition is solid at a temperature of 40 ° C. It may use a dispersion in a suitable solvent (preferably a solution in water) or a new composition that dissolves in the form of a new type suitable for the manufacture of leather.颉 Composition S including -9-This paper wave scale is applicable to China National Standard (CNS) A4 specification (2.0 × 297 mm) I ^ I installed ------- Order ----- γ Silver ¢ ^- Read the precautions on the back before filling out this page) Printed by the Consumers' Cooperatives of the Ministry of Economic Affairs and Standards Bureau 426739 A7 B7 V. Invention Description (?) A) 1 G to 6 0% by weight of tanning agent-b) 1 ( ] To 彳 5% by weight, c) 1Q to 4Q% by weight of a neutralizer, and d) 0 to 4% by weight of a further additive. Among them, * holding good is that these compositions include; 〇2 卩 to 6 (]% by weight of tanning agent, b) 1 ϋ to 4Q% by weight of oiling agent, c) 10 to 25% by weight of neutralization Agents, and d) 2 to 35% by weight of further additives. The percentages in each case are based on the total weight of the composition that treats the leather. The novel composition is manufactured in a manner known per se * such as a tanning agent, an oiling agent combined with, if necessary, an undiluted form, Further additives and another ingredient. In this case, the tanning and oiling agents and further additives present must be selected so that the resulting composition will be a homogeneous mixture when added to water at least eight times 1 f] to 60 f. However | It is preferred to use tanning agents such as solutions or suspensions, or dispersions, oiling agents and any other additives, warm them, and then dry the mixture. In the case of lysates, suspensions and dispersions, the The solvent used is water, although preservative solvents such as osmium or polyols or hydrocarbons are also suitable. Produce a mixture, for example, at a temperature between 1 α and 6 G υ, preferably -10-This paper size applies the Chinese National Standards (CMS) Α4 specification (210 X 297 mm) ----- --- J! .- Pack ------ Order --- 1 -----(Read the precautions on the back before filling this page) 4267 3 9 A7 B7 Staff of the Central Government Bureau of the Ministry of Economic Affairs Consumption cooperation Du printed 5. Description of the invention [^ 'I 1 is at room temperature, which is between about 1 ί and 1 5' 3 ift combined * preferably-1 1 I »It must be evenly divided as desired The group of suspensions or liquids present or% if necessary 可 1 I can be handled by appropriate treatment such as t using a mm companion or please £ 1 1 read | ultrasonic processing to achieve read back | 1 干 m m Μ The conventional method produces but should be performed normally under the uniform distribution m pieces of note 1 I i i | Ingredients are easy to dissolve. 1 Solution in water or easy to fb or disperse and dry out. The method is C of M 11 and then fill in 1. This book is best to use. The method that produces drying very quickly. Page 1 Drying is better by about 80. To 140 ° ° C. Spray drying from 100 to 1 2 0 1 1 is carried out. 0 1 1 It is also possible to spray solution suspensions or dispersions to taT m. m raw materials such as sodium chlorite sodium formate protein powder I powder and simultaneously or subsequently dried i mulberry 0 1 according to this jib method novel composition to obtain r; flake or m granular form 1 1 which can be used in this form to The aqueous composition line 1 1 for the leather manufacturing is non-pink ridge, which is easy to distribute evenly in water and even in extended storage and at a temperature of about 40 VK S is maintained at a flow rate. If the raw material of the carrier 1 is not used or the non-m-shaped compound is used as the raw material of the carrier i, the novel composition can be manufactured in the form of a salt or a low form. It is also advantageous for R-injection-丄 ii ·: > Processing: 1 ί In the case of simultaneous or subsequent dyeing and reducing the burden on the environment 1 new composition suitable for the manufacture of different types of leather m such as goats * 1 1 full-thick light or heavy-duty leather of sheep cattle or pigs or Suede leather: make it possible to use 1 1 with this composition to make it suitable for all applications m such as shoe home 1 t-11-1 1 This paper size applies to Chinese National Standard (CNS) A4 (2I0X297 mm) 426739 Ministry of Economic Affairs A7 B7 printed by the Consumers' Cooperative of the Central Bureau of Standards 5. Description of the invention () Leather, new leather composition of tools, automobiles, and bag products are also suitable for tanning and oiling of hides, and the preservation of fur is extremely unaffected: Leather manufacturing can be used conventionally In all wet finishes, such as tanks, Dosamat, tanners or mixers. II Manufacture> For example, pre-tanned leather via feed | such as wet blue or white wet leather, based on the weight of M substrate at 10 to 5 (TC 5 Q to 3 I) ΰ% water, Then add 5 to 3 D% of the new composition and leave it at the set temperature for 30 to 1 δ for 0 minutes while cycling. Secondly, if necessary, add 3% of formic acid in two parts over 5 minutes. Soil treatment 4 Q to 60 minutes. Then drain the aqueous solution, wash the leather in 10 G to 3 Q 0% water for 5 to 10 minutes, drain the lotion, and finish the leather as conventionally > A new composition containing no active ingredients other than the oiling agent is also made, and the subsequent processing steps, such as neutralization, dyeing and finishing, can be performed conventionally. The present invention therefore additionally provides a method for manufacturing leather And a method of hides and skins, which comprises treating pretanned leather or hides in a water solution with a composition comprising the following ingredients: a) a tanning agent and b) an oiling agent M and, if necessary, c) further adding 劏 and Forms a homogeneous mixture when added to at least eight times the amount of water from [Q to 6 G t Exist. By the method of the present invention * to obtain and in separate steps. Zhuozhong W Tanning Agent 1 2-This paper size applies the Chinese National Standard (CNS) A4 specification (2I0X297 mm) ^ * Binding ^ > (poor first (Please read the notes on the back and fill in this page.) Printed by the Ministry of Economic Affairs, Central Bureau of Standards, Shellfish Consumer Cooperation, Du printed 426739 A7 B7 5. The invention description (v \) and the leather made by the oil treatment are the same or better Quality leather. The following examples illustrate the invention without limiting the invention by K: parts and percentages are expressed in terms of weight, weight, temperature, and ° C. I Example 1: Mix the following ingredients M at room temperature to form a uniform warm compound: 12.5 parts of neutralizer (aqueous solution of about 3 5 of aromatic sulfonic acid and aliphatic dicarboxylic acid), 12.3 parts of penetration aid (about 5 Q% aqueous solution of condensation product of aromatic sulfonic acid), 10.0 parts of tanning agent (approximately a mixture of vegetable tanning agent and aromatic tincture for tanning) 50% aqueous solution), 15.0 parts of tanning agent (approximately 55% aqueous solution of condensation product of phenol boric acid and aromatic hydroxyl compartment) * 47.5 parts of oiling agent (natural and synthetic sulfite) About 5 G% aqueous solution of oil-based oiling agent) and 2.5 parts of stabilizer (sulfated fatty alcohol) for oiling agent, the mixture was spray-dried at atmospheric pressure and 1 1 ΰ QC to produce A 1 powder, which is combined with wet finishing of blue wet skin and white wet skin, and is especially used for making furniture K and shoe leather. Example 2 ·· The following ingredients were mixed at room temperature to form a homogeneous mixture: 12.5 parts of a neutralizer (about 35% aqueous solution of a warm compound of an aromatic sulfonic acid and an aliphatic disoteric acid) i 2.5 parts of permeation aid (about 5 Q% of the shrinkage product of aromatic sulfonic acid / water soluble-1 3-this paper size applies to China National Standard (CNS) 8 4 specifications (210X297 mm) ~ -------- ^ Install -----.— Order --- ^ --- f Line- '.. (^ Read the notes on the back before filling this page) 426739 A7 B7 Ministry of Economic Affairs消费 Standards Bureau employee consumption cooperation
五、發明説明 (xly 1 1 I 液 )， 1 1 | 10 G份 的 鞣 m (丙烯酸酯共聚合物之約;] 〇%水溶液） » 1 1 15 .〇份 的 鞣 劑 芳族 羥 基礙和 碌 酸 的 縮 產 物 之 约 5 3 % 水 I k 1 1 閲^ I 溶 液） 讀 背 1 1 » 1¾ 4 7 .5份 的 上 油 劑 (M 亞 硫酸化 天 然 和 合 成 性 脂 肪 為 基 m 的 之 注 1 I 意 \ | 上 油劑 之 约 50¾ 水溶 液 )和 事 ί§ 1 I 再 2 . 5份的用於上油劑之安定劑（硫 酸 fb 脂 肪 醇 ) 填 1 氣壓 寫 本 裝 混 合 物 在 大 和 在u 〇 下 噴 霧 乾 燥 以 產 生 — 種 粉 頁 1 I 末 ，其 適 合 於 藍 濕皮 和 白濕皮 的 '濕 法 慘 蝥 特 別 是 用 於 製 1 1 造 家具 和 η 車 裝 飾皮 革 Κ及鞋 子 皮 革 [ 1 實 例3 在 室 溫 下混 合 下例成 份 W 形 成 __. 種 均 勻 混 .合 物 訂 2 4 _ 〇份 的 m 劑 (環狀 化 含抅之 賜 和 磺 酸 的 縮 合 產 物 之 约 50 [ % 水溶 液 ) [ 20 .0份 的 鞣 m ( 植物 .ί生 鞣劑及 有 鞣 製 作 闬 之 芳 族 的 混 合 1 | —ί 物 之約 5 0% 水 溶 疲） 線 2 0 .0份 的 液 II 三 聚氪 胺 樹脂， 1 I 12 _ 〇份 的 鞣 劑 (丙烯酸酯聚合物的约3 0%水溶液） 和 [ I 2 4 ‘ 〇份 的 上 油 劑 (以 亞 硫酸化 天 和 合 成 性 脂 肪 為 基 Ί 礎 的上 油 劑 之 约 50% 水 溶液） 1 1 混 合 物 在 大 氣壓 和 在1 10 X:. 下 噴 乾 燥 Μ 產 生 撞 粉 1 末 ，其 適 合 於 藍 濕皮 和 白濕皮 的 濕 法 修 m 特 別 是 用 於 p i 1 I 造 鞋子 面 革 〇 1 1 黃 例4 將 — 塊 m m 皮 (牛）敗 置 於 有 30 :C 的 ISO % 之 水 的 1 1 -1 1 - 1 I 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 426739 B7 五、發明説明（4 ) 染缸中，和加人1 . 5 %之碳酸氫钠。i D分鐘之後，加入1 0 %實例：L的組成物和皮革於3 (TC處理G分鐘 > 然後加入丨Ο ϋ %水和將溫度上昇至6 (PC :經過i Q分鐘*二部份加人2 % 的甲酸及持缄處理3 〇分鐘：然後排出水溶液，庋革於200 %的冷水漂洗5分鐘且如習知地完成=: 所產生的皮革顯著比智知方法所製得之皮革柔钦，在 其製俺中 < 中和，鞣製和上油已個別地在一系列中進行。 此外|其明顯改善撕裂強度，和降低孬化值同時降低製造 成本。 實例5 :在室溫下混合下例成份以形成一種均勻混合物： 1 2 . 5份的中和劑（芳族磺酸與脂族二羧酸之混合物的約5 0 %水溶液）， i 2 . 5份的滲透輔助劑（芳族磺酸的縮合產物之約5 Q %水溶 m )' 1 0 . 0份的輮劑（植物性鞣劑和具有鞣製作周之芳族通的縮 合產物之溫合物的約5 α %水溶液）， U . ΰ份的鞣劑（苯酚磺酸和芳族羥基頭之縮合產物的約5 5 %水溶液）* 4 7 . 5份的上油劑（Μ亞硫酸化天然和合i成性脂肪為基礎的 上油劑之约5β%水溶液）， 2 . 5份的於上油劑之安定劑（硫酸（b脂肪_)， 3 2 . Q份的水性染劑調配物，包含4 (3重量％的黑色染科 C . I 酸性黑2 1 G，與 -1 5- 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 297公釐） n^— 1 1— - -1. , 1— hh - m in 一 J I. m t4 (背先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作杜印製 426739 A7 B7 五、發明説明（4 ) 物 配 , 調 燥 料乾 染霧 性嗔 水下 之V 笔 ο 1; 1 碳ί% 蠆 重 ο 5 约 含 包 的 份 在 和 壓 氣 大 在 物 合 曰比 ' yf* 物 -vf 勻 均 種 I 成 形 M 汾 成 例 下 合 混 下 溫 室 在 6 dHJ 扠 實 劑 鞣 性 物 植 的 份 約 之 物 產 含 縮 的 瓯 族 芳 之 用 作 製 鞣 有 具 /rv 劑 的液 份溶 ο水 15¾ 約 V—/ ιΓη 液 物 溶 合 水混 的 之 物酸 聚羧 共 二 酷族 酸肪 烯脂 丙與 ¾酸 40磺 族 1(芳 0 ( 肋 透 滲 的 份 劑 和 中 的 份 液 溶 水% 液 溶 水 妬 ο 4 約 之 物 產 合 0 的 酸 磺 族 芳 /V 劑 肋 輔 透 滲 的 份 的 礎 基 為 肪 脂 性 成 合 和 然 天 fb 酸 硫) 亞液 M溶 ί水 劑 ％ 油50 上妁 的之 份劑 5 由 . 30上 硝 芒 -—. 劑 載 的 份 粉製 種於 一 用 生 是 產別 Μ特 燥 -乾整 霧修 噴法 下濕 Ρ 的 ο 皮 11濕 在白 和和 壓皮 氣濕 大藍 在於 物合 合 適 混其 末 (资先閱讀背面之注意事項再填寫本頁) |裝· 訂 經濟部中央樣準局員工消費合作社印製 的 水 之% ο 3 的 Ρ ο 3 有 於 置 放 '—/ 牛 皮 濕 藍 塊 J 1 革將 面 ： 子 7 鞋 授 餚實 分30 60於 里 里 TJ M-\ 處 處 r- 及 Q 3 ο 人、.' 1 5 2 革 里ί 皮性 和 酸 物I. 成 C 組料 的染 6 里| 例碳 實的% % . Ιο I 3 J 入入鐘 加加分 和後90 ’ 然行 缸。進 染鐘 Ρ 分液 10溶 過水 涇 出 br V 後 60然 至 「. 昇 鐘 上分 度30 溫續 將繼 及理 水處 的及 % 酸 ο 甲 20的 < % 加 1 後人 然加 鐘 本紙浪尺度適用中國國家揉準（CNS ) A4规格（210X 297公釐） 426739 A7 B7 五、發明説明（5 ) 在 。 ο ， 行 成 钦 進 完 m 中 地革列 知 皮集 習之 一 如得在 且製地 鐘所別 分法個 L0 方已 洗知油 漂 晋 上 水比和 冷著製 的顯鞣 ¾革， Q 皮和 2 的中 於生 ， 革產中 皮所餚 將 製 ’ 其 (，請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家橾準（CNS ) A4規格（210X 297公釐）V. Description of the invention (xly 1 1 I solution), 1 1 | 10 G parts of tanning m (approximately acrylate copolymer;] 0% aqueous solution) »1 1 15. 0 parts of tanning agent aromatic hydroxy hinders and Approximately 53% of the condensation product of uric acid Water I k 1 1 ^ ^ I solution) Read back 1 1 »1 ¾ 4 7 .5 parts of oiling agent (M sulfite natural and synthetic fats based on m Note 1 I means (approximately 50¾ water solution of oiling agent) and things ί§ 1 I and then 2.5 parts of stabilizer for oiling agent (sulfuric acid fb fatty alcohol) Fill in 1 air pressure book containing the mixture in Yamato in u 〇 Spray drying to produce — a kind of powder sheet 1 I, which is suitable for the 'wet method of blue wet skin and white wet skin, especially for making furniture 1 and car decoration leather K and shoe leather [1 Example 3 Mixing at room temperature In the following example, the ingredient W forms __. Homogeneous mixtures. The compound is 2 4 _ 0 parts of the m agent (about 50 [% aqueous solution] of the cyclic condensed product containing osmium sulfonium and sulfonic acid] [20.0 parts of Tanning m (vegetable. Mixed with tanning agent and aromatic with tanning 1 1 ~-about 50% water soluble) Thread 2 0. 0 parts of liquid II melamine resin, 1 I 12 _ 0 parts of tanning agent (approximately 30% aqueous solution of acrylate polymer) and [I 2 4 '0 parts of oiling agent (approximately based on sulfite and synthetic fat-based oiling agent 50% aqueous solution) 1 1 mixture is spray-dried at atmospheric pressure and at 1 10 X :. M produces powder 1 which is suitable for wet repair of blue wet and white wet leather, especially for pi 1 I shoes Leather 01 1 Yellow Example 4-mm leather (cow) lose to 30 : C ISO 1% of water 1 1 -1 1-1 I This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) A7 426739 B7 V. Description of the invention (4) In the dyeing tank, and add 1 . 5% sodium bicarbonate. After i D minutes, add 10% Example: the composition of L and leather at 3 (TC treatment G minutes) and then add 丨 ϋ ϋ% water and raise the temperature to 6 (PC: after i Q minutes * two parts Add 2% formic acid and hold it for 30 minutes: then drain the aqueous solution, rinse the leather in 200% cold water for 5 minutes and finish it as usual =: the leather produced is significantly better than the leather made by the Zhizhi method Rouqin, in its manufacturing process < neutralization, tanning and oiling have been performed individually in a series. In addition | it significantly improves tear strength, and reduces the curing value while reducing manufacturing costs. Example 5: in the room The following ingredients were mixed at a warm temperature to form a homogeneous mixture: 12.5 parts of a neutralizer (about 50% aqueous solution of a mixture of aromatic sulfonic acid and aliphatic dicarboxylic acid), and 2.5 parts of penetration aid Agent (about 5 Q% water-soluble m of the condensation product of aromatic sulfonic acid) '10.0 parts of tincture (vegetable tanning agent and the temp condensate of the condensation product with the aromatic pass of the tanning process, about 5 α% Aqueous solution), U. Part of tanning agent (approximately 55% aqueous solution of condensation product of phenolsulfonic acid and aromatic hydroxyl head) * 4 7. 5 parts of oiling agent (about 5β% water solution of sulfite-based natural and synthetic fat-based oiling agent), 2.5 parts of oiling agent stabilizer (sulfuric acid (b fat_), 3 2. Q parts of water-based dye formulations, including 4 (3% by weight of Black Dyestuff C. I Acid Black 2 1 G, and -1 5-This paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) n ^ — 1 1—--1., 1— hh-m in 1 J I. m t4 (Read the precautions on the back first and then fill out this page) Staff Consumer Cooperation of the Central Standards Bureau of the Ministry of Economic Affairs Printed 426739 A7 B7 V. Description of the invention (4) Material distribution, dry dyeing, fogging, V pen under water ο 1; 1 carbon %% 虿 weight ο 5 Inclusive of the content and pressure He Yuebi 'yf * 物 -vf homogeneous species I forming M Fen as an example mixing under the greenhouse in 6 dHJ fork solid agent tanning plant planting properties of the condensed scented scented fragrant used as tanning equipment / The solution of rv agent is dissolved in water 15¾ about V— / ιΓη liquid material is mixed with water and mixed acid acid polycarboxy co-diacid fatty acid acrylate ¾ Acid 40 Sulfur 1 (Aromatic 0 (Ribose Permeable Parts and Liquid Dissolved Water %% Liquid Soluble Water) ο 4 Properties of 0 Sulfur Sulfur Aromatic / V Agent Ribs Supplement Permeable Parts The basis is fatty composition and natural fb acid and sulfur) sub-liquid M soluble water agent% oil 50 parts of the top 5 5 parts from 30 on nitrate ---. It is produced by special dry-dry and mist-repairing method. Peel 11 is wet in white and pressed in the air and wet blue. It is suitable for mixing (read the precautions on the back before filling this page) ) | Binding and ordering% of water printed by employees of the Central Procurement Bureau of the Ministry of Economic Affairs. Ο 3 of the ο 3 ο 3 to be placed '— / cowhide wet blue block J 1 leather noodles: child 7 30 60 in Lili TJ M- \ everywhere r- and Q 3 ο person,. '1 5 2 leather leather and acid I. 6 dyes into C-group | example carbon%%. Ιο I 3 J into the bell to add extra points and after 90 'then line the cylinder. Into the dyeing bell P, liquid separation 10, dissolving in water and br V 60, and then reaching "30. Dividing on the clock 30, the temperature will continue to be followed by the water management and the% acid ο A 20 <% plus 1 and then In addition, the scale of the paper wave is applicable to the Chinese National Standard (CNS) A4 (210X 297 mm) 426739 A7 B7 V. Description of the invention (5) In. Just as in the case of the local clock, the L0 side has been washed to know the oil bleaching, the water ratio and the cold-made tanned ¾ leather, Q leather and 2 in the middle of the raw, leather and middle skin will be cooked ('Please read the notes on the back before filling out this page) The paper size printed by the Employees' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs applies to the Chinese National Standard (CNS) A4 (210X 297 mm)